TWI452691B - Semiconductor structure and method for making the same, and method for forming epitaxial semi-finished product - Google Patents
Semiconductor structure and method for making the same, and method for forming epitaxial semi-finished product Download PDFInfo
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本發明是有關於一種半導體結構及其製作方法,特別是指一種半導體結構及其製作方法和磊晶半成品的製作方法。The present invention relates to a semiconductor structure and a method of fabricating the same, and more particularly to a semiconductor structure, a method of fabricating the same, and a method of fabricating an epitaxial semi-finished product.
參閱圖1,為傳統的具有光伏特特性的磊晶元件,包括一由砷化鎵(GaAs)為主要材質所構成且易於磊晶成長薄膜的磊晶用基板111、一以磊晶的方式形成於該磊晶用基板111上的磊晶膜112,及一形成於該磊晶膜112部份頂面的電極113,該電極113可將外界提供的電能傳送至該磊晶膜112,使其產生電能轉換為光能或是光能轉換為電能的作用模式。Referring to FIG. 1 , a conventional epitaxial device having photovoltaic characteristics includes an epitaxial substrate 111 composed of gallium arsenide (GaAs) as a main material and which is easy to epitaxially grow a thin film, and is formed by epitaxy. An epitaxial film 112 on the epitaxial substrate 111, and an electrode 113 formed on a top surface of the epitaxial film 112, the electrode 113 can transfer externally supplied electric energy to the epitaxial film 112. The mode of action of converting electrical energy into light energy or converting light energy into electrical energy.
以作為太陽能電池為例,光由遠離該磊晶用基板111的磊晶膜112的頂面吸收,並在該磊晶膜112產生光電效應而將光能轉換為電能。由於在光電轉換的過程中該磊晶元件需要該磊晶膜112盡量吸收光能、傳送電能,該磊晶用基板111散逸廢熱能,因此,該磊晶元件的磊晶用基板111需具備將穿透該磊晶膜112而到達該磊晶用基板111的光反射至該磊晶膜112而供該磊晶膜112吸收,及供多餘熱量散逸的特性;以現實狀態而言,該以砷化鎵(GaAs)製成的磊晶用基板111雖然易於供該磊晶膜112成長,卻是不易於散熱的材質。For example, as a solar cell, light is absorbed by the top surface of the epitaxial film 112 away from the epitaxial substrate 111, and a photoelectric effect is generated in the epitaxial film 112 to convert light energy into electric energy. Since the epitaxial film 112 needs to absorb light energy and transmit electric energy as much as possible in the process of photoelectric conversion, the epitaxial substrate 111 dissipates waste heat energy. Therefore, the epitaxial substrate 111 of the epitaxial element needs to have The light that has penetrated the epitaxial film 112 and reaches the epitaxial substrate 111 is reflected to the epitaxial film 112 for absorption by the epitaxial film 112, and the excess heat is dissipated; in reality, the arsenic is used. Although the epitaxial substrate 111 made of gallium (GaAs) is easily grown by the epitaxial film 112, it is a material that does not easily dissipate heat.
參閱圖2,因此,目前的磊晶元件多是將該磊晶膜112與該磊晶用基板111分離並再與一永久基板121連結。目前的磊晶元件包括該以具有散熱效果的材質所組成的永久基板121、一形成於該永久基板121上的磊晶膜122、一夾設於該永久基板121及該磊晶膜122間,使兩者緊密貼合的高分子膠123,及一形成於該磊晶膜122部份裸露表面且可傳送電能至外界的電極124。Referring to FIG. 2 , the current epitaxial film is mostly separated from the epitaxial substrate 111 and connected to a permanent substrate 121 . The current epitaxial element includes a permanent substrate 121 composed of a material having a heat dissipation effect, an epitaxial film 122 formed on the permanent substrate 121, and a sandwich between the permanent substrate 121 and the epitaxial film 122. The polymer glue 123 which closely bonds the two, and an electrode 124 formed on a part of the exposed surface of the epitaxial film 122 and capable of transmitting electric energy to the outside.
光自該磊晶膜122頂面照射,部份的光直接由該磊晶膜122吸收,部份的光穿過該磊晶膜122往該高分子膠123及該永久基板121行進,並利用高分子膠123與磊晶膜122間的折射率差形成全反射效果,將光反射至該磊晶膜122,其餘的光則藉由該永久基板121的反射而由該磊晶膜122吸收。然,由於高分子膠123的折射率易受溫度及溼度等外在環境因素的影響而不穩定,使得透過該高分子膠123的光全反射效果不穩定,且高分子膠123為不良導熱材質,即使該永久基板121是以散熱效果佳的材質所組成,該磊晶膜122的熱亦無法有效經由該高分子膠123傳送至該永久基板121以達到預計的散熱效果。The light is irradiated from the top surface of the epitaxial film 122, and part of the light is directly absorbed by the epitaxial film 122, and part of the light passes through the epitaxial film 122 to the polymer gel 123 and the permanent substrate 121, and is utilized. The difference in refractive index between the polymer paste 123 and the epitaxial film 122 forms a total reflection effect, and the light is reflected to the epitaxial film 122, and the remaining light is absorbed by the epitaxial film 122 by the reflection of the permanent substrate 121. However, since the refractive index of the polymer gel 123 is easily affected by external environmental factors such as temperature and humidity, the total light reflection effect through the polymer gel 123 is unstable, and the polymer gel 123 is a poor heat conductive material. Even if the permanent substrate 121 is composed of a material having good heat dissipation effect, the heat of the epitaxial film 122 cannot be efficiently transmitted to the permanent substrate 121 via the polymer gel 123 to achieve a desired heat dissipation effect.
本發明者為解決連結該永久基板121及該磊晶膜122的高分子膠散熱效果差及易受環境影響特性的問題,發展出一不需高分子膠即可製得的磊晶元件。The inventors of the present invention have developed an epitaxial element which can be obtained without a polymer glue in order to solve the problem of poor heat dissipation and high environmental resistance of the polymer paste connecting the permanent substrate 121 and the epitaxial film 122.
參閱圖3,該磊晶元件包含一磊晶膜131、一直接形成於該磊晶膜131底面且以金屬為主要材質而具有散熱效果的永久基板132,及一形成於該磊晶膜131頂面的電極133。Referring to FIG. 3, the epitaxial element includes an epitaxial film 131, a permanent substrate 132 directly formed on the bottom surface of the epitaxial film 131 and having a heat dissipation effect on a metal as a main material, and a top surface formed on the epitaxial film 131. Surface electrode 133.
