TWI819349B - 半導體裝置及其製造方法 - Google Patents
半導體裝置及其製造方法 Download PDFInfo
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Abstract
在一實施例中,一種半導體裝置包括:源極/汲極區域,鄰接基板的通道區域;接觸蝕刻終止層,在源極/汲極區域上;第一源極/汲極觸點,穿過接觸蝕刻終止層延伸並連接到源極/汲極區域;閘極結構,在通道區域上;閘極觸點,連接到閘極結構;以及接觸間隔件,圍繞閘極觸點。接觸間隔件、閘極結構、接觸蝕刻終止層及基板共同界定一孔隙,孔隙位於閘極結構與第一源極/汲極觸點之間。
Description
本揭示的實施方式係關於半導體裝置及其製造方法。
半導體裝置使用在各種電子應用中,例如個人電腦、行動電話、數位攝影機及其他電子設備。通常透過以下操作製造半導體裝置:在半導體基板上方相繼沉積材料的絕緣或介電層、導電層及半導體層,並且使用微影技術圖案化各種材料層以在其上形成電路部件及元件。
半導體工業透過持續減小最小特徵大小來持續改進各種電子元件(例如電晶體、二極體、電阻器、電容器等)的整合密度,這允許將更多元件整合到給定區域中。然而,隨著最小特徵大小減小,出現應當解決的額外問題。
根據本揭示之一實施方式,提供一種半導體裝置,包含:一源極/汲極區域,鄰接一基板的一通道區域;一接觸蝕刻終止層,在源極/汲極區域上;一第一源極/汲
極觸點,延伸穿過接觸蝕刻終止層,第一源極/汲極觸點連接到源極/汲極區域;一閘極結構,在通道區域上;一閘極觸點,連接到閘極結構;以及一接觸間隔件,圍繞閘極觸點,其中接觸間隔件、閘極結構、接觸蝕刻終止層及基板共同界定在閘極結構與第一源極/汲極觸點之間的一孔隙。
根據本揭示之一實施方式,提供一種半導體裝置,包含:一第一源極/汲極區域;一通道區域,鄰接第一源極/汲極區域;一閘極結構,在通道區域上,閘極結構透過一第一孔隙與第一源極/汲極區域分離;一閘極遮罩,在閘極結構上;一閘極觸點,延伸穿過閘極遮罩以接觸閘極結構;以及一接觸間隔件,圍繞閘極觸點,第一孔隙暴露接觸間隔件的一底表面、閘極結構的一側壁、第一源極/汲極區域的一側壁及通道區域的一頂表面。
根據本揭示之一實施方式,提供一種製造半導體的方法,包含:穿過一閘極遮罩蝕刻一第一接觸開口以暴露一閘極結構及一閘極間隔件,閘極間隔件沿著閘極結構的一側壁並且沿著閘極遮罩的一側壁設置;移除閘極間隔件以沿著閘極結構的側壁延伸第一接觸開口;在閘極結構上方的第一接觸開口的一上部中沉積一間隔層,間隔層沿著閘極結構的側壁密封第一接觸開口的一下部;以及在第一接觸開口的上部中形成一閘極觸點,閘極觸點連接到閘極結構,間隔層圍繞閘極觸點設置。
50:基板
50N:n型區域
50P:p型區域
52:鰭部
56:隔離區域
58:通道區域
62:虛擬介電層
64:虛擬閘極層
66:遮罩層
72:虛擬介電質
74:虛擬閘極
76:遮罩
82:閘極間隔件
84:鰭部間隔件
86:源極/汲極凹陷
88:磊晶源極/汲極區域
88A:襯墊層
88B:主要層
88C:覆蓋層
92:接觸蝕刻終止層
94:第一層間介電質
96:凹陷
102:閘極介電層
104:閘極電極層
112:閘極介電質
114:閘極電極
116:凹陷
116V:孔隙
118:介電層
120:閘極遮罩
122:接觸開口
122C:拐角區域
124:導電層
126:金屬半導體合金區域
128:金屬
132:下部源極/汲極觸點
132/132A:下部源極/汲極觸點
132/132B:下部源極/汲極觸點
134:接觸遮罩
134/134A:接觸遮罩
134/134B:接觸遮罩
142:蝕刻終止層
144:第二層間介電質
144A:下部
144B:上部
152:接觸開口
154:導電層
156:上部源極/汲極觸點
162:接觸開口
162/162A:接觸開口
162/162B:接觸開口
162L:下部
162U:上部
164:間隔層
166:孔隙
168:接觸間隔件
170:導電層
172:閘極觸點
172/172A:閘極觸點
172/172B:閘極觸點
172BM:主要部分
172BV1:通孔部分
172BV2:通孔部分
174:閘極結構
A-A':橫截面
B-B':橫截面
C-C':橫截面
當結合隨附圖式閱讀時,自以下詳細敘述將最佳地理解本揭示的態樣。應注意,根據工業中的標準實務,各個特徵並非按比例繪製。事實上,出於論述清晰的目的,可任意增加或減小各個特徵的尺寸。
第1圖示出根據一些實施例的呈三維視圖的鰭式場效電晶體(fin field-effect transistor,FinFET)的實例。
第2圖至第31C圖是根據一些實施例的在製造FinFET時的中間階段的視圖。
第32圖是根據一些其他實施例的FinFET的橫截面圖。
第33圖是根據一些其他實施例的FinFET的自上向下視圖。
第34圖是根據一些其他實施例的FinFET的橫截面圖。
第35圖是根據一些其他實施例的FinFET的橫截面圖。
第36圖是根據一些其他實施例的FinFET的自上向下視圖。
以下揭示內容提供許多不同實施例或實例,以便實施本揭示的不同特徵。下文敘述元件及佈置的具體實例以
簡化本揭示。當然,此等僅為實例且並不意欲為限制性。例如以下敘述中在第二特徵上方或第二特徵上形成第一特徵可包括以直接接觸形成第一特徵及第二特徵的實施例,且亦可包括在第一特徵與第二特徵之間形成額外特徵以使得第一特徵及第二特徵可不處於直接接觸的實施例。此外,本揭示可在各個實例中重複元件符號及/或字母。此重複是出於簡便性及清晰的目的且本身並不指示所論述的各個實施例及/或配置之間的關是。
另外,為了便於敘述,本文可使用空間相對性術語(例如「在…下方」、「在…之下」、「下部」、「在…之上」、「上部」及類似術語)來敘述如諸圖中所示出的一個元件或特徵與另一元件或特徵的關是。除了諸圖所描繪的定向外,空間相對性術語意欲涵蓋使用或操作中之裝置的不同定向。設備可經其他方式定向(旋轉90度或處於其他定向)且由此可同樣地解讀本文所使用的空間相對性敘述詞。
根據各個實施例,在用於形成到電晶體的閘極結構的觸點的製程期間移除用於電晶體的閘極間隔件。因此在閘極結構與到電晶體的源極/汲極區域的觸點之間形成氣隙或孔隙。氣隙或孔隙具有低相對電容率,從而允許減小電晶體的寄生電容,藉此改進所得FinFET的效能。
第1圖示出根據一些實施例的鰭式場效電晶體(FinFET)的實例。第1圖是三維視圖,其中為了清楚說明而省略FinFET的一些特徵。FinFET包括從基板50
(例如半導體基板)延伸的鰭部52,其中鰭部52用作FinFET的通道區域58。在相鄰鰭部52之間設置隔離區域56,例如淺溝槽隔離(shallow trench isolation,STI)區域,鰭部52位於相鄰的隔離區域56之上且從相鄰隔離區域56之間突出。儘管將隔離區域56敘述/示出為與基板50隔離,如本文所使用,術語「基板」可指單獨的半導體基板或半導體基板及隔離區域的組合。此外,儘管將鰭部52的底部示出為單一的與基板50連續的材料,鰭部52及/或基板50的底部可包含單一材料或複數種材料。在此上下文中,鰭部52指在相鄰隔離區域56之間延伸的部分。
閘極介電質112是沿著側壁並位於鰭部52的頂表面上方。閘極電極114位於閘極介電質112上方。磊晶源極/汲極區域88設置在鰭部52相對於閘極介電質112及閘極電極114的相對側面中。可在各個鰭部52之間共享磊晶源極/汲極區域88。舉例而言,相鄰的磊晶源極/汲極區域88可具有電性連接,例如經由透過磊晶生長聚結磊晶源極/汲極區域88,或經由耦合磊晶源極/汲極區域88與相同的源極/汲極觸點。
第1圖進一步圖示在後續圖中使用的參考橫截面。橫截面A-A’沿著鰭部52的縱軸並且例如在FinFET的磊晶源極/汲極區域88之間的電流流動方向上。橫截面B-B’與橫截面A-A’垂直並且沿著閘極電極114的縱軸。橫截面C-C’與橫截面B-B’平行並且穿過FinFET的磊
晶源極/汲極區域88延伸。為了清楚起見,後續圖式參考這些參考橫截面。
在使用閘極在後製程(gate-last process)而形成的FinFET的內容中敘述本文論述的一些實施例。在其他實施例中,可使用閘極在先製程(gate-first process)。此外,一些實施例考量了用於平面裝置(例如平面FET)中的態樣。
