TWI805842B - Covering tape for packing elecronic component and package - Google Patents

Covering tape for packing elecronic component and package Download PDF

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Publication number
TWI805842B
TWI805842B TW108133496A TW108133496A TWI805842B TW I805842 B TWI805842 B TW I805842B TW 108133496 A TW108133496 A TW 108133496A TW 108133496 A TW108133496 A TW 108133496A TW I805842 B TWI805842 B TW I805842B
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heat
layer
cover tape
sealing layer
tape
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TW108133496A
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TW202017820A (en
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井上真邦
長塚保則
築山一樹
萩尾宏徳
宮地貴樹
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日商大日本印刷股份有限公司
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D73/00Packages comprising articles attached to cards, sheets or webs
    • B65D73/02Articles, e.g. small electrical components, attached to webs
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/28Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D85/00Containers, packaging elements or packages, specially adapted for particular articles or materials
    • B65D85/67Containers, packaging elements or packages, specially adapted for particular articles or materials for web or tape-like material
    • B65D85/671Containers, packaging elements or packages, specially adapted for particular articles or materials for web or tape-like material wound in flat spiral form

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Packaging Frangible Articles (AREA)
  • Packages (AREA)
  • Laminated Bodies (AREA)

Abstract

The present disclosure provides a covering tape for packing electronic component, the covering tape comprising: a base material layer, a heat seal layer that is disposed at one surface side of the base material layer and includes an ethylene-vinyl acetate copolymer, and an antistatic layer that is disposed at the opposite surface side to the heat seal layer side of the base material layer and includes a conductive polymer; wherein the Vickers hardness of the heat seal layer is a specific value or more.

Description

電子零件包裝用覆蓋帶及包裝體Cover tape and package body for packaging electronic parts

本發明係關於一種電子零件包裝用覆蓋帶及使用其之包裝體。The invention relates to a cover tape for packaging electronic parts and a package using the same.

近年來,IC(Integrated Circuit,積體電路)、電阻、電晶體、二極體、電容器、壓電元件暫存器等電子零件係進行編帶包裝,而供於表面安裝。編帶包裝中,於具有複數個收納電子零件之收納部之載帶收納電子零件之後,利用覆蓋帶將載帶熱密封,而獲得用於保管及搬送電子零件之包裝體。又,於電子零件之安裝時,將覆蓋帶自載帶剝離,將電子零件自動取出而表面安裝於基板。關於電子零件之表面安裝,伴隨近年來之電子設備之高速通信化、高速運算處理化,有零件件數增加之傾向,而要求安裝之進一步之效率化、高速化。再者,覆蓋帶亦稱為頂帶。In recent years, electronic components such as IC (Integrated Circuit), resistors, transistors, diodes, capacitors, and piezoelectric element registers have been taped and packaged for surface mounting. In the tape packaging, after storing the electronic components in a carrier tape having a plurality of storage portions for storing electronic components, the carrier tape is heat-sealed with a cover tape to obtain a package for storing and transporting the electronic components. In addition, when mounting electronic components, the cover tape is peeled off from the carrier tape, and the electronic components are automatically taken out and surface-mounted on the substrate. With regard to the surface mounting of electronic components, with the high-speed communication and high-speed computing processing of electronic equipment in recent years, there is a tendency for the number of parts to increase, and further efficiency and speed of mounting are required. Furthermore, the cover tape is also called the top tape.

對於覆蓋帶,要求可自載帶容易地剝離。若覆蓋帶之剝離強度過強,則存在如下問題:於電子零件之安裝時將覆蓋帶自載帶剝離時,載帶振動而電子零件自收納部跳出或覆蓋帶斷裂。伴隨安裝之高速化,於以高速剝離覆蓋帶之情形時,尤其成為問題。For the cover tape, it is required to be easily peelable from the carrier tape. If the peeling strength of the cover tape is too strong, there is a problem that when the cover tape is peeled from the carrier tape during mounting of electronic parts, the carrier tape vibrates and the electronic parts jump out of the storage portion or the cover tape breaks. This becomes a problem particularly when the cover tape is peeled off at high speed along with the speed-up of mounting.

又,編帶包裝中存在如下情形:電子零件因與載帶或覆蓋帶之摩擦或接觸而產生靜電,此外因安裝時將覆蓋帶自載帶剝離而產生靜電。後者之現象稱為剝離帶電。剝離速度越快,剝離帶電越大。因剝離帶電,導致安裝時電子零件附著於覆蓋帶,無法將電子零件正常取出,或電子零件自載帶之收納部跳出。其導致安裝效率之下降。進而,亦有因靜電而產生電子零件之劣化及破壞之虞。Also, in tape packaging, static electricity may be generated by friction or contact between electronic parts and the carrier tape or cover tape, and static electricity may be generated by peeling the cover tape from the carrier tape during mounting. The latter phenomenon is called stripping electrification. The faster the stripping speed, the greater the stripping charge. Due to the stripped electrification, the electronic parts are attached to the cover tape during installation, and the electronic parts cannot be taken out normally, or the electronic parts jump out of the storage part of the carrier tape. This leads to a decrease in installation efficiency. Furthermore, there is also a possibility of deterioration and destruction of electronic components due to static electricity.

因此,提出有各種具有抗靜電性之覆蓋帶(例如參照專利文獻1~3)。 [先前技術文獻] [專利文獻]Therefore, various cover tapes having antistatic properties have been proposed (for example, refer to Patent Documents 1 to 3). [Prior Art Literature] [Patent Document]

[專利文獻1]日本專利第4162961號 [專利文獻2]日本專利特開平10-95448號公報 [專利文獻3]日本專利第4061136號[Patent Document 1] Japanese Patent No. 4162961 [Patent Document 2] Japanese Patent Laid-Open No. 10-95448 [Patent Document 3] Japanese Patent No. 4061136

[發明所欲解決之問題][Problem to be solved by the invention]

然而,本發明之發明者等瞭解到即便於使用具有抗靜電性之覆蓋帶之情形時,亦有電子零件附著於覆蓋帶之情況。However, the inventors of the present invention have found that even when an antistatic cover tape is used, electronic parts may adhere to the cover tape.

本發明係鑒於上述問題而成者,其目的在於提供一種可抑制電子零件之附著之電子零件包裝用覆蓋帶。 [解決問題之技術手段]This invention was made in view of the above-mentioned problem, and it aims at providing the cover tape for packaging electronic components which can suppress the adhesion of electronic components. [Technical means to solve the problem]

本發明之一實施形態提供一種電子零件包裝用覆蓋帶,其具有:基材層;熱密封層,其配置於上述基材層之一面側,包含乙烯-乙酸乙烯酯共聚物;及抗靜電層,其配置於上述基材層之與上述熱密封層側之面相反之面側,包含導電性高分子;且上述熱密封層之維氏硬度為2.0以上。One embodiment of the present invention provides a cover tape for packaging electronic components, which has: a base material layer; a heat seal layer, which is arranged on one side of the base material layer, and includes an ethylene-vinyl acetate copolymer; and an antistatic layer. , which is disposed on the side of the substrate layer opposite to the side of the heat-sealing layer, and includes a conductive polymer; and the heat-sealing layer has a Vickers hardness of 2.0 or more.

本發明之一實施形態提供一種包裝體,其具備:載帶,其具有收納電子零件之複數個收納部;電子零件,其收納於上述收納部;及上述電子零件包裝用覆蓋帶,其以覆蓋上述收納部之方式配置。 [發明之效果]One embodiment of the present invention provides a package including: a carrier tape having a plurality of storage sections for storing electronic components; electronic components stored in the storage sections; The storage part is configured in the manner mentioned above. [Effect of Invention]

本發明中,可提供一種可抑制電子零件之附著之電子零件包裝用覆蓋帶。In the present invention, a cover tape for packaging electronic components capable of suppressing adhesion of electronic components can be provided.

下述中一面參照圖式等一面對本發明之實施形態進行說明。但,本發明能以多種不同態樣實施,並不限定於下述中例示之實施形態之記載內容進行解釋。又,圖式有為使說明更明確,而與實際形態相比,關於各部之寬度、厚度、形狀等模式性地表示之情形,但僅為一例,並不限定本發明之解釋。又,本說明書與各圖中,對於與關於已提出之圖已經敍述者同樣之要素,有附上同一符號而適當省略詳細說明之情形。Embodiments of the present invention will be described below with reference to the drawings and the like. However, the present invention can be implemented in various forms, and should not be limited to the descriptions of the embodiments exemplified below and interpreted. In addition, in order to clarify the description, the drawings may schematically show the width, thickness, shape, etc. of each part compared with the actual form, but these are just examples and do not limit the interpretation of the present invention. In addition, in this specification and each drawing, the same reference numerals may be attached to the same elements as those described in the already proposed drawings, and detailed description may be appropriately omitted.

