TWI790346B - Textile thread, its manufacturing method, and fabric containing same - Google Patents

Textile thread, its manufacturing method, and fabric containing same Download PDF

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TWI790346B
TWI790346B TW108103266A TW108103266A TWI790346B TW I790346 B TWI790346 B TW I790346B TW 108103266 A TW108103266 A TW 108103266A TW 108103266 A TW108103266 A TW 108103266A TW I790346 B TWI790346 B TW I790346B
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mass
polypropylene
fiber
yarn
fibers
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TW108103266A
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Chinese (zh)
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TW201934825A (en
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西山豊一
山內洋
水橋秀章
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日商大和紡績股份有限公司
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    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/41Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads with specific twist
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/26Yarns or threads characterised by constructional features, e.g. blending, filament/fibre with characteristics dependent on the amount or direction of twist
    • D02G3/28Doubled, plied, or cabled threads
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/36Cored or coated yarns or threads
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/208Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based
    • D03D15/217Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based natural from plants, e.g. cotton
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/283Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/14Other fabrics or articles characterised primarily by the use of particular thread materials
    • D04B1/16Other fabrics or articles characterised primarily by the use of particular thread materials synthetic threads
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53Polyethers

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Botany (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Woven Fabrics (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Knitting Of Fabric (AREA)

Abstract

本發明係關於一種紡織線,其係包含大於50質量%之水分率未達0.15質量%之聚丙烯系纖維者,該紡織線中之長度3mm以上之細毛數為40根/10m以下,氣孔率為40~65%,撚係數為2.4~6.0,或者該紡織線中之長度3mm以上之細毛數為40根/10m以下,撚角為23°以上。又,本發明係關於一種紡織線,其係包含5質量%以上之依據JIS L 1015(2010)測定之水分率為0.15質量%以上之聚丙烯系纖維者,該紡織線中之長度3mm以上之細毛數為40根/10m以下,氣孔率為40~65%,撚係數為2.4~6.0,或者該紡織線中之長度3mm以上之細毛數為40根/10m以下,撚角為23°以上。 The present invention relates to a textile thread comprising polypropylene-based fibers with a moisture content of more than 50% by mass and less than 0.15% by mass, the number of fine hairs with a length of 3mm or more in the textile thread is 40 or less per 10m, and the porosity 40~65%, the twist coefficient is 2.4~6.0, or the number of fine hairs with a length of 3mm or more in the textile thread is 40 or less per 10m, and the twist angle is 23° or more. Also, the present invention relates to a textile thread containing 5% by mass or more of polypropylene-based fibers with a moisture content of 0.15% by mass or more as measured in accordance with JIS L 1015 (2010), and the length of the textile thread is 3 mm or more. The number of fine hairs is less than 40/10m, the porosity is 40~65%, the twist coefficient is 2.4~6.0, or the number of fine hairs with a length of 3mm or more in the textile thread is less than 40/10m, and the twist angle is more than 23°.

Description

紡織線與其製造方法及包含其之布帛Textile thread, its manufacturing method, and fabric containing same

本發明係關於一種包含聚丙烯系纖維之紡織線與其製造方法及包含其之布帛。The present invention relates to a textile thread containing polypropylene fiber, a manufacturing method thereof and a fabric containing the same.

聚丙烯系纖維為輕量且具有保溫性之纖維,廣泛用於衣料或工業材料等。例如專利文獻1及2記載有於組合有撥水性纖維與親水性纖維之衣料用紡織線中,可使用聚丙烯纖維作為撥水性纖維。專利文獻3記載有於用於傢俱等之工業材料之由異素材粗紗構成之賽絡紡(sirospun)紡織線中,可使用聚丙烯纖維作為合成纖維。Polypropylene-based fibers are lightweight and heat-retaining fibers, and are widely used in clothing and industrial materials. For example, Patent Documents 1 and 2 describe that polypropylene fibers can be used as water-repellent fibers in textile yarns for clothing in which water-repellent fibers and hydrophilic fibers are combined. Patent Document 3 discloses that polypropylene fibers can be used as synthetic fibers in sirospun yarns made of heterogeneous rovings used for industrial materials such as furniture.

另一方面,合成纖維之纖維強度高於天然纖維,使用包含合成纖維之紡織線之布料存在容易起毛球之問題,從而對提高合成纖維之抗起毛球性展開研究。例如,專利文獻4~6提出有於包含聚酯短纖維之紡織線中,藉由減少細毛數而提高使用該紡織線之布料之抗起毛球性。 先前技術文獻 專利文獻On the other hand, the fiber strength of synthetic fibers is higher than that of natural fibers, and fabrics using textile threads containing synthetic fibers are prone to pilling, so research has been conducted on improving the pilling resistance of synthetic fibers. For example, Patent Documents 4 to 6 propose that in textile threads containing polyester staple fibers, the pilling resistance of fabrics using the textile threads is improved by reducing the number of fine hairs. prior art literature patent documents

專利文獻1:日本特開平04-091240號公報 專利文獻2:日本特開平05-033234號公報 專利文獻3:日本特開平10-088440號公報 專利文獻4:日本特開2008-133584號公報 專利文獻5:日本特開2004-197243號公報 專利文獻6:日本特開2004-218092號公報Patent Document 1: Japanese Patent Application Laid-Open No. 04-091240 Patent Document 2: Japanese Patent Application Laid-Open No. 05-033234 Patent Document 3: Japanese Patent Application Laid-Open No. 10-088440 Patent Document 4: Japanese Patent Laid-Open No. 2008-133584 Patent Document 5: Japanese Unexamined Patent Publication No. 2004-197243 Patent Document 6: Japanese Patent Laid-Open No. 2004-218092

發明所欲解決之課題The problem to be solved by the invention

然而,專利文獻1~6中對於提高使用包含聚丙烯系纖維之紡織線之情形時之布帛之抗起毛球性並無研究。However, in Patent Documents 1 to 6, there is no study on improving the pilling resistance of the fabric in the case of using a spun yarn made of polypropylene-based fibers.

本發明為了解決上述先前問題,提供一種能夠提高布帛之抗起毛球性之包含聚丙烯系纖維之紡織線與其製造方法及包含其之布帛。 解決課題之技術手段In order to solve the above-mentioned problems, the present invention provides a spun yarn comprising polypropylene fibers capable of improving the pilling resistance of fabrics, a method for producing the same, and fabrics comprising the same. Technical means to solve problems

本發明係關於一種紡織線,其係包含大於50質量%之依據JIS L 1015(2010)測定之水分率未達0.15質量%之聚丙烯系纖維者,其特徵在於:依據JIS L 1095(2010)9.22.2 B法測定之上述紡織線每10 m中存在之長度3 mm以上之細毛數為40根/10 m以下,上述紡織線之氣孔率為40~65%,撚係數為2.4~6.0。The present invention relates to a textile thread comprising more than 50% by mass of polypropylene-based fibers with a moisture content of less than 0.15% by mass measured according to JIS L 1015 (2010), characterized in that: according to JIS L 1095 (2010) 9.22.2 The number of fine hairs with a length of more than 3 mm per 10 m of the above-mentioned textile thread measured by method B is less than 40/10 m, the porosity of the above-mentioned textile thread is 40-65%, and the twist coefficient is 2.4-6.0.

又,本發明係關於一種紡織線,其係包含5質量%以上之聚丙烯系纖維者,其特徵在於:上述聚丙烯系纖維依據JIS L 1015(2010)測定之水分率為0.15質量%以上,依據JIS L 1095(2010)9.22.2 B法測定之上述紡織線每10 m中存在之長度3 mm以上之細毛數為40根/10 m以下,上述紡織線之氣孔率為40~65%,撚係數為2.4~6.0。Also, the present invention relates to a textile thread comprising 5% by mass or more of polypropylene-based fibers, wherein the polypropylene-based fibers have a moisture content of 0.15% by mass or more as measured in accordance with JIS L 1015 (2010), According to JIS L 1095 (2010) 9.22.2 B method, the number of fine hairs with a length of 3 mm or more per 10 m of the above-mentioned textile thread is 40/10 m or less, and the porosity of the above-mentioned textile thread is 40~65%. The twist coefficient is 2.4~6.0.

又,本發明係關於一種紡織線,其係包含大於50質量%之依據JIS L 1015(2010)測定之水分率未達0.15質量%之聚丙烯系纖維者,其特徵在於:依據JIS L 1095(2010)9.22.2 B法測定之上述紡織線每10 m中存在之長度3 mm以上之細毛數為40根/10 m以下,上述紡織線之撚角為23°以上。Also, the present invention relates to a textile thread comprising more than 50% by mass of polypropylene-based fibers with a moisture content of less than 0.15% by mass measured according to JIS L 1015 (2010), characterized in that: according to JIS L 1095 ( 2010) 9.22.2 The number of fine hairs with a length of more than 3 mm per 10 m of the above-mentioned textile thread measured by method B is less than 40/10 m, and the twist angle of the above-mentioned textile thread is more than 23°.

又,本發明係關於一種紡織線,其係包含5質量%以上之聚丙烯系纖維者,其特徵在於:上述聚丙烯系纖維依據JIS L 1015(2010)測定之水分率為0.15質量%以上,依據JIS L 1095(2010)9.22.2 B法測定之上述紡織線每10 m中存在之長度3 mm以上之細毛數為40根/10 m以下,上述紡織線之撚角為23°以上。Also, the present invention relates to a textile thread comprising 5% by mass or more of polypropylene-based fibers, wherein the polypropylene-based fibers have a moisture content of 0.15% by mass or more as measured in accordance with JIS L 1015 (2010), According to JIS L 1095 (2010) 9.22.2 B method, the number of fine hairs with a length of 3 mm or more per 10 m of the above-mentioned textile thread is 40 or less per 10 m, and the twist angle of the above-mentioned textile thread is 23° or more.

又,本發明係關於一種紡織線之製造方法,其係製造上述紡織線之方法,其特徵在於:於環錠精紡中包括如下步驟:準備至少一股包含大於50質量%之依據JIS L 1015(2010)測定之水分率未達0.15質量%之聚丙烯系纖維之粗紗A;向牽伸區供給含有至少一股粗紗A之兩股粗紗進行牽伸後,一面併紗一面向撚線區供給;及利用空氣沿粗紗之行進方向抽吸剛供給至撚線區後之兩股粗紗而使纖維收攏後進行撚線。In addition, the present invention relates to a method for manufacturing a textile thread, which is a method for manufacturing the above-mentioned textile thread, which is characterized in that: ring spinning includes the following steps: preparing at least one strand containing more than 50% by mass according to JIS L 1015 (2010) Roving A of polypropylene-based fibers whose moisture content is less than 0.15% by mass as measured by (2010); two rovings containing at least one roving A are supplied to the drafting zone for drafting, and one side is paralleled and the other is supplied to the twisting zone ; and use the air to suck the two strands of roving just supplied to the twisting area along the traveling direction of the roving so that the fibers are gathered and then twisted.

又,本發明係關於一種紡織線之製造方法,其係製造上述紡織線之方法,其特徵在於:於環錠精紡中包括如下步驟:準備至少一股包含5質量%以上之聚丙烯系纖維B之粗紗B;向牽伸區供給含有至少一股粗紗B之兩股粗紗進行牽伸後,一面併紗一面向撚線區供給;及利用空氣沿粗紗之行進方向抽吸剛供給至撚線區後之兩股粗紗而使纖維收攏後進行撚線;且上述聚丙烯系纖維依據JIS L 1015(2010)測定之水分率為0.15質量%以上。In addition, the present invention relates to a method for producing a textile thread, which is a method for producing the above-mentioned textile thread, and is characterized in that: ring spinning includes the following steps: preparing at least one polypropylene-based fiber containing 5% by mass or more The roving B of B; two strands of rovings containing at least one roving B are supplied to the drafting area for drafting, and one side is paralleled and the other is supplied to the twisting area; and the air is sucked along the traveling direction of the roving and just supplied to the twisting line The two rovings at the back of the zone are twisted after the fibers are gathered; and the moisture content of the above-mentioned polypropylene-based fibers measured according to JIS L 1015 (2010) is 0.15% by mass or more.

又,本發明係關於一種布帛,其特徵在於:包含上述紡織線。 發明之效果Also, the present invention relates to a fabric characterized by comprising the above-mentioned spun yarn. The effect of the invention

本發明可提供一種能夠提高布帛之抗起毛球性之包含聚丙烯系纖維之紡織線、及包含其之抗起毛球性良好之布帛。又,根據本發明,可獲得能夠提高布帛之抗起毛球性之包含聚丙烯系纖維之紡織線。尤其於使用依據JIS L 1015(2010)測定之水分率為0.15質量%以上之聚丙烯系纖維之情形時,能夠提高布帛之抗起毛球性之包含聚丙烯系纖維之紡織線之製造步驟之生產性亦提高。The present invention can provide a spun yarn comprising a polypropylene-based fiber capable of improving the pilling resistance of a fabric, and a fabric comprising the same having good pilling resistance. Also, according to the present invention, it is possible to obtain a spun yarn made of polypropylene-based fibers capable of improving the pilling resistance of the fabric. In particular, when using polypropylene-based fibers with a moisture content of 0.15% by mass or more as measured in accordance with JIS L 1015 (2010), the production of textile yarns containing polypropylene-based fibers that can improve the pilling resistance of fabrics Sex also improves.

本發明之發明人等對於提高使用包含聚丙烯系纖維之紡織線之情形時之布帛之抗起毛球性進行銳意研究。其結果發現,於包含大於50質量%之依據JIS L 1015(2010)測定之水分率未達0.15質量%之聚丙烯系纖維之紡織線中,將依據JIS L 1095(2010)9.22.2 B法測定之紡織線每10 m中存在之長度3 mm以上之細毛數設為40根/10 m以下,氣孔率設為40~65%,撚係數設為2.4~6.0,或者將依據JIS L 1095(2010)9.22.2 B法測定之紡織線每10 m中存在之長度3 mm以上之細毛數設為40根/10 m以下,撚角設為23°以上,藉此使用該紡織線之布帛之抗起毛球性提高。並且發現,具有此種細毛數、氣孔率及撚係數或具有此種細毛數及撚角之紡織線可藉由如下方式獲得:於環錠精紡中,準備包含大於50質量%之依據JIS L 1015(2010)測定之水分率未達0.15質量%之聚丙烯系纖維之粗紗A,向牽伸區供給含有至少一股粗紗A之兩股粗紗進行牽伸後,一面併紗一面向撚線區供給,利用空氣沿粗紗之行進方向抽吸剛供給至撚線區後之兩股粗紗而使纖維收攏後進行撚線。還發現,尤其藉由使用包含5質量%以上之依據JIS L 1015(2010)測定之水分率為0.15質量%以上之聚丙烯系纖維之粗紗B,紡織線之製造步驟之生產性提高。其原因在於,於使用依據JIS L 1015(2010)測定之水分率未達0.15質量%之聚丙烯系纖維之情形時,製造步驟中容易產生靜電,但藉由使用依據JIS L 1015(2010)測定之水分率為0.15質量%以上之聚丙烯系纖維,靜電之產生被抑制。藉由抑制靜電之產生,可抑制因紡織步驟中發生之纖維向各機台之旋轉部分等之纏繞或纖維束之鬆散蓬亂等導致機械效率降低或引起機械故障之情況,而實現穩定生產,並且,可抑制製成紡織線時之細毛或製成布帛時之起毛球性等之品質劣化。The inventors of the present invention earnestly studied to improve the pilling resistance of the fabric in the case of using a spun yarn made of polypropylene-based fibers. As a result, it was found that in textile yarns containing more than 50% by mass of polypropylene-based fibers with a moisture content of less than 0.15% by mass measured according to JIS L 1015 (2010), the method according to JIS L 1095 (2010) 9.22.2 B The measured number of fine hairs with a length of 3 mm or more per 10 m of the textile thread is set to 40/10 m or less, the porosity is set to 40~65%, and the twist coefficient is set to 2.4~6.0, or according to JIS L 1095 ( 2010) 9.22.2 The number of fine hairs with a length of 3 mm or more in each 10 m of the textile thread measured by the method B is set to 40/10 m or less, and the twist angle is set to 23° or more, so as to use the textile thread. Improved pilling resistance. And it was found that a textile thread having such a number of fine hairs, porosity and twist coefficient or having such a number of fine hairs and a twist angle can be obtained by preparing to contain more than 50% by mass of JIS L 1015(2010) roving A of polypropylene-based fibers whose moisture content is less than 0.15% by mass, after feeding two rovings containing at least one roving A to the drafting zone and drawing, one side is doubling and the other is facing the twisting zone Supply, use air to suck the two strands of roving just after being supplied to the twisting area along the traveling direction of the roving, so that the fibers are gathered and then twisted. In particular, it was found that the productivity of the manufacturing process of the spinning yarn was improved by using the roving B containing 5% by mass or more of polypropylene-based fibers having a moisture content of 0.15% by mass or more as measured in accordance with JIS L 1015 (2010). The reason for this is that static electricity is likely to be generated during the manufacturing process when using polypropylene-based fibers with a moisture content of less than 0.15% by mass measured in accordance with JIS L 1015 (2010). The generation of static electricity is suppressed for polypropylene-based fibers with a moisture content of 0.15% by mass or more. By suppressing the generation of static electricity, it is possible to suppress the decrease in mechanical efficiency or cause mechanical failure due to the winding of fibers to the rotating parts of each machine or the looseness of fiber bundles in the spinning process, and to achieve stable production, and , It can suppress the quality deterioration of fluff when it is made into a textile thread or pilling when it is made into a cloth.

以下,只要無特別說明,所謂水分率意指依據JIS L 1015(2010)測定之值。關於成為測定水分率之對象之纖維,任意地截取進行紡織前之原棉之狀態即亦附著有纖維處理劑等之狀態之纖維供於測定。又,以下只要無特別說明,所謂細毛數意指依據JIS L 1095(2010)9.22.2 B法測定之紡織線每10 m中存在之規定長度之細毛數。Hereinafter, unless otherwise specified, the water content means a value measured in accordance with JIS L 1015 (2010). Regarding the fibers to be measured for moisture content, fibers in the state of raw cotton before spinning, that is, fibers in a state in which a fiber treatment agent and the like are adhered, are randomly cut and used for measurement. Hereinafter, unless otherwise specified, the number of fine hairs refers to the number of fine hairs of a predetermined length per 10 m of textile yarn measured in accordance with JIS L 1095 (2010) 9.22.2 B method.

以下,將包含大於50質量%之水分率未達0.15質量%之聚丙烯系纖維(以下亦記作聚丙烯系纖維A)之紡織線設為紡織線A進行說明,將包含5質量%以上之水分率為0.15質量%以上之聚丙烯系纖維(以下亦記作聚丙烯系纖維B)之紡織線設為紡織線B進行說明。Hereinafter, a spun yarn containing more than 50% by mass of polypropylene-based fibers (hereinafter also referred to as polypropylene-based fiber A) with a moisture content of less than 0.15% by mass will be described as spun yarn A, and will contain 5% by mass or more A spun thread of a polypropylene-based fiber having a moisture content of 0.15% by mass or more (hereinafter also referred to as a polypropylene-based fiber B) will be described as a spun thread B.

(紡織線A) 藉由使紡織線A之長度3 mm以上之細毛數為40根/10 m以下、氣孔率為40~65%、撚係數為2.4~6.0、或藉由使長度3 mm以上之細毛數為40根/10 m以下、撚角為23°以上,包含紡織線A之布帛之抗起毛球性變得良好。(textile thread A) By making the number of fine hairs with a length of 3 mm or more of the textile thread A be 40/10 m or less, the porosity is 40~65%, and the twist coefficient is 2.4~6.0, or by making the number of fine hairs with a length of 3 mm or more be 40 Threads/10 m or less and a twist angle of 23° or more, the pilling resistance of the fabric including the spun yarn A becomes good.

藉由使紡織線A之長度3 mm以上之細毛數為40根/10 m以下,布帛之抗起毛球性變得良好。就進一步提高布帛之抗起毛球性之觀點而言,較佳為長度3 mm以上之細毛數為35根/10 m以下,更佳為30根/10 m以下,最佳為10根/10 m以下。又,長度5 mm以上之細毛數較佳為5根/10 m以下,更佳為3根/10 m以下,進而較佳為1根/10 m以下,最佳為0根/10 m。When the number of fine hairs with a length of 3 mm or more of the spun yarn A is 40/10 m or less, the pilling resistance of the fabric becomes good. From the viewpoint of further improving the pilling resistance of the fabric, the number of fine hairs with a length of 3 mm or more is preferably 35 or less, more preferably 30 or less, most preferably 10/10 m the following. Also, the number of fine hairs with a length of 5 mm or more is preferably at most 5/10 m, more preferably at most 3/10 m, still more preferably at most 1/10 m, and most preferably at most 0/10 m.

藉由使紡織線A之氣孔率為40~65%,布帛之抗起毛球性變得良好。就布帛之抗起毛球性及柔軟之質地之觀點而言,氣孔率為43~65%較佳為。於本發明中,所謂氣孔率意指紗線中空氣所占比率,如下文所述,藉由利用電子顯微鏡觀察紗線側面而計算紗線直徑,根據紗線之直徑及比重而算出。By making the porosity of the spun yarn A 40 to 65%, the pilling resistance of the fabric becomes good. From the viewpoint of the anti-pilling property and soft texture of the fabric, the porosity is preferably 43-65%. In the present invention, the so-called air porosity refers to the ratio of air in the yarn. As described below, the diameter of the yarn is calculated by observing the side of the yarn with an electron microscope, and is calculated from the diameter and specific gravity of the yarn.

藉由使紡織線A之撚係數為2.4~6.0,布帛之抗起毛球性變得良好。就布帛之抗起毛球性及柔軟之質地之觀點而言,撚係數較佳為2.8~4.5,更佳為3.0~4.0。By setting the twist coefficient of the spun yarn A to 2.4 to 6.0, the pilling resistance of the fabric becomes good. From the viewpoint of pilling resistance and soft texture of the fabric, the twist coefficient is preferably 2.8-4.5, more preferably 3.0-4.0.

藉由使紡織線A之撚角為23°以上,布帛之抗起毛球性變得良好。就進一步提高布帛之抗起毛球性之觀點而言,撚角較佳為25°以上,更佳為26°以上,進而較佳為27°以上。再者,紡織線A之撚角之上限並無特別限定,例如就提高編成性之觀點而言,較佳為45°以下。When the twist angle of the spun yarn A is 23° or more, the pilling resistance of the fabric becomes good. From the viewpoint of further improving the pilling resistance of the fabric, the twist angle is preferably at least 25°, more preferably at least 26°, and still more preferably at least 27°. Furthermore, the upper limit of the twist angle of the spun yarn A is not particularly limited, but is preferably 45° or less from the viewpoint of improving weavability, for example.

紡織線A只要包含大於50質量%之聚丙烯系纖維A即可,並無特別限定,就輕量性或保溫性之觀點而言,較佳為包含60質量%以上之聚丙烯系纖維A,更佳為包含70質量%以上。作為聚丙烯系纖維A,適當使用可用作撥水性纖維之普通聚丙烯系纖維等即可。The spun thread A is not particularly limited as long as it contains more than 50% by mass of the polypropylene-based fiber A. From the viewpoint of lightness and heat retention, it is preferable to contain at least 60% by mass of the polypropylene-based fiber A. More preferably, it contains 70 mass % or more. As the polypropylene-based fiber A, general polypropylene-based fibers that can be used as water-repellent fibers, etc. may be appropriately used.

於聚丙烯系纖維A中,聚丙烯可為丙烯之均聚物,亦可為丙烯含量超過50莫耳%之包含丙烯及能夠與其共聚合之成分之共聚物。能夠與丙烯共聚合之成分並無特別限定,例如可列舉:乙烯、丁烯、甲基戊烯等烯烴系單體。較佳為丙烯均聚物。上述聚丙烯可單獨使用一種,亦可將兩種以上組合使用。In the polypropylene-based fiber A, polypropylene may be a homopolymer of propylene, or a copolymer containing propylene and a component that can be copolymerized with it, with a propylene content of more than 50 mol%. The component that can be copolymerized with propylene is not particularly limited, and examples thereof include olefin-based monomers such as ethylene, butene, and methylpentene. Preferred is a propylene homopolymer. The above-mentioned polypropylenes may be used alone or in combination of two or more.

就紡絲性之觀點而言,上述聚丙烯之熔體質量流率(MFR)較佳為5~60 g/10 min。於本發明中,聚丙烯之MFR係依據ISO1133於230℃、2.16k g荷重下測定。From the viewpoint of spinnability, the melt mass flow rate (MFR) of the above-mentioned polypropylene is preferably 5 to 60 g/10 min. In the present invention, the MFR of polypropylene is measured at 230° C. under a load of 2.16 kg in accordance with ISO1133.