第2圖至第31C圖是根據一些實施例的在製造FinFET時的中間階段的視圖。第2圖、第3圖及第4圖是三維視圖,圖示了與第1圖類似的三維視圖。第5A圖、第6A圖、第7A圖、第8A圖、第9A圖、第10A圖、第11A圖、第12A圖、第13A圖、第14A圖、第15A圖、第16A圖、第17A圖、第18A圖、第19A圖、第20A圖、第21A圖、第22A圖、第23A圖、第24A圖、第25A圖、第26A圖、第27A圖、第28A圖、第29A圖、第30A圖及第31A圖是沿著與第1圖中的參考橫截面A-A’類似的橫截面示出的橫截面圖。第5B圖、第6B圖、第7B圖、第8B圖、第9B圖、第10B圖、第11B圖、第12B圖、第13B圖、第14B圖、第15B圖、第16B圖、第17B圖、第18B圖、第19B圖、第20B圖、第21B圖、第22B圖、第23B圖、第24B圖、第25B圖、第26B圖、第27B圖、第28B圖、第29B圖、第30B圖及第31B圖是沿著與第1圖中的參考橫截面B-B’類似的橫截面示出的橫截面圖。第5C圖、第6C圖、第
7C圖、第8C圖、第9C圖、第10C圖、第11C圖、第12C圖、第13C圖、第14C圖、第15C圖、第16C圖、第17C圖、第18C圖、第19C圖、第20C圖、第21C圖、第22C圖、第23C圖、第24C圖、第25C圖、第26C圖、第27C圖、第28C圖、第29C圖、第30C圖及第31C圖是沿著與第1圖中的參考橫截面C-C’類似的橫截面示出的橫截面圖。
在第2圖中,提供了基板50。基板50可為半導體基板,例如主體(bulk)半導體、絕緣體上半導體(semiconductor-on-insulator,SOI)基板、或類似者,此半導體基板可為摻雜(例如用p型或n型雜質)或未摻雜的。基板50可為晶圓,例如矽晶圓。通常,SOI基板是在絕緣體層上形成的一層半導體材料。絕緣體層可為例如埋入的氧化物(buried oxide,BOX)層、氧化矽層、或類似者。在基板(通常為矽或玻璃基板)上提供絕緣體層。亦可使用其他基板,例如多層或梯度基板。在一些實施例中,基板50的半導體材料可包括矽;鍺;化合物半導體,包括碳化矽、砷化鎵、磷化鎵、磷化銦、砷化銦及/或銻化銦;合金半導體,包括鍺矽、磷砷化鎵、砷化鋁銦、砷化鋁鎵、砷化鎵銦、磷化鎵銦及/或磷砷化鎵銦;或類似者。
基板50具有n型區域50N及p型區域50P。n型區域50N可以用於形成n型裝置,例如NMOS電晶體,例如n型FinFET,而p型區域50P可以用於形成p型裝
置,例如PMOS電晶體,例如p型FinFET。n型區域50N可與p型區域50P實體分離(未單獨示出),並且可在n型區域50N與p型區域50P之間設置任何數量的裝置特徵(例如其他主動裝置、摻雜區域、隔離結構等)。儘管所示出的是一個n型區域50N及一個p型區域50P,然而可提供任何數量的n型區域50N及p型區域50P。
鰭部52形成在基板50中。鰭部52是半導體條帶(semiconductor strip)。可透過在基板50中蝕刻溝槽以在基板50中形成鰭部52。蝕刻可為任何可接受的蝕刻製程,例如反應性離子蝕刻(reactive ion etch,RIE)、中性束蝕刻(neutral beam etch,NBE)、類似者、或其組合。蝕刻製程可為各向異性的。
可透過任何適當方法對鰭部52進行圖案化。例如可使用一或多個微影製程(包括雙圖案化或多圖案化製程)對鰭部52進行圖案化。通常,雙圖案化或多圖案化製程結合微影及自對準製程,從而允許產生一圖案,此圖案的間距小於例如另外使用單個直接微影製程獲得的圖案的間距。舉例而言,在一個實施例中,在基板上方形成犧牲層並且使用微影製程對犧牲層進行圖案化。使用自對準製程在圖案化後的犧牲層旁形成間隔件。隨後移除犧牲層,並且可隨後使用殘餘的間隔件作為遮罩來圖案化鰭部52。在一些實施例中,遮罩(或其他層)可保留在鰭部52上。
STI區域56位於基板50上方並形成在相鄰的鰭部52之間。STI區域56圍繞鰭部52的下部設置,使得
鰭部52的上部從相鄰STI區域56之間突出。換言之,鰭部52的上部在STI區域56的頂表面之上延伸。STI區域56將相鄰裝置的特徵分離。
可透過任何適當方法形成STI區域56。例如可以在基板50上方並且在相鄰鰭部52之間形成絕緣材料。絕緣材料可為氧化物(例如氧化矽)、氮化物(例如氮化矽)、類似者、或其組合,可透過化學氣相沉積(chemical vapor deposition,CVD)製程形成此絕緣材料,例如高密度電漿化學氣相沉積(high density plasma CVD,HDP-CVD)、可流動化學氣相沉積(flowable chemical vapor deposition,FCVD)、其類似者、或其組合。可使用透過任何可接受的製程形成的其他絕緣材料。在一些實施例中,介電材料是透過FCVD形成的氧化矽。一旦形成絕緣材料,就可執行退火製程。儘管將STI區域56各自示出為單一層,在一些實施例中可使用多個層。舉例而言,在一些實施例中,可首先沿著基板50及鰭部52的表面形成襯墊(未單獨示出)。其後,可在襯墊上方形成絕緣材料(例如先前敘述者)。在一實施例中,形成絕緣材料,使得過量的絕緣材料覆蓋鰭部52。隨後將移除製程應用於絕緣材料以移除鰭部52上方的過量絕緣材料。在一些實施例中,可利用平坦化製程,例如化學機械拋光(chemical mechanical polish,CMP)、回蝕製程、其組合、或類似者。在遮罩保留在鰭部52上的實施例中,平坦化製程可暴露遮罩或移除遮罩。在平坦化製程之後,
絕緣材料及遮罩(若存在)或鰭部52的頂表面是共面的(在製程變化內)。因此,絕緣材料暴露遮罩(若存在)或鰭部52的頂表面。在所示出的實施例中,沒有遮罩保留在鰭部52上。隨後凹陷絕緣材料以形成STI區域56。凹陷絕緣材料,使得鰭部52的上部從絕緣材料的相鄰部分之間突出。另外,STI區域56的頂表面可具有所示出的平坦表面、凸起表面、凹入表面(例如凹槽)、或其組合。可透過適當蝕刻將STI區域56的頂表面形成為平坦、凸起及/或凹入的。可使用任何可接受的蝕刻製程使絕緣材料凹陷,例如對絕緣材料的材料具有選擇性的蝕刻製程(例如以相較於蝕刻鰭部52的材料更快的速率來選擇性地蝕刻STI區域56的絕緣材料)。舉例而言,可使用稀釋氫氟酸(dilute hydrofluoric acid,dHF)執行氧化物移除。
先前敘述的製程僅是可如何形成鰭部52及STI區域56的一個實例。在一些實施例中,可使用遮罩及磊晶生長製程形成鰭部52。舉例而言,可以在基板50的頂表面上方形成介電層,並且可以穿過介電層蝕刻溝槽以暴露下層基板50。可以在溝槽中磊晶生長磊晶結構,並且可以使介電層凹陷以讓磊晶結構從介電層突起,從而形成鰭部52。在其中磊晶生長磊晶結構的一些實施例中,可在生長期間原位摻雜磊晶生長的材料,這可省去先前及/或後續佈植,儘管可一起使用原位及佈植摻雜。
另外,可有利地在n型區域50N中磊晶生長與p型區域50P中的材料不同的材料。在各個實施例中,鰭部
52的上部可由鍺矽(SixGe1-x,其中x可以在0至1的範圍中)、碳化矽、純或實質上純的鍺、III-V族化合物半導體、II-VI族化合物半導體、或類似者形成。舉例而言,用於形成III-V族化合物半導體的可用材料包括但不限於砷化銦、砷化鋁、砷化鎵、磷化銦、氮化鎵、砷化銦鎵、砷化銦鋁、銻化鎵、銻化鋁、磷化鋁、磷化鎵及類似材料。
另外,可在鰭部52及/或基板50中形成適當的阱(未單獨示出)。阱可具有與源極/汲極區域的導電類型相反的導電類型,將隨後在n型區域50N及p型區域50P的每一者中形成這些源極/汲極區域。在一些實施例中,在n型區域50N中形成p型阱,並且在p型區域50P中形成n型阱。在一些實施例中,在n型區域50N及p型區域50P兩者中形成p型阱或n型阱。
在具有不同阱類型的實施例中,可使用遮罩(未單獨示出)實現用於n型區域50N及p型區域50P的不同佈植步驟,遮罩例如為光阻。舉例而言,可在n型區域50N中的鰭部52及STI區域56上方形成光阻。圖案化光阻以暴露p型區域50P。可以透過使用旋轉塗佈技術來形成光阻,並且可使用可接受的微影技術來圖案化光阻。一旦光阻受到圖案化後,在p型區域50P中執行n型雜質佈植,並且光阻可用作為遮罩以大致上防止將n型雜質佈植到n型區域50N中。n型雜質可為磷、砷、銻、或類似者,且n型雜質在區域中的佈植濃度為約1013cm-3至約1014
