TWI722418B - Semiconductor structure and manufacturing method thereof - Google Patents
Semiconductor structure and manufacturing method thereof Download PDFInfo
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本發明是有關於一種半導體結構及其製造方法,且特別是有關於一能夠改善相鄰的位元線之間的接觸窗的電阻的半導體結構及其製造方法。The present invention relates to a semiconductor structure and a manufacturing method thereof, and more particularly to a semiconductor structure and a manufacturing method thereof that can improve the resistance of a contact window between adjacent bit lines.
在目前動態隨機存取記憶體(dynamic random access memory,DRAM)的製程中,在形成位元線之後,會於相鄰的位元線之間形成穿過下方的介電層而與主動區電性連接的接觸窗,且此接觸窗亦會與後續所形成的電容器電性連接。In the current process of dynamic random access memory (DRAM), after the bit lines are formed, a dielectric layer is formed between adjacent bit lines to pass through the underlying dielectric layer to be electrically connected to the active region. The contact window is electrically connected, and the contact window will also be electrically connected with the capacitor formed later.
隨著元件尺寸持續縮小,相鄰元件之間的間距也隨之縮小。因此,形成相鄰的位元線之間的接觸窗時,必須縮減接觸窗的尺寸,且接觸窗與主動區接觸的區域也隨之縮小,因而導致在操作元件時流經接觸窗的電流量降低而影響元件效能。As the size of components continues to shrink, the spacing between adjacent components also shrinks. Therefore, when forming a contact window between adjacent bit lines, the size of the contact window must be reduced, and the contact area between the contact window and the active area is also reduced, resulting in a decrease in the amount of current flowing through the contact window when operating the element. And affect component performance.
本發明提供一種半導體結構,其中相鄰的位元線之間的接觸窗與主動區具有較大的接觸面積。The present invention provides a semiconductor structure in which a contact window between adjacent bit lines and an active region have a larger contact area.
本發明提供一種半導體結構的製造方法,其用以製造上述的半導體結構。The present invention provides a method for manufacturing a semiconductor structure, which is used for manufacturing the above-mentioned semiconductor structure.
本發明的半導體結構包括基底、介電層、多條位元線、間隙壁以及接觸窗。所述基底具有彼此平行設置的多個主動區。所述介電層設置於所述基底上。所述多條位元線彼此平行地設置於所述介電層上。每一所述位元線與所述主動區部分重疊。每一所述位元線在其延伸方向上具有彼此交替的第一部分與第二部分,且所述第一部分的寬度小於所述第二部分的寬度。所述間隙壁設置於每一所述位元線的側壁上。所述接觸窗設置於相鄰的位元線之間並與所述相鄰的位元線中的至少一者的所述第一部分相鄰,且穿過所述介電層而與所述主動區接觸。The semiconductor structure of the present invention includes a substrate, a dielectric layer, a plurality of bit lines, spacers and contact windows. The substrate has a plurality of active regions arranged parallel to each other. The dielectric layer is disposed on the substrate. The plurality of bit lines are arranged on the dielectric layer in parallel with each other. Each of the bit lines partially overlaps the active area. Each bit line has a first part and a second part alternating with each other in the extending direction, and the width of the first part is smaller than the width of the second part. The spacer is arranged on the side wall of each bit line. The contact window is disposed between adjacent bit lines and is adjacent to the first portion of at least one of the adjacent bit lines, and passes through the dielectric layer to communicate with the active Zone contact.
在本發明的半導體結構的一實施例中,從上視角度而言,在與所述位元線的延伸方向垂直的方向上,所述第一部分的第一側的側壁與所述第二部分的所述第一側的側壁之間具有第一距離,且所述第一距離例如不超過5 nm。In an embodiment of the semiconductor structure of the present invention, from a top perspective, in a direction perpendicular to the extension direction of the bit line, the sidewalls of the first side of the first part are opposite to the sidewalls of the second part. There is a first distance between the side walls of the first side, and the first distance does not exceed 5 nm, for example.
