TWI430161B - Conductive sheet, method of using conductive sheet, and capacitive touch panel - Google Patents

Conductive sheet, method of using conductive sheet, and capacitive touch panel Download PDF

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TWI430161B
TWI430161B TW100103120A TW100103120A TWI430161B TW I430161 B TWI430161 B TW I430161B TW 100103120 A TW100103120 A TW 100103120A TW 100103120 A TW100103120 A TW 100103120A TW I430161 B TWI430161 B TW I430161B
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conductive
conductive sheet
lattice
lattices
pattern
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TW100103120A
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TW201203062A (en
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Tadashi Kuriki
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Fujifilm Corp
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    • GPHYSICS
    • G06COMPUTING; CALCULATING OR COUNTING
    • G06FELECTRIC DIGITAL DATA PROCESSING
    • G06F3/00Input arrangements for transferring data to be processed into a form capable of being handled by the computer; Output arrangements for transferring data from processing unit to output unit, e.g. interface arrangements
    • G06F3/01Input arrangements or combined input and output arrangements for interaction between user and computer
    • G06F3/03Arrangements for converting the position or the displacement of a member into a coded form
    • G06F3/041Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means
    • G06F3/0412Digitisers structurally integrated in a display
    • GPHYSICS
    • G06COMPUTING; CALCULATING OR COUNTING
    • G06FELECTRIC DIGITAL DATA PROCESSING
    • G06F3/00Input arrangements for transferring data to be processed into a form capable of being handled by the computer; Output arrangements for transferring data from processing unit to output unit, e.g. interface arrangements
    • G06F3/01Input arrangements or combined input and output arrangements for interaction between user and computer
    • G06F3/03Arrangements for converting the position or the displacement of a member into a coded form
    • G06F3/041Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means
    • G06F3/044Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means by capacitive means
    • G06F3/0445Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means by capacitive means using two or more layers of sensing electrodes, e.g. using two layers of electrodes separated by a dielectric layer
    • GPHYSICS
    • G06COMPUTING; CALCULATING OR COUNTING
    • G06FELECTRIC DIGITAL DATA PROCESSING
    • G06F3/00Input arrangements for transferring data to be processed into a form capable of being handled by the computer; Output arrangements for transferring data from processing unit to output unit, e.g. interface arrangements
    • G06F3/01Input arrangements or combined input and output arrangements for interaction between user and computer
    • G06F3/03Arrangements for converting the position or the displacement of a member into a coded form
    • G06F3/041Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means
    • G06F3/044Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means by capacitive means
    • G06F3/0446Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means by capacitive means using a grid-like structure of electrodes in at least two directions, e.g. using row and column electrodes
    • GPHYSICS
    • G06COMPUTING; CALCULATING OR COUNTING
    • G06FELECTRIC DIGITAL DATA PROCESSING
    • G06F2203/00Indexing scheme relating to G06F3/00 - G06F3/048
    • G06F2203/041Indexing scheme relating to G06F3/041 - G06F3/045
    • G06F2203/04112Electrode mesh in capacitive digitiser: electrode for touch sensing is formed of a mesh of very fine, normally metallic, interconnected lines that are almost invisible to see. This provides a quite large but transparent electrode surface, without need for ITO or similar transparent conductive material

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  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Theoretical Computer Science (AREA)
  • Human Computer Interaction (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Position Input By Displaying (AREA)
  • Non-Insulated Conductors (AREA)
  • Laminated Bodies (AREA)

Description

導電片、導電片的使用方法以及靜電電容式觸控面板Conductive sheet, method of using conductive sheet, and capacitive touch panel

本發明是有關於一種導電片、導電片的使用方法以及靜電電容式觸控面板,例如,本發明是有關於一種適合用於投影型靜電電容式的觸控面板的導電片、導電片的使用方法以及靜電電容式觸控面板。The present invention relates to a conductive sheet, a method of using a conductive sheet, and an electrostatic capacitive touch panel. For example, the present invention relates to a conductive sheet and a conductive sheet suitable for use in a projection type capacitive touch panel. Method and electrostatic capacitive touch panel.

關於使用金屬細線的透明導電膜,例如,如美國專利申請公開第2004/0229028號說明書以及國際公開第2006/001461號手冊所揭示般,正在繼續進行研究。Regarding the use of a transparent conductive film using metal thin wires, for example, as disclosed in the specification of U.S. Patent Application Publication No. 2004/0229028 and the International Publication No. 2006/001461, the research is continuing.

最近,觸控面板受到關注。一般認為,觸控面板主要是應用於個人數位助理(Personal Digital Assistant,PDA)或行動電話等小尺寸設備,但由於對個人電腦用顯示器等的應用而向大尺寸化進步。Recently, touch panels have received attention. It is generally considered that the touch panel is mainly applied to a small-sized device such as a personal digital assistant (PDA) or a mobile phone, but it has been increasing in size due to applications for displays for personal computers and the like.

在如此的未來的動向下,先前的電極由於使用氧化銦錫(Indium Tin Oxide,ITO),因此電阻變大,應用尺寸變大,隨之,有電極間的電流的傳輸速度變慢、響應速度(接觸指尖後直至檢測出該指尖的位置為止的時間)變慢的問題。In the future, the previous electrode uses Indium Tin Oxide (ITO), so the resistance becomes large, and the application size becomes large. Accordingly, the transmission speed of the current between the electrodes becomes slow and the response speed is high. (The time until the position of the fingertip is detected after touching the fingertip) becomes slow.

因此,想到了將多數個由金屬製細線(金屬細線)構成的格子排列而構成電極,以此來降低表面電阻。作為將金屬細線用於電極的觸控面板,例如已知有專利文獻日本專利特開平5-224818號公報、美國專利第5113041號說明書、國際公開第1995/27334號手冊、美國專利申請公開第 2004/0239650號說明書、美國專利第7202859號說明書、國際公開第1997/18508號手冊、日本專利特開2003-099185號公報。Therefore, it has been considered that a plurality of lattices made of metal thin wires (metal thin wires) are arranged to form an electrode, thereby reducing the surface resistance. As a touch panel using a thin metal wire for an electrode, for example, a patent document is disclosed in Japanese Laid-Open Patent Publication No. Hei 5-224818, No. 5111101, and No. 1995/27334, and U.S. Patent Application Publication No. The specification of 2004/0239650, the specification of U.S. Patent No. 7,202,859, the Handbook of International Publication No. 1997/18508, and the Japanese Patent Laid-Open No. 2003-099185.

然而,於將金屬細線用於電極時,由於金屬細線是由不透明之材料所製作,故透明性或視認性成問題。However, when a metal thin wire is used for an electrode, since the fine metal wire is made of an opaque material, transparency or visibility is a problem.

本發明是考慮到上述問題而成,其目的在於提供一種即便於觸控面板中以金屬細線圖案構成電極時亦可確保高透明性的導電片、導電片的使用方法以及靜電電容式觸控面板。The present invention has been made in view of the above problems, and an object thereof is to provide a conductive sheet, a conductive sheet, and a capacitive touch panel which can ensure high transparency even when an electrode is formed by a thin metal pattern in a touch panel. .

[1]本發明的第1發明的導電片的特徵在於:包括基體及形成於基體上之導電部,上述導電部形成有由金屬細線形成的2個以上的導電性的大格子、及將相鄰接的上述大格子間加以電性連接的由金屬細線形成的連接部,各上述大格子分別是由2個以上的小格子組合而構成,藉由上述大格子的組合而構成電路,於將上述小格子的間距設為Ps時,上述連接部的寬度Wc滿足Wc>Ps/[1] The conductive sheet according to the first aspect of the present invention includes a substrate and a conductive portion formed on the substrate, wherein the conductive portion is formed with two or more conductive large lattices formed of fine metal wires, and a phase Each of the large lattices is formed by a combination of two or more small lattices, and each of the large grids is electrically connected to the adjacent large grids, and the plurality of grids are combined to form a circuit. When the pitch of the small lattice is Ps, the width Wc of the connecting portion satisfies Wc>Ps/ .

[2]如第1發明所述的導電片,其中2個以上的上述大格子經由上述連接部排列於第1方向上從而構成1個導電圖案,2個以上的上述導電圖案排列於與上述第1方向正交的第2方向上,於相鄰接的上述導電圖案之間配置有不存在上述小格子的電性絕緣的絕緣部,藉由上述導電圖案、上述絕緣部的排列而構成上述電路。[2] The conductive sheet according to the first aspect of the invention, wherein the two or more large lattices are arranged in the first direction via the connecting portion to form one conductive pattern, and the two or more conductive patterns are arranged in the same manner as the above In the second direction orthogonal to the one direction, an electrically insulating insulating portion in which the small lattice is not present is disposed between the adjacent conductive patterns, and the conductive pattern and the insulating portion are arranged to form the circuit. .

[3]如第1發明所述的導電片,其中上述大格子的一邊的長度為3mm~10mm。[3] The conductive sheet according to the first aspect of the invention, wherein a length of one side of the large lattice is 3 mm to 10 mm.

[4]如第1發明所述的導電片,其中上述小格子的一邊的長度為30μm~500μm。[4] The conductive sheet according to the first aspect of the invention, wherein a length of one side of the small lattice is 30 μm to 500 μm.

[5]如第1發明所述的導電片,其中上述小格子的彼此相向的邊的間隔為30μm~500μm。[5] The conductive sheet according to the first aspect of the invention, wherein an interval between the mutually opposing sides of the small lattice is 30 μm to 500 μm.

[6]如第1發明所述的導電片,其中上述金屬細線的線寬為10μm以下。[6] The conductive sheet according to the first aspect of the invention, wherein the metal thin wires have a line width of 10 μm or less.

[7]本發明的第2發明的導電片的特徵在於:包括基體、形成於上述基體的一個主面上的第1導電部、及形成於上述基體的另一主面上的第2導電部,上述第1導電部具有由金屬細線形成的2個以上的導電性的第1大格子、及將相鄰接的上述第1大格子間加以電性連接的由金屬細線形成的第1連接部,上述第2導電部具有由金屬細線形成的2個以上的導電性的第2大格子、及將相鄰接的上述第2大格子間加以電性連接的由金屬細線形成的第2連接部,各上述第1大格子以及各上述第2大格子分別是由2個以上的小格子組合而構成,上述第1大格子經由上述第1連接部排列於第1方向上從而構成1個第1導電圖案,藉由上述第1大格子與上述第2大格子的組合而構成電路,於將上述小格子的間距設為Ps時,上述第1連接部的寬度Wc1以及上述第2連接部的寬度Wc2滿足Wc1>Ps/ [7] The conductive sheet according to the second aspect of the present invention, comprising: a base; a first conductive portion formed on one main surface of the base; and a second conductive portion formed on the other main surface of the base The first conductive portion has two or more conductive first large lattices formed of thin metal wires, and a first connection portion formed of metal thin wires electrically connecting the adjacent first large lattices The second conductive portion has two or more conductive second large lattices formed of thin metal wires, and second conductive portions formed of thin metal wires electrically connecting the adjacent second large lattices Each of the first large lattices and each of the second large lattices is composed of a combination of two or more small lattices, and the first large lattices are arranged in the first direction via the first connecting portions to constitute one first The conductive pattern is configured by a combination of the first large lattice and the second large lattice, and when the pitch of the small lattice is Ps, the width Wc1 of the first connecting portion and the width of the second connecting portion Wc2 satisfies Wc1>Ps/

Wc2>Ps/Wc2>Ps/ .

[8]如第2發明的導電片,其中上述第1大格子經由上述第1連接部排列於第1方向上從而構成由金屬細線形成的1個第1導電圖案,2個以上的上述第2大格子經由上述第2連接部排列於與上述第1方向正交的第2方向上從而構成由金屬細線形成的1個第2導電圖案,於相鄰接的上述第1導電圖案之間配置有不存在上述小格子的電性絕緣的第1絕緣部,於相鄰接的上述第2導電圖案之間配置有不存在上述小格子的電性絕緣的第2絕緣部,藉由上述第1導電圖案、上述第2導電圖案、上述第1絕緣部、上述第2絕緣部的排列而構成上述電路。[8] The conductive sheet according to the second aspect of the invention, wherein the first large lattice is arranged in the first direction via the first connecting portion, thereby forming one first conductive pattern formed of thin metal wires, and two or more of the second conductive patterns The large lattice is arranged in the second direction orthogonal to the first direction via the second connecting portion to form one second conductive pattern formed of thin metal wires, and is disposed between the adjacent first conductive patterns The first insulating portion that is electrically insulated from the small lattice is not present, and the second insulating portion that is electrically insulated from the small lattice is disposed between the adjacent second conductive patterns, and the first conductive portion is disposed by the first conductive portion The pattern, the second conductive pattern, the first insulating portion, and the second insulating portion are arranged to constitute the circuit.

[9]如第2發明的導電片,其中上述金屬細線的線寬為10μm以下。[9] The conductive sheet according to the second aspect of the invention, wherein the metal thin wire has a line width of 10 μm or less.

[10]如第2發明的導電片,其中上述第1大格子的邊部的直線部與上述第2大格子的邊部的直線部間之投影距離是根據上述小格子的尺寸而設定。[10] The conductive sheet according to the second aspect of the invention, wherein a projection distance between a straight portion of a side portion of the first large lattice and a straight portion of a side portion of the second large lattice is set according to a size of the small lattice.

[11]如第2發明的導電片,其中上述投影距離為100μm~400μm。[11] The conductive sheet according to the second aspect of the invention, wherein the projection distance is 100 μm to 400 μm.

[12]如第2發明的導電片,其中上述第1導電部具有:連接於各上述第1導電圖案的端部的第1端子配線圖案,及形成於上述基體的一個主面的1條邊的長度方向中央部分、且與對應的上述第1端子配線圖案連接的多個第1端子;上述第2導電部具有:連接於各上述第2導電圖案的端部的第2端子配線圖案,及形成於上述基體的另一主面的1條邊的長度方向中央部分、且與對應的上述第2端子 配線圖案連接的多個第2端子。[12] The conductive sheet according to the second aspect of the invention, wherein the first conductive portion has a first terminal wiring pattern connected to an end portion of each of the first conductive patterns, and one side formed on one main surface of the base body a plurality of first terminals connected to the corresponding first terminal wiring pattern at a central portion in the longitudinal direction, and the second conductive portion has a second terminal wiring pattern connected to an end portion of each of the second conductive patterns, and formed a central portion in the longitudinal direction of one side of the other main surface of the base body and the corresponding second terminal A plurality of second terminals connected to the wiring pattern.

[13]如第2發明的導電片,其中自上表面觀看時,排列有多個上述第1端子的部分與排列有多個上述第2端子的部分相鄰接。[13] The conductive sheet according to the second aspect of the invention, wherein, when viewed from the upper surface, a portion in which the plurality of first terminals are arranged is adjacent to a portion in which the plurality of second terminals are arranged.

[14]如第2發明的導電片,其中各上述第1導電圖案的端部與對應的上述第1端子配線圖案分別經由第1結線部而連接,各上述第2導電圖案的端部與對應的上述第2端子配線圖案是分別經由第2結線部而連接,多個上述第1結線部沿著上述第2方向而直線狀地排列,多個上述第2結線部沿著上述第1方向而直線狀地排列。[14] The conductive sheet according to the second aspect of the invention, wherein an end portion of each of the first conductive patterns and the corresponding first terminal wiring pattern are connected via a first junction portion, and an end portion of each of the second conductive patterns corresponds to The second terminal wiring patterns are connected via the second connection portion, and the plurality of first connection portions are linearly arranged along the second direction, and the plurality of second connection portions are along the first direction. Arranged in a straight line.

[15]如第2發明的導電片,其中上述第1絕緣部與上述第2絕緣部將上述基體夾在中間而相向,自上表面觀看時,上述第1絕緣部與上述第2絕緣部的相向部分的形狀為多邊形狀。[15] The conductive sheet according to the second aspect of the invention, wherein the first insulating portion and the second insulating portion face each other with the base body interposed therebetween, and when viewed from a top surface, the first insulating portion and the second insulating portion The shape of the opposing portion is polygonal.

[16]如第2發明的導電片,其中上述多邊形狀為正方形狀。[16] The conductive sheet according to the second aspect of the invention, wherein the polygonal shape is a square shape.

[17]如第2發明的導電片,其中上述多邊形狀為楔形狀。[17] The conductive sheet according to the second aspect of the invention, wherein the polygonal shape is a wedge shape.

[18]如第1發明或第2發明的導電片,其中上述小格子為多邊形狀。[18] The conductive sheet according to the first or second aspect of the invention, wherein the small lattice is polygonal.

[19]如第2發明的導電片,其中上述小格子為正方形狀。[19] The conductive sheet according to the second aspect of the invention, wherein the small lattice is square.

[20]本發明的第3發明的導電片的使用方法是使用第1導電片與第2導電片的導電片的使用方法,上述第1導 電片上形成有由金屬細線形成的2個以上的導電性的第1大格子、及將相鄰接的上述第1大格子間加以電性連接的由金屬細線形成的第1連接部,各上述第1大格子分別是由2個以上的小格子組合而構成,於將上述小格子的間距設為Ps時,上述第1連接部的寬度Wc1滿足Wc1>Ps/,上述第2導電片上形成有由金屬細線形成的2個以上的導電性的第2大格子、及將相鄰接的上述第2大格子間加以電性連接的由金屬細線形成的第2連接部,各上述第2大格子分別是由2個以上的小格子組合而構成,於將上述小格子的間距設為Ps時,上述第2連接部的寬度Wc2滿足Wc2>Ps/,該導電片的使用方法的特徵在於:上述第1導電片中,2個以上的上述第1大格子經由上述第1連接部排列於第1方向上從而構成1個第1導電圖案,上述第2導電片中,2個以上的上述第2大格子經由上述第2連接部排列於與上述第1方向正交的第2方向上從而構成1個第2導電圖案,藉由將上述第1導電片與上述第2導電片組合,以將上述第1電片的上述第1連接部與上述第2導電片的上述第2連接部組合以形成上述小格子的排列的方式配置。[20] A method of using a conductive sheet according to a third aspect of the present invention is a method of using a conductive sheet of a first conductive sheet and a second conductive sheet, wherein two or more conductive layers formed of thin metal wires are formed on the first conductive sheet. a first large lattice and a first connecting portion formed of a thin metal wire electrically connecting the adjacent first large lattices, wherein each of the first large lattices is composed of two or more small lattices Further, when the pitch of the small lattice is Ps, the width Wc1 of the first connecting portion satisfies Wc1>Ps/ The second conductive sheet is formed with a second large grid of two or more conductive layers formed of thin metal wires and a second connection formed of thin metal wires electrically connecting the adjacent second large lattices. Each of the second large lattices is composed of a combination of two or more small lattices. When the pitch of the small lattices is Ps, the width Wc2 of the second connection portion satisfies Wc2>Ps/ In the first conductive sheet, two or more of the first large lattices are arranged in the first direction via the first connecting portion to form one first conductive pattern, and the first conductive sheet is used. In the second conductive sheet, two or more of the second large lattices are arranged in the second direction orthogonal to the first direction via the second connection portion to form one second conductive pattern, and the first conductive layer is formed by the first conductive layer. The sheet is combined with the second conductive sheet, and the first connecting portion of the first electric piece and the second connecting portion of the second conductive sheet are combined to form an arrangement of the small lattices.

