TWI641321B - Processed konjac food or drink having blood glucose increase suppressing effect - Google Patents

Processed konjac food or drink having blood glucose increase suppressing effect Download PDF

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TWI641321B
TWI641321B TW103110447A TW103110447A TWI641321B TW I641321 B TWI641321 B TW I641321B TW 103110447 A TW103110447 A TW 103110447A TW 103110447 A TW103110447 A TW 103110447A TW I641321 B TWI641321 B TW I641321B
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德田雅明
村尾孝兒
菱谷哲嗣
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國立大學法人香川大學
好喜歡食品工業股份有限公司
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Abstract

本發明提供一種具有抑制血糖值上升的效果的蒟蒻加工食品。 The present invention provides a Konjac processed food having the effect of suppressing the rise of blood sugar level.

本發明的蒟蒻的加工食品,含有pH在2.5~7.4的範圍的蒟蒻與稀有糖作為有效成分,可攝取用於抑制血糖值上升而攝取之稀有糖一日用量0.3~50g/日、具有抑制血糖值上升的效果,整形為方塊狀、絲狀、丸狀、粒狀或板狀。藉一次攝取,可使抑制血糖值上升的效果持續一天以上。例如,藉由製成加入了稀有糖的蒟蒻的加工食品,無飲食時的障礙,符合消費者的嗜好,因此容易長期攝取,可長期維持抑制血糖值上升的效果。 The processed food of konjac of the present invention contains konjac and rare sugars with a pH in the range of 2.5 to 7.4 as effective ingredients, and can ingest the daily consumption of rare sugars used to inhibit the rise of blood sugar level from 0.3 to 50 g / day. The effect of increasing the value is shaped as square, filament, pellet, grain or plate. With one ingestion, the effect of suppressing the rise in blood sugar level can last more than one day. For example, by making processed food of Konjac with rare sugar added, there are no barriers to eating and drinking, which is in line with consumer preferences, so it is easy to take for a long time and can maintain the effect of suppressing the rise of blood sugar for a long time.

Description

具有抑制血糖值上升的效果的蒟蒻加工飲食品 Konjac processed foods and beverages with the effect of suppressing the rise of blood sugar level

本發明係關於具有抑制血糖值上升的效果的蒟蒻加工飲食品,藉由組合具有特徵性之生理活性物質的蒟蒻及稀有糖,而提供可發揮充實之機能性的新穎機能性食品,以促進健康。 The present invention relates to a Konjac processed food and drink product having an effect of suppressing the rise of blood sugar level, and by combining Konjac and rare sugar with a characteristic physiologically active substance, a novel functional food capable of exerting full functionality is provided to promote health .

目前在日本,糖尿病患者或被強烈懷疑患有糖尿病的人、與所謂肥胖的人數多,此等情況稱為「代謝症候群」,其中,特別容易引發腦血管障礙,被視為危險因子。尤其是未出現檢查值異常或症狀的高血糖症、高脂血症和高尿酸血症特別危險,急需其因應對策。以預防此等疾病為目的,以特定保健用食品為首的各種健康食品的需求高漲,食品的生理機能重新受到關注。尤其是,已知食物纖維具有以整腸作用、抑制食後血糖上升作用為中心的生理作用,經常被利用作為提高食品機能的素材。另外,稀有糖等係作為具有生理活性、並且即使添加在食品中亦不妨礙食品的味道、食感、風味等之機能的物質,而受到關注,稀有糖中,特別是關於D-阿洛酮糖,已有報告指出其具有低卡路里、改善血糖值、改善動脈硬化的效果等,因此,被期待作為生活習慣病預防素材和生體機能改善劑。然而,有關將此等併用的情況下的生體機能的報告為數稀有。 At present, in Japan, there are many people with diabetes or people who are strongly suspected of having diabetes, and so-called obesity. These conditions are called "metabolic syndrome". Among them, cerebrovascular disorders are particularly prone to be considered as risk factors. In particular, hyperglycemia, hyperlipidemia, and hyperuricemia without abnormal examination values or symptoms are particularly dangerous, and countermeasures are urgently needed. For the purpose of preventing these diseases, the demand for various health foods, including foods for specific health uses, is on the rise, and the physiological functions of foods are regaining attention. In particular, it is known that dietary fiber has a physiological effect centered on the effect of bowel adjustment and the effect of suppressing the rise of blood glucose after eating, and is often used as a material for improving food functions. In addition, rare sugars have attracted attention as substances that have physiological activity and do not interfere with the function of food taste, texture, flavor, etc. even when added to foods. Among rare sugars, especially D-aloxone Sugar has been reported to have low-calorie, blood sugar-improving, and arteriosclerosis-improving effects. Therefore, it is expected to be used as a preventive material for lifestyle-related diseases and as an agent for improving body functions. However, reports on biological functions in cases where these are used in combination are rare.

作為食物纖維所造成之生體機能的改善,例如提案有: 一種菊芋蒟蒻,係以糖尿病和生活習慣病的改善及預防效果為前提,利用將被稱為天然胰島素的生菊芋的菊粉添加到富含葡糖甘露聚糖食物纖維的蒟蒻精粉中而得到的相乘效果,而可期待抑制血糖值上升的作用、並具有調理通用性(專利文獻1);一種營養輔助食品,其特徵在於,在乾燥蒟蒻中配合有椰子水的濃縮成分及/或椰子粉(專利文獻2);一種蒟蒻凍膠的製造方法,係使葡糖甘露聚糖溶解在水中,將得到的溶解液填充到容器中,使裝入容器中的溶解液凝膠化者,其特徵在於,使豆腐渣與葡糖甘露聚糖一起溶解在水中(專利文獻3);一種蒟蒻製造方法,其特徵在於,將蒟蒻葡糖甘露聚糖溶解在水中使其溶膠化,在該溶膠化後的水溶蒟蒻葡糖甘露聚糖中添加增黏多糖類及其他的添加物進行攪拌和混合,將混合有該增黏多糖類及添加物的溶膠化蒟蒻葡糖甘露聚糖冷卻、凝膠化,製造在食用時於體內溶膠化的蒟蒻產品(專利文獻4)。 As the improvement of biological functions caused by dietary fiber, for example, proposals include: A Jerusalem artichoke konjac, which is based on the premise of the improvement and prevention of diabetes and lifestyle habits. It is obtained by adding inulin of raw artichoke called natural insulin to konjac fine powder rich in glucose mannan dietary fiber. It can be expected to have the synergistic effect of suppressing the increase in blood sugar level and has the versatility of conditioning (Patent Document 1); a nutritional supplement food characterized in that a concentrated component of coconut water and / or coconut is blended with dried Konjac Powder (Patent Document 2); a method for producing Konjac jelly, in which glucomannan is dissolved in water, the obtained solution is filled into a container, and the solution contained in the container is gelled, It is characterized by dissolving tofu dregs together with glucomannan in water (Patent Document 3); a manufacturing method of Konjac, characterized by dissolving konjac glucose mannan in water to make it sol-soluble After adding water-soluble konjac glucomannan mannan to the tackifying polysaccharides and other additives for stirring and mixing, the solized konjac glucomannan mannans mixed with the viscosifying polysaccharides and additives are cooled and gelled , Manufacturing Konjac products that are sol-gelated in the body when eaten (Patent Document 4).

另一方面,稀有糖係近年來受到關注的亦可使用作為甜味劑的具有生理作用的一種糖,已有報告指出其具有低卡路里、改善血糖值、改善動脈硬化的效果等,因此,被期待作為生活習慣病預防素材和身體機能改善劑。 On the other hand, rare sugars have attracted attention in recent years and can also be used as a sweetener with a physiological role. Sugar has been reported to have low calories, improve blood sugar levels, and improve arteriosclerosis. It is expected to be used as a preventive material for lifestyle-related diseases and as an agent for improving body functions.

例如,已提案有:一種碳水化合物及/或糖類的組合物,其含有D-阿洛酮糖及/或其衍生物,相較於單獨攝取碳水化合物及/或糖類,其攝取後的血糖值的急劇上升受到抑制(專利文獻5、6);作為具有抑制攝取碳水化合物及/或糖類時血糖急劇上升的效果的組合物,含有D-阿洛糖,抑制攝取碳水化合物及/或糖類時血糖值急劇上升的組合物(專利文獻7);在含有食物纖維、與稀有糖作為有效成分的肝功能、血糖值、血清脂質值、體重增加及內臟脂肪蓄積的功能改善組成物中,含有組 成物整體的1重量%以上的食物纖維,含有組成物整體的2重量%以上的稀有糖及/或其衍生物,使用D-阿洛酮糖及/或其衍生物作為稀有糖,使用水溶性食物纖維難消化性糊精作為食物纖維(專利文獻8)。 For example, there has been proposed a composition of carbohydrates and / or carbohydrates containing D-psicose and / or derivatives thereof. Compared with carbohydrates and / or carbohydrates taken alone, the blood glucose level after ingestion Is inhibited from rapid rise (Patent Documents 5 and 6); as a composition having the effect of suppressing a rapid rise in blood sugar when carbohydrates and / or sugars are ingested, it contains D-allose to suppress blood sugar when carbohydrates and / or sugars are ingested A composition with a sharp increase in value (Patent Document 7); in a functional improvement composition containing dietary fiber, and rare sugar as an active ingredient, liver function, blood sugar level, serum lipid value, weight gain, and visceral fat accumulation, contains a group 1% by weight or more of dietary fiber in the whole product, containing 2% or more by weight of the whole composition of rare sugar and / or its derivatives, using D-aloxulose and / or its derivatives as the rare sugar, using water-soluble Sexual dietary fiber is indigestible dextrin as dietary fiber (Patent Document 8).

[先前技術文獻] [Prior Technical Literature] [專利文獻] [Patent Literature]

專利文獻1:日本專利特開2011-130776號公報 Patent Document 1: Japanese Patent Laid-Open No. 2011-130776

專利文獻2:日本專利特開2008-237058號公報 Patent Document 2: Japanese Patent Laid-Open No. 2008-237058

專利文獻3:日本專利特開2002-204662號公報 Patent Document 3: Japanese Patent Laid-Open No. 2002-204662

專利文獻4:日本專利特開平08-131096號公報 Patent Document 4: Japanese Patent Laid-Open No. 08-131096

專利文獻5:日本專利特開2005-213227號公報 Patent Document 5: Japanese Patent Laid-Open No. 2005-213227

專利文獻6:WO2006/101118 Patent Literature 6: WO2006 / 101118

專利文獻7:日本專利第5116072號公報 Patent Document 7: Japanese Patent No. 5116072

專利文獻8:日本專利特開2010-18528號公報 Patent Document 8: Japanese Patent Laid-Open No. 2010-18528

專利文獻9:日本專利特願2013-17033號 Patent Document 9: Japanese Patent Application No. 2013-17033

專利文獻10:WO2008/142860號公報 Patent Literature 10: WO2008 / 142860

專利文獻11:日本專利第3829211號公報 Patent Document 11: Japanese Patent No. 3829211

專利文獻12:日本專利第3840511號公報 Patent Document 12: Japanese Patent No. 3840511

專利文獻13:日本專利第3905830號公報 Patent Document 13: Japanese Patent No. 3905830

專利文獻14:日本專利第4822541號公報 Patent Document 14: Japanese Patent No. 4822541

專利文獻15:日本專利特開2008-289408號公報 Patent Literature 15: Japanese Patent Laid-Open No. 2008-289408

日本的糖尿病患者目前據說已達800萬人,包括跨學科 領域在內據說有2200萬人。習知中,蒟蒻甘露聚糖(蒟蒻)被期待為可使血糖值降低的食品。例如,在專利文獻2中,由每日餵食混合有該營養輔助食品的飼料的老鼠,確認了腦內的乙醯膽鹼顯著增加,由此,獲得由於該營養輔助食品的低卡路里而確保了營養均衡的結論,具有使血糖值降低,表現出降血壓作用,而且提供飽腹感的效果。在專利文獻4中,使用該蒟蒻產品2個月後的事例,根據一人的資料,得到了以下結論:形成大量的具有黏性的水溶性食物纖維,於身體中作用,能夠發揮抑制血中膽固醇或血糖值的上升等的機能。然而,尚未有臨床試驗數據證明蒟蒻屬於可使血糖值降低的食品。 Diabetes patients in Japan are now said to have reached 8 million people, including interdisciplinary In the field, there are said to be 22 million people. According to the conventional knowledge, Konjac mannan (Konjac) is expected to be a food that can lower the blood sugar level. For example, in Patent Document 2, a rat fed daily with a feed supplemented with the nutritional supplementary food confirmed that the acetylcholine in the brain increased significantly, thereby obtaining the low calorie content of the nutritional supplementary food. The conclusion of balanced nutrition has the effect of lowering blood sugar level, showing blood pressure lowering effect, and providing satiety. In Patent Document 4, the case after using this Konjac product for 2 months, according to one person's data, the following conclusion was obtained: a large amount of viscous water-soluble dietary fiber is formed, which acts in the body and can exert inhibition of blood cholesterol Or functions such as an increase in blood sugar level. However, there is no clinical trial data to prove that Konjac is a food that can lower blood sugar levels.

另外,在將蒟蒻甘露聚糖與其他的生理活性成分類一起食用時,係將兩者的粉末混合而形成為粉末狀態或者將兩者混合利用蒟蒻甘露聚糖的凝膠化作用形成為成形體。如此,為了製成可作為此種生體機能改善食品而食用的形態,大多需要繁雜的操作。 In addition, when konjac mannan is eaten together with other physiological activities, the powder of the two is mixed to form a powder state or the two are mixed to form a shaped body by the gelation of konjac mannan . In this way, in order to produce a form that can be eaten as such a bio-function-improving food, many complicated operations are required.

另外,為了製成任何人都能容易地、喜好地食用的形態的食品,提案有製成凍膠狀、或添加在糕點類中等,然而,作為能夠簡便地長期連續食用的食品,還不能令人滿意。 In addition, in order to make foods that can be easily and easily consumed by anyone, it is proposed to be made into jelly or added to confectionery, etc. However, as a food that can be easily and continuously consumed for a long time, it cannot be ordered People are satisfied.

另一方面,已知稀有糖具有使血糖值降低的作用、與食物纖維類一起攝取,但作為食物纖維類,具體而言僅已知有難消化性糊精類,目前對於用於以最終商品的形態容易攝取的改善,尚未有任何提案。 On the other hand, it is known that rare sugars have the effect of lowering the blood sugar level and are taken together with dietary fiber, but as dietary fiber, specifically only indigestible dextrins are known. There is no proposal to improve the easy intake form.