在本發明的半導體結構的一實施例中,從上視角度而言,在與所述位元線的延伸方向垂直的方向上,所述第一部分的與所述第一側相對的第二側的側壁與所述第二部分的所述第二側的側壁之間具有第二距離,且所述第二距離例如不超過5 nm。In an embodiment of the semiconductor structure of the present invention, from a top perspective, in a direction perpendicular to the extension direction of the bit line, a second side of the first portion opposite to the first side There is a second distance between the side wall of the second part and the side wall of the second side of the second part, and the second distance does not exceed 5 nm, for example.
在本發明的半導體結構的一實施例中,從上視角度而言,在與所述位元線的延伸方向垂直的方向上,所述第一部分的第一側的側壁與所述第二部分的所述第一側的側壁之間具有第一距離,且所述第一距離例如不超過所述第二部分的寬度的35%。In an embodiment of the semiconductor structure of the present invention, from a top perspective, in a direction perpendicular to the extension direction of the bit line, the sidewalls of the first side of the first part are opposite to the sidewalls of the second part. There is a first distance between the side walls of the first side, and the first distance does not exceed 35% of the width of the second part, for example.
在本發明的半導體結構的一實施例中,從上視角度而言,在與所述位元線的延伸方向垂直的方向上,所述第一部分的與所述第一側相對的第二側的側壁與所述第二部分的所述第二側的側壁之間具有第二距離,且所述第二距離例如不超過所述第二部分的寬度的35%。In an embodiment of the semiconductor structure of the present invention, from a top perspective, in a direction perpendicular to the extension direction of the bit line, a second side of the first portion opposite to the first side There is a second distance between the side wall of and the side wall of the second side of the second part, and the second distance does not exceed 35% of the width of the second part, for example.
在本發明的半導體結構的一實施例中,所述第一距離與所述第二距離例如相等。In an embodiment of the semiconductor structure of the present invention, the first distance and the second distance are, for example, equal.
在本發明的半導體結構的一實施例中,相鄰的位元線的所述第一部分彼此交錯開。In an embodiment of the semiconductor structure of the present invention, the first portions of adjacent bit lines are staggered.
本發明的半導體結構的製造方法包括以下步驟。首先,於基底上形成介電層,其中所述基底具有彼此平行設置的多個主動區。接著,於所述介電層上形成彼此平行的多條位元線,每一所述位元線與所述主動區部分重疊,其中每一所述位元線在其延伸方向上具有彼此交替的第一部分與第二部分,且所述第一部分的寬度小於所述第二部分的寬度。然後,於每一所述位元線的側壁上形成間隙壁。之後,於相鄰的位元線之間形成接觸窗,其中所述接觸窗與所述相鄰的位元線中的至少一者的所述第一部分相鄰,且穿過所述介電層而與所述主動區接觸。The manufacturing method of the semiconductor structure of the present invention includes the following steps. First, a dielectric layer is formed on a substrate, wherein the substrate has a plurality of active regions arranged parallel to each other. Next, a plurality of bit lines parallel to each other are formed on the dielectric layer, each of the bit lines partially overlaps the active region, and each of the bit lines has alternating directions in the extending direction. The first part and the second part of, and the width of the first part is smaller than the width of the second part. Then, a spacer is formed on the side wall of each bit line. Afterwards, a contact window is formed between adjacent bit lines, wherein the contact window is adjacent to the first portion of at least one of the adjacent bit lines and passes through the dielectric layer And contact with the active area.
在本發明的半導體結構的製造方法的一實施例中,從上視角度而言,在與所述位元線的延伸方向垂直的方向上,所述第一部分的第一側的側壁與所述第二部分的所述第一側的側壁之間具有第一距離,且所述第一距離例如不超過5 nm。In an embodiment of the manufacturing method of the semiconductor structure of the present invention, from a top view, in a direction perpendicular to the extension direction of the bit line, the sidewall of the first side of the first portion is connected to the There is a first distance between the side walls of the first side of the second part, and the first distance does not exceed 5 nm, for example.
在本發明的半導體結構的製造方法的一實施例中,從上視角度而言,在與所述位元線的延伸方向垂直的方向上,所述第一部分的與所述第一側相對的第二側的側壁與所述第二部分的所述第二側的側壁之間具有第二距離,且所述第二距離例如不超過5 nm。In an embodiment of the manufacturing method of the semiconductor structure of the present invention, from a top view, in a direction perpendicular to the extension direction of the bit line, the first part of the first part is opposite to the first side There is a second distance between the side wall on the second side and the side wall on the second side of the second part, and the second distance does not exceed 5 nm, for example.