[21]本發明的第4發明的靜電電容式觸控面板的特徵在於包括上述第1發明或第2發明的導電片。[21] The capacitive touch panel of the fourth invention of the present invention is characterized by comprising the conductive sheet of the first invention or the second invention.

如以上所說明,根據本發明的導電片以及導電片的使用方法,可使形成於基體上的導電圖案實現低電阻化,並且即便於觸控面板中以金屬細線圖案構成電極時,亦可確 保高透明性,例如適合用於投影型靜電電容式的觸控面板。As described above, according to the conductive sheet of the present invention and the method of using the conductive sheet, the conductive pattern formed on the substrate can be made low-resistance, and even when the electrode is formed by a thin metal pattern in the touch panel, High transparency, for example, suitable for projection type capacitive touch panels.

另外,本發明的靜電電容式觸控面板可實現形成於基體上的導電圖案的低電阻化,並且即便於以金屬細線圖案構成電極時,亦可確保高透明性,例如亦可應對投影型靜電電容式的觸控面板的大尺寸化。Further, the capacitive touch panel of the present invention can achieve low resistance of the conductive pattern formed on the substrate, and can ensure high transparency even when the electrode is formed by the metal thin line pattern, for example, it can also cope with the projection type static electricity. The capacitive touch panel is large in size.

上述目的及其他目的、特徵以及優點可根據與隨附圖式相配合的較佳實施形態例的說明而更為清楚明瞭。The above and other objects, features, and advantages will be apparent from the description of the preferred embodiments of the invention.

以下,參照圖1~圖17,對本發明的導電片、導電片的使用方法以及靜電電容式觸控面板的實施形態例加以說明。再者,本說明書中表示數值範圍的「~」的含義是,將其前後所記載的數值作為下限值以及上限值而包含在內。Hereinafter, an embodiment of a conductive sheet, a conductive sheet, and a capacitive touch panel of the present invention will be described with reference to FIGS. 1 to 17 . In the present specification, the meaning of "~" in the numerical range is that the numerical values described before and after are included as the lower limit and the upper limit.

第1實施形態之導電片(以下記作第1導電片10A)如圖1所示,具有形成於第1透明基體12A(參照圖2)的一個主面上的第1導電部13A。該第1導電部13A形成有由金屬細線形成的2個以上的導電性的第1大格子14A、及將相鄰接的第1大格子14A間加以電性連接的由金屬細線形成的第1連接部16A,各第1大格子14A分別是由2個以上的小格子18組合而構成,藉由第1大格子14A的組合而構成電路(導電性的電路圖案)。此處,小格子18是設定為最小的正方形狀。金屬細線例如是由金(Au)、銀(Ag)或銅(Cu)構成。As shown in FIG. 1, the conductive sheet (hereinafter referred to as the first conductive sheet 10A) of the first embodiment has a first conductive portion 13A formed on one main surface of the first transparent substrate 12A (see FIG. 2). The first conductive portion 13A is formed with two or more conductive first large lattices 14A formed of thin metal wires and first metal thin wires electrically connecting the adjacent first large lattices 14A. In the connection portion 16A, each of the first large lattices 14A is composed of a combination of two or more small lattices 18, and a circuit (conductive circuit pattern) is formed by a combination of the first large lattices 14A. Here, the small lattice 18 is set to a minimum square shape. The fine metal wires are made of, for example, gold (Au), silver (Ag), or copper (Cu).

第1大格子14A的一邊的長度較佳為3mm~10mm, 更佳為4mm~6mm。若一邊的長度小於上述下限值,則於將第1導電片10A用於例如觸控面板時,檢測時的第1大格子14A的靜電電容降低,故成為檢測不良的可能性變高。另一方面,若一邊的長度超過上述上限值,則位置檢測精度可能下降。就同樣的觀點而言,構成第1大格子14A的小格子18的一邊的長度較佳為50μm~500μm,更佳為150μm~300μm。於小格子18為上述範圍時,進而,透明性亦可保持良好,於安裝於顯示裝置的前表面時,可看到顯示而無不協調感。The length of one side of the first large lattice 14A is preferably 3 mm to 10 mm. More preferably 4mm~6mm. When the length of one side is less than the above-described lower limit, when the first conductive sheet 10A is used for, for example, a touch panel, the capacitance of the first large lattice 14A at the time of detection is lowered, which may increase the detection failure. On the other hand, if the length of one side exceeds the above upper limit value, the position detection accuracy may decrease. From the same viewpoint, the length of one side of the small lattice 18 constituting the first large lattice 14A is preferably 50 μm to 500 μm, and more preferably 150 μm to 300 μm. When the small lattice 18 is in the above range, the transparency can be kept good, and when it is attached to the front surface of the display device, the display can be seen without any uncomfortable feeling.

進而,2個以上的第1大格子14A經由第1連接部16A排列於x方向(第1方向)上,構成由金屬細線形成的1個導電性的電路圖案(以下,記作第1導電圖案22A),2個以上的第1導電圖案22A排列在與x方向正交的y方向(第2方向)上,於相鄰接的第1導電圖案22A之間,配置有不存在小格子18的電性絕緣的第1絕緣部24A。Further, two or more first large lattices 14A are arranged in the x direction (first direction) via the first connecting portion 16A, and constitute one conductive circuit pattern formed of thin metal wires (hereinafter, referred to as a first conductive pattern) 22A), two or more first conductive patterns 22A are arranged in the y direction (second direction) orthogonal to the x direction, and between the adjacent first conductive patterns 22A, the small lattice 18 is not disposed. The first insulating portion 24A that is electrically insulated.

x方向表示例如後述的投影型靜電電容式的觸控面板100(參照圖3)的水平方向(或垂直方向)、或設置著觸控面板100的顯示面板110的水平方向(或垂直方向)。The x direction indicates, for example, a horizontal direction (or a vertical direction) of a projection type capacitive touch panel 100 (see FIG. 3 ) to be described later, or a horizontal direction (or a vertical direction) of the display panel 110 on which the touch panel 100 is provided.

而且,如圖1所示,在第1大格子14A的四個邊部中,和不與鄰接的第1大格子14A連接的一個頂點部分26a鄰接的第1邊部28a以及第2邊部28b,分別成為多數個針狀的線32(小格子18的邊)自沿著第1邊部28a以及第2邊部28b連續的直線部30梳齒狀地伸出的形態(以下,將線32亦記作梳齒32)。另一方面,和不與鄰接的第1大格 子14A連接的另一頂點部分26b鄰接的第3邊部28c以及第4邊部28d,分別成為形成有沿著第3邊部28c以及第4邊部28d連續的直線部30的形態,進而,於另一頂點部分26b,成為將對應的一個小格子18(準確而言是鄰接的兩條邊)去掉的形態。Further, as shown in FIG. 1, the first side portion 28a and the second side portion 28b adjacent to one vertex portion 26a that is not connected to the adjacent first large lattice 14A are formed in the four side portions of the first large lattice 14A. Each of the plurality of needle-shaped wires 32 (the sides of the small lattices 18) is formed in a comb-like shape from the straight portion 30 continuous along the first side portion 28a and the second side portion 28b (hereinafter, line 32 is provided). Also recorded as comb teeth 32). On the other hand, and not with the first big grid Each of the third side portion 28c and the fourth side portion 28d adjacent to the other apex portion 26b to which the sub-portion 14A is connected has a form in which the straight portion 30 continuous along the third side portion 28c and the fourth side portion 28d is formed, and further, In the other vertex portion 26b, a corresponding one of the small lattices 18 (accurately, two adjacent sides) is removed.

第1連接部16A具有4個中格子20(第1中格子20a~第4中格子20d)鋸齒狀地排列的形狀,其中上述中格子20具有包含4個小格子18的大小。即,第1中格子20a存在於第2邊部28b的直線部30與第4邊部28d的直線部30的交界部分,具有與1個小格子18形成L字形的空間的形狀。第2中格子20b與第1中格子20a的1條邊(第2邊部28b的直線部30)鄰接,具有形成有正方形的空間的形狀,即,將4個小格子18排列成矩陣狀並去掉中央十字而成的形狀。第3中格子20c與第1中格子20a鄰接,並且與第2中格子20b鄰接而配置,具有與第2中格子20b相同的形狀。第4中格子20d存在於第3邊部28c的第2個直線部30(自最外側朝向第1大格子14A的內部的第2個直線部30)與第1邊部28a的交界部分,與第2中格子20b鄰接,並且與第3中格子20c鄰接而配置,與第1中格子20a同樣,具有與1個小格子18形成L字形的空間的形狀。第4中格子20d的1條邊存在於第1大格子14A中的第4邊部28d的直線部30的延長線上。而且,將小格子18的排列間距設定為Ps時,中格子20的排列間距Pm有2×Ps的關係。另外,第1連接部16A的寬度Wc1(第 2中格子20b的頂點至第3中格子20c的頂點之間,且沿著y方向的距離)滿足Wc1>Ps/,此處為6×(Ps/)。The first connecting portion 16A has a shape in which four intermediate lattices 20 (the first intermediate lattice 20a to the fourth intermediate lattice 20d) are arranged in a zigzag shape, and the intermediate lattice 20 has a size including four small lattices 18. In other words, the first intermediate lattice 20a has a shape in which a space between the straight portion 30 of the second side portion 28b and the straight portion 30 of the fourth side portion 28d is formed in a L-shaped space with one small lattice 18. The second intermediate lattice 20b is adjacent to one side of the first intermediate lattice 20a (the linear portion 30 of the second side portion 28b), and has a shape in which a square space is formed, that is, four small lattices 18 are arranged in a matrix and removed. The shape of the central cross. The third intermediate lattice 20c is adjacent to the first intermediate lattice 20a, and is disposed adjacent to the second intermediate lattice 20b, and has the same shape as the second intermediate lattice 20b. The fourth intermediate lattice 20d is present at a boundary portion between the second straight portion 30 of the third side portion 28c (the second straight portion 30 from the outermost side toward the inside of the first large lattice 14A) and the first side portion 28a, and The second intermediate lattice 20b is adjacent to the third intermediate lattice 20c, and has a shape in which an L-shaped space is formed with one small lattice 18, similarly to the first intermediate lattice 20a. One side of the fourth middle lattice 20d exists on the extension line of the straight portion 30 of the fourth side portion 28d of the first large lattice 14A. Further, when the arrangement pitch of the small lattices 18 is set to Ps, the arrangement pitch Pm of the intermediate lattices 20 has a relationship of 2 × Ps. Further, the width Wc1 of the first connecting portion 16A (the distance from the vertex of the second intermediate lattice 20b to the apex of the third intermediate lattice 20c and along the y direction) satisfies Wc1>Ps/ , here is 6×(Ps/ ).

存在於各第1導電圖案22A的一個端部側的第1大格子14A的開放端成為不存在第1連接部16A的形狀。存在於各第1導電圖案22A的另一端部側的第1大格子14A的端部經由第1結線部40a(參照圖3)而電性連接於由金屬細線形成的第1端子配線圖案41a。The open end of the first large lattice 14A which is present on one end side of each of the first conductive patterns 22A has a shape in which the first connecting portion 16A does not exist. The end portion of the first large lattice 14A existing on the other end side of each of the first conductive patterns 22A is electrically connected to the first terminal wiring pattern 41a formed of a thin metal wire via the first junction portion 40a (see FIG. 3).

如此,第1導電片10A中,2個以上的第1大格子14A經由第1連接部16A排列於x方向上,從而構成1個第1導電圖案22A,分別將2個以上的小格子18組合而構成各第1大格子14A,當將小格子18的間距設定為Ps時,使第1連接部16A的寬度Wc1滿足Wc1>Ps/,因此與由1個ITO膜形成1個電極的構成相比較,可大幅度地降低電阻。因此,於使用該第1導電片10A而應用於例如投影型靜電電容式的觸控面板時,可提高響應速度,且可促進觸控面板之大尺寸化。In the first conductive sheet 10A, two or more first large lattices 14A are arranged in the x direction via the first connecting portion 16A, thereby constituting one first conductive pattern 22A, and two or more small lattices 18 are combined. When the first large lattice 14A is formed, when the pitch of the small lattices 18 is set to Ps, the width Wc1 of the first connecting portion 16A is made to satisfy Wc1>Ps/ Therefore, the electric resistance can be greatly reduced as compared with a configuration in which one electrode is formed by one ITO film. Therefore, when the first conductive sheet 10A is used and applied to, for example, a projection type capacitive touch panel, the response speed can be improved, and the size of the touch panel can be increased.

繼而,參照圖3~圖7,對使用上述第1導電片10A的觸控面板100加以說明。Next, the touch panel 100 using the first conductive sheet 10A will be described with reference to FIGS. 3 to 7.

觸控面板100具有感測器本體102及未圖示的控制電路(由IC電路等構成)。如圖3、圖4以及圖5A所示,感測器本體102具有由上述第1導電片10A與後述的第2導電片10B積層而構成的第1實施形態的觸控面板用導電片(以下,記作第1積層導電片50A)、以及積層於該第1積層導電片50A上的保護層106(圖5A中省略保護層106 的記載)。第1積層導電片50A以及保護層106例如是配置於液晶顯示器等的顯示裝置108中的顯示面板110上。自上表面觀看時,感測器本體102具有配置於與顯示面板110的顯示畫面110a對應的區域中的感測器部112、以及配置於與顯示面板110的外周部分對應的區域中的端子配線部114(所謂邊框)。The touch panel 100 includes a sensor body 102 and a control circuit (consisting of an IC circuit or the like) (not shown). As shown in FIG. 3, FIG. 4, and FIG. 5A, the sensor body 102 has a conductive sheet for a touch panel of the first embodiment which is formed by laminating the first conductive sheet 10A and a second conductive sheet 10B to be described later (hereinafter It is referred to as a first build-up conductive sheet 50A), and a protective layer 106 laminated on the first build-up conductive sheet 50A (the protective layer 106 is omitted in FIG. 5A). Record). The first build-up conductive sheet 50A and the protective layer 106 are, for example, disposed on the display panel 110 of the display device 108 such as a liquid crystal display. The sensor body 102 has a sensor portion 112 disposed in a region corresponding to the display screen 110a of the display panel 110 and a terminal wiring disposed in a region corresponding to the outer peripheral portion of the display panel 110 when viewed from the upper surface. Part 114 (so-called frame).

應用於觸控面板100中的第1導電片10A如圖4所示,於與感測器部112相對應的部分,排列有上述多數個第1導電圖案22A,於端子配線部114,排列有自各第1結線部40a導出的由金屬細線形成的多個第1端子配線圖案41a。As shown in FIG. 4, the first conductive sheet 10A applied to the touch panel 100 has a plurality of first conductive patterns 22A arranged in a portion corresponding to the sensor portion 112, and is arranged in the terminal wiring portion 114. A plurality of first terminal wiring patterns 41a formed of thin metal wires which are led out from the respective first junction portions 40a.

圖3的例子中,自上表面觀看時,第1導電片10A的外形具有長方形狀,感測器部112的外形亦具有長方形狀。端子配線部114中,於第1導電片10A的一條長邊側的周緣部,在其長度方向中央部分,在上述一條長邊的長度方向上排列形成有多個第1端子116a。另外,沿著感測器部112的一條長邊(距第1導電片10A的一條長邊最近的長邊,y方向)而直線狀地排列有多個第1結線部40a。自各第1結線部40a導出的第1端子配線圖案41a被引導向第1導電片10A的一條長邊的大致中央部,分別電性連接於對應的第1端子116a。因此,與對應於感測器部112的一條長邊的兩側的各第1結線部40a連接的第1端子配線圖案41a是以大致相同的長度而引導。當然,亦可於第1導電片10A的角落部或其附近形成第1端子116a,然而 有以下問題:多個第1端子配線圖案41a中,最長的第1端子配線圖案41a與最短的第1端子配線圖案41a之間長度上產生較大的差異,對於與最長的第1端子配線圖案41a及其附近的多個第1端子配線圖案41a對應的第1導電圖案22A的訊號傳輸變慢。因此,藉由如本實施形態般於第1導電片10A的一條長邊的長度方向中央部分形成第1端子116a,可抑制局部的訊號傳輸的延遲,從而實現響應速度的高速化。In the example of FIG. 3, the outer shape of the first conductive sheet 10A has a rectangular shape when viewed from the upper surface, and the outer shape of the sensor portion 112 also has a rectangular shape. In the terminal wiring portion 114, a plurality of first terminals 116a are arranged in the longitudinal direction of the one long side in the longitudinal direction central portion of one of the long sides of the first conductive sheet 10A. Further, a plurality of first junction portions 40a are linearly arranged along one long side of the sensor portion 112 (the longest side closest to one long side of the first conductive sheet 10A, the y direction). The first terminal wiring pattern 41a led out from each of the first junction portions 40a is guided to a substantially central portion of one long side of the first conductive sheet 10A, and is electrically connected to the corresponding first terminal 116a. Therefore, the first terminal wiring patterns 41a connected to the respective first connection portions 40a on both sides of one long side of the sensor portion 112 are guided by substantially the same length. Of course, the first terminal 116a may be formed at or near the corner portion of the first conductive sheet 10A. In the plurality of first terminal wiring patterns 41a, the length between the longest first terminal wiring pattern 41a and the shortest first terminal wiring pattern 41a is greatly different, and the longest first terminal wiring pattern is used. The signal transmission of the first conductive pattern 22A corresponding to the plurality of first terminal wiring patterns 41a in the vicinity of 41a and the vicinity thereof becomes slow. Therefore, by forming the first terminal 116a in the central portion in the longitudinal direction of one long side of the first conductive sheet 10A as in the present embodiment, the delay of local signal transmission can be suppressed, and the response speed can be increased.

