TWI712669B - Adhesive sheet and method of use - Google Patents
Adhesive sheet and method of use Download PDFInfo
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- TWI712669B TWI712669B TW106105590A TW106105590A TWI712669B TW I712669 B TWI712669 B TW I712669B TW 106105590 A TW106105590 A TW 106105590A TW 106105590 A TW106105590 A TW 106105590A TW I712669 B TWI712669 B TW I712669B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form
- B32B3/10—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material
- B32B3/14—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material characterised by a face layer formed of separate pieces of material which are juxtaposed side-by-side
- B32B3/16—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material characterised by a face layer formed of separate pieces of material which are juxtaposed side-by-side secured to a flexible backing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/10—Adhesives in the form of films or foils without carriers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/06—Interconnection of layers permitting easy separation
Abstract
黏著薄片(100)的特徵在於,係具備黏著劑層(3)、設置於黏著劑層(3)的兩面之第1薄片(1)及第2薄片(2),第2薄片(2)之在俯視下之包含相對向的端部或該端部的附近之第1區域(21a)、和第1區域(21a)以外的第2區域(21b),從黏著劑層(3)剝離的剝離性是不同的,當將第1薄片(1)之從黏著劑層(3)剝離的剝離力設定為F1,將在第2區域(21b)之第2薄片(2)之從黏著劑層(3)剝離的剝離力設定為F2,將在第1區域(21a)之第2薄片(2)之從黏著劑層(3)剝離的剝離力設定為F3的情況,滿足下述數式(F1)的條件F2<F1<F3‧‧‧(F1)。 The adhesive sheet (100) is characterized in that it has an adhesive layer (3), a first sheet (1) and a second sheet (2) provided on both sides of the adhesive layer (3), and one of the second sheet (2) In a plan view, the first region (21a) including the opposite end or the vicinity of the end and the second region (21b) other than the first region (21a) are peeled from the adhesive layer (3) The properties are different. When the peeling force of the first sheet (1) from the adhesive layer (3) is set to F 1 , the second sheet (2) in the second area (21b) is separated from the adhesive layer (3) The peeling force of peeling is set to F 2 , and the peeling force of the second sheet (2) in the first area (21a) is set to F 3 for peeling from the adhesive layer (3), and the following number is satisfied The condition of formula (F1) is F 2 <F 1 <F 3 ‧‧‧(F1).
Description
本發明是關於黏著薄片及其使用方法。 The present invention relates to adhesive sheets and methods of use.
作為黏著薄片,要求衝壓加工步驟可穩定地進行(作業穩定性)。特別是要求,在將黏著劑層實施衝壓加工後,將衝壓加工後之黏著劑層以外的部分(廢料部)除去的步驟(廢料除去步驟)之作業穩定性。更具體的說,在將包含黏著薄片的衝壓加工步驟、廢料除去步驟、以及對於被黏著體的貼合步驟之程序藉由連續式(in-line type)的裝置進行時,在將黏著劑層實施衝壓加工後,當將廢料除去時,要求避免發生黏著劑層中途斷裂的問題(以下也稱為廢料除去不良)。 As an adhesive sheet, it is required that the stamping process can be performed stably (work stability). In particular, it is required to perform the operation stability in the step (scrap removal step) of removing parts other than the adhesive layer (scrap part) after the press processing after the press processing of the adhesive layer. More specifically, when the process including the press processing step of the adhesive sheet, the waste removal step, and the bonding step to the adherend is performed by an in-line type device, the adhesive layer When the waste is removed after pressing, it is required to avoid the problem of breakage of the adhesive layer in the middle (hereinafter also referred to as defective removal of waste).
為了解決上述課題,例如在文獻1(日本特開平11-181364號公報)提出由表面基材、黏著劑、剝離薄片所構成的黏著薄片。文獻1的黏著薄片,是將表面基材及黏著劑對於剝離薄片的剝離力(180度)分別調整為既定範圍。
In order to solve the above-mentioned problems, for example, Document 1 (Japanese Patent Application Laid-Open No. 11-181364) proposes an adhesive sheet composed of a surface substrate, an adhesive, and a release sheet. In the adhesive sheet of
然而,文獻1的黏著薄片,並無法充分抑制廢料除去
不良。
However, the adhesive sheet of
本發明的目的是提供一種可充分抑制廢料除去不良之黏著薄片及其使用方法。更具體的說是提供一種黏著薄片及其使用方法,在利用連續式的裝置進行包含黏著薄片的衝壓加工步驟、廢料除去步驟、以及對於被黏著體的貼合步驟之程序時,可充分抑制廢料除去不良。 The object of the present invention is to provide an adhesive sheet that can sufficiently suppress poor removal of waste materials and a method of use thereof. More specifically, it provides an adhesive sheet and a method of using the same, which can sufficiently suppress waste when a continuous device is used to carry out the press processing step including the adhesive sheet, the waste removal step, and the bonding step to the adherend. Remove bad.