聚丙烯系纖維A可藉由常規方法製造。例如可藉由以下方式獲得:使用紡絲頭,將聚丙烯或包含聚丙烯之樹脂組成物進行熔融紡絲而製成未延伸絲,對所獲得之未延伸絲進行延伸,賦予纖維處理劑(油劑),利用捲縮機賦予捲縮,加以乾燥。The polypropylene-based fiber A can be produced by a conventional method. For example, it can be obtained by: using a spinning head, melt-spinning polypropylene or a resin composition containing polypropylene to form an undrawn yarn, drawing the obtained undrawn yarn, and applying a fiber treatment agent ( Oil agent) is crimped with a crimper and dried.

聚丙烯系纖維A可為聚丙烯之單一成分纖維,亦可為聚丙烯彼此或聚丙烯與其他樹脂之複合纖維。於將聚丙烯系纖維A著色之情形時,於聚丙烯中混合顏料、或與易被染料染色之成分進行複合製成芯鞘型等形狀即可。The polypropylene-based fiber A may be a single-component fiber of polypropylene, or may be a composite fiber of polypropylene or polypropylene and other resins. In the case of coloring the polypropylene-based fiber A, it is sufficient to mix a pigment in polypropylene, or compound it with a component that is easily dyed with a dye, and make it into a core-sheath shape or the like.

聚丙烯系纖維A之纖維截面形狀並無特別限定,可為圓形或非圓形(所謂異形截面)之任意形狀。The fiber cross-sectional shape of the polypropylene-based fiber A is not particularly limited, and may be any shape of circular or non-circular (so-called special-shaped cross-section).

上述纖維處理劑較佳為親水性油劑。藉由賦予親水性油劑,有抑制靜電、紡織步驟中之生產性優化之傾向。The above-mentioned fiber treatment agent is preferably a hydrophilic oil agent. By imparting a hydrophilic oil agent, there is a tendency to suppress static electricity and optimize productivity in spinning steps.

聚丙烯系纖維A之纖維長度並無特別限定,較佳為24~75 mm,更佳為28~65 mm,進而較佳為32~54 mm,尤佳為34~48 mm。The fiber length of the polypropylene-based fiber A is not particularly limited, but is preferably 24-75 mm, more preferably 28-65 mm, further preferably 32-54 mm, and especially preferably 34-48 mm.

聚丙烯系纖維A之單絲纖維強度較佳為1.8~7.0 cN/dtex,更佳為2.0~6.0 cN/dtex,進而較佳為3.0~6.0 cN/dtex。若單絲纖維強度為1.8 cN/dtex以上,則即便受到加工纖維時之外力(例如紡織張力等),纖維亦不易斷裂。又,若單絲纖維強度為7 cN/dtex以下,則可獲得抗起毛球性更佳之纖維。The monofilament fiber strength of the polypropylene-based fiber A is preferably 1.8-7.0 cN/dtex, more preferably 2.0-6.0 cN/dtex, and still more preferably 3.0-6.0 cN/dtex. If the monofilament fiber strength is 1.8 cN/dtex or more, the fiber will not be easily broken even if it is subjected to an external force (such as textile tension, etc.) during fiber processing. Also, if the monofilament fiber strength is 7 cN/dtex or less, fibers with better pilling resistance can be obtained.

聚丙烯系纖維A之伸度較佳為5~70%,更佳為10~40%。若伸度為5~70%,則可獲得質地柔軟之纖維。The elongation of the polypropylene fiber A is preferably 5-70%, more preferably 10-40%. If the elongation is 5~70%, the fiber with soft texture can be obtained.

紡織線A亦可包含聚丙烯系纖維A以外之其他纖維。其他纖維並無特別限定,例如可列舉:聚丙烯系纖維以外之聚烯烴系纖維、丙烯酸系纖維、聚酯纖維、尼龍纖維、乙酸酯纖維、丙烯酸酯纖維、乙烯-乙烯醇系纖維及胺基甲酸酯纖維等合成纖維,或絹纖維、絨(wool)纖維、開司米山羊毛纖維、棉(cotton)纖維、麻纖維、嫘縈纖維及銅氨纖維等天然纖維等。紡織線A根據用途及目的等可適當包含未達50質量%之其他纖維。再者,紡織線A可包含未達5質量%之下述聚丙烯系纖維B作為其他纖維。The spun thread A may also contain other fibers than the polypropylene-based fiber A. Other fibers are not particularly limited, and examples thereof include polyolefin fibers other than polypropylene fibers, acrylic fibers, polyester fibers, nylon fibers, acetate fibers, acrylic fibers, ethylene-vinyl alcohol fibers, and amine fibers. Synthetic fibers such as urethane fibers, or natural fibers such as silk fibers, wool fibers, cashmere goat hair fibers, cotton fibers, hemp fibers, rayon fibers, and cupro fibers. The textile thread A may appropriately contain other fibers of less than 50% by mass depending on the use and purpose. In addition, the spun yarn A may contain less than 5% by mass of the following polypropylene-based fiber B as other fibers.

聚丙烯系纖維A及其他纖維並無特別限定,例如單絲纖維纖度可為0.1~100 dtex。於將紡織線A用於衣料之情形時,聚丙烯系纖維A及其他纖維之單絲纖維纖度較佳為0.4~5 dtex,更佳為0.5~3.5 dtex,進而較佳為0.6~2.5 dtex。於將紡織線A用於工業材料之情形時,單絲纖維纖度較佳為5~50 dtex。又,聚丙烯系纖維A及其他纖維之纖維長度較佳為24~75 mm。The polypropylene-based fiber A and other fibers are not particularly limited, for example, the fineness of the monofilament fiber may be 0.1-100 dtex. When the textile thread A is used for clothing, the monofilament fineness of the polypropylene fiber A and other fibers is preferably 0.4-5 dtex, more preferably 0.5-3.5 dtex, and still more preferably 0.6-2.5 dtex. When the textile thread A is used for industrial materials, the fineness of the monofilament fiber is preferably 5-50 dtex. Also, the fiber length of the polypropylene-based fiber A and other fibers is preferably 24 to 75 mm.

紡織線A之支數並無特別限定,以英式棉紗支數計可為5~100S之範圍,較佳為10~90S,更佳為15~85S,進而較佳為20~80S。The count of the textile thread A is not particularly limited, but it can range from 5 to 100S, preferably 10 to 90S, more preferably 15 to 85S, and even more preferably 20 to 80S in terms of English cotton yarn count.

紡織線A較佳為由兩股纖維束構成之撚合線。是否為由兩股纖維束構成之撚合線可藉由將紡織線向加撚方向之反方向進行扭轉而解撚時是否分解為兩股纖維束來確認。若為由兩股纖維束構成之撚合線,則於將各纖維束併紗、加撚時亦分別對每股纖維束施加鬆撚,因此抑制於製成紡織線時產生細毛,製成布帛時之起毛球性顯著改善。又,由於自各股粗紗變為經牽伸之纖維束相互交撚之狀態,故纖維束與纖維束相互纏繞(纖維束彼此交聯)程度改善,藉此製成布帛時之起毛球性顯著改善。由兩股纖維束構成之撚合線可藉由下述賽絡緊密紡(Siro-Compact Spinning)製造。The textile thread A is preferably a twisted thread composed of two fiber bundles. Whether it is a twisted yarn composed of two fiber bundles can be confirmed by twisting the textile yarn in the opposite direction to the twisting direction and whether it is decomposed into two fiber bundles when untwisting. In the case of a twisted yarn composed of two fiber bundles, when the fiber bundles are combined and twisted, loose twist is also applied to each fiber bundle, so that it is suppressed to produce fine hair when it is made into a textile yarn, and it is made into a cloth. Significant improvement in pilling. In addition, since each roving becomes a state in which the drawn fiber bundles are intertwined with each other, the degree of intertwining between fiber bundles (fiber bundles are cross-linked) is improved, and the pilling property of fabrics is significantly improved. A twisted yarn composed of two fiber bundles can be produced by the following Siro-Compact Spinning.

紡織線A之紡織方法並無特別限定,可藉由在環錠法中按照如下所述之步驟進行精紡而製作。預先準備至少一股包含大於50質量%之聚丙烯系纖維A之粗紗A,向牽伸區供給含有至少一股粗紗A之兩股粗紗進行牽伸後,一面併紗一面向撚線區供給,利用空氣沿粗紗之行進方向抽吸剛供給至撚線區後之兩股粗紗而使纖維收攏後進行撚線,藉此可獲得紡織線A。該紡織方法係將賽絡紡與緊密紡併用之方法,亦稱為賽絡緊密紡,藉由該紡織方法獲得之紡織線亦稱為賽絡緊密線或緊密賽絡線。於賽絡緊密紡中,藉由將撚係數調整至2.4~6.0之範圍,容易獲得具有上述規定之細毛數及氣孔率之紡織線,可提高布帛之抗起毛球性。就布帛之抗起毛球性及柔軟之質地之觀點而言,撚係數較佳為2.8~4.5,更佳為3.0~4.0。The spinning method of the spun yarn A is not particularly limited, and it can be produced by worsted spinning in the following steps in the ring spinning method. Pre-preparing at least one roving A containing more than 50% by mass of polypropylene-based fiber A, supplying two rovings A containing at least one roving A to the drafting zone for drafting, doubling one side and supplying it to the twisting zone, The two strands of roving immediately after being supplied to the twisting zone are sucked by air along the traveling direction of the roving, the fibers are gathered and then twisted, whereby a spun yarn A can be obtained. The weaving method is a method of combining siro spinning and compact spinning, also known as siro compact spinning, and the textile thread obtained by this weaving method is also called siro compact thread or compact siro thread. In siro compact spinning, by adjusting the twist coefficient to the range of 2.4~6.0, it is easy to obtain the textile yarn with the above-mentioned number of fine hairs and porosity, and the pilling resistance of the fabric can be improved. From the viewpoint of pilling resistance and soft texture of the fabric, the twist coefficient is preferably 2.8-4.5, more preferably 3.0-4.0.

上述兩股粗紗可均為粗紗A。或者可以使所獲得之紡織線A中之聚丙烯系纖維A之含量大於50質量%之方式適當組合使用粗紗A與其他粗紗。The above-mentioned two strands of rovings may both be rovings A. Alternatively, the roving A and other rovings may be used in combination appropriately so that the content of the polypropylene-based fiber A in the obtained spun yarn A exceeds 50% by mass.

(紡織線B) 藉由使紡織線B之長度3 mm以上之細毛數為40根/10 m以下、氣孔率為40~65%、撚係數為2.4~6.0、或藉由使長度3 mm以上之細毛數為40根/10 m以下、撚角為23°以上,包含紡織線B之布帛之抗起毛球性變得良好。(textile thread B) By setting the number of fine hairs with a length of 3 mm or more in the textile thread B to 40 per 10 m or less, with a porosity of 40 to 65%, and a twist coefficient of 2.4 to 6.0, or by making the number of fine hairs with a length of 3 mm or more to 40 Threads/10 m or less and a twist angle of 23° or more, the pilling resistance of the fabric including the spun yarn B becomes good.

藉由使紡織線B之長度3 mm以上之細毛數為40根/10 m以下,布帛之抗起毛球性變得良好。就進一步提高布帛之抗起毛球性之觀點而言,較佳為長度3 mm以上之細毛數為35根/10 m以下,更佳為30根/10 m以下,最佳為10根/10 m以下。又,長度5 mm以上之細毛數較佳為5根/10 m以下,更佳為3根/10 m以下,進而較佳為1根/10 m以下,最佳為0根/10 m。When the number of fine hairs with a length of 3 mm or more of the spun yarn B is 40/10 m or less, the pilling resistance of the fabric becomes good. From the viewpoint of further improving the pilling resistance of the fabric, the number of fine hairs with a length of 3 mm or more is preferably 35 or less, more preferably 30 or less, most preferably 10/10 m the following. Also, the number of fine hairs with a length of 5 mm or more is preferably at most 5/10 m, more preferably at most 3/10 m, still more preferably at most 1/10 m, and most preferably at most 0/10 m.

藉由使紡織線B之氣孔率為40~65%,布帛之抗起毛球性變得良好。就布帛之抗起毛球性及柔軟之質地之觀點而言,氣孔率較佳為50~65%,更佳為55~65%。By making the porosity of the spun yarn B 40 to 65%, the pilling resistance of the fabric becomes good. From the viewpoint of pilling resistance and soft texture of the fabric, the porosity is preferably 50-65%, more preferably 55-65%.

藉由使紡織線B之撚係數為2.4~6.0,布帛之抗起毛球性變得良好。就布帛之抗起毛球性及柔軟之質地之觀點而言,撚係數較佳為2.8~4.5,更佳為3.0~4.0。By setting the twist coefficient of the spun yarn B to 2.4 to 6.0, the pilling resistance of the fabric becomes good. From the viewpoint of pilling resistance and soft texture of the fabric, the twist coefficient is preferably 2.8-4.5, more preferably 3.0-4.0.

藉由使紡織線B之撚角為23°以上,布帛之抗起毛球性變得良好。就進一步提高布帛之抗起毛球性之觀點而言,撚角較佳為25°以上,更佳為26°以上,進而較佳為27°以上。再者,紡織線B之撚角之上限並無特別限定,例如就提高編成性之觀點而言,較佳為45°以下。When the twist angle of the spun yarn B is 23° or more, the pilling resistance of the fabric becomes good. From the viewpoint of further improving the pilling resistance of the fabric, the twist angle is preferably at least 25°, more preferably at least 26°, and still more preferably at least 27°. Furthermore, the upper limit of the twist angle of the spun yarn B is not particularly limited, but is preferably 45° or less from the viewpoint of improving weavability, for example.

紡織線B只要包含5質量%以上之聚丙烯系纖維B即可,並無特別限定,就紡織步驟之生產性之觀點而言,較佳為包含30質量%以上之聚丙烯系纖維B,更佳為包含50質量%以上。The spinning thread B is not particularly limited as long as it contains 5% by mass or more of the polypropylene-based fiber B. From the viewpoint of productivity in the spinning process, it is preferably 30% by mass or more of the polypropylene-based fiber B, and more Preferably, it contains 50% by mass or more.

聚丙烯系纖維B之水分率為0.15質量%以上即可,較佳為0.2質量%以上,更佳為0.25質量%以上。又,聚丙烯系纖維B之水分率較佳為1.0質量%以下,更佳為0.4質量%以下,並無特別限定。例如藉由使聚丙烯纖維中含有親水性成分使之親水化,可獲得水分率為0.15質量%以上之聚丙烯系纖維B。聚丙烯系纖維B較佳為包含相對於聚丙烯成分100質量份為0.025~0.25質量份之親水性成分,更佳為包含0.05~0.1質量份。The moisture content of the polypropylene fiber B may be at least 0.15% by mass, preferably at least 0.2% by mass, more preferably at least 0.25% by mass. Also, the moisture content of the polypropylene-based fiber B is preferably at most 1.0% by mass, more preferably at most 0.4% by mass, and is not particularly limited. For example, by hydrophilizing polypropylene fibers by containing a hydrophilic component, polypropylene-based fibers B having a water content of 0.15% by mass or more can be obtained. The polypropylene-based fiber B preferably contains 0.025 to 0.25 parts by mass of the hydrophilic component with respect to 100 parts by mass of the polypropylene component, more preferably contains 0.05 to 0.1 parts by mass.

於聚丙烯系纖維B中,聚丙烯可為丙烯之均聚物,亦可為丙烯含量超過50莫耳%之包含丙烯及能夠與其共聚合之成分之共聚物。能夠與丙烯共聚合之成分並無特別限定,例如可列舉:乙烯、丁烯、甲基戊烯等烯烴系單體。較佳為丙烯均聚物。上述聚丙烯可單獨使用一種,亦可將兩種以上組合使用。In the polypropylene-based fiber B, polypropylene may be a homopolymer of propylene, or a copolymer containing propylene and a component that can be copolymerized with it, with a propylene content of more than 50 mol%. The component that can be copolymerized with propylene is not particularly limited, and examples thereof include olefin-based monomers such as ethylene, butene, and methylpentene. Preferred is a propylene homopolymer. The above-mentioned polypropylenes may be used alone or in combination of two or more.

就紡絲性之觀點而言,上述聚丙烯之熔體質量流率(MFR)較佳為5~60 g/10 min。From the viewpoint of spinnability, the melt mass flow rate (MFR) of the above-mentioned polypropylene is preferably 5 to 60 g/10 min.

上述親水性成分只要為具有水溶性或水分散性者即可,並無特別限定。作為水溶性之親水性成分,例如可列舉:離子性界面活性劑、非離子性界面活性劑等,其中,較佳為非離子界面活性劑。作為酯型非離子界面活性劑,可列舉:甘油脂肪酸酯、山梨醇酐脂肪酸酯及蔗糖脂肪酸酯等;作為醚型非離子界面活性劑,可列舉:聚氧乙烯(POE)烷基醚、聚氧乙烯(POE)烷基苯基醚、聚氧乙烯聚氧丙烯二醇等。其中,較佳為聚氧乙烯烷基醚或聚氧伸烷基衍生物(兩化合物均例如由花王公司製造,商品名“EMULGEN”)。The above-mentioned hydrophilic component is not particularly limited as long as it is water-soluble or water-dispersible. As a water-soluble hydrophilic component, an ionic surfactant, a nonionic surfactant, etc. are mentioned, for example, Among them, a nonionic surfactant is preferable. Examples of ester-type nonionic surfactants include: glycerin fatty acid esters, sorbitan fatty acid esters, and sucrose fatty acid esters; examples of ether-type nonionic surfactants include: polyoxyethylene (POE) alkyl Ether, polyoxyethylene (POE) alkylphenyl ether, polyoxyethylene polyoxypropylene glycol, etc. Among them, polyoxyethylene alkyl ethers or polyoxyalkylene derivatives (both compounds are manufactured by Kao Corporation under the trade name "EMULGEN") are preferred.

上述水溶性之親水性成分之分子量較佳為200~5000,更佳為300~3000。於單獨使用親水性界面活性劑作為上述水溶性之親水性成分之情形時,親水性界面活性劑之分子量較佳為1000以下。The molecular weight of the above-mentioned water-soluble hydrophilic component is preferably 200-5000, more preferably 300-3000. When using a hydrophilic surfactant alone as the above-mentioned water-soluble hydrophilic component, the molecular weight of the hydrophilic surfactant is preferably 1,000 or less.

作為水分散性之親水性成分,例如可使用:高嶺土、膨潤石、蒙脫石、膨潤土等黏土礦物,發煙二氧化矽、膠體二氧化矽、矽膠等親水性二氧化矽,滑石、沸石等多層結構或非晶形之無機粒子,纖維素等天然高分子多糖類,甲殼素、殼聚糖等胺基系高分子多糖類等。高分子多糖類以奈米纖維之形態添加即可。黏土礦物或奈米纖維等係以固體形態添加,故亦發揮作為保水劑之效果。無機粒子之平均粒徑宜儘可能較小,較佳為100 nm以下。再者,平均粒徑係取利用相位阱(phase trap)法粒徑測定裝置所測得者。Examples of water-dispersible hydrophilic components include: clay minerals such as kaolin, bentonite, montmorillonite, and bentonite; hydrophilic silica such as fumed silica, colloidal silica, and silica gel; talc, zeolite, etc. Multilayer structure or amorphous inorganic particles, natural polymer polysaccharides such as cellulose, amine-based polymer polysaccharides such as chitin and chitosan, etc. Polymer polysaccharides can be added in the form of nanofibers. Clay minerals or nanofibers are added in solid form, so they also function as water-retaining agents. The average particle size of the inorganic particles should be as small as possible, preferably below 100 nm. In addition, the average particle diameter is what measured with the particle diameter measuring apparatus of the phase trap method.

聚丙烯系纖維B可藉由將包含聚丙烯與含親水性成分之母料樹脂組成物之聚丙烯系樹脂組成物進行熔融紡絲而獲得。上述聚丙烯系樹脂組成物較佳為包含相對於聚丙烯100質量份為1~10質量份之母料樹脂組成物。The polypropylene-based fiber B can be obtained by melt-spinning a polypropylene-based resin composition including polypropylene and a masterbatch resin composition containing a hydrophilic component. It is preferable that the said polypropylene resin composition contains the masterbatch resin composition of 1-10 mass parts with respect to 100 mass parts of polypropylene.

上述母料樹脂組成物包含作為能夠加熱熔融之基礎樹脂之聚丙烯與親水性成分。上述母料樹脂組成物較佳為包含1~10質量%之上述親水性成分,更佳為包含2~8質量%之上述親水性成分。作為基礎樹脂之聚丙烯可為與構成聚丙烯系纖維B之聚丙烯相同或不同者。The above-mentioned masterbatch resin composition includes polypropylene as a heat-meltable base resin and a hydrophilic component. The above-mentioned masterbatch resin composition preferably contains 1-10% by mass of the above-mentioned hydrophilic component, more preferably contains 2-8% by mass of the above-mentioned hydrophilic component. The polypropylene as the base resin may be the same as or different from the polypropylene constituting the polypropylene-based fiber B.

上述母料樹脂組成物較佳為進而包含相溶化劑。作為相溶化劑,較佳為例如乙烯-丙烯酸酯共聚物、乙烯-丙烯酸-順丁烯二酸共聚物等包含極性基(酸酐基)之乙烯系共聚物。含有極性基之乙烯系共聚物藉由具有極性基,與親水性成分之親和性變高,又,熔點相對低於聚丙烯,因此容易進行混練而較佳。相溶化劑之熔點(DSC法)較佳為70~110℃。熔點更佳為80~105℃。It is preferable that the above-mentioned masterbatch resin composition further contains a compatibilizing agent. As the compatibilizing agent, for example, vinyl copolymers containing polar groups (acid anhydride groups), such as ethylene-acrylic acid ester copolymers and ethylene-acrylic acid-maleic acid copolymers, are preferable. Since the polar group-containing ethylene-based copolymer has a polar group, the affinity with the hydrophilic component becomes high, and since the melting point is relatively lower than that of polypropylene, it is preferable that kneading is easy. The melting point (DSC method) of the compatibilizer is preferably 70~110°C. The melting point is more preferably 80~105°C.

上述母料樹脂組成物亦可進而包含MFR高於上述基礎樹脂之聚丙烯之高MFR聚丙烯,高MFR聚丙烯之MFR較佳為比上述基礎樹脂之MFR高10倍以上。例如,高MFR聚丙烯之MFR較佳為100~3000 g/10 min,更佳為500~2500 g/10 min。高MFR聚丙烯可單獨使用一種,亦可將兩種以上組合使用。The above-mentioned masterbatch resin composition may further include high MFR polypropylene having an MFR higher than that of the above-mentioned base resin. The MFR of the high-MFR polypropylene is preferably more than 10 times higher than the MFR of the above-mentioned base resin. For example, the MFR of high MFR polypropylene is preferably 100~3000 g/10 min, more preferably 500~2500 g/10 min. One type of high MFR polypropylene may be used alone, or two or more types may be used in combination.

上述母料樹脂組成物之製造方法較佳為包括:一次加工步驟,對基礎樹脂之聚丙烯與親水性成分進行熔融混練,經冷卻後將其碎片化;及二次加工步驟,於上述經碎片化之樹脂組成物中熔融混練高MFR聚丙烯,經冷卻後將其碎片化。再者,有時將「碎片」稱為「顆粒」。The manufacturing method of the above-mentioned masterbatch resin composition preferably includes: a primary processing step, melting and kneading the polypropylene and the hydrophilic component of the base resin, and fragmenting it after cooling; The high MFR polypropylene is melt-kneaded in the resin composition, and it is fragmented after cooling. Furthermore, "fragments" are sometimes referred to as "particles".

於上述一次加工步驟中,首先,使用擠出機,將擠出部連續地連接至具備減壓管線之混練室,向上述混練室內供給親水性成分(液狀)或視需要溶解或分散於水等溶劑中之親水性成分、與基礎樹脂之聚丙烯,於混合之同時將溶劑以氣體之狀態經由上述減壓管線而去除,繼而,自擠出部擠出樹脂組成物,藉此獲得樹脂組成物。若進而添加相溶化劑,則基礎樹脂與親水性成分之混合變得有效率,因此較佳。又,於上述二次加工步驟中,較佳為視情況添加作為親水性成分中之固體之親水性成分的保水劑。In the above-mentioned primary processing step, first, using an extruder, the extrusion part is continuously connected to a kneading chamber equipped with a decompression line, and a hydrophilic component (liquid) is supplied to the above-mentioned kneading chamber or dissolved or dispersed in water if necessary. The hydrophilic component in the solvent and the polypropylene of the base resin are mixed, and the solvent is removed in a gaseous state through the above-mentioned decompression line while mixing, and then the resin composition is extruded from the extrusion part to obtain the resin composition. things. Furthermore, if a compatibilizing agent is added, mixing of a base resin and a hydrophilic component becomes efficient, and it is preferable. In addition, in the above-mentioned secondary processing step, it is preferable to add a water retaining agent as a solid hydrophilic component in the hydrophilic component as the case may be.