另一方面,第2導電片10B如圖3、圖4以及圖5A所示,具有形成於第2透明基體12B的一個主面上的第2導電部13B。該第2導電部13B形成有由金屬細線形成的2個以上的導電性的第2大格子14B、以及將鄰接的第2大格子14B間電性連接的由金屬細線形成的第2連接部16B,各第2大格子14B如圖6所示,分別是由2個以上的小格子18組合而構成,第2連接部16B是藉由配置有具有小格子18的n倍(n為大於1的實數)的間距的1個以上的中格子20而構成。關於第2大格子14B的一邊的長度,亦與上述第1大格子14A相同,較佳為3mm~10mm,更佳為4mm~6mm。On the other hand, as shown in FIGS. 3, 4, and 5A, the second conductive sheet 10B has the second conductive portion 13B formed on one main surface of the second transparent substrate 12B. The second conductive portion 13B is formed with two or more conductive second large lattices 14B formed of thin metal wires, and a second connecting portion 16B formed of thin metal wires electrically connecting the adjacent second large lattices 14B. As shown in FIG. 6, each of the second large lattices 14B is composed of a combination of two or more small lattices 18, and the second connecting portion 16B is provided with n times having a small lattice 18 (n is greater than 1). One or more intermediate lattices 20 having a pitch of a real number are formed. The length of one side of the second large lattice 14B is also the same as that of the first large lattice 14A, and is preferably 3 mm to 10 mm, and more preferably 4 mm to 6 mm.

進而,將2個以上的第2大格子14B經由第2連接部16B排列於y方向(第2方向)上,從而構成由金屬細線形成的1個導電性的電路圖案(以下,記作第2導電圖案22B),將2個以上的第2導電圖案22B排列於與y方向正交的x方向(第1方向)上,且於鄰接的第2導電圖案22B 間配置有不存在小格子18的電性絕緣的第2絕緣部24B。Further, two or more second large lattices 14B are arranged in the y direction (second direction) via the second connecting portion 16B, thereby constituting one conductive circuit pattern formed of thin metal wires (hereinafter, referred to as second In the conductive pattern 22B), two or more second conductive patterns 22B are arranged in the x direction (first direction) orthogonal to the y direction, and adjacent to the second conductive patterns 22B The second insulating portion 24B having no electrical insulation of the small lattice 18 is disposed therebetween.

如圖4所示,在存在於每隔一個(例如第奇數個)的第2導電圖案22B的一個端部側之第2大格子14B的開放端、以及存在於第偶數個的第2導電圖案22B的另一端部側之第2大格子14B的開放端,分別成為不存在第2連接部16B的形狀。另一方面,存在於第奇數個的各第2導電圖案22B的另一端部側之第2大格子14B的端部、以及存在於第偶數個的各第2導電圖案22B的另一端部側之第2大格子14B的端部,分別經由第2結線部40b而電性連接於由金屬細線形成的第2端子配線圖案41b。As shown in FIG. 4, the open end of the second large lattice 14B existing on one end side of every other (for example, the odd-numbered) second conductive patterns 22B, and the second conductive pattern existing in the even number are present. The open ends of the second large lattices 14B on the other end side of the 22B are in a shape in which the second connecting portions 16B are not present. On the other hand, the end portion of the second large lattice 14B on the other end side of each of the odd-numbered second conductive patterns 22B and the other end portion side of the even-numbered second conductive patterns 22B exist. The end of the second large lattice 14B is electrically connected to the second terminal wiring pattern 41b formed of thin metal wires via the second junction portion 40b.

而且,於對應於感測器部112的部分,排列有多數個第2導電圖案22B,於端子配線部114,排列有自各第2結線部40b導出的多個第2端子配線圖案41b。Further, a plurality of second conductive patterns 22B are arranged in a portion corresponding to the sensor portion 112, and a plurality of second terminal wiring patterns 41b derived from the respective second connection portions 40b are arranged in the terminal wiring portion 114.

如圖3所示,端子配線部114中,於第2導電片10B的一條長邊側的周緣部,於其長度方向中央部分,在上述一條長邊的長度方向上排列形成有多個第2端子116b。另外,沿著感測器部112的一條短邊(距第2導電片10B的一條短邊最近的短邊,x方向),直線狀地排列有多個第2結線部40b(例如第奇數個的第2結線部40b),沿著感測器部112的另一短邊(距第2導電片10B的另一短邊最近的短邊,x方向),直線狀地排列有多個第2結線部40b(例如第偶數個的第2結線部40b)。As shown in FIG. 3, in the terminal wiring portion 114, a plurality of second portions are arranged in the longitudinal direction of the one long side of the peripheral portion of the long side of the second conductive sheet 10B in the longitudinal direction. Terminal 116b. Further, a plurality of second junction portions 40b are arranged linearly along one short side of the sensor portion 112 (the short side closest to one short side of the second conductive sheet 10B, and the x direction) (for example, the odd number The second junction portion 40b) is linearly arranged along the other short side of the sensor portion 112 (the short side closest to the other short side of the second conductive sheet 10B, the x direction). The junction portion 40b (for example, the even-numbered second junction portion 40b).

多個第2導電圖案22B中,例如第奇數個的第2導電圖案22B分別連接於對應的第奇數個的第2結線部40b, 第偶數個的第2導電圖案22B分別連接於對應的第偶數個的第2結線部40b。自第奇數個的第2結線部40b導出的第2端子配線圖案41b以及自第偶數個的第2結線部40b導出的第2端子配線圖案41b被引導向第2導電片10B的一條長邊的大致中央部,分別電性連接於對應的第2端子116b。因此,例如第1個第2端子配線圖案41b與第2個第2端子配線圖案41b是以大致相同的長度而引導,以下相同,第2n-1個的第2端子配線圖案41b與第2n個的第2端子配線圖案41b是以大致相同的長度而引導(n=1、2、3…)。Among the plurality of second conductive patterns 22B, for example, the odd-numbered second conductive patterns 22B are respectively connected to the corresponding odd-numbered second connection portions 40b. The even-numbered second conductive patterns 22B are respectively connected to the corresponding even-numbered second junction portions 40b. The second terminal wiring pattern 41b derived from the odd-numbered second junction portion 40b and the second terminal wiring pattern 41b derived from the even-numbered second junction portion 40b are guided to one long side of the second conductive sheet 10B. The substantially central portion is electrically connected to the corresponding second terminal 116b. Therefore, for example, the first and second terminal wiring patterns 41b and the second and second terminal wiring patterns 41b are guided by substantially the same length, and the second and second second terminal wiring patterns 41b and 2n are the same. The second terminal wiring patterns 41b are guided by substantially the same length (n=1, 2, 3, . . . ).

當然,亦可於第2導電片10B的角落部或其附近形成第2端子116b,然而如上所述,存在以下問題:對於與最長的第2端子配線圖案41b及其附近的多個第2端子配線圖案41b對應的第2導電圖案22B的訊號傳輸變慢。因此,藉由如本實施形態般於第2導電片10B的一條長邊的長度方向中央部分形成第2端子116b,可抑制局部的訊號傳輸的延遲,從而實現響應速度的高速化。Needless to say, the second terminal 116b may be formed in the corner portion of the second conductive sheet 10B or in the vicinity thereof. However, as described above, the second terminal wiring pattern 41b and the plurality of second terminals in the vicinity thereof are the longest. The signal transmission of the second conductive pattern 22B corresponding to the wiring pattern 41b becomes slow. Therefore, by forming the second terminal 116b in the central portion in the longitudinal direction of one long side of the second conductive sheet 10B as in the present embodiment, the delay of local signal transmission can be suppressed, and the response speed can be increased.

再者,亦可使第1端子配線圖案41a的導出形態與上述第2端子配線圖案41b相同,使第2端子配線圖案41b的導出形態與上述第1端子配線圖案41a相同。In addition, the lead-out pattern of the first terminal wiring pattern 41a may be the same as that of the second terminal wiring pattern 41b, and the lead-out pattern of the second terminal wiring pattern 41b may be the same as that of the first terminal wiring pattern 41a.

而且,於將該第1積層導電片50A用作觸控面板時,於第1導電片10A上形成保護層,並將自第1導電片10A的多數個第1導電圖案22A導出的第1端子配線圖案41a、與自第2導電片10B的多個第2導電圖案22B導出 的第2端子配線圖案41b連接於例如控制掃描的控制電路。When the first laminated conductive sheet 50A is used as a touch panel, a protective layer is formed on the first conductive sheet 10A, and the first terminal derived from the plurality of first conductive patterns 22A of the first conductive sheet 10A is formed. The wiring pattern 41a and the plurality of second conductive patterns 22B derived from the second conductive sheet 10B are derived The second terminal wiring pattern 41b is connected to, for example, a control circuit that controls scanning.

作為觸控位置的檢測方式,可較佳地採用自電容(self capacitive)方式或互電容(mutual capacitive)方式。即,若為自電容方式,則對第1導電圖案22A依序供給用以檢測觸控位置的電壓訊號,對第2導電圖案22B依序供給用以檢測觸控位置的電壓訊號。使指尖接觸或接近保護層106的上表面,由此和觸控位置相向的第1導電圖案22A及第2導電圖案22B與GND(地線)之間的電容增大,因此來自該第1導電圖案22A及第2導電圖案22B的傳輸訊號的波形成為與來自其他導電圖案的傳輸訊號的波形不同的波形。因此,控制電路根據由第1導電圖案22A及第2導電圖案22B所供給的傳輸訊號來運算觸控位置。另一方面,互電容方式的情況下,例如對第1導電圖案22A依序供給用以檢測觸控位置的電壓訊號,對第2導電圖案22B依序進行感測(傳輸訊號的檢測)。使指尖接觸或接近保護層106的上表面,由此對和觸控位置相向的第1導電圖案22A與第2導電圖案22B間的寄生電容並列地增加手指的浮游電容,因此來自該第2導電圖案22B的傳輸訊號的波形成為與來自其他第2導電圖案22B的傳輸訊號的波形不同的波形。因此,控制電路根據供給電壓訊號的第1導電圖案22A的次序、及所供給的來自第2導電圖案22B的傳輸訊號來運算觸控位置。藉由採用此種自電容方式或互電容方式的觸控位置的檢測方法,即便同時使2個指尖接觸或接近保護層106的上表面,亦可檢測各觸控位置。 再者,與投影型靜電電容式的檢測電路相關的先前技術文獻有美國專利第4,582,955號說明書、美國專利第4,686,332號說明書、美國專利第4,733,222號說明書、美國專利第5,374,787號說明書、美國專利第5,543,588號說明書、美國專利第7,030,860號說明書、美國公開專利2004/0155871號說明書等。As a method of detecting the touch position, a self capacitive method or a mutual capacitive method can be preferably used. That is, in the case of the self-capacitance mode, the first conductive pattern 22A is sequentially supplied with a voltage signal for detecting the touch position, and the second conductive pattern 22B is sequentially supplied with a voltage signal for detecting the touch position. Since the fingertip is brought into contact with or close to the upper surface of the protective layer 106, the capacitance between the first conductive pattern 22A and the second conductive pattern 22B and the GND (ground) which opposes the touch position increases, and thus the first The waveforms of the transmission signals of the conductive patterns 22A and the second conductive patterns 22B are different from the waveforms of the transmission signals from the other conductive patterns. Therefore, the control circuit calculates the touch position based on the transmission signals supplied from the first conductive pattern 22A and the second conductive pattern 22B. On the other hand, in the case of the mutual capacitance method, for example, a voltage signal for detecting a touch position is sequentially supplied to the first conductive pattern 22A, and the second conductive pattern 22B is sequentially sensed (detection of a transmission signal). The fingertip is brought into contact with or close to the upper surface of the protective layer 106, thereby increasing the floating capacitance of the finger in parallel with the parasitic capacitance between the first conductive pattern 22A and the second conductive pattern 22B facing the touch position. The waveform of the transmission signal of the conductive pattern 22B is a waveform different from the waveform of the transmission signal from the other second conductive pattern 22B. Therefore, the control circuit calculates the touch position based on the order of the first conductive patterns 22A to which the voltage signals are supplied and the supplied transmission signals from the second conductive patterns 22B. By adopting such a self-capacitance method or a mutual capacitance type touch position detecting method, even if two fingertips are simultaneously brought into contact with or close to the upper surface of the protective layer 106, each touch position can be detected. Further, the prior art documents relating to the projection type electrostatic capacitance type detection circuit include the specification of U.S. Patent No. 4,582,955, the specification of U.S. Patent No. 4,686,332, the specification of U.S. Patent No. 4,733,222, the specification of U.S. Patent No. 5,374,787, and U.S. Patent No. 5,543,588. The specification, the specification of U.S. Patent No. 7,030,860, the specification of U.S. Patent Publication No. 2004/0155871, and the like.

而且,如圖6所示,若觀看第2導電圖案22B的第2大格子14B的4個邊部中,鄰接於不與鄰接的第2大格子14B連接的一個頂點部分26a的第5邊部28e以及第6邊部28f,則第5邊部28e與第1導電片10A中的第1大格子14A的第1邊部28a相同,成為多數個針狀的線32(小格子18的邊)自沿著第5邊部28e連續的直線部30梳齒狀地伸出的形態。第6邊部28f與第1導電片10A中的第1大格子14A的第3邊部28c相同,成為形成有沿著第6邊部28f連續的直線部30的形態。若觀看和不與鄰接的第2大格子14B連接的另一頂點部分26b鄰接的第7邊部28g以及第8邊部28h,則第7邊部28g與第5邊部28e相同,成為多數個針狀的線32(小格子18的邊)自沿著第7邊部28g連續的直線部30梳齒狀地伸出的形態,第8邊部28h與第6邊部28f相同,成為形成有沿著第8邊部28h連續的直線部30的形態。Further, as shown in FIG. 6, when the four side portions of the second large lattice 14B of the second conductive pattern 22B are viewed, the fifth side portion of one vertex portion 26a that is not connected to the adjacent second large lattice 14B is adjacent. In the 28e and the sixth side portion 28f, the fifth side portion 28e is the same as the first side portion 28a of the first large lattice 14A in the first conductive sheet 10A, and is a plurality of needle-shaped lines 32 (edges of the small lattice 18). A form in which the straight portion 30 continuous along the fifth side portion 28e is extended in a comb shape. Similarly to the third side portion 28c of the first large lattice 14A in the first conductive sheet 10A, the sixth side portion 28f is formed to have a straight portion 30 continuous along the sixth side portion 28f. When the seventh side portion 28g and the eighth side portion 28h which are adjacent to the other apex portion 26b which is not connected to the adjacent second large lattice 14B are viewed, the seventh side portion 28g is the same as the fifth side portion 28e, and is plural. The acicular line 32 (the side of the small lattice 18) is formed in a comb-like shape from the straight portion 30 continuous along the seventh side portion 28g, and the eighth side portion 28h is formed in the same manner as the sixth side portion 28f. The form of the straight portion 30 that continues along the eighth side portion 28h.

另外,第2連接部16B具有4個中格子20(第5中格子20e~第8中格子20h)鋸齒狀地排列的形狀,該中格子20具有包含4個小格子18的大小。即,第5中格子20e 存在於第6邊部28f的第2條直線部30(自最外側朝向第2大格子14B的內部的第2條直線部)與第8邊部28h的直線部30的交界部分,具有與1個小格子18形成L字形的空間的形狀。第6中格子20f鄰接於第5中格子20e的1條邊(第6邊部28f的第2條直線部30),具有形成有正方形的空間的形狀,即,由4個小格子18排列成矩陣狀並將中央的十字去掉的形狀。第7中格子20g與第5中格子20e鄰接,並且與第6中格子20f鄰接而配置,具有與第6中格子20f相同的形狀。第8中格子20h存在於第7邊部28g的直線部30與第5邊部28e的交界部分,與第6中格子20f鄰接,並且與第7中格子20g鄰接而配置,與第5中格子20e同樣地具有與1個小格子18形成L字形的空間的形狀。第8中格子20h的1條邊存在於第5中格子20e的第8邊部28h的直線部30的延長線上。對於該第2導電片10B而言,當將小格子18的排列間距設為Ps時,中格子20的排列間距Pm亦有2×Ps的關係。另外,第2連接部的寬度Wc2(第6中格子20f的頂點至第7中格子20g的頂點之間、且沿著x方向的距離)滿足Wc2>Ps/,此處為6×(Ps/)。Further, the second connecting portion 16B has a shape in which four intermediate lattices 20 (the fifth intermediate lattice 20e to the eighth intermediate lattice 20h) are arranged in a zigzag shape, and the intermediate lattice 20 has a size including four small lattices 18. In other words, the fifth intermediate lattice 20e is present in the second straight portion 30 of the sixth side portion 28f (the second straight portion from the outermost side toward the inside of the second large lattice 14B) and the straight portion 30 of the eighth side portion 28h. The boundary portion has a shape in which an L-shaped space is formed with one small lattice 18. The sixth intermediate lattice 20f is adjacent to one side of the fifth intermediate lattice 20e (the second linear portion 30 of the sixth side portion 28f), and has a shape in which a square space is formed, that is, a matrix formed by four small lattices 18 Shape that will remove the central cross. The seventh middle lattice 20g is adjacent to the fifth intermediate lattice 20e, and is disposed adjacent to the sixth intermediate lattice 20f, and has the same shape as the sixth intermediate lattice 20f. The eighth intermediate lattice 20h is present at a boundary portion between the linear portion 30 and the fifth side portion 28e of the seventh side portion 28g, is adjacent to the sixth intermediate lattice 20f, and is disposed adjacent to the seventh intermediate lattice 20g, and is arranged in the fifth intermediate lattice. 20e similarly has a shape in which an L-shaped space is formed with one small lattice 18. One side of the eighth middle lattice 20h exists on the extension line of the straight portion 30 of the eighth side portion 28h of the fifth middle lattice 20e. In the second conductive sheet 10B, when the arrangement pitch of the small lattices 18 is Ps, the arrangement pitch Pm of the intermediate lattices 20 also has a relationship of 2 × Ps. Further, the width Wc2 of the second connecting portion (the distance from the vertex of the sixth middle lattice 20f to the apex of the seventh intermediate lattice 20g and along the x direction) satisfies Wc2>Ps/ , here is 6×(Ps/ ).

而且,例如於第2導電片10B上積層第1導電片10A而製成第1積層導電片50A時,如圖7所示,第1導電圖案22A的第1連接部16A與第2導電圖案22B的第2連接部16B成為將第1透明基體12A(參照圖5A)夾在中間而相向的形態,第1導電圖案22A的第1絕緣部24A與 第2導電圖案22B的第2絕緣部24B同樣地成為將第1透明基體12A夾在中間而相向的形態。再者,第1導電圖案22A與第2導電圖案22B的各線寬相同,然而圖7中,為了使第1導電圖案22A與第2導電圖案22B的位置明瞭,圖中誇張地使第1導電圖案22A的線寬變粗,使第2導電圖案22B的線寬變細。When the first conductive sheet 10A is laminated on the second conductive sheet 10B to form the first laminated conductive sheet 50A, as shown in FIG. 7, the first connecting portion 16A and the second conductive pattern 22B of the first conductive pattern 22A are formed. The second connecting portion 16B is in a state in which the first transparent substrate 12A (see FIG. 5A) is opposed to each other, and the first insulating portion 24A of the first conductive pattern 22A is Similarly, in the second insulating portion 24B of the second conductive pattern 22B, the first transparent substrate 12A is opposed to each other with the first transparent substrate 12A interposed therebetween. Further, the respective line widths of the first conductive pattern 22A and the second conductive pattern 22B are the same. However, in FIG. 7, in order to make the positions of the first conductive pattern 22A and the second conductive pattern 22B clear, the first conductive pattern is exaggerated in the drawing. The line width of 22A becomes thicker, and the line width of the second conductive pattern 22B is made thinner.

