TWI551696B - Cold rolled steel sheet and method for producing the same - Google Patents

Description

Cold rolled steel sheet and method of manufacturing same

The present invention relates to a cold-rolled steel sheet suitable for use as a plate, a disk, a ring, or the like of an automotive drive-train parts. The raw material is excellent in punchability and heat strain resistance.

It is used as a plate, a disk, a ring, etc. (for example, an automatic transmission (AT) plate, etc.) of a drive system component of an automobile. Before the steel plate is punched into a predetermined shape, hardening is performed for the purpose of hardening. (Quenching) or the like is heat-treated and adjusted to a predetermined hardness, and then bonded by a friction material. However, in the existing manufacturing method, a large amount of heat energy is consumed in the heat treatment, and a dedicated heat treatment apparatus is required, so that an increase in manufacturing cost cannot be avoided.

Under the above circumstances, in recent years, a cold-rolled steel sheet which is adjusted to a desired hardness by cold rolling has been used instead of the heat treatment after the blanking. In the case of applying a cold-rolled steel sheet, heat treatment such as quenching is not required, so that the manufacturing cost can be drastically reduced. However, in the case of applying a cold-rolled steel sheet, a large warpage sometimes occurs in the parts after press working. Therefore, there is a problem that shape straightening is required after punching. Further, there is a problem that a predetermined shape cannot be obtained even if it is corrected. Even if a good flatness is obtained after stamping, residual stress is also present when exposed to high temperatures in a bonding process with a friction material or an actual use environment (residual Stress) The problem of thermal strain that is released and deformed.

Various techniques have been proposed so far for cold-rolled steel sheets for drive-type parts including a plate. For example, Patent Document 1 proposes a technique for producing a steel sheet by hot rolling a steel at a finishing temperature (Ar ₃ transformation point - 20 ° C) or more, and cooling at a cooling rate of more than 120 ° C / sec. The temperature is 650° C. or less, and the difference between the cooling stop temperature of the center portion in the width direction of the steel sheet and the edge portion is 30° C. or less, and the winding is performed at a winding temperature of 600° C. or less. After pickling, the rolling reduction ratio is 40. % or more of cold rolling, or annealing at an annealing temperature of 600 ° C or higher and below the A _c1 transformation point, and then cold rolling at a rolling reduction ratio of 40% or more, whereby the surface hardness of steel sheet Hv is 170. ～300, the maximum value ΔHv of the difference in sheet surface hardness at each position in the longitudinal direction and the width direction of the steel sheet is 20 or less, wherein the steel contains C: 0.05% to 0.6% by mass%, and Si: 2.0% or less, Mn: 0.2% to 2.0%, P: 0.03% or less, S: 0.03% or less, Sol. Al: 0.1% or less, and N: 0.01% or less, and the balance contains Fe and unavoidable impurities. According to the technique proposed in Patent Document 1, the following direct cold-rolled steel sheet is obtained, that is, the difference in residual stress caused by the difference in the longitudinal direction and the width direction of the steel sheet is suppressed, and the flatness after the stamping is suppressed. Excellent.

Patent Document 2 proposes a technique in which the steel material is hot-rolled at a finish rolling finishing temperature of the finish rolling at an Ar ₃ transformation point or higher, and is cooled to 500° C. to 650° C. within 8 s after completion of the finish rolling, and The hot-rolled steel sheet is formed by performing a winding treatment at 500 ° C to 650 ° C, and then the cold-rolled steel sheet is subjected to cold rolling at a rolling reduction ratio of 30% to 70% to produce a cold-rolled steel sheet having the following steel raw materials as follows The composition contains C: 0.05% to less than 0.10%, Si: 0.5% or less, Mn: 0.20% to 2.0%, P: 0.03% or less, S: 0.020% or less, and Cr: 0.05% to 0.5% by mass%. %, and the rest contains Fe and unavoidable impurities. The hot-rolled steel sheet has a pro-eutectoid ferrite, a pearlite, a bainitic ferrite or a matrix of a bainite having a structure in which a cemetite present in the matrix of 1.0×10 ⁴ /mm 2 or more is dispersed, and the above-mentioned hot-rolled steel sheet The tensile strength is 440 MPa or more. Moreover, according to the technique proposed in Patent Document 2, a cold-rolled steel sheet having excellent flatness after press working and excellent end surface properties is obtained.

Patent Document 3 proposes a technique in which a slab is hot rolled at a hot rolling processing temperature: Ar ₃ transformation point or higher, and a winding temperature: 500 ° C to 600 ° C, and after pickling the hot rolled steel sheet, Cold rolling is performed at a rolling reduction ratio of 50% or more without annealing, and further, a cold rolled steel sheet is produced by performing a light draft rolling of a rolling reduction of 1% or less using a roll having a diameter of 300 mm or more. The slab has a composition of C: 0.15 mass% to 0.25 mass%, Si: 0.25 mass% or less, Mn: 0.3 mass% to 0.9 mass%, P: 0.03 mass% or less, and S: 0.015 mass%. Hereinafter, Al: 0.01% by mass to 0.08% by mass, N: 0.008% by mass or less, Ti: 0.01% by mass to 0.05% by mass, B: 0.002% by mass to 0.005% by mass, and the remainder is substantially Fe. According to the technique proposed in Patent Document 3, a cold rolled steel sheet for automatic transmission is obtained in which residual stress generated during cold rolling is reduced. Prior art document patent document

Patent Document 1: Japanese Patent Laid-Open Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei.

However, in the technique proposed in Patent Document 1, since the rapid cooling is performed after the completion of the hot rolling and the temperature is wound at a temperature as low as 600 ° C or lower, the residual stress inside the hot-rolled steel sheet is increased, and as a result, it is cold. The rolled steel sheet also has a state in which a large residual stress is accumulated. When the directly cold-rolled steel sheet in which the large residual stress is accumulated is press-formed, good flatness is obtained while maintaining the press forming, but in the bonding step of the friction material after the press forming The residual stress is released by heating, so that there is a problem of thermal strain in which flatness is deteriorated.

In the technique proposed in Patent Document 2, since a large number of hot-rolled steel sheets containing a lot of ferrite or toughened iron which are harder than ferrite iron are subjected to cold rolling, cold iron and waves are formed during cold rolling. Uneven deformation occurs near the phase boundary of the iron or toughened iron, and the residual stress inside the steel sheet increases. Therefore, when the cold-rolled steel sheet thus obtained is subjected to press forming, a good flat shape and appearances of punched surface are obtained while maintaining the press forming, but the same as the technique proposed in Patent Document 1. There is a problem of generating a heat strain.

