TWI495090B - Memory structure and fabricating method thereof - Google Patents

Memory structure and fabricating method thereof Download PDF

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TWI495090B
TWI495090B TW101102517A TW101102517A TWI495090B TW I495090 B TWI495090 B TW I495090B TW 101102517 A TW101102517 A TW 101102517A TW 101102517 A TW101102517 A TW 101102517A TW I495090 B TWI495090 B TW I495090B
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gate
substrate
dummy gate
forming
layer
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TW201332088A (en
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Tsung Mu Lai
Chun Hung Lu
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Ememory Technology Inc
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記憶體結構及其製造方法Memory structure and manufacturing method thereof

本發明是有關於一種記憶體結構及其製造方法,且特別是有關於一種具有自對準分離閘極結構的記憶體結構及其製造方法。The present invention relates to a memory structure and a method of fabricating the same, and more particularly to a memory structure having a self-aligned separation gate structure and a method of fabricating the same.

在各種非揮發性記憶體產品中,具有可進行多次資料之存入、讀取、擦除等動作,且存入之資料在斷電後也不會消失之優點的快閃記憶體,已成為個人電腦和電子設備所廣泛採用的一種記憶體元件。Among various non-volatile memory products, there is a flash memory that can perform operations such as storing, reading, erasing, etc., and the stored data does not disappear after power-off. It has become a memory component widely used in personal computers and electronic devices.

典型的快閃記憶體是以摻雜的多晶矽(polysilicon)製作浮置閘極(floating gate)與控制閘極(control gate)。此外,在習知技術中,亦有採用電荷陷入層(charge trapping layer)取代多晶矽浮置閘極,此電荷陷入層之材質例如是氮化矽。這種氮化矽電荷陷入層上下通常各有一層氧化矽,而形成氧化矽/氮化矽/氧化矽(oxide-nitride-oxide,簡稱ONO)複合層。A typical flash memory is a floating gate and a control gate made of doped polysilicon. In addition, in the prior art, a charge trapping layer is used instead of a polysilicon floating gate, and the material of the charge trapping layer is, for example, tantalum nitride. The tantalum nitride charge trapping layer usually has a layer of yttrium oxide on top of each other to form an oxide-nitride-oxide (ONO) composite layer.

另外,為了減小記憶胞面積暨增進寫入效應,可在控制閘極側壁另設選擇閘極(select gate),而形成分離閘極(split-gate)結構。In addition, in order to reduce the memory cell area and enhance the writing effect, a select gate may be additionally provided on the control gate sidewall to form a split-gate structure.

本發明的目的就是在提供一種記憶體結構,其具有製造成本低的優點。It is an object of the present invention to provide a memory structure that has the advantage of being inexpensive to manufacture.

本發明的另一目的就是在提供一種記憶體結構的製造方法,其可有效地簡化製程。Another object of the present invention is to provide a method of fabricating a memory structure that can effectively simplify the process.

本發明的一實施例提出一種記憶體結構,包括至少一記憶胞,記憶胞包括基底、電荷儲存結構、控制閘極、選擇閘極、虛擬閘極、介電層及兩摻雜區。電荷儲存結構設置於基底上。控制閘極設置於電荷儲存結構上。選擇閘極設置於控制閘極一側的基底上。虛擬閘極設置於控制閘極另一側的基底上。介電層設置於選擇閘極與控制閘極之間、選擇閘極與基底之間、虛擬閘極與控制閘極之間、及虛擬閘極與基底之間。摻雜區分別設置於由控制閘極、選擇閘極與虛擬閘極所形成的結構兩側的基底中。An embodiment of the present invention provides a memory structure including at least one memory cell including a substrate, a charge storage structure, a control gate, a selection gate, a dummy gate, a dielectric layer, and two doped regions. The charge storage structure is disposed on the substrate. The control gate is disposed on the charge storage structure. The selection gate is disposed on the substrate on the side of the control gate. The dummy gate is disposed on the substrate on the other side of the control gate. The dielectric layer is disposed between the selection gate and the control gate, between the selection gate and the substrate, between the dummy gate and the control gate, and between the dummy gate and the substrate. The doped regions are respectively disposed in the substrate on both sides of the structure formed by the control gate, the selection gate, and the dummy gate.

依照本發明的一實施例所述,在上述之記憶體結構中,選擇閘極與虛擬閘極在遠離控制閘極的一側例如是分別具有凹口。According to an embodiment of the invention, in the memory structure, the gate and the dummy gate have a recess, for example, on a side away from the control gate.

依照本發明的一實施例所述,在上述之記憶體結構中,選擇閘極與虛擬閘極的形狀例如分別是L形或L形的鏡像。According to an embodiment of the invention, in the memory structure, the shape of the gate and the dummy gate is, for example, an L-shaped or L-shaped mirror image, respectively.

依照本發明的一實施例所述,在上述之記憶體結構中,接近虛擬閘極的摻雜區更包括延伸至虛擬閘極下方的基底中。According to an embodiment of the invention, in the memory structure described above, the doped region close to the dummy gate further includes a substrate extending below the dummy gate.

依照本發明的一實施例所述,在上述之記憶體結構中,更包括間隙壁,設置於選擇閘極側壁上與虛擬閘極側壁上。According to an embodiment of the invention, in the memory structure, a spacer is further disposed on the sidewall of the selection gate and the sidewall of the dummy gate.

依照本發明的一實施例所述,在上述之記憶體結構中,更包括金屬矽化物層,設置於選擇閘極上、虛擬閘極上與摻雜區上。According to an embodiment of the invention, in the memory structure, a metal germanide layer is further disposed on the selective gate, the dummy gate and the doped region.

依照本發明的一實施例所述,在上述之記憶體結構中,金屬矽化物層更包括設置於控制閘極上。According to an embodiment of the invention, in the memory structure, the metal telluride layer further comprises a gate disposed on the control gate.

依照本發明的一實施例所述,在上述之記憶體結構中,電荷儲存結構由基底起依序包括底介電層、電荷儲存層與頂介電層。According to an embodiment of the invention, in the memory structure, the charge storage structure includes a bottom dielectric layer, a charge storage layer and a top dielectric layer in sequence from the substrate.

依照本發明的一實施例所述,在上述之記憶體結構中,當記憶體結構包括多個記憶胞時,相鄰兩個記憶胞例如是呈鏡像配置。According to an embodiment of the invention, in the above memory structure, when the memory structure includes a plurality of memory cells, the adjacent two memory cells are, for example, in a mirror image configuration.

依照本發明的一實施例所述,在上述之記憶體結構中,介電層包括第一介電層、第二介電層、第三介電層及第四介電層。第一介電層設置於選擇閘極與控制閘極之間。第二介電層設置於選擇閘極與基底之間。第三介電層設置於虛擬閘極與控制閘極之間。第四介電層設置於虛擬閘極與基底之間。According to an embodiment of the present invention, in the memory structure, the dielectric layer includes a first dielectric layer, a second dielectric layer, a third dielectric layer, and a fourth dielectric layer. The first dielectric layer is disposed between the selection gate and the control gate. The second dielectric layer is disposed between the selection gate and the substrate. The third dielectric layer is disposed between the dummy gate and the control gate. The fourth dielectric layer is disposed between the dummy gate and the substrate.