在本發明的半導體結構的製造方法的一實施例中,從上視角度而言,在與所述位元線的延伸方向垂直的方向上,所述第一部分的第一側的側壁與所述第二部分的所述第一側的側壁之間具有第一距離,且所述第一距離例如不超過所述第二部分的寬度的35%。In an embodiment of the manufacturing method of the semiconductor structure of the present invention, from a top view, in a direction perpendicular to the extension direction of the bit line, the sidewall of the first side of the first portion is connected to the There is a first distance between the side walls of the first side of the second part, and the first distance does not exceed 35% of the width of the second part, for example.
在本發明的半導體結構的製造方法的一實施例中,從上視角度而言,在與所述位元線的延伸方向垂直的方向上,所述第一部分的與所述第一側相對的第二側的側壁與所述第二部分的所述第二側的側壁之間具有第二距離,且所述第二距離例如不超過所述第二部分的寬度的35%。In an embodiment of the manufacturing method of the semiconductor structure of the present invention, from a top view, in a direction perpendicular to the extension direction of the bit line, the first part of the first part is opposite to the first side There is a second distance between the side wall of the second side and the side wall of the second side of the second part, and the second distance does not exceed 35% of the width of the second part, for example.
在本發明的半導體結構的製造方法的一實施例中,所述第一距離與所述第二距離例如相等。In an embodiment of the manufacturing method of the semiconductor structure of the present invention, the first distance and the second distance are, for example, equal.
在本發明的半導體結構的製造方法的一實施例中,所述位元線的形成方法包括以下步驟。首先,於所述介電層上形成位元線材料層。接著,於所述位元線材料層上形成彼此平行的多條罩幕圖案。然後,於所述位元線材料層上形成圖案化光阻層,其中所述圖案化光阻層暴露每一所述罩幕圖案的一部分。而後,進行等向性蝕刻製程,移除被暴露的罩幕圖案的一部分,以減少所述被暴露的罩幕圖案的寬度。接著,移除所述圖案化光阻層。然後,以所述多條罩幕圖案為罩幕,進行非等向性蝕刻製程,移除部分所述位元線材料層。之後,移除所述光阻圖案。In an embodiment of the method for manufacturing a semiconductor structure of the present invention, the method for forming the bit line includes the following steps. First, a bit line material layer is formed on the dielectric layer. Then, a plurality of mask patterns parallel to each other are formed on the bit line material layer. Then, a patterned photoresist layer is formed on the bit line material layer, wherein the patterned photoresist layer exposes a part of each of the mask patterns. Then, an isotropic etching process is performed to remove a part of the exposed mask pattern to reduce the width of the exposed mask pattern. Then, the patterned photoresist layer is removed. Then, using the multiple mask patterns as a mask, an anisotropic etching process is performed to remove part of the bit line material layer. After that, the photoresist pattern is removed.
在本發明的半導體結構的製造方法的一實施例中,所述間隙壁的形成方法包括以下步驟。首先,在形成所述多條位元線之後,於所述介電層上共形地形成間隙壁材料層。之後,進行非等向性蝕刻製程,移除部分所述間隙壁材料層。In an embodiment of the method for manufacturing a semiconductor structure of the present invention, the method for forming the spacer includes the following steps. First, after forming the plurality of bit lines, a spacer material layer is conformally formed on the dielectric layer. Afterwards, an anisotropic etching process is performed to remove part of the spacer material layer.
在本發明的半導體結構的製造方法的一實施例中,所述接觸窗的形成方法包括包括以下步驟。首先,在形成所述間隙壁之後,於所述介電層上形成介電材料層,以覆蓋所述多條位元線。接著,移除部分所述介電材料層,以暴露出所述多條位元線的頂面。然後,移除鄰近所述第一部分的所述介電材料層以及下方的所述介電層,以形成暴露出部分所述主動區的開口。之後,於所述開口中形成導電層。In an embodiment of the method for manufacturing a semiconductor structure of the present invention, the method for forming the contact window includes the following steps. First, after forming the spacers, a dielectric material layer is formed on the dielectric layer to cover the plurality of bit lines. Then, a part of the dielectric material layer is removed to expose the top surface of the plurality of bit lines. Then, the dielectric material layer adjacent to the first portion and the dielectric layer below are removed to form an opening exposing part of the active region. Afterwards, a conductive layer is formed in the opening.