In the technique proposed in Patent Document 3, the C content is as high as 0.15 mass% to 0.25 mass%, and the winding temperature in the hot rolling step is as low as 500 ° C to 600 ° C, so that a large amount of ferrite or toughening is generated in the hot rolled steel sheet. iron. Therefore, similarly to the technique proposed in Patent Document 2, the residual stress in the steel sheet during cold rolling increases, and as a result, even if a flat shape is obtained while maintaining press forming, there is a case where heating occurs after press forming. The problem of thermal strain.

An object of the present invention is to solve the above problems and to provide a cold-rolled steel sheet having a hardness required for use as a drive component such as a plate or a disk, a flatness after press, a press end surface property, and a heat-resistant strain characteristic, and a method for producing the same. Here, the heat-resistant strain property is a property in which the deformation of the steel sheet is small and sufficient flatness is obtained when heated to a temperature range of about 100° C. to 400° C. in the bonding step of the friction material or the actual use environment.

In order to solve the above problems, the inventors of the present invention have actively studied various factors affecting the heat-resistant strain characteristics of the cold-rolled steel sheet, the flatness after press, and the properties of the press-faced end.

As a result, it was found that in order to improve the heat resistance strain characteristics, it is effective to reduce the residual stress after cold rolling. In addition, it is found that in order to reduce the residual stress after cold rolling, it is important to set the rolling reduction in cold rolling to a predetermined value or less; and to reduce the amount of C of the steel material to a predetermined value or less and to specify the hot rolling step. The winding temperature, whereby the hot-rolled sheet before cold rolling is used as the main phase of the ferrite-grained iron, the volume fraction of the ferrite phase or the toughened iron phase of the hot-rolled sheet is lowered, and the steel sheet after cold rolling is controlled Average particle size and average aspect ratio of the Borne or toughened iron phase.

The hot-rolled sheet before cold rolling contains ferrite iron as a main phase, and a ferromagnetic phase or a toughened iron phase as a hard phase (hereinafter, any of a ferrite phase and a tough iron phase may be used hereinafter) In the case of the above-mentioned "hard phase", uneven deformation occurs in the vicinity of the interface between the ferrite-iron phase and the hard phase during cold rolling, and residual stress is likely to be accumulated. Therefore, by setting the hot-rolled sheet before cold rolling as the ferrite-grain main phase and reducing the volume fraction of the hard phase contained in the hot-rolled sheet, it is possible to reduce the accompanying ferrite iron/wave during cold rolling. The residual stress of uneven deformation near the interface of the iron or the interface of the ferrite iron/toughened iron can improve the heat-resistant strain characteristics of the cold-rolled steel sheet. When the above-described cold-rolled steel sheet is used to manufacture a drive component such as a plate, it is of course possible to solve the problem of lowering the flatness due to thermal strain after being press-formed into a predetermined shape, even in the step of bonding with the friction material or the actual use environment. The lower exposure to high temperatures also solves the problem of flatness reduction caused by thermal strain.

The present inventors have found that the hot-rolled sheet before cold rolling is used as the main phase of the ferrite-grained iron, the volume fraction of the hard phase of the hot-rolled sheet is lowered, and the average particle diameter and the average aspect ratio of the hard phase are controlled. It is extremely effective to improve the flatness and the end face properties of the cold-rolled steel sheet after the press.

By forming a hard phase as much as possible in the hot-rolled sheet before cold rolling, uniform characteristics are obtained in the steel sheet after cold rolling, and good flatness is obtained after punching. Further, by forming a hard phase as much as possible in the hot-rolled sheet before cold rolling, the hetero-phase interface (the interface between the ferrite-grained iron phase and the hard phase) which is likely to cause cracks is reduced during press forming, and thus the punching end face property is improved.

In the cold rolling, the hard phase extends in the rolling direction, but the hardness difference between the ferrite iron and the hard phase as the main phase is large, and thus the hard phase is extended toward the rolling direction (that is, the aspect ratio of the hard phase is larger), The larger the strain accumulated in the interface between the ferrite grain iron phase and the hard phase, the residual stress is accumulated, and the heat-resistant strain characteristics of the cold-rolled steel sheet are lowered. Therefore, in order to improve these characteristics, it is necessary to set the average aspect ratio of the hard phase containing any one or more of the ferrite and the toughened iron phase to a predetermined value or less. Further, by controlling the average particle diameter of the hard phase to a predetermined value or less, even if cracks occur from the boundary between different phases, crack propagation can be prevented from being largely propagated, and a defective end face can be obtained.

In order to reduce the volume fraction of the hard phase of the hot-rolled sheet by reducing the volume fraction of the hard phase of the hot-rolled sheet, the hot-rolled sheet before cold rolling is reduced to a predetermined value or less. It is necessary to set the winding temperature of the hot rolling step to a high temperature exceeding 600 ° C and 750 ° C or lower. In order to control the average particle diameter and the average aspect ratio of the hard phase of the steel sheet after cold rolling, in addition to optimizing the rolling conditions of the hot rolled sheet, it is also necessary to limit the rolling reduction ratio of the cold rolling.

The present invention has been completed based on the above findings, and the gist of the present invention is as follows. [1] A cold-rolled steel sheet having excellent pressability and heat-resistant strain characteristics, which has a composition of C: 0.01% or more and 0.08% or less, Si: 0.01% or more and 1.0% or less, and Mn: 0.05% by mass%. The above is 1.0% or less, P: 0.03% or less, S: 0.015% or less, Al: 0.005% or more and 0.10% or less, and N: 0.01% or less, and the balance contains Fe and unavoidable impurities; and has the following structure: The area ratio of the ferrite-grain iron phase is 80% or more, and the area ratio of the hard phase including at least one of the ferrite phase and the toughened iron phase is 20% or less in total, and the average particle diameter of the hard phase is 1 μm or more. 10 μm or less, and the average aspect ratio of the hard phase is 10.0 or less; and the Vickers hardness is Hv170 or more.

[2] The cold-rolled steel sheet having excellent pressability and heat-resistant strain characteristics as in the above [1], in addition to the above composition, further contains, by mass%, Cu: 0.01% or more and 0.20% or less, and Ni: 0.01% or more and 0.50%. Any one of the following.