除使用包含聚丙烯與含親水性成分之母料樹脂組成物之聚丙烯系樹脂組成物以外,聚丙烯系纖維B可藉由常規方法製造。例如可藉由以下方式獲得:使用紡絲頭,將包含聚丙烯與含親水性成分之母料樹脂組成物之聚丙烯系樹脂組成物進行熔融紡絲而製成未延伸絲,對所獲得之未延伸絲進行延伸,賦予纖維處理劑(油劑),利用捲縮機賦予捲縮,加以乾燥。The polypropylene-based fiber B can be produced by a conventional method except for using a polypropylene-based resin composition including polypropylene and a masterbatch resin composition containing a hydrophilic component. For example, it can be obtained by melt-spinning a polypropylene-based resin composition comprising polypropylene and a masterbatch resin composition containing a hydrophilic component using a spinning head to produce an undrawn yarn, and the obtained The unstretched yarn is stretched, a fiber treatment agent (oil agent) is applied, crimped by a crimper, and dried.

具體而言,可藉由如下方式製作聚丙烯系纖維B(未延伸絲)。 (1)以基礎樹脂之聚丙烯:親水性成分(聚氧乙烯烷基醚):相溶化劑=100:2~8:2~8(質量份)進行一次加工(一次加工樹脂)。 (2)作為二次加工,進行一次加工樹脂:高MFR聚丙烯=100:5~15(質量份)之加工而製作母料樹脂組成物(二次加工樹脂)。 (3)將於100質量份之聚丙烯中混合1~10質量份左右之上述母料樹脂組成物(二次加工樹脂)而獲得之聚丙烯系樹脂組成物進行熔融紡絲。Specifically, the polypropylene-based fiber B (undrawn yarn) can be produced as follows. (1) Perform primary processing (primary processing resin) with polypropylene of base resin: hydrophilic component (polyoxyethylene alkyl ether): compatibilizer = 100: 2~8: 2~8 (parts by mass). (2) As secondary processing, a primary processing resin:high MFR polypropylene=100:5~15 (parts by mass) is processed to produce a masterbatch resin composition (secondary processing resin). (3) Melt-spinning a polypropylene-based resin composition obtained by mixing about 1 to 10 parts by mass of the above-mentioned masterbatch resin composition (secondary processing resin) with 100 parts by mass of polypropylene.

聚丙烯系纖維B可為聚丙烯之單一成分,亦可為聚丙烯彼此或聚丙烯與其他樹脂之複合成分。於將聚丙烯系纖維B著色之情形時,於聚丙烯中混合顏料、或與易被染料染色之成分進行複合製成芯鞘型等形狀即可。The polypropylene-based fiber B may be a single component of polypropylene, or a composite component of polypropylene or polypropylene and other resins. In the case of coloring the polypropylene-based fiber B, it is sufficient to mix a pigment in polypropylene, or compound it with a component that is easily dyed with a dye, and make it into a core-sheath shape or the like.

聚丙烯系纖維B之纖維截面形狀並無特別限定,可為圓形或非圓形(所謂異形截面)之任意形狀。The fiber cross-sectional shape of the polypropylene-based fiber B is not particularly limited, and may be any shape of circular or non-circular (so-called special-shaped cross-section).

上述纖維處理劑較佳為親水性油劑。藉由賦予親水性油劑,有抑制靜電、紡織步驟中之生產性優化之傾向。The above-mentioned fiber treatment agent is preferably a hydrophilic oil agent. By imparting a hydrophilic oil agent, there is a tendency to suppress static electricity and optimize productivity in spinning steps.

聚丙烯系纖維B之纖維長度並無特別限定,較佳為24~75 mm,更佳為28~65 mm,進而較佳為32~54 mm,尤佳為34~48 mm。The fiber length of the polypropylene-based fiber B is not particularly limited, but is preferably 24-75 mm, more preferably 28-65 mm, further preferably 32-54 mm, and especially preferably 34-48 mm.

聚丙烯系纖維B之單絲纖維強度較佳為1.8~7.0 cN/dtex,更佳為2.0~6.0 cN/dtex,進而較佳為3.0~6.0 cN/dtex。若單絲纖維強度為1.8 cN/dtex以上,則即便受到加工纖維時之外力(例如紡織張力等),纖維亦不易斷裂。又,若單絲纖維強度為7.0 cN/dtex以下,則可獲得抗起毛球性更佳之纖維。The monofilament fiber strength of the polypropylene-based fiber B is preferably 1.8-7.0 cN/dtex, more preferably 2.0-6.0 cN/dtex, and still more preferably 3.0-6.0 cN/dtex. If the monofilament fiber strength is 1.8 cN/dtex or more, the fiber will not be easily broken even if it is subjected to an external force (such as textile tension, etc.) during fiber processing. Also, if the monofilament fiber strength is 7.0 cN/dtex or less, fibers with better pilling resistance can be obtained.

聚丙烯系纖維B之伸度較佳為5~70%,更佳為10~40%。若伸度為5~70%,則可獲得質地柔軟之纖維。The elongation of the polypropylene fiber B is preferably 5-70%, more preferably 10-40%. If the elongation is 5~70%, the fiber with soft texture can be obtained.

紡織線B亦可包含聚丙烯系纖維B以外之其他纖維。其他纖維並無特別限定,例如可列舉:聚丙烯系纖維B以外之聚烯烴系纖維、丙烯酸系纖維、聚酯纖維、尼龍纖維、乙酸酯纖維、丙烯酸酯纖維、乙烯-乙烯醇系纖維及胺基甲酸酯纖維等合成纖維,或絹纖維、絨(wool)纖維、開司米山羊毛纖維、棉(cotton)纖維、麻纖維等天然纖維,嫘縈纖維、銅氨纖維、溶劑紡絲纖維素纖維等再生纖維等。紡織線B根據用途及目的等可適當包含50質量%以下之其他纖維。紡織線B可包含5質量%以上之聚丙烯系纖維B、95質量%以下之聚丙烯系纖維B以外之其他聚丙烯系纖維。就輕量性及保溫性之觀點而言,紡織線B較佳為包含合計50質量%以上之聚丙烯系纖維B與其他聚丙烯系纖維,更佳為包含70質量%以上,進而較佳為包含80質量%以上,進而更佳為包含90質量%以上,尤佳為100質量%由聚丙烯系纖維B與其他聚丙烯系纖維構成。The spun yarn B may contain fibers other than the polypropylene-based fiber B. Other fibers are not particularly limited, and examples thereof include polyolefin fibers other than polypropylene fibers B, acrylic fibers, polyester fibers, nylon fibers, acetate fibers, acrylic fibers, ethylene-vinyl alcohol fibers, and Synthetic fibers such as urethane fibers, or natural fibers such as silk fibers, wool fibers, cashmere goat hair fibers, cotton fibers, and hemp fibers, rayon fibers, cupro fibers, and solvent-spun cellulose Regenerated fibers such as fibers, etc. The spun thread B may appropriately contain other fibers of not more than 50% by mass depending on the use and purpose. The spun yarn B may contain 5% by mass or more of polypropylene-based fibers B and 95% by mass or less of polypropylene-based fibers other than polypropylene-based fibers B. From the viewpoint of lightness and heat retention, the spun yarn B preferably contains a total of 50% by mass or more of polypropylene-based fibers B and other polypropylene-based fibers, more preferably contains 70% by mass or more, and is still more preferably It contains 80% by mass or more, more preferably contains 90% by mass or more, and most preferably 100% by mass is composed of polypropylene-based fiber B and other polypropylene-based fibers.

於將紡織線B設為混合有合計90質量%以上之聚丙烯系纖維B與其他聚丙烯系纖維之紗線(混紡線)之情形時,相對於該合計而言之聚丙烯系纖維B之含量較佳為5質量%以上。更佳為30質量%以上,進而更佳為50質量%以上。若聚丙烯系纖維B處於上述範圍,則抑制於紡織步驟中產生靜電,因此有優化生產性之傾向。When the spun yarn B is a yarn (blended yarn) in which polypropylene-based fibers B and other polypropylene-based fibers are mixed in a total of 90% by mass or more, the percentage of polypropylene-based fibers B relative to the total The content is preferably at least 5% by mass. More preferably, it is 30 mass % or more, More preferably, it is 50 mass % or more. When the polypropylene-based fiber B is within the above-mentioned range, the generation of static electricity in the spinning step is suppressed, and thus productivity tends to be optimized.

聚丙烯系纖維B及其他纖維並無特別限定,例如單絲纖維纖度可為0.1~100 dtex。於將紡織線B用於衣料之情形時,聚丙烯系纖維B及其他纖維之單絲纖維纖度較佳為0.4~5 dtex,更佳為0.5~3.5 dtex,進而較佳為0.6~2.5 dtex。於將紡織線B用於工業材料之情形時,單絲纖維纖度較佳為5~50 dtex。聚丙烯系纖維B及其他纖維之纖維長度較佳為24~75 mm。The polypropylene-based fiber B and other fibers are not particularly limited, for example, the fineness of the monofilament fiber may be 0.1-100 dtex. When the textile thread B is used for clothing, the monofilament fineness of the polypropylene fiber B and other fibers is preferably 0.4-5 dtex, more preferably 0.5-3.5 dtex, and still more preferably 0.6-2.5 dtex. When the textile thread B is used for industrial materials, the fineness of the monofilament fiber is preferably 5-50 dtex. The fiber length of the polypropylene-based fiber B and other fibers is preferably 24-75 mm.

於將紡織線B用於衣料之情形時,在設為僅由聚丙烯系纖維B與其他聚丙烯系纖維構成之紗線(混紡線)之情況下,聚丙烯系纖維B與其他聚丙烯系纖維之平均纖度較佳為0.8~2.2 dtex。更佳為1.2~2.0 dtex。若平均纖度處於上述範圍,則有紡織步驟中之生產性與質地變得良好之傾向。 上述平均纖度之計算如下所示。 平均纖度(dtex)=(聚丙烯系纖維B之纖度×混紡率)+(其他聚丙烯系纖維之纖度×混紡率)In the case of using spun yarn B for clothing, in the case of a yarn (blend yarn) composed only of polypropylene-based fiber B and other polypropylene-based fibers, polypropylene-based fiber B and other polypropylene-based fibers The average fineness of the fiber is preferably 0.8~2.2 dtex. More preferably 1.2~2.0 dtex. When the average fineness is within the above-mentioned range, the productivity and texture in the spinning process tend to be good. The calculation of the above-mentioned average fineness is as follows. Average fineness (dtex) = (fineness of polypropylene fiber B × blending ratio) + (denier of other polypropylene fibers × blending ratio)

紡織線B之支數並無特別限定,以英式棉紗支數計可為5~100S之範圍,較佳為10~90S,更佳為15~85S,進而較佳為20~80S。The count of the textile thread B is not particularly limited, but it can range from 5 to 100S, preferably 10 to 90S, more preferably 15 to 85S, and more preferably 20 to 80S in terms of British cotton yarn count.

紡織線B較佳為由兩股纖維束構成之撚合線。是否為由兩股纖維束構成之撚合線可藉由將紡織線向加撚方向之反方向進行扭轉而解撚時是否分解為兩股纖維束來確認。若為由兩股纖維束構成之撚合線,則於將各纖維束併紗、加撚時亦分別對每股纖維束施加鬆撚,因此抑制於製成紡織線時產生細毛,製成布帛時之起毛球性顯著改善。又,由於自各股粗紗變為經牽伸之纖維束相互交撚之狀態,故纖維束與纖維束相互纏繞(纖維束彼此交聯)程度改善,藉此製成布帛時之起毛球性顯著改善。由兩股纖維束構成之撚合線可藉由下述賽絡緊密紡而製造。The textile thread B is preferably a twisted thread composed of two fiber bundles. Whether it is a twisted yarn composed of two fiber bundles can be confirmed by twisting the textile yarn in the opposite direction to the twisting direction and whether it is decomposed into two fiber bundles when untwisting. In the case of a twisted yarn composed of two fiber bundles, when the fiber bundles are combined and twisted, loose twist is also applied to each fiber bundle, so that it is suppressed to produce fine hair when it is made into a textile yarn, and it is made into a cloth. Significant improvement in pilling. In addition, since each roving becomes a state in which the drawn fiber bundles are intertwined with each other, the degree of intertwining between fiber bundles (fiber bundles are cross-linked) is improved, and the pilling property of fabrics is significantly improved. A twisted yarn consisting of two fiber bundles can be produced by siro compact spinning as described below.

紡織線B之紡織方法並無特別限定,可藉由在環錠法中按照如下所述之步驟進行精紡而製作。預先準備至少一股包含5質量%以上之聚丙烯系纖維B之粗紗B,向牽伸區供給含有至少一股粗紗B之兩股粗紗進行牽伸後,一面併紗一面向撚線區供給,利用空氣沿粗紗之行進方向抽吸剛供給至撚線區後之兩股粗紗而使纖維收攏後進行撚線,藉此可獲得紡織線B(賽絡緊密線)。於賽絡緊密紡中,藉由將撚係數調整至2.4~6.0之範圍,容易獲得具有上述規定之細毛數及氣孔率之紡織線,可提高布帛之抗起毛球性。就布帛之抗起毛球性及柔軟之質地之觀點而言,撚係數較佳為2.8~4.5,更佳為3.0~4.0。The spinning method of the spun yarn B is not particularly limited, and it can be produced by worsted spinning in the following steps in the ring spinning method. At least one roving B containing at least 5% by mass of polypropylene-based fiber B is prepared in advance, two rovings containing at least one roving B are supplied to the drafting zone for drafting, and one side is doubling and the other is supplied to the twisting zone. The two strands of roving immediately supplied to the twisting zone are sucked by air along the traveling direction of the roving to gather the fibers and then twist the yarn to obtain a textile yarn B (siro compact yarn). In siro compact spinning, by adjusting the twist coefficient to the range of 2.4~6.0, it is easy to obtain the textile yarn with the above-mentioned number of fine hairs and porosity, and the pilling resistance of the fabric can be improved. From the viewpoint of pilling resistance and soft texture of the fabric, the twist coefficient is preferably 2.8-4.5, more preferably 3.0-4.0.

上述兩股粗紗可均為粗紗B。或者可以使所獲得之紡織線B中之聚丙烯系纖維B之含量成為5質量%以上之方式適當組合使用粗紗B與其他粗紗。The above two rovings may both be roving B. Alternatively, the roving B and other rovings may be used in appropriate combination so that the content of the polypropylene-based fiber B in the obtained spun yarn B becomes 5% by mass or more.

(布帛) 布帛包含上述紡織線。布帛可為針織物,亦可為梭織物。就提高抗起毛球性之觀點而言,上述布帛較佳為包含50質量%以上之選自由紡織線A及紡織線B所組成之群中之一種以上之紡織線,更佳為包含75質量%以上,進而較佳為包含85質量%以上,進而更佳為包含95質量%以上,尤佳為100質量%由上述紡織線構成。上述布帛可於所損本發明之效果之範圍內包含紡織線A及紡織線B以外之其他紗線,例如紡織線及/或長絲線。再者,上述布帛可為單層構造,亦可包括兩層以上之層。(cloth) The cloth includes the above-mentioned textile threads. Cloth can be knitted or woven. From the viewpoint of improving the pilling resistance, the above-mentioned fabric preferably contains 50% by mass or more of one or more types of textile threads selected from the group consisting of Textile thread A and Textile thread B, more preferably contains 75% by mass The above, more preferably 85% by mass or more, still more preferably 95% by mass or more, and most preferably 100% by mass of the above-mentioned spun yarn. The aforementioned fabric may contain yarns other than the spun yarn A and the spun yarn B, such as spun yarns and/or filament yarns, within the range of impairing the effects of the present invention. Furthermore, the above-mentioned fabric may have a single-layer structure, or may include two or more layers.

上述布帛含有表面層與裏面層(肌側),表面層及/或裏面層較佳為包含選自由紡織線A及紡織線B所組成之群中之一種以上之紡織線。藉由包含選自由紡織線A及紡織線B所組成之群中之一種以上之紡織線,布帛之抗起毛球性提高。就進一步提高抗起毛球性之觀點而言,較佳為包含50質量%以上之選自由紡織線A及紡織線B所組成之群中之一種以上之紡織線,更佳為包含75質量%以上,進而較佳為包含85質量%以上,進而更佳為包含95質量%以上,尤佳為100質量%由上述紡織線構成。The above-mentioned fabric includes a surface layer and an inner layer (skin side), and the surface layer and/or the inner layer preferably contain one or more types of woven yarns selected from the group consisting of woven yarns A and B. By including at least one kind of spun yarn selected from the group consisting of spun yarn A and spun yarn B, the pilling resistance of the fabric improves. From the viewpoint of further improving the pilling resistance, it is preferable to contain at least 50% by mass of one or more textile threads selected from the group consisting of Textile Yarn A and Textile Yarn B, more preferably at least 75% by mass. , and more preferably contain 85% by mass or more, still more preferably contain 95% by mass or more, and most preferably 100% by mass are composed of the above-mentioned textile thread.

又,藉由上述表面層及/或裏面層包含選自由紡織線A及紡織線B所組成之群中之一種以上之紡織線、即包含作為疏水性纖維之聚丙烯系纖維,上述布帛之洗滌速乾性提高。又,若上述表面層及/裏面層含有包含經親水化之疏水性纖維即水分率為0.15質量%以上之聚丙烯系纖維B的紡織線B,則水分更容易擴散。In addition, since the surface layer and/or the back layer contain one or more textile threads selected from the group consisting of textile threads A and textile threads B, that is, polypropylene-based fibers as hydrophobic fibers, the washing of the above-mentioned cloth Quick drying is improved. In addition, if the above-mentioned surface layer and/or back layer contain spun yarns B made of hydrophilized hydrophobic fibers, that is, polypropylene-based fibers B with a moisture content of 0.15% by mass or more, moisture will diffuse more easily.

上述表面層及/或裏面層亦可包含選自由紡織線A及紡織線B所組成之群中之一種以上之紡織線以外之其他紗線。上述其他紗線可為紡織線、複絲及單絲之任意者,就保溫性或柔軟之質地之觀點較佳為紡織線。上述紡織線可藉由環錠法、自由端(open-end)法、束合法、交替撚線法、纏繞法、渦流法(MVS法)及無撚法等任意方法製造。又,亦可為於環錠法中對環錠精紡機導入緊密紡系統之緊密紡織。又,可使用單紗或賽絡線,亦可將多股撚合使用。上述其他紗線可由親水性纖維及/或疏水性纖維構成。The above-mentioned surface layer and/or inner layer may also contain other yarns other than one or more kinds of textile threads selected from the group consisting of textile threads A and B. The aforementioned other yarn may be any of woven yarn, multifilament, and monofilament, and is preferably woven yarn from the viewpoint of heat retention or soft texture. The above-mentioned spun yarn can be produced by any method such as the ring spinning method, the open-end method, the bundle method, the alternate twist method, the winding method, the eddy current method (MVS method), and the untwisted method. In addition, compact spinning in which a compact spinning system is introduced into a ring spinning machine in the ring spinning method may also be used. In addition, a single yarn or a twin yarn may be used, or a plurality of twisted yarns may be used. The above-mentioned other yarns may be composed of hydrophilic fibers and/or hydrophobic fibers.

作為上述疏水性纖維,可列舉水分率未達5質量%之纖維,例如:聚酯纖維、聚烯烴纖維、聚醯胺纖維、丙烯酸系纖維、氯乙烯系纖維等。作為聚酯纖維,例如可使用由選自聚對苯二甲酸乙二酯、聚對苯二甲酸丁二酯、聚對苯二甲酸丙二酯、聚萘二甲酸乙二酯、聚乳酸、聚丁二酸丁二酯及其共聚物等中之一種以上之聚酯系樹脂構成之纖維。作為聚烯烴纖維,例如可使用由選自聚丙烯、聚乙烯、聚丁烯-1及乙烯-丙烯共聚物中之一種以上之聚烯烴系樹脂構成之纖維。作為聚醯胺纖維,例如可使用由尼龍6或尼龍66之類的聚醯胺樹脂構成之纖維。Examples of the above-mentioned hydrophobic fibers include fibers having a moisture content of less than 5% by mass, such as polyester fibers, polyolefin fibers, polyamide fibers, acrylic fibers, vinyl chloride fibers, and the like. As the polyester fiber, for example, a fiber selected from polyethylene terephthalate, polybutylene terephthalate, polytrimethylene terephthalate, polyethylene naphthalate, polylactic acid, poly Fiber composed of one or more polyester resins among butylene succinate and its copolymers. As polyolefin fibers, for example, fibers composed of one or more polyolefin resins selected from polypropylene, polyethylene, polybutene-1, and ethylene-propylene copolymers can be used. As the polyamide fiber, for example, a fiber made of polyamide resin such as nylon 6 or nylon 66 can be used.

於使用上述疏水性纖維之情形時,就容易使水分擴散之觀點而言,較佳為使用水分率為0.5質量%以上且未達5.0質量%之經親水化處理之疏水性纖維。作為親水化處理,例如可列舉:電暈放電處理、磺化處理、接枝聚合處理、於纖維中混入親水化劑、以及藉由塗佈、附著、吸浸等方式賦予親水化劑及/或吸水劑。例如,作為針對聚酯纖維之親水化處理,可列舉:於染色步驟中使用聚酯用吸水加工劑進行同浴加工。When using the above-mentioned hydrophobic fiber, it is preferable to use a hydrophilic-treated hydrophobic fiber having a moisture content of 0.5% by mass or more and less than 5.0% by mass from the viewpoint of facilitating moisture diffusion. As the hydrophilization treatment, for example, corona discharge treatment, sulfonation treatment, graft polymerization treatment, mixing a hydrophilizing agent into the fiber, and imparting a hydrophilizing agent and/or Absorbent. For example, one-bath processing using a water-absorbing agent for polyester in the dyeing step is exemplified as the hydrophilization treatment for polyester fibers.

作為上述聚酯用吸水加工劑,例如可列舉:於聚酯上鍵結有聚乙二醇側鏈之化合物;由對苯二甲酸二甲酯、間苯二甲酸二甲酯及聚乙二醇構成之共聚合聚酯樹脂;由對苯二甲酸二甲酯及聚乙二醇構成之共聚合聚酯樹脂;由對苯二甲酸、己二酸、5-磺基間苯二甲酸及聚乙二醇構成之共聚合聚酯樹脂;由對苯二甲酸及/或間苯二甲酸、伸烷基二醇以及聚伸烷基二醇構成之嵌段共聚合聚酯樹脂等。作為聚酯用吸水加工劑之市售品,例如可列舉:NICEPOLE PR-99(日華化學公司製造)、NICEPOLE PRK-60(日華化學公司製造)、NICEPOLE PR-86E(日華化學公司製造)、SR1805M(高松油脂公司製造)、MEIKA FINISH SRM-65(明成化學公司製造)等。作為尼龍用吸水加工劑,例如可列舉:NICEPOLE PRN(日華化學公司製造)。Examples of the above-mentioned water-absorbing agent for polyester include: compounds having polyethylene glycol side chains bonded to polyester; dimethyl terephthalate, dimethyl isophthalate, and polyethylene glycol Copolymerized polyester resin composed of dimethyl terephthalate and polyethylene glycol; composed of terephthalic acid, adipic acid, 5-sulfoisophthalic acid and polyethylene glycol Copolymerized polyester resin composed of diol; block copolymerized polyester resin composed of terephthalic acid and/or isophthalic acid, alkylene glycol and polyalkylene glycol, etc. Examples of commercially available water-absorbing agents for polyester include NICEPOLE PR-99 (manufactured by Nichika Chemical Co., Ltd.), NICEPOLE PRK-60 (manufactured by Nichika Chemical Co., Ltd.), NICEPOLE PR-86E (manufactured by Nichika Chemical Co., Ltd. ), SR1805M (manufactured by Takamatsu Oil Co., Ltd.), MEIKA FINISH SRM-65 (manufactured by Meisei Chemical Co., Ltd.), etc. As a water absorption processing agent for nylon, NICEPOLE PRN (made by the Nikka Chemical Co., Ltd.) is mentioned, for example.

上述經親水化之疏水性纖維之親水化程度可藉由親水化處理後之疏水性纖維之水分率與疏水性纖維之公定水分率之差而特定。就容易獲得規定之吸液力之觀點而言,親水化程度之下限較佳為0.1質量%以上。更佳為0.2質量%以上。親水化程度之上限並無特別限定,由於即便親水化程度超過1.0質量%,水分之擴散性亦幾乎不變,故較佳為1.0質量%以下。The degree of hydrophilization of the above-mentioned hydrophilized hydrophobic fibers can be specified by the difference between the moisture content of the hydrophobic fibers after the hydrophilization treatment and the conventional moisture content of the hydrophobic fibers. The lower limit of the degree of hydrophilization is preferably 0.1% by mass or more from the viewpoint of easy acquisition of predetermined liquid absorption. More preferably, it is 0.2 mass % or more. The upper limit of the degree of hydrophilization is not particularly limited, but since the diffusibility of water hardly changes even if the degree of hydrophilization exceeds 1.0% by mass, it is preferably 1.0% by mass or less.

