TW201325466A - Powdered brown alga and use for same - Google Patents

Powdered brown alga and use for same Download PDF

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Publication number
TW201325466A
TW201325466A TW101137572A TW101137572A TW201325466A TW 201325466 A TW201325466 A TW 201325466A TW 101137572 A TW101137572 A TW 101137572A TW 101137572 A TW101137572 A TW 101137572A TW 201325466 A TW201325466 A TW 201325466A
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Taiwan
Prior art keywords
food
brown algae
weight
powdered
powder
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TW101137572A
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Chinese (zh)
Inventor
Naoki Kikuchi
Etsuko Isaji
Tohru Yoshioka
Keiko Matsui
Ryoji Otsubo
Yasunari Ogiu
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Kikkoman Biochemifa Company
Kikkoman Soyfoods Company
Kikkoman Corp
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Publication of TW201325466A publication Critical patent/TW201325466A/en

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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/52Adding ingredients
    • A23L2/66Proteins
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L17/00Food-from-the-sea products; Fish products; Fish meal; Fish-egg substitutes; Preparation or treatment thereof
    • A23L17/60Edible seaweed
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/52Adding ingredients
    • A23L2/62Clouding agents; Agents to improve the cloud-stability

Abstract

The present invention relates to a powdered brown alga that includes a water-soluble algin and an insoluble component, with a ratio by weight of the water-soluble algin to the insoluble component of 1:0.05 to 1:4. The present invention also relates to a suspending agent using the powdered brown alga, a solution containing precipitate particles using the suspending agent, and a suspension method; and a food-product improvement agent using the powdered brown alga, a food product using the food-improvement agent, and a method for manufacturing the food product.

Description

粉末褐藻及其利用 Powder brown algae and its utilization

本發明係關於一種粉末褐藻。又,本發明亦關於使用粉末褐藻之沈澱防止劑、使用上述沈澱防止劑之含沈澱粒子之溶液、沈澱防止方法、使用粉末褐藻之食品改良劑(尤其是麵粉食品改良劑及食品之增黏凝膠化改良劑)、使用上述食品改良劑之食品及食品之製造方法。 The present invention relates to a powdered brown alga. Further, the present invention relates to a precipitating agent for preventing the use of powdered brown algae, a solution containing precipitated particles using the above-mentioned precipitation preventing agent, a method for preventing precipitation, a food improving agent using powdered brown algae (especially a flour food improving agent, and a food additive) A gelation improver), a food and a food manufacturing method using the above food improver.

自古以來食用之海藻類不僅將其本身烹飪或加工而食用,亦以追加方式添加至海藻以外之食品中而利用。例如,人們常常將海藻乾燥或加工而製成粉末海藻,將其加入至「香松」、「味噌湯」、「湯」、「調味料」、「甜不辣」、「果汁」中,或捏合至「麵條」、「麵包」、「休閒點心」中而食用。於此種情形時,粉末海藻多用於對該等食品賦予海藻之較佳之風味或獨特之色調,或追加海藻中所含之豐富之礦物質成分、食物纖維及功能性成分(褐藻糖膠等)。 Seaweeds that have been eaten since ancient times are not only eaten and processed by themselves, but are also added to foods other than seaweed for use. For example, people often dry or process seaweed to make powdered seaweed, and add it to "sweet pine", "Miso soup", "soup", "flavoring", "sweet and spicy", "juice", or It is kneaded into "noodles", "bread" and "leisure snacks" and eaten. In this case, the powdered seaweed is often used to impart a better flavor or unique color to the seaweed to the food, or to add the rich mineral components, dietary fiber and functional ingredients (fucoidan, etc.) contained in the seaweed. .

近年來,業界提出有以增黏穩定或食感改良為目的而將此種粉末海藻用於海藻以外之食品中之技術。例如,可列舉改良「麵條」之食感(專利文獻1及2)之技術,改善「粉絲」之彈性(專利文獻3)之技術,改良「麵包」之食感(專利文獻1及4)之技術,對「調味品類食品」或「調味料」等賦予黏性(專利文獻5及6)之技術,改良「漢堡」、「糯米丸子串」、「巴伐露斯」、「霜淇淋」等之食感(專利 文獻7)之技術。 In recent years, the industry has proposed a technique for applying such powdered seaweed to foods other than seaweed for the purpose of improving viscosity stability or improving food texture. For example, the technique of improving the taste of "noodles" (Patent Documents 1 and 2), improving the flexibility of "fans" (Patent Document 3), and improving the texture of "bread" (Patent Documents 1 and 4) Technology, which provides adhesion to "flavored foods" or "flavorings" (Patent Documents 5 and 6), and improves "Hamburg", "Glutinous Rice Balls", "Bavarus", "Cream Cream" Food sense (patent Document 7).

又,為了賦予海藻所含之豐富之礦物質成分、食物纖維及功能性成分(褐藻糖膠等)而將海藻用於海藻以外之食品或化妝品之情形時,亦有較多情形不宜賦予海藻之風味或色調。因此,關於海藻或來自海藻之提取物,為了將其等用於他物,於食品用途及化妝品用途方面均提出有儘量減輕其氣味及顏色之技術。於食品用途方面,例如可列舉:以將海蘿原藻水洗、漂白並乾燥而獲得之海蘿乾燥物為主體之食品添加用海蘿(專利文獻7);以包括於特定溫度下將藻類原料加熱一定時間之加熱步驟、與以特定溫度之冷水或溫水提取褐藻糖膠之提取步驟為特徵的褐藻糖膠萃取物之製造方法(專利文獻8)等。於化妝品用途方面,可列舉海藻提取物之純化方法等(專利文獻9),該方法之特徵在於對海藻提取物進行活性碳處理及陽離子交換吸附處理。 In addition, when seaweed is used for foods or cosmetics other than seaweed in order to impart rich mineral components, dietary fibers, and functional ingredients (fucoidan, etc.) contained in seaweed, there are many cases where it is not appropriate to impart seaweed. Flavor or color. Therefore, regarding seaweed or an extract derived from seaweed, in order to use it for other purposes, techniques for minimizing odor and color have been proposed for food use and cosmetic use. For the use of the food, for example, a seaweed for food addition mainly comprising a dry dried kelp obtained by washing, bleaching and drying the seaweed (PTL 7); and the algae raw material is included at a specific temperature. A heating step of heating for a certain period of time, a method for producing a fucoidan extract characterized by an extraction step of extracting fucoidan with a specific temperature of cold water or warm water (Patent Document 8), and the like. For the purpose of cosmetics, a method for purifying a seaweed extract or the like (Patent Document 9), which is characterized in that the seaweed extract is subjected to activated carbon treatment and cation exchange adsorption treatment.

又,亦提出有以食用海藻本身為目的,同時設法減輕海藻味以更易於食用、被更多人喜好之技術。例如可列舉:藉由使裙帶菜與鹼金屬鹽及酒糟進行接觸處理而減輕海藻味之「裙帶菜粉末」(專利文獻10);使海藻類與茶提取物接觸、繼而將海藻類與茶提取物分離而獲得海藻之「海藻類之脫臭方法」(專利文獻11);以10%~54%之含水乙醇清洗食用海藻而獲得之「低鹽、低臭之裙帶菜、昆布、鹿尾菜、黑海帶、海蘊等海藻」(專利文獻12)等。 In addition, there is also a technique for eating seaweed itself, and at the same time trying to reduce the taste of seaweed to make it easier to eat and more popular. For example, the "Wakame powder" which reduces the seaweed flavor by contacting the wakame with the alkali metal salt and the vinasse (Patent Document 10); contacting the seaweed with the tea extract, and then extracting the seaweed and the tea "Deodorization method of seaweed" obtained by separating the seaweed (Patent Document 11); "low-salt, low-odor wakame, kelp, deer, black" obtained by washing edible seaweed with 10% to 54% of aqueous ethanol Seaweed such as kelp and seaweed (Patent Document 12).

另一方面,提出有為了使各種食品儘量「美味」、「廉價」或「可簡便利用」而進行改良並供於消費者的各種技 術,亦有大量實用化者。此種改良食品之技術中,作為相對廉價且可簡單利用、可根據目的而簡易區分使用者,廣泛利用食品添加物。藉由將食品添加物應用於食品中,將食品改良以使其更「美味」、「廉價」或「可簡便利用」,此對消費者而言為較大之優點,業界基於此種觀點進行有各種食品添加物於食品中之應用研究。 On the other hand, there are various techniques for improving and providing consumers with various foods as "delicious", "cheap" or "easy to use" as possible. There are also a lot of practical people. In such a technique for improving food, it is relatively inexpensive and can be easily used, and the user can be easily distinguished according to the purpose, and the food additive is widely used. By applying food additives to foods, foods are modified to make them more "delicious," "cheap," or "easy to use," which is a big advantage for consumers, and the industry is based on this view. There are various food additives for application research in food.

然而,近年來隨著人們對安全食品之關注提高,有時消費者認為食品添加物(可分為源自天然物質且因有實際使用成果而被認可之添加物即「現有添加物」,與作為化學合成品之添加物而被認可之「指定添加物」兩種)之使用及使用其之食品不佳。 However, in recent years, as people pay more attention to safe foods, consumers sometimes think that food additives (which can be classified into natural substances and approved by actual use results are "existing additives"), and The use of "specified additives" which are recognized as additives for chemical synthetic products and the use of the foods thereof are not good.

例如,小麥在世界範圍內被廣泛食用,除以由小麥而獲得之麵粉本身作為直接料理之材料以外,亦以麵包類、麵條類、點心類、混合粉類、包子類等使用或加工麵粉而成之食品(麵粉食品)之形式被消費。麵粉食品隨處可見,可想而知其需求非常大。作為目前於麵粉食品中用作食品添加物者,可列舉微晶纖維素、果膠、海藻酸鈉、海藻酸酯、鹿角菜膠、卡德蘭膠、古亞膠、三仙膠等。 For example, wheat is widely used in the world, and the flour itself obtained from wheat is used as a material for direct cooking, and flour is also used or processed in bread, noodles, snacks, mixed powders, buns, and the like. The form of Chengzhi Food (Flour Food) is consumed. Flour food can be seen everywhere, and it can be imagined that its demand is very large. As a food additive currently used in flour foods, microcrystalline cellulose, pectin, sodium alginate, alginic acid ester, carrageenan, cadmium gum, guar gum, and celery gum can be cited.

又,作為其他例子,廣泛進行有藉由將食品或其一部分增黏凝膠化而改良食品之食感等嘗試。藉由增黏凝膠化改良而獲得之食品各種各樣,不僅有果凍或布丁等膠狀食品,例如乳酪等乳製品、香腸等畜肉製品等亦作為在製造過程中藉由將其一部分增黏凝膠化以改良食感等之食品而為人所知。作為用作有助於增黏凝膠化之食品添加物者, 可列舉微晶纖維素、果膠、海藻酸鈉、海藻酸酯、鹿角菜膠、卡德蘭膠、古亞膠、三仙膠等。 Further, as another example, attempts have been made to improve the food texture of foods by thickening and gelling foods or a part thereof. The foods obtained by the improvement of the viscosity-increasing gelation are not only jelly-like foods such as jelly or pudding, but also dairy products such as cheese, sausages and other meat products, etc., as a part of the manufacturing process is also viscous. Gelation is known for improving foods such as food texture. As a food additive that helps to increase the viscosity of gelatinization, Examples thereof include microcrystalline cellulose, pectin, sodium alginate, alginic acid ester, carrageenan, cadmium gum, guar gum, and sanxian gum.

不使用此種食品添加物之食品有如下較大之問題:未發揮食品添加物之優點,價格高,味道、氣味、香味、外觀、色彩、食感較差,味道、氣味、香味、外觀、色彩、食感等隨時間經過之變化較大,難以加工等。因此,不使用此種食品添加物之食品亦存在可供作食品之原材料之種類(例如對於麵粉食品而言,為小麥之品種等)、食品之種類、提供地點、提供時間、提供方法及製造方法等大幅度受限的問題。 Foods that do not use such food additives have the following major problems: they do not exhibit the advantages of food additives, high prices, taste, smell, aroma, appearance, color, poor food taste, taste, smell, aroma, appearance, color The sense of food, etc. vary greatly with time, and it is difficult to process. Therefore, foods that do not use such food additives also have types of raw materials that can be used as foods (for example, wheat varieties for flour foods), types of foods, locations, time of supply, methods of supply, and manufacture. Methods and other issues that are greatly limited.

為了解決此種問題,提出有於食品中使用具有類似效果之「食品」作為改良劑代替「食品添加物」之技術。其中,作為使用「海藻」來改良食品之嘗試,例如對於麵粉食品,提出有以下技術:將以水等將海蘿溶膠化或清洗而獲得者乾燥,將其加入至「麵包」中而改良食感之技術(參照專利文獻1及4);使將海蘿原藻水洗、漂白並乾燥而獲得之海蘿乾燥物與糊精混合,調配至吐司麵包中,使生麵團之紋理、甜味及保存時間變佳之技術(參照專利文獻7);以及將以水等將海蘿溶膠化並乾燥而獲得者(參照專利文獻1)、直接粉碎麒麟菜而獲得之粉末(參照專利文獻13)、直接粉碎裙帶菜而獲得之粉末及糊劑(參照專利文獻14)、直接粉碎裙帶菜及腔昆布而獲得之粉末(參照專利文獻15)或直接粉碎昆布而獲得之粉末(參照專利文獻16)加入至「麵條」中改良食感之技術等。 In order to solve such a problem, a technique in which a "food" having a similar effect is used as a modifier in a food instead of a "food additive" has been proposed. In an attempt to improve the food using "seaweed", for example, in the case of a flour food, there is a technique in which a person who has been solified or washed with water or the like is dried, and added to "bread" to improve the food. Technology of sensation (refer to Patent Documents 1 and 4); the dried hawthorn obtained by washing, bleaching and drying the seaweed, and the dextrin are mixed with the dextrin to prepare the texture and sweetness of the dough. And a technique in which the storage time is improved (refer to Patent Document 7), and a powder obtained by sol-geling and drying the sea ale with water or the like (see Patent Document 1) and directly pulverizing Eucheuma (refer to Patent Document 13). Powders and pastes obtained by directly pulverizing wakame (see Patent Document 14), powders obtained by directly pulverizing wakame and kelp (see Patent Document 15), or powders obtained by directly pulverizing kelp (refer to Patent Document 16) To the technique of improving the sense of food in "noodles".

又,作為使用「海藻」並藉由增黏凝膠化等而改良食品之嘗試,例如提出有以下技術:以微生物學方法分解海藻而獲得之可用於飲料食品之均勻且懸浮性/浮游性優異的「海藻分解物」(例如參照專利文獻17~18);將自龍鬚菜熱水提取而獲得之多糖體添加至調味品類或乳製品等中而改良食感之技術(例如參照專利文獻19);為了獲得昆布中所含之海藻酸帶來之食用肉彼此之黏合效果及高湯帶來之風味提昇效果,於含有以水泡發昆布而獲得之高湯之泡菜液中浸漬混入昆布之端肉的技術(例如,參照專利文獻20);對乾燥狀態之海藻進行碳酸鈉或消石灰處理後,以超微粉碎機粉碎,添加至香腸中而提高凝膠強度或食感之技術(例如參照專利文獻21);向在水中膨潤之海藻類中添加縮合磷酸鹽並攪拌,向所獲得之糊劑中添加有機酸、鈣鹽或乳成分而獲得食用凝膠之技術(例如參照專利文獻22);對海藻浸漬液進行酵素處理後,藉由鈣離子溶液使其凝固為膠狀之技術(例如參照專利文獻23);由含瓊脂之海藻之溶出成分與含海藻酸之海藻之溶出成分製作燕窩之類的食品的技術(例如參照專利文獻24)等。 In addition, as an attempt to improve foods by using "seaweed" and by gelation or the like, for example, there is proposed a technique for decomposing seaweed by microbiological methods, which is excellent in uniformity and suspension/floating property of beverages and foods. "seaweed decomposition product" (see, for example, Patent Documents 17 to 18); a technique of adding a polysaccharide obtained by hot water extraction of Asparagus to a seasoning or a dairy product to improve the texture (for example, see Patent Document 19) In order to obtain the adhesion effect of the edible meats brought by the alginic acid contained in the kelp and the flavor-enhancing effect of the broth, the kimchi liquid containing the broth obtained by the blister-free kelp is immersed in the kelp meat. (For example, refer to Patent Document 20); a technique in which the seaweed in a dry state is subjected to sodium carbonate or slaked lime treatment, and then pulverized by an ultrafine pulverizer and added to a sausage to increase gel strength or texture (for example, refer to Patent Document 21). a technique of adding a condensed phosphate to seaweed which is swollen in water and stirring it, and adding an organic acid, a calcium salt or a milk component to the obtained paste to obtain a edible gel ( For example, refer to Patent Document 22); a technique in which a seaweed immersion liquid is subjected to an enzyme treatment, and then solidified into a gel form by a calcium ion solution (for example, refer to Patent Document 23); a dissolution component of agar-containing seaweed and alginate-containing material A technique for producing a food such as bird's nest by the eluted component of seaweed (for example, refer to Patent Document 24).

[先前技術文獻] [Previous Technical Literature] [專利文獻] [Patent Literature]

[專利文獻1]日本專利特開2009-225665號公報 [Patent Document 1] Japanese Patent Laid-Open Publication No. 2009-225665

[專利文獻2]日本專利特開2007-104959號公報 [Patent Document 2] Japanese Patent Laid-Open Publication No. 2007-104959

[專利文獻3]日本專利特開2008-271954號公報 [Patent Document 3] Japanese Patent Laid-Open Publication No. 2008-271954

[專利文獻4]日本專利特開2009-082034號公報 [Patent Document 4] Japanese Patent Laid-Open Publication No. 2009-082034

[專利文獻5]日本專利特開2001-352937號公報 [Patent Document 5] Japanese Patent Laid-Open Publication No. 2001-352937

[專利文獻6]日本專利特開2007-300816號公報 [Patent Document 6] Japanese Patent Laid-Open Publication No. 2007-300816

[專利文獻7]日本專利特開平08-000228號公報 [Patent Document 7] Japanese Patent Laid-Open Publication No. 08-000228

[專利文獻8]日本專利特開2005-225924號公報 [Patent Document 8] Japanese Patent Laid-Open Publication No. 2005-225924

[專利文獻9]日本專利特開2005-145983號公報 [Patent Document 9] Japanese Patent Laid-Open Publication No. 2005-145983

[專利文獻10]日本專利特開2010-110263號公報 [Patent Document 10] Japanese Patent Laid-Open Publication No. 2010-110263

[專利文獻11]日本專利特開2005-287313號公報 [Patent Document 11] Japanese Patent Laid-Open Publication No. 2005-287313

[專利文獻12]日本專利特開平11-169137號公報 [Patent Document 12] Japanese Patent Laid-Open No. Hei 11-169137

[專利文獻13]日本專利特開2010-178713號公報 [Patent Document 13] Japanese Patent Laid-Open Publication No. 2010-178713

[專利文獻14]日本專利特開2005-095078號公報 [Patent Document 14] Japanese Patent Laid-Open Publication No. 2005-095078

[專利文獻15]日本專利特開平06-284873號公報 [Patent Document 15] Japanese Patent Laid-Open No. Hei 06-284873

[專利文獻16]日本專利特開2001-238623號公報 [Patent Document 16] Japanese Patent Laid-Open Publication No. 2001-238623

[專利文獻17]日本專利特開2008-154538號公報 [Patent Document 17] Japanese Patent Laid-Open Publication No. 2008-154538

[專利文獻18]日本專利特開2008-187948號公報 [Patent Document 18] Japanese Patent Laid-Open Publication No. 2008-187948

[專利文獻19]日本專利特開2002-212201號公報 [Patent Document 19] Japanese Patent Laid-Open Publication No. 2002-212201

[專利文獻20]日本專利特開2003-304835號公報 [Patent Document 20] Japanese Patent Laid-Open Publication No. 2003-304835

[專利文獻21]日本專利特開2007-268515號公報 [Patent Document 21] Japanese Patent Laid-Open Publication No. 2007-268515

[專利文獻22]日本專利特開平09-271331號公報 [Patent Document 22] Japanese Patent Laid-Open No. 09-271331

[專利文獻23]日本專利特開平10-004930號公報 [Patent Document 23] Japanese Patent Laid-Open No. Hei 10-004930

[專利文獻24]日本專利特開平05-336932號公報 [Patent Document 24] Japanese Patent Laid-Open No. Hei 05-336932

如以上所述,為了賦予海藻之礦物質、食物纖維及功能性成分,以及為了食用海藻本身,已製造出各種海藻處理 物,但業界要求亦容易用於廣泛之各種食品及化妝品等之更新穎之海藻處理物。又,以利用海藻進行之增黏或食感改良為目的而製造出各種海藻處理物,但要求效果更高之沈澱防止劑及食品改良劑。 As described above, in order to impart minerals, dietary fiber and functional ingredients of seaweed, and to consume seaweed itself, various seaweed treatments have been produced. However, the industry requirements are also easy to use in a wide variety of food and cosmetics and other innovative seaweed treatments. In addition, various seaweed treated products are produced for the purpose of improving the viscosity or the texture of the seaweed, but a more effective precipitation preventing agent and a food improving agent are required.

又,目前為止,在以防止沈澱為目的使用粉末海藻本身而非海藻之一種成分方面完全無嘗試。 Further, so far, there has been no attempt at using powder seaweed itself for the purpose of preventing sedimentation, rather than a component of seaweed.

基於以上之背景,本發明之目的在於提供一種可安全地廣泛用於各種食品及化妝品等之源自海藻的新穎材料。又,本發明之目的在於提供一種可代替先前之食品添加物且具有較高之效果的新穎之沈澱防止劑及食品改良劑。 Based on the above background, an object of the present invention is to provide a novel material derived from seaweed which can be safely used in various foods, cosmetics, and the like. Further, it is an object of the present invention to provide a novel precipitation preventing agent and food improving agent which can replace the prior food additive and have a high effect.

本發明者等人為了解決該問題而進行努力研究,結果發現,藉由將褐藻粉碎,以特定之溶液進行清洗後,進行脫水並乾燥,可獲得源自海藻之可安全地用作新穎食品材料之粉末褐藻。本發明者等人進而反覆研究,結果發現,該粉末褐藻具有不溶性成分相對於水溶性褐藻膠成分之含量較低的特徵,未處理之情況下若於含有沈澱之粒子之對象溶液中添加該粉末褐藻,與僅將褐藻製成乾燥粉末而獲得之粉末褐藻相比,可獲得顯著之沈澱防止作用,並且發現,可在不大幅度提高對象溶液之黏度之情況下獲得該沈澱防止作用。 In order to solve this problem, the inventors of the present invention have conducted intensive studies to find that it is possible to safely use it as a novel food material derived from seaweed by pulverizing brown algae, washing it with a specific solution, and then dehydrating and drying it. Powder brown algae. The present inventors have further studied and found that the powdered brown algae has a characteristic that the content of the insoluble component is lower than that of the water-soluble alginate component, and if the powder is added to the target solution containing the precipitated particles, the powder is not added. The brown algae can obtain a remarkable precipitation preventing effect as compared with the powder brown algae obtained by only making the brown algae into a dry powder, and it is found that the precipitation preventing effect can be obtained without greatly increasing the viscosity of the target solution.

進而,本發明者等人發現,藉由使用該粉末褐藻,與先前所使用之食品添加物相比,可更佳地改良各種食品之食感、紋理、體積、嗜好性等,從而完成本發明。 Further, the inventors of the present invention have found that by using the powdered brown algae, the food texture, texture, volume, taste, and the like of various foods can be better improved than the food additive previously used, thereby completing the present invention. .

即,本發明係關於以下者。 That is, the present invention relates to the following.

[1] [1]

一種粉末褐藻,其含有水溶性褐藻膠成分及不溶性成分,且水溶性褐藻膠成分與不溶性成分之重量比為1:0.05~1:4。 A powdered brown algae comprising a water-soluble alginate component and an insoluble component, and the weight ratio of the water-soluble alginate component to the insoluble component is 1:0.05 to 1:4.

[2] [2]

如上述[1]之粉末褐藻,其中不溶性成分之含量為5~35重量%。 The powdered brown algae according to the above [1], wherein the content of the insoluble component is 5 to 35% by weight.

[3] [3]

如上述[1]之粉末褐藻,其中水溶性褐藻膠成分之含量為10~70重量%。 The powdered brown algae according to the above [1], wherein the content of the water-soluble alginate component is 10 to 70% by weight.

[4] [4]

如上述[1]之粉末褐藻,其中水溶性褐藻膠成分與不溶性成分之重量比為1:0.05~1:1.5。 The powder brown algae according to the above [1], wherein the weight ratio of the water-soluble alginate component to the insoluble component is 1:0.05 to 1:1.5.

[5] [5]

如上述[1]之粉末褐藻,其中表示色彩之亮度之L值為45以上。 The powder brown algae according to the above [1], wherein the L value indicating the brightness of the color is 45 or more.

[6] [6]

如上述[5]之粉末褐藻,其中表示色彩之亮度之L值為70以上。 The powdered brown algae according to the above [5], wherein the L value indicating the brightness of the color is 70 or more.

[7] [7]

如上述[5]之粉末褐藻,其中表示色彩之亮度之L值為72以上。 The powdered brown algae according to the above [5], wherein the L value indicating the brightness of the color is 72 or more.

[8] [8]

如上述[1]之粉末褐藻,其係將褐藻粉碎、清洗及乾燥而獲得,且上述清洗係利用包含水、醇、脫色劑及鹼之清洗溶液進行之清洗。 The powdered brown algae according to the above [1], which is obtained by pulverizing, washing and drying brown algae, and the washing is carried out by using a washing solution containing water, an alcohol, a decolorizing agent and an alkali.

[9] [9]

如上述[8]之粉末褐藻,其中褐藻係屬於昆布目巨藻科或昆布目昆布科者。 The powdered brown algae according to the above [8], wherein the brown algae belongs to the group of the giant algae family of K. sinensis or the kelp group.

[10] [10]

一種沈澱防止劑,其含有如上述[1]至[9]中任一項之粉末褐藻。 A precipitation preventing agent containing the powdered brown algae according to any one of the above [1] to [9].

[11] [11]

一種沈澱防止劑,其係含有將褐藻粉碎、清洗及乾燥而獲得之粉末褐藻者,且上述清洗係利用包含水、醇、脫色劑及鹼之清洗溶液進行之清洗。 A precipitating agent containing powdered brown algae obtained by pulverizing, washing and drying brown algae, and the washing is carried out by using a washing solution containing water, an alcohol, a decolorizing agent and an alkali.

[12] [12]

一種含沈澱粒子之溶液,其係含有0.01重量%~5.0重量%之如上述[1]至[9]中任一項之粉末褐藻,且黏度為100 mPa‧s以下之防止沈澱者。 A solution containing precipitated particles, which contains 0.01% by weight to 5.0% by weight of the powdered brown algae according to any one of the above [1] to [9], and has a viscosity of 100 mPa·s or less to prevent precipitation.

[13] [13]

如上述[12]之含沈澱粒子之溶液,其係含蛋白質之飲料。 A solution containing precipitated particles according to the above [12], which is a protein-containing beverage.

[14] [14]

一種沈澱防止方法,其包括將如上述[1]至[9]中任一項 之粉末褐藻添加至含沈澱粒子之溶液中之步驟。 A method for preventing precipitation, which comprises any of [1] to [9] as described above The step of adding the powdered brown algae to the solution containing the precipitated particles.

[15] [15]

一種食品改良劑,其含有如上述[1]至[9]中任一項之粉末褐藻。 A food improver comprising the powdered brown algae according to any one of the above [1] to [9].

[16] [16]

如上述[15]之食品改良劑,其係麵粉食品改良劑或食品之增黏凝膠化改良劑。 The food improving agent according to the above [15], which is a flour food improving agent or a viscosity-increasing gelatinizing agent for foods.

[17] [17]

一種食品,其係調配有如上述[15]之食品改良劑者,且含有0.01~20.0重量%之上述粉末褐藻。 A foodstuff which is formulated with the food improver of the above [15], and contains 0.01 to 20.0% by weight of the above-mentioned powder brown algae.

[18] [18]

如上述[17]之食品,其係麵粉食品、乳製品、畜肉製品或凝膠化食品。 The food of the above [17], which is a flour food, a dairy product, a meat product or a gelled food.

[19] [19]

如上述[17]之食品,其係麵包類、麵條類、小麥點心類、小麥混合粉類或包子類。 The food according to the above [17], which is a bread, a noodle, a wheat snack, a wheat mixed powder or a bun.

[20] [20]

如上述[17]之食品,其係霜淇淋類、雪霜類、乳酪類、酸乳酪類、香腸類、漢堡類、肉丸子類、混練肉類、混練魚類、果凍類、布丁類或甜品類。 The food of the above [17], which is a cream, a snow cream, a cheese, a yoghurt, a sausage, a hamburger, a meatball, a mixed meat, a mixed fish, a jelly, a pudding or a dessert. .

[21] [twenty one]

一種食品之製造方法,其包括於食品中調配如上述[15]之食品改良劑之步驟。 A method of producing a food comprising the step of formulating a food improver according to the above [15] in a food.

又,本發明亦關於以下之粉末褐藻、沈澱防止劑及含沈 澱粒子之溶液。 Moreover, the present invention also relates to the following powder brown algae, precipitation inhibitor and sinking A solution of the particles.

[22] [twenty two]

如上述[1]之粉末褐藻,其中水溶性褐藻膠成分與不溶性成分之重量比為1:0.05~1:1.1。 The powder brown algae according to the above [1], wherein the weight ratio of the water-soluble alginate component to the insoluble component is 1:0.05 to 1:1.1.

[23] [twenty three]

如上述[1]之粉末褐藻,其中不溶性成分之含量為5~30重量%。 The powdered brown algae according to the above [1], wherein the content of the insoluble component is 5 to 30% by weight.

[24] [twenty four]

如上述[1]之粉末褐藻,其中不溶性成分之含量為10~30重量%。 The powdered brown algae according to the above [1], wherein the content of the insoluble component is 10 to 30% by weight.

[25] [25]

如上述[1]之粉末褐藻,其中水溶性褐藻膠成分之含量為30~60重量%。 The powdered brown algae according to the above [1], wherein the content of the water-soluble alginate component is 30 to 60% by weight.

[26] [26]

如上述[1]之粉末褐藻,其中水溶性褐藻膠成分之含量為40~60重量%。 The powder brown algae according to the above [1], wherein the content of the water-soluble alginate component is 40 to 60% by weight.

[27] [27]

如上述[5]之粉末褐藻,其中表示色彩之亮度之L值為75以上。 The powder brown algae according to the above [5], wherein the L value indicating the brightness of the color is 75 or more.

[28] [28]

如上述[1]之粉末褐藻,其中褐藻係屬於昆布目昆布科、昆布目巨藻科或墨角藻目公牛藻科者。 The powdered brown algae according to the above [1], wherein the brown algae belongs to the group consisting of Kunbu, Kumbu, K., or A. algae.

[29] [29]

如上述[1]之粉末褐藻,其中褐藻係屬於昆布目者。 The powder brown algae according to the above [1], wherein the brown algae belongs to the kelp.

[30] [30]

如上述[1]之粉末褐藻,其中褐藻係屬於昆布目昆布科或昆布目巨藻科者。 The powdered brown algae according to the above [1], wherein the brown algae belongs to the group of Kumbuco or Kumbuphyllum.

[31] [31]

如上述[1]之粉末褐藻,其含有蛋白質,且蛋白質之含量為15重量%以下。 The powdered brown algae according to the above [1], which contains protein and has a protein content of 15% by weight or less.

[32] [32]

如上述[1]之粉末褐藻,其中1重量%分散液之黏度為0.1~100(mPa‧s)。 The powdered brown algae according to the above [1], wherein the viscosity of the 1% by weight dispersion is 0.1 to 100 (mPa ‧ s).

[33] [33]

如上述[1]之粉末褐藻,其具有通過篩孔尺寸0.05 mm~0.50 mm之篩網之平均粒徑。 The powdered brown algae according to the above [1], which has an average particle diameter of a sieve passing through a mesh size of 0.05 mm to 0.50 mm.

[34] [34]

如上述[1]之粉末褐藻,其具有通過篩孔尺寸0.10 mm~0.25 mm之篩網之平均粒徑。 The powdered brown algae according to the above [1], which has an average particle diameter of a sieve passing through a mesh size of 0.10 mm to 0.25 mm.

[35] [35]

如上述[1]之粉末褐藻,其具有通過篩孔尺寸0.10 mm~0.15 mm之篩網之平均粒徑。 The powdered brown algae according to the above [1], which has an average particle diameter of a sieve passing through a mesh size of 0.10 mm to 0.15 mm.

[36] [36]

如上述[1]之粉末褐藻,其係海藻味經減低者。 The powdered brown algae according to the above [1], wherein the seaweed taste is reduced.

[37] [37]

如上述[8]之粉末褐藻,其中醇係選自由甲醇、乙醇、異丙醇及正丙醇所組成之群。 The powder brown algae according to the above [8], wherein the alcohol is selected from the group consisting of methanol, ethanol, isopropanol and n-propanol.

[38] [38]

如上述[8]之粉末褐藻,其中脫色劑為次氯酸鈉。 The powder brown algae according to the above [8], wherein the decolorizing agent is sodium hypochlorite.

[39] [39]

如上述[8]之粉末褐藻,其中鹼為碳酸鈉。 A powdered brown algae according to the above [8], wherein the base is sodium carbonate.