自上表面觀看積層的第1導電片10A及第2導電片10B時,成為以填埋第1導電片10A上形成的第1大格子14A的間隙的方式而排列有第2導電片10B的第2大格子14B的形態。即,成為鋪滿大格子的形態。此時,第1大格子14A的第1邊部28a以及第2邊部28b的梳齒32的各頂端成為由第2大格子14B的第6邊部28f以及第8邊部28h的各直線部30所連接的形狀,結果成為排列有小格子18的形態,同樣,第2大格子14B的第5邊部28e以及第7邊部28g的梳齒32的各頂端成為由第1大格子14A的第3邊部28c以及第4邊部28d的各直線部30所連接的形狀,結果成為排列有小格子18的形態,且成為幾乎無法辨別第1大格子14A與第2大格子14B的邊界的狀態。When the laminated first conductive sheet 10A and the second conductive sheet 10B are viewed from the upper surface, the second conductive sheet 10B is arranged so as to fill the gap between the first large lattices 14A formed on the first conductive sheet 10A. 2 large lattice 14B form. That is, it becomes a form in which a large lattice is spread. At this time, the respective distal ends of the comb teeth 32 of the first side portion 28a and the second side portion 28b of the first large lattice 14A are the straight portions of the sixth side portion 28f and the eighth side portion 28h of the second large lattice 14B. As a result of the 30 connected shapes, the small lattices 18 are arranged. Similarly, the respective distal ends of the comb teeth 32 of the fifth side portion 28e and the seventh side portion 28g of the second large lattice 14B are formed by the first large lattice 14A. The shape in which the linear portions 30 of the third side portion 28c and the fourth side portion 28d are connected is such that the small lattices 18 are arranged, and the boundary between the first large lattice 14A and the second large lattice 14B is hardly distinguishable. status.

此處,例如於使第1大格子14A以及第2大格子14B的邊部全部形成為直線部30的情形時,即,於將自第1大格子14A的第1邊部28a以及第2邊部28b伸出的多數條線32的開放端連接而形成新的直線部30、同樣地將自第2大格子14B的第5邊部28e以及第7邊部28g伸出的多數條線32的開放端連接而形成新的直線部30的情形 時,會產生以下問題:由於重合的位置精度的稍許偏差,直線部30彼此的重疊部分的寬度變大(粗線),由此第1大格子14A與第2大格子14B的邊界顯眼,視認性惡化,而本實施形態中如上所述,藉由梳齒32的頂端與直線部30的重疊,第1大格子14A與第2大格子14B的邊界不顯眼,視認性提昇。再者,第1絕緣部24A與第2絕緣部24B相向的部分形成有1個中格子的程度的開口,但其與上述粗線不同,並不遮光,因此在外部幾乎不顯眼。特別是若為1個中格子的程度的開口,則與周圍的小格子18相比尺寸上幾乎相同,故更不顯眼。Here, for example, when all of the side portions of the first large lattice 14A and the second large lattice 14B are formed as the straight portion 30, that is, the first side portion 28a and the second side of the first large lattice 14A are formed. The open ends of the plurality of lines 32 extending from the portion 28b are connected to form a new straight portion 30, and the plurality of lines 32 extending from the fifth side portion 28e and the seventh side portion 28g of the second large lattice 14B are similarly formed. The case where the open end is connected to form a new straight portion 30 When there is a slight deviation in the positional accuracy of the overlap, the width of the overlapping portion of the straight portions 30 becomes larger (thick line), whereby the boundary between the first large lattice 14A and the second large lattice 14B is conspicuous, and the visibility is recognized. In the present embodiment, as described above, by the overlap of the distal end of the comb tooth 32 and the linear portion 30, the boundary between the first large lattice 14A and the second large lattice 14B is inconspicuous, and the visibility is improved. In addition, the portion in which the first insulating portion 24A and the second insulating portion 24B face each other has one opening in the middle lattice. However, unlike the above-described thick line, the first insulating portion 24A does not block light, and thus is hardly conspicuous to the outside. In particular, if the opening is one of the middle lattices, the size is almost the same as that of the surrounding small lattices 18, so that it is less conspicuous.

另外,例如於使第1大格子14A以及第2大格子14B的第1邊部28a~第8邊部28h全部形成為直線部30的情形時,第2大格子14B的第5邊部28e~第8邊部28h的直線部30位於第1大格子14A的第1邊部28a~第4邊部28d的直線部30的正下方。此時,由於各直線部30亦作為導電部分而發揮功能,故於第1大格子14A的邊部與第2大格子14B的邊部之間形成寄生電容,該寄生電容的存在對於電荷資訊而言起到雜訊(noise)成分的作用,引起訊雜比(Signal to Noise ratio,S/N比)的顯著下降。而且,因於各第1大格子14A與各第2大格子14B間形成有寄生電容,故成為第1導電圖案22A與第2導電圖案22B間並列連接有多數個寄生電容的形態,結果存在CR時間常數變大的問題。若CR時間常數變大,則可能導致供給於第1導電圖案22A(以及第2導電圖案22B)的電壓訊號的 波形的上升時間變慢,於特定的掃描時間內幾乎不會產生用以檢測位置的電場。另外,來自第1導電圖案22A以及第2導電圖案22B的傳輸訊號的波形的上升時間或下降時間亦變慢,可能於特定的掃描時間內無法捕捉傳輸訊號的波形的變化,而導致檢測精度下降、響應速度下降。即,為了實現檢測精度的提昇、響應速度的提昇,只有減少第1大格子14A以及第2大格子14B的個數(降低解析度)、或減小適應的顯示畫面的尺寸,而產生無法例如應用於B5版、A4版及該尺寸以上的大畫面的問題。In addition, for example, when all of the first side portion 28a to the eighth side portion 28h of the first large lattice 14A and the second large lattice 14B are formed as the straight portion 30, the fifth side portion 28e of the second large lattice 14B is The linear portion 30 of the eighth side portion 28h is located directly below the straight portion 30 of the first side portion 28a to the fourth side portion 28d of the first large lattice 14A. At this time, since each linear portion 30 also functions as a conductive portion, a parasitic capacitance is formed between the side portion of the first large lattice 14A and the side portion of the second large lattice 14B, and the existence of the parasitic capacitance is for charge information. It acts as a noise component, causing a significant drop in the Signal to Noise ratio (S/N ratio). In addition, since parasitic capacitance is formed between each of the first large lattices 14A and the second large lattices 14B, a plurality of parasitic capacitances are connected in parallel between the first conductive patterns 22A and the second conductive patterns 22B, and as a result, CR is present. The problem of a large time constant. If the CR time constant becomes large, the voltage signals supplied to the first conductive pattern 22A (and the second conductive pattern 22B) may be caused. The rise time of the waveform becomes slower, and an electric field for detecting the position is hardly generated in a specific scanning time. In addition, the rising time or falling time of the waveform of the transmission signal from the first conductive pattern 22A and the second conductive pattern 22B is also slow, and the waveform of the transmission signal cannot be captured during a specific scanning time, resulting in a decrease in detection accuracy. The response speed is reduced. In other words, in order to improve the detection accuracy and improve the response speed, only the number of the first large lattices 14A and the second large lattices 14B is reduced (the resolution is lowered), or the size of the adaptive display screen is reduced. It is applied to the B5 version, the A4 version, and the large screen above this size.

相對於此,本實施形態中,如圖5A所示,使第1大格子14A的邊部的直線部30與第2大格子14B的邊部的直線部30之投影距離Lf和小格子18的1條邊的長度(50μm~500μm)大致相同。進而,自第1大格子14A的第1邊部28a以及第2邊部28b伸出的針狀的線32分別是僅頂端與第2大格子14B的第6邊部28f以及第8邊部28h的直線部30相向,且自第2大格子14B的第5邊部28e以及第7邊部28g伸出的針狀的線32分別是僅頂端與第1大格子14A的第3邊部28c以及第4邊部28d的直線部30相向,因此形成於第1大格子14A與第2大格子14B之間的寄生電容變小。結果CR時間常數亦變小,可實現檢測精度的提昇、響應速度的提昇。On the other hand, in the present embodiment, as shown in FIG. 5A, the projection distance Lf between the straight portion 30 of the side portion of the first large lattice 14A and the straight portion 30 of the side portion of the second large lattice 14B and the small lattice 18 are formed. The length of one side (50 μm to 500 μm) is substantially the same. Further, the needle-shaped wires 32 extending from the first side portion 28a and the second side portion 28b of the first large lattice 14A are only the distal end and the sixth side portion 28f and the eighth side portion 28h of the second large lattice 14B. The linear portions 30 are opposed to each other, and the needle-shaped wires 32 extending from the fifth side portion 28e and the seventh side portion 28g of the second large lattice 14B are only the distal end and the third side portion 28c of the first large lattice 14A, and Since the straight portions 30 of the fourth side portion 28d face each other, the parasitic capacitance formed between the first large lattice 14A and the second large lattice 14B becomes small. As a result, the CR time constant is also reduced, and the detection accuracy can be improved and the response speed can be improved.

關於上述投影距離Lf的最適距離,較佳為相較於第1大格子14A以及第2大格子14B的尺寸而根據構成第1大格子14A以及第2大格子14B的小格子18的尺寸(線寬 以及一邊的長度)來適當設定。此時,若小格子18的尺寸相對於具有一定尺寸的第1大格子14A以及第2大格子14B而過大,則雖然透光性提昇,但可能由於傳輸訊號的動態範圍(dynamic range)變小而引起檢測感度下降。相反,若小格子18的尺寸過小,則雖然檢測感度提昇,但可能由於線寬的減小有限而透光性惡化。The optimum distance of the projection distance Lf is preferably a size of the small lattice 18 constituting the first large lattice 14A and the second large lattice 14B compared to the sizes of the first large lattice 14A and the second large lattice 14B. width And the length of one side) is set as appropriate. At this time, if the size of the small lattice 18 is too large with respect to the first large lattice 14A and the second large lattice 14B having a certain size, the light transmittance is improved, but the dynamic range of the transmission signal may be small. And the detection sensitivity is reduced. On the contrary, if the size of the small lattice 18 is too small, although the detection sensitivity is improved, the light transmittance may be deteriorated due to the limited reduction in the line width.

因此,於將小格子18的線寬設為1μm~9μm時,上述投影距離Lf的最適值(最適距離)較佳為100μm~400μm,更佳為200μm~300μm。若使小格子18的線寬變窄,則雖然上述最適距離亦可縮短,但電阻變高,因此即便寄生電容變小,CR時間常數亦變高,結果可能引起檢測感度下降、響應速度下降。因此,小格子18的線寬較佳為上述範圍。Therefore, when the line width of the small lattice 18 is 1 μm to 9 μm, the optimum value (optimum distance) of the projection distance Lf is preferably 100 μm to 400 μm, and more preferably 200 μm to 300 μm. When the line width of the small lattice 18 is narrowed, the optimum distance can be shortened, but the electric resistance is increased. Therefore, even if the parasitic capacitance is small, the CR time constant is also increased, and as a result, the detection sensitivity is lowered and the response speed is lowered. Therefore, the line width of the small lattice 18 is preferably in the above range.

而且,例如根據顯示面板110的尺寸或感測器部112的尺寸以及觸控位置檢測的解析度(驅動脈波的脈波週期)來決定第1大格子14A及第2大格子14B的尺寸以及小格子18的尺寸,以小格子18的線寬為基準來算出第1大格子14A與第2大格子14B間的最適距離。Further, for example, the size of the first large lattice 14A and the second large lattice 14B is determined according to the size of the display panel 110 or the size of the sensor portion 112 and the resolution of the touch position detection (pulse period of the driving pulse wave). The size of the small lattice 18 is calculated based on the line width of the small lattice 18, and the optimum distance between the first large lattice 14A and the second large lattice 14B is calculated.

另外,自上表面觀看第1連接部16A與第2連接部16B相向的部分時,第2連接部16B的第5中格子20e與第7中格子20g的交點位於第1大格子14A的第2中格子20b的大致中心,第2連接部16B的第6中格子20f與第8中格子20h的交點位於第1大格子14A的第3中格子20c的大致中心,藉由該些第1中格子20a~第8中格子20h 的組合,而成為形成有多個小格子18的形態。即,於第1連接部16A與第2連接部16B相向的部分,藉由第1連接部16A與第2連接部16B的組合,而成為排列有多個小格子18的形態,與周圍的構成第1大格子14A的小格子18或構成第2大格子14B的小格子18不相區分,視認性提昇。When the portion where the first connecting portion 16A and the second connecting portion 16B face each other is viewed from the upper surface, the intersection of the fifth intermediate lattice 20e and the seventh intermediate lattice 20g of the second connecting portion 16B is located at the second of the first large lattice 14A. The substantially center of the middle lattice 20b, the intersection of the sixth intermediate lattice 20f and the eighth intermediate lattice 20h of the second connecting portion 16B is located substantially at the center of the third intermediate lattice 20c of the first large lattice 14A, and the first intermediate lattice 20a~8th grid 20h The combination is formed into a form in which a plurality of small lattices 18 are formed. In other words, in the portion where the first connecting portion 16A and the second connecting portion 16B face each other, a combination of the first connecting portion 16A and the second connecting portion 16B forms a plurality of small lattices 18, and the surrounding configuration The small lattice 18 of the first large lattice 14A or the small lattice 18 constituting the second large lattice 14B are not distinguished, and the visibility is improved.

本實施形態中,於端子配線部114中,在第1導電片10A的一條長邊側的周緣部的長度方向中央部分形成多個第1端子116a,於第2導電片10B的一條長邊側的周緣部的長度方向中央部分形成多個第2端子116b。特別是圖3的例子中,第1端子116a與第2端子116b是以不重疊且相接近的狀態而排列,進而,使第1端子配線圖案41a與第2端子配線圖案41b上下不重疊。再者,亦可形成第1端子116a與例如第奇數個的第2端子配線圖案41b為一部分上下重疊的形態。In the present embodiment, a plurality of first terminals 116a are formed in the central portion in the longitudinal direction of the peripheral portion of one long side of the first conductive sheet 10A in the terminal wiring portion 114, and one long side of the second conductive sheet 10B is formed. A plurality of second terminals 116b are formed in a central portion in the longitudinal direction of the peripheral portion. In particular, in the example of FIG. 3, the first terminal 116a and the second terminal 116b are arranged in a state in which they are not overlapped, and the first terminal wiring pattern 41a and the second terminal wiring pattern 41b are not vertically overlapped. In addition, for example, the first terminal 116a and the second terminal wiring pattern 41b of the odd number may be vertically overlapped.

藉此,可經由2個連接器(第1端子用連接器以及第2端子用連接器)或1個連接器(連接於第1端子116a以及第2端子116b的複合連接器)以及電纜(cable),將多個第1端子116a以及多個第2端子116b電性連接於控制電路。Thereby, it is possible to pass through two connectors (the first terminal connector and the second terminal connector) or one connector (the composite connector connected to the first terminal 116a and the second terminal 116b) and the cable (cable) The plurality of first terminals 116a and the plurality of second terminals 116b are electrically connected to the control circuit.

另外,由於使第1端子配線圖案41a與第2端子配線圖案41b不上下重疊,因此可抑制第1端子配線圖案41a與第2端子配線圖案41b之間產生寄生電容,抑制響應速度下降。In addition, since the first terminal wiring pattern 41a and the second terminal wiring pattern 41b are not vertically overlapped, generation of parasitic capacitance between the first terminal wiring pattern 41a and the second terminal wiring pattern 41b can be suppressed, and the decrease in response speed can be suppressed.

由於沿著感測器部112的一條長邊排列第1結線部40a,且沿著感測器部112的兩側的短邊排列第2結線部40b,故可減少端子配線部114的面積。此種情況可促進含有觸控面板100的顯示面板110的小型化,並且可使顯示畫面110a給人以看起來較大的印象。另外,可使作為觸控面板100的操作性亦提昇。Since the first junction portion 40a is arranged along one long side of the sensor portion 112, and the second junction portion 40b is arranged along the short sides of both sides of the sensor portion 112, the area of the terminal wiring portion 114 can be reduced. Such a situation can promote miniaturization of the display panel 110 including the touch panel 100, and can cause the display screen 110a to give a large impression. In addition, the operability as the touch panel 100 can also be improved.

為了進一步減小端子配線部114的面積,可想到使鄰接的第1端子配線圖案41a間的距離、鄰接的第2端子配線圖案41b間的距離變窄,但此時,考慮到防止發生遷移(migration),較佳為10μm以上、50μm以下。In order to further reduce the area of the terminal wiring portion 114, it is conceivable to narrow the distance between the adjacent first terminal wiring patterns 41a and the distance between the adjacent second terminal wiring patterns 41b. However, in this case, it is considered that migration is prevented ( Migration) is preferably 10 μm or more and 50 μm or less.

此外,自上表面觀看時,可想到藉由在鄰接的第1端子配線圖案41a間配置第2端子配線圖案41b而減小端子配線部114的面積,但若圖案的形成有偏移,則可能第1端子配線圖案41a與第2端子配線圖案41b上下重疊,配線間的寄生電容變大,導致響應速度下降。因此,採用此種配置構成時,較佳為將鄰接的第1端子配線圖案41a間的距離設定為50μm以上、100μm以下。Further, when viewed from the upper surface, it is conceivable that the area of the terminal wiring portion 114 is reduced by arranging the second terminal wiring pattern 41b between the adjacent first terminal wiring patterns 41a. However, if the pattern is formed, the pattern may be shifted. The first terminal wiring pattern 41a and the second terminal wiring pattern 41b are vertically overlapped, and the parasitic capacitance between the wirings is increased, resulting in a decrease in response speed. Therefore, in the case of such an arrangement, it is preferable to set the distance between the adjacent first terminal wiring patterns 41a to 50 μm or more and 100 μm or less.