本說明書中,於表現在某構件上配置其他構件之態樣時,在僅記為「於上」或「於下」之情形時,只要無特別預先說明,設為包括以與某構件相接之方式於正上方或正下方配置其他構件之情形、及於某構件之上方或下方進而隔著另外之構件配置其他構件之情形兩者。又,本說明書中,於表現在某構件之面配置其他構件之態樣時,在僅記為「於面側」或「於面」之情形時,只要無特別預先說明,設為包括以與某構件相接之方式於正上方或正下方配置其他構件之情形、及於某構件之上方或下方進而隔著另外之構件配置其他構件之情形兩者。In this specification, when expressing the aspect of arranging other components on a certain component, when it is only described as "on top" or "under", unless otherwise specified in advance, it is assumed that it is included to be in contact with a certain component. Both the case of disposing other components directly above or directly below, and the situation of disposing other components above or below a certain component through another component. Also, in this specification, when expressing an aspect of arranging another member on the surface of a member, when it is only described as "on the side of the face" or "on the face", unless otherwise specified, it is assumed to include the same as Both the case of arranging other members directly above or directly below a certain member in a connected manner, and the case of arranging other members above or below a certain member with another member interposed therebetween.

以下,對本發明之電子零件包裝用覆蓋帶及包裝體進行詳細說明。Hereinafter, the cover tape and package body for electronic component packaging of this invention are demonstrated in detail.

A.電子零件包裝用覆蓋帶 本發明之電子零件包裝用覆蓋帶具有:基材層;熱密封層,其配置於上述基材層之一面側,包含乙烯-乙酸乙烯酯共聚物;及抗靜電層,其配置於上述基材層之與上述熱密封層側之面相反之面側,包含導電性高分子;且上述熱密封層之維氏硬度為2.0以上。再者,本說明書中,有將「電子零件包裝用覆蓋帶」簡稱為「覆蓋帶」之情形。A. Cover tape for electronic parts packaging The cover tape for packaging electronic parts of the present invention has: a base material layer; a heat-sealing layer disposed on one side of the base material layer and comprising an ethylene-vinyl acetate copolymer; and an antistatic layer disposed on the base material The side of the layer opposite to the side of the heat-sealing layer includes a conductive polymer; and the Vickers hardness of the heat-sealing layer is 2.0 or more. In addition, in this specification, a "cover tape for packaging electronic components" may be simply referred to as a "cover tape".

參照圖式對本發明之覆蓋帶進行說明。圖1係表示本發明之覆蓋帶之一例之概略剖視圖。如圖1所示,本發明之覆蓋帶1具有:基材層2;熱密封層3,其配置於基材層2之一面側,包含乙烯-乙酸乙烯酯共聚物;及抗靜電層4,其配置於基材層2之與熱密封層3側之面相反之面側,包含導電性高分子。熱密封層3之維氏硬度為特定範圍。The cover tape of the present invention will be described with reference to the drawings. Fig. 1 is a schematic sectional view showing an example of the cover tape of the present invention. As shown in FIG. 1 , the cover tape 1 of the present invention has: a base material layer 2; a heat-sealing layer 3, which is disposed on one side of the base material layer 2, comprising ethylene-vinyl acetate copolymer; and an antistatic layer 4, It is disposed on the side of the substrate layer 2 opposite to the side of the heat-sealing layer 3 and includes a conductive polymer. The Vickers hardness of the heat-sealing layer 3 is within a specific range.

圖2(a)、(b)係表示使用本發明之電子零件包裝用覆蓋帶之包裝體之一例的概略俯視圖及剖視圖,圖2(b)係圖2(a)之A-A線剖視圖。如圖2(a)、(b)所示,包裝體10具備:載帶11,其具有收納電子零件13之複數個收納部12;電子零件13,其收納於收納部12;及覆蓋帶1,其以覆蓋收納部12之方式配置。於載帶11熱密封有覆蓋帶1,於覆蓋帶1之熱密封層3之兩端以特定寬度呈線狀設有熱密封部3h。又,包裝體10中,載帶11可具有輸送孔14。Fig. 2 (a), (b) are the schematic top view and sectional view of an example of the packaging body showing the use of the cover tape for packaging electronic parts of the present invention, and Fig. 2 (b) is the A-A sectional view of Fig. 2 (a). As shown in Figure 2 (a), (b), the package 10 is equipped with: a carrier tape 11, which has a plurality of storage parts 12 for storing electronic parts 13; electronic parts 13, which are stored in the storage parts 12; and a cover tape 1 , which is arranged to cover the housing portion 12 . The cover tape 1 is heat-sealed to the carrier tape 11 , and heat-sealed portions 3 h are provided in a linear shape with a predetermined width at both ends of the heat-seal layer 3 of the cover tape 1 . Moreover, in the package 10, the carrier tape 11 may have the conveyance hole 14. As shown in FIG.

本發明之發明者等首先瞭解到具有包含導電性高分子之抗靜電層與包含乙烯-乙酸乙烯酯共聚物之熱密封層之覆蓋帶兼具良好之抗靜電性、以及熱密封性及剝離性。然而,瞭解到即便於使用具有良好之抗靜電性之覆蓋帶之情形時,亦有電子零件附著於覆蓋帶之情形。繼而,為解決上述問題而進行努力研究,結果本發明之發明者等瞭解到對於電子零件向覆蓋帶之附著,不僅靜電而且覆蓋帶之熱密封層之硬度亦產生影響。進而反覆研究,發現藉由將包含乙烯-乙酸乙烯酯共聚物之熱密封層之硬度設為特定範圍,可抑制電子零件向覆蓋帶之附著。The inventors of the present invention first realized that a cover tape having an antistatic layer comprising a conductive polymer and a heat-sealing layer comprising an ethylene-vinyl acetate copolymer has good antistatic properties, heat-sealing properties, and peelability . However, it has been found that even when a cover tape having good antistatic properties is used, electronic parts may adhere to the cover tape. Then, as a result of diligent research to solve the above problems, the inventors of the present invention found that not only static electricity but also the hardness of the heat-sealing layer of the cover tape affects the adhesion of electronic components to the cover tape. Furthermore, after repeated studies, it was found that the adhesion of electronic parts to the cover tape can be suppressed by setting the hardness of the heat-sealing layer made of an ethylene-vinyl acetate copolymer into a specific range.

藉由將覆蓋帶之熱密封層之硬度設為特定範圍而可抑制電子零件向覆蓋帶之附著之理由並不確定,但推測為如下。維氏硬度係壓入硬度之一種。本發明中,覆蓋帶之熱密封層之維氏硬度為特定值以上,而成為相對較硬之層。因此,推測為於使用本發明之覆蓋帶之包裝體中,於包裝體之製作時或包裝體之保管或搬送時,電子零件接觸於覆蓋帶之熱密封層時,覆蓋帶之熱密封層難以追隨於電子零件之接觸面,即電子零件難以陷入於覆蓋帶之熱密封層。因此,推測為於使用本發明之覆蓋帶之包裝體中,將覆蓋帶自載帶剝離時,可使電子零件難以貼附於覆蓋帶之熱密封層。The reason why the adhesion of electronic components to the cover tape can be suppressed by setting the hardness of the heat-sealing layer of the cover tape into a specific range is not certain, but it is estimated as follows. Vickers hardness is one of indentation hardness. In the present invention, the Vickers hardness of the heat-sealing layer of the cover tape is a specific value or more, and thus becomes a relatively hard layer. Therefore, it is speculated that in the package using the cover tape of the present invention, when the electronic component is in contact with the heat-sealing layer of the cover tape during the production of the package or during the storage or transportation of the package, the heat-sealing layer of the cover tape is difficult to Following the contact surface of electronic parts, it is difficult for electronic parts to sink into the heat-sealing layer of the cover tape. Therefore, it is presumed that in the package using the cover tape of the present invention, when the cover tape is peeled off from the carrier tape, it is possible to make it difficult for electronic components to adhere to the heat-sealing layer of the cover tape.

另一方面,若覆蓋帶之熱密封層為相對較軟之層,則電子零件接觸於覆蓋帶之熱密封層時,覆蓋帶之熱密封層易追隨於電子零件之接觸面,即電子零件易陷入於覆蓋帶之熱密封層。因此,認為即便於覆蓋帶具有抗靜電性之情形時,亦產生電子零件向覆蓋帶之熱密封層之貼附。On the other hand, if the heat-sealing layer of the cover tape is a relatively soft layer, when the electronic parts are in contact with the heat-sealing layer of the cover tape, the heat-sealing layer of the cover tape is easy to follow the contact surface of the electronic parts, that is, the electronic parts are easy to Trapped in the heat seal layer of the cover tape. Therefore, it is considered that even when the cover tape has antistatic properties, the adhesion of electronic components to the heat-sealing layer of the cover tape occurs.

亦認為若假設無須考慮覆蓋帶之熱密封性及剝離性,則優先電子零件難以貼附之觀點而選擇熱密封層之材料。但,本發明之覆蓋帶中,重要的是為使熱密封性及剝離性良好而使用包含乙烯-乙酸乙烯酯共聚物之熱密封層,且將熱密封層之維氏硬度設為特定值以上。通常而言,乙烯-乙酸乙烯酯共聚物有使層相對較柔之傾向,因此有電子零件易貼附於包含乙烯-乙酸乙烯酯共聚物之層之傾向,但藉由將熱密封層之維氏硬度設為特定值以上,可使電子零件難以貼附。It is also considered that if it is assumed that there is no need to consider the heat-sealability and peelability of the cover tape, the material of the heat-sealing layer will be selected based on the viewpoint that electronic parts are difficult to attach. However, in the cover tape of the present invention, it is important to use a heat-sealing layer containing an ethylene-vinyl acetate copolymer for good heat-sealing properties and peelability, and to set the Vickers hardness of the heat-sealing layer to a specific value or more. . In general, ethylene-vinyl acetate copolymers have a tendency to make layers relatively soft, and thus have a tendency for electronic parts to be easily attached to layers comprising ethylene-vinyl acetate copolymers, but by making the heat-sealing layer dimensionally When the hardness is set above a certain value, it is difficult to attach electronic parts.

