TWI816979B - 基於奈米碳管的紅外隱身布料及紅外隱身衣服 - Google Patents
基於奈米碳管的紅外隱身布料及紅外隱身衣服 Download PDFInfo
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- TWI816979B TWI816979B TW109105078A TW109105078A TWI816979B TW I816979 B TWI816979 B TW I816979B TW 109105078 A TW109105078 A TW 109105078A TW 109105078 A TW109105078 A TW 109105078A TW I816979 B TWI816979 B TW I816979B
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Abstract
一種紅外隱身布料,其包括:一布料襯底;一紅外光吸收體,該紅外
光吸收體設置在所述布料襯底上;所述紅外光吸收體包括一奈米碳管結構,該奈米碳管結構包括一第一層奈米碳管拉膜、一第二層奈米碳管拉膜和一第三層奈米碳管拉膜,所述第一層奈米碳管拉膜、第二層奈米碳管拉膜和第三層奈米碳管拉膜層疊設置。
Description
本發明涉及一種紅外隱身布料及紅外隱身衣服,尤其涉及一種基於奈米碳管的紅外隱身布料及紅外隱身衣服。
紅外輻射係波長介於可見光與微波之間的電磁波,人眼察覺不到。要察覺這種輻射的存在並測量其強弱,必須把它轉變成可以察覺和測量的其他物理量。隨著光電技術的發展,熱紅外探測在現代軍事偵察監視中發揮著至關重要的作用,熱紅外威脅也不斷升級。紅外隱身技術係通過降低目標物體的紅外輻射特性,以降低目標物體與複雜環境之間的紅外輻射特徵差異,從而使探測系統難以發現目標物體或者使探測系統的探測效果降低。然而,先前的紅外隱身技術對紅外輻射的吸收率較低,導致隱身效果較差。
有鑒於此,提供一種隱身效果較好的紅外隱身布料及紅外隱身衣服實為必要。
一種紅外隱身布料,其包括:一布料襯底;一紅外光吸收體,該紅外光吸收體設置在所述布料襯底上;所述紅外光吸收體包括一奈米碳管結構,該奈米碳管結構包括一第一層奈米碳管拉膜、一第二層奈米碳管拉膜和一第三層奈米碳管拉膜,所述第一層奈米碳管拉膜、第二層奈米碳管拉膜和第三層奈米碳管拉膜層疊設置,所述第一層奈米碳管拉膜、第二層奈米碳管拉膜和第三層奈米碳管拉膜中的每一層包括複數個奈米碳管首尾相連且基本沿同一方向延伸,所述第一層奈米碳管拉膜和所述第二層奈米碳管拉膜中奈米碳管的延伸方
向形成42度至48度的夾角,所述第一層奈米碳管拉膜和所述第三層奈米碳管拉膜中的奈米碳管的延伸方向形成84度至96度的夾角。
一種紅外隱身服裝,其包括一衣服本體,該衣服本體的至少部分佈料為所述的紅外隱身布料。
與先前技術相比,本發明利用三層層疊設置的奈米碳管拉膜作為紅外光吸收體,由於兩層奈米碳管拉膜中奈米碳管的長度延伸方向垂直交叉設置,第三層奈米碳管拉膜中奈米碳管的長度延伸方向與所述兩層奈米碳管拉膜形成42度至48度的夾角,故該紅外光吸收體不僅具有較高的吸收率,幾乎高達99%,而且具有全向吸收性能,且其吸收率與紅外光的偏振無關,從而使得所述紅外隱身布料及紅外隱身衣服具有較好的隱身效果。
10:樣品一
20:樣品二
30:樣品三
40:樣品四
12:第一層奈米碳管拉膜
14:第二層奈米碳管拉膜
16:第三層奈米碳管拉膜
18:第四層奈米碳管拉膜
100:紅外探測器
110:紅外光吸收體
112:熱電元件
114:電訊號檢測器
200:紅外成像儀
210:紅外接收器
220:紅外探測器組件
230:訊號處理器
240:紅外像顯示器
300:紅外隱身布料
310:布料襯底
400:紅外隱身衣服
圖1為本發明第一實施例提供的奈米碳管拉膜的掃描電鏡照片。
圖2為本發明第一實施例提供的垂直交叉設置的兩層奈米碳管拉膜(樣品一)中奈米碳管的長度延伸方向的示意圖。
圖3為所述樣品一的掃描電鏡照片。
