TWI534162B - 在矽烷接枝方法存在下使用之鹵化阻燃系統 - Google Patents
在矽烷接枝方法存在下使用之鹵化阻燃系統 Download PDFInfo
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- TWI534162B TWI534162B TW100117558A TW100117558A TWI534162B TW I534162 B TWI534162 B TW I534162B TW 100117558 A TW100117558 A TW 100117558A TW 100117558 A TW100117558 A TW 100117558A TW I534162 B TWI534162 B TW I534162B
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- Prior art keywords
- composition
- decane
- polyolefin
- weight
- halogenated
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- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical class N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims description 30
- 238000000034 method Methods 0.000 title claims description 26
- 230000008569 process Effects 0.000 title description 10
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 title 1
- 229910000077 silane Inorganic materials 0.000 title 1
- 239000000203 mixture Substances 0.000 claims description 81
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 claims description 66
- 229920000098 polyolefin Polymers 0.000 claims description 47
- 239000006229 carbon black Substances 0.000 claims description 31
- 238000004132 cross linking Methods 0.000 claims description 28
- -1 polyethylene Polymers 0.000 claims description 27
- 239000003054 catalyst Substances 0.000 claims description 25
- 239000000654 additive Substances 0.000 claims description 24
- BZQKBFHEWDPQHD-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-[2-(2,3,4,5,6-pentabromophenyl)ethyl]benzene Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1CCC1=C(Br)C(Br)=C(Br)C(Br)=C1Br BZQKBFHEWDPQHD-UHFFFAOYSA-N 0.000 claims description 22
- DIOQZVSQGTUSAI-NJFSPNSNSA-N decane Chemical class CCCCCCCCC[14CH3] DIOQZVSQGTUSAI-NJFSPNSNSA-N 0.000 claims description 18
- 239000000945 filler Substances 0.000 claims description 17
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- 238000001125 extrusion Methods 0.000 claims description 8
- LBIHNTAFJVHBLJ-UHFFFAOYSA-N 3-(triethoxymethyl)undec-1-ene Chemical compound C(=C)C(C(OCC)(OCC)OCC)CCCCCCCC LBIHNTAFJVHBLJ-UHFFFAOYSA-N 0.000 claims description 6
- 230000003078 antioxidant effect Effects 0.000 claims description 6
- 125000003118 aryl group Chemical group 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 150000002367 halogens Chemical class 0.000 claims description 3
- 239000006078 metal deactivator Substances 0.000 claims description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 125000001624 naphthyl group Chemical group 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- JCSJJSBQVCWCKY-UHFFFAOYSA-N CC(C(C(OC)(OC)OC)(CCC)OC)(CCCCCCC)CCC Chemical compound CC(C(C(OC)(OC)OC)(CCC)OC)(CCCCCCC)CCC JCSJJSBQVCWCKY-UHFFFAOYSA-N 0.000 claims 1
- 150000001649 bromium compounds Chemical group 0.000 claims 1
- 125000002081 peroxide group Chemical group 0.000 claims 1
- 235000019241 carbon black Nutrition 0.000 description 29
- 229920000642 polymer Polymers 0.000 description 27
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 16
- 239000005977 Ethylene Substances 0.000 description 16
- 239000004711 α-olefin Substances 0.000 description 16
- 239000003063 flame retardant Substances 0.000 description 15
- 239000004594 Masterbatch (MB) Substances 0.000 description 14
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 description 14
- 125000000217 alkyl group Chemical group 0.000 description 12
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- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 7
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- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 6