於覆蓋帶之抗靜電性不充分之情形時,由於靜電對附著之貢獻較大,故而藉由將熱密封層之維氏硬度設為特定值以上所產生之效果有限。因此,重要的是將包含乙烯-乙酸乙烯酯共聚物之熱密封層之維氏硬度設為特定值以上,並且於基材層之與熱密封層相反之面側具有包含導電性高分子之抗靜電層。包含導電性高分子之抗靜電層之抗靜電性能難以受到溫度或濕度之影響而獲得穩定之抗靜電性能,因此易享有藉由將熱密封層之維氏硬度設為特定值以上所產生之效果。又,包含導電性高分子之抗靜電層與包含其他抗靜電劑之抗靜電層相比通常可使層之厚度較薄,因此對熱密封性能之影響較少。紙載帶與塑膠載帶相比熱密封性及剝離性不佳,因此於使用紙載帶之情形時尤其重要的是抑制對熱密封性能之影響。又,導電性高分子難以發生自層內部向層表面側經時析出之所謂滲出現象。因此,藉由在具有包含乙烯-乙酸乙烯酯共聚物之熱密封層之覆蓋帶中使用包含導電性高分子之抗靜電層,可抑制於包裝體中紙載帶之表面與覆蓋帶之抗靜電層之表面接觸時抗靜電劑透印而剝離性能下降。In the case where the antistatic property of the cover tape is insufficient, the effect of setting the Vickers hardness of the heat-sealing layer to a certain value or more is limited because static electricity greatly contributes to the adhesion. Therefore, it is important to set the Vickers hardness of the heat-sealing layer made of ethylene-vinyl acetate copolymer to a certain value or more, and to have a resistance layer made of a conductive polymer on the side of the substrate layer opposite to the heat-sealing layer. Static layer. The antistatic performance of the antistatic layer containing conductive polymers is difficult to be affected by temperature or humidity to obtain stable antistatic performance, so it is easy to enjoy the effect produced by setting the Vickers hardness of the heat sealing layer above a specific value . In addition, the antistatic layer containing conductive polymer can generally make the thickness of the layer thinner than the antistatic layer containing other antistatic agents, so it has less influence on the heat sealing performance. Compared with plastic carrier tapes, paper carrier tapes are inferior in heat sealability and peelability, so when using paper carrier tapes, it is especially important to suppress the influence on heat sealability. Also, the so-called exudation phenomenon in which the conductive polymer is precipitated from the inside of the layer to the surface of the layer over time is less likely to occur. Therefore, by using an antistatic layer containing a conductive polymer in a cover tape having a heat seal layer containing an ethylene-vinyl acetate copolymer, the antistatic properties of the surface of the paper carrier tape and the cover tape in the package can be suppressed. When the surface of the layer is in contact, the antistatic agent will print through and the peeling performance will decrease.

又,為使覆蓋帶之抗靜電性提高,考慮於熱密封層添加抗靜電劑。於熱密封層使用乙烯-乙酸乙烯酯共聚物之情形時,為抑制對熱密封性能之影響或抑制滲出現象,可使用非離子性界面活性劑或極性相對較低之離子性活性劑。由於紙載帶與塑膠載帶相比熱密封性及剝離性不佳,故而於使用紙載帶之情形時尤其重要的是抑制對熱密封性能之影響。但,非離子性界面活性劑或極性相對較低之離子性活性劑易留存於層內部而難以發生滲出現象,但相反有難以發揮抗靜電性能之虞。因此,藉由在基材層之與熱密封層相反之面側具有包含導電性高分子之抗靜電層,可使覆蓋帶之抗靜電性提高。再者,藉由在基材層之與熱密封層相反之面側使用包含導電性高分子之抗靜電層,並且於熱密封層添加抗靜電劑,可使覆蓋帶之抗靜電性進一步提高。Also, in order to improve the antistatic property of the cover tape, it is considered to add an antistatic agent to the heat seal layer. When ethylene-vinyl acetate copolymer is used in the heat-sealing layer, a non-ionic surfactant or a relatively low-polarity ionic active agent can be used to suppress the effect on the heat-sealing performance or to suppress bleeding. Since paper carrier tapes are inferior in heat sealability and peelability compared to plastic carrier tapes, it is especially important to suppress the influence on heat sealability when paper carrier tapes are used. However, non-ionic surfactants or ionic active agents with relatively low polarity tend to remain inside the layer and are difficult to bleed out, but on the contrary, it may be difficult to exert antistatic performance. Therefore, the antistatic property of the cover tape can be improved by having an antistatic layer containing a conductive polymer on the side of the substrate layer opposite to the heat-sealing layer. Furthermore, the antistatic property of the cover tape can be further improved by using an antistatic layer containing a conductive polymer on the side of the substrate layer opposite to the heat-sealing layer, and adding an antistatic agent to the heat-sealing layer.

如此,本發明中,於具有包含導電性高分子之抗靜電層與包含乙烯-乙酸乙烯酯共聚物之熱密封層之覆蓋帶中,熱密封層之維氏硬度為特定值以上,藉此於使用本發明之覆蓋帶之包裝體中在將覆蓋帶自載帶剝離時,可抑制電子零件向覆蓋帶之貼附。因此,可抑制因電子零件向覆蓋帶貼附所引起之電子零件自載帶之收納部之跳出、浮升、立起等,而可正常取出電子零件。因此,可使安裝效率提高。Thus, in the present invention, in the cover tape having an antistatic layer comprising a conductive polymer and a heat-sealing layer comprising an ethylene-vinyl acetate copolymer, the heat-sealing layer has a Vickers hardness of a specified value or more, whereby In the package using the cover tape of the present invention, when the cover tape is peeled off from the carrier tape, adhesion of electronic components to the cover tape can be suppressed. Therefore, it is possible to suppress jumping, lifting, and standing up of the electronic parts from the storage portion of the carrier tape due to the attachment of the electronic parts to the cover tape, and it is possible to take out the electronic parts normally. Therefore, mounting efficiency can be improved.

以下,對本發明之覆蓋帶之各構成進行說明。Hereinafter, each structure of the cover tape of this invention is demonstrated.

1.熱密封層 本發明中之熱密封層係配置於基材層之一面側,包含乙烯-乙酸乙烯酯共聚物之層。熱密封層係於使用本發明之覆蓋帶製造包裝體時藉由對載帶熱密封,而將覆蓋帶與載帶接著。1. Heat sealing layer The heat-sealing layer in the present invention is disposed on one side of the substrate layer and includes a layer of ethylene-vinyl acetate copolymer. The heat-sealing layer adheres the cover tape to the carrier tape by heat-sealing the carrier tape when the package is manufactured using the cover tape of the present invention.

熱密封層之維氏硬度為2.0以上。藉由上述維氏硬度為上述範圍,可抑制電子零件向覆蓋帶之貼附。熱密封層之維氏硬度亦可為2.3以上,亦可為2.6以上。又,熱密封層之維氏硬度之上限並無特別限定,例如可設為6.0以下,亦可為5.5以下。若上述維氏硬度過高,則有熱密封性下降之虞,且有於使覆蓋帶成為卷狀時無法徹底地捲繞,或熱密封層產生皸裂之虞。The Vickers hardness of the heat-sealing layer is above 2.0. When the said Vickers hardness is the said range, the sticking of an electronic component to a cover tape can be suppressed. The Vickers hardness of the heat-sealing layer may be not less than 2.3, or not less than 2.6. Moreover, the upper limit of the Vickers hardness of a heat-sealing layer is not specifically limited, For example, it may be 6.0 or less, and may be 5.5 or less. When the said Vickers hardness is too high, heat-sealing property may fall, and when a cover tape is made into a roll shape, it may not be fully wound, or a heat-sealing layer may crack.