[40] [40]

一種沈澱防止劑,其包含如上述[1]至[9]中任一項之粉末褐藻。 A precipitation preventing agent comprising the powdered brown algae according to any one of the above [1] to [9].

[41] [41]

如上述[12]之含沈澱粒子之溶液,其係飲料、食品、化妝品或醫藥品。 A solution containing precipitated particles according to the above [12], which is a beverage, a food, a cosmetic or a pharmaceutical.

[42] [42]

如上述[13]之含沈澱粒子之溶液,其係含蛋白質之飲料、調配粉末之茶飲料、加入有選自蔬菜汁、果汁及食物纖維之沈澱成分的飲料、加入有果凍之飲料、調味品或醬料。 The solution containing the precipitated particles according to the above [13], which is a protein-containing beverage, a powdered tea beverage, a beverage added with a precipitating component selected from vegetable juice, fruit juice and dietary fiber, a jelly-added beverage, and a condiment Or sauces.

又,本發明亦關於以下之麵粉食品改良劑、麵粉食品及麵粉食品之製造方法。 Further, the present invention relates to the following method for producing a flour food improver, a flour food, and a flour food.

[43] [43]

一種麵粉食品改良劑,其含有如上述[1]至[9]中任一項之粉末褐藻。 A flour food improver comprising the powdered brown algae according to any one of the above [1] to [9].

[44] [44]

一種麵粉食品,其係調配有如上述[43]之麵粉食品改良劑者,且相對於粉體原料含有0.01~20.0重量%之上述粉末褐藻。 A flour food product which is formulated with the flour food improver of the above [43], and contains 0.01 to 20.0% by weight of the powder brown algae relative to the powder raw material.

[45] [45]

一種麵粉食品,其係調配有如上述[43]之麵粉食品改良劑者,且相對於麵粉含有0.01~50.0重量%之上述粉末褐藻。 A flour food product which is formulated with the flour food improver of the above [43], and contains 0.01 to 50.0% by weight of the above-mentioned powder brown algae relative to the flour.

[46] [46]

一種麵粉食品之製造方法,其係包括將如上述[43]之麵粉食品改良劑調配至麵粉中之步驟者,且調配步驟後,進而包括加熱調配有麵粉食品改良劑之麵粉之步驟。 A method for producing a flour food comprising the steps of formulating a flour food improving agent according to the above [43] into a flour, and after the compounding step, further comprising the step of heating the flour blended with the flour food improving agent.

又,本發明亦關於以下之食品之增黏凝膠化改良劑、食品及食品之製造方法。 Further, the present invention also relates to a viscosity-increasing gelatinizing agent for foods, a method for producing foods and foods.

[47] [47]

一種食品之增黏凝膠化改良劑,其含有如上述[1]至[9]中任一項之粉末褐藻。 A viscosity-increasing gelatinization agent for foods, which comprises the powdered brown algae according to any one of the above [1] to [9].

[48] [48]

如上述[47]之食品之增黏凝膠化改良劑,其係增黏劑、凝膠化劑、穩定劑、澱粉接著劑、食感改良劑、物性改良劑、保形性改良劑、保水性改良劑、體積控制劑、乳化控制劑、脫水收縮防止劑、乳清分離防止劑等、耐熱劑、抗熱震性賦予劑、凝固劑、包衣劑、軟化劑、分散劑、滲透劑、氣泡量控制劑、剝離劑、脫模劑、膨脹率控制劑、彈力改良劑、良率提高劑或膜形成劑。 The viscosity-increasing gelatinizing agent for foods according to the above [47], which is a tackifier, a gelling agent, a stabilizer, a starch adhesive, a food texture improving agent, a physical property improving agent, a shape modifying improver, and a water retention agent. Improver, volume control agent, emulsification control agent, syneresis preventive agent, whey separation preventive agent, heat-resistant agent, thermal shock resistance imparting agent, coagulant, coating agent, softener, dispersant, penetrant, A bubble amount controlling agent, a releasing agent, a releasing agent, an expansion ratio controlling agent, an elastic modifier, a yield improving agent, or a film forming agent.

[49] [49]

一種食品,其係調配有如上述[47]之食品之增黏凝膠化改良劑者,且相對於食品原料中之水含有0.01~50.0重量%之上述粉末褐藻。 A foodstuff which is formulated with the viscosity-increasing gelatin of the food of the above [47], and contains 0.01 to 50.0% by weight of the powder brown algae relative to the water in the food material.

[50] [50]

一種凝膠化食品,其係如上述[17]者,且進而含有鈣。 A gelled food product according to the above [17], which further contains calcium.

[51] [51]

一種食品之製造方法,其包括將如上述[47]之食品之增黏凝膠化改良劑調配至食品中之步驟,且食品為凝膠化食品,該方法進而包括將含有鈣之原料調配至食品中之步驟。 A method for producing a food comprising the step of formulating a viscosity-increasing gelatinizing agent for a food according to the above [47] into a food, and the food is a gelled food, the method further comprising blending a raw material containing calcium to The steps in the food.

藉由本發明,可提供新穎之粉末褐藻作為可安全地廣泛用於各種食品及化妝品等之源自海藻之新穎材料。又,根據本發明,可提供在未處理情況下在不大幅度增黏含有沈澱之粒子之溶液之情況下發揮優異之沈澱防止作用、安全性亦較高之沈澱防止劑,故而可實現例如作為經乳化之溶液及/或含有粉末之溶液的飲料、食品、化妝水、洗潔劑、醫藥品等各種領域之製品的沈澱防止。 According to the present invention, novel powdered brown algae can be provided as a novel material derived from seaweed which can be safely used in various foods, cosmetics, and the like. Moreover, according to the present invention, it is possible to provide a precipitation preventing agent which exhibits an excellent precipitation preventing action and a high safety when the solution containing the precipitated particles is not greatly thickened in the untreated state, and thus can be realized, for example, as a precipitation preventing agent. Precipitation prevention of products in various fields such as beverages, foods, lotions, detergents, and pharmaceuticals, which are emulsified solutions and/or powder-containing solutions.

以下,對本發明進行詳細說明。以下之說明存在基於本發明之代表性實施態樣而完成之情況,但本發明並不限定於此種實施態樣。 Hereinafter, the present invention will be described in detail. The following description is based on a representative embodiment of the present invention, but the present invention is not limited to such an embodiment.

本發明係關於粉末褐藻、含有該粉末褐藻之沈澱防止劑及食品改良劑。 The present invention relates to a powdered brown algae, a precipitation preventing agent containing the powdered brown algae, and a food improving agent.

本發明之粉末褐藻係源自褐藻之粉末,與自原料褐藻提取特定之成分而獲得之提取物不同。本發明之粉末褐藻保持有褐藻中所含之成分之大部分,亦可為不含源自褐藻之 部分成分者,亦可為源自褐藻之部分成分變化為其他成分者。例如,藉由下述之製造例1等之製法而獲得之本發明之粉末褐藻雖然於清洗步驟中失去源自褐藻之部分成分,源自褐藻之部分成分變化為其他成分,但保持有褐藻中所含之成分之大部分。 The powdered brown algae of the present invention is derived from a powder of brown algae, which is different from an extract obtained by extracting a specific component from the raw brown algae. The powdered brown algae of the present invention retains most of the components contained in the brown algae, and may also be free from brown algae. Some components may also be those in which the components derived from brown algae are changed to other components. For example, the powdered brown algae of the present invention obtained by the production method of the following Production Example 1 or the like loses part of the components derived from brown algae in the washing step, and some components derived from brown algae change to other components, but remain in brown algae. Most of the ingredients contained.

作為成為本發明之粉末褐藻之原料的褐藻,例如可列舉外子藻目、褐殼藻目、索藻目、萱藻目、網管藻目、馬鞭藻目、黑頂藻目、酸藻目、毛頭藻目、昆布目、網地藻目、墨角藻目等屬於褐藻綱之褐藻。 Examples of the brown algae which are the raw material of the powdered brown algae of the present invention include exophyta, brown algae, spirulina, algae, cyanobacteria, verbena, sphaerotheca, and algae. It is a brown algae of the brown algae class, such as the head of the genus Hymenoptera, the kelp, the cyanobacteria, and the sphagnum.

就易獲得性之觀點而言,又,將本發明之粉末褐藻用作沈澱防止劑或食品改良劑之情形時,就充分發揮該等之效果之觀點而言,上述中,較佳可使用屬於索藻目(海蘊科、麵條藻科等)、昆布目或墨角藻目(墨角藻科、鹿尾菜科、微勞馬尾藻科等)之褐藻。成為原料之褐藻更佳為屬於昆布目之褐藻(孔葉藻科(Agarum)、翅藻科(Alaria)、翅藻科(Alariaceae)、貓腳昆布科(Arthrothamnus)、繩藻科(Chorda)、多肋藻科(Costaria)、Cymathaere科、腔昆布科(Ecklonia)、擬昆布科(Eckloniopsis)、黑海帶科(Eisenia)、Streptophyllopsis科、解氏藻科(Kjellmaniella)、昆布科(Laminaria)、偽繩藻科(Pseudochorda)、裙帶菜科(Undaria)、巨藻科等)或屬於墨角藻目之褐藻(墨角藻科、鹿尾菜科、微勞馬尾藻科、公牛藻科等),進而較佳為屬於昆布目昆布科、昆布目巨藻科、昆布目翅藻科或墨角藻目公牛藻科之褐藻,進而更佳為屬於昆布目昆布科或昆布目巨藻科之 褐藻,尤佳為屬於昆布目巨藻科之褐藻。例如,作為成為原料之褐藻,可使用屬於巨藻科之淡黑巨海藻、屬於昆布科之巨海藻或昆布、屬於翅藻科之裙帶菜或者屬於公牛藻科之南極公牛藻。 In the case of using the powdered brown algae of the present invention as a precipitation preventing agent or a food improving agent, the above-mentioned effects are preferably used. Brown algae of the genus Mosquito (Haiyunke, Noodleaceae, etc.), Kleinexus or Fucus sinensis (Hymenoptera, Cervus, S. cerevisiae, etc.). The brown algae that is the raw material is preferably a brown algae belonging to the genus Kumbu (Agarum, Alaria, Alariaceae, Arthrothamnus, and Chorda). Costaria, Cymathaere, Ecklonia, Eckloniopsis, Eisenia, Streptophyllopsis, Kjellmaniella, Laminaria, Pseudo Pseudochorda, Undaria, Macroalgae, etc. or brown algae of the genus Fucus (Hymenoptera, Erigeraceae, Micro-Salmophyllum, Bull's algae, etc.) Jia is a brown algae belonging to the genus Kunbu, Kunming, the genus Klein, or the algae of the genus Corydalis, and more preferably belongs to the genus Kumbu or the kelp Brown algae, especially the brown algae belonging to the family Macroba. For example, as the brown algae to be used as a raw material, it is possible to use a pale black giant seaweed belonging to the genus Macrophyta, a giant seaweed or kelp belonging to the genus Cucurbitaceae, a wakame belonging to the genus Hymenoptera, or an Antarctic bull genus belonging to the genus Bull.

本發明之粉末褐藻之平均粒徑並無特別限定,根據使用用途,可為過篩孔徑2 mm左右之顆粒,亦可為過篩孔徑0.02 mm以下,作為通過之篩網之篩孔尺寸,較佳為0.05 mm~0.50 mm,更佳為0.10 mm~0.25 mm,例如0.10 mm~0.15 mm。例如,將含有本發明之粉末褐藻之沈澱防止劑或食品改良劑以粉末形態使用之情形時,隨著粒徑變小,有作為沈澱防止劑或食品改良劑之效果提高之傾向,但若粒徑過小,則有粒子彼此凝聚、作為沈澱防止劑或食品改良劑之效果降低之情形。再者,於將沈澱防止劑或食品改良劑分散於水等溶液中之後使用之情形時,只要可獲得均勻之分散液,則粉末褐藻之粒徑並無特別限定。具有上述所需之平均粒徑之粉末褐藻可藉由通過所需之篩孔尺寸之篩網而獲得。 The average particle diameter of the powdered brown algae of the present invention is not particularly limited, and may be a sieve having a sieved pore size of about 2 mm or a sieved pore diameter of 0.02 mm or less as a sieve size of the sieve passing through, depending on the intended use. Preferably, it is 0.05 mm to 0.50 mm, more preferably 0.10 mm to 0.25 mm, for example, 0.10 mm to 0.15 mm. For example, when the precipitation inhibitor or the food improving agent containing the powdered brown algae of the present invention is used in the form of a powder, the effect as a precipitation preventing agent or a food improving agent tends to increase as the particle diameter becomes smaller, but if the particle size is small, When the diameter is too small, the particles are agglomerated with each other, and the effect as a precipitation preventing agent or a food improving agent is lowered. In the case where the precipitation preventing agent or the food improving agent is used after being dispersed in a solution such as water, the particle size of the powdered brown algae is not particularly limited as long as a uniform dispersion liquid can be obtained. The powdered brown algae having the above-mentioned desired average particle diameter can be obtained by passing through a sieve having a desired mesh size.

本發明之粉末褐藻具有與將原料褐藻中之特定之成分提取純化而獲得之提取物不同之組成。又,本發明之粉末褐藻具有與僅將褐藻直接藉由水等製成糊劑後、藉由水等溶膠化後、或清洗並晾乾後,加以乾燥而獲得之褐藻粉末等亦不同之組成。 The powdered brown algae of the present invention has a composition different from that obtained by extracting and purifying a specific component of the raw material brown algae. Further, the powdered brown algae of the present invention has a composition different from that of brown algae which is obtained by directly forming a brown algae directly into a paste by water or the like, solating by water or the like, or washing and drying. .

於一態樣中,本發明之粉末褐藻以特定之重量比含有下述中分別詳述之水溶性褐藻膠成分及不溶性成分。本發明 之粉末褐藻中之水溶性褐藻膠成分與不溶性成分之重量比為1:0.05~1:4,將本發明之粉末褐藻用作沈澱防止劑或食品改良劑之情形時,就充分發揮該等之效果之觀點而言,較佳為1:0.05~1:1.5,更佳為1:0.05~1:1.1,進而較佳為1:0.05~1:0.75。 In one aspect, the powdered brown algae of the present invention contains a water-soluble alginate component and an insoluble component as described in detail below in a specific weight ratio. this invention The weight ratio of the water-soluble alginate component to the insoluble component in the powder brown algae is 1:0.05 to 1:4, and when the powdered brown algae of the present invention is used as a precipitation preventing agent or a food improving agent, the above-mentioned From the viewpoint of the effect, it is preferably from 1:0.05 to 1:1.5, more preferably from 1:0.05 to 1:1.1, still more preferably from 1:0.05 to 1:0.75.

於一態樣中,本發明之粉末褐藻之特徵組成根據用作原料之褐藻之種類而有所不同,例如尤其是可藉由測定粉末褐藻中之水溶性褐藻膠成分而確認。本說明書中,所謂水溶性褐藻膠成分係指水溶性海藻酸鹽(鈉鹽、鈣鹽、鎂鹽等)經鈉鹽換算者。 In one aspect, the characteristic composition of the powdered brown algae of the present invention varies depending on the kind of brown algae used as a raw material, and can be confirmed, for example, in particular, by measuring the water-soluble alginate component in the powder brown algae. In the present specification, the water-soluble alginate component means a water-soluble alginate (sodium salt, calcium salt, magnesium salt, etc.) which is converted into a sodium salt.

於將粉末褐藻用作沈澱防止劑或食品改良劑之情形時,就充分發揮該等之效果之觀點而言,本發明之粉末褐藻之水溶性褐藻膠成分於滿足上述水溶性褐藻膠成分與不溶性成分之重量比之範圍內,較佳為10~80重量%,更佳為10~70重量%,進而較佳為30~60重量%,尤佳為40~60重量%。水溶性褐藻膠成分可使用下述之實施例2中所記載之方法而測定。 In the case where the powdered brown algae is used as a precipitation preventing agent or a food improving agent, the water-soluble alginate component of the powdered brown algae of the present invention satisfies the above-described water-soluble alginate component and insolubleness from the viewpoint of sufficiently exerting the effects. The weight ratio of the components is preferably from 10 to 80% by weight, more preferably from 10 to 70% by weight, still more preferably from 30 to 60% by weight, still more preferably from 40 to 60% by weight. The water-soluble alginate component can be measured by the method described in the following Example 2.

於一態樣中,本發明之粉末褐藻之特徵組成根據用作原料之褐藻之種類而有所不同,例如尤其可藉由測定粉末褐藻中之不溶性成分而確認。本說明書中,所謂不溶性成分係指粉末褐藻中所含之成分中除去灰分、蛋白質、脂質、水分及水溶性褐藻膠成分之成分,更詳細而言係指除去作為水溶性成分之水分、水溶性褐藻膠成分、水溶性灰分及水溶性蛋白質以及作為水不溶性成分之水不溶性灰分、水 不溶性蛋白質及脂質之成分。粉末褐藻中之不溶性成分之含量可藉由使用下述之實施例2中所記載之方法,自粉末褐藻之重量減去灰分、蛋白質、脂質、水分及水溶性褐藻膠成分之含量而算出。於一態樣中,該不溶性成分之主成分為不溶性食物纖維(尤其是纖維素及半纖維素)。 In one aspect, the characteristic composition of the powdered brown algae of the present invention varies depending on the kind of brown algae used as a raw material, and can be confirmed, for example, particularly by measuring an insoluble component in the powder brown algae. In the present specification, the insoluble component refers to a component which removes ash, protein, lipid, water, and water-soluble alginate component among the components contained in the powdered brown algae, and more specifically, removes moisture and water solubility as a water-soluble component. Alginate component, water-soluble ash and water-soluble protein, and water-insoluble ash and water as water-insoluble components Insoluble protein and lipid components. The content of the insoluble component in the powdered brown algae can be calculated by subtracting the contents of ash, protein, lipid, water and water-soluble alginate components from the weight of the powdered brown algae by using the method described in Example 2 below. In one aspect, the main component of the insoluble component is insoluble dietary fiber (especially cellulose and hemicellulose).

於將粉末褐藻用作沈澱防止劑或食品改良劑之情形時,就充分發揮該等之效果之觀點而言,本發明之粉末褐藻之不溶性成分於滿足上述之水溶性褐藻膠成分與不溶性成分之重量比之範圍中,較佳為80重量%以下,更佳為5~35重量%,進而較佳為5~30重量%。 In the case where the powdered brown algae is used as a precipitation preventing agent or a food improving agent, the insoluble component of the powdered brown algae of the present invention satisfies the above-described water-soluble alginate component and insoluble component from the viewpoint of sufficiently exerting the effects. In the range of the weight ratio, it is preferably 80% by weight or less, more preferably 5 to 35% by weight, still more preferably 5 to 30% by weight.

於一態樣中,此種本發明之粉末褐藻之特徵組成根據用作原料之褐藻之種類亦有所不同,例如尤其可藉由測定粉末褐藻中之蛋白質之量而確認。本發明之粉末褐藻中之蛋白質較佳為15重量%以下,更佳為10.5重量%以下,進而較佳為5重量%以下,尤佳為2重量%以下。蛋白質可使用下述之實施例2中所記載之方法而測定。 In one aspect, the characteristic composition of the powdered brown algae of the present invention varies depending on the type of brown algae used as a raw material, and can be confirmed, for example, by measuring the amount of protein in the powder brown algae. The protein in the powder brown algae of the present invention is preferably 15% by weight or less, more preferably 10.5% by weight or less, further preferably 5% by weight or less, and particularly preferably 2% by weight or less. The protein can be measured by the method described in the following Example 2.

於一態樣中,本發明之粉末褐藻之特徵組成亦可藉由確認製成分散液後是否發生由鈣引起之凝膠化而判斷。發生由鈣引起之凝膠化的代表性成分為海藻酸鈉。有無發生凝膠化可使用下述之實施例2中所記載之方法而測定。具有此種特徵之本發明之粉末褐藻亦可用作各種溶液之凝膠化劑。 In one aspect, the characteristic composition of the powdered brown algae of the present invention can also be judged by confirming whether gelation by calcium occurs after the dispersion is prepared. A representative component of the gelation caused by calcium is sodium alginate. The presence or absence of gelation can be measured by the method described in the following Example 2. The powdered brown algae of the present invention having such characteristics can also be used as a gelling agent for various solutions.

於一態樣中,關於本發明之粉末褐藻,於將含有粉末褐藻或粉末褐藻之沈澱防止劑添加至其他飲料食品、化妝 品、日用品、醫藥品等中之情形時,就不對各製品之色彩造成影響之方面而言,或於調配含有粉末褐藻之食品改良劑之情形時,就不對食品之色彩造成影響之方面而言,較佳為降低海藻色。海藻色之降低之程度可藉由測定粉末褐藻之粉體之L值而判斷。 In one aspect, the powdered brown algae of the present invention is added to other beverages and cosmetics by using a precipitation inhibitor containing powdered brown algae or powdered brown algae. In the case of products, daily necessities, pharmaceuticals, etc., in terms of not affecting the color of each product, or in the case of blending a food improver containing powdered brown algae, it does not affect the color of the food. Preferably, the seaweed color is lowered. The degree of reduction in seaweed color can be judged by measuring the L value of the powder of powdered brown algae.

L值表示色彩之亮度,以0~100之數值表示。L值為100之情形時表示最亮之狀態(完全之白色),L值為0之情形時表示最暗之狀態(完全之黑色)。 The L value indicates the brightness of the color, expressed as a value from 0 to 100. When the L value is 100, it indicates the brightest state (complete white), and when the L value is 0, it indicates the darkest state (complete black).

本發明之粉末褐藻之以粉末狀態進行測定之粉體之L值可藉由下述之實施例2中所記載之方法測定。於一態樣中,本發明之粉末褐藻之粉體之L值較佳為45以上,更佳為70以上,進而較佳為72以上,進而更佳為75以上,尤佳為80以上。 The L value of the powder measured in the powder state of the powdered brown algae of the present invention can be measured by the method described in the following Example 2. In one aspect, the L value of the powder of the powdered brown algae of the present invention is preferably 45 or more, more preferably 70 or more, still more preferably 72 or more, still more preferably 75 or more, and still more preferably 80 or more.

於一態樣中,關於本發明之粉末褐藻,尤其是1重量%分散液之黏度較佳為0.1~1500(mPa‧s),更佳為1.0~1000(mPa‧s),進而較佳為1.0~100(mPa‧s)。有1重量%分散液之黏度越高,於使用含有粉末褐藻之沈澱防止劑之情形時越容易獲得沈澱防止效果之傾向,但若黏度過高,則有容易影響將沈澱防止劑用於飲料等之情形時之食感之傾向。又,有1重量%分散液之黏度越高,於使用含有粉末褐藻之食品改良劑之情形時越容易獲得改良效果之傾向,但若黏度過高,則有使用時之操作變差之傾向。如下述之實施例等所記載之內容般,黏度可於液溫20℃下使用BL型黏度計,以60 rpm之轉速進行測定。 In one aspect, the viscosity of the powdered brown algae, especially the 1% by weight dispersion, of the present invention is preferably 0.1 to 1500 (mPa ‧ s), more preferably 1.0 to 1000 (mPa ‧ s), and further preferably 1.0~100 (mPa‧s). The higher the viscosity of the 1% by weight dispersion, the easier the precipitation prevention effect is when the precipitation inhibitor containing powdered brown algae is used. However, if the viscosity is too high, the precipitation inhibitor is easily affected for use in beverages, etc. The tendency of food sense in the case of the situation. Further, the higher the viscosity of the 1% by weight dispersion liquid, the easier the improvement effect is obtained when the food improving agent containing the powdered brown algae is used. However, if the viscosity is too high, the operation at the time of use tends to be deteriorated. As described in the following examples and the like, the viscosity can be measured at a liquid temperature of 20 ° C using a BL type viscometer at a number of revolutions of 60 rpm.

關於本發明之粉末褐藻,於將粉末褐藻或含有粉末褐藻之沈澱防止劑添加至其他飲料食品、化妝品、日用品、醫藥品等中之情形時,就不對各製品之氣味造成影響之方面而言,或於將含有粉末褐藻之食品改良劑調配至食品等中之情形時,就不對各製品之氣味造成影響之方面而言,較佳為充分降低海藻味。所謂海藻味係指海腥味等源自海藻之獨特香味。海藻味是否降低,可藉由例如與僅將未處理之褐藻及/或褐藻乾燥粉碎而獲得之粉末褐藻進行比較而判斷。於一態樣中,本發明之粉末褐藻較佳為引起令人不快之氣味的1種或複數種物質之含量較低。 With regard to the powdered brown algae of the present invention, when the powdered brown algae or the precipitation inhibitor containing powdered brown algae is added to other beverages, cosmetics, daily necessities, pharmaceuticals, etc., it does not affect the odor of each product. When the food improving agent containing the powdered brown algae is blended into a food or the like, it is preferable to sufficiently reduce the seaweed taste in terms of not affecting the odor of each product. The so-called seaweed flavor refers to the unique flavor derived from seaweed, such as sea bream. Whether or not the seaweed taste is lowered can be judged by, for example, comparing the powdered brown algae obtained by dry-pulverizing only untreated brown algae and/or brown algae. In one aspect, the powdered brown algae of the present invention preferably has a low content of one or more substances which cause an unpleasant odor.

本發明之粉末褐藻可將成為原料之褐藻粉碎、清洗及乾燥而獲得。就清洗效率之觀點而言,較佳為於清洗褐藻前將其粉碎。 The powdered brown algae of the present invention can be obtained by pulverizing, washing and drying the brown algae which are raw materials. From the viewpoint of cleaning efficiency, it is preferred to pulverize the brown algae before washing it.

褐藻之粉碎中,就作業效率之觀點而言,較佳可將乾燥褐藻粉碎。其粉碎程度並無特別限定,但若粉碎程度較低,褐藻之粒子較粗,則無法充分攪拌褐藻,無法清洗至其內部,從而成為殘留有較強之海藻味及海藻色之粉末褐藻,另一方面,若粉碎程度較高,粒子過細,則此次粒子彼此固著。因此,關於粉碎程度,作為粉碎物所通過之篩網之篩孔尺寸,較佳為0.01 mm~4 mm,更佳為0.05 mm~0.45 mm,但並不限定於此。粉碎可藉由業者公知之方法,例如使用槌磨機等之方法而進行。 In the pulverization of brown algae, it is preferred to pulverize dry brown algae from the viewpoint of work efficiency. The degree of pulverization is not particularly limited. However, if the degree of pulverization is low and the particles of brown algae are coarse, the brown algae cannot be sufficiently stirred, and the inside of the algae cannot be washed, and the powdered brown algae having a strong seaweed taste and seaweed color remain. On the one hand, if the degree of pulverization is high and the particles are too fine, the particles are fixed to each other. Therefore, as for the degree of pulverization, the mesh size of the sieve passing through the pulverized material is preferably 0.01 mm to 4 mm, more preferably 0.05 mm to 0.45 mm, but is not limited thereto. The pulverization can be carried out by a method known to the manufacturer, for example, by a method such as a honing machine.

繼而,清洗經粉碎之褐藻。本說明書中,所謂清洗,包括清洗作用及/或脫色作用。清洗可使用含有水、醇及脫 色劑之清洗溶液進行,較佳為使用進而含有鹼之清洗溶液進行。 The pulverized brown algae are then washed. In the present specification, the term "cleaning" includes cleaning action and/or decolorization. Wash can be used with water, alcohol and off The cleaning solution of the toner is preferably carried out using a cleaning solution containing an alkali.

作為用於清洗之醇,例如可列舉甲醇、乙醇、異丙醇、正丙醇等低級醇,該等可單獨使用,亦可組合2種以上使用。就安全性及易獲得性之觀點而言,較佳可使用甲醇或乙醇,更佳可使用乙醇。清洗溶液中之醇含量根據清洗溶液之組成而有所不同,只要為可發揮所需之清洗/脫色作用之量,則並無特別限定,可參照下述之實施例等之記載而決定。例如使用乙醇作為醇之情形時,相對於清洗溶液總量,可使用30 v/v%以上、較佳為35 v/v%以上、例如40~55 v/v%左右之量。 The alcohol to be used for washing may, for example, be a lower alcohol such as methanol, ethanol, isopropyl alcohol or n-propanol. These may be used singly or in combination of two or more. From the viewpoint of safety and availability, it is preferred to use methanol or ethanol, and more preferably ethanol. The content of the alcohol in the cleaning solution varies depending on the composition of the cleaning solution, and is not particularly limited as long as it can exert the required cleaning/decoloring effect, and can be determined by referring to the following examples and the like. For example, when ethanol is used as the alcohol, an amount of 30 v/v% or more, preferably 35 v/v% or more, for example, 40 to 55 v/v% may be used with respect to the total amount of the cleaning solution.

作為用於清洗之脫色劑,可例示次氯酸鈉等氯系漂白劑,過碳酸鈉、過氧化氫、臭氧等氧系漂白劑,二氧化硫脲、二亞硫磺酸鈉等還原系漂白劑。該等中,就易獲得性及安全性等觀點而言,尤其可使用次氯酸鈉或過氧化氫,更佳可使用次氯酸鈉。脫色劑之使用量根據其種類或清洗溶液之組成而有所不同,只要為可發揮所需之清洗/脫色作用之量,則並無特別限定,可參照下述之實施例等之記載而決定。例如使用次氯酸鈉之情形時,相對於下述實施例1所使用程度之量之清洗溶液中之水量,較佳可使用5 mL~700 mL之有效氯濃度12%以上之次氯酸鈉水溶液,更佳可使用200 mL~400 mL。脫色劑之使用量較少之情形時,粉末褐藻之海藻色不會充分降低。 The decolorizing agent to be used for washing may, for example, be a chlorine bleach such as sodium hypochlorite, an oxygen bleach such as sodium percarbonate, hydrogen peroxide or ozone, or a reducing bleach such as thiourea or sodium disulfite. Among these, sodium hypochlorite or hydrogen peroxide can be used in particular from the viewpoints of availability and safety, and sodium hypochlorite can be more preferably used. The amount of the decolorizing agent to be used varies depending on the type of the cleaning solution or the composition of the cleaning solution, and is not particularly limited as long as it can exert the required cleaning/decoloring effect, and can be determined by referring to the following examples and the like. . For example, in the case of using sodium hypochlorite, it is preferable to use 5 mL to 700 mL of an aqueous solution of sodium hypochlorite having an effective chlorine concentration of 12% or more with respect to the amount of water in the cleaning solution used in the following Example 1. 200 mL~400 mL. When the amount of the decolorizing agent used is small, the seaweed color of the powdered brown algae is not sufficiently lowered.

作為用於清洗之鹼,可使用有機鹼金屬鹽及無機鹼金屬 鹽,例如可列舉:檸檬酸鈉、檸檬酸鉀、酒石酸鈉、蘋果酸鈉、乙酸鈉、乳酸鈉、琥珀酸鈉、琥珀酸鉀、多磷酸鈉、多磷酸鉀、焦磷酸鈉、焦磷酸鉀、磷酸鈉、磷酸鉀、碳酸鈉、碳酸氫鈉、碳酸鉀、氫氧化鈉、氫氧化鉀等。作為較佳之例,可列舉:碳酸氫鈉、碳酸鈉、碳酸鉀,尤佳可使用碳酸鈉。該等可單獨使用,亦可組合2種以上使用。又,該等鹼可使用晶體、水合物、無水物之任一形態者。鹼之使用量根據其種類或清洗溶液之組成而有所不同,只要為可發揮所需之清洗/脫色作用之量,則並無特別限定,可參照下述之實施例等之記載而決定。例如使用碳酸鈉之情形時,相對於下述實施例1所使用程度之量之清洗溶液中之水量,較佳可添加1 g~50 g,更佳可添加5 g~25 g。 As the base for washing, an organic alkali metal salt and an inorganic alkali metal can be used. Examples of the salt include sodium citrate, potassium citrate, sodium tartrate, sodium malate, sodium acetate, sodium lactate, sodium succinate, potassium succinate, sodium polyphosphate, potassium polyphosphate, sodium pyrophosphate, potassium pyrophosphate, Sodium phosphate, potassium phosphate, sodium carbonate, sodium hydrogencarbonate, potassium carbonate, sodium hydroxide, potassium hydroxide, and the like. As a preferable example, sodium hydrogencarbonate, sodium carbonate, and potassium carbonate are mentioned, and sodium carbonate is especially preferable. These may be used alone or in combination of two or more. Further, as the base, any form of crystal, hydrate or anhydrate can be used. The amount of the base to be used varies depending on the type thereof or the composition of the cleaning solution, and is not particularly limited as long as it can exert the desired cleaning/decoloring effect, and can be determined by referring to the following examples and the like. For example, in the case of using sodium carbonate, it is preferred to add 1 g to 50 g, more preferably 5 g to 25 g, to the amount of water in the cleaning solution in an amount to be used in the following Example 1.

使用上述各成分之清洗可將除水以外之各成分分別溶解於水中,依序用作清洗溶液,亦可將除水以外之各成分中之2種以上組合而溶解於水中,依序用作清洗溶液。清洗可根據作為目的之清洗/脫色之程度而進行複數次。為方便起見,可以將除水以外之各成分全部溶解於水中而成之溶液作為清洗溶液而使用。 Each of the components other than water may be dissolved in water, and may be used as a cleaning solution in sequence, or two or more of the components other than water may be combined and dissolved in water, and sequentially used as a cleaning solution. Wash the solution. The cleaning can be carried out plural times depending on the degree of cleaning/decoloration for the purpose. For the sake of convenience, a solution obtained by dissolving all components other than water in water may be used as a cleaning solution.

