TWI693282B - Automobile glass cleaner and preparation method thereof - Google Patents

Automobile glass cleaner and preparation method thereof Download PDF

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TWI693282B
TWI693282B TW108115907A TW108115907A TWI693282B TW I693282 B TWI693282 B TW I693282B TW 108115907 A TW108115907 A TW 108115907A TW 108115907 A TW108115907 A TW 108115907A TW I693282 B TWI693282 B TW I693282B
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TW202041666A (en
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簡景昇
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簡景昇
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Abstract

本發明係為一種汽車玻璃清潔劑及其製備方法,包含有將氧化矽、氧化鎂、的氧化鈣、的氧化鋁及的氧化鐵之粉末均勻混合之粉末混合步驟;將上述混合後氧化矽、氧化鎂、氧化鈣、氧化鋁及氧化鐵高溫燒製形成球體並使粒子鈍化形成無銳角之燒製結球步驟;將球體研磨成奈米研磨粒子之奈米研磨步驟;準備無磷洗淨劑之步驟;將研磨粒子與粉狀無磷洗潔劑以1:1的比例混合之均勻混合步驟;藉此,俾提供一種清除汽車玻璃上的污垢及油膜,使玻璃回復清晰的清潔劑組合物及其製備方法。 The present invention is an automobile glass cleaner and its preparation method, which includes a powder mixing step of uniformly mixing powders of silicon oxide, magnesium oxide, calcium oxide, aluminum oxide and iron oxide; Magnesium oxide, calcium oxide, aluminum oxide, and iron oxide are fired at high temperature to form spheres and passivate the particles to form a sintered spheroidizing step without sharp angles; the nano-grinding step of grinding the spheres into nano-abrasive particles; prepare phosphorus-free detergents Step; a uniform mixing step of mixing the abrasive particles with the powdered phosphorus-free detergent at a ratio of 1:1; thereby, to provide a detergent composition that removes dirt and oil film on automobile glass and restores the glass to clear Its preparation method.

Description

汽車玻璃清潔劑及其製備方法 Automobile glass cleaner and preparation method thereof

本發明係為一種汽車玻璃清潔劑及其製備方法,特別是一種可清除汽車玻璃上的污垢及油膜,使玻璃回復清晰的清潔劑及其製備方法。 The invention is an automobile glass cleaner and a preparation method thereof, in particular a cleaner and a preparation method which can remove dirt and oil film on an automobile glass and make the glass clear.

按,由於汽車在行駛時,汽車玻璃會沾染灰塵與汽機車排放的廢氣,或長時間停放於戶外造成玻璃氧化,甚至在打蠟時臘膜噴濺到汽車玻璃上,造成汽車玻璃上形成油膜與髒汙;如第1圖所示,汽車玻璃10上的油膜11與髒汙當積累至一定厚度時,不僅會影響玻璃的清晰度與使用者的視線,當下雨開啟雨刷時,雨刷無法有效刷除雨水而越刷越霧,且雨刷會受油膜11之阻力影響而跳動,進而影響行車安全。 Press, because when the car is driving, the car glass will be contaminated with dust and exhaust gas emitted by the steam locomotive, or parked outdoors for a long time to cause glass oxidation, and even the wax film is sprayed on the car glass during waxing, causing an oil film to form on the car glass And dirt; as shown in Figure 1, the oil film 11 and dirt on the car glass 10 when accumulated to a certain thickness, will not only affect the clarity of the glass and the user's sight, when the rain wiper is turned on, the wiper will not be effective The rain is wiped off and the fog becomes more and more, and the wiper will jump under the influence of the resistance of the oil film 11, thereby affecting driving safety.

而目前汽車玻璃所使用的清潔劑,主要為一般玻璃清洗劑與油膜清除劑,一般的玻璃清潔劑可洗去灰塵髒污,而油膜清除劑則可清除玻璃上的油膜;因此,使用者必須備置二種不同的清潔劑,實有購買成本的增加、佔據容置空間、且必須先清潔玻璃後再進行除油膜作業,而有費時費力之缺失帶改進。 At present, the cleaning agents used in automobile glass are mainly general glass cleaners and oil film removers. General glass cleaners can wash away dust and dirt, and oil film removers can remove oil films on the glass; therefore, users must Two different cleaning agents are prepared, which actually increases the purchase cost, occupies the accommodating space, and must clean the glass before performing the degreasing film operation, and there is a time-consuming and labor-intensive improvement.