參閱圖4、圖5,上述該磊晶元件的製作流程是先準備一磊晶用基板134,再以磊晶的方式於該磊晶用基板134上依序形成一作為後續製程中蝕刻犧牲用的第二層體135,及一可產生光電轉換效應的第一層體136,其中,該第二層體135與該第一層體136間的蝕刻速率比例高。繼續於該第一層體136頂面以例如濺鍍或熱蒸鍍方式形成一覆蓋該第一層體136的部份頂面,且具有複數間隔地成整齊排列而定義出每一磊晶元件的磊晶膜131之底著區塊138的底著層137,並蝕刻裸露於該底著層137外的第一層體136,而成為如圖4及圖5所示的半導體結構。配合參閱圖3,然後以該底著層137作為種子(seed)向上電鍍增厚為複數間隔且分別形成於該第一層體136頂面且定義為磊晶膜131的區域,而成為永久基板132。Referring to FIG. 4 and FIG. 5, the epitaxial element is prepared by first preparing an epitaxial substrate 134, and then sequentially forming an epitaxial substrate on the epitaxial substrate 134 for etching in a subsequent process. The second layer body 135, and a first layer body 136 which can produce a photoelectric conversion effect, wherein the etching rate ratio between the second layer body 135 and the first layer body 136 is high. Continuing on the top surface of the first layer body 136, a top surface covering a portion of the first layer body 136 is formed by, for example, sputtering or thermal evaporation, and is arranged in a plurality of intervals to define each epitaxial element. The epitaxial film 131 is bottomed on the bottom layer 137 of the block 138, and the first layer body 136 exposed outside the underlying layer 137 is etched to become a semiconductor structure as shown in FIGS. 4 and 5. Referring to FIG. 3, the underlying layer 137 is used as a seed to be plated up to a plurality of spaces and formed on the top surface of the first layer body 136 and defined as the epitaxial film 131, thereby becoming a permanent substrate. 132.
接著以濕蝕刻的方式將該第二層體135蝕刻完全,該磊晶用基板134與該第一層體136分離,此時,該第一層體136形成的磊晶膜131,及以該底著層137經電鍍增厚形成的永久基板132構成複數獨立的磊晶半成品(圖未示)。為不遺漏地聚集該等磊晶半成品,在蝕刻該第二層體135前先在該永久基板132的頂面黏貼一張藍膠(blue tape)以固定每一個磊晶半成品。Then, the second layer body 135 is completely etched by wet etching, and the epitaxial substrate 134 is separated from the first layer body 136. At this time, the epitaxial film 131 formed by the first layer body 136, and The permanent substrate 132 formed by the plating of the underlayer 137 is formed into a plurality of independent epitaxial semi-finished products (not shown). In order to gather the epitaxial semi-finished products without fail, a blue tape is adhered to the top surface of the permanent substrate 132 to etch each epitaxial semi-finished product before etching the second layer body 135.
最後,移除該等磊晶半成品的永久基板132頂面的藍膠,再於該磊晶膜131頂面形成一電極133,而製成如圖3所示的磊晶元件。即,目前的磊晶元件多是先將該磊晶膜131與該磊晶用基板134分離,再與該永久基板132連結。Finally, the blue gel on the top surface of the permanent substrate 132 of the epitaxial semi-finished product is removed, and an electrode 133 is formed on the top surface of the epitaxial film 131 to form an epitaxial element as shown in FIG. That is, in many conventional epitaxial elements, the epitaxial film 131 is separated from the epitaxial substrate 134 and then connected to the permanent substrate 132.
若以上述方式製作出的磊晶元件是處於理想狀態,則由於在製作過程中的半導體結構中的底著層137是具散熱特性的金屬材質,且形成該永久基板132時是以電鍍的方式直接增厚該底著層137,而不需另外再以高分子膠黏著於該磊晶膜131再另外固定傳統的永久基板132,確實可減少高分子膠不易散熱而造成該磊晶元件廢熱能無法散逸的瓶頸。If the epitaxial element fabricated in the above manner is in an ideal state, the underlying layer 137 in the semiconductor structure during fabrication is a metal material having heat dissipation characteristics, and the permanent substrate 132 is formed by electroplating. The underlying layer 137 is directly thickened, and the conventional permanent substrate 132 is additionally fixed by polymer bonding to the epitaxial film 131, which can reduce the heat dissipation of the polymer paste and cause waste heat energy of the epitaxial element. The bottleneck that cannot be dissipated.
但發明人發現,在實際的製程中在形成該半導體結構時,該底著層137的底著區塊138是獨立地形成於該第一層體136頂面,無論是僅有該底著層137的狀態或是已將該底著層137增厚成為永久基板132,都易由於施力不平均,或間隔的底著區塊138與該磊晶膜131間的貼附性不佳而自該等底著區塊138(或永久基板132)的周圍開始變形且翹曲。因此,以該半導體結構製作出的磊晶元件,易由於該永久基板132與該磊晶膜131間貼合不完整,導致整體元件良率不高,且該磊晶元件在作動時積存於該磊晶膜131的廢熱也難以自該永久基板132散逸,降低該永久基板132散熱的效果,導致該磊晶元件可靠度及使用壽命降低。However, the inventors have found that the underlying block 138 of the underlying layer 137 is independently formed on the top surface of the first layer body 136 when forming the semiconductor structure in an actual process, regardless of the underlying layer. The state of 137 or the thickening of the underlayer 137 to the permanent substrate 132 is easy due to uneven application of force, or poor adhesion between the spacers 138 and the epitaxial film 131. The periphery of the bottom block 138 (or permanent substrate 132) begins to deform and warp. Therefore, the epitaxial element fabricated by the semiconductor structure is susceptible to incomplete bonding between the permanent substrate 132 and the epitaxial film 131, resulting in an overall component yield being low, and the epitaxial element is accumulated in the operation. The waste heat of the epitaxial film 131 is also difficult to dissipate from the permanent substrate 132, thereby reducing the heat dissipation effect of the permanent substrate 132, resulting in a decrease in reliability and service life of the epitaxial element.
此外,利用藍膠固定每一個獨立的磊晶半成品,再於形成電極133前撕除該藍膠,也造成耗材資源的浪費,且貼覆及移除藍膠亦增加製程時間(cycle time)。In addition, the use of blue glue to fix each of the individual epitaxial semi-finished products, and then to remove the blue gel before forming the electrode 133, also causes waste of consumable resources, and the attachment and removal of the blue glue also increases the cycle time.
