TWI550069B - Polymerizable liquid crystal composition - Google Patents
Polymerizable liquid crystal composition Download PDFInfo
- Publication number
- TWI550069B TWI550069B TW100132720A TW100132720A TWI550069B TW I550069 B TWI550069 B TW I550069B TW 100132720 A TW100132720 A TW 100132720A TW 100132720 A TW100132720 A TW 100132720A TW I550069 B TWI550069 B TW I550069B
- Authority
- TW
- Taiwan
- Prior art keywords
- liquid crystal
- film
- group
- phase
- polymerizable liquid
- Prior art date
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- 239000004973 liquid crystal related substance Substances 0.000 title claims description 196
- 239000000203 mixture Substances 0.000 title claims description 54
- 239000010408 film Substances 0.000 claims description 188
- 150000001875 compounds Chemical class 0.000 claims description 111
- 239000012788 optical film Substances 0.000 claims description 77
- 239000000758 substrate Substances 0.000 claims description 75
- 239000004990 Smectic liquid crystal Substances 0.000 claims description 33
- 239000003795 chemical substances by application Substances 0.000 claims description 33
- 239000002904 solvent Substances 0.000 claims description 32
- 125000001424 substituent group Chemical group 0.000 claims description 24
- 238000000576 coating method Methods 0.000 claims description 22
- 239000011248 coating agent Substances 0.000 claims description 20
- 238000004519 manufacturing process Methods 0.000 claims description 18
- 229920000058 polyacrylate Polymers 0.000 claims description 15
- 125000001153 fluoro group Chemical group F* 0.000 claims description 14
- 229910052731 fluorine Inorganic materials 0.000 claims description 12
- 125000000623 heterocyclic group Chemical group 0.000 claims description 9
- 230000000379 polymerizing effect Effects 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 6
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 5
- 125000001624 naphthyl group Chemical group 0.000 claims description 4
- 230000001747 exhibiting effect Effects 0.000 claims description 3
- FRASJONUBLZVQX-UHFFFAOYSA-N 1,4-naphthoquinone Chemical compound C1=CC=C2C(=O)C=CC(=O)C2=C1 FRASJONUBLZVQX-UHFFFAOYSA-N 0.000 claims 1
- 229940126062 Compound A Drugs 0.000 claims 1
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 claims 1
- 239000012071 phase Substances 0.000 description 95
- 239000010410 layer Substances 0.000 description 59
- 238000000034 method Methods 0.000 description 45
- -1 cyclohexane-1,4-diyl group Chemical group 0.000 description 33
- 125000000217 alkyl group Chemical group 0.000 description 30
- 239000000975 dye Substances 0.000 description 27
- 238000005401 electroluminescence Methods 0.000 description 21
- 125000004432 carbon atom Chemical group C* 0.000 description 20
- 239000002346 layers by function Substances 0.000 description 16
- 238000006116 polymerization reaction Methods 0.000 description 16
- 239000010409 thin film Substances 0.000 description 15
- 239000011521 glass Substances 0.000 description 13
- 239000000463 material Substances 0.000 description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 10
- 229910052799 carbon Inorganic materials 0.000 description 10
- 125000005843 halogen group Chemical group 0.000 description 10
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 10
- 239000011229 interlayer Substances 0.000 description 10
- 229920000642 polymer Polymers 0.000 description 10
- 125000003277 amino group Chemical group 0.000 description 9
- 230000010287 polarization Effects 0.000 description 9
- 230000007704 transition Effects 0.000 description 9
- 125000001309 chloro group Chemical group Cl* 0.000 description 8
- BGTOWKSIORTVQH-UHFFFAOYSA-N cyclopentanone Chemical compound O=C1CCCC1 BGTOWKSIORTVQH-UHFFFAOYSA-N 0.000 description 8
- 238000001035 drying Methods 0.000 description 8
- 239000003999 initiator Substances 0.000 description 8
- 238000002347 injection Methods 0.000 description 8
- 239000007924 injection Substances 0.000 description 8
- 239000003505 polymerization initiator Substances 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- 239000004372 Polyvinyl alcohol Substances 0.000 description 7
- 238000010521 absorption reaction Methods 0.000 description 7
- 239000000987 azo dye Substances 0.000 description 7
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- 239000000049 pigment Substances 0.000 description 7
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- 238000007789 sealing Methods 0.000 description 7