圖4為本發明第一實施例提供的層疊設置的三層奈米碳管拉膜(樣品二)中奈米碳管的長度延伸方向的示意圖。
圖5為本發明第一實施例提供的層疊設置的四層奈米碳管拉膜(樣品三)中奈米碳管的長度延伸方向的示意圖。
圖6為所述樣品三的掃描電鏡照片。
圖7為本發明第一實施例提供的三層奈米碳管拉膜(樣品四)中奈米碳管的長度延伸方向的示意圖。
圖8為所述樣品四的結構示意圖。
圖9為所述樣品四的掃描電鏡照片。
圖10為所述樣品一在紫外(UV)-近紅外(NIR)波長範圍內的的透射光譜圖。
圖11為所述樣品三在紫外(UV)-近紅外(NIR)波長範圍內的的反射光譜圖。
圖12為所述樣品四在紫外(UV)-近紅外(NIR)波長範圍內的透射光譜圖。
圖13為所述樣品四在紫外(UV)-近紅外(NIR)波長範圍內的反射光譜圖。
圖14為所述樣品四在紫外(UV)-近紅外(NIR)波長範圍內的吸收光譜圖。
圖15為所述樣品四在中紅外(MIR)波長範圍內的透射光譜圖。
圖16為所述樣品四在中紅外(MIR)波長範圍內的反射光譜圖。
圖17為所述樣品四在中紅外(MIR)波長範圍內的吸收光譜圖。
圖18為所述樣品四在入射角為0°至60°時測得的可見光至近紅外波長範圍內的光譜圖。
圖19為所述樣品四在入射角為0°至60°時測得的中紅外波長範圍內的光譜圖。
圖20為所述樣品四在入射偏振度為0°至90°時測得的可見光-紅外波長範圍內的光譜圖。
圖21為所述樣品四在入射偏振度為0°至90°時測得的中紅外波長範圍內的光譜圖。
圖22為本發明第二實施例提供的紅外探測器的結構示意圖。
圖23為本發明第二實施例提供的設置有抗蝕劑層的紅外光吸收體分別被布、刀和砂紙刮擦的光學照片。
圖24為本發明第三實施例提供的紅外成像儀的結構示意圖。
圖25為本發明第四實施例提供的紅外隱身布料的結構示意圖。
圖26為本發明第四實施例提供的被紅外隱身布料覆蓋的手的光學照片。
圖27為本發明第四實施例提供的被紅外隱身布料覆蓋的手的熱像照片。
圖28為本發明第五實施例提供的紅外隱身衣服的結構示意圖。
下面將結合附圖及具體實施例對本發明提供的紅外隱身布料及紅外隱身衣服做進一步的詳細說明。
本發明第一實施例提供一種紅外吸收體,該紅外吸收體係由多層奈米碳管拉膜層疊設置而成的奈米碳管結構。
請參見圖1,所述奈米碳管拉膜包括複數個首尾相連且基本沿同一方向延伸的奈米碳管。所述奈米碳管包括單壁奈米碳管、雙壁奈米碳管及多壁奈米碳管中的一種或複數種。所述單壁奈米碳管的直徑為0.5奈米~50奈米,所述雙壁奈米碳管的直徑為1.0奈米~50奈米,所述多壁奈米碳管的直徑為1.5奈米~50奈米。所述奈米碳管均勻分佈,且平行於奈米碳管拉膜表面。所述奈米碳管拉膜中的奈米碳管之間通過凡得瓦力連接。一方面,首尾相連的奈米碳管之間通過凡得瓦力連接,另一方面,平行的奈米碳管之間亦通過凡得瓦力結合,故,該奈米碳管拉膜具有一定的柔韌性,可以彎曲折疊成任意形狀而不破裂,且具有良好的自支撐性能。所述奈米碳管拉膜可通過直接拉伸一奈米碳管陣列獲得。可以理解,所述奈米碳管拉膜中基本沿同一方向延伸的奈米碳管,係大部分的奈米碳管沿同一方向延伸。當然,所述奈米碳管拉膜中存在少數隨機排列的奈米碳管,這些奈米碳管不會對奈米碳管拉膜中大多數奈米碳管的整體取向排列構成明顯影響。故,“基本沿同一方向延伸”可以更加準確地描述所述奈米碳管拉膜的內部結構。
當至少兩層奈米碳管拉膜重疊設置時,相鄰的奈米碳管拉膜之間通過凡得瓦力緊密結合。進一步,相鄰兩層奈米碳管拉膜中奈米碳管的延伸方向形成一夾角α,0≦α≦90度。
所述自支撐性能為奈米碳管拉膜不需要大面積的載體支撐,而只要相對兩邊提供支撐力即能整體上懸空而保持自身膜狀狀態,即將所述奈米碳管拉膜置於(或固定於)間隔一固定距離設置的兩個支撐體上時,位於兩個支撐體之間的奈米碳管拉膜能夠保持自身層狀狀態。可以理解,所述紅外吸收體也具有自支撐性能。
為了研究所述紅外吸收體的吸收性能,本發明製備了四種不同的樣品進行測試比對,這四種樣品分別如圖2至圖8所示。為了清楚顯示樣品一、樣品二、樣品三和樣品四中奈米碳管的位置和排列關係,圖2、圖4、圖5和圖