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- 229920000140 heteropolymer Polymers 0.000 description 6
- 239000000178 monomer Substances 0.000 description 6
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 6
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 6
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- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 5
- 150000001336 alkenes Chemical class 0.000 description 5
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- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
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- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 3
- 239000002841 Lewis acid Substances 0.000 description 3
- 239000002879 Lewis base Substances 0.000 description 3
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 229910000420 cerium oxide Inorganic materials 0.000 description 3
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- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 3
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- ORECYURYFJYPKY-UHFFFAOYSA-N n,n'-bis(2,2,6,6-tetramethylpiperidin-4-yl)hexane-1,6-diamine;2,4,6-trichloro-1,3,5-triazine;2,4,4-trimethylpentan-2-amine Chemical compound CC(C)(C)CC(C)(C)N.ClC1=NC(Cl)=NC(Cl)=N1.C1C(C)(C)NC(C)(C)CC1NCCCCCCNC1CC(C)(C)NC(C)(C)C1 ORECYURYFJYPKY-UHFFFAOYSA-N 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
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- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
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- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
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- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
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- CCCMONHAUSKTEQ-UHFFFAOYSA-N octadec-1-ene Chemical compound CCCCCCCCCCCCCCCCC=C CCCMONHAUSKTEQ-UHFFFAOYSA-N 0.000 description 2
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- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
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- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical class C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/14—Macromolecular materials
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/02—Halogenated hydrocarbons
- C08K5/03—Halogenated hydrocarbons aromatic, e.g. C6H5-CH2-Cl
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/443—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/016—Flame-proofing or flame-retarding additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0066—Flame-proofing or flame-retarding additives
Landscapes
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
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- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
- Graft Or Block Polymers (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
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| US7754969B2 (en) * | 2007-06-08 | 2010-07-13 | Southwire Company | Armored cable with integral support |
| WO2011156077A1 (en) * | 2010-06-08 | 2011-12-15 | Union Carbide Chemicals & Plastics Technology Llc | Halogenated flame retardant systems for use in presence of silane grafting process |
| DE102012022482A1 (de) * | 2012-11-19 | 2014-05-22 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Polymerzusammensetzung mit verbesserter Langzeitstabilität, hieraus hergestellte Formteile sowie Verwendungszwecke |
| DE102013005307A1 (de) | 2013-03-25 | 2014-09-25 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verwendung von organischen Oxyimiden als Flammschutzmittel für Kunststoffe sowie flammgeschützte Kunststoffzusammensetzung und hieraus hergestelltem Formteil |