清洗中,作為清洗對象之經粉碎之褐藻與清洗溶液之重量比並無特別限定,例如較佳為經粉碎之褐藻(g):清洗溶液(mL)=1:5~1:100,更佳為1:20~1:50。清洗係將經粉碎之褐藻與清洗溶液混合,較佳為攪拌5分鐘以上,就清洗效率之觀點而言,更佳為攪拌30分鐘以上之程度而進 行。為方便起見,攪拌可於室溫下進行,若為所使用之醇之沸點以下,則亦可進行加熱。 In the cleaning, the weight ratio of the pulverized brown algae to the washing solution to be cleaned is not particularly limited, and for example, preferably pulverized brown algae (g): washing solution (mL) = 1:5 to 1:100, more preferably It is 1:20~1:50. The washing system mixes the pulverized brown algae with the washing solution, preferably for stirring for 5 minutes or more, and more preferably, for the purpose of washing efficiency, it is more preferably stirred for 30 minutes or more. Row. For the sake of convenience, the stirring can be carried out at room temperature, and if it is at most the boiling point of the alcohol used, heating can also be carried out.

上述之清洗後,經由乾燥步驟可獲得粉末褐藻。乾燥可藉由於上述清洗後,將藉由過濾除去溶液而獲得之殘渣加以乾燥而進行。過濾可按照慣例,使用濾布、濾紙等進行。乾燥可使用加熱乾燥、減壓乾燥、冷凍乾燥等公知之方法進行。就簡便性之觀點而言,較佳可使用加熱乾燥。進行加熱乾燥之情形時之溫度及時間可進行適當設定,若溫度過高,則有粉末褐藻之色彩變濃之情形,若溫度過低,則乾燥所需時間較長,故可於60℃~90℃左右之溫度下進行乾燥。乾燥時間並無特別限制,根據乾燥溫度,可進行30分鐘~6小時左右。乾燥後,可視需要進而藉由粉碎機將乾燥物粉碎。 After the above washing, powdered brown algae can be obtained through a drying step. Drying can be carried out by drying the residue obtained by removing the solution by filtration after the above washing. Filtration can be carried out by using a filter cloth, filter paper, or the like according to a convention. Drying can be carried out by a known method such as heat drying, reduced pressure drying, or freeze drying. From the standpoint of simplicity, it is preferred to use heat drying. The temperature and time when heating and drying can be appropriately set. If the temperature is too high, the color of the powdered brown algae becomes rich. If the temperature is too low, the drying takes a long time, so it can be 60 ° C~ Drying is carried out at a temperature of about 90 °C. The drying time is not particularly limited, and it can be carried out for about 30 minutes to 6 hours depending on the drying temperature. After drying, the dried product is further pulverized by a pulverizer as needed.

藉由以上方法而獲得之粉末褐藻與僅將褐藻乾燥後粉末化而獲得者相比,特徵在於水溶性褐藻膠成分較多、不溶性褐藻膠成分等不溶性成分較少。作為不溶性成分之詳細內容,亦具有不溶性褐藻膠成分較少,不溶性食物纖維(纖維素、半纖維素等)較多的特徵。又,由於係藉由不包括提取褐藻中之特定成分之步驟的方法而獲得,與藉由包括提取特定成分之步驟的方法而獲得者相比,特徵在於除該特定成分以外之成分、例如褐藻中所含之食物纖維等成分之含量較多。作為褐藻之成分,已知有海藻酸、褐藻糖膠、岩藻黃素、纖維素、半纖維素、昆布糖、糖醛酸、多糖醛酸、硫酸多糖、蛋白質、脂質、無機質等。 The powdered brown algae obtained by the above method is characterized by a large amount of water-soluble alginate components and insoluble components such as insoluble alginate components, compared with those obtained by drying only brown algae and then pulverizing them. As a detail of the insoluble component, the insoluble alginate component is less, and the insoluble dietary fiber (cellulose, hemicellulose, etc.) is many. Further, since it is obtained by a method not including a step of extracting a specific component in brown algae, compared with a person obtained by a method including a step of extracting a specific component, a component other than the specific component, such as brown algae The content of dietary fiber and other ingredients contained in the food is high. As a component of brown algae, alginic acid, fucoidan, fucoxanthin, cellulose, hemicellulose, laminaria, uronic acid, polysaccharide aldehyde acid, sulfated polysaccharide, protein, lipid, inorganic substance and the like are known.

於一態樣中,本發明之粉末褐藻若添加至含沈澱粒子之溶液中,則發揮防止沈澱粒子沈澱之作用,因此可用作沈澱防止劑。因此,本發明提供含有上述粉末褐藻之沈澱防止劑,較佳為提供包含上述粉末褐藻之沈澱防止劑。又,本發明亦提供包括將上述粉末褐藻添加至含沈澱粒子之溶液中之步驟的沈澱防止方法。 In one aspect, the powdered brown algae of the present invention acts as a precipitation preventing agent when it is added to a solution containing precipitated particles to prevent sedimentation of precipitated particles. Accordingly, the present invention provides a precipitation preventing agent containing the above-mentioned powder brown algae, and preferably provides a precipitation preventing agent containing the above-mentioned powder brown algae. Further, the present invention also provides a precipitation preventing method comprising the step of adding the above-mentioned powdered brown algae to a solution containing precipitated particles.

本說明書中,所謂由沈澱防止劑產生之沈澱防止作用係指若向於未添加沈澱防止劑之情形時靜置後經過一定時間(例如,製造剛完成後~6個月)會產生沈澱之溶液(含沈澱粒子之溶液)中添加沈澱防止劑,則會防止沈澱產生之作用。與未添加之情形相比,沈澱產生之防止包括不產生沈澱、延遲沈澱之產生及減少沈澱之產生量。例如較佳為將本發明之沈澱防止劑添加至含沈澱粒子之溶液中,靜置數天~數週、或根據含沈澱粒子之溶液之種類靜置數週~數月左右後,以目視未確認到產生沈澱物。通常稱作增黏劑者,可藉由使液體增黏而防止沈澱物之產生,但有因黏度提高而導致液體之觸感(例如於飲料食品之情形時之吞咽感或食感,於化妝品或醫藥品之情形時之使用感等)可大幅度變化之缺點。本發明之沈澱防止劑不會大幅提高液體之黏度,可防止沈澱物之產生,因此不僅有於使用前無需為了使沈澱粒子分散而進行攪拌之優點,且由於黏度較低,故而有對容器之制約較少、以噴霧等塗佈時可進行較廣範圍之塗佈等優點。又,由於黏度較低,因此例如若為食品,則有吞咽感或食感較佳之優點,若為化妝品或醫藥 品,則有使用感清爽之優點。 In the present specification, the precipitation preventing action by the precipitation preventing agent means a solution which precipitates after a certain period of time (for example, ~6 months after the completion of the production) if the precipitation preventing agent is not added. When a precipitation inhibitor is added to the solution containing the precipitated particles, the effect of precipitation is prevented. Precipitation prevention includes no precipitation, delayed precipitation, and reduced precipitation generation compared to the case where no addition is made. For example, it is preferred to add the precipitation preventing agent of the present invention to a solution containing precipitated particles, to stand for several days to several weeks, or to stand for several weeks to several months depending on the type of the solution containing the precipitated particles, and visually unconfirmed. To produce a precipitate. Usually called tackifier, it can prevent the formation of sediment by making the liquid thicker, but it can cause the touch of liquid due to the increase of viscosity (for example, swallowing or food in the case of beverages and foods, in cosmetics). Or the sense of use in the case of pharmaceuticals, etc.) can be greatly changed. The precipitation preventing agent of the present invention does not greatly increase the viscosity of the liquid, and can prevent the generation of precipitates. Therefore, there is no need to stir the precipitated particles before use, and since the viscosity is low, there is a container. There are few restrictions, and it is possible to apply a wide range of coatings when applied by spraying or the like. Moreover, since the viscosity is low, for example, if it is a food, it has the advantage of being swallowed or having a good food feeling, if it is a cosmetic or a medicine. The product has the advantage of refreshing use.

成為添加本發明之沈澱防止劑之對象的溶液為含沈澱粒子之溶液。所謂含沈澱粒子之溶液,如上所述係指靜置後經過一定時間(例如製造剛完成後~6個月)會產生沈澱之溶液。本說明書中,將成為該沈澱之粒子稱作沈澱粒子,沈澱粒子可為乳化球(液體),亦可為粉末(固體)。例如亦可為含有液體及/或固體之蛋白質之沈澱粒子。作為此種含沈澱粒子之溶液之例,例如可列舉含有各種乳化球、各種粒子、各種粉末或組合該等中之2者以上而含有之溶液。就本發明之沈澱防止劑為部分水溶性之觀點而言,溶液較佳為以水溶性基材作為基底者。 The solution to be added to the object of the precipitation preventing agent of the present invention is a solution containing precipitated particles. The solution containing precipitated particles, as described above, refers to a solution which will precipitate after a certain period of time (for example, ~6 months after the completion of the production) after standing. In the present specification, the particles to be precipitated are referred to as precipitated particles, and the precipitated particles may be emulsified spheres (liquid) or powder (solid). For example, it may be a precipitated particle containing a liquid and/or a solid protein. Examples of the solution containing the precipitated particles include a solution containing various emulsified spheres, various particles, various powders, or a combination of two or more of them. From the viewpoint that the precipitation preventing agent of the present invention is partially water-soluble, the solution is preferably a water-soluble substrate as a substrate.

作為含沈澱粒子之溶液之具體例,可例示:作為含有各種乳化球、各種粒子及/或各種粉末之飲料的含蛋白質之飲料,具體為加工乳、普通乳、濃厚乳、低脂乳、脫脂乳、乳飲料(例如咖啡飲料、奶茶、可可飲料等)、醱酵乳飲料、豆乳、豆乳飲料、乳油、咖啡奶精、酸乳酪、乳酸菌飲料、煉乳;加入有沈澱成分之茶飲料;調配粉末之茶飲料,具體為調配有各種粉末(茶粉末等)之各種茶等;蔬菜汁、果汁等加入有食物纖維等沈澱成分之飲料,具體為果實飲料、碳酸果實飲料、粉末清涼飲料、粉末即席飲料(粉末檸檬茶、粉末小豆湯等)、甜米酒等;加入有各種果凍之飲料等。亦可例示進而於該等飲料中添加殼物粉(玉米粉、大麥粉、米粉、豆粉、黃豆粉等)而成者。 Specific examples of the solution containing the precipitated particles include protein-containing beverages as beverages containing various emulsified spheres, various particles, and/or various powders, specifically processed milk, ordinary milk, thick milk, low fat milk, and degreased. Milk, milk beverage (eg coffee beverage, milk tea, cocoa beverage, etc.), fermented milk beverage, soymilk, soymilk beverage, emulsifiable concentrate, coffee creamer, yoghurt, lactic acid bacteria beverage, condensed milk; tea beverage with precipitated ingredients; powder blending The tea beverage is specifically a variety of teas prepared with various powders (tea powder, etc.); vegetable juices, juices, and the like, which are added with a precipitating component such as dietary fiber, specifically fruit drinks, carbonated fruit drinks, powdered refreshing drinks, powdery instant drinks. (Powdered lemon tea, powdered bean soup, etc.), sweet rice wine, etc.; and various kinds of jelly drinks are added. It is also possible to exemplify the addition of shell powder (corn flour, barley flour, rice flour, soy flour, soy flour, etc.) to the beverages.

作為食品、調味料,可例示含有各種固體調味料之調味 品、醬料等,具體而言,可列舉清肉湯、醬油、各種醬料(伍斯特郡辣醬油、多明格拉斯醬、麵醬、白醬料、蠔油、番茄醬、烤肉之調味汁、火鍋漿料、蓋飯漿料等)、各種調味品、蛋黃醬型調味料、各種麵粉糊(咖哩露等)、麵醬油等。 As foods and seasonings, seasonings containing various solid seasonings can be exemplified Products, sauces, etc., specifically, can be broth, soy sauce, various sauces (Worcestershire spicy sauce, Dominglas sauce, noodle sauce, white sauce, oyster sauce, tomato sauce, barbecue seasoning Juice, hot pot paste, rice cake slurry, etc.), various seasonings, mayonnaise-type seasonings, various flour pastes (curry gel, etc.), noodles and so on.

作為化妝品,可例示含有各種乳化球、各種粒子及/或各種粉末之化妝水、乳液、清潔液、洗髮精、護髮素、防曬霜、漱口液、生髮劑等。作為日用品,可例示含有各種乳化球、各種粒子及/或各種粉末之洗潔劑、上漿劑、除臭劑、漂白劑、柔軟劑、芳香劑、除蟲劑、釉藥溶液、水系塗料等。作為醫藥品,可例示含有各種乳化球、各種粒子或各種粉末之內服液、塗佈液等。 As the cosmetic, a lotion, an emulsion, a cleansing liquid, a shampoo, a conditioner, a sunscreen, a mouthwash, a hair restorer, and the like containing various emulsified spheres, various particles, and/or various powders can be exemplified. Examples of the daily necessities include detergents, sizing agents, deodorants, bleaches, softeners, fragrances, insecticides, glaze solutions, water-based paints, and the like which contain various emulsified spheres, various particles, and/or various powders. . The pharmaceutical product may, for example, be an internal liquid or a coating liquid containing various emulsified spheres, various particles or various powders.

本發明之沈澱防止劑係源自褐藻,就可飲用食用且安全性較高之觀點而言,作為添加沈澱防止劑之對象之含沈澱粒子之溶液較佳為飲料、食品、調味料、化妝品或醫藥品。又,就即便對於藉由作為先前公知之沈澱防止劑之代表例的鹿角菜膠難以防止沈澱之溶液亦可防止沈澱之觀點而言,本發明之沈澱防止劑較佳為含有乳蛋白質、大豆蛋白質、豌豆蛋白質、小麥蛋白質、米蛋白質、血漿蛋白質、源自椰子之蛋白質等各種蛋白質的含蛋白質之飲料。 The precipitation preventing agent of the present invention is derived from brown algae, and the solution containing the precipitated particles as a target for adding a precipitation preventing agent is preferably a beverage, a food, a seasoning, a cosmetic or a viewpoint of being drinkable and safe. Pharmaceutical products. In addition, the precipitation preventive agent of the present invention preferably contains milk protein, soy protein, even from the viewpoint that it is difficult to prevent the precipitation of the carrageenan as a representative example of the previously known precipitation preventive agent, and the precipitation prevention agent is preferably contained. Protein-containing beverages of various proteins such as pea protein, wheat protein, rice protein, plasma protein, and protein derived from coconut.

含沈澱粒子之溶液中之沈澱粒子之含有比率並無特別限定,例如為總重量之0.01~50.0重量%,較佳為0.1~20.0重量%。 The content ratio of the precipitated particles in the solution containing the precipitated particles is not particularly limited, and is, for example, 0.01 to 50.0% by weight, preferably 0.1 to 20.0% by weight based on the total weight.

於含沈澱粒子之溶液中作為沈澱防止劑而添加之粉末褐 藻之量根據成為沈澱防止之對象之溶液的組成而有所不同,較佳為總重量之0.01~20.0重量%,就獲得所需之沈澱防止作用之觀點及經濟性之觀點而言,更佳為0.01~5.0重量%,進而較佳為0.1~1.0重量%。 Powder brown added as a precipitation preventive agent in a solution containing precipitated particles The amount of the algae varies depending on the composition of the solution to be prevented by the precipitation, and is preferably from 0.01 to 20.0% by weight based on the total weight, and is more preferable from the viewpoint of obtaining a desired precipitation prevention effect and economy. It is 0.01 to 5.0% by weight, and more preferably 0.1 to 1.0% by weight.

藉由本發明之沈澱防止劑而防止沈澱之含沈澱粒子之溶液的黏度並無特別限定,由於本發明之沈澱防止劑可在不使對象液之黏度大幅度增加之情況下發揮沈澱防止作用,故較佳為0.1 mPa‧s~200 mPa‧s,更佳為1 mPa‧s~100 mPa‧s。例如,即便為1 mPa‧s~50 mPa‧s、1 mPa‧s~30 mPa‧s等較低黏度,本發明之沈澱防止劑亦可發揮沈澱防止作用。 The viscosity of the solution containing the precipitated particles to be precipitated by the precipitation preventing agent of the present invention is not particularly limited, and the precipitation preventing agent of the present invention can exhibit a precipitation preventing effect without greatly increasing the viscosity of the target liquid. It is preferably 0.1 mPa‧s to 200 mPa‧s, more preferably 1 mPa‧s to 100 mPa‧s. For example, the precipitation preventive agent of the present invention can exert a precipitation preventing effect even at a low viscosity such as 1 mPa‧s to 50 mPa‧s and 1 mPa‧s to 30 mPa‧s.

上述含沈澱粒子之溶液均可利用先前公知之製造方法而製造,藉由添加本發明之沈澱防止劑,可防止沈澱粒子之沈澱。 The solution containing the precipitated particles can be produced by a conventionally known production method, and precipitation of precipitated particles can be prevented by adding the precipitation preventive agent of the present invention.

又,本發明亦關於含有上述粉末褐藻之食品改良劑。食品改良劑只要為含有上述粉末褐藻者,則並無特別限定。例如視需要亦可含有現有之分散助劑(糖類、澱粉類等)等,以使向食品中之調配變得容易。又,本發明之食品改良劑根據其用途,亦可進而含有選自例如多糖類、纖維質、大豆相關物質、澱粉、糖類、糖醇、甜味料、乳製品、蛋白質、油脂、酶、維生素、乳化劑、食品原材料、製造用劑、效價調整劑、pH值調整劑、香辛料、抗氧化劑、強化劑、膨脹劑、調味劑、著色劑、防腐劑、調味料等公知之食品用原料或添加物中之1種以上成分,亦可與 該等成分之1種以上併用。 Further, the present invention also relates to a food improving agent containing the above powdered brown algae. The food improving agent is not particularly limited as long as it contains the powdered brown algae. For example, a conventional dispersing aid (sugar, starch, etc.) or the like may be contained as needed to facilitate the preparation into food. Further, the food improving agent of the present invention may further contain, for example, a polysaccharide, a fiber, a soybean-related substance, a starch, a sugar, a sugar alcohol, a sweetener, a dairy product, a protein, a fat, an enzyme, a vitamin, depending on the use thereof. Raw materials for foods such as emulsifiers, food materials, manufacturing agents, potency adjusters, pH adjusters, spices, antioxidants, fortifiers, bulking agents, flavoring agents, coloring agents, preservatives, seasonings, etc. One or more components in the additive may also be combined with One or more of these components are used in combination.

於一態樣中,本發明之食品改良劑較佳為麵粉食品改良劑或食品之增黏凝膠化改良劑。本說明書中,所謂「麵粉食品改良劑」係指具有改良下述之麵粉食品之作用(例如改良食感、紋理、體積、嗜好性等之作用)的改良劑。 In one aspect, the food improving agent of the present invention is preferably a flour food improver or a viscosity-increasing gelatinizing agent for foods. In the present specification, the "flour food improving agent" refers to an improving agent having an effect of improving the following flour foods (for example, improving the effects of texture, texture, volume, and taste).

本說明書中,所謂「增黏凝膠化改良劑」係指具有主要藉由發揮增黏凝膠化作用(增黏作用、凝膠化作用或伴有該兩者之作用)而改良食品之作用的改良劑。作為此種增黏凝膠化改良劑,可列舉可賦予增黏凝膠化以及由增黏凝膠化作用產生之增黏、凝膠化、穩定、澱粉膠黏、食感改良、物性改良(保形性改良、保水性改良等)、體積控制、乳化控制、脫水收縮防止(乳清分離防止等)、耐熱(賦予抗熱震性等)、凝固、包衣(冷凍食品時之品質維持等)、軟化、分散、滲透(色素滲透等)、氣泡量控制、剝離、脫模、膨脹率控制、彈力改良、良率提高、膜形成等中之1種以上效果之改良劑。因此,本說明書中之「增黏凝膠化改良劑」中包括例如食品之增黏劑、凝膠化劑、穩定劑、澱粉接著劑、食感改良劑、物性改良劑(保形性改良劑、保水性改良劑等)、體積控制劑、乳化控制劑、脫水收縮防止劑(乳清分離防止劑等)、耐熱劑(抗熱震性賦予劑等)、凝固劑、包衣劑、軟化劑、分散劑、滲透劑、氣泡量控制劑、剝離劑、脫模劑、膨脹率控制劑、彈力改良劑、良率提高劑、膜形成劑等。 In the present specification, the term "viscosifying gelation improving agent" means a function of improving food by mainly exerting a viscosity-increasing gelation effect (adhesion, gelation, or both). Amendment. Examples of such a viscosity-increasing gelation-improving agent include viscosity-increasing gelation and viscosity-increasing gelation, gelation, stabilization, starch adhesion, food texture improvement, and physical property improvement ( (shape retention improvement, water retention improvement, etc.), volume control, emulsification control, syneresis prevention (whey separation prevention, etc.), heat resistance (giving thermal shock resistance, etc.), coagulation, coating (quality maintenance during frozen food, etc.) ), an agent for softening, dispersing, infiltrating (pigmenting, etc.), controlling the amount of bubbles, peeling, demolding, expansion rate control, elastic strength improvement, yield improvement, film formation, and the like. Therefore, the "viscosifying gelation improver" in the present specification includes, for example, a tackifier, a gelling agent, a stabilizer, a starch adhesive, a food texture improving agent, and a physical property improving agent (conformity improving agent). , water retention improver, etc.), volume control agent, emulsification control agent, syneresis preventive agent (whey separation inhibitor, etc.), heat-resistant agent (anti-thermal shock imparting agent, etc.), coagulant, coating agent, softener , a dispersing agent, a penetrating agent, a bubble amount controlling agent, a releasing agent, a releasing agent, an expansion ratio controlling agent, an elastic modifier, a yield improving agent, a film forming agent, and the like.

由於本發明之食品改良劑含有上述粉末褐藻,故而較佳 為粉末狀之形態,但亦可對其進行二次加工,使其成為糊劑狀、固體狀、液體狀、顆粒狀、膠囊狀或錠狀。可將該等直接調配至食品中,亦可於使用前將其溶解、分散至水等中而使用。尤其是將本發明之食品改良劑用作食品之增黏凝膠化改良劑之情形時,就充分獲得增黏凝膠化帶來之改良作用之觀點而言,較佳可於食品之製造過程中將本發明之食品改良劑分散、溶解至水等中而使用。 Since the food improving agent of the present invention contains the above-mentioned powder brown algae, it is preferred It is in the form of a powder, but it may be subjected to secondary processing to form a paste, a solid, a liquid, a granule, a capsule or a tablet. These may be directly formulated into a food, or may be used by dissolving and dispersing it in water or the like before use. In particular, when the food improving agent of the present invention is used as a viscosity-increasing gelatinizing agent for foods, it is preferably in the production process of foods from the viewpoint of sufficiently improving the effect of viscosity-increasing gelation. The food improving agent of the present invention is used by dispersing and dissolving it in water or the like.

本發明之食品改良劑向食品中之調配量只要可獲得所需之改良效果,則並無特別限定,可根據調配其之食品,考慮具有相同之改良作用之食品添加物之添加量等而適當決定。於一態樣中,食品改良劑中之上述粉末褐藻相對於全部粉體原料或食品原料,較佳為含有0.01重量%以上,更佳為含有0.01~20.0重量%,進而較佳為含有0.05~10.0重量%。再者,本說明書中,所謂「相對於粉體原料」之「粉體原料」係指用於欲製造之食品之生麵團中之粉體原料(例如麵粉、澱粉、米粉、大麥粉、蕎麥粉、豆粉、加工澱粉、黑麥粉、玉米粉、烤大豆粉、道明寺粉、黍粉、穀粉、稗粉等)的總量。 The amount of the food-improving agent of the present invention to be added to the food is not particularly limited as long as the desired improvement effect can be obtained, and it is possible to appropriately consider the amount of the food additive having the same improvement effect, etc., depending on the food to be blended. Decide. In one aspect, the powdered brown algae in the food improving agent preferably contains 0.01% by weight or more, more preferably 0.01% to 20.0% by weight, and even more preferably 0.05%, based on the entire powder raw material or food material. 10.0% by weight. In the present specification, the "powder material" relative to the "powder material" means the powder material (for example, flour, starch, rice flour, barley flour, buckwheat flour) used in the dough of the food to be manufactured. The total amount of soybean powder, processed starch, rye flour, corn flour, roasted soybean meal, Dominican powder, glutinous rice flour, flour, and lotus root starch.

於一態樣中,於使用本發明之食品改良劑作為麵粉食品改良劑之情形時,麵粉食品改良劑中之上述粉末褐藻相對於麵粉,較佳為含有0.01重量%以上,更佳為含有0.01~50.0重量%,進而較佳為含有0.01~20.0重量%,尤佳為含有0.05~10.0重量%。 In one aspect, in the case of using the food improving agent of the present invention as a flour food improving agent, the powdered brown algae in the flour food improving agent preferably contains 0.01% by weight or more, more preferably 0.01%, based on the flour. It is preferably from 5 to 20.0% by weight, more preferably from 0.01 to 20.0% by weight, even more preferably from 0.05 to 10.0% by weight.

於一態樣中,於使用本發明之食品改良劑作為食品之增 黏凝膠化改良劑之情形時,增黏凝膠化改良劑中之上述粉末褐藻相對於原料中之水(亦包括除水以外之液體原料中之水),較佳為含有0.01重量%以上,更佳為含有0.01~50.0重量%,進而較佳為含有0.05~20.0重量%,尤佳為含有0.1~15.0重量%。 In one aspect, the use of the food improver of the present invention as an increase in food In the case of a viscogelation improver, the powdered brown algae in the viscosity-increasing gelatinizing agent preferably contains 0.01% by weight or more with respect to water in the raw material (including water in a liquid raw material other than water). More preferably, it is 0.01 to 50.0% by weight, further preferably 0.05 to 20.0% by weight, and particularly preferably 0.1 to 15.0% by weight.

本發明之食品改良劑可單獨用於食品中,亦可與已知之食品改良劑併用。與已知之食品改良劑併用之情形時,可適當調整使用量。 The food improver of the present invention can be used alone in foods or in combination with known food improvers. When it is used in combination with a known food improver, the amount of use can be appropriately adjusted.

尤其是藉由本發明之食品改良劑將水等液體增黏、凝膠化、凝固之情形時(用作凝膠化劑之情形時),較佳為藉由與鈣併用,可容易地增黏、凝膠化、凝固。與鈣之併用可使用含有鈣之原料而進行。作為此種原料,只要為含有鈣、可調配至食品中之原料,則並無特別限定,較佳為食品用原料,例如可使用氯化鈣、檸檬酸鈣、甘油磷酸鈣、葡萄糖酸鈣、氫氧化鈣、碳酸鈣、乳酸鈣、泛酸鈣、焦磷酸二氫鈣、硫酸鈣、磷酸三鈣、磷酸氫鈣、磷酸二氫鈣、丙酸鈣、羧甲基纖維素鈣、硬脂醯乳酸鈣、貝殼煅燒鈣、蛋殼煅燒鈣、骨煅燒鈣、海膽煅燒鈣、珊瑚煅燒鈣、磷酸三鈣、貝殼非煅燒鈣、珊瑚非煅燒鈣、蛋殼非煅燒鈣、骨非煅燒鈣、珍珠層非煅燒鈣、骨炭、生石灰。該等可單獨使用,亦可組合2種以上使用。 In particular, when the liquid such as water is viscous, gelled, or solidified by the food improving agent of the present invention (when used as a gelling agent), it is preferably used in combination with calcium to easily be viscous. , gelatinization, solidification. The combination with calcium can be carried out using a raw material containing calcium. The raw material is not particularly limited as long as it is calcium-containing and can be blended into a food, and is preferably a food material. For example, calcium chloride, calcium citrate, calcium glycerophosphate, calcium gluconate, or the like can be used. Calcium hydroxide, calcium carbonate, calcium lactate, calcium pantothenate, calcium dihydrogen pyrophosphate, calcium sulfate, tricalcium phosphate, calcium hydrogen phosphate, calcium dihydrogen phosphate, calcium propionate, calcium carboxymethyl cellulose, stearic acid lactic acid Calcium, shell calcined calcium, eggshell calcined calcium, bone calcined calcium, sea urchin calcined calcium, coral calcined calcium, tricalcium phosphate, shell non-calcined calcium, coral non-calcined calcium, eggshell non-calcined calcium, bone non-calcined calcium, pearl Layer non-calcined calcium, bone charcoal, quicklime. These may be used alone or in combination of two or more.

含有鈣之原料之使用量可根據欲獲得之食品之形態等進行適當調整,以鈣成分換算計,較佳為全部食品之0.01~50重量份,更佳為0.1~25重量份,進而較佳為0.5~15 重量份。藉由將本發明之食品改良劑與微量之鈣併用,與未併用時相比,可獲得較高之增黏效果,藉由與更多量之鈣併用,可容易地獲得較高之凝膠化、凝固效果。 The amount of the raw material containing calcium can be appropriately adjusted depending on the form of the food to be obtained, and is preferably from 0.01 to 50 parts by weight, more preferably from 0.1 to 25 parts by weight, based on the total amount of the calcium, more preferably from 0.1 to 25 parts by weight. 0.5~15 Parts by weight. By using the food improving agent of the present invention in combination with a trace amount of calcium, a higher viscosity-increasing effect can be obtained as compared with when not used in combination, and a higher gel can be easily obtained by using in combination with a larger amount of calcium. Chemical and solidification effects.

併用本發明之食品改良劑與含有鈣之原料之情形時,只要可獲得所需之改良效果,則其使用方法並無特別限制,尤其是於將水等液體凝膠化、凝固之情形時,較佳為分別準備本發明之食品改良劑之分散溶解液與含有鈣之原料之分散溶解液,於非加熱或加熱下混合兩者,以進行均勻之凝膠化、凝固。混合較佳為於攪拌下進行,以進行均勻之凝膠化、凝固。 When the food improving agent of the present invention and the raw material containing calcium are used in combination, the method of use is not particularly limited as long as the desired improvement effect can be obtained, especially when a liquid such as water is gelled or solidified. It is preferred to separately prepare a dispersion solution of the food-improving agent of the present invention and a dispersion solution of a material containing calcium, and mix them under non-heating or heating to perform uniform gelation and solidification. The mixing is preferably carried out under stirring to effect uniform gelation and solidification.

含有上述粉末褐藻之食品改良劑可廣泛調配至各種食品中。因此,本發明亦提供調配有上述之本發明之食品改良劑的食品。本發明之食品藉由調配本發明之食品改良劑,如下述之實施例所示,食感、紋理、體積、保形性、保水性、嗜好性等獲得改良。並非受理論所束縛,認為此種改良之原因在於:藉由本發明之食品改良劑,根據調配之食品而賦予增黏、凝膠化、穩定、澱粉膠黏、食感改良、物性改良(保形性改良、保水性改良等)、體積控制、乳化控制、脫水收縮防止(乳清分離防止等)、耐熱(抗熱震性賦予等)、凝固、包衣、軟化、分散、滲透、氣泡量控制、剝離、脫模、膨脹率控制、彈力改良、良率提高、膜形成等中之1種以上效果。 The food improver containing the above powdered brown algae can be widely formulated into various foods. Accordingly, the present invention also provides a food product formulated with the above-described food improver of the present invention. The food of the present invention is improved by blending the food improving agent of the present invention as shown in the following examples, and the texture, texture, volume, shape retention, water retention, taste, and the like are improved. It is not bound by theory, and the reason for such improvement is that the food improving agent of the present invention imparts viscosity, gelation, stability, starch adhesion, food texture improvement, and physical property improvement according to the formulated food (conformity) Improvement, water retention improvement, etc.), volume control, emulsification control, syneresis prevention (whey separation prevention, etc.), heat resistance (thermal shock resistance, etc.), solidification, coating, softening, dispersion, penetration, bubble volume control One or more effects of peeling, mold release, expansion ratio control, elastic strength improvement, yield improvement, and film formation.

例如,並非受理論所束縛,本發明之食品改良劑所含之本發明之粉末褐藻之分散液之黏度為於食品中調配時易於 操作之黏度,例如添加至麵粉食品中之情形時,可控制生麵團黏度或氣泡性。又,本發明之食品改良劑所含之粉末褐藻調配至液體中之後,無論有無加熱步驟,均可使液體增黏凝膠化,伴隨此種作用,可控制食感、紋理、體積、保形性、保水性、嗜好性等。 For example, it is not bound by theory, and the viscosity of the dispersion of the powdered brown algae of the present invention contained in the food improving agent of the present invention is easy to prepare in a food product. The viscosity of the operation, for example, when added to a flour food, controls the viscosity or bubble of the dough. Moreover, after the powdered brown algae contained in the food improving agent of the present invention is formulated into a liquid, the liquid can be gelatinized by the heating step, with or without the heating action, and the food texture, texture, volume, and conformal shape can be controlled. Sex, water retention, hobbies, etc.

又,若使用可賦予食品以上述1種以上效果之本發明之食品改良劑,藉由改良食感等,不僅可改良食品,使其變得「美味」,亦可改良所使用之原料品質較低之食品(例如降低麵粉品質之麵粉食品等)之各種特性,故而亦可改良食品而使其變得「廉價」。進而,由於可改良食品之食感或物性,使其易於加工,故而亦可改良食品以使其可更「簡便地利用」,於產業上有利。 In addition, by using a food improving agent of the present invention which can impart the above-described effects or more to the food, it is possible to improve the food quality and improve the food quality, and to improve the quality of the raw materials used. Low foods (such as flour foods that reduce flour quality, etc.) can be modified to make them "cheap". Further, since the food texture or physical properties of the food can be improved and the processing is easy, the food can be improved to make it more "easy to use", which is industrially advantageous.