[3] The cold-rolled steel sheet having excellent pressability and heat-resistant strain characteristics as in the above [1] or [2], in addition to the above composition, further contains, by mass%, Ti: 0.005% or more and 0.10% or less, and Nb: 0.005%. The above is 0.10% or less, V: 0.005% or more and 0.50% or less, Zr: 0.005% or more and 0.10% or less, Mo: 0.02% or more and 0.50% or less, Cr: 0.03% or more and 0.50% or less, and B: 0.0003%. Any of the above and 0.0050% or less.

[4] The cold-rolled steel sheet excellent in the squeezing property and the heat-resistant strain characteristic of any one of the above [1] to [3], in addition to the above composition, further contains Ca: 0.0003% or more and 0.0050% or less by mass%. And REM: 0.0003% or more and 0.0100% or less.

[5] The cold-rolled steel sheet having excellent pressability and heat-resistant strain characteristics according to any one of the above [1] to [4], in addition to the above composition, further contains, by mass%, Sb: 0.001% or more and 0.030% or less. Sn: Any one or more of 0.001% or more and 0.030% or less.

[6] A method for producing a cold-rolled steel sheet having excellent squeezing properties and heat-resistant strain characteristics, wherein the steel material is subjected to hot rolling at a finishing finish temperature of 800 ° C or higher and 950 ° C or lower, and after hot rolling is over 600 Winding is performed at a winding temperature of ° C and 750 ° C or less, and scale is removed by pickling, and then cold rolling is performed at a rolling reduction ratio of 30% or more and 70% or less. The following composition contains, by mass%, C: 0.01% or more and 0.08% or less, Si: 0.01% or more and 1.0% or less, Mn: 0.05% or more and 1.0% or less, P: 0.03% or less, and S: 0.015% or less. Al: 0.005% or more and 0.10% or less, and N: 0.01% or less, and the balance contains Fe and unavoidable impurities.

[7] The method for producing a cold-rolled steel sheet having excellent pressability and heat-resistant strain characteristics as described in the above [6], after performing the above-described cold rolling, performing temper rolling.

[8] The method for producing a cold-rolled steel sheet having excellent pressability and heat-resistant strain characteristics as described in the above [6] or [7], in addition to the above composition, further contains Cu: 0.01% or more and 0.20% or less in terms of % by mass, Ni : 0.01% or more and 0.50% or less.

[9] The method for producing a cold-rolled steel sheet having excellent pressability and heat-resistant strain characteristics according to any one of the above [6] to [8], further comprising, in addition to the above composition, Ti: 0.005% or more and 0.10 by mass% % or less, Nb: 0.005% or more and 0.10% or less, V: 0.005% or more and 0.50% or less, Zr: 0.005% or more and 0.10% or less, Mo: 0.02% or more and 0.50% or less, and Cr: 0.03% or more and 0.50. % or less, B: 0.0003% or more and 0.0050% or less.

[10] The method for producing a cold-rolled steel sheet having excellent pressability and heat-resistant strain characteristics according to any one of the above [6] to [9], further comprising, in addition to the above composition, Ca: 0.0003% or more and 0.0050% by mass % or less, REM: 0.0003% or more and 0.0100% or less.

[11] The method for producing a cold-rolled steel sheet having excellent pressability and heat-resistant strain characteristics according to any one of the above [6] to [10], further comprising, in addition to the above composition, Sb: 0.001% or more and 0.030% by mass % or less, and Sn: 0.001% or more and 0.030% or less. (Effect of the invention)

According to the present invention, it is possible to easily produce a cold-rolled steel sheet having excellent heat resistance and strain characteristics in addition to the flatness after press and the good end surface properties of the press, thereby realizing an industrially remarkable effect. The cold-rolled steel sheet according to the present invention is extremely suitable as a material for automotive parts, particularly for driving parts such as plates or discs.

First, the reason for limiting the component composition of the cold-rolled steel sheet of the present invention will be described. The % of the unit of the content of each component element means the meaning of mass% unless otherwise specified.

C: 0.01% or more and 0.08% or less C is an element required for strengthening the steel sheet, and it is necessary to set the C content to 0.01% or more in order to obtain the hardness required as a raw material for a drive component such as a plate or a disk. On the other hand, when the C content is more than 0.08%, the hardness becomes too high, and the iron content of the wave is increased, the flatness after the pressing is deteriorated, and the end surface properties of the press are deteriorated. Therefore, the upper limit of the C content is set to 0.08%. In particular, from the viewpoint of punching the end face properties, the C content is preferably made less than 0.05%. More preferably, it is 0.04% or less.

Si: 0.01% or more and 1.0% or less Si is a deoxidizer of steel, and has an effect of improving the cleanliness of steel. Therefore, the content is made 0.01% or more. Si is also an element which improves the hardness of a steel sheet by solid solution hardening, and can add this element in order to obtain a desired hardness. However, when the Si content exceeds 1.0%, the surface quality of the steel sheet deteriorates, so the upper limit of the Si content is made 1.0%. In particular, since the sheet used in the friction-generating part requires a good surface property, it is preferably set to 0.6% or less.

Mn: 0.05% or more and 1.0% or less Mn is an element which improves the hardness of the steel sheet by solid solution strengthening, and it is necessary to set the Mn content to 0.05% or more in order to obtain a desired hardness. It is preferably 0.1% or more. When the Mn content is more than 1.0%, the pulverized iron or the toughened iron or the like is excessively formed, and the pulverized iron or the like is formed in a layered manner due to segregation, and the end surface properties of the press are deteriorated. Therefore, the Mn content is set to 1.0% or less. It is preferably 0.5% or less.

P: 0.03% or less P is an element which is easily segregated in steel. When it is contained in a large amount, P is segregated to promote formation of a layered structure, and the end surface properties of the press are deteriorated. Therefore, the P content needs to be set to 0.03% or less. It is preferably 0.02% or less.

S: 0.015% or less S forms a sulfide-based intermediate such as MnS, and deteriorates the surface properties of the press. Therefore, the S content needs to be set to 0.015% or less. It is preferably 0.010% or less.

Al: 0.005% or more and 0.10% or less Al is added as a deoxidizing element, whereby the cleanliness of the steel sheet can be improved. Therefore, the content thereof is required to be 0.005% or more. It is preferably 0.03% or more. On the other hand, when the Al content exceeds 0.10%, an oxide is excessively formed and the surface properties are deteriorated, and the adhesion to the friction material is deteriorated. Therefore, the Al content is set to 0.10% or less. It is preferably 0.08% or less.

N: 0.01% or less N is a harmful element in the present invention, and if the content is excessive, the ductility of the steel sheet is lowered, and the end surface properties of the press are deteriorated. Therefore, the N content is set to 0.01% or less. It is preferably 0.006% or less.