另外,對於屬於稀有糖之一種的D-阿洛酮糖純品,係根據抑制血糖值上升的效果,而申請為特定保健用食品中。零卡路里的人工甜味劑通常於味質方向存在問題,但D-阿洛酮糖係味質良好、零卡路里、且具有功能性的天然類甜味劑,因此,若能夠簡便地利用作為適合糖尿病患者的甜味料,對他們來說將是極大喜訊,也有助於解決社會問題。 In addition, for pure D-psicose which is one of rare sugars, it is applied for food for specific health care based on the effect of suppressing the rise of blood sugar level. Zero-calorie artificial sweeteners usually have problems in the direction of taste, but D-aloxone sugar-based natural sweeteners with good taste, zero calories, and functionality are therefore suitable if they can be easily used. The sweet taste of diabetics will be great news for them and will also help solve social problems.

本發明者等人為了發現藉由在屬於具有降低血糖值作用效果的成分的食物纖維類中特別地組合蒟蒻(蒟蒻甘露聚糖)與稀有糖,找到能夠長期連續地持續作用的食品的形態,反復進行了研究開發,結果發現,將脫鹼蒟蒻(中和蒟蒻、pH在2.5~7.4的範圍內的蒟蒻)與稀有糖的組合有望。在健康人體中,在攝取澱粉或蔗糖後,在動脈中約15分鐘後其血糖值達到最大,在靜脈中約30分鐘後其血糖值達到最大,接著逐漸恢復到平常值。本發明的目的在於提供一種蒟蒻加工飲食品,係僅藉由使通常食用的蒟蒻中含有稀有糖並進食,即可抑制血漿葡萄糖濃度的異常上升。本發明的目的在於提供一種具有抑制血糖值上升的效果的蒟蒻加工飲食品,其特徵在於,提供將脫鹼蒟蒻與稀有糖組合而得到的各種形態的蒟蒻加工飲食品。 The inventors of the present invention have found a form of food that can continue to function for a long period of time by combining konjac (konjac mannan) and rare sugars particularly in dietary fiber belonging to a component having an effect of reducing blood sugar level. After repeated research and development, it was found that the combination of desalinated konjac (neutralized konjac, konjac with a pH in the range of 2.5 to 7.4) and rare sugar is promising. In healthy people, after ingesting starch or sucrose, the blood glucose value reaches its maximum after about 15 minutes in the arteries, and reaches its maximum value after about 30 minutes in the vein, and then gradually returns to the normal value. An object of the present invention is to provide a Konjac processed food or drink, which can suppress the abnormal increase in plasma glucose concentration by simply eating the Konjac containing rare sugar and eating. An object of the present invention is to provide a konjac processed food and drink having an effect of suppressing an increase in blood sugar level, characterized in that it provides various forms of konjac processed food and drink obtained by combining alkalescent konjac and rare sugar.

更具體而言,本發明的目的在於提供一種沙拉用蒟蒻、醬漬鮪魚蓋飯所使用的似鮪魚片蒟蒻、似魚子醬蒟蒻等的加入了稀有糖的蒟蒻成形品。 More specifically, an object of the present invention is to provide a konjac shaped product to which rare sugar is added, such as konjac for salad, konjac flakes konjac, caviar konjac, and the like used in konjac salad, pickled tuna rice.

本發明的要點在於以下的(1)至(11)的具有抑制血糖值上升的效果的蒟蒻加工飲食品。 The gist of the present invention lies in the Konjac processed foods and beverages of the following (1) to (11) which have the effect of suppressing the increase in blood sugar level.

(1)一種具有抑制血糖值上升的效果的蒟蒻加工飲食品,係整形為方塊狀、絲狀、丸狀、粒狀、板狀的蒟蒻加工食品,其含有pH在2.5~7.4的範圍的蒟蒻及稀有糖作為有效成分。 (1) A konjac processed food and drink product having an effect of suppressing an increase in blood sugar level, is a konjac processed food shaped into a square, a filament, a pellet, a granule, or a plate, and contains a pH in the range of 2.5 to 7.4 Konjac and rare sugar as active ingredients.

(2)如上述(1)之具有抑制血糖值上升的效果的蒟蒻加工飲食品,其中,經整形之蒟蒻,係藉由混合至少可中和該蒟蒻中含有的鹼份的量的酸性素材並進行加熱處理而製造。 (2) The Konjac processed foods and beverages having the effect of suppressing the increase in blood glucose level as described in (1) above, wherein the shaped Konjac is mixed with an acidic material that can neutralize at least the amount of alkali contained in the Konjac by mixing Manufactured by heat treatment.

(3)如上述(2)之具有抑制血糖值上升的效果的蒟蒻加工飲食品,其 中,酸性素材係包含選自調味料、增稠物質、果汁、將果實及/或蔬菜破碎並過濾而得到的蔬果泥(puree)、果實糊、蔬菜糊中的1種以上。 (3) The Konjac processed food and drink product having the effect of suppressing the rise in blood glucose level as described in (2) above, Among them, the acidic material system contains one or more kinds selected from the group consisting of seasonings, thickening substances, fruit juices, puree, fruit paste, and vegetable paste obtained by crushing and filtering fruits and / or vegetables.

(4)如上述(2)或(3)之具有抑制血糖值上升的效果的蒟蒻加工飲食品,其中,酸性素材係包含與鹼中和的選自葡糖酸、檸檬酸及乳酸中的1種以上的酸味料。 (4) Konjac processed foods and beverages having the effect of suppressing the increase in blood sugar level as described in (2) or (3) above, wherein the acidic material contains 1 selected from gluconic acid, citric acid and lactic acid neutralized with alkali More than one kind of sour taste.

(5)如上述(1)~(4)項中任一項之具有抑制血糖值上升的效果的蒟蒻加工飲食品,其中,含有pH在2.5~7.4的範圍的蒟蒻及稀有糖作為有效成分的蒟蒻,係將整形為一定形狀之添加有稀有糖的著色蒟蒻依單色或2種以上不同顏色組合成的沙拉用蒟蒻、使添加有稀有糖之鮪魚醬漬液浸滲至內部的似鮪魚切片蒟蒻、或似魚子醬之添加有稀有糖的蒟蒻。 (5) Konjac processed foods and beverages having the effect of suppressing the increase in blood glucose level as described in any one of (1) to (4) above, which contain Konjac and rare sugars having a pH in the range of 2.5 to 7.4 as active ingredients Konjac is a kind of colored tuna that is shaped into a certain shape and added with rare sugar. It is a monochromatic salad or a combination of two or more different colors. It is a tuna-like fish that is made of konjac soaked with rare sugar. Slice konjac or konjac with rare sugar added to it like caviar.

(6)如上述(1)~(5)項中任一項之具有抑制血糖值上升的效果的蒟蒻加工飲食品,其中,稀有糖為D-阿洛酮糖及/或D-阿洛糖。 (6) Konjac processed foods and beverages having the effect of suppressing the increase in blood sugar level according to any one of the above items (1) to (5), wherein the rare sugar is D-alloxanose and / or D-allose .

(7)如上述(6)之具有抑制血糖值上升的效果的蒟蒻加工飲食品,其中,D-阿洛酮糖為D-阿洛酮糖及/或其衍生物,D-阿洛酮糖的衍生物為選自D-阿洛酮糖的醛基變成醇基而得到的糖醇、D-阿洛酮糖的醇基被氧化而得到的糖醛酸、與D-阿洛酮糖的醇基被NH2基取代而得到的胺基糖中的D-阿洛酮糖衍生物。 (7) Konjac processed foods and beverages having the effect of suppressing the increase in blood glucose level as described in (6) above, wherein D-psicose is D-psicose and / or its derivatives, D-psicose The derivatives are selected from the group consisting of sugar alcohols obtained by changing the aldehyde group of D-psicose to alcohol groups, uronic acid obtained by oxidizing the alcohol group of D-psicose, and those with D-psicose D-psicose derivatives in amino sugars obtained by substitution of alcohol groups with NH 2 groups.

(8)如上述(6)或(7)之具有抑制血糖值上升的效果的蒟蒻加工飲食品,其中,D-阿洛糖為D-阿洛糖及/或其衍生物,D-阿洛糖的衍生物為選自D-阿洛糖的醛基變成醇基而得到的糖醇、D-阿洛糖的醇基被氧化而得到的糖醛酸、與D-阿洛糖的醇基被NH2基取代而得到的胺基糖中的D-阿洛糖衍生物。 (8) Konjac processed foods and beverages having the effect of suppressing the increase in blood glucose level as described in (6) or (7) above, wherein D-allose is D-allose and / or its derivatives, D-allox The sugar derivative is a sugar alcohol selected from an aldehyde group of D-allose to an alcohol group, a uronic acid obtained by oxidizing the alcohol group of D-allose, and an alcohol group with D-allose D-allose derivative in amino sugars substituted by NH 2 groups.

(9)如上述(1)~(8)項中任一項之具有抑制血糖值上升的效果的蒟蒻 加工飲食品,其中,蒟蒻加工飲食品係依稀有糖的一日用量為0.3~50g/日而與蒟蒻一起攝取,以抑制血糖值上升。 (9) Konjac which has the effect of suppressing the rise of blood glucose as described in any one of the above items (1) to (8) Processed foods and drinks, among them, the daily consumption of konjac processed foods is 0.3-50g / day, and it is taken together with konjac to suppress the rise of blood sugar level.

(10)如上述(1)~(9)項中任一項之具有抑制血糖值上升的效果的蒟蒻加工飲食品,其中,係用於以相對於飲食品整體含有蒟蒻40~95重量%及稀有糖0.1~10.0重量%的形態,與蒟蒻一起攝取稀有糖的一日用量者。 (10) The konjac processed food and drink product having the effect of suppressing the increase in blood glucose level according to any one of the above items (1) to (9), which is used to contain konjac 40 to 95% by weight relative to the entire food and beverage product and Those in the form of 0.1 to 10.0% by weight of rare sugar, who take a daily dose of rare sugar together with Konjac.

(11)如上述(1)~(10)項中任一項之具有抑制血糖值上升的效果的蒟蒻加工飲食品,其中,係用於依一日一次以上與蒟蒻一起攝取稀有糖的一日用量者。 (11) Konjac processed foods and beverages having the effect of inhibiting the rise in blood sugar level as described in any one of (1) to (10) above, which are used for daily intake of rare sugar together with Konjac more than once a day Dosage.

另外,本發明之要旨在於一種容器裝飲食品,係收納有以下(12)及(13)之具有抑制血糖值上升的效果的蒟蒻加工飲食品。 In addition, the gist of the present invention is directed to a food and beverage packaged in a container, which contains the processed konjac processed food and beverage having the following effects (12) and (13) having an effect of suppressing an increase in blood sugar level.

(12)一種容器裝飲食品,係收納有上述(1)~(11)項中任一項之具有抑制血糖值上升的效果的蒟蒻加工飲食品 (12) A food and beverage packaged in a container, containing a processed Kombucha food and beverage having the effect of suppressing an increase in blood glucose level according to any one of the above items (1) to (11)

(13)如上述(12)之容器裝飲食品,其係在一容器中,與蒟蒻一起含有屬於一日所需攝取量的0.3~50g的稀有糖。 (13) The food and beverage in containers as described in (12) above, which contains 0.3 to 50 g of rare sugar, which is a daily intake required, together with Konjac.

本發明能夠得到如下的效果。本發明的蒟蒻加工飲食品,係藉由將中和後的蒟蒻與稀有糖組合,發揮了由單獨的成分所無法預料的抑制血漿葡萄糖濃度異常上升的作用,能夠重新提供對糖尿病患者的預防與治療有用的生體機能改善用飲食品。本發明的將中和後的蒟蒻與稀有糖組合而得到的蒟蒻加工飲食品係能夠以各種形態提供。 The present invention can obtain the following effects. The processed konjac food and beverage of the present invention, by combining the neutralized konjac and rare sugar, exerts an unpredictable effect of suppressing abnormal rise in plasma glucose concentration by a single component, and can provide prevention and prevention for diabetes patients again The biological functions useful for treatment can be improved with food and drink. The konjac processed food and beverage line obtained by combining the neutralized konjac and rare sugar can be provided in various forms.

另外,本發明的將中和後的蒟蒻與稀有糖組合而得到的蒟蒻加工飲食品,由於容易對調味、風味等賦予變化,因此,不會使飲食者感到厭煩。一般而言,健康食品類為了發揮其作用效果需要長期連續攝 取,而本發明的將脫鹼蒟蒻與稀有糖組合而得到的蒟蒻加工飲食品即適合於此種長期攝取。 In addition, the processed konjac processed foods and beverages obtained by combining the neutralized konjac and rare sugars of the present invention are easy to impart changes in flavor, flavor, etc., so that they do not bother the diners. Generally speaking, in order to exert their effects, health foods need to be continuously taken for a long time The konjac processed foods and beverages obtained by combining alkalescent konjac and rare sugars of the present invention are suitable for such long-term intake.

更詳細而言,本發明的蒟蒻加工飲食品能夠得到如下的效果。(1)將蒟蒻與稀有糖組合而得到的蒟蒻加工飲食品,能夠得到抑制血糖值上升的效果。(2)抑制血糖值上升的效果,係在攝取後持續約一天的時間。(3)將蒟蒻與稀有糖組合而得到的蒟蒻加工飲食品,能夠較自由地變更其風味、食感等,因此,能夠應對各種喜好。(4)能夠適合於各飲食者的喜好,因此,能夠不使飲食者厭煩地進行長期持續的攝取。(5)對於糖尿病患者等的以血糖值上升為原因的疾病的預防或治療是有用的。 In more detail, the Konjac processed food and drink of the present invention can obtain the following effects. (1) Konjac processed foods and beverages obtained by combining Konjac and rare sugar can obtain the effect of suppressing the increase in blood sugar level. (2) The effect of suppressing the rise of blood sugar level lasts for about one day after ingestion. (3) Konjac processed foods and beverages obtained by combining Konjac with rare sugar can change its flavor, texture, etc. relatively freely, so it can respond to various preferences. (4) Since it can be adapted to the preferences of each dieter, it is possible to continue long-term ingestion without annoying the dieter. (5) It is useful for the prevention or treatment of diseases such as diabetic patients whose blood sugar level rises.