另外,由於目前所使用的油膜清除劑,主要以介面活性劑、乙二醇(或丙二醇)之液狀組合物,或為添加玻璃系粉末之研磨劑為大宗。然,由於以界面活性劑及乙二醇為原料之清潔劑係呈鹼性,其會人體肌膚產生受侵蝕而受傷;而以玻璃系粉末研磨劑為原料之清潔劑,由於其所含 之玻璃系粉末由於並非為無鈍角之設計,因此玻璃系粉末很容易在擦拭時刮傷汽車玻璃表面並產生刮痕,進而使油膜、灰塵、髒污容易堆積於刮痕中,導致汽車玻璃無法有效清潔乾淨。 In addition, the oil film scavengers currently used are mainly composed of surfactants, liquid compositions of ethylene glycol (or propylene glycol), or abrasives added with glass-based powders. Of course, because the detergent based on surfactant and ethylene glycol is alkaline, it will cause human skin to be eroded and injured; while the detergent based on glass powder abrasives, due to its content Because the glass powder is not designed without obtuse angles, the glass powder can easily scratch the surface of the car glass and produce scratches when it is wiped, which makes the oil film, dust, and dirt easily accumulate in the scratches, causing the car glass to fail Effectively clean.

本發明之目的,即在於改善上述之缺失,俾提供一種可清除汽車玻璃上的污垢及油膜,使玻璃回復清晰的清潔劑及其製備方法。 The purpose of the present invention is to improve the above-mentioned deficiencies, so as to provide a cleaning agent that can remove dirt and oil film on automobile glass, and restore the glass to clear, and a preparation method thereof.

為達到上述目的,本發明之清潔劑及其製備方法,包含有如下之步驟:粉末混合:將8~12%的氧化矽、8~12%的氧化鎂、8~12%的氧化鈣、8~12%的氧化鋁及8~12%的氧化鐵之粉末均勻混合;燒製結球:將上述混合後氧化矽、氧化鎂、氧化鈣、氧化鋁及氧化鐵高溫燒製,使氧化矽、氧化鎂、氧化鈣、氧化鋁及氧化鐵之粉末結合形成一混合球體,且上述該些混合後之氧化矽、氧化鎂、氧化鈣、氧化鋁及氧化鐵高溫燒製會使粒子鈍化形成無銳角;研磨:將經上述燒製步驟後之混合球體研磨成研磨粒子,並使研磨粒子之粒徑達到奈米級粉末,同時,每一研磨粒子之周緣皆為無銳角狀,且該些研磨粒子並不溶於水中;無磷洗潔劑製備:準備粉狀無磷洗潔劑,該無磷洗潔劑可用以清潔玻璃;該洗潔劑之成分可為粉末狀的10%的纖維酵素(BIO-LITE)、10%的汙垢分解酵素(PROTEASE)、5%的直鏈式烷基苯磺酸鈉(LAS)、10%的天然非離子活性劑(NONION)、10%的污垢再附著防止劑(MACP)、5%的洗淨強化助劑(SODA)均勻混合; 均勻混合:上述經研磨步驟後之研磨粒子與粉狀無磷洗潔劑以1:1的比例均勻混合,即形成可去除油膜、灰塵、髒污的玻璃洗淨劑;藉此,俾提供一種可清除汽車玻璃上的污垢及油膜,使玻璃回復清晰的製備方法。 In order to achieve the above object, the cleaning agent of the present invention and its preparation method include the following steps: powder mixing: 8 to 12% of silicon oxide, 8 to 12% of magnesium oxide, 8 to 12% of calcium oxide, 8 ~12% of alumina and 8-12% of iron oxide powder are evenly mixed; sintered ball: the above mixed silicon oxide, magnesium oxide, calcium oxide, aluminum oxide and iron oxide are fired at high temperature to make silicon oxide and oxidation The powders of magnesium, calcium oxide, aluminum oxide and iron oxide combine to form a mixed sphere, and the high-temperature firing of these mixed silicon oxide, magnesium oxide, calcium oxide, aluminum oxide and iron oxide will passivate the particles to form no acute angle; Grinding: grind the mixed spheres after the above-mentioned firing steps into abrasive particles, and make the particle size of the abrasive particles reach nanometer-level powder. At the same time, the periphery of each abrasive particle is non-acute angle, and the abrasive particles are combined Insoluble in water; preparation of phosphorus-free detergent: prepare powder-free phosphorus-free detergent, which can be used to clean glass; the composition of the detergent can be powdered 10% cellulase (BIO- LITE), 10% dirt decomposition enzyme (PROTEASE), 5% linear alkylbenzene sulfonate (LAS), 10% natural non-ionic active agent (NONION), 10% dirt re-adhesion inhibitor ( MACP), 5% cleaning and strengthening aid (SODA), evenly mixed; Homogeneous mixing: the above-mentioned abrasive particles after the grinding step and the powdered phosphorus-free detergent are evenly mixed at a ratio of 1:1, that is, a glass detergent that can remove oil film, dust, and dirt is formed; thereby, to provide a Preparation method for removing dirt and oil film on automobile glass and making the glass clear.