依據本發明的一態樣是提供一種黏著薄片,係具備黏著劑層、設置於前述黏著劑層的兩面之第1薄片及第2薄片,前述第2薄片之在俯視下之包含相對向的端部或該端部的附近之第1區域、和前述第1區域以外的第2區域,從前述黏著劑層剝離之剝離性是不同的,當將前述第1薄片從前述黏著劑層剝離的剝離力設定為F1,將在前述第2區域之第2薄片從前述黏著劑層剝離的剝離力設定為F2,將在前述第1區域之第2薄片從前述黏著劑層剝離的剝離力設定為F3的情況,滿足下述數式(F1)的條件F2<F1<F3‧‧‧(F1)。 According to one aspect of the present invention, an adhesive sheet is provided, which is provided with an adhesive layer, a first sheet and a second sheet disposed on both sides of the adhesive layer, and the second sheet includes opposite ends in a plan view. The first area near the end or the first area and the second area other than the first area have different releasability from the adhesive layer. When the first sheet is peeled off from the adhesive layer The force is set to F 1 , the peeling force of the second sheet in the second area from the adhesive layer is set to F 2 , the peeling force of the second sheet in the first area from the adhesive layer is set to In the case of F 3 , the condition F 2 <F 1 <F 3 ‧‧‧(F1) is satisfied in the following formula (F1).
本發明的一態樣之黏著薄片較佳為,在前述第1薄片設置第1剝離層,前述黏著劑層和前述第1薄片是透過前述第1剝離層而被積層;在前述第2薄片設置第2剝離層,前述黏著劑層和前述第2薄片是透過前述第2剝離層而被積層。 In the adhesive sheet of one aspect of the present invention, it is preferable that a first release layer is provided on the first sheet, the adhesive layer and the first sheet are laminated through the first release layer; and the second sheet is provided The second release layer, the adhesive layer and the second sheet are laminated through the second release layer.
本發明的一態樣之黏著薄片較佳為,前述黏著薄片呈 長條狀,前述第1區域是包含前述第2薄片之在俯視下之寬度方向的兩端部或該兩端部的附近。 One aspect of the adhesive sheet of the present invention is preferably that the aforementioned adhesive sheet is It is elongated, and the said 1st area|region contains the both ends of the width direction of a plan view of the said 2nd sheet, or the vicinity of the said both ends.
依據本發明的一態樣是提供一種黏著薄片之使用方法,是使用本發明的一態樣之黏著薄片的方法,係具備有:實施在前述黏著薄片之前述黏著劑層及前述第2薄片形成切痕之半切割而將前述黏著劑層分割為衝壓加工部、前述衝壓加工部以外的連續狀廢料部之步驟,以及從前述黏著薄片將前述連續狀廢料部除去的步驟。 According to one aspect of the present invention, there is provided a method of using an adhesive sheet. The method of using the adhesive sheet of one aspect of the present invention is provided with: the adhesive layer implemented on the adhesive sheet and the second sheet are formed The step of half-cutting the cut to divide the adhesive layer into a press-processed part, a continuous waste part other than the press-processed part, and a step of removing the continuous waste part from the adhesive sheet.
本發明的一態樣之黏著薄片之使用方法較佳為,前述衝壓加工部是設置於前述第2區域內。 In the method of using the adhesive sheet according to one aspect of the present invention, it is preferable that the punching part is provided in the second area.
依據本發明,可提供一種能夠充分抑制廢料除去不良之黏著薄片及其使用方法。 According to the present invention, it is possible to provide an adhesive sheet capable of sufficiently suppressing defective removal of waste materials and a method of use thereof.
1‧‧‧第1薄片 1‧‧‧The first slice
2‧‧‧第2薄片 2‧‧‧Second sheet
3‧‧‧黏著劑層 3‧‧‧Adhesive layer
4‧‧‧切痕 4‧‧‧Cut
5‧‧‧輔助帶體 5‧‧‧Auxiliary belt
11‧‧‧第1基材薄片 11‧‧‧The first substrate sheet
12‧‧‧第1剝離層 12‧‧‧The first peeling layer
21‧‧‧第2基材薄片 21‧‧‧Second substrate sheet
21a‧‧‧第1區域
21a‧‧‧
21b‧‧‧第2區域
21b‧‧‧
22‧‧‧第2剝離層 22‧‧‧Second peeling layer
31‧‧‧衝壓加工部 31‧‧‧Stamping Department
32‧‧‧連續狀廢料部 32‧‧‧Continuous waste department
100、100A‧‧‧黏著薄片 100, 100A‧‧‧ adhesive sheet
圖1係顯示本發明的第一實施形態之黏著薄片的概略圖。 Fig. 1 is a schematic view showing the adhesive sheet of the first embodiment of the present invention.
圖2係顯示圖1的II-II剖面之剖面圖。 Fig. 2 is a cross-sectional view showing the II-II section of Fig. 1.
圖3係顯示在本發明的第一實施形態之黏著薄片設置衝壓加工部並貼合輔助帶體的狀態之概略圖。 Fig. 3 is a schematic view showing a state in which a press working part is provided on the adhesive sheet of the first embodiment of the present invention and an auxiliary tape body is attached.
圖4係顯示圖3的IV-IV剖面之剖面圖。 Fig. 4 is a cross-sectional view showing the IV-IV section of Fig. 3.
圖5係顯示從本發明的第一實施形態之黏著薄片將連續狀廢料部除去的狀態之概略圖。 Fig. 5 is a schematic view showing a state where the continuous waste part is removed from the adhesive sheet of the first embodiment of the present invention.
圖6係顯示圖5的VI-VI剖面之剖面圖。 Fig. 6 is a cross-sectional view showing the VI-VI section of Fig. 5.
圖7係顯示在本發明的第二實施形態之黏著薄片設置 衝壓加工部的狀態之概略圖。 Figure 7 shows the arrangement of the adhesive sheet in the second embodiment of the present invention A schematic diagram of the state of the press processing section.
