TWI660930B - 具有高熱膨脹係數之抗損壞玻璃 - Google Patents
具有高熱膨脹係數之抗損壞玻璃 Download PDFInfo
- Publication number
- TWI660930B TWI660930B TW107132600A TW107132600A TWI660930B TW I660930 B TWI660930 B TW I660930B TW 107132600 A TW107132600 A TW 107132600A TW 107132600 A TW107132600 A TW 107132600A TW I660930 B TWI660930 B TW I660930B
- Authority
- TW
- Taiwan
- Prior art keywords
- glass
- mol
- mole
- temperature
- ion
- Prior art date
Links
- 239000011521 glass Substances 0.000 title claims abstract description 179
- 238000005342 ion exchange Methods 0.000 claims abstract description 35
- 229910052845 zircon Inorganic materials 0.000 claims abstract description 26
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims abstract description 26
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 14
- 150000002500 ions Chemical group 0.000 claims abstract description 13
- 238000000354 decomposition reaction Methods 0.000 claims description 31
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 30
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 19
- 230000006835 compression Effects 0.000 claims description 12
- 238000007906 compression Methods 0.000 claims description 12
- 229910000272 alkali metal oxide Inorganic materials 0.000 claims description 4
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 abstract description 6
- 239000010410 layer Substances 0.000 description 39
- 238000007373 indentation Methods 0.000 description 34
- 239000000203 mixture Substances 0.000 description 19
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 238000000137 annealing Methods 0.000 description 7
- 239000007788 liquid Substances 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 229910006404 SnO 2 Inorganic materials 0.000 description 5
- -1 for example Chemical class 0.000 description 5
- 239000000156 glass melt Substances 0.000 description 4
- 230000003287 optical effect Effects 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 229910018068 Li 2 O Inorganic materials 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 239000006059 cover glass Substances 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 101001062093 Homo sapiens RNA-binding protein 15 Proteins 0.000 description 2
- 102100029244 RNA-binding protein 15 Human genes 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000007655 standard test method Methods 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000007545 Vickers hardness test Methods 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000006121 base glass Substances 0.000 description 1
- 229910001423 beryllium ion Inorganic materials 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000003280 down draw process Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000006060 molten glass Substances 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 238000013001 point bending Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/097—Glass compositions containing silica with 40% to 90% silica, by weight containing phosphorus, niobium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C21/00—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
- C03C21/001—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions
- C03C21/002—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions to perform ion-exchange between alkali ions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/18—Compositions for glass with special properties for ion-sensitive glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2204/00—Glasses, glazes or enamels with special properties