圖1A至圖1F為依照本發明實施例的半導體結構的製造流程上視示意圖。圖2A至圖2F為沿圖1A至圖1F中的I-I’剖線所繪示的剖面示意圖。1A to 1F are schematic top views of a manufacturing process of a semiconductor structure according to an embodiment of the present invention. 2A to 2F are schematic cross-sectional views along the line I-I' in FIGS. 1A to 1F.
首先,請同時參照圖1A與圖2A,提供基底100。基底100例如是矽基底。基底100中具有用以定義出多個主動區102的隔離結構104。主動區102的排列方式不限於圖1A中所繪示的排列方式。隔離結構104例如是淺溝渠隔離結構(shallow trench isolation,STI)。此外,基底100上與基底100中形成有用以構成記憶單元的各種元件(例如閘極結構、源極區、汲極區等)。然而,為了使圖式清楚,圖中省略了上述各種元件。然後,於基底100上形成介電層106。介電層106例如為氧化物層,其形成方法例如為化學氣相沉積法。介電層106覆蓋基底100上的各種元件。此外,介電層106中形成有內連線結構。同樣地,為了使圖式清楚,圖中省略了上述內連線結構。First, please refer to FIG. 1A and FIG. 2A at the same time to provide a
接著,請同時參照圖1B與圖2B,於介電層106上形成位元線材料層108。位元線材料層108例如為多晶矽層,但本發明不限於此。在其他實施例中,視實際需求,位元線材料層108也可以是由多晶矽層、矽化鎢層與氮化矽層所構成的複合層。此外,還可於位元線材料層108上形成硬罩幕材料層110。硬罩幕材料層110可以是氧化物層、氮化物層或是由氧化物層與氮化物層所構成的堆疊層,但本發明不限於此。在其他實施例中,視實際需求,硬罩幕材料層110也可以是其他材料的單一層或複合層。之後,可進行雙重圖案化(double patterning)製程,以於硬罩幕材料層110上形成多條罩幕圖案112。在其他實施例中,視實際情況,也可採用一般的單一圖案化製程,而不須進行雙重圖案化製程。罩幕圖案112例如為氧化物層。Next, referring to FIG. 1B and FIG. 2B at the same time, a bit
然後,請同時參照圖1C與圖2C,於硬罩幕材料層110上形成圖案化光阻層114。圖案化光阻層114暴露每一條罩幕圖案112的對應於後續欲形成的位元線中寬度較小的區域的部分。在本實施例中,圖案化光阻層114暴露的區域彼此交替排列,但本發明不限於此。在其他實施例中,視實際的佈局需求可調整圖案化光阻層114所暴露的區域。Then, referring to FIG. 1C and FIG. 2C at the same time, a patterned
接著,請同時參照圖1D與圖2D,進行等向性蝕刻製程,移除被暴露的罩幕圖案112的一部分,以減少被暴露的罩幕圖案112的寬度。上述的等向性蝕刻製程例如是使用緩衝氫氟酸(buffered hydrofluoric acid,BHF)的濕蝕刻製程。如此一來,可使罩幕圖案112具有寬度較小的第一部分112a與寬度較大的第二部分112b,且第一部分112a對應於後續欲形成的位元線中寬度較小的區域。罩幕圖案112作為將位元線材料層108圖案化為多條位元線時的罩幕。由於罩幕圖案112具有寬度較小的第一部分112a與寬度較大的第二部分112b,因此後續所形成的位元線亦可具有寬度較小的部分與寬度較大的部分。以下將對此進一步說明。Next, referring to FIGS. 1D and 2D at the same time, an isotropic etching process is performed to remove a part of the exposed
然後,請同時參照圖1E與圖2E,移除圖案化光阻層114。接著,以罩幕圖案112為蝕刻罩幕,進行非等向性蝕刻製程,移除部分硬罩幕材料層110,以形成硬罩幕圖案(未繪示)。接著,以硬罩幕圖案為蝕刻罩幕,進行非等向性蝕刻製程,移除部分位元線材料層108,以形成具有寬度較小的第一部分116a與寬度較大的第二部分116b的位元線116。Then, referring to FIG. 1E and FIG. 2E at the same time, the patterned