作為上述親水性纖維,可列舉水分率為5質量%以上之纖維,例如:紙漿、棉(cotton)、麻、絲綢及絨(wool)等天然纖維,黏液嫘縈、銅氨纖維及溶劑紡絲纖維素纖維等再生纖維素纖維,以及具有親水性之合成纖維等。就容易吸水擴散之觀點而言,親水性纖維更佳為經精練漂白之纖維素纖維。Examples of the above-mentioned hydrophilic fibers include fibers with a moisture content of 5% by mass or more, such as natural fibers such as pulp, cotton, hemp, silk, and wool, viscose rayon, cupro fibers, and solvent-spun fibers. Regenerated cellulose fibers such as cellulose fibers, and hydrophilic synthetic fibers, etc. From the viewpoint of easy water absorption and diffusion, the hydrophilic fiber is more preferably scoured and bleached cellulose fiber.

於上述其他紗線中,親水性纖維及/或疏水性纖維之單絲纖維纖度較佳為0.5~3.5 dtex,更佳為0.6~2.5 dtex。Among the other yarns mentioned above, the monofilament fineness of the hydrophilic fiber and/or the hydrophobic fiber is preferably 0.5-3.5 dtex, more preferably 0.6-2.5 dtex.

上述裏面層較佳為含有包含水分率為0.15質量%以上之聚丙烯系纖維B之紡織線B。藉由由包含水分率為0.15質量%以上之聚丙烯系纖維B之紡織線B構成作為肌側之裏面層,不僅裏面層之抗起毛球性提高,且有效利用聚丙烯系纖維之輕量性及保溫性而可提高布帛之吸水速乾性、尤其是洗滌後之吸水速乾性。就抗起毛球性、輕量性、保溫性及吸水速乾性之觀點而言,上述裏面層較佳為包含50質量%以上之紡織線B,更佳為包含75質量%以上,進而較佳為包含85質量%以上,進而更佳為包含95質量%以上,尤佳為100質量%由紡織線B構成。The above-mentioned back layer is preferably a spun yarn B containing polypropylene-based fibers B with a water content of 0.15% by mass or more. By constituting the inner layer on the muscle side with the spun yarn B containing the polypropylene fiber B with a moisture content of 0.15% by mass or more, not only the pilling resistance of the inner layer is improved, but also the lightness of the polypropylene fiber is effectively utilized It can improve the water absorption and quick-drying properties of fabrics, especially the water absorption and quick-drying properties after washing. From the standpoint of pilling resistance, light weight, heat retention and quick-drying properties, the above-mentioned inner layer preferably contains 50% by mass or more of the textile thread B, more preferably contains 75% by mass or more, and is still more preferably It contains 85 mass % or more, More preferably, it contains 95 mass % or more, Most preferably, 100 mass % is comprised from the textile thread B.

於構成上述裏面層之其他紗線為紡織線之情形時,紡織線之支數並無特別限定,以英式棉紗支數計可為5~100S之範圍,較佳為10~90S,更佳為15~85S,進而較佳為20~80S。構成上述紡織線之纖維之單絲纖維纖度較佳為0.4~20 dtex,更佳為0.5~3.5 dtex,進而較佳為0.6~2.5 dtex。構成上述紡織線之纖維之纖維長度較佳為24~75 mm。When the other yarns constituting the above-mentioned inner layer are textile threads, the count of the textile threads is not particularly limited, and it can be in the range of 5~100S, preferably 10~90S, more preferably in the English cotton yarn count 15~85S, and more preferably 20~80S. The monofilament fineness of the fibers constituting the above-mentioned textile yarn is preferably 0.4-20 dtex, more preferably 0.5-3.5 dtex, and still more preferably 0.6-2.5 dtex. The fiber length of the fibers constituting the above-mentioned textile thread is preferably 24-75 mm.

就輕量性、保溫性及吸水速乾性之觀點而言,構成上述裏面層之紡織線B較佳為包含30質量%以上之聚丙烯系纖維B,更佳為包含50質量%以上,進而較佳為包含70質量%以上。構成上述裏面層之紡織線B可僅由聚丙烯系纖維B構成,亦可包含其他纖維。聚丙烯系纖維B與其他纖維可藉由混紡、合紗、混織、併紗、交織等任意方法進行組合。From the viewpoints of lightness, heat retention, and quick-drying properties, the textile thread B constituting the inner layer preferably contains 30% by mass or more of polypropylene-based fibers B, more preferably 50% by mass or more, and more preferably Preferably, it contains 70% by mass or more. The woven yarn B constituting the above-mentioned inner layer may consist of only polypropylene-based fibers B, or may contain other fibers. The polypropylene-based fiber B and other fibers can be combined by any method such as blending, yarn joining, mixed weaving, doubling, and interweaving.

上述其他纖維並無特別限定,可適當使用合成纖維、天然纖維、再生纖維等。作為具體例,可列舉:聚丙烯系纖維B以外之聚烯烴纖維、丙烯酸系纖維、尼龍、聚酯系纖維、尼龍纖維、嫘縈纖維、銅氨纖維、乙酸酯纖維、乙烯-乙烯醇纖維、聚胺基甲酸酯纖維、棉(cotton)纖維、麻纖維、絹纖維、絨(wool)纖維及開司米山羊毛纖維等,可將上述多種纖維進行組合。其中,較佳為選自由聚丙烯系纖維B以外之聚丙烯纖維、聚酯系纖維、丙烯酸系纖維、聚胺基甲酸酯纖維及絨(wool)纖維所組成之群中之一種以上,更佳為選自由聚丙烯系纖維B以外之聚丙烯纖維、聚胺基甲酸酯纖維及聚酯系纖維所組成之群中之一種以上。藉由使用聚丙烯系纖維B以外之聚丙烯纖維,輕量性及保溫性變得良好。藉由使用聚胺基甲酸酯纖維,不僅賦予伸縮性,且降低透氣性,藉此可進一步提高保溫性。藉由使用聚酯系纖維,可提高速乾性。藉由使用丙烯酸系纖維,可提高保溫性及染色性。The above-mentioned other fibers are not particularly limited, and synthetic fibers, natural fibers, regenerated fibers, and the like can be suitably used. Specific examples include polyolefin fibers other than polypropylene fibers B, acrylic fibers, nylon, polyester fibers, nylon fibers, rayon fibers, cupro fibers, acetate fibers, and ethylene-vinyl alcohol fibers , polyurethane fiber, cotton (cotton) fiber, hemp fiber, silk fiber, velvet (wool) fiber and cashmere goat hair fiber, etc., the above-mentioned various fibers can be combined. Among them, it is preferably at least one selected from the group consisting of polypropylene fibers other than polypropylene fibers B, polyester fibers, acrylic fibers, polyurethane fibers, and wool fibers. Preferably, it is at least one kind selected from the group consisting of polypropylene fibers other than polypropylene-based fibers B, polyurethane fibers, and polyester-based fibers. By using a polypropylene fiber other than the polypropylene-based fiber B, lightness and heat retention become favorable. By using the polyurethane fiber, not only stretchability is imparted, but also air permeability is lowered, whereby heat retention can be further improved. Quick-drying properties can be improved by using polyester fibers. By using acrylic fibers, heat retention and dyeability can be improved.

構成上述裏面層之紡織線B根據目的等可包含70質量%以下之其他纖維。構成上述裏面層之紡織線B可包含30質量%以上之聚丙烯系纖維B、70質量%以下之聚丙烯系纖維B以外之其他聚丙烯系纖維。就輕量性及保溫性之觀點而言,構成上述裏面層之紡織線B較佳為包含合計30質量%以上之聚丙烯系纖維B與其他聚丙烯系纖維,更佳為包含50質量%以上。構成上述裏面層之紡織線B並無特別限定,例如可包含30~70質量%之聚酯纖維。又,構成上述裏面層之紡織線B並無特別限定,例如可包含1~10質量%之聚胺基甲酸酯纖維。The spun yarn B constituting the above-mentioned back layer may contain 70% by mass or less of other fibers depending on the purpose or the like. The woven yarn B constituting the above-mentioned inner layer may contain 30% by mass or more of polypropylene-based fibers B and 70% by mass or less of polypropylene-based fibers other than polypropylene-based fibers B. From the viewpoint of lightness and heat retention, the woven yarn B constituting the above-mentioned inner layer preferably contains a total of 30% by mass or more of polypropylene-based fibers B and other polypropylene-based fibers, more preferably 50% by mass or more . The woven yarn B constituting the inner layer is not particularly limited, and may contain, for example, 30 to 70% by mass of polyester fiber. Moreover, the woven yarn B which comprises the said back layer is not specifically limited, For example, it may contain the polyurethane fiber of 1-10 mass %.

於本發明之一種以上之實施形態中,在構成裏面層之紗線係由包含聚丙烯系纖維B之紡織線B構成之情形時,上述表面層較佳為由包含選自由水分率為0.5質量%以上且未達5.0質量%之疏水性纖維及水分率為5.0質量%以上之親水性纖維所組成之群中之至少一種纖維的紗線構成。可提高布帛之吸水速乾性、及洗滌後之吸水速乾性。In one or more embodiments of the present invention, when the yarn constituting the inner layer is composed of woven yarn B comprising polypropylene fiber B, the above-mentioned surface layer is preferably composed of fibers having a moisture content of 0.5 mass. % and less than 5.0% by mass of hydrophobic fibers and hydrophilic fibers with a moisture content of 5.0% by mass or more. It can improve the water absorption and quick-drying properties of fabrics and the water-absorbing and quick-drying properties after washing.

於其等實施形態中,就容易使水分擴散之觀點而言,表面層更佳為由包含經親水化之疏水性纖維之紗線構成。構成上述表面層之紗線較佳為包含30質量%以上之選自由經親水化之疏水性纖維及親水性纖維所組成之群中之至少一種纖維,更佳為包含50質量%以上,進而更佳為包含70質量%以上。例如,於欲獲得乾爽之表面層觸感之情形時,作為上述經親水化之疏水性纖維,就通用性之觀點而言較佳為使用聚酯纖維。構成上述表面層之紗線較佳為包含30質量%以上之聚酯纖維,更佳為包含70質量%以上之聚酯纖維。In these embodiments, it is more preferable that the surface layer is composed of a yarn containing hydrophilized hydrophobic fibers from the viewpoint of easily diffusing moisture. The yarn constituting the surface layer preferably contains at least 30% by mass of at least one fiber selected from the group consisting of hydrophilized hydrophobic fibers and hydrophilic fibers, more preferably contains 50% by mass or more, and more preferably Preferably, it contains 70% by mass or more. For example, when it is desired to obtain a dry touch of the surface layer, it is preferable to use polyester fibers as the above-mentioned hydrophilized hydrophobic fibers from the viewpoint of versatility. The yarn constituting the above-mentioned surface layer preferably contains 30% by mass or more of polyester fiber, more preferably contains 70% by mass or more of polyester fiber.

於其等實施形態中,構成表面層之紗線可為紡織線、複絲及單絲之任意者,就柔軟之質地之觀點而言較佳為複絲。於構成上述表面層之紗線中,疏水性纖維及/或疏水性纖維之單絲纖維纖度較佳為0.4~20 dtex,更佳為0.5~3.5 dtex,進而較佳為0.6~2.5 dtex。In these embodiments, the yarn constituting the surface layer may be any of woven yarn, multifilament and monofilament, and is preferably a multifilament from the viewpoint of soft texture. In the yarns constituting the above surface layer, the hydrophobic fiber and/or the monofilament fineness of the hydrophobic fiber is preferably 0.4-20 dtex, more preferably 0.5-3.5 dtex, further preferably 0.6-2.5 dtex.

於其等實施形態中,較佳為將構成裏面層之紡織線B與構成表面層之紗線進行梭織或針織,且使構成裏面層之紡織線B朝向表面層而至少露出一部分。水分自作為肌膚接觸面之裏面層向表面層之移動變快,吸水速乾性提高。In these embodiments, it is preferable to weave or knit the woven yarns B constituting the inner layer and the yarns constituting the surface layer, and expose at least a part of the woven threads B constituting the inner layer toward the surface layer. Moisture moves from the inner layer to the surface layer as the skin contact surface faster, and the water absorption and quick-drying properties are improved.

上述布帛可為具有雙層構造以上之多層構造之針織物,亦可為具有雙層構造以上之多層構造之梭織物。於針織物之情形時,可為單面針織、或者以表裏面不同素材之方式進行變形針織之添紗組織平針或網眼編織,可列舉:雙面針織中之平滑針織、瓦楞針織,作為雙面針織之變化組織之多步驟雙面針織之單面蜂巢針織等。於梭織物之情形時,可列舉:雙層梭織或單層梭織之緞紋梭織、3/1斜紋梭織等。尤佳為具有由雙面針織之單面蜂巢之組織構成之雙層構造之針織物。此時,較佳為由蜂巢面構成裏面層。The above-mentioned fabric may be a knitted fabric having a multi-layer structure of more than double layer structure, or may be a woven fabric having a multi-layer structure of more than double layer structure. In the case of knitted fabrics, it can be single-sided knitting, or plain stitch or mesh knitting with textured knitting of different materials on the front and back. Examples include: smooth knitting and corrugated knitting in double-sided knitting, as double-sided knitting. One-side honeycomb knitting, multi-step double-side knitting, single-side honeycomb knitting, etc. In the case of woven fabrics, examples include satin weave, 3/1 twill weave, etc. of double-layer weave or single-layer weave. Especially preferred is a knitted fabric having a double-layered structure consisting of a double-knit single-jersey honeycomb structure. In this case, it is preferable that the inner layer is constituted by a honeycomb surface.

又,上述布帛可為保溫性、吸水性及伸縮性優異之汗布,汗布之裏面層(裏料)可為裏毛或裏起毛。藉由使表面層為包含選自由紡織線A及紡織線B所組成之群中之一種以上之紡織線之平紋針織(天竺編織),汗布之抗起毛球性及洗滌乾燥性提高。又,於汗布係由表層紗線、中層紗線及裏層紗線構成之情形時,藉由使用選自由紡織線A及紡織線B所組成之群中之一種以上之紡織線作為表層紗線、中層紗線,抗起毛球性及洗滌乾燥性進一步提高。In addition, the above-mentioned fabric may be jersey excellent in heat retention, water absorption, and stretchability, and the inner layer (lining) of the jersey may be inner pile or inner nap. By making the surface layer a plain weave (Tianzhu weave) containing one or more textile threads selected from the group consisting of the textile threads A and B, the pilling resistance and the washing and drying properties of the single jersey are improved. Also, when the jersey is composed of surface yarns, middle yarns, and back yarns, by using one or more textile threads selected from the group consisting of textile threads A and textile threads B as the surface layer yarns Thread, middle layer yarn, anti-pilling and washing drying properties are further improved.

上述布帛可於精練步驟之後進行染色加工,可於精加工時併用吸水加工、去污(SR,Soil release)加工、抗菌加工、防靜電加工等。The above-mentioned fabrics can be dyed after the scouring step, and water absorption, soil release (SR, Soil release) processing, antibacterial processing, antistatic processing, etc. can be used in the finishing process.

上述布帛可藉由例如以下之方法製造。 <布帛之製造方法1> 包括如下步驟:準備包含疏水性纖維之紗線(亦稱為紗線m); 準備紡織線B; 以由紗線m構成表面層、由紡織線B構成裏面層之方式進行梭織或針織而製作布料;以及 於選自由精練步驟及染色步驟所組成之群中之至少一種加工之基礎上進而實施吸水加工,對構成表面層之疏水性纖維實施加工以使水分率成為0.5質量%以上。The said fabric can be manufactured by the following method, for example. <How to make fabric 1> comprising the steps of: preparing a yarn comprising hydrophobic fibers (also referred to as yarn m); Prepare spinning thread B; Cloth is produced by weaving or knitting in such a way that the outer layer is formed of yarn m and the inner layer is formed by textile thread B; and At least one process selected from the group consisting of a scouring process and a dyeing process is further subjected to water absorption processing, and the hydrophobic fibers constituting the surface layer are processed so that the moisture content becomes 0.5% by mass or more.

<布帛之製造方法2> 包括如下步驟:準備包含親水性纖維之紗線(亦稱為紗線n); 準備紡織線B; 以由紗線n構成表面層、由紡織線B構成裏面層之方式進行梭織或針織而製作布料;以及 實施選自由精練步驟、漂白步驟(僅針對棉、麻等天然纖維素纖維)、染色步驟及精加工步驟(柔軟加工)所組成之群中之至少一種加工。<How to make fabric 2> comprising the steps of: preparing a yarn comprising hydrophilic fibers (also referred to as yarn n); Prepare spinning thread B; Cloth is produced by weaving or knitting in such a way that the outer layer is formed of yarn n and the inner layer is formed of textile thread B; and At least one process selected from the group consisting of scouring, bleaching (only for natural cellulose fibers such as cotton and hemp), dyeing, and finishing (softening) is performed.

就吸水速乾性較高之觀點而言,上述布帛較佳為於蒸散性(II)試驗(依據紡檢(BOKEN)規格BQE A 028)中之蒸散率於試驗開始20分鐘後達30%以上。蒸散性(II)試驗係綜合評價吸水性與速乾性兩者之試驗,蒸散率具體而言按照下文記述之方法測定。From the standpoint of high water absorption and quick-drying properties, the above-mentioned fabric preferably has an evaporation rate of 30% or more in the evapotranspiration (II) test (according to BOKEN specification BQE A 028) 20 minutes after the start of the test. The evapotranspiration (II) test is a test for comprehensively evaluating both water absorption and quick-drying properties. Specifically, the evapotranspiration rate is measured according to the method described below.

或者就吸水速乾性較高之觀點而言,上述布帛較佳為依據ISO17617(2014)水分乾燥速率測定(Determination of moisture drying rate)(方法B-水平乾燥(Method B-Horizontal drying))測定之乾燥時間(Drying time)(蒸散率達到100%之時間)為45分鐘以下。 ISO17617之測定方法與上述蒸散性(II)試驗相同,求出相對於自剛滴下後起至蒸散率達到90%為止之最短時間的蒸散率之回歸直線。 y=ax+b[y:蒸散率(%)、a:斜率、x:時間、b:截距] 由根據回歸直線所獲得之數值,算出乾燥時間(Drying time)(蒸散率達到100%之時間)。 乾燥速率(Drying rate)(%/min)=a 乾燥時間(Drying time)(100%)=(100-b)/aAlternatively, from the standpoint of high water absorption and quick-drying properties, the above-mentioned fabric is preferably dried according to ISO17617 (2014) Determination of moisture drying rate (Method B-Horizontal drying) Drying time (the time for the evapotranspiration rate to reach 100%) is less than 45 minutes. The measurement method of ISO17617 is the same as the above-mentioned evapotranspiration (II) test, and the regression line of the evapotranspiration rate relative to the shortest time from immediately after dropping until the evapotranspiration rate reaches 90% is obtained. y=ax+b[y: evapotranspiration rate (%), a: slope, x: time, b: intercept] Calculate the drying time (the time when the evapotranspiration rate reaches 100%) from the value obtained from the regression line. Drying rate (Drying rate) (%/min) = a Drying time (100%)=(100-b)/a

就洗滌後之吸水速乾性較高之觀點而言,上述布帛較佳為經過10次洗滌後於蒸散性(I)試驗(依據紡檢規格BQE A 006)中之蒸散率於試驗開始30分鐘後達20%以上。蒸散性(II)試驗係綜合評價吸水性與速乾性兩者之試驗,蒸散率具體而言按照下文記述之方法測定。From the viewpoint of high water absorption and quick-drying after washing, the above-mentioned fabric is preferably 30 minutes after the start of the test in the evapotranspiration (I) test (according to the textile inspection specification BQE A 006) after 10 washes. Up to 20% or more. The evapotranspiration (II) test is a test for comprehensively evaluating both water absorption and quick-drying properties. Specifically, the evapotranspiration rate is measured according to the method described below.

上述布帛、或者上述布帛之裏面層及/或表面層依據JIS L 1076 A法,使用ICI型試驗機測定之抗起毛球性較佳為3級以上,更佳為3.5級以上,進而較佳為4級以上。The above-mentioned fabric, or the inner layer and/or surface layer of the above-mentioned fabric has a pilling resistance measured by an ICI-type testing machine in accordance with JIS L 1076 A method, preferably at least grade 3, more preferably at least grade 3.5, and even more preferably at least grade 3.5. Level 4 and above.

於本發明之一種以上之實施形態中,上述布帛為由表面層、裏面層、及連結其等之接結線所構成之衣料用織物,較佳為選自由表面層及裏面層所組成之群中之一種以上之層包含選自由紡織線A及紡織線B所組成之群中之一種以上之紡織線。上述衣料用織物藉由包含選自由紡織線A及紡織線B所組成之群中之一種以上之紡織線,抗起毛球性提高。就進一步提高抗起毛球性之觀點而言,較佳為包含50質量%以上之選自由紡織線A及紡織線B所組成之群中之一種以上之紡織線,更佳為包含75質量%以上,進而較佳為包含85質量%以上,進而更佳為包含95質量%以上,尤佳為100質量%由上述紡織線構成。In one or more embodiments of the present invention, the above-mentioned fabric is a clothing fabric composed of a surface layer, a back layer, and a binding thread connecting them, preferably selected from the group consisting of the surface layer and the back layer. One or more layers include one or more textile threads selected from the group consisting of textile threads A and textile threads B. The aforementioned fabric for clothing includes one or more kinds of textile yarns selected from the group consisting of the textile yarns A and B, so that pilling resistance is improved. From the viewpoint of further improving the pilling resistance, it is preferable to contain at least 50% by mass of one or more textile threads selected from the group consisting of Textile Yarn A and Textile Yarn B, more preferably at least 75% by mass. , and more preferably contain 85% by mass or more, still more preferably contain 95% by mass or more, and most preferably 100% by mass are composed of the above-mentioned textile thread.

上述衣料用織物中,表面層及裏面層可設為分別與上述含有表面層及裏面層之布帛中之表面層及裏面層相同之構成。In the above fabric for clothing, the surface layer and the back layer may have the same configurations as those of the above-mentioned fabric including the surface layer and the back layer.

上述接結線包含纖度為10~220 dtex之單絲。藉此,接結線不會老化,織物兼備厚度與輕量性。就老化及質地之觀點而言,上述單絲之纖度較佳為10~110 dtex,更佳為20~50 dtex。The above-mentioned binding thread includes monofilament with a fineness of 10-220 dtex. In this way, the binding thread will not deteriorate, and the fabric has both thickness and lightness. From the viewpoint of aging and texture, the fineness of the above monofilament is preferably 10-110 dtex, more preferably 20-50 dtex.

上述接結線可為單獨使用上述單絲者,亦可為將上述單絲與複絲或紡織線進行併紗後插入織成者,亦可為交織而成者。就對織物同時賦予厚度與輕量性之觀點而言,接結線較佳為僅由上述單絲構成。The above-mentioned binding yarn may be obtained by using the above-mentioned monofilament alone, or may be obtained by doubling the above-mentioned monofilament and multifilament or a spun yarn, and inserting and weaving, or may be interlaced. From the viewpoint of simultaneously imparting thickness and lightness to the fabric, the binding thread is preferably composed of only the above-mentioned monofilaments.

構成上述接結線之纖維並無特別限定,就洗滌速乾性之觀點而言,較佳為疏水性纖維。疏水性纖維並無特別限定,例如可列舉:聚酯纖維、聚丙烯纖維B以外之聚烯烴纖維、聚醯胺纖維、丙烯酸系纖維、氯乙烯系纖維等。作為聚酯纖維,例如可使用由選自聚對苯二甲酸乙二酯、聚對苯二甲酸丁二酯、聚對苯二甲酸丙二酯、聚萘二甲酸乙二酯、聚乳酸、聚丁二酸丁二酯及其共聚物等中之一種以上之聚酯系樹脂構成之纖維。作為聚烯烴纖維,例如可使用由選自聚丙烯、聚乙烯、聚丁烯-1及乙烯-丙烯共聚物中之一種以上之聚烯烴系樹脂構成之纖維。作為聚醯胺纖維,例如可使用由尼龍6或尼龍66之類的聚醯胺樹脂構成之纖維。就洗滌速乾性之觀點而言,構成上述接結線之纖維較佳為聚酯纖維。The fiber constituting the above-mentioned binding thread is not particularly limited, but it is preferably a hydrophobic fiber from the viewpoint of washing quick-drying property. Hydrophobic fiber is not specifically limited, For example, polyester fiber, polyolefin fiber other than polypropylene fiber B, polyamide fiber, acrylic fiber, vinyl chloride fiber etc. are mentioned. As the polyester fiber, for example, a fiber selected from polyethylene terephthalate, polybutylene terephthalate, polytrimethylene terephthalate, polyethylene naphthalate, polylactic acid, poly Fiber composed of one or more polyester resins among butylene succinate and its copolymers. As polyolefin fibers, for example, fibers composed of one or more polyolefin resins selected from polypropylene, polyethylene, polybutene-1, and ethylene-propylene copolymers can be used. As the polyamide fiber, for example, a fiber made of polyamide resin such as nylon 6 or nylon 66 can be used. From the viewpoint of washing quick-drying properties, the fibers constituting the above-mentioned binding thread are preferably polyester fibers.