因此,本發明之一目的,即在提供一種在製程中底著層不翹曲而提升磊晶元件良率的半導體結構的製作方法。Accordingly, it is an object of the present invention to provide a method of fabricating a semiconductor structure that enhances the yield of the epitaxial element without warping the underlayer during the process.
其次,本發明之另一目的,即在提供一種具有底著層不翹曲而提升磊晶元件良率的半導體結構。Secondly, another object of the present invention is to provide a semiconductor structure having a bottom layer that does not warp and which enhances the yield of the epitaxial element.
再者,本發明之另一目的,即在提供一種提升良率的磊晶半成品的製作方法。Furthermore, another object of the present invention is to provide a method for fabricating an epitaxial semi-finished product with improved yield.
於是,本發明半導體結構的製作方法包含一磊晶用基板準備步驟、一磊晶層單元形成步驟,及一底著層形成步驟。Therefore, the method for fabricating the semiconductor structure of the present invention comprises an epitaxial substrate preparation step, an epitaxial layer unit forming step, and a bottom layer forming step.
該磊晶用基板準備步驟為準備一磊晶用基板。The substrate preparation step for epitaxy is to prepare an epitaxial substrate.
該磊晶層單元形成步驟是磊晶一第一層體於該磊晶用基板上而形成一磊晶層單元。The epitaxial layer unit forming step is to form an epitaxial layer unit by epitaxial-first layer body on the epitaxial substrate.
該底著層形成步驟是於該第一層體上形成一定義複數蝕刻道圖案的底著層,該底著層包括複數彼此間隔且規則排列的底著區,及複數連接區,每一連接區連接彼此相鄰的底著區的角隅,該磊晶層單元頂面和該底著層的底著區與連接區共同界定出複數預定分割該磊晶層單元成多數分別對應於該等底著區之磊晶膜的蝕刻道。The underlayer forming step is to form an underlayer on the first layer body defining a plurality of etched trace patterns, the underlayer comprising a plurality of bottom regions spaced apart from each other and regularly arranged, and a plurality of connection regions, each connection a region connecting corners of the adjacent regions adjacent to each other, the top surface of the epitaxial layer unit and the bottom region of the underlying layer and the connection region collectively defining a plurality of predetermined divisions of the epitaxial layer unit to correspond to the plurality The etching channel of the epitaxial film of the bottom region.
此外,本發明半導體結構包含一磊晶用基板,及一主體。In addition, the semiconductor structure of the present invention comprises a substrate for epitaxy, and a body.
該主體包括一磊晶層單元,及一底著層,該磊晶層單元具有一自該磊晶用基板向上形成的第一層體,該底著層形成於該第一層體頂面,且包括複數彼此間隔且規則排列的底著區,及複數連接區,每一連接區連接彼此相鄰的底著區的角隅,該磊晶層單元頂面和該底著層的底著區與連接區共同界定出複數預定分割該磊晶層單元成多數分別對應於該等底著區之磊晶膜的蝕刻道。The main body includes an epitaxial layer unit and a bottom layer, the epitaxial layer unit has a first layer body formed upward from the epitaxial substrate, and the bottom layer is formed on the top surface of the first layer body. And comprising a plurality of spaced apart and regularly arranged bottom regions, and a plurality of connecting regions, each connecting region connecting corners of adjacent bottom regions, the top surface of the epitaxial layer unit and the bottom region of the bottom layer Cooperating with the connection region defines a plurality of etched tracks which are predetermined to divide the epitaxial layer unit into a plurality of epitaxial films respectively corresponding to the underlying regions.
最後,本發明磊晶半成品的製作方法包含一半導體結構製程,及一成型分離製程。Finally, the method for fabricating the epitaxial semi-finished product of the present invention comprises a semiconductor structure process and a molding separation process.
該半導體結構製程包括一準備一磊晶用基板的磊晶用基板準備步驟,及一磊晶層單元形成步驟,其中,該磊晶用基板準備步驟是準備一磊晶用基板,該磊晶層單元形成步驟依序於該磊晶用基板磊晶一第二層體及一第一層體於該磊晶用基板上而形成一磊晶層單元,該底著層形成步驟是於該第一層體上形成一定義複數蝕刻道圖案的底著層,該底著層包括複數彼此間隔且規則排列的底著區,及複數連接區,每一連接區連接彼此相鄰的底著區的角隅,該磊晶層單元頂面和該底著層的底著區與連接區共同界定出複數預定分割該磊晶層單元成多數分別對應於該等底著區之磊晶膜的蝕刻道。The semiconductor structure process includes an epitaxial substrate preparation step for preparing an epitaxial substrate, and an epitaxial layer unit forming step, wherein the epitaxial substrate preparation step is to prepare an epitaxial substrate, the epitaxial layer The unit forming step sequentially forms a second layer body and a first layer body on the epitaxial substrate to form an epitaxial layer unit, and the underlayer forming step is the first Forming an underlayer on the layer body defining a plurality of etched trace patterns, the underlayer comprising a plurality of bottom regions spaced apart from each other and regularly arranged, and a plurality of connection regions, each of the connection regions connecting the corners of the adjacent regions adjacent to each other The top surface of the epitaxial layer unit and the bottom region of the underlying layer and the connection region together define a plurality of etched tracks that are predetermined to divide the epitaxial layer unit into a plurality of epitaxial films respectively corresponding to the underlying regions.
該成型分離製程包括一蝕刻加強道形成步驟、一電鍍增厚層形成步驟,及一磊晶用基板分離步驟,其中,該蝕刻加強道形成步驟是移除該半導體結構對應裸露於該底著層外的第一層體結構,而使未被移除的該底著層下的第一層體結構、該第二層體頂面,及該底著層的底著區與連接區共同界定出一預定分割該磊晶層單元成多數分別對應於該等底著區之磊晶膜的蝕刻加強道,該蝕刻加強道的深度大於該蝕刻道,該電鍍增厚層形成步驟於該底著層頂面形成一具備導熱特性的電鍍增厚層,該磊晶用基板分離步驟是移除該第二層體,使該磊晶用晶板與該磊晶層單元的第一層體分離,製得多數磊晶半成品。The molding separation process includes an etching enhancement track forming step, an electroplating thickening layer forming step, and an epitaxial substrate separating step, wherein the etching reinforcing track forming step is to remove the semiconductor structure correspondingly exposed to the underlying layer An outer first layer structure, wherein the first layer structure under the underlayer that is not removed, the top surface of the second layer, and the bottom region of the bottom layer are jointly defined with the connection region a predetermined step of dividing the epitaxial layer unit into an etch enhancement track respectively corresponding to the epitaxial films of the underlying regions, the etching enhancement track having a depth greater than the etching track, the plating thickening layer forming step of the underlying layer Forming a plating thickening layer having a thermal conductive property, the substrate separating step of the epitaxial layer is to remove the second layer body, and separating the epitaxial crystal plate from the first layer body of the epitaxial layer unit. Most of the epitaxial semi-finished products.