在本實施例中,藉由在圖1D與圖2D所述的步驟中,控制罩幕圖案112的移除量來調整所形成的第一部分112a的寬度,進而可得到所需的位元線116的第一部分116a的寬度。如圖1E所示,從上視角度而言,在與位元線116的延伸方向垂直的方向上,第一部分116a的一側的側壁與第二部分116b的在同一側的側壁之間具有距離D1,且在相對的另一側,第一部分116a的側壁與第二部分116b的側壁之間具有距離D2。在一實施例中,距離D1不超過5 nm,且距離D2不超過5 nm。在另一實施例中,距離D1不超過第二部分116b的寬度W的35%,且距離D2不超過第二部分116b的寬度W的35%。此外,在本實施例中,距離D1與距離D2相等,但本發明不限於此。在其他實施例中,視實際的佈局需求可使距離D1與距離D2彼此不同。In this embodiment, by controlling the removal amount of the
接著,請同時參照圖1F與圖2F,於位元線116的側壁上形成間隙壁118。間隙壁118例如是氮化物層。間隙壁118的形成方法例如是先於介電層106上共形地形成間隙壁材料層,然後進行非等向性蝕刻製程,以移除部分間隙壁材料層。然後,於介電層106上形成介電層材料層,以覆蓋位元線116與間隙壁118。之後,例如進行化學機械研磨製程(CMP),移除部分介電材料層,以暴露出位元線116的頂面,並於位元線116之間形成介電層120。接著,移除鄰近第一部分116a的介電層120以及下方的介電層106,以形成暴露出部分主動區102的開口122。之後,於開口122中填入導電層,以於介電層120與介電層106中形成與主動區102接觸的接觸窗124。接觸窗124用以使後續所形成的元件(例如電容器)與主動區102電性連接。Next, referring to FIG. 1F and FIG. 2F at the same time, a
在本實施例中,位元線116具有寬度較小的第一部分116a與寬度較大的第二部分116b,且位元線116之間的接觸窗124設置為與第一部分116a相鄰。如此一來,相較於一般具有均一寬度的位元線,接觸窗124可具有較大的尺寸而具有較低的電阻,且接觸窗124與主動區102之間可以具有較大的接觸面積而提高了在操作元件時流經接觸窗124與主動區102的電流量,進而提高元件的電性表現。如圖1F中的區域126所示,相較於一般具有均一寬度的位元線,接觸窗124增加了尺寸以及與主動區102之間的接觸面積。In this embodiment, the
此外,在本實施例中,第一部分116a的側壁與第二部分116b的側壁之間的距離D1、D2不超過5 nm,或者距離D1、D2不超過第二部分116b的寬度W的35%。如此一來,在藉由縮小位元線116的寬度以增加接觸窗124的尺寸的情況下,亦可將位元線116本身的電阻維持在所需的程度,不會因縮小位元線116的寬度過度縮小導致電阻過度提高,因而影響元件的電性表現。In addition, in this embodiment, the distance D1, D2 between the sidewall of the
100:基底
102:主動區
104:隔離結構
106、120:介電層
108:位元線材料層
110:硬罩幕材料層
112:罩幕圖案
112a、116a:第一部分
112b、116b:第二部分
114:圖案化光阻層
116:位元線
118:間隙壁
122:開口
124:接觸窗
126:區域
D1、D2:距離
W:寬度100: base
102: active area
104:
圖1A至圖1F為依照本發明實施例的半導體結構的製造流程上視示意圖。 圖2A至圖2F為沿圖1A至圖1F中的I-I’剖線所繪示的剖面示意圖。1A to 1F are schematic top views of a manufacturing process of a semiconductor structure according to an embodiment of the present invention. 2A to 2F are schematic cross-sectional views along the line I-I' in FIGS. 1A to 1F.
116:位元線 116: bit line
116a:第一部分 116a: Part One
116b:第二部分 116b: Part Two
118:間隙壁 118: Clearance Wall
120:介電層 120: Dielectric layer
124:接觸窗 124: contact window
126:區域 126: area
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