TWI878645B - 用於分離甲醇和(甲基)丙烯酸甲酯之方法 - Google Patents
用於分離甲醇和(甲基)丙烯酸甲酯之方法 Download PDFInfo
- Publication number
- TWI878645B TWI878645B TW111104240A TW111104240A TWI878645B TW I878645 B TWI878645 B TW I878645B TW 111104240 A TW111104240 A TW 111104240A TW 111104240 A TW111104240 A TW 111104240A TW I878645 B TWI878645 B TW I878645B
- Authority
- TW
- Taiwan
- Prior art keywords
- meth
- methanol
- acrylate
- formula
- methyl
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/02—Preparation of carboxylic acid esters by interreacting ester groups, i.e. transesterification
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/009—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping in combination with chemical reactions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/34—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping with one or more auxiliary substances
- B01D3/40—Extractive distillation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
- C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
- C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
- C07C29/84—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation by extractive distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/02—Monohydroxylic acyclic alcohols
- C07C31/04—Methanol
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
- C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
- C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
- C07C69/54—Acrylic acid esters; Methacrylic acid esters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
- B01J2231/49—Esterification or transesterification
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/46—Titanium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP21157515.4 | 2021-02-17 | ||
| EP21157515 | 2021-02-17 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW202246205A TW202246205A (zh) | 2022-12-01 |
| TWI878645B true TWI878645B (zh) | 2025-04-01 |
Family
ID=74666517
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW111104240A TWI878645B (zh) | 2021-02-17 | 2022-02-07 | 用於分離甲醇和(甲基)丙烯酸甲酯之方法 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US11952336B2 (https=) |
| EP (1) | EP4294782A1 (https=) |
| JP (1) | JP2024507195A (https=) |
| KR (1) | KR20230147142A (https=) |
| CN (1) | CN116867759B (https=) |
| CA (1) | CA3208372A1 (https=) |
| MX (1) | MX2023009670A (https=) |
| TW (1) | TWI878645B (https=) |
| WO (1) | WO2022175122A1 (https=) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW201615609A (zh) * | 2014-10-31 | 2016-05-01 | 陶氏全球科技公司 | 使用變壓蒸餾破壞甲醇/甲基丙烯酸甲酯共沸物 |
| TW201619116A (zh) * | 2014-09-30 | 2016-06-01 | 巴地斯顏料化工廠 | (甲基)丙烯酸c-c烷基酯之製備 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3338439A1 (de) | 1983-10-22 | 1985-05-02 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur destillativen aufarbeitung von wasser und methanol enthaltenden hoeheren alokoholen mit 6 bis 20 c-atomen |
| DE3803406C2 (de) | 1988-02-05 | 1997-02-13 | Roehm Gmbh | Verfahren zur Trennung von Methanol-Methylmethacrylat-Mischungen |
| US6093842A (en) * | 1998-09-25 | 2000-07-25 | General Electric Company | Process for continuous production of carbonate esters |
| DE10200171A1 (de) | 2002-01-04 | 2003-07-10 | Roehm Gmbh | Verfahren zur kontinuierlichen Herstellung von Alkyl(meth)acrylaten |
| JP2004189650A (ja) * | 2002-12-10 | 2004-07-08 | Mitsubishi Rayon Co Ltd | (メタ)アクリル酸エステルの製造方法 |
| DE502005003037D1 (de) | 2004-12-20 | 2008-04-10 | Evonik Degussa Gmbh | Verfahren zur rückgewinnung von methanol |
| GB0523340D0 (en) * | 2005-11-16 | 2005-12-28 | Ciba Sc Holding Ag | Manufacture of esters |
| EP1995231B1 (en) | 2007-05-25 | 2013-11-20 | Evonik Röhm GmbH | Process for preparation of methyl methacrylate using recycled methanol |
| EP1994978A1 (en) | 2007-05-25 | 2008-11-26 | Evonik Röhm GmbH | Process for preparation of methyl methacrylate by esterification during oxidation |
| JP5964180B2 (ja) * | 2012-08-27 | 2016-08-03 | 大阪有機化学工業株式会社 | (メタ)アクリル酸エステルの製造方法 |
| JP6132570B2 (ja) * | 2013-02-04 | 2017-05-24 | 大阪有機化学工業株式会社 | (メタ)アクリル酸エステルの製造方法 |
| CN105339341B (zh) * | 2013-06-27 | 2018-02-13 | 大阪有机化学工业株式会社 | (甲基)丙烯酸酯的制造系统 |
| CN103304371A (zh) * | 2013-07-01 | 2013-09-18 | 济南大学 | 甲醇-丙烯酸甲酯共沸混合物的间歇萃取精馏分离方法 |
| EP2886529A1 (en) | 2013-12-20 | 2015-06-24 | Evonik Industries AG | Process for producing methyl methacrylate |
| CN104311418A (zh) * | 2014-11-06 | 2015-01-28 | 旭阳化学技术研究院有限公司 | 甲醇与(甲基)丙烯酸甲酯混合物的共沸精馏分离及处理方法 |
| CN106699560B (zh) * | 2015-11-18 | 2020-08-14 | 上海浦景化工技术股份有限公司 | 一种含甲基丙烯酸甲酯的物流的分离设备与分离方法 |
-
2022
- 2022-02-07 MX MX2023009670A patent/MX2023009670A/es unknown
- 2022-02-07 JP JP2023549685A patent/JP2024507195A/ja active Pending
- 2022-02-07 KR KR1020237031543A patent/KR20230147142A/ko active Pending
- 2022-02-07 WO PCT/EP2022/052808 patent/WO2022175122A1/en not_active Ceased
- 2022-02-07 TW TW111104240A patent/TWI878645B/zh active
- 2022-02-07 US US18/546,583 patent/US11952336B2/en active Active
- 2022-02-07 EP EP22703408.9A patent/EP4294782A1/en active Pending
- 2022-02-07 CN CN202280015497.7A patent/CN116867759B/zh active Active
- 2022-02-07 CA CA3208372A patent/CA3208372A1/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW201619116A (zh) * | 2014-09-30 | 2016-06-01 | 巴地斯顏料化工廠 | (甲基)丙烯酸c-c烷基酯之製備 |
| TW201615609A (zh) * | 2014-10-31 | 2016-05-01 | 陶氏全球科技公司 | 使用變壓蒸餾破壞甲醇/甲基丙烯酸甲酯共沸物 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN116867759B (zh) | 2026-01-23 |
| WO2022175122A1 (en) | 2022-08-25 |
| US20240034711A1 (en) | 2024-02-01 |
| TW202246205A (zh) | 2022-12-01 |
| CA3208372A1 (en) | 2022-08-25 |
| CN116867759A (zh) | 2023-10-10 |
| KR20230147142A (ko) | 2023-10-20 |
| JP2024507195A (ja) | 2024-02-16 |
| MX2023009670A (es) | 2023-08-25 |
| US11952336B2 (en) | 2024-04-09 |
| EP4294782A1 (en) | 2023-12-27 |
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