7中,每層奈米碳管拉膜僅繪製一根奈米碳管(實際上,每層奈米碳管拉膜包括複數個基本平行的奈米碳管),其不能成為對本發明的限制。
樣品一10
垂直交叉設置的兩層奈米碳管拉膜形成樣品一10。具體的,如圖2和圖3所示,樣品一10由垂直交叉設置的兩層奈米碳管拉膜組成,每層奈米碳管拉膜中的奈米碳管首尾相連且沿同一方向延伸,兩層奈米碳管拉膜中的奈米碳管的長度延伸方向形成約90度的夾角。也即樣品一10中,兩層奈米碳管拉膜層疊設置並形成“十”字的形狀。
樣品二20
三層奈米碳管拉膜層疊設置,相鄰奈米碳管拉膜中的奈米碳管的長度延伸方向形成約60度的夾角。具體的,如圖4所示,樣品二20由第一層奈米碳管拉膜12、第二層奈米碳管拉膜14和第三層奈米碳管拉膜16依次層疊設置(圖4中,第一層奈米碳管拉膜12、第二層奈米碳管拉膜14和第三層奈米碳管拉膜16中的每一層僅繪製了一個奈米碳管,用於清楚顯示第一層奈米碳管拉膜12、第二層奈米碳管拉膜14和第三層奈米碳管拉膜16中奈米碳管的位置關係),第二層奈米碳管拉膜14位於第一層奈米碳管拉膜12和第三層奈米碳管拉膜16中間,第一層奈米碳管拉膜12中奈米碳管的長度延伸方向和第二層奈米碳管拉膜14中奈米碳管的長度延伸方向形成約60度的夾角,第二層奈米碳管拉膜14中奈米碳管的長度延伸方向和第三層奈米碳管拉膜16中奈米碳管的長度延伸方向形成約60度的夾角。
樣品三30
四層奈米碳管拉膜層疊設置。具體的,如圖5和圖6所示,樣品三30由第一層奈米碳管拉膜12、第二層奈米碳管拉膜14、第三層奈米碳管拉膜16和第四層奈米碳管拉膜18依次層疊設置。圖5中,第一層奈米碳管拉膜12、第二層奈米碳管拉膜14、第三層奈米碳管拉膜16和第四層奈米碳管拉膜18中的每一層僅繪製了一個奈米碳管,用於清楚顯示第一層奈米碳管拉膜12、第二層奈米碳管拉膜14、第三層奈米碳管拉膜16和第四層奈米碳管拉膜18中奈米碳管的位置關係。第一層奈米碳管拉膜12中奈米碳管的長度延伸方向和第二層奈米碳管拉膜14中奈米碳管的長度延伸方向形成45度的夾角,第二層奈米碳管拉膜14中奈米碳管的長度延伸方向和第三層奈米碳管拉膜16中奈米碳管的長
度延伸方向形成45度的夾角。第四層奈米碳管拉膜18中奈米碳管的長度延伸方向與第三層奈米碳管拉膜16中奈米碳管的長度延伸方向形成45度的夾角,並與第一層奈米碳管拉膜12中奈米碳管的長度延伸方向形成90度的夾角。也即樣品三30中,四層奈米碳管拉膜層疊設置並形成“米”字的形狀。
樣品四40
三層奈米碳管拉膜層疊設置。具體的,如圖7和圖8所示,樣品四40由第一層奈米碳管拉膜12、第二層奈米碳管拉膜14和第三層奈米碳管拉膜16依次層疊設置,第二層奈米碳管拉膜14位於第一層奈米碳管拉膜12和第三層奈米碳管拉膜16中間,第一層奈米碳管拉膜12中奈米碳管的長度延伸方向和第二層奈米碳管拉膜14中奈米碳管的長度延伸方向形成45度的夾角,第二層奈米碳管拉膜14中奈米碳管的長度延伸方向和第三層奈米碳管拉膜16中奈米碳管的長度延伸方向形成45度的夾角。第一層奈米碳管拉膜12中奈米碳管的長度延伸方向和第三層奈米碳管拉膜16中奈米碳管的長度延伸方向形成90度的夾角。
樣品四40中,第一層奈米碳管拉膜12中奈米碳管的長度延伸方向、第三層奈米碳管拉膜16中奈米碳管的長度延伸方向,分別與第二層奈米碳管拉膜14中奈米碳管的長度延伸方向形成42度~48度的夾角,且第一層奈米碳管拉膜12中奈米碳管的長度延伸方向和第三層奈米碳管拉膜16中奈米碳管的長度延伸方向形成84度~96度的夾角。優選地,第一層奈米碳管拉膜12中奈米碳管的長度延伸方向、第三層奈米碳管拉膜16中奈米碳管的長度延伸方向,分別與第二層奈米碳管拉膜14中奈米碳管的長度延伸方向形成45度的夾角,且第一層奈米碳管拉膜12中奈米碳管的長度延伸方向和第三層奈米碳管拉膜16中奈米碳管的長度延伸方向形成90度的夾角。
以下從所吸收光譜的範圍、不同入射角的吸收光譜及不同偏振角度的吸收光譜來對比分析上述四種樣品的吸收性能。
