JP6791757B2 - 三次元成形のためのイオン交換可能なガラス物品 - Google Patents
三次元成形のためのイオン交換可能なガラス物品 Download PDFInfo
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- JP6791757B2 JP6791757B2 JP2016554681A JP2016554681A JP6791757B2 JP 6791757 B2 JP6791757 B2 JP 6791757B2 JP 2016554681 A JP2016554681 A JP 2016554681A JP 2016554681 A JP2016554681 A JP 2016554681A JP 6791757 B2 JP6791757 B2 JP 6791757B2
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- 239000011521 glass Substances 0.000 title claims description 185
- 238000000465 moulding Methods 0.000 title description 4
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 31
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 23
- 238000007906 compression Methods 0.000 claims description 15
- 230000006835 compression Effects 0.000 claims description 15
- 238000005342 ion exchange Methods 0.000 claims description 15
- 229910052708 sodium Inorganic materials 0.000 claims description 11
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 7
- 229910052744 lithium Inorganic materials 0.000 claims description 7
- 229910052796 boron Inorganic materials 0.000 claims description 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 5
- 229910052700 potassium Inorganic materials 0.000 claims description 5
- 239000011591 potassium Substances 0.000 claims description 5
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 4
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 4
- 229910001408 cation oxide Inorganic materials 0.000 claims description 4
- 229910001409 divalent cation oxide Inorganic materials 0.000 claims description 4
- 239000010410 layer Substances 0.000 description 30
- 239000011734 sodium Substances 0.000 description 18
- 238000003286 fusion draw glass process Methods 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 238000005259 measurement Methods 0.000 description 7
- 238000007373 indentation Methods 0.000 description 6
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- 239000006060 molten glass Substances 0.000 description 6
- 229910052845 zircon Inorganic materials 0.000 description 6
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 230000015556 catabolic process Effects 0.000 description 4
- 150000001768 cations Chemical class 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 3
- 239000006121 base glass Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 150000002500 ions Chemical group 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 3
- 239000011819 refractory material Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 2
- 238000000137 annealing Methods 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000006059 cover glass Substances 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000007496 glass forming Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 238000003283 slot draw process Methods 0.000 description 2
- 238000007655 standard test method Methods 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 229910018068 Li 2 O Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 238000006124 Pilkington process Methods 0.000 description 1
- 238000007545 Vickers hardness test Methods 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000005354 aluminosilicate glass Substances 0.000 description 1
- CNLWCVNCHLKFHK-UHFFFAOYSA-N aluminum;lithium;dioxido(oxo)silane Chemical compound [Li+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O CNLWCVNCHLKFHK-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910001423 beryllium ion Inorganic materials 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000003426 chemical strengthening reaction Methods 0.000 description 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- YWEUIGNSBFLMFL-UHFFFAOYSA-N diphosphonate Chemical compound O=P(=O)OP(=O)=O YWEUIGNSBFLMFL-UHFFFAOYSA-N 0.000 description 1
- 238000003280 down draw process Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000002241 glass-ceramic Substances 0.000 description 1
- 238000011090 industrial biotechnology method and process Methods 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 1
- 229910052808 lithium carbonate Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- DLYUQMMRRRQYAE-UHFFFAOYSA-N phosphorus pentoxide Inorganic materials O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000013001 point bending Methods 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 229910052642 spodumene Inorganic materials 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/097—Glass compositions containing silica with 40% to 90% silica, by weight containing phosphorus, niobium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B17/00—Forming molten glass by flowing-out, pushing-out, extruding or drawing downwardly or laterally from forming slits or by overflowing over lips
- C03B17/06—Forming glass sheets
- C03B17/064—Forming glass sheets by the overflow downdraw fusion process; Isopipes therefor
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C21/00—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
- C03C21/001—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions
- C03C21/002—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions to perform ion-exchange between alkali ions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/083—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
- C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31—Surface property or characteristic of web, sheet or block
- Y10T428/315—Surface modified glass [e.g., tempered, strengthened, etc.]
