TWI742838B - Cleaner formula with calcium oxide component of biological shell and preparation method thereof - Google Patents

Abstract

The present invention is a detergent formula with calcium oxide component of biological shell and a preparation method thereof. The formula includes a total weight percentage of 0.01%-1% natural biological shell calcium oxide, 1%-30% moisturizer, and 10% -90% purified water, acid-base regulator 1%~5%, and any one or more of surfactant 0%-50%, emulsifier 0%-20%, thickener 0%-30% The combination of ingredients. After mixing the above formula uniformly according to the steps, the resulting detergent is suitable for cleaning the human body, food, clothing, and the environment, and takes into account the requirements of disinfection and environmental protection. In particular, the detergent uses natural biological shells as raw materials, except In addition to excellent cleaning and sterilization effects, it also has the advantages of not harming organisms, humans and the environment.

Description

Cleaner formula with calcium oxide component of biological shell and preparation method thereof

The invention relates to a green environmentally friendly cleaning agent product, in particular to a cleaning agent with a natural biological shell calcium oxide source and a preparation method thereof.

Bacteria are the pathogens of many infectious diseases; in order to avoid the health and environmental concerns caused by bacteria, many antibacterial agents have been put on the market, including alcohol, strong acid, strong alkali, bleach, silver ion and other types.

After calcium oxide is dissolved in water, it will be converted into calcium hydroxide aqueous solution under the induction of hydroxyl groups in the water, which has excellent antibacterial effect. In the early years, it was believed that the antibacterial effect of calcium hydroxide aqueous solution came from its strong alkali characteristics, but recent studies have pointed out that the antibacterial effect of calcium hydroxide aqueous solution is significantly better than that of sodium hydroxide with the same pH value, which represents another antibacterial effect. There are reasons.

Studies have pointed out that when calcium oxide reacts with hydroxyl groups, it will release many superoxide anions, which are so-called reactive oxygen species. Active oxygen can attack the macromolecules of organisms, such as protein and DNA, etc., so it can destroy the virus or bacteria shells that come into contact with it, achieving the effect of antibacterial and disinfection, and its effect is better than alcohol.

According to the above research, there are products in the market based on the characteristics of calcium oxide, and powdered calcium oxide is sold for consumers to dissolve and use by themselves. However, when consumers dissolve powdered calcium oxide products on their own, there will be safety and use concerns. For example: Excessive calcium oxide will release greater heat energy when mixed with water. If the pH of the solution is too high, it will also have an adverse effect on skin contact.

Although known literature points out that it is better to dissolve 1 gram of calcium oxide in 1 liter of water when making a bacteriostatic agent with calcium oxide, but the user may not have relevant professional knowledge, and it is easy for people to make it at home. Insufficient weighing tools and wrong modulation indicate that the risk of consumers' self-operation is quite high. Therefore, it is reasonable to develop finished formulas that are safe and convenient to use, and reduce the trouble and danger of self-preparation by the people.

In addition, the calcium hydroxide aqueous solution is an aqueous solution containing part of the precipitate, which has strong alkali properties and antibacterial properties, but the effect of cleaning oil stains is limited. Therefore, when cleaning the body or the environment, additional soap components are required; furthermore, hydrogen Calcium oxide aqueous solution has extremely low viscosity and is a dosage form with fairly high fluidity, which is not easy to control in use, so it is appropriate to improve the dosage form formula.

It is worth mentioning that Taiwan is located on an island. Shellfish has been cultivated on the west coast for many years. The annual production of oyster shells is as high as 160,000 metric tons. However, only a small amount is used for building materials and poultry feed, and the added value is quite low. However, 95% of the components of shells are calcium carbonate, which can be converted into calcium oxide after calcination. If the remanufactured shells can be used in household products, the added value of these aquatic wastes can be increased and recycled.

In view of the fact that calcium oxide has a sterilization effect, the existing technology fails to meet market needs in terms of safety, convenience and environmental protection. The inventor has accumulated many years of research and practical experience in related fields and created A detergent formula with calcium oxide components in a biological shell and a preparation method thereof can effectively overcome the deficiencies of the prior art.