cm-3。在佈植之後移除光阻,例如透過可接受的灰化製程來移除光阻。
在佈植p型區域50P之後或之前,在p型區域50P中的鰭部52及STI區域56上方形成遮罩(未單獨示出),遮罩例如為光阻。對光阻進行圖案化以暴露n型區域50N。可以透過使用旋轉塗佈技術來形成光阻,並且可以使用可接受的微影技術對光阻進行圖案化。一旦光阻受到圖案化後,可在n型區域50N中執行p型雜質佈植,並且光阻可用作為遮罩以實質上防止將p型雜質佈植到p型區域50P中。p型雜質可為硼、氟化硼、銦、或類似者,且p型雜質在區域中的佈植濃度為約1013cm-3至約1014cm-3。在佈植之後移除光阻,例如透過任何可接受的灰化製程來移除光阻。
在佈植n型區域50N及p型區域50P之後,可執行退火以修復佈植損壞並且活化所佈植的p型及/或n型雜質。在磊晶生長用於鰭部52的磊晶結構的一些實施例中,可在生長期間原位摻雜生長的材料,這可省去先前及/或後續佈植,儘管可一起使用原位及佈植摻雜。
在第3圖中,在鰭部52上形成虛擬介電層62。可由例如氧化矽、氮化矽、其組合、或類似者的介電材料形成虛擬介電層62,可根據可接受的技術沉積或熱生長此介電材料。在虛擬介電層62上方形成虛擬閘極層64,並且在虛擬閘極層64上方形成遮罩層66。可在虛擬介電層62上方沉積虛擬閘極層64並且隨後執行平坦化,例如透
過化學機械拋光來執行平坦化。可在虛擬閘極層64上方沉積遮罩層66。可由導電或不導電材料形成虛擬閘極層64,例如非晶矽、多晶矽(聚矽(polysilicon))、多晶鍺矽(poly-SiGe)、金屬、金屬氮化物、金屬矽化物、金屬氧化物、或類似者,並可透過物理氣相沉積(physical vapor deposition,PVD)、化學氣相沉積(CVD)、或類似方式沉積此材料。可由具有蝕刻選擇性高於蝕刻絕緣材料(例如STI區域56及/或虛擬介電層62)的材料來形成虛擬閘極層64。可由介電材料形成遮罩層66,介電材料例如氮化矽、氮氧化矽、或類似者。在此實例中,單個虛擬閘極層64及單個遮罩層66形成並跨過n型區域50N及p型區域50P。在所示出的實施例中,虛擬介電層62覆蓋鰭部52及STI區域56,使得虛擬介電層62位於STI區域56上方並且在虛擬閘極層64與STI區域56之間延伸。在另一實施例中,虛擬介電層62僅覆蓋鰭部52。
在第4圖中,使用可接受的微影及蝕刻技術對遮罩層66進行圖案化以形成遮罩76。隨後透過任何可接受的蝕刻技術將遮罩76的圖案轉移到虛擬閘極層64以形成虛擬閘極74。可選地透過任何可接受的蝕刻技術進一步將遮罩76的圖案轉移到虛擬介電層62以形成虛擬介電質72。虛擬閘極74覆蓋鰭部52個別的通道區域58。遮罩76的圖案可用於實體分離相鄰的虛擬閘極74。虛擬閘極74亦可具有縱向方向,此縱向方向(在製程變化內)實質上垂直於鰭部52的縱向方向。可在圖案化虛擬閘極74期
間移除遮罩76,或可在後續處理期間移除遮罩76。
第5A圖至第31C圖示出在製造實施例裝置時的各個額外步驟。第5A圖至第31C圖示出在n型區域50N及p型區域50P的任一者中的特徵。例如所示出的結構可適用於n型區域50N及p型區域50P兩者。在伴隨每個圖的文字中敘述n型區域50N及p型區域50P的結構差異(若有)。
在第5A圖至第5C圖中,在鰭部52上方、在遮罩76(若存在)、虛擬閘極74及虛擬介電質72的暴露的側壁上形成閘極間隔件82。可透過保形地沉積一或多種介電材料並且隨後蝕刻介電材料來形成閘極間隔件82。可接受的介電材料可包括氧化矽、氮化矽、氮氧化矽、氮碳氧化矽、或類似者,可透過保形沉積製程形成介電材料,例如化學氣相沉積(CVD)、電漿增強化學氣相沉積(plasma-enhanced chemical vapor deposition,PECVD)、原子層沉積(atomic layer deposition,ALD)、電漿增強的原子層沉積(plasma-enhanced atomic layer deposition,PEALD)、或類似者。可使用透過任何可接受的製程形成的其他絕緣材料。可執行任何可接受的蝕刻製程(例如乾式蝕刻、濕式蝕刻、類似製程、或其組合)以對介電材料進行圖案化。蝕刻可為各向異性的。當蝕刻時,介電材料具有餘留在虛擬閘極74的側壁上的部分(因此形成閘極間隔件82)。如隨後將更詳細敘述,在一些實施例中,調整用於形成閘極間隔件82的
蝕刻,使得當蝕刻時,介電材料亦具有餘留在鰭部52的側壁上的部分(因此形成鰭部間隔件84)。在蝕刻之後,鰭部間隔件84(若存在)及閘極間隔件82可以具有筆直側壁(如圖所示)或可以具有彎曲的側壁(未單獨示出)。
另外,可執行佈植以形成輕微摻雜的源極/汲極(lightly doped source/drain,LDD)區域(未單獨示出)。在具有不同裝置類型的實施例中,與用於先前敘述的阱的佈植類似,例如可在n型區域50N上方形成光阻的遮罩(未單獨示出),同時暴露p型區域50P,並且可佈植適當類型(例如p型)的雜質到p型區域50P中暴露的鰭部52中。可隨後移除遮罩。隨後,可在p型區域50P上方形成例如光阻的遮罩(未單獨示出),同時暴露n型區域50N,並且可佈植適當類型的雜質(例如n型)至n型區域50N中暴露的鰭部52中。可隨後移除遮罩。n型雜質可為先前敘述的n型雜質中的任一者,並且p型雜質可為先前敘述的p型雜質中的任一者。在佈植期間,虛擬閘極74維持覆蓋通道區域58,使得通道區域58保持實質上不具有用於佈植形成LDD區域的雜質。LDD區域的雜質濃度可為約1015cm-3至約1019cm-3的範圍內。退火可用於修復佈植損壞並且活化所佈植的雜質。
注意到,先前的揭示內容通常敘述了形成間隔件及LDD區域的製程。可使用其他製程及序列。例如可利用較少或額外的間隔件,可利用不同步驟序列,可形成及移除額外間隔件,及/或類似者。此外,可使用不同的結構及
步驟形成n型裝置及p型裝置。
在第6A圖至第6C圖中,在鰭部52中形成源極/汲極凹陷86。在所示出的實施例中,源極/汲極凹陷86延伸到鰭部52中。源極/汲極凹陷86亦可延伸到基板50中。在各個實施例中,源極/汲極凹陷86可延伸到基板50的頂表面而不蝕刻基板50;可對鰭部52進行經蝕刻,使得源極/汲極凹陷86的底表面設置在STI區域56的頂表面之下;或類似者。可透過使用各向異性蝕刻製程(例如RIE、NBE、或類似者)蝕刻鰭部52來形成源極/汲極凹陷86。在用於形成源極/汲極凹陷86的蝕刻製程期間,閘極間隔件82及虛擬閘極74共同遮蔽鰭部52的部分。在源極/汲極凹陷86達到期望深度之後,可使用固定時間的蝕刻製程以終止源極/汲極凹陷86的蝕刻。在一些實施例中,亦使鰭部間隔件84凹陷,直到鰭部間隔件84到達其期望高度。控制鰭部間隔件84的高度得以控制隨後生長的源極/汲極區域的尺寸。
在第7A圖至第7C圖中,在源極/汲極凹陷86中形成磊晶源極/汲極區域88。磊晶源極/汲極區域88因而設置在鰭部52中,使得每個虛擬閘極74(及對應的通道區域58)位於個別相鄰對的磊晶源極/汲極區域88之間。磊晶源極/汲極區域88因此鄰接通道區域58。在一些實施例中,閘極間隔件82用於以適當的橫向距離分離磊晶源極/汲極區域88與虛擬閘極74,使得磊晶源極/汲極區域88不會讓FinFET後續形成的閘極發生短路。
可選擇磊晶源極/汲極區域88的材料以在相應通道區域58中施加應力,藉此改進效能。
可透過遮蔽p型區域50P來形成n型區域50N中的磊晶源極/汲極區域88。隨後在n型區域50N中的源極/汲極凹陷86中磊晶生長n型區域50N中的磊晶源極/汲極區域88。磊晶源極/汲極區域88可包括適用於n型裝置的任何可接受的材料。舉例而言,若鰭部52是矽,則n型區域50N中的磊晶源極/汲極區域88可包括在通道區域58上施加拉伸應變的材料,例如矽、碳化矽、磷摻雜的碳化矽、磷化矽、或類似者。n型區域50N中的磊晶源極/汲極區域88可被稱為「n型源極/汲極區域」。n型區域50N中的磊晶源極/汲極區域88可具有從鰭部52的個別表面升高的表面並且可具有維面(facet)。