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31—Surface property or characteristic of web, sheet or block
- Y10T428/315—Surface modified glass [e.g., tempered, strengthened, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Glass Compositions (AREA)
- Surface Treatment Of Glass (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201361870301P | 2013-08-27 | 2013-08-27 | |
| US61/870,301 | 2013-08-27 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201906796A TW201906796A (zh) | 2019-02-16 |
| TWI660930B true TWI660930B (zh) | 2019-06-01 |
Family
ID=51493068
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW107132600A TWI660930B (zh) | 2013-08-27 | 2014-08-26 | 具有高熱膨脹係數之抗損壞玻璃 |
| TW103129400A TWI639572B (zh) | 2013-08-27 | 2014-08-26 | 具有高熱膨脹係數之抗損壞玻璃 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW103129400A TWI639572B (zh) | 2013-08-27 | 2014-08-26 | 具有高熱膨脹係數之抗損壞玻璃 |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US9969644B2 (OSRAM) |
| EP (1) | EP3038983B1 (OSRAM) |
| JP (1) | JP6600309B2 (OSRAM) |
| KR (1) | KR102290967B1 (OSRAM) |
| CN (2) | CN113860730A (OSRAM) |
| TW (2) | TWI660930B (OSRAM) |
| WO (1) | WO2015031188A1 (OSRAM) |
Families Citing this family (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9359251B2 (en) | 2012-02-29 | 2016-06-07 | Corning Incorporated | Ion exchanged glasses via non-error function compressive stress profiles |
| US11079309B2 (en) | 2013-07-26 | 2021-08-03 | Corning Incorporated | Strengthened glass articles having improved survivability |
| WO2015031188A1 (en) * | 2013-08-27 | 2015-03-05 | Corning Incorporated | Damage resistant glass with high coefficient of thermal expansion |
| KR102314817B1 (ko) | 2013-11-19 | 2021-10-20 | 코닝 인코포레이티드 | 이온 교환 가능한 높은 내손상성 유리 |
| US9517968B2 (en) | 2014-02-24 | 2016-12-13 | Corning Incorporated | Strengthened glass with deep depth of compression |
| US9359243B2 (en) * | 2014-05-13 | 2016-06-07 | Corning Incorporated | Transparent glass-ceramic articles, glass-ceramic precursor glasses and methods for forming the same |
| TWI705889B (zh) | 2014-06-19 | 2020-10-01 | 美商康寧公司 | 無易碎應力分布曲線的玻璃 |
| KR20190143469A (ko) | 2014-10-08 | 2019-12-30 | 코닝 인코포레이티드 | 금속 산화물 농도 구배를 포함한 유리 및 유리 세라믹 |
| US10150698B2 (en) | 2014-10-31 | 2018-12-11 | Corning Incorporated | Strengthened glass with ultra deep depth of compression |
| KR102648369B1 (ko) | 2014-11-04 | 2024-03-15 | 코닝 인코포레이티드 | 비-취약성 응력 프로파일 및 이의 제조방법 |
| WO2016210244A1 (en) | 2015-06-26 | 2016-12-29 | Corning Incorporated | Glass with high surface strength |
| US11104602B2 (en) | 2015-06-26 | 2021-08-31 | Corning Incorporated | Glass with high surface strength |
| US11613103B2 (en) | 2015-07-21 | 2023-03-28 | Corning Incorporated | Glass articles exhibiting improved fracture performance |
| US10579106B2 (en) | 2015-07-21 | 2020-03-03 | Corning Incorporated | Glass articles exhibiting improved fracture performance |
| CN108367964A (zh) | 2015-12-08 | 2018-08-03 | 康宁股份有限公司 | S形应力分布及其形成方法 |
| ES2879650T3 (es) | 2015-12-11 | 2021-11-22 | Corning Inc | Artículos a base de vidrio formables por fusión que incluyen un gradiente de concentración de óxido de metal |
| US10550029B2 (en) | 2015-12-17 | 2020-02-04 | Corning Incorporated | Ion exchangeable glass with fast diffusion |
| TWI853308B (zh) * | 2016-02-22 | 2024-08-21 | 美商康寧公司 | 無鹼硼鋁矽酸鹽玻璃 |