如此,對於第1積層導電片50A而言,於使用該第1積層導電片50A而應用於例如投影型靜電電容式的觸控面板100時,可提高響應速度,且可促進觸控面板100的大尺寸化。而且,第1導電片10A的第1大格子14A與第2導電片10B的第2大格子14B的邊界不顯眼,另外,藉由第1連接部16A與第2連接部16B的組合而形成有多個小格子18,故不存在局部產生粗線等不良狀況,整體的視認 性變良好。When the first multilayer conductive sheet 50A is applied to, for example, the projection type capacitive touch panel 100, the first multilayer conductive sheet 50A can improve the response speed and can facilitate the touch panel 100. Large size. Further, the boundary between the first large lattice 14A of the first conductive sheet 10A and the second large lattice 14B of the second conductive sheet 10B is inconspicuous, and a combination of the first connecting portion 16A and the second connecting portion 16B is formed. A plurality of small lattices 18, so there is no bad condition such as partial thick lines, and the overall visibility Sex has changed.

另外,可大幅度地減小多數個第1導電圖案22A以及第2導電圖案22B的CR時間常數,藉此可提高響應速度,驅動時間(掃描時間)內的位置檢測亦變容易。此種情況可促進觸控面板100的畫面尺寸(縱×橫的尺寸,不含厚度)的大型化。Further, the CR time constant of the plurality of first conductive patterns 22A and the second conductive patterns 22B can be greatly reduced, whereby the response speed can be improved, and position detection within the driving time (scanning time) can be facilitated. In this case, the size of the screen of the touch panel 100 (longitudinal × horizontal size, no thickness) can be increased.

上述第1積層導電片50A中,如圖4以及圖5A所示,於第1透明基體12A的一個主面上形成第1導電圖案22A,於第2透明基體12B的一個主面上形成第2導電圖案22B,但除此以外,亦可如圖5B所示,於第1透明基體12A的一個主面上形成第1導電圖案22A,於第1透明基體12A的另一主面上形成第2導電圖案22B。此時,不存在第2透明基體12B,而成為於第2導電部13B上積層有第1透明基體12A、於第1透明基體12A上積層有第1導電部13A的形態。另外,第1導電片10A與第2導電片10B之間亦可存在其他層,若第1導電圖案22A與第2導電圖案22B為絕緣狀態,則該些導電圖案亦可相向而配置。In the first laminated conductive sheet 50A, as shown in FIGS. 4 and 5A, the first conductive pattern 22A is formed on one main surface of the first transparent substrate 12A, and the second conductive layer 22A is formed on one main surface of the second transparent substrate 12B. In addition to the conductive pattern 22B, as shown in FIG. 5B, the first conductive pattern 22A may be formed on one main surface of the first transparent substrate 12A, and the second surface of the first transparent substrate 12A may be formed on the other main surface. Conductive pattern 22B. In this case, the second transparent substrate 12B is not present, and the first transparent substrate 12A is laminated on the second conductive portion 13B, and the first conductive portion 13A is laminated on the first transparent substrate 12A. Further, another layer may be present between the first conductive sheet 10A and the second conductive sheet 10B. When the first conductive pattern 22A and the second conductive pattern 22B are insulated, the conductive patterns may be arranged to face each other.

此時,如圖8A~圖8C中示意性地表示般,可較佳地採用三種構成態樣。At this time, as schematically shown in FIGS. 8A to 8C, three constitutional aspects can be preferably employed.

即,圖8A所示的第1構成例具有以下構成,於顯示裝置108上經由透明黏接劑120而積層有圖5B所示的第1積層導電片50A(第1導電部13A、第1透明基體12A以及第2導電部13B),進而,於該第1積層導電片50A上積層有硬塗層122,於該硬塗層122上積層有抗反射層 124。此處,由顯示裝置108上的透明黏接劑120、第2導電部13B、第1透明基體12A以及第1導電部13A構成觸控面板100,由該觸控面板100上的硬塗層122以及抗反射層124構成抗反射膜126。In other words, the first configuration example shown in FIG. 8A has the following configuration, and the first laminated conductive sheet 50A shown in FIG. 5B is laminated on the display device 108 via the transparent adhesive 120 (the first conductive portion 13A and the first transparent portion). Further, a base layer 12A and a second conductive portion 13B) are further provided with a hard coat layer 122 on the first build-up conductive sheet 50A, and an anti-reflection layer is laminated on the hard coat layer 122. 124. Here, the touch panel 100 is constituted by the transparent adhesive 120, the second conductive portion 13B, the first transparent substrate 12A, and the first conductive portion 13A on the display device 108, and the hard coat layer 122 on the touch panel 100 is formed. And the anti-reflection layer 124 constitutes an anti-reflection film 126.

圖8B所示的第2構成例具有以下構成:於顯示裝置108上經由透明黏接劑120而積層有圖5B所示的第1積層導電片50A及保護樹脂層128,進而,於該保護樹脂層128上積層有硬塗層122,於該硬塗層122上積層有抗反射層124。此處,由顯示裝置108上的透明黏接劑120、第2導電部13B、第1透明基體12A、第1導電部13A以及保護樹脂層128構成觸控面板100,由該觸控面板100上的硬塗層122以及抗反射層124構成抗反射膜126。The second configuration example shown in FIG. 8B has a configuration in which the first build-up conductive sheet 50A and the protective resin layer 128 shown in FIG. 5B are laminated on the display device 108 via the transparent adhesive 120, and further, the protective resin A hard coat layer 122 is laminated on the layer 128, and an anti-reflection layer 124 is laminated on the hard coat layer 122. Here, the transparent adhesive 120, the second conductive portion 13B, the first transparent substrate 12A, the first conductive portion 13A, and the protective resin layer 128 on the display device 108 constitute the touch panel 100 from the touch panel 100. The hard coat layer 122 and the anti-reflection layer 124 constitute an anti-reflection film 126.

圖8C所示的第3構成例具有以下構成:於顯示裝置108上經由第1透明黏接劑120A而積層有圖5B所示的第1積層導電片50A及第2透明黏接劑120B,進而,於該第2透明黏接劑120B上積層有透明膜130,於該透明膜130上積層有硬塗層122,於該硬塗層122上積層有抗反射層124。此處,由顯示裝置108上的第1透明黏接劑120A、第2導電部13B、第1透明基體12A、第1導電部13A以及第2透明黏接劑120B構成觸控面板100,由該觸控面板100上的透明膜130、硬塗層122以及抗反射層124構成抗反射膜126。The third configuration example shown in FIG. 8C has a configuration in which the first build-up conductive sheet 50A and the second transparent adhesive 120B shown in FIG. 5B are laminated on the display device 108 via the first transparent adhesive 120A. A transparent film 130 is laminated on the second transparent adhesive 120B, and a hard coat layer 122 is laminated on the transparent film 130, and an anti-reflection layer 124 is laminated on the hard coat layer 122. Here, the touch panel 100 is configured by the first transparent adhesive 120A, the second conductive portion 13B, the first transparent substrate 12A, the first conductive portion 13A, and the second transparent adhesive 120B on the display device 108. The transparent film 130, the hard coat layer 122, and the anti-reflection layer 124 on the touch panel 100 constitute an anti-reflection film 126.

另外,如圖3所示,較佳為於第1導電片10A及第2導電片10B的例如各角落部,形成第1導電片10A與第2 導電片10B貼合時所使用的定位用第1對準標記118a以及第2對準標記118b。該第1對準標記118a以及第2對準標記118b於將第1導電片10A與第2導電片10B貼合而製成第1積層導電片50A時,形成新的複合對準標記,該複合對準標記亦作為將該第1積層導電片50A設置於顯示面板110上時所使用的定位用的對準標記而發揮功能。Further, as shown in FIG. 3, it is preferable to form the first conductive sheet 10A and the second portion at, for example, corner portions of the first conductive sheet 10A and the second conductive sheet 10B. The positioning first alignment mark 118a and the second alignment mark 118b used when the conductive sheet 10B is bonded together. When the first conductive sheet 10A and the second conductive sheet 10B are bonded together to form the first laminated conductive sheet 50A, the first alignment mark 118a and the second alignment mark 118b form a new composite alignment mark, and the composite is formed. The alignment mark also functions as an alignment mark for positioning when the first build-up conductive sheet 50A is placed on the display panel 110.

繼而,參照圖9~圖12,對第2實施形態的觸控面板用導電片(以下,記作第2積層導電片50B)加以說明。Next, a conductive sheet for a touch panel (hereinafter referred to as a second build-up conductive sheet 50B) according to the second embodiment will be described with reference to FIG. 9 to FIG.

該第2積層導電片50B如圖9所示,具有與上述第1積層導電片50A大致相同的構成,但於以下方面不同:如圖10所示,第1大格子14A的第1邊部28a~第4邊部28d分別具有由2個以上的矩形形狀排列而成的矩形波形狀;如圖11所示,第2大格子14B的第5邊部28e~第8邊部28h分別具有由2個以上的矩形形狀排列而成的矩形波形狀。As shown in FIG. 9, the second build-up conductive sheet 50B has substantially the same configuration as the first laminated conductive sheet 50A, but differs in the following points: as shown in FIG. 10, the first side portion 28a of the first large lattice 14A The fourth side portion 28d has a rectangular wave shape in which two or more rectangular shapes are arranged. As shown in Fig. 11, the fifth side portion 28e to the eighth side portion 28h of the second large lattice 14B have two A rectangular wave shape in which a plurality of rectangular shapes are arranged.

具體而言,關於第1大格子14A,將圖1所示的第1導電片10A的第1大格子14A的第1邊部28a以及第2邊部28b的各梳齒32分別一個隔一個地相連,形成將小格子18一個隔一個地排列的形態,且將第3邊部28c以及第4邊部28d的各直線部30分別一個隔一個地分離,形成將小格子18一個隔一個地排列的形態,藉此如圖10所示,使第2積層導電片50B的第1大格子14A的第1邊部28a~第4邊部28d分別具有由2個以上的矩形形狀排列而成的矩形波形狀,特別是使第1大格子14A的第1邊部28a與 和該第1邊部28a相向的第4邊部28d的各矩形波形狀互不相同,且使第1大格子14A的第2邊部28b與和該第2邊部28b相向的第3邊部28c的各矩形波形狀互不相同。Specifically, in the first large lattice 14A, the comb teeth 32 of the first side portion 28a and the second side portion 28b of the first large lattice 14A of the first conductive sheet 10A shown in FIG. 1 are separated one by one. In the form of arranging the small lattices 18 one by one, the linear portions 30 of the third side portion 28c and the fourth side portion 28d are separated one by one, and the small lattices 18 are arranged one by one. As shown in FIG. 10, each of the first side portion 28a to the fourth side portion 28d of the first large lattice 14A of the second laminated conductive sheet 50B has a rectangular shape in which two or more rectangular shapes are arranged. The wave shape, in particular, the first side portion 28a of the first large lattice 14A and The rectangular wave shape of the fourth side portion 28d facing the first side portion 28a is different from each other, and the second side portion 28b of the first large lattice 14A and the third side portion facing the second side portion 28b are formed. The rectangular wave shapes of 28c are different from each other.

同樣地,對於第2大格子14B,將圖6所示的第2導電片10B的第2大格子14B的第5邊部28e以及第7邊部28g的各梳齒32分別一個隔一個地相連,形成將小格子18一個隔一個地排列的形態,且將第6邊部28f以及第8邊部28h的各直線部30分別一個隔一個地分離,形成將小格子18一個隔一個地排列的形態,藉此如圖11所示,使第2導電片10B的第2大格子14B的第5邊部28e~第8邊部28h分別具有由2個以上的矩形形狀排列而成的矩形波形狀,特別是使第2大格子14B的第5邊部28e與和該第5邊部28e相向的第8邊部28h的各矩形波形狀互不相同,使第2大格子14B的第6邊部28f與和該第6邊部28f相向的第7邊部28g的各矩形波形狀互不相同。Similarly, in the second large lattice 14B, the fifth side portion 28e of the second large lattice 14B and the comb teeth 32 of the seventh side portion 28g of the second conductive sheet 10B shown in Fig. 6 are connected one by one. In a form in which the small lattices 18 are arranged one by one, the linear portions 30 of the sixth side portion 28f and the eighth side portion 28h are separated one by one, and the small lattices 18 are arranged one by one. As shown in FIG. 11, the fifth side portion 28e to the eighth side portion 28h of the second large lattice 14B of the second conductive sheet 10B have a rectangular wave shape in which two or more rectangular shapes are arranged. In particular, the rectangular shape of the fifth side portion 28e of the second large lattice 14B and the eighth side portion 28h facing the fifth side portion 28e are different from each other, and the sixth side portion of the second large lattice 14B is made different. The shape of each rectangular wave of 28f and the seventh side portion 28g facing the sixth side portion 28f are different from each other.

而且,例如於第2導電片10B上積層第1導電片10A而製成第2積層導電片50B時,如圖12所示,與第1積層導電片50A(參照圖7)的情形相同,成為第1導電圖案22A的第1連接部16A與第2導電圖案22B的第2連接部16B將第1透明基體12A(參照圖5A)夾在中間而相向、且第1導電圖案22A的第1絕緣部24A與第2導電圖案22B的第2絕緣部24B將第1透明基體12A夾在中間而相向的形態。再者,第1導電圖案22A與第2導電圖案22B的各線寬相同,但圖12中亦與圖7相同,為了使 第1導電圖案22A與第2導電圖案22B的位置明瞭,圖中誇張地使第1導電圖案22A的線寬變粗、使第2導電圖案22B的線寬變細。When the first conductive sheet 10A is laminated on the second conductive sheet 10B to form the second laminated conductive sheet 50B, as shown in FIG. 12, it is the same as in the case of the first laminated conductive sheet 50A (see FIG. 7). The first connection portion 16A of the first conductive pattern 22A and the second connection portion 16B of the second conductive pattern 22B are opposed to each other with the first transparent substrate 12A (see FIG. 5A) interposed therebetween, and the first insulation of the first conductive pattern 22A The portion 24A and the second insulating portion 24B of the second conductive pattern 22B are opposed to each other with the first transparent substrate 12A interposed therebetween. Further, the first conductive pattern 22A and the second conductive pattern 22B have the same line width, but in FIG. 12, the same as FIG. The positions of the first conductive pattern 22A and the second conductive pattern 22B are clear, and the line width of the first conductive pattern 22A is made thicker in the drawing, and the line width of the second conductive pattern 22B is made thinner.

自上表面觀看所積層的第1導電片10A以及第2導電片10B時,成為以填埋第1導電片10A上形成的第1大格子14A的間隙的方式而排列有第2導電片10B的第2大格子14B的形態。此時,第1大格子14A的第1邊部28a以及第2邊部28b的各矩形波形狀的凹部42a的開口部分成為由第2大格子14B的第6邊部28f以及第8邊部28h的各矩形波形狀的凸部42b的頂端部分連接的形狀,結果成為連續排列有小格子18的形態,同樣,第1大格子14A的第3邊部28c以及第4邊部28d的各矩形波形狀的凹部42a的開口部分成為由第2大格子14B的第5邊部28e以及第7邊部28g的各矩形波形狀的凸部42b的頂端部分連接的形狀,結果成為連續排列有小格子的形態,而成為幾乎無法區分第1大格子14A與第2大格子14B的邊界的狀態。即,藉由矩形波形狀的凹部42a的開口部分與凸部42b的頂端部分的重疊,第1大格子14A與第2大格子14B的邊界不顯眼,視認性提昇。再者,第1絕緣部24A與第2絕緣部24B相向的部分形成有十字形狀的開口,但其與上述粗線不同,並不遮光,故在外部幾乎不顯眼。When the laminated first conductive sheet 10A and the second conductive sheet 10B are viewed from the upper surface, the second conductive sheet 10B is arranged so as to fill the gap between the first large lattices 14A formed on the first conductive sheet 10A. The form of the second large lattice 14B. At this time, the opening portions of the rectangular wave-shaped concave portions 42a of the first side portion 28a and the second side portion 28b of the first large lattice 14A are the sixth side portion 28f and the eighth side portion 28h of the second large lattice 14B. The shape in which the distal end portions of the rectangular wave-shaped convex portions 42b are connected to each other is such that the small lattices 18 are continuously arranged. Similarly, the rectangular waves of the third side portion 28c and the fourth side portion 28d of the first large lattice 14A are similarly formed. The opening portion of the concave portion 42a of the shape is connected to the distal end portion of each of the rectangular wave-shaped convex portions 42b of the fifth side portion 28e of the second large lattice 14B and the seventh side portion 28g, and as a result, a small lattice is continuously arranged. In the form, it is almost impossible to distinguish the state of the boundary between the first large lattice 14A and the second large lattice 14B. In other words, by the overlap of the opening portion of the rectangular wave-shaped concave portion 42a and the distal end portion of the convex portion 42b, the boundary between the first large lattice 14A and the second large lattice 14B is inconspicuous, and the visibility is improved. In addition, the portion in which the first insulating portion 24A and the second insulating portion 24B face each other is formed with a cross-shaped opening. However, unlike the thick line, the first insulating portion 24A does not block light, and thus is hardly conspicuous to the outside.

關於第1連接部16A與第2連接部16B相向的部分,亦與第1積層導電片50A相同,第2連接部16B的第5中格子20e與第7中格子20g的交點位於第1連接部16A的 第2中格子20b的大致中心,第2連接部16B的第6中格子20f與第8中格子20h的交點位於第1連接部16A的第3中格子20c的大致中心,藉由該些第1中格子20a~第8中格子20h的組合,而成為形成有多個小格子18的形態。即,於第1連接部16A與第2連接部16B相向的部分,藉由第1連接部16A與第2連接部16B的組合,而成為排列有多個小格子18的形態,與周圍的構成第1大格子14A的小格子18或構成第2大格子14B的小格子18不相區分,視認性提昇。The portion where the first connecting portion 16A and the second connecting portion 16B face each other is also the same as the first laminated conductive sheet 50A, and the intersection of the fifth intermediate lattice 20e and the seventh intermediate lattice 20g of the second connecting portion 16B is located at the first connecting portion. 16A The approximate center of the second intermediate lattice 20b, the intersection of the sixth intermediate lattice 20f and the eighth intermediate lattice 20h of the second connecting portion 16B is located substantially at the center of the third intermediate lattice 20c of the first connecting portion 16A, and the first The combination of the middle lattice 20a and the eighth intermediate lattice 20h is a form in which a plurality of small lattices 18 are formed. In other words, in the portion where the first connecting portion 16A and the second connecting portion 16B face each other, a combination of the first connecting portion 16A and the second connecting portion 16B forms a plurality of small lattices 18, and the surrounding configuration The small lattice 18 of the first large lattice 14A or the small lattice 18 constituting the second large lattice 14B are not distinguished, and the visibility is improved.