上述衣料用織物只要為由表面層、裏面層(肌側)、及連結其等之接結線所構成之組織,則並無特別限定,較佳為採用不同組織織成表面層及裏面層、或者採用裏面層為疏織且表面層為密織之疏密構造。又,上述衣料用織物無需於橫方向上所見之該織物之截面形狀中一定要能夠明確地確認到三層構造,但較佳為採用雙面(double face)織或瓦楞織。藉由採用其等織法,可包含較多空氣層而優化保溫性,從而較佳。此處,將內層與外層之編織組織不同者稱為雙面織,將內層與外層之編織組織相同、且空間部具有空氣層者稱為瓦楞織。The above-mentioned fabric for clothing is not particularly limited as long as it is composed of the surface layer, the back layer (muscle side), and the binding thread connecting them. It is preferable to use different textures to weave the surface layer and the back layer, or It adopts a density structure in which the inner layer is open weave and the surface layer is dense weave. In addition, the above-mentioned fabric for clothing does not necessarily have to be able to clearly recognize the three-layer structure in the cross-sectional shape of the fabric seen in the transverse direction, but it is preferable to use a double-face (double face) weave or a corrugated weave. By using other weaving methods, more air layers can be included to optimize heat retention, which is better. Here, the weaving structure of the inner layer and the outer layer is called double weave, and the weaving structure of the inner layer and the outer layer is the same, and the space part has an air layer is called corrugated weave.

上述衣料用織物可於精練步驟加工後進行染色加工,可於精加工時併用吸水加工、去污(SR,Soil release)加工、抗菌加工、防靜電加工等。The above fabrics for clothing can be dyed after the scouring process, and can be combined with water absorption, SR (Soil release) processing, antibacterial processing, antistatic processing, etc. during the finishing process.

就洗滌速乾性較高之觀點而言,上述衣料用織物依據紡檢規格BQE A 024-2016,藉由以下試驗方法測定之90分鐘後之乾燥率較佳為40%以上,更佳為45%以上。具體之測定方法參照下文之記述。From the point of view of high washing quick-drying, the drying rate of the above-mentioned clothing fabrics according to the textile inspection specification BQE A 024-2016, measured by the following test method after 90 minutes, is preferably 40% or more, more preferably 45% above. For the specific measurement method, refer to the description below.

就保溫性較高之觀點而言,上述衣料用織物使用加多技術公司(Kato Tech Co.,Ltd.)製造之THERMOLAB 2藉由乾接觸(dry contact)法測定之保溫率較佳為40.5%以上,更佳為41.0%以上。具體之測定方法參照下文之記述。From the point of view of high thermal insulation, the thermal insulation rate of the above-mentioned clothing fabrics measured by the dry contact (dry contact) method using THERMOLAB 2 manufactured by Kato Tech Co., Ltd. is preferably 40.5%. Above, more preferably above 41.0%. For the specific measurement method, refer to the description below.

就吸水性及洗滌乾燥性優異之觀點而言,上述衣料用織物藉由JIS L 1907滴下法測定之吸水時間較佳為30秒以下,更佳為20秒以下,進而較佳為15秒以下。From the viewpoint of excellent water absorption and washing and drying properties, the water absorption time of the clothing fabric as measured by the JIS L 1907 dropping method is preferably 30 seconds or less, more preferably 20 seconds or less, and still more preferably 15 seconds or less.

上述衣料用織物之裏面層及/或表面層依據JIS L 1076 A法,使用ICI型試驗機測定之抗起毛球性較佳為3級以上,更佳為3.5級以上,進而較佳為4級以上。The inner layer and/or surface layer of the above-mentioned fabrics for clothing use JIS L 1076 A method, and the pilling resistance measured by ICI-type testing machine is preferably grade 3 or higher, more preferably grade 3.5 or higher, and more preferably grade 4 above.

於本發明之一種以上之實施形態中,布帛並無特別限定,就輕量性等穿著性之觀點而言,例如單位面積重量較佳為450 g/m2 以下,更佳為400 g/m2 以下,進而較佳為300 g/m2 以下,尤佳為200 g/m2 以下。又,上述布帛並無特別限定,就保溫性等觀點而言,單位面積重量較佳為50 g/m2 以上。In one or more embodiments of the present invention, the fabric is not particularly limited, but from the viewpoint of wearability such as light weight, for example, the weight per unit area is preferably 450 g/ m2 or less, more preferably 400 g/m2 2 or less, more preferably 300 g/m 2 or less, especially preferably 200 g/m 2 or less. Also, the above-mentioned fabric is not particularly limited, and the weight per unit area is preferably 50 g/m 2 or more from the viewpoint of heat retention and the like.

又,上述布帛並無特別限定,厚度較佳為4.0 mm以下,更佳為3.5 mm以下,進而較佳為2.5 mm以下,尤佳為1.5 mm以下。又,上述布帛並無特別限定,厚度較佳為0.5 mm以上。Also, the above-mentioned fabric is not particularly limited, but the thickness is preferably 4.0 mm or less, more preferably 3.5 mm or less, still more preferably 2.5 mm or less, especially preferably 1.5 mm or less. Also, the above-mentioned fabric is not particularly limited, but the thickness is preferably 0.5 mm or more.

上述布帛可用於衣料或工業基材等。作為衣料,例如可列舉:內衣、內褲、襯衣(shirt)、套衫(jumper)、毛衣(sweater)、短褲、訓練服(training wear)、緊身衣(tights)、纏腰帶、圍巾、帽子、手套、襪子、耳罩等。作為工業基材,例如可列舉:地毯、寢具、傢俱等。The above-mentioned fabric can be used for clothing, industrial substrates, and the like. Examples of clothing materials include underwear, panties, shirts, jumpers, sweaters, shorts, training wear, tights, loincloths, scarves, hats, gloves, Socks, earmuffs, etc. As an industrial base material, a carpet, bedding, furniture, etc. are mentioned, for example.

以下使用圖式進行說明。圖1係本發明之一實施形態中使用之一例之環錠精紡機之局部立體圖。Hereinafter, it demonstrates using a figure. Fig. 1 is a partial perspective view of an example of a ring spinning machine used in an embodiment of the present invention.

將兩股粗紗1a、1b經由導紗桿(guide bar)101及喇叭環(trumpet)102而並列地供給至由後輥(back roller)103、中輥(middle roller)104、皮圈(apron)105及前輥(front roller)106構成之牽伸區,一面平行牽伸一面向撚線區供給。使用由空氣抽吸部107、透氣皮圈108、旋轉輥109及輔助輥110構成之集束裝置,利用空氣沿粗紗之行進方向抽吸剛供給至撚線區後之兩股經牽伸之粗紗(纖維束)2a、2b而使纖維收攏後,經由導紗鉤(snail wire)111、鋼絲圈(traveller)112及環(ring)113進行撚線而獲得紡織線(賽絡緊密線)10。Two strands of roving 1a, 1b are supplied in parallel via a guide bar 101 and a trumpet 102 to a back roller 103, a middle roller 104, and an apron. 105 and the draft zone that front roller (front roller) 106 constitutes, one side parallel drafts one side and supplies to twisting zone. Using the converging device composed of the air suction part 107, the breathable apron 108, the rotating roller 109 and the auxiliary roller 110, the two drafted rovings (fibers) just supplied to the twisting area are sucked by air along the traveling direction of the roving. Bundle) 2a, 2b to gather the fibers, and twist through a snail wire 111 , a traveler 112 , and a ring 113 to obtain a spun yarn (siro compacted yarn) 10 .

於製作紡織線A之情形時,粗紗1a、1b可均為粗紗A。或者可為:粗紗1a及1b之一者為粗紗A,粗紗1a及1b之另一者為將所獲得之紡織線A中之聚丙烯系纖維A之含量調整至大於50質量%之其他粗紗。In the case of producing the spun yarn A, the rovings 1a and 1b may both be rovings A. Alternatively, one of the rovings 1a and 1b may be the roving A, and the other of the rovings 1a and 1b may be another roving in which the content of the polypropylene-based fiber A in the obtained spun yarn A is adjusted to more than 50% by mass.

於製作紡織線B之情形時,粗紗1a、1b可均為粗紗B。或者可為:粗紗1a及1b之一者為粗紗B,粗紗1a及1b之另一者為將所獲得之紡織線B中之聚丙烯系纖維B之含量調整至5質量%以上之其他粗紗。In the case of producing the spun yarn B, the rovings 1a and 1b may both be rovings B. Alternatively, one of the rovings 1a and 1b may be the roving B, and the other of the rovings 1a and 1b may be another roving in which the content of the polypropylene-based fiber B in the obtained spun yarn B is adjusted to 5% by mass or more.

圖2係本發明之一實施形態中使用之擠出機之示意性說明圖。該擠出機201係由原料供給口202、樹脂熔融部203、混練分散部204、減壓管線205、擠出部206及取出部207構成。首先,自樹脂熔融部203之原料供給口202供給聚合物(能夠加熱熔融之基礎樹脂)與親水性成分(液狀)或視需要溶解於水之親水性成分。供給前可預先將兩者進行混合。繼而,送至混練分散部204,於混練分散部204中有複數片旋轉之混練板,於此處將聚合物與溶解於水之親水性成分均勻混合。繼而,自減壓管線205將水分以水蒸氣之狀態去除。繼而,自擠出部206擠出樹脂組成物,加以冷卻,自取出部207取出,若冷卻後進行切割則成為顆粒狀之樹脂組成物(一次加工樹脂)。 實施例Fig. 2 is a schematic explanatory diagram of an extruder used in one embodiment of the present invention. The extruder 201 is composed of a raw material supply port 202 , a resin melting part 203 , a kneading and dispersing part 204 , a decompression line 205 , an extruding part 206 and a taking out part 207 . First, a polymer (base resin that can be heated and melted) and a hydrophilic component (liquid) or a hydrophilic component dissolved in water are supplied from the raw material supply port 202 of the resin melting part 203 . Both may be previously mixed before supplying. Then, it is sent to the kneading and dispersing section 204, where there are a plurality of rotating kneading plates, where the polymer and the hydrophilic component dissolved in water are evenly mixed. Then, the moisture is removed from the decompression line 205 in the state of water vapor. Next, the resin composition is extruded from the extrusion part 206, cooled, taken out from the take-out part 207, and cut to become a granular resin composition (primary processed resin) after cooling. Example

以下,藉由實施例而更具體地說明本發明。本發明並不限定於下述實施例。Hereinafter, the present invention will be described more specifically by means of examples. The present invention is not limited to the following examples.

(測定方法) (1)熔體質量流率(MFR) 依據ISO1133,於230℃、2.16 kg荷重下測定。 (2)水分率 依據JIS L 1015(2010),於溫度20℃、相對濕度65%之標準狀態下測定。 (3)細毛數 依據JIS L 1095(2010)9.22.2 B法進行測定。使用LASERSPOT(型號LST-V++,計測器工業股份有限公司製造)作為細毛試驗機,試驗條件設為走紗速度50 m/min、試驗長度100 m、N=1。 (4)英式棉紗支數 依據JIS L 1095(2010)9.4.1之一般紡織線之正量TEX-支數測定之棉紗支數測定方法進行測定。 (5)撚係數 依據JIS L 1095(2010)9.15.1 A法測定撚數,根據下式算出撚係數。 撚係數=每1英吋長之紗線之撚數/√支數 (6)撚角 (a)將紗線沿水平方向放置,使用KEYENCE製造之電子顯微鏡VE-9800,獲得紗線之側面之圖像(100倍)。 (b)於所獲得之紗線之側面圖像之左端與右端,分別取紗線之截面方向之中點,將2點間直線連結而獲得紗線軸。以所獲得之紗線軸作為基準線。例如,於圖3中,C及D分別為紗線之側面圖像之左端與右端之紗線之截面方向之中點,Lb為基準線。 (c)測定基準線與經加撚之紗線表面之纖維所成之銳角作為撚角。例如,於圖3中,基準線Lb與紗線表面之纖維所成之銳角α為撚角。 (7)氣孔率、表觀密度 (I)基於紗線之側面觀察而進行之紡織線直徑之計算 利用KEYENCE製造之電子顯微鏡VE-9800(倍率:40倍至100倍)拍攝紗線於無張力狀態下之側面圖像。如圖4所示,引出紗線任意部位之紗線之最外側之纖維(以下稱為最外端纖維)於紗線之長度方向上之切線,相對於紗線之中心軸(長度方向)垂直地作出該切線之垂線。取該垂線與構成紗線之最外端纖維之交點A。進而,隔著紗線之中心軸,取交點A之相反側之最外端纖維之交點B。由AB間之距離測定紗線之直徑。對單個樣品於不同部位拍攝5張圖像。對各圖像求出5處之紗線直徑,作為該圖像之代表值。進而,求出5張圖像之平均值,作為該紗線樣品之代表值。 (II)紡織線之表觀密度之計算 由正量支數(JIS L 1095 9.4.1正量TEX及支數)算出每單位長度之重量,藉由使用(I)中測得之紡織線直徑,將紗線之截面近似為圓而算出體積,用每單位長度之重量除以所算出之體積,藉此定義紗線之表觀密度。表觀密度越小,紗線之每單位長度之蓬鬆度越大。 利用KEYENCE製造之電子顯微鏡VE-9800以倍率270倍拍攝紗線之截面圖像。為了保存截面形狀,使用環氧樹脂進行包埋,使用切片機(Leica EM UC6)利用玻璃刀進行修面。利用KEYENCE製造之電子顯微鏡VE-9800以(倍率270倍)進行觀察。 (III)氣孔率之計算方法 算出任意之與構成紗線之纖維素材比重相同、且與該紗線重量相同之圓柱之體積Vm。進而,使用(I)中測得之紗線直徑,將該紗線之截面近似為圓而算出紗線之體積Vy。用Vm除以Vy並乘以100,而獲得紗線中纖維所占之體積之比率。藉由自100減去該比率而導出紗線內之空氣所占之比率即氣孔率。其中,計算時採用JIS L 1096:2010 8.11表觀比重及氣孔體積率中記載之纖維比重。 (8)起毛球試驗 依據JIS L 1076 A法,使用ICI型試驗機進行起毛球試驗,確認起毛球之產生程度。 (9)纖維物性 依據JIS L 1015,測定單絲纖維強度及伸度。 (10)單位面積重量、厚度及總體密度 依據JIS L 1096(2010)測定單位面積重量及厚度。總體密度係基於單位面積重量及厚度而算出。 (11)紡絲步驟之生產性 按照以下之5個階段基準評價紡織步驟中之各步驟((I)混打棉、(II)梳棉、(III)併條、(IV)粗紡、(V)精紡、(VI)卷線)之生產性,取該平均分數作為綜合評分。 5:良好 4:大體良好 3:一般 2:故障較多 1:無法進行生產 (12)布帛之編成性 按照以下之5個階段基準評價布帛製作時之編成性。 5:良好 4:大體良好 3:一般 2:故障較多 1:無法進行生產 (13)吸水速乾性評價1 依據一般財團法人BOKEN品質評價機構之蒸散性(II)試驗(紡檢規格BQE A 028),求出20分鐘後之蒸散率。BOKEN一般製品基準為30%以上。蒸散率具體藉由以下之方法測定、計算。 (a)測定直徑約9 cm之試驗片與培養皿之質量(W)。 (b)於培養皿中滴下0.1 mL水,於其上放置試驗片,測定質量(W0)。 (c)於標準狀態(20℃、65%RH)下放置,間隔規定時間測定質量(Wt),算出20分鐘後之蒸散率(%)。 蒸散率(%)=[(W0-Wt)/(W0-W)]×100 (14)吸水速乾性評價2 依據一般財團法人BOKEN品質評價機構之蒸散性(I)試驗(紡檢規格BQE A 006),求出30分鐘後之蒸散率。一般製品基準為20%以上。蒸散率具體藉由以下之方法測定、計算。 (a)測定直徑約9 cm之試驗片與表面皿之質量(W)。 (b)於表面皿中滴下1 mL水,於其上放置試驗片,測定質量(W0)。 (c)於標準狀態(20℃、65%RH)下放置,間隔規定時間測定質量(Wt),算出各個時間之蒸散率(%)。 蒸散率(%)=[(W0-Wt)/(W0-W)]×100 (15)吸水速乾性評價3 使用水分管理測試儀(MMT,Moisture Management Tester),依據AATCC TM 195(美國纖維化學技術·染色技術協會規格)或GB/T21655.2(中國標準規格)進行吸水速乾性試驗。具體而言,將於裝置中放入試樣(9 cm×9 cm),歷時20秒向試樣之浸水面(肌側面、裏面層)滴下試驗水(約0.2 mL),利用裝置內部之感測器,記錄每經過一定時間後該水分之擴散、浸透狀態,歷時120秒結束。根據自動算出之下述測定項目,參照下述表1中記載之GB/T21655.2(中國標準規格)之1~5階段評價、或下述表2中記載之AATCC TM 195(美國纖維化學技術·染色技術協會規格)之1~5階段評價而進行評價。 (16)洗滌方法 依據JIS L 0217 103法進行。 (17)保溫性 使用加多技術公司製造之THERMOLAB 2,藉由乾接觸法測定保溫率,評價保溫性。具體而言,測定於一定之空氣流(30 cm/s)中,自設定於環境溫度+10℃之加熱板隔著試驗片(20×20 cm)釋放熱量之熱釋放速度(消耗電力),求出保溫率。保溫率之數字越大,判定保溫性越高。 (18)洗滌乾燥性 依據紡檢規格BQE A 024-2016,藉由以下之試驗方法測定90分鐘後之乾燥率及乾燥率達到90%之時間,評價洗滌乾燥性。90分鐘後之乾燥率越高,表明洗滌乾燥性越高。乾燥率達到90%之時間越短,表明洗滌乾燥性越高。 (a)於標準狀態(20℃、65%RH)下調整試驗片,測定質量(W)。 (b)於水中浸漬30分鐘後,進行30分鐘脫水。 (c)測定脫水後之質量(W1 )後,將試驗片懸掛於標準狀態之環境中,每隔規定時間測定質量(Wx),根據下式求出乾燥率。 乾燥率(%)={(W1 -W)-(Wx -W)}/(W1 -W)X100 (19)吸水性 藉由JIS L 1907滴下法測定吸水時間,評價吸水性。吸水時間越短,表明吸水性越高。 (20)透氣性 藉由JIS L 1096 A法(弗雷澤(Frajour)式法)評價透氣性。(Measurement method) (1) Melt mass flow rate (MFR) Measured at 230° C. under a load of 2.16 kg in accordance with ISO1133. (2) Moisture content is measured in accordance with JIS L 1015 (2010) under the standard conditions of temperature 20°C and relative humidity 65%. (3) The number of fine hairs was measured in accordance with JIS L 1095 (2010) 9.22.2 B method. A LASERSPOT (model LST-V++, manufactured by Kekeki Kogyo Co., Ltd.) was used as a wool testing machine, and the test conditions were set at a yarn running speed of 50 m/min, a test length of 100 m, and N=1. (4) The British cotton yarn count is measured according to the cotton yarn count determination method of JIS L 1095 (2010) 9.4.1, the positive TEX-count determination of general textile threads. (5) Twist coefficient The number of twists was measured according to JIS L 1095 (2010) 9.15.1 A method, and the twist coefficient was calculated according to the following formula. Twist coefficient = number of twists per 1 inch of yarn / √ count (6) Twist angle (a) Place the yarn in the horizontal direction, use the electronic microscope VE-9800 manufactured by KEYENCE to obtain the side surface of the yarn Image (100x). (b) Take the midpoint of the cross-sectional direction of the yarn at the left end and the right end of the side image of the obtained yarn, respectively, and connect the two points with a straight line to obtain the yarn shaft. Take the obtained yarn shaft as the reference line. For example, in Fig. 3, C and D are respectively the middle point of the cross-sectional direction of the yarn at the left end and the right end of the side image of the yarn, and Lb is the reference line. (c) Measure the acute angle formed by the reference line and the fibers on the surface of the twisted yarn as the twist angle. For example, in Fig. 3, the acute angle α formed by the reference line Lb and the fibers on the surface of the yarn is the twist angle. (7) Porosity, apparent density (I) Calculation of the diameter of the textile thread based on the side observation of the yarn. Using the electron microscope VE-9800 (magnification: 40 times to 100 times) manufactured by KEYENCE, the yarn is photographed under no tension. Side view of the state. As shown in Figure 4, the tangent of the outermost fiber (hereinafter referred to as the outermost fiber) of the yarn drawn from any part of the yarn in the length direction of the yarn is perpendicular to the central axis (length direction) of the yarn Draw a perpendicular to the tangent. Take the intersection point A of the perpendicular line and the outermost fiber constituting the yarn. Furthermore, the intersection point B of the outermost fiber on the opposite side to the intersection point A is taken across the central axis of the yarn. The diameter of the yarn is determined from the distance between AB. Five images were taken at different parts of a single sample. The yarn diameters at five locations were obtained for each image and used as representative values of the image. Furthermore, the average value of 5 images was calculated|required as the representative value of this yarn sample. (II) Calculation of the apparent density of the textile thread Calculate the weight per unit length from the positive count (JIS L 1095 9.4.1 positive TEX and count), by using the diameter of the textile thread measured in (I) , The cross section of the yarn is approximated as a circle to calculate the volume, and the weight per unit length is divided by the calculated volume to define the apparent density of the yarn. The smaller the apparent density, the larger the bulkiness per unit length of the yarn. The cross-sectional image of the yarn was taken with an electron microscope VE-9800 manufactured by KEYENCE at a magnification of 270 times. In order to preserve the cross-sectional shape, epoxy resin was used for embedding, and a microtome (Leica EM UC6) was used for trimming with a glass knife. Observation was performed with an electron microscope VE-9800 manufactured by KEYENCE (magnification: 270 times). (III) Calculation method of porosity Calculate the volume Vm of any cylinder having the same specific gravity as the fiber material constituting the yarn and the same weight as the yarn. Furthermore, using the yarn diameter measured in (I), the yarn volume Vy is calculated by approximating the cross section of the yarn to a circle. Divide Vm by Vy and multiply by 100 to obtain the ratio of the volume occupied by fibers in the yarn. The porosity, the ratio of air in the yarn, is derived by subtracting this ratio from 100. Among them, the fiber specific gravity recorded in JIS L 1096:2010 8.11 apparent specific gravity and pore volume ratio was used for calculation. (8) Pilling test According to JIS L 1076 A method, use the ICI type testing machine to conduct the pilling test to confirm the degree of pilling. (9) Fiber properties According to JIS L 1015, the strength and elongation of monofilament fibers were measured. (10) Weight per unit area, thickness and overall density The weight per unit area and thickness were measured in accordance with JIS L 1096 (2010). The overall density was calculated based on the basis weight and thickness. (11) The productivity of the spinning process is evaluated in accordance with the following 5-stage benchmarks for each step in the spinning process ((I) blended cotton, (II) carding, (III) drawing frame, (IV) slubbing, (V) ) Worsted spinning, (VI) coiled yarn) productivity, take the average score as the comprehensive score. 5: Good 4: Generally good 3: Fair 2: Many failures 1: Production impossible (12) Weaving property of fabric The weaving property at the time of fabric production was evaluated according to the following 5-stage criteria. 5: Good 4: Generally good 3: General 2: Many faults 1: Cannot be produced (13) Evaluation of water absorption and quick drying 1 According to the evapotranspiration (II) test of the BOKEN Quality Evaluation Institute of the General Foundation (BQE A 028 of the spinning inspection specification ) to find the evapotranspiration rate after 20 minutes. The standard of BOKEN general products is more than 30%. Specifically, the evapotranspiration rate is measured and calculated by the following methods. (a) Measure the mass (W) of the test piece and petri dish with a diameter of about 9 cm. (b) Drop 0.1 mL of water into the petri dish, place the test piece on it, and measure the mass (W0). (c) Place it in the standard state (20°C, 65%RH), measure the mass (Wt) at regular intervals, and calculate the evaporation rate (%) after 20 minutes. Evapotranspiration rate (%)=[(W0-Wt)/(W0-W)]×100 (14) Water absorption and quick-drying evaluation 2 According to the evapotranspiration (I) test of the BOKEN Quality Evaluation Institute of the General Foundation (BQE A 006), to find the evapotranspiration rate after 30 minutes. The general product benchmark is more than 20%. Specifically, the evapotranspiration rate is measured and calculated by the following method. (a) Measure the mass (W) of the test piece and watch glass with a diameter of about 9 cm. (b) Drop 1 mL of water into a watch glass, place a test piece on it, and measure the mass (W0). (c) Place it in the standard state (20°C, 65%RH), measure the mass (Wt) at regular intervals, and calculate the evaporation rate (%) at each time. Evapotranspiration rate (%)=[(W0-Wt)/(W0-W)]×100 (15) Water absorption and quick-drying evaluation 3 Using a moisture management tester (MMT, Moisture Management Tester), according to AATCC TM 195 (American Fiber Chemical Technology · Dyeing Technology Association specification) or GB/T21655.2 (China standard specification) for water absorption and quick-drying test. Specifically, a sample (9 cm × 9 cm) will be placed in the device, and the test water (about 0.2 mL) will be dripped on the water-immersed surface (the side of the muscle, the inner layer) of the sample for 20 seconds, using the feeling inside the device. The measuring device records the diffusion and penetration state of the water after a certain period of time, and it lasts for 120 seconds. According to the following measurement items automatically calculated, refer to the 1~5 stage evaluation of GB/T21655.2 (China Standard Specification) recorded in the following Table 1, or the AATCC TM 195 (American Fiber Chemical Technology) recorded in the following Table 2・Evaluation based on the 1st to 5th stages of the Association of Dyeing Technology Standards). (16) Washing method is carried out according to JIS L 0217 103 method. (17) Heat retention The heat retention was evaluated by measuring the heat retention rate by the dry contact method using THERMOLAB 2 manufactured by Jiaduo Technology Co., Ltd. Specifically, in a constant air flow (30 cm/s), the heat release rate (power consumption) of the heat released from the heating plate set at the ambient temperature +10°C through the test piece (20×20 cm) was measured, Find the insulation rate. The larger the number of heat retention rate, the higher the heat retention. (18) Washing dryness According to the textile inspection specification BQE A 024-2016, the drying rate after 90 minutes and the time for the drying rate to reach 90% are measured by the following test method, and the washing dryness is evaluated. The higher the drying rate after 90 minutes, the higher the washing dryness. The shorter the time for the drying rate to reach 90%, the higher the dryness of washing. (a) Adjust the test piece under the standard state (20°C, 65%RH), and measure the mass (W). (b) After immersing in water for 30 minutes, dehydration was performed for 30 minutes. (c) After measuring the mass (W 1 ) after dehydration, hang the test piece in the environment of the standard state, measure the mass (Wx) every predetermined time, and obtain the drying rate according to the following formula. Drying rate (%)={(W 1 -W)-(W x -W)}/(W 1 -W)X100 (19) Water absorption The water absorption time was measured by the JIS L 1907 dropping method, and the water absorption was evaluated. The shorter the water absorption time, the higher the water absorption. (20) Air permeability The air permeability was evaluated by JIS L 1096 A method (Frajour's method).