Specifically, the present invention is to produce a detergent formula and its preparation method according to the existing market needs. Through accurate calculation of the component ratio and step modulation, it can take into account the aspects of safety, cleaning, antibacterial, etc., and does not affect the environment and the health of users. , Which effectively overcomes the safety concerns caused by consumers when they configure themselves; in addition, the use of first-class industrial waste in the formula is more environmentally friendly.

In order to achieve the above-mentioned purpose, the present invention is a cleaning agent formula with calcium oxide in the biological shell. The water is 10%-90% by weight, the acid-base regulator is 1%~5% by weight; and optionally any one or a combination of the following components: Surfactant is 0%-50% by weight, The emulsifier is 0%-20% by weight, and the thickener is 0%-30% by weight.

The following is a further description of the implementation of each component: When implemented, the biological shell calcium oxide is made from shells or egg shells at 800-1,500°C After being calcined at high temperature, it is extracted through sieving and grinding; the particle size of calcium oxide ranges from 50 to 10,000 mesh.

In practice, the surfactants are alkyl glucosides, sulfosuccinates, TEA N-cocoyl glutamate, and α-olefin sulfonates. Α-olefin sulfonate, mono alkyl phosphate, polyoxyethylene fatty acid ester, alkyl betaine, alkyl amine betaine alkyl amide betaine) any one or a combination of them.

In practice, the emulsifier is composed of any one of polyglyceryl-3 stearate, cetyl alcohol, lecithin, glyceryl monostearate or Multiple combinations.

In implementation, the moisturizer is composed of any one or a combination of polyols, polymer polysaccharides, and amino acids.

In implementation, the thickening agent is composed of any one or a combination of polymer glue, polymer polysaccharide, and polyquaternary ammonium salt polymer.

When implemented, the detergent formulation can be liquid, milky or muddy.

In implementation, the purified water is drinking water or deionized water that meets drinking standards.

The present invention also provides a cleaning agent preparation method based on the above formula, including the following steps: (1) mixing biological shell calcium oxide with purified water; (2) mixing the mixed liquid obtained in step (1) at room temperature Quickly mix the humectant and the acid-base regulator, and optionally take any one or more of the following ingredients and mix until completely dissolved: surfactant, emulsifier, thickener.

In implementation, when the step (2) selects a surfactant, it further includes: (3) slowly mixing the mixed liquid obtained in step (2) with the surfactant at room temperature until it is completely dissolved.

Compared with the prior art, the present invention provides a formula that uses natural biological shells as raw materials. In addition to having excellent cleaning and sterilization effects and reducing the impact of strong alkalis on the body during use, it is also environmentally friendly and does not harm organisms. The advantages of the human body and the environment, and provide various formulation designs, improve the flexibility of use, and can effectively avoid the danger caused by the user's self-adjustment.

Hereinafter, according to the technical means of the present invention, the following is a list of embodiments suitable for the present invention:

The present invention is a cleaning agent formula with calcium oxide component of biological shell. Its components include: calcium oxide of biological shell is 0.01%-1% by weight, moisturizer is 1%-30% by weight, and purified water is taken by weight percentage. 10%-90%, the weight percentage of acid-base regulator is 1%-5%, and optionally any one or a combination of the following components: surfactant weight percentage 0%-50%, emulsifier weight percentage 0% -20%, the weight percentage of thickener is 0%-30%.

Among them, the biological shell calcium oxide is extracted from natural shells or egg shells after being calcined at a high temperature of 800 to 1,500°C, then sieved and ground into powder, and its particle size ranges from 50 to 10,000 mesh, that is, 0.0013 to 0.27 mm.

The function of the above moisturizer is to protect the user's skin from drying and peeling due to long-term contact with alkaline soaps when the user's skin is in contact. In implementation, the moisturizer is composed of any one or a combination of polyols, polymer polysaccharides, and amino acids.

The above-mentioned purified water should meet the drinking water quality standards; during implementation, in order to reduce the competition between magnesium, sodium, zinc, and iron ions in the water with calcium ions, deionized water can be further used.