可透過遮蔽n型區域50N來形成p型區域50P中的磊晶源極/汲極區域88。隨後,在p型區域50P中的源極/汲極凹陷86中磊晶生長p型區域50P中的磊晶源極/汲極區域88。磊晶源極/汲極區域88可包括適用於p型裝置的任何可接受材料。舉例而言,若鰭部52是矽,則p型區域50P中的磊晶源極/汲極區域88可包括在通道區域58上施加壓縮應變的材料,例如鍺矽、硼摻雜的鍺矽、鍺、鍺錫、或類似者。p型區域50P中的磊晶源極/汲極區域88可稱為「p型源極/汲極區域」。p型區域50P中的磊晶源極/汲極區域88可具有從鰭部52個別的表面升高的表面並且可具有維面。
類似於前述用於形成LDD區域的製程,磊晶源極/汲極區域88及/或鰭部52可佈植有雜質以形成源極/汲極區域,接著進行退火。源極/汲極區域的雜質濃度可為約1019cm-3至約1021cm-3的範圍內。用於源極/汲極區域的n型及/或p型雜質可為前述的雜質中的任一者。在一些實施例中,可在生長期間原位摻雜磊晶源極/汲極區域88。
由於用於形成磊晶源極/汲極區域88的磊晶製程,磊晶源極/汲極區域的上表面具有從鰭部52的側壁向外橫向擴展的維面。在一些實施例中,此等維面導致相鄰磊晶源極/汲極區域88接合,如第7C圖所示。在一些實施例中,在完成磊晶製程之後,相鄰磊晶源極/汲極區域88保持分離。在所示出的實施例中,形成鰭部間隔件84以覆蓋在STI區域56之上延伸的鰭部52的側壁的一部分,由此阻擋磊晶生長。在另一實施例中,用於形成閘極間隔件82的間隔件蝕刻經調整為不形成鰭部間隔件84,以便允許磊晶源極/汲極區域88延伸到STI區域56的表面。
磊晶源極/汲極區域88可包括一或多個半導體材料層。例如磊晶源極/汲極區域88可各自包括襯墊層88A、主要層88B及覆蓋層88C(或更一般而言,第一半導體材料層、第二半導體材料層及第三半導體材料層)。磊晶源極/汲極區域88可使用任何數量的半導體材料層。襯墊層88A、主要層88B及覆蓋層88C(finishing layer)可由不同半導體材料形成並且可經摻雜到不同的雜質濃度。
在一些實施例中,主要層88B的雜質濃度大於覆蓋層88C的雜質濃度,而覆蓋層88C的雜質濃度大於襯墊層88A的雜質濃度。在磊晶源極/汲極區域88包括三個半導體材料層的實施例中,襯墊層88A可在源極/汲極凹陷86中生長,主要層88B可在襯墊層88A上生長,而覆蓋層88C可在主要層88B上生長。以與主要層88B相比較小的雜質濃度形成襯墊層88A可增加源極/汲極凹陷86中的黏合性,並且以與主要層88B相比較小的雜質濃度形成覆蓋層88C可減小在隨後處理期間摻雜劑從主要層88B向外擴散。
在第8A圖至第8C圖中,在磊晶源極/汲極區域88、閘極間隔件82及遮罩76(若存在)或虛擬閘極74上方沉積第一層間介電質94(inter-layer dielectric,ILD)。可由介電材料形成第一層間介電質94,可透過任何適當方法沉積此介電材料,例如CVD、電漿增強化學氣相沉積(PECVD)、FCVD或類似者。可接受的介電材料可包括磷矽酸鹽玻璃(PSG)、硼矽酸鹽玻璃(BSG)、硼摻雜的磷矽酸鹽玻璃(BPSG)、未摻雜的矽酸鹽玻璃(USG)、或類似者。可使用任何可接受製程形成的其他絕緣材料。
在一些實施例中,在第一層間介電質94與磊晶源極/汲極區域88、閘極間隔件82及遮罩76(若存在)或虛擬閘極74之間形成接觸蝕刻終止層92(contact etch stop layer,CESL)。可由蝕刻選擇性高於蝕刻第一層間介電質94的介電材料形成接觸蝕刻終止層92,例如氮化
矽、氧化矽、氮氧化矽、或類似者。可透過任何適當方法(例如CVD、ALD、或類似者)形成接觸蝕刻終止層92。
在第9A圖至第9C圖中,執行移除製程以使第一層間介電質94的頂表面與遮罩76(若存在)或虛擬閘極74的頂表面齊平。在一些實施例中,可利用平坦化製程,例如化學機械拋光(CMP)、回蝕製程、其組合、或類似者。平坦化製程亦可移除虛擬閘極74上的遮罩76以及沿著遮罩76的側壁的閘極間隔件82的部分。在平坦化製程之後,第一層間介電質94、接觸蝕刻終止層92、閘極間隔件82及遮罩76(若存在)或虛擬閘極74的頂表面是(在製程變化內)共面的。亦在平坦化製程之後,閘極間隔件82具有均勻高度。因此,透過第一層間介電質94而暴露出遮罩76(若存在)或虛擬閘極74的頂表面。在所示出的實施例中,遮罩76保留,並且平坦化製程使第一層間介電質94的頂表面與遮罩76的頂表面齊平。
在第10A圖至第10C圖中,遮罩76(若存在)及虛擬閘極74在蝕刻製程中移除,使得形成凹陷96。亦可移除凹陷96中的虛擬介電質72的部分。在一些實施例中,僅移除虛擬閘極74,而保留虛擬介電質72且透過凹陷96暴露虛擬介電質72。在一些實施例中,從晶粒的第一區域(例如核心邏輯區域)中的凹陷96移除虛擬介電質72,並且在晶粒的第二區域(例如輸入/輸出區域)中的凹陷96中保留虛擬介電質72。在一些實施例中,透過各向異性的乾式蝕刻製程來移除虛擬閘極74。舉例而言,蝕
刻製程可包括使用乾式蝕刻製程來選擇性地蝕刻虛擬閘極74,此乾式蝕刻製程中的反應氣體對虛擬閘極74的蝕刻速率大於對第一層間介電質94或閘極間隔件82的蝕刻速率。在移除期間,在蝕刻虛擬閘極74時,虛擬介電質72可用作為蝕刻終止層。在移除虛擬閘極74之後,可隨後可選地移除虛擬介電質72。每個凹陷96暴露及/或覆蓋鰭部52個別的通道區域58。
在第11A圖至第11C圖中,在凹陷96中形成閘極介電層102。在閘極介電層102上形成閘極電極層104。閘極介電層102及閘極電極層104是用於替換閘極的層,並且各自沿著側壁並在通道區域58的頂表面上方延伸。
閘極介電層102設置在鰭部52的側壁及/或頂表面上以及閘極間隔件82的側壁上。亦可在第一層間介電質94及閘極間隔件82的頂表面上形成閘極介電層102。閘極介電層102可包括氧化物(例如氧化矽或金屬氧化物)、矽酸鹽(例如金屬矽酸鹽)、其組合、其多層、或類似者。閘極介電層102可包括介電常數值大於約7.0的介電材料(例如高介電常數介電材料),例如下列金屬氧化物或矽酸鹽:鉿、鋁、鋯、鑭、錳、鋇、鈦、鉛及其組合。閘極介電層102的形成方法可包括分子束沉積(molecular-beam deposition,MBD)、原子層沉積(ALD)、PECVD及類似者。在虛擬介電質72的部分保留在凹陷96中的實施例中,閘極介電層102包括虛擬介電質72的材料(例如氧化矽)。儘管示出了單層的閘極介
電層102,閘極介電層102可包括任何數量的界面層及任何數量的主要層。例如閘極介電層102可包括界面層及覆蓋的高介電常數介電層。
閘極電極層104可包括含金屬材料,例如氮化鈦、氧化鈦、氮化鉭、碳化鉭、鎢、鈷、釕、鋁、其組合、其多層、或類似者。儘管示出了單層的閘極電極層104,閘極電極層104可包括任何數量的工作函數調諧層、任何數量的阻障層、任何數量的膠合層及填充材料。
在n型區域50N及p型區域50P中形成閘極介電層102可同時發生,使得在每個區域中的閘極介電層102由相同材料形成,並且形成閘極電極層104可同時發生,使得在每個區域中的閘極電極層104由相同材料形成。在一些實施例中,可透過不同製程形成每個區域中的閘極介電層102,使得閘極介電層102可為不同材料及/或具有不同數量的層,及/或可由不同製程形成每個區域中的閘極電極層104,使得閘極電極層104可為不同材料及/或具有不同數量的層。當使用不同製程時,可使用各種遮蔽步驟以遮蔽及暴露適當區域。
在第12A圖至第12C圖中,執行移除製程以移除閘極介電層102及閘極電極層104的材料的過量部分,此等過量部分在第一層間介電質94、接觸蝕刻終止層92及閘極間隔件82的頂表面上方,從而形成閘極介電質112及閘極電極114。在一些實施例中,可利用平坦化製程,例如化學機械拋光(CMP)、回蝕製程、其組合、或類似者。
在平坦化時,閘極介電層102具有餘留在凹陷96中的部分(因此形成閘極介電質112)。在平坦化時,閘極電極層104具有餘留在凹陷96中的部分(因此形成閘極電極114)。在平坦化製程之後,閘極間隔件82、接觸蝕刻終止層92、第一層間介電質94、閘極介電質112及閘極電極114的頂表面是(在製程變化內)共面的。閘極介電質112及閘極電極114形成所得FinFET的替換閘極。每個個別對的閘極介電質112及閘極電極114可統稱為「閘極結構」。各個閘極結構沿著鰭部52的通道區域58的頂表面、側壁及底表面延伸。