10‧‧‧汽車玻璃 10‧‧‧Auto glass

11‧‧‧油膜 11‧‧‧oil film

12‧‧‧擦拭件 12‧‧‧ Wipe

第1圖係汽車玻璃附著油膜及髒汙之剖視構造圖。 Figure 1 is a cross-sectional structural view of an oil film and dirt attached to an automobile glass.

第2圖係本發明之製造流程圖。 Figure 2 is a manufacturing flowchart of the present invention.

第3圖係汽車玻璃附著油膜及髒汙之剖視構造圖,及利用本發明與擦拭件清洗汽車玻璃之示意圖。 FIG. 3 is a cross-sectional structural view of an oil film and dirt attached to an automobile glass, and a schematic diagram of cleaning the automobile glass using the present invention and a wiper.

有關本發明為達到目的所運用之技術手段及其構造,茲謹再配合第2至第3圖所示之實施例,詳細說明如下:如第2圖所示,本發明之清潔劑製備方法,包含有如下之步驟:粉末混合:將8~12%的氧化矽、8~12%的氧化鎂、8~12%的氧化鈣、8~12%的氧化鋁及8~12%的氧化鐵之粉末均勻混合。 Regarding the technical means and the structure used by the present invention to achieve the purpose, I would like to cooperate with the embodiments shown in FIGS. 2 to 3, and the detailed description is as follows: As shown in FIG. 2, the preparation method of the cleaning agent of the present invention, It includes the following steps: powder mixing: mixing 8-12% silica, 8-12% magnesia, 8-12% calcium oxide, 8-12% alumina and 8-12% iron oxide The powder is mixed evenly.

燒製結球:將上述混合後氧化矽、氧化鎂、氧化鈣、氧化鋁及氧化鐵高溫燒製,使氧化矽、氧化鎂、氧化鈣、氧化鋁及氧化鐵之粉末結合形成一混合球體,且上述該些混合後之氧化矽、氧化鎂、氧化鈣、氧化鋁及氧化鐵高溫燒製會使粒子鈍化形成無銳角。 Sintered ball: The above mixed silicon oxide, magnesium oxide, calcium oxide, aluminum oxide and iron oxide are fired at high temperature to combine the powders of silicon oxide, magnesium oxide, calcium oxide, aluminum oxide and iron oxide to form a mixed sphere, and The high-temperature firing of the mixed silicon oxide, magnesium oxide, calcium oxide, aluminum oxide, and iron oxide will passivate the particles to form no sharp angles.

奈米研磨:將經上述燒製步驟後之混合球體研磨成研磨粒 子,並使研磨粒子之粒徑達到奈米級粉末,同時,每一研磨粒子之周緣皆為無銳角狀,且該些研磨粒子並不溶於水中。 Nano-grinding: grind the mixed spheres after the above firing steps into abrasive particles The particle size of the abrasive particles can reach nano-level powder. At the same time, the peripheral edge of each abrasive particle has no acute angle, and the abrasive particles are not soluble in water.

無磷洗潔劑:準備粉狀無磷洗潔劑,該無磷洗潔劑可用以清潔玻璃;該洗潔劑之成分可為粉末狀的10%的纖維酵素(BIO-LITE)、10%的汙垢分解酵素(PROTEASE)、5%的直鏈式烷基苯磺酸鈉(LAS)、10%的天然非離子活性劑(NONION)、10%的污垢再附著防止劑(MACP)、5%的洗淨強化助劑(SODA)均勻混合。 Phosphorus-free detergent: prepare powder-free phosphorus-free detergent, which can be used to clean glass; the composition of the detergent can be powdered 10% fiber enzyme (BIO-LITE), 10% Protease (PROTEASE), 5% linear alkylbenzene sulfonate (LAS), 10% natural non-ionic active agent (NONION), 10% scale re-adhesion inhibitor (MACP), 5% The SODA is evenly mixed.