圖9為所述樣品一10在紫外(UV)-近紅外(NIR)波長範圍內的的透射光譜圖。由圖9可以得知,樣品一10的透射率很高,故導致其吸收率較低。其原因係:樣品一10的結構過於稀疏,孔隙的數量和尺寸都很大,有較多的光穿過樣品一10的孔隙,導致樣品一10具有較強的光透射率,高達2.6%,但係光的吸收率卻很低。
圖10為所述樣品三30在紫外(UV)-近紅外(NIR)波長範圍內的的反射光譜圖。由圖10可以得知,樣品三30的反射率很高,高達3.3%,故導致其吸收率較低。其原因係:樣品三30的結構過於緊致而稠密,當光照射到樣品三30時,有較多的光被樣品三30反射,導致樣品三30具有較強的光反射率,但係光的吸收率卻很低。另,樣品二20的吸收率也很低。
進一步,使用兩個獨立的光學測量系統對所述樣品四40的光透射率和反射率進行測量。圖11和圖12分別係樣品四40在紫外(UV)~近紅外(NIR)波長範圍內,也即在250奈米(nm)至2微米(μm)波長範圍內的透射光譜圖和反射光譜圖。圖13係利用配備有積分球的分光亮度計在UV~NIR波長範圍內測量的光譜圖,插圖係高吸收區域的放大圖。由圖11至圖13可知,樣品四40在UV~NIR波長範圍(250nm~2μm)內的吸收率大於或者等於98.85%。
圖14和圖15分別係樣品四40在中紅外(MIR)波長範圍(2μm~20μm)內測量的透射光譜圖和反射光譜圖。圖16係利用傅立葉轉換紅外(FTIR)光譜儀在MIR波長範圍內測量的光譜圖,插圖係高吸收區域的放大圖。由圖14至圖16可知,樣品四40在MIR波長範圍(2μm~20μm)內的吸收率大於或者等於98.975%。
圖17為所述樣品四40在入射角為0°至60°時測得的可見光至NIR波長範圍內的光譜圖,所述入射角係指光線與法線之間的角度,所述法線垂直與樣品四40的表面。也即,樣品四40中,奈米碳管的長度延伸方向平行於樣品四40的表面,光線照射到樣品四40的表面,該光線與所述法線之間的夾角就係所述入射角。由圖17可知,在250nm~2μm波長範圍內,樣品四40的吸收率保持穩定,並且與光的入射角無關,並且所有入射角中最低的吸收率也大於98%。故,樣品四40在250nm~2μm的可見光至NIR波長範圍內可以達到全向吸收。所述“全向吸收”係指,在各個入射角度,樣品四40均有較高的吸收率。
圖18為所述樣品四40在入射角為0°至60°時測得的中紅外波長範圍內的光譜圖。由圖18可知,在2μm~20μm的波長範圍內,樣品四40的吸收率保持穩定,與光的入射角無關,並且所有入射角中最低的吸收率也大於98.5%。故,樣品四40在2μm~20μm的中紅外波長範圍內也可以達到全向吸收。
圖19為所述樣品四40在入射偏振度為0°至90°時測得的可見光-紅外波長範圍內的光譜圖。由圖19可知,無論入射光的偏振如何,吸收光譜幾乎相同。故,樣品四40在250nm~2μm的可見光至NIR波長範圍內的吸收與光的偏振無關。
圖20為所述樣品四40在入射偏振度為0°至90°時測得的中紅外波長範圍內的光譜圖。由圖20可知,無論入射光的偏振如何,吸收光譜幾乎相同。故,樣品四40在2μm~20μm的中紅外波長範圍內的吸收與光的偏振也無關。
由圖11-圖20的測試結果可知,樣品四40對紫外至中紅外波長範圍(250nm至20μm)的吸收與光的入射角及偏振均無關。故,對紫外至中紅外波長範圍(250nm至20μm)內光的吸收,樣品四40具有全向性能,且與偏振無關。
另,發明人發現,樣品四10中,所述第二層奈米碳管拉膜14與所述第一層奈米碳管拉膜12,或者與所述第三層奈米碳管拉膜16調換位置,並不影響樣品四10的吸收性能。也即,所述樣品四10中,所述第二層奈米碳管拉膜14、所述第一層奈米碳管拉膜12和所述第三層奈米碳管拉膜16依次層疊設置;所述第一層奈米碳管拉膜12位於所述第二層奈米碳管拉膜14和所述第三層奈米碳管拉膜16之間;第一層奈米碳管拉膜12中奈米碳管的長度延伸方向和第二層奈米碳管拉膜14中奈米碳管的長度延伸方向形成42度~48度的夾角,第二層奈米碳管拉膜14中奈米碳管的長度延伸方向和第三層奈米碳管拉膜16中奈米碳管的長度延伸方向形成42度~48度的夾角。