本發明的一實施例提出一種記憶體結構的製造方法,包括下列步驟。首先,於基底上形成堆疊結構,且堆疊結構由基底起包括電荷儲存結構、控制閘極及犧牲層。接著,於堆疊結構所暴露的基底上與控制閘極側壁上形成介電層。然後,於基底上共形地形成覆蓋堆疊結構的導體層。接下來,於位於堆疊結構兩側的導體層上形成第一間隙壁,且第一間隙壁部分覆蓋導體層。之後,以第一間隙壁作為罩幕,移除部份導體層,以於堆疊結構兩側分別形成選擇閘極與虛擬閘極。繼之,於由控制閘極、選擇閘極與虛擬閘極所形成的結構兩側的基底中分別形成摻雜區。An embodiment of the invention provides a method of fabricating a memory structure comprising the following steps. First, a stacked structure is formed on a substrate, and the stacked structure includes a charge storage structure, a control gate, and a sacrificial layer from the substrate. Next, a dielectric layer is formed on the substrate exposed by the stacked structure and on the sidewalls of the control gate. Then, a conductor layer covering the stacked structure is conformally formed on the substrate. Next, a first spacer is formed on the conductor layers on both sides of the stacked structure, and the first spacer portion partially covers the conductor layer. Thereafter, a portion of the conductor layer is removed by using the first spacer as a mask to form a selective gate and a dummy gate on both sides of the stacked structure. Then, doped regions are respectively formed in the substrates on both sides of the structure formed by the control gate, the selection gate and the dummy gate.

依照本發明的一實施例所述,在上述之記憶體結構的製造方法中,第一間隙壁的形成方法包括下列步驟。首先,共形地形成覆蓋導體層的第一間隙壁材料層。接著,對第一間隙壁材料層進行回蝕刻製程。According to an embodiment of the present invention, in the method of fabricating the memory structure described above, the method of forming the first spacer includes the following steps. First, a first spacer material layer covering the conductor layer is formed conformally. Next, an etch back process is performed on the first spacer material layer.

依照本發明的一實施例所述,在上述之記憶體結構的製造方法中,接近虛擬閘極的摻雜區的形成方法包括下列步驟。首先,於基底上形成暴露出堆疊結構之一側的圖案化光阻層。接著,以圖案化光阻層作為罩幕,對基底進行離子植入製程。According to an embodiment of the present invention, in the method of fabricating the memory structure described above, the method of forming the doped region close to the dummy gate includes the following steps. First, a patterned photoresist layer exposing one side of the stacked structure is formed on the substrate. Next, the substrate is subjected to an ion implantation process using the patterned photoresist layer as a mask.

依照本發明的一實施例所述,在上述之記憶體結構的製造方法中,接近選擇閘極的摻雜區的形成方法包括以控制閘極、選擇閘極與虛擬閘極作為罩幕,對基底進行離子植入製程。According to an embodiment of the present invention, in the method of fabricating a memory structure, a method of forming a doped region close to a select gate includes controlling a gate, selecting a gate, and a dummy gate as a mask. The substrate is subjected to an ion implantation process.

依照本發明的一實施例所述,在上述之記憶體結構的製造方法中,於形成選擇閘極與虛擬閘極之後,更包括移除犧牲層。According to an embodiment of the invention, in the method of fabricating the memory structure, after the selection gate and the dummy gate are formed, the sacrificial layer is further removed.

依照本發明的一實施例所述,在上述之記憶體結構的製造方法中,更包括於控制閘極上、選擇閘極上、虛擬閘極上與摻雜區上形成金屬矽化物層。According to an embodiment of the invention, in the method for fabricating a memory structure, the method further includes forming a metal telluride layer on the control gate, the selection gate, the dummy gate, and the doped region.

依照本發明的一實施例所述,在上述之記憶體結構的製造方法中,於形成選擇閘極與虛擬閘極之後,更包括移除第一間隙壁。According to an embodiment of the invention, in the method of fabricating the memory structure, after the forming the gate and the dummy gate are formed, the first spacer is further removed.

依照本發明的一實施例所述,在上述之記憶體結構的製造方法中,於形成選擇閘極與虛擬閘極之後,更包括移除部份介電層,以暴露出部分基底。According to an embodiment of the invention, in the method of fabricating the memory structure, after forming the gate and the dummy gate, a portion of the dielectric layer is removed to expose a portion of the substrate.

依照本發明的一實施例所述,在上述之記憶體結構的製造方法中,於形成選擇閘極與虛擬閘極之後,更包括於選擇閘極的側壁上與虛擬閘極的側壁上形成第二間隙壁。According to an embodiment of the present invention, in the method of fabricating the memory structure, after forming the gate and the dummy gate, forming a second surface on the sidewall of the gate and the sidewall of the dummy gate Two gap walls.

依照本發明的一實施例所述,在上述之記憶體結構的製造方法中,更包括於選擇閘極上、虛擬閘極上與些摻雜區上形成金屬矽化物層。According to an embodiment of the invention, in the method for fabricating a memory structure, the method further includes forming a metal germanide layer on the select gate, the dummy gate, and the doped regions.

依照本發明的一實施例所述,在上述之記憶體結構的製造方法中,於形成選擇閘極與虛擬閘極之後,更包括移除虛擬閘極。According to an embodiment of the invention, in the method of fabricating the memory structure, after forming the select gate and the dummy gate, the virtual gate is further removed.

依照本發明的一實施例所述,在上述之記憶體結構的製造方法中,虛擬閘極的移除方法包括下列步驟。首先,於基底上形成暴露出堆疊結構接近虛擬閘極之一側的圖案化光阻層。接著,以圖案化光阻層作為罩幕,移除虛擬閘極。According to an embodiment of the invention, in the method of fabricating the memory structure, the method of removing the dummy gate includes the following steps. First, a patterned photoresist layer is formed on the substrate exposing a side of the stacked structure close to the virtual gate. Next, the patterned photoresist layer is used as a mask to remove the dummy gate.

依照本發明的一實施例所述,在上述之記憶體結構的製造方法中,遠離選擇閘極的摻雜區的形成方法包括在移除虛擬閘極之後,以圖案化光阻層作為罩幕,對基底進行離子植入製程。According to an embodiment of the present invention, in the method of fabricating the memory structure, the method of forming the doped region away from the selection gate includes patterning the photoresist layer as a mask after removing the dummy gate , the substrate is subjected to an ion implantation process.

依照本發明的一實施例所述,在上述之記憶體結構的製造方法中,接近選擇閘極的摻雜區的形成方法包括以控制閘極與選擇閘極作為罩幕,對基底進行離子植入製程。According to an embodiment of the present invention, in the method for fabricating a memory structure, a method of forming a doped region close to a gate includes performing a ion implantation on the substrate by using a gate and a gate as a mask. Into the process.

依照本發明的一實施例所述,在上述之記憶體結構的製造方法中,於移除虛擬閘極之後,更包括於控制閘極與選擇閘極所形成的結構兩側形成第三間隙壁。According to an embodiment of the present invention, in the method of fabricating the memory structure, after removing the dummy gate, a third spacer is formed on both sides of the structure formed by the control gate and the selection gate. .

依照本發明的一實施例所述,在上述之記憶體結構的製造方法中,於移除虛擬閘極之後,更包括於選擇閘極上與摻雜區上形成金屬矽化物層。According to an embodiment of the invention, in the method for fabricating a memory structure, after removing the dummy gate, a metal germanide layer is formed on the selective gate and the doped region.

基於上述,由於本發明所提出之記憶體結構的製造方法是以第一間隙壁作為罩幕,移除部份導體層而形成選擇閘極與虛擬閘極,所以可避免以光阻定義選擇閘極與虛擬閘極時,可能發生的偏移(overlay shift)問題。Based on the above, since the memory structure of the present invention is manufactured by using the first spacer as a mask, a part of the conductor layer is removed to form a selective gate and a dummy gate, so that the gate can be prevented from being defined by the photoresist. Overlap shift problems that can occur with poles and virtual gates.

此外,本發明所提出之記憶體結構由於製程簡單且能減少光罩的使用量,因此具有製造成本低的優點。In addition, the memory structure proposed by the present invention has the advantages of low manufacturing cost because the process is simple and the amount of use of the photomask can be reduced.

為讓本發明之上述特徵和優點能更明顯易懂,下文特舉實施例,並配合所附圖式作詳細說明如下。The above described features and advantages of the present invention will be more apparent from the following description.

圖1A至圖1E所繪示為本發明之第一實施例的記憶體結構的製造流程剖面圖。1A to 1E are cross-sectional views showing a manufacturing process of a memory structure according to a first embodiment of the present invention.