The above is the basic component of the cold-rolled steel sheet of the present invention, but the cold-rolled steel sheet of the present invention contains the following elements as needed in addition to the basic components.

Cu: 0.01% or more and 0.20% or less, and Ni: 0.01% or more and 0.50% or less. Cu and Ni are elements which contribute to the hardness of the steel sheet by solid solution strengthening, and are required for the steel sheet. The hardness may contain these elements. In order to obtain the above effects, the Cu content is preferably 0.01% or more, and the Ni content is made 0.01% or more. More preferably, the Cu content is 0.02% or more, and the Ni content is 0.02% or more. On the other hand, when the content of these elements is excessive, the surface properties are deteriorated, and the adhesion to the friction material is deteriorated. Therefore, the Cu content is preferably 0.20% or less, and the Ni content is made 0.50% or less. More preferably, the Cu content is set to 0.10% or less, and the Ni content is set to 0.30% or less.

Ti: 0.005% or more and 0.10% or less, Nb: 0.005% or more and 0.10% or less, V: 0.005% or more and 0.50% or less, Zr: 0.005% or more and 0.10% or less, and Mo: 0.02% or more and 0.50% or less. Cr: 0.03% or more and 0.50% or less, and B: 0.0003% or more and 0.0050% or less. Ti, Nb, V, Zr, Mo, Cr, and B are elements which contribute to the improvement of the hardness of the steel sheet. It is preferred that the steel sheet imparts the desired hardness to contain the elements. On the other hand, if the content of these elements is excessive, the residual stress increases, and flatness or thermal strain after punching occurs. Therefore, the Ti content is preferably 0.005% or more and 0.10% or less, the Nb content is 0.005% or more and 0.10% or less, the V content is 0.005% or more and 0.50% or less, and the Zr content is 0.005% or more and 0.10. % or less, the Mo content is 0.02% or more and 0.50% or less, the Cr content is 0.03% or more and 0.50% or less, and the B content is 0.0003% or more and 0.0050% or less. More preferably, the Ti content is 0.008% or more and 0.03% or less, the Nb content is 0.008% or more and 0.05% or less, the V content is 0.01% or more and 0.20% or less, and the Zr content is 0.01% or more and 0.03% or less. The Mo content is set to 0.05% or more and 0.20% or less, the Cr content is set to 0.05% or more and 0.20% or less, and the B content is set to 0.0005% or more and 0.0030% or less.

Ca: 0.0003% or more and 0.0050% or less, and any one or more of REM: 0.0003% or more and 0.0100% or less. Both Ca and REM are elements having a function of controlling the form of the sulfide to a spherical shape and improving the punching end surface property of the steel sheet. It can be included as needed. In order to obtain the above effects, the Ca content is preferably 0.0003% or more, and the REM content is 0.0003% or more. More preferably, the Ca content is 0.0008% or more, and the REM content is 0.0008% or more. On the other hand, when the content of these elements is excessive, the medium is increased and the surface end properties of the steel sheet are deteriorated. Therefore, the Ca content is preferably made 0.0050% or less, and the REM content is made 0.0100% or less. Further, it is more preferable to set the Ca content to 0.0030% or less and the REM content to 0.0050% or less.

Sb: 0.001% or more and 0.030% or less, and Sn: 0.001% or more and 0.030% or less. Sb and Sn are elements which improve the surface properties of the steel sheet, and have an effect of improving the adhesion to the friction material. In order to obtain the above effects, the Sb content is preferably 0.001% or more, and the Sn content is 0.001% or more. On the other hand, when the content of these elements is excessive, surface segregation becomes remarkable, and the surface properties of the steel sheet deteriorate and the adhesion to the friction material is lowered. Therefore, the Sb content is preferably made 0.030% or less. The Sn content is set to 0.030% or less. More preferably, the Sb content is made 0.005% or more and 0.020% or less, and the Sn content is made 0.005% or more and 0.015% or less.

The rest of the above components are Fe and unavoidable impurities. Examples of the unavoidable impurities include O, Mg, Co, Zn, Ta, W, Pb, and Bi, and the content of these elements is acceptable as long as they are each about 0.01% or less.

Next, the structure of the cold rolled steel sheet of the present invention will be described. The cold-rolled steel sheet according to the present invention has a structure in which the area ratio of the ferrite-grained iron phase is 80% or more, and the area ratio of the hard phase including at least one of the ferrite phase and the toughened iron phase is 20% or less. The average particle diameter of the hard phase is 1 μm or more and 10 μm or less, and the average aspect ratio of the hard phase is 10.0 or less.

In the present invention, the residual stress in the cold-rolled steel sheet is lowered by making the deformation in the steel sheet during cold rolling uniform. From the above point of view, the cold-rolled steel sheet of the present invention needs to have the main phase as a soft ferrite-grained iron phase and suppress the hard corrugated iron phase and the toughened iron phase. When the hard phase including any one or more of the ferrite phase and the toughened iron phase is more than 20% in total area ratio, the residual stress after cold rolling increases, and the shape of the steel sheet after the press is deteriorated. At the time of pressing, a crack is generated at the interface between the ferrite grain iron phase and the hard phase, and the stamping end surface property of the steel sheet is deteriorated. Further, since the heat-resistant strain characteristics are deteriorated due to an increase in the residual stress, after the cold-rolled steel sheet is press-formed, thermal strain is generated when exposed to a high-temperature environment.

For the above reasons, in the present invention, the area ratio of the ferrite-grain iron phase needs to be 80% or more, and the area ratio of the hard phase including at least one of the ferrite phase and the toughened iron phase is set to 20 %the following. The area ratio of the ferrite iron phase is preferably set to 85% or more, more preferably 90% or more. On the other hand, the area ratio of the hard phase is preferably 15% or less in total, more preferably 10% or less.

However, if the area ratio of the hard phase is extremely low, the required hardness of the steel sheet cannot be obtained, and therefore the area ratio of the hard phase is preferably 2% or more in total. Further, the cold rolled steel sheet structure of the present invention may contain ferritic carbon iron in addition to the ferrite iron phase, the buck iron phase, and the toughened iron phase. The area ratio of Xueming carbon iron is preferably set to 1% or less.

Further, the cold-rolled steel sheet according to the present invention has a structure in which an average particle diameter of a hard phase including at least one of a ferrite phase and a toughened iron phase is 1 μm or more and 10 μm or less, and the hard phase is The average aspect ratio is 10.0 or less. Further, the method of determining the average particle diameter and the average aspect ratio of the hard phase is described in Examples to be described later.