第一層奈米碳管拉膜12中奈米碳管的長度延伸方向和第三層奈米碳管拉膜16中奈米碳管的長度延伸方向形成84度~96度的夾角。優選地,第一層奈米碳管拉膜12中奈米碳管的長度延伸方向和第二層奈米碳管拉膜14中奈米碳管的長度延伸方向形成45度的夾角,第二層奈米碳管拉膜14中奈米碳管的長度延伸方向和第三層奈米碳管拉膜16中奈米碳管的長度延伸方向形成45度的夾角,第一層奈米碳管拉膜12中奈米碳管的長度延伸方向和第三層奈米碳管拉膜16中奈米碳管的長度延伸方向形成90度的夾角。
所述樣品一10的吸收率較低,可能係因為樣品一10中兩層奈米碳管拉膜交叉層疊設置,奈米碳管稀疏,大部分光從樣品一10中稀疏的奈米碳管之間的間隙穿過,故所述樣品一10的透光率較高,而吸收率較低。
所述樣品三30中,四層奈米碳管拉膜呈“米”字形層疊設置,隨著奈米碳管拉膜層數的增加,奈米碳管之間的間隙逐漸減小,透光率會降低,但係由於奈米碳管比較稠密,在空氣與奈米碳管的介面處會引起更多的反射,大部分光會被反射,故所述樣品三30的反射率較高,而吸收率也較低。
故,作為紅外吸收體,與層疊設置的兩層奈米碳管拉膜(所述樣品一10)及四層奈米碳管拉膜(所述樣品三30)相比,層疊設置的三層奈米碳管拉膜具有較高的吸收率。進一步,發明人發現,當兩層奈米碳管拉膜幾乎垂直交叉設置,而剩下的一層奈米碳管拉膜與這兩層奈米碳管拉膜幾乎呈45度角設置時(所述樣品四40),具有更高的吸收率,幾乎高達99%,而且具有全向吸收性能,且其吸收率與紅外光的偏振無關。而相鄰奈米碳管拉膜中的奈米碳管的長度延伸方向形成約60度的夾角(所述樣品二20)時,卻沒有這樣的效果。
請參見圖22,本發明第二實施例提供一種紅外探測器100,該紅外探測器100包括一紅外光吸收體110,一熱電元件112和一電訊號檢測器114。所述紅外光吸收體110設置於所述熱電元件112上,並與所述熱電元件112直接接觸設置。所述熱電元件112與所述紅外光吸收體110層疊設置時,所述紅外光吸收體110中奈米碳管的長度延伸方向平行於熱電元件112與紅外光吸收體110的接觸面。所述電訊號檢測器114與所述熱電元件112通過導線電連接,所述電訊號檢測器114與所述熱電元件112串聯形成一回路,用於檢測所述熱電元件112的電學訊號變化。
所述紅外光吸收體110為與所述樣品四40結構相同的奈米碳管結構,也即所述紅外光吸收體110由第一層奈米碳管拉膜12、第二層奈米碳管拉膜14和第三層奈米碳管拉膜16依次層疊設置而成。所述第一層奈米碳管拉膜12、第二層奈米碳管拉膜14和第三層奈米碳管拉膜16均包括複數個在奈米碳管的延伸方向上首尾相連且沿同一方向延伸的奈米碳管。第二層奈米碳管拉膜14位於第一層奈米碳管拉膜12和第三層奈米碳管拉膜16的中間,並且第一層奈米碳管拉膜12、第三層奈米碳管拉膜16均與第二層奈米碳管拉膜14直接接觸。第一層奈米碳管拉膜12中奈米碳管的長度延伸方向和第二層奈米碳管拉膜14中奈米碳管的長度延伸方向形成42度~48度的夾角,第二層奈米碳管拉膜14中奈米碳管的長度延伸方向和第三層奈米碳管拉膜16中奈米碳管的長度延伸方向形成42度~48度的夾角。第一層奈米碳管拉膜12中奈米碳管的長度延伸方向和
第三層奈米碳管拉膜16中奈米碳管的長度延伸方向形成84度~96度的夾角。優選地,第一層奈米碳管拉膜12中奈米碳管的長度延伸方向和第二層奈米碳管拉膜14中奈米碳管的長度延伸方向形成45度的夾角,第二層奈米碳管拉膜14中奈米碳管的長度延伸方向和第三層奈米碳管拉膜16中奈米碳管的長度延伸方向形成45度的夾角,第一層奈米碳管拉膜12中奈米碳管的長度延伸方向和第三層奈米碳管拉膜16中奈米碳管的長度延伸方向形成90度的夾角。所述第一層奈米碳管拉膜12、第二層奈米碳管拉膜14和第三層奈米碳管拉膜16均為自支撐結構,故,所述紅外光吸收體110也為自支撐結構。所述紅外光吸收體110中的複數個奈米碳管平行於所述熱電元件112的表面。