另外,作為本發明的蒟蒻加工食品,可舉例如沙拉用蒟蒻、醬漬鮪魚蓋飯所使用的似鮪魚切片蒟蒻、似魚子醬蒟蒻等之將加入了稀有糖的蒟蒻成形為板狀或粒狀的例子。此等蒟蒻成形品能夠賦予與各自用途相對應的食味、食感,並能夠發揮上述的生理效果。 In addition, examples of the processed konjac food of the present invention include, for example, konjac for salad, konjac slices used in pickled tuna rice bowl, konjac like caviar, and konjac like caviar. Granular example. These konjac shaped products can impart the taste and texture corresponding to their respective uses, and can exert the aforementioned physiological effects.

圖1表示實際驗證含有微細粒狀蒟蒻與稀有糖的蔬果冰沙(smoothie)式飲食品所造成的抑制血糖值上升效果的試驗結果。 Fig. 1 shows the test results of actually verifying the effect of suppressing the increase in blood sugar level caused by a smoothie-type food and beverage product containing fine granular Konjac and rare sugar.

圖2係將圖1記載的試驗結果校正為0分鐘值進行表示。 FIG. 2 shows the test result described in FIG. 1 corrected to a value of 0 minutes.

圖3表示收納有色彩不同的沙拉用蒟蒻的容器的外觀。 Fig. 3 shows the appearance of a container in which konjac for salad of different colors is stored.

圖4表示收納有醬漬鮪魚蓋飯用蒟蒻的容器的外觀。 Fig. 4 shows the appearance of a container in which konjac for pickled tuna rice bowl is stored.

圖5表示醬漬鮪魚蓋飯用蒟蒻的剖面形狀。 FIG. 5 shows the cross-sectional shape of Konjac for pickled tuna rice bowl.

圖6表示收納有似魚子醬蒟蒻顆粒的容器的外觀。 Fig. 6 shows the appearance of a container that contains caviar-like Konjac particles.

本發明係關於一種含有pH在2.5~7.4的範圍的蒟蒻及稀有糖作為有效成分,為了抑制血糖值上升而依稀有糖的一日用量為0.3~50g/日進行攝取的具有抑制血糖值上升的效果的蒟蒻加工飲食品;可發揮較單獨之蒟蒻或稀有糖更優越的生理活性。優越之生理活性,係根據藉由以含有細微粒狀蒟蒻與稀有糖為特徵之具有抑制血糖值上升的效果的蔬果冰沙式飲食品所證實(專利文獻9),發現在蔬果冰沙式飲食品以外之蒟蒻加工飲食品中亦可發揮較單獨之蒟蒻或稀有糖更優越的生理活性,遂完成本發明。本發明之蒟蒻加工飲食品,係關於可預防糖尿病等生活習慣病的優良飲食品。本發明之蒟蒻加工飲食品不對飲食造成任何妨礙,可進行各種調味,故容易長期持續攝取蒟蒻與稀有糖,對生活習慣病之預防、治療有用。 The present invention relates to an extract containing Konjac and rare sugar with a pH in the range of 2.5 to 7.4 as an active ingredient. In order to suppress the increase in blood sugar level, the daily dosage of the rare sugar is 0.3 to 50 g / day. Konjac processed foods and beverages with effects; it can exert superior physiological activity than Konjac or rare sugar alone. The superior physiological activity is confirmed by the fruit and vegetable smoothie-type food and beverage that has the effect of suppressing the increase in blood sugar level, characterized by containing fine particles of Konjac and rare sugar (Patent Document 9). The processed foods and drinks of Konjac other than products can also exert more superior physiological activity than Konjac or rare sugar alone, thus completing the present invention. The konjac processed food and drink of the present invention relates to an excellent food and drink that can prevent lifestyle diseases such as diabetes. The processed konjac food and beverage of the present invention does not cause any hindrance to the diet and can be subjected to various flavorings, so it is easy to continue to ingest konjac and rare sugar for a long time, which is useful for the prevention and treatment of lifestyle habits.

另外,作為本發明的加工食品,能夠將含有稀有糖的蒟蒻成形為板狀或粒狀來使用。可舉例如蔬菜沙拉中添加的板狀或粒狀的蒟蒻成形品、醬漬鮪魚蓋飯等所使用的似鮪魚切片的蒟蒻成形品、或似魚子醬粒狀的蒟蒻成形品等。 In addition, as the processed food of the present invention, konjac containing rare sugar can be formed into a plate shape or a granular shape and used. For example, a plate-shaped or granular konjac shaped product to be added to a vegetable salad, a konjac shaped product like sliced tuna used in pickled tuna rice bowl, etc., or a konjac shaped product like caviar granules, etc.

以下,在對本發明進行說明時,葡糖甘露聚糖、蒟蒻甘露聚糖及蒟蒻係作為同義詞而使用。本發明係藉由使用這些用語所包括的物質,可得到既定的效果。 Hereinafter, in describing the present invention, glucomannan, konjac mannan, and konjac are used as synonyms. The present invention can obtain predetermined effects by using substances included in these terms.

作為本發明對象的蒟蒻加工食品,係含有pH在2.5~7.4的範圍的蒟蒻及稀有糖作為有效成分,為蔬果冰沙式飲食品以外之、經整形的蒟蒻加工食品。為方塊狀、絲狀、丸狀、粒狀、板狀之無著色或有著色者。可舉例如將整形為一定形狀之添加有稀有糖的著色蒟蒻依單色或2種以上不同顏色組合包裝成的沙拉用蒟蒻、浸漬於醬漬鮪魚蓋飯所使用之添加有鮪魚醬漬液的使稀有糖浸滲至內部的pH在 2.5~7.4的範圍的似鮪魚切片蒟蒻、或似魚子醬之pH在2.5~7.4的範圍的添加有稀有糖的蒟蒻。 The processed Konjac food, which is the object of the present invention, contains Konjac and rare sugars having a pH in the range of 2.5 to 7.4 as active ingredients, and is a shaped Konjac processed food other than vegetable and fruit smoothie foods and beverages. It is square, filiform, pill-shaped, granular, or plate-shaped without coloring or with coloring. For example, it can be shaped into a certain shape, and the colored konjac with rare sugar added is packaged in a single color or a combination of two or more different colors. Of soaking the rare sugar to the internal pH at Tuna-like slices of Konjac in the range of 2.5 to 7.4, or Konjac with rare sugar added in the range of 2.5 to 7.4 with a pH of 2.5 to 7.4.

在本發明中,雖然以證實了能夠發揮作為蒟蒻加工飲食品的優異生理活性的蔬果冰沙式飲食品為例進行說明,但關於與蒟蒻加工飲食品相關的稀有糖的含量、稀有糖攝取量、抑制血糖值上升的效果、蒟蒻的中和步驟、加熱條件、製造中使用的其他材料,係於作為本發明對象的蒟蒻加工食品亦共通。 In the present invention, although a fruit and vegetable smoothie-type food and beverage that has demonstrated excellent physiological activity as a processed Konjac processed food and drink is described as an example, regarding the content of rare sugars and intake of rare sugar related to processed Konjac processed food and drink The effect of suppressing the increase in blood sugar level, the step of neutralizing konjac, the heating conditions, and other materials used in the production are also common to the processed food of konjac that is the object of the present invention.

〔蔬果冰沙式飲食品〕 〔Fruit and Fruit Smoothie Food and Drink〕

蔬果冰沙(smoothie)一直以來受到年輕人喜愛,其係將新鮮水果完整弄碎而得到的濃厚水果飲料。本發明的蔬果冰沙式飲食品,係為了製造使用微細粒狀蒟蒻的新形態的蔬果冰沙,而利用微細粒狀蒟蒻、濃縮果汁、增稠劑、果實的磨細物或粉碎物或其他調味料,作成蔬果冰沙式的有黏性、水果味的調味糊。 Smoothie has always been loved by young people. It is a thick fruit drink obtained by completely crushing fresh fruits. The fruit and vegetable smoothie-type food and beverage of the present invention utilizes fine-grained konjac, concentrated fruit juice, thickener, ground or pulverized fruit of fruit, etc. in order to produce a new form of fruit and vegetable smoothie using fine-grained konjac Seasoning, made into a fruit and vegetable smoothie with a sticky, fruity flavor paste.

此蔬果冰沙式飲食品可作為減肥食品而混合等量的水或牛奶以湯匙食用,或稀釋後用吸管飲用,並可做成冷凍型之形態。此蔬果冰沙式飲食品係美味、好看、具有水果味的感覺,尤其飽腹感佳,故在發揮任一機能方面其效果均格外優越,亦可利用作為有助於減肥的飲食品的蒟蒻加工品。 This vegetable and fruit smoothie food and beverage can be used as a diet food and mixed with an equal amount of water or milk to eat with a spoon, or diluted to drink with a straw, and can be made into a frozen form. This vegetable and fruit smoothie diet is delicious, good-looking, and has a fruity taste, especially fullness, so its effect is particularly superior in exerting any function, and it can also be used as a dietary product that helps to lose weight. Processed products.

例如,本發明的蔬果冰沙,係藉由在微細粒狀蒟蒻中混合糖類、濃縮果汁、增稠劑、果實的磨細物或粉碎物或其他調味料並進行加熱而製造。藉由使用藍莓風味、草莓風味、蘋果風味等的濃縮果汁或各種調味料,能夠製造富於變化的蔬果冰沙,另外,藉由調節微細粒狀蒟蒻的粒徑和添加量,能夠對其口感等食感賦予變化。本發明的蔬果冰沙式飲食品中含有被中和的或未被中和的微細粒狀蒟蒻與稀有糖。 For example, the vegetable and fruit smoothie of the present invention is manufactured by mixing sugar, concentrated fruit juice, thickener, ground or pulverized fruit of fruit, or other seasonings with fine granular konjac and heating them. By using concentrated fruit juices or various seasonings such as blueberry flavor, strawberry flavor, apple flavor, etc., it is possible to produce varied fruit and vegetable smoothies. In addition, by adjusting the particle size and amount of fine-grained Konjac, it can be tasted Wait for food to give change. The vegetable and fruit smoothie-type food and beverage of the present invention contains fine-grained konjac and rare sugar that are neutralized or not neutralized.

〔微細粒狀蒟蒻與稀有糖的含量〕 〔Content of fine granular Konjac and rare sugar〕

本發明的蔬果冰沙式飲食品中含有的被中和的微細粒狀蒟蒻,係較佳地賦予與習知蔬果冰沙中的弄碎果實同樣的食感,並且以發揮降低血糖值效果的範圍含有在飲食品中,較佳係以飲食品整體的40~95重量%的比例存在。當含有量超過上限值時,喪失蔬果冰沙本有的黏性或食感;當含有量低於下限值時,不僅無法呈現蔬果冰沙本有的性狀,而且發揮降低血糖值效果的作用效果降低。更佳係50~85重量%的範圍,對於發揮作為蔬果冰沙的食感與降低血糖值的效果較有效。 The neutralized fine granular konjac contained in the vegetable and fruit smoothie-type food and beverage of the present invention preferably imparts the same eating sensation as the crushed fruit in the conventional vegetable and fruit smoothie, and exerts the effect of lowering blood sugar level The range is included in the food and drink, and preferably exists in a proportion of 40 to 95% by weight of the entire food and drink. When the content exceeds the upper limit, the inherent viscosity or texture of the vegetable and fruit smoothies is lost; when the content is lower than the lower limit, not only the inherent characteristics of the vegetable and fruit smoothies cannot be exhibited, but also the effect of lowering blood sugar levels The effect is reduced. More preferably, the range of 50 to 85% by weight is more effective for exerting the feeling of being a vegetable and fruit smoothie and lowering the blood sugar level.

另外,藉由將微細粒狀蒟蒻設為0.1~3.0mm的範圍,可發揮作為蔬果冰沙的食感與降低血糖值的效果。當粒徑大於上限值時,口感或下嚥感等食感降低,不能稱為蔬果冰沙,且飲用時亦出現困難。另外,當粒徑小於下限值時,會成為與果汁類或牛奶等同樣的稀薄狀態。更佳係微細粒狀蒟蒻在0.1~2.0mm的範圍內。 In addition, by setting the fine-grained Konjac in the range of 0.1 to 3.0 mm, the effect as a smoothie of vegetables and fruits and the reduction of blood sugar level can be exerted. When the particle size is larger than the upper limit, the mouthfeel or the swallowing sensation is reduced, and it cannot be called a fruit and vegetable smoothie, and there are difficulties in drinking. In addition, when the particle size is less than the lower limit, it will be in the same thin state as juices, milk, etc. More preferably, the fine granular Konjac is in the range of 0.1 to 2.0 mm.

稀有糖例如可舉例如D-阿洛酮糖或D-阿洛糖,蔬果冰沙式飲食品中的稀有糖含量較佳為0.1至50.0重量%的範圍。當含量大於上限值時,無法期望抑制血糖值上升的效果進一步提高,且在經濟方面亦不佳。更佳之稀有糖的含有範圍為0.1~10.0重量%的範圍。 Examples of the rare sugars include D-psicose and D-psicose, and the content of the rare sugars in the fruit and vegetable smoothie food and beverage is preferably in the range of 0.1 to 50.0% by weight. When the content is greater than the upper limit, the effect of suppressing the increase in blood glucose level cannot be expected to be further improved, and it is also economically unfavorable. More preferably, the rare sugar content range is 0.1 to 10.0% by weight.

〔稀有糖攝取量〕 〔Rare sugar intake〕

D-阿洛糖及/或其衍生物、及/或D-阿洛酮糖及/或其衍生物的投予量,在經口投予的情況下,對成人而言,作為D-阿洛酮糖,較佳係一日攝取0.3~50g,但亦可根據年齡、症狀而適當增減。當依與蒟蒻組合的形態攝取時,抑制血糖值上升的效果在攝取後持續約一天的時間。 上述一日量的稀有糖,係在與蒟蒻組合的形態下,一日攝取一次,或隔開適當的間隔一日分2或3次,攝取稀有糖的一日用量。 The dose of D-allose and / or its derivatives, and / or D-alloxulose and / or its derivatives, when administered orally, is considered as D-A Lupulose is preferably ingested 0.3 to 50g a day, but can also be appropriately increased or decreased according to age and symptoms. When ingested in combination with Konjac, the effect of suppressing the rise in blood sugar level continues for about one day after ingestion. The above-mentioned daily amount of rare sugar is in a form combined with konjac, ingested once a day, or divided into two or three times a day at appropriate intervals to ingest the daily amount of rare sugar.