首先,請參照圖1A,於基底100上形成堆疊結構102,且堆疊結構102由基底100起包括電荷儲存結構104、控制閘極106及犧牲層108。基底100例如是矽基底。電荷儲存結構104由基底100起依序可包括底介電層110、電荷儲存層112與頂介電層114。底介電層110的材料例如是氧化矽。電荷儲存層112的材料例如是氮化矽。頂介電層114的材料例如是氧化矽。控制閘極106除了可在讀取時控制通道導通及在寫入/擦除時提供橫向電場外,可保護位於其下方的電荷儲存結構104,而使得電荷儲存結構104具有較佳的均勻性(uniformity)。控制閘極106的材料例如是摻雜多晶矽。犧牲層108的材料例如是氮化矽。其中,電荷儲存結構104、控制閘極106及犧牲層108的形成方法例如是藉由沉積製程與圖案化製程而形成之。在此實施例中,雖然是以形成兩個堆疊結構102進行說明,但並不用以限制本發明,只要形成至少一堆疊結構102即屬於本發明所保護之範圍。First, referring to FIG. 1A, a stacked structure 102 is formed on a substrate 100, and the stacked structure 102 includes a charge storage structure 104, a control gate 106, and a sacrificial layer 108 from the substrate 100. The substrate 100 is, for example, a crucible substrate. The charge storage structure 104 may include a bottom dielectric layer 110, a charge storage layer 112, and a top dielectric layer 114 in sequence from the substrate 100. The material of the bottom dielectric layer 110 is, for example, ruthenium oxide. The material of the charge storage layer 112 is, for example, tantalum nitride. The material of the top dielectric layer 114 is, for example, yttrium oxide. In addition to controlling the conduction of the channel during reading and providing a transverse electric field during writing/erasing, the control gate 106 can protect the charge storage structure 104 underneath, thereby providing better uniformity of the charge storage structure 104 ( Uniformity). The material of the control gate 106 is, for example, doped polysilicon. The material of the sacrificial layer 108 is, for example, tantalum nitride. The method for forming the charge storage structure 104, the control gate 106 and the sacrificial layer 108 is formed, for example, by a deposition process and a patterning process. In this embodiment, although the description is made to form two stacked structures 102, it is not intended to limit the present invention, and it is within the scope of the present invention to form at least one stacked structure 102.

接著,於基底100上形成暴露出堆疊結構102之一側的圖案化光阻層116。圖案化光阻層116的材料例如是正型光阻或負型光阻,而圖案化光阻層116的形成方法例如是進行微影製程而形成之。Next, a patterned photoresist layer 116 exposing one side of the stacked structure 102 is formed on the substrate 100. The material of the patterned photoresist layer 116 is, for example, a positive photoresist or a negative photoresist, and the formation method of the patterned photoresist layer 116 is formed, for example, by a lithography process.

然後,以圖案化光阻層116作為罩幕,於堆疊結構102之預定形成虛擬閘極之一側的基底100中形成摻雜區118。摻雜區118的形成方法例如是以圖案化光阻層116作為罩幕,對基底100進行離子植入製程而形成之。Then, with the patterned photoresist layer 116 as a mask, a doped region 118 is formed in the substrate 100 on the side of the stacked structure 102 on which one of the dummy gates is formed. The method of forming the doping region 118 is formed by, for example, patterning the photoresist layer 116 as a mask to perform an ion implantation process on the substrate 100.

接下來,請參照圖1B,移除圖案化光阻層116。圖案化光阻層116的移除方法例如是乾式去光阻法或濕式去光光阻法。Next, referring to FIG. 1B, the patterned photoresist layer 116 is removed. The method of removing the patterned photoresist layer 116 is, for example, a dry de-resisting method or a wet de-glazing method.

之後,於堆疊結構102所暴露的基底100上與控制閘極106側壁上形成介電層120。介電層120的材料例如是氧化矽,而介電層120的形成方法例如是熱氧化法。此外,介電層120的形成步驟更可於電荷儲存結構104側壁上形成介電層120。Thereafter, a dielectric layer 120 is formed on the substrate 100 exposed by the stacked structure 102 and on the sidewalls of the control gate 106. The material of the dielectric layer 120 is, for example, ruthenium oxide, and the formation method of the dielectric layer 120 is, for example, a thermal oxidation method. In addition, the forming step of the dielectric layer 120 further forms the dielectric layer 120 on the sidewalls of the charge storage structure 104.

繼之,於基底100上共形地形成覆蓋堆疊結構102的導體層122。導體層122的材料例如是摻雜多晶矽,而導體層122的形成方法例如是化學氣相沈積法。Next, a conductor layer 122 covering the stacked structure 102 is conformally formed on the substrate 100. The material of the conductor layer 122 is, for example, doped polysilicon, and the method of forming the conductor layer 122 is, for example, a chemical vapor deposition method.

再者,共形地形成覆蓋導體層122的間隙壁材料層124。間隙壁材料層124的材料例如是氮化矽,而間隙壁材料層124的形成方法例如是化學氣相沈積法。Furthermore, the spacer material layer 124 covering the conductor layer 122 is conformally formed. The material of the spacer material layer 124 is, for example, tantalum nitride, and the method of forming the spacer material layer 124 is, for example, a chemical vapor deposition method.

隨後,請參照圖1C,對間隙壁材料層124進行回蝕刻製程,以於位於堆疊結構102兩側的導體層122上形成間隙壁124a,且間隙壁124a部分覆蓋導體層122。此外,藉由間隙壁124a的寬度可調整後續所形成之選擇閘極的長度與虛擬閘極的長度。Subsequently, referring to FIG. 1C , the spacer material layer 124 is etched back to form spacers 124 a on the conductor layers 122 on both sides of the stacked structure 102 , and the spacers 124 a partially cover the conductor layers 122 . In addition, the length of the subsequently formed select gate and the length of the dummy gate can be adjusted by the width of the spacer 124a.

接著,以間隙壁124a作為罩幕,移除部份導體層122,以於堆疊結構102兩側分別形成選擇閘極122a與虛擬閘極122b,且可同時暴露出犧牲層108。由於選擇閘極122a與虛擬閘極122b的關鍵尺寸是由導體層122的膜厚與間隙壁124a的寬度所決定,並非使用光罩進行定義,因此可簡化製程。其中,選擇閘極122a與虛擬閘極122b藉由介電層120與控制閘極106進行隔離。部份導體層122的移除方法例如是乾式蝕刻法。Then, the partial conductor layer 122 is removed by using the spacers 124a as a mask to form the selection gate 122a and the dummy gate 122b on both sides of the stacked structure 102, and the sacrificial layer 108 can be exposed at the same time. Since the critical dimension of the selection gate 122a and the dummy gate 122b is determined by the film thickness of the conductor layer 122 and the width of the spacer 124a, it is not defined using a photomask, so that the process can be simplified. The selection gate 122a and the dummy gate 122b are isolated from the control gate 106 by the dielectric layer 120. The method of removing part of the conductor layer 122 is, for example, a dry etching method.

此外,由於虛擬閘極122b是形成於摻雜區118上方,所以接近虛擬閘極122b的摻雜區118可延伸至虛擬閘極122b下方的基底100中。另外,選擇閘極122a與虛擬閘極122b在遠離控制閘極108的一側例如是分別具有凹口126。選擇閘極122a與虛擬閘極122b的形狀分別例如是L形或L形的鏡像。Moreover, since the dummy gate 122b is formed over the doped region 118, the doped region 118 proximate to the dummy gate 122b can extend into the substrate 100 under the dummy gate 122b. In addition, the selection gate 122a and the dummy gate 122b have, for example, notches 126 on the side remote from the control gate 108, respectively. The shapes of the selection gate 122a and the dummy gate 122b are respectively, for example, an L-shaped or L-shaped mirror image.