When the average particle diameter of the hard phase exceeds 10 μm, the crack generated at the interface between the hard phase and the ferrite phase is largely propagated, and the end surface of the steel sheet is damaged, and the end surface property is lowered. Therefore, the average particle diameter of the hard phase is set to 10 μm or less. It is preferably 7 μm or less. The smaller the average particle diameter of the hard phase, the better from the viewpoint of the punchability of the steel sheet. However, in order to reduce the average particle diameter of the hard phase, it is necessary to lower the finish rolling finishing temperature and the winding temperature of the hot rolling at the time of manufacture of the steel sheet. On the other hand, in order to obtain the structure in which the ferrite-grained iron phase is the main phase of the present invention, it is necessary to set the finish rolling finishing temperature and the winding temperature of the hot rolling to a predetermined temperature or higher as described later, and to be in the range of the hot rolling conditions. There is a limit to the refinement of crystal grains in the inner hard phase. Therefore, the average particle diameter of the hard phase is set to 1 μm or more.

Further, when the average aspect ratio of the hard phase exceeds 10.0, the strain at the interface between the hard phase and the ferrite-grained iron phase as the main phase increases, and the residual stress increases, so that the heat-resistant strain characteristics of the cold-rolled steel sheet are lowered. Therefore, the average aspect ratio of the hard phase is set to be 10.0 or less. It is preferably 8.0 or less.

The hardness of the cold-rolled steel sheet of the present invention is 170 or more in terms of Hv (Vickers hardness). If the hardness of the steel sheet is less than Hv170, the strength is insufficient, and it is not possible to withstand the use of a plate, a disk, or a ring as a drive component of an automobile. Therefore, the hardness of the cold rolled steel sheet is set to Hv170 or more. It is preferably Hv190 or more. On the other hand, the hardness of the cold-rolled steel sheet according to the present invention is mainly based on work hardening of cold rolling. Therefore, if the hardness is too high (that is, if the rolling reduction ratio of the cold rolling is too high), the residual stress of the steel sheet also increases. Thereby the heat resistant strain characteristics are deteriorated. Therefore, the hardness of the cold rolled steel sheet is preferably set to Hv 250 or less.

Next, a method of producing the cold-rolled steel sheet of the present invention will be described. The cold-rolled steel sheet according to the present invention is obtained by subjecting a steel material having the above chemical composition to hot rolling to form a hot-rolled sheet having a ferrite-grained iron phase as a main phase, and removing the scale by pickling. The rolling reduction rate is cold rolling the hot rolled sheet.

The method for producing the steel raw material is not particularly limited. For example, the molten steel having the above composition is melted in a converter or an electric furnace, preferably secondary smelting by a vacuum degassing furnace, and a steel such as a slab is formed by a manufacturing method such as continuous casting. Common methods for raw materials can be applied.

Next, hot rolling including rough rolling and finish rolling is performed on the steel raw material to form a hot rolled sheet. In the case of performing hot rolling, the steel raw material may be subjected to direct rolling, which is hot rolling immediately after casting, or after heating for the purpose of supplementing heat after casting, and then hot rolling. When the steel material is heated before hot rolling, the heating temperature is not particularly limited, but is preferably set to a temperature in the range of 1000 ° C or more and 1300 ° C or less. When the heating temperature is less than 1000 ° C, the deformation resistance is increased, and a good shape cannot be obtained. On the other hand, when the temperature is higher than 1300 ° C, the growth of the scale is promoted, and the surface properties of the steel sheet are lowered. Further, the conditions of the rough rolling are not particularly limited.

Finishing finish temperature: 800 ° C or more and 950 ° C or less If the finish rolling finish temperature exceeds 950 ° C, the structure of the hot rolled sheet is coarsened. As a result, the average particle diameter of the hard phase of the steel sheet after cold rolling increases, and the end surface properties of the press are deteriorated. On the other hand, when the finishing rolling temperature is less than 800 ° C, the structure of the hot-rolled sheet becomes a structure containing extremely extended crystal grains, and the aspect ratio of the hard phase also increases. When the steel sheet having the hard phase extending in the rolling direction at the stage of the hot-rolled sheet is further cold-rolled, the hardness difference between the hard phase and the ferrite-grain phase as the main phase is large, and thus the structure is elongated in the rolling direction. At the time, a large residual stress is generated at the interface between the hard phase and the ferrite phase iron phase as the main phase. Therefore, the residual stress accumulated in the steel sheet after cold rolling increases, and thermal strain is likely to occur. Therefore, the finish rolling finishing temperature is set to 800 ° C or more and 950 ° C or less. It is preferably 850 ° C or higher and 920 ° C or lower.

Winding temperature: more than 600 ° C and 750 ° C or less. When the winding temperature is 600 ° C or less, a corrugated iron phase or a tough iron phase is excessively generated, and the target steel sheet mainly composed of the ferrite core phase cannot be obtained. organization. On the other hand, when the winding temperature exceeds 750 ° C, the ferrite phase or the ferritic carbon iron particles are coarsened, and the press end surface properties of the steel sheet are deteriorated, or the surface properties of the steel sheet are deteriorated. Therefore, the winding temperature is set to exceed 600 ° C and 750 ° C or less. It is preferably 620 ° C or more and 700 ° C or less.

The cooling rate at the time of cooling to the winding temperature after completion of the finish rolling is not particularly limited. However, in order to set the hot-rolled sheet and the finally obtained cold-rolled steel sheet into a desired structure, it is preferable to finish the finish rolling temperature to the coil. The average cooling rate in the temperature range around the temperature is set to 10 ° C / s or more and less than 120 ° C / s. More preferably, it is 15 ° C / s or more and 50 ° C / s or less. The hot-rolled sheet obtained as described above is subjected to cold rolling after pickling by pickling, thereby forming a cold-rolled steel sheet.

Cold rolling reduction ratio: 30% or more and 70% or less In order to obtain the hardness of the steel sheet required as a raw material for a drive component such as a plate by cold rolling, it is necessary to set the rolling reduction ratio to 30% or more. On the other hand, when the rolling reduction ratio exceeds 70%, the residual stress increases, and the average aspect ratio of the hard phase including the ferrite and/or the toughened iron phase exceeds a predetermined value, and thermal strain is likely to occur. Therefore, the rolling reduction ratio of cold rolling is set to 30% or more and 70% or less. It is preferably 40% or more and 60% or less.