均勻混合:上述經研磨步驟後之研磨粒子與粉狀無磷洗潔劑以1:1的比例均勻混合,即形成可去除油膜、灰塵、髒污的玻璃洗淨劑。 Uniform mixing: the above-mentioned grinding particles after the grinding step and the powdered phosphorus-free detergent are uniformly mixed in a ratio of 1:1 to form a glass detergent that can remove oil film, dust and dirt.

藉由上述步驟,可得汽車玻璃清潔劑之組合物,該組合物內含有粉狀研磨粒子與粉狀無磷洗潔劑,該粉狀研磨粒子與粉狀無磷洗潔劑之比例為1:1,其中,該研磨粒子含有8~12%氧化矽、8~12%氧化鎂、8~12%氧化鈣、8~12%氧化鋁及8~12%氧化鐵之無鈍角粉末粒子;而較佳之實施例是,該洗淨劑則包含有粉末狀之10%的纖維酵素(BIO-LITE)、10%的汙垢分解酵素(PROTEASE)、5%的直鏈式烷基苯磺酸鈉(LAS)、10%的天然飛離子活性劑(NONION)、10%的污垢再附著防止劑(MACP)、5%的洗淨強化助劑(SODA);藉此,均勻混合後即形成玻璃清潔劑。 Through the above steps, a composition of automotive glass cleaner can be obtained, which contains powdered abrasive particles and powdered phosphorus-free detergent, the ratio of the powdered abrasive particles to powdered phosphorus-free detergent is 1 : 1, where the abrasive particles contain 8-12% silicon oxide, 8-12% magnesium oxide, 8-12% calcium oxide, 8-12% alumina and 8-12% iron oxide non-obtuse powder particles; and A preferred embodiment is that the detergent contains powdered 10% cellulase (BIO-LITE), 10% dirt decomposition enzyme (PROTEASE), and 5% sodium linear alkylbenzene sulfonate ( LAS), 10% natural flying ion active agent (NONION), 10% dirt re-adhesion prevention agent (MACP), 5% cleaning strengthening aid (SODA); by this, it forms a glass cleaner after uniform mixing .

使用時,先將汽車玻璃10以水液淋濕,然後將擦拭件20(如:泡棉、麂皮、纖維布、…等)浸濕,接著將本發明之清潔劑均勻灑於擦拭件20上,然後再以擦拭件20擦拭清潔汽車玻璃10(如第3圖所示),此時由於研磨粒子不溶於水中,該些研磨粒子可隨擦拭件20之移動而對附著於汽車玻璃10上的油膜11及髒污進行研磨,使破壞、分解油膜11及髒 污,且可對汽車玻璃10進行研磨拋光;同時,藉由粉狀洗淨劑接觸殘留於汽車玻璃10上之水液時,粉狀洗淨劑可溶於水中,並隨使用者移動擦拭件20而可對汽車玻璃10進行清潔,進而可有效洗淨、移除附著於汽車玻璃上的油膜11與髒汙,使汽車玻璃10回復原本的潔淨度與光亮度,即可提高避免油膜11及髒汙影響、干擾雨刷之動作,實可提高行車安全。 When in use, first wet the automobile glass 10 with water, then wet the wiper 20 (such as foam, suede, fiber cloth, etc.), and then evenly spray the cleaning agent of the present invention on the wiper 20 Then, wipe the cleaning glass 10 with the wiper 20 (as shown in Figure 3). At this time, since the abrasive particles are not soluble in water, the abrasive particles can adhere to the car glass 10 as the wiper 20 moves The oil film 11 and the dirt are polished to destroy and decompose the oil film 11 and the dirt Dirt, and can grind the automobile glass 10; at the same time, when the powdery detergent contacts the water remaining on the automobile glass 10, the powdery detergent can be dissolved in water, and the wiper moves with the user 20, the automobile glass 10 can be cleaned, and the oil film 11 and dirt attached to the automobile glass can be effectively washed and removed, and the automobile glass 10 can be restored to the original cleanliness and brightness, which can improve the avoidance of the oil film 11 and The dirt affects and interferes with the operation of the wipers, which can actually improve driving safety.