本發明之功效:利用該底著層的連接區牽制該底著層相鄰的底著區的角隅,避免該等角隅翹曲,且平整地貼附於該磊晶層單元的底著層,以提高半導體結構形成的磊晶元件的散熱效果及良率。The effect of the invention is that the corner joint of the bottom layer adjacent to the bottom layer is pinned by the connecting layer of the bottom layer to avoid the warp of the isosceles, and is attached to the bottom of the epitaxial layer flatly The layer is used to improve the heat dissipation effect and yield of the epitaxial element formed by the semiconductor structure.
有關本發明之前述及其他技術內容、特點與功效,在以下配合參考圖式之一個較佳實施例的詳細說明中,將可清楚的呈現。The above and other technical contents, features and advantages of the present invention will be apparent from the following detailed description of the preferred embodiments.
在本發明被詳細描述之前,要注意的是,在以下的說明內容中,類似的元件是以相同的編號來表示。Before the present invention is described in detail, it is noted that in the following description, similar elements are denoted by the same reference numerals.
參閱圖3、圖6,及圖7,本發明磊晶半成品的製作方法的一較佳實施例依序包含一半導體結構製程21,及一成型分離製程22,其中,該半導體結構製程21依序包括一磊晶用基板準備步驟211、一磊晶層單元形成步驟212,及一底著層形成步驟213,而先製作出如圖7所示的半導體結構3,該成型分離製程22依序包含一蝕刻加強道形成步驟221、一電鍍增厚層形成步驟222,及一磊晶用基板分離步驟223,而製作出如圖13所示的磊晶半成品4,之後,再配合對該磊晶半成品4實施一分割及形成電極23的步驟,即可製作出如圖3所示的磊晶元件,而可解決目前製作磊晶元件時會發生的永久基板的底著層翹曲導致良率及散熱效果不佳的問題。Referring to FIG. 3, FIG. 6, and FIG. 7, a preferred embodiment of the method for fabricating an epitaxial semi-finished product of the present invention sequentially includes a semiconductor structure process 21 and a molding and separation process 22, wherein the semiconductor structure process 21 is sequentially followed. An epitaxial substrate preparation step 211, an epitaxial layer unit formation step 212, and an underlayer formation step 213 are performed, and the semiconductor structure 3 as shown in FIG. 7 is first formed, and the molding separation process 22 is sequentially included. An etching enhancement track forming step 221, an electroplating thickening layer forming step 222, and an epitaxial substrate separating step 223, to produce an epitaxial semi-finished product 4 as shown in FIG. 13, and then cooperating with the epitaxial semi-finished product 4 performing a step of dividing and forming the electrode 23, thereby forming an epitaxial element as shown in FIG. 3, which can solve the underlying layer warpage of the permanent substrate which occurs when the epitaxial element is currently produced, resulting in yield and heat dissipation. Poor effect.
參閱圖6、圖8,實施該半導體結構製程21時先進行該磊晶用基板準備步驟211,準備一以砷化鎵(GaAs)為主要材料所構成的磊晶用基板31。Referring to FIGS. 6 and 8, when the semiconductor structure process 21 is performed, the epitaxial substrate preparation step 211 is performed to prepare an epitaxial substrate 31 made of gallium arsenide (GaAs) as a main material.
接著進行該磊晶層單元形成步驟212,於該磊晶用基板31上以磊晶的方式依序形成一第二層體324,及一第一層體323,該第一、二層體323、324共同界定為一磊晶層單元321,該第二層體324與該第一層體323間的蝕刻選擇速率比例高;以氫氟酸(HF)作為蝕刻液為例,該第二層體324的蝕刻速率遠較該第一層體323的蝕刻速率為大。Then, the epitaxial layer unit forming step 212 is performed, and a second layer body 324 is sequentially formed on the epitaxial substrate 31 in an epitaxial manner, and a first layer body 323, the first layer and the second layer body 323. 324 is collectively defined as an epitaxial layer unit 321, and the ratio of etching selectivity between the second layer body 324 and the first layer body 323 is high; taking hydrofluoric acid (HF) as an etching liquid as an example, the second layer The etching rate of the body 324 is much larger than the etching rate of the first layer body 323.
參閱圖6、圖7,繼續進行該底著層形成步驟213,先利用沈積的方式於該第一層體323的頂面形成一底著準備層(圖未示),再經由黃光微影製程於該底著準備層頂面定義出欲形成該底著層325的區域,接著移除該底著準備層的部份區域而成為一底著層325,而製得該半導體結構3。Referring to FIG. 6 and FIG. 7 , the bottom layer forming step 213 is continued. First, a bottom preparation layer (not shown) is formed on the top surface of the first layer body 323 by deposition, and then processed by a yellow light lithography process. The bottom surface of the preparation layer defines a region where the underlayer 325 is to be formed, and then a portion of the underlying layer is removed to form a primer layer 325, thereby fabricating the semiconductor structure 3.
參閱圖7,該半導體結構的底著層325具有複數規則排列地形成於該第一層體323頂面且為正方形的底著區327,及複數連接區328,每一連接區328具有一基部329及四延伸部330。該基部329位於四相鄰底著區327的中央,每一連接區328的四延伸部330分別連接四相鄰底著區327的角隅,且相鄰的兩延伸部330呈一垂直的預定夾設角度,此時,該裸露於該底著層325外的第一層體323的頂面、該等底著區327,及該等連接區328界定複數蝕刻道33,該等蝕刻道33預定分割該第一層體323成為多數分別對應該等底著區327的磊晶膜131(圖3)。Referring to FIG. 7, the underlying layer 325 of the semiconductor structure has a plurality of regularly arranged base regions 327 formed on the top surface of the first layer body 323 and having a square shape, and a plurality of connection regions 328 each having a base portion 329 and four extensions 330. The base portion 329 is located at the center of the four adjacent bottom regions 327, and the four extension portions 330 of each of the connection regions 328 are respectively connected to the corners of the four adjacent bottom regions 327, and the adjacent two extending portions 330 are vertically predetermined. The angle is sandwiched. At this time, the top surface of the first layer body 323 exposed outside the bottom layer 325, the bottom regions 327, and the connection regions 328 define a plurality of etching tracks 33. The first layer body 323 is predetermined to be divided into a plurality of epitaxial films 131 (Fig. 3) respectively corresponding to the underlying regions 327.