〔本發明的蔬果冰沙式飲食品的抑制血糖值上升的效果的例子〕 [Example of the effect of suppressing the increase in blood sugar level of the vegetable and fruit smoothie food and beverage of the present invention]

為了實際驗證本發明的蔬果冰沙式飲食品的抑制血糖值上升的效果,進行了試驗。準備以下的5種試料,由健康人7人在飲用此等後飲用葡萄糖,測定經過30分鐘、60分鐘與120分鐘時的血糖值。 In order to actually verify the effect of suppressing the increase in blood sugar level of the fruit and vegetable smoothie food and beverage of the present invention, an experiment was conducted. The following five kinds of samples were prepared. Seven healthy people drank glucose after drinking this, and the blood glucose values at 30 minutes, 60 minutes, and 120 minutes were measured.

(A)空腹時葡萄糖負荷試驗,(B)含有稀有糖的試料,(C)含有微細粒狀蒟蒻與稀有糖的試料,(D)含有大量微細粒狀蒟蒻的試料,(E)含有少量微細粒狀蒟蒻的試料。 (A) Glucose load test on fasting, (B) Samples containing rare sugar, (C) Samples containing fine granular Konjac and rare sugar, (D) Samples containing large amount of fine granular Konjac, (E) Small amounts of fine Sample of granular konjac.

算出測定數據的平均值並將測定結果示於圖1。根據圖1所示的試驗結果可知,藉由飲用蒟蒻,葡萄糖負荷試驗中的血糖值上升受到抑制,但是,藉由同時飲用稀有糖,能夠獲得單獨時所無法獲得的優異的抑制血糖值上升效果。亦即,實際驗證了本發明的含有微細粒狀蒟蒻與稀有糖的蔬果冰沙式飲食品具有優異的抑制血糖值上升效果。 The average value of the measurement data was calculated, and the measurement result is shown in FIG. 1. As can be seen from the test results shown in FIG. 1, by drinking Konjac, the rise in blood sugar level in the glucose load test is suppressed, but by drinking rare sugar at the same time, it is possible to obtain an excellent effect of suppressing the rise in blood sugar level that cannot be obtained alone . That is, it has been practically verified that the fruit and vegetable smoothie-type food and beverage containing fine granular Konjac and rare sugar of the present invention has an excellent effect of suppressing the increase in blood sugar level.

本發明係關於針對需要要求節約貧乏的胰島素、改善胰島素敏感度、及抑制高血糖的疾病、藉由抑制血漿葡萄糖濃度(血糖值)的日內異常上升而改善症狀、或者預防發病的例如糖尿病、潛在的糖尿病狀態、肥胖症、高脂血症、動脈硬化症等的預防和治療的人的飲食品和健康飲食品。 The present invention relates to diseases that require saving of poor insulin, improving insulin sensitivity, and inhibiting hyperglycemia, improving symptoms by suppressing abnormal increase in plasma glucose concentration (glycemic value) within a day, or preventing the onset of, for example, diabetes, potential Foods and healthy foods for the prevention and treatment of diabetes, obesity, hyperlipidemia, arteriosclerosis, etc.

本發明的飲食品及健康飲食品的特徵在於,含有被中和的蒟蒻加工食品與稀有糖及/或其衍生物作為有效成分。 The food and beverage and healthy food and beverage of the present invention are characterized by containing neutralized konjac processed food and rare sugars and / or derivatives thereof as active ingredients.

〔微細粒狀蒟蒻的製造〕 〔Manufacture of fine granular Konjac〕

在製造微細粒狀蒟蒻時,可使用藉由通常的方法製造的成形體。例如,將蒟蒻粉在冷水或溫水中混合、攪拌製成糊化物後,用鹼(氫氧化鈣)使其凝膠化而得到通常的絲狀或板狀的鹼蒟蒻(pH12.0),將該鹼蒟蒻磨碎或破碎,從而製造微細粒狀蒟蒻。蒟蒻粉的濃度為2~4%左右,此時,可尤其是以改善物性為目的而添加木薯澱粉等,或者為了對成形體進行著色而添加黃色、紅色、綠色等的著色劑,亦可以使用經過脫鹼的蒟蒻。 When producing fine granular Konjac, a shaped body produced by a usual method can be used. For example, after mixing Konjac powder in cold or warm water and stirring to make a paste, it is gelled with alkali (calcium hydroxide) to obtain the usual silky or plate-like alkali Konjac (pH12.0), The alkali konjac is ground or broken to produce fine granular konjac. The concentration of konjac powder is about 2 to 4%. In this case, cassava starch, etc. can be added especially for the purpose of improving physical properties, or coloring agents such as yellow, red, and green can be added to color the molded body. It can also be used Konjac after dealkali.

可使用錘磨機、快磨機(flash mill)等破碎機將該凝膠狀成形體微細化,進一步使用高壓均質器使其變小。另外,可以使用穿設有多個成形孔的穿孔板,與形成蒟蒻絲或絲狀蒟蒻等情況同樣地、從在混練裝置的排出口設置的穿孔板向熱水槽同時擠出成形為15~60條的線狀體,在藉由熟成而凝固後在粉碎機中予以細碎。對應於微細粒狀蒟蒻的製造方式,生成物的表面狀態等有所變化。 The gel-like shaped body can be miniaturized using a crusher such as a hammer mill or a flash mill, and further reduced using a high-pressure homogenizer. In addition, a perforated plate with a plurality of forming holes can be used, and it can be simultaneously extruded into a hot water tank from the perforated plate provided at the discharge port of the kneading device to 15 to 60 in the same way as the formation of konjac wire or silky konjac, etc. The strip-shaped linear bodies are solidified by ripening and then finely crushed in a pulverizer. The surface state of the product changes according to the manufacturing method of fine granular Konjac.

〔微細粒狀蒟蒻的長度或粒徑〕 [Length or particle size of fine granular Konjac]

微細粒狀蒟蒻的長度或粒徑可以根據其用途適當選擇,可以使用3mm以下、較佳0.1mm~2.0mm的範圍的微細粒狀蒟蒻,其形狀可舉例如圓柱狀、方柱狀、板狀、球狀、外表面具有凹凸的粒狀等。由於在與食品混合時感覺不到粒狀物存在的磨碎物的粒徑為約90μm以下,因此較佳為100μm以上。可藉由磨碎處理的程度製成大小的磨碎顆粒,亦可藉由磨碎機的運轉時間來決定粒徑。 The length or particle size of the fine-grained Konjac can be appropriately selected according to its application, and fine-grained Konjac can be used in the range of 3 mm or less, preferably 0.1 mm to 2.0 mm, and the shape thereof can be, for example, cylindrical, square columnar, or plate-shaped , Spherical, granular with uneven surface, etc. Since the particle size of the ground product that does not feel the presence of particulate matter when mixed with food is about 90 μm or less, it is preferably 100 μm or more. The size of the grinding particles can be made by the degree of grinding treatment, and the particle size can also be determined by the running time of the grinding machine.

〔蒟蒻的中和步驟〕 〔Kujian neutralization procedure〕

本發明的微細粒狀蒟蒻可依含有鹼成分的狀態使用,但較佳係將所含的鹼成分中和再使用。蒟蒻係以蒟蒻薯或蒟蒻精粉作為原料,以氫氧化鈣、鹼水等鹼使其凝固而得到的物質,通常製造出的蒟蒻的pH為10~12。凝固而得到的物質通常是整形後的蒟蒻,形狀一般為方塊狀、絲狀、丸狀、粒狀或板狀,為無著色或者經過著色的物質。無著色的物質大致分為不使用海藻粉的白色蒟蒻、以海藻粉著色後的黑色系蒟蒻。經過著色的蒟蒻混入有不易溶出至調味液中的油性的天然色素。例如,作為不會從蒟蒻內溶出到水及調味液中的天然色素,有如混入有黃色(胡蘿蔔素)、紅色(甜椒)、黑色(烏賊墨液)、藍色(梔子)及/或綠色(金盞花、梔子)而著色為各種顏色的蒟蒻。 The fine granular Konjac of the present invention can be used in a state containing an alkali component, but it is preferable to neutralize the alkali component contained before reuse. Konjac is made of Konjac or Konjac fine powder as a raw material and solidified with alkali such as calcium hydroxide or alkaline water. The pH of Konjac is usually 10-12. The material obtained by solidification is usually Konjac after reshaping, and the shape is generally square, silk, pellet, granular or plate-like, which is uncolored or colored. Substances without coloration are roughly divided into white kombu which does not use seaweed powder, and black kombu that is colored with seaweed powder. The colored Konjac is mixed with oily natural pigments that are not easily dissolved into the seasoning liquid. For example, as natural pigments that do not dissolve into water and seasoning liquids from Konjac, there are yellow (carotene), red (sweet pepper), black (squid ink), blue (gardenia), and / or Green (Calendula, Gardenia) and colored Konjac in various colors.

蒟蒻較佳係中和至pH2.5~7.4,用於中和蒟蒻中的鹼所需要的酸量,係將既定重量的蒟蒻用均質器磨碎,在其中混合至少可中和微細粒狀蒟蒻的鹼成分的量的酸性素材,此時,添加有機酸,藉由測定中和至pH2.6~7.4所需要的酸量來決定。作為有機酸,主要使用醋酸、檸檬酸、乳酸、蘋果酸、葡糖酸等食品添加物,較佳亦可考慮調味料、果汁等其他成分中含有的酸性成分。為了可常溫流通,添加酸使製品pH達到2.5~7.0,較佳5.0~4.0,並例如在85℃進行30~60分鐘的加熱殺菌。為了以冷藏、冰溫保鮮或冷凍的方式流通,可調節至pH7.4,但是基於到消費者手中後的產品的管理問題,pH較佳調節為2.5~7.0。 Konjac is preferably neutralized to pH 2.5 to 7.4. It is used to neutralize the amount of acid required in the alkali in Konjac. It is to grind the Konjac with a given weight with a homogenizer, and mix it to at least neutralize the fine-grained Konjac. For the acidic material with the amount of the alkaline component, at this time, the organic acid is added, and it is determined by measuring the amount of acid required to neutralize to pH 2.6 to 7.4. As the organic acid, food additives such as acetic acid, citric acid, lactic acid, malic acid, and gluconic acid are mainly used. Preferably, acidic components contained in other ingredients such as seasonings and fruit juices are also considered. In order to be able to circulate at room temperature, acid is added to make the product pH reach 2.5 ~ 7.0, preferably 5.0 ~ 4.0, and heat sterilization is performed at 85 ° C for 30 ~ 60 minutes, for example. In order to circulate in the form of refrigeration, ice temperature preservation or freezing, the pH can be adjusted to 7.4, but based on the management of the product after reaching the consumer, the pH is preferably adjusted to 2.5 ~ 7.0.

微細粒狀蒟蒻的利用酸性成分進行的中和步驟,可在容器內進行,接著將中和物收納在個別的包裝容器內而進行,但是亦可以在將微細粒狀蒟蒻、有機酸、調味料、果汁等封入到個別的包裝用的容器內之後使其中和。另外,亦可以將包括微細粒狀蒟蒻在內的所 有食品材料收納在流通用的個別包裝容器內後,在加熱殺菌步驟中使其中和。填充的包裝用的容器的素材為與玻璃製相比更具有耐熱性與保香性的塑膠製,硬質容器或可撓性的層壓袋、進而高熱壓殺菌袋係在操作性方面效率高。包裝後的加熱處理係以將蒟蒻的鹼迅速地中和除去、與加快調味成分向蒟蒻內滲透為目的,同時進行有害菌的殺菌。 The neutralization step of the fine granular Konjac using acidic components can be carried out in a container, and then the neutralized product can be carried out in a separate packaging container. However, the fine granular Konjac, organic acid, seasoning , Juice, etc. are sealed in individual packaging containers and neutralized. In addition, you can also use the fine granular Konjac After the food materials are stored in individual packaging containers that are versatile, they are neutralized in the heat sterilization step. The material of the filled packaging container is made of plastic which is more heat-resistant and fragrance-preserving than glass, rigid containers or flexible laminated bags, and high-pressure sterilization bags are highly efficient in terms of operability . The heat treatment after packaging is for the purpose of quickly neutralizing and removing the konjac alkali, and to accelerate the penetration of the seasoning ingredients into the konjac, while sterilizing harmful bacteria.

〔加熱條件〕 〔Heating conditions〕

製造出的微粒狀蒟蒻係在加熱殺菌後使用,根據加熱處理條件,有時會引起蒟蒻的軟化、橡膠質化,此現象與調味蒟蒻的pH相關。考慮到食感與保存性的最佳加熱條件,係在pH3.5~6.0的範圍為50~95℃、在pH6.0~9.0的範圍為100~120℃的關係,通常的處理時間為60分鐘以內。在此加熱處理中,雖然視蒟蒻的形狀而異,但在結束時,調味液成分充分滲透入蒟蒻而予以調味,在加熱步驟結束時,微細粒狀蒟蒻被中和至規定的pH。 The produced particulate Konjac is used after heat sterilization. Depending on the heat treatment conditions, the Konjac may be softened and rubberized. This phenomenon is related to the pH of the seasoned Konjac. Considering the optimal heating conditions for food feeling and preservation, the relationship between pH 3.5 ~ 6.0 is 50 ~ 95 ° C and pH 6.0 ~ 9.0 is 100 ~ 120 ° C, and the usual processing time is 60 Within minutes. In this heat treatment, although it varies depending on the shape of Konjac, at the end, the seasoning liquid component sufficiently penetrates into Konjac to be seasoned, and at the end of the heating step, the fine granular Konjac is neutralized to a predetermined pH.

〔蔬果冰沙式飲食品的製造中使用的其他材料〕 [Other materials used in the manufacture of vegetable and fruit smoothie foods and beverages]

在製造本發明的蔬果冰沙式飲食品時,係適當使用酸性素材和增稠劑等。 When manufacturing the fruit and vegetable smoothie food and beverage of the present invention, acidic materials, thickeners, etc. are suitably used.