熱密封層之維氏硬度可利用熱密封層所使用之材料之種類或含量進行調節。本發明中之熱密封層亦可僅利用乙烯-乙酸乙烯酯共聚物獲得所期望之維氏硬度。例如,可使用獲得所期望之維氏硬度之乙烯-乙酸乙烯酯共聚物。但,通常知悉乙烯-乙酸乙烯酯共聚物於樹脂中柔軟性亦較佳。因此,藉由使用經改性之乙烯-乙酸乙烯酯共聚物或經交聯之乙烯-乙酸乙烯酯共聚物,可提高熱密封層之維氏硬度而獲得所期望之維氏硬度。或者,藉由使用乙烯-乙酸乙烯酯共聚物與較該乙烯-乙酸乙烯酯共聚物硬之有機物或無機物,可提高熱密封層之維氏硬度而獲得所期望之維氏硬度。作為較乙烯-乙酸乙烯酯共聚物硬之有機物,通常可列舉:耐熱性較乙烯-乙酸乙烯酯共聚物高之樹脂、儲存彈性模數較乙烯-乙酸乙烯酯共聚物高之樹脂、密度較乙烯-乙酸乙烯酯共聚物高之樹脂、經交聯之樹脂等。該等有機物或無機物可於熱密封層內以粒子狀存在,亦能以與乙烯-乙酸乙烯酯共聚物相容或不相容之狀態存在。The Vickers hardness of the heat-sealing layer can be adjusted by the type or content of the material used in the heat-sealing layer. The heat-sealing layer in the present invention can also only use ethylene-vinyl acetate copolymer to obtain the desired Vickers hardness. For example, ethylene-vinyl acetate copolymers that give the desired Vickers hardness can be used. However, it is generally known that ethylene-vinyl acetate copolymer has better flexibility among resins. Therefore, by using the modified ethylene-vinyl acetate copolymer or the cross-linked ethylene-vinyl acetate copolymer, the Vickers hardness of the heat-sealing layer can be increased to obtain a desired Vickers hardness. Alternatively, by using an ethylene-vinyl acetate copolymer and an organic or inorganic substance harder than the ethylene-vinyl acetate copolymer, the Vickers hardness of the heat-sealing layer can be increased to obtain a desired Vickers hardness. As organic substances harder than ethylene-vinyl acetate copolymers, generally, resins with higher heat resistance than ethylene-vinyl acetate copolymers, resins with higher storage elastic modulus than ethylene-vinyl acetate copolymers, and resins with higher densities than ethylene-vinyl acetate copolymers can be listed. - Resin with high vinyl acetate copolymer, cross-linked resin, etc. These organic or inorganic substances may exist in the form of particles in the heat-sealing layer, and may also exist in a state compatible or incompatible with the ethylene-vinyl acetate copolymer.

本發明中之熱密封層之維氏硬度係利用奈米壓痕法所得之維氏硬度。作為熱密封層之利用奈米壓痕法所得之維氏硬度(無因次)之具體測定方法,對於熱密封層之與基材層為相反側之面,自垂直方向壓入對面角136°之鑽石正四角錐形狀之維氏壓頭,根據所得之荷重-位移曲線算出壓痕硬度(壓入硬度)HIT ,進而將壓痕硬度(壓入硬度)HIT 換算成維氏硬度HV,將其對於30個部位求得平均,將該平均值設為熱密封層之維氏硬度。再者,壓痕硬度(壓入硬度)HIT 更具體而言如下述式(1)所示藉由如下方式求得,即計算藉由維氏壓頭之最大壓入深度hmax 之壓入所形成之稜錐形的凹陷壓頭之接觸投影面積Ap (mm2 ),將試驗最大荷重F(N)除以該接觸投影面積Ap (mm2 )。 HIT =F/Ap (1) 又,自壓痕硬度(壓入硬度)HIT 向維氏硬度HV之換算依照下述式(2)。 HV=HIT ×0.0945   (2) 熱密封層之維氏硬度之測定方法之詳細內容如下所述。可基於奈米壓痕法,於下述特定條件下將壓頭壓入熱密封層,而測定熱密封層之維氏硬度。再者,利用奈米壓痕法之維氏硬度之測定可使用Fischer Instruments公司製造之Picodentor HM-500進行測定。 <測定條件> ・負載荷重   0~0.27 mN(連續地增加荷重,根據壓入深度測定硬度) ・荷重施加速度   0.27 mN/10秒 ・保持時間   10秒 ・荷重卸載速度   0.27 mN/10秒 ・壓頭   維氏(四角錐之前端部分之對面角為136°) ・測定溫度   25℃±3℃ ・變更測定部位,N=30且最大壓入深度hmax 為0.8 μm~1.0 μm之部位之平均值The Vickers hardness of the heat-sealing layer in the present invention is the Vickers hardness obtained by nanoindentation method. As a specific measurement method for the Vickers hardness (dimensionless) obtained by the nanoindentation method of the heat-sealing layer, for the surface of the heat-sealing layer that is opposite to the base layer, indent from the vertical direction at an opposite angle of 136° The Vickers indenter in the shape of a diamond square pyramid, calculates the indentation hardness (indentation hardness) H IT according to the obtained load-displacement curve, and then converts the indentation hardness (indentation hardness) H IT into Vickers hardness HV. The average value was calculated|required about 30 places, and this average value was made into the Vickers hardness of a heat-sealing layer. Furthermore, the indentation hardness (indentation hardness) H IT is more specifically obtained as shown in the following formula (1) by calculating the maximum indentation depth h max of the Vickers indenter. The contact projected area A p (mm 2 ) of the formed pyramid-shaped concave indenter is divided by the contact projected area A p (mm 2 ) of the maximum test load F(N). H IT =F/A p (1) The conversion from the indentation hardness (indentation hardness) H IT to the Vickers hardness HV follows the following formula (2). HV=H IT ×0.0945 (2) The details of the method for measuring the Vickers hardness of the heat-sealing layer are as follows. Based on the nano-indentation method, the indenter can be pressed into the heat-sealing layer under the following specific conditions to measure the Vickers hardness of the heat-sealing layer. In addition, the measurement of the Vickers hardness by the nanoindentation method can be measured using Picodentor HM-500 by Fischer Instruments company. <Measurement conditions> ・Load load 0~0.27 mN (increase the load continuously, measure the hardness according to the indentation depth) ・Load application speed 0.27 mN/10 seconds ・Hold time 10 seconds ・Load unloading speed 0.27 mN/10 seconds ・Indenter Vickers (the opposite angle of the front end of the quadrangular pyramid is 136°) ・Measurement temperature 25℃±3℃ ・Change the measurement location, the average value of the part where N=30 and the maximum indentation depth h max is 0.8 μm~1.0 μm

熱密封層包含乙烯-乙酸乙烯酯共聚物。藉由熱密封層包含乙烯-乙酸乙烯酯共聚物,對載帶之熱密封性及剝離性變得良好。通常,紙載帶之表面之凹凸較塑膠載帶大,難以熱密封成對覆蓋帶不產生計劃外之剝離,且於安裝時容易自覆蓋帶剝離。具有包含乙烯-乙酸乙烯酯共聚物之熱密封層之覆蓋帶即便對於紙載帶,亦可獲得良好之熱密封性及良好之剝離性。乙烯-乙酸乙烯酯共聚物可經改性,亦可經交聯。The heat seal layer comprises ethylene-vinyl acetate copolymer. When the heat-sealing layer contains the ethylene-vinyl acetate copolymer, the heat-sealing property and peelability to the carrier tape become favorable. Usually, the unevenness of the surface of the paper carrier tape is larger than that of the plastic carrier tape, it is difficult to heat seal the paired cover tape without unplanned peeling, and it is easy to peel off from the cover tape during installation. A cover tape having a heat-sealing layer comprising an ethylene-vinyl acetate copolymer can obtain good heat-sealing properties and good peelability even for paper carrier tapes. Ethylene-vinyl acetate copolymers can be modified and crosslinked.

熱密封層中之乙烯-乙酸乙烯酯共聚物之含量例如可設為5質量%以上,亦可為10質量%以上,亦可為15質量%以上。又,上述乙烯-乙酸乙烯酯共聚物之含量例如可設為100質量%以下,亦可為50質量%以下,亦可為40質量%以下,亦可為30質量%以下。The content of the ethylene-vinyl acetate copolymer in the heat-sealing layer may be, for example, 5% by mass or more, 10% by mass or more, or 15% by mass or more. Moreover, content of the said ethylene-vinyl acetate copolymer may be 100 mass % or less, 50 mass % or less, 40 mass % or less, or 30 mass % or less, for example.

熱密封層只要包含乙烯-乙酸乙烯酯共聚物,亦可包含其他樹脂。作為其他樹脂,例如可列舉:聚乙烯或聚丙烯等聚烯烴、聚酯、聚丙烯酸酯或聚甲基丙烯酸酯等丙烯酸樹脂等。該等樹脂亦可經改性。該等樹脂可用於熱密封層之維氏硬度之調整。The heat-sealing layer may contain other resins as long as it contains an ethylene-vinyl acetate copolymer. Examples of other resins include polyolefins such as polyethylene and polypropylene, polyesters, acrylic resins such as polyacrylates and polymethacrylates, and the like. These resins may also be modified. These resins can be used to adjust the Vickers hardness of the heat-sealing layer.

熱密封層中,視需要亦可包含例如黏著賦予劑、抗靜電劑、抗黏連劑、分散劑、填充劑、塑化劑、著色劑等添加劑。該等添加劑可用於熱密封層之維氏硬度之調整。於熱密封層中添加抗靜電劑之情形時,其添加量可設為使本發明之覆蓋帶之表面電阻處於後述之數值範圍內所需之值。In the heat-sealing layer, for example, additives such as tackifiers, antistatic agents, antiblocking agents, dispersants, fillers, plasticizers, and coloring agents may be contained as necessary. These additives can be used to adjust the Vickers hardness of the heat-sealing layer. When adding an antistatic agent to a heat-sealing layer, the addition amount can be made into the value required for the surface resistance of the cover tape of this invention to fall in the numerical value range mentioned later.