然後,請參照圖1D,可選擇性地移除犧牲層108,而暴露出控制閘極106。犧牲層108的移除方法例如是溼式蝕刻法或乾式蝕刻法。在此實施例中,由於犧牲層108與間隙壁124a的材料相似,因此間隙壁124a可選擇性地在移除犧牲層108的製程中一併移除,而能簡化製程,但並不用以限制本發明。於其他實施例中,犧牲層108與間隙壁124a亦可分別進行移除。Then, referring to FIG. 1D, the sacrificial layer 108 can be selectively removed to expose the control gate 106. The removal method of the sacrificial layer 108 is, for example, a wet etching method or a dry etching method. In this embodiment, since the sacrificial layer 108 is similar in material to the spacers 124a, the spacers 124a can be selectively removed in the process of removing the sacrificial layer 108, which simplifies the process, but is not limited. this invention. In other embodiments, the sacrificial layer 108 and the spacers 124a may also be removed separately.

接下來,請參照圖1E,可選擇性地於選擇閘極122a的側壁上與虛擬閘極122b的側壁上形成間隙壁128。間隙壁128的材料例如是氧化矽。間隙壁128形成方法例如是先利用化學氣相沉積法共形地形成覆蓋選擇閘極122a與虛擬閘極122b的間隙壁材料層,接著再對間隙壁材料層進行回蝕刻法而形成之。值得注意的是,在形成間隙壁128的製程中,可同時移除位於由控制閘極106、選擇閘極122a與虛擬閘極122b所形成的結構兩側的部分介電層120,而暴露出部分基底100。Next, referring to FIG. 1E, a spacer 128 may be selectively formed on the sidewall of the selection gate 122a and the sidewall of the dummy gate 122b. The material of the spacer 128 is, for example, ruthenium oxide. The spacer 128 is formed by, for example, conformally forming a spacer material layer covering the selection gate 122a and the dummy gate 122b by chemical vapor deposition, and then forming the spacer material layer by etch-etching. It should be noted that in the process of forming the spacers 128, a portion of the dielectric layer 120 on both sides of the structure formed by the control gate 106, the selection gate 122a and the dummy gate 122b can be simultaneously removed, and exposed. Part of the substrate 100.

之後,可利用控制閘極106、選擇閘極122a、虛擬閘極122b與間隙壁128作為罩幕,對基底100進行離子植入製程,以於由控制閘極106、選擇閘極122a與虛擬閘極122b所形成的結構兩側的基底100中分別形成摻雜區118、130。其中,摻雜區118接近虛擬閘極122b,而摻雜區130接近選擇閘極122a。在此實施例中,雖然摻雜區118、130是藉由上述方法所形成,且摻雜區118是藉由進行兩次離子植入製程所形成,但並不用以限制本發明。於此技術領域具有通常知識者亦可採用其他方法完成摻雜區118、130的製作。亦即,只要將摻雜區118、130分別於形成由控制閘極106、選擇閘極122a與虛擬閘極122b所形成的結構兩側的基底100中,即屬於本發明所保護的範圍。Thereafter, the control gate 106, the selection gate 122a, the dummy gate 122b, and the spacer 128 can be used as a mask to perform an ion implantation process on the substrate 100 to control the gate 106, select the gate 122a, and the dummy gate. Doped regions 118, 130 are formed in the substrates 100 on both sides of the structure formed by the electrodes 122b, respectively. The doped region 118 is close to the dummy gate 122b, and the doped region 130 is close to the selection gate 122a. In this embodiment, although the doping regions 118, 130 are formed by the above method, and the doping region 118 is formed by performing two ion implantation processes, it is not intended to limit the present invention. Those skilled in the art may also use other methods to fabricate the doped regions 118, 130. That is, as long as the doping regions 118, 130 are respectively formed in the substrate 100 on both sides of the structure formed by the control gate 106, the selection gate 122a and the dummy gate 122b, it is within the scope of the present invention.

接下來,可選擇性地於控制閘極106上、選擇閘極122a上、虛擬閘極122b上與摻雜區118、130上形成金屬矽化物層132。金屬矽化物層132的材料例如是TiSi2 、CoSi2 或NiSi2 ,而金屬矽化物層132的形成方法例如是進行自對準金屬矽化物製程而形成之。Next, a metal telluride layer 132 can be selectively formed on the control gate 106, the select gate 122a, the dummy gate 122b, and the doped regions 118, 130. The material of the metal telluride layer 132 is, for example, TiSi 2 , CoSi 2 or NiSi 2 , and the method of forming the metal telluride layer 132 is formed, for example, by performing a self-aligned metal telluride process.

基於上述實施例可知,由於上述記憶體結構的製造方法是以間隙壁124a作為罩幕,移除部份導體層122而形成選擇閘極122a與虛擬閘極122b,所以可避免一般分離閘極記憶胞常遇到的選擇閘極對準問題。According to the above embodiment, since the memory structure is manufactured by using the spacers 124a as a mask, the partial conductor layer 122 is removed to form the selective gate 122a and the dummy gate 122b, so that the general separation gate memory can be avoided. The choice of gate alignment problems often encountered by cells.

圖2所繪示為本發明之第二實施例的記憶體結構的剖面圖。其中,圖2為接續圖1C之後所進行的圖式說明。2 is a cross-sectional view showing the structure of a memory according to a second embodiment of the present invention. 2 is a schematic illustration of the following description taken after FIG. 1C.

接著,藉由圖2來說明本發明之第二實施例的記憶體結構的製造方法。Next, a method of manufacturing the memory structure of the second embodiment of the present invention will be described with reference to FIG.

請同時參照圖2與圖1A至圖1E,第二實施例與第一實施例的差異在於:第二實施例並未移除覆蓋控制閘極106的犧牲層108,所以金屬矽化物層132只形成在選擇閘極122a上、虛擬閘極122b上與摻雜區118、130上,而未形成在控制閘極108上。此外,第二實施例在形成選擇閘極122a上與虛擬閘極122b之後,可選擇性地移除間隙壁124a。間隙壁124a的移除方法例如是乾式蝕刻法。在此實施例中,雖然是以移除間隙壁124a為例進行說明,但並不用以限制本發明。在其他實施例中,亦可保留間隙壁124a。此外,圖2與圖1A至圖1E中相同的標號表示相似的構件,且具有相似的材料、配置方式、形成方法及功效,故於此不再贅述。Referring to FIG. 2 and FIG. 1A to FIG. 1E simultaneously, the difference between the second embodiment and the first embodiment is that the second embodiment does not remove the sacrificial layer 108 covering the control gate 106, so the metal telluride layer 132 only It is formed on the selection gate 122a, on the dummy gate 122b, and on the doping regions 118, 130, but not on the control gate 108. Furthermore, the second embodiment selectively removes the spacers 124a after forming the selective gate 122a and the dummy gate 122b. The method of removing the spacers 124a is, for example, a dry etching method. In this embodiment, although the removal of the spacer 124a is taken as an example, it is not intended to limit the present invention. In other embodiments, the spacers 124a may also be retained. In addition, the same reference numerals in FIG. 2 and FIGS. 1A to 1E denote similar members, and have similar materials, configurations, formation methods, and effects, and thus will not be described again.

同樣地,第二實施例之記憶體結構的製造方法是以間隙壁124a作為罩幕,移除部份導體層122而形成選擇閘極122a與虛擬閘極122b,所以可避免一般分離閘極記憶胞會遭遇的選擇閘極對準問題。Similarly, the memory structure of the second embodiment is manufactured by using the spacers 124a as a mask to remove a portion of the conductor layer 122 to form the selective gate 122a and the dummy gate 122b, thereby avoiding the general separation gate memory. The choice of gate alignment problems encountered by the cell.

圖3A至圖3D所繪示為本發明之第三實施例的記憶體結構的製造流程剖面圖。3A to 3D are cross-sectional views showing a manufacturing process of a memory structure according to a third embodiment of the present invention.