酸性素材包含選自調味料、增稠物質、果汁、和將果實及/或蔬菜破碎並過濾而得到的蔬果泥(puree)、果實糊、蔬菜糊中的1種以上,只要調節pH值使得至少能夠中和微細粒狀蒟蒻的鹼成分即可。酸性素材具有食感,能夠在具有可品味與磨碎泥不同食感的特徵的快速混合中,於保留蔬菜本來的美味、顏色、食感、香味之下,完成食材。另外,能夠作出將果實及/或蔬菜破碎並過濾而得到的蔬果泥(puree)、果 實糊、蔬菜糊等獨創的食感。 The acidic material contains one or more kinds selected from seasonings, thickening substances, fruit juices, puree, fruit paste, vegetable paste obtained by crushing and filtering fruits and / or vegetables, as long as the pH value is adjusted so that at least It is sufficient to neutralize the alkali component of fine granular Konjac. The acidic material has a sense of taste, and can be used to complete the ingredients while retaining the original taste, color, taste, and aroma of vegetables in the rapid mixing with the characteristics of different tastes with the taste of grated mud. In addition, it is possible to produce puree and fruit obtained by crushing and filtering fruits and / or vegetables The original taste of solid paste and vegetable paste.

增稠物質只要是食品用黏性物質就沒有特別限制,有如以澱粉、海藻成分等天然多糖類為代表的作為公知食品添加物的天然橡膠成分、增黏多糖類等。低pH食品中廣泛使用果膠。果膠的種類大致區分為高甲氧基果膠與低甲氧基果膠,根據黏度、凝膠化特性區分使用。作為使用微細粒狀蒟蒻的果醬的增稠物質,較佳係不使用高甲氧基果膠、而使用低甲氧基果膠。另外,具體而言,可使用黃原膠、羅望子果膠、瓜爾豆膠、塔拉膠、塔拉豆膠、刺槐豆膠、角叉菜膠等。 The thickening substance is not particularly limited as long as it is a viscous substance for food, and examples include natural rubber components and thickening polysaccharides as well-known food additives represented by natural polysaccharides such as starch and seaweed components. Pectin is widely used in low pH foods. The types of pectin are roughly divided into high-methoxyl pectin and low-methoxyl pectin, which are used according to their viscosity and gelation characteristics. As a thickening substance using a fine granular Konjac jam, it is preferable not to use high-methoxy pectin but to use low-methoxy pectin. In addition, specifically, xanthan gum, tamarind pectin, guar gum, tara gum, tara gum, locust bean gum, carrageenan, and the like can be used.

藉由使微細粒狀蒟蒻的長度、粒形或粒徑變化,也可表現果實的果肉、果皮的食感,因此,亦可將天然素材的一部分或全部以微細蒟蒻粒子替換。另外,食感也由於所使用的添加劑的種類而變化。例如,在對微細粒狀蒟蒻、濃縮果汁的使用量或濃縮果汁的種類與品質、以及增稠劑的種類與量等進行研究時,可決定最佳的黏性的品質。黏性的品質包括以黏彈性為中心的複雜的物性的組合,因此,難以將其數值化,即使具有利用黏度計、流變儀、稠度測定儀等專門設備的測定值也難以求得最佳值。在決定最佳的黏性的品質時,結果不得不由人的五感根據感官實驗確認決定最好的結果。濃縮果汁可以例示草莓、藍莓、甜瓜等的利用。 By changing the length, grain shape or particle size of the fine granular Konjac, the flesh and peel of the fruit can also be expressed. Therefore, part or all of the natural material can be replaced with fine Konjac particles. In addition, the food texture also changes depending on the type of additives used. For example, when researching the use of fine granular Konjac, concentrated fruit juice, the type and quality of concentrated fruit juice, and the type and amount of thickener, the best viscosity quality can be determined. The viscous quality includes a complex combination of physical properties centered on viscoelasticity. Therefore, it is difficult to quantify it. Even with special equipment such as a viscometer, rheometer, and consistency tester, it is difficult to obtain the best value. value. When deciding the best sticky quality, the result has to be determined by the human five senses based on sensory experiments to determine the best result. Concentrated juices can be exemplified by the use of strawberries, blueberries, melons, etc.

作為調味液,係使用醋酸、砂糖、山梨糖醇、食鹽、麩胺酸鈉、乳酸鈣、牛肉萃取物、濃味醬油等,只要是在煮菜、炒菜、拌菜等中所使用的西式、日式、中華式的調味料,即可使用。為了呈現出果實風味,可以利用藍莓或草莓等的濃縮果汁、調味料(flavor)、果肉等。 As the seasoning liquid, acetic acid, granulated sugar, sorbitol, table salt, sodium glutamate, calcium lactate, beef extract, concentrated soy sauce, etc., as long as it is used in cooking, stir-frying, mixing vegetables, etc. Japanese and Chinese seasonings are ready to use. In order to express the fruit flavor, concentrated fruit juices, flavors, pulp, etc., such as blueberries or strawberries, can be used.

另外,當使用著色為各種顏色的微細粒狀蒟蒻時,可期待顏色豐富並趣味的健康食品。利用微細粒狀蒟蒻作為素材的食品, 可開發出低卡路里、發揮健康感覺的新產品,作為蔬果冰沙式飲食品的範圍變大。 In addition, when fine grained Konjac colored in various colors is used, healthy foods rich in color and interesting can be expected. Food that uses fine grained Konjac as raw material, New products with low calories and healthy feelings can be developed, and the range as a fruit and vegetable smoothie-type food and beverage becomes larger.

〔稀有糖〕 〔Rare Sugar〕

本發明的蒟蒻加工飲食品中,較佳係使用D-阿洛糖或D-阿洛酮糖或者其等的混合物。在蒟蒻加工飲食品中,依可攝取到屬於成人攝取量的一日量0.3~50g的範圍含有稀有糖。例如,蔬果冰沙式的飲食品中的稀有糖的含量為0.1~10.0重量%、較佳1.0~5.0重量%、更佳1.0~2.0重量%的範圍。當未滿0.1重量%時,難以攝取屬於成人攝取量的一日量0.3~50g,抑制血糖上升的效果不夠。另外,當超過10重量%時,大多會過剩攝取而不佳。此等稀有糖的水溶液為無色透明,無氣味,有甜味。因此,即使添加在蔬果冰沙式飲食品中,亦不損害外觀或味道。作為稀有糖的成分,可使用下述甜味料:果糖的比例為20~80重量份,葡萄糖及阿洛酮糖的合計比例為80~20重量份左右,在將葡萄糖及阿洛酮糖的合計設為100重量份的情況下,阿洛酮糖為5重量份以上、較佳10重量份以上的比率,該甜味劑接近砂糖的甜度與味質,可預防肥胖等生活習慣病(專利文獻10)。作為該甜味料,市售有含有稀有糖的糖漿(商品名:Rare Sugar Sweet)。 In the Konjac processed foods and beverages of the present invention, it is preferred to use D-allose, D-alloxulose, or a mixture thereof. Konjac processed foods and beverages contain rare sugars in the range of 0.3 to 50 g per day, which is the daily intake for adults. For example, the content of rare sugars in the vegetable and fruit smoothie-type food and beverage is in the range of 0.1 to 10.0% by weight, preferably 1.0 to 5.0% by weight, and more preferably 1.0 to 2.0% by weight. When it is less than 0.1% by weight, it is difficult to ingest the daily intake of 0.3 to 50 g, which is an intake amount for adults, and the effect of suppressing the increase in blood sugar is insufficient. In addition, when it exceeds 10% by weight, excessive intake is often not good. The aqueous solution of these rare sugars is colorless, transparent, odorless, and sweet. Therefore, even if it is added to a fruit and vegetable smoothie food and beverage, it does not damage the appearance or taste. As a component of the rare sugar, the following sweeteners can be used: the ratio of fructose is 20 to 80 parts by weight, and the total ratio of glucose and allulose is about 80 to 20 parts by weight. When the total amount is 100 parts by weight, the ratio of allulose is 5 parts by weight or more, preferably 10 parts by weight or more. This sweetener is close to the sweetness and taste of granulated sugar, which can prevent lifestyle habits such as obesity ( Patent Document 10). As this sweetener, a syrup containing rare sugar (trade name: Rare Sugar Sweet) is commercially available.

稀有糖可定義為自然界中僅微量存在的單糖和糖醇。對於六碳糖(己糖),在醛糖的情況下,存在L-阿洛糖、L-古洛糖、L-葡萄糖、L-半乳糖、L-阿卓糖、L-伊杜糖、L-甘露糖、L-塔洛糖、D-塔洛糖、D-甘露糖、D-伊杜糖、D-阿卓糖、D-半乳糖、D-葡萄糖、D-古洛糖、D-阿洛糖這16種;在酮糖的情況下,存在L-阿洛酮糖、L-山梨糖、L-果糖、L-塔格糖、D-塔格糖、D-果糖、D-山梨糖、D-阿洛酮糖這8種。 自然界中大量存在的單糖有D-葡萄糖、D-果糖、D-半乳糖、D-甘露糖、D-核糖、D-木糖、L-阿拉伯糖這7種,這等以外的單糖均為稀有糖。 Rare sugars can be defined as monosaccharides and sugar alcohols that only exist in trace amounts in nature. For six-carbon sugars (hexoses), in the case of aldoses, there are L-allose, L-gulose, L-glucose, L-galactose, L-altrose, L-idose, L-mannose, L-talose, D-talose, D-mannose, D-idulose, D-altrose, D-galactose, D-glucose, D-gulose, D -16 types of alloses; in the case of ketoses, there are L-allose, L-sorbose, L-fructose, L-tagatose, D-tagatose, D-fructose, D- There are 8 types of sorbose and D-psicose. There are 7 types of monosaccharides that exist in nature, including D-glucose, D-fructose, D-galactose, D-mannose, D-ribose, D-xylose, and L-arabinose. For rare sugar.

D-阿洛酮糖或D-阿洛糖係天然微量存在的單糖,並未有此等稀有糖對人具有毒性的報告,可以認為對動物的毒性低。 D-psicose or D-psicose is a monosaccharide naturally present in trace amounts. There is no report of the toxicity of these rare sugars to humans, and it can be considered that the toxicity to animals is low.

〔D-阿洛酮糖〕 〔D-Aloxulose〕

D-阿洛酮糖係稀有糖中目前已大量生產的稀有糖。D-阿洛酮糖係分類為屬於稀有糖的己酮糖的阿洛酮糖的D體,為六碳糖(C6H12O6)。D-阿洛酮糖的甜味高雅、清爽,不致有如糖精般伴隨苦或澀的不悅感,類似於果糖的甜味。甜度為蔗糖的約70%。 D-aloxone sugar-based rare sugars are currently produced in large quantities. The D-aloxone sugar system is classified as the D body of alloxan sugar, which is a hexanose sugar that is a rare sugar, and is a six-carbon sugar (C 6 H 12 O 6 ). The sweetness of D-psicose is elegant and refreshing, without the unpleasant feeling of bitterness or astringency like saccharin, similar to the sweetness of fructose. The sweetness is about 70% of sucrose.

關於D-阿洛酮糖,目前通常之製法為使用酶(表異構酶)對果糖進行處理而獲得,但亦可從天然物中萃取。在製造D-阿洛酮糖時,可以使用精製酶,亦可以利用生產該酶的微生物。另外,己酮糖-3-表異構酶係將果糖等己酮糖的3位的OH進行異構化的酶,亦已知使用D-塔格糖-3-表異構酶或D-阿洛酮糖-3-表異構酶的方法。另外,可使用精製酶或將生產該酶的微生物固定化而得到的固定化酶或固定化微生物。 Regarding D-psicose, the current general method is obtained by treating fructose with an enzyme (epimerase), but it can also be extracted from natural substances. When manufacturing D-psicose, a refined enzyme may be used, or a microorganism that produces the enzyme may be used. In addition, hexulose-3-epimerase is an enzyme that isomerizes the 3-position OH of hexulose such as fructose, and it is also known to use D-tagatose-3-epimerase or D- Alloxan-3-epimerase method. In addition, a purified enzyme or an immobilized enzyme or immobilized microorganism obtained by immobilizing the microorganism producing the enzyme can be used.

針對D-阿洛酮糖的衍生物進行說明。 The derivative of D-psicose will be described.

將從某種起始化合物藉由化學反應轉換了分子結構而得到的化合物稱為起始化合物的衍生物。包括D-阿洛酮糖在內的六碳糖的衍生物,通常為糖醇(將單糖類還原時,醛基和酮基變成醇基,成為碳原子數相同的多元醇)、糖醛酸(單糖類的醇基被氧化而得到的物質,天然中已知有D-葡萄糖醛酸、半乳糖醛酸、甘露糖醛酸)、胺基糖(糖分子的OH基被NH2基取代而得到的物質,有葡萄糖胺、半乳糖胺、糖苷等)等,但是並不限定於此等。 A compound obtained by converting a molecular structure of a certain starting compound through a chemical reaction is called a derivative of the starting compound. Derivatives of six-carbon sugars including D-psicose, usually sugar alcohols (when monosaccharides are reduced, aldehyde groups and keto groups become alcohol groups and become polyols with the same number of carbon atoms), uronic acid (A substance obtained by oxidizing a monosaccharide alcohol group, D-glucuronic acid, galacturonic acid, mannuronic acid), amino sugar (the OH group of the sugar molecule is replaced by the NH 2 group is known in nature) The obtained substance includes glucosamine, galactosamine, glycoside, etc.), but it is not limited thereto.

〔D-阿洛糖〕 [D-Allose]

D-阿洛糖的生產,係使用L-鼠李糖異構酶將D-阿洛酮糖異構化,使用可藉由從其混合物中分離D-阿洛糖而生產的L-鼠李糖異構酶,可由D-阿洛酮糖大量生產稀有糖D-阿洛糖。在製造D-阿洛糖與D-阿洛酮糖的混合物時,係使L-鼠李糖異構酶作用於D-阿洛酮糖發生異構化反應,來製備D-阿洛酮糖及D-阿洛糖的混合物的方法可有利地實施。可不需將D-阿洛酮糖與D-阿洛糖分離而依混合液的型式獲得。 The production of D-allose is the isomerization of D-allulose using L-rhamnose isomerase, and the use of L-rhamnose produced by separating D-allose from its mixture Sugar isomerase can produce rare sugar D-allose from D-alloxanose in large quantities. In the manufacture of a mixture of D-allose and D-psicose, the isomerization reaction of L-rhamnose isomerase on D-psicose to produce D-psicose And the method of the mixture of D-allose can be advantageously carried out. It can be obtained according to the type of mixed liquid without separating D-psicose and D-psicose.