以下,舉實施形態為例並根據圖式來說明本發明。本發明並不限定於實施形態的內容。又在圖式中,為了說明容易起見,會有放大或縮小而進行圖示的部分。 Hereinafter, an embodiment is taken as an example and the present invention is explained based on the drawings. The present invention is not limited to the content of the embodiment. In the drawings, for the sake of ease of description, there are parts that are shown enlarged or reduced.
首先,說明本實施形態的黏著薄片。 First, the adhesive sheet of this embodiment will be described.
本實施形態的黏著薄片100,如圖1及圖2所示般,是呈長條狀(帶狀),且具備有第1薄片1、第2薄片2、以及黏著劑層3。第1薄片1及第2薄片2設置於黏著劑層3的兩面。
The
第1薄片1係具備第1基材薄片11及第1剝離層12。第1薄片1和黏著劑層3是透過第1剝離層12而被積層。第2薄片2係具備第2基材薄片21及第2剝離層22。第2薄片2和黏著劑層3是透過第2剝離層22而被積層。
The
第2薄片2在俯視下具有第1區域21a及第2區域21b。第1區域21a之從黏著劑層3剝離的剝離性和第2區域21b之從黏著劑層3剝離的剝離性是不同的。此外,第1區域21a係包含相對向的端部,亦即第2薄片2之在俯視下之寬度方向的兩端部。更具體的說,第1區域
21a,是在第2薄片2之在俯視下之寬度方向的兩端部的附近,沿著該兩端部而在整個長度方向連續地設置。
The
本實施形態之黏著薄片100,當將第1薄片1之從黏著劑層3剝離的剝離力設定為F1,將在第2區域21b之第2薄片2從黏著劑層3剝離的剝離力設定為F2,將在第1區域21a之第2薄片2從黏著劑層3剝離的剝離力設定為F3的情況,滿足下述數式(F1)的條件F2<F1<F3‧‧‧(F1)。
In the
當不滿足前述(F1)的條件的情況,在廢料除去步驟中,衝壓加工部31容易從第1薄片1剝離,要將衝壓加工部31留在第1薄片1上變困難。此外,在廢料除去步驟中,構成連續狀廢料部32之黏著劑層3容易留在第1薄片1側。
When the aforementioned condition (F1) is not satisfied, the press-worked
剝離力F1、剝離力F2及剝離力F3,例如將含有剝離對象的薄片(第1薄片1或第2薄片2)及黏著劑層3之試料(寬度:100mm、長度:100mm)予以固定,使用拉伸試驗機,將剝離對象的薄片以300mm/分的速度朝180°方向進行拉伸,藉此可測定剝離對象的薄片和黏著劑層3之界面的剝離力(單位:mN/100mm)。
The peeling force F 1 , the peeling force F 2 and the peeling force F 3 are , for example, a sample (width: 100 mm, length: 100 mm) containing the sheet to be peeled (
剝離力F1、剝離力F2及剝離力F3的測定方法並不限定於上述的方法。當剝離力過大的情況或是過小的情況,並無法利用上述方法進行測定。在這種情況,可將剝離力的測定條件(試料大小及速度等)適宜地改變,來調查剝離力F1、剝離力F2及剝離力F3的大小關係。此外,例 如,當剝離力過大而無法測定剝離力的情況,可說該試料的剝離力是比能夠測定剝離力的試料之剝離力更大。 The measuring methods of peeling force F 1 , peeling force F 2 and peeling force F 3 are not limited to the above-mentioned methods. When the peeling force is too large or too small, the above method cannot be used for measurement. In this case, the measurement conditions (sample size, speed, etc.) of the peeling force can be appropriately changed to investigate the relationship between the peeling force F 1 , the peeling force F 2, and the peeling force F 3 . In addition, for example, when the peeling force is too large to measure the peeling force, it can be said that the peeling force of the sample is greater than the peeling force of the sample capable of measuring the peeling force.