Description
ガラス物品において、前記ガラス物品が少なくとも約50モル%のSiO2、少なくとも約8モル%のAl2O3、少なくとも約1モル%のP2O5、および少なくとも約12モル%のNa2Oを含み、前記ガラス物品がイオン交換可能であり、約825℃以下の軟化点、および30ppm/℃以下の高温熱膨張係数を有することを特徴とするガラス物品。
前記ガラス物品がイオン交換され、前記ガラス物品の表面から、前記物品中のある層深さまで延在する圧縮層を有し、前記圧縮層が少なくとも約700MPaの最大圧縮応力を有することを特徴とする実施形態1に記載のガラス物品。
前記最大圧縮応力が少なくとも約800MPaであることを特徴とする実施形態2に記載のガラス物品。
前記最大圧縮応力が少なくとも約900MPaであることを特徴とする実施形態3に記載のガラス物品。
前記層深さが少なくとも約20μmであることを特徴とする実施形態2〜4のいずれか一項に記載のガラス物品。
前記ガラス物品が少なくとも約10kgf(約98N)のビッカース亀裂発生閾値を有することを特徴とする実施形態2〜5のいずれか一項に記載のガラス物品。
前記ガラス物品が、約50モル%〜約65モル%のSiO2、約10モル%〜約20モル%のAl2O3、約1モル%〜約8モル%のP2O3、約2モル%〜約10モル%のB2O3、および約14モル%〜約20モル%のNa2Oを含むことを特徴とする実施形態1〜6のいずれか一項に記載のガラス物品。
前記ガラス物品が約1モル%〜約7モル%のZnOをさらに含むことを特徴とする実施形態7に記載のガラス物品。
Al2O3(モル%)>P2O5(モル%)+B2O3(モル%)、Al2O3(モル%)>B2O3(モル%)、およびNa2O(モル%)>Al2O3(モル%)であることを特徴とする実施形態7または実施形態8に記載のガラス物品。
0.3≦[(R2O(モル%)+RO(モル%)+B2O3(モル%)]/[(Al2O3(モル%)+P2O5(モル%)+SiO2(モル%)]≦0.45であり、ここでR2Oは一価カチオン酸化物であり、ROは二価カチオン酸化物であることを特徴とする実施形態7〜9のいずれか一項に記載のガラス物品。
前記ガラス物品がリチウム、カリウム、およびアルカリ土類金属の少なくとも1つを実質的に含まないことを特徴とする実施形態1〜10のいずれか一項に記載のガラス物品。
前記軟化点が約800℃未満であることを特徴とする実施形態1〜11のいずれか一項に記載のガラス物品。
前記軟化点が約775℃未満であることを特徴とする実施形態1〜12のいずれか一項に記載のガラス物品。
前記ガラス物品が非平面形状を有することを特徴とする実施形態1〜13のいずれか一項に記載のガラス物品。
前記ガラス物品がダウンドロー可能であることを特徴とする実施形態1〜14のいずれか一項に記載のガラス物品。
ガラス物品において、前記ガラス物品が少なくとも約50モル%のSiO2、少なくとも約8モル%のAl2O3、少なくとも約1モル%のP2O5、および少なくとも約12モル%のNa2Oを含み、前記ガラス物品がイオン交換され、前記ガラス物品の表面から、前記物品中のある層深さまで延在する圧縮層を有し、前記圧縮層が少なくとも約700MPaの最大圧縮応力を有し、前記ガラス物品が約825℃以下の軟化点および29ppm/℃以下の高温熱膨張係数を有することを特徴とするガラス物品。
前記最大圧縮応力が少なくとも約800MPaであることを特徴とする実施形態16に記載のガラス物品。
前記最大圧縮応力が少なくとも約900MPであることを特徴とする実施形態17に記載のガラス物品。
前記層深さが少なくとも約20μmであることを特徴とする実施形態16〜18のいずれか一項に記載のガラス物品。
前記ガラス物品が少なくとも約10kgf(約98N)のビッカース亀裂発生閾値を有することを特徴とする実施形態16〜19のいずれか一項に記載のガラス物品。
前記ガラス物品が、約50モル%〜約65モル%のSiO2、約10モル%〜約20モル%のAl2O3、約1モル%〜約8モル%のP2O3、約2モル%〜約10モル%のB2O3、および約14モル%〜約20モル%のNa2Oを含むことを特徴とする実施形態16〜20のいずれか一項に記載のガラス物品。
前記ガラス物品が約1モル%〜約7モル%のZnOをさらに含むことを特徴とする実施形態21に記載のガラス物品。
Al2O3(モル%)>P2O5(モル%)+B2O3(モル%)、Al2O3(モル%)>B2O3(モル%)、およびNa2O(モル%)>Al2O3(モル%)であることを特徴とする実施形態21または実施形態22に記載のガラス物品。
0.3≦[(R2O(モル%)+RO(モル%)+B2O3(モル%)]/[(Al2O3(モル%)+P2O5(モル%)+SiO2(モル%)]≦0.45であり、ここでR2Oは一価カチオン酸化物であり、ROは二価カチオン酸化物であることを特徴とする実施形態21〜23のいずれか一項に記載のガラス物品。
前記ガラス物品がリチウム、カリウム、およびアルカリ土類金属の少なくとも1つを実質的に含まないことを特徴とする実施形態16〜24のいずれか一項に記載のガラス物品。
前記軟化点が約800℃未満であることを特徴とする実施形態16〜25のいずれか一項に記載のガラス物品。
前記軟化点が約775℃未満であることを特徴とする実施形態16〜26のいずれか一項に記載のガラス物品。
前記ガラス物品が非平面形状を有することを特徴とする実施形態16〜27のいずれか一項に記載のガラス物品。
前記ガラス物品がダウンドロー可能であることを特徴とする実施形態16〜28のいずれか一項に記載のガラス物品。
Claims (12)
- ガラス物品において、前記ガラス物品が約50モル%〜約65モル%のSiO2、約8モル%〜約20モル%のAl2O3、約1モル%〜約8モル%のP2O5、約2モル%〜約10モル%のB 2 O 3 、および約12モル%〜約20モル%のNa2Oを含み、前記ガラス物品がイオン交換可能であり、30ppm/℃以下の高温熱膨張係数を有し、