該第2積層導電片50B中,雖未圖示,但第1結線部40a以及第2結線部40b的排列狀態、端子配線部114中的第1端子配線圖案41a以及第2端子配線圖案41b的排列狀態、第1端子116a以及第2端子116b的排列狀態亦與上述第1積層導電片50A相同。In the second laminated conductive sheet 50B, the arrangement state of the first junction portion 40a and the second junction portion 40b, and the first terminal wiring pattern 41a and the second terminal wiring pattern 41b in the terminal wiring portion 114 are not shown. The arrangement state, the arrangement state of the first terminal 116a and the second terminal 116b are also the same as those of the first build-up conductive sheet 50A.

如此,對於第2積層導電片50B而言,於使用該第2積層導電片50B而應用於例如投影型靜電電容式的觸控面板100時,亦可提高響應速度,且可促進觸控面板100的大尺寸化。而且,第1導電片10A的第1大格子14A與第2導電片10B的第2大格子14B的邊界不顯眼,另外,藉由第1連接部16A與第2連接部16B的組合而形成有多個小格子18,故不存在局部產生粗線等不良狀況,整體的視認性變良好。When the second laminated conductive sheet 50B is applied to, for example, the projection type capacitive touch panel 100, the second laminated conductive sheet 50B can improve the response speed and can facilitate the touch panel 100. Large size. Further, the boundary between the first large lattice 14A of the first conductive sheet 10A and the second large lattice 14B of the second conductive sheet 10B is inconspicuous, and a combination of the first connecting portion 16A and the second connecting portion 16B is formed. Since a plurality of small lattices 18 are provided, there is no problem such as local occurrence of thick lines, and the overall visibility is good.

特別是該第2積層導電片50B中,第1大格子14A的4條邊(第1邊部28a~第4邊部28d)以及第2大格子14B 的4條邊(第5邊部28e~第8邊部28h)的形狀均為矩形波形狀,且各邊的形狀等價地相同,因此可抑制第1大格子14A或第2大格子14B的端部的電荷的定域,防止指尖位置的誤檢測。In particular, in the second laminated conductive sheet 50B, the four sides (the first side portion 28a to the fourth side portion 28d) of the first large lattice 14A and the second large lattice 14B The four sides (the fifth side portion 28e to the eighth side portion 28h) have a rectangular wave shape, and the shapes of the respective sides are equivalently the same. Therefore, the ends of the first large lattice 14A or the second large lattice 14B can be suppressed. The localization of the charge to prevent false detection of the position of the fingertip.

另外,該第2積層導電片50B中,亦如圖5A所示,使第1大格子14A的邊部的直線部30與第2大格子14B的邊部的直線部30之投影距離Lf與小格子18的1條邊的長度(50μm~500μm)大致相同。進而,僅自第1大格子14A的各邊部伸出的矩形波形狀的頂點與自第2大格子14B的各邊部伸出的矩形波形狀的頂點分別相向,因此第1大格子14A與第2大格子14B間形成的寄生電容變小。結果,CR時間常數亦變小,可實現檢測精度的提昇、響應速度的提昇。Further, as shown in FIG. 5A, the second laminated conductive sheet 50B has a projection distance Lf between the straight portion 30 of the side portion of the first large lattice 14A and the straight portion 30 of the side portion of the second large lattice 14B. The length (50 μm to 500 μm) of one side of the lattice 18 is substantially the same. Further, since only the apexes of the rectangular wave shape extending from the respective side portions of the first large lattice 14A and the vertices of the rectangular wave shape extending from the respective side portions of the second large lattice 14B are opposed to each other, the first large lattice 14A and The parasitic capacitance formed between the second large lattices 14B becomes small. As a result, the CR time constant is also reduced, and the detection accuracy can be improved and the response speed can be improved.

繼而,參照圖13以及圖14,對第2積層導電片50B的變形例進行說明。Next, a modification of the second build-up conductive sheet 50B will be described with reference to FIGS. 13 and 14.

該變形例的積層導電片50Ba的第1導電片10Aa具有與上述第2積層導電片50B的第1導電片10A(參照圖10)基本相同的構成,但於以下方面不同:如圖13所示,第1連接部16A並非格子形狀,而是形成為大致Z字形(鋸齒狀)的線狀。該第1連接部16A是形成於第1大格子14A的第2邊部28b的直線部30和第4邊部28d的直線部30的交界部分、與第1大格子14A的第1邊部28a的直線部30和第3邊部28c的直線部30的交界部分之間。The first conductive sheet 10Aa of the laminated conductive sheet 50Ba of the modified example has substantially the same configuration as the first conductive sheet 10A (see FIG. 10) of the second laminated conductive sheet 50B, but differs in the following points: The first connecting portion 16A is not formed in a lattice shape but in a substantially zigzag (zigzag) linear shape. The first connecting portion 16A is a boundary portion between the straight portion 30 of the second side portion 28b of the first large lattice 14A and the straight portion 30 of the fourth side portion 28d, and the first side portion 28a of the first large lattice 14A. Between the straight portion 30 and the boundary portion of the straight portion 30 of the third side portion 28c.

同樣,第2導電片10Ba具有與上述第2積層導電片 50B的第2導電片10B(參照圖11)基本相同的構成,但於以下方面不同:如圖14所示,第2連接部16B並非格子形狀,而是形成為大致Z字形(鋸齒狀)的線狀。該第2連接部16B是形成於第2大格子14B的第6邊部28f的直線部30和第8邊部28h的直線部30的交界部分、與第2大格子14B的第5邊部28e的直線部30和第7邊部28g的直線部30的交界部分之間。Similarly, the second conductive sheet 10Ba has the second laminated conductive sheet The second conductive sheet 10B (see FIG. 11) of 50B has substantially the same configuration, but differs in the following points: as shown in FIG. 14, the second connecting portion 16B is formed in a substantially zigzag shape (zigzag shape) instead of a lattice shape. Linear. The second connecting portion 16B is a boundary portion between the straight portion 30 of the sixth side portion 28f of the second large lattice 14B and the straight portion 30 of the eighth side portion 28h, and the fifth side portion 28e of the second large lattice 14B. Between the straight portion 30 and the boundary portion of the straight portion 30 of the seventh side portion 28g.

而且,第1連接部16A的寬度Wc1(一個拐點至另一拐點之間、且沿著y方向的距離)滿足Wc1>Ps/,此處為2×(Ps/)。同樣,第2連接部16B的寬度Wc2(一個拐點至另一拐點之間、且沿著x方向的距離)滿足Wc2>Ps/,此處為2×(Ps/)。Moreover, the width Wc1 of the first connecting portion 16A (the distance between one inflection point and the other inflection point and along the y direction) satisfies Wc1>Ps/ , here is 2×(Ps/ ). Similarly, the width Wc2 of the second connecting portion 16B (the distance between one inflection point and the other inflection point and along the x direction) satisfies Wc2>Ps/ , here is 2×(Ps/ ).

對於該變形例的積層導電片50Ba而言,於使用該積層導電片50Ba而應用於例如投影型靜電電容式的觸控面板時,亦可提高響應速度,且可促進觸控面板的大尺寸化。When the laminated conductive sheet 50Ba of the present modification is applied to, for example, a projection type capacitive touch panel, the laminated conductive sheet 50Ba can improve the response speed and can promote the size of the touch panel. .

上述第1導電片10A(10Aa)以及第2導電片10B(10Ba)中,若第1連接部16A的寬度以及第2連接部16B的寬度過大,則有時大格子14的配置變困難,外觀變差,因此其上限較佳為2×(Ps/)~20×(Ps/),更佳為8×(Ps/)~14×(Ps/)。In the first conductive sheet 10A (10Aa) and the second conductive sheet 10B (10Ba), when the width of the first connecting portion 16A and the width of the second connecting portion 16B are too large, the arrangement of the large lattices 14 may become difficult. Variation, so the upper limit is preferably 2 × (Ps / )~20×(Ps/ ), more preferably 8 × (Ps / )~14×(Ps/ ).

另外,上述第1導電片10A(10Aa)以及第2導電片10B(10Ba)中,小格子18的尺寸(1邊的長度或對角線的長度等)或構成第1大格子14A的小格子18的個數、構成第2大格子14B的小格子18的個數亦可根據所應用 的觸控面板的尺寸或解析度(配線數)而適當設定。In the first conductive sheet 10A (10Aa) and the second conductive sheet 10B (10Ba), the size of the small lattice 18 (the length of one side or the length of the diagonal line) or the small lattice constituting the first large lattice 14A. The number of 18s and the number of small lattices 18 constituting the second large lattice 14B may also be applied according to the application. The size or resolution (number of wirings) of the touch panel is appropriately set.

上述第1導電片10A(10Aa)以及第2導電片10B(10Ba)中,將構成第1連接部16A以及第2連接部16B的中格子20的排列間距Pm設定為小格子18的排列間距Ps的2倍,除此以外,可根據中格子的數量任意設定為1.5倍、3倍等。關於中格子20的排列間距Pm,若其間隔過窄、或過大,則第1大格子14A或第2大格子14B的配置變困難,外觀變差,故較佳為小格子18的排列間距Ps的1倍~10倍,更佳為1倍~5倍。In the first conductive sheet 10A (10Aa) and the second conductive sheet 10B (10Ba), the arrangement pitch Pm of the intermediate lattices 20 constituting the first connecting portion 16A and the second connecting portion 16B is set to the arrangement pitch Ps of the small lattices 18 In addition to this, it can be arbitrarily set to 1.5 times, 3 times, etc. according to the number of medium grids. When the arrangement pitch Pm of the intermediate lattices 20 is too narrow or too large, the arrangement of the first large lattice 14A or the second large lattice 14B becomes difficult, and the appearance is deteriorated. Therefore, the arrangement pitch Ps of the small lattices 18 is preferable. 1 to 10 times, more preferably 1 to 5 times.

另外,小格子18的尺寸(1邊的長度或對角線的長度等)或構成第1大格子14A的小格子18的個數、構成第2大格子14B的小格子18的個數亦可根據所應用的觸控面板的尺寸或解析度(配線數)而適當設定。Further, the size of the small lattice 18 (the length of one side or the length of the diagonal line), the number of the small lattices 18 constituting the first large lattice 14A, and the number of the small lattices 18 constituting the second large lattice 14B may be It is set as appropriate according to the size or resolution (number of wirings) of the touch panel to be applied.

上述例子中,表示出了將第1導電片10A(10Aa)以及第2導電片10B(10Ba)應用於投影型靜電電容式的觸控面板100的例子,除此以外,當然亦可應用於表面型靜電電容式的觸控面板或電阻膜式的觸控面板。In the above example, the first conductive sheet 10A (10Aa) and the second conductive sheet 10B (10Ba) are applied to the projection type capacitive touch panel 100, and of course, it can be applied to the surface. A capacitive touch panel or a resistive touch panel.

其次,作為製造第1導電片10A(10Aa)或第2導電片10B(10Ba)的方法,例如可於第1透明基體12A上以及第2透明基體12B上對具有含有感光性鹵化銀鹽的乳劑層的感光材料進行曝光,並實施顯影處理,藉此於曝光部以及未曝光部分別形成金屬銀部以及透光性部,而形成第1導電圖案22A以及第2導電圖案22B。再者,亦可進而對金屬銀部實施物理顯影及/或電鍍處理,藉此使金屬銀部 承載導電性金屬。Next, as a method of producing the first conductive sheet 10A (10Aa) or the second conductive sheet 10B (10Ba), for example, an emulsion containing a photosensitive silver halide salt can be applied to the first transparent substrate 12A and the second transparent substrate 12B. The photosensitive material of the layer is exposed and subjected to development processing, whereby the metal silver portion and the light transmissive portion are formed in the exposed portion and the unexposed portion, respectively, and the first conductive pattern 22A and the second conductive pattern 22B are formed. Furthermore, the metal silver portion can be further subjected to physical development and/or electroplating treatment, thereby making the metal silver portion Carrying a conductive metal.

另一方面,於如圖5B所示般在第1透明基體12A的一個主面上形成第1導電圖案22A,並於第1透明基體12A的另一主面上形成第2導電圖案22B時,若依照通常的製法而採用最初對一個主面進行曝光、然後對另一主面進行曝光的方法,則有時無法獲得所需的第1導電圖案22A以及第2導電圖案22B。特別是難以均勻地形成自第1大格子14A以及第2大格子14B的邊部伸出梳齒32的圖案、或自第1大格子14A以及第2大格子14B的邊部伸出矩形波形狀的圖案。On the other hand, when the first conductive pattern 22A is formed on one main surface of the first transparent substrate 12A and the second conductive pattern 22B is formed on the other main surface of the first transparent substrate 12A, as shown in FIG. 5B, If the first main surface is exposed by exposure and then the other main surface is exposed in accordance with a usual method, the desired first conductive pattern 22A and second conductive pattern 22B may not be obtained. In particular, it is difficult to uniformly form a pattern in which the comb teeth 32 are extended from the side portions of the first large lattice 14A and the second large lattice 14B, or a rectangular wave shape is extended from the side portions of the first large lattice 14A and the second large lattice 14B. picture of.

因此,可較佳地採用以下所示的製造方法。Therefore, the manufacturing method shown below can be preferably employed.

即,對第1透明基體12A的兩面上形成的感光性鹵化銀乳劑層進行統括曝光,於第1透明基體12A的一個主面上形成第1導電圖案22A,於第1透明基體12A的另一主面上形成第2導電圖案22B。That is, the photosensitive silver halide emulsion layer formed on both surfaces of the first transparent substrate 12A is collectively exposed, and the first conductive pattern 22A is formed on one main surface of the first transparent substrate 12A, and the other is formed on the first transparent substrate 12A. The second conductive pattern 22B is formed on the main surface.

參照圖15~圖17,對該製造方法的具體例加以說明。A specific example of the manufacturing method will be described with reference to Figs. 15 to 17 .

首先,於圖15的步驟S1中,製作長條的感光材料140。感光材料140如圖16A所示,具有第1透明基體12A、形成於該第1透明基體12A的一個主面上的成光性鹵化銀乳劑層(以下稱為第1感光層142a)、以及形成於第1透明基體12A的另一主面上的感光性鹵化銀乳劑層(以下稱為第2感光層142b)。First, in step S1 of Fig. 15, a long photosensitive material 140 is produced. As shown in FIG. 16A, the photosensitive material 140 has a first transparent substrate 12A, a light-forming silver halide emulsion layer (hereinafter referred to as a first photosensitive layer 142a) formed on one main surface of the first transparent substrate 12A, and a formation. A photosensitive silver halide emulsion layer (hereinafter referred to as a second photosensitive layer 142b) on the other main surface of the first transparent substrate 12A.

於圖15的步驟S2中,對感光材料140進行曝光。該曝光處理中,進行第1曝光處理與第2曝光處理(兩面同 時曝光),上述第1曝光處理是對第1感光層142a朝向第1透明基體12A而照射光,沿著第1曝光圖案對第1感光層142a進行曝光,上述第2曝光處理是對第2感光層142b朝向第1透明基體12A而照射光,沿著第2曝光圖案對第2感光層142b進行曝光(兩面同時曝光)。圖16B的例子中,一方面將長條的感光材料140朝一個方向搬送,一方面對第1感光層142a介隔第1光罩146a而照射第1光144a(平行光),並且對第2感光層142b介隔第2光罩146b而照射第2光144b(平行光)。第1光144a是藉由利用途中的第1準直透鏡150a將自第1光源148a出射的光轉換成平行光而獲得,第2光144b是藉由利用途中的第2準直透鏡150b將自第2光源148b出射的光轉換成平行光而獲得。圖16B的例子中,表示出使用2個光源(第1光源148a以及第2光源148b)的情形,亦可使自1個光源出射的光經由光學系統而加以分割,形成第1光144a以及第2光144b,且照射於第1感光層142a以及第2感光層142b。In step S2 of Fig. 15, the photosensitive material 140 is exposed. In the exposure processing, the first exposure processing and the second exposure processing are performed (both sides are the same) In the first exposure process, the first photosensitive layer 142a is irradiated with light toward the first transparent substrate 12A, and the first photosensitive layer 142a is exposed along the first exposure pattern, and the second exposure process is the second exposure process. The photosensitive layer 142b is irradiated with light toward the first transparent substrate 12A, and the second photosensitive layer 142b is exposed along the second exposure pattern (both surfaces are simultaneously exposed). In the example of FIG. 16B, on the one hand, the long photosensitive material 140 is conveyed in one direction, and the first photosensitive layer 142a is shielded from the first light-receiving layer 146a by the first light 144a (parallel light), and the second light is applied to the first light-receiving layer 142a. The photosensitive layer 142b is irradiated with the second light 144b (parallel light) via the second mask 146b. The first light 144a is obtained by converting the light emitted from the first light source 148a into parallel light by the first collimating lens 150a in the advantageous use, and the second light 144b is obtained by the second collimating lens 150b in the advantageous use. The light emitted from the second light source 148b is converted into parallel light and obtained. In the example of FIG. 16B, when two light sources (the first light source 148a and the second light source 148b) are used, light emitted from one light source may be divided by the optical system to form the first light 144a and the first light. The light 144b is irradiated to the first photosensitive layer 142a and the second photosensitive layer 142b.

繼而,於圖15的步驟S3中,對曝光後的感光材料140進行顯影處理,藉此如圖5B所示般製作第1積層導電片50A。第1積層導電片50A具有第1透明基體12A、形成於該第1透明基體12A的一個主面上的沿著第1曝光圖案的第1導電部13A(第1導電圖案22A等)、以及形成於第1透明基體12A的另一主面上的依照第2曝光圖案的第2導電部13B(第2導電圖案22B等)。再者,第1感光層142a以及第2感光層142b的曝光時間以及顯影時間會根 據第1光源148a以及第2光源148b的種類或顯影液的種類等不同而有各種各樣的變化,故較佳數值範圍不可一概而定,但要調整為顯影率達到100%的曝光時間以及顯影時間。Then, in step S3 of FIG. 15, the exposed photosensitive material 140 is subjected to development processing, whereby the first laminated conductive sheet 50A is produced as shown in FIG. 5B. The first laminated conductive sheet 50A includes a first transparent substrate 12A, a first conductive portion 13A (such as a first conductive pattern 22A) formed along a first exposure pattern formed on one main surface of the first transparent substrate 12A, and a first transparent layer 12A. The second conductive portion 13B (the second conductive pattern 22B or the like) according to the second exposure pattern on the other main surface of the first transparent substrate 12A. Furthermore, the exposure time and development time of the first photosensitive layer 142a and the second photosensitive layer 142b are rooted. There are various changes depending on the type of the first light source 148a and the second light source 148b, the type of the developer, and the like. Therefore, the preferred numerical range is not always limited, but the exposure time is adjusted to 100% of the development rate and Development time.