在第13A圖至第13C圖中,使閘極結構(包括閘極介電質112及閘極電極114)凹陷以直接在閘極結構上方形成凹陷116。可使用任何可接受的蝕刻製程讓閘極結構凹陷,例如對閘極結構的材料具有選擇性的蝕刻製程(例如對閘極介電質112及閘極電極114的材料選擇性蝕刻的速率大於對第一層間介電質94及接觸蝕刻終止層92的材料蝕刻的速率)。閘極間隔件82亦可凹陷(未單獨示出)。當凹陷閘極間隔件82時,閘極間隔件82的凹陷量可相同或不同於閘極結構的凹陷量。
在第14A圖至第14C圖中,在凹陷116中保形地沉積一或多個介電層118。亦可在閘極間隔件82、第一層間介電質94及接觸蝕刻終止層92的頂表面上形成介電層118。由蝕刻選擇性高於第一層間介電質94及接觸蝕刻終止層92的介電材料來形成介電層118。可接受的介
電材料可包括氮化矽、氮碳化矽、氮氧化矽、氮碳氧化矽、或類似者,可透過保形的沉積製程形成此介電材料,例如化學氣相沉積(CVD)、電漿增強的化學氣相沉積(PECVD)、原子層沉積(ALD)、電漿增強的原子層沉積(PEALD)、或類似者。可使用透過任何可接受的製程形成的其他絕緣材料。在一些實施例中,在介電層118的沉積期間發生夾斷(pinch-off),使得凹陷116中的介電層118的形成是不完全的。因此,從沒有被介電層118填充的凹陷116的部分形成孔隙116V。
在第15A圖至第15C圖中,執行移除製程以移除介電層118的過量部分,此等過量部分位於閘極間隔件82、第一層間介電質94及接觸蝕刻終止層92的頂表面上方,從而形成閘極遮罩120。在一些實施例中,可利用平坦化製程,例如化學機械拋光(CMP)、回蝕製程、其組合、或類似者。在平坦化時,介電層118具有餘留在凹陷116中的部分(因此形成閘極遮罩120)。在平坦化製程之後,閘極間隔件82、接觸蝕刻終止層92、第一層間介電質94及閘極遮罩120的頂表面是共面的(在製程變化內)。閘極觸點將隨後形成以穿過閘極遮罩120而接觸閘極電極114的頂表面。可透過或可不透過平坦化製程破壞孔隙116V(若存在)。閘極間隔件82設置在閘極遮罩120及閘極結構(包括閘極介電質112及閘極電極114)的側壁上。
在第16A圖至第16C圖中,形成接觸開口122,
接觸開口122穿過第一層間介電質94及接觸蝕刻終止層92。接觸開口122是透過自對準接觸(self-aligned contact,SAC)製程而形成的源極/汲極接觸開口,使得實質上沒有第一層間介電質94的殘留物保留在接觸開口122的拐角區域122C中。接觸開口122的拐角區域122C是透過接觸蝕刻終止層92的側壁及磊晶源極/汲極區域88的頂表面界定的拐角。
作為形成接觸開口122的實例,可在第一層間介電質94及閘極遮罩120上方形成遮罩。利用槽開口對遮罩進行圖案化,此槽開口具有接觸開口122的圖案。遮罩可例如為光阻,例如單層光阻、雙層光阻、三層光阻、或類似者,可使用可接受的微影技術對光阻進行圖案化以形成槽開口。可使用透過任何可接受製程形成的其他類型的遮罩。槽開口是與鰭部52的縱向方向平行行進的條帶,從而覆蓋第一層間介電質94及閘極遮罩120。第一層間可隨後使用遮罩作為蝕刻遮罩並且使用接觸蝕刻終止層92作為蝕刻終止層來蝕刻介電質94。蝕刻可為任何可接受的蝕刻製程,例如對第一層間介電質94的材料具有選擇性的蝕刻製程(例如以與接觸蝕刻終止層92及閘極遮罩120的材料相比更快的速率選擇性蝕刻第一層間介電質94的材料)。蝕刻製程可為各向異性的。因此蝕刻未由遮罩覆蓋(例如由槽開口暴露)的第一層間介電質94的部分以形成接觸開口122。接觸開口122隨後透過任何可接受的蝕刻製程延伸穿過接觸蝕刻終止層92以暴露磊晶源極/汲
極區域88。在蝕刻製程之後,可移除遮罩,例如透過任何可接受的灰化製程移除遮罩。取決於用於形成接觸開口122的蝕刻製程的選擇性,可能發生接觸蝕刻終止層92及/或閘極遮罩120的一些損失,使得接觸蝕刻終止層92及/或閘極遮罩120的側壁及/或頂表面在蝕刻之後彎曲。閘極遮罩120在蝕刻期間覆蓋閘極結構(包括閘極介電質122及閘極電極114),藉此保護閘極結構不受到蝕刻損失。
在第17A圖至第17C圖中,在接觸開口122中形成用於源極/汲極觸點的導電層124。舉例而言,可透過以下操作形成導電層124:在接觸開口122中形成襯墊(未單獨示出)(例如擴散阻障層、黏合層、或類似者)及導電材料。襯墊可包括鈦、氮化鈦、鉭、氮化鉭、或類似者。導電材料可為金屬,例如銅、銅合金、銀、金、鎢、鈷、鋁、鎳、或類似者,可透過沉積製程形成金屬,例如PVD、ALD、CVD、或類似者。在閘極間隔件82、接觸蝕刻終止層92及/或閘極遮罩120的側壁及/或頂表面上形成導電層124。
可選地,在磊晶源極/汲極區域88與導電層124之間形成金屬半導體合金區域126。金屬半導體合金區域126可以是由金屬矽化物(例如矽化鈦、矽化鈷、矽化鎳等)形成的矽化物區域、由金屬鍺化物(例如鍺化鈦、鍺化鈷、鍺化鎳等)形成的鍺化物區域、由金屬矽化物及金屬鍺化物兩者形成的鍺化矽區域、或類似者。可以在導電
層124之前透過以下操作形成金屬半導體合金區域126:在接觸通孔122中(例如在磊晶源極/汲極區域88上)沉積金屬128並且隨後執行熱退火製程。在閘極間隔件82、接觸蝕刻終止層92及/或金屬遮罩120的側壁及/或頂表面上形成金屬128。金屬128可以是能夠與磊晶源極/汲極區域88的半導體材料(例如矽、鍺矽、鍺等)反應以形成低電阻金屬半導體合金的任何金屬,例如鎳、鈷、鈦、鉭、鉑、鎢、其他貴金屬、其他耐火金屬、稀土金屬或其合金。金屬128可以透過沉積製程沉積,例如ALD、CVD、PVD、或類似者。在熱退火製程之後,可選地執行清洗製程(例如濕式清洗)以從接觸開口122(例如從金屬半導體合金區域126的表面)移除金屬128的任何殘留物。在所示出的實施例中,省略清洗製程,使得金屬128的殘留物保留在接觸蝕刻終止層92的側壁上。可以隨後在金屬半導體合金區域126上形成導電層124。
在第18A圖至第18C圖中,執行移除製程以移除金屬128(若存在)及導電層124的過量部分,此等過量部分位於閘極間隔件82、接觸蝕刻終止層92、第一層間介電質94及閘極遮罩120的頂表面上方。移除製程亦可移除閘極間隔件82、接觸蝕刻終止層92、第一層間介電質94及/或閘極遮罩120的一些部分。在一些實施例中,可利用平坦化製程,例如化學機械拋光(CMP)、回蝕製程、其組合、或類似者。在接觸開口122中的殘餘的導電層124在接觸開口122中形成下部源極/汲極觸點132。在平坦
化製程之後,閘極間隔件82、接觸蝕刻終止層92、第一層間介電質94、閘極遮罩120、金屬128(若存在)及下部源極/汲極觸點132的頂表面是(在製程變化內)共面的。下部源極/汲極觸點132延伸穿過第一層間介電質94。在平坦化製程之後可保留或可沒有保留孔隙116V(若存在)。
在第19A圖至第19C圖中,可選地在下部源極/汲極觸點132上方形成接觸遮罩134。接觸遮罩134可由從與閘極遮罩120的候選材料相同群組中選擇的材料形成。閘極遮罩120及接觸遮罩134可由相同材料形成,或可包括不同材料。可以由閘極遮罩120類似的方式形成接觸遮罩134。例如可凹陷下部源極/汲極觸點132。可使用任何可接受的蝕刻製程使下部源極/汲極觸點132凹陷。可在凹陷中保形地沉積一或多個介電層。可執行移除製程以移除介電層的過量部分,此等過量部分位於閘極間隔件82、接觸蝕刻終止層92、第一層間介電質94及閘極遮罩120的頂表面上方。在一些實施例中,可利用平坦化製程,例如化學機械拋光(CMP)、回蝕製程、其組合、或類似者。在平坦化時,介電層具有餘留在凹陷中的部分(因此形成接觸遮罩134)。在平坦化製程之後,閘極間隔件82、接觸蝕刻終止層92、第一層間介電質94、閘極遮罩120及接觸遮罩134的頂表面是(在製程變化內)共面的。將隨後形成源極/汲極觸點以穿透接觸遮罩134來接觸下部源極/汲極觸點132的頂表面。