此時製得的半導體結構3包含一磊晶用基板31,及一形成於該磊晶用基板31上的主體32。The semiconductor structure 3 obtained at this time includes an epitaxial substrate 31 and a main body 32 formed on the epitaxial substrate 31.
該磊晶用基板31是以砷化鎵(GaAs)為主要材料所構成,半導體材料可於該磊晶用基板31上以磊晶的方式形成薄膜,薄膜與該磊晶用基板31間晶格匹配、平整,且品質良好。The epitaxial substrate 31 is made of gallium arsenide (GaAs) as a main material, and a semiconductor material can be epitaxially formed on the epitaxial substrate 31, and a thin film is formed between the thin film and the epitaxial substrate 31. Matching, leveling, and good quality.
該主體32包括一磊晶層單元321及一底著層325。該磊晶層單元321具有一形成於該磊晶用基板31上的第二層體324,及一以磊晶的方式形成於該第二層體324上的第一層體323,該第一層體323以砷化鎵系化合物為主要材料所構成,且具有將光能轉換為電能,及將電能轉換為光能釋出的光電半導體特性。該第二層體324與該第一層體323間的蝕刻選擇速率比例高,即,該第二層體324對於蝕刻液的蝕刻速率遠大於該第一層體323對於蝕刻液的蝕刻速率。The body 32 includes an epitaxial layer unit 321 and a bottom layer 325. The epitaxial layer unit 321 has a second layer body 324 formed on the epitaxial substrate 31, and a first layer body 323 formed on the second layer body 324 in an epitaxial manner. The layer body 323 is composed of a gallium arsenide compound as a main material, and has photoelectric semiconductor characteristics in which light energy is converted into electric energy and electric energy is converted into light energy. The ratio of the etching selectivity between the second layer body 324 and the first layer body 323 is high, that is, the etching rate of the second layer body 324 for the etching liquid is much larger than the etching rate of the first layer body 323 for the etching liquid.
藉由該第二層體324與該第一層體323的高蝕刻選擇比例,將該第二層體324作為犧牲層體並移除而可使該第一層體323與該磊晶用基板31完全分離。The first layer body 323 and the epitaxial substrate can be removed by removing the second layer body 324 as a sacrificial layer by the high etching selectivity of the second layer body 324 and the first layer body 323. 31 completely separated.
該底著層325形成於該第一層體323上,且主要製作材料為金屬並具有散熱特性,該底著層325具有複數彼此間隔地呈規則排列,且為正方形的底著區327,及複數連接區328。該等底著區327間的距離相等,每一連接區328具有一位於四相鄰底著區327幾何中心的基部329,及四分別連接四相鄰底著區327的角隅的延伸部330,由於該等底著區327間的距離相等,且該基部329位於該等底著區327的幾何中心,故該等延伸部330皆等長,每一底著區327的兩兩延伸部330間夾設一成90°的預定夾設角度。The underlayer 325 is formed on the first layer body 323, and is mainly made of metal and has heat dissipation characteristics. The underlayer 325 has a plurality of bottom regions 327 which are regularly arranged at intervals and are square, and A plurality of connection areas 328. The distance between the base regions 327 is equal. Each of the joint regions 328 has a base 329 at the geometric center of the four adjacent base regions 327, and four extension portions 330 respectively connecting the corners of the four adjacent base regions 327. Since the distances between the base regions 327 are equal, and the base portion 329 is located at the geometric center of the base regions 327, the extension portions 330 are all equal in length, and the two extension portions 330 of each of the bottom regions 327 are A predetermined clamping angle of 90° is interposed.
該磊晶層單元321的第一層體323頂面與該底著層325的底著區327及連接區328相配合界定複數蝕刻道33,該等蝕刻道33將該磊晶層單元321的第一層體323預定分割為多數個對應於該底著區327的磊晶膜131(如圖3)。由於每一連接區328藉由兩兩成垂直的延伸部330連接該等相鄰的底著區327,故所界定出的蝕刻道33為成對稱的六邊形。The top surface of the first layer body 323 of the epitaxial layer unit 321 cooperates with the bottom region 327 and the connection region 328 of the underlying layer 325 to define a plurality of etching tracks 33, and the etching channels 33 of the epitaxial layer unit 321 The first layer body 323 is predetermined to be divided into a plurality of epitaxial films 131 corresponding to the underlying regions 327 (Fig. 3). Since each of the connection regions 328 connects the adjacent bottom regions 327 by two or two vertical extensions 330, the defined etching lanes 33 are symmetrical hexagons.
此外,該底著層325的連接區328利用延伸部330連接彼此相鄰的底著區327的角隅,使形成於該第一層體323上的底著區327藉由該延伸部330及固定於相鄰四底著區327間的基部329形成可對稱地牽制該等底著區327的角隅避免往遠離該第一層體323的方向翹曲的力量,達到該磊晶層單元321與該底著層325間連結的密合度為較佳的功效。In addition, the connecting portion 328 of the bottom layer 325 is connected to the corners of the adjacent bottom regions 327 by the extending portion 330, so that the bottom portion 327 formed on the first layer body 323 is formed by the extending portion 330 and The base 329 fixed between the adjacent four bottom regions 327 forms a corner that can symmetrically pin the corners of the base regions 327 to avoid warping away from the first layer body 323 to reach the epitaxial layer unit 321 The degree of adhesion to the underlayer 325 is a preferred effect.
要說明的是,視欲形成的磊晶元件的技術而定,該磊晶層單元321可包括複數第一層體323,且此處非為本發明的重點,故僅以第一層體323總括之。It should be noted that, depending on the technology of the epitaxial element to be formed, the epitaxial layer unit 321 may include a plurality of first layer bodies 323, and is not the focus of the present invention here, so only the first layer body 323 is used. In summary.