In the present invention, from the viewpoint of the correction of the shape of the steel sheet and the adjustment of the residual stress, it is also possible to perform temper rolling or a leveler after cold rolling. From the viewpoint of adjusting the residual stress, it is preferable to carry out the temper rolling delay and set the elongation to 0.3% or more. More preferably, it is 0.4% or more. However, from the viewpoint of the flatness of the steel sheet after the temper rolling, it is preferably 1.0% or less. Example

The steel of the chemical composition shown in Table 1 was melted in a converter, and a steel slab (steel raw material) was formed by a continuous casting method. Then, these steel raw materials were subjected to hot rolling, cooling, and winding under the conditions shown in Table 2 to form a hot rolled sheet. Then, after the scale was removed by pickling, cold rolling was performed at the rolling reduction ratio shown in Table 2 to form a cold rolled steel sheet. The shape correction is performed on a part of the cold-rolled steel sheet by a leveling machine or a temper rolling.

[Table 1]

[Table 2]

A test piece was taken from the obtained cold-rolled steel sheet, and the structure observation was performed according to the method shown below, and the area ratio of the ferrite grain iron phase, the waved iron phase, the toughened iron phase, and the hard phase (waved iron phase) were determined. And/or toughened iron phase) average particle size and average aspect ratio. Further, a test piece was taken from the obtained cold-rolled steel sheet, and hardness, flatness after press, stamping end face property, and heat-resistant strain characteristic were evaluated by the method shown below.

The microstructure of the plate thickness profile parallel to the rolling direction was observed, and the microstructure was observed with a 3% nitric acid etch solution (Nital), and a scanning electron microscope (scanning electron) was used at a plate thickness of 1/4. Microscope (SEM) photographs at 500 times and 3 fields of view, and the area ratio of each phase and the particle diameter and aspect of the hard phase including at least one of the ferrite and the toughened iron phase by image processing. Quantitative than to quantify. The particle size is set to the square root of the value obtained by multiplying the major axis length a of the crystal grain by the minor axis length b ( ). The aspect ratio is a value (a/b) obtained by dividing the major axis length a of the crystal grain by the minor axis length b. The average particle diameter and the average aspect ratio of the hard phase are, in image processing, the arithmetic mean of the particle diameter and aspect ratio of all crystal grains identified as either of the ferrite phase or the toughened iron phase.

A sample having a plate thickness profile parallel to the rolling direction is embedded in the resin, and the plate thickness profile is ground, and the thickness is 1/4 of the thickness according to Japanese Industrial Standards (JIS). The Z 2244 was measured by a Vickers hardness tester at a load of 500 gf at 5 points, and the average value was taken as the hardness.

Flatness after stamping An annular plate having an outer diameter of 100 mm and an inner diameter of 80 mm was punched out from the obtained cold-rolled steel sheet, and the plate was placed on a measuring table of a laser displacement meter by means of a thunder The measurement device measures the height from the table to the upper surface of the annular portion of the plate to the entire annular portion, and calculates the difference between the minimum value and the maximum value. When the difference between the minimum value and the maximum value is 0.2 mm or less, the flatness is good: (○). On the other hand, the case where the difference between the minimum value and the maximum value exceeds 0.2 mm is set as the flatness: poor (×).

Stamping end face properties An annular plate having an outer diameter of 100 mm and an inner diameter of 80 mm was punched out from the obtained cold-rolled steel sheet, and the punched end surface was observed, and the case where no damage or secondary shear surface was used was a stamped end face. Character: Good (○). On the other hand, the case where the damage or the secondary shear plane was observed was taken as the stamping end face property: poor (×).

Heat-Resistant Strain Characteristics An annular plate having an outer diameter of 100 mm and an inner diameter of 80 mm was punched out from the obtained cold-rolled steel sheet, and the plate was held at 300 ° C for 1 hour, and then heat-treated to room temperature. After the heat treatment, the shape of the plate was measured by a laser measuring device in the same manner as in the above-described "measurement of flatness after pressing", and the difference between the minimum value and the maximum value of the height of the annular portion of the plate was calculated. The case where the difference between the minimum value and the maximum value is 0.2 mm or less is made into a heat-resistant strain characteristic: good (○). On the other hand, the case where the difference between the minimum value and the maximum value exceeds 0.2 mm is taken as the heat-resistant strain characteristic: poor (×). These results are shown in Table 3.

[table 3]

The cold-rolled steel sheets of the invention examples each have a sufficient hardness such as a Vickers hardness of Hv 170 or more, and are excellent in flatness after press working and punching end face properties, and are excellent in heat-resistant strain characteristics. On the other hand, the characteristics of any of the cold-rolled steel sheets of the comparative examples which are outside the range of the present invention were inferior. The present application claims priority based on Japanese Patent Application No. 2013-076860, filed on Jan.

no

no

no

Claims (25)