而且,本實施形態的製造方法中,第1曝光處理如圖17所示,於第1光層142a上例如密接配置第1光罩146a,自與該第1光罩146a相向而配置的第1光源148a朝向第1光罩146a照射第1光144a,藉此對第1感光層142a進行曝光。第1光罩146a是由以透明的鈉玻璃形成的玻璃基板、及形成於該玻璃基板上的遮罩圖案(第1曝光圖案152a)所構成。因此,藉由該第1曝光處理,對第1感光層142a中沿著第1光罩146a上形成的第1曝光圖案152a的部分進行曝光。亦可於第1感光層142a與第1光罩146a之間設置2μm~10μm左右的間隙。In the manufacturing method of the first embodiment, as shown in FIG. 17, the first photomask 146a is placed in close contact with each other on the first optical layer 142a, and the first photomask 146a is disposed opposite to the first photomask 146a. The light source 148a irradiates the first light 144a toward the first mask 146a, thereby exposing the first photosensitive layer 142a. The first photomask 146a is composed of a glass substrate formed of transparent soda glass and a mask pattern (first exposure pattern 152a) formed on the glass substrate. Therefore, the portion of the first photosensitive layer 142a along the first exposure pattern 152a formed on the first mask 146a is exposed by the first exposure processing. A gap of about 2 μm to 10 μm may be provided between the first photosensitive layer 142a and the first mask 146a.

同樣,第2曝光處理中,於第2感光層142b上例如密接配置第2光罩146b,自與該第2光罩146b相向而配置的第2光源148b朝向第2光罩146b照射第2光144b,藉此對第2感光層142b進行曝光。第2光罩146b與第1光罩146a相同,是由以透明的鈉玻璃形成的玻璃基板、及形成於該玻璃基板上的遮罩圖案(第2曝光圖案152b)所構成。因此,藉由該第2曝光處理,對第2感光層142b中沿著第2光罩146b上形成的第2曝光圖案152b的部分進行曝光。此時,亦可於第2感光層142b與第2光罩146b之間設置2μm~10μm左右的間隙。Similarly, in the second exposure processing, for example, the second photomask 146b is placed in close contact with the second photosensitive layer 142b, and the second light source 148b disposed to face the second mask 146b is irradiated with the second light toward the second mask 146b. 144b, thereby exposing the second photosensitive layer 142b. Similarly to the first mask 146a, the second mask 146b is composed of a glass substrate formed of transparent soda glass and a mask pattern (second exposure pattern 152b) formed on the glass substrate. Therefore, the portion of the second photosensitive layer 142b along the second exposure pattern 152b formed on the second mask 146b is exposed by the second exposure processing. At this time, a gap of about 2 μm to 10 μm may be provided between the second photosensitive layer 142b and the second mask 146b.

第1曝光處理以及第2曝光處理中,可使來自第1光源148a的第1光144a的出射時序與自第2光源148b的第2光144b的出射時序設為同時,亦可使該些出射時序不同。若為同時,則可利用1次曝光處理對第1感光層142a與第2感光層142b同時曝光,可縮短處理時間。In the first exposure processing and the second exposure processing, the emission timing of the first light 144a from the first light source 148a and the emission timing of the second light 144b from the second light source 148b may be simultaneously set, and the emission may be performed. The timing is different. At the same time, the first photosensitive layer 142a and the second photosensitive layer 142b can be simultaneously exposed by one exposure process, and the processing time can be shortened.

再者,於第1感光層142a以及第2感光層142b均未經光譜增感時,若自兩側對感光材料140進行曝光,則來自一側的曝光會對另一側(背側)的圖像形成造成影響。Further, when the first photosensitive layer 142a and the second photosensitive layer 142b are not spectrally sensitized, if the photosensitive material 140 is exposed from both sides, the exposure from one side will be on the other side (back side). Image formation has an impact.

即,關於到達第1感光層142a的來自第1光源148a的第1光144a,由於第1感光層142a中的鹵化銀粒子而發生散射,作為散射光而透過第1透明基體12A,其一部分到達第2感光層142b。於是,第2感光層142b與第1透明基體12A的交界部分之較大範圍受到曝光,形成潛像。因此,第2感光層142b上,進行了來自第2光源148b的第2光144b的曝光與來自第1光源148a的第1光144a的曝光,於其後的顯影處理中製成第1積層導電片50A時,除了由第2曝光圖案152b所得的導電圖案(第2導電部13B)以外,於該導電圖案間形成有由來自第1光源148a的第1光144a所形成的薄導電層,而無法獲得所需的圖案(沿著第2曝光圖案152b的圖案)。此種情況於第1感光層142a中亦相同。In other words, the first light 144a from the first light source 148a that has reached the first photosensitive layer 142a is scattered by the silver halide particles in the first photosensitive layer 142a, and passes through the first transparent substrate 12A as scattered light, and a part of the light reaches the first transparent substrate 12A. The second photosensitive layer 142b. Then, a large range of the boundary portion between the second photosensitive layer 142b and the first transparent substrate 12A is exposed to form a latent image. Therefore, in the second photosensitive layer 142b, exposure of the second light 144b from the second light source 148b and exposure of the first light 144a from the first light source 148a are performed, and in the subsequent development processing, the first laminated conductive layer is formed. In the sheet 50A, in addition to the conductive pattern (second conductive portion 13B) obtained by the second exposure pattern 152b, a thin conductive layer formed by the first light 144a from the first light source 148a is formed between the conductive patterns. The desired pattern (the pattern along the second exposure pattern 152b) cannot be obtained. This case is also the same in the first photosensitive layer 142a.

本發明者為了避免此種情況而進行了潛心研究,結果表明,藉由將第1感光層142a以及第2感光層142b的厚度設定於特定範圍,或規定第1感光層142a以及第2感光 層142b的塗佈銀量,鹵化銀自身吸收光,可限制朝向背面的透光。本實施形態中,可將第1感光層142a以及第2感光層142b的厚度設定為1μm以上、4μm以下。上限值較佳為2.5μm。另外,將第1感光層142a以及第2感光層142b的塗佈銀量規定為5g/m2 ~20g/m2The inventors of the present invention conducted intensive studies to avoid such a situation, and as a result, the thickness of the first photosensitive layer 142a and the second photosensitive layer 142b is set to a specific range, or the first photosensitive layer 142a and the second photosensitive layer are defined. The amount of silver applied to 142b, the silver halide itself absorbs light, and can restrict light transmission toward the back surface. In the present embodiment, the thickness of the first photosensitive layer 142a and the second photosensitive layer 142b can be set to 1 μm or more and 4 μm or less. The upper limit is preferably 2.5 μm. Further, the amount of silver applied to the first photosensitive layer 142a and the second photosensitive layer 142b is set to 5 g/m 2 to 20 g/m 2 .

上述兩面密接的曝光方式中,由於附著於膜表面的塵埃等抑制曝光而導致的圖像缺陷成問題。關於防止塵埃附著,已知有於膜上塗佈導電性物質,但在處理後亦會殘存金屬氧化物等,有損最終產品的透明性,另外,導電性高分子於保存性等方面有問題。因此,本發明者進行了潛心研究,結果得知,藉由減少了黏合劑量的鹵化銀可獲得抗靜電所必需的導電性,而規定第1感光層142a以及第2感光層142b的銀/黏合劑的體積比。即,第1感光層142a以及第2感光層142b的銀/黏合劑體積比為1/1以上,較佳為2/1以上。In the exposure method in which the two surfaces are in close contact with each other, image defects caused by dust or the like adhering to the surface of the film are prevented from being exposed. It is known that the conductive material is applied to the film, but the metal oxide or the like remains after the treatment, which impairs the transparency of the final product, and the conductive polymer has problems in storage stability and the like. . Therefore, the present inventors conducted intensive studies, and as a result, it has been found that the silver/bonding of the first photosensitive layer 142a and the second photosensitive layer 142b can be specified by obtaining a silver halide having a reduced binder amount to obtain conductivity necessary for antistatic property. The volume ratio of the agent. That is, the silver/adhesive volume ratio of the first photosensitive layer 142a and the second photosensitive layer 142b is 1/1 or more, preferably 2/1 or more.

如上所述,藉由對第1感光層142a以及第2感光層142b的厚度、塗佈銀量、銀/黏合劑的體積比進行設定及規定,如圖17所示,到達第1感光層142a的來自第1光源148a的第1光144a不到達第2感光層142b,同樣,到達第2感光層142b的來自第2光源148b的第2光144b不到達第1感光層142a,結果,於利用此後的顯影處理來製成第1積層導電片50A時,如圖5B所示,於第1透明基體12A的一個主面上僅形成由第1曝光圖案152a所得的導電圖案(構成第1導電部13A的圖案),於第1透明 基體12A的另一主面上僅形成由第2曝光圖案152b所得的導電圖案(構成第2導電部13B的圖案),可獲得所需的圖案。As described above, by setting and defining the thickness of the first photosensitive layer 142a and the second photosensitive layer 142b, the amount of applied silver, and the volume ratio of the silver/binder, as shown in FIG. 17, the first photosensitive layer 142a is reached. The first light 144a from the first light source 148a does not reach the second photosensitive layer 142b, and the second light 144b from the second light source 148b that has reached the second photosensitive layer 142b does not reach the first photosensitive layer 142a. When the first build-up conductive sheet 50A is formed by the development process thereafter, as shown in FIG. 5B, only the conductive pattern obtained by the first exposure pattern 152a is formed on one main surface of the first transparent substrate 12A (constituting the first conductive portion). 13A pattern), in the first transparent Only the conductive pattern (the pattern constituting the second conductive portion 13B) obtained by the second exposure pattern 152b is formed on the other main surface of the base 12A, and a desired pattern can be obtained.

如此,上述使用兩面統括曝光的製造方法中,可獲得兼具導電性與兩面曝光的適應性的第1感光層142a以及第2感光層142b,另外,可藉由1次對第1透明基體12A的曝光處理而於第1透明基體12A的兩面上任意形成相同圖案或不同圖案,藉此,可容易地形成觸控面板100的電極,並且可實現觸控面板100的薄型化(低背化)。As described above, in the above-described manufacturing method using the double-sided exposure, the first photosensitive layer 142a and the second photosensitive layer 142b having both conductivity and double-sided exposure can be obtained, and the first transparent substrate 12A can be used once. In the exposure process, the same pattern or a different pattern is arbitrarily formed on both surfaces of the first transparent substrate 12A, whereby the electrodes of the touch panel 100 can be easily formed, and the touch panel 100 can be made thinner (lower). .

上述例子是使用感光性鹵化銀乳劑層形成第1導電圖案22A以及第2導電圖案22B的製造方法,其他製造方法有如下製造方法。The above example is a method of producing the first conductive pattern 22A and the second conductive pattern 22B using a photosensitive silver halide emulsion layer, and other manufacturing methods have the following manufacturing methods.

即,亦可對形成於第1透明基體12A以及第2透明基體12B上的銅箔上的光阻膜進行曝光、顯影處理而形成阻劑圖案,對自阻劑圖案露出的銅箔進行蝕刻,藉此形成第1導電圖案22A以及第2導電圖案22B。In other words, the resist film formed on the copper foil formed on the first transparent substrate 12A and the second transparent substrate 12B may be exposed and developed to form a resist pattern, and the copper foil exposed from the resist pattern may be etched. Thereby, the first conductive pattern 22A and the second conductive pattern 22B are formed.

或者,亦可於第1透明基體12A以及第2透明基體12B上印刷含有金屬微粒子的漿料,對該漿料進行金屬電鍍,藉此形成第1導電圖案22A以及第2導電圖案22B。Alternatively, a slurry containing metal fine particles may be printed on the first transparent substrate 12A and the second transparent substrate 12B, and the slurry may be subjected to metal plating to form the first conductive pattern 22A and the second conductive pattern 22B.

亦可於第1透明基體12A以及第2透明基體12B上,藉由網版印刷版或凹版印刷版而印刷形成第1導電圖案22A以及第2導電圖案22B。The first conductive pattern 22A and the second conductive pattern 22B may be printed on the first transparent substrate 12A and the second transparent substrate 12B by a screen printing plate or a gravure printing plate.

亦可於第1透明基體12A以及第2透明基體12B上藉由噴墨而形成第1導電圖案22A以及第2導電圖案22B。The first conductive pattern 22A and the second conductive pattern 22B may be formed by inkjet on the first transparent substrate 12A and the second transparent substrate 12B.

繼而,對於本實施形態的第1導電片10A(10Aa)以及第2導電片10B(10Ba),以作為特佳態樣的使用鹵化銀照相感光材料的方法為中心加以描述。In the first conductive sheet 10A (10Aa) and the second conductive sheet 10B (10Ba) of the present embodiment, a method of using a silver halide photographic light-sensitive material as a particularly preferable embodiment will be mainly described.

本實施形態的第1導電片10A(10Aa)以及第2導電片10B(10Ba)的製造方法,視感光材料與顯影處理的形態不同而包含以下三種形態。The method for producing the first conductive sheet 10A (10Aa) and the second conductive sheet 10B (10Ba) according to the present embodiment includes the following three aspects depending on the form of the photosensitive material and the development processing.

(1)對不含物理顯影核的感光性鹵化銀黑白感光材料進行化學顯影或熱顯影,於該感光材料上形成金屬銀部的態樣。(1) Chemically developing or thermally developing a photosensitive silver halide black-and-white photosensitive material containing no physical developing core to form a metallic silver portion on the photosensitive material.

(2)對鹵化銀乳劑層中含有物理顯影核的感光性鹵化銀黑白感光材料進行溶解物理顯影,於該感光材料上形成金屬銀部的態樣。(2) Dissolving physical development of a photosensitive silver halide black-and-white photosensitive material containing a physical development nucleus in a silver halide emulsion layer, and forming a metallic silver portion on the photosensitive material.

(3)將不含物理顯影核的感光性鹵化銀黑白感光材料、與具有含有物理顯影核的非感光性層的顯像片重合,進行擴散轉印顯影,於非感光性顯像片上形成金屬銀部的態樣。(3) A photosensitive silver halide black-and-white photosensitive material containing no physical development core is superposed on a developing sheet having a non-photosensitive layer containing a physical development nucleus, and diffusion-transfer development is carried out to form a metal on the non-photosensitive display sheet. The state of the silver department.

上述(1)的態樣為一體型黑白顯影型,於感光材料上形成透光性導電膜等透光性導電性膜。所得的顯影銀為化學顯影銀或熱顯影銀,就其為高比表面的細絲(filament)的方面而言,於後續的電鍍或物理顯影過程中活性高。The aspect of the above (1) is an integrated black-and-white development type, and a light-transmitting conductive film such as a light-transmitting conductive film is formed on the photosensitive material. The resulting developed silver is chemically developed silver or thermally developed silver, which is highly active in subsequent plating or physical development in terms of a filament having a high specific surface.

上述(2)的態樣中,於曝光部,物理顯影核附近的鹵化銀粒子溶解並沈積於顯影核上,藉此於感光材料上形成透光性導電性膜等透光性導電性膜。該(2)的態樣亦為一體型黑白顯影型。因顯影作用為於物理顯影核上的析 出,故活性高,但顯影銀為比表面小的球形。In the aspect of the above (2), the silver halide particles in the vicinity of the physical development nucleus are dissolved and deposited on the developing nucleus in the exposed portion, whereby a light-transmitting conductive film such as a light-transmitting conductive film is formed on the photosensitive material. The aspect of (2) is also an integrated black and white development type. Analysis due to development on the physical development nucleus Out, the activity is high, but the developed silver is spherical smaller than the surface.

上述(3)的態樣中,於未曝光部,鹵化銀粒子溶解並擴散,且沈積於顯像片上的顯影核上,藉此於顯像片上形成透光性導電性膜等透光性導電性膜。該(3)的態樣為所謂的分開(separate)型,且為自感光材料剝離顯像片而使用的態樣。In the aspect of the above (3), the silver halide particles are dissolved and diffused in the unexposed portion, and are deposited on the developing core on the developing sheet, thereby forming a light-transmitting conductive film such as a light-transmitting conductive film on the developing sheet. Sex film. The aspect of the (3) is a so-called separate type, and is an aspect used for peeling off a developing sheet from a photosensitive material.

任一態樣均亦可選擇負型顯影處理以及反轉顯影處理中的任一顯影(擴散轉印方式的情況下,藉由使用直接正型(auto positive type)感光材料作為感光材料,可實現負型顯影處理)。Any of the negative development processing and the reverse development processing may be selected in any of the aspects (in the case of the diffusion transfer method, by using an auto positive type photosensitive material as a photosensitive material, it is possible to realize Negative development processing).

此處所謂化學顯影、熱顯影、溶解物理顯影、擴散轉印顯影,是指如業界通使用的術語般的含意,於照相化學的通常教科書、例如菊地真一著「照相化學」(共立出版社,1955年發行)、C.E.K.Mees編「The Theory of Photographic Processes,4th ed.」(Mcmillan公司,1977年發行)中有所解說。本案是與液體處理有關的發明,但亦可參考應用熱顯影方式作為其他顯影方式的技術。例如可應用日本專利特開2004-184693號、日本專利特開2004-334077號、日本專利特開2005-010752號的各公報,日本專利特願2004-244080號、日本專利特願2004-085655號的各說明書中記載的技術。Here, chemical development, thermal development, dissolved physical development, and diffusion transfer development refer to the meaning of the term as used in the industry. In general textbooks of photographic chemistry, such as Kikuchi, "Photography Chemistry" (Kyoritsu Press, Issued in 1955), CEK Mees, "The Theory of Photographic Processes, 4th ed." (Mcmillan, 1977). This case is an invention related to liquid processing, but it is also possible to refer to a technique in which a thermal development method is applied as another development method. For example, Japanese Laid-Open Patent Publication No. 2004-184693, Japanese Patent Laid-Open No. 2004-334077, Japanese Patent Laid-Open No. Hei No. 2005-010752, Japanese Patent Application No. 2004-244080, Japanese Patent Application No. 2004-085655 The technology described in each specification.

此處,以下對本實施形態的第1導電片10A(10Aa)以及第2導電片10B(10Ba)的各層的構成加以詳細說明。Here, the configuration of each layer of the first conductive sheet 10A (10Aa) and the second conductive sheet 10B (10Ba) of the present embodiment will be described in detail below.

[第1透明基體12A、第2透明基體12B][First transparent substrate 12A, second transparent substrate 12B]

第1透明基體12A以及第2透明基體12B可列舉塑膠膜、塑膠板、玻璃板等。Examples of the first transparent substrate 12A and the second transparent substrate 12B include a plastic film, a plastic plate, and a glass plate.