進而,根據本發明之食品改良劑,如下述之實施例所記載,可獲得不遜於先前之用於食品改良之食品添加物之改良效果,因此可代替食品添加物。藉此,可消除因不使用食品添加物而產生之各種問題(例如價格高,味道、氣味、香味、外觀、色彩、食感較差,味道、氣味、香味、外觀、色彩、食感隨時間經過之變化較大,難以加工等),可解除或減少與可提供之作為食品之原料(例如若為麵粉食品,則為麵粉之品種等)、食品之種類、提供地點、提供時間、提供方法及製造方法等相關之限制。 Further, according to the food improving agent of the present invention, as described in the following examples, an improvement effect of the food additive for food improvement which is not inferior to the prior art can be obtained, and therefore, the food additive can be replaced. Thereby, various problems caused by not using food additives can be eliminated (for example, high price, taste, smell, aroma, appearance, color, poor food taste, taste, smell, aroma, appearance, color, food texture over time) The change is large, it is difficult to process, etc.), and the raw materials that can be provided as food (for example, flour varieties, etc.), the type of food, the place of supply, the time of providing, the method of providing, and the method of providing Related methods of manufacturing methods and the like.

作為可由本發明之食品改良劑代替之食品添加物等,可列舉具有欲獲得之作用之已知食品添加物等,例如可例示微晶纖維素、粉末纖維素、果膠、海藻酸鈉、海藻酸、海 藻酸酯、鹿角菜膠、卡德蘭膠、古亞膠、三仙膠、刺槐豆膠、羅望子膠、瓊脂、明膠等,但並不限定於該等。 The food additive or the like which can be replaced by the food improving agent of the present invention may, for example, be a known food additive or the like having an effect to be obtained, and examples thereof include microcrystalline cellulose, powdered cellulose, pectin, sodium alginate, and seaweed. Acid, sea Alginate, carrageenan, cadmium gum, guar gum, sanxian gum, locust bean gum, tamarind gum, agar, gelatin, etc., but are not limited thereto.

本發明之食品只要為可使用本發明之食品改良劑來改良食感等之食品,則其加工形態等並無特別限制。又,本發明使用本發明之食品改良劑,亦提供賦予有增黏、凝膠化、穩定、澱粉膠黏、食感改良、物性改良(保形性改良、保水性改良等)、體積控制、乳化控制、脫水收縮防止(乳清分離防止等)、耐熱(抗熱震性賦予等)、凝固、包衣、軟化、分散、滲透、氣泡量控制、剝離、脫模、膨脹率控制、彈力改良、良率提高、膜形成等中之1種以上效果之該種食品。 The food of the present invention is not particularly limited as long as it is a food which can improve the texture and the like by using the food improving agent of the present invention. Moreover, the present invention uses the food improving agent of the present invention to provide adhesion, gelation, stability, starch adhesion, improved food texture, physical property improvement (shape retention improvement, water retention improvement, etc.), volume control, Emulsification control, syneresis prevention (whey separation prevention, etc.), heat resistance (thermal shock resistance, etc.), solidification, coating, softening, dispersion, penetration, bubble volume control, peeling, demoulding, expansion ratio control, elastic improvement Such a food having one or more effects of improvement in yield, film formation, and the like.

例如本發明之食品改良劑可為具有針對麵粉食品之改良效果之麵粉食品改良劑,本發明之食品可為麵粉食品。麵粉食品只要為使用麵粉獲得之食品,則其加工形態等並無特別限制。又,由於本發明之食品改良劑具有針對麵粉食品之改良效果,故而認為對於使用大麥粉代替麵粉獲得之食品亦同樣地具有改良效果。作為麵粉食品之較佳之例,可列舉以下詳述之麵包類、麵條類、小麥點心類、小麥混合粉類及包子類等,作為尤佳之例,可列舉麵包類、麵條類及包子類。 For example, the food improving agent of the present invention may be a flour food improving agent having an effect of improving the flour food, and the food of the present invention may be a flour food. The flour food is not particularly limited as long as it is a food obtained by using flour. Further, since the food improving agent of the present invention has an effect of improving the flour food, it is considered that the food obtained by using barley flour instead of the flour has an improved effect. Preferred examples of the flour food include breads, noodles, wheat snacks, wheat mixed powders, and steamed buns, which are described in detail below. Examples of the preferred examples include breads, noodles, and buns.

再者,本說明書中,所謂麵粉,只要為收割小麥(小麥屬植物)製成之粉,則並無特別限定,例如可例示低筋麵粉、中筋麵粉、高筋麵粉、澄粉、全麥粉、粗粒小麥粉等。該等可單獨使用,亦可組合2種以上使用。 In addition, in the present specification, the flour is not particularly limited as long as it is a powder obtained by harvesting wheat (Triticum), and examples thereof include low-gluten flour, medium-gluten flour, high-gluten flour, pure flour, and whole wheat flour. , semolina and so on. These may be used alone or in combination of two or more.

(1)麵包類 (1) Bread

本發明之食品改良劑如下述之實施例11所示,若將其用於麵包類,則主要可增加麵包之體積,改良食感。 The food improving agent of the present invention is as shown in the following Example 11, and if it is used for bread, it can mainly increase the bread volume and improve the texture.

例如,並非受理論所束縛,若用於吐司麵包等,則藉由控制生麵團黏度或氣泡性,麵包體積增加,紋理變得較佳,鬆軟感、融口感、柔軟感或鬆脆感等食感獲得改良,嗜好性提高。 For example, it is not bound by theory. If it is used for toast bread, etc., by controlling the viscosity or bubble of the dough, the bread volume is increased, the texture is better, and the texture is soft, melted, soft, or crispy. The food sensation is improved and the hobby is improved.

又,若用於麵包皮類、餡餅類或麵包粉類,則藉由控制氣泡性或生麵團黏度,鬆脆感或融口感等食感得以改良之同時,賦予強度,抑制因來自配料之水分轉移導致之泡漲。 Further, when used for crusts, pies, or bread flours, by controlling the bubble property or the dough viscosity, the texture is improved, such as a crispy feeling or a melted feeling, and the strength is imparted, and the ingredients are suppressed. The soaking caused by moisture transfer.

只要不脫離本發明之精神,本發明之食品改良劑可應用於全部麵包類。本說明書中,所謂麵包類係指於麵粉中加入水,根據所需而添加酵母、醱酵粉、碳酸氫鈉等,視需要醱酵後,經過烤、蒸、炸等加熱步驟而獲得之麵粉加工品及將其進一步加工而獲得之食品。作為麵包類之例,可列舉膳食麵包(吐司麵包、法式麵包、麵包捲、牛角麵包、英式鬆餅、貝果等)、烹飪麵包、小甜麵包、丹麥酥皮餅、比薩餅皮、脆硬麵包、脆麵包丁、蒸麵包、乾麵包、麵包粉等,但並不限定於該等。 The food improver of the present invention can be applied to all breads without departing from the spirit of the present invention. In the present specification, the term "bread" refers to a flour obtained by adding water to a flour, adding yeast, fermented powder, sodium hydrogencarbonate, etc. as needed, and fermenting, if necessary, after heating, such as roasting, steaming, or frying. Processed products and foods obtained by further processing them. Examples of breads include dietary bread (toast, baguette, bread rolls, croissants, English muffins, bagels, etc.), cooking bread, sweet rolls, danish pastry, pizza, and crisps. Hard bread, crispy bread, steamed bread, dry bread, bread flour, etc., but not limited to these.

(2)麵條類 (2) Noodles

本發明之食品改良劑如下述之實施例12及13所示,若用於麵條類,則主要提高麵條類之斷裂強度(拉伸應力)及變形率,改良食感。尤其是改良麵條之彈力、順滑度、咬勁 等食感。又,可有效地抑制麵條類失去彈性,改善嗜好性。 As shown in the following Examples 12 and 13, the food improving agent of the present invention mainly improves the breaking strength (tensile stress) and the deformation ratio of the noodle, and improves the texture when used in noodles. Especially to improve the elasticity, smoothness and bite of the noodles. Waiting for food. Further, it is possible to effectively suppress the loss of elasticity of the noodles and improve the taste.

只要不脫離本發明之精神,本發明之食品改良劑可應用於全部麵條類,尤其是可應用於作為麵粉食品之麵條類。本說明書中,所謂作為麵粉食品之麵條類,通常係指使於麵粉中加入水及鹽等而成之生麵團成形為細長或較薄之麵粉加工品及將其進一步加工而獲得之食品。作為麵條類之例,可列舉含有麵粉作為原料之中式拉麵、蕎麥麵、烏龍麵、掛麵、冷麵、寬麵條、米線、大麥麵、朝鮮冷麵、意大利麵、餃子皮等,進而可列舉將該等製成生麵條、煮麵、蒸麵、冷藏麵、冷凍麵、乾麵條、速食麵、長壽麵者,但並不限定於該等。 The food improver of the present invention can be applied to all noodles, especially to noodles as flour food, without departing from the spirit of the present invention. In the present specification, the noodle as a flour food is generally a food obtained by forming a raw dough obtained by adding water or salt to flour into a slender or thin flour processed product and further processing the same. Examples of the noodle include a flour as a raw material, a ramen noodles, a soba noodles, an oolong noodles, noodles, noodles, noodles, rice noodles, barley noodles, Korean noodles, noodles, dumplings, and the like. The raw noodles, boiled noodles, steamed noodles, refrigerated noodles, frozen noodles, dried noodles, instant noodles, and longevity noodles are listed as such, but are not limited thereto.

(3)小麥點心類 (3) Wheat snacks

本發明之食品改良劑如下述之實施例11所示,顯示出針對麵包類之優異之改良效果,又,如下述之實施例14所示,顯示出針對包子之優異之改良效果,同樣地若用於小麥點心類,則發揮食感改良、脫水收縮防止、穩定性提高等各種改良效果。 The food improving agent of the present invention exhibits an excellent effect of improving the bread as shown in the following Example 11, and shows an excellent improvement effect on the bun as shown in the following Example 14, and similarly, When it is used for wheat snacks, various improvement effects such as improvement in food texture, prevention of syneresis, and improvement in stability are exhibited.

例如若為日式點心類,則可獲得如以下之改良效果: 用於長崎蛋糕類、丸子皮類、今川燒系之皮類或包子系之皮類時,並非受理論所束縛,藉由控制生麵團黏度或氣泡性而改良鬆軟感、融口感、濃厚感或柔軟感等食感; 用於江米條類、炸糕類、豆類點心類等時,並非受理論所束縛,控制氣泡性,改良酥脆感、鬆軟感或融口感等食 感,提高嗜好性。 For example, if it is a Japanese dim sum, the following improvement effects can be obtained: It is not bound by theory when used in Nagasaki cakes, meatballs, Imakawa's skin or bun, and it improves the softness, mouthfeel, thickness or by controlling the viscosity or bubble of the dough. Soft feeling and other food sensations; When used in river rice strips, fried cakes, and bean snacks, it is not bound by theory, and it controls bubble, and improves crispy, soft, or melted food. Feeling, improve hobbies.

又,若為西式點心類,則可獲得如以下之改良效果:用於蛋糕類、甜甜圈類、派類、可麗餅類、休閒點心類、曲奇類、脆餅類、薄煎餅類等之生麵團時,並非受理論所束縛,藉由控制生麵團黏度或氣泡性而改良鬆軟感、融口感、柔軟感或鬆脆感等食感,提高嗜好性。 Moreover, if it is a western-style dim sum, the improvement effect as follows is used for cakes, donuts, pies, crepes, snacks, cookies, shortbreads, pancakes When the dough is doughed, it is not bound by the theory. By controlling the viscosity or bubble of the dough, the texture, the feeling of softness, the softness or the crunchiness are improved, and the taste is improved.

又,若為中式點心,可獲得如以下之改良效果:用於包子類生麵團時,並非受理論所束縛,藉由控制生麵團黏度或氣泡性,改良鬆軟感、融口感、濃厚感或柔軟感等食感,提高嗜好性。 Moreover, in the case of a Chinese dim sum, the following improvement effects can be obtained: when used for bun-like dough, it is not bound by theory, and by controlling the viscosity or bubble of the dough, the texture is soft, melted, thick or soft. Feelings and other food sensations, improve hobbies.

只要不脫離本發明之精神,本發明之食品改良劑可應用於全部小麥點心類。本說明書中,所謂小麥點心類係使用麵粉作為主原料,經過加熱步驟而製造,指通常作為點心而食用之日式、西式、亞洲式點心類或與其等類似之全部食品。作為小麥點心之例,可列舉含有麵粉作為原料之鯛魚燒、包子、月餅、長崎蛋糕、葛根點心、大福餅、糯米餡餅、薄脆餅乾、炸糕、乾點心餡餅、磅蛋糕、甜甜圈、烤薄餅、海綿蛋糕、可麗餅、威化餅、脆餅、油酥蛋糕、休閒點心、泡芙點心、餅乾、曲奇、乾麵包、普澤餅等,但並不限定於該等。 The food improver of the present invention can be applied to all wheat snacks without departing from the spirit of the present invention. In the present specification, the wheat confectionery is made by using a flour as a main raw material and is produced by a heating step, and refers to a Japanese-style, Western-style, Asian-style snack or the like which is usually eaten as a snack. Examples of wheat snacks include squid, buns, moon cakes, Nagasaki cakes, kudzu desserts, dafu cakes, glutinous rice cakes, crackers, fried cakes, dried dessert pies, pound cakes, and sweets containing flour as a raw material. Circles, pancakes, sponge cakes, crepes, wafers, shortbreads, pastry cakes, snacks, puffs, biscuits, cookies, dry bread, pudding cakes, etc., but are not limited to these.

(4)小麥混合粉類 (4) Wheat mixed powder

本發明之食品改良劑如下述之實施例11所示,藉由於麵包類之製造步驟中混入麵粉中,顯示出針對所獲得之麵包類之優異之改良效果,同樣地用於小麥混合粉類時,主要 改良食感或穩定性。並非受理論所束縛,尤其是藉由使生麵團之揉合變得較佳之同時控制凝膠強度,改良食感,提高嗜好性。 The food improving agent of the present invention, as shown in the following Example 11, is exhibited by the flour in the manufacturing step of the bread, and exhibits an excellent improvement effect on the obtained bread, and is similarly used for the wheat mixed powder. ,main Improve food texture or stability. It is not bound by theory, especially by making the blending of the dough better while controlling the gel strength, improving the texture and improving the taste.

例如甜不辣類、油炸食品類及油炸餡餅類等之麵糊系混合粉之情形時,並非受理論所束縛,藉由控制生麵團黏度或氣泡性,於改良鬆軟感、融口感、柔軟感或鬆脆感等食感之同時,賦予強度而抑制因來自配料之水分轉移所導致之泡漲,提高嗜好性。 For example, in the case of batter-type mixed powders such as sweet and non-spicy, fried foods, and fritters, it is not bound by theory, and by controlling the viscosity or bubble of the dough, it is improved in softness and melting. At the same time, it gives a feeling of softness or crunchiness, and imparts strength to suppress swelling due to moisture transfer from the ingredients, thereby improving the taste.

只要不脫離本發明之精神,本發明之食品改良劑可應用於全部小麥混合粉類。本說明書中,所謂小麥混合粉類通常係指藉由以將麵粉作為基礎之粉體進行加工/烹飪之粉、該加工烹飪品以及使用該等之食品。作為小麥混合粉類之例,可列舉含有麵粉作為原料之大麥加工品、預混粉(各種蛋糕混合粉、各種麵包混合粉、甜不辣粉、乾炸粉、大阪燒混合粉等)等,但並不限定於該等。 The food improver of the present invention can be applied to all wheat mixed powders without departing from the spirit of the present invention. In the present specification, the term "wheat mixed powder" generally means a powder processed, cooked, or processed using a powder based on flour, a processed product, and a food product using the same. Examples of the wheat mixed powder include barley processed products containing flour as a raw material, premixed powders (various cake mixed powders, various bread mixed powders, sweet non-spicy powders, dry fried powders, Osaka-fired mixed powders, etc.), and the like. However, it is not limited to these.

(5)包子類 (5) Buns

本發明之食品改良劑如下述之實施例14所示,用於包子類時,主要增加包子之體積,改良食感,提高嗜好性。 The food improving agent of the present invention, as shown in the following Example 14, is mainly used for buns, which mainly increases the volume of the steamed buns, improves the texture, and improves the taste.

例如並非受理論所束縛,藉由控制生麵團黏度或氣泡性,增加包子之體積,改良鬆軟感、融口感或柔軟感等食感,提高嗜好性。 For example, it is not bound by theory. By controlling the viscosity or bubble of the dough, the volume of the steamed buns is increased, and the texture of the soft, melted or soft feeling is improved, and the taste is improved.

進而,用於小籠包類時,藉由提高彈力性等,使皮穩定化,因而可防止湯之滲出,亦改良食感。 Further, in the case of the skein type, the skin is stabilized by improving the elasticity and the like, thereby preventing the oozing of the soup and improving the texture.

只要不脫離本發明之精神,本發明之食品改良劑可應用 於全部包子類。本說明書中,所謂包子類,通常係指以麵粉為基礎之中式包子類及改制其而獲得之小麥包子類。作為包子類之例,可列舉肉包、豆餡包、叉燒包、包子、韭菜包等,但並不限定於該等。 The food improver of the present invention can be applied without departing from the spirit of the present invention. For all package subclasses. In the present specification, the term "bunch" generally refers to a wheat-based bun which is obtained by substituting a flour-based medium-sized bun. Examples of the buns include meat packs, bean stuffing packs, pork roasts, steamed buns, and leeks, but are not limited thereto.

進而,本發明之食品改良劑可為尤其藉由增黏凝膠化等作用而具有對食品之改良效果的食品之增黏凝膠化改良劑,作為本發明之食品之較佳之例,通常可列舉調配凝膠化劑、增黏劑、穩定劑、澱粉接著劑等而改良之食品。作為尤佳之例,可列舉以下詳述之乳製品、畜肉製品及凝膠化食品。 Further, the food improving agent of the present invention may be a viscosity-increasing gelatinizing agent for a food having an effect of improving foods by an action such as viscosity-gating gelation, and is preferably a preferred example of the food of the present invention. A food product improved by blending a gelling agent, a tackifier, a stabilizer, a starch adhesive, and the like is listed. As a preferable example, a dairy product, a meat product, and a gelled food described in detail below can be cited.

(6)乳製品 (6) Dairy products

本發明之食品改良劑如下述之實施例15及16所示,調配至乳製品中時,藉由發揮脫水收縮防止、乳清分離防止等作用,可提高乳製品之保形率,提高穩定性。 When the food improving agent of the present invention is formulated into the dairy products as shown in the following Examples 15 and 16, the effect of preventing syneresis and preventing whey separation can be achieved, and the shape retention rate of the dairy product can be improved and the stability can be improved. .

例如並非受理論所束縛,調配至如霜淇淋之冷凍甜點類或乳油類中之情形時,藉由控制膨脹率、霜淇淋中之冰晶變細、乳油中之氣泡變細等,融口感或濃厚感、柔軟感等食感獲得改良。又,保形率亦提高。調配至乳酪類中之情形時,強度、彈力等增大,食感獲得改良,嗜好性亦提高。 For example, it is not bound by theory, and when it is blended into frozen desserts or creams such as cream, it can be controlled by controlling the expansion ratio, the ice crystals in the cream, and the bubbles in the cream. The food texture such as thick feeling and soft feeling is improved. Moreover, the shape retention rate has also increased. When blended into the cheese, the strength, elasticity, and the like are increased, the food texture is improved, and the taste is also improved.

只要不脫離本發明之精神,本發明之食品改良劑可應用於全部乳製品。 The food improver of the present invention can be applied to all dairy products without departing from the spirit of the present invention.

本說明書中,所謂乳製品,通常為以乳之形式飲用食用者、其加工品及使用該等之全部食品。再者,認為本發明 之食品改良劑對於使用源自植物之乳代替源自動物之乳而獲得之食品亦同樣地具有改良效果,因此本說明書中之乳製品亦包括使用源自植物之乳代替源自動物之乳而獲得之食品。例如本說明書中之乳製品包括使用源自牛、綿羊、山羊等之乳或源自大豆等豆類之豆乳而獲得之食品。該等乳可單獨使用,亦可組合2種以上。 In the present specification, the term "dairy product" is generally used to drink the consumer, the processed product, and all of the foods in the form of milk. Furthermore, the present invention is considered The food improver also has an improved effect on the use of plant-derived milk instead of animal-derived milk. Therefore, the dairy product in the present specification also includes the use of plant-derived milk instead of animal-derived milk. The food obtained. For example, the dairy product in the present specification includes a food obtained by using milk derived from cows, sheep, goats, or the like, or soybean milk derived from beans such as soybeans. These milks may be used singly or in combination of two or more.

作為乳製品之例,可列舉加工乳、普通乳、濃厚乳、低脂乳、脫脂乳、乳飲料、乳油、咖啡奶精、酸乳酪、卡士達醬、蛋奶酥、霜淇淋、冰牛奶、乳酸霜淇淋、冷凍甜品、奶粉、煉乳、乳酪、加乳雪霜、加油脂雪霜等,但並不限定於該等。 Examples of the dairy product include processed milk, ordinary milk, thick milk, low fat milk, skim milk, milk beverage, emulsifiable concentrate, coffee creamer, yogurt, kashida sauce, souffle, cream, ice. Milk, lactic acid cream, frozen dessert, milk powder, condensed milk, cheese, milk cream, grease cream, etc., but not limited to these.

(7)畜肉製品 (7) Livestock products

本發明之食品改良劑如下述之實施例17所示,調配至畜肉中時,良率變佳,水分含量亦上升。藉此,多汁感等食感獲得改良,嗜好性亦提高。 As shown in Example 17 below, the food improving agent of the present invention has a good yield and a high moisture content when formulated into livestock meat. Thereby, the sense of food such as juicy feeling is improved, and the taste is also improved.

只要不脫離本發明之精神,本發明之食品改良劑可應用於全部畜肉製品。認為本發明之食品改良劑對於使用魚肉代替畜肉而獲得之食品亦同樣地具有改良效果,因此本說明書中之畜肉製品亦包括使用魚肉而獲得之食品。本說明書中,所謂畜肉製品,通常為可食用之肉類(包括魚肉類)、其加工品、及使用該等之全部食品。例如本說明書中之畜肉製品包括使用牛肉、豬肉、雞肉、鴨肉、羊肉、馬肉、鹿肉、魚肉等作為肉類而獲得之食品。該等肉類可單獨使用,亦可組合2種以上。 The food improver of the present invention can be applied to all livestock meat products without departing from the spirit of the present invention. It is considered that the food improving agent of the present invention has an improved effect on the food obtained by using the fish meat instead of the meat, and therefore the meat meat product in the present specification also includes the food obtained by using the fish meat. In the present specification, the meat product is generally edible meat (including fish meat), processed products thereof, and all foods using the same. For example, the meat products in the present specification include foods obtained by using beef, pork, chicken, duck, lamb, horse meat, venison, fish, and the like as meat. These meats may be used alone or in combination of two or more.

作為畜肉製品之例,可列舉火腿、培根、香腸、薩拉米香腸、肝糊、加有各種肉之副食品(烤牛肉、漢堡、乾炸食品、雞塊、餃子、包子、炸肉餅、叉燒等)、加有各種肉之罐頭(鹹牛肉等)、各種魚肉食品(魚肉香腸、炸魚肉餅、魚肉山芋餅、魚糕、魚醬、氽魚丸子等)等,但並不限定於該等。 Examples of meat products include ham, bacon, sausage, salami, liver paste, and various food supplements (roasted beef, burgers, fried foods, chicken nuggets, dumplings, buns, croquettes, For example, pork roast, etc., and various kinds of canned meat (salted beef, etc.), various fish foods (fish sausage, fried fish patties, fish yam cake, fish cake, fish sauce, squid balls, etc.), but are not limited thereto. Wait.

(8)凝膠化食品 (8) Gelled food

本發明之食品改良劑具有若添加至水中則在不經過加熱步驟之情況下增黏凝膠化之特性(經過加熱步驟亦會增黏凝膠化)。例如,如下述之實施例18所示,調配至果凍中之情形時,可獲得凝膠強度較高、變形率較低之果凍,可獲得即便具有較佳之硬度亦容易咬碎等食感改善效果。 The food improver of the present invention has the property of being thickened and gelled without being subjected to a heating step if added to water (the gelation is also enhanced by a heating step). For example, as shown in the following Example 18, when blended into a jelly, a jelly having a high gel strength and a low deformation rate can be obtained, and a food-sensing improvement effect such as easy crushing even with a preferable hardness can be obtained. .

只要不脫離本發明之精神,本發明之食品改良劑可應用於全部凝膠化食品。應用於凝膠化食品時,凝膠化食品較佳可含有本發明之食品改良劑與鈣。鈣可使用上述之含有鈣之原料進行調配。 The food improver of the present invention can be applied to all gelled foods without departing from the spirit of the present invention. When applied to a gelled food, the gelled food preferably contains the food improver of the present invention and calcium. Calcium can be formulated using the calcium-containing materials described above.

本說明書中,所謂凝膠化食品,通常為使液體凝固為膠狀而食用之全部食品,可列舉各種果凍、果醬、布丁、巴伐露斯、米粉糕、金鍔餅、羊羹、葛根粉絲、葛饅頭、涼粉、水饅頭、蘋果餡餅、慕斯、餅餡、軟糖、果汁軟糖、人工鹹魚子、果凝凍等,但並不限定於該等。 In the present specification, the gelled food is usually a whole food which is obtained by solidifying the liquid into a gel form, and includes various kinds of jelly, jam, pudding, bavarus, rice cake, ginseng cake, alpaca, and puerarin. Ge Weitou, jelly powder, water taro, apple pie, mousse, cake filling, soft candy, marshmallow, artificial salted caviar, fruit jelly, etc., but not limited to these.

又,本發明亦提供包括將上述食品改良劑調配至食品中之步驟的食品之製造方法。例如於一態樣中,本發明亦提供包括將上述食品改良劑調配至麵粉中之步驟的麵粉食品 之製造方法。將食品改良劑調配至食品中之方法並無特別限制。例如於食品之原料中:可直接調配至主原料中;可調配至除主原料以外之原料(副原料、原料水、原料液等)中;可於混合任意2種以上原料後調配;或者可於混合主原料與副原料、原料水或原料液等後調配;可調配粉體等形狀之食品改良劑,亦可製成水溶液狀、分散液狀或糊劑狀後調配。調配之具體方法亦無特別限定,可混合、撒、塗、揉入、醃漬、或注入而調配。 Further, the present invention also provides a method of producing a food comprising the step of blending the above-mentioned food improving agent into a food. For example, in one aspect, the present invention also provides a flour food comprising the step of formulating the above food improving agent into flour. Manufacturing method. There is no particular limitation on the method of blending the food improver into the food. For example, in the raw material of food: it can be directly formulated into the main raw material; it can be blended into raw materials other than the main raw material (auxiliary raw materials, raw water, raw material liquid, etc.); it can be blended after mixing any two or more kinds of raw materials; After mixing the main raw material, the auxiliary raw material, the raw material water or the raw material liquid, etc., the food improving agent in the shape of a powder or the like may be prepared, and may be formulated into an aqueous solution, a dispersion liquid or a paste. The specific method of blending is also not particularly limited, and may be blended, sprinkled, coated, infused, pickled, or injected.

調配食品改良劑之步驟可於食品之製造過程中之任何階段進行,亦可於加熱或冷卻等步驟中進行。例如於食品為麵粉食品之情形時,通常於食用前之任一階段對麵粉食品進行加熱,於本發明之一態樣中,有時為了獲得所需之改良效果,較佳為於食用前進行加熱之步驟之前將食品改良劑調配至麵粉中。食用前之加熱可於各麵粉食品公知之溫度下進行。又,例如於本發明之食品改良劑為粉末形態,存在其他粉體原料作為食品原料之情形時,首先將食品改良劑調配至其他粉體原料中,藉此可容易地使食品改良劑均勻地分散,故而較佳。 The step of formulating the food improver can be carried out at any stage in the manufacturing process of the food, or in the steps of heating or cooling. For example, when the food is a flour food, the flour food is usually heated at any stage before the eating. In one aspect of the present invention, sometimes in order to obtain the desired improvement effect, it is preferred to perform before eating. The food improver is formulated into the flour prior to the step of heating. Heating prior to consumption can be carried out at temperatures known to the individual flour foods. Further, for example, when the food improving agent of the present invention is in the form of a powder and the other powder raw material is used as a food material, the food improving agent is first formulated into other powder raw materials, whereby the food improving agent can be easily uniformly obtained. Dispersed, so it is better.

除上述調配步驟以外之食品之製造方法並無特別限定,可使用公知之方法製造各食品。 The method for producing the food other than the above-described mixing step is not particularly limited, and each food can be produced by a known method.

進而,本發明亦提供以將上述本發明之食品改良劑調配至食品中為特徵的食品之改良方法,更詳細而言,本發明亦提供增黏方法、凝膠化方法、穩定化方法、增黏穩定化方法、黏度控制方法、食感改良方法、物性改良方法(保 形性改良方法、保水性改良方法等)、體積控制方法、乳化控制方法、脫水收縮防止方法(乳清分離防止方法等)、耐熱化方法(抗熱震性賦予方法等)、凝固方法、包衣方法、軟化方法、分散方法、滲透方法、氣泡量控制方法、剝離方法、脫模方法、膨脹率控制方法、彈力改良方法、良率提高方法及膜形成方法等。該等方法中之食品改良劑於食品中之調配方法可參照上述之記載而容易地理解。 Further, the present invention also provides an improved method for blending the above-described food improving agent of the present invention into a food, and more particularly, the present invention also provides a viscosity increasing method, a gelating method, a stabilizing method, and an increase Viscosity stabilization method, viscosity control method, food improvement method, physical property improvement method Shape improvement method, water retention improvement method, etc.), volume control method, emulsification control method, syneresis prevention method (whey separation prevention method, etc.), heat resistance method (heat shock resistance imparting method, etc.), solidification method, package Coating method, softening method, dispersion method, infiltration method, bubble amount control method, peeling method, demolding method, expansion ratio control method, elastic strength improving method, yield improving method, film forming method, and the like. The method of blending the food improving agent in the foods in the above methods can be easily understood by referring to the above description.

[實施例] [Examples]

以下,列舉實施例及製造例(以下亦簡稱為「實施例等」)對本發明進行進一步具體說明。以下之實施例等所示之原料、程序、使用量、比率、操作順序等只要不脫離本發明之精神,則可適當變更。因此,本發明之範圍並不限制於以下所示之具體例等。 Hereinafter, the present invention will be further specifically described by way of examples and production examples (hereinafter also referred to as "examples, etc."). The materials, procedures, usage amounts, ratios, operation procedures, and the like shown in the following examples and the like can be appropriately changed without departing from the spirit of the invention. Therefore, the scope of the present invention is not limited to the specific examples and the like shown below.

實施例1:粉末褐藻之製造Example 1: Manufacture of powdered brown algae 製造例1Manufacturing example 1

[粉碎]以槌磨粉碎機將乾燥褐藻(褐藻綱-昆布目-巨藻科-巨藻屬-淡黑巨海藻(Lessonia nigrescens))粉碎,獲得褐藻粉碎物。 [Crushing] The dried brown algae (Brown algae-Kumba-Dalaceae-Lycophyllum-Lessonia nigrescens) was pulverized by a honing mill to obtain a brown algae pulverized product.

[清洗]將該褐藻粉碎物100 g加入容器中,加入水1643 mL、乙醇(100%)1352 mL、次氯酸鈉水溶液(商品名:Tsuruchlone N-40,鶴見曹達公司製造,有效氯濃度12%以上)400 mL、碳酸鈉(商品名:蘇打灰,Central Glass公司製造)10 g,以600 rpm攪拌30分鐘而清洗。 [Cleaning] 100 g of the pulverized brown algae was added to the vessel, and water was added in 1643 mL, ethanol (100%) 1352 mL, and sodium hypochlorite aqueous solution (trade name: Tsuruchlone N-40, manufactured by Tsurumi Soda Co., Ltd., effective chlorine concentration of 12% or more) 400 mL, sodium carbonate (trade name: soda ash, manufactured by Central Glass Co., Ltd.) 10 g, and washed at 600 rpm for 30 minutes.

[脫水]使用濾布(通氣性20 cm3/cm2‧秒)將其脫水。 [Dehydration] The filter cloth (air permeability: 20 cm 3 /cm 2 ‧ seconds) was used for dehydration.

[乾燥]將該經脫水之清洗褐藻放入65℃~85℃之乾燥機中乾燥2小時,以絞果汁器粉碎後,獲得粒徑0.13 mm左右之粉末褐藻(製造例1)。 [Drying] The dehydrated washed brown algae were dried in a dryer at 65 ° C to 85 ° C for 2 hours, and pulverized by a twisted juice machine to obtain powdered brown algae having a particle diameter of about 0.13 mm (Production Example 1).