A cold-rolled steel sheet having a composition containing, by mass%, C: 0.01% or more and 0.08% or less, Si: 0.01% or more, 1.0% or less, Mn: 0.05% or more, 1.0% or less, P: 0.03% Hereinafter, S: 0.015% or less, Al: 0.005% or more, 0.10% or less, and N: 0.01% or less, and the balance contains Fe and unavoidable impurities; in addition to the above composition, further contains Ti: 0.005% by mass% The above is 0.10% or less, Nb: 0.005% or more and 0.10% or less, V: 0.005% or more and 0.50% or less, Zr: 0.005% or more and 0.10% or less, Mo: 0.02% or more and 0.50% or less, and Cr: 0.03%. Any one or more of 0.50% or less and B: 0.0003% or more and 0.0050% or less; in addition to the above composition, Ca: 0.0003% or more and 0.0050% or less, and REM: 0.0003% or more and 0.0100% by mass% Any one of the following: and has a structure in which the area ratio of the ferrite-grained iron phase is 80% or more, and the area ratio of the hard phase including at least one of the ferrite phase and the toughened iron phase is 20%. Hereinafter, the average particle diameter of the hard phase is 1 μm or more and 10 μm or less, and the hard phase is The average aspect ratio is 10.0 or less; and the cold rolled steel sheet has a Vickers hardness of Hv 170 or more and 250 or less. The cold-rolled steel sheet according to item 1 of the patent application, wherein In addition to the above-described composition, it is further contained in any one or more of Cu: 0.01% or more and 0.20% or less, and Ni: 0.01% or more and 0.50% or less. A cold-rolled steel sheet having a composition containing, by mass%, C: 0.01% or more and 0.08% or less, Si: 0.01% or more, 1.0% or less, Mn: 0.05% or more, 1.0% or less, P: 0.03% Hereinafter, S: 0.015% or less, Al: 0.005% or more, 0.10% or less, and N: 0.01% or less, and the balance contains Fe and unavoidable impurities; in addition to the above composition, further contains Ti: 0.005% by mass% The above is 0.10% or less, Nb: 0.005% or more and 0.10% or less, V: 0.005% or more and 0.50% or less, Zr: 0.005% or more and 0.10% or less, Mo: 0.02% or more and 0.50% or less, and Cr: 0.03%. In addition to the above composition, Sb: 0.001% or more and 0.030% or less, and Sn: 0.001% or more and 0.030%, in addition to the above composition, in addition to the above-mentioned composition Any one of the following: and has a structure in which the area ratio of the ferrite-grained iron phase is 80% or more, and the area ratio of the hard phase including at least one of the ferrite phase and the toughened iron phase is 20%. Hereinafter, the average particle diameter of the hard phase is 1 μm or more and 10 μm or less, and the hard phase is flat. The aspect ratio is 10.0 or less; cold-rolled steel sheet of the Vickers hardness of Hv170 or more and 250 or less. A cold rolled steel sheet according to claim 3, wherein In addition to the above-described composition, it is further contained in any one or more of Cu: 0.01% or more and 0.20% or less, and Ni: 0.01% or more and 0.50% or less. A cold-rolled steel sheet having a composition containing, by mass%, C: 0.01% or more and 0.08% or less, Si: 0.01% or more, 1.0% or less, Mn: 0.05% or more, 1.0% or less, P: 0.03% Hereinafter, S: 0.015% or less, Al: 0.005% or more, 0.10% or less, and N: 0.01% or less, and the balance contains Fe and unavoidable impurities; in addition to the above composition, further contains Ca: 0.0003% by mass% In addition to the above-described composition, Sb: 0.001% or more and 0.030% or less, and Sn: 0.001% or more and 0.030%, in addition to the above composition, in addition to the above-mentioned composition. Any one of the following: and has a structure in which the area ratio of the ferrite-grained iron phase is 80% or more, and the area ratio of the hard phase including at least one of the ferrite phase and the toughened iron phase is 20%. Hereinafter, the average particle diameter of the hard phase is 1 μm or more and 10 μm or less, and the average aspect ratio of the hard phase is 10.0 or less. The cold rolled steel sheet has a Vickers hardness of Hv 170 or more and 250 or less. The cold-rolled steel sheet according to the fifth aspect of the invention, further comprising, in addition to the above composition, at least one of Cu: 0.01% or more and 0.20% or less, and Ni: 0.01% or more and 0.50% or less by mass%. . A cold rolled steel sheet according to claim 5, wherein In addition to the above composition, Ti is contained in an amount of 0.005% or more and 0.10% or less, Nb is 0.005% or more and 0.10% or less, V is 0.005% or more and 0.50% or less, and Zr is 0.005% or more and 0.10% or less. Mo: 0.02% or more and 0.50% or less, Cr: 0.03% or more and 0.50% or less, and B: 0.0003% or more and 0.0050% or less. The cold-rolled steel sheet according to the fifth aspect of the invention, further comprising, in addition to the above composition, at least one of Cu: 0.01% or more and 0.20% or less, and Ni: 0.01% or more and 0.50% or less by mass%. In addition to the above composition, Ti is contained in an amount of 0.005% or more and 0.10% or less, Nb is 0.005% or more and 0.10% or less, V is 0.005% or more and 0.50% or less, and Zr is 0.005% or more and 0.10%. Hereinafter, Mo: 0.02% or more and 0.50% or less, Cr: 0.03% or more and 0.50% or less, and B: 0.0003% or more and 0.0050% or less. In the method of producing a cold-rolled steel sheet, the steel material is subjected to hot rolling at a finishing temperature of 800 ° C or higher and 950 ° C or lower, and after the hot rolling is completed, the coil is rolled at a winding temperature of more than 600 ° C and 750 ° C or lower. Winding and removing the scale by pickling, and then performing cold rolling at a rolling reduction ratio of 30% or more and 70% or less, the steel raw material having the following composition, containing: C: 0.01% or more, 0.08% by mass% Hereinafter, Si: 0.01% or more and 1.0% or less, Mn: 0.05% or more, 1.0% or less, P: 0.03% or less, S: 0.015% or less, and Al: 0.005% or more and 0.10% or less, and N: 0.01% or less, and further containing, by mass%, any one or more of Cu: 0.01% or more and 0.20% or less, and Ni: 0.01% or more and 0.50% or less; and further containing Ti: 0.005% or more by mass% 0.10% or less, Nb: 0.005% or more and 0.10% or less, V: 0.005% or more and 0.50% or less, Zr: 0.005% or more and 0.10% or less, Mo: 0.02% or more and 0.50% or less, and Cr: 0.03% or more and 0.50% or less and B: 0.0003% or more and 0.0050% or less; the remainder contains Fe and unavoidable impurities. The method for producing a cold-rolled steel sheet according to claim 9, wherein after the cold rolling is performed, the temper rolling is performed. In the method of producing a cold-rolled steel sheet, the steel material is subjected to hot rolling at a finishing temperature of 800 ° C or higher and 950 ° C or lower, and after the hot rolling is completed, the coil is rolled at a winding temperature of more than 600 ° C and 750 ° C or lower. Winding and removing the scale by pickling, and then performing cold rolling at a rolling reduction ratio of 30% or more and 70% or less, the steel raw material having the following composition, containing: C: 0.01% or more, 0.08% by mass% Hereinafter, Si: 0.01% or more and 1.0% or less, Mn: 0.05% or more, 1.0% or less, P: 0.03% or less, S: 0.015% or less, Al: 0.005% or more, 