熱密封層之厚度例如可設為0.05 μm以上50 μm以下。於紙載帶之情形時,熱密封層之厚度例如可設為5 μm以上50 μm以下,亦可為10 μm以上25 μm以下。於塑膠載帶之情形時,熱密封層之厚度例如可設為0.05 μm以上10 μm以下,亦可為0.1 μm以上5 μm以下。若熱密封層之厚度過薄,則有無法獲得均勻之膜之情形。又,若熱密封層之厚度過厚,則有覆蓋帶之透明性下降,或對載帶之熱密封性下降之虞。The thickness of the heat-sealing layer can be set to, for example, not less than 0.05 μm and not more than 50 μm. In the case of a paper carrier tape, the thickness of the heat-sealing layer may be, for example, not less than 5 μm and not more than 50 μm, or may be not less than 10 μm and not more than 25 μm. In the case of a plastic carrier tape, the thickness of the heat-sealing layer may be, for example, not less than 0.05 μm and not more than 10 μm, or may be not less than 0.1 μm and not more than 5 μm. When the thickness of the heat-sealing layer is too thin, a uniform film may not be obtained. Moreover, when the thickness of a heat-sealing layer is too thick, the transparency of a cover tape may fall, or the heat-sealing property to a carrier tape may fall.

作為熱密封層之形成方法,例如可列舉如下方法:使用將乙烯-乙酸乙烯酯共聚物及視需要之上述其他樹脂或添加劑等分散或溶解於溶劑而成之熱密封層用組合物,於基材層之一面側塗佈上述熱密封層用組合物並使其乾燥。作為上述熱密封層用組合物之塗佈方法,例如可列舉輥塗法、逆輥塗佈法、凹版塗佈法、凹版反向塗佈法、缺角輪塗佈法、棒式塗佈法、線棒塗佈法、桿式塗佈法、接觸塗佈法、刀式塗佈法、模嘴塗佈法、流塗法、浸漬塗佈法、噴塗法等公知之塗佈法。As a method of forming the heat-sealing layer, for example, the method of using a composition for a heat-sealing layer obtained by dispersing or dissolving an ethylene-vinyl acetate copolymer and, if necessary, the above-mentioned other resins or additives, etc. in a solvent, on a base One side of the material layer was coated with the above-mentioned composition for a heat seal layer and dried. Examples of coating methods for the composition for the heat seal layer include roll coating, reverse roll coating, gravure coating, gravure reverse coating, chipped wheel coating, and bar coating. , wire bar coating method, rod coating method, contact coating method, knife coating method, die coating method, flow coating method, dip coating method, spray coating method and other known coating methods.

又,可使用膜作為熱密封層。於此情形時,作為基材層及熱密封層之積層方法,並無特別限定,可使用公知之方法。例如可列舉:將預先製造之膜利用接著劑貼合於基材層之方法、或將熱熔融之膜之原材料利用T型模頭等擠出於基材層而獲得積層體之方法等。作為接著劑,例如可使用聚酯系接著劑、聚胺基甲酸酯系接著劑、丙烯酸系接著劑等。Also, a film may be used as the heat-sealing layer. In this case, the lamination method of the base material layer and the heat-sealing layer is not particularly limited, and a known method can be used. For example, a method of laminating a pre-manufactured film to a base layer with an adhesive, or a method of extruding a thermally fused film raw material onto a base layer using a T-die or the like to obtain a laminate. As an adhesive agent, a polyester adhesive agent, a polyurethane adhesive agent, an acrylic adhesive agent etc. can be used, for example.

2.抗靜電層 本發明中之抗靜電層係配置於基材層之與熱密封層側之面相反之面側,包含導電性高分子,用以防止覆蓋帶帶電之層。藉由具有抗靜電層,可防止帶有靜電而污物或灰塵等向覆蓋帶之表面附著,或防止因與其他面接觸而產生靜電。2. Antistatic layer The antistatic layer in the present invention is disposed on the side of the substrate layer opposite to the side of the heat-sealing layer, and contains conductive polymers to prevent the charged layer from being covered. By having an antistatic layer, it is possible to prevent dirt or dust from adhering to the surface of the cover tape due to static electricity, or to prevent static electricity from being in contact with other surfaces.

作為導電性高分子,例如可列舉:聚噻吩、聚苯胺、聚吡咯、聚乙炔、聚(對伸苯)、聚苯乙炔、聚乙烯咔唑等。其中,導電性高分子較佳為選自由聚噻吩、聚苯胺及聚吡咯所組成之群中之1種以上。其原因在於,可獲得不依存於濕度之充分之抗靜電性及透明性。作為聚噻吩,例如較佳地使用PEDOT/PSS(聚(3,4-乙二氧基噻吩/聚苯乙烯磺酸)。作為聚苯胺,例如較佳地使用磺化聚苯胺。Examples of conductive polymers include polythiophene, polyaniline, polypyrrole, polyacetylene, poly(paraphenylene), polyphenylene vinylene, polyvinylcarbazole, and the like. Among them, the conductive polymer is preferably one or more selected from the group consisting of polythiophene, polyaniline, and polypyrrole. This is because sufficient antistatic properties and transparency independent of humidity can be obtained. As polythiophene, for example, PEDOT/PSS (poly(3,4-ethylenedioxythiophene/polystyrenesulfonic acid) is preferably used. As polyaniline, for example, sulfonated polyaniline is preferably used.

抗靜電層中之導電性高分子之含量可設為使本發明之覆蓋帶之表面電阻處於後述之數值範圍內所需之值。The content of the conductive polymer in the antistatic layer can be set to a value required to make the surface resistance of the cover tape of the present invention fall within the numerical range described later.

抗靜電層包含導電性高分子作為必需成分,但亦可包含導電性高分子以外之抗靜電劑。The antistatic layer contains a conductive polymer as an essential component, but may contain an antistatic agent other than the conductive polymer.

又,抗靜電層亦可包含樹脂。In addition, the antistatic layer may contain resin.

抗靜電層之厚度可設為使本發明之覆蓋帶之表面電阻處於後述之數值範圍內所需之值。The thickness of the antistatic layer can be set to a value required to make the surface resistance of the cover tape of the present invention fall within the numerical range described later.

作為抗靜電層之形成方法,例如可列舉如下方法:使用將導電性高分子等分散或溶解於溶劑而成之抗靜電層用組合物,於基材層之另一面側塗佈上述抗靜電層用組合物並使其乾燥。作為上述抗靜電層用組合物之塗佈方法,例如可列舉:氣刀塗佈法、刮刀塗佈法(blade coating)、刀式塗佈法(knife coating)、桿式塗佈法、棒式塗佈法、直接輥式塗佈法、逆輥塗佈法、凹版塗佈法、斜板式塗佈法等公知之塗佈法。As a method for forming the antistatic layer, for example, the method of coating the antistatic layer on the other side of the substrate layer using a composition for an antistatic layer obtained by dispersing or dissolving a conductive polymer etc. in a solvent Apply composition and allow to dry. Examples of coating methods for the antistatic layer composition include air knife coating, blade coating, knife coating, rod coating, and rod coating. Known coating methods such as coating method, direct roll coating method, reverse roll coating method, gravure coating method, inclined plate coating method, etc.

抗靜電層之厚度例如可設為0.03 μm以上5 μm以下。The thickness of the antistatic layer can be set to, for example, not less than 0.03 μm and not more than 5 μm.

3.基材層 本發明中之基材層係支持上述熱密封層或抗靜電層之層。3. Substrate layer The substrate layer in the present invention is a layer supporting the above-mentioned heat-sealing layer or antistatic layer.

作為基材層,只要具有可承受保存及搬送時之外力之機械強度、或可承受製造及編帶包裝之耐熱性等,便可應用各種材料。例如可列舉:聚對苯二甲酸乙二酯、聚對苯二甲酸丁二酯、聚萘二甲酸乙二酯、對苯二甲酸乙二酯-間苯二甲酸乙二酯共聚物、對苯二甲酸-環己烷二甲醇-乙二醇共聚物等聚酯;尼龍6、尼龍66、尼龍610等聚醯胺;聚乙烯、聚丙烯、聚甲基戊烯等聚烯烴等。其中,聚對苯二甲酸乙二酯、聚萘二甲酸乙二酯等聚酯之成本方面及機械強度較佳,因此較佳地使用。As the base layer, various materials can be used as long as they have mechanical strength to withstand external forces during storage and transportation, or heat resistance to withstand manufacturing and tape packaging. For example, polyethylene terephthalate, polybutylene terephthalate, polyethylene naphthalate, polyethylene terephthalate-isophthalate copolymer, terephthalate Diformic acid-cyclohexanedimethanol-ethylene glycol copolymer and other polyesters; nylon 6, nylon 66, nylon 610 and other polyamides; polyethylene, polypropylene, polymethylpentene and other polyolefins, etc. Among them, polyesters such as polyethylene terephthalate and polyethylene naphthalate are better in terms of cost and mechanical strength, and therefore are preferably used.

又,基材層中,視需要亦可包含例如填充劑、塑化劑、著色劑、抗靜電劑等添加劑。Moreover, additives, such as a filler, a plasticizer, a coloring agent, and an antistatic agent, can also be contained in a base material layer as needed.