以下,根據實施例對本發明的蔬果冰沙式飲食品進行詳細說明,但是,本發明並不受這些實施例限定。D-阿洛糖為D-阿洛糖及/或其衍生物,D-阿洛糖的衍生物為選自D-阿洛糖的醛基變成醇基而得到的糖醇、D-阿洛糖的醇基被氧化而得到的糖醛酸、和D-阿洛糖的醇基被NH2基取代而得到的胺基糖中的D-阿洛糖衍生物。 Hereinafter, the vegetable and fruit smoothie food and beverage of the present invention will be described in detail based on examples, but the present invention is not limited to these examples. D-allose is D-allose and / or its derivatives, and D-allose derivatives are sugar alcohols and D-alloses obtained by changing the aldehyde group of D-allose to an alcohol group The D-allose derivative in the amine sugar obtained by oxidizing the uronic acid obtained by oxidizing the sugar alcohol group and the D-allose sugar alcohol group by the NH 2 group.

本發明的蒟蒻加工飲食品的製造方法,除了使蒟蒻素材含有稀有糖的方法以外,可以使用申請前公知的pH在2.5~7.4的範圍的蒟蒻的製造方法。 In the method for producing Konjac processed foods and beverages of the present invention, in addition to the method in which the Konjac material contains rare sugar, a method for producing Konjac that has a pH in the range of 2.5 to 7.4 known before the application can be used.

(1)將藉胛使用氫氧化鈣進行凝固而得到的蒟蒻,浸漬在用於中和蒟蒻中的該鹼所需量的有機酸與賦予香味的調味液中,進行中和與調味液成分的滲透。調節調味液使得蒟蒻的pH成為2.5~7.4。必要量的稀有糖可以混合在蒟蒻原料中,亦可以混合在調味液中使其滲透至蒟蒻中(參照專利文獻11)。 (1) Konjac konjac obtained by coagulation of calcium hydroxide by scapula is immersed in the amount of organic acid required to neutralize the alkali in Konjac and flavoring liquid that imparts fragrance to neutralize and seasoning liquid components penetration. Adjust the seasoning liquid to make the Konjac pH 2.5 ~ 7.4. The necessary amount of rare sugar may be mixed in the Konjac raw material, or may be mixed in the seasoning liquid to make it penetrate into Konjac (refer to Patent Document 11).

(2)pH在2.5~7.4的範圍的加入了稀有糖的蒟蒻的著色方法,係例如可以在蒟蒻原料中一併混練入將麥類的表皮部分烘焙而得到的粉、與黑色及紅橙色的色調的天然色素而著色為黑色系(參照專利文獻 12);亦可以從動植物中以油溶性狀態萃取色素,於其中加入乳化劑使其在水中呈小粒狀分散的狀態,將此狀態之天然色素予以混練進行著色(專利文獻13參照)。 (2) The coloring method of Konjac with rare sugar added in the pH range of 2.5 to 7.4. For example, it is possible to mix the powder obtained by baking the skin part of wheat together with black and red-orange in Konjac raw materials. Natural pigment of hue and black color (refer to patent literature 12); It is also possible to extract pigments in an oil-soluble state from animals and plants, add an emulsifier to disperse them in small particles in water, and mix and color the natural pigments in this state (refer to Patent Document 13).

(3)本發明的蒟蒻加工飲食品亦可為蒟蒻麵的高熱壓殺菌袋食品,其特徵在於,係使用由蒟蒻、澱粉、麩蛋白及小麥粉構成的原料粉,添加在水中攪拌製成蒟蒻糊,在其中添加氫氧化鈣進行混練,在該狀態下使其通過穿孔板而在熱水浴中進行加熱,將由此固化成形的作成麵狀蒟蒻的pH10~12的蒟蒻麵與酸性的調味料組合,pH調節為9~3者,以及將其在高熱壓殺菌袋內進行高熱壓處理後者;亦可使用在蒟蒻麵中混合有稀有糖的原料粉及/或蒟蒻糊。亦可在酸性的調味料中混合稀有糖,調節或加強稀有糖量(專利文獻14)。 (3) The Konjac processed foods and beverages of the present invention may also be high-pressure sterilization bag foods of Konjac noodles, characterized in that raw material powders composed of Konjac, starch, bran and wheat flour are used and added to stir in water Konjac paste, which is added with calcium hydroxide for kneading. In this state, it is passed through a perforated plate and heated in a hot water bath, and the solidified and shaped kakimaki pH10 ~ 12 kombu surface and acidic seasoning Material combination, the pH is adjusted to 9 to 3, and the latter is subjected to high-pressure treatment in a high-pressure sterilization bag; the raw material powder and / or konjac paste mixed with rare sugar in the konjac noodles can also be used. It is also possible to mix rare sugars with acidic seasoning to adjust or strengthen the amount of rare sugars (Patent Document 14).

(4)在下述不需進行長時間加熱、未混練調味料、依較一般蒟蒻更短時間即使味道滲入至關東煮蒟蒻中的方法中,所需量之稀有糖可混合至蒟蒻原料中,亦可混合至調味液使其滲透至蒟蒻:將蒟蒻粉,與溶解有由選自麩胺酸鈉、肌苷酸鈉、鳥苷酸鈉、琥珀酸鈉、肉萃取物、魚萃取物、貝萃取物及蔬菜萃取物所組成群、且至少含有肌苷酸鈉及琥珀酸鈉的2種以上的調味料構成的呈現甘醇味的調味料、呈現鹽味的調味料及呈現甜味的調味料的各調味料的熱水混合攪拌,製成蒟蒻糊,添加氫氧化鈣使其凝膠化,得到pH11以上的常溫流通的調味蒟蒻,在不對其進行脫鹼、其鹼殘留的狀態下進一步在關東煮湯中煮5~10分鐘,作成滲入了關東煮味而可食用的關東煮蒟蒻(參照專利文獻15)。 (4) In the following method that does not require long-time heating, no kneading seasoning, and a shorter time than the general Konjac, even if the taste penetrates into the Kanto boiled Konjac, the required amount of rare sugar can be mixed into the Konjac raw material, or Mix until the seasoning liquid penetrates into Konjac: Konjac powder is mixed with sodium glutamate, sodium inosine, sodium guanylate, sodium succinate, meat extract, fish extract, shellfish extract And vegetable extracts, each of which contains at least two types of seasonings of sodium inosinate and sodium succinate, a seasoning exhibiting a glycol flavor, a seasoning exhibiting a salt flavor, and a seasoning exhibiting a sweet flavor The hot water of the seasoning is mixed and stirred to make a Konjac paste, and calcium hydroxide is added to make it gelatinized to obtain a seasoned Konjac circulated at room temperature of pH 11 or higher, and the broth is further cooked in Kanto without being alkalized and its alkali remaining. Cook for 5 to 10 minutes to make Kanto boiled Konjac that is edible with Kanto cooking taste (see Patent Document 15).

利用實施例對本發明的詳細情況進行說明。本發明不受此等實施例的任何限定。 The details of the present invention will be described using examples. The invention is not limited in any way by these embodiments.

(參考例1) (Reference example 1) 〔使用微細粒狀蒟蒻與稀有糖的蔬果冰沙的製造〕 [Manufacture of vegetable and fruit smoothies using fine granular Konjac and rare sugar]

製作將藍莓的濃縮果汁與還原糖飴、砂糖等甜味劑料、蘋果酸等酸味料、黃原膠等增稠劑與水混合的表1所示組成的調味液,在粒徑0.1mm~1mm的微細粒狀蒟蒻1kg中混合pH為3.0的調味料300g,進一步添加D-阿洛酮糖70.0g作為固態成分後,放入高速攪拌裝置中混合5秒鐘。將此放入聚丙烯製容器中以120℃加熱15分鐘。所製造出的蔬果冰沙式的加工食品的pH為3.7,糖度為11.4%。各原料素材的成分、種類、配合比例的詳細情況示於表1。 Prepare a seasoning solution of the composition shown in Table 1 that mixes concentrated fruit juice of blueberries, sweeteners such as reduced sugar syrup, granulated sugar, sour tastes such as malic acid, and thickeners such as xanthan gum, with a diameter of 0.1mm ~ 1 g of fine granular Konjac 1 kg was mixed with 300 g of a seasoning with a pH of 3.0, 70.0 g of D-psicose was further added as a solid component, and the mixture was placed in a high-speed stirring device for 5 seconds. This was placed in a polypropylene container and heated at 120 ° C for 15 minutes. The processed fruit and vegetable smoothie-like processed food has a pH of 3.7 and a sugar content of 11.4%. Table 1 shows the details of the ingredients, types, and blending ratio of each raw material.

此製品含有約5重量%的D-阿洛酮糖,藉由飲食100g,可攝取約5g的D-阿洛酮糖。由10人的專門評判員對該產品進行測試,結果確認了具有作為蔬果冰沙的食感。 This product contains about 5% by weight of D-psicose, and with 100g of diet, about 5g of D-psicose can be ingested. The product was tested by a special panel of 10 judges, and the result confirmed that it had a sense of eating as a vegetable and fruit smoothie.

(參考例2) (Reference example 2)

與實施例1同樣地製造藍莓蔬果冰沙式飲食品。將調味液的組成示於表2。添加15g的D-阿洛酮糖,製造含有約1重量%的D-阿洛酮糖的藍莓蔬果冰沙式飲食品。試吃該蔬果冰沙式飲食品的10人的專門評判員全員判定其具有作為蔬果冰沙的良好風味、食感。 In the same manner as in Example 1, a blueberry, fruit and vegetable smoothie-type food and beverage was produced. Table 2 shows the composition of the seasoning liquid. 15 g of D-psicose was added to produce a blueberry, vegetable, and fruit smoothie-style food and drink containing about 1% by weight of D-psicose. All of the 10 panelists who tasted the fruit and vegetable smoothie-style food and beverage judged that they had good flavor and texture as a fruit and vegetable smoothie.

(參考例3) (Reference example 3)

與實施例1同樣地,在具有表3記載的組成的調味液中,代替D- 阿洛酮糖添加由D-阿洛酮糖與D-阿洛糖的混合物構成的稀有糖70g,製造草莓蔬果冰沙。製品由10人的專門評判員全員判定作為蔬果冰沙良好。 As in Example 1, in the seasoning liquid having the composition described in Table 3, instead of D- Alloxan sugar is added with 70 g of a rare sugar composed of a mixture of D-aloxulose and D-allose to make a strawberry vegetable smoothie. The product was judged to be good as a fruit and vegetable smoothie by all the 10 judges.

(參考例4) (Reference example 4)

為了實際驗證作為具有抑制血糖值上升的效果的蒟蒻加工飲食品的蔬果冰沙式飲食品的抑制血糖值上升的效果,進行了試驗。 In order to actually verify the effect of suppressing the increase in blood sugar level of the fruit and vegetable smoothie-type food and drink which is a processed Konjac processed food and drink product having the effect of suppressing the increase in blood sugar level, an experiment was conducted.

此試驗獲得7名不屬於下述的除外基準的健康自願者(男性2名、女性5名)的協助而實施。 This test was implemented with the assistance of 7 healthy volunteers (2 males and 5 females) who did not fall within the exclusion criteria described below.

<除外基準> <Excluded benchmark>

(1)對D-阿洛酮糖成分有藥物過敏的患者 (1) Patients with drug allergies to the D-psicose component

(2)1型糖尿病患者 (2) Patients with type 1 diabetes

(3)有糖尿病性酮症酸中毒(由於血糖過高,血液成為酸性,可見口渴感、多飲、倦怠感、體重減少等惡化的糖尿病症狀。進一步發展時會引起血壓降低、心動過速、意識障礙等)經歷的患者 (3) Diabetic ketoacidosis (due to high blood sugar, the blood becomes acidic, and diabetic symptoms such as thirst, polydipsia, tiredness, weight loss, etc. can be seen. The further development will cause lower blood pressure and tachycardia , Consciousness, etc.)

(4)有重度的腎障礙、肝障礙、心臟病的患者,或者有其他嚴重的併發症,根據主治醫生的判斷,被判斷為不適合作為對象的患者 (4) Patients with severe kidney disorders, liver disorders, heart diseases, or other serious complications, according to the judgment of the attending doctor, are judged to be unsuitable for the target patients

(5)目前是感染症的患者。接受過手術的患者、或預約了手術的患者。 (5) Currently, he is an infectious patient. Patients who have undergone surgery, or have scheduled surgery.

(6)懷孕中或哺乳中的患者 (6) Patients who are pregnant or breastfeeding

(7)正在參加其他臨床試驗的患者 (7) Patients who are participating in other clinical trials

(8)試驗責任醫師或試驗分擔醫師判斷不適合作為本試驗對象的患者 (8) The trial responsible physician or trial sharing physician judges that the patient is unsuitable for cooperation as the subject of the trial

〔檢查方法〕 〔Inspection Method〕

檢查按照以下的步驟。 Check and follow the steps below.

(1)前一天晚上9點以後禁食,第二天上午8點半集合。 (1) Fasting after 9 pm the day before, and gathering at 8:30 am the next day.

(2)在75g葡萄糖負荷試驗開始前30分鐘,飲用以下的物質。 (2) Drink the following substances 30 minutes before the start of the 75g glucose load test.

A:什麼都不喝(無添加) A: Drink nothing (no addition)

B:將5g的D-阿洛酮糖溶解在50ml的水中得到的物質 B: A substance obtained by dissolving 5 g of D-psicose in 50 ml of water

C:甘露聚糖蔬果冰沙(含有82.5%的蒟蒻)+5g的D-阿洛酮糖 C: Mannan vegetable and fruit smoothie (containing 82.5% Konjac) + 5g of D-aloxulose

D:甘露聚糖蔬果冰沙(含有82.5%的蒟蒻) D: Mannan vegetable and fruit smoothie (containing 82.5% Konjac)

E:甘露聚糖蔬果冰沙(含有41.25%的蒟蒻) E: Mannan fruit and vegetable smoothie (contains 41.25% of Konjac)

(3)30分鐘後採血(0分鐘值) (3) Blood collection after 30 minutes (0 minute value)

(4)採血後立刻攝取加入了75gD-葡萄糖的飲料。 (4) Immediately after taking blood, drink 75g D-glucose.