| TWI675015B (zh) | 2016-04-08 | 2019-10-21 | 美商康寧公司 | 包含金屬氧化物濃度梯度之玻璃基底物件 |
| US10271442B2 (en) | 2016-04-08 | 2019-04-23 | Corning Incorporated | Glass-based articles including a stress profile comprising two regions, and methods of making |
| CN109476530A (zh) | 2016-07-28 | 2019-03-15 | 康宁股份有限公司 | 具有抗光致暗化性的玻璃 |
| US10065880B2 (en) | 2016-11-07 | 2018-09-04 | Corning Incorporated | Lithium containing glasses |
| CN110167894A (zh) * | 2016-11-07 | 2019-08-23 | 康宁股份有限公司 | 含锂玻璃 |
| US10899653B2 (en) | 2017-01-09 | 2021-01-26 | Corning Incorporated | Ion-exchangeable glass with low coefficient of thermal expansion |
| WO2018164904A1 (en) * | 2017-03-09 | 2018-09-13 | Corning Incorporated | Method of electrostatic charge reduction of glass by surface chemical treatment |
| US11028007B2 (en) | 2017-06-22 | 2021-06-08 | Corning Incorporated | Automotive glass compositions, articles and hybrid laminates |
| NL2020896B1 (en) | 2018-05-08 | 2019-11-14 | Corning Inc | Water-containing glass-based articles with high indentation cracking threshold |
| TWI891613B (zh) | 2018-11-16 | 2025-08-01 | 美商康寧公司 | 用於透過蒸氣處理而強化之玻璃成分及方法 |
| WO2020102147A2 (en) | 2018-11-16 | 2020-05-22 | Corning Incorporated | Laminated glass articles comprising a hydrogen-containing glass core layer and methods of forming the same |
| CN109836037A (zh) * | 2019-03-22 | 2019-06-04 | 科立视材料科技有限公司 | 一种具有低成本高压缩应力层的磷铝硅酸盐玻璃 |
| WO2020231959A1 (en) | 2019-05-16 | 2020-11-19 | Corning Incorporated | Glasses with modified young's modulus profile |
| US12122711B2 (en) | 2019-05-16 | 2024-10-22 | Corning Incorporated | Steam strengthenable glass compositions with low phosphorous content |
| CN114127024B (zh) | 2019-05-16 | 2023-10-24 | 康宁股份有限公司 | 具有蒸汽处理雾度抗性的玻璃组合物及其方法 |
| JP7296539B2 (ja) * | 2019-11-18 | 2023-06-23 | Ａｇｃ株式会社 | 支持ガラス基板及び積層体 |
| CN114845965A (zh) | 2020-02-25 | 2022-08-02 | 日本电气硝子株式会社 | 强化玻璃板及强化用玻璃板 |
| EP3904306B1 (en) | 2020-04-30 | 2023-06-07 | Schott Ag | Multi-fiber light guide, device with a multi-fiber light guide and method for producing the same |
| GB202012825D0 (en) | 2020-05-12 | 2020-09-30 | Corning Inc | Fusion formable and steam strengthenable glass compositions with platinum compatibility |
| WO2022145281A1 (ja) | 2020-12-28 | 2022-07-07 | 日本電気硝子株式会社 | 強化ガラス板 |
| WO2024086037A1 (en) * | 2022-10-21 | 2024-04-25 | Corning Incorporated | Zircon-compatible alkali glasses |
| JP2024094213A (ja) | 2022-12-27 | 2024-07-09 | 日本電気硝子株式会社 | ガラス管及び医薬品容器 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110294648A1 (en) * | 2010-05-27 | 2011-12-01 | Christy Lynn Chapman | Ion exchangeable glasses |
| TW201228970A (en) * | 2010-11-30 | 2012-07-16 | Corning Inc | Glass with surface and central regions under compression |
| TW201231431A (en) * | 2010-11-30 | 2012-08-01 | Corning Inc | Ion exchangeable glass with deep compressive layer and high damage threshold |
| CN102718401A (zh) * | 2006-10-10 | 2012-10-10 | 日本电气硝子株式会社 | 钢化玻璃基板 |
| TW201331148A (zh) * | 2011-11-16 | 2013-08-01 | Corning Inc | 具高裂隙初始閾值的離子可交換玻璃 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4055703A (en) * | 1975-08-15 | 1977-10-25 | Ppg Industries, Inc. | Ion exchange strengthened glass containing P2 O5 |
| US4042405A (en) * | 1976-03-18 | 1977-08-16 | American Optical Corporation | High strength ophthalmic lens |
| GB2335423A (en) * | 1998-03-20 | 1999-09-22 | Pilkington Plc | Chemically toughenable glass |