剝離力F1及剝離力F2,可藉由例如改變設置於第1薄片1及第2薄片2之剝離層的配方或厚度、或是改變第1薄片1及第2薄片2的種類或厚度,來進行調整。
The peeling force F 1 and the peeling force F 2 can be changed by, for example, changing the formula or thickness of the peeling layer provided on the
剝離力F3可藉由例如下述方法(i)~(v)中之任一方法等進行調整。亦即,能使在第2薄片2之第1區域21a的剝離力F3比第2區域21b的剝離力F2更大。
The peeling force F 3 can be adjusted by, for example, any of the following methods (i) to (v). That is, make a greater peel force in the
(i)在第2薄片2之第1區域21a不設置第2剝離層22(參照圖2)。
(i) The
(ii)對於在第2薄片2之第1區域21a的第2剝離層22,實施電暈處理及電漿處理等的改質處理。
(ii) The
(iii)讓在第2薄片2之第1區域21a的第2剝離層22之效力失活。
(iii) The effect of the
(iv)對於在第2薄片2之第1區域21a進行UV照射等而予以重剝離化。
(iv) The
(v)在第2薄片2之第2區域21b的第2剝離層22及第1區域21a的第2剝離層22,是使用不同剝離劑所形成的。
(v) The
本實施形態所使用之第1薄片1係具備第1基材薄片11及第1剝離層12。此外,本實施形態所使用之第2薄片2係具備第2基材薄片21及第2剝離層22。
The
第1薄片1的厚度沒有特別的限制,通常為20μm以上250μm以下,較佳為38μm以上100μm以下。
The thickness of the
第2薄片2的厚度沒有特別的限制,通常為20μm以上250μm以下,較佳為25μm以上75μm以下,更佳為25μm以上50μm以下。
The thickness of the
作為第1基材薄片11及第2基材薄片21,可列舉樹脂薄膜及紙等。作為樹脂薄膜的樹脂可列舉:聚對苯二甲酸乙二酯、聚乙烯、聚丙烯、聚丁烯、聚丁二烯、聚甲基戊烯、聚氯乙烯、氯乙烯共聚物、聚對苯二甲酸丁二酯、聚氨酯、乙烯-醋酸乙烯共聚物、離子聚合物樹脂、乙烯(甲基)丙烯酸共聚物、聚苯乙烯、聚碳酸酯、氟樹脂、低密度聚乙烯、直鏈低密度聚乙烯、及三醋酸纖維素等。作為紙可列舉:道林紙、塗層紙、玻璃紙、及層壓紙等。其等可將1種單獨使用,也能將2種以上併用。其中,基於便宜且具有彈性的觀點,較佳為聚對苯二甲酸乙二酯薄膜。
As the first base material sheet 11 and the second
第1剝離層12及第2剝離層22能夠使用剝離劑來形成。
The
作為這種剝離劑,可列舉例如矽酮系樹脂、氟系樹脂、及長鏈烷基系樹脂等。其等可將1種單獨使用,也能將2種以上併用。其等當中,基於便宜且能獲得穩定的性能之觀點,較佳為矽酮系樹脂。 Examples of such release agents include silicone resins, fluorine resins, and long-chain alkyl resins. These can be used individually by 1 type, and can also use 2 or more types together. Among them, a silicone-based resin is preferred from the viewpoint of being inexpensive and capable of obtaining stable performance.
第1剝離層12或第2剝離層22的厚度,個別較佳為0.01μm以上2.0μm以下,更佳為0.05μm以上0.5μm以
下。
The thickness of the
本實施形態所使用的黏著劑層3,可使用公知的黏著劑來形成。作為這種黏著劑並沒有特別的限定,可列舉:丙烯酸系黏著劑、橡膠系黏著劑、矽酮系黏著劑、聚氨酯系黏著劑、聚酯系黏著劑、環氧系黏著劑、及聚醯亞胺系黏著劑等。其等可將1種單獨使用,也能將2種以上併用。這種黏著劑可按照黏著薄片的用途而適宜地選擇。此外,這種黏著劑,按照必要可含有硬化助劑、能量射束硬化性成分、及其他樹脂成分。
The
例如,當黏著薄片的用途為晶片之晶粒接合(die bond)步驟所使用之薄膜狀黏著劑或倒裝晶片(flip chip)構裝所使用的底部填充(underfill)薄片等的情況,作為黏著劑,較佳為使用環氧系黏著劑或聚醯亞胺系黏著劑。 For example, when the application of the adhesive sheet is the film-like adhesive used in the die bond step of the chip or the underfill sheet used in the flip chip assembly, it is used as the adhesive The agent is preferably an epoxy-based adhesive or a polyimide-based adhesive.
黏著薄片的用途為同時兼具切割時的晶圓固定功能及晶粒接合時的晶粒黏著功能之切割晶粒接合薄膜的情況,作為黏著劑,較佳為含有丙烯酸系聚合物等的黏結劑(binder)成分及環氧系黏著劑,又按照必要,可使用含有能量射束硬化性化合物、能量射束硬化型聚合物及硬化助劑等之物。 The use of the adhesive sheet is a dicing die bonding film that has both the wafer fixing function during dicing and the die bonding function during die bonding. As an adhesive, it is preferably an adhesive containing acrylic polymer or the like (Binder) components and epoxy adhesives, and if necessary, materials containing energy beam curable compounds, energy beam curable polymers, and curing aids can be used.
當黏著薄片的用途為半導體晶圓之背面保護膜的情況,作為黏著劑,較佳為含有丙烯酸系聚合物等的黏結劑 成分、環氧系黏著劑及硬化助劑,又按照必要可使用含有能量射束硬化性化合物、能量射束硬化型聚合物、填料、及著色劑等之物。 When the adhesive sheet is used as a protective film on the back of a semiconductor wafer, as the adhesive, it is preferably an adhesive containing acrylic polymer or the like Ingredients, epoxy-based adhesives and hardening aids, and, as necessary, materials containing energy beam hardening compounds, energy beam hardening polymers, fillers, and coloring agents can be used.
黏著劑層3的厚度,依其用途而有各種選擇,基於進行衝壓加工時之加工性的觀點,較佳為1μm以上300μm以下,更佳為5μm以上200μm以下,特佳為10~100μm。
The thickness of the
首先,針對本實施形態之黏著薄片的使用方法做說明。 First, the method of using the adhesive sheet of this embodiment will be explained.