基材層可為單層,亦可為同種或不同種之複數層之積層體。又,基材層可為延伸膜,亦可為未延伸膜。其中,出於使強度提高之目的,基材層亦可為於單軸方向或雙軸方向延伸之膜。The substrate layer may be a single layer or a laminate of multiple layers of the same type or different types. In addition, the base material layer may be a stretched film or an unstretched film. Here, for the purpose of improving the strength, the base material layer may be a film stretched in a uniaxial direction or a biaxial direction.

基材層之厚度例如可設為2.5 μm以上300 μm以下,亦可為6 μm以上100 μm以下,亦可為12 μm以上50 μm以下。若基材層之厚度過厚,則有編帶包裝時之熱密封溫度變高之情形,於成本方面亦不利。又,若基材層之厚度過薄,則有機械強度不足之情形。The thickness of the substrate layer may be, for example, from 2.5 μm to 300 μm, from 6 μm to 100 μm, or from 12 μm to 50 μm. If the thickness of the base layer is too thick, the heat-sealing temperature at the time of tape packaging may become high, which is also disadvantageous in terms of cost. Moreover, when the thickness of a base material layer is too thin, mechanical strength may become insufficient.

基材層亦可實施例如電暈放電處理、電漿處理、臭氧處理、火焰處理、底塗劑(亦稱為增黏塗佈劑、接著促進劑、易接著劑)塗佈處理、預熱處理、除塵處理、蒸鍍處理、鹼處理、噴砂處理等易接著處理。The substrate layer can also be implemented such as corona discharge treatment, plasma treatment, ozone treatment, flame treatment, primer (also known as adhesion-promoting coating agent, adhesion promoter, easy-adhesive agent) coating treatment, preheating treatment , Dust removal treatment, evaporation treatment, alkali treatment, sand blasting treatment, etc. are easy to follow.

4.底塗層 本發明中,亦可例如圖3所示,視需要於基材層2及熱密封層3之間配置有底塗層5。藉由底塗層,可使基材層及熱密封層之密接性提高。又,藉由底塗層,於將本發明之覆蓋帶熱密封於載帶時,可使緩衝性提高。4. Base coat In the present invention, for example, as shown in FIG. 3 , an undercoat layer 5 may be arranged between the base material layer 2 and the heat-sealing layer 3 as needed. The adhesion between the base material layer and the heat-sealing layer can be improved by the undercoat layer. In addition, when the cover tape of the present invention is heat-sealed to the carrier tape by the undercoat layer, cushioning properties can be improved.

作為底塗層之材料係根據基材層及熱密封層之材料等而適當選擇者,例如可列舉:聚乙烯或聚丙烯等聚烯烴、聚胺基甲酸酯、聚酯等。The material of the undercoat layer is appropriately selected according to the materials of the base material layer and the heat-sealing layer, and examples thereof include polyolefins such as polyethylene and polypropylene, polyurethane, and polyester.

底塗層之厚度例如可設為5 μm以上25 μm以下。The thickness of the undercoat layer can be set to, for example, not less than 5 μm and not more than 25 μm.

作為底塗層,可使用膜。於此情形時,作為基材層及底塗層之積層方法,並無特別限定,可使用公知之方法。例如可列舉:將預先製造之膜利用接著劑貼合於基材層之方法、或將熱熔融之膜之原材料利用T型模頭等擠出於基材層而獲得積層體之方法等。再者,關於接著劑,與上述熱密封層之項中記載者相同。As an undercoat, films can be used. In this case, the lamination method of the base layer and the primer layer is not particularly limited, and a known method can be used. For example, a method of laminating a pre-manufactured film to a base layer with an adhesive, or a method of extruding a thermally fused film raw material onto a base layer using a T-die or the like to obtain a laminate. In addition, about an adhesive agent, it is the same as what was described in the said heat-sealing layer.

5.覆蓋帶 作為本發明之覆蓋帶之表面電阻,本發明之覆蓋帶之配置有抗靜電層之側的面之表面電阻例如可設為1×107 Ω/□以上1×1013 Ω/□以下。又,本發明之覆蓋帶之配置有熱密封層之側的面之表面電阻例如可設為1×107 Ω/□以上1×1013 Ω/□以下。又,本發明之覆蓋帶之配置有抗靜電層之側的面之表面電阻及本發明之覆蓋帶之配置有熱密封層之側的面之表面電阻例如可設為1×107 Ω/□以上1×1013 Ω/□以下。若表面電阻過高,則有靜電之擴散效果極端下降,難以保護電子零件免受靜電破壞之情形。又,若表面電阻過低,則有會自外部經由電子零件包裝用覆蓋帶對電子零件通電,而受到電性破壞之虞。5. Cover tape As the surface resistance of the cover tape of the present invention, the surface resistance of the surface of the cover tape of the present invention on the side where the antistatic layer is disposed can be, for example, 1×10 7 Ω/□ or more than 1×10 13 Ω/□ □ Below. In addition, the surface resistance of the surface of the cover tape of the present invention on which the heat-sealing layer is arranged can be, for example, not less than 1×10 7 Ω/□ and not more than 1×10 13 Ω/□. In addition, the surface resistance of the surface of the cover tape of the present invention on which the antistatic layer is disposed and the surface resistance of the surface of the cover tape of the present invention on which the heat-sealing layer is disposed can be, for example, 1×10 7 Ω/□ More than 1×10 13 Ω/□ and less. If the surface resistance is too high, the diffusion effect of static electricity will be extremely reduced, and it will be difficult to protect electronic components from static electricity damage. Moreover, if the surface resistance is too low, the electronic component may be electrically broken by being energized from the outside through the cover tape for electronic component packaging.

表面電阻係依據IEC(International Electro technical Commission,國際電工委員會)61340進行測定。具體而言,於約23℃且約40%RH之環境下進行測定。測定器例如可使用數位超高阻/微電流儀5450(ADC公司製造)。The surface resistance was measured in accordance with IEC (International Electrotechnical Commission, International Electrotechnical Commission) 61340. Specifically, the measurement is performed in an environment of about 23° C. and about 40% RH. As a measuring device, for example, a digital ultra-high resistance/microcurrent meter 5450 (manufactured by ADC Corporation) can be used.

B.包裝體 本發明之包裝體具備:載帶,其具有收納電子零件之複數個收納部;電子零件,其收納於上述收納部;及上述覆蓋帶,其以覆蓋上述收納部之方式配置。B. Package body The package of the present invention includes: a carrier tape having a plurality of storage sections for storing electronic components; an electronic component stored in the storage sections; and the cover tape arranged to cover the storage sections.

本發明中,藉由具備上述覆蓋帶,於將覆蓋帶自載帶剝離時,可抑制電子零件向覆蓋帶之貼附。因此,可抑制因電子零件向覆蓋帶之貼附所引起之電子零件自載帶之收納部之跳出、浮升、立起等,而可正常取出電子零件。因此,可使安裝效率提高。In this invention, by providing the said cover tape, when peeling a cover tape from a carrier tape, sticking of an electronic component to a cover tape can be suppressed. Therefore, it is possible to suppress jumping, lifting, and standing up of the electronic parts from the storage portion of the carrier tape due to the attachment of the electronic parts to the cover tape, and it is possible to take out the electronic parts normally. Therefore, mounting efficiency can be improved.

圖2(a)、(b)係表示本發明之包裝體之一例之概略俯視圖及剖視圖。再者,關於圖2(a)、(b),因已記載於上述「A.電子零件包裝用覆蓋帶」之項中,故省略此處之說明。Fig. 2(a), (b) is a schematic plan view and cross-sectional view showing an example of the package of the present invention. 2(a) and (b) have already been described in the item "A. Electronic component packaging cover tape" above, so the description here is omitted.

以下,對本發明之包裝體之各構成進行說明。Hereinafter, each structure of the package body of this invention is demonstrated.

1.覆蓋帶 關於本發明中之覆蓋帶,因已記載於上述「A.電子零件包裝用覆蓋帶」之項中,故省略此處之說明。1. Covering tape The cover tape in the present invention has already been described in the item "A. Cover tape for packaging electronic components" above, so the description here is omitted.

本發明之包裝體中,覆蓋帶之熱密封層與載帶於熱密封部接著。熱密封部例如可配置於覆蓋帶之熱密封層與載帶相接之部分之一部分。即,熱密封層亦可具有熱密封部與非熱密封部。藉此,可使覆蓋帶對於載帶之剝離性良好。In the package of the present invention, the heat-seal layer of the cover tape and the carrier tape are bonded at the heat-sealed portion. The heat-sealed portion can be arranged, for example, at a part of the portion where the heat-sealed layer of the cover tape is in contact with the carrier tape. That is, the heat-sealing layer may have a heat-sealing portion and a non-heat-sealing portion. Thereby, the releasability of a cover tape with respect to a carrier tape can be made favorable.

2.載帶 本發明中之載帶係具有收納電子零件之複數個收納部之構件。2. Carrier tape The carrier tape in the present invention is a member having a plurality of storage portions for storing electronic components.