在第20A圖至第20C圖中,在閘極間隔件82、第一層間介電質94、閘極遮罩120及接觸遮罩134(若存在)或下部源極/汲極觸點132上方沉積第二層間介電質144。在一些實施例中,第二層間介電質144是透過可流動CVD方法形成的可流動膜。在一些實施例中,第二層間介電質144由介電材料形成,例如磷矽酸鹽玻璃(phosphosilicate glass,PSG)、硼矽玻璃(borosilicate glas,BSG)、硼磷矽酸鹽玻璃(borophosphosilicate glass,BPSG)、無摻雜矽玻璃(undoped silicon glass,USG)、或類似者,可透過任何適當方法沉積此介電材料,例如CVD、PECVD、或類似者。
在一些實施例中,在第二層間介電質144與閘極間隔件82、第一層間介電質94、閘極遮罩120及接觸遮罩134(若存在)或下部源極/汲極觸點132之間形成蝕刻終止層142(etch stop layer,ESL)。蝕刻終止層142可包括具有與蝕刻第二層間介電質144相比較高的蝕刻選擇性的介電材料,例如氮化矽、氧化矽、氮氧化矽、或類似者。
在第21A圖至第21C圖中,形成接觸開口152,接觸開口152穿過第二層間介電質144、蝕刻終止層142及接觸遮罩134A(若存在)的第一子部分(subset)。可使用可接受的微影及蝕刻技術形成接觸開口152。蝕刻製程可為各向異性的。接觸開口152暴露下部源極/汲極觸
點132A的第一子部分的頂表面。接觸開口152不是穿過接觸遮罩134B(若存在)的第二子部分而形成,使得下部源極/汲極觸點132B的第二子部分的頂表面保持被覆蓋。下部源極/汲極觸點132A專屬於特定磊晶源極/汲極區域88,並且不與閘極電極114共享。下部源極/汲極觸點132B將與閘極電極114的子部分共享。共享的觸點可用於電晶體的閘極電極114永久連接到另一電晶體的磊晶源極/汲極區域88的裝置,例如記憶體裝置(例如靜態隨機存取記憶體(Static Random Access Memory,SRAM)單元)。
在第22A圖至第22C圖中,在接觸開口152中形成用於閘極觸點的導電層154。例如可透過以下操作形成導電層154:在接觸開口152中形成襯墊(未單獨示出)(例如擴散阻障層、黏合層、或類似者)及導電材料。襯墊可包括鈦、氮化鈦、鉭、氮化鉭、或類似者。導電材料可為金屬,例如銅、銅合金、銀、金、鎢、鈷、鋁、鎳、或類似者,可透過沉積製程形成金屬,例如PVD、ALD、CVD、或類似者。在第二層間介電質144、蝕刻終止層142、接觸遮罩134A(若存在)及/或下部源極/汲極觸點132A的側壁及/或頂表面上形成導電層154。
在第23A圖至第23C圖中,執行移除製程以移除導電層154的過量部分,此等過量部分位於第二層間介電質144的頂表面上方。移除製程亦可移除第二層間介電質144的一些部分。在一些實施例中,可利用平坦化製程,
例如化學機械拋光(CMP)、回蝕製程、其組合、或類似者。接觸開口152中的殘餘的導電層154在接觸開口152中形成上部源極/汲極觸點156。在平坦化製程之後,第二層間介電質144及上部源極/汲極觸點156的頂表面是共面的(在製程變化內)。上部源極/汲極觸點156延伸穿過第二層間介電質144、蝕刻終止層142及接觸遮罩134A(若存在)。
在第24A圖至第24C圖中,可選地在上部源極/汲極觸點156及第二層間介電質144的材料的原始部分上再次沉積第二層間介電質144的材料的額外部分。第二層間介電質144可以因此包括下部144A(其包括第二層間介電質144的材料的原始部分)及上部144B(其包括第二層間介電質144的材料的額外部分)。
在第25A圖至第25C圖中,形成接觸開口162,接觸開口162穿過第二層間介電質144、蝕刻終止層142及閘極遮罩120。可使用可接受的微影及蝕刻技術形成接觸開口162。蝕刻製程可為各向異性的。舉例而言,當閘極遮罩120由氮化矽形成時,蝕刻可為利用四氟化碳(CF4)執行的乾式蝕刻。接觸開口162暴露閘極電極114的頂表面及閘極間隔件82的側壁。
在第26A圖至第26C圖中,加寬接觸開口162B的子部分以同時暴露接觸遮罩134B(若存在)的頂表面或下部源極/汲極觸點132B的頂表面。可使用可接受的微影及蝕刻技術加寬接觸開口162B。蝕刻製程可為各向
異性的。舉例而言,當接觸遮罩134由氮化矽形成時,蝕刻可以是利用四氟化碳(CF4)執行的乾式蝕刻。接觸開口162A的子部分沒有加寬。
隨後移除閘極間隔件82以擴展接觸開口162。閘極間隔件82的移除沿著閘極結構(包括閘極介電質112及閘極電極114)的側壁延伸接觸開口162。擴展的接觸開口162具有上部162U及下部162L。接觸開口162的上部162U延伸穿過第二層間介電質144及蝕刻終止層142。接觸開口162的下部162L暴露閘極介電質112、接觸蝕刻終止層92及磊晶源極/汲極區域88的側壁。接觸開口162的下部162L亦可暴露鰭部52的頂表面及蝕刻終止層142的底表面。擴展接觸開口162增加接觸開口162的寬度及深度。如上文提及,閘極間隔件82具有均勻高度。因此,當移除閘極間隔件82時,接觸開口162的下部162L亦具有均勻高度。
用於移除閘極間隔件82的蝕刻製程可與用於加寬接觸開口162B並且初始形成接觸開口162的蝕刻製程不同(例如可用不同蝕刻參數、不同蝕刻劑及/或不同類型的蝕刻執行)。可使用可接受的微影及蝕刻技術移除閘極間隔件82。蝕刻可為對閘極間隔件82的材料具有選擇性(例如以與第二層間介電質144、蝕刻終止層142、閘極電極114、閘極介電質112、第一層間介電質94、接觸蝕刻終止層92、磊晶源極/汲極區域88及鰭部52的材料相比更快的速率蝕刻閘極間隔件82的材料)的濕式或乾式
蝕刻。在一些實施例中,蝕刻是各向同性蝕刻(或至少以與用於加寬接觸開口162B及/或初始形成接觸開口162的蝕刻製程相比較大的各向同性程度蝕刻閘極間隔件82)。例如當閘極間隔件82由氮化矽形成時,蝕刻可為利用磷酸(H3PO4)執行的濕式蝕刻。在一些實施例中,用於移除閘極間隔件82的蝕刻製程包括將閘極間隔件82浸泡在蝕刻溶液中,蝕刻溶液包括含有磷酸的水。可透過將閘極間隔件82浸漬在蝕刻溶液中、用蝕刻溶液噴塗閘極間隔件82、或類似者使閘極間隔件82浸泡在蝕刻溶液中。閘極間隔件82可以在蝕刻溶液中浸泡持續時間達約10秒至約1000秒的範圍內。在浸泡期間,蝕刻溶液的溫度可在約25℃至約200℃的範圍內。用在此範圍中的參數執行蝕刻製程得以在不過度蝕刻鰭部52、閘極介電質112、或閘極電極114之情況下移除閘極間隔件82。用在此範圍之外的參數執行蝕刻製程可能無法在不過度蝕刻鰭部52、閘極介電質112及閘極電極114的情況下移除閘極間隔件82。
在第27A圖至第27C圖中,加寬的接觸開口162B可選地延伸穿過接觸遮罩134B(若存在)並且暴露下部源極/汲極觸點132B。使用可接受的微影及蝕刻技術,接觸開口162B可延伸穿過接觸遮罩134B。蝕刻製程可為各向異性的。例如當接觸遮罩134由氮化矽形成時,蝕刻可為利用四氟化碳(CF4)執行的乾式蝕刻。
在第28A圖至第28C圖中,在接觸開口162中沉積間隔層164。間隔層164形成在第二層間介電質144、
閘極電極114、閘極介電質112及下部源極/汲極觸點132B的頂表面上。間隔層164亦形成在蝕刻終止層142的底表面及第二層間介電質144、蝕刻終止層142及接觸蝕刻終止層92的側壁上。如隨後將更詳細敘述,間隔層164亦可形成在閘極介電質112的側壁上。間隔層164由介電材料形成。可接受的介電材料可包括氮化矽、氮碳化矽、氮氧化矽、氮碳氧化矽、或類似者,此等介電材料可透過保形沉積製程形成,例如化學氣相沉積(CVD)、電漿增強化學氣相沉積(PECVD)、原子層沉積(ALD)、電漿增強原子層沉積(PEALD)、或類似者。可使用透過任何可接受製程形成的其他絕緣材料。
在沉積間隔層164期間,出現夾斷現象(pinch-off),使得在接觸開口162的下部162L中的間隔層164的形成不完全。因此,間隔層164密封接觸開口162的下部162L,使得從未由間隔層164填充的接觸開口162的下部162L形成孔隙166。為了促進形成孔隙166,更傾向造成夾斷現象的沉積製程(例如CVD)可用於沉積間隔層164。例如可透過CVD由氮化矽形成間隔層164。亦可出現夾斷現象,這是因為接觸開口162的下部162L及因此孔隙166具有小寬度,例如在約1nm至約20nm的範圍中的寬度W1。