製造例2Manufacturing Example 2

製造例1之清洗步驟中,將次氯酸鈉400 mL改為300 mL,除此以外,進行與製造例1相同之處理,獲得粉末褐藻(製造例2)。 In the washing step of the production example 1, the same treatment as in Production Example 1 was carried out, except that 400 mL of sodium hypochlorite was changed to 300 mL, and powdered brown algae (Production Example 2) was obtained.

製造例3Manufacturing Example 3

製造例1之清洗步驟中,將次氯酸鈉400 mL改為200 mL,除此以外,進行與製造例1相同之處理,獲得粉末褐藻(製造例3)。 In the washing step of Production Example 1, the same treatment as in Production Example 1 was carried out except that 400 mL of sodium hypochlorite was changed to 200 mL, and powdered brown algae (Production Example 3) was obtained.

製造例4Manufacturing Example 4

製造例1之清洗步驟中,將水1643 mL改為900 mL,將乙醇1352 mL改為900 mL,將次氯酸鈉400 mL改為200 mL,除此以外,進行與製造例1相同之處理,獲得粉末褐藻(製造例4)。 In the washing step of Production Example 1, the same treatment as in Production Example 1 was carried out to obtain a powder by changing the water 1643 mL to 900 mL, changing the ethanol 1352 mL to 900 mL, and changing the sodium hypochlorite 400 mL to 200 mL. Brown algae (Production Example 4).

製造例5Manufacturing Example 5

製造例1之清洗步驟中,將水1643 mL改為900 mL,將乙醇1352 mL改為900 mL,將次氯酸鈉400 mL改為5 mL,除此以外,進行與製造例1相同之處理,獲得粉末褐藻(製造例5)。 In the washing step of Production Example 1, the same treatment as in Production Example 1 was carried out to obtain a powder by changing the water 1643 mL to 900 mL, the ethanol 1352 mL to 900 mL, and the sodium hypochlorite 400 mL to 5 mL. Brown algae (Production Example 5).

製造例6Manufacturing Example 6

將製造例1之粉碎步驟中獲得之褐藻粉碎物製成粉末褐藻(製造例6)。 The brown algae pulverized product obtained in the pulverization step of Production Example 1 was made into powdered brown algae (Production Example 6).

實施例2:粉末褐藻之評價Example 2: Evaluation of powdered brown algae (1)海藻味之減輕評價 (1) Evaluation of the reduction of seaweed flavor

針對實施例1獲得之粉末褐藻(製造例1~6),分別將3 g分散溶解於297 mL之水中,獲得1重量%分散液。聞該溶液之氣味,海藻味未減輕而強烈殘留時設為1,海藻味有所減輕、氣味較弱時設為5,以1~5進行評價。以製造例1之氣味作為評價5之基準,以製造例6之氣味作為評價1之基準。 With respect to the powder brown algae (Production Examples 1 to 6) obtained in Example 1, 3 g of the dispersion was dissolved in 297 mL of water to obtain a 1% by weight dispersion. When the smell of the solution was smelled, the seaweed taste was not reduced, and when it was strongly left, it was set to 1, and the seaweed taste was reduced, and when the smell was weak, it was set to 5, and it was evaluated by 1 to 5. The odor of Production Example 1 was used as the basis of Evaluation 5, and the odor of Production Example 6 was used as the basis of Evaluation 1.

(2)海藻色之降低評價 (2) Evaluation of the reduction of seaweed color

針對上述(1)獲得之1重量%分散液,目視觀察透明燒杯中之色彩,海藻色未降低、色彩較強時設為1,海藻色有所降低、色彩較弱時設為5,以1~5進行評價。以製造例1之海藻色作為評價5之基準,以製造例6之海藻色作為評價1之基準。 With respect to the 1% by weight dispersion obtained in the above (1), the color in the transparent beaker was visually observed, the algae color was not lowered, the color was set to 1 when the color was strong, the algae color was lowered, and the color was weakly set to 5, to 1 ~5 for evaluation. The seaweed color of Production Example 1 was used as the basis of Evaluation 5, and the seaweed color of Production Example 6 was used as the standard of Evaluation 1.

(3)1%黏度 (3) 1% viscosity

針對上述(1)獲得之1重量%分散液,於液溫20℃下,使用BL型黏度計,以轉速60 rpm求出黏度。 With respect to the 1% by weight dispersion obtained in the above (1), the viscosity was determined at a liquid temperature of 20 ° C using a BL type viscometer at a number of revolutions of 60 rpm.

(4)由鈣引起之凝膠化 (4) Gelation caused by calcium

針對上述(1)獲得之1重量%分散液,取其5 mL放入燒杯中,加入1 mL之7.5%氯化鈣溶液,觀察是否形成凝膠。 For the 1% by weight dispersion obtained in the above (1), 5 mL of the dispersion was placed in a beaker, and 1 mL of a 7.5% calcium chloride solution was added to observe whether or not a gel was formed.

(5)粉末褐藻之粉體之L值 (5) L value of powdered brown algae powder

針對實施例1獲得之粉末褐藻(製造例1~6),使用色彩色差計CR-300(Minolta製造)測定粉體之L值。 With respect to the powder brown algae (Production Examples 1 to 6) obtained in Example 1, the L value of the powder was measured using a color difference meter CR-300 (manufactured by Minolta).

針對下述(6)~(13),只要無特別說明,則「%」係指 「重量%」。 For the following (6)~(13), unless otherwise stated, "%" means "weight%".

(6)水溶性褐藻膠成分(%) (6) Water-soluble alginate components (%)

藉由作為公知之陰離子性多糖類之測定法之膠體滴定法,測定粉末褐藻中所含之水溶性褐藻膠成分(%)。膠體滴定法可應用例如日本專利特開平11-042470中所記載之方法。即,針對上述(1)獲得之1重量%分散液,取其0.5 mL放入燒杯中,加入10 mL之水與N/200甲基乙二醇殼聚糖溶液5 mL。繼而加入數滴甲苯胺藍指示劑,以N/400聚乙烯硫酸鉀當量溶液(以下稱作PVSK(Polyvinyl Potassium Sulfate Solution))進行滴定,以自藍色變色為紫紅色並保持10秒以上之點為終點。未加試樣之情形設為空白樣品。由於褐藻中所含之含有水溶性之糖醛酸之陰離子性多糖類主要為海藻酸鹽,海藻酸鈉之1個分子之分子量=198,因此此時N/400 PVSK標準溶液之滴定量1 mL相當於198×1/400=0.495 mg之海藻酸鈉。故而藉由下式可求出粉末褐藻中所含之水溶性褐藻膠成分(將水溶性海藻酸鹽以鈉鹽換算者)(%)。 The water-soluble alginate component (%) contained in the powdered brown algae was measured by a colloidal titration method which is a measurement method of a known anionic polysaccharide. For the colloidal titration method, for example, the method described in Japanese Patent Laid-Open No. Hei 11-042470 can be applied. That is, for the 1% by weight dispersion obtained in the above (1), 0.5 mL of the dispersion was placed in a beaker, and 10 mL of water and 5 mL of N/200 methyl glycol chitosan solution were added. Then add a few drops of toluidine blue indicator, and titrate with N/400 polyethylene potassium sulfate equivalent solution (hereinafter referred to as PVSK (Polyvinyl Potassium Sulfate Solution)) to change from blue to purple and keep it for more than 10 seconds. As the end point. The case where no sample is added is set as a blank sample. Since the anionic polysaccharide containing water-soluble uronic acid contained in brown algae is mainly alginate, the molecular weight of one molecule of sodium alginate is 198, so the titration of N/400 PVSK standard solution is 1 mL at this time. Equivalent to 198 × 1 / 400 = 0.495 mg of sodium alginate. Therefore, the water-soluble alginate component (the water-soluble alginate as a sodium salt) (%) contained in the powdered brown algae can be obtained by the following formula.

水溶性褐藻膠成分(%)=(空白樣品滴定量(mL)-試樣之滴定量(mL))÷試樣之量(mL)×0.495(mg)÷1000(mg)÷0.01(%液)×100(%) Water-soluble alginate component (%) = (blank sample titration (mL) - sample titer (mL)) ÷ sample amount (mL) × 0.495 (mg) ÷ 1000 (mg) ÷ 0.01 (% liquid ) × 100 (%)

(7)蛋白質(凱氏法) (7) Protein (Kjeldahl method)

蛋白質係按照食品衛生檢查指針-理化學編(1991年6月25日發行,發行所:社團法人日本食品衛生協會,下同)23頁所記載之方法進行分析。 The protein is analyzed according to the method described in the Food Hygiene Inspection Guide - Science and Technology (issued on June 25, 1991, issued by the Japan Society of Food Hygiene, the same below).

取試樣0.5 g放入凱氏分解燒瓶中,加入硫酸鉀5 g作為分解促進劑,繼而加入濃硫酸15 mL,平穩地振盪混合後,以文火加熱。分解一開始液體就黑化起泡。於成為黑色黏稠液後,加強加熱。若反應進行,則產生二氧化硫與二氧化碳,且溶液逐漸由黑褐色變為褐色,最後成為藍色乃至藍綠色清澈之溶液。進而持續1~2小時強熱而完成分解。冷卻後於分解液中加入脫離子水約120 mL,加入數塊沸石或少量粒狀鋅,然後緩慢加入30%氫氧化鈉溶液70 mL,使其與蒸餾裝置(B-324:Buchi製造,Shibata化學)連結。其後,藉由自動滴定裝置(719:Metrohm-Shibata股份有限公司製造)進行滴定,利用下式,由所獲得之氮量(%)之值算出蛋白質量。式中,作為「氮-蛋白質換算係數」,粉末褐藻之情形時使用6.25。 0.5 g of the sample was placed in a Kjeldahl decomposition flask, 5 g of potassium sulfate was added as a decomposition accelerator, and then 15 mL of concentrated sulfuric acid was added thereto, and the mixture was smoothly shaken and mixed, and then heated by a simmer. At the beginning of the decomposition, the liquid is blackened and foamed. After becoming a black viscous liquid, strengthen the heating. If the reaction proceeds, sulfur dioxide and carbon dioxide are produced, and the solution gradually changes from dark brown to brown, and finally becomes a blue or even blue-green clear solution. Further, the decomposition is continued for 1 to 2 hours of intense heat. After cooling, add about 120 mL of deionized water to the decomposing solution, add a few pieces of zeolite or a small amount of granular zinc, and then slowly add 70 mL of 30% sodium hydroxide solution to the distillation apparatus (B-324: manufactured by Buchi, Shibata). Chemical) link. Thereafter, titration was carried out by an automatic titration apparatus (719: manufactured by Metrohm-Shibata Co., Ltd.), and the amount of protein was calculated from the value of the amount of nitrogen (%) obtained by the following formula. In the formula, as a "nitrogen-protein conversion factor", 6.25 is used in the case of powdered brown algae.

蛋白質(%)=氮量(%)×(氮-蛋白質換算係數) Protein (%) = nitrogen amount (%) × (nitrogen-protein conversion factor)

(8)不溶性成分 (8) Insoluble components

粉末褐藻中之不溶性成分之含量係利用下式算出。不溶性成分(%) The content of the insoluble component in the powder brown algae was calculated by the following formula. Insoluble ingredients (%)

=100-水分(%)-蛋白質(%)-脂質(%)-灰分(%)-水溶性褐藻膠成分(%) =100-Moisture (%)-Protein (%)-Lipid (%)-Ace (%)-Water-soluble alginate (%)

式中,水溶性褐藻膠成分、蛋白質及灰分之含量係利用上述(6)、(7)及下述(9)中所記載之方法而測定。水分及脂質之含量係利用以下記載之方法測定。 In the formula, the content of the water-soluble alginate component, the protein, and the ash is measured by the methods described in the above (6), (7), and the following (9). The contents of water and lipids were measured by the methods described below.

水分係按照食品衛生檢查指針-理化學編18頁所記載之方法,藉由常壓加熱乾燥法測定。 The water content is measured by a normal pressure heating and drying method in accordance with the method described in the Food Hygiene Inspection Guide - Physical Chemistry, p.

於調節為特定溫度(100~135℃)之定溫乾燥機上放入稱量皿,加熱1~2小時後轉移至保乾器(desiccator)中。放置冷卻,達到室溫後立即稱量,求出恆量值(W0 g)。 Place the weighing dish on a constant temperature dryer adjusted to a specific temperature (100~135 °C), heat it for 1-2 hours, and transfer to a desiccator. After standing to cool, weighed immediately after reaching room temperature, and found a constant value (W 0 g).

取大致1 g試樣,將其平鋪並蓋上蓋子,準確地稱量(W1 g)。挪動蓋子,放入定溫乾燥器(DX400:Yamato公司製造)中。乾燥4小時後,於乾燥器中迅速對容器蓋上蓋子,轉移至保乾器中放置冷卻。達到室溫後立即稱量(W2 g)。稱量後,藉由下式算出試樣中之水分。 Approximately 1 g of the sample was taken, tiled and covered, and accurately weighed (W 1 g). Move the lid and place it in a constant temperature dryer (DX400: manufactured by Yamato Co., Ltd.). After drying for 4 hours, the container was quickly capped in a desiccator and transferred to a desiccator for cooling. Immediately after reaching room temperature (W 2 g). After weighing, the moisture in the sample was calculated by the following formula.

水分(%)=(W1-W2)/(W1-W0)×100 Moisture (%) = (W 1 - W 2 ) / (W 1 - W 0 ) × 100

脂質係應用食品衛生檢查指針-理化學編25頁所記載之溶劑萃取法,使用二氯甲烷作為溶劑進行測定。 The lipid-based application food hygiene inspection indicator - the solvent extraction method described on page 25 of the chemistry, and the measurement using dichloromethane as a solvent.

將5 g(S g)試樣加入圓筒濾紙中。於其上輕輕塞入脫脂棉,放入萃取管中。預先以100~105℃之定溫乾燥器(DX400:Yamato公司製造)將接受器之燒瓶乾燥1~2小時,轉移至保乾器中,放置冷卻後求出恆量值(W0 g)。 A 5 g (S g) sample was added to the cylindrical filter paper. Gently insert the cotton wool onto it and place it in the extraction tube. The flask of the receiver was dried in a constant temperature drier at 100 to 105 ° C (DX400: manufactured by Yamato Co., Ltd.) for 1 to 2 hours, transferred to a desiccator, and cooled to obtain a constant value (W 0 g).

於其中加入約容積之2/3之二氯甲烷,連結冷卻管並隔水加熱,萃取8小時。結束萃取後,迅速自萃取管卸除,利用鑷子夾出圓筒濾紙,再次連結冷卻管並隔水加熱,藉此使二氯甲烷完全蒸發。 About 2/3 of the volume of methylene chloride was added thereto, and the cooling tube was connected and heated with water, and extracted for 8 hours. After the end of the extraction, it was quickly removed from the extraction tube, and the cylindrical filter paper was taken out by tweezers, and the cooling tube was again connected and heated by water to completely evaporate the dichloromethane.

用紗布擦拭燒瓶外側,放入100~105℃之定溫乾燥器中,乾燥1小時,轉移至保乾器中放置冷卻後進行稱量,求出恆量值(W g)。脂質量係利用下式算出。 The outside of the flask was wiped with gauze, placed in a constant temperature drier at 100 to 105 ° C, dried for 1 hour, transferred to a desiccator, placed and cooled, and weighed to obtain a constant value (W g). The fat mass was calculated by the following formula.

脂質(%)=(W-W0)/S×100 Lipid (%) = (WW 0 ) / S × 100

(9)灰分 (9) Ash

灰分係按照食品衛生檢查指針-理化學編37頁所記載之方法而測定。 The ash system is measured in accordance with the method described in the Food Hygiene Inspection Guide - Lithology, pp. 37.

稱取約2 g(W1 g)之試樣放入預先設為恆量之灰化容器(W0 g)中,放入550~660℃之電爐(KL-280:ADVANTEC製造)中,使其灰化直至成為白色或接近白色。灰化後,取出灰化容器,於鋁托盤等上放置冷卻直至溫度接近200℃,轉移至保乾器中,恢復至室溫後進行稱量,求出恆量值(W2 g)。 A sample of about 2 g (W 1 g) was weighed into a ashing vessel (W 0 g) which was previously set to a constant amount, and placed in an electric furnace (KL-280: manufactured by ADVANTEC) at 550 to 660 ° C to make it Ashed until it becomes white or nearly white. After the ashing, the ashing container was taken out, and placed on an aluminum tray or the like until the temperature was close to 200 ° C, transferred to a desiccator, and returned to room temperature, and then weighed to obtain a constant value (W 2 g).

灰分係利用下式算出。 The ash system was calculated by the following formula.

灰分(%)=(W2-W0)/(W1-W0)×100 Ash (%) = (W 2 - W 0 ) / (W 1 - W 0 ) × 100

(10)~(13)各種礦物質 (10)~(13) various minerals 鈉、鉀及鎂Sodium, potassium and magnesium

鈉、鉀及鎂係利用食品衛生檢查指針-理化學編64頁所記載之方法而測定。 Sodium, potassium, and magnesium are measured by the method described in Food Safety Inspection Guide - page 64 of the Chemical Engineering.

準確稱取均勻之試樣約2 g,放入石英坩堝中,於電熱器上預灰化後,在500~550℃之電爐(KL-600:Yamato公司製造)中使其灰化。放置冷卻後,於灰中加入20%鹽酸5 mL,在水浴上蒸乾。進而加入1%鹽酸10 mL,一面加溫一面使用濾紙過濾至100 mL容積之容量瓶中。加入1%鹽酸,一面加溫一面重複充分清洗之操作,將濾紙及灰化容器充分清洗後,以1%鹽酸進行定量,立即轉移至聚乙烯製容器中,獲得測定用試驗溶液。 About 2 g of the uniform sample was accurately weighed, placed in a quartz crucible, pre-ashed on an electric heater, and then ashed in an electric furnace (KL-600: manufactured by Yamato Co., Ltd.) at 500 to 550 °C. After standing to cool, 5 mL of 20% hydrochloric acid was added to the ash and evaporated to dryness on a water bath. Further, 10 mL of 1% hydrochloric acid was added, and the mixture was filtered while using a filter paper to a volumetric flask of 100 mL volume. After adding 1% hydrochloric acid, the washing operation was repeated while heating, and the filter paper and the ashing container were thoroughly washed, and then quantified by 1% hydrochloric acid, and immediately transferred to a polyethylene container to obtain a test solution for measurement.

使用偏光Zeeman原子吸光光度計(Z-6100形:日立公司製造),測定試驗溶液之吸光度,由預先測定之校正曲線 求出試驗溶液中之濃度。此時,針對濃度較高之試樣溶液,使用1%鹽酸稀釋為適當之濃度後進行測定。 The absorbance of the test solution was measured using a polarized Zeeman atomic absorption spectrophotometer (Z-6100 shape: manufactured by Hitachi, Ltd.), and the calibration curve was determined in advance. Determine the concentration in the test solution. At this time, the sample solution having a higher concentration was diluted with an appropriate concentration using 1% hydrochloric acid, and then measured.

試樣中之鈉、鉀或鎂含量係利用下式算出。 The sodium, potassium or magnesium content in the sample was calculated by the following formula.

鈉、鉀或鎂(mg%) =A×P×(100/W)×(100/1000) Sodium, potassium or magnesium (mg%) =A×P×(100/W)×(100/1000)

A:由校正曲線求出之試驗溶液中之鈉、鉀或鎂濃度(ppm) A: sodium, potassium or magnesium concentration in the test solution obtained from the calibration curve (ppm)

P:稀釋率 P: dilution rate

W:試樣之採用量(g) W: the amount of sample used (g)

iron

鐵係利用食品衛生檢查指針-理化學編68頁所記載之方法而測定。測定用試驗溶液係利用與測定鈉及鉀時相同之方法調製。 The iron system is measured by the method described in the Food Hygiene Inspection Guide - page 68 of the Chemical Engineering. The test solution for measurement was prepared by the same method as in the case of measuring sodium and potassium.

自試驗溶液將含有0.05~1 mg鐵之一定量分裝入50 mL容積之容量瓶中,以1%鹽酸定容為50 mL,藉由偏光Zeeman原子吸光光度計(Z-6100形:日立公司製造)測定吸光度。另取鐵標準溶液0~1.0 mL,根據進行同樣之操作而製成之校正曲線求出鐵濃度。 From the test solution, a quantitative solution containing 0.05 to 1 mg of iron was placed in a volumetric flask of 50 mL volume, and the volume was adjusted to 50 mL with 1% hydrochloric acid by a polarized Zeeman atomic absorption spectrophotometer (Z-6100: Hitachi Manufacturing) Determination of absorbance. Another iron standard solution 0 to 1.0 mL was taken, and the iron concentration was determined from the calibration curve prepared by the same operation.

試樣中之鐵濃度係利用下式算出。 The iron concentration in the sample was calculated by the following formula.

鐵(mg/100 g)=C×(100/V)×(100/W)×(100/1000) Iron (mg/100 g) = C × (100 / V) × (100 / W) × (100 / 1000)

C:由校正曲線求出之試驗溶液中之鈣濃度(ppm) C: calcium concentration in the test solution obtained from the calibration curve (ppm)

V:來自試樣溶液之分裝量 V: the amount of the sample from the sample solution

W:試樣之採用量(g) W: the amount of sample used (g)

(14)不溶性成分/水溶性褐藻膠成分(重量) (14) Insoluble ingredients / water-soluble alginate ingredients (weight)

由上述(6)及(8)中所獲得之值而計算。 It is calculated from the values obtained in the above (6) and (8).

將粉末褐藻之評價結果示於以下之表1中。再者,已知作為原料之褐藻中含有作為不溶性成分之不溶性海藻酸鹽,但認為,如製造例1~5所示,藉由利用含有鹼(碳酸鈉)之清洗液進行清洗,該不溶性海藻酸鹽變化為水溶性海藻酸鹽,不溶性成分之量減少,水溶性褐藻膠成分之量增加。 The evaluation results of the powder brown algae are shown in Table 1 below. In addition, it is known that the brown algae as a raw material contains insoluble alginate as an insoluble component, but it is considered that, as shown in Production Examples 1 to 5, the insoluble seaweed is washed by a washing liquid containing an alkali (sodium carbonate). The acid salt is changed to a water-soluble alginate, the amount of the insoluble component is reduced, and the amount of the water-soluble alginate component is increased.

實施例3:粉末褐藻之製造2Example 3: Production of powdered brown algae 2 製造例7~10Manufacturing example 7~10

於製造例1中,作為乾燥褐藻,使用褐藻綱-昆布目-昆布科-巨藻屬-巨海藻(Macrocystis pyrifera)、褐藻綱-昆布目-昆布科-昆布屬-昆布(Laminaria japonica)、褐藻綱-昆布目-翅藻科-裙帶菜屬-裙帶菜(Undaria pinnatifida)、或褐藻綱-墨角藻目-公牛藻科-公牛藻屬-南極公牛藻(Durvillaea antarctica),除此以外,進行與製造例1相同之處理,獲得粉末褐藻(製造例7~10)。 In Production Example 1, as a dry brown alga, a brown algae-Kumba-Kumba-Macrocystis pyrifera, a brown algae-Kumba-Kumbuco-Laminaria japonica, brown algae were used. - Undaria pinnatifida, or brown algae - Fucus algae - Bull algae - Bull algae - Durvillaea antarctica, in addition to The same treatment as in Production Example 1 was carried out to obtain powdered brown algae (Production Examples 7 to 10).

製造例11~14Manufacturing Example 11~14

於製造例6中,作為乾燥褐藻,使用褐藻綱-昆布目-昆布科-巨藻屬-巨海藻(Macrocystis pyrifera)、褐藻綱-昆布目-昆布科-昆布屬-昆布(Laminaria japonica)、褐藻綱-昆布目-翅藻科-裙帶菜屬-裙帶菜(Undaria pinnatifida)、或褐藻綱-墨角藻目-公牛藻科-公牛藻屬-南極公牛藻(Durvillaea antarctica),除此以外,進行與製造例1相同之處理,獲得粉末褐藻(製造例11~14)。 In Production Example 6, as a dry brown algae, a brown algae-Kumba-Kumba-Macrocystis pyrifera, a brown algae-Kumba-Kumbuco-Laminaria japonica, brown algae were used. - Undaria pinnatifida, or brown algae - Fucus algae - Bull algae - Bull algae - Durvillaea antarctica, in addition to The same treatment as in Production Example 1 was carried out to obtain powdered brown algae (Production Examples 11 to 14).

實施例4:粉末褐藻之評價2Example 4: Evaluation of powdered brown algae 2

針對實施例3獲得之粉末褐藻(製造例7~14),使用與實施例2相同之方法進行評價。將評價結果示於以下之表2中。 The powdered brown algae (Production Examples 7 to 14) obtained in Example 3 were evaluated in the same manner as in Example 2. The evaluation results are shown in Table 2 below.

實施例5:可可豆乳飲料之製造Example 5: Manufacture of cocoa soymilk beverage 可可豆乳飲料1~8Cocoa soy milk drink 1~8

分別使用0.3重量份之上述實施例1或3之粉末褐藻(製造例1~7或11),與砂糖5重量份、食鹽0.05重量份、可可粉末1重量份、甘油脂肪酸酯(Excel、花王公司製造)0.1重量份及蔗糖脂肪酸酯(DK Ester、第一工業製藥公司製造)0.03重量份共同混合,於常溫下將其分散至未調整豆乳23重量份中後,以全部達到100重量份之方式加入剩餘量之水。一面攪拌一面加熱溶解,使其達到75℃,繼而藉由高壓乳化機(APV-100、APV Systems公司)於15 MPa下均質化後,於沸水中殺菌10分鐘而製造可可豆乳飲料。將製成之可可豆乳飲料分別設為可可豆乳飲料1~8。 0.3 parts by weight of the powdered brown algae of the above Example 1 or 3 (Production Examples 1 to 7 or 11), 5 parts by weight of granulated sugar, 0.05 parts by weight of salt, 1 part by weight of cocoa powder, and glycerin fatty acid ester (Excel, Kao) were used, respectively. 0.1 parts by weight and 0.03 parts by weight of sucrose fatty acid ester (DK Ester, manufactured by Dai-ichi Kogyo Co., Ltd.) were mixed together, and dispersed to 23 parts by weight of unadjusted soybean milk at room temperature, and all reached 100 parts by weight. The way to add the remaining amount of water. The mixture was heated and dissolved while stirring to 75 ° C, and then homogenized by a high pressure emulsifier (APV-100, APV Systems) at 15 MPa, and then sterilized in boiling water for 10 minutes to produce a cocoa soy milk beverage. The cocoa soymilk beverages prepared are respectively set as cocoa soymilk drinks 1-8.

可可豆乳飲料9~10Cocoa soy milk drink 9~10

上述可可豆乳飲料1~7之製造方法中,使用下述者代替粉末褐藻:常用於防止豆乳飲料之沈澱的鹿角菜膠(GENULACTA type K-100-J、三晶公司製造)0.2重量份;或常用於防止霜淇淋混合物之沈澱的昆布中之主要多糖類即海藻酸鈉(Duck Algin、Kikkoman Biochemifa公司製造)0.2重量份,除此以外,以同樣之方式進行製造,獲得豆乳飲料9~10。 In the method for producing the above-mentioned cocoa soy milk beverages 1 to 7, the powdered brown algae is used in place of 0.2 parts by weight of carrageenan (manufactured by GENULACTA type K-100-J, manufactured by Sanken Co., Ltd.) which is often used for preventing precipitation of soymilk beverage; The soy milk beverage 9-10 is obtained in the same manner except that 0.2 parts by weight of sodium alginate (manufactured by Duck Algin, manufactured by Kikkoman Biochemifa Co., Ltd.), which is a main polysaccharide in the kelp which is used for preventing precipitation of the cream cream mixture, is used. .

可可豆乳飲料11Cocoa Soy Milk Drink 11

上述可可豆乳飲料1~8之製造方法中,不使用粉末褐藻,除此以外,以同樣之方式進行製造,獲得豆乳飲料11。 In the method for producing the above-mentioned cocoa soy milk beverages 1 to 8, the soy milk beverage 11 was obtained in the same manner except that the powdered brown algae was not used.

實施例6:可可豆乳飲料之評價Example 6: Evaluation of Cocoa Soymilk Beverage (1)大豆蛋白質及可可粉末之沈澱防止 (1) Precipitation prevention of soy protein and cocoa powder

針對實施例5獲得之可可豆乳飲料1~11,將其加入玻璃製之樣品瓶中,於冰箱中靜置5~6天,以目視確認是否存在大豆蛋白質與可可粉末之沈澱,對沈澱防止效果進行評價。將結果示於表3。 The cocoa soymilk beverages 1 to 11 obtained in Example 5 were added to a sample vial made of glass, and allowed to stand in a refrigerator for 5 to 6 days to visually confirm the presence or absence of precipitation of soybean protein and cocoa powder, and the effect of preventing sedimentation. Conduct an evaluation. The results are shown in Table 3.

(2)風味 (2) flavor

針對實施例5獲得之可可豆乳飲料1~11,分別進行試飲,確認風味。將結果示於表3。 The cocoa soymilk drinks 1 to 11 obtained in Example 5 were each subjected to a test drink to confirm the flavor. The results are shown in Table 3.

(3)可可豆乳飲料之黏度 (3) Viscosity of cocoa soy milk drink

針對實施例5獲得之可可豆乳飲料1~11,於液溫20℃下,使用BL型黏度計,於轉速60 rpm下求出黏度。 For the cocoa soymilk beverages 1 to 11 obtained in Example 5, the viscosity was determined at a rotation speed of 60 rpm using a BL type viscometer at a liquid temperature of 20 °C.

添加有製造例1~5及7之粉末褐藻之可可豆乳飲料1~5及7係大豆蛋白質及可可粉末之沈澱得以防止、風味亦較佳之飲料。又,亦未產生因添加粉末褐藻而導致之著色之問題。再者,可可豆乳飲料1~5及7均具有1~40 mPa‧s左右之較低之黏度,認為表3所示之沈澱防止效果並非由增黏作用產生。 A beverage in which the precipitation of the cocoa soy milk beverages 1 to 5 and the 7-series soybean protein and the cocoa powder of the powdered brown algae of the production examples 1 to 5 and 7 was prevented and the flavor was also improved. Moreover, there was no problem of coloring due to the addition of powdered brown algae. Furthermore, the cocoa soymilk drinks 1 to 5 and 7 each have a lower viscosity of about 1 to 40 mPa·s, and it is considered that the precipitation prevention effect shown in Table 3 is not caused by the adhesion enhancement.

實施例7:可可乳飲料之製造Example 7: Manufacture of cocoa milk beverage 可可乳飲料1~5Cocoa milk drink 1~5

分別使用0.3重量份之上述實施例1之粉末褐藻(製造例1~3、5或6),與砂糖5重量份、食鹽0.05重量份、可可粉末1重量份、甘油脂肪酸酯(Excel、花王公司製造)0.1重量份、蔗糖脂肪酸酯(DK Ester、第一工業製藥公司製造)0.03重量份共同混合,於常溫下將其分散於23重量份之牛乳中後,以全部達到100重量份之方式加入剩餘量之水。一面攪拌一面加熱溶解,使其達到75℃,繼而,藉由 高壓乳化機(APV-100、APV Systems公司)於15 MPa下均質化後,於沸水中殺菌10分鐘而製造可可乳飲料。將製成之可可乳飲料分別設為可可乳飲料1~5。 0.3 parts by weight of the powdered brown algae of the above Example 1 (manufacturing examples 1 to 3, 5 or 6), 5 parts by weight of granulated sugar, 0.05 parts by weight of salt, 1 part by weight of cocoa powder, and glycerin fatty acid ester (Excel, Kao) were used, respectively. 0.1 parts by weight of sucrose fatty acid ester (DK Ester, manufactured by Daiichi Kogyo Co., Ltd.), 0.03 parts by weight, and mixed at room temperature, after dispersing it in 23 parts by weight of milk, to 100 parts by weight. Add the remaining amount of water in a way. Stir on one side while heating to 75 ° C, and then The high-pressure emulsifier (APV-100, APV Systems) was homogenized at 15 MPa, and then sterilized in boiling water for 10 minutes to produce a cocoa milk beverage. The prepared cocoa milk drinks were respectively set to 1 to 5 of cocoa milk drinks.

可可乳飲料6~8Cocoa milk drink 6~8

上述可可乳飲料1~5之製造方法中,使用下述者代替粉末褐藻:常用於防止乳飲料之沈澱之鹿角菜膠(GENULACTA type K-100-J、三晶公司製造)0.2重量份;常用於防止霜淇淋混合物之沈澱之昆布中之主要之多糖類即海藻酸鈉(Duck Algin、Kikkoman Biochemifa公司製造)0.2重量份;或常用於防止乳飲料之沈澱之微晶纖維素(旭化成化學公司製造、Ceolus FD-101)0.2重量份,除此以外,以同樣之方式進行製造,獲得乳飲料6~8。 In the method for producing the above-mentioned cocoa milk beverages 1 to 5, the powder brown algae is used in place of 0.2 parts by weight of carrageenan (manufactured by GENULACTA type K-100-J, manufactured by Sanjing Co., Ltd.) which is often used for preventing precipitation of milk beverages; 0.2 g parts of sodium alginate (made by Duck Algin, manufactured by Kikkoman Biochemifa Co., Ltd.), the main polysaccharide in the kelp which prevents the precipitation of the cream cream mixture; or microcrystalline cellulose which is often used for preventing the precipitation of milk beverages (Asahi Kasei Chemical Co., Ltd.) The production was carried out in the same manner except that 0.2 parts by weight of Seolus FD-101) was produced, and milk beverages 6 to 8 were obtained.