前記ガラス物品が約1モル%〜約7モル%のZnOをさらに含む、
ことを特徴とするガラス物品。 - 前記ガラス物品がイオン交換され、前記ガラス物品の表面から、前記物品中のある層深さまで延在する圧縮層を有し、前記圧縮層が少なくとも約700MPaの最大圧縮応力を有することを特徴とする請求項1に記載のガラス物品。
- 前記層深さが少なくとも約20μmであることを特徴とする請求項1または2に記載のガラス物品。
- 前記ガラス物品が少なくとも約10kgf(約98N)のビッカース亀裂発生閾値を有することを特徴とする請求項2または3に記載のガラス物品。
- 前記ガラス物品が、約50モル%〜約65モル%のSiO2、約10モル%〜約20モル%のAl2O3、約1モル%〜約8モル%のP2O3 、および約14モル%〜約20モル%のNa2Oを含むことを特徴とする請求項1〜4のいずれか一項に記載のガラス物品。
- Al2O3(モル%)>P2O5(モル%)+B2O3(モル%)、Al2O3(モル%)>B2O3(モル%)、およびNa2O(モル%)>Al2O3(モル%)であることを特徴とする請求項1〜5のいずれか一項に記載のガラス物品。
- 0.3≦[(R2O(モル%)+RO(モル%)+B2O3(モル%)]/[(Al2O3(モル%)+P2O5(モル%)+SiO2(モル%)]≦0.45であり、ここでR2Oは一価カチオン酸化物であり、ROは二価カチオン酸化物であることを特徴とする請求項1〜6のいずれか一項に記載のガラス物品。
- 前記ガラス物品がリチウム、カリウム、およびアルカリ土類金属の少なくとも1つを含まないことを特徴とする請求項1〜7のいずれか一項に記載のガラス物品。
- 前記軟化点が約800℃未満であることを特徴とする請求項1〜8のいずれか一項に記載のガラス物品。
- 前記ガラス物品が非平面形状を有することを特徴とする請求項1〜9のいずれか一項に記載のガラス物品。
- 前記ガラス物品が約50モル%〜約60モル%のSiO2を含むことを特徴とする、請求項1〜10のいずれか一項に記載のガラス物品。
- Al2O3(モル%)>P2O5(モル%)+B2O3(モル%)であることを特徴とする請求項1〜5のいずれか一項に記載のガラス物品。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201461945430P | 2014-02-27 | 2014-02-27 | |
US61/945,430 | 2014-02-27 | ||
PCT/US2015/017017 WO2015130587A1 (en) | 2014-02-27 | 2015-02-23 | Ion exchangeable glass article for three-dimensional forming |
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KR20190122267A (ko) * | 2011-11-16 | 2019-10-29 | 코닝 인코포레이티드 | 높은 균열 개시 임계값을 갖는 이온 교환가능한 유리 |
JP6725416B2 (ja) * | 2013-11-19 | 2020-07-15 | コーニング インコーポレイテッド | 損傷抵抗性の高いイオン交換可能なガラス |
WO2015130587A1 (en) * | 2014-02-27 | 2015-09-03 | Corning Incorporated | Ion exchangeable glass article for three-dimensional forming |
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CN107140828B (zh) * | 2017-06-08 | 2019-12-06 | 东旭科技集团有限公司 | 一种玻璃组合物及其制备方法和应用 |
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CN107651837B (zh) * | 2017-09-27 | 2021-03-26 | 东旭光电科技股份有限公司 | 一种用于保护显示器件的玻璃组合物及其制备方法 |
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WO2020102147A2 (en) | 2018-11-16 | 2020-05-22 | Corning Incorporated | Laminated glass articles comprising a hydrogen-containing glass core layer and methods of forming the same |
TW202026257A (zh) | 2018-11-16 | 2020-07-16 | 美商康寧公司 | 用於透過蒸氣處理而強化之玻璃成分及方法 |
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US9975803B2 (en) | 2018-05-22 |
KR20160124898A (ko) | 2016-10-28 |
KR102347803B1 (ko) | 2022-01-06 |
WO2015130587A1 (en) | 2015-09-03 |
US10737971B2 (en) | 2020-08-11 |
EP3110769B1 (en) | 2023-04-05 |
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