本實施形態之黏著薄片的使用方法,是使用本實施形態之黏著薄片100的方法,係具備以下所說明的衝壓加工步驟及廢料除去步驟。
The method of using the adhesive sheet of the present embodiment is the method of using the
在衝壓加工步驟中,如圖3及圖4所示般,實施在黏著薄片100之黏著劑層3及第2薄片2形成切痕4之半切割,而將黏著劑層3分割為衝壓加工部31、衝壓加工部31以外的連續狀廢料部32。
In the press processing step, as shown in FIGS. 3 and 4, the
衝壓加工部31,如圖3所示般,較佳為設置於第2薄片2之第2區域21b內。此外,衝壓加工部31,是在黏著薄片100之整個長度方向設置於複數部位。
As shown in FIG. 3, the punching
在衝壓加工步驟之半切割是指,以黏著薄片100不被切斷的方式形成切痕4。藉由切痕4,使黏著劑層3及第2薄片2被切斷,但第1薄片1並未被切斷。切痕4是從黏著薄片100之第2薄片2側通過第2薄片2及黏著劑層
3而到達第1薄片1。切痕4至少到達黏著劑層3和第1薄片1的界面即可,但較佳為將黏著劑層3完全切開,而在第1薄片1的表面形成切口。
The half-cutting in the stamping process refers to forming the
在這種半切割中,可適宜地使用公知的衝壓刀。 In this half-cutting, a known punching knife can be suitably used.
衝壓加工步驟之半切割,是在衝壓加工部31的全周實施而設置衝壓加工部31。
The half cutting in the press working step is performed on the entire circumference of the
衝壓加工部31以外的部分,是成為從黏著薄片100將第2薄片2剝離時一起被剝離之連續狀廢料部32。
The portion other than the press-processed
在衝壓加工步驟之後,可如圖3及圖4所示般,進行在黏著薄片100之第2薄片2的表面設置輔助帶體5之輔助帶體貼合步驟。
After the punching process, as shown in FIGS. 3 and 4, an auxiliary tape body bonding step in which an
藉由將該輔助帶體5在整個長度方向進行貼合,可將形成有切痕4之第2薄片2一體化。因此,在後述的廢料除去步驟中,可將黏著劑層3的表面之第2薄片2剝離。
By bonding the
作為輔助帶體5可使用公知的膠帶。
As the
在廢料除去步驟中,如圖5及圖6所示般,從第1薄片1將連續狀廢料部32剝離,從黏著薄片100將連續狀廢料部32除去。
In the waste removal step, as shown in FIGS. 5 and 6, the
連續狀廢料部32,是和第2薄片2及輔助帶體5一起被除去。藉由將該連續狀廢料部32從黏著薄片100除去,如圖5所示般,可獲得被裁切成衝壓加工部31的形狀之黏著劑膜。
The
在此,衝壓加工部31在俯視下的形狀沒有特別的限定,按照其使用目的可適宜地改變。作為衝壓加工部31
在俯視下的形狀,可列舉多角形(三角形、四角形及五角形等)、圓形、橢圓形及星型等。
Here, the shape of the press-processed
如此般獲得的黏著劑膜,可運用於各種用途,適用於例如晶片之晶粒接合步驟所使用的薄膜狀黏著劑、切割晶粒接合薄膜、底部填充薄片、半導體晶圓的背面保護膜等。 The adhesive film obtained in this way can be used in various applications, such as film-like adhesives used in the die bonding step of wafers, dicing die bonding films, underfill sheets, backside protection films for semiconductor wafers, etc.
在本實施形態之黏著薄片的使用方法中,在廢料除去步驟之後,可具備將衝壓加工部31貼合於被黏著體之貼合步驟。在該貼合步驟中,是將第1薄片1剝離,並將衝壓加工部31貼合於被黏著體。
In the method of using the adhesive sheet of the present embodiment, after the waste removal step, a bonding step of bonding the
此外,在本實施形態之黏著薄片的使用方法中較佳為,前述衝壓加工步驟、前述廢料除去步驟及前述貼合步驟是藉由連續式的裝置來連續地進行。 In addition, in the method of using the adhesive sheet of the present embodiment, it is preferable that the press processing step, the waste removal step, and the bonding step are continuously performed by a continuous device.
依據本實施形態可發揮以下的作用效果。 According to this embodiment, the following effects can be achieved.
(1)連續狀廢料部32和第2薄片2一起被除去。在包含第1區域21a之區域中,連續狀廢料部32是和第1薄片1及第2薄片2進行接著。而且,比起第1薄片1之從黏著劑層3剝離的剝離力F1,在第1區域21a之第2薄片2之從黏著劑層3剝離的剝離力F3較大。因此,在廢料除去步驟中,可抑制構成連續狀廢料部32之黏著劑層3殘留於第1薄片1側。如此,可充分抑制廢料除去不良。
(1) The
(2)比起在第2區域21b之第2薄片2之從黏著劑層3剝離的剝離力F2,第1薄片1之從黏著劑層3剝離的剝離力F1較大。因此,在廢料除去步驟中,能將衝壓加工部31留在第1薄片1上。
(2) than in the
(3)在本實施形態較佳為,衝壓加工步驟、廢料除去步驟及貼合步驟是藉由連續式的裝置連續地進行。如此般使一連串的步驟連續進行,可效率良好地使用黏著薄片100而讓作業性及生產性提高。
(3) In this embodiment, it is preferable that the press processing step, the waste removal step, and the bonding step are continuously performed by a continuous device. In this way, a series of steps are continuously performed, the
接下來,針對本發明的第二實施形態,根據圖式做說明。 Next, the second embodiment of the present invention will be described based on the drawings.