首先,請參照圖3A,於基底200上形成堆疊結構202,且堆疊結構202由基底200起包括電荷儲存結構204、控制閘極206及犧牲層208。基底200例如是矽基底。電荷儲存結構204由基底200起依序可包括底介電層210、電荷儲存層212與頂介電層214。底介電層210的材料例如是氧化矽。電荷儲存層212的材料例如是氮化矽。頂介電層214的材料例如是氧化矽。控制閘極206除了可在讀取時控制通道導通及在寫入/擦除時提供橫向電場外,可保護位於其下方的電荷儲存結構204,而使得電荷儲存結構204具有較佳的均勻性(uniformity)。控制閘極206的材料例如是摻雜多晶矽。犧牲層208的材料例如是氮化矽。其中,電荷儲存結構204、控制閘極206及犧牲層208的形成方法例如是藉由沉積製程與圖案化製程而形成之。在此實施例中,雖然是以形成兩個堆疊結構202進行說明,但並不用以限制本發明,只要形成至少一堆疊結構202即屬於本發明所保護之範圍。First, referring to FIG. 3A, a stacked structure 202 is formed on the substrate 200, and the stacked structure 202 includes a charge storage structure 204, a control gate 206, and a sacrificial layer 208 from the substrate 200. The substrate 200 is, for example, a crucible substrate. The charge storage structure 204 may include a bottom dielectric layer 210, a charge storage layer 212, and a top dielectric layer 214 in sequence from the substrate 200. The material of the bottom dielectric layer 210 is, for example, ruthenium oxide. The material of the charge storage layer 212 is, for example, tantalum nitride. The material of the top dielectric layer 214 is, for example, ruthenium oxide. In addition to controlling the conduction of the channel during reading and providing a transverse electric field during writing/erasing, the control gate 206 protects the charge storage structure 204 underneath, thereby providing better uniformity of the charge storage structure 204 ( Uniformity). The material of the control gate 206 is, for example, doped polysilicon. The material of the sacrificial layer 208 is, for example, tantalum nitride. The method for forming the charge storage structure 204, the control gate 206 and the sacrificial layer 208 is formed, for example, by a deposition process and a patterning process. In this embodiment, although the description is made to form two stacked structures 202, it is not intended to limit the present invention, and it is within the scope of the present invention to form at least one stacked structure 202.

接著,於堆疊結構202所暴露的基底200上與控制閘極206側壁上形成介電層216。介電層216的材料例如是氧化矽,而介電層216的形成方法例如是熱氧化法。此外,介電層216的形成步驟更可於電荷儲存結構204側壁上形成介電層216。Next, a dielectric layer 216 is formed on the substrate 200 exposed by the stacked structure 202 and on the sidewalls of the control gate 206. The material of the dielectric layer 216 is, for example, ruthenium oxide, and the formation method of the dielectric layer 216 is, for example, a thermal oxidation method. In addition, the step of forming the dielectric layer 216 further forms the dielectric layer 216 on the sidewalls of the charge storage structure 204.

繼之,於基底200上共形地形成覆蓋堆疊結構202的導體層218。導體層218的材料例如是摻雜多晶矽,而導體層218的形成方法例如是化學氣相沈積法。Next, a conductor layer 218 covering the stacked structure 202 is conformally formed on the substrate 200. The material of the conductor layer 218 is, for example, doped polysilicon, and the method of forming the conductor layer 218 is, for example, a chemical vapor deposition method.

再者,共形地形成覆蓋導體層218的間隙壁材料層220。間隙壁材料層220的材料例如是氮化矽,而間隙壁材料層220的形成方法例如是化學氣相沈積法。Furthermore, the spacer material layer 220 covering the conductor layer 218 is conformally formed. The material of the spacer material layer 220 is, for example, tantalum nitride, and the method of forming the spacer material layer 220 is, for example, a chemical vapor deposition method.

隨後,請參照圖3B,對間隙壁材料層220進行回蝕刻製程,以於位於堆疊結構202兩側的導體層218上形成間隙壁220a,且間隙壁220a部分覆蓋導體層218。此外,藉由間隙壁220a的寬度可調整後續所形成之選擇閘極的長度與虛擬閘極的長度。Subsequently, referring to FIG. 3B, the spacer material layer 220 is etched back to form a spacer 220a on the conductor layer 218 on both sides of the stacked structure 202, and the spacer 220a partially covers the conductor layer 218. In addition, the length of the subsequently formed selection gate and the length of the dummy gate can be adjusted by the width of the spacer 220a.

接著,以間隙壁220a作為罩幕,移除部份導體層218,以於堆疊結構202兩側分別形成選擇閘極218a與虛擬閘極218b,且可同時暴露出犧牲層208。由於選擇閘極218a與虛擬閘極218b的關鍵尺寸是由導體層218的膜厚與間隙壁220a的寬度所決定,並非使用光罩進行定義,因此可避免對準偏移而造成的選擇閘極長度偏差。其中,選擇閘極218a與虛擬閘極218b藉由介電層216與控制閘極206進行隔離。部份導體層218的移除方法例如是乾式蝕刻法。Then, a portion of the conductor layer 218 is removed by using the spacer 220a as a mask to form a selection gate 218a and a dummy gate 218b on both sides of the stacked structure 202, and the sacrificial layer 208 may be exposed at the same time. Since the critical dimension of the selection gate 218a and the dummy gate 218b is determined by the film thickness of the conductor layer 218 and the width of the spacer 220a, it is not defined by the reticle, so that the selection gate can be avoided due to the alignment offset. Length deviation. The gate 218a and the dummy gate 218b are separated from the control gate 206 by the dielectric layer 216. The method of removing part of the conductor layer 218 is, for example, a dry etching method.

此外,選擇閘極218a與虛擬閘極218b在遠離控制閘極208的一側例如是分別具有凹口222。選擇閘極218a與虛擬閘極218b的形狀分別例如是L形或L形的鏡像。Further, the selection gate 218a and the dummy gate 218b have, for example, notches 222 on the side remote from the control gate 208, respectively. The shape of the selection gate 218a and the dummy gate 218b are respectively, for example, an L-shaped or L-shaped mirror image.

然後,請參照圖3C,可選擇性地移除間隙壁220a。間隙壁220a的移除方法例如是乾式蝕刻法。在此實施例中,雖然是以移除間隙壁220a為例進行說明,但並不用以限制本發明。在其他實施例中,亦可保留間隙壁220a。Then, referring to FIG. 3C, the spacer 220a can be selectively removed. The method of removing the spacer 220a is, for example, a dry etching method. In this embodiment, although the removal of the spacer 220a is taken as an example, it is not intended to limit the present invention. In other embodiments, the spacers 220a may also be retained.

接下來,於基底200上形成暴露出堆疊結構202接近虛擬閘極218b之一側的圖案化光阻層224。圖案化光阻層224的材料例如是正型光阻或負型光阻,而圖案化光阻層224的形成方法例如是進行微影製程而形成之。Next, a patterned photoresist layer 224 exposing the stacked structure 202 to one side of the dummy gate 218b is formed on the substrate 200. The material of the patterned photoresist layer 224 is, for example, a positive photoresist or a negative photoresist, and the formation method of the patterned photoresist layer 224 is formed, for example, by a lithography process.

之後,以圖案化光阻層224作為罩幕,移除虛擬閘極218b。虛擬閘極218b的移除方法例如是乾式蝕刻法。值得注意的是,在移除虛擬閘極218b的製程中,可同時移除位於虛擬閘極218b附近的介電層216,而暴露出部分基底200。Thereafter, the dummy gate 218b is removed by patterning the photoresist layer 224 as a mask. The method of removing the dummy gate 218b is, for example, a dry etching method. It should be noted that in the process of removing the dummy gate 218b, the dielectric layer 216 located near the dummy gate 218b can be simultaneously removed to expose a portion of the substrate 200.

繼之,以圖案化光阻層224作為罩幕,對基底200進行離子植入製程,以於遠離選擇閘極218a的基底200中摻雜區226。Next, with the patterned photoresist layer 224 as a mask, the substrate 200 is subjected to an ion implantation process to separate the doped regions 226 from the substrate 200 of the selection gate 218a.

隨後,請參照圖3D,移除圖案化光阻層224。圖案化光阻層224的移除方法例如是乾式去光阻法。Subsequently, referring to FIG. 3D, the patterned photoresist layer 224 is removed. The method of removing the patterned photoresist layer 224 is, for example, a dry de-resisting method.