The surfactant and emulsifier are mainly used for cleaning oil stains, so that the cleaning agent has the effect of decontamination and cleaning. When the surfactant is implemented, it is alkyl glucosides, sulfosuccinates, TEA N-cocoyl glutamate, and α-olefin sulfonate. Α-olefin sulfonate, monoalkyl Any one or a combination of mono alkyl phosphate, polyoxyethylene fatty acid ester, alkyl betaine, and alkyl amide betaine.

When the emulsifier is implemented, it is any one or more of polyglyceryl-3 stearate, cetyl alcohol, lecithin, and glyceryl monostearate The combination.

The main function of the thickener is to increase the viscosity of the liquid and support the suspension of particles. In practice, the thickener is composed of any one or a combination of polymer glues, polymer polysaccharides, and polyquaternary ammonium salt polymers.

The function of the acid-base regulator is to adjust the pH value of the liquid; because the antibacterial effect of calcium hydroxide cleaner is not caused by strong alkali, so adding the acid-base regulator can adjust the pH value of the cleaner and avoid contact with strong alkali The danger caused.

When implemented, the detergent dosage form can be liquid, milky or muddy. The following provides examples for different dosage forms.

Example one:

The formula takes 0.5%-0.7% natural biological shell calcium oxide, 6%-8% moisturizer, 70.3%-77.5% purified water, and 10%-12% surfactant, 5% -7% thickener, 1%-2% acid-base regulator, can be made into liquid detergent.

When in use, the liquid detergent can be contained in a pressing bottle with a nozzle, which can be sprayed on the environment, human body, or as a collar cleaner to eliminate odors, pathogens, etc. in the environment. Experiments have proved that its antibacterial power (for example: Escherichia coli, Pseudomonas aeruginosa, Salmonella, drug-resistant Staphylococcus aureus, etc.) reaches more than 99%, and it can remove more than 85% of common odors in the environment, such as ammonia. In addition, surfactants and thickeners are selected in the formula, and the natural biological shell calcium oxide, moisturizer, purified water, and acid-base regulator can be used to achieve the effect of disinfection and sterilization.

Embodiment two:

The formula takes 0.5%-0.7% of the total weight percentage of biological shell calcium oxide, 8%-10% humectant, 48.3%-58.5% purified water, 12%-14% surfactant, 5%-8% emulsifier, 15%-17% thickener, and 1 %-2% acid-base regulator can be made into a milky cleaner.

When used, the milky cleanser can be contained in a pressing bottle, and then released in a squeezed manner after pressing. After being mixed with ordinary water, it can produce foam to clean clothes, food, etc. This dosage form can be used in shower milk , Laundry detergent, dishwashing detergent, vegetable and fruit cleaning agent, etc.

Furthermore, after actual testing, if no acid-base regulator is added to the formula of the milky cleaner, it will not affect the effect of disinfection and sterilization. Its antibacterial power still reaches more than 99%, and it has more than 85% of the ammonia in the environment. Therefore, milky cleaners without acid-base regulators can be used in cleaning environments, such as cleaning floors, toilets, toilets, kitchen range hoods, etc. that do not directly contact the human body.

Embodiment three:

The formula takes the total weight percentage of 0.9%-1% of biological shell calcium oxide, 8%-10% humectant, 34%-45.1% purified water, 5%-8% surfactant, 15%-18 % Emulsifier, 25%-27% thickener, and 1%-2% acid-base regulator can be made into a mud-like cleaner.

When in use, the mud-like detergent can be contained in a containing box, and then taken by a spoon. Mud-like detergent mixed with ordinary clean water can also produce foam to clean clothes and the environment. Moreover, mud-like detergent can produce higher cleaning effect than liquid or milky detergents. Can be used as a powerful cleaner.

According to actual tests, if no acid-base regulator is added to the formula of the muddy cleaner, it will not affect the effect of disinfection and sterilization. Its antibacterial power still reaches more than 99%, and the removal rate of ammonia in the environment is more than 85%. Therefore, mud-like cleaners without acid-base regulators can be used in cleaning environments, such as cleaning the floor, toilets, toilets, kitchen range hoods, etc. that do not directly contact the human body, especially general cleaning The part that is not easy to clean with the agent.