[表1]

Figure 108103266-A0304-0001
[Table 1]
Figure 108103266-A0304-0001

[表2]

Figure 108103266-A0304-0002
[Table 2]
Figure 108103266-A0304-0002

<母料樹脂組成物之製造例1> [一次加工樹脂] (1)準備聚氧伸烷基醚(花王股份有限公司製造,EMULGEN 1108,有效成分100質量%,分子量473)作為水溶性之親水性成分。 (2)準備聚丙烯(MFR為20 g/10 min)之顆粒(直徑2 mm、高度2 mm之圓柱形)作為基礎樹脂。 (3)自圖2所示之擠出機之原料供給口202供給基礎樹脂顆粒80質量份、包含4質量%聚氧伸烷基醚之聚丙烯(MFR為800 g/10 min)12.5質量份、親水性成分2.5質量份及相溶化劑(乙烯-丙烯酸-順丁烯二酸共聚物(MFR為80 g/10 min(190℃、2.16 kg),熔點(DSC法)為98℃)5質量份。 (4)將擠出機內之加工溫度設定於170~190℃。於樹脂熔融部203沿旋轉軸將供給物向前運送,於混練分散部204有複數片旋轉之混練板,於此處將基礎樹脂與親水性成分均勻混合,繼而,將減壓管線205設為真空(負壓),藉此同時去除水分。 (5)繼而,自擠出部206擠出樹脂組成物,經冷卻後自取出口207取出。 (6)導入造粒機,進行顆粒化(一次加工樹脂)。(一次加工步驟) [二次加工樹脂] (1)使用上述擠出機,對藉由一次步驟獲得之顆粒化之樹脂組成物(一次加工樹脂)100質量份混合作為高MFR丙烯之MFR為2000 g/10 min之低立體規則性聚丙烯(商品名「L-MODU」S400,出光興產股份有限公司製造)10質量份,自原料供給口202供給。 (2)進行熔融混練,加以冷卻,利用造粒機進行顆粒化,而獲得直徑2 mm、高度2 mm之圓柱形之聚丙烯系母料樹脂組成物(二次加工樹脂)。<Manufacturing Example 1 of Masterbatch Resin Composition> [primary processing resin] (1) A polyoxyalkylene ether (manufactured by Kao Corporation, EMULGEN 1108, active ingredient 100% by mass, molecular weight 473) was prepared as a water-soluble hydrophilic component. (2) Prepare polypropylene (MFR 20 g/10 min) pellets (cylindrical shape with a diameter of 2 mm and a height of 2 mm) as the base resin. (3) 80 parts by mass of base resin pellets and 12.5 parts by mass of polypropylene (MFR: 800 g/10 min) containing 4 mass % polyoxyalkylene ether are supplied from the raw material supply port 202 of the extruder shown in FIG. 2 , 2.5 parts by mass of hydrophilic components and compatibilizer (ethylene-acrylic acid-maleic acid copolymer (MFR: 80 g/10 min (190°C, 2.16 kg), melting point (DSC method) is 98°C) 5 mass share. (4) Set the processing temperature in the extruder at 170~190°C. In the resin melting part 203, the supply is forwarded along the rotating shaft, and there are a plurality of rotating kneading plates in the kneading and dispersing part 204, where the base resin and the hydrophilic component are uniformly mixed, and then the decompression line 205 is set to Vacuum (negative pressure), whereby moisture is removed at the same time. (5) Next, the resin composition is extruded from the extrusion part 206 and taken out from the extraction port 207 after being cooled. (6) Import into a granulator for granulation (primary processing of resin). (one processing step) [Secondary processing resin] (1) Using the extruder above, 100 parts by mass of the pelletized resin composition (primary processing resin) obtained in one step was mixed with low stereoregularity polypropylene having an MFR of 2000 g/10 min as high MFR propylene (trade name "L-MODU" S400, manufactured by Idemitsu Kosan Co., Ltd.) 10 parts by mass were supplied from the raw material supply port 202 . (2) Melt kneading, cooling, and granulation with a granulator to obtain a cylindrical polypropylene-based masterbatch resin composition (secondary processing resin) with a diameter of 2 mm and a height of 2 mm.

<纖維之製造例1> (1)將聚丙烯(MFR為20 g/10 min)之顆粒(直徑2 mm、高度2 mm之圓柱形)100質量份、製造例1中獲得之母料樹脂組成物2質量份及碳黑2質量份進行混合。 (2)自熔融紡絲用擠出機之原料供給口供給(1)之混合樹脂組成物(顆粒),使用常規方法之熔融紡絲機,經擠出機熔融混練後,進行熔融紡絲。其後,使用公知之延伸機進行延伸,以附著量成為0.15質量%之方式賦予常用之親水性之纖維處理劑,利用捲縮機賦予捲縮,進行切割,而製作單絲纖維纖度約1.8 dtex、纖維長度為38 mm之聚丙烯系纖維(以下亦記為親水化PP纖維1(黑色))。<Production Example 1 of Fiber> (1) 100 parts by mass of polypropylene (MFR 20 g/10 min) pellets (cylindrical shape with a diameter of 2 mm and a height of 2 mm), 2 parts by mass of the masterbatch resin composition obtained in Production Example 1, and carbon black 2 parts by mass were mixed. (2) The mixed resin composition (pellets) of (1) is supplied from the raw material supply port of the extruder for melt spinning, melt-kneaded by the extruder using a conventional melt spinning machine, and then melt-spun. Thereafter, stretching is performed using a known stretching machine, a commonly used hydrophilic fiber treatment agent is applied so that the adhesion amount becomes 0.15% by mass, crimping is applied by a crimper, and cutting is performed to produce a monofilament fiber with a fineness of about 1.8 dtex 1. Polypropylene fiber with a fiber length of 38 mm (hereinafter also referred to as hydrophilized PP fiber 1 (black)).

<纖維之製造例2> (1)將聚丙烯(MFR為20 g/10 min)之顆粒(直徑2 mm、高度2 mm之圓柱形)100質量份與碳黑2質量份進行混合。 (2)自熔融紡絲用擠出機之原料供給口供給(1)之混合樹脂組成物(顆粒),使用常規方法之熔融紡絲機,經擠出機熔融混練後,進行熔融紡絲。其後,使用公知之延伸機進行延伸,以附著量成為0.15質量%之方式賦予與製造例1相同之親水性之纖維處理劑,利用捲縮機賦予捲縮,進行切割,而製作單絲纖維纖度約1.8 dtex、纖維長度為38 mm之聚丙烯系纖維(以下亦記為普通PP纖維1(黑色))。<Production example 2 of fiber> (1) 100 parts by mass of polypropylene (MFR: 20 g/10 min) pellets (cylindrical shape with a diameter of 2 mm and a height of 2 mm) were mixed with 2 parts by mass of carbon black. (2) The mixed resin composition (pellets) of (1) is supplied from the raw material supply port of the extruder for melt spinning, melt-kneaded by the extruder using a conventional melt spinning machine, and then melt-spun. Thereafter, stretching was carried out using a known stretching machine, and the same hydrophilic fiber treatment agent as in Production Example 1 was applied so that the adhesion amount became 0.15% by mass, crimping was applied by a crimper, and cutting was performed to produce monofilament fibers A polypropylene-based fiber with a denier of about 1.8 dtex and a fiber length of 38 mm (hereafter also referred to as ordinary PP fiber 1 (black)).

<纖維之製造例3> 自熔融紡絲用擠出機之原料供給口供給聚丙烯(MFR為20 g/10 min)之顆粒(直徑2 mm、高度2 mm之圓柱形)100質量份,使用常規方法之熔融紡絲機,經擠出機熔融混練後,進行熔融紡絲。其後,使用公知之延伸機進行延伸,以附著量成為0.15質量%之方式賦予與製造例1相同之親水性之纖維處理劑,利用捲縮機賦予捲縮,進行切割,而製作單絲纖維纖度約1.3 dtex、纖維長度為38 mm之聚丙烯系纖維(以下亦記為普通PP纖維2(白色))。<Production example 3 of fiber> 100 parts by mass of polypropylene (MFR: 20 g/10 min) pellets (cylindrical shape with a diameter of 2 mm and a height of 2 mm) are supplied from the raw material supply port of the extruder for melt spinning, and a melt spinning machine using a conventional method is used , after being melted and kneaded by an extruder, melt spinning is carried out. Thereafter, stretching was carried out using a known stretching machine, and the same hydrophilic fiber treatment agent as in Production Example 1 was applied so that the adhesion amount became 0.15% by mass, crimping was applied by a crimper, and cutting was performed to produce monofilament fibers Polypropylene-based fibers with a fineness of about 1.3 dtex and a fiber length of 38 mm (hereinafter also referred to as ordinary PP fiber 2 (white)).

<纖維之製造例4> (1)將聚丙烯(MFR為20 g/10 min)之顆粒(直徑2 mm、高度2 mm之圓柱形)100質量份與製造例1中獲得之母料樹脂組成物2質量份進行混合。 (2)自熔融紡絲用擠出機之原料供給口供給(1)之混合樹脂組成物(顆粒),使用常規方法之熔融紡絲機,經擠出機熔融混練後,進行熔融紡絲。其後,使用公知之延伸機進行延伸,以附著量成為0.15質量%之方式賦予與製造例1相同之親水性之纖維處理劑,利用捲縮機賦予捲縮,進行切割,而製作單絲纖維纖度約1.9 dtex、纖維長度為38 mm之聚丙烯系纖維(以下亦記為親水化PP纖維2(白色))。<Example 4 of fiber production> (1) 100 parts by mass of polypropylene (MFR 20 g/10 min) pellets (cylindrical shape with a diameter of 2 mm and a height of 2 mm) were mixed with 2 parts by mass of the masterbatch resin composition obtained in Production Example 1. (2) The mixed resin composition (pellets) of (1) is supplied from the raw material supply port of the extruder for melt spinning, melt-kneaded by the extruder using a conventional melt spinning machine, and then melt-spun. Thereafter, stretching was carried out using a known stretching machine, and the same hydrophilic fiber treatment agent as in Production Example 1 was applied so that the adhesion amount became 0.15% by mass, crimping was applied by a crimper, and cutting was performed to produce monofilament fibers Polypropylene fiber with a fineness of about 1.9 dtex and a fiber length of 38 mm (hereinafter also referred to as hydrophilized PP fiber 2 (white)).

<纖維之製造例5> 自熔融紡絲用擠出機之原料供給口供給聚丙烯(MFR為20 g/10 min)之顆粒(直徑2 mm、高度2 mm之圓柱形)100質量份,使用常規方法之熔融紡絲機,經擠出機熔融混練後,進行熔融紡絲。其後,使用公知之延伸機進行延伸,以附著量成為0.15質量%之方式賦予與製造例1相同之親水性之纖維處理劑,利用捲縮機賦予捲縮,進行切割,而製作單絲纖維纖度約1.24 dtex、纖維長度為38 mm之聚丙烯系纖維(以下亦記為普通PP纖維3(白色))。<Manufacturing example 5 of fiber> 100 parts by mass of polypropylene (MFR: 20 g/10 min) pellets (cylindrical shape with a diameter of 2 mm and a height of 2 mm) are supplied from the raw material supply port of the extruder for melt spinning, and a melt spinning machine using a conventional method is used , after being melted and kneaded by an extruder, melt spinning is carried out. Thereafter, stretching was carried out using a known stretching machine, and the same hydrophilic fiber treatment agent as in Production Example 1 was applied so that the adhesion amount became 0.15% by mass, crimping was applied by a crimper, and cutting was performed to produce monofilament fibers Polypropylene fiber with a fineness of about 1.24 dtex and a fiber length of 38 mm (hereinafter also referred to as ordinary PP fiber 3 (white)).

(實施例1) 將製造例2中獲得之普通PP纖維1(黑色)依序投入混打棉步驟、梳棉步驟、併條步驟、粗紡步驟中,而獲得50格令/12 yd之粗紗。繼而,使用2股所獲得之由普通PP纖維1(黑色)100質量%構成之粗紗,利用導入有緊密紡系統之環錠精紡機,賦予40倍之牽伸,利用空氣沿粗紗之行進方向進行抽吸而使纖維收攏後,以撚係數3.6進行撚線,而製作英式棉紗支數40 s之紡織線(賽絡緊密線)。具體而言,如圖1所示,將兩股由普通PP纖維1(黑色)100質量%構成之粗紗1a、1b經由導紗桿101及喇叭環102而並列地供給至由後輥103、中輥104、皮圈105及前輥106構成之牽伸區,一面並排牽伸一面向撚線區供給,使用由空氣抽吸部107、透氣皮圈108、旋轉輥109及輔助輥110構成之集束裝置,利用空氣沿粗紗之行進方向抽吸剛供給至撚線區後之兩股經牽伸之粗紗(纖維束)2a、2b而使纖維收攏後,經由導紗鉤111、鋼絲圈112及環113進行撚線,而獲得由兩股纖維束經併紗、加撚而成之紡織線(賽絡緊密線)10。(Example 1) The ordinary PP fiber 1 (black) obtained in Manufacturing Example 2 was sequentially put into the cotton blending step, carding step, drawing step, and roving step to obtain a roving of 50 grains/12 yd. Next, using 2 strands of roving made of ordinary PP fiber 1 (black) 100% by mass, using a ring spinning machine equipped with a compact spinning system, a draft of 40 times is given, and the roving is carried out along the traveling direction of the roving by air. After the fibers are gathered by suction, the yarn is twisted with a twist coefficient of 3.6 to produce a textile yarn with an English cotton count of 40 s (siro compact yarn). Specifically, as shown in FIG. 1, two rovings 1a, 1b made of ordinary PP fiber 1 (black) 100% by mass are supplied in parallel to the rear roller 103, middle The drafting area composed of roller 104, apron 105 and front roller 106 is drawn side by side while supplying to the twisting area, using a converging device composed of air suction part 107, breathable apron 108, rotating roller 109 and auxiliary roller 110 , using air to suck the two drafted rovings (fiber bundles) 2a, 2b just supplied to the twisting area along the traveling direction of the roving to make the fibers gather, and then pass through the yarn guide hook 111, the traveler 112 and the ring 113. Twisted yarn to obtain a textile yarn (siro compact yarn) 10 formed by doubling and twisting two fiber bundles.

使用上述獲得之紡織線,利用織針24之橫織機編織形成單位面積重量約120 g/m2 之平針組織之針織物。Using the textile yarn obtained above, a flat knitting fabric with a weight per unit area of about 120 g/m 2 was woven on a flat knitting machine with knitting needles 24 .

(實施例2) 將製造例3中獲得之普通PP纖維2(白色)依序投入混打棉步驟、梳棉步驟、併條步驟、粗紡步驟,而獲得50格令/12 yd之粗紗。使用2股所獲得之由普通PP纖維4(白色)100質量%構成之粗紗,除此以外,藉由與實施例1相同之方式獲得由兩股纖維束經併紗、加撚而成之紡織線(賽絡緊密線)。使用所獲得之紡織線,藉由與實施例1相同之方式編織形成單位面積重量約120 g/m2 之平針組織之針織物。(Example 2) The ordinary PP fiber 2 (white) obtained in Production Example 3 was put into the cotton blending step, the carding step, the drawing step, and the roving step in order to obtain a 50 grain/12 yd roving. In addition to using 2 strands of roving made of 100% by mass of ordinary PP fiber 4 (white), in the same manner as in Example 1, a woven fabric formed by doubling and twisting two strands of fiber bundles was obtained. line (siro tight line). Using the obtained spun yarn, knit in the same manner as in Example 1 to form a plain knitted fabric with a weight per unit area of about 120 g/m 2 .

(實施例3) 將製造例1中獲得之親水化PP纖維1(黑色)依序投入混打棉步驟、梳棉步驟、併條步驟、粗紡步驟,而獲得50格令/12 yd之粗紗。使用2股所獲得之由親水化PP纖維1(黑色)100質量%構成之粗紗,除此以外,藉由與實施例1相同之方式獲得由兩股纖維束經併紗、加撚而成之紡織線(賽絡緊密線)。使用所獲得之紡織線,藉由與實施例1相同之方式編織形成單位面積重量約120 g/m2 之平針組織之針織物。(Example 3) The hydrophilized PP fiber 1 (black) obtained in Production Example 1 was put into the cotton blending step, the carding step, the drawing step, and the roving step in sequence to obtain a roving of 50 grains/12 yd. In addition to using 100 mass% of the hydrophilized PP fiber 1 (black) roving obtained by 2 strands, in the same manner as in Example 1, a roving formed by doubling and twisting two strands of fiber bundles was obtained. Textile thread (siro compact thread). Using the obtained spun yarn, knit in the same manner as in Example 1 to form a plain knitted fabric with a weight per unit area of about 120 g/m 2 .

(實施例4) 將製造例1中獲得之親水化PP纖維1(黑色)8質量份與製造例3中獲得之普通PP纖維2(白色)92質量份依序投入打棉步驟、梳棉步驟、併條步驟、粗紡步驟,而獲得50格令/12 yd之粗紗。使用2股所獲得之由親水化PP纖維1(黑色)8質量%及普通PP纖維2(白色)92質量%構成之粗紗,除此以外,藉由與實施例1相同之方式獲得由兩股纖維束經併紗、加撚而成之紡織線(賽絡緊密線)。使用所獲得之紡織線,藉由與實施例1相同之方式編織形成單位面積重量約120 g/m2 之平針組織之針織物。所獲得之布帛含有8質量%之聚丙烯系纖維B,聚丙烯系纖維B與其他聚丙烯系纖維之平均纖度為1.34 dtex。(Example 4) 8 parts by mass of hydrophilized PP fiber 1 (black) obtained in Production Example 1 and 92 parts by mass of ordinary PP fiber 2 (white) obtained in Production Example 3 were put into the beating step and the carding step in sequence , drawing step, and roving step to obtain 50 grains/12 yd of roving. A roving made of 8% by mass of hydrophilized PP fiber 1 (black) and 92% by mass of ordinary PP fiber 2 (white) obtained by using two strands was obtained in the same manner as in Example 1. Textile thread (siro compact thread) made of fiber bundles by doubling and twisting. Using the obtained spun yarn, knit in the same manner as in Example 1 to form a plain knitted fabric with a weight per unit area of about 120 g/m 2 . The obtained fabric contained 8% by mass of the polypropylene-based fiber B, and the average fineness of the polypropylene-based fiber B and other polypropylene-based fibers was 1.34 dtex.

(實施例5) 將製造例1中獲得之親水化PP纖維1(黑色)8質量份、製造例4中獲得之親水化PP纖維2(白色)46質量份、及製造例5中獲得之普通PP纖維3(白色)46質量份依序投入打棉步驟、梳棉步驟、併條步驟、粗紡步驟,而獲得50格令/12 yd之粗紗。使用2股所獲得之由親水化PP纖維1(黑色)8質量%、親水化PP纖維2(白色)46質量%及普通PP纖維3(白色)46質量%構成之粗紗,除此以外,藉由與實施例1相同之方式獲得由兩股纖維束經併紗、加撚而成之紡織線(賽絡緊密線)。使用所獲得之紡織線,藉由與實施例1相同之方式編織形成單位面積重量約120 g/m2 之平針組織之針織物。所獲得之布帛含有54質量%之聚丙烯系纖維B,聚丙烯系纖維B與其他聚丙烯系纖維之平均纖度為1.59 dtex。(Example 5) 8 parts by mass of hydrophilized PP fiber 1 (black) obtained in Production Example 1, 46 parts by mass of hydrophilized PP fiber 2 (white) obtained in Production Example 4, and ordinary 46 parts by mass of PP fiber 3 (white) were put into the beating step, the carding step, the drawing step, and the roving step in sequence to obtain a roving of 50 grains/12 yd. A roving composed of hydrophilized PP fiber 1 (black) 8% by mass, hydrophilized PP fiber 2 (white) 46% by mass, and ordinary PP fiber 3 (white) 46% by mass obtained by using two strands was used. In the same manner as in Example 1, a textile yarn (siro compacted yarn) formed by doubling and twisting two fiber bundles was obtained. Using the obtained spun yarn, knit in the same manner as in Example 1 to form a plain knitted fabric with a weight per unit area of about 120 g/m 2 . The obtained fabric contained 54% by mass of the polypropylene-based fiber B, and the average fineness of the polypropylene-based fiber B and other polypropylene-based fibers was 1.59 dtex.

(比較例1) 將製造例3中獲得之普通PP纖維2(白色)依序投入混打棉步驟、梳棉步驟、併條步驟、粗紡步驟,而獲得90格令/12 yd之粗紗。使用1股所獲得之由普通PP纖維2(白色)100質量%構成之粗紗,利用環錠精紡機,賦予36倍之牽伸,以撚係數3.4進行撚線,而製作英式棉紗支數40s之紡織線(環錠線)。使用所獲得之紡織線,藉由與實施例1相同之方式編織形成單位面積重量約120 g/m2 之平針組織之針織物。(Comparative Example 1) The common PP fiber 2 (white) obtained in Production Example 3 was sequentially put into the cotton blending step, carding step, drawing frame step, and roving step to obtain a 90 grain/12 yd roving. Using a 100% roving made of ordinary PP fiber 2 (white) obtained by 1 strand, using a ring spinning machine, giving a draft of 36 times, twisting with a twist coefficient of 3.4, and producing an English cotton yarn count of 40s Textile thread (ring thread). Using the obtained spun yarn, knit in the same manner as in Example 1 to form a plain knitted fabric with a weight per unit area of about 120 g/m 2 .