再者,可選擇性地於選擇閘極218a的側壁上與控制閘極206的側壁上形成間隙壁228。間隙壁228的材料例如是氧化矽。間隙壁228形成方法例如是先利用化學氣相沉積法共形地形成覆蓋選擇閘極218a與控制閘極206的間隙壁材料層,接著再對間隙壁材料層進行回蝕刻法而形成之。值得注意的是,在形成間隙壁228的製程中,可同時移除位於選擇閘極218a附近的介電層216,而暴露出部分基底200。Furthermore, a spacer 228 can be selectively formed on the sidewall of the selection gate 218a and the sidewall of the control gate 206. The material of the spacer 228 is, for example, ruthenium oxide. The spacer 228 is formed by, for example, conformally forming a spacer material layer covering the selection gate 218a and the control gate 206 by chemical vapor deposition, and then forming the spacer material layer by etch-etching. It should be noted that in the process of forming the spacers 228, the dielectric layer 216 located near the selection gate 218a can be simultaneously removed to expose a portion of the substrate 200.

之後,可利用控制閘極206、選擇閘極218a與間隙壁228作為罩幕,對基底200進行離子植入製程,以於由控制閘極206與選擇閘極218a所形成的結構兩側的基底200中分別形成摻雜區226、230。其中,摻雜區226遠離選擇閘極218a,而摻雜區230接近選擇閘極218a。在此實施例中,雖然摻雜區226、230是藉由上述方法所形成,且摻雜區226是藉由進行兩次離子植入製程所形成,但並不用以限制本發明。於此技術領域具有通常知識者亦可採用其他方法完成摻雜區226、230的製作。亦即,只要將摻雜區226、230分別於形成由控制閘極206與選擇閘極218a所形成的結構兩側的基底200中,即屬於本發明所保護的範圍。Thereafter, the control gate 206, the selection gate 218a and the spacer 228 can be used as a mask to perform an ion implantation process on the substrate 200 to form a substrate on both sides of the structure formed by the control gate 206 and the selection gate 218a. Doped regions 226, 230 are formed in 200, respectively. The doped region 226 is away from the select gate 218a, and the doped region 230 is adjacent to the select gate 218a. In this embodiment, although the doping regions 226, 230 are formed by the above method, and the doping region 226 is formed by performing two ion implantation processes, it is not intended to limit the present invention. Those skilled in the art may also use other methods to fabricate the doped regions 226, 230. That is, as long as the doping regions 226, 230 are respectively formed in the substrate 200 on both sides of the structure formed by the control gate 206 and the selection gate 218a, it is within the scope of the present invention.

接下來,可選擇性地於選擇閘極218a上與摻雜區226、230上形成金屬矽化物層232。金屬矽化物層232的材料例如是TiSi2 、CoSi2 或NiSi2 ,而金屬矽化物層232的形成方法例如是進行自對準金屬矽化物製程而形成之。Next, a metal telluride layer 232 can be selectively formed on the select gate 218a and the doped regions 226, 230. The material of the metal telluride layer 232 is, for example, TiSi 2 , CoSi 2 or NiSi 2 , and the method of forming the metal telluride layer 232 is formed, for example, by performing a self-aligned metal telluride process.

基於上述實施例可知,由於上述記憶體結構的製造方法是以間隙壁220a作為罩幕,移除部份導體層218而形成選擇閘極218a,所以可減少光罩的使用量,且能簡化製程。According to the above embodiment, since the memory structure is manufactured by using the spacer 220a as a mask and removing part of the conductor layer 218 to form the selection gate 218a, the amount of the mask can be reduced, and the process can be simplified. .

以下,以下,藉由圖1E與圖2來介紹上述實施例的記憶體結構。Hereinafter, the memory structure of the above embodiment will be described below with reference to FIGS. 1E and 2.

請參照圖1E,記憶體結構包括至少一記憶胞134,各個記憶胞134包括基底100、電荷儲存結構104、控制閘極106、選擇閘極122a、虛擬閘極122b、介電層120及摻雜區118、130。相鄰兩個記憶胞134例如是呈鏡像配置。電荷儲存結構104設置於基底100上。電荷儲存結構104由基底100起依序可包括底介電層110、電荷儲存層112與頂介電層114。控制閘極106設置於電荷儲存結構104上。選擇閘極122a設置於控制閘極106一側的基底200上。虛擬閘極122b設置於控制閘極106另一側的基底200上。選擇閘極122a與虛擬閘極122b在遠離控制閘極108的一側例如是分別具有凹口126。選擇閘極122a與虛擬閘極122b的形狀分別例如是L形或L形的鏡像。介電層120包括介電層120a、120b、120c、120d,其中介電層120a設置於選擇閘極122a與控制閘極106之間,介電層120b設置於選擇閘極122a與基底100之間,介電層120c設置於虛擬閘極122b與控制閘極106之間,且介電層120d設置於虛擬閘極122b與基底100之間。在此實施例中,介電層120a、120b、120c、120d分別為介電層120的一部分,且例如是由同一道製程所形成的同一膜層,但並不用以限制本發明。在其他實施例中,介電層120a、120b、120c、120d亦可為由不同製程所形成的不同膜層。摻雜區118、130分別設置於由控制閘極106、選擇閘極122a與虛擬閘極122b所形成的結構兩側的基底100中。另外,記憶胞134更可包括間隙壁128,設置於選擇閘極122a側壁上與虛擬閘極122b側壁上。記憶胞138更可包括金屬矽化物層132,設置於控制閘極106、選擇閘極122a上、虛擬閘極122b上與摻雜區118、130上。此外,由於圖1E的記憶體結構中各構件的材料、配置方式、形成方法與功效已於上述實施例中進行詳盡地說明,故於此不再贅述。Referring to FIG. 1E, the memory structure includes at least one memory cell 134. Each memory cell 134 includes a substrate 100, a charge storage structure 104, a control gate 106, a selection gate 122a, a dummy gate 122b, a dielectric layer 120, and a doping layer. Areas 118, 130. The adjacent two memory cells 134 are, for example, in a mirrored configuration. The charge storage structure 104 is disposed on the substrate 100. The charge storage structure 104 may include a bottom dielectric layer 110, a charge storage layer 112, and a top dielectric layer 114 in sequence from the substrate 100. Control gate 106 is disposed on charge storage structure 104. The selection gate 122a is disposed on the substrate 200 on the side of the control gate 106. The dummy gate 122b is disposed on the substrate 200 on the other side of the control gate 106. The selection gate 122a and the dummy gate 122b have, for example, notches 126 on the side remote from the control gate 108, respectively. The shapes of the selection gate 122a and the dummy gate 122b are respectively, for example, an L-shaped or L-shaped mirror image. The dielectric layer 120 includes dielectric layers 120a, 120b, 120c, and 120d. The dielectric layer 120a is disposed between the selection gate 122a and the control gate 106. The dielectric layer 120b is disposed between the selection gate 122a and the substrate 100. The dielectric layer 120c is disposed between the dummy gate 122b and the control gate 106, and the dielectric layer 120d is disposed between the dummy gate 122b and the substrate 100. In this embodiment, the dielectric layers 120a, 120b, 120c, and 120d are respectively a part of the dielectric layer 120, and are, for example, the same film layer formed by the same process, but are not intended to limit the present invention. In other embodiments, the dielectric layers 120a, 120b, 120c, 120d may also be different film layers formed by different processes. The doped regions 118, 130 are respectively disposed in the substrate 100 on both sides of the structure formed by the control gate 106, the selection gate 122a, and the dummy gate 122b. In addition, the memory cell 134 may further include a spacer 128 disposed on the sidewall of the selection gate 122a and the sidewall of the dummy gate 122b. The memory cell 138 may further include a metal telluride layer 132 disposed on the control gate 106, the select gate 122a, the dummy gate 122b, and the doped regions 118, 130. In addition, since the materials, arrangement, formation method and effect of each member in the memory structure of FIG. 1E have been described in detail in the above embodiments, they will not be described again.