0.10% or less, and N: 0.01% or less ,and Further, in terms of % by mass, Cu: 0.01% or more and 0.20% or less, and Ni: 0.01% or more and 0.50% or less; and further, in terms of % by mass, Ca: 0.0003% or more and 0.0050% or less, and REM: 0.0003 Any one or more of % or more and 0.0100% or less; the balance contains Fe and unavoidable impurities. The method for producing a cold-rolled steel sheet according to claim 11, wherein after the cold rolling is performed, the temper rolling is performed. In the method of producing a cold-rolled steel sheet, the steel material is subjected to hot rolling at a finishing temperature of 800 ° C or higher and 950 ° C or lower, and after the hot rolling is completed, the coil is rolled at a winding temperature of more than 600 ° C and 750 ° C or lower. Winding and removing the scale by pickling, and then performing cold rolling at a rolling reduction ratio of 30% or more and 70% or less, the steel raw material having the following composition, containing: C: 0.01% or more, 0.08% by mass% Hereinafter, Si: 0.01% or more and 1.0% or less, Mn: 0.05% or more, 1.0% or less, P: 0.03% or less, S: 0.015% or less, Al: 0.005% or more, 0.10% or less, and N: 0.01% or less Further, Ti is contained in an amount of 0.005% or more and 0.10% or less, Nb: 0.005% or more and 0.10% or less, V: 0.005% or more and 0.50% or less, and Zr: 0.005% or more and 0.10% or less in terms of % by mass, and Mo: 0.02% or more and 0.50% or less, Cr: 0.03% or more and 0.50% or less, and B: 0.0003% or more and 0.0050% or less; Further, in terms of % by mass, Ca: 0.0003% or more and 0.0050% or less, and REM: 0.0003% or more and 0.0100% or less are contained, and the remainder contains Fe and unavoidable impurities. The method for producing a cold-rolled steel sheet according to the above-mentioned aspect of the invention, further comprising, in addition to the above composition, Cu: 0.01% or more and 0.20% or less, and Ni: 0.01% or more and 0.50% or less by mass% Any one or more. The method for producing a cold-rolled steel sheet according to claim 13 or claim 14, wherein the cold rolling is performed after the cold rolling is performed. In the method of producing a cold-rolled steel sheet, the steel material is subjected to hot rolling at a finishing temperature of 800 ° C or higher and 950 ° C or lower, and after the hot rolling is completed, the coil is rolled at a winding temperature of more than 600 ° C and 750 ° C or lower. Winding and removing the scale by pickling, and then performing cold rolling at a rolling reduction ratio of 30% or more and 70% or less, the steel raw material having the following composition, containing: C: 0.01% or more, 0.08% by mass% Hereinafter, Si: 0.01% or more and 1.0% or less, Mn: 0.05% or more, 1.0% or less, P: 0.03% or less, S: 0.015% or less, Al: 0.005% or more, 0.10% or less, and N: 0.01% or less Furthermore, it further contains, by mass%, any one or more of Cu: 0.01% or more and 0.20% or less, and Ni: 0.01% or more and 0.50% or less; Further, in terms of % by mass, Sb: 0.001% or more and 0.030% or less, and Sn: 0.001% or more and 0.030% or less are contained, and the remainder contains Fe and unavoidable impurities. The method for producing a cold-rolled steel sheet according to claim 16, wherein after the cold rolling is performed, the temper rolling is performed. In the method of producing a cold-rolled steel sheet, the steel material is subjected to hot rolling at a finishing temperature of 800 ° C or higher and 950 ° C or lower, and after the hot rolling is completed, the coil is rolled at a winding temperature of more than 600 ° C and 750 ° C or lower. Winding and removing the scale by pickling, and then performing cold rolling at a rolling reduction ratio of 30% or more and 70% or less, the steel raw material having the following composition, containing: C: 0.01% or more, 0.08% by mass% Hereinafter, Si: 0.01% or more and 1.0% or less, Mn: 0.05% or more, 1.0% or less, P: 0.03% or less, S: 0.015% or less, Al: 0.005% or more, 0.10% or less, and N: 0.01% or less Further, Ti is contained in an amount of 0.005% or more and 0.10% or less, Nb: 0.005% or more and 0.10% or less, V: 0.005% or more and 0.50% or less, and Zr: 0.005% or more and 0.10% or less in terms of % by mass, and Mo: 0.02% or more and 0.50% or less, Cr: 0.03% or more and 0.50% or less, B: 0.0003% or more and 0.0050% or less, and further, Sb: 0.001% or more and 0.030% or less in terms of % by mass, Sn : 0.001% or more and 0.030% or less; The rest contains Fe and unavoidable impurities. The method for producing a cold-rolled steel sheet according to claim 18, which further comprises, in addition to the above composition, Cu: 0.01% or more and 0.20% or less, and Ni: 0.01% or more and 0.50% or less by mass%. Any one or more. The method for producing a cold-rolled steel sheet according to claim 18, wherein the cold rolling is performed after the cold rolling is performed. In the method of producing a cold-rolled steel sheet, the steel material is subjected to hot rolling at a finishing temperature of 800 ° C or higher and 950 ° C or lower, and after the hot rolling is completed, the coil is rolled at a winding temperature of more than 600 ° C and 750 ° C or lower. Winding and removing the scale by pickling, and then performing cold rolling at a rolling reduction ratio of 30% or more and 70% or less, the steel raw material having the following composition, containing: C: 0.01% or more, 0.08% by mass% Hereinafter, Si: 0.01% or more and 1.0% or less, Mn: 0.05% or more, 1.0% or less, P: 0.03% or less, S: 0.015% or less, Al: 0.005% or more, 0.10% or less, and N: 0.01% or less Further, it contains, by mass%, Ca: 0.0003% or more and 0.0050% or less, and REM: 0.0003% or more and 0.0100% or less, and further contains, by mass%, Sb: 0.001% or more and 0.030% or less, Sn. : 0.001% or more and 0.030% or less; The rest contains Fe and unavoidable impurities. The method for producing a cold-rolled steel sheet according to claim 21, further comprising, in addition to the above composition, Cu: 0.01% or more and 0.20% or less, and Ni: 0.01% or more and 0.50% or less by mass% Any one or more. The method for producing a cold-rolled steel sheet according to any one of the above-mentioned claims, wherein, in addition to the above composition, further contains Ti: 0.005% or more and 0.10% or less, and Nb: 0.005% or more and 0.10 by mass%. % or less, V: 0.005% or more and 0.50% or less, Zr: 0.005% or more and 0.10% or less, Mo: 0.02% or more and 0.50% or less, Cr: 0.03% or more and 0.50% or less, and B: 0.0003% or more and 0.0050. Any one or more of % or less. The method for producing a cold-rolled steel sheet according to claim 21, further comprising, in addition to the above composition, Cu: 0.01% or more and 0.20% or less, and Ni: 0.01% or more and 0.50% or less by mass% In addition to the above composition, Ti is contained in an amount of 0.005% or more and 0.10% or less, Nb is 0.005% or more and 0.10% or less, V is 0.005% or more and 0.50% or less, and Zr is 0.005% or more. Further, 0.10% or less, Mo: 0.02% or more and 0.50% or less, Cr: 0.03% or more and 0.50% or less, and B: 0.0003% or more and 0.0050% or less. The method for producing a cold-rolled steel sheet according to any one of claims 21 to 24, wherein after the cold rolling is performed, the temper rolling is performed.