參閱圖9,再特別說明的是,該等底著區327也可為矩形,且每一矩形間的距離相等,則該連接彼此相鄰的底著區327角隅的延伸部330可為等長且對稱,且兩兩相鄰的延伸部330夾一預定夾設角度,使該等蝕刻道33為六邊形,且該連接區328的延伸部330及基部329具有且該連接區328的延伸部330及基部329具有可避免底著區327的角隅翹曲的牽制力量。Referring to FIG. 9, in particular, the bottom regions 327 may also be rectangular, and the distance between each of the rectangles is equal, and the extensions 330 of the bottom regions 327 adjacent to each other may be equal. Long and symmetrical, and two adjacent extensions 330 are sandwiched by a predetermined angle, such that the etched tracks 33 are hexagonal, and the extension 330 and the base 329 of the connection region 328 have and the connection region 328 The extension 330 and the base 329 have a pinning force that prevents the corners of the base region 327 from warping.
參閱圖6,製作得到該半導體結構3(如圖7)後,進行該成型分離製程22以製作出磊晶半成品。配合參閱圖7和圖10,首先進行該蝕刻加強道形成步驟221,利用該底著層325作為蝕刻裸露於該底著層325外的該磊晶層單元321的硬式光罩(hard mask),以乾蝕刻的方式自裸露於該底著層325外的第一層體323頂面往該磊晶用基板31的方向蝕刻至裸露於該底著層325外的磊晶層單元321剩餘部份第二層體324。該裸露出的第二層體324的頂面、該第一層體323,及該底著層325界定複數較該蝕刻道33為深的蝕刻加強道34。Referring to FIG. 6, after the semiconductor structure 3 (FIG. 7) is fabricated, the molding separation process 22 is performed to fabricate an epitaxial semi-finished product. Referring to FIG. 7 and FIG. 10, the etching enhancement track forming step 221 is first performed, and the underlying layer 325 is used as a hard mask for etching the epitaxial layer unit 321 exposed outside the underlying layer 325. Etching from the top surface of the first layer body 323 exposed outside the underlayer 325 to the remaining portion of the epitaxial substrate 31 to the remaining portion of the epitaxial layer unit 321 exposed outside the underlying layer 325 by dry etching The second layer body 324. The top surface of the exposed second layer body 324, the first layer body 323, and the underlying layer 325 define a plurality of etched reinforcement tracks 34 that are deeper than the etched track 33.
參閱圖6、10、11,接著,再進行該電鍍增厚層形成步驟222,於該蝕刻加強道34內填充一充填物35至滿溢該蝕刻加強道34,且滿溢出的充填物35覆蓋位於該蝕刻加強道34周圍的底著層325頂面,覆蓋寬度約為30μm,該充填物35可選自光阻、二氧化矽,及其中之一組合為材料所構成,在該較佳實施例中,該充填物35為光阻,但不應以光阻為限。參閱圖6、12,之後,自該底著層325未被該充填物35覆蓋的頂面以電鍍的方式形成一具有高導熱特性的電鍍增厚層41,再移除該充填物35。該電鍍增厚層41亦可以具有磁性的材料所構成,且該電鍍增厚層41及該底著層325構成一永久基板單元40,該電鍍增厚層41形成後,再利用化學溶液,例如丙酮將該充填物35移除。Referring to Figures 6, 10, and 11, then, the plating thickening layer forming step 222 is performed, in which the filling reinforcement 35 is filled with a filling material 35 to overflow the etching reinforcement track 34, and the overflowing filling material 35 is covered. The top surface of the underlying layer 325 around the etched reinforcement track 34 has a width of about 30 μm, and the filler 35 may be selected from the group consisting of photoresist, cerium oxide, and a combination thereof, as a material. In the example, the filler 35 is a photoresist, but should not be limited to photoresist. Referring to Figures 6, 12, thereafter, a top surface of the underlying layer 325 that is not covered by the filler 35 is electroplated to form an electroplated thickened layer 41 having high thermal conductivity characteristics, and the fill 35 is removed. The plating thickening layer 41 may also be made of a magnetic material, and the plating thickening layer 41 and the underlying layer 325 form a permanent substrate unit 40. After the plating thickening layer 41 is formed, a chemical solution is used, for example, Acetone removes the fill 35.
參閱圖6、12、13,繼續,再進行一磊晶用基板分離步驟223,將該永久基板單元40、該磊晶層單元321,及該磊晶用基板31整體沈浸例如氫氟酸液體等蝕刻液,由於該第二層體324較該第一層體323對於蝕刻液的蝕刻選擇速率比例高,於是,透過位於該蝕刻加強道34內的蝕刻液及該第二層體324的外周面的蝕刻液蝕刻該第二層體324,先將該第二層體324與該磊晶層單元321的第一層體323完全分離,再繼續利用蝕刻液或相異的化學溶液將附著於該磊晶用基板31上的第二層體324蝕刻完全,而可得到完整的磊晶用基板31。該第一層體323、該底著層325及該電鍍增厚層41相配合得到多數磊晶半成品4;要說明的是,若該電鍍增厚層41具有磁性,可利用外界提供位於該電鍍增厚層41上的磁力吸引該電鍍增厚層41而使該等磊晶半成品4遠離該磊晶用基板31,且由於該磊晶用基板31未受破壞,而可於清潔該磊晶用基板31表面的汗染物與微粒後,回收再重覆利用同一塊磊晶用基板31製作半導體結構3(如圖7所示)。Referring to FIGS. 6 , 12 , and 13 , an epitaxial substrate separation step 223 is further performed, and the permanent substrate unit 40 , the epitaxial layer unit 321 , and the epitaxial substrate 31 are entirely immersed in, for example, a hydrofluoric acid liquid. The etchant has a higher ratio of etching selectivity to the etchant than the first layer 323, so that the etchant located in the etch pad 34 and the outer peripheral surface of the second layer 324 are transmitted. The etching solution etches the second layer body 324, and completely separates the second layer body 324 from the first layer body 323 of the epitaxial layer unit 321 , and then continues to adhere thereto by using an etching solution or a different chemical solution. The second layer body 324 on the epitaxial substrate 31 is completely etched to obtain a complete epitaxial substrate 31. The first layer body 323, the bottom layer 325 and the plating thickening layer 41 are combined to obtain a plurality of epitaxial semi-finished products 4; it is to be noted that if the plating thickening layer 41 has magnetic properties, the external plating may be provided by the external plating. The magnetic force on the thickening layer 41 attracts the plating thickening layer 41 to move the epitaxial semi-finished products 4 away from the epitaxial substrate 31, and since the epitaxial substrate 31 is not damaged, the epitaxial crystal can be cleaned. After the sweat stains and fine particles on the surface of the substrate 31, the semiconductor structure 3 (shown in FIG. 7) is produced by recycling and re-using the same epitaxial substrate 31.