| JP5589252B2 (ja) * | 2006-10-10 | 2014-09-17 | 日本電気硝子株式会社 | 強化ガラス基板 |
| US8802581B2 (en) * | 2009-08-21 | 2014-08-12 | Corning Incorporated | Zircon compatible glasses for down draw |
| JP5645099B2 (ja) * | 2009-09-09 | 2014-12-24 | 日本電気硝子株式会社 | 強化ガラス |
| US8778820B2 (en) * | 2010-05-27 | 2014-07-15 | Corning Incorporated | Glasses having low softening temperatures and high toughness |
| US9540278B2 (en) * | 2010-05-27 | 2017-01-10 | Corning Incorporated | Ion exchangeable glasses |
| JP2012036074A (ja) * | 2010-07-12 | 2012-02-23 | Nippon Electric Glass Co Ltd | ガラス板 |
| US20120052271A1 (en) * | 2010-08-26 | 2012-03-01 | Sinue Gomez | Two-step method for strengthening glass |
| JP2012148909A (ja) * | 2011-01-18 | 2012-08-09 | Nippon Electric Glass Co Ltd | 強化ガラス及び強化ガラス板 |
| JP2013043795A (ja) * | 2011-08-23 | 2013-03-04 | Nippon Electric Glass Co Ltd | 強化ガラス及びその製造方法 |
| US10941071B2 (en) * | 2013-08-02 | 2021-03-09 | Corning Incorporated | Hybrid soda-lime silicate and aluminosilicate glass articles |
| WO2015031188A1 (en) * | 2013-08-27 | 2015-03-05 | Corning Incorporated | Damage resistant glass with high coefficient of thermal expansion |
| TWI689480B (zh) * | 2013-08-29 | 2020-04-01 | 美商康寧公司 | 含有硼及磷的可離子交換玻璃 |
| US10550029B2 (en) * | 2015-12-17 | 2020-02-04 | Corning Incorporated | Ion exchangeable glass with fast diffusion |
-
2014
- 2014-08-22 WO PCT/US2014/052262 patent/WO2015031188A1/en not_active Ceased
- 2014-08-22 JP JP2016538987A patent/JP6600309B2/ja not_active Expired - Fee Related
- 2014-08-22 CN CN202111287979.1A patent/CN113860730A/zh active Pending
- 2014-08-22 US US14/465,888 patent/US9969644B2/en active Active
- 2014-08-22 CN CN201480058858.1A patent/CN105683108A/zh active Pending
- 2014-08-22 KR KR1020167007766A patent/KR102290967B1/ko not_active Expired - Fee Related
- 2014-08-22 EP EP14761494.5A patent/EP3038983B1/en not_active Not-in-force
- 2014-08-26 TW TW107132600A patent/TWI660930B/zh not_active IP Right Cessation
- 2014-08-26 TW TW103129400A patent/TWI639572B/zh not_active IP Right Cessation
-
2018
- 2018-04-27 US US15/964,688 patent/US10919797B2/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102718401A (zh) * | 2006-10-10 | 2012-10-10 | 日本电气硝子株式会社 | 钢化玻璃基板 |
| US20110294648A1 (en) * | 2010-05-27 | 2011-12-01 | Christy Lynn Chapman | Ion exchangeable glasses |
| TW201228970A (en) * | 2010-11-30 | 2012-07-16 | Corning Inc | Glass with surface and central regions under compression |
| TW201231431A (en) * | 2010-11-30 | 2012-08-01 | Corning Inc | Ion exchangeable glass with deep compressive layer and high damage threshold |
| TW201331148A (zh) * | 2011-11-16 | 2013-08-01 | Corning Inc | 具高裂隙初始閾值的離子可交換玻璃 |
Also Published As
| Publication number | Publication date |
|---|---|
| US10919797B2 (en) | 2021-02-16 |
| TW201509860A (zh) | 2015-03-16 |
| EP3038983A1 (en) | 2016-07-06 |
| KR102290967B1 (ko) | 2021-08-19 |
| TW201906796A (zh) | 2019-02-16 |
| JP2016529199A (ja) | 2016-09-23 |
| CN105683108A (zh) | 2016-06-15 |
| US9969644B2 (en) | 2018-05-15 |
| US20150064472A1 (en) | 2015-03-05 |
| US20180244560A1 (en) | 2018-08-30 |
| KR20160046878A (ko) | 2016-04-29 |
| JP6600309B2 (ja) | 2019-10-30 |
| CN113860730A (zh) | 2021-12-31 |
| WO2015031188A1 (en) | 2015-03-05 |
| TWI639572B (zh) | 2018-11-01 |
| EP3038983B1 (en) | 2021-10-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Annulment or lapse of patent due to non-payment of fees |