(比較例2) 將製造例3中獲得之普通PP纖維2(白色)依序投入混打棉步驟、梳棉步驟、併條步驟、粗紡步驟,而獲得180格令/6yd之粗紗。使用1股所獲得之由普通PP纖維2(白色)100質量%構成之粗紗,利用VORTEX精紡機進行紡織,而製作英式棉紗支數40s之紡織線(MVS線)。使用所獲得之紡織線,藉由與實施例1相同之方式編織形成單位面積重量約120 g/m2 之平針組織之針織物。(Comparative Example 2) The common PP fiber 2 (white) obtained in Production Example 3 was put into the cotton blending step, carding step, drawing frame step, and roving step in sequence to obtain a 180 grain/6yd roving. A roving made of 100% by mass of ordinary PP fiber 2 (white) obtained from one strand was spun on a VORTEX worsted spinning machine to produce a spinning thread (MVS thread) with an English cotton count of 40s. Using the obtained spun yarn, knit in the same manner as in Example 1 to form a plain knitted fabric with a weight per unit area of about 120 g/m 2 .

(比較例3) 將製造例1中獲得之親水化PP纖維1(黑色)25質量份與製造例3中獲得之普通PP纖維2(白色)75質量份依序投入打棉步驟、梳棉步驟、併條步驟、粗紡步驟,而獲得50格令/12 yd之粗紗。使用2股所獲得之由親水化PP纖維1(黑色)25質量%及普通PP纖維2(白色)75質量%構成之粗紗,利用環錠精紡機,賦予40倍之牽伸,以撚係數3.4進行撚線,而製作英式棉紗支數40s之紡織線(賽絡線)。使用所獲得之紡織線,藉由與實施例1相同之方式編織形成單位面積重量約120 g/m2 之平針組織之針織物。(Comparative Example 3) Put 25 parts by mass of hydrophilized PP fiber 1 (black) obtained in Production Example 1 and 75 parts by mass of ordinary PP fiber 2 (white) obtained in Production Example 3 into the beating step and carding step in sequence , drawing step, and roving step to obtain 50 grains/12 yd of roving. A roving composed of 25% by mass of hydrophilized PP fiber 1 (black) and 75% by mass of ordinary PP fiber 2 (white) obtained by using 2 strands, was given a draft of 40 times by using a ring spinning machine, and the twist coefficient was 3.4 Twisted yarn is used to produce textile yarn (siro yarn) with British cotton count 40s. Using the obtained spun yarn, knit in the same manner as in Example 1 to form a plain knitted fabric with a weight per unit area of about 120 g/m 2 .

(比較例4) 將市售之普通聚對苯二甲酸乙二酯系纖維(單絲纖維纖度1.3 dtex、纖維長度38 mm,以下亦記為「RPET纖維1」)依序投入混打棉步驟、梳棉步驟、併條步驟、粗紡步驟,而獲得100格令/12 yd之粗紗。使用1股所獲得之由100質量%之RPET纖維1構成之粗紗,利用環錠精紡機,賦予40倍之牽伸,以撚係數3.6進行撚線,而製作英式棉紗支數40s之紡織線(環錠線)。使用所獲得之紡織線,藉由與實施例1相同之方式編織形成單位面積重量約120 g/m2 之平針組織之針織物。(Comparative Example 4) Commercially available ordinary polyethylene terephthalate fibers (single fiber fineness 1.3 dtex, fiber length 38 mm, hereinafter also referred to as "RPET fiber 1") are sequentially put into the cotton blending step , carding step, drawing step, roving step to obtain 100 grains/12 yd of roving. Using a roving made of 100% by mass RPET fiber 1 obtained from one strand, the ring spinning machine was used to give a draft of 40 times, and twist the yarn with a twist coefficient of 3.6 to produce a textile yarn with an English cotton yarn count of 40s (Ring Spinning Wire). Using the obtained spun yarn, knit in the same manner as in Example 1 to form a plain knitted fabric with a weight per unit area of about 120 g/m 2 .

(比較例5) 將市售之普通聚對苯二甲酸乙二酯系纖維(單絲纖維纖度0.9 dtex、纖維長度38 mm,以下亦記為「RPET纖維2」)依序投入混打棉步驟、梳棉步驟、併條步驟、粗紡步驟,而獲得100格令/12 yd之粗紗。使用2股所獲得之由100質量%之RPET纖維2構成之粗紗,除此以外,藉由與實施例1相同之方式獲得紡織線(賽絡緊密線)。使用所獲得之紡織線,藉由與實施例1相同之方式編織形成單位面積重量約120 g/m2 之平針組織之針織物。(Comparative Example 5) Commercially available ordinary polyethylene terephthalate fibers (single fiber fineness 0.9 dtex, fiber length 38 mm, hereinafter also referred to as "RPET fiber 2") were sequentially put into the cotton blending step , carding step, drawing step, roving step to obtain 100 grains/12 yd of roving. A spun yarn (siro compacted yarn) was obtained in the same manner as in Example 1 except that the obtained roving consisting of 100% by mass of the RPET fiber 2 obtained by two strands was used. Using the obtained spun yarn, knit in the same manner as in Example 1 to form a plain knitted fabric with a weight per unit area of about 120 g/m 2 .

(比較例6) 將RPET纖維1(單絲纖維纖度1.3 dtex、纖維長度38 mm)依序投入混打棉步驟、梳棉步驟、併條步驟、粗紡步驟,而獲得50格令/12 yd之粗紗。使用2股所獲得之由100質量%之RPET纖維1構成之粗紗,除此以外,藉由與實施例1相同之方式獲得紡織線(賽絡緊密線)。使用所獲得之紡織線,藉由與實施例1相同之方式編織形成單位面積重量約120 g/m2 之平針組織之針織物。(Comparative Example 6) RPET fiber 1 (single fiber fineness 1.3 dtex, fiber length 38 mm) was sequentially put into the cotton blending step, carding step, drawing step, and slubbing step to obtain 50 grains/12 yd roving. A spun yarn (siro compacted yarn) was obtained in the same manner as in Example 1 except for using two obtained rovings composed of 100% by mass of the RPET fiber 1 . Using the obtained spun yarn, knit in the same manner as in Example 1 to form a plain knitted fabric with a weight per unit area of about 120 g/m 2 .

使用實施例1~5及比較例1~6之針織物,如上所述般進行起毛球試驗,將其結果示於下述表3及表4。於下述表3及表4中亦顯示:纖維之單絲纖維纖度及水分率、紡織線之英式棉紗支數、撚係數、細毛數、表觀密度及氣孔率之結果。下述表3及表4中亦一併顯示紡織步驟之生產性及布帛之編成性之結果。Using the knitted fabrics of Examples 1 to 5 and Comparative Examples 1 to 6, the pilling test was performed as described above, and the results are shown in Tables 3 and 4 below. Also shown in Table 3 and Table 4 below are the results of monofilament fineness and moisture content of the fiber, British cotton yarn count of the textile thread, twist coefficient, fine wool number, apparent density and porosity. The following Tables 3 and 4 also show the results of the productivity of the weaving process and the weaving performance of the fabric.

[表3]

Figure 108103266-A0304-0003
[table 3]
Figure 108103266-A0304-0003

[表4]

Figure 108103266-A0304-0004
[Table 4]
Figure 108103266-A0304-0004

根據上述表3及表4之結果,可知:使用實施例之紡織線A或紡織線B之布帛其抗起毛球性為3級以上,具有抗起毛球性。另一方面,使用比較例1、3~6之紡織線之布帛其抗起毛球性未達3級,抗起毛球性較差。使用比較例2之紡織線(MVS線)之布帛其抗起毛球性為4級以上,抗起毛球性良好,但紡織線之生產性較差。紡織線B之紡織步驟之生產性尤為良好,平均達4以上。根據實施例1~4與實施例5之對比可知:若撚角為27°以上,則抗起毛球性更良好。According to the results in Table 3 and Table 4 above, it can be seen that the pilling resistance of the fabrics using the spun yarn A or the spun yarn B of the examples is grade 3 or higher, and has pilling resistance. On the other hand, the pilling resistance of the fabrics using the spun yarns of Comparative Examples 1, 3-6 did not reach Grade 3, and the pilling resistance was poor. The fabric using the textile yarn (MVS yarn) of Comparative Example 2 had a pilling resistance of grade 4 or higher, which was good in pilling resistance, but the productivity of the textile yarn was poor. The productivity of the weaving step of the weaving line B is particularly good, with an average of 4 or more. According to the comparison between Examples 1-4 and Example 5, it can be seen that if the twist angle is greater than 27°, the pilling resistance is better.

(實施例6) 作為表層紗線及中層紗線,使用藉由與實施例4相同之方式製作之紡織線B(賽絡緊密線)。 作為裏層紗線,使用以如下方式製作者:將普通PP纖維(單絲纖維纖度1.3 dtex、纖維長度38 mm)依序投入混打棉步驟、梳棉步驟、併條步驟、粗紡步驟中,而獲得120格令/12 yd之粗紗,使用1股所獲得之由普通PP纖維2(白色)100質量%構成之粗紗,利用環錠精紡機,賦予14.4倍之牽伸,以撚係數3.2進行撚線而獲得之英式棉紗支數12s之紡織線(環錠線)。 依據圖5所示之編織組織圖及表5所示之條件,利用30英吋18G織針之裏毛用單面織機,由表層紗線及中層紗線構成表面之平針線圈,於背面,將裏層紗線跳2針插入至表層紗線而構成絨頭線圈,進行交錯編織,藉此編織形成雙層構造織物(單位面積重量271 g/m2 )。使用針布起毛機,對所獲得之織物之裏層紗線(絨頭)實施最終起毛加工。將所獲得之織物皂洗後,使用拉幅機於130℃下進行90秒最終定型。所獲得之織物之表面層為平針,裏面層為裏起毛。(Example 6) As the surface layer yarn and the middle layer yarn, the spun yarn B (siro compacted yarn) produced in the same manner as in Example 4 was used. As the inner layer yarn, it is produced in the following way: ordinary PP fiber (single fiber fineness 1.3 dtex, fiber length 38 mm) is put into the blending cotton step, carding step, drawing step, and slubbing step in sequence, To obtain a roving of 120 grains/12 yd, use 1 share of the roving made of ordinary PP fiber 2 (white) 100% by mass, use a ring spinning machine, give a draft of 14.4 times, and perform it with a twist coefficient of 3.2 Textile thread (ring-spun thread) of English cotton count 12s obtained by twisting. According to the knitting structure diagram shown in Figure 5 and the conditions shown in Table 5, using a single-jersey loom for inner wool with 30-inch 18G knitting needles, the flat stitch loops on the surface are formed by the surface yarn and the middle yarn, and on the back, the The yarn of the inner layer is inserted into the yarn of the outer layer by jumping 2 stitches to form pile loops, which are interlaced and woven to form a double-layer structure fabric (weight per unit area: 271 g/m 2 ). The inner layer yarn (pile) of the obtained fabric is subjected to final raising processing by using a card clothing raising machine. After soaping the obtained fabric, final setting was performed at 130° C. for 90 seconds using a tenter. The surface layer of the obtained fabric is plain stitch, and the inner layer is napped.

(實施例7) 作為表層紗線及中層紗線,使用藉由與實施例5相同之方式製作之紡織線B(賽絡緊密線)。 作為裏層紗線,使用藉由與實施例6相同之方式製作之英式棉紗支數12s紡織線(環錠線)。 依據圖5所示之編織組織圖及表5所示之條件,利用30英吋11G織針之裏毛用單面織機,由表層紗線及中層紗線構成表面之平針線圈,於背面,將裏層紗線跳2針插入至表層紗線而構成絨頭線圈,進行交錯編織,藉此編織形成雙層構造織物(單位面積重量339 g/m2 )。使用針布起毛機,對所獲得之織物之裏層紗線(絨頭)實施最終起毛加工。將所獲得之織物皂洗後,使用拉幅機於130℃下進行90秒最終定型。所獲得之織物之表面層為平針,裏面層為裏起毛。(Example 7) As the surface layer yarn and the middle layer yarn, the spun yarn B (siro compacted yarn) produced in the same manner as in Example 5 was used. As the inner layer yarn, an English cotton count 12s spinning thread (ring-spun thread) produced in the same manner as in Example 6 was used. According to the knitting structure diagram shown in Figure 5 and the conditions shown in Table 5, using a single jersey loom for the inner wool with 30 inches of 11G knitting needles, the flat stitch stitches on the surface are formed by the surface yarn and the middle yarn. The yarn of the inner layer is inserted into the yarn of the outer layer by skipping 2 stitches to form pile loops, and then weaves interlacedly to form a double-layer structure fabric (weight per unit area: 339 g/m 2 ). The inner layer yarn (pile) of the obtained fabric is subjected to final raising processing by using a card clothing raising machine. After soaping the obtained fabric, final setting was performed at 130° C. for 90 seconds using a tenter. The surface layer of the obtained fabric is plain stitch, and the inner layer is napped.

(實施例8) 作為表層紗線及中層紗線,使用藉由與實施例3相同之方式製作之紡織線B(賽絡緊密線)。 作為裏層紗線,使用以如下方式製作者:將普通PP纖維(單絲纖維纖度1.9 dtex、纖維長度38 mm)依序投入混打棉步驟、梳棉步驟、併條步驟、粗紡步驟,而獲得120格令/12 yd之粗紗,使用1股所獲得之由普通PP纖維100質量%構成之粗紗,利用環錠精紡機,賦予28.8倍之牽伸,以撚係數3.4進行撚線而獲得之英式棉紗支數24s之紡織線(環錠線)。 依據圖5所示之編織組織圖及表5所示之條件,利用30英吋11G織針之裏毛用單面織機,由表層紗線及中層紗線構成表面之平針線圈,於背面,將裏層紗線跳2針插入至表層紗線而構成絨頭線圈,進行交錯編織,藉此編織形成雙層構造織物(單位面積重量296 g/m2 )。使用針布起毛機,對所獲得之織物之裏層紗線(絨頭)實施最終起毛加工。將所獲得之織物皂洗後,使用拉幅機於130℃下進行90秒最終定型。所獲得之織物之表面層為平針,裏面層為裏起毛。(Example 8) As the surface layer yarn and the middle layer yarn, the spun yarn B (siro compacted yarn) produced in the same manner as in Example 3 was used. As the inner layer yarn, it is produced in the following way: ordinary PP fiber (single fiber fineness 1.9 dtex, fiber length 38 mm) is put into the cotton blending step, carding step, drawing step, and slubbing step in sequence, and Obtain 120 grains/12 yd roving, use 1 strand of roving made of ordinary PP fiber 100% by mass, use a ring spinning machine, give 28.8 times the draft, and twist the yarn with a twist coefficient of 3.4. Textile thread (ring spun thread) with British cotton count 24s. According to the knitting structure diagram shown in Figure 5 and the conditions shown in Table 5, using a single jersey loom for the inner wool with 30 inches of 11G knitting needles, the flat stitch stitches on the surface are formed by the surface yarn and the middle yarn. The inner layer yarn is inserted into the outer layer yarn by 2 stitches to form pile loops, and interlaced weaving is performed to form a double-layer structure fabric (weight per unit area: 296 g/m 2 ). The inner layer yarn (pile) of the obtained fabric is subjected to final raising processing by using a card clothing raising machine. After soaping the obtained fabric, final setting was performed at 130° C. for 90 seconds using a tenter. The surface layer of the obtained fabric is plain stitch, and the inner layer is napped.

(比較例7) 作為表層紗線及中層紗線,使用由棉(cotton)構成之英式棉紗支數23s之紡織線(空氣精紡絲)。 作為裏層紗線,使用由棉(cotton)構成之英式棉紗支數16s之紡織線(空氣精紡絲)。 依據圖5所示之編織組織圖及表5所示之條件,利用30英吋16G織針之裏毛用單面織機,由表層紗線及中層紗線構成表面之平針線圈,於背面,將裏層紗線跳2針插入至表層紗線而構成絨頭線圈,進行交錯編織,藉此編織形成雙層構造織物(單位面積重量330 g/m2 )。使用針布起毛機,對所獲得之織物之裏層紗線(絨頭)實施最終起毛加工。將所獲得之織物皂洗後,使用拉幅機於130℃下進行90秒最終定型。所獲得之織物之表面層為平針,裏面層為裏起毛。(Comparative Example 7) As the surface layer yarn and the middle layer yarn, a spun yarn (air worsted yarn) made of cotton and having an English cotton count of 23 s was used. As the inner layer yarn, a spun yarn (air-worsted yarn) made of cotton and having an English cotton count of 16s was used. According to the knitting structure chart shown in Figure 5 and the conditions shown in Table 5, using a single jersey loom for the inner wool with 30 inches of 16G knitting needles, the flat stitch loop on the surface is formed by the surface yarn and the middle yarn, and on the back, the The yarn of the inner layer is inserted into the yarn of the outer layer by skipping 2 stitches to form pile loops, which are interlaced to form a double-layer structure fabric (weight per unit area: 330 g/m 2 ). The inner layer yarn (pile) of the obtained fabric is subjected to final raising processing by using a card clothing raising machine. After soaping the obtained fabric, final setting was performed at 130° C. for 90 seconds using a tenter. The surface layer of the obtained fabric is plain stitch, and the inner layer is napped.

(比較例8) 作為表層紗線及中層紗線,使用由棉(cotton)構成之英式棉紗支數18s之紡織線(空氣精紡絲)。 作為裏層紗線,使用由聚酯10質量%及棉(cotton)90質量%構成之英式棉紗支數6s之紡織線(環錠線)。 依據圖5所示之編織組織圖及表5所示之條件,利用30英吋11G織針之裏毛用單面織機,由表層紗線、中層紗線構成表面之平針線圈,於背面,將裏層紗線跳2針插入至表層紗線而構成絨頭線圈,進行交錯編織,藉此編織形成雙層構造織物(單位面積重量330 g/m2 )。使用針布起毛機,對所獲得之織物之裏層紗線(絨頭)實施最終起毛加工。將所獲得之織物皂洗後,使用拉幅機於130℃下進行90秒最終定型。所獲得之織物之表面層為平針,裏面層為裏起毛。(Comparative Example 8) As the surface layer yarn and the middle layer yarn, a spun yarn (air worsted yarn) made of cotton and having an English cotton count of 18s was used. As the inner layer yarn, a spun yarn (ring-spun yarn) with an English cotton count of 6 s composed of 10% by mass of polyester and 90% by mass of cotton was used. According to the knitting structure diagram shown in Figure 5 and the conditions shown in Table 5, using a single-jersey loom for inner wool with 30-inch 11G knitting needles, the flat stitch loops on the surface are formed by the surface yarn and the middle yarn. The yarn of the inner layer is inserted into the yarn of the outer layer by skipping 2 stitches to form pile loops, which are interlaced to form a double-layer structure fabric (weight per unit area: 330 g/m 2 ). The inner layer yarn (pile) of the obtained fabric is subjected to final raising processing by using a card clothing raising machine. After soaping the obtained fabric, final setting was performed at 130° C. for 90 seconds using a tenter. The surface layer of the obtained fabric is plain stitch, and the inner layer is napped.

對實施例6~8之織物之表面層進行如上所述之起毛球試驗,將其結果示於下述表5。又,如上所述般測定實施例6~8及比較例7~8之織物之保溫性及洗滌乾燥性,將其結果示於下述表5。The above-mentioned pilling test was performed on the surface layers of the fabrics of Examples 6 to 8, and the results are shown in Table 5 below. Also, the heat retention and washing and drying properties of the fabrics of Examples 6 to 8 and Comparative Examples 7 to 8 were measured as described above, and the results are shown in Table 5 below.

[表5]

Figure 108103266-A0304-0005
[table 5]
Figure 108103266-A0304-0005

根據上述表5,可知:實施例6~8之織物之抗起毛球性良好。又,由水分率為0.15質量%以上之經親水化之聚丙烯系纖維B構成表面層、由疏水性之聚丙烯系纖維構成裏面層之實施例6~8之織物不僅保溫性優異,且洗滌乾燥性良好。According to the above Table 5, it can be seen that the anti-pilling properties of the fabrics of Examples 6-8 are good. In addition, the fabrics of Examples 6 to 8, in which the surface layer is composed of the hydrophilized polypropylene fiber B with a moisture content of 0.15% by mass or more, and the back layer is composed of hydrophobic polypropylene fiber, are not only excellent in heat retention, but also washable. Good drying properties.

(實施例9) 使用聚酯複絲(111 dtex、單絲纖維數144根、單絲纖維纖度0.77 dtex)作為表面層用紗線,使用藉由與實施例3相同之方式製作之紡織線B作為裏面層用紗線,依據圖6所示之編織組織圖,利用34英吋24G織針之雙面織機,編織形成表面為平針組織、背面為蜂巢構造之雙面織物(單位面積重量179 g/m2 )。纖維混合率:聚酯纖維43質量%、水分率為0.3質量%之聚丙烯系纖維57質量%。將所獲得之織物精練後,使用陽離子染料與聚酯用吸水劑(日華化學公司製造,商品名NICEPOLE PR-99),藉由同浴進行125℃、40分鐘之染色及吸水加工,其後,進行最終吸水。經親水化之疏水性纖維(聚酯纖維)之水分率為0.7質量%,親水化程度(經親水化之疏水性纖維之水分率與疏水性纖維之公定水分率之差)為0.3質量%。(Example 9) Polyester multifilament (111 dtex, 144 filaments per filament, 0.77 dtex per filament) was used as the yarn for the surface layer, and textile yarn B produced in the same manner as in Example 3 was used. As the yarn for the inner layer, according to the weaving structure diagram shown in Figure 6, use a double-sided loom with 34 inches of 24G knitting needles to weave to form a double-sided fabric with a plain stitch on the surface and a honeycomb structure on the back (the weight per unit area is 179 g /m 2 ). Fiber mixing ratio: 43% by mass of polyester fiber, 57% by mass of polypropylene-based fiber with a moisture content of 0.3% by mass. After scouring the obtained fabric, use cationic dye and polyester water-absorbing agent (manufactured by Nichika Chemical Co., Ltd., trade name NICEPOLE PR-99) to perform dyeing and water-absorbing processing at 125°C for 40 minutes in the same bath, and then , for final water absorption. The moisture content of the hydrophilized hydrophobic fiber (polyester fiber) is 0.7% by mass, and the degree of hydrophilization (difference between the moisture content of the hydrophilized hydrophobic fiber and the conventional moisture content of the hydrophobic fiber) is 0.3% by mass.

(比較例9) 使用藉由與比較例1相同之方式製作之由普通PP纖維2(白色)100質量%構成環錠線(以下亦記為PP環錠線)作為裏面層用紗線,除此以外,藉由與實施例9相同之方法編織形成雙面織物(單位面積重量167 g/m2 )。纖維混合率:聚酯纖維43質量%、水分率為0.1質量%之聚丙烯纖維57質量%。藉由與實施例9相同之方法對所獲得之織物進行加工。經親水化之疏水性纖維(聚酯纖維)之水分率為0.7質量%,親水化程度(經親水化之疏水性纖維之水分率與疏水性纖維之公定水分率之差)為0.3質量%。(Comparative Example 9) A ring-spun yarn made of 100% by mass of ordinary PP fiber 2 (white) (hereinafter also referred to as PP ring-spun yarn) produced in the same manner as in Comparative Example 1 was used as the yarn for the back layer, except Otherwise, a double-sided fabric (weight per unit area: 167 g/m 2 ) was woven by the same method as in Example 9. Fiber mixing rate: 43% by mass of polyester fiber, 57% by mass of polypropylene fiber with a moisture content of 0.1% by mass. The obtained fabric was processed by the same method as in Example 9. The moisture content of the hydrophilized hydrophobic fiber (polyester fiber) is 0.7% by mass, and the degree of hydrophilization (difference between the moisture content of the hydrophilized hydrophobic fiber and the conventional moisture content of the hydrophobic fiber) is 0.3% by mass.

對實施例9之織物之裏面層進行如上所述之起毛球試驗,將其結果示於下述表6。對實施例9及比較例9之織物進行吸水速乾性評價1,將其評價結果(蒸散率)示於下述表6。對實施例9及比較例9之織物進行初期及洗滌10次後之吸水速乾性評價2,將評價結果示於下述表6。亦於下述表6中記載織物之單位面積重量與厚度。對實施例9及比較例9之織物進行吸水速乾性評價3,將評價結果示於表6。The inner layer of the fabric of Example 9 was subjected to the above-mentioned pilling test, and the results are shown in Table 6 below. Water absorption and quick-drying evaluation 1 was performed on the fabrics of Example 9 and Comparative Example 9, and the evaluation results (evapotranspiration rate) are shown in Table 6 below. The fabrics of Example 9 and Comparative Example 9 were subjected to water absorption and quick-drying evaluation 2 at the initial stage and after 10 washes, and the evaluation results are shown in Table 6 below. The basis weight and thickness of the fabrics are also reported in Table 6 below. Water absorption and quick-drying evaluation 3 was performed on the fabrics of Example 9 and Comparative Example 9, and the evaluation results are shown in Table 6.