得到多數以永久基板單元40之對應於連接區328的結構而彼此連接的多數磊晶半成品4後,若再進行該分割及形成電極23的步驟,沿著該蝕刻加強道34分割該永久基板單元40之對應於連接區328的結構則可得到複數獨立的磊晶半成品4。參閱圖3、7、13,其中,每一獨立的磊晶半成品4具有一磊晶膜131,及一永久基板132。該永久基板132具有一底著區327,及形成於該底著區327頂面的部份電鍍增厚層41。最後,分別於該等磊晶半成品4的磊晶膜131相反於該永久基板132的表面鍍上預定的電極133,即可製得如圖3所示的磊晶元件。After a plurality of epitaxial semiconductors 4 connected to each other in a structure corresponding to the connection region 328 of the permanent substrate unit 40 are obtained, the step of dividing and forming the electrodes 23 is further performed, and the permanent substrate unit is divided along the etching enhancement track 34. A structure corresponding to the connection region 328 of 40 can obtain a plurality of independent epitaxial semi-finished products 4. Referring to Figures 3, 7, and 13, wherein each of the individual epitaxial semiconductors 4 has an epitaxial film 131 and a permanent substrate 132. The permanent substrate 132 has a bottom region 327 and a portion of the plating thickening layer 41 formed on the top surface of the bottom region 327. Finally, the epitaxial film 131 of the epitaxial semi-finished products 4 is respectively plated with a predetermined electrode 133 opposite to the surface of the permanent substrate 132 to obtain an epitaxial element as shown in FIG.
由上述說明可知,本發明主要是利用該底著層325的連接區328而使形成的永久基板單元40平整地與該磊晶層單元321連結而不翹曲或掀起,進而有效提升整體製程的良率。且在該磊晶用基板分離步驟223中,不需再另外以藍膠將該等欲製作成為磊晶元件的磊晶半成品4定位,可直接以該等連接區328連接並固定該等磊晶半成品4的底著區327。It can be seen from the above description that the present invention mainly utilizes the connection region 328 of the underlayer 325 to form the permanent substrate unit 40 uniformly connected to the epitaxial layer unit 321 without warping or lifting, thereby effectively improving the overall process. Yield. In the epitaxial substrate separation step 223, the epitaxial semi-finished products 4 to be formed into epitaxial elements are not separately positioned by blue glue, and the epitaxial layers can be directly connected and fixed by the connection regions 328. The bottom portion 327 of the semi-finished product 4.
參閱圖6、14,再需說明的是,該較佳實施例的製作方法可重覆該磊晶層單元形成步驟212而在該磊晶用基板31上依序形成多數磊晶層單元321,再繼續於該最頂層的磊晶層單元321進行該底著層形成步驟213。配合參閱圖15,接著,再進行該成型分離製程22,利用該蝕刻液進行最頂層的磊晶層單元321所形成的磊晶半成品4(如圖13)與該磊晶用基板31分離的動作,得到該最頂層的磊晶層單元321所製得的磊晶半成品4(如圖13),再利用化學溶液完全移除最頂層的磊晶層單元321的第二層體324,並保留次一層的磊晶層單元321的第一層體323且使其完全裸露;再重覆進行該底著層形成步驟213、該蝕刻加強道形成步驟221、該電鍍增厚層形成步驟222,與該磊晶用基板分離步驟223,直到連接該磊晶用基板31的磊晶層單元321與該磊晶用基板31分離,最後,利用化學蝕刻溶液和水等液體清潔於該磊晶用基板31表面殘餘的第二層體324、微粒與髒汙,而將該磊晶用基板31恢復為未使用的狀態,再進一步可回收再重新利用該磊晶用基板31。Referring to FIGS. 6 and 14, it is to be noted that the method for fabricating the preferred embodiment can repeat the epitaxial layer cell formation step 212 to sequentially form a plurality of epitaxial layer cells 321 on the epitaxial substrate 31. The underlayer formation step 213 is continued on the topmost epitaxial layer unit 321 . Referring to FIG. 15, the molding separation process 22 is further performed, and the epitaxial semi-finished product 4 (FIG. 13) formed by the topmost epitaxial layer unit 321 is separated from the epitaxial substrate 31 by the etching solution. Obtaining the epitaxial semi-finished product 4 (as shown in FIG. 13) obtained by the topmost epitaxial layer unit 321 , and completely removing the second layer body 324 of the topmost epitaxial layer unit 321 by using a chemical solution, and retaining the time a first layer body 323 of the epitaxial layer unit 321 of one layer and completely exposed; the underlying layer forming step 213, the etching enhancement track forming step 221, the plating thickening layer forming step 222, and the The epitaxial substrate separation step 223 is performed until the epitaxial layer unit 321 connected to the epitaxial substrate 31 is separated from the epitaxial substrate 31, and finally, the surface of the epitaxial substrate 31 is cleaned by a chemical etching solution and a liquid such as water. The remaining second layer body 324, the fine particles and the dirt are stained, and the epitaxial substrate 31 is returned to the unused state, and the epitaxial substrate 31 can be further recovered and reused.
綜上所述,本發明半導體結構利用該等連接區328的延伸部330與該等底著區327的角隅對稱地連接,使該底著層325及該形成於該底著層325上的電鍍增厚層41不翹曲及變形。此外,以本發明半導體結構3繼續製作出的磊晶半成品4所構成的磊晶元件的永久基板132亦不翹曲,並利用該永久基板132的散熱特性佳,促進由該磊晶膜131所產生的廢熱能可透過平貼於該磊晶膜131上且不翹曲的永久基板132順利散熱,避免元件處於過熱的狀態。In summary, the semiconductor structure of the present invention utilizes the extensions 330 of the connection regions 328 to be symmetrically connected to the corners of the base regions 327 such that the underlayer 325 and the underlying layer 325 are formed. The plating thickening layer 41 is not warped and deformed. In addition, the permanent substrate 132 of the epitaxial element formed by the epitaxial semi-finished product 4 which is continuously formed by the semiconductor structure 3 of the present invention is not warped, and the heat dissipation property of the permanent substrate 132 is improved, and the epitaxial film 131 is promoted by the epitaxial film 131. The generated waste heat energy can be smoothly dissipated through the permanent substrate 132 which is affixed to the epitaxial film 131 and is not warped, and the component is prevented from being overheated.