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- UHFFVFAKEGKNAQ-UHFFFAOYSA-N 2-benzyl-2-(dimethylamino)-1-(4-morpholin-4-ylphenyl)butan-1-one Chemical compound C=1C=C(N2CCOCC2)C=CC=1C(=O)C(CC)(N(C)C)CC1=CC=CC=C1 UHFFVFAKEGKNAQ-UHFFFAOYSA-N 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
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- 230000005525 hole transport Effects 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 125000003545 alkoxy group Chemical group 0.000 description 5
- 230000004888 barrier function Effects 0.000 description 5
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
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- 239000011159 matrix material Substances 0.000 description 5
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- 150000003254 radicals Chemical class 0.000 description 5
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- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 4
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- 125000001246 bromo group Chemical group Br* 0.000 description 4
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 4
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 4
- ISAOCJYIOMOJEB-UHFFFAOYSA-N desyl alcohol Natural products C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 4
- 238000001962 electrophoresis Methods 0.000 description 4
- LZCLXQDLBQLTDK-UHFFFAOYSA-N ethyl 2-hydroxypropanoate Chemical compound CCOC(=O)C(C)O LZCLXQDLBQLTDK-UHFFFAOYSA-N 0.000 description 4
- 239000003112 inhibitor Substances 0.000 description 4
- 150000002576 ketones Chemical class 0.000 description 4
- 230000033001 locomotion Effects 0.000 description 4
- 239000003504 photosensitizing agent Substances 0.000 description 4
- 230000002829 reductive effect Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229920002554 vinyl polymer Polymers 0.000 description 4
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 3
- 125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 description 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 3
- 244000028419 Styrax benzoin Species 0.000 description 3
- 235000000126 Styrax benzoin Nutrition 0.000 description 3
- 235000008411 Sumatra benzointree Nutrition 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
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- 239000012965 benzophenone Substances 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000002274 desiccant Substances 0.000 description 3
- 235000019382 gum benzoic Nutrition 0.000 description 3
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- RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Chemical compound SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 description 3
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 3
- 238000007740 vapor deposition Methods 0.000 description 3
- QGKMIGUHVLGJBR-UHFFFAOYSA-M (4z)-1-(3-methylbutyl)-4-[[1-(3-methylbutyl)quinolin-1-ium-4-yl]methylidene]quinoline;iodide Chemical compound [I-].C12=CC=CC=C2N(CCC(C)C)C=CC1=CC1=CC=[N+](CCC(C)C)C2=CC=CC=C12 QGKMIGUHVLGJBR-UHFFFAOYSA-M 0.000 description 2
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 2
- YIKSHDNOAYSSPX-UHFFFAOYSA-N 1-propan-2-ylthioxanthen-9-one Chemical compound S1C2=CC=CC=C2C(=O)C2=C1C=CC=C2C(C)C YIKSHDNOAYSSPX-UHFFFAOYSA-N 0.000 description 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 2
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 2
- XLLIQLLCWZCATF-UHFFFAOYSA-N 2-methoxyethyl acetate Chemical compound COCCOC(C)=O XLLIQLLCWZCATF-UHFFFAOYSA-N 0.000 description 2
- JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-naphthol Chemical compound C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
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- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 239000004986 Cholesteric liquid crystals (ChLC) Substances 0.000 description 2
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
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- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 2
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- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 2
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- 229910003437 indium oxide Inorganic materials 0.000 description 2
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 2
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- DBAMLKZZDQYENY-UHFFFAOYSA-N 2-[diphenylphosphoryl(phenyl)methyl]-1,3,5-trimethylbenzene Chemical compound CC1=C(C(C2=CC=CC=C2)P(C2=CC=CC=C2)(C2=CC=CC=C2)=O)C(=CC(=C1)C)C DBAMLKZZDQYENY-UHFFFAOYSA-N 0.000 description 1
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- XMLYCEVDHLAQEL-UHFFFAOYSA-N 2-hydroxy-2-methyl-1-phenylpropan-1-one Chemical compound CC(C)(O)C(=O)C1=CC=CC=C1 XMLYCEVDHLAQEL-UHFFFAOYSA-N 0.000 description 1