作為載帶,只要為具有複數個收納部者即可,例如可使用壓紋載帶(亦稱為壓紋帶)、打孔載帶(亦稱為打孔帶)、壓製載帶(亦稱為壓製帶)之任一者。其中,就成本、成形性、尺寸精度等觀點而言,較佳地使用壓紋載帶。As the carrier tape, as long as it has a plurality of storage parts, for example, embossed carrier tape (also called embossed tape), perforated carrier tape (also called perforated tape), pressed carrier tape (also called is any one of the pressed belt). Among them, an embossed carrier tape is preferably used from the standpoint of cost, formability, dimensional accuracy, and the like.

作為載帶之材質,例如可列舉:聚氯乙烯、聚苯乙烯、聚酯、聚丙烯、聚碳酸酯、聚丙烯腈、ABS(acrylonitrile-butadiene-styrene,丙烯腈-丁二烯-苯乙烯)樹脂等塑膠或紙等。其中,載帶之材質較佳為紙。即,較佳為紙製之紙載帶。其原因在於,紙載帶於成本、環境負荷等方面優異。As the material of the carrier tape, for example, polyvinyl chloride, polystyrene, polyester, polypropylene, polycarbonate, polyacrylonitrile, ABS (acrylonitrile-butadiene-styrene, acrylonitrile-butadiene-styrene) Plastic such as resin or paper, etc. Among them, the material of the carrier tape is preferably paper. That is, it is preferably a paper carrier tape made of paper. This is because paper carrier tapes are excellent in terms of cost, environmental load, and the like.

載帶之厚度係根據載帶之材質或電子零件之厚度等而適當選擇。例如,載帶之厚度可設為30 μm以上1000 μm以下。若載帶之厚度過厚,則成形性變差,若載帶之厚度過薄,則有強度不足之情形。The thickness of the carrier tape is appropriately selected according to the material of the carrier tape or the thickness of the electronic parts. For example, the thickness of the carrier tape can be set to not less than 30 μm and not more than 1000 μm. If the thickness of the carrier tape is too thick, the formability will be deteriorated, and if the thickness of the carrier tape is too thin, the strength may be insufficient.

載帶具有複數個收納部。收納部通常於載帶之長邊方向隔開特定間隔而配置。作為收納部之大小、深度、間距等,根據電子零件之大小、厚度等而適當調整。The carrier tape has a plurality of storage parts. The accommodating parts are usually arranged at predetermined intervals in the longitudinal direction of the carrier tape. The size, depth, pitch, and the like of the housing portion are appropriately adjusted according to the size, thickness, and the like of electronic components.

作為具有收納部之載帶之形成方法,可應用通常之載帶之成形方法,根據載帶之種類或材質等而適當選擇。例如可列舉:加壓成形、真空成形、壓空成形、衝壓加工、壓縮加工等。As a method of forming the carrier tape having the storage portion, a general carrier tape forming method can be applied, and it can be appropriately selected according to the type and material of the carrier tape. For example, press forming, vacuum forming, pressure forming, press processing, compression processing, etc. are mentioned.

3.電子零件 作為本發明之包裝體中所用之電子零件,並無特別限定,例如可列舉:IC、電阻、電容器、電感器、電晶體、二極體、LED(發光二極體)、液晶、壓電元件暫存器、濾波器、晶體振盪子、晶體振子、連接器、開關、電容(volume)、繼電器等。關於IC之形式,亦並無特別限定。3. Electronic parts The electronic components used in the package of the present invention are not particularly limited, and examples thereof include ICs, resistors, capacitors, inductors, transistors, diodes, LEDs (light-emitting diodes), liquid crystals, and piezoelectric elements. Registers, filters, crystal oscillators, crystal oscillators, connectors, switches, capacitors (volume), relays, etc. The form of IC is also not particularly limited.

4.包裝體 本發明之包裝體係用於電子零件之保管及搬送。電子零件以包裝體之狀態被保管及搬送,並供於安裝。於安裝時,將覆蓋帶剝離,取出收納於載帶之收納部之電子零件,並向基板等安裝。4. Package body The packaging system of the present invention is used for storage and transportation of electronic parts. Electronic parts are stored and transported in a packaged state, and are provided for installation. When mounting, the cover tape is peeled off, and the electronic components stored in the storage portion of the carrier tape are taken out, and mounted on a substrate or the like.

再者,本發明並不限定於上述實施形態。上述實施形態為例示,具有與本發明之申請專利範圍中記載之技術思想實質上相同之構成且發揮同樣之作用效果者不論為何種者,均包含於本發明之技術範圍內。 [實施例]In addition, this invention is not limited to the said embodiment. The above-mentioned embodiments are examples, and those having substantially the same configuration as the technical idea described in the claims of the present invention and exerting the same effects are included in the technical scope of the present invention. [Example]

以下示出實施例及比較例,對本發明進行更詳細地說明。Examples and comparative examples are shown below to describe the present invention in more detail.

[實施例1] 作為基材層,準備兩面經實施電暈處理之厚度25 μm之雙軸延伸聚對苯二甲酸乙二酯膜(Futamura Chemical公司製造,FE2002,以下稱為「PET膜」)。藉由在PET膜之一面側塗佈下述之包含導電性高分子之抗靜電層用組合物A,而形成厚度0.05 μm之抗靜電層。藉由在PET膜之與形成有抗靜電層之面相反之面側塗佈下述之底塗層用組合物A,而形成厚度1 μm之底塗層。藉由在底塗層之與PET膜相反之面側熔融擠出下述之包含乙烯-乙酸乙烯酯共聚物之熱密封層用組合物A,而形成厚度25 μm之熱密封層。藉此,獲得實施例1之覆蓋帶。所得之覆蓋帶具有包含導電性高分子之抗靜電層、PET膜之基材層、底塗層、包含乙烯-乙酸乙烯酯共聚物之熱密封層按此順序積層而成之構造。[Example 1] As the substrate layer, a biaxially stretched polyethylene terephthalate film (manufactured by Futamura Chemical Co., FE2002, hereinafter referred to as "PET film") having a thickness of 25 μm subjected to corona treatment on both sides was prepared. An antistatic layer having a thickness of 0.05 μm was formed by coating the following composition A for an antistatic layer containing a conductive polymer on one side of the PET film. An undercoat layer having a thickness of 1 μm was formed by applying the following undercoat composition A on the side of the PET film opposite to the surface on which the antistatic layer was formed. A heat-sealing layer having a thickness of 25 μm was formed by melt-extruding the following composition A for a heat-sealing layer containing an ethylene-vinyl acetate copolymer on the side of the primer layer opposite to the PET film. Thereby, the cover tape of Example 1 was obtained. The obtained cover tape has a structure in which an antistatic layer including a conductive polymer, a substrate layer of a PET film, a primer layer, and a heat-sealing layer including an ethylene-vinyl acetate copolymer are laminated in this order.

(抗靜電層用組合物A) 具有PEDOT/PSS作為導電性高分子、丙烯酸系單體作為硬化成分、氮丙啶化合物作為硬化劑之二液硬化型之抗靜電塗佈劑(Aracoat AS601D(荒川化學工業公司製造)100質量份與Aracoat CL910(荒川化學工業公司製造)10質量份之混合物)。(Composition A for antistatic layer) 100 parts by mass of a two-component curable antistatic coating agent (Aracoat AS601D (manufactured by Arakawa Chemical Industry Co., Ltd.)) having PEDOT/PSS as a conductive polymer, an acrylic monomer as a curing component, and an aziridine compound as a curing agent. 10 parts by mass of Aracoat CL910 (manufactured by Arakawa Chemical Industry Co., Ltd.).

(底塗層用組合物A) 胺基甲酸酯系增黏塗佈劑(Takenate A-3075(三井化學公司製造)30質量份與Takelac A-3210(三井化學公司製造)100質量份之混合物)。(Composition A for Undercoating) Urethane-based thickening coating agent (a mixture of 30 parts by mass of Takenate A-3075 (manufactured by Mitsui Chemicals) and 100 parts by mass of Takelac A-3210 (manufactured by Mitsui Chemicals)).

(熱密封層用組合物A) 包含乙烯-乙酸乙烯酯共聚物之聚烯烴系接著性樹脂(Melthene M MX53C(Tosoh公司製造)90質量份與抗黏連劑BL15MB(Tosoh公司製造)10質量份之混合物)。(Composition A for heat seal layer) Polyolefin-based adhesive resin containing an ethylene-vinyl acetate copolymer (mixture of 90 parts by mass of Melthene M MX53C (manufactured by Tosoh) and 10 parts by mass of antiblocking agent BL15MB (manufactured by Tosoh)).

[實施例2] 除使用下述之熱密封層用組合物B以外,以與實施例1同樣之方式製作覆蓋帶。[Example 2] Except having used the following composition B for heat seal layers, it carried out similarly to Example 1, and produced the cover tape.

(熱密封層用組合物B) 包含乙烯-乙酸乙烯酯共聚物之聚烯烴系接著性樹脂(Melthene M MX53C(Tosoh公司製造)97質量份與抗黏連劑BL15MB(Tosoh公司製造)3質量份之混合物)。(Composition B for heat seal layer) Polyolefin-based adhesive resin containing an ethylene-vinyl acetate copolymer (mixture of 97 parts by mass of Melthene M MX53C (manufactured by Tosoh) and 3 parts by mass of antiblocking agent BL15MB (manufactured by Tosoh)).