上述塑膠膜以及塑膠板的原料例如可使用:聚對苯二甲酸乙二酯(PET)、聚萘二甲酸乙二酯(PEN)等聚酯類;聚乙烯(PE)、聚丙烯(PP)、聚苯乙烯、EVA(Ethylene Vinyl Acetate,乙烯-乙酸乙烯酯)等聚烯烴類;乙烯系樹脂;除此之外,可使用聚碳酸酯(PC)、聚醯胺、聚醯亞胺、丙烯酸系樹脂、三乙醯纖維素(TAC)等。For the raw materials of the plastic film and the plastic plate, for example, polyesters such as polyethylene terephthalate (PET) and polyethylene naphthalate (PEN); polyethylene (PE) and polypropylene (PP) can be used. Polyolefins such as polystyrene, EVA (Ethylene Vinyl Acetate), and vinyl resins; in addition, polycarbonate (PC), polyamide, polyimine, acrylic acid can be used. Resin, triethyl cellulose (TAC), and the like.

第1透明基體12A以及第2透明基體12B較佳為PET(融點:258℃)、PEN(融點:269℃)、PE(融點:135℃)、PP(融點:163℃)、聚苯乙烯(融點;230℃)、聚氯乙烯(融點:180℃)、聚偏二氯乙烯(融點:212℃)或TAC(融點:290℃)等融點為約290℃以下的塑膠膜或塑膠板,特別就透光性或加工性等觀點而言,較佳為PET。第1積層導電片50A或第2積層導電片50B(50Ba)中使用的第1導電片10A(10Aa)以及第2導電片10B(10Ba)般的導電性膜要求透明性,故較佳為第1透明基體12A以及第2透明基體12B的透明度高。The first transparent substrate 12A and the second transparent substrate 12B are preferably PET (melting point: 258 ° C), PEN (melting point: 269 ° C), PE (melting point: 135 ° C), PP (melting point: 163 ° C), The melting point of polystyrene (melting point; 230 ° C), polyvinyl chloride (melting point: 180 ° C), polyvinylidene chloride (melting point: 212 ° C) or TAC (melting point: 290 ° C) is about 290 ° C The following plastic film or plastic plate is preferably PET in terms of light transmittance or workability. The conductive film such as the first conductive sheet 10A (10Aa) and the second conductive sheet 10B (10Ba) used in the first laminated conductive sheet 50A or the second laminated conductive sheet 50B (50Ba) is required to have transparency, and therefore it is preferably The transparency of the transparent substrate 12A and the second transparent substrate 12B is high.

[銀鹽乳劑層][Silver Salt Emulsion Layer]

成為第1導電片10A(10Aa)以及第2導電片10B(10Ba)的導電層(第1大格子14A、第1連接部16A、第2大格子14B、第2連接部16B、小格子18等導電部)的銀鹽乳劑層除了含有銀鹽與黏合劑以外,還含有溶劑或染料等添加劑。The conductive layer (the first large lattice 14A, the first connecting portion 16A, the second large lattice 14B, the second connecting portion 16B, the small lattice 18, etc.) of the first conductive sheet 10A (10Aa) and the second conductive sheet 10B (10Ba) The silver salt emulsion layer of the conductive portion contains an additive such as a solvent or a dye in addition to the silver salt and the binder.

本實施形態中使用的銀鹽可列舉鹵化銀等無機銀鹽以及乙酸銀等有機銀鹽。本實施形態中,較佳為使用作為光感測器的特性優異的鹵化銀。The silver salt used in the present embodiment may, for example, be an inorganic silver salt such as silver halide or an organic silver salt such as silver acetate. In the present embodiment, it is preferable to use silver halide which is excellent in characteristics as a photosensor.

銀鹽乳劑層的塗佈銀量(銀鹽的塗佈量)換算成銀而較佳為1g/m2 ~30g/m2 ,更佳為1g/m2 ~25g/m2 ,進而佳為5g/m2 ~20g/m2 。藉由將該塗佈銀量設定為上述範圍,於製成第1積層導電片50A或第2積層導電片50B(50Ba)時可獲得所需的表面電阻。The amount of coated silver (coating amount of the silver salt) of the silver salt emulsion layer is preferably 1 g/m 2 to 30 g/m 2 , more preferably 1 g/m 2 to 25 g/m 2 , and more preferably 1 g/m 2 to 25 g/m 2 . 5g/m 2 ~ 20g/m 2 . By setting the amount of coated silver to the above range, a desired surface resistance can be obtained when the first build-up conductive sheet 50A or the second build-up conductive sheet 50B (50 Ba) is formed.

本實施形態中使用的黏合劑例如可列舉:明膠(gelatin)、聚乙烯醇(PVA)、聚乙烯吡咯烷酮(PVP)、澱粉等多糖類、纖維素及其衍生物、聚環氧乙烯(poly vinyloxide)、聚乙烯基胺、殼聚糖(chitosan)、聚離胺酸、聚丙烯酸、聚海藻酸、聚玻尿酸、羧基纖維素等。該些黏合劑視官能基的離子性不同而具有中性、陰離子性、陽離子性的性質。Examples of the binder used in the present embodiment include gelatin, polyvinyl alcohol (PVA), polyvinylpyrrolidone (PVP), polysaccharides such as starch, cellulose and derivatives thereof, and polyvinyloxide. ), polyvinylamine, chitosan, polylysine, polyacrylic acid, polyalginic acid, polyhyaluronic acid, carboxy cellulose, and the like. These binders have neutral, anionic, and cationic properties depending on the ionicity of the functional groups.

本實施形態的銀鹽乳劑層中含有的黏合劑的含量並無特別限定,可於能發揮分散性及密接性的範圍內適當決定。銀鹽乳劑層中的黏合劑的含量以銀/黏合劑體積比計較佳為1/4以上,更佳為1/2以上。銀/黏合劑體積比較佳為100/1以下,更佳為50/1以下。另外,銀/黏合劑體積比進而佳為1/1~4/1,最佳為1/1~3/1。藉由將銀鹽乳劑層中的銀/黏合劑體積比設定為該範圍,即便調整了塗佈銀量時亦可抑制電阻值的不均,獲得具有均勻表面電阻的第1積層導電片50A或第2積層導電片50B。再者,銀/黏合劑體 積比可藉由將原料的鹵化銀量/黏合劑量(重量比)轉換成銀量/黏合劑量(重量比),進而將銀量/黏合劑量(重量比)轉換成銀量/黏合劑量(體積比)而求出。The content of the binder contained in the silver salt emulsion layer of the present embodiment is not particularly limited, and can be appropriately determined within a range in which dispersibility and adhesion can be exhibited. The content of the binder in the silver salt emulsion layer is preferably 1/4 or more, more preferably 1/2 or more in terms of a silver/binder volume ratio. The volume of the silver/binder is preferably 100/1 or less, more preferably 50/1 or less. Further, the silver/binder volume ratio is preferably from 1/1 to 4/1, and most preferably from 1/1 to 3/1. By setting the silver/binder volume ratio in the silver salt emulsion layer to this range, unevenness in resistance value can be suppressed even when the amount of coated silver is adjusted, and the first laminated conductive sheet 50A having uniform surface resistance can be obtained or The second build-up conductive sheet 50B. Furthermore, the silver/gluer body The product ratio can be converted into silver amount/adhesive amount (volume ratio) by converting the amount of silver halide/binder (weight ratio) of the raw material into silver amount/binder amount (weight ratio). It is obtained by comparison.

<溶劑><solvent>

用於形成銀鹽乳劑層的溶劑並無特別限定,例如可列舉水、有機溶劑(例如甲醇等醇類、丙酮等酮類、甲醯胺等醯胺類、二甲基亞碸等亞碸類、乙酸乙酯等酯類、醚類等)、離子性液體以及該些溶劑的混合溶劑。The solvent for forming the silver salt emulsion layer is not particularly limited, and examples thereof include water and an organic solvent (for example, an alcohol such as methanol, a ketone such as acetone, a guanamine such as formamide, or an anthraquinone such as dimethyl hydrazine. , an ester such as ethyl acetate, an ether or the like), an ionic liquid, and a mixed solvent of the solvents.

本實施形態的銀鹽乳劑層中使用的溶劑的含量相對於銀鹽乳劑層所含的銀鹽、黏合劑等的合計重量而為30wt%~90wt%的範圍,較佳為50wt%~80wt%的範圍。The content of the solvent to be used in the silver salt emulsion layer of the present embodiment is in the range of 30% by weight to 90% by weight, preferably 50% by weight to 80% by weight based on the total weight of the silver salt, the binder, and the like contained in the silver salt emulsion layer. The scope.

<其他添加劑><Other additives>

關於本實施形態中使用的各種添加劑,並無特別限制,可較佳地使用公知的添加劑。The various additives used in the present embodiment are not particularly limited, and known additives can be preferably used.

[其他層構成][Other layer composition]

亦可於銀鹽乳劑層上設置未圖示的保護層。本實施形態中所謂「保護層」,是指由明膠或高分子聚合物之類的黏合劑形成的層,是為了表現出防擦傷或改良力學特性的效果而形成於具有感光性的銀鹽乳劑層上。其厚度較佳為0.5μm以下。保護層的塗佈方法以及形成方法並無特別限定,可適當選擇公知的塗佈方法以及形成方法。另外,亦可於銀鹽乳劑層16的更下方設置例如底塗層。A protective layer (not shown) may be provided on the silver salt emulsion layer. In the present embodiment, the term "protective layer" means a layer formed of a binder such as gelatin or a polymer, and is formed into a photosensitive silver salt emulsion in order to exhibit an effect of preventing scratches or improving mechanical properties. On the floor. The thickness thereof is preferably 0.5 μm or less. The coating method and the formation method of the protective layer are not particularly limited, and a known coating method and formation method can be appropriately selected. Further, for example, an undercoat layer may be provided further below the silver salt emulsion layer 16.

接著,對第1導電片10A(10Aa)以及第2導電片10B(10Ba)的製作方法的各步驟加以說明。Next, each step of the method of producing the first conductive sheet 10A (10Aa) and the second conductive sheet 10B (10Ba) will be described.

[曝光][exposure]

本實施形態中,包括藉由印刷方式來施加第1導電圖案22A以及第2導電圖案22B的情形,除了印刷方式以外,藉由曝光與顯影等來形成第1導電圖案22A以及第2導電圖案22B。即,對設於第1透明基體12A以及第2透明基體12B上的具有含銀鹽的層的感光材料或塗佈有光微影用光聚合物的感光材料進行曝光。曝光可使用電磁波來進行。電磁波例如可列舉可見光線、紫外線等光、X射線等放射線等。進而,曝光時亦可利用具有波長分佈的光源,亦可使用特定波長的光源。In the present embodiment, the first conductive pattern 22A and the second conductive pattern 22B are applied by printing, and the first conductive pattern 22A and the second conductive pattern 22B are formed by exposure, development, or the like in addition to the printing method. . That is, the photosensitive material having the layer containing the silver salt provided on the first transparent substrate 12A and the second transparent substrate 12B or the photosensitive material coated with the photopolymer for photolithography is exposed. Exposure can be performed using electromagnetic waves. Examples of the electromagnetic wave include visible light, ultraviolet light, and the like, and radiation such as X-ray. Further, a light source having a wavelength distribution or a light source having a specific wavelength may be used for the exposure.

[顯影處理][development processing]

本實施形態中,對乳劑層進行曝光後,進而進行顯影處理。顯影處理可使用銀鹽相片膜或列印紙、印刷製版用膜、光罩用乳膠遮罩等所使用的通常的顯影處理的技術。顯影液並無特別限定,亦可使用PQ顯影液、MQ顯影液、MAA顯影液等,市售品例如可使用富士膠片公司調配的CN-16、CR-56、CP45X、FD-3、Papitol,KODAK公司調配的C-41、E-6、RA-4、D-19、D-72等顯影液或其套組(kit)所含的顯影液。另外,亦可使用平版顯影液。In the present embodiment, after the emulsion layer is exposed, development processing is further performed. For the development treatment, a technique of usual development treatment used for a silver salt photographic film or a printing paper, a film for printing plate, a latex mask for a photomask, or the like can be used. The developer is not particularly limited, and a PQ developer, an MQ developer, a MAA developer, or the like may be used. For commercial products, for example, CN-16, CR-56, CP45X, FD-3, and Papitol formulated by Fujifilm Co., Ltd. may be used. A developing solution contained in a developing solution such as C-41, E-6, RA-4, D-19, D-72 or a kit thereof prepared by KODAK. Alternatively, a lithographic developer can be used.

本發明的顯影處理可包含為了去除未曝光部分的銀鹽而實現穩定而進行的固定處理。本發明的固定處理可使用銀鹽相片膜或列印紙、印刷製版用膜、光罩用乳膠遮罩等所使用的固定處理的技術。The development treatment of the present invention may include a fixing treatment for achieving stabilization in order to remove the silver salt of the unexposed portion. The fixing treatment of the present invention can be carried out using a silver salt photographic film or a printing paper, a film for printing plate, a latex mask for a mask, and the like.

上述固定步驟中的固定溫度較佳為約20℃~約50 ℃,進而佳為25℃~45℃。另外,固定時間較佳為5秒~1分鐘,進而佳為7秒~50秒。固定液的補充量相對於感光材料的處理量而較佳為600ml/m2 以下,更佳為500ml/m2 以下,特佳為300ml/m2 以下。The fixing temperature in the above fixing step is preferably from about 20 ° C to about 50 ° C, and more preferably from 25 ° C to 45 ° C. In addition, the fixed time is preferably from 5 seconds to 1 minute, and more preferably from 7 seconds to 50 seconds. The amount of the fixing liquid to be added is preferably 600 ml/m 2 or less, more preferably 500 ml/m 2 or less, and particularly preferably 300 ml/m 2 or less, based on the amount of the photosensitive material.

實施了顯影、固定處理的感光材料較佳為實施水洗處理或穩定處理。上述水洗處理或穩定處理中,水洗水量通常是相對於感光材料1m2 以20L以下來進行,亦能以3L以下的補充量(亦包括0,即積水水洗)來進行。The photosensitive material subjected to development and fixation treatment is preferably subjected to a water washing treatment or a stabilization treatment. In the water washing treatment or the stabilization treatment, the amount of the water washing water is usually 20 L or less with respect to 1 m 2 of the photosensitive material, and can be carried out with a replenishing amount of 3 L or less (including 0, that is, water washing).

顯影處理後的曝光部所含的金屬銀的重量較佳為相對於曝光前的曝光部所含的銀的重量而為50wt%以上的含有率,更佳為80wt%以上。若曝光部所含的銀的重量相對於曝光前的曝光部所含的銀的重量而為50wt%以上,則可獲得高導電性,故較佳。The weight of the metallic silver contained in the exposed portion after the development treatment is preferably 50% by weight or more, more preferably 80% by weight or more, based on the weight of the silver contained in the exposed portion before the exposure. When the weight of the silver contained in the exposed portion is 50% by weight or more based on the weight of the silver contained in the exposed portion before the exposure, high conductivity can be obtained, which is preferable.

本實施形態中的顯影處理後的灰階並無特別限定,較佳為超過4.0。若顯影處理後的灰階超過4.0,則可於將透光性部的透光性保持得較高的狀態下提高導電性金屬部的導電性。使灰階為4.0以上的方法例如可列舉上述銠離子、銥離子的摻雜。The gray scale after the development treatment in the present embodiment is not particularly limited, but is preferably more than 4.0. When the gradation after the development treatment exceeds 4.0, the conductivity of the conductive metal portion can be improved while maintaining the light transmittance of the light-transmitting portion high. Examples of the method of setting the gradation to 4.0 or more include doping of the above-described cerium ions and cerium ions.

經由以上步驟可獲得導電片,所得導電片的表面電阻較佳為在0.1Ω/sq.~100Ω/sq.的範圍內。下限值較佳為1Ω/sq.以上,更佳為3Ω/sq.以上,進而佳為5Ω/sq.以上,進一步佳為10Ω/sq.。上限值較佳為70Ω/sq.以下,更佳為50Ω/sq.以下。另外,對於顯影處理後的導電片,亦可進一步進行砑光處理,可藉由砑光處理來調整成所需的表面電 阻。The conductive sheet can be obtained through the above steps, and the surface resistance of the obtained conductive sheet is preferably in the range of 0.1 Ω/sq. to 100 Ω/sq. The lower limit is preferably 1 Ω/sq. or more, more preferably 3 Ω/sq. or more, further preferably 5 Ω/sq. or more, and further preferably 10 Ω/sq. The upper limit is preferably 70 Ω/sq. or less, more preferably 50 Ω/sq. or less. In addition, the conductive sheet after the development process can be further subjected to calendering treatment, and can be adjusted to a desired surface electric power by calendering treatment. Resistance.

[物理顯影以及電鍍處理][Physical development and plating treatment]

本實施形態中,為了使藉由上述曝光以及顯影處理而形成的金屬銀部的導電性提昇,亦可進行用以使上述金屬銀部承載導電性金屬粒子的物理顯影及/或電鍍處理。本發明中,可僅利用物理顯影或電鍍處理的任一種而使金屬性銀部承載導電性金屬粒子,亦可將物理顯影與電鍍處理組合而使金屬銀部承載導電性金屬粒子。再者,將對金屬銀部實施物理顯影及/或電鍍處理而成的部分包括在內而稱為「導電性金屬部」。In the present embodiment, in order to improve the conductivity of the metal silver portion formed by the exposure and development processes, physical development and/or plating treatment for carrying the conductive metal particles on the metal silver portion may be performed. In the present invention, the metallic silver portion may carry the conductive metal particles by any of physical development or plating treatment, or the metal silver portion may be carried by the physical development and the plating treatment. Further, a portion obtained by subjecting the metal silver portion to physical development and/or plating treatment is referred to as a "conductive metal portion".

所謂本實施形態中的「物理顯影」,是指於金屬或金屬化合物的核上利用還原劑將銀離子等金屬離子還原而使金屬粒子析出。該物理現象是用於一步黑白膠片(instant black and white film,一步B&W膠片)、一步幻燈膠片(instant slide film)或印刷版製造等中,本發明中可使用該技術。The term "physical development" in the present embodiment means that metal ions such as silver ions are reduced by a reducing agent on a core of a metal or a metal compound to precipitate metal particles. This physical phenomenon is used in one-time black and white film (one-step B&W film), one-step slide film or printing plate manufacturing, and the like, which can be used in the present invention.

另外,物理顯影可與曝光後的顯影處理同時進行,亦可於顯影處理後另外進行。Further, the physical development may be performed simultaneously with the development processing after the exposure, or may be additionally performed after the development processing.

本實施形態中,電鍍處理可使用無電電鍍(化學還原電鍍或置換電鍍)、電解電鍍、或無電電鍍與電解電鍍兩種。本實施形態的無電電鍍可使用公知的無電電鍍技術,例如可使用印刷配線板等中使用的無電電鍍技術,無電電鍍較佳為無電鍍銅。In the present embodiment, electroplating treatment may be performed by electroless plating (chemical reduction plating or displacement plating), electrolytic plating, or electroless plating