在第29A圖至第29C圖中,對間隔層164進行圖案化以形成接觸間隔件168。可透過任何可接受的蝕刻製程對間隔層164進行圖案化,例如對間隔層164的材料
具有選擇性的蝕刻製程(例如以與第二層間介電質144及閘極電極114的材料相比更快的速率選擇性蝕刻間隔層164的材料)。蝕刻製程可為各向異性的。對間隔層164進行圖案化移除了位於第二層間介電質144、閘極電極114及下部源極/汲極觸點132B上方的間隔層164的水平部分。在蝕刻時,間隔層164具有餘留在第二層間介電質144、蝕刻終止層142及CESL的側壁上的垂直部分(因此形成接觸間隔件168)。第二層間介電質144、閘極電極114及下部源極/汲極觸點132B的頂表面在移除間隔層164的水平部分之後暴露出。延伸穿過蝕刻終止層142的接觸間隔件168具有位於蝕刻終止層142之上及之下設置的部分。位於蝕刻終止層142之下的接觸間隔件168的部分接觸蝕刻終止層142的底表面並且沿著此底表面延伸。在所示出的實施例中,接觸間隔件168沒有形成在閘極介電質112的側壁上,使得閘極介電質112的側壁不具有接觸間隔件168。
透過下列界定孔隙166(並且因此暴露下列):接觸間隔件168的底表面;鰭部52的頂表面;以及閘極介電質112、接觸蝕刻終止層92及磊晶源極/汲極區域88的側壁。因此,孔隙166設置在閘極電極114與源極/汲極觸點132、156之間。孔隙166可用空氣填充或可處於真空下,這兩者皆具有與移除的閘極間隔件82的介電材料相比較低的相對電容率。在較小的裝置大小下,在源極/汲極觸點132、156與閘極電極114之間的電容可為
寄生電容的主要來源。降低在源極/汲極觸點132、156與閘極電極114之間的相對電容率減小寄生電容,藉此改進所得FinFET的效能。
如上文提及,接觸開口162的下部162L具有均勻高度。因此,孔隙166亦具有均勻(例如相同)高度。透過移除閘極間隔件82形成孔隙166允許孔隙166跨基板50具有更均勻的尺寸。另外,間隔層164(參見第28A圖至第28C圖)在線程中端(MEOL)製程中而非在線程前端(FEOL)製程中形成。在沉積間隔層164期間形成孔隙166因此允許在處理的稍後階段中形成孔隙166,使得在形成孔隙166之後執行較少處理步驟。可因此減小在後續處理中損壞孔隙166的風險。可因此改進製造良率。
在第30A至第30C圖中,在接觸開口162中形成用於閘極觸點的導電層170。例如可透過以下操作形成導電層170:在接觸開口162中形成襯墊(未單獨示出)(例如擴散阻障層、黏合層、或類似者)及導電材料。襯墊可包括鈦、氮化鈦、鉭、氮化鉭、或類似者。導電材料可為金屬,例如銅、銅合金、銀、金、鎢、鈷、鋁、鎳、或類似者,此金屬可透過沉積製程形成,例如PVD、ALD、CVD、或類似者。導電層170形成在接觸間隔件168、第二層間介電質144、閘極電極114及下部源極/汲極觸點132B的側壁及/或頂表面上。
在第31A圖至第31C圖中,執行移除製程以移除導電層170的過量部分,此等過量部分位於第二層間介電
質144的頂表面上方。移除製程亦可移除第二層間介電質144的一些部分,例如在上部源極/汲極觸點156的頂表面上方的部分。在一些實施例中,可利用平坦化製程,例如化學機械拋光(CMP)、回蝕製程、其組合、或類似者。接觸開口162中的殘餘的導電層170在接觸開口162中形成閘極觸點172。在平坦化製程之後,第二層間介電質144、上部源極/汲極觸點156及閘極觸點172的頂表面是共面的(在製程變化內)。閘極觸點172延伸穿過第二層間介電質144及蝕刻終止層142。
接觸開口162A中的閘極觸點172A的子部分專屬於特定閘極電極114,並且不與磊晶源極/汲極區域88共享。接觸開口162B中的閘極觸點172B的子部分穿過下部源極/汲極觸點132B與磊晶源極/汲極區域88的子部分共享。根據各個實施例,閘極觸點172B各自具有延伸穿過第二層間介電質144及蝕刻終止層142的主要部分172BM、延伸穿過閘極遮罩120以接觸下層閘極電極114的第一通孔部分172BV1、以及延伸穿過接觸遮罩134以接觸下層的下部源極/汲極觸點132B的第二通孔部分172BV2。接觸間隔件168具有在閘極觸點172B的主要部分172BM下面並且在閘極觸點172B的通孔部分172BV1、172BV2之間的部分。
第32圖是根據一些其他實施例的FinFET的視圖。此實施例與第31A圖的實施例類似,不同之處在於接觸間隔件168亦形成在閘極介電質112的側壁上,使得其
等沿著閘極介電質112延伸並且接觸閘極介電質112。例如在沉積間隔層164期間(參見第28A圖至第28C圖),可在接觸開口162的下部162L中進一步向下發生夾斷。因此,在此實施例中的孔隙166具有與在第31A圖的實施例中的孔隙166相比較小的高度。
第33圖是根據一些實施例的FinFET的視圖。具體地,第33圖是第31A圖及第32圖的裝置的自上向下視圖,其中為了清楚說明而省略FinFET的一些特徵。如更清晰地看到,孔隙166沿著閘極結構174的側壁延伸。孔隙166使源極/汲極觸點132、156與閘極結構174分離。透過接觸間隔件168界定孔隙166。
第34圖是根據一些其他實施例的FinFET的視圖。此實施例與第31A圖的實施例類似,不同之處在於省略接觸遮罩134。因此,閘極觸點172B不包括延伸穿過接觸遮罩134的通孔部分172BV2(參見第31A圖)。而是,閘極觸點172B的主要部分172BM(參見第31A圖)沿著下部源極/汲極觸點132B的頂表面延伸。由於在形成接觸開口152期間減小的蝕刻選擇性(參見第21A圖至第21C圖),上部源極/汲極觸點156可部分延伸到下部源極/汲極觸點132中。
第35圖是根據一些其他實施例的FinFET的視圖。此實施例與第34圖的實施例類似,不同之處在於接觸間隔件168亦形成在閘極介電質112的側壁上。因此,在此實施例中的孔隙166可具有與在第34圖的實施例中的
孔隙166相比較小的高度。
第36圖是根據一些實施例的FinFET的視圖。具體地,第36圖是自上向下視圖,其中為了清楚說明而省略FinFET的一些特徵。此實施例與第33圖的實施例類似,不同之處在於省略接觸遮罩134。
實施例可實現優點。孔隙166可用空氣填充或可處於真空下,該兩者皆具有與移除的閘極間隔件82的介電材料相比較低的相對電容率。在較小的裝置大小下,在源極/汲極觸點132、156與閘極電極114之間的電容可為寄生電容的主要來源。降低在源極/汲極觸點132、156與閘極電極114之間的面積的相對電容率減小寄生電容,藉此改進所得FinFET的效能。另外,透過移除閘極間隔件82形成孔隙166允許將孔隙166形成到相同高度且在處理的後續步驟中。可因此改進製造良率。
所揭示的FinFET實施例亦可以應用於奈米結構裝置,例如奈米結構(例如奈米片、奈米線、閘極全包圍、或類似者)場效電晶體(nanostructure field-effect transistors,NSFET)。在NSFET的實施例中,奈米結構取代鰭部,其中透過對通道層及犧牲層的交替堆疊層進行圖案化來形成此奈米結構。以類似於上文敘述的實施例的方式形成虛擬閘極結構及源極/汲極區域。在移除虛擬閘極結構之後,可以部分地移除或完全移除通道區域中的犧牲層。以類似於上文敘述的實施例的方式形成替換閘極結構,替換閘極結構可部分或完全填充透過移除犧牲層
餘留的開口,並且替換閘極結構可部分地圍繞或完全地圍繞NSFET裝置的通道區域中的通道層。可以類似於上文敘述的實施例的方式形成層間介電質及到替換閘極結構及源極/汲極區域的觸點。奈米結構裝置的形成可以如在美國專利申請案公開案第2016/0365414號中所揭示,此公開案的全部內容透過引用的方式併入本文中。
另外,FinFET/NSFET裝置可透過上層互連結構中的金屬化層互連以形成積體電路。可以在線程後端(BEOL)製程中形成上層互連結構,其中金屬化層連接到上部源極/汲極觸點156及閘極觸點172。可在BEOL製程期間與互連結構整合額外特徵,額外特徵例如被動裝置、記憶體(例如磁阻隨機存取記憶體(magnetoresistive random-access memory,MRAM)、電阻隨機存取記憶體(resistive random access memory,RRAM)、相變隨機存取記憶體(phase-change random access memory,PCRAM)等)、或類似者。