所述紅外光吸收體110在吸收紅外光後自身溫度升高,又由於奈米碳管的導熱係數高,故紅外光吸收體110能夠將熱量傳遞給所述熱電元件112。當所述熱電元件112吸收熱量後,該熱電元件112的溫度升高,使得該熱電元件112的電學性能發生改變。
所述熱電元件112可為熱釋電元件、熱敏電阻或熱電偶元件等。具體地,所述熱釋電元件為高熱電係數的材料,如鋯鈦酸鉛系陶瓷、鉭酸鋰、鈮酸鋰、硫酸三甘鈦等。所述熱敏電阻可為半導體熱敏電阻、金屬熱敏電阻、合金熱敏電阻等。本實施例中,所述熱電元件112為鋯鈦酸鉛系陶瓷。
由於所述電訊號檢測器114用於檢測所述熱電元件112的電學訊號的改變,故所述電訊號檢測器114的種類根據熱電元件112的不同而不同。在一實施例中,所述熱電元件112為熱釋電元件,該熱釋電元件的溫度升高使熱釋電元件的兩端出現電壓或產生電流,這時,所述電訊號檢測器114可為電流-電壓變換器,該電流-電壓變換器與熱釋電元件串聯形成回路,即可檢測出所述熱釋電元件的電壓或電流的變化。在另一實施例中,所述熱電元件112為熱敏電阻,該熱敏電阻的溫度升高,電阻發生改變,這時,所述電訊號檢測器114包括一電源和一電流檢測器,該電源、電流檢測器與熱敏電阻串聯形成回路,通過電流檢測器測量得到電流的變化,用以檢測出熱敏電阻的電阻改變。在另一實施例中,所述熱電元件112為熱電偶,將所述紅外光吸收體110設置在熱電偶的一端,熱電偶的兩端出現溫度差,即會在熱電偶的兩端出現電勢差,這時,所述電訊號檢測器114可為一電壓檢測器,該電壓檢測器與熱電偶串聯形成回路,即可檢測出所述熱電偶的電勢變化。
所述紅外探測器100的工作過程為:紅外光輻射至所述紅外光吸收體110(即樣品四40)上,所述樣品四40對紅外光完美吸收並將所吸收的紅外光轉化為熱量;該熱量被傳遞給所述熱電元件112;所述熱電元件112吸收熱量後溫度升高,導致熱電元件112的電阻、電流或電壓等電學性能發生變化,當所述電訊號檢測器114與熱電元件112的兩端電連接形成回路時,該電訊號檢測器114能夠檢測出熱電元件112的電學訊號發生改變,從而檢測出探測區域記憶體在紅外光。
進一步,所述紅外光吸收體110上設置一透明的塗層,由於該塗層係透明的,紅外光可以穿過該塗層被所述紅外吸收體110吸收。故該塗層不影響紅外光吸收體110的吸收率。所述塗層可以在不影響吸收效果的前提下提高紅外光吸收體110的機械性能。所述塗層設置在奈米碳管結構的表面,優選的,所述塗層設置在每一個奈米碳管的外表面。所述塗層可以為光刻膠,透明聚合物等。優選的,所述塗層的材料為紫外光刻膠,該紫外光刻膠可以在紫外光的照射下固化,所述紫外光刻膠可以為聚乙烯醇肉桂酸醋、環化橡膠系抗蝕劑等。具體的,在紅外光吸收體110中奈米碳管的表面沈積紫外光刻膠,然後紫外光照射沈積有紫外光刻膠的紅外光吸收體110,從而使得紫外光刻膠層緊密設置在所述紅外光吸收體110上。所述紫外光照射的作用:不僅促使紅外光吸收體110與紫外光刻膠層緊密結合,而且增強了紅外光吸收體110中奈米碳管網路的表面形態,從而提高了其耐磨性。圖23係設置有紫外光刻膠層的紅外光吸收體110分別被布、刀和砂紙刮擦的光學照片。由圖23可知,無論係被布刮擦,還係被刀和砂紙刮擦,設置有紫外光刻膠層的紅外光吸收體110均具有良好的耐磨性,不會輕易被損壞。
本發明第二實施例提供的紅外探測器100具有以下優點:第一、所述紅外光吸收體110對波長在2μm-20μm的近紅外至中紅外光具有良好的吸收效果,提高了所述熱電元件112的回應度和靈敏度,從而使得所述紅外探測器100具有較高的靈敏度;第二、所述紅外光吸收體110不僅具有全向吸收性能,而且與偏振無關,擴大了紅外探測器100的使用範圍。
請參見圖24,本發明第三實施例提供一種紅外成像儀200,該紅外成像儀200包括一紅外接收器210、一紅外探測器組件220、一訊號處理器230及一紅外像顯示器240。所述紅外接收器210用於接收紅外輻射光譜並將紅外光
傳遞至所述紅外探測器組件220;所述紅外探測器組件220用於將紅外輻射光譜轉化為電學訊號,並將電學訊號傳遞至所述訊號處理器230;所述訊號處理器230用於對電學訊號進行處理計算得到熱場分佈資料;所述紅外像顯示器240根據熱場分佈資料顯示紅外熱像圖。