| JP6311319B2 (ja) | 2014-01-14 | 2018-04-18 | 大日本印刷株式会社 | 樹脂組成物、リフレクター、リフレクター付きリードフレーム、及び半導体発光装置 |
| DE102014210214A1 (de) | 2014-05-28 | 2015-12-03 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verwendung von Oxyimid-enthaltenden Copolymeren oder Polymeren als Flammschutzmittel, Stabilisatoren, Rheologiemodifikatoren für Kunststoffe, Initiatoren für Polymerisations- und Pfropfprozesse, Vernetzungs- oder Kopplungsmittel sowie solche Copolymere oder Polymere enthaltende Kunststoffformmassen |
| DE102014211276A1 (de) | 2014-06-12 | 2015-12-17 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verwendung von Hydroxybenzotriazol-Derivaten und/oder Hydroxy-Indazol-Derivaten als Flammschutzmittel für Kunststoffe sowie flammgeschützte Kunststoffformmasse |
| US10119015B2 (en) * | 2014-06-18 | 2018-11-06 | Dow Global Technologies Llc | Moisture-curable polymeric compositions having halogenated polymers and metal mercaptides |
| KR102602891B1 (ko) * | 2015-04-30 | 2023-11-17 | 다우 글로벌 테크놀로지스 엘엘씨 | 폴리올레핀의 실란 가교결합을 위한 경화 조절 첨가제로서 하이드록실-말단화된 pdms |
| EP3510604B1 (en) | 2016-09-08 | 2022-08-31 | Dow Global Technologies LLC | Flame retardant polymeric composition |
| US11299616B2 (en) * | 2017-06-29 | 2022-04-12 | Dow Global Technologies Llc | Moisture-cured wire and cable constructions |
| CN110997835B (zh) * | 2017-07-31 | 2022-05-27 | 陶氏环球技术有限责任公司 | 电线和电缆绝缘和护套层的可湿气固化的组合物 |
| US11459452B2 (en) * | 2017-08-10 | 2022-10-04 | Dow Global Technologies Llc | Compositions comprising brominated polymeric flame retardant |
| CN111989361B (zh) * | 2018-04-26 | 2023-06-27 | 陶氏环球技术有限责任公司 | 聚烯烃添加剂配制物 |
| CA3097645A1 (en) | 2018-04-27 | 2019-10-31 | Dow Global Technologies Llc | Polymeric composition containing a light stabilizer |
| US11021425B2 (en) | 2018-10-12 | 2021-06-01 | International Business Machines Corporation | Polybrominated diphenyl-based flame retardant compounds |
| CN113454157B (zh) * | 2019-02-06 | 2024-01-09 | 陶氏环球技术有限责任公司 | 阻燃可湿交联的组合物 |
| CN110698600B (zh) * | 2019-10-14 | 2022-09-27 | 湖南工学院 | 一种本体阻燃型聚丙烯接枝物的制备方法及应用 |
| KR20250068235A (ko) * | 2023-11-09 | 2025-05-16 | 주식회사 세스맷 | 난연성 수지 혼합물을 포함하는, 팽창 완충 특성의 기공 구조를 갖는 이차전지용 단열 소화 폼과 그 제조 방법 |
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| BE794718Q (fr) | 1968-12-20 | 1973-05-16 | Dow Corning Ltd | Procede de reticulation d'olefines |
| GB1526398A (en) | 1974-12-06 | 1978-09-27 | Maillefer Sa | Manufacture of extruded products |
| US4144202A (en) | 1977-12-27 | 1979-03-13 | Union Carbide Corporation | Dielectric compositions comprising ethylene polymer stabilized against water treeing with epoxy containing organo silanes |
| US4598116A (en) | 1984-11-09 | 1986-07-01 | Union Carbide Corporation | Scorch resistant compositions based on water-curable thermoplastic polymers having hydrolyzable, pendant silane moieties, and organo titanates |
| US5112919A (en) | 1989-10-30 | 1992-05-12 | Union Carbide Chemicals & Plastics Technology Corporation | Solid feeding of silane crosslinking agents into extruder |
| US5272236A (en) | 1991-10-15 | 1993-12-21 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
| US5266627A (en) | 1991-02-25 | 1993-11-30 | Quantum Chemical Corporation | Hydrolyzable silane copolymer compositions resistant to premature crosslinking and process |
| US5246783A (en) | 1991-08-15 | 1993-09-21 | Exxon Chemical Patents Inc. | Electrical devices comprising polymeric insulating or semiconducting members |
| US5783638A (en) | 1991-10-15 | 1998-07-21 | The Dow Chemical Company | Elastic substantially linear ethylene polymers |