可可乳飲料9Cocoa Milk Drink 9

上述可可乳飲料1~5之製造方法中,不使用粉末褐藻,除此以外,以同樣之方式進行製造,獲得乳飲料9。 In the method for producing the cocoa milk beverages 1 to 5, the powdered brown algae was used, and the same was carried out to obtain a milk beverage 9.

實施例8:可可乳飲料之評價Example 8: Evaluation of Cocoa Milk Beverage (1)乳蛋白質及可可粉末之沈澱防止 (1) Precipitation prevention of milk protein and cocoa powder

對於實施例7獲得之乳飲料1~9,將其加入玻璃製之樣品瓶中,於冰箱中靜置5~6天,以目視確認是否存在大豆蛋白質與可可粉末之沈澱,對沈澱防止效果進行評價。將結果示於表4。 For the milk beverages 1 to 9 obtained in Example 7, they were placed in a sample vial made of glass and allowed to stand in the refrigerator for 5 to 6 days to visually confirm the presence or absence of precipitation of the soy protein and the cocoa powder, and the effect of preventing sedimentation was carried out. Evaluation. The results are shown in Table 4.

(2)風味 (2) flavor

對於實施例7獲得之乳飲料1~9,分別進行試飲,確認風味。將結果示於表4。 The milk beverages 1 to 9 obtained in Example 7 were each subjected to a test drink to confirm the flavor. The results are shown in Table 4.

(3)可可乳飲料之黏度 (3) Viscosity of cocoa milk beverage

對於實施例7獲得之可可乳飲料1~9,於液溫20℃下,使用BL型黏度計,於轉速60 rpm下求出黏度。 For the cocoa milk drinks 1 to 9 obtained in Example 7, the viscosity was determined at a rotational speed of 60 rpm using a BL type viscometer at a liquid temperature of 20 °C.

添加有製造例1~3或5之粉末褐藻之乳飲料1~4係乳蛋白質及可可粉末之沈澱得以防止、風味亦較佳之飲料。又,亦未產生因添加粉末褐藻而導致之著色之問題。再者,乳飲料1~4均具有1~60 mPa‧s左右之較低之黏度,認為表4所示之沈澱防止效果並非由增黏作用產生。 A beverage in which the milk powder of the powdered brown algae of the production examples 1 to 3 or 5, the milk protein 1 and 4, and the cocoa powder were precipitated, and the flavor was also improved. Moreover, there was no problem of coloring due to the addition of powdered brown algae. Furthermore, the milk beverages 1 to 4 each have a low viscosity of about 1 to 60 mPa·s, and it is considered that the precipitation prevention effect shown in Table 4 is not caused by the viscosity enhancement.

實施例9:抹茶乳飲料之製造Example 9: Manufacture of matcha milk beverage 抹茶乳飲料1~5Matcha milk drink 1~5

分別使用0.3重量份之上述實施例1之粉末褐藻(製造例1~3、5或6),與砂糖7重量份、食鹽0.04重量份、抹茶粉末1重量份共同混合,於常溫下將其分散至牛乳30重量份中後,以全部達到100重量份之方式加入剩餘量之水。一面攪拌一面加熱溶解,使其達到75℃,繼而藉由高壓乳化機(APV-100、APV Systems公司)於20 MPa下均質化後,於沸 水中殺菌10分鐘而製造乳飲料。將製成之抹茶乳飲料分別設為抹茶乳飲料1~5。 0.3 parts by weight of the powdered brown algae of the above Example 1 (Production Examples 1 to 3, 5 or 6) were used, and 7 parts by weight of granulated sugar, 0.04 parts by weight of salt, and 1 part by weight of Matcha powder were mixed together and dispersed at normal temperature. After 30 parts by weight of the milk, the remaining amount of water was added in such a manner that the total amount reached 100 parts by weight. The mixture was heated and dissolved while stirring to 75 ° C, and then homogenized by a high pressure emulsifier (APV-100, APV Systems) at 20 MPa, and then boiled. A milk beverage was prepared by sterilizing in water for 10 minutes. The prepared matcha milk drinks were respectively set to 1 to 5 of matcha milk drinks.

抹茶乳飲料6~8Matcha milk drink 6~8

上述抹茶乳飲料1~5之製造方法中,使用下述者代替粉末褐藻:常用於防止乳飲料之沈澱的鹿角菜膠(GENULACTA type K-100-J、三晶公司製造)0.2重量份;常用於防止霜淇淋混合物之沈澱的昆布中之主要多糖類即海藻酸鈉(Duck Algin、Kikkoman Biochemifa公司製造)0.2重量份;或常用於防止乳飲料之沈澱的微晶纖維素(旭化成化學公司製造、Ceolus FD-101)0.2重量份,除此以外,以同樣之方式進行製造,獲得抹茶乳飲料6~8。 In the method for producing the above-mentioned matcha milk beverages 1 to 5, the powdered brown algae is used in place of 0.2 parts by weight of carrageenan (manufactured by GENULACTA type K-100-J, manufactured by Sanken Co., Ltd.) which is often used for preventing precipitation of milk beverages; 0.2 parts by weight of sodium alginate (made by Duck Algin, manufactured by Kikkoman Biochemifa Co., Ltd.), a main polysaccharide in kelp which prevents precipitation of a cream cream mixture, or microcrystalline cellulose (made by Asahi Kasei Chemical Co., Ltd.) which is commonly used for preventing precipitation of milk beverages In the same manner, except that 0.2 parts by weight of Ceolus FD-101) was used, a matcha milk beverage 6 to 8 was obtained.

抹茶乳飲料9Matcha milk drink 9

上述抹茶乳飲料1~5之製造方法中,不使用粉末褐藻,除此以外,以同樣之方式進行製造,獲得抹茶乳飲料9。 In the method for producing the above-mentioned matcha milk beverages 1 to 5, the powdered brown algae was used, and the same was carried out in the same manner to obtain a matcha milk beverage 9.

實施例10:抹茶乳飲料之評價Example 10: Evaluation of Matcha Milk Beverage (1)乳蛋白質及抹茶粉末之沈澱防止 (1) Precipitation prevention of milk protein and matcha powder

針對實施例9獲得之抹茶乳飲料1~9,將其加入玻璃製之樣品瓶中,於冰箱中靜置5~6天,以目視確認是否存在乳蛋白質與抹茶粉末之沈澱,對沈澱防止效果進行評價。將結果示於表5。 The matcha milk beverages 1 to 9 obtained in Example 9 were added to a sample vial made of glass, and allowed to stand in the refrigerator for 5 to 6 days to visually confirm the presence or absence of precipitation of milk protein and matcha powder, and the effect of preventing sedimentation was observed. Conduct an evaluation. The results are shown in Table 5.

(2)風味 (2) flavor

針對實施例9獲得之抹茶乳飲料1~9,分別進行試飲,確認風味。將結果示於表5。 The matcha milk drinks 1 to 9 obtained in Example 9 were each subjected to a test drink to confirm the flavor. The results are shown in Table 5.

(3)抹茶乳飲料之黏度 (3) Viscosity of matcha milk beverage

針對實施例9獲得之抹茶乳飲料1~9,於液溫20℃下,使用BL型黏度計,於轉速60 rpm下求出黏度。 The matcha milk beverages 1 to 9 obtained in Example 9 were obtained at a liquid temperature of 20 ° C using a BL type viscometer at a rotational speed of 60 rpm.

添加有製造例1~3或5之粉末褐藻之抹茶乳飲料1~4係乳蛋白質及抹茶粉末之沈澱得以防止、風味亦較佳之飲料。又,亦未產生因添加粉末褐藻而導致之著色之問題。再者,抹茶乳飲料1~4均具有1~60 mPa‧s左右之較低之黏度,認為表5所示之沈澱防止效果並非由增黏作用產生。 A beverage in which the precipitate of the 1 to 4 milk protein and the matcha powder of the powdered brown algae of the production example 1 to 3 or 5 was added and the flavor was also improved. Moreover, there was no problem of coloring due to the addition of powdered brown algae. Furthermore, the matcha milk beverages 1 to 4 each have a low viscosity of about 1 to 60 mPa·s, and it is considered that the precipitation prevention effect shown in Table 5 is not caused by the viscosity enhancement.

如上述實施例6所示,本發明之粉末褐藻具有即便為常用於防止飲料、尤其是乳飲料之沈澱的鹿角菜膠亦無法完成之針對可可豆乳飲料之優異的沈澱防止作用。又,如上述實施例7所示,即便於使用牛乳代替豆乳之飲料中亦具有沈澱防止作用。進而,如上述實施例10所示,即便於使用抹茶粉末之飲料中,亦與使用可可粉末之情形同樣地具有沈澱防止作用。因此認為,不僅可添加至先前使用鹿角菜膠進行沈澱防止之飲料中,亦有藉由添加至目前為止因沈澱或分離而無法商品化之液體商品中而產生出新液體商 品之可能性,商品價值非常高。 As shown in the above-mentioned Example 6, the powdered brown algae of the present invention has an excellent precipitation preventing action against the cocoa soymilk beverage even if the carrageenan which is commonly used for preventing the precipitation of beverages, especially milk beverages, cannot be completed. Further, as shown in the above-mentioned Example 7, even in the beverage using cow's milk instead of soymilk, it has a precipitation preventing effect. Further, as shown in the above-described Example 10, even in the case of using the matcha powder, it has a precipitation preventing action as in the case of using the cocoa powder. Therefore, it is considered that not only can it be added to a beverage which has been previously used for sedimentation prevention by carrageenan, but also a new liquid quotient is produced by adding to a liquid commodity which has not been commercialized by sedimentation or separation so far. The possibility of goods, the value of goods is very high.

實施例11:吐司麵包Example 11: Toast Bread 11-1吐司麵包之製造11-1 Toast Bread Manufacturing

於高筋麵粉90重量份中加入木薯澱粉10重量份,以粉體方式混合,製成100重量份。 10 parts by weight of tapioca starch was added to 90 parts by weight of the high-gluten flour, and mixed in a powder form to prepare 100 parts by weight.

於其中以粉體方式混合綿白糖5重量份、食鹽2重量份、脫脂奶粉2重量份、醱酵食品0.1重量份。 5 parts by weight of cotton white sugar, 2 parts by weight of salt, 2 parts by weight of skim milk powder, and 0.1 parts by weight of yeast food were mixed in a powder form.

進而,加入0.5重量份之先前通常用作麵包之改良劑之食品添加物即微晶纖維素(旭化成化學公司製造、Ceolus FD-101)、果膠(Hercules公司製造、GENU Pectin Freeze-J)、海藻酸鈉(Kikkoman Biochemifa公司製造、Duck Algin)、海藻酸鈣(FMC Biopolymer公司製造、TXF 200)或海藻酸酯(Kikkoman Biochemifa公司製造、Duck Loid)或製造例1或6之粉末褐藻中之任一種作為改良劑,並充分混合。 Further, 0.5 parts by weight of a food additive previously used as a bread improver, microcrystalline cellulose (manufactured by Asahi Kasei Chemical Co., Ltd., Ceolus FD-101), pectin (manufactured by Hercules, GENU Pectin Freeze-J), Sodium alginate (manufactured by Kikkoman Biochemifa, Duck Algin), calcium alginate (manufactured by FMC Biopolymer, TXF 200) or alginic acid (manufactured by Kikkoman Biochemifa, Duck Loid) or powdered brown algae of Production Example 1 or 6 One is used as a modifier and is thoroughly mixed.

將該粉體粉體分別投入攪拌器(SK Mixer公司製造、SK 10)中,添加使乾酵母1.5重量份分散於水65重量份之一部分中而成者後,進而加入剩餘之水,低速混合3分鐘,中速混合6分鐘。 The powder powder was placed in a stirrer (manufactured by SK Mixer Co., Ltd., SK 10), and 1.5 parts by weight of dry yeast was added to one part of 65 parts by weight of water, and then the remaining water was added thereto, and the mixture was mixed at a low speed. 3 minutes, mix at medium speed for 6 minutes.

進而,添加起酥油5重量份,低速混合3分鐘,中速混合6分鐘,高速混合2分鐘,獲得生麵球。 Further, 5 parts by weight of shortening was added, mixed at a low speed for 3 minutes, mixed at a medium speed for 6 minutes, and mixed at a high speed for 2 minutes to obtain a dough ball.

適當調節粉溫、水溫、室溫,使生麵團之捏合溫度達到約28℃。將所獲得之生麵球放入容器中,以濕毛巾覆蓋後放入恆溫機中,使其於30℃下醱酵70分鐘。將生麵團之氣 體排出後,分割為280 g。 The powder temperature, water temperature, and room temperature were appropriately adjusted so that the kneading temperature of the dough reached about 28 °C. The obtained dough ball was placed in a container, covered with a wet towel, placed in a thermostat, and fermented at 30 ° C for 70 minutes. Will be the dough After the body is discharged, it is divided into 280 g.

經過25分鐘放置醱酵時間後,成形並放入模具中,然後放入培爐中,於38℃、濕度85%之條件下最後醱酵60分鐘。 After leaving the fermentation time for 25 minutes, it was formed into a mold, placed in a furnace, and finally fermented for 60 minutes at 38 ° C and a humidity of 85%.

將其放入烘箱中,於210℃下焙燒20分鐘,獲得吐司麵包。 This was placed in an oven and baked at 210 ° C for 20 minutes to obtain toast bread.

將所獲得之吐司麵包冷卻至室溫。另一方面,於上述之吐司麵包製造中,以相同方式製造未加改良劑者作為對照。 The toasted bread obtained was cooled to room temperature. On the other hand, in the above-mentioned toast bread production, the unmodified agent was produced in the same manner as a control.

11-2相對體積11-2 relative volume

針對上述11-1所製造之各麵包,於製造第二天測定其高度,乘以模具之縱向長度及橫向長度,算出麵包之體積,藉由以下之計算式算出麵包之相對體積(份)。 For each of the breads produced in the above 11-1, the height was measured on the second day of manufacture, multiplied by the longitudinal length and the lateral length of the mold, and the bread volume was calculated, and the relative volume (parts) of the bread was calculated by the following calculation formula.

所謂相對體積,係用各試驗區之體積除以對照區之體積後,以份表示者。認為麵包之體積較大者外觀較鬆軟,組織之比重即每1 cm3之重量變得較輕,影響到柔軟之食感,亦有較多較佳之情形,但若體積過大,則亦存在組織變得空隙較多而引起空洞現象,或導致難以咀嚼之現象之情況,需加以注意。 The relative volume is expressed in parts after dividing the volume of each test zone by the volume of the control zone. It is considered that the larger the bread size is softer, the weight of the tissue becomes lighter per 1 cm 3 , which affects the soft food texture, and there are many better cases, but if the volume is too large, there is also tissue. Need to pay attention to the situation that it becomes more voids and causes voids, or causes it to be difficult to chew.

將結果示於下述表6。根據所添加之改良劑之不同,可獲得相對體積不同之麵包。添加製造例1之粉末褐藻之情 形時,可獲得不僅不遜於添加先前一直使用之食品添加物之情形、並且具有更佳之相對體積之麵包。 The results are shown in Table 6 below. Breads of different relative volumes can be obtained depending on the modifiers added. Adding the powder brown algae of the manufacturing example 1 In the case of a shape, it is possible to obtain a bread which is not only inferior to the case of adding a food additive which has been used before, and has a better relative volume.

11-3相對良率11-3 relative yield

測定上述11-1中之各麵包之製造時之焙燒前之生麵球的重量及製成之麵包之製造第二天的重量,藉由以下之計算式,由表示麵包重量相對於生麵團重量之比率之重量良率(份)算出相對良率(份)。 The weight of the dough ball before calcination and the weight of the second day of manufacture of the prepared bread at the time of manufacture of each of the above 11-1 breads were measured, and the weight of the bread relative to the dough weight was expressed by the following formula The weight yield (parts) of the ratio is calculated as the relative yield (parts).

所謂相對良率,係用試驗區之焙燒前後之重量良率除以對照區之重量良率後,以份表示者。若超過100,數值較大,則認為具有提高良率之效果,由於數值過高之情形時,亦存在未烤熟之可能性,故而需加以注意。 The relative yield is expressed in parts after dividing the weight yield before and after calcination in the test zone by the weight yield of the control zone. If it exceeds 100, the value is large, and it is considered to have an effect of improving the yield. Since the value is too high, there is a possibility that it is not cooked, so care must be taken.

將結果示於下述表6。根據所添加之改良劑之不同,可獲得相對良率不同之麵包。添加製造例1之粉末褐藻之情形時,可獲得不僅不遜於添加先前一直使用之食品添加物之情形、並且具有更佳之相對良率之麵包。 The results are shown in Table 6 below. Depending on the modifier to be added, breads with different yields can be obtained. In the case of adding the powdered brown algae of Production Example 1, it is possible to obtain a bread which is not only inferior to the case where the food additive which has been used before is added, but also has a better relative yield.

11-4相對比容11-4 relative volume

針對上述11-1所製造之各麵包,以上述11-2及11-3所記載之方法測定製造第二天之麵包之體積與重量。藉由以下之計算式,由表示麵包之相對於每1 cm3之重量之比率的比容算出相對比容(份)。 For each of the breads produced in the above 11-1, the volume and weight of the bread of the second day of manufacture were measured by the methods described in the above 11-2 and 11-3. The relative specific volume (parts) is calculated from the specific volume representing the ratio of the bread to the weight per 1 cm 3 by the following calculation formula.

所謂相對比容,係用試驗區之比容除以對照區之比容 後,以份表示者。若超過100,數值較大,則認為每1 cm3之重量變輕,影響到柔軟之食感,亦存在較多較佳之情形,但若值過高,則亦存在組織變得空隙較多而引起空洞現象,或導致難以咀嚼之現象之情況,需加以注意。 The relative specific volume is expressed in parts after dividing the specific volume of the test zone by the specific volume of the control zone. If it exceeds 100 and the value is large, it is considered that the weight per 1 cm 3 becomes lighter, which affects the soft texture. There are also many better cases. However, if the value is too high, the structure becomes more void. Attention should be paid to the situation that causes a void or a phenomenon that is difficult to chew.

將結果示於下述表6。根據所添加之改良劑之不同,可獲得相對比容不同之麵包。添加製造例1之粉末褐藻之情形時,可獲得不僅不遜於添加先前一直使用之食品添加物之情形、並且具有更佳之相對比容之麵包。 The results are shown in Table 6 below. Breads of different specific specific abilities can be obtained depending on the modifier to be added. In the case of adding the powdered brown algae of Production Example 1, it is possible to obtain a bread which is not only inferior to the case where the food additive which has been used before is added, and which has a better relative specific volume.

11-5紋理解析11-5 texture analysis

針對上述11-1所製造之各麵包,於製造第二天將所製成之麵包切為厚度3 cm,使用流變計(SUN Science公司製造、Rheo Meter CR-500DX),進行以下之11-5-1~11-5-6中記載之紋理解析。 For each of the breads produced in the above 11-1, the bread produced was cut to a thickness of 3 cm on the second day of manufacture, and a rheometer (manufactured by SUN Science, Rheo Meter CR-500DX) was used to carry out the following 11- Texture analysis described in 5-1~11-5-6.

分析條件設為柱塞速度300 mm/min、間隙10 mm、重複 2次。 The analysis conditions were set to a plunger speed of 300 mm/min, a gap of 10 mm, and a repetition. 2 times.

針對上述11-1所獲得之各麵包,對製造第二天之在室溫下放置者與利用專業電子爐(三洋電機產業公司製造、Range-pro EM-1503T)於1,500 W下對其進行電子爐加熱處理15秒而獲得者進行紋理解析。 For each bread obtained in the above 11-1, the person who was placed at room temperature on the second day of manufacture was electronically charged at 1,500 W using a professional electric furnace (manufactured by Sanyo Electric Industries Co., Ltd., Range-pro EM-1503T). The furnace was heat treated for 15 seconds and the winner was subjected to texture analysis.

再者,關於相對彈力性、相對凝聚性、相對膠著性及相對咀嚼性,經電子爐加熱處理者之分析較為困難,只對製造第二天之在室溫下放置之麵包進行紋理解析。 Furthermore, regarding relative elasticity, relative cohesiveness, relative adhesion, and relative chewiness, it is difficult to analyze the heat treatment by the electric furnace, and only the bread placed at room temperature on the second day of manufacture is subjected to texture analysis.

11-5-1相對最大荷重11-5-1 relative maximum load

測定將柱塞壓入試樣而切斷所需之最大荷重(重量),進而算出相對最大荷重(份)。 The maximum load (weight) required for cutting the plunger into the sample was measured, and the relative maximum load (parts) was calculated.

所謂相對最大荷重,係用試驗區之最大荷重除以對照區之最大荷重後,以份表示者。若該值較大,則表示切斷需要較大之力,故為以牙齒咬、以舌擠碎或以手撕碎需要用力之較硬之麵包,若值較小,則表示為牙齒容易咬、舌容易擠碎、手容易撕碎、即「柔軟」之麵包。 The so-called relative maximum load is expressed in parts after dividing the maximum load of the test zone by the maximum load of the control zone. If the value is large, it means that the cutting requires a large force, so it is a bite that needs to be hard to bite, crushed by the tongue or shredded by hand. If the value is small, it means that the tooth is easy to bite. The tongue is easily crushed, and the hand is easily shredded, that is, "soft" bread.

11-5-2相對變形率11-5-2 relative deformation rate

測定將柱塞壓入試樣直至切斷前,試樣未斷而凹陷變形之相對於原來之厚度的比率即變形率(份),繼而算出相對變形率。 The ratio of the deformation ratio (parts) which is the ratio of the thickness of the sample to the original thickness before the cutting of the sample was measured until the sample was pressed, and the relative deformation ratio was calculated.

所謂相對變形率,係用試驗區之變形率除以對照區之變形率後,以份表示者。若該值較大,則表示直至切斷前試樣凹陷變形之長度較長,為難以切斷之麵包,若值較小,則表示變形之長度較短,為容易切斷之具有「鬆脆柔軟」 或「酥脆柔軟」之食感之麵包。 The relative deformation rate is expressed in parts after dividing the deformation rate of the test zone by the deformation rate of the control zone. If the value is large, it means that the length of the deformation of the sample before the cutting is long, which is a bread that is difficult to cut. If the value is small, the length of the deformation is short, and it is easy to cut. soft" Or "crunchy and soft" bread.

11-5-3相對彈力性11-5-3 relative elasticity

紋理解析中,測定因將柱塞壓入試樣中導致之試樣之變形於撤去力時恢復之比率,將該比率表示為彈力性。用試驗區之彈力性除以對照區之彈力性後,以份表示算出相對彈力性。 In the texture analysis, the ratio at which the deformation of the sample caused by pressing the plunger into the sample was recovered at the withdrawal force was measured, and the ratio was expressed as the elasticity. After the elasticity of the test zone is divided by the elasticity of the control zone, the relative elasticity is calculated in parts.

若該值較大,則係指按下時之恢復具有較強之彈力,若值較小,則係指恢復較差,成為一直凹陷之狀態,彈力較弱。即,若值較大,則表示為具有有「彈性」之食感之麵包。 If the value is large, it means that the recovery has a strong elastic force when pressed, and if the value is small, it means that the recovery is poor, and the state is always depressed, and the elasticity is weak. That is, when the value is large, it is expressed as a bread having a "elastic" texture.

11-5-4相對凝聚性11-5-4 relative cohesion

紋理解析中,重複2次將柱塞壓入試樣中並施加負荷之操作,測定第1次與第2次之負荷能之比率,將其表示為凝聚性。 In the texture analysis, the operation of pressing the plunger into the sample and applying a load was repeated twice, and the ratio of the first and second load energies was measured, and this was expressed as cohesiveness.

用試驗區之凝聚性除以對照區之凝聚性後,以份表示算出相對凝聚性。若該值較大,則表示難以變形,難以崩散,即,為難以食用之麵包,若值較小,則表示為具有「容易崩散」、「易於食用」、「融口感較佳」之食感之麵包。 After the cohesiveness of the test zone was divided by the cohesiveness of the control zone, the relative cohesiveness was calculated in parts. If the value is large, it means that it is difficult to deform and it is difficult to disintegrate, that is, it is a bread that is difficult to eat. If the value is small, it means that it is "easy to collapse", "easy to eat", and "better in melting". Foody bread.

11-5-5相對膠著性11-5-5 relative adhesiveness

將用上述11-5-4所測定之凝聚性乘以上述11-5-1所測定之最大荷重而獲得之值表示為膠著性。 The value obtained by multiplying the cohesiveness measured by the above 11-5-4 by the maximum load measured by the above 11-5-1 is expressed as a tackiness.

用試驗區之膠著性除以對照區之膠著性後,以份表示算出相對膠著性。若該值較大,則表示膠狀感/橡膠狀感/糊 狀感較強,即為難以下嚥之麵包,若值較小,則表示為具有膠狀感較小、「容易崩散」、「易於下嚥」之食感之麵包。 After the adhesion of the test zone was divided by the adhesion of the control zone, the relative adhesion was calculated in parts. If the value is large, it means a gel-like feeling/rubbery feeling/paste The shape is strong, that is, it is a bread that is difficult to swallow. If the value is small, it is a bread with a feeling of gelatininess, "easy to collapse", and "easy to swallow".

11-5-6相對咀嚼性11-5-6 relative chewiness

將用上述11-5-3所測定之彈力性乘以上述11-5-5所測定之膠著性而獲得之值表示為咀嚼性。 The value obtained by multiplying the elasticity measured by the above 11-5-3 by the adhesiveness measured by the above 11-5-5 is expressed as chewiness.

用試驗區之咀嚼性除以對照區之咀嚼性後,以份表示算出相對咀嚼性。若該值較大,則表示咀嚼所需之力較大,即為直至將其磨碎為可下嚥之狀態所需之力較大、難以咀嚼之麵包,若值較小,則表示咀嚼所需之力較小,為具有「容易咀嚼」、「融口感較佳」之食感之麵包。 After the chewability of the test area was divided by the chewiness of the control area, the relative chewiness was calculated in parts. If the value is large, it means that the force required for chewing is large, that is, the bread which is required to be grinded into a state capable of swallowing and which is difficult to chew, and if the value is small, it means a chewing place. It has less force and is a bread with a sense of "easy to chew" and "feel better".

對於上述紋理解析,將在室溫下放置之麵包之結果示於表7,將剛以專業電子爐對麵包進行加熱處理後之結果示於表8。 For the texture analysis described above, the results of the bread placed at room temperature are shown in Table 7, and the results of heat treatment of the bread just in a professional electric furnace are shown in Table 8.

添加製造例1之粉末褐藻之情形時,紋理解析之任一項中均具有較佳之值,可獲得不僅不遜於添加先前一直使用之食品添加物之情形、並且紋理更佳之麵包。 When the powdered brown algae of Production Example 1 is added, it has a preferable value in any of the texture analysis, and a bread which is not only inferior to the case where the food additive which has been used before is added, and which has a better texture can be obtained.

11-6官能檢查11-6 functional examination

對於上述11-1所製造之各麵包,於製造第二天進行官能檢查。具體而言,於是否為柔軟之食感、是否為令人愉悅之彈力感、融口感是否較佳方面,以對照區為0,以較佳者為+,以-3至+3之7個等級進行評價,藉由平均分表示。 For each of the breads produced in the above 11-1, the functional inspection was performed on the second day of manufacture. Specifically, in terms of whether it is a soft food texture, whether it is a pleasant feeling of elasticity, or whether the mouth feel is good, the control area is 0, preferably +, and -3 to +3 Ratings are evaluated by means of an average score.

官能檢查係由經訓練之共計15名官能檢查員進行。又,選出自己最喜歡之食感之1種麵包,以人數表示嗜好性。 The functional examination was performed by a total of 15 functional inspectors trained. In addition, one of the breads of your favorite food is selected, and the hobby is expressed by the number of people.

另一方面,針對所製成之麵包之外觀,評價以菜刀切斷之面。將結果示於表9。 On the other hand, for the appearance of the prepared bread, the surface cut with a kitchen knife was evaluated. The results are shown in Table 9.

添加製造例1之粉末褐藻之情形時,官能檢查之任一項中均平衡性良好地具有較高之評價,可獲得與添加先前一直使用之食品添加物之情形相比總分及嗜好性最高之麵包。又,調配製造例6之粉末褐藻之情形時,獲得官能檢查之任一項中均為評價較低、總分及嗜好性亦較低、進而具有黑點、外觀亦欠佳之麵包。 When the powdered brown algae of the production example 1 was added, the balance of the functional test was excellent, and the evaluation was excellent, and the total score and the preference were higher than those of the food additive which had been used before. Bread. Further, in the case of blending the powdered brown algae of Production Example 6, any of the functional test was obtained, which was low in evaluation, low in total score and preference, and further had black spots and poor appearance.

實施例12:中式拉麵Example 12: Chinese ramen 12-1中式拉麵之製造12-1 Chinese Ramen Manufacturing

於95.0重量份之準高筋麵粉中加入5.0重量份之木薯澱粉並充分混合,製成100.0重量份之粉體。 To 95.0 parts by weight of the quasi-high-gluten flour, 5.0 parts by weight of tapioca starch was added and thoroughly mixed to prepare 100.0 parts by weight of a powder.

相對於該100.0重量份,進而加入0.5重量份之先前通常用作麵條類之改良劑之食品添加物即微晶纖維素(旭化成化學公司製造、Ceolus FD-101)、κ-鹿角菜膠(三晶公司、GENULACTA type K-100-J)、卡德蘭膠(武田藥品工業公司製造、卡德蘭膠)、古亞膠(三榮藥品貿易公司製造、Guarcol U-40)、三仙膠(丸善藥品產業公司製造、Xanthan FNCS)、海藻酸鈉(Kikkoman Biochemifa公司製造、Duck Algin)或海藻酸鈣(FMC Biopolymer公司製造、TXF 200)、或者製造例1或6之粉末褐藻中之任一種作為改良劑並充分混合。 With respect to the 100.0 parts by weight, 0.5 parts by weight of a food additive previously used as a modifier for noodles, that is, microcrystalline cellulose (manufactured by Asahi Kasei Chemical Co., Ltd., Ceolus FD-101), kappa-carrageenan (three Crystal Corporation, GENULACTA type K-100-J), Kadran gum (manufactured by Takeda Pharmaceutical Co., Ltd., Kadran Glue), Guaya Gum (manufactured by Sanrong Pharmaceutical Trading Co., Ltd., Guarcol U-40), Sanxian Gum ( Any of the powdered brown algae manufactured by Maruzen Pharmaceutical Industries Co., Ltd., Xanthan FNCS), sodium alginate (Kikkoman Biochemifa, Duck Algin) or calcium alginate (FMC Biopolymer, TXF 200), or the production example 1 or 6 Improver and mix well.

另一方面,充分混合1.0重量份之食鹽,將其溶解於34.0重量份之水中並使之懸浮而製成混練水。 On the other hand, 1.0 part by weight of the salt was sufficiently mixed, dissolved in 34.0 parts by weight of water, and suspended to prepare a kneaded water.

將其分別加入上述準高筋麵粉、木薯澱粉及改良劑之混合粉體中混合10分鐘,經過10分鐘之熟化時間後,藉由常 法使生麵團通過輥軋輥而製成粗麵帶(3.0 mm),將2層重疊通過輥,將此作業重複兩次。 Adding them to the above mixed powder of quasi-high-gluten flour, tapioca starch and improver for 10 minutes, after 10 minutes of ripening time, by usual The dough was passed through a roll to make a dough strip (3.0 mm), and two layers were overlapped by a roll, and this work was repeated twice.

藉由同一輥將其依序壓延至2.0 mm→1.5 mm→1.0 mm後,使其通過安裝有角20號之切刀之切麵條機,切割為麵線狀而獲得生麵條。 After being calendered to 2.0 mm → 1.5 mm → 1.0 mm by the same roller, it was cut into a noodle shape by a noodle machine equipped with a No. 20 cutter to obtain raw noodles.

將該生中式拉麵於生的狀態下裝入聚乙烯袋中,在冰箱中保管一晚。 The raw Chinese ramen was placed in a polyethylene bag in a raw state, and stored in a refrigerator for one night.

另一方面,上述中式拉麵之製造中,以同樣方式製造未加改良劑者作為對照。 On the other hand, in the manufacture of the above-mentioned Chinese ramen, the unmodified agent was produced in the same manner as a control.

12-2麵線拉伸試驗12-2 upper thread tensile test

針對上述12-1製造之各中式拉麵,於製造第二天,將生中式拉麵之麵線切為8 cm,於沸水中煮3分30秒後,使用流變計(SUN Science公司製造、Rheo Meter CR-500DX)進行以下之12-2-1及12-2-2之拉伸試驗。 For the Chinese ramen noodles manufactured in the above 12-1, the noodle of the raw ramen noodles was cut to 8 cm on the second day of manufacture, and after boiling for 3 minutes and 30 seconds in boiling water, a rheometer (manufactured by SUN Science, Rheo) was used. Meter CR-500DX) Perform the tensile tests of 12-2-1 and 12-2-2 below.

分析條件為拉伸速度設為150 mm/min,直至麵線被拉斷。 The analysis conditions were such that the stretching speed was set to 150 mm/min until the upper thread was broken.

12-2-1相對拉伸應力12-2-1 relative tensile stress

將麵線向相反方向拉伸,測定切斷所需之拉伸應力(重量),繼而算出相對拉伸應力(份)。 The needle thread was stretched in the opposite direction, and the tensile stress (weight) required for cutting was measured, and then the relative tensile stress (part) was calculated.