在本實施形態,除了取代黏著薄片100而使用黏著薄片100A以外是具有與第一實施形態同樣的構造,因此僅針對黏著薄片100A及其使用方法做說明,而將除此以外的說明予以省略。
In this embodiment, except that the
本實施形態之黏著薄片100A,如圖7所示般是呈長條狀,且具備第1薄片1、第2薄片2、黏著劑層3。第1薄片1及第2薄片2設置於黏著劑層3的兩面。
The
第2薄片2在俯視下,如圖7所示般具有第1區域21a、第2區域21b。第1區域21a和第2區域21b,從黏著劑層3剝離之剝離性是不同。此外,第1區域21a,是包含第2薄片2之在俯視下之寬度方向的兩端部。而且,第1區域21a不僅設置於第2薄片2之在俯視下之寬度方
向的兩端部附近,在俯視下之長度方向的一部分,連在俯視下之寬度方向的中央附近都設有第1區域21a。更具體的說,在俯視下,在複數個衝壓加工部31之間的部分,連寬度方向的中央附近都設有第1區域21a。
The
在本實施形態之黏著薄片的使用方法之衝壓加工步驟中,如圖7所示般,實施在黏著薄片100A之黏著劑層3及第2薄片2形成切痕4之半切割,而設置衝壓加工部31。這時,衝壓加工部31如圖7所示般,是設置於第2薄片2之第2區域21b內。
In the press processing step of the method of using the adhesive sheet of the present embodiment, as shown in FIG. 7, a half-cut is performed to form a
依據本實施形態,可發揮與前述第一實施形態的作用效果(1)~(3)同樣的作用效果,且還能發揮下述作用效果(4)。 According to this embodiment, the same effect as the effect (1) to (3) of the aforementioned first embodiment can be exhibited, and the following effect (4) can also be exhibited.
(4)第1區域21a不僅設置於第2薄片2之在俯視下之寬度方向的兩端部附近,在俯視下之長度方向的一部分,連在俯視下之寬度方向的中央附近都設有第1區域21a。因此,在第二實施形態,第1區域21a的面積變得比前述第一實施形態之第1區域21a的面積更大。如此,在廢料除去步驟中,能更確實地抑制構成連續狀廢料部32之黏著劑層3殘留於第1薄片1側。
(4) The
本發明並不限定於前述的實施形態,可達成本發明的 目的之範圍內的變形、改良等也包含於本發明。 The present invention is not limited to the foregoing embodiments, and can reach the cost of the invention Modifications and improvements within the scope of the purpose are also included in the present invention.
例如,在前述實施形態,被裁切成既定形狀的黏著劑膜的用途,是作為晶片的晶粒接合步驟所使用之薄膜狀黏著劑、切割晶粒接合薄膜、底部填充薄片、半導體晶圓的背面保護膜等所使用之黏著劑膜,但並不限定於此。作為被裁切成既定形狀的黏著劑膜的用途,可列舉標籤、貼紙及徽章(wappen)等。 For example, in the foregoing embodiment, the adhesive film cut into a predetermined shape is used as a thin film adhesive used in the die bonding step of a wafer, a dicing die bonding film, an underfill sheet, and a semiconductor wafer The adhesive film used for the back surface protective film etc., but it is not limited to this. Examples of the use of the adhesive film cut into a predetermined shape include labels, stickers, wappen, and the like.
在前述實施形態,是以包含第2薄片2之在俯視下之寬度方向之兩端部的方式設置第1區域21a,但並不限定於此。例如,第1區域21a也能設置成,不包含第2薄片2在俯視下之寬度方向的兩端部,而是包含該兩端部的附近。
In the aforementioned embodiment, the
在前述實施形態,黏著劑層3是設置於俯視下之全面,但並不限定於此。例如,在俯視下,在黏著劑層3形成有不存在黏著劑的空間部亦可。
In the foregoing embodiment, the
在前述第二實施形態,如圖7所示般,在俯視下,在複數個衝壓加工部31之間的部分,分別包含端部之2個第1區域21a連寬度方向的中央附近都設置。而且,這2個第1區域21a,在複數個衝壓加工部31之間的部分是分開的,但並不限定於此。在複數個衝壓加工部31之間的部分,分別包含端部之2個第1區域21a連寬度方向的中央附近都設置且互相連結亦可。在此情況,除了在兩端部之連續狀廢料部32,甚至連在複數個衝壓加工部31之間的部分之連續狀廢料部32也能抑制廢料除去不良。如
此,在廢料除去步驟中,可更確實地抑制構成連續狀廢料部32之黏著劑層3殘留於第1薄片1側。
In the aforementioned second embodiment, as shown in FIG. 7, in a plan view, the two
接下來,利用實施例及比較例來更詳細地說明本發明,但本發明並不限定於這些例子。 Next, the present invention will be explained in more detail using examples and comparative examples, but the present invention is not limited to these examples.
作為第1薄片是準備下述的重剝離薄片,作為第2薄片是準備下述的輕剝離薄片。第1薄片及第2薄片為長條狀的薄片。 As the first sheet, the following heavy release sheet was prepared, and as the second sheet, the following light release sheet was prepared. The first sheet and the second sheet are elongated sheets.
製品名:SP-PET38T124-2、琳得科株式會社製 Product name: SP-PET38T124-2, manufactured by Lindk Co., Ltd.