接著,請同時參照圖2與圖1E,第二實施例與第一實施例的差異在於:由於第二實施例的記憶胞136更包括覆蓋控制閘極106的犧牲層108,所以金屬矽化物層132只設置在選擇閘極122a上、虛擬閘極122b上與摻雜區118、130上,而未設置在控制閘極108上。同樣地,由於圖2的記憶體結構中各構件的材料、配置方式、形成方法與功效已於上述實施例中進行詳盡地說明,故於此不再贅述。Next, referring to FIG. 2 and FIG. 1E simultaneously, the difference between the second embodiment and the first embodiment is that since the memory cell 136 of the second embodiment further includes the sacrificial layer 108 covering the control gate 106, the metal telluride layer 132 is disposed on the selection gate 122a, the dummy gate 122b, and the doped regions 118, 130, and is not disposed on the control gate 108. Similarly, since the materials, arrangement, formation methods, and effects of the components in the memory structure of FIG. 2 have been described in detail in the above embodiments, they are not described herein.

基於上述實施例可知,上述記憶體結構的自動對準選擇閘極方法具有小面積和性能穩定的優點。Based on the above embodiments, the automatic alignment selection gate method of the above memory structure has the advantages of small area and stable performance.

綜上所述,上述實施例至少具有下列優點:In summary, the above embodiment has at least the following advantages:

1. 藉由上述實施例所提出之記憶體結構的製造方法可具有高度製程穩定性。1. The method of fabricating the memory structure proposed by the above embodiments can have high process stability.

2. 上述實施例所提出之記憶體結構具有高集成度的優點。2. The memory structure proposed in the above embodiments has the advantage of high integration.

雖然本發明已以實施例揭露如上,然其並非用以限定本發明,任何熟習此技藝者,在不脫離本發明之精神和範圍內,當可作些許之更動與潤飾,因此本發明之保護範圍當視後附之申請專利範圍所界定者為準。Although the present invention has been disclosed in the above embodiments, it is not intended to limit the present invention, and the present invention may be modified and modified without departing from the spirit and scope of the invention. The scope is subject to the definition of the scope of the patent application attached.

100、200...基底100, 200. . . Base

102、202...堆疊結構102, 202. . . Stack structure

104、204...電荷儲存結構104, 204. . . Charge storage structure

106、206...控制閘極106, 206. . . Control gate

108、208...犧牲層108, 208. . . Sacrificial layer

110、210...底介電層110, 210. . . Bottom dielectric layer

112、212...電荷儲存層112, 212. . . Charge storage layer

114、214...頂介電層114,214. . . Top dielectric layer

116、224...圖案化光阻層116, 224. . . Patterned photoresist layer

118、130、226、230...摻雜區118, 130, 226, 230. . . Doped region

120、120a、120b、120c、120d、216...介電層120, 120a, 120b, 120c, 120d, 216. . . Dielectric layer

122、218...導體層122,218. . . Conductor layer

122a、218a...選擇閘極122a, 218a. . . Select gate

122b、218b...虛擬閘極122b, 218b. . . Virtual gate

124、220...間隙壁材料層124, 220. . . Gap material layer

124a、128、220a、228...間隙壁124a, 128, 220a, 228. . . Clearance wall

126、222...凹口126, 222. . . Notch

132、232...金屬矽化物層132, 232. . . Metal telluride layer

134、136...記憶胞134, 136. . . Memory cell

圖1A至圖1E所繪示為本發明之第一實施例的記憶體結構的製造流程剖面圖。1A to 1E are cross-sectional views showing a manufacturing process of a memory structure according to a first embodiment of the present invention.

圖2所繪示為本發明之第二實施例的記憶體結構的剖面圖。2 is a cross-sectional view showing the structure of a memory according to a second embodiment of the present invention.

圖3A至圖3D所繪示為本發明之第三實施例的記憶體結構的製造流程剖面圖。3A to 3D are cross-sectional views showing a manufacturing process of a memory structure according to a third embodiment of the present invention.

100...基底100. . . Base

104...電荷儲存結構104. . . Charge storage structure

106...控制閘極106. . . Control gate

110...底介電層110. . . Bottom dielectric layer

112...電荷儲存層112. . . Charge storage layer

114...頂介電層114. . . Top dielectric layer

118、130...摻雜區118, 130. . . Doped region

120、120a、120b、120c、120d...介電層120, 120a, 120b, 120c, 120d. . . Dielectric layer

122a...選擇閘極122a. . . Select gate

122b...虛擬閘極122b. . . Virtual gate

126...凹口126. . . Notch

128...間隙壁128. . . Clearance wall

132...金屬矽化物層132. . . Metal telluride layer

134...記憶胞134. . . Memory cell

Claims (25)

一種記憶體結構,包括至少一記憶胞,該記憶胞包括:一基底;一電荷儲存結構,設置於該基底上;一控制閘極,設置於該電荷儲存結構上;一選擇閘極,設置於該控制閘極一側的該基底上;一虛擬閘極,設置於該控制閘極另一側的該基底上;一介電層,設置於該選擇閘極與該控制閘極之間、該選擇閘極與該基底之間、該虛擬閘極與該控制閘極之間、及該虛擬閘極與該基底之間;以及兩摻雜區,分別設置於由該控制閘極、該選擇閘極與該虛擬閘極所形成的結構兩側的該基底中,其中該選擇閘極與該虛擬閘極在遠離該控制閘極的一側分別具有一凹口。 A memory structure includes at least one memory cell, the memory cell comprising: a substrate; a charge storage structure disposed on the substrate; a control gate disposed on the charge storage structure; and a selection gate disposed on The control gate is disposed on the substrate on one side of the gate; a dummy gate is disposed on the substrate on the other side of the control gate; a dielectric layer is disposed between the selection gate and the control gate, Selecting a gate and the substrate, between the dummy gate and the control gate, and between the dummy gate and the substrate; and two doped regions respectively disposed by the control gate and the selection gate In the substrate on both sides of the structure formed by the pole and the dummy gate, wherein the selection gate and the dummy gate respectively have a notch on a side away from the control gate. 如申請專利範圍第1項所述之記憶體結構,其中該選擇閘極與該虛擬閘極的形狀分別為L形或L形的鏡像。 The memory structure of claim 1, wherein the shape of the selection gate and the dummy gate are respectively L-shaped or L-shaped. 如申請專利範圍第1項所述之記憶體結構,其中接近該虛擬閘極的該摻雜區更包括延伸至該虛擬閘極下方的該基底中。 The memory structure of claim 1, wherein the doped region adjacent to the dummy gate further comprises a substrate extending below the dummy gate. 如申請專利範圍第1項所述之記憶體結構,更包括一間隙壁,設置於該選擇閘極側壁上與該虛擬閘極側壁上。 The memory structure of claim 1, further comprising a spacer disposed on the sidewall of the select gate and the sidewall of the dummy gate. 如申請專利範圍第1項所述之記憶體結構,更包括一金屬矽化物層,設置於該選擇閘極上、該虛擬閘極上與 該摻雜區上。 The memory structure of claim 1, further comprising a metal telluride layer disposed on the select gate and on the dummy gate On the doped region. 如申請專利範圍第5項所述之記憶體結構,其中該金屬矽化物層更包括設置於該控制閘極上。 The memory structure of claim 5, wherein the metal telluride layer further comprises a gate electrode disposed on the control gate. 如申請專利範圍第1項所述之記憶體結構,其中該電荷儲存結構由該基底起依序包括一底介電層、一電荷儲存層與一頂介電層。 The memory structure of claim 1, wherein the charge storage structure comprises a bottom dielectric layer, a charge storage layer and a top dielectric layer in sequence from the substrate. 如申請專利範圍第1項所述之記憶體結構,其中當記憶體結構包括多個記憶胞時,相鄰兩個記憶胞呈鏡像配置。 The memory structure of claim 1, wherein when the memory structure comprises a plurality of memory cells, the adjacent two memory cells are mirrored. 如申請專利範圍第1項所述之記憶體結構,其中該介電層包括:一第一介電層,設置於該選擇閘極與該控制閘極之間;一第二介電層,設置於該選擇閘極與該基底之間;一第三介電層,設置於該虛擬閘極與該控制閘極之間;以及一第四介電層,設置於該虛擬閘極與該基底之間。 The memory structure of claim 1, wherein the dielectric layer comprises: a first dielectric layer disposed between the selection gate and the control gate; and a second dielectric layer disposed Between the selected gate and the substrate; a third dielectric layer disposed between the dummy gate and the control gate; and a fourth dielectric layer disposed on the dummy gate and the substrate between. 一種記憶體結構的製造方法,包括:於一基底上形成一堆疊結構,且該堆疊結構由該基底起包括一電荷儲存結構、一控制閘極及一犧牲層;於該堆疊結構所暴露的該基底上與該控制閘極側壁上形成一介電層;於該基底上共形地形成覆蓋該堆疊結構的一導體層;於位於該堆疊結構兩側的該導體層上形成一第一間 隙壁,且該第一間隙壁部分覆蓋該導體層;以該第一間隙壁作為罩幕,移除部份該導體層,以於該堆疊結構兩側分別形成一選擇閘極與一虛擬閘極;以及於由該控制閘極、該選擇閘極與該虛擬閘極所形成的結構兩側的該基底中分別形成一摻雜區。 A method of fabricating a memory structure, comprising: forming a stacked structure on a substrate, and the stacked structure comprises a charge storage structure, a control gate and a sacrificial layer from the substrate; the exposed structure is exposed Forming a dielectric layer on the substrate and the sidewall of the control gate; forming a conductor layer covering the stack structure on the substrate; forming a first space on the conductor layer on both sides of the stack structure a gap wall, and the first spacer wall partially covers the conductor layer; the first spacer wall is used as a mask to remove a portion of the conductor layer, so as to form a selection gate and a virtual gate on both sides of the stack structure And forming a doping region in the substrate on both sides of the structure formed by the control gate, the selection gate and the dummy gate. 如申請專利範圍第10項所述之記憶體結構的製造方法,其中該第一間隙壁的形成方法包括:共形地形成覆蓋該導體層的一第一間隙壁材料層;以及對該第一間隙壁材料層進行一回蝕刻製程。 The method of fabricating a memory structure according to claim 10, wherein the method of forming the first spacer comprises: conformally forming a first spacer material layer covering the conductor layer; and the first The spacer material layer is subjected to an etching process. 如申請專利範圍第10項所述之記憶體結構的製造方法,其中接近該虛擬閘極的該摻雜區的形成方法包括:於該基底上形成暴露出該堆疊結構之一側的一圖案化光阻層;以及以該圖案化光阻層作為罩幕,對該基底進行一離子植入製程。 The method of fabricating a memory structure according to claim 10, wherein the forming of the doped region adjacent to the dummy gate comprises: forming a pattern on the substrate exposing a side of the stacked structure a photoresist layer; and using the patterned photoresist layer as a mask to perform an ion implantation process on the substrate. 如申請專利範圍第10項所述之記憶體結構的製造方法,其中接近該選擇閘極的該摻雜區的形成方法包括以該控制閘極、該選擇閘極與該虛擬閘極作為罩幕,對該基底進行一離子植入製程。 The method of fabricating a memory structure according to claim 10, wherein the method of forming the doped region adjacent to the select gate comprises using the control gate, the select gate, and the dummy gate as a mask And performing an ion implantation process on the substrate. 如申請專利範圍第10項所述之記憶體結構的製造方法,其中於形成該選擇閘極與該虛擬閘極之後,更包括移除該犧牲層。 The method of fabricating a memory structure according to claim 10, wherein after the forming the gate and the dummy gate are formed, the sacrificial layer is further removed. 如申請專利範圍第14項所述之記憶體結構的製 造方法,更包括於該控制閘極上、該選擇閘極上、該虛擬閘極上與該些摻雜區上形成一金屬矽化物層。 The system for memory structure as described in claim 14 The method further includes forming a metal telluride layer on the control gate, the select gate, the dummy gate and the doped regions. 如申請專利範圍第10項所述之記憶體結構的製造方法,其中於形成該選擇閘極與該虛擬閘極之後,更包括移除該第一間隙壁。 The method of fabricating a memory structure according to claim 10, wherein after the forming the gate and the dummy gate are formed, the first spacer is further removed. 如申請專利範圍第10項所述之記憶體結構的製造方法,其中於形成該選擇閘極與該虛擬閘極之後,更包括移除部份該介電層,以暴露出部分該基底。 The method of fabricating a memory structure according to claim 10, wherein after forming the select gate and the dummy gate, further comprising removing a portion of the dielectric layer to expose a portion of the substrate. 如申請專利範圍第10項所述之記憶體結構的製造方法,其中於形成該選擇閘極與該虛擬閘極之後,更包括於該選擇閘極的側壁上與該虛擬閘極的側壁上形成一第二間隙壁。 The method of fabricating a memory structure according to claim 10, wherein after forming the selective gate and the dummy gate, further comprising forming on a sidewall of the selective gate and a sidewall of the dummy gate a second spacer. 如申請專利範圍第10項所述之記憶體結構的製造方法,更包括於該選擇閘極上、該虛擬閘極上與該些摻雜區上形成一金屬矽化物層。 The method for fabricating a memory structure according to claim 10, further comprising forming a metal telluride layer on the dummy gate, the dummy gate and the doped regions. 如申請專利範圍第10項所述之記憶體結構的製造方法,其中於形成該選擇閘極與該虛擬閘極之後,更包括移除該虛擬閘極。 The method of fabricating a memory structure according to claim 10, wherein after the forming the gate and the dummy gate are formed, the removing the dummy gate further comprises removing the dummy gate. 如申請專利範圍第20項所述之記憶體結構的製造方法,其中該虛擬閘極的移除方法包括:於該基底上形成暴露出該堆疊結構接近該虛擬閘極之一側的一圖案化光阻層;以及以該圖案化光阻層作為罩幕,移除該虛擬閘極。 The method of fabricating a memory structure according to claim 20, wherein the method of removing the dummy gate comprises: forming a pattern on the substrate exposing a side of the stacked structure close to the virtual gate a photoresist layer; and the patterned photoresist layer is used as a mask to remove the dummy gate. 如申請專利範圍第21項所述之記憶體結構的製 造方法,其中遠離該選擇閘極的該摻雜區的形成方法包括在移除該虛擬閘極之後,以該圖案化光阻層作為罩幕,對該基底進行一離子植入製程。 The system for memory structure as described in claim 21 The method of forming a doped region away from the select gate includes performing an ion implantation process on the substrate after the dummy gate is removed and the patterned photoresist layer is used as a mask. 如申請專利範圍第20項所述之記憶體結構的製造方法,其中接近該選擇閘極的該摻雜區的形成方法包括以該控制閘極與該選擇閘極作為罩幕,對該基底進行一離子植入製程。 The method of fabricating a memory structure according to claim 20, wherein the method of forming the doped region adjacent to the select gate comprises using the control gate and the select gate as a mask to perform the substrate An ion implantation process. 如申請專利範圍第20項所述之記憶體結構的製造方法,其中於移除該虛擬閘極之後,更包括於該控制閘極與該選擇閘極所形成的結構兩側形成一第三間隙壁。 The method for fabricating a memory structure according to claim 20, wherein after the dummy gate is removed, a third gap is formed on both sides of the structure formed by the control gate and the selection gate. wall. 如申請專利範圍第20項所述之記憶體結構的製造方法,其中於移除該虛擬閘極之後,更包括於該選擇閘極上與該些摻雜區上形成一金屬矽化物層。 The method of fabricating a memory structure according to claim 20, wherein after removing the dummy gate, further comprising forming a metal telluride layer on the selected gate and the doped regions.
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