在一實施例中,一種裝置包括:源極/汲極區域,鄰接基板的通道區域;接觸蝕刻終止層,在源極/汲極區域上;第一源極/汲極觸點,穿過接觸蝕刻終止層延伸,第一源極/汲極觸點連接到源極/汲極區域;閘極結構,在通道區域上;閘極觸點,連接到閘極結構;以及接觸間隔件,圍繞閘極觸點,其中接觸間隔件、閘極結構、接觸蝕刻終止層及基板共同界定在閘極結構與第一源極/汲極
觸點之間的孔隙。在一些實施例中,裝置進一步包括:在閘極結構上的蝕刻終止層,閘極觸點及接觸間隔件延伸穿過蝕刻終止層,接觸間隔件具有在蝕刻終止層之上設置的第一部分並且具有在蝕刻終止層下面設置的第二部分。在裝置的一些實施例中,接觸蝕刻終止層及第一源極/汲極觸點的頂表面是共面的,並且裝置進一步包括:第二源極/汲極觸點,延伸穿過蝕刻終止層並且到第一源極/汲極觸點中。在一些實施例中,裝置進一步包括:在第一源極/汲極觸點上的接觸遮罩,接觸蝕刻終止層及接觸遮罩的頂表面是共面的;以及第二源極/汲極觸點,延伸穿過接觸遮罩及蝕刻終止層。在裝置的一些實施例中,閘極結構包括閘極介電質,閘極介電質的側壁暴露於孔隙,閘極介電質的側壁不具有接觸間隔件。在裝置的一些實施例中,閘極結構包括閘極介電質,閘極介電質的側壁暴露於孔隙,接觸間隔件沿著閘極介電質的側壁延伸。
在一實施例中,一種裝置包括:第一源極/汲極區域;通道區域,鄰接第一源極/汲極區域;閘極結構,在通道區域上,閘極結構透過第一孔隙與第一源極/汲極區域分離;閘極遮罩,在閘極結構上;閘極觸點,延伸穿過閘極遮罩以接觸閘極結構;以及接觸間隔件,圍繞閘極觸點,第一孔隙暴露接觸間隔件的底表面、閘極結構的側壁、第一源極/汲極區域的側壁及通道區域的頂表面。在裝置的一些實施例中,接觸間隔件沿著閘極觸點的側壁、閘極結構的頂表面及閘極結構的側壁延伸。在裝置的一些實施
例中,接觸間隔件沿著閘極觸點的側壁及閘極結構的頂表面延伸,閘極結構的側壁不具有接觸間隔件。在一些實施例中,裝置進一步包括:鄰接通道區域的第二源極/汲極區域,閘極結構透過第二孔隙與第二源極/汲極區域分離,第一孔隙及第二孔隙具有相同高度。
在一實施例中,一種方法包括:穿過閘極遮罩蝕刻第一接觸開口以暴露閘極結構及閘極間隔件,閘極間隔件沿著閘極結構的側壁並且沿著閘極遮罩的側壁設置;移除閘極間隔件以沿著閘極結構的側壁延伸第一接觸開口;在閘極結構上方的第一接觸開口的上部中沉積間隔層,間隔層沿著閘極結構的側壁密封第一接觸開口的下部;以及在第一接觸開口的上部中形成閘極觸點,閘極觸點連接到閘極結構,間隔層圍繞閘極觸點設置。在一些實施例中,方法進一步包括:生長鄰接通道區域的源極/汲極區域,閘極結構在通道區域上方設置;在源極/汲極區域上方沉積第一層間介電質;穿過第一層間介電質蝕刻第二接觸開口以暴露源極/汲極區域,在蝕刻第二接觸開口時閘極遮罩覆蓋閘極結構;以及在第二接觸開口中形成下部源極/汲極觸點,下部源極/汲極觸點連接到源極/汲極區域。在方法的一些實施例中,下部源極/汲極觸點、閘極遮罩及閘極間隔件的頂表面是共面的。在一些實施例中,方法進一步包括:在下部源極/汲極觸點上方形成接觸遮罩,接觸遮罩、閘極遮罩及閘極間隔件的頂表面是共面的。在一些實施例中,方法進一步包括:在下部源極/汲極觸點、
遮罩遮罩及閘極間隔件上方沉積第二層間介電質;穿過第二層間介電質蝕刻第一接觸開口;以及在移除閘極間隔件之前,加寬第一接觸開口以暴露下部源極/汲極觸點,間隔層進一步在下部源極/汲極觸點上方沉積。在方法的一些實施例中,閘極結構的側壁不具有間隔層。在方法的一些實施例中,閘極結構的側壁接觸間隔層。在方法的一些實施例中,穿過閘極遮罩蝕刻第一接觸開口包括執行各向異性蝕刻製程,並且移除閘極間隔件包括執行各向同性蝕刻製程。在方法的一些實施例中,閘極遮罩包括氮化矽,並且各向異性蝕刻製程是利用四氟化碳執行的乾式蝕刻。在方法的一些實施例中,閘極間隔件包括氮化矽,並且各向同性蝕刻製程是利用磷酸執行的濕式蝕刻。
上文概述若干實施例的特徵,使得熟習此項技術者可更好地理解本揭示的態樣。熟習此項技術者應瞭解,可輕易使用本揭示作為設計或修改其他製程及結構的基礎,以便執行本文所介紹的實施例的相同目的及/或實現相同優點。熟習此項技術者亦應認識到,此類等效構造並未脫離本揭示的精神及範疇,且可在不脫離本揭示的精神及範疇的情況下產生本文的各種變化、取代及更改。
50:基板
52:鰭部
58:通道區域
88:磊晶源極/汲極區域
92:接觸蝕刻終止層
112:閘極介電質
114:閘極電極
132/132A:下部源極/汲極觸點
132/132B:下部源極/汲極觸點
134/134A:接觸遮罩
134/134B:接觸遮罩
142:蝕刻終止層
144:第二層間介電質
156:上部源極/汲極觸點
166:孔隙
168:接觸間隔件
172/172A:閘極觸點
172/172B:閘極觸點
172BM:主要部分
172BV1:通孔部分
Claims (10)
- 一種半導體裝置,包含:一源極/汲極區域,鄰接一基板的一通道區域;一接觸蝕刻終止層,在該源極/汲極區域上;一第一源極/汲極觸點,延伸穿過該接觸蝕刻終止層,該第一源極/汲極觸點連接到該源極/汲極區域;一閘極結構,在該通道區域上;一閘極觸點,連接到該閘極結構;以及一接觸間隔件,圍繞該閘極觸點,其中該接觸間隔件、該閘極結構、該接觸蝕刻終止層、該基板及該源極/汲極區域共同界定在該閘極結構與該第一源極/汲極觸點之間的一孔隙。
- 如請求項1所述之半導體裝置,進一步包含:一蝕刻終止層,位於該閘極結構上,該閘極觸點及該接觸間隔件延伸穿過該蝕刻終止層,該接觸間隔件具有一第一部分與一第二部分,該第一部分設置在該蝕刻終止層之上,該第二部分設置在該蝕刻終止層下。
- 如請求項1所述之半導體裝置,其中該閘極結構包含一閘極介電質,該閘極介電質的一側壁暴露於該孔隙,該閘極介電質的該側壁不具有該接觸間隔件。
- 如請求項1所述之半導體裝置,其中該閘極 結構包含一閘極介電質,該閘極介電質的一側壁暴露於該孔隙,該接觸間隔件沿著該閘極介電質的該側壁延伸。
- 一種半導體裝置,包含:一第一源極/汲極區域;一通道區域,鄰接該第一源極/汲極區域;一閘極結構,在該通道區域上,該閘極結構透過一第一孔隙與該第一源極/汲極區域分離;一閘極遮罩,在該閘極結構上;一閘極觸點,延伸穿過該閘極遮罩以接觸該閘極結構;以及一接觸間隔件,圍繞該閘極觸點,該第一孔隙暴露該接觸間隔件的一底表面、該閘極結構的一側壁、該第一源極/汲極區域的一側壁及該通道區域的一頂表面。
- 如請求項5所述之半導體裝置,其中該接觸間隔件沿著該閘極觸點的一側壁、該閘極結構的一頂表面及該閘極結構的該側壁延伸。
- 如請求項5所述之半導體裝置,其中該接觸間隔件沿著該閘極觸點的一側壁及該閘極結構的一頂表面延伸,該閘極結構的該側壁不具有該接觸間隔件。
- 如請求項5所述之半導體裝置,進一步包含: 鄰接該通道區域的一第二源極/汲極區域,該閘極結構透過一第二孔隙與該第二源極/汲極區域分離,該第一孔隙及該第二孔隙具有一相同高度。
- 一種製造半導體的方法,包含:穿過一閘極遮罩蝕刻一第一接觸開口以暴露一閘極結構及一閘極間隔件,該閘極間隔件沿著該閘極結構的一側壁並且沿著該閘極遮罩的一側壁設置;移除該閘極間隔件以沿著該閘極結構的該側壁延伸該第一接觸開口;在該閘極結構上方的該第一接觸開口的一上部中沉積一間隔層,其中在沉積該間隔層的期間,出現一夾斷現象,使得該第一接觸開口的一下部中的該間隔層形成不完全,且該間隔層沿著該閘極結構的該側壁密封該第一接觸開口的該下部,使得從未由該間隔層填充的該接觸開口的該下部形成一孔隙;以及在該第一接觸開口的該上部中形成一閘極觸點,該閘極觸點連接到該閘極結構,該間隔層圍繞該閘極觸點設置。
- 如請求項9所述之方法,進一步包含:生長鄰接一通道區域的一源極/汲極區域,該閘極結構在該通道區域上方設置;在該源極/汲極區域上方沉積一第一層間介電質;穿過該第一層間介電質蝕刻一第二接觸開口以暴露該源 極/汲極區域,在蝕刻該第二接觸開口時該閘極遮罩覆蓋該閘極結構;以及在該第二接觸開口中形成一下部源極/汲極觸點,該下部源極/汲極觸點連接到該源極/汲極區域。
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