厚度:38μm Thickness: 38μm
基材薄片的材質:聚對苯二甲酸乙二酯(PET) The material of the substrate sheet: Polyethylene terephthalate (PET)
製品名:SP-PET381031、琳得科株式會社製 Product name: SP-PET381031, manufactured by Lindk Co., Ltd.
厚度:38μm Thickness: 38μm
基材薄片的材質:聚對苯二甲酸乙二酯(PET) The material of the substrate sheet: Polyethylene terephthalate (PET)
對於剝離層的處理:有(在剝離層之寬度方向的兩端部附近,在沿著兩端部的區域實施電漿處理,藉此形成第1區域)。 Treatment of the peeling layer: Yes (in the vicinity of both ends in the width direction of the peeling layer, plasma treatment is applied to the areas along the both ends to form the first area).
接下來,在第1薄片及第2薄片之間形成乾燥後的厚度為25μm之黏著劑層,而獲得黏著薄片。具體而言,首先,在第1薄片(重剝離薄片),以乾燥後的厚度成為25μm的方式藉由刀式塗布機塗布黏著劑,然後進行乾燥而形成黏著劑層。接下來,將第2薄片(輕剝離薄片)積層並捲繞而獲得長條狀的黏著薄片。 Next, an adhesive layer having a thickness of 25 μm after drying was formed between the first sheet and the second sheet to obtain an adhesive sheet. Specifically, first, the adhesive is applied by a knife coater so that the thickness after drying becomes 25 μm on the first sheet (heavy release sheet), and then dried to form an adhesive layer. Next, the second sheet (light release sheet) is laminated and wound to obtain a long adhesive sheet.
接下來,將所獲得的長條狀的黏著薄片以230mm的寬度裁斷。形成於第2薄片(輕剝離薄片)之第1區域,是包含第2薄片之在俯視下之寬度方向的兩端部,離端部的距離約10mm。 Next, the obtained long adhesive sheet was cut to a width of 230 mm. The first area formed on the second sheet (light release sheet) includes both ends of the second sheet in the width direction in a plan view, and the distance from the end is about 10 mm.
此外,將第1薄片之從黏著劑層剝離的剝離力F1、在第2區域之第2薄片之從黏著劑層剝離的剝離力F2,使用拉伸試驗機依下述條件進行測定的結果,剝離力F1為492mN/100mm,剝離力F2為156mN/100mm。又已知當實施電漿處理的情況,剝離力變得非常大,可推斷在第1區域之第2薄片之從黏著劑層剝離的剝離力F3是比剝離力F1更大。 In addition, the peeling force F 1 of the first sheet from the adhesive layer and the peeling force F 2 of the second sheet from the adhesive layer in the second area were measured using a tensile tester under the following conditions As a result, the peeling force F 1 was 492 mN/100 mm, and the peeling force F 2 was 156 mN/100 mm. When the case of the embodiment and the known plasma treatment, the peel force becomes very large, the second sheet can be concluded in the first area of the peel force F 3 adhesive layer is greater than the peel force F. 1.
試料的大小:寬度100mm×長度100mm The size of the sample: width 100mm×length 100mm
拉伸速度:300mm/分 Stretching speed: 300mm/min
拉伸方向:180°方向 Stretching direction: 180° direction
對於所獲得的黏著薄片,使用LC膠帶積層裝置(琳得科株式會社製、「RAD-3600F/12」),依下述條件實施在黏著劑層及第2薄片形成切痕之半切割,藉此設置圓形的衝壓加工部、及衝壓加工部以外之連續狀廢料部,然 後從黏著薄片將連續狀廢料部除去。確認這時之黏著劑層的狀態的結果,在連續狀廢料部之黏著劑層的斷裂、在衝壓加工部之黏著劑層的分離並未發生。 For the obtained adhesive sheet, using an LC tape laminating device (manufactured by Lindeco Co., Ltd., "RAD-3600F/12"), the adhesive layer and the second sheet were half-cut to form cuts under the following conditions. This set up a circular stamping part and a continuous scrap part other than the stamping part. Then remove the continuous waste from the adhesive sheet. As a result of confirming the state of the adhesive layer at this time, the fracture of the adhesive layer in the continuous scrap part and the separation of the adhesive layer in the press processing part did not occur.
裝置內溫度:30℃ Temperature inside the device: 30℃
衝壓加工部的直徑:200mm Diameter of the stamping part: 200mm
進給速度:20mm/sec Feeding speed: 20mm/sec
除了在第2薄片未形成第1區域以外,是與實施例1同樣地獲得黏著薄片。 The adhesive sheet was obtained in the same manner as in Example 1, except that the first area was not formed in the second sheet.
而且,對於所獲得的黏著薄片,與實施例1同樣的,從黏著薄片將連續狀廢料部除去。確認這時的黏著劑層的狀態的結果,連續狀廢料部之黏著劑層的寬度方向之端部無法從重剝離薄片剝離,朝長度方向延伸後斷裂。 Furthermore, with respect to the obtained adhesive sheet, as in Example 1, the continuous waste part was removed from the adhesive sheet. As a result of confirming the state of the adhesive layer at this time, the width direction end of the adhesive layer of the continuous scrap portion could not be peeled from the heavy peeling sheet, and it was broken after extending in the longitudinal direction.