(5)在其後30分鐘(30分鐘值)、60分鐘(60分鐘值)、120分鐘(120分鐘值)採血。 (5) Blood was collected at the following 30 minutes (30 minutes value), 60 minutes (60 minutes value), 120 minutes (120 minutes value).

(6)在分離血清後,測定血糖值。 (6) After separating the serum, measure the blood sugar level.

〔檢查結果的分析〕 [Analysis of inspection results]

參加者全員顯示出正常的糖耐量,因此,使用全部資料進行分析。 All participants showed normal glucose tolerance, so all data were used for analysis.

如圖1所示,對A~E的5組的採血結果進行比較研究,判定如下。 As shown in Figure 1, the blood collection results of the five groups A to E were compared and determined as follows.

‧A組(無添加組,僅為通常的OGTT)30分鐘值、60分鐘值、120分鐘值均比其他組高。 ‧The 30-minute value, 60-minute value and 120-minute value of group A (no additional group, only the usual OGTT) are higher than other groups.

‧B組(試驗前投予5g的D-阿洛酮糖)與A組相比有一定程度(5~10mg/dl)的血糖抑制效果。 ‧Compared with group A, group B (administered 5g of D-psicose prior to the test) had a certain degree of blood sugar inhibitory effect (5-10mg / dl).

‧C組(試驗前投予甘露聚糖蔬果冰沙〔含有82.5%的蒟蒻〕+5g的D-阿洛酮糖),整體血糖值的上升最低。 ‧C group (administration of mannan fruit and vegetable smoothie [containing 82.5% Konjac] + 5g of D-psicose) prior to the test showed the lowest increase in overall blood sugar level.

‧D組(試驗前單獨投予甘露聚糖蔬果冰沙〔含有82.5%的蒟蒻〕),與A組相比,30分鐘值與120分鐘值低。 ‧Group D (single mannan vegetable and fruit smoothie [containing 82.5% Konjac] before the test), compared with group A, the 30-minute value and the 120-minute value were lower.

‧E組(試驗前單獨投予甘露聚糖蔬果冰沙〔含有41.25%的蒟蒻〕),顯示出僅次於C組的降低血糖的作用。 ‧Group E (single mannan vegetable and fruit smoothie [containing 41.25% Konjac] before the test) showed the blood sugar lowering effect after Group C.

藉由該試驗,可認為D-阿洛酮糖與甘露聚糖蔬果冰沙均具有一定的抑制血糖上升的效果。 Through this test, it can be considered that both D-psicose and mannan vegetable and fruit smoothies have a certain effect of inhibiting the rise of blood sugar.

對於75g葡萄糖負荷試驗,A組、B組、D組係在上午實施,C組和E組在下午實施。另外,對於甘露聚糖蔬果冰沙,因為具有一定程度的卡路里,所以,基於全部在相同條件下對進行比較的目的,在各個測定中,藉由由30分鐘值、60分鐘值、120分鐘值減去 0分鐘值,對30分鐘、60分鐘、120分鐘與0分鐘比較的變化值進行比較研究。將其結果示於圖2。由此判定如下。 For the 75g glucose load test, Group A, Group B, and Group D were implemented in the morning, and Group C and Group E were implemented in the afternoon. In addition, mannan sugar vegetable and fruit smoothies have a certain degree of calories, so for the purpose of comparing all under the same conditions, in each measurement, by 30 minutes, 60 minutes, 120 minutes minus The value of 0 minutes is a comparative study of the change value comparing 30 minutes, 60 minutes, 120 minutes and 0 minutes. The results are shown in Figure 2. The judgment is as follows.

‧A組(無添加組、僅為通常的OGTT)30分鐘值、60分鐘值、120分鐘值均比其他組高。 ‧The 30-minute value, 60-minute value, and 120-minute value of group A (no added group, only the usual OGTT) are higher than other groups.

‧B組(試驗前投予5g的D-阿洛酮糖)與A組相比有一定程度(5~10mg/dl)的血糖抑制效果。 ‧Compared with group A, group B (administered 5g of D-psicose prior to the test) had a certain degree of blood sugar inhibitory effect (5-10mg / dl).

‧C組(試驗前投予甘露聚糖蔬果冰沙〔含有82.5%的蒟蒻〕+5g的D-阿洛酮糖),30分鐘值和60分鐘值中,血糖值上升得到最大抑制,顯示出比A組低12mg/dl、14mg/dl的值。整體血糖值的上升最低。 ‧C group (administration of mannan fruit and vegetable smoothie [containing 82.5% Konjac] + 5g of D-aloxulose) before the test, the increase in blood glucose level was suppressed to the greatest extent between the 30-minute value and the 60-minute value, showing Values of 12 mg / dl and 14 mg / dl were lower than those in group A. The overall rise in blood glucose is the lowest.

‧D組(試驗前單獨投予甘露聚糖蔬果冰沙〔含有82.5%的蒟蒻〕),30分鐘值、60分鐘值和120分鐘值均顯示出比A組低的值。 ‧Group D (mannan fruit and vegetable smoothie (containing 82.5% Konjac) alone before the test), the 30-minute value, 60-minute value and 120-minute value all showed lower values than group A.

‧E組(試驗前單獨投予甘露聚糖蔬果冰沙〔含有41.25%的蒟蒻〕),30分鐘值和60分鐘值與A組相比顯示出5~10mg/dl左右的抑制。 ‧E group (single mannan vegetable and fruit smoothie [containing 41.25% Konjac] before the test), the 30-minute value and the 60-minute value showed inhibition of about 5-10 mg / dl compared with group A.

〔考察結果〕 〔Examination results〕

藉由上述投予試驗,判定如下。 Based on the above-mentioned administration test, the judgment is as follows.

(1)藉由攝取5g的D-阿洛酮糖,觀察到了抑制血糖上升的效果。 (1) By ingesting 5 g of D-psicose, an effect of suppressing the increase in blood glucose was observed.

(2)即使單獨攝取甘露聚糖蔬果冰沙〔含有82.5%的蒟蒻〕、或單獨攝取甘露聚糖蔬果冰沙〔含有41.25%的蒟蒻〕,亦觀察到了一定的效果。 (2) Even if ingested mannan fruit and vegetable smoothie alone (contains 82.5% konjac), or ingested mannan fruit and fruit smoothie alone (contains 41.25% konjac), a certain effect was observed.

(3)甘露聚糖蔬果冰沙〔含有82.5%的蒟蒻〕+5g的D-阿洛酮糖的併用,抑制血糖上升的效果最大,顯示出可期待兩者的相加效果的可能性。 (3) The combined use of mannan fruit and vegetable smoothie [containing 82.5% Konjac] + 5g of D-psicose has the greatest effect of suppressing the rise of blood sugar, showing the possibility of expecting the combined effect of the two.

算出測定的數據的平均值,並且將加上數據之起始點(將經過時間 0分鐘的血糖值設為0)的曲線圖示於圖2。根據圖2所示試驗結果可知,藉由飲用甘露聚糖蔬果冰沙,葡萄糖負荷試驗中的血糖值的上升被抑制,但藉由同時飲用稀有糖,可獲得單獨飲用時無法獲得的優異的抑制血糖值上升的效果。 Calculate the average value of the measured data, and add the starting point of the data (the elapsed time The graph of the blood glucose level at 0 minutes is set to 0) in FIG. 2. From the test results shown in Figure 2, it can be seen that by drinking mannan fruit and vegetable smoothies, the increase in blood glucose level in the glucose load test is suppressed, but by simultaneously drinking rare sugar, excellent suppression that cannot be obtained when consumed alone can be obtained The effect of rising blood sugar levels.

亦即,實際驗證了本發明的含有微細粒狀蒟蒻與稀有糖的蔬果冰沙式飲食品具有抑制血糖值上升的效果。另外,根據其他的試驗結果判定,抑制血糖值上升的效果在飲用後持續約一天的時間。 That is, it has actually been verified that the vegetable and fruit smoothie-type food and beverage containing fine granular Konjac and rare sugar of the present invention has an effect of suppressing the increase in blood sugar level. In addition, according to other test results, the effect of suppressing the increase in blood glucose level continued for about one day after drinking.

在以下的實施例中,列舉包括加入了稀有糖的蒟蒻的其他的飲食品的例子,此等飲食品亦可發揮與上述蔬果冰沙同樣的生理效果。 In the following examples, examples of other foods and beverages including Konjac added with rare sugar are cited. These foods and beverages can also exert the same physiological effects as the above-mentioned vegetable and fruit smoothies.

(實施例1) (Example 1) 〔沙拉用蒟蒻的製造1〕 [Manufacture of Konjac for Salad 1]

將蘋果酸、乳酸鈣、抗壞血酸鈉等的酸味料與水、以及含稀有糖的糖漿混合,製作表4所示的pH為3.0的調味液,將該調味液300g與成形為40×15×2mm的板狀蒟蒻1kg混合後,放入高速攪拌裝置中混合5秒鐘。將其與調味液一起放入聚丙烯製容器中以120℃加熱15分鐘。製造出的板狀加工食品的pH為3.7。該產品中滲透有含稀有糖的調味液。 A sour sauce such as malic acid, calcium lactate, sodium ascorbate, etc. is mixed with water and a syrup containing rare sugar to prepare a seasoning liquid with a pH of 3.0 shown in Table 4, and 300 g of the seasoning liquid is formed into 40 × 15 × 2 mm After mixing 1kg of the plate-like konjac, it was placed in a high-speed stirring device and mixed for 5 seconds. This was put in a polypropylene container together with the seasoning liquid and heated at 120 ° C for 15 minutes. The pH of the manufactured plate-shaped processed food was 3.7. The product is infiltrated with flavoring liquid containing rare sugar.

將該板狀蒟蒻加工食品直接或者切斷成任意形狀後添加到蔬菜切塊中製作蔬菜沙拉。 The plate-shaped konjac processed food is directly or cut into an arbitrary shape, and then added to vegetable cut pieces to make a vegetable salad.

[表4]3色沙拉蒟蒻調味液配方 [Table 4] 3-color salad Konjac seasoning formula

(實施例2) (Example 2) 〔沙拉用蒟蒻的製造2〕 [Manufacture of Konjac for Salad 2]

在10kg的D-阿洛糖與3kg的蒟蒻粉中添加100L熱水(40~50℃),緩慢地混合、攪拌製成糊狀,放置2小時後,在蒟蒻糊中添加1.7%的氫氧化鈣液10L,進行混練使其變得均勻,在使其凝膠化的同時將其放入模箱中,以沸騰的熱水使其加熱凝固,製造含有約9重量%的D-阿洛糖的凝固蒟蒻。然後,將凝固的蒟蒻切斷為厚2mm、寬15mm、長40mm的長方形板狀,得到多個板狀蒟蒻。將該板狀蒟蒻與調味液一起收納在容器中,在溫度120℃進行20分鐘的操作。另外,在製造凝固蒟蒻時,藉由添加紅色、黃色、綠色等的各種色素,形成為進行了色彩不同著色的加入了稀有糖的板狀蒟蒻。將如此製造出的色彩不同的板狀蒟蒻適當混合,與調味液一起收納在聚丙烯容器中,進行加熱處理。 Add 100L of hot water (40 ~ 50 ℃) to 10kg of D-allose and 3kg of Konjac powder, slowly mix and stir to make a paste. After standing for 2 hours, add 1.7% hydroxide to Konjac paste Calcium liquid 10L, knead to make it uniform, put it in a mold box while gelling it, heat it with boiling hot water to solidify it, and manufacture D-allose containing about 9% by weight Solidified konjac. Then, the solidified konjac was cut into a rectangular plate shape with a thickness of 2 mm, a width of 15 mm, and a length of 40 mm to obtain a plurality of plate-shaped konjac. This plate-like konjac was stored in a container together with the seasoning liquid, and the operation was performed at a temperature of 120 ° C for 20 minutes. In addition, when manufacturing solidified konjac, by adding various pigments such as red, yellow, green, etc., a plate-like konjac with rare sugar added and colored in different colors is formed. The plate-shaped konjac with different colors produced in this way is appropriately mixed, stored in a polypropylene container together with the seasoning liquid, and subjected to heat treatment.

調味液的成分為肌苷酸鈉0.1%、麩胺酸鈉1.0%、琥珀酸鈉0.4%、還原糖飴20.0%、食鹽2.3%、蘋果酸1.0%,其pH值為3.7。 The ingredients of the seasoning liquid are sodium inosinate 0.1%, sodium glutamate 1.0%, sodium succinate 0.4%, reduced sugar syrup 20.0%, table salt 2.3%, malic acid 1.0%, and its pH value is 3.7.

(實施例3) (Example 3) 〔沙拉用蒟蒻的製造3〕 [Manufacture of Konjac for Salad 3]

在5kg的D-阿洛酮糖和3kg的蒟蒻粉中添加100L熱水(40~50℃),緩慢地混合、攪拌製成糊狀,放置2小時後,在蒟蒻糊中添加1.7%的氫氧化鈣液10L,進行混練使其變得均勻,在使其凝膠化的同時將其放入模箱中,以沸騰的熱水使其加熱凝固,製造含有約4.5重量%的D-阿洛酮糖的強固蒟蒻。然後,將凝固的蒟蒻切斷為厚2mm、寬15mm、長40mm的長方形板狀,得到多個板狀蒟蒻。將5kg的該板狀蒟蒻與10kg的酸性調味液在由密封的真空斜軸捏合機構成的真空罐中混合,一邊攪拌、一邊在真空度0.07~0.08Mpa、溫度70℃進行1小時的操作。酸性調味液的成分為肌苷酸鈉0.1%、麩胺酸鈉1.0%、琥珀酸鈉0.4%、還原糖飴20.0%、食鹽2.3%、蘋果酸1.0%,其pH值為3.7。 Add 100L of hot water (40 ~ 50 ℃) to 5kg of D-psicose and 3kg of Konjac powder, slowly mix and stir to make a paste. After standing for 2 hours, add 1.7% hydrogen to Konjac paste Mix 10L of calcium oxide solution to make it uniform, and place it in a mold box while gelatinizing it, heat it with boiling hot water to solidify it, and manufacture D-allo containing about 4.5% by weight The strong konjac of ketose. Then, the solidified konjac was cut into a rectangular plate shape with a thickness of 2 mm, a width of 15 mm, and a length of 40 mm to obtain a plurality of plate-shaped konjac. 5 kg of this plate-like konjac and 10 kg of acidic seasoning liquid were mixed in a vacuum tank composed of a sealed vacuum inclined shaft kneader, and the operation was performed at a vacuum degree of 0.07 to 0.08 MPa and a temperature of 70 ° C. for 1 hour while stirring. The composition of the acidic seasoning liquid is sodium inosinate 0.1%, sodium glutamate 1.0%, sodium succinate 0.4%, reduced sugar syrup 20.0%, table salt 2.3%, malic acid 1.0%, and its pH value is 3.7.