特別說明的是,該粉狀無磷洗潔劑亦可添加其他洗淨成分來增加洗淨效果,也可添加芳香劑,該無磷洗淨劑並不以上述揭露成分為限。 In particular, the powdered phosphorus-free detergent can also be added with other cleaning ingredients to increase the cleaning effect, and fragrances can also be added. The phosphorus-free detergent is not limited to the above-mentioned disclosed ingredients.

由是,從以上所述可知,本發明具有如下之優點: Therefore, as can be seen from the above, the present invention has the following advantages:

(一)由於本發明之清潔劑添加有研磨粒子,該些研磨粒子可對附著於汽車玻璃上的油膜及髒汙進行研磨,使油膜及髒汙可受研磨摩擦而自玻璃表面脫落;相較於僅用一般玻璃洗淨劑來清洗,本發明確可有效清除油膜及髒汙,提高汽車玻璃的潔淨度。 (1) Because the cleaning agent of the present invention is added with abrasive particles, the abrasive particles can grind the oil film and dirt attached to the automobile glass, so that the oil film and dirt can be detached from the glass surface by the friction of grinding; Since it is only cleaned with general glass cleaners, the present invention can effectively remove oil film and dirt, and improve the cleanliness of automobile glass.

(二)由於本發明之研磨粒子先經高溫燒製,使研磨粒子鈍化無銳角後,再研磨形成奈米級粉末,當本發明之研磨粒子進行研磨時,其並不會刮傷玻璃表面,因此不會有刮痕產生,進而可避免後續灰塵髒汙卡固於刮痕中,本發明確具有實用性。 (2) Because the abrasive particles of the present invention are fired at a high temperature to passivate the abrasive particles without sharp angles, they are then ground to form nano-sized powders. When the abrasive particles of the present invention are ground, they will not scratch the glass surface. Therefore, there will be no scratches, which can prevent subsequent dust from being stuck in the scratches, and the invention is indeed practical.

(三)由於本發明進一步含有洗淨劑,該洗淨劑可溶於水中,在研磨粒子研磨清除油膜及髒汙的同時,也可對玻璃進行洗淨清潔,使玻璃回復潔淨、清晰如新;相較於習用必須分次使用油膜清除劑、玻璃清潔劑之方式,本發明確具有使用方便性與快速性。 (3) Since the present invention further contains a cleaning agent, the cleaning agent is soluble in water, and at the same time when the abrasive particles are grinded to remove the oil film and dirt, the glass can also be washed and cleaned to make the glass clean and clear as new Compared with the conventional method of using oil film scavengers and glass cleaners in stages, the present invention does have the convenience and speed of use.

(四)由於本發明可有效將汽車玻璃清除油膜及髒汙,並可洗淨汽車玻璃,當雨刷刷動時,雨刷不會受油膜及髒污的干擾而跳動,也 不會無法刷除雨水而產生水痕、霧痕,進而可有效提高行車安全。 (4) Since the present invention can effectively remove oil film and dirt on automobile glass, and can wash automobile glass, when the wiper brush moves, the wiper will not jump due to the interference of the oil film and dirt, and Will not be unable to brush off the rain to produce water marks and fog marks, which can effectively improve driving safety.

由是,本發明確可提供一種可清除汽車玻璃上的污垢及油膜,使玻璃回復清晰的清潔劑及其製備方法,本發明確具有顯著之進步性,且其構造確為未曾有過,誠已符合發明專利之要件,爰依法提出專利申請,並祈賜專利為禱,至感德便。 Therefore, the present invention can indeed provide a cleaning agent that can remove dirt and oil film on automobile glass and restore the glass to clear, and the preparation method thereof. The present invention does have significant progress, and its structure is indeed unprecedented. In line with the requirements of the invention patent, I filed a patent application in accordance with the law, and prayed for the patent as a prayer.

惟以上所述,僅為本發明之可行實施例,該實施例主要僅在於用以舉例說明本發明為達到目的所運用之技術手段及其構造,因此並不能以之限定本發明之保護範圍,舉凡依本發明說明書及申請專利範圍所為之等效變化或修飾,皆應仍屬本發明所涵蓋之保護範圍者。 However, the above is only a feasible embodiment of the present invention. This embodiment is mainly only used to illustrate the technical means and structure used by the present invention to achieve the purpose, so it cannot be used to limit the protection scope of the present invention. Any equivalent changes or modifications based on the description of the present invention and the scope of patent application shall fall within the scope of protection covered by the present invention.