- BQZJOQXSCSZQPS-UHFFFAOYSA-N 2-methoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OC)C(=O)C1=CC=CC=C1 BQZJOQXSCSZQPS-UHFFFAOYSA-N 0.000 description 1
- LWRBVKNFOYUCNP-UHFFFAOYSA-N 2-methyl-1-(4-methylsulfanylphenyl)-2-morpholin-4-ylpropan-1-one Chemical compound C1=CC(SC)=CC=C1C(=O)C(C)(C)N1CCOCC1 LWRBVKNFOYUCNP-UHFFFAOYSA-N 0.000 description 1
- NNAHKQUHXJHBIV-UHFFFAOYSA-N 2-methyl-1-(4-methylthiophen-2-yl)-2-morpholin-4-ylpropan-1-one Chemical compound CC1=CSC(C(=O)C(C)(C)N2CCOCC2)=C1 NNAHKQUHXJHBIV-UHFFFAOYSA-N 0.000 description 1
- JBIJLHTVPXGSAM-UHFFFAOYSA-N 2-naphthylamine Chemical compound C1=CC=CC2=CC(N)=CC=C21 JBIJLHTVPXGSAM-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/02—Liquid crystal materials characterised by optical, electrical or physical properties of the components, in general
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
- C09K19/10—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
- C09K19/20—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing carbon and oxygen atoms as chain links, e.g. esters or ethers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/34—Non-steroidal liquid crystal compounds containing at least one heterocyclic ring
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/30—Polarising elements
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Nonlinear Science (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Liquid Crystal (AREA)
- Polarising Elements (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Liquid Crystal Substances (AREA)
- Polymerisation Methods In General (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
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| JP2010205215 | 2010-09-14 |
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| CN (1) | CN102433129B (enExample) |
| TW (1) | TWI550069B (enExample) |
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| JP6123563B2 (ja) * | 2012-08-31 | 2017-05-10 | 住友化学株式会社 | 円偏光板および表示装置 |
| JP2015038598A (ja) | 2013-07-18 | 2015-02-26 | 富士フイルム株式会社 | 位相差フィルム、偏光板および液晶表示装置 |
| JP2015043073A (ja) * | 2013-07-25 | 2015-03-05 | 富士フイルム株式会社 | 位相差フィルム、偏光板および液晶表示装置 |
| TWI635165B (zh) * | 2013-08-09 | 2018-09-11 | 住友化學股份有限公司 | Optical anisotropic layer forming composition |
| KR102177052B1 (ko) | 2013-08-09 | 2020-11-10 | 스미또모 가가꾸 가부시키가이샤 | 광학 이방성 적층체의 제조 방법 |
| KR20150093591A (ko) * | 2014-02-07 | 2015-08-18 | 스미또모 가가꾸 가부시키가이샤 | 장척 편광 필름의 제조 방법 |
| JP2015197492A (ja) * | 2014-03-31 | 2015-11-09 | 富士フイルム株式会社 | 光学異方性膜とその製造方法、積層体とその製造方法、偏光板、液晶表示装置及び有機ｅｌ表示装置 |
| JP6609897B2 (ja) * | 2014-04-10 | 2019-11-27 | 大日本印刷株式会社 | 位相差フィルム |
| JP6149006B2 (ja) * | 2014-06-18 | 2017-06-14 | 富士フイルム株式会社 | 反射フィルムおよび反射フィルムを有するディスプレイ |
| JP6728581B2 (ja) * | 2014-06-25 | 2020-07-22 | 住友化学株式会社 | 光吸収異方性膜、３次元光吸収異方性膜及びその製造方法 |
| US10557978B2 (en) * | 2015-07-24 | 2020-02-11 | Sumitomo Chemical Company, Limited | Composition, optical film including composition, and method of producing optical film |
| CN105885871B (zh) * | 2016-02-25 | 2018-05-08 | 江苏和成新材料有限公司 | 一种聚合性液晶组合物 |
| CN105572948B (zh) * | 2016-03-23 | 2022-03-25 | 大连龙宁科技有限公司 | 一种高温高湿液晶显示装置及其制造方法 |
| JP6469180B2 (ja) * | 2017-07-18 | 2019-02-13 | 富士フイルム株式会社 | 光学異方性膜とその製造方法、積層体とその製造方法、偏光板、液晶表示装置及び有機ｅｌ表示装置 |
| JP2019133151A (ja) * | 2018-02-01 | 2019-08-08 | 住友化学株式会社 | 偏光膜形成用組成物 |
| JP7441005B2 (ja) | 2018-02-05 | 2024-02-29 | 住友化学株式会社 | 偏光膜形成用組成物、偏光膜、偏光板およびその製造方法 |
| CN111886527B (zh) * | 2018-03-23 | 2022-05-24 | 富士胶片株式会社 | 偏振器、偏振器的制造方法、层叠体及图像显示装置 |
| JP7339014B2 (ja) | 2018-04-13 | 2023-09-05 | 住友化学株式会社 | 重合性液晶組成物 |
| JP7281881B2 (ja) * | 2018-07-31 | 2023-05-26 | 住友化学株式会社 | 水平配向液晶硬化膜およびこれを含む積層体 |
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| KR20190117446A (ko) | 2019-10-16 |
| JP2020098349A (ja) | 2020-06-25 |
| TW201224125A (en) | 2012-06-16 |
| JP6960481B2 (ja) | 2021-11-05 |
| KR102332389B1 (ko) | 2021-12-01 |
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| KR102202105B1 (ko) | 2021-01-13 |
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| JP6380603B2 (ja) | 2018-08-29 |
| JP6132049B2 (ja) | 2017-05-24 |
| JP2018205753A (ja) | 2018-12-27 |
| CN102433129A (zh) | 2012-05-02 |
| KR20200026864A (ko) | 2020-03-11 |
| JP2012083734A (ja) | 2012-04-26 |
| KR102089222B1 (ko) | 2020-03-13 |
| KR101906596B1 (ko) | 2018-10-10 |
| KR102031970B1 (ko) | 2019-10-14 |
| JP6658818B2 (ja) | 2020-03-04 |
| KR20210005972A (ko) | 2021-01-15 |
| KR20120028265A (ko) | 2012-03-22 |
| JP5982762B2 (ja) | 2016-08-31 |
| CN102433129B (zh) | 2016-04-13 |
| JP2016186075A (ja) | 2016-10-27 |
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