所述紅外接收器210用於接收物體發射的紅外輻射光譜,也即物體所發射的紅外光。進一步,所述紅外接收器210還可彙聚所述紅外輻射光譜。本實施例中,所述紅外接收器210為紅外鏡頭。具體地,物體發射的紅外輻射光譜經紅外鏡頭接收和彙聚後,直接被傳遞至所述紅外探測器組件220。可以理解,所述紅外接收器210也可以省略。
所述紅外探測器元件220包括複數個第二實施例中的紅外探測器100,該複數個紅外探測器100呈二維陣列式均勻分佈,且每個紅外探測器100均可將紅外輻射光譜轉化為電學訊號變化。可以理解,每個紅外探測器100相當於一個圖元點,每個紅外探測器100將所在位置的紅外輻射光譜轉化為電學訊號,從而實現所述紅外探測器元件220對物體發射的紅外輻射光譜的探測。任意相鄰的兩個紅外探測器100的間距可以根據熱成像的解析度要求進行選擇。
所述訊號處理器230用於對每個紅外探測器100的電學訊號進行處理計算,從而得到物體的熱場分佈情況。具體地,所述訊號處理器230根據每個紅外探測器100的電學訊號變化計算其對應的物體表面位置的溫度資料。即,所述訊號處理器230根據電學訊號可計算出物體的熱場分佈資料。
所述紅外像顯示器240用於顯示被測物體的紅外熱像圖。所述紅外像顯示器240的紅外熱像圖係根據物體的熱場分佈資料顯示的,不同的溫度採用不同的顏色顯示。故,所述紅外像顯示器240顯示的紅外熱像圖與物體的溫度分佈相對應,用於反映物體各個位置的溫度情況。例如,當紅外成像儀200用於醫學領域時,可以對人體進行全身熱成像,專業醫生可根據熱像圖判斷出人體不同部位的疾病性質和病變的程度,為臨床診斷提供依據。
所述紅外成像儀200在工作時,物體發出的紅外光被所述紅外接收器210接收;所述紅外接收器210將紅外光接收並彙聚後,再將紅外光傳遞至所述紅外探測器組件220;所述紅外探測器組件220將紅外光轉化為電學訊號,再將電學訊號傳遞給所述訊號處理器230;所述訊號處理器230對電學訊號進行
處理計算從而得到物體的各個位置的溫度資料,即物體的熱場分佈資料;所述紅外像顯示器240再根據計算得到的熱場分佈資料顯示出物體的紅外熱像圖。
本發明第三實施例提供的紅外成像儀200具有以下優點:第一、所述紅外光吸收體110對波長在2μm-20μm的近紅外至中紅外光具有良好的吸收效果,提高了所述熱電元件112的回應度和靈敏度,從而使得所述紅外成像儀200具有較高的靈敏度;第二、所述紅外光吸收體110不僅具有全向吸收性能,而且與偏振無關,擴大了紅外成像儀200的使用範圍。
請參見圖25,本發明第四實施例提供一種紅外隱身布料300,該紅外隱身布料300包括一布料襯底310和設置在該布料襯底310上的所述紅外光吸收體110。所述紅外光吸收體110具有與所述樣品四40相同的材料及結構,也即所述紅外吸收體110就係所述樣品四40。所述紅外光吸收體110也可以設置在兩個布料襯底310之間,形成三明治結構。所述複數個奈米碳管平行於所述紅外光吸收體110靠近所述布料襯底310的表面。
可以將紅外光吸收體110直接設置在布料襯底310上,也可以通過膠黏劑固定在布料襯底310上。本實施例中,將紅外光吸收體110直接設置在布料襯底310上後,用有機溶劑潤濕或者浸潤所述紅外光吸收體110和布料襯底310,利用有機溶劑揮發所產生的表面張力,從而使紅外光吸收體110緊密地與布料襯底310結合。所述有機溶劑的材料不限,只要易揮發,並且不會溶解所述布料襯底310即可。本實施例中,所述有機溶劑為乙醇。優選的,所述布料襯底310具有一通孔,以至於所述紅外光吸收體110懸空設置在所述布料襯底310上。所述布料襯底310的材料不限,可以為絕緣材料,也可以為導電體,可以為柔性材料,也可以為非柔性材料。本實施例中,所述布料襯底310的材料不限,比如棉、滌綸、絲綢、呢絨、麻、皮革等。另一實施例中,所述紅外光吸收體110被縫製在兩層布料之間。