The preparation method adapted to the above-mentioned embodiment is carried out according to the following steps: (1) Mixing the calcium oxide of the biological shell with purified water; (2) The mixture obtained in step (1) is slowly mixed with humectant and acid-base regulator at room temperature, and optionally any one or more of the following ingredients are mixed to completely dissolve: surfactant, emulsifier, Thickener.

When selecting a surfactant in this step (2), it further includes: (3) slowly mixing the mixture obtained in step (2) with the surfactant at room temperature until it is completely dissolved. For example, if surfactants and emulsifiers are selected in step (2), the mixture obtained from step (1) is slowly mixed with humectant, emulsifier, and acid-base regulator at room temperature until completely dissolved, and then mixed slowly Surfactant to completely dissolve.

Or, for example, if surfactants and thickeners are selected in step (2), the mixture obtained from step (1) is slowly mixed with humectant, thickener, and acid-base regulator at room temperature until it is completely dissolved. Mix the surfactant slowly until it is completely dissolved.

If emulsifiers and thickeners are selected in this step (2), but no surfactant is selected, then step (3) is not necessary. In step (2), the mixture obtained in step (1), moisturizer, The acid-base regulator, emulsifier, and thickener are mixed at a slow speed until completely dissolved.

The above are only examples of preferred embodiments of the present invention, and are not intended to limit the scope of the present invention. Anything similar or similar to the purpose, formula, and steps of the present invention should belong to the patent scope of the present invention.

Claims (10)

A cleaning agent formula with calcium oxide for biological shells, including: calcium oxide for biological shells is 0.01%-1% by weight, moisturizers are 1%-30% by weight, and purified water is 10%-90% by weight 、The acid-base regulator is 1%-5% by weight; and optionally any one or a combination of the following ingredients: 0%-50% by weight for surfactants, 0%-20% by weight for emulsifiers , The thickener is 0%-30% by weight. The cleaning agent formula with calcium oxide component of biological shell as described in claim 1, wherein the calcium oxide of biological shell is obtained by sieving and pulverizing shells or egg shells after being calcined at a high temperature of 800 to 1,500°C. The diameter range is 50-10,000mesh. The detergent formulation with calcium oxide component of the biological shell as described in claim 1, wherein the surfactant is alkyl glucosides, sulfosuccinates, and coconut oil base TEA N-cocoyl glutamate, α-olefin sulfonate, mono alkyl phosphate, polyoxyethylene fatty acid ester , Alkyl betaine (alkyl betaine), alkyl amide betaine (alkyl amide betaine) any one or a combination of more. The cleaning agent formulation with calcium oxide component of biological shell as described in claim 1, wherein the emulsifier is composed of polyglyceryl-3 stearate, cetyl alcohol, and lecithin ( lecithin), glyceryl monostearate (glyceryl monostearate), any one or a combination of more. The cleansing agent formulation with calcium oxide component of the biological shell according to claim 1, wherein the moisturizing agent is composed of any one or a combination of polyols, polymer polysaccharides, and amino acids. The cleaning agent formulation with calcium oxide component of the biological shell according to claim 1, wherein the thickener is any one or a combination of any one or more of polymer glue, polymer polysaccharide, and polyquaternary ammonium salt polymer. The cleaning agent formulation with calcium oxide component of the biological shell as described in claim 1, wherein the cleaning agent formulation can be liquid, milky or muddy. The detergent formulation with calcium oxide component of biological shell as described in claim 1, wherein the purified water is drinking water or deionized water that meets drinking standards. A preparation method of the detergent formulation according to any one of claims 1 to 8, the preparation method comprising the following steps: (1) mixing biological shell calcium oxide with purified water; (2) combining step (1) ) The resulting mixed liquid is slowly mixed with humectant and acid-base regulator at room temperature, and optionally any one or more of the following ingredients are mixed to completely dissolve: surfactant, emulsifier, thickener. As described in claim 9, the method for preparing a detergent formulation with calcium oxide components in a biological shell, when the step (2) selects a surfactant, it further includes: (3) putting the mixture obtained in step (2) at room temperature Mix slowly with surfactant until completely dissolved.