[表6]

Figure 108103266-A0304-0006
[Table 6]
Figure 108103266-A0304-0006

根據上述表6之結果,可知:實施例9之布帛之抗起毛球性良好。又,實施例9之布帛之蒸散性較高。實施例9尤其於蒸散性(II)試驗之蒸散率優異。認為實施例9之布帛蒸散性優異之原因在於,MMT試驗中之裏面層(肌面)之吸水速度較快,因此水分順利轉移,而自表面層蒸散。另一方面,比較例9中之聚丙烯纖維之水分率為0.1質量%,因此濕潤性明顯較低,蒸散率較低。又,於蒸散性(I)試驗中,確認實施例9之布帛於初期(未經洗滌)與經10次洗滌時洗滌之吸水速乾之耐久性。其結果,初期之蒸散率與經10次洗滌後之蒸散率相同,由此可確認具有洗滌耐久性。From the results in Table 6 above, it can be seen that the fabric of Example 9 has good pilling resistance. Also, the fabric of Example 9 had high transpiration properties. Example 9 is especially excellent in the evapotranspiration rate in the evapotranspiration (II) test. It is considered that the reason for the excellent transpiration of the fabric of Example 9 is that the water absorption rate of the inner layer (skin surface) in the MMT test is relatively fast, so the water is transferred smoothly and evaporated from the surface layer. On the other hand, the moisture content of the polypropylene fibers in Comparative Example 9 was 0.1% by mass, so the wettability was significantly low and the evaporation rate was low. Also, in the evaporability (I) test, the durability of water absorption and quick-drying of the fabric of Example 9 at the initial stage (unwashed) and after 10 washes was confirmed. As a result, the initial evapotranspiration rate was the same as the evapotranspiration rate after 10 washes, and it was confirmed that it had washing durability.

(實施例10) 使用藉由與實施例3相同之方式獲得之紡織線B(以下亦記為「PP40」)及聚酯複絲(33 dtex、單絲纖維數24根,以下亦記為「30d/24F」)作為表面層及裏面層用紗線,使用聚酯單絲(33.3 dtex,以下亦記為「30d/1F」)作為接結線,依據圖7A及圖7B所示之編織組織圖(編織方法圖)及下述表7所示之條件,利用34英吋18G織針之雙面織機,編織形成表面為平針組織、背面為蜂巢構造之瓦楞織之織物(單位面積重量281 g/m2 )。纖維混合率:親水化PP纖維1(黑色)69.8質量%、聚酯纖維30.2質量%。將所獲得之織物皂洗後,使用拉幅機於130℃下進行90秒最終定型。(Example 10) The textile yarn B obtained in the same manner as in Example 3 (hereinafter also referred to as "PP40") and polyester multifilament (33 dtex, the number of single filament fibers is 24, hereinafter also referred to as "PP40") was used. 30d/24F") as the yarn for the surface layer and the inner layer, using polyester monofilament (33.3 dtex, hereinafter also referred to as "30d/1F") as the binding thread, according to the weaving diagram shown in Figure 7A and Figure 7B (Weaving method diagram) and the conditions shown in Table 7 below, use a double-sided loom with 34 inches of 18G knitting needles to weave a corrugated fabric with a plain stitch on the surface and a honeycomb structure on the back (the weight per unit area is 281 g/ m 2 ). Fiber mixing ratio: hydrophilized PP fiber 1 (black) 69.8% by mass, polyester fiber 30.2% by mass. After soaping the obtained fabric, final setting was performed at 130° C. for 90 seconds using a tenter.

(實施例11) 使用由以與實施例4相同之方式獲得之紡織線B(以下亦記為「PP40(淡灰色花紋)」)與聚胺基甲酸酯纖維紗線(低溫聚胺基甲酸酯彈性纖維,Nisshinbo Textile公司製造之「MOBILON MTR22-R」,22 dtex,以下亦記為「Pu20d」)併紗而成者作為表面層及裏面層用紗線,使用聚酯單絲(30d/1F)作為接結線,依據圖8A及圖8B所示之編織組織圖(編織方法圖)及下述表8所示之條件,利用34英吋24G織針之雙面織機,編織形成表面為平針組織、背面為網狀構造之瓦楞織之織物(單位面積重量387 g/m2 )。纖維混合率:親水化PP纖維(黑色)6.2質量%、普通PP纖維71.3質量%、聚酯纖維18.7質量%、聚胺基甲酸酯纖維3.8質量%。將所獲得之織物皂洗後,使用拉幅機於130℃下進行90秒最終定型。(Example 11) The textile yarn B obtained in the same manner as in Example 4 (hereinafter also referred to as "PP40 (light gray pattern)") and polyurethane fiber yarn (low temperature polyurethane Ester elastic fiber, "MOBILON MTR22-R" manufactured by Nisshinbo Textile Co., Ltd., 22 dtex, hereinafter also referred to as "Pu20d") and yarns are used as the yarn for the surface layer and the back layer, and polyester monofilament (30d /1F) As a binding thread, according to the knitting structure diagram (knitting method diagram) shown in Figure 8A and Figure 8B and the conditions shown in the following Table 8, using a double-sided loom with 34-inch 24G knitting needles, the knitting surface is Plain knit, corrugated fabric with mesh structure on the back (weight per unit area: 387 g/m 2 ). Fiber mixing rate: hydrophilized PP fiber (black) 6.2% by mass, normal PP fiber 71.3% by mass, polyester fiber 18.7% by mass, polyurethane fiber 3.8% by mass. After soaping the obtained fabric, final setting was performed at 130° C. for 90 seconds using a tenter.

(比較例10) 使用精梳紗線(支數40,以下亦記為「CM40」)及聚酯複絲(30d/24F)作為表面層及裏面層用紗線,除此以外,藉由與實施例10相同之方式編織形成表面為平針組織、背面為蜂巢構造之瓦楞織之織物(單位面積重量261 g/m2 )。具體之編織條件如下述表9所示。纖維混合率:棉纖維67.3質量%、聚酯纖維32.7質量%。將所獲得之織物皂洗後,使用拉幅機於130℃下進行一次90秒最終定型。(Comparative Example 10) In addition to using combed yarn (count 40, hereinafter also referred to as "CM40") and polyester multifilament (30d/24F) as the yarn for the surface layer and the back layer, by In the same manner as in Example 10, a corrugated fabric with plain stitch on the surface and honeycomb structure on the back (weight per unit area: 261 g/m 2 ) was formed. The specific knitting conditions are shown in Table 9 below. Fiber mixing rate: 67.3% by mass of cotton fiber and 32.7% by mass of polyester fiber. After soaping the obtained fabric, final setting was performed once at 130° C. for 90 seconds using a tenter.

(比較例11) 使用由精梳紗線(CM40)與聚胺基甲酸酯纖維紗線(Pu20d)併紗而成者作為表面層用紗線,使用由以與比較例1相同之方式獲得之由普通PP纖維2(白色)100質量%構成環錠線(以下亦記為「PP40/R」)與聚胺基甲酸酯纖維紗線(Pu20d)併紗而成者作為裏面層用紗線,除此以外,藉由與實施例11相同之方式編織形成表面為平針組織、背面為網狀構造之瓦楞織之織物(單位面積重量348 g/m2 )。具體之編織條件如下述表10所示。纖維混合率:棉32.6質量%、普通PP纖維2(白色)44.9質量%、聚酯纖維18.7質量%、聚胺基甲酸酯纖維3.8質量%。將所獲得之織物皂洗後,使用拉幅機於130℃下進行兩次各90秒之最終定型。(Comparative Example 11) Combed yarn (CM40) and polyurethane fiber yarn (Pu20d) doubling were used as the yarn for the surface layer. The ring-spun yarn (hereinafter also referred to as "PP40/R") and polyurethane fiber yarn (Pu20d) composed of 100% by mass of ordinary PP fiber 2 (white) is used as the yarn for the inner layer Except for the thread, a corrugated fabric (weight per unit area: 348 g/m 2 ) was formed by knitting in the same manner as in Example 11, with a plain stitch on the surface and a mesh structure on the back. The specific knitting conditions are shown in Table 10 below. Fiber mixing rate: 32.6% by mass of cotton, 44.9% by mass of ordinary PP fiber 2 (white), 18.7% by mass of polyester fiber, and 3.8% by mass of polyurethane fiber. After soaping the obtained fabric, final setting was performed twice at 130° C. for 90 seconds each using a tenter.

(比較例12) 使用精梳紗線(支數30,以下亦記為「CM30」)作為表面層及裏面層用紗線,使用聚酯複絲(83 dtex、單絲纖維數48根,以下亦記為「75d/48F」)作為接結線,依據圖9所示之編織組織圖(編織方法圖)及下述表11所示之條件,利用34英吋24G織針之雙面織機,編織形成瓦楞織之織物(單位面積重量285 g/m2 )。纖維混合率:棉纖維76質量%、聚酯纖維24質量%。將所獲得之織物皂洗後,使用拉幅機於130℃下進行90秒最終定型。(Comparative Example 12) A combed yarn (count 30, hereinafter also referred to as "CM30") was used as the yarn for the surface layer and the back layer, and polyester multifilament (83 dtex, 48 filaments per filament, below Also denoted as "75d/48F") as a binding thread, according to the knitting structure diagram (knitting method diagram) shown in Figure 9 and the conditions shown in the following Table 11, use a double-sided loom with 34 inches 24G knitting needles to knit Form corrugated fabric (weight per unit area 285 g/m 2 ). Fiber mixing rate: 76% by mass of cotton fiber and 24% by mass of polyester fiber. After soaping the obtained fabric, final setting was performed at 130° C. for 90 seconds using a tenter.

[表7]

Figure 108103266-A0304-0007
[Table 7]
Figure 108103266-A0304-0007

[表8]

Figure 108103266-A0304-0008
[Table 8]
Figure 108103266-A0304-0008

[表9]

Figure 108103266-A0304-0009
[Table 9]
Figure 108103266-A0304-0009

[表10]

Figure 108103266-A0304-0010
[Table 10]
Figure 108103266-A0304-0010

[表11]

Figure 108103266-A0304-0011
[Table 11]
Figure 108103266-A0304-0011

對實施例10、11及比較例10~12之織物之表面層及裏面層進行如上所述之起毛球試驗,將其結果示於下述表12。如上所述般測定實施例10、11及比較例10~12之織物之厚度、總體密度、保溫率、洗滌乾燥性、吸水性及透氣性,將其結果示於下述表12。於下述表12中亦一併顯示線圈橫列數及線圈縱行數。The above-mentioned pilling test was performed on the surface layer and the back layer of the fabrics of Examples 10 and 11 and Comparative Examples 10 to 12, and the results are shown in Table 12 below. The thickness, overall density, heat retention rate, washing and drying property, water absorption and air permeability of the fabrics of Examples 10, 11 and Comparative Examples 10 to 12 were measured as described above, and the results are shown in Table 12 below. In Table 12 below, the number of courses and the number of wales are also shown together.

[表12]

Figure 108103266-A0304-0012
[Table 12]
Figure 108103266-A0304-0012

根據上述表12之結果,可知:實施例10、11之織物之抗起毛球性良好。又,實施例10、11之織物不僅保溫性較高,且輕量性及洗滌乾燥性良好。According to the results in Table 12 above, it can be seen that the fabrics of Examples 10 and 11 have good pilling resistance. In addition, the fabrics of Examples 10 and 11 not only have high heat retention, but also have good lightness and washing and drying properties.

通常情況下,若增大接結線之給紗比率(接結線之線圈長度(cm/100針)÷表面層紗線之線圈長度(cm/100針))則布料厚度增加,但和實施例10、11及比較例10~11相比,使用複絲作為接結線之比較例12雖然給紗比率最高,厚度卻最小。因此,總體密度為0.248 g/cm3 ,單絲使用量約2倍以上,輕量性較差。再者,於表面層及裏面層插入聚胺基甲酸酯纖維紗線之情形時,出現線圈重疊,輕量性較差,但另一方面保溫性提高。Normally, if the yarn feeding ratio of the binding thread is increased (the loop length of the binding thread (cm/100 needles) ÷ the loop length of the surface layer yarn (cm/100 needles)), the thickness of the fabric increases, but the same as in Example 10 , 11 and Comparative Examples 10 to 11, although Comparative Example 12 using multifilament as the binding thread has the highest yarn feeding ratio, the thickness is the smallest. Therefore, the overall density is 0.248 g/cm 3 , and the amount of monofilament used is more than twice that of light weight. Furthermore, when the polyurethane fiber yarn is inserted in the surface layer and the back layer, loops overlap, and the lightness is poor, but on the other hand, the heat retention property is improved.

實施例10及比較例10之織物為表面平針組織、背面蜂巢構造之相同組織,未配置聚胺基甲酸酯之織物具有良好之透氣性,因此洗滌乾燥性均較佳,但配置有雙層親水化聚丙烯系纖維之實施例10之洗滌乾燥性提高顯著,90分鐘後之乾燥率為比較例10之2倍。The fabrics of Example 10 and Comparative Example 10 are the same fabric with plain stitch on the surface and honeycomb structure on the back. The fabric without polyurethane has good air permeability, so the washing and drying properties are better, but it is equipped with double layers The washing and drying property of Example 10 of the hydrophilized polypropylene fiber is significantly improved, and the drying rate after 90 minutes is twice that of Comparative Example 10.

1a、1b‧‧‧粗紗 2a、2b‧‧‧經牽伸之粗紗(纖維束) 10‧‧‧紡織線 101‧‧‧導紗桿 102‧‧‧喇叭環 103‧‧‧後輥 104‧‧‧中輥 105‧‧‧皮圈 106‧‧‧前輥 107‧‧‧空氣抽吸部 108‧‧‧透氣皮圈 109‧‧‧旋轉輥 110‧‧‧輔助輥 111‧‧‧導紗鉤 112‧‧‧鋼絲圈 113‧‧‧環 201‧‧‧擠出機 202‧‧‧原料供給口 203‧‧‧樹脂熔融部 204‧‧‧混練分散部 205‧‧‧減壓管線 206‧‧‧擠出部 207‧‧‧取出部1a, 1b‧‧‧roving 2a, 2b‧‧‧Drawn roving (fiber bundle) 10‧‧‧Textile thread 101‧‧‧Yam guide rod 102‧‧‧Horn ring 103‧‧‧Rear roller 104‧‧‧Medium Roller 105‧‧‧Leather 106‧‧‧Front roller 107‧‧‧Air suction part 108‧‧‧breathable apron 109‧‧‧rotating roller 110‧‧‧Auxiliary roller 111‧‧‧Yam guide hook 112‧‧‧Traveler 113‧‧‧ring 201‧‧‧Extruder 202‧‧‧Raw material supply port 203‧‧‧Resin melting part 204‧‧‧mixing and dispersing department 205‧‧‧Decompression pipeline 206‧‧‧Extrusion Department 207‧‧‧Extraction Department

圖1係本發明之一實施形態中使用之一例之環錠精紡機之局部立體圖。 圖2係本發明之一實施形態中使用之一例之擠出機之示意性說明圖。 圖3係對本發明之一實施形態中之紡織線之撚角進行說明之紡織線之側面照片。 圖4係對本發明之一實施形態中之紡織線之直徑進行說明之紡織線之側面照片。 圖5係實施例6~8及比較例7~8中採用之編織組織圖。 圖6係實施例9中採用之編織組織圖。 圖7A係實施例10中採用之編織組織圖之局部圖。 圖7B係實施例10中採用之編織組織圖之局部圖。 圖8A係實施例11中採用之編織組織圖之局部圖。 圖8B係實施例11中採用之編織組織圖之局部圖。 圖9係比較例12中採用之編織組織圖。Fig. 1 is a partial perspective view of an example of a ring spinning machine used in an embodiment of the present invention. Fig. 2 is a schematic explanatory diagram of an example of an extruder used in an embodiment of the present invention. Fig. 3 is a side photograph of a spun yarn illustrating the lay angle of the spun yarn in one embodiment of the present invention. Fig. 4 is a side view of a textile thread illustrating the diameter of the textile thread in one embodiment of the present invention. Fig. 5 is the knitting structure chart that adopts in embodiment 6~8 and comparative example 7~8. Fig. 6 is a diagram of the weaving structure adopted in embodiment 9. Fig. 7A is a partial view of a weaving structure diagram used in Example 10. Fig. 7B is a partial view of the weaving structure chart adopted in Example 10. Fig. 8A is a partial view of a weaving structure diagram used in Example 11. Fig. 8B is a partial diagram of the weaving structure chart adopted in the eleventh embodiment. FIG. 9 is a diagram of a weaving structure used in Comparative Example 12. FIG.

1a、1b:粗紗 1a, 1b: Roving

2a、2b:經牽伸之粗紗(纖維束) 2a, 2b: Drawn roving (fiber bundle)

10:紡織線 10: textile thread

101:導紗桿 101: guide rod

102:喇叭環 102: horn ring

103:後輥 103: Rear roller

104:中輥 104: middle roller

105:皮圈 105: apron

106:前輥 106: front roller

107:空氣抽吸部 107: Air suction part

108:透氣皮圈 108: breathable apron

109:旋轉輥 109:Rotary roller

110:輔助輥 110: auxiliary roller

111:導紗鉤 111: guide hook

112:鋼絲圈 112: Traveler

113:環 113: ring

Claims (13)

一種紡織線,其係包含大於50質量%之依據JIS L 1015(2010)測定之水分率未達0.15質量%之聚丙烯系纖維者,其特徵在於:依據JIS L 1095(2010)9.22.2 B法測定之上述紡織線每10m中存在之長度3mm以上之細毛數為40根/10m以下,上述紡織線之氣孔率為40~65%,撚係數為2.4~6.0。 A textile thread comprising more than 50% by mass of polypropylene-based fibers with a moisture content of less than 0.15% by mass measured according to JIS L 1015 (2010), characterized in that: according to JIS L 1095 (2010) 9.22.2 B The number of fine hairs with a length of more than 3mm in each 10m of the above-mentioned textile thread measured by the method is 40/10m or less, the porosity of the above-mentioned textile thread is 40-65%, and the twist coefficient is 2.4-6.0. 一種紡織線,其係包含5質量%以上之聚丙烯系纖維者,其特徵在於:上述聚丙烯系纖維依據JIS L 1015(2010)測定之水分率為0.15質量%以上,依據JIS L 1095(2010)9.22.2 B法測定之上述紡織線每10m中存在之長度3mm以上之細毛數為40根/10m以下,上述紡織線之氣孔率為40~65%,撚係數為2.4~6.0。 A textile thread comprising at least 5% by mass of polypropylene-based fibers, wherein the polypropylene-based fibers have a moisture content of at least 0.15% by mass as measured in accordance with JIS L 1015 (2010), and in accordance with JIS L 1095 (2010) ) 9.22.2 The number of fine hairs with a length of more than 3mm per 10m of the above-mentioned textile thread measured by B method is less than 40/10m, the porosity of the above-mentioned textile thread is 40-65%, and the twist coefficient is 2.4-6.0. 如請求項1或2所述之紡織線,其中,上述紡織線之撚角為23°以上。 The textile yarn according to claim 1 or 2, wherein the twist angle of the textile yarn is 23° or more. 一種紡織線,其係包含大於50質量%之依據JIS L 1015(2010)測定之水分率未達0.15質量%之聚丙烯系纖維者,其特徵在於:依據JIS L 1095(2010)9.22.2 B法測定之上述紡織線每10m中存在之長度3mm以上之細毛數為40根/10m以下,上述紡織線之撚角為23°以上。 A textile thread comprising more than 50% by mass of polypropylene-based fibers with a moisture content of less than 0.15% by mass measured according to JIS L 1015 (2010), characterized in that: according to JIS L 1095 (2010) 9.22.2 B The number of fine hairs with a length of 3mm or more per 10m of the above-mentioned textile thread measured by the method is 40 or less per 10m, and the twist angle of the above-mentioned textile thread is 23° or more. 一種紡織線,其係包含5質量%以上之聚丙烯系纖維者,其特徵在於:上述聚丙烯系纖維依據JIS L 1015(2010)測定之水分率為0.15質量%以上, 依據JIS L 1095(2010)9.22.2 B法測定之上述紡織線每10m中存在之長度3mm以上之細毛數為40根/10m以下,上述紡織線之撚角為23°以上。 A textile thread comprising more than 5% by mass of polypropylene-based fibers, wherein the moisture content of the polypropylene-based fibers measured in accordance with JIS L 1015 (2010) is 0.15% by mass or more, According to JIS L 1095 (2010) 9.22.2 B method, the number of fine hairs with a length of 3mm or more per 10m of the above-mentioned textile thread is 40 or less per 10m, and the twist angle of the above-mentioned textile thread is 23° or more. 如請求項1、2、4、5中任一項所述之紡織線,其中,上述紡織線係由兩股纖維束構成之撚合線。 The textile yarn according to any one of claims 1, 2, 4, and 5, wherein the textile yarn is a twisted yarn composed of two fiber bundles. 如請求項2或5所述之紡織線,其中,上述聚丙烯系纖維含有相對於聚丙烯成分100質量份為0.025~0.25質量份之親水性成分。 The textile thread according to claim 2 or 5, wherein the polypropylene-based fiber contains 0.025 to 0.25 parts by mass of a hydrophilic component relative to 100 parts by mass of the polypropylene component. 如請求項7所述之紡織線,其中,上述親水性成分包含非離子界面活性劑。 The spun yarn according to claim 7, wherein the hydrophilic component contains a nonionic surfactant. 一種紡織線之製造方法,其係製造如請求項1或4所述之紡織線之方法,其特徵在於:於環錠精紡中包括如下步驟:準備至少一股包含大於50質量%之依據JIS L 1015(2010)測定之水分率未達0.15質量%之聚丙烯系纖維之粗紗A;向牽伸區供給含有至少一股粗紗A之兩股粗紗進行牽伸後,一面併紗一面向撚線區供給;及利用空氣沿粗紗之行進方向抽吸剛供給至撚線區後之兩股粗紗而使纖維收攏後進行撚線。 A method for manufacturing a textile thread, which is a method for manufacturing the textile thread as described in claim 1 or 4, characterized in that: ring spinning includes the following steps: preparing at least one strand containing more than 50% by mass according to JIS Roving A of polypropylene-based fibers whose moisture content as measured in L 1015(2010) is less than 0.15% by mass; two rovings containing at least one roving A are supplied to the drafting zone for drafting, and one side is paralleled and the other is twisted Zone supply; and use air to suck the two strands of roving just supplied to the twisting zone along the traveling direction of the roving so that the fibers are gathered and then twisted. 一種紡織線之製造方法,其係製造如請求項2或5所述之紡織線之方法,其特徵在於:於環錠精紡中包括如下步驟:準備至少一股包含5質量%以上之聚丙烯系纖維之粗紗B;向牽伸區供給含有至少一股粗紗B之兩股粗紗進行牽伸後,一面併紗一面向撚線區供給;及 利用空氣沿粗紗之行進方向抽吸剛供給至撚線區後之兩股粗紗而使纖維收攏後進行撚線;上述聚丙烯系纖維依據JIS L 1015(2010)測定之水分率為0.15質量%以上。 A method for manufacturing a textile thread, which is a method for manufacturing the textile thread as described in claim 2 or 5, characterized in that: ring spinning includes the following steps: preparing at least one strand of polypropylene containing more than 5% by mass Fiber-based roving B; two rovings containing at least one roving B are supplied to the drafting zone for drafting, and one side is doubling and the other is supplied to the twisting zone; and The two strands of roving immediately supplied to the twisting zone are sucked by air along the traveling direction of the roving to gather the fibers and twist them; the moisture content of the above-mentioned polypropylene-based fibers measured in accordance with JIS L 1015 (2010) is 0.15% by mass or more . 一種布帛,其包含如請求項1至8中任一項所述之紡織線。 A fabric comprising the textile thread according to any one of claims 1 to 8. 如請求項11所述之布帛,其中,上述布帛含有表面層與裏面層,選自由表面層及裏面層所組成之群中之一種以上之層包含如請求項1至8中任一項所述之紡織線。 The fabric according to claim 11, wherein the fabric includes a surface layer and an inner layer, and one or more layers selected from the group consisting of the surface layer and the inner layer include any one of claims 1 to 8. The textile thread. 如請求項11或12所述之布帛,其中,上述布帛係由表面層、裏面層、及連結其等之接結線所構成之衣料用織物,選自由表面層及裏面層所組成之群中之一種以上之層包含如請求項1至8中任一項所述之紡織線。 The fabric according to claim 11 or 12, wherein the fabric is a fabric for clothing consisting of a surface layer, a back layer, and a tie thread connecting them, and is selected from the group consisting of the surface layer and the back layer More than one layer comprises the textile thread according to any one of claims 1-8.
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