| US5278272A (en) | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
| CA2156816A1 (en) * | 1994-09-07 | 1996-03-08 | Jeffrey S. Borke | Flame retardant insulation compositions having enhanced curability |
| KR100276152B1 (ko) * | 1995-02-16 | 2001-03-02 | 고토 기치 | 결정성 폴리올레핀 수지 조성물 및 당해 조성물을 함유하는 전기 절연 부품 |
| US5824718A (en) | 1995-04-20 | 1998-10-20 | The Dow Chemical Company | Silane-crosslinkable, substantially linear ethylene polymers and their uses |
| JP3186542B2 (ja) * | 1995-09-27 | 2001-07-11 | 住友ベークライト株式会社 | 難燃発泡架橋ポリオレフィン絶縁電線の製造方法 |
| KR100455476B1 (ko) | 1995-12-27 | 2005-01-15 | 스미또모 베이크라이트 가부시키가이샤 | 난연성실란-가교결합폴리올레핀의제조방법 |
| US6924031B2 (en) | 1998-09-25 | 2005-08-02 | Pirelli Cavi E Sistemi S.P.A. | Low-smoke self-extinguishing electrical cable and flame-retardant composition used therein |
| US6496629B2 (en) | 1999-05-28 | 2002-12-17 | Tycom (Us) Inc. | Undersea telecommunications cable |
| JP2002155187A (ja) * | 2000-11-17 | 2002-05-28 | Hitachi Cable Ltd | シラン架橋ポリオレフィン成型物 |
| DE10154302C1 (de) * | 2001-11-05 | 2003-07-10 | Rehau Ag & Co | Vernetzte Artikel |
| US6714707B2 (en) | 2002-01-24 | 2004-03-30 | Alcatel | Optical cable housing an optical unit surrounded by a plurality of gel layers |
| EP1597308B1 (en) * | 2003-02-18 | 2008-08-13 | Union Carbide Chemicals & Plastics Technology Corporation | Flame retardant composition |
| MXPA06002482A (es) * | 2003-09-05 | 2006-06-20 | Oration Union Carbide Chemical | Composicion retardante de flama con excelente procesabilidad. |
| US7355089B2 (en) | 2004-03-17 | 2008-04-08 | Dow Global Technologies Inc. | Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates |
| KR101010288B1 (ko) * | 2008-10-21 | 2011-01-25 | 주식회사 위스컴 | 내열·난연 열가소성 수지 조성물 |
| CN101565525B (zh) | 2009-06-04 | 2011-11-02 | 上海凯波特种电缆料厂有限公司 | 一种用硅烷改性阻燃聚乙烯电缆料的方法 |
| WO2011156077A1 (en) * | 2010-06-08 | 2011-12-15 | Union Carbide Chemicals & Plastics Technology Llc | Halogenated flame retardant systems for use in presence of silane grafting process |
-
2011
- 2011-05-11 WO PCT/US2011/036057 patent/WO2011156077A1/en not_active Ceased
- 2011-05-11 US US13/698,887 patent/US9228131B2/en active Active
- 2011-05-11 CN CN201180038619.6A patent/CN103068864B/zh active Active
- 2011-05-11 KR KR1020127032102A patent/KR101825240B1/ko not_active Expired - Fee Related
- 2011-05-11 JP JP2013514181A patent/JP5889882B2/ja not_active Expired - Fee Related
- 2011-05-11 CA CA2799389A patent/CA2799389C/en active Active
- 2011-05-11 BR BR112012031033A patent/BR112012031033A2/pt active Search and Examination
- 2011-05-11 MX MX2012014294A patent/MX340175B/es active IP Right Grant
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- 2011-05-19 TW TW100117558A patent/TWI534162B/zh active
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Also Published As
| Publication number | Publication date |
|---|---|
| TW201204751A (en) | 2012-02-01 |
| JP2016047926A (ja) | 2016-04-07 |
| JP6329522B2 (ja) | 2018-05-23 |
| EP2580258A1 (en) | 2013-04-17 |
| US9228131B2 (en) | 2016-01-05 |
| BR112012031033A2 (pt) | 2016-10-25 |
| CA2799389C (en) | 2017-01-24 |
| CN103068864B (zh) | 2014-09-17 |
| WO2011156077A1 (en) | 2011-12-15 |
| KR20130121686A (ko) | 2013-11-06 |
| CN103068864A (zh) | 2013-04-24 |
| EP2580258B1 (en) | 2014-04-30 |
| MX2012014294A (es) | 2013-02-12 |
| JP5889882B2 (ja) | 2016-03-22 |
| US20130079448A1 (en) | 2013-03-28 |
| JP2013532206A (ja) | 2013-08-15 |
| CA2799389A1 (en) | 2011-12-15 |
| MX340175B (es) | 2016-06-29 |
| KR101825240B1 (ko) | 2018-02-02 |
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