此外,本發明還提供該半導體結構3及磊晶半成品4的製作方法,避免目前該等磊晶半成品4需利用藍膠固定的藍膠資源浪費,故確實能達成本發明之目的。In addition, the present invention also provides a method for fabricating the semiconductor structure 3 and the epitaxial semi-finished product 4, thereby avoiding the waste of the blue-glue resources that the epitaxial semi-finished products 4 need to be fixed by the blue glue, so that the object of the present invention can be achieved.
惟以上所述者,僅為本發明之較佳實施例而已,當不能以此限定本發明實施之範圍,即大凡依本發明申請專利範圍及發明說明內容所作之簡單的等效變化與修飾,皆仍屬本發明專利涵蓋之範圍內。The above is only the preferred embodiment of the present invention, and the scope of the invention is not limited thereto, that is, the simple equivalent changes and modifications made by the scope of the invention and the description of the invention are All remain within the scope of the invention patent.
131...磊晶膜131. . . Epitaxial film
132...永久基板132. . . Permanent substrate
133...電極133. . . electrode
21...半導體結構製程twenty one. . . Semiconductor structure process
211...磊晶用基板準備步驟211. . . Epitaxial substrate preparation step
212...磊晶層單元形成步驟212. . . Epitaxial layer unit formation step
213...底著層形成步驟213. . . Bottom layer formation step
22...成型分離製程twenty two. . . Molding separation process
221...蝕刻加強道形成步驟221. . . Etched reinforcement path forming step
222...電鍍增厚層形成步驟222. . . Electroplating thickening layer forming step
223...磊晶用基板分離步驟223. . . Epitaxial substrate separation step
23...分割及形成電極twenty three. . . Segmentation and formation of electrodes
3...半導體結構3. . . Semiconductor structure
31...磊晶用基板31. . . Epitaxial substrate
32...主體32. . . main body
321...磊晶層單元321. . . Epitaxial layer unit
323...第一層體323. . . First layer
324...第二層體324. . . Second layer
325...底著層325. . . Bottom layer
327...底著區327. . . Bottom area
328...連接區328. . . Connection area
329...基部329. . . Base
330...延伸部330. . . Extension
33...蝕刻道33. . . Etch
34...蝕刻加強道34. . . Etched reinforcement
35...充填物35. . . Filling
4...磊晶半成品4. . . Epitaxial semi-finished products
40...永久基板單元40. . . Permanent substrate unit
41...電鍍增厚層41. . . Electroplated thickening layer
圖1是一示意圖,說明一傳統的磊晶元件;Figure 1 is a schematic view showing a conventional epitaxial element;
圖2是一示意圖,說明目前具有高分子膠的磊晶元件;2 is a schematic view showing an epitaxial element having a polymer gel;
圖3是一示意圖,說明一散熱效果佳的磊晶元件;3 is a schematic view showing an epitaxial element with good heat dissipation effect;
圖4是一立體圖,說明目前的半導體結構;Figure 4 is a perspective view showing the current semiconductor structure;
圖5是一剖視示意圖,說明目前的半導體結構;Figure 5 is a cross-sectional view showing the current semiconductor structure;
圖6是一流程圖,說明以本發明磊晶半成品的製作方法再繼續製作出磊晶元件的流程;6 is a flow chart for explaining the flow of the epitaxial element production process by the method for fabricating the epitaxial semi-finished product of the present invention;
圖7是一立體圖,說明本發明的一半導體結構;Figure 7 is a perspective view showing a semiconductor structure of the present invention;
圖8是一示意圖,說明形成於該磊晶用基板頂面的磊晶層單元;Figure 8 is a schematic view showing an epitaxial layer unit formed on the top surface of the epitaxial substrate;
圖9是一立體圖,說明本發明該半導體結構的底著區可為矩形;Figure 9 is a perspective view showing the bottom surface of the semiconductor structure of the present invention may be rectangular;
圖10是一示意圖,說明一第二層體頂面、一第一層體,及一底著層界定複數蝕刻加強道;Figure 10 is a schematic view showing a second layer top surface, a first layer body, and a bottom layer defining a plurality of etched reinforcement tracks;
圖11是一示意圖,說明填充一充填物於該等蝕刻加強道;Figure 11 is a schematic view showing filling of a filler in the etched reinforcement tracks;
圖12是一示意圖,說明電鍍一電鍍增厚層於該底著層頂面;Figure 12 is a schematic view showing a plating-plating thickening layer on the top surface of the underlying layer;
圖13是一示意圖,說明一磊晶用基板與複數磊晶半成品分離;Figure 13 is a schematic view showing a substrate for epitaxy separated from a plurality of epitaxial semi-finished products;
圖14是一示意圖,說明於該磊晶用基板上形成多數磊晶層單元;及Figure 14 is a schematic view showing formation of a plurality of epitaxial layer units on the substrate for epitaxy;
圖15是一示意圖,說明在該最頂層的磊晶層單元形成該蝕刻加強道。Figure 15 is a schematic view showing the formation of the etch-enhanced track in the topmost epitaxial layer unit.
3...半導體結構3. . . Semiconductor structure
31...磊晶用基板31. . . Epitaxial substrate
32...主體32. . . main body
321...磊晶層單元321. . . Epitaxial layer unit
323...第一層體323. . . First layer
324...第二層體324. . . Second layer
325...底著層325. . . Bottom layer
327...底著區327. . . Bottom area
328...連接區328. . . Connection area
329...基部329. . . Base
330...延伸部330. . . Extension
33...蝕刻道33. . . Etch
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TW201027677A (en) * | 2008-10-28 | 2010-07-16 | Osram Opto Semiconductors Gmbh | Carrier body for a semiconductor component, semiconductor component and method for manufacturing a carrier body |
TW201030837A (en) * | 2008-11-19 | 2010-08-16 | Agency Science Tech & Res | Method of at least partially releasing an epitaxial layer |
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US20050151138A1 (en) * | 2003-11-12 | 2005-07-14 | Slater David B.Jr. | Methods of processing semiconductor wafer backsides having light emitting devices (LEDS) thereon and leds so formed |
TW201027677A (en) * | 2008-10-28 | 2010-07-16 | Osram Opto Semiconductors Gmbh | Carrier body for a semiconductor component, semiconductor component and method for manufacturing a carrier body |
US20100109024A1 (en) * | 2008-11-04 | 2010-05-06 | Canon Kabushiki Kaisha | Transfer method of functional region, led array, led printer head, and led printer |
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