[比較例1] 除使用下述之熱密封層用組合物C以外,以與實施例1同樣之方式製作覆蓋帶。[Comparative example 1] Except having used the following composition C for heat seal layers, it carried out similarly to Example 1, and produced the cover tape.

(熱密封層用組合物C) 包含乙烯-乙酸乙烯酯共聚物之聚烯烴系接著性樹脂(Melthene M MX53C,Tosoh公司製造)。(Composition C for heat seal layer) Polyolefin-based adhesive resin containing ethylene-vinyl acetate copolymer (Melthene M MX53C, manufactured by Tosoh Corporation).

[評價] (維氏硬度) 利用上述「A.電子零件包裝用覆蓋帶  1.熱密封層」之項中記載之方法,對覆蓋帶之熱密封層之與基材層為相反側之面的維氏硬度進行測定。[evaluate] (Vickers hardness) Using the method described in the item "A. Cover tape for electronic component packaging 1. Heat seal layer", measure the Vickers hardness of the surface of the heat seal layer of the cover tape opposite to the base layer.

(表面電阻) 利用上述「A.電子零件包裝用覆蓋帶  5.覆蓋帶」之項中記載之方法,對覆蓋帶之表面電阻進行測定。(surface resistance) The surface resistance of the cover tape was measured using the method described in the above item "A. Cover tape for electronic component packaging 5. Cover tape".

(行為異常數) 測定將覆蓋帶自包裝體剝離時電子零件跳出之數作為行為異常數。一面將電容器(GRM0222C1H220JA02,0.22 pF,尺寸為0402,村田製作所公司製造)500個作為電子零件連續地配置於寬度8 mm之紙載帶(HP33M,北越紀州製紙公司製造)之空腔,一面將紙載帶與寬度5 mm之覆蓋帶熱密封,藉此獲得卷狀之包裝體。將包裝體之卷於60℃95%RH之恆溫恆濕試驗室保管24小時。使用覆蓋帶剝離裝置(附有7英吋卷盤保持器之智慧型進料機,FUJI公司製造),以0.1 m/秒之速度將覆蓋帶自保管後之卷狀之包裝體剝離。剝離於25℃30%RH之環境下進行,於10秒結束。利用高速相機(1000圖框/秒,解析度為512×512,FASTCAM MC2.1,Photron公司製造)觀察剝離時之電子零件之行為。將剝離時電子零件自紙載帶之空腔較紙載帶之上表面浮起之情形、電子零件旋轉90度而立起之情形、電子零件自紙載帶之空腔跳出之情形設為異常行為,一面將利用高速相機拍攝之影像以慢動作播放,一面以目視觀察發生異常行為之數並予以合計。(number of abnormal behaviors) The number of electronic parts jumping out when the cover tape was peeled off from the package was measured as the number of behavioral abnormalities. On the one hand, 500 capacitors (GRM0222C1H220JA02, 0.22 pF, size 0402, manufactured by Murata Manufacturing Co., Ltd.) were continuously arranged as electronic parts in the cavity of a paper carrier tape (HP33M, manufactured by Hokuetsu Kishu Paper Co., Ltd.) with a width of 8 mm. The carrier tape was heat-sealed with a cover tape having a width of 5 mm, whereby a roll-shaped package was obtained. Store the package roll in a constant temperature and humidity laboratory at 60°C and 95%RH for 24 hours. Using a cover tape peeling device (intelligent feeder with a 7-inch reel holder, manufactured by FUJI Corporation), the cover tape was peeled off from the roll-shaped package after storage at a speed of 0.1 m/sec. The peeling is carried out in an environment of 25°C and 30%RH, and ends in 10 seconds. A high-speed camera (1000 frames/second, resolution 512×512, FASTCAM MC2.1, manufactured by Photron Corporation) was used to observe the behavior of the electronic parts during peeling. When peeling off, the situation where the electronic parts float from the cavity of the paper carrier tape, the situation where the electronic parts are rotated 90 degrees to stand up, and the situation where the electronic parts jump out of the cavity of the paper carrier tape are abnormal behaviors. , while playing the images captured by the high-speed camera in slow motion, while visually observing and counting the number of abnormal behaviors.

將實施例1~3及比較例1之覆蓋帶之評價結果示於表1。Table 1 shows the evaluation results of the cover tapes of Examples 1-3 and Comparative Example 1.

[表1]

Figure AA1
Figure AA1-1
[Table 1]
Figure AA1
Figure AA1-1

根據表1可知,熱密封層之維氏硬度為2.0以上之實施例1、2之覆蓋帶的將覆蓋帶自包裝體剝離時之異常行為數較熱密封層之維氏硬度未達2.0之比較例1之覆蓋帶減少。再者,實施例1、2及比較例1之覆蓋帶之熱密封層側之表面電阻及抗靜電層側之表面電阻均為同樣之值,可以說為良好。As can be seen from Table 1, the number of abnormal behaviors of the cover tapes of Examples 1 and 2 in which the Vickers hardness of the heat-sealing layer is 2.0 or more when the cover tape is peeled from the package is compared with the Vickers hardness of the heat-sealing layer which is less than 2.0. The cover band of Example 1 is reduced. Furthermore, the surface resistance of the heat seal layer side and the surface resistance of the antistatic layer side of the cover tapes of Examples 1 and 2 and Comparative Example 1 were all the same value, which can be said to be good.

1:覆蓋帶 2:基材層 3:熱密封層 3h:熱密封部 4:抗靜電層 5:底塗層 10:包裝體 11:載帶 12:收納部 13:電子零件 14:輸送孔1: cover tape 2: Substrate layer 3: heat sealing layer 3h: heat sealing part 4: Antistatic layer 5: Base coat 10: Package body 11: Carrier tape 12: storage department 13:Electronic parts 14: Delivery hole

圖1係例示本發明之電子零件包裝用覆蓋帶之概略剖視圖。 圖2(a)、(b)係例示本發明之包裝體之概略俯視圖及剖視圖。 圖3係例示本發明之電子零件包裝用覆蓋帶之概略剖視圖。Fig. 1 is a schematic sectional view illustrating an example of a cover tape for packaging electronic components of the present invention. Fig. 2 (a), (b) is a schematic plan view and a cross-sectional view illustrating the packaging body of the present invention. Fig. 3 is a schematic sectional view illustrating an example of the cover tape for packaging electronic components of the present invention.

1:覆蓋帶 1: cover tape

2:基材層 2: Substrate layer

3:熱密封層 3: heat sealing layer

4:抗靜電層 4: Antistatic layer

Claims (6)

一種電子零件包裝用覆蓋帶,其具有: 基材層; 熱密封層,其配置於上述基材層之一面側,包含乙烯-乙酸乙烯酯共聚物;及 抗靜電層,其配置於上述基材層之與上述熱密封層側之面相反之面側,包含導電性高分子;且 上述熱密封層之維氏硬度為2.0以上。A cover tape for packaging electronic parts, which has: substrate layer; A heat-sealing layer, which is disposed on one side of the above-mentioned substrate layer, comprises ethylene-vinyl acetate copolymer; and An antistatic layer, which is disposed on the side of the substrate layer opposite to the side of the heat-sealing layer, and includes a conductive polymer; and The Vickers hardness of the heat-sealing layer is 2.0 or more. 如請求項1之電子零件包裝用覆蓋帶,其中上述熱密封層包含經改性之乙烯-乙酸乙烯酯共聚物或經交聯之乙烯-乙酸乙烯酯共聚物。The cover tape for electronic component packaging according to claim 1, wherein the heat-sealing layer comprises a modified ethylene-vinyl acetate copolymer or a cross-linked ethylene-vinyl acetate copolymer. 如請求項1或2之電子零件包裝用覆蓋帶,其中上述熱密封層包含耐熱性較上述乙烯-乙酸乙烯酯共聚物高之樹脂、儲存彈性模數較上述乙烯-乙酸乙烯酯共聚物高之樹脂、密度較上述乙烯-乙酸乙烯酯共聚物高之樹脂、或經交聯之樹脂。The cover tape for packaging electronic parts as claimed in claim 1 or 2, wherein the heat-sealing layer contains a resin with higher heat resistance than the above-mentioned ethylene-vinyl acetate copolymer, and a resin with a higher storage elastic modulus than the above-mentioned ethylene-vinyl acetate copolymer. Resin, a resin having a density higher than the above-mentioned ethylene-vinyl acetate copolymer, or a cross-linked resin. 如請求項1或2之電子零件包裝用覆蓋帶,其中上述熱密封層包含粒子狀之有機物或無機物。The cover tape for packaging electronic components according to claim 1 or 2, wherein the heat-sealing layer contains particulate organic or inorganic substances. 一種包裝體,其具備: 載帶,其具有收納電子零件之複數個收納部; 電子零件,其收納於上述收納部;及 如請求項1或2之電子零件包裝用覆蓋帶,其以覆蓋上述收納部之方式配置。A kind of packaging body, it has: Carrier tape, which has a plurality of storage parts for storing electronic parts; Electronic parts, which are housed in the above-mentioned storage section; and The cover tape for packaging electronic components according to Claim 1 or 2, which is disposed so as to cover the above-mentioned accommodating portion. 如請求項5之包裝體,其中上述載帶為紙製之紙載帶。The package according to claim 5, wherein the above-mentioned carrier tape is a paper carrier tape.
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