Claims (3)

一種汽車玻璃清潔劑的製備方法,包含有如下之步驟:粉末混合:將8~12%的氧化矽、8~12%的氧化鎂、8~12%的氧化鈣、8~12%的氧化鋁及8~12%的氧化鐵之粉末均勻混合;燒製結球:將上述混合後氧化矽、氧化鎂、氧化鈣、氧化鋁及氧化鐵高溫燒製,使氧化矽、氧化鎂、氧化鈣、氧化鋁及氧化鐵之粉末結合形成一混合球體,且上述該些混合後之氧化矽、氧化鎂、氧化鈣、氧化鋁及氧化鐵高溫燒製會使粒子鈍化形成無銳角;研磨:將經上述燒製步驟後之混合球體研磨成研磨粒子,並使研磨粒子之粒徑達到奈米級粉末,同時,每一研磨粒子之周緣皆為無銳角狀,且該些研磨粒子並不溶於水中;無磷洗潔劑製備:準備粉狀無磷洗潔劑,該無磷洗潔劑可用以清潔玻璃;均勻混合:上述經研磨步驟後之研磨粒子與粉狀無磷洗潔劑以1:1的比例均勻混合,即形成可去除油膜、灰塵、髒污的玻璃洗淨劑。 A preparation method of automobile glass cleaner includes the following steps: powder mixing: 8~12% silica, 8~12% magnesia, 8~12% calcium oxide, 8~12% alumina And 8~12% of iron oxide powder are evenly mixed; sintering ball: the above mixed silicon oxide, magnesium oxide, calcium oxide, aluminum oxide and iron oxide are fired at high temperature, so that silicon oxide, magnesium oxide, calcium oxide, oxidation The powder of aluminum and iron oxide is combined to form a mixed sphere, and the high-temperature firing of the mixed silicon oxide, magnesium oxide, calcium oxide, aluminum oxide and iron oxide will passivate the particles to form no acute angle; grinding: will be burned by the above After the preparation step, the mixed spheres are grinded into abrasive particles, and the particle size of the abrasive particles reaches nano-level powder. At the same time, the periphery of each abrasive particle has no acute angle, and the abrasive particles are not soluble in water; no phosphorus Preparation of detergent: prepare powder-free phosphorus-free detergent, which can be used to clean glass; evenly mixed: the ratio of grinding particles and powder-free phosphorus-free detergent after the above grinding step is 1:1 Evenly mixed to form a glass cleaner that can remove oil film, dust and dirt. 如請求項1所述之該汽車玻璃清潔劑的製備方法,其中該洗潔劑之成分包含粉末狀的10%的纖維酵素、10%的汙垢分解酵素、5%的直鏈式烷基苯磺酸鈉、10%的天然非離子活性劑、10%的污垢再附著防止劑、5%的洗淨強化助劑均勻混合。 The preparation method of the automotive glass cleaner according to claim 1, wherein the composition of the detergent includes powdered 10% cellulase, 10% dirt decomposing enzyme, and 5% linear alkylbenzenesulfonate Sodium, 10% natural non-ionic active agent, 10% dirt re-adhesion preventive agent, and 5% cleaning strengthening aid are mixed evenly. 一種汽車玻璃清潔劑組合物,係由請求項1或2所述之製備方法所製成。 An automobile glass cleaner composition is made by the preparation method described in claim 1 or 2.
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100339326B1 (en) * 1996-04-16 2002-11-18 더 프록터 앤드 갬블 캄파니 Heavy chain side-chained detergent
CN101490228A (en) * 2006-07-24 2009-07-22 埃科莱布有限公司 Warewashing composition for use in automatic dishwashing machines, and method for using
CN102060562A (en) * 2010-11-18 2011-05-18 陕西科技大学 Preparation method of ceramic granules

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100339326B1 (en) * 1996-04-16 2002-11-18 더 프록터 앤드 갬블 캄파니 Heavy chain side-chained detergent
CN101490228A (en) * 2006-07-24 2009-07-22 埃科莱布有限公司 Warewashing composition for use in automatic dishwashing machines, and method for using
CN102060562A (en) * 2010-11-18 2011-05-18 陕西科技大学 Preparation method of ceramic granules

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