根據實施例1與比較例1之比較結果可明顯確認,當剝離力F1、剝離力F2及剝離力F3滿足前述數式(F1)的條件的情況(實施例1),可充分抑制廢料除去不良。相對於此,所使用的黏著薄片在第2薄片並未設置從黏著劑層剝離的剝離性不同的2個區域的情況(比較例1),並無法抑制廢料除去不良。 According to the comparison result of Example 1 and Comparative Example 1, it can be clearly confirmed that when the peeling force F 1 , the peeling force F 2 and the peeling force F 3 satisfy the conditions of the aforementioned formula (F1) (Example 1), it can be sufficiently suppressed Poor waste removal. On the other hand, in the adhesive sheet used, when the second sheet did not provide two regions with different releasability from the adhesive layer (Comparative Example 1), it was not possible to suppress defective removal of waste.
作為第2薄片是使用下述的輕剝離薄片,對於剝離層的處理如下述般改變,除此以外是與實施例1同樣地獲得 黏著薄片。 As the second sheet, the following light release sheet was used, and the handling of the release layer was changed as follows, except that it was obtained in the same manner as in Example 1 Adhesive flakes.
製品名:SP-PET381031、琳得科株式會社製 Product name: SP-PET381031, manufactured by Lindk Co., Ltd.
厚度:38μm Thickness: 38μm
基材薄片的材質:聚對苯二甲酸乙二酯(PET) The material of the substrate sheet: polyethylene terephthalate (PET)
對於剝離層的處理:有(在剝離層之寬度方向的兩端部附近,除了沿著兩端部的區域,在俯視下之複數個衝壓加工部之間的部分,連包含寬度方向的中央附近的區域(參照圖7)也實施電漿處理,藉此形成第1區域)。 Treatment of the peeling layer: Yes (in the vicinity of both ends in the width direction of the peeling layer, except for the area along the two ends, in the part between the plurality of punching parts in the plan view, including the widthwise center The region (see FIG. 7) is also subjected to plasma treatment, thereby forming the first region).
而且,對於所獲得的黏著薄片,與實施例1同樣的,從黏著薄片將連續狀廢料部除去。確認這時的黏著劑層的狀態的結果,在連續狀廢料部之黏著劑層的斷裂、在衝壓加工部之黏著劑層的分離並未發生。 Furthermore, with respect to the obtained adhesive sheet, as in Example 1, the continuous waste part was removed from the adhesive sheet. As a result of confirming the state of the adhesive layer at this time, the breakage of the adhesive layer in the continuous scrap part and the separation of the adhesive layer in the press processing part did not occur.
1‧‧‧第1薄片 1‧‧‧The first slice
2‧‧‧第2薄片 2‧‧‧Second sheet
3‧‧‧黏著劑層 3‧‧‧Adhesive layer
11‧‧‧第1基材薄片 11‧‧‧The first substrate sheet
12‧‧‧第1剝離層 12‧‧‧The first peeling layer
21‧‧‧第2基材薄片 21‧‧‧Second substrate sheet
21a‧‧‧第1區域
21a‧‧‧
21b‧‧‧第2區域
21b‧‧‧
22‧‧‧第2剝離層 22‧‧‧Second peeling layer
100‧‧‧黏著薄片 100‧‧‧Adhesive sheet
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TW200532850A (en) * | 2004-03-17 | 2005-10-01 | Nitto Denko Corp | Dicing die-bonding film |
TW200627536A (en) * | 2004-06-08 | 2006-08-01 | Hitachi Chemical Co Ltd | Adhesive sheet, method for producing the sheet, method for producing semiconductor device, and the semiconductor device |
CN101120131A (en) * | 2004-12-22 | 2008-02-06 | 纳幕尔杜邦公司 | Heavy calendered multiple component sheets and multi-layer laminates and packages therefrom |
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JPS5193849U (en) * | 1975-01-25 | 1976-07-28 | ||
JPH0791514B2 (en) * | 1987-09-29 | 1995-10-04 | 藤森工業株式会社 | Release film for double-sided adhesive tape |
JPH1121521A (en) * | 1997-07-02 | 1999-01-26 | Sekisui Chem Co Ltd | Double-coated pressure-sensitive adhesive tape |
JP5432459B2 (en) * | 2008-02-22 | 2014-03-05 | リンテック株式会社 | Substrate-less double-sided adhesive sheet and release sheet |
JP5394661B2 (en) * | 2008-06-17 | 2014-01-22 | リンテック株式会社 | Adhesive sheet |
JP5594860B2 (en) * | 2009-03-27 | 2014-09-24 | リンテック株式会社 | Hard coat film processing method, hard coat film and protective film |
JP2014189660A (en) * | 2013-03-27 | 2014-10-06 | Lintec Corp | Method for manufacturing laminate, adhesive roll and adhesive layer-containing laminated structure using laminate |
JP2014189659A (en) * | 2013-03-27 | 2014-10-06 | Lintec Corp | Method for manufacturing laminate, adhesive roll and adhesive layer-containing laminated structure using laminate |
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TW200532850A (en) * | 2004-03-17 | 2005-10-01 | Nitto Denko Corp | Dicing die-bonding film |
TW200627536A (en) * | 2004-06-08 | 2006-08-01 | Hitachi Chemical Co Ltd | Adhesive sheet, method for producing the sheet, method for producing semiconductor device, and the semiconductor device |
CN101120131A (en) * | 2004-12-22 | 2008-02-06 | 纳幕尔杜邦公司 | Heavy calendered multiple component sheets and multi-layer laminates and packages therefrom |
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WO2017145734A1 (en) | 2017-08-31 |
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