所謂相對拉伸應力,係用試驗區之拉伸應力除以對照區之拉伸應力後,以份表示者。若該值較小,則表示較少之力可將麵線切斷,故牙齒容易咬、舌容易擠碎,麵條伸長時該值亦會降低,為鬆軟且柔軟之麵條。若該值較大,則表示以牙齒咬、以舌擠碎或以手撕碎需要用力,認為亦與 麵條之彈性相關,為「較硬」「有咬勁」之麵條。將結果示於表10。 The relative tensile stress is expressed in parts after the tensile stress of the test zone is divided by the tensile stress of the control zone. If the value is small, it means that less force can cut the upper thread, so the teeth are easy to bite, the tongue is easily crushed, and the value is also lowered when the noodles are stretched, which is a soft and soft noodle. If the value is large, it means that the teeth are bitten, the tongue is crushed or the hands are shredded. The elasticity of the noodles is related to the "harder" and "bite" noodles. The results are shown in Table 10.

12-2-2相對變形率12-2-2 relative deformation rate

將麵線向相反方向拉伸,測定直至切斷前試樣未斷、伸長而變形之相對於原來之長度的比率即變形率(份),繼而算出相對變形率。 The needle thread was stretched in the opposite direction, and the ratio of the deformation to the original length, that is, the deformation ratio (part) before the cutting, was measured, and the relative deformation ratio was calculated.

所謂相對變形率,係用試驗區之變形率除以對照區之變形率後,以份表示者。若該值較小,則變形之長度較短、容易切斷,故而作為麵條而言係指「鬆脆容易切斷」。若該值較大,則表示直至切斷前試樣變形之長度較長,認為亦與麵條之彈性相關,如橡膠般不易斷裂而充分伸長,為「有延伸性」之麵條。將結果示於表10。 The relative deformation rate is expressed in parts after dividing the deformation rate of the test zone by the deformation rate of the control zone. If the value is small, the length of the deformation is short and it is easy to cut. Therefore, as a noodle, it means "crunchy and easy to cut". If the value is large, it means that the length of the deformation of the sample until the cutting is long, and it is considered that it is also related to the elasticity of the noodle, and is not easily broken by rubber and is sufficiently elongated to be an "extended" noodle. The results are shown in Table 10.

添加製造例1之粉末褐藻之情形時,可獲得不遜於添加先前之食品添加物之情形、咬勁良好、並且有延伸性之中式拉麵。 When the powdered brown algae of Production Example 1 was added, it was possible to obtain a kneading dough which was not inferior to the case where the prior food additive was added, which had a good bite and an extensibility.

12-3官能檢查12-3 functional examination

針對上述12-1製造之各中式拉麵,於製造第二天進行官能檢查。 For each of the Chinese ramen manufactured by the above 12-1, the functional inspection was performed on the second day of manufacture.

關於官能檢查,將各生中式拉麵於沸水中煮3分鐘30秒而烹飪,針對放入裝有湯之容器中者,於剛完成烹飪後以及於湯中保持10分鐘後實施官能檢查。具體而言,針對剛完成烹飪之麵條,評價是否為順滑之食感、硬度是否充分、是否具有令人愉悅之彈力,繼而針對在湯中保持10分鐘後之麵條,評價煮後延伸情況,以對照區為0,以較佳者為+,以-3至+3之7個等級進行評價,藉由平均分表示。 For the functional inspection, each of the raw Chinese ramen was cooked in boiling water for 3 minutes and 30 seconds for cooking, and for the person who was placed in the container filled with the soup, the functional test was performed immediately after the cooking was completed and after 10 minutes in the soup. Specifically, for the noodles that have just been cooked, it is evaluated whether it is a smooth food texture, whether the hardness is sufficient, whether it has a pleasant elasticity, and then the noodle after 10 minutes in the soup is evaluated, and the post-cooking extension is evaluated. The control area is 0, preferably +, and 7 to -3 to 3, and is represented by the average score.

官能檢查係由經訓練之共計20名官能檢查員進行。又,選出自己最喜歡之食感之1種麵條,以人數表示嗜好性。另一方面,關於經煮過之中式拉麵之外觀,以目視評價其色彩。將結果示於表11。 The functional examination was performed by a total of 20 functional inspectors trained. In addition, one type of noodles of your favorite food is selected, and the hobby is expressed by the number of people. On the other hand, regarding the appearance of the cooked Chinese ramen, the color was visually evaluated. The results are shown in Table 11.

添加製造例1之粉末褐藻之情形時,官能檢查之任一項中均平衡性良好地具有較高之評價,可獲得與添加先前一 直使用之食品添加物之情形相比總分及嗜好性最高之中式拉麵。又,調配製造例6之粉末褐藻之情形時,可獲得嗜好性較低、外觀亦為茶色之較差之中式拉麵。 When the powdered brown algae of Production Example 1 was added, the balance of any of the functional tests was well evaluated, and the previous one was obtained and added. The case of the food additive used directly compared to the total score and the most desirable middle-sized ramen. Further, in the case of blending the powdered brown algae of Production Example 6, it is possible to obtain a poorly-like ramen type having a low taste and a brown appearance.

實施例13:烏龍麵Example 13: Udon Noodles 13-1烏龍麵之製造13-1 manufacture of oolong noodles

於100.0重量份之中筋麵粉中加入0.5重量份之實施例12所使用之改良劑(先前通常用作麵條類之改良劑之食品添加物即微晶纖維素、κ-鹿角菜膠、卡德蘭膠、古亞膠、三仙膠、海藻酸鈉或海藻酸鈣或製造例1或6之粉末褐藻中之一種)並充分混合。 0.5 parts by weight of the modifier used in Example 12 was added to 100.0 parts by weight of the gluten flour (previously used as a food additive for noodle improver, microcrystalline cellulose, kappa-carrageenan, Cardland Gum, Guadal, Sanxian gum, sodium alginate or calcium alginate or one of the powdered brown algae of Production Example 1 or 6) and thoroughly mixed.

另一方面,將2.0重量份之食鹽溶於34.0重量份之水中使之懸浮而製成混練水。 On the other hand, 2.0 parts by weight of the salt was dissolved in 34.0 parts by weight of water to be suspended to prepare a kneaded water.

將其分別加入上述之中筋麵粉與改良劑之混合物中並混合10分鐘,經過10分鐘之熟化時間後,藉由常法,使生麵團通過輥軋輥而製成粗麵帶(3.0 mm),將2層重疊,重複2次通過輥之作業。 Adding them separately to the above mixture of gluten flour and improver and mixing for 10 minutes. After 10 minutes of aging time, the dough is passed through a roll to make a dough strip (3.0 mm) by a conventional method. The two layers overlap and the operation of passing the roller is repeated twice.

藉由同一輥將其依序壓延至2.3 mm→2.0 mm→1.7 mm後,使其通過安裝有角10號之切刀之切麵條機,切割為麵線狀而獲得生麵條。 After being calendered to 2.3 mm → 2.0 mm → 1.7 mm by the same roller, it was cut into a noodle shape by a noodle machine equipped with a No. 10 cutter to obtain raw noodles.

將該生烏龍麵於生的狀態下裝入聚乙烯袋中,於冰箱中保管一晚。 The raw udon noodles were placed in a polyethylene bag in a state of being stored, and stored in a refrigerator for one night.

另一方面,上述烏龍麵之製造中,以相同方式製造未加改良劑者作為對照。 On the other hand, in the manufacture of the above-mentioned oolong noodle, the unmodified agent was produced in the same manner as a control.

13-2麵線拉伸試驗13-2 upper thread tensile test

針對上述13-1所製造之各烏龍麵,於製造第二天將生烏龍麵之麵線切為8 cm,以沸水煮15分鐘後,利用與上述12-2相同之方法進行拉伸試驗。將結果示於表12。 For each of the oolong noodles manufactured in the above 13-1, the noodle line of the raw oolong noodles was cut into 8 cm on the second day of manufacture, and boiled for 15 minutes in boiling water, and then stretched by the same method as the above 12-2. test. The results are shown in Table 12.

添加製造例1之粉末褐藻之情形時,可獲得與添加先前之食品添加物之情形相比更佳、咬勁良好、並且有延伸性之烏龍麵。 When the powdered brown algae of Production Example 1 was added, it was possible to obtain a better, bite-strength, and extensible wok face as compared with the case of adding the previous food additive.

13-3官能檢查13-3 functional examination

針對上述13-1製造之個烏龍麵,於製造第二天進行官能檢查。 For the udon noodles manufactured in the above 13-1, the functional inspection was performed on the second day of manufacture.

關於官能檢查,將各生烏龍麵於沸水中煮15分鐘而烹飪,針對放入裝有湯之容器中者,於剛完成烹飪後即於湯中保持10分鐘後實施官能檢查。具體而言,對於剛完成烹飪後之麵條,關於是否為順滑之食感、硬度是否充分、及是否具有令人愉悅之彈牙感之黏彈性,繼而針對在湯中保持10分鐘後之麵條,關於煮後延伸情況,以對照區為0,以較佳者為+,以-3至+3之7個等級進行評價,藉由平均分 表示。 For the functional examination, the raw udon noodles were cooked in boiling water for 15 minutes for cooking, and for the person who was placed in the container filled with the soup, the functional test was carried out after the cooking was completed for 10 minutes. Specifically, for the noodles that have just been cooked, whether it is a smooth texture, whether the hardness is sufficient, and whether it has a pleasant elasticity of the elastic tooth, and then the noodles kept in the soup for 10 minutes. For the post-cooking extension, the control area is 0, preferably +, and the evaluation is performed on 7 levels of -3 to +3, with an average score. Said.

官能檢查係由經訓練之共計20名官能檢查員進行。又,選出自己最喜歡之食感之1種麵條,以人數表示嗜好性。另一方面,關於經煮過之烏龍麵之外觀,以目視評價其色彩。將結果示於表13。 The functional examination was performed by a total of 20 functional inspectors trained. In addition, one type of noodles of your favorite food is selected, and the hobby is expressed by the number of people. On the other hand, regarding the appearance of the cooked udon noodles, the color was visually evaluated. The results are shown in Table 13.

添加製造例1之粉末褐藻之情形時,官能檢查之任一項中均平衡性良好地具有較高之評價,可獲得與添加先前一直使用之食品添加物之情形相比總分及嗜好性最高之烏龍麵。又,調配製造例6之粉末褐藻之情形時,可獲得嗜好性較低、外觀亦為淡褐色之較差之烏龍麵。 When the powdered brown algae of the production example 1 was added, the balance of the functional test was excellent, and the evaluation was excellent, and the total score and the preference were higher than those of the food additive which had been used before. The udon noodles. Further, in the case of blending the powdered brown algae of Production Example 6, it was possible to obtain a poorly formed ulong noodles which had a low taste and a pale brown appearance.

實施例14:包子Example 14: Buns 14-1包子之製造14-1 manufacture of buns

將準高筋麵粉50.0重量份與低筋麵粉50.0重量份充分混合,於其中加入砂糖15重量份、食鹽0.5重量份、醱酵粉 1.0重量份。 50.0 parts by weight of the quasi-high-gluten flour and 50.0 parts by weight of the low-gluten flour are thoroughly mixed, and 15 parts by weight of granulated sugar, 0.5 parts by weight of salt, and mash powder are added thereto. 1.0 parts by weight.

進而,添加0.5重量份之先前通常用作包子之改良劑之食品添加物即海藻酸鈉(Kikkoman Biochemifa公司製造、Duck Algin)或微晶纖維素(旭化成化學公司製造、Ceolus FD-101)或者製造例1或6之粉末褐藻中之任一種作為改良劑並充分混合。 Further, 0.5 parts by weight of a food additive previously used as a modifier for a bun, that is, sodium alginate (Kikkoman Biochemifa, manufactured by Duck Algin) or microcrystalline cellulose (manufactured by Asahi Kasei Chemical Co., Ltd., Ceolus FD-101) or manufactured is added. Any of the powdered brown algae of Example 1 or 6 was used as a modifier and thoroughly mixed.

將該粉體投入攪拌器(SK Mixer公司製造、SK 10)中,添加使起酥油與乾酵母2.0重量份分散於水54重量份中而成者後,以低速混合3分鐘,以高速混合3分鐘。 The powder was placed in a stirrer (manufactured by SK Mixer Co., Ltd., SK 10), and 2.0 parts by weight of shortening oil and dry yeast were added to 54 parts by weight of water, and then mixed at a low speed for 3 minutes to mix at a high speed. minute.

結束混合後,以濕毛巾覆蓋生麵團,於室溫下醱酵20分鐘。醱酵後,將生麵團以50 g逐一分開,揉圓排列於鋪有烹調紙之鐵板上。20分鐘之放置醱酵時間後,用擀麵杖將生麵團擀平,成形為包裹餡之形狀。將其放入設定為40℃、濕度50%之條件之培爐中30分鐘進行二次醱酵。 After the mixing was completed, the dough was covered with a wet towel and fermented at room temperature for 20 minutes. After the fermentation, the dough was separated by 50 g one by one, and the rounds were arranged on an iron plate with cooking paper. After the fermentation time of 20 minutes, the dough is flattened with a rolling pin and shaped into a shape of a stuffing. This was placed in a furnace set to 40 ° C and a humidity of 50% for 30 minutes for secondary fermentation.

醱酵後,於蒸籠中蒸15分鐘,於室溫下放置20分鐘而冷卻。 After fermentation, it was steamed in a steamer for 15 minutes and allowed to stand at room temperature for 20 minutes to cool.

其後,於5℃之冰箱中保存一晚。 Thereafter, it was stored in a refrigerator at 5 ° C for one night.

另一方面,上述包子之製造中,以相同方式製造未加改良劑者作為對照。 On the other hand, in the manufacture of the above-mentioned steamed buns, the unmodified agent was produced in the same manner as a control.

14-2相對體積14-2 relative volume

針對上述14-1製造之各包子,於製造第二天測定高度及底面圓之直徑,又,根據直徑計算出半徑。各包子之體積係藉由以下之計算式算出。 For each of the buns manufactured in the above 14-1, the height and the diameter of the bottom circle were measured on the second day of manufacture, and the radius was calculated from the diameter. The volume of each bun is calculated by the following calculation formula.

又,由所獲得之體積算出相對體積。所謂相對體積,係用各試驗區之體積除以對照區之體積後,以份表示者。包子之體積較大者外觀較鬆軟,認為組織之比重即每1 cm3之重量變輕,影響到柔軟之食感,雖然較佳之情形亦較多,但若體積過大,則亦存在組織變得空隙較多而引起空洞現象,或導致難以咀嚼之現象之情況,需加以注意。將結果示於表14。 Further, the relative volume is calculated from the obtained volume. The relative volume is expressed in parts after dividing the volume of each test zone by the volume of the control zone. The larger the size of the buns, the softer the appearance. The weight of the tissue is lighter per 1 cm 3 , which affects the soft texture. Although it is better, if the volume is too large, the tissue will become Attention should be paid to the case where there are many voids causing voids or causing difficulty in chewing. The results are shown in Table 14.

根據所添加之改良劑之不同,可獲得相對體積不同之包子。添加製造例1之粉末褐藻之情形時,可獲得與添加先前一直使用之食品添加物之情形相比,具有更佳之相對體積之包子。 Buns having different relative volumes can be obtained depending on the modifier to be added. When the powdered brown algae of Production Example 1 was added, it was possible to obtain a bun having a better relative volume than the case of adding the food additive which has been used before.

14-3紋理解析14-3 texture analysis

針對上述14-1製造、冷藏保存之各包子,於製造第二天以成為3 cm之厚度之方式切掉上部,覆蓋保鮮膜在電子爐中於1500 W下加熱15秒後,使用流變計(SUN Science(股)、Rheo Meter CR-500DX),進行以下之14-3-1~14-3-5所記載 之紋理解析。測定條件設為柱塞速度120 mm/min、間隙20 mm、重複2次。將結果示於表15。 For each of the buns manufactured and stored in the above-mentioned 14-1, the upper portion was cut to a thickness of 3 cm on the second day of manufacture, and the wrap film was covered in an electric furnace at 1500 W for 15 seconds, and then a rheometer was used. (SUN Science, Rheo Meter CR-500DX), as described in 14-3-1~14-3-5 below Texture resolution. The measurement conditions were set to a plunger speed of 120 mm/min, a gap of 20 mm, and repeated twice. The results are shown in Table 15.

14-3-1相對最大荷重14-3-1 relative maximum load

測定將柱塞壓入試樣而切斷所需之最大荷重(重量),繼而算出相對最大荷重(份)。 The maximum load (weight) required for cutting the plunger into the sample was measured, and then the relative maximum load (parts) was calculated.

所謂相對最大荷重,係用試驗區之最大荷重除以對照區之最大荷重後,以份表示者。若該值較大,則表示切斷需要較大之力,故以牙齒咬、以舌擠碎或以手撕碎需要用力,為較硬之包子,若值較小,則表示為牙齒容易咬、舌容易擠碎、手容易撕碎、即「柔軟」之包子。 The so-called relative maximum load is expressed in parts after dividing the maximum load of the test zone by the maximum load of the control zone. If the value is large, it means that the cutting requires a large force, so the teeth are bitten, the tongue is crushed or the hand is shredded. It is a hard bun. If the value is small, it means that the teeth are easy to bite. The tongue is easily crushed, and the hand is easily shredded, that is, the "soft" buns.

14-3-2相對彈力性14-3-2 relative elasticity

於紋理解析中,測定因將柱塞壓入試樣中而引起之試樣之變形在撤去力時恢復之比率,將該比率表示為彈力性。用試驗區之彈力性除以對照區之彈力性後,以份表示算出相對彈力性。 In the texture analysis, the ratio of the deformation of the sample caused by pressing the plunger into the sample at the time of the force removal was measured, and the ratio was expressed as the elasticity. After the elasticity of the test zone is divided by the elasticity of the control zone, the relative elasticity is calculated in parts.

若該值較大,則係指按下時之恢復較強,具有彈力,若值較小,則係指恢復較差,成為一直凹陷之狀態,彈力較弱。即,若值較大,則表示為具有「有彈性」之食感之包子。 If the value is large, it means that the recovery is strong when pressed, and has elasticity. If the value is small, it means that the recovery is poor, and it becomes a state of being depressed all the time, and the elasticity is weak. That is, if the value is large, it is expressed as a buns having a "flexible" texture.

14-3-3相對凝聚性14-3-3 relative cohesion

於紋理解析中,重複2次將柱塞壓入試樣並施加負荷之操作,測定第1次與第2次之負荷能之比率,將其表示為凝聚性。 In the texture analysis, the operation of pressing the plunger into the sample and applying a load was repeated twice, and the ratio of the first and second load energies was measured, and this was expressed as cohesiveness.

用試驗區之凝聚性除以對照區之凝聚性後,以份表示算 出相對凝聚性。若該值較大,則表示難以變形、難以崩散,即為難以食用之包子,若值較小,則表示為具有「容易崩散」、「易於食用」、「融口感較佳」之食感之包子。 After dividing the cohesiveness of the test zone by the cohesiveness of the control zone, Relatively cohesive. If the value is large, it means that it is difficult to deform and is difficult to disintegrate, that is, it is a bun that is difficult to eat. If the value is small, it means that it has "easily broken", "easy to eat", and "better in melting". Feeling the buns.

14-3-4相對膠著性14-3-4 relative adhesiveness

將用上述14-3-3所測得之凝聚性乘以上述14-3-1所測得之最大荷重而獲得之值表示為膠著性。 The value obtained by multiplying the cohesiveness measured by the above 14-3-3 by the maximum load measured by the above 14-3-1 is expressed as the adhesiveness.

用試驗區之膠著性除以對照區之膠著性後,以份表示算出相對膠著性。若該值較大,則表示膠狀感/橡膠狀感/糊狀感較強,即為難以下嚥之包子,若值較小,則表示為具有膠狀感較小、「容易崩散」、「易於下嚥」之食感之包子。 After the adhesion of the test zone was divided by the adhesion of the control zone, the relative adhesion was calculated in parts. If the value is large, it means that the gelatinous feeling/rubbery feeling/paspy feeling is strong, that is, the steamed buns are difficult to swallow, and if the value is small, it means that the gelatinous feeling is small and “easy to collapse”. A buns that are "easy to swallow".

14-3-5相對咀嚼性14-3-5 relative chewiness

將用上述14-3-2所測得之彈力性乘以上述14-3-4所測得之膠著性而獲得之值表示為咀嚼性。 The value obtained by multiplying the elasticity measured by the above 14-3-2 by the above-mentioned 14-3-4 measured colloidality is expressed as chewiness.

用試驗區之咀嚼性除以對照區之咀嚼性後,以份表示算出相對咀嚼性。若該值較大,則表示咀嚼所需之力較大,即為直至磨碎為可下嚥之狀態所需之力較大、難以咀嚼之包子,若值較小,則表示為咀嚼所需之力較小、具有「容易咀嚼」「融口感較佳」之食感之包子。 After the chewability of the test area was divided by the chewiness of the control area, the relative chewiness was calculated in parts. If the value is large, it means that the force required for chewing is large, that is, the buns that are required to be swallowed to be swallowable and which are difficult to chew, and if the value is small, it is required for chewing. It has a small force and has a buns that are easy to chew and have a better taste.

添加製造例1之粉末褐藻之情形時,可獲得紋理解析之任一項中不僅均不遜於添加先前一直使用之食品添加物之情形、並且具有較佳之值之包子。 When the powdered brown algae of Production Example 1 is added, it is possible to obtain a bun which is not only inferior to the case where the food additive which has been used before is added, and which has a preferable value, in any of the texture analysis.

14-4官能檢查14-4 functional examination

針對上述14-1製造、冷藏保存之各包子,覆蓋保鮮膜在電子爐中於1500 W下加熱30秒後,供於官能檢查。官能試驗時,於是否為柔軟之食感、是否為令人愉悅之彈力感、融口感是否較佳方面,以對照區為0,以較佳者為+,以-3至+3之7個等級進行評價,藉由平均分表示。 For each of the buns manufactured and stored in the above-mentioned 14-1, the wrap film was heated in an electric furnace at 1500 W for 30 seconds, and then subjected to functional inspection. In the functional test, the control area is 0, preferably +, and -3 to +3, depending on whether it is soft, whether it is a pleasant elastic feeling, or whether the mouth feels better. Ratings are evaluated by means of an average score.

官能檢查係由經訓練之共計4名官能檢查員進行。又,選出自己最喜歡之食感之1種包子,以人數表示嗜好性。 The functional examination was performed by a total of 4 functional inspectors trained. In addition, one of the buns of your favorite food is selected, and the hobby is expressed by the number of people.

另一方面,針對所製成之包子之外觀,以目視進行評價。將結果示於表16。 On the other hand, the appearance of the prepared buns was evaluated visually. The results are shown in Table 16.

添加製造例1之粉末褐藻之情形時,可獲得官能檢查之任一項中均平衡性良好地具有較高之評價,總分及嗜好性不僅不遜於添加先前用於包子之食品添加物之情形,並且為更佳之評價之包子。又,調配製造例6之粉末褐藻之情形時,獲得雖然官能檢查中之任一項之評價均不低,但有強烈之海藻味,嗜好性較低,進而亦有黑點,外觀亦欠佳之包子。 When the powdered brown algae of Production Example 1 was added, it was found that any of the functional tests had a good balance with good balance, and the total score and taste were not inferior to the case of adding the food additive previously used for the steamed buns. And a buns for a better evaluation. Further, in the case of blending the powdered brown algae of Production Example 6, it was obtained that although the evaluation of any of the functional tests was not low, there was a strong seaweed taste, the preference was low, and there were also black spots, and the appearance was also poor. The buns.

實施例15:乳製品1 Example 15: Dairy product 1 15-1霜淇淋之製造15-1 Frost Cream Manufacturing

將水48.2重量份、加糖煉乳14.0重量份、生乳油(乳脂肪分45%)10.0重量份、飴糖7.0重量份以液體形式混合。於將脫脂奶粉12.0重量份、綿白糖4.0重量份、甘油脂肪酸酯0.3重量份以粉體形式混合而成者中混合0.3重量份之先前通常用作霜淇淋之改良劑之食品添加物即刺槐豆膠(MRC Polysaccharide公司製造、Soalocust A-120H)、古亞膠(三榮藥品貿易公司製造、Guarcol U40)、羅望子膠(大日本住友製藥公司製造、Glyloid 2A)、海藻酸鈉(Kikkoman Biochemifa公司製造、Duck Algin)、微晶纖維素(旭化成化學公司製造、Ceolus FD101)、κ-鹿角菜膠(三晶公司製造、GENU LACTA TYPE K-100-J)或海藻酸酯(Kikkoman Biochemifa公司製造、Duck Loid)、或製造例1或6之粉末褐藻中之任一種作為改良劑。 48.2 parts by weight of water, 14.0 parts by weight of sweetened condensed milk, 10.0 parts by weight of raw emulsifiable concentrate (milk fat fraction: 45%), and 7.0 parts by weight of sucrose were mixed in a liquid form. 0.10 parts by weight of the skim milk powder, 4.0 parts by weight of the white sugar, and 0.3 parts by weight of the glycerin fatty acid ester are mixed in a powder form, and 0.3 parts by weight of the food additive which has been conventionally used as a conditioner for the cream cream is mixed. Locust bean gum (manufactured by MRC Polysaccharide, Soalocust A-120H), Guaya gum (manufactured by Sanrong Pharmaceutical Trading Co., Ltd., Guarcol U40), tamarind gum (manufactured by Dainippon Sumitomo Pharmaceutical Co., Ltd., Glyloid 2A), sodium alginate (Kikkoman) Manufactured by Biochemifa, Duck Algin), microcrystalline cellulose (manufactured by Asahi Kasei Chemical Co., Ltd., Ceolus FD101), κ-carrageenan (manufactured by Sanjing Co., Ltd., GENU LACTA TYPE K-100-J) or alginate (Kikkoman Biochemifa) Manufacture, Duck Loid, or any of the powdered brown algae of Production Example 1 or 6 as a modifier.

將該混合粉體加入先前之混合液體中,於加熱沸騰中加溫,使其分散、溶解。達到65℃後,加入溶化之無鹽奶油 4.0重量份,以1,200 rpm將其均質化1分鐘。均質化後,再次以沸水將其加溫至85℃,其後在冰箱中冷卻。於冷卻後補正蒸發之水分量,於其中加入香草油0.1重量份、香草香精0.1重量份並充分攪拌,獲得霜淇淋混合物。 The mixed powder is added to the previously mixed liquid, heated in boiling by heating, and dispersed and dissolved. After reaching 65 ° C, add dissolved salt-free cream 4.0 parts by weight, which was homogenized at 1,200 rpm for 1 minute. After homogenization, it was again heated to 85 ° C with boiling water, and then cooled in a refrigerator. After cooling, the amount of water evaporated was adjusted, and 0.1 part by weight of vanilla oil and 0.1 part by weight of vanilla extract were added thereto and thoroughly stirred to obtain a cream mixture.

將所獲得之霜淇淋混合物投入冷凍器中,於-8℃下攪拌約28分鐘,獲得霜淇淋。將所獲得之霜淇淋放入容器中,於-18℃下保存。另一方面,製造未於上述之霜淇淋中加入改良劑者作為對照區,供於試驗。 The obtained cream mixture was placed in a freezer and stirred at -8 ° C for about 28 minutes to obtain a cream. The obtained cream was placed in a container and stored at -18 °C. On the other hand, those who did not add the modifier to the above-mentioned cream were used as a control zone for the test.

15-2膨脹率之測定15-2 expansion rate determination

針對上述15-1製造之各霜淇淋,分別測定冷凍前之霜淇淋混合物之重量(g)與同容量之冷凍後之霜淇淋之重量(g),藉由以下之計算式算出各霜淇淋之膨脹率(數5)。 For each cream produced in the above 15-1, the weight (g) of the cream mixture before freezing and the weight (g) of the frozen cream after the same volume were measured, and each of the following formulas was used to calculate each weight. The expansion rate of frost cream (number 5).

膨脹率係表示空氣於霜淇淋中之混合比率之數值,若膨脹率之值較高,則成為清爽之口味較輕者,若膨脹率之值較低,則成為發黏之口味較重者,故需根據欲獲得之霜淇淋之口味而調製。 The expansion ratio is the value of the mixing ratio of air in the cream. If the value of the expansion ratio is high, the taste is lighter. If the value of the expansion ratio is low, the taste is sticky. Therefore, it needs to be prepared according to the taste of the cream to be obtained.

將結果示於下述表17。 The results are shown in Table 17 below.

根據所添加之改良劑之不同,可獲得膨脹率不同之霜淇淋。添加製造例1之粉末褐藻之情形時,可獲得不僅不遜於添加先前一直用作改良劑之食品添加物之情形、並且具有更佳之相對體積之霜淇淋。 Depending on the modifier to be added, a cream with a different expansion ratio can be obtained. When the powdered brown algae of Production Example 1 was added, it was possible to obtain a cream which is not only inferior to the case of adding a food additive which has been used as a modifier, but also has a better relative volume.

15-3抗熱震性試驗(保形率)15-3 thermal shock resistance test (conformity rate)

使用霜淇淋挖杓將冷凍保存之霜淇淋放入小型杯中,在杯上蓋上膜之蓋,於5℃下放置1小時後,於-18℃下放置1小時。將此操作重複5次,最後於室溫下放置30分鐘。測定冷凍時(放置於室溫下之前)之重量及放置於室溫下30分鐘後之未溶化之霜淇淋部分之重量,藉由以下所示之計算式求出保形率(數6)。 Using a cream rinse, place the frozen cream in a small cup, cover the cup with a film cover, leave it at 5 ° C for 1 hour, and leave it at -18 ° C for 1 hour. This operation was repeated 5 times and finally left at room temperature for 30 minutes. The weight of the frost-free portion after freezing (before standing at room temperature) and the unmelted cream portion after 30 minutes at room temperature were measured, and the shape retention ratio was calculated by the following formula (number 6). .

較理想為霜淇淋於流通過程中常為冷凍狀態,實際上存在於常溫下放置一段時間而再次冷凍之情況。將其稱為熱震。若抗熱震性較弱,則容易溶化,霜淇淋中之冰晶之紋理變粗,口味變差。就現在之霜淇淋之流通狀況而言,要求抗熱震性優異者。 It is preferred that the cream is often frozen in the circulation process, and actually exists in a condition where it is left at room temperature for a while and then frozen again. Call it a thermal shock. If the thermal shock resistance is weak, it is easily dissolved, and the texture of the ice crystal in the cream cream becomes thick and the taste is deteriorated. In terms of the current circulation status of the cream, it is required to be excellent in thermal shock resistance.

將結果示於下述表17。 The results are shown in Table 17 below.

根據所添加之改良劑之不同,可獲得保形率不同之霜淇淋。添加製造例1之粉末褐藻之情形時,可獲得不僅不遜於添加先前一直使用之食品添加物之情形、並且更佳之保形率之霜淇淋。若為保形率經改善之霜淇淋,即便目視亦可確認脫水收縮得以防止,認為藉由乳清分離防止作用、脫水收縮防止作用,保形率得以改善。 Depending on the modifier to be added, a cream with a different shape retention rate can be obtained. In the case of adding the powdered brown algae of Production Example 1, it is possible to obtain a cream cream which is not inferior to the case where the food additive which has been used before is added, and which has a better shape retention ratio. In the case of the cream which has an improved shape retention ratio, it is confirmed that the syneresis can be prevented even by visual observation, and it is considered that the shape retention rate is improved by the whey separation preventing action and the syneresis preventing action.

15-4官能檢查15-4 functional examination

對上述15-1製造之各霜淇淋及上述15-3中施加熱震之各霜淇淋進行官能檢查。具體而言,於挖杓順暢性是否較佳、冰晶之紋理是否較細、融口感是否較佳及濃厚感是否較高方面,以對照區為0,以較佳者為+,以-3至+3之7個等級進行評價,藉由平均分表示。 Each of the creams manufactured in the above 15-1 and the creams to which the thermal shock was applied in the above 15-3 were subjected to a functional inspection. Specifically, in terms of whether the excavation smoothness is better, whether the texture of the ice crystal is finer, whether the fusion feeling is better, and whether the thick feeling is higher, the control area is 0, preferably +, and -3 to The evaluation was performed on 7 levels of +3, expressed by the average score.

通常之霜淇淋之官能檢查由共計13名官能檢查員、熱震後之霜淇淋之官能檢查由共計10名官能檢查員進行。又,選出自己最喜歡之食感之1種霜淇淋,以人數表示嗜好性。 The usual cream test was performed by a total of 13 functional inspectors, a total of 10 functional inspectors. In addition, one of the creams of your favorite food is selected, and the hobby is expressed by the number of people.

將關於15-1製造之霜淇淋之結果示於表18,將關於15-3中施加熱震之霜淇淋之結果示於表19。 The results of the creams produced in the 15-1 are shown in Table 18, and the results of the creams applied to the thermal shock in 15-3 are shown in Table 19.