圖26為所述紅外隱身布料300隱身效果測試的光學照片,圖27為紅外熱像儀對覆蓋有紅外隱身布料300的手所捕獲的熱像照片。由圖26和圖27可知,當所述紅外隱身布料300覆蓋手時,該手所發出的紅外均被紅外隱身布料300吸收,不會穿過紅外隱身布料300被其他紅外探測系統所檢測到。故,所述紅外隱身布料300具有良好的隱身效果。
請參見圖28,本發明第五實施例提供一種紅外隱身衣服400,該紅外隱身衣服400至少部分係由所述紅外隱身布料300製成。也即,所述紅外隱身衣服400可以全部由所述紅外隱身布料300製成,也可以部分由所述紅外隱身布料300製成。所述紅外隱身衣服400也不僅限於衣服,可以為手套、口罩等,這些衣服、手套、口罩可以統稱為紅外隱身服裝。所述紅外隱身服裝包括一衣服本體,該衣服本體的至少部分佈料為所述的紅外隱身布料300。
本發明第四實施例提供的紅外隱身布料300和第五實施例提供的紅外隱身衣服400具有以下優點:第一、所述紅外光吸收體110對波長在2μm-20μm的近紅外至中紅外光具有良好的吸收效果,提高了所述紅外隱身布料300和紅外隱身衣服400的隱身效果;第二、所述紅外光吸收體110不僅具有全向吸收性能,而且與偏振無關,擴大了紅外隱身布料300和紅外隱身衣服400的使用範圍,也進一步提高了它們的隱身效果。
綜上所述,本發明確已符合發明專利之要件,遂依法提出專利申請。惟,以上所述者僅為本發明之較佳實施例,自不能以此限制本案之申請專利範圍。舉凡習知本案技藝之人士援依本發明之精神所作之等效修飾或變化,皆應涵蓋於以下申請專利範圍內。
110:紅外光吸收體
300:紅外隱身布料
310:布料襯底
Claims (10)
- 一種紅外隱身布料,其包括:一布料襯底;一紅外光吸收體,該紅外光吸收體設置在所述布料襯底上;其特徵在於,所述紅外光吸收體包括一奈米碳管結構,該奈米碳管結構包括一第一層奈米碳管拉膜、一第二層奈米碳管拉膜和一第三層奈米碳管拉膜,所述第一層奈米碳管拉膜、第二層奈米碳管拉膜和第三層奈米碳管拉膜層疊設置,所述第一層奈米碳管拉膜、第二層奈米碳管拉膜和第三層奈米碳管拉膜中的每一層包括複數個奈米碳管首尾相連且基本沿同一方向延伸,所述第一層奈米碳管拉膜和所述第二層奈米碳管拉膜中奈米碳管的延伸方向形成42度至48度的夾角,所述第一層奈米碳管拉膜和所述第三層奈米碳管拉膜中的奈米碳管的延伸方向形成84度至96度的夾角。
- 如請求項1所述的紅外隱身布料,其特徵在於,所述紅外隱身布料包括兩個布料襯底,所述紅外光吸收體設置在所述兩個布料襯底之間。
- 如請求項1所述的紅外隱身布料,其特徵在於,所述第一層奈米碳管拉膜和所述第二層奈米碳管拉膜中奈米碳管的延伸方向形成45度的夾角。
- 如請求項1所述的紅外隱身布料,其特徵在於,所述第一層奈米碳管拉膜和所述第三層奈米碳管拉膜中的奈米碳管的延伸方向形成90度的夾角。
- 如請求項1所述的紅外隱身布料,其特徵在於,所述第二層奈米碳管拉膜位於所述第一層奈米碳管拉膜和所述第三層奈米碳管拉膜之間,所述第一層奈米碳管拉膜和所述第三層奈米碳管拉膜中的奈米碳管的延伸方向形成90度的夾角,並且所述第一層奈米碳管拉膜和所述第二層奈米碳管拉膜中奈米碳管的延伸方向形成45度的夾角。
- 如請求項1所述的紅外隱身布料,其特徵在於,所述複數個奈米碳管在奈米碳管的延伸方向上首尾相連。
- 如請求項1所述的紅外隱身布料,其特徵在於,所述複數個奈米碳管平行於所述布料襯底的表面。
- 如請求項7所述的紅外隱身布料,其特徵在於,所述紅外光吸收體進一步包括一透明塗層,該透明塗層設置在所述奈米碳管結構的表面。
- 如請求項1所述的紅外隱身布料,其特徵在於,所述紅外光吸收體在250nm至2μm的波長範圍內的吸收率大於或者等於98.85%,在2μm至20μm的波長範圍內吸收率大於或者等於98.975%。
- 一種紅外隱身服裝,其包括一衣服本體,其特徵在於,所述衣服本體的至少部分佈料為請求項1-9中任意一項所述的紅外隱身布料。
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