另外,在製造凝固蒟蒻時,藉由添加紅色、黃色、綠色等的各種色素,製造色彩不同的著色板狀蒟蒻,與上述同樣地在調味液中進行加熱處理。 In addition, when producing solidified Konjac, by adding various pigments such as red, yellow, green, etc., colored plate-like Konjac with different colors is produced, and heat treatment is performed in the seasoning liquid in the same manner as above.

將如此製造出的色彩不同的板狀蒟蒻適當混合,與調味液一起收納在聚丙烯容器中。 The plate-shaped konjac with different colors produced in this way is appropriately mixed and stored in a polypropylene container together with the seasoning liquid.

(實施例4) (Example 4) 〔醬漬鮪魚蓋飯用蒟蒻的製造〕 [Manufacture of konjac for pickled tuna rice bowl]

製造具有與醬漬鮪魚蓋飯用的鮪魚切片同樣的味道與食感的蒟蒻片。 Konjac slices are produced with the same taste and texture as the tuna slices for pickled tuna rice bowl.

在D-阿洛酮糖5kg、蒟蒻粉3kg與著色料中添加100L熱水(40~50℃),緩慢地混合、攪拌製成糊狀,放置2小時後,在蒟蒻糊中添加1.7%的氫氧化鈣液10L,進行混練使得變得均勻,在使其凝膠化的同時將 其放入模箱中,以沸騰的熱水使其加熱凝固,製造凝固蒟蒻。然後,由凝固蒟蒻成形為厚7mm、寬30mm、長45mm,且從距其橫端部20mm的中央附近傾斜地在縱方向上以厚度減少的方式切斷,成形為長方形的板狀蒟蒻。將該板狀蒟蒻的截面形狀示於圖5。將10片該板狀蒟蒻與表5所示的調味液一起封入在120×150mm的聚丙烯容器內,在120℃加熱15分鐘,由此製造醬漬鮪魚蓋飯用蒟蒻。 Add 100L of hot water (40 ~ 50 ℃) to 5kg of D-psicose, 3kg of konjac powder and coloring material, slowly mix and stir to make a paste. After standing for 2 hours, add 1.7% to konjac paste Calcium hydroxide solution 10L, after mixing to make it uniform, while making it gel It is placed in a mold box and heated and solidified with boiling hot water to make solidified konjac. Then, the solidified konjac was formed into a 7 mm thick, 30 mm wide and 45 mm long, and cut obliquely in the longitudinal direction from the vicinity of the center of 20 mm from the lateral end to decrease the thickness in the longitudinal direction to form a rectangular plate-like konjac. The cross-sectional shape of this plate-like konjac is shown in FIG. 5. Ten pieces of this plate-shaped konjac were enclosed in a polypropylene container of 120 × 150 mm together with the seasoning liquid shown in Table 5, and heated at 120 ° C. for 15 minutes, thereby preparing konjac for pickled tuna rice bowl.

此蒟蒻成形品係藉由使厚度從縱方向的約中間部起向端部傾斜地減少,能夠呈現與鮪魚切片同樣的食感。例如,鮪魚切片式的蒟蒻較佳係呈厚5~8mm、縱40~50mm、橫25~35mm的板狀,使厚度從其中央部附近起在縱方向上依次減少。通過感官實驗,得知此形狀具有鮪魚的食感、感覺不到蒟蒻的食感的感官結果。 This Konjac shaped product reduces the thickness from approximately the middle of the longitudinal direction to the end, and can exhibit the same taste as the tuna slices. For example, konjac sliced tuna is preferably in the form of a plate with a thickness of 5 to 8 mm, a length of 40 to 50 mm, and a width of 25 to 35 mm, so that the thickness sequentially decreases from the vicinity of the center portion in the longitudinal direction. Through a sensory experiment, it was found that this shape has a sensory result of tuna fish's sense of eating and no sense of the taste of Konjac.

(實施例5) (Example 5) 〔似魚子醬式蒟蒻的製造〕 [Manufacture of Konjac-like caviar]

在D-阿洛酮糖5kg、蒟蒻粉3kg與黑色著色料的混合物中添加100L熱水(40~50℃),緩慢地混合、攪拌製成糊狀,放置2小時後,在蒟蒻糊中添加1.7%的氫氧化鈣液10L,進行混練使其勻,在使其凝膠化的同時從多個細孔擠出,藉由在細孔出口切斷而形成為微粒狀,以沸騰的熱水使其加熱凝固,製造黑色的凝固蒟蒻粒。 Add 100L of hot water (40 ~ 50 ℃) to the mixture of 5kg of D-psicose, 3kg of Konjac powder and black coloring material, slowly mix and stir to make a paste. After 2 hours, add it to Konjac paste 10L of 1.7% calcium hydroxide solution, kneaded to make it uniform, extruded from multiple pores while gelatinizing, formed into fine particles by cutting at the outlet of the pores, with boiling hot water It is heated and solidified to produce black solidified Konjac grains.

將此蒟蒻顆粒與表6中記載的調味液一起封入在120×150mm的聚丙烯容器內,在120℃加熱15分鐘,由此製造似魚子醬式蒟蒻粒。將封入的似魚子醬式蒟蒻粒的外觀示於圖6。 The Konjac granules were sealed in a polypropylene container of 120 × 150 mm together with the seasoning liquid described in Table 6, and heated at 120 ° C. for 15 minutes, thereby producing caviar-like Konjac granules. Fig. 6 shows the appearance of the enclosed caviar-like konjac grains.

(產業上的可利用性) (Industry availability)

本發明的蒟蒻加工飲食品,係藉由飲食,發揮抑制血糖值上升的效果。可較自由地變更其風味、食感等,因此,可應對各種嗜好,能夠長期持續攝取。藉由此等特徵,本發明可提供對於糖尿病患者等以血糖值上升為原因的疾病的預防或治療有用的各種蒟蒻加工飲食品。 The Konjac processed food and drink of the present invention exerts the effect of suppressing the increase in blood sugar level through diet. It can change its flavor, food feel, etc. more freely, so it can cope with various hobbies and can continue to ingest for a long time. With these characteristics, the present invention can provide various Konjac processed foods and drinks that are useful for the prevention or treatment of diseases such as diabetic patients whose blood sugar level rises.

Claims (10)

一種具有抑制血糖值上升的效果的蒟蒻加工飲食品,其特徵在於:含有pH在2.5~7.4的範圍的蒟蒻及稀有糖作為有效成分,稀有糖係至少含有D-阿洛酮糖及/或D-阿洛糖。A processed konjac processed food and drink having an effect of suppressing the increase in blood sugar level, characterized in that it contains konjac and rare sugars having a pH in the range of 2.5 to 7.4 as active ingredients, and the rare sugar system contains at least D-aloxulose and / or D -Allose. 如申請專利範圍第1項之具有抑制血糖值上升的效果的蒟蒻加工飲食品,其中,pH在2.5~7.4的範圍的蒟蒻係粒徑為0.1~3.0mm的微細粒狀蒟蒻。For example, the Konjac processed foods and beverages having the effect of suppressing the rise of blood sugar level as claimed in item 1 of the patent scope, wherein the Konjac series of fine granular Konjac having a pH in the range of 2.5 to 7.4 is 0.1 to 3.0 mm. 如申請專利範圍第1或2項之具有抑制血糖值上升的效果的蒟蒻加工飲食品,其中,蒟蒻加工飲食品為蔬果冰沙(smoothie)式飲食品。For example, the Konjac processed foods and beverages having the effect of suppressing the rise of blood sugar level according to item 1 or 2 of the patent application range, wherein the Konjac processed foods and beverages are smoothie-type foods and drinks. 如申請專利範圍第1或2項之具有抑制血糖值上升的效果的蒟蒻加工飲食品,其中,pH在2.5~7.4的範圍的蒟蒻係粒徑為0.1~3.0mm的微細粒狀蒟蒻,係藉由混合至少可中和該微細粒狀蒟蒻中含有的鹼份的量的酸性素材並進行加熱處理而製造。For example, the Konjac processed foods and beverages with the effect of inhibiting the rise of blood sugar level in the patent application scope 1 or 2, wherein the Konjac series of fine granular Konjac with a pH in the range of 2.5 ~ 7.4 is 0.1 ~ 3.0mm, borrowed It is produced by mixing an acidic material capable of neutralizing at least the amount of alkali contained in the fine granular Konjac and performing heat treatment. 如申請專利範圍第1或2項之具有抑制血糖值上升的效果的蒟蒻加工飲食品,其中,pH在2.5~7.4的範圍的蒟蒻係粒徑為0.1~3.0mm的微細粒狀蒟蒻,係藉由混合至少可中和該微細粒狀蒟蒻中含有的鹼份的量的酸性素材並進行加熱處理而製造;該酸性素材係包含選自調味料、增稠物質、果汁、將果實及/或蔬菜破碎並過濾而得到的蔬果泥(puree)、果實糊、蔬菜糊中的1種以上。For example, the Konjac processed foods and beverages with the effect of inhibiting the rise of blood sugar level in the patent application scope 1 or 2, wherein the Konjac series of fine granular Konjac with a pH in the range of 2.5 ~ 7.4 is 0.1 ~ 3.0mm, borrowed It is manufactured by mixing and heating an acidic material that can neutralize at least the amount of alkali contained in the fine granular Konjac; the acidic material contains a material selected from the group consisting of seasonings, thickening substances, fruit juices, fruits and / or vegetables One or more kinds of puree, fruit paste, and vegetable paste obtained by crushing and filtering. 如申請專利範圍第1或2項之具有抑制血糖值上升的效果的蒟蒻加工飲食品,其中,pH在2.5~7.4的範圍的蒟蒻係粒徑為0.1~3.0mm的微細粒狀蒟蒻,係藉由混合至少可中和該微細粒狀蒟蒻中含有的鹼份的量的酸性素材並進行加熱處理而製造;該酸性素材係包含選自調味料、增稠物質、果汁、將果實及/或蔬菜破碎並過濾而得到的蔬果泥(puree)、果實糊、蔬菜糊中的1種以上;該酸性素材係包含與鹼中和的選自葡糖酸、檸檬酸及乳酸中的1種以上的酸味料。For example, the Konjac processed foods and beverages with the effect of inhibiting the rise of blood sugar level in the patent application scope 1 or 2, wherein the Konjac series of fine granular Konjac with a pH in the range of 2.5 ~ 7.4 is 0.1 ~ 3.0mm, borrowed It is manufactured by mixing and heating an acidic material that can neutralize at least the amount of alkali contained in the fine granular Konjac; the acidic material contains a material selected from the group consisting of seasonings, thickening substances, fruit juices, fruits and / or vegetables One or more kinds of puree, fruit paste, and vegetable paste obtained by crushing and filtering; the acidic material contains one or more kinds of sour taste selected from gluconic acid, citric acid, and lactic acid neutralized with alkali material. 如申請專利範圍第1或2項之具有抑制血糖值上升的效果的蒟蒻加工飲食品,其中,蒟蒻加工飲食品係與蒟蒻一起攝取用於抑制血糖值上升之一日用量為0.3~50g/日的稀有糖。For example, the Konjac processed foods and beverages with the effect of inhibiting the rise of blood sugar level as claimed in item 1 or 2 of the patent application range, in which the Konjac processed foods and beverages are taken together with Konjac to suppress the rise of blood sugar level, the daily dosage is 0.3 ~ 50g / day Rare sugar. 如申請專利範圍第1或2項之具有抑制血糖值上升的效果的蒟蒻加工飲食品,其係用於以相對於飲食品整體含有蒟蒻40~95重量%及稀有糖0.1~10.0重量%的形態,與蒟蒻一起攝取稀有糖的一日用量者。For example, the Konjac processed foods and beverages with the effect of suppressing the rise of blood sugar level according to item 1 or 2 of the patent application are used in the form of containing Konjac 40 to 95% by weight and rare sugar 0.1 to 10.0% by weight relative to the entire food and beverage , Daily intake of rare sugar together with Konjac. 如申請專利範圍第1或2項之具有抑制血糖值上升的效果的蒟蒻加工飲食品,其係用於依一日一次以上與蒟蒻一起攝取稀有糖的一日用量者。For example, the Konjac processed foods and beverages with the effect of inhibiting the rise of blood sugar level according to item 1 or 2 of the patent scope are used for daily intake of rare sugar together with Konjac more than once a day. 一種容器裝飲食品,其特徵在於:收納有申請專利範圍第1或2項之具有抑制血糖值上升的效果的蒟蒻加工飲食品;其係在一容器中,與蒟蒻一起含有屬於一日所需攝取量的0.3~50g的稀有糖。A food and beverage packaged in a container, characterized in that it contains a processed konjac processed food and beverage with the effect of suppressing the rise of blood sugar level according to item 1 or 2 of the patent scope; it is contained in a container together with konjac for one day The intake of 0.3-50g of rare sugar.
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010018528A (en) * 2008-07-09 2010-01-28 Matsutani Chem Ind Ltd Biological function improving composition comprising dietary fiber and rare sugar
JP2011130776A (en) * 2011-03-17 2011-07-07 Food Business Supply:Kk Konnyaku containing raw jerusalem artichoke, cooked rice like grain made of konnyaku containing raw jerusalem artichoke, and method for producing them
JP2012147770A (en) * 2010-12-28 2012-08-09 Haisukii Shokuhin Kogyo Kk Method for producing ground devil's tongue food

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010018528A (en) * 2008-07-09 2010-01-28 Matsutani Chem Ind Ltd Biological function improving composition comprising dietary fiber and rare sugar
JP2012147770A (en) * 2010-12-28 2012-08-09 Haisukii Shokuhin Kogyo Kk Method for producing ground devil's tongue food
JP2011130776A (en) * 2011-03-17 2011-07-07 Food Business Supply:Kk Konnyaku containing raw jerusalem artichoke, cooked rice like grain made of konnyaku containing raw jerusalem artichoke, and method for producing them

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