添加製造例1之粉末褐藻之情形時,可獲得官能檢查之任一項中均平衡性良好地具有較高之評價,與添加先前一直用作改良劑之食品添加物之情形相比總分及嗜好性最高之霜淇淋。熱震後之霜淇淋之官能檢查中,亦可獲得不遜於添加先前一直用作改良劑之食品添加物之情形、嗜好性最高之霜淇淋。又,調配製造例6之粉末褐藻之情形時,獲得官能檢查之任一項中均為評價較低、總分及嗜好性亦 較低、進而有黑點、外觀亦欠佳之霜淇淋。 When the powdered brown algae of Production Example 1 is added, it is possible to obtain a high degree of balance in any of the functional tests, and the total score is compared with the case of adding a food additive which has been used as a modifier. The most hobby cream. In the sensory examination of the cream after the thermal shock, it is also possible to obtain a cream which is not inferior to the case of adding a food additive which has been used as a modifier, and has the highest preference. Further, in the case of blending the powdered brown algae of Production Example 6, all of the functional tests were evaluated with lower evaluation, total score, and preference. A creamy cream that is lower and has a black spot and a poor appearance.

實施例16:乳製品2 Example 16: Dairy 2 16-1再製乳酪之製造16-1 Remanufactured Cheese

稱量天然乳酪85重量份、水12.75重量份、多磷酸鈉1.7重量份、碳酸氫鈉0.38重量份、甘油脂肪酸酯0.17重量份置於容器中,於其中添加0.3重量份之先前通常用作再製乳酪之改良劑之食品添加物即刺槐豆膠(MRC Polysaccharide公司製造、Soalocust A-120H)、三仙膠(丸善藥品產業公司製造、Xanthan CNJS)或海藻酸鈉(Kikkoman Biochemifa公司製造、Duck Algin)、或者製造例1或6之粉末褐藻中之任一種作為改良劑,連同容器放入加熱沸水浴中並充分攪拌,使其分散、溶解。 Weighing 85 parts by weight of natural cheese, 12.75 parts by weight of water, 1.7 parts by weight of sodium polyphosphate, 0.38 parts by weight of sodium hydrogencarbonate, and 0.17 parts by weight of glycerin fatty acid ester were placed in a container, and 0.3 parts by weight was added thereto, which was previously used as usual. The food additive of the cheese-making improver is locust bean gum (MRC Polysaccharide, Soalocust A-120H), Sanxian gum (manufactured by Maruzen Pharmaceutical Co., Ltd., Xanthan CNJS) or sodium alginate (Kikkoman Biochemifa, Duck Algin) Or any one of the powdered brown algae of Production Example 1 or 6 as a modifier, and placed in a heated boiling water bath together with a container and thoroughly stirred to disperse and dissolve.

分散、溶解後,補正蒸發之水分量,以每杯50 g將其分注入小型杯中。於室溫下放置冷卻一段時間後,在杯上蓋上膜之蓋,於5℃之冰箱中保存。另一方面,製造未於上述再製乳酪中加入改良劑者作為對照區供於試驗。 After dispersing and dissolving, correct the amount of water evaporated, and inject it into a small cup at 50 g per cup. After standing at room temperature for a while, the lid of the membrane was placed on the cup and stored in a refrigerator at 5 °C. On the other hand, the manufacturer who did not add the modifier to the above-mentioned processed cheese was used as a control zone for the test.

16-2紋理解析16-2 texture analysis

針對上述16-1製造、經冷藏保存之各再製乳酪,於製造後數天以內使用流變計(SUN Science公司製造、Rheo Meter CR-500DX)進行以下之3-2-1~3-2-4所記載之紋理解析。測定條件設為柱塞速度60 mm/min、間隙15 mm、重複2次。 For each of the reconstituted cheeses which were produced in the above-mentioned 16-1 and stored in a refrigerated state, a rheometer (manufactured by SUN Science Co., Ltd., Rheo Meter CR-500DX) was used for the following 3-2-1~3-2- 4 texture analysis described. The measurement conditions were set to a plunger speed of 60 mm/min, a gap of 15 mm, and repeated twice.

將結果示於表20。 The results are shown in Table 20.

16-2-1相對最大荷重16-2-1 relative maximum load

測定將柱塞壓入試樣而切斷所需之最大荷重(重量),繼而算出相對最大荷重(份)。 The maximum load (weight) required for cutting the plunger into the sample was measured, and then the relative maximum load (parts) was calculated.

所謂相對最大荷重,係用試驗區之最大荷重除以對照區之最大荷重後,以份表示者。若該值較大,則表示切斷需要較大之力,故而為以牙齒咬、以舌擠碎或以手撕碎需要用力之較硬之再製乳酪,若值較小,則表示為牙齒容易咬、舌容易擠碎、手容易撕碎、即「柔軟」之再製乳酪。 The so-called relative maximum load is expressed in parts after dividing the maximum load of the test zone by the maximum load of the control zone. If the value is large, it means that the cutting requires a large force, so it is a harder re-made cheese that needs to be hardened by biting the teeth, crushing the tongue or shredding with hands. If the value is small, it means that the teeth are easy. Biting, the tongue is easy to crush, and the hand is easily shredded, that is, "soft" re-made cheese.

16-2-2相對變形率16-2-2 relative deformation rate

將再製乳酪壓縮,施加負荷直至乳酪開裂,測定試樣未開裂而壓縮變形之厚度相對於原來之厚度的比率即變形率(份),繼而算出相對變形率。所謂相對變形率,係用試驗區之變形率除以對照區之變形率後,以份表示者。若該值較小,則表示為容易分開、較脆之再製乳酪。 The processed cheese was compressed, and a load was applied until the cheese was cracked, and the ratio of the thickness of the sample which was not cracked and the thickness of the compression deformation to the original thickness, that is, the deformation ratio (part) was measured, and then the relative deformation ratio was calculated. The relative deformation rate is expressed in parts after dividing the deformation rate of the test zone by the deformation rate of the control zone. If the value is small, it means a reconstituted cheese that is easy to separate and brittle.

16-2-3相對彈力性16-2-3 relative elasticity

於紋理解析中,測定因將柱塞壓入試樣引起之試樣之變形於撤去力時恢復之比率,將該比率表示為彈力性。用試驗區之彈力性除以對照區之彈力性後,以份表示算出相對彈力性。 In the texture analysis, the ratio at which the deformation of the sample caused by pressing the plunger into the sample was recovered at the withdrawal force was measured, and the ratio was expressed as the elasticity. After the elasticity of the test zone is divided by the elasticity of the control zone, the relative elasticity is calculated in parts.

若該值較大,則係指按下之之恢復較強,有彈力,若值較小,則係指恢復較差,成為一直凹陷之狀態,彈力較弱。即,若值較大,則表示為有咬勁之再製乳酪。 If the value is larger, it means that the recovery is stronger and has elasticity. If the value is smaller, it means that the recovery is poor, and it becomes a state of depression all the time, and the elasticity is weak. That is, if the value is large, it means that there is a bite of reconstituted cheese.

16-2-4相對凝聚性16-2-4 relative cohesion

於紋理解析中,重複2次將柱塞壓入試樣並施加負荷之操作,測定第1次與第2次之負荷能之比率,將其表示為凝 聚性。 In the texture analysis, the plunger is pressed into the sample and the load is applied twice, and the ratio of the first and second load energy is measured, and it is expressed as coagulation. Poly.

用試驗區之凝聚性除以對照區之凝聚性後,以份表示算出相對凝聚性。若該值較大,則表示難以變形,難以崩散、即為保形性較佳之再製乳酪。 After the cohesiveness of the test zone was divided by the cohesiveness of the control zone, the relative cohesiveness was calculated in parts. If the value is large, it means that it is difficult to deform and is difficult to disintegrate, that is, a reconstituted cheese having better shape retention.

添加製造例1之粉末褐藻之情形時,可獲得不遜於添加先前一直用作改良劑之食品添加物之情形、有較佳之硬度、彈力的易分割之保形性較佳的再製乳酪。 When the powdered brown algae of the production example 1 is added, it is possible to obtain a reconstituted cheese which is not inferior to the case where the food additive which has been used as the modifier has been added, and which has better hardness and elasticity and which is easy to be divided and has good shape retention property.

16-3官能檢查16-3 functional examination

對上述16-1製造之各再製乳酪進行官能檢查。 Each of the processed cheeses manufactured in the above 16-1 was subjected to a functional inspection.

關於官能檢查,具體而言,於各再製乳酪是否有硬度、是否有彈力、融口感是否較佳及是否較脆方面,以對照區為0,以較佳者為+,以-3至+3之7個等級進行評價,藉由平均分表示。 Regarding the functional examination, specifically, whether the respective processed cheese has hardness, elasticity, whether the mouth feel is good or not, the control area is 0, preferably +, and -3 to +3. The seven levels are evaluated and expressed by the average score.

官能檢查係由經訓練之共計4名官能檢查員進行。又,選出自己最喜歡之食感之1種再製乳酪,以人數表示嗜好性。另一方面,關於再製乳酪之外觀,以目視評價其色彩。 The functional examination was performed by a total of 4 functional inspectors trained. In addition, one of the re-made cheeses of your favorite food is selected, and the preference is expressed by the number of people. On the other hand, regarding the appearance of the reconstituted cheese, the color was visually evaluated.

將關於外觀之結果示於表20,將其他官能檢查之結果示 於表21。 The results on the appearance are shown in Table 20, and the results of other functional tests are shown. In Table 21.

添加製造例1之粉末褐藻之情形時,可獲得官能檢查之任一項中均平衡性良好地具有較高之評價,與添加先前一直用作改良劑之食品添加物之情形相比總分及嗜好性最高之再製乳酪。又,調配製造例6之粉末褐藻之情形時,獲得嗜好性較低、外觀亦為茶色且有黑點、難言較佳之再製乳酪。 When the powdered brown algae of Production Example 1 is added, it is possible to obtain a high degree of balance in any of the functional tests, and the total score is compared with the case of adding a food additive which has been used as a modifier. Re-cooked cheese with the highest preference. Further, in the case of blending the powdered brown algae of Production Example 6, a reconstituted cheese having a lower taste, a brownish appearance, and a black spot was obtained, which is difficult to say.

實施例17:畜肉製品Example 17: Meat products 17-1香腸之製造17-1 sausage manufacturing

相對於豬肉糜66.99重量份、冰水26.8重量份及豬油(精製豬油)2.68重量份,添加0.3重量份之先前通常用作香腸之改良劑之食品添加物即微晶纖維素(旭化成化學公司製造、Ceolus FD-101)、κ-鹿角菜膠(三晶公司製造、KC-200S)或海藻酸鈉(Kikkoman Biochemifa公司製造、Duck Algin)、或者製造例1或6之粉末褐藻中之任一種(作為改良劑)、食鹽1.68重量份、綿白糖1重量份、磷酸鹽製劑0.2重量份、美味調味料0.2重量份、白胡椒0.14重量份、顆粒雞架湯0.14重量份、肉豆蔻0.07重量份、抗壞血酸鈉0.03重量份、鼠尾草0.03重量份、芫荽0.03重量份及亞硝酸鈉 0.01重量份之混合物,並充分混合。 With respect to 66.99 parts by weight of pork mash, 26.8 parts by weight of ice water, and 2.68 parts by weight of lard (refined lard), 0.3 parts by weight of a food additive previously used as a modifier for sausages, microcrystalline cellulose (Asahi Kasei Chemicals) was added. Manufactured by the company, Ceolus FD-101), κ-carrageenan (manufactured by Sanjing Co., Ltd., KC-200S) or sodium alginate (Kikkoman Biochemifa, manufactured by Duck Algin), or the powdered brown algae of the manufacturing example 1 or 6. One (as a modifier), 1.68 parts by weight of salt, 1 part by weight of white sugar, 0.2 parts by weight of a phosphate preparation, 0.2 parts by weight of a delicious seasoning, 0.14 parts by weight of white pepper, 0.14 parts by weight of granulated chicken soup, and 0.07 by weight of nutmeg. Serving, 0.03 parts by weight of sodium ascorbate, 0.03 parts by weight of sage, 0.03 parts by weight of cerium and sodium nitrite 0.01 parts by weight of the mixture was thoroughly mixed.

使用灌香腸機將該肉灌入天然羊腸。將肉灌至適當長度後,用風箏線捆縛,切下後,於75℃之熱水浴中煮沸40分鐘獲得煮香腸。將該煮香腸冷藏保存(5℃)一晚,第二天供於試驗。另一方面,以相同方式製造未於上述香腸製造方法中加入改良劑者作為對照。 The meat is poured into the natural sheep intestine using a sausage machine. After the meat is poured to the appropriate length, it is bound with a kite string, cut, and boiled in a hot water bath at 75 ° C for 40 minutes to obtain boiled sausage. The boiled sausage was stored refrigerated (5 ° C) for one night and the next day was used for the test. On the other hand, a manufacturer who did not add the modifier in the above sausage production method was used in the same manner as a control.

17-2烹煮良率17-2 cooking yield

針對上述17-1製造之各香腸,測定75℃、40分鐘之煮沸步驟前後之重量,算出烹煮良率,繼而將對照區之烹煮良率設為100,藉由以下之式算出相對烹煮良率(份)(數7)。 For each sausage manufactured in the above 17-1, the weight before and after the boiling step at 75 ° C for 40 minutes was measured, and the cooking yield was calculated, and then the cooking yield of the control zone was set to 100, and the relative cooking was calculated by the following formula. Boil rate (parts) (number 7).

相對烹煮良率係表示在煮沸步驟後存留肉汁情況如何、是否成為更多汁之食品味道的指標之一,若該值較高,則存留相應程度之肉汁。 The relative cooking yield is one of the indicators of how the gravy remains after the boiling step and whether it becomes the taste of more juice food. If the value is higher, the corresponding gravy is retained.

將結果示於表22。 The results are shown in Table 22.

添加製造例1之粉末褐藻之情形時,可獲得與添加先前一直用作改良劑之食品添加物之情形相比,烹煮良率更高、可存留更多之肉汁之品質較高的香腸。 When the powdered brown algae of Production Example 1 was added, it was possible to obtain a sausage having a higher cooking yield and a higher quality of gravy than the case of adding a food additive which has been used as a modifier.

17-3水分值17-3 moisture value

針對上述17-1製造之各香腸,於製造第二天,使用食物加工機連同皮製成肉糜,利用其中10 g,藉由乾燥減量法(105℃、4小時)測定水分值,繼而將對照區之水分值設為100,藉由以下之式算出相對水分值(份)。 For each of the sausages manufactured in the above 17-1, on the second day of manufacture, the meat processing machine was used together with the skin to make the meat emulsion, and 10 g was used, and the moisture value was measured by the drying reduction method (105 ° C, 4 hours), and then The water content of the control zone was set to 100, and the relative moisture value (parts) was calculated by the following formula.

相對水分值係表示製成之香腸中殘留何種程度之肉汁、是否殘留有更多汁之食品味道的指標之一,若該值較高,則殘留相應程度之肉汁。 The relative moisture value indicates one of the indicators of the degree of gravy remaining in the prepared sausage and the taste of the food containing more juice. If the value is high, the corresponding degree of gravy remains.

將結果示於表23。 The results are shown in Table 23.

添加製造例1之粉末褐藻之情形時,可獲得與添加先前一直用作改良劑之食品添加物之情形相比水分值更高、殘留有更多之肉汁之品質較高的香腸。 When the powdered brown algae of the production example 1 was added, it was possible to obtain a sausage having a higher moisture content and a higher quality of gravy remaining than the case where the food additive which has been used as a modifier was added.

17-4官能檢查17-4 functional examination

於製造第二天對上述17-1製造之各香腸進行官能檢查。關於官能檢查,於即將食用香腸前在沸水中煮沸3分鐘而烹飪,並供於官能檢查。 The sausages manufactured in the above 17-1 were subjected to a functional inspection on the second day of manufacture. Regarding the functional examination, it is cooked in boiling water for 3 minutes before eating the sausage, and is used for functional examination.

針對該等,於多汁感、彈力、美味程度方面,以對照區為0,以較佳者為+,以-3至+3之7個等級進行評價,藉由平均分表示。官能檢查係由經訓練之4名官能檢查員進行。將結果示於表24。 For the above, in terms of juicyness, elasticity, and taste, the control area is 0, preferably +, and 7 to -3 to 7 levels, expressed by the average score. The functional examination was performed by four trained inspectors. The results are shown in Table 24.

添加製造例1之粉末褐藻之情形時,可獲得不遜於添加先前之食品添加物之情形、多汁且有咬勁、並且美味的香腸。認為製造例1之粉末褐藻可代替鹿角菜膠等而用作香腸之食感改良劑之食品添加物。 When the powdered brown algae of Production Example 1 was added, a sausage which was not inferior to the case where the prior food additive was added, which was juicy, biting, and delicious was obtained. It is considered that the powdered brown algae of Production Example 1 can be used as a food additive for a food texture improving agent for sausages instead of carrageenan or the like.

實施例18:凝膠化食品Example 18: Gelatinized food 18-1葡萄果凍之製造18-1 Grape jelly manufacturing

於30.0重量份之綿白糖中加入1.2重量份之檸檬酸三鈉及0.01重量份之六偏磷酸鈉並充分混合。 To 30.0 parts by weight of the white sugar, 1.2 parts by weight of trisodium citrate and 0.01 part by weight of sodium hexametaphosphate were added and thoroughly mixed.

進而,加入4重量份或6重量份之先前通常用作凝膠化食品之凝膠化劑之食品添加物即ι-鹿角菜膠(Marine-Science公司製造、TS-150)或果膠(三晶公司製造、GENU Pectin 121- J)或者製造例1或6之粉末褐藻中之一種作為凝膠化劑並充分混合。 Further, 4 parts by weight or 6 parts by weight of a food additive previously used as a gelling agent for gelled foods, iota-carrageenan (manufactured by Marine-Science, TS-150) or pectin (three Manufactured by Crystal Corporation, GENU Pectin 121- J) Or one of the powdered brown algae of Production Example 1 or 6 is used as a gelling agent and thoroughly mixed.

將該粉體放入20重量份之水中並充分攪拌使其分散,進而加入20重量份之市售葡萄汁(100%葡萄汁飲料)、0.2重量份之葡萄香料及0.1重量份之梔子色素並充分攪拌混合。 The powder was placed in 20 parts by weight of water and thoroughly stirred to disperse, and further 20 parts by weight of commercially available grape juice (100% grape juice beverage), 0.2 parts by weight of grape flavor, and 0.1 part by weight of hazelnut pigment were added. Mix well with stirring.

另一方面,將0.2重量份之磷酸氫鈣及10重量份之葡萄糖酸-δ-內酯加入全部剩餘重量份之水中並充分混合。 On the other hand, 0.2 part by weight of calcium hydrogen phosphate and 10 parts by weight of glucono-δ-lactone were added to all remaining parts by weight of water and thoroughly mixed.

將其加入混合上述粉體、水、果汁、香料及色素而獲得者中,迅速攪拌混合,填充於杯中。將其放入冰箱,放置一晚使其凝膠化,供於試驗。 This was added to a mixture obtained by mixing the above powder, water, fruit juice, flavor, and coloring matter, and the mixture was rapidly stirred and filled, and filled in a cup. Place it in the refrigerator and leave it overnight for gelation for testing.

18-2凝膠斷裂強度試驗18-2 gel breaking strength test

針對上述18-1製造之各葡萄果凍,於製造第二天使用流變計(SUN Science公司製造、Rheo Meter CR-500DX),進行以下之18-2-1及18-2-2之凝膠斷裂強度試驗。 For each of the grape jelly manufactured in the above 18-1, a rheometer (manufactured by SUN Science Co., Ltd., Rheo Meter CR-500DX) was used for the following day to carry out the following gels of 18-2-1 and 18-2-2. Break strength test.

分析條件係使用直徑12.5 mm之印模、於壓縮速度50 mm/min下進行。 The analytical conditions were carried out using a 12.5 mm diameter stamp at a compression speed of 50 mm/min.

18-2-1凝膠強度18-2-1 gel strength

以印模壓縮果凍,測定使果凍斷裂所需之應力(重量)而獲得凝膠強度。凝膠強度為果凍恰好凝膠化時獲得之應力,係表示果凍是否凝膠化、果凍是否緊固等果凍之硬度的指標。 The jelly was compressed by an impression, and the stress (weight) required to break the jelly was measured to obtain gel strength. The gel strength is the stress obtained when the jelly is just gelled, and is an indicator of the hardness of the jelly such as whether the jelly is gelled or whether the jelly is fastened.

將結果示於表25。 The results are shown in Table 25.

18-2-2變形率18-2-2 deformation rate

以印模壓縮果凍,測定直至果凍變形而斷裂之距離,獲得用其除以果凍之高度而獲得之值之以份表示者作為變形率。 The jelly was compressed by an impression, and the distance of the break until the jelly was deformed was measured, and the value obtained by dividing the height obtained by dividing the jelly into a part was obtained as a deformation ratio.

變形率為表示果凍食感之指標之一,認為若該值較低,則為具有易切、口感清爽、在口中易崩散、易粉碎、鮮明之食感等之果凍。若該值較高,則為具有難切、有彈力、綿軟、在口中難以崩散、難以食盡之食感等之果凍等。關於何種食感較佳,根據食用者之喜好而不同。 The deformation rate is one of the indicators indicating the texture of the jelly, and it is considered that if the value is low, it is a jelly which is easy to cut, has a refreshing mouthfeel, is easily broken in the mouth, is easily pulverized, and has a sharp texture. If the value is high, it is jelly which is difficult to cut, has elasticity, is soft, is hard to collapse in the mouth, and is difficult to eat. What kind of food is better, depending on the preferences of the consumer.

將結果示於表25。 The results are shown in Table 25.

先前用作凝膠化劑之食品添加物中,ι-鹿角菜膠為若不加熱則不凝膠化,無法獲得凝膠化之果凍。即便添加製造例6之粉末褐藻亦未引起凝膠化。 In the food additive previously used as a gelling agent, iota-carrageenan does not gel even if it is not heated, and gelation jelly cannot be obtained. Even if the powdered brown algae of Production Example 6 was added, gelation was not caused.

另一方面,添加製造例1之粉末褐藻之情形時,與添加先前一直用作凝膠化劑之食品添加物之果膠之情形相比,使用濃度4.0重量份時,可獲得2倍以上之凝膠強度,使用濃度6.0重量份時亦可獲得比果膠更高之凝膠強度,顯示製造例1之粉末褐藻為無需加熱而可獲得較高之凝膠強度 之有用之凝膠化劑。 On the other hand, in the case of adding the powdered brown algae of Production Example 1, when the concentration of 4.0 parts by weight is used, it is more than 2 times as compared with the case of adding the pectin which has been used as the food additive of the gelling agent. Gel strength, gel strength higher than that of pectin was also obtained when the concentration was 6.0 parts by weight, and the powdered brown algae of Production Example 1 was obtained to obtain higher gel strength without heating. A useful gelling agent.

又,關於變形率,添加製造例1之粉末褐藻之情形時,成為與添加果膠之情形相比變形率較低之果凍,可獲得與先前不同之易切、口感清爽、在口中易於崩散、易粉碎、鮮明之食感之果凍。 In addition, when the powdered brown algae of the production example 1 is added to the deformation rate, the jelly having a lower deformation rate than that in the case of adding the pectin can be obtained, which is different from the previous one, which is easy to cut, has a refreshing taste, and is easily disintegrated in the mouth. Easy to smash, fresh and delicious jelly.

本申請案主張基於2011年10月11日提出申請之日本專利申請案第2011-224237號、2012年2月8日提出申請之日本專利申請案第2012-25592號及2012年4月23日提出申請之日本專利申請案第2012-98018號之優先權,該等內容作為參照而併入本文中。 Japanese Patent Application No. 2011-224237, filed on Oct. 11, 2011, and Japanese Patent Application No. 2012-25592, filed on Feb. 8, 2012, and filed on April 23, 2012 Priority is claimed on Japanese Patent Application No. 2012-98018, which is incorporated herein by reference.

[產業上之可利用性][Industrial availability]

本發明具有如下產業上之可利用性:可提供新穎之粉末褐藻作為可廣泛地安全地用於各種食品及化妝品等之源自海藻的新穎材料。 The present invention has the following industrial applicability: a novel powdered brown algae can be provided as a novel material derived from seaweed which can be widely and safely used for various foods and cosmetics and the like.

進而,本發明具有如下產業上之可利用性:亦提供海藻色減輕、可於色彩方面無問題地使用之粉末褐藻,及海藻味減輕、可於氣味方面無問題地使用之粉末褐藻。此種粉末褐藻於用於例如飲料食品之領域之情形時,可於無損欲調配其之食品本來具有之風味或色調之情況下廣泛地用於各種食品。 Further, the present invention has the following industrial applicability: a powdered brown algae which is reduced in seaweed color, can be used without any problem in color, and a powdered brown algae which is reduced in seaweed taste and can be used without problems in odor. Such a powdered brown algae can be widely used for various foods in the case of use in the field of, for example, beverages and foods, without impairing the flavor or color tone of the food to which it is originally intended.

又,亦具有如下產業上之可利用性:根據本發明,可提供不會使未處理之情況下含有沈澱之粒子之溶液大幅度增黏、發揮優異之沈澱防止作用、安全性亦較高之沈澱防止劑,可防止例如含有經乳化之溶液及/或粉末之溶液即飲 料、食品、化妝水、洗潔劑、醫藥品等各種領域中之製品的沈澱。 Further, according to the present invention, it is possible to provide a solution which does not cause a large amount of a solution containing particles which are precipitated in the case of no treatment, and exhibits an excellent precipitation preventing action and a high safety. a precipitation preventing agent which prevents, for example, a solution containing an emulsified solution and/or a powder Precipitation of products in various fields such as materials, foods, lotions, detergents, and pharmaceuticals.

又,亦具有如下產業上之可利用性:根據本發明,亦可提供不影響各種領域中之製品之本來之氣味或色調的沈澱防止劑,使用該沈澱防止劑,可提供在不影響本來之氣味或色調之情況下防止沈澱之製品及沈澱防止方法。 Further, it has the following industrial applicability: according to the present invention, it is also possible to provide a precipitation preventing agent which does not affect the original odor or color tone of a product in various fields, and the use of the precipitation preventing agent can be provided without affecting the original A product for preventing precipitation and a method for preventing precipitation in the case of odor or color tone.

進而,本發明具有如下產業上之可利用性:可提供可代替先前之食品添加物、可充分改良相同食品之食感、紋理、體積、嗜好性等之食品改良劑(尤其是麵粉食品改良劑及食品之增黏凝膠化改良劑)。又,具有如下產業上之可利用性:使用該食品改良劑,可提供食品之食感、紋理、體積、嗜好性等經充分改善之食品及經改良成為「美味」、「廉價」或「可簡便利用」之食品,以及該等之製造方法。 Further, the present invention has the following industrial applicability: a food improver (especially a flour food improver) which can replace the previous food additive and can sufficiently improve the texture, texture, volume, taste, and the like of the same food can be provided. And food viscosity-increasing gelatin improver). In addition, it has the following industrial applicability: the use of the food improver can provide foods with improved food texture, texture, volume, taste, and the like, and can be improved into "delicious", "cheap" or "can be" Food that is easy to use, and how to make it.

又,亦具有如下產業上之可利用性:根據本發明,亦可提供不影響食品之本來之氣味或色調的食品改良劑,使用該食品改良劑,亦可提供在不影響本來之氣味或色調之情況下得以改良之食品以及其製造方法。 Further, it has the following industrial applicability: according to the present invention, a food improving agent which does not affect the original odor or color tone of the food can be provided, and the food improving agent can be used without imparting an influence on the original odor or color tone. Foods that have been improved and their manufacturing methods.

此種本發明之食品改良劑於食品領域、尤其是麵包類、麵條類、小麥點心類、小麥混合粉類或包子類等麵粉食品之領域及進行利用增黏凝膠化進行之改良之食品(乳製品、畜肉製品及凝膠化食品等)之領域中具有產業上之可利用性。 Such a food improving agent of the present invention is used in the field of foods, particularly in the field of flour foods such as breads, noodles, wheat snacks, wheat mixed powders or steamed buns, and foods modified by viscosity-increasing gelation ( It is industrially available in the fields of dairy products, livestock products, gelled foods, and the like.

Claims (21)

一種粉末褐藻,其含有水溶性褐藻膠成分及不溶性成分,且水溶性褐藻膠成分與不溶性成分之重量比為1:0.05~1:4。 A powdered brown algae comprising a water-soluble alginate component and an insoluble component, and the weight ratio of the water-soluble alginate component to the insoluble component is 1:0.05 to 1:4. 如請求項1之粉末褐藻,其中不溶性成分之含量為5~35重量%。 The powdered brown algae according to claim 1, wherein the content of the insoluble component is 5 to 35% by weight. 如請求項1之粉末褐藻,其中水溶性褐藻膠成分之含量為10~70重量%。 The powdered brown algae according to claim 1, wherein the content of the water-soluble alginate component is 10 to 70% by weight. 如請求項1之粉末褐藻,其中水溶性褐藻膠成分與不溶性成分之重量比為1:0.05~1:1.5。 The powder brown algae according to claim 1, wherein the weight ratio of the water-soluble alginate component to the insoluble component is 1:0.05 to 1:1.5. 如請求項1之粉末褐藻,其中表示色彩之亮度之L值為45以上。 The powder brown algae according to claim 1, wherein the L value indicating the brightness of the color is 45 or more. 如請求項5之粉末褐藻,其中表示色彩之亮度之L值為70以上。 The powder brown algae according to claim 5, wherein the L value indicating the brightness of the color is 70 or more. 如請求項5之粉末褐藻,其中表示色彩之亮度之L值為72以上。 The powder brown algae according to claim 5, wherein the L value indicating the brightness of the color is 72 or more. 如請求項1之粉末褐藻,其係將褐藻粉碎、清洗及乾燥而獲得,且上述清洗係利用含有水、醇、脫色劑及鹼之清洗溶液進行之清洗。 The powdered brown algae according to claim 1 is obtained by pulverizing, washing and drying the brown algae, and the washing is performed by using a washing solution containing water, an alcohol, a decolorizing agent and an alkali. 如請求項8之粉末褐藻,其中褐藻係屬於昆布目巨藻科或昆布目昆布科者。 The powdered brown algae according to claim 8, wherein the brown algae belongs to the group consisting of the giant algae family or the Kunbu group. 一種沈澱防止劑,其含有如請求項1至9中任一項之粉末 褐藻。 A precipitation preventing agent containing the powder according to any one of claims 1 to 9 Brown algae. 一種沈澱防止劑,其係含有將褐藻粉碎、清洗及乾燥而獲得之粉末褐藻者,且上述清洗係利用含有水、醇、脫色劑及鹼之清洗溶液進行之清洗。 A precipitating agent containing powdered brown algae obtained by pulverizing, washing and drying brown algae, and the washing is carried out by using a washing solution containing water, an alcohol, a decolorizing agent and an alkali. 一種含沈澱粒子之溶液,其係含有0.01重量%~5.0重量%之如請求項1至9中任一項之粉末褐藻,且黏度為100 mPa‧s以下之防止沈澱者。 A solution containing precipitated particles, which comprises 0.01% by weight to 5.0% by weight of the powdered brown algae according to any one of claims 1 to 9, and has a viscosity of 100 mPa·s or less to prevent precipitation. 如請求項12之含沈澱粒子之溶液,其係含蛋白質之飲料。 A solution containing the precipitated particles of claim 12 which is a protein-containing beverage. 一種沈澱防止方法,其包括將如請求項1至9中任一項之粉末褐藻添加至含沈澱粒子之溶液中之步驟。 A method of preventing precipitation, which comprises the step of adding the powdered brown algae according to any one of claims 1 to 9 to a solution containing precipitated particles. 一種食品改良劑,其含有如請求項1至9中任一項之粉末褐藻。 A food improver comprising the powdered brown algae according to any one of claims 1 to 9. 如請求項15之食品改良劑,其係麵粉食品改良劑或食品之增黏凝膠化改良劑。 A food improver according to claim 15 which is a flour food improver or a viscosity-increasing gelatinizer for food. 一種食品,其係調配有如請求項15之食品改良劑者,且含有0.01~20.0重量%之上述粉末褐藻。 A food product formulated with the food improver of claim 15 and containing 0.01 to 20.0% by weight of the above-mentioned powder brown algae. 如請求項17之食品,其係麵粉食品、乳製品、畜肉製品或凝膠化食品。 The food of claim 17, which is a flour food, a dairy product, a meat product or a gelled food. 如請求項17之食品,其係麵包類、麵條類、小麥點心類、小麥混合粉類或包子類。 The food of claim 17, which is a bread, a noodle, a wheat snack, a wheat mixed powder or a bun. 如請求項17之食品,其係霜淇淋類、雪霜類、乳酪類、酸乳酪類、香腸類、漢堡類、肉丸子類、混練肉類、混練魚類、果凍類、布丁類或甜品類。 The food of claim 17, which is a cream, a snow cream, a cheese, a yoghurt, a sausage, a hamburger, a meatball, a mixed meat, a mixed fish, a jelly, a pudding or a dessert. 一種食品之製造方法,其包括將如請求項15之食品改良劑調配至食品中之步驟。 A method of producing a food comprising the step of formulating a food improver according to claim 15 into a food.
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Cited By (4)

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* Cited by examiner, † Cited by third party
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Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08228A (en) * 1994-06-23 1996-01-09 Funoran:Kk Glue plant as food additive and its usage
JP3053794B2 (en) * 1997-12-17 2000-06-19 理研食品株式会社 Low salt and low odor seaweed, method for producing the same, and food and drink using the same
JP4002475B2 (en) * 2002-06-11 2007-10-31 日本食品化工株式会社 Method for producing noodles
JP2006143817A (en) * 2004-11-17 2006-06-08 South Product:Kk Manufacturing method of decolored fucoidan
JP4893124B2 (en) * 2006-06-27 2012-03-07 ライオン株式会社 Liquid oral composition

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