TWI456006B - 光硬化性樹脂組成物、以及使用其之施水構件及功能性面板（二） - Google Patents

光硬化性樹脂組成物、以及使用其之施水構件及功能性面板（二） Download PDF

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TWI456006B
TWI456006B TW101126171A TW101126171A TWI456006B TW I456006 B TWI456006 B TW I456006B TW 101126171 A TW101126171 A TW 101126171A TW 101126171 A TW101126171 A TW 101126171A TW I456006 B TWI456006 B TW I456006B
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resin composition
photocurable resin
meth
isocyanate
group
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TW201317304A (zh
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Takenobu Ishihara
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Bridgestone Corp
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    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
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    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
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    • C08F290/068—Polysiloxanes
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    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
    • C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
    • C08F299/06—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polyurethanes
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
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    • C08G18/40—High-molecular-weight compounds
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/61—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/73—Polyisocyanates or polyisothiocyanates acyclic
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    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
    • C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
    • C08G18/753—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
    • C08G18/755—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
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    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
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    • C08G77/38—Polysiloxanes modified by chemical after-treatment
    • C08G77/382—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon
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    • C09D175/04—Polyurethanes
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    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
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    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
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    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
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    • C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
    • C08G77/16—Polysiloxanes containing silicon bound to oxygen-containing groups to hydroxyl groups
    • E—FIXED CONSTRUCTIONS
    • E03—WATER SUPPLY; SEWERAGE
    • E03C—DOMESTIC PLUMBING INSTALLATIONS FOR FRESH WATER OR WASTE WATER; SINKS
    • E03C1/00—Domestic plumbing installations for fresh water or waste water; Sinks
    • E03C1/12—Plumbing installations for waste water; Basins or fountains connected thereto; Sinks
    • E03C1/18—Sinks, whether or not connected to the waste-pipe

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Polyurethanes Or Polyureas (AREA)
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Claims (11)

  1. 一種光硬化性樹脂組成物，其包含有：(A)二甲基聚矽氧烷(甲基)丙烯酸酯低聚物，係使(a)以下述通式(1)所表示之聚矽氧烷多元醇、(b)異氰酸酯、及(c)末端具有可與異氰酸酯反應的官能基之(甲基)丙烯酸酯單體進行反應所獲得； 其中，前述通式(1)中，n係表示使該(A)二甲基聚矽氧烷(甲基)丙烯酸酯低聚物的數量平均分子量成為700~40000之任意選擇的整數，R係表示總碳數1~30的烷撐基，或具有醚鍵之總碳數1~30的官能基；(B)光聚合性低聚物及/或(C)光聚合性單體，其可與該(A)二甲基聚矽氧烷(甲基)丙烯酸酯低聚物共聚合；(D)含氟化合物；以及(E)光聚合引發劑；該(A)二甲基聚矽氧烷(甲基)丙烯酸酯低聚物的含量相對於該(B)光聚合性低聚物及/或(C)光聚合性單體的合計為0.05質量%~10質量%；該(B)光聚合性低聚物為具有1,2-聚環氧丁烷 單元之(甲基)丙烯酸酯低聚物。
  2. 如申請專利範圍第1項之光硬化性樹脂組成物，其中該(b)異氰酸酯中之異氰酸酯基與該(a)以通式(1)所表示之聚矽氧烷多元醇中之羥基的當量比(異氰酸酯基/羥基)係大於100/100但300/100以下。
  3. 如申請專利範圍第1或2項之光硬化性樹脂組成物，其中該(C)光聚合性單體的溶解性參數(SP值)為20.0(J/cm3 )1/2 以下。
  4. 如申請專利範圍第1項之光硬化性樹脂組成物，其中該(C)光聚合性單體為以下述通式(A)所表示之化合物：(CH2 =CR1 COO)n R2 ．．．通式(A)其中，前述通式(A)中，R1 係表示氫原子或甲烷基，R2 係表示碳數5~20的n價烴基，n係表示1~4範圍內的整數。
  5. 如申請專利範圍第1項之光硬化性樹脂組成物，其中該(b)異氰酸酯為分子構造中具有環狀骨架之聚異氰酸酯化合物。
  6. 如申請專利範圍第1項之光硬化性樹脂組成物，其中該(c)(甲基)丙烯酸酯單體中之可與異氰酸酯基反應的官能基為羥基。
  7. 如申請專利範圍第1項之光硬化性樹脂組成物，其中該(D)含氟化合物係具有光聚合性的官能基。
  8. 如申請專利範圍第1項之光硬化性樹脂組成物，其 中該(A)二甲基聚矽氧烷(甲基)丙烯酸酯低聚物的固形分含量相對於該(D)含氟化合物的固形分含量之比(A/D)為0.2~10。
  9. 如申請專利範圍第8項之光硬化性樹脂組成物，其中該(A)二甲基聚矽氧烷(甲基)丙烯酸酯低聚物的固形分含量相對於該(D)含氟化合物的固形分含量之比(A/D)為0.4~3。
  10. 一種施水構件，其具有：塗佈層，係使如申請專利範圍第1至9項中任一項之光硬化性樹脂組成物硬化而形成；以及基材層。
  11. 一種功能性面板，其具有：塗佈層，係使如申請專利範圍第1至9項中任一項之光硬化性樹脂組成物硬化而形成；以及基材層。
TW101126171A 2011-07-19 2012-07-19 光硬化性樹脂組成物、以及使用其之施水構件及功能性面板（二） TWI456006B (zh)

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JP6077792B2 (ja) * 2012-08-28 2017-02-08 株式会社ブリヂストン 硬化性樹脂組成物を硬化させてなる硬化層を少なくとも表面に有する部材
CN105733434B (zh) * 2014-12-26 2019-09-24 中国涂料株式会社 光固化性树脂组合物、及固化膜、带膜基材及其制造方法
US20210163668A1 (en) * 2018-04-12 2021-06-03 Basf Se Electroactive polymers
CN110606932A (zh) * 2019-10-28 2019-12-24 广东昊辉新材料有限公司 一种光固化聚氨酯丙烯酸酯水分散体及其制备方法
CN111057203B (zh) * 2019-12-31 2022-03-22 北京松井工程技术研究院有限公司 硅氟聚氨酯丙烯酸树脂及其制备方法与应用

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JP2010111800A (ja) * 2008-11-07 2010-05-20 Dh Material Kk 被膜形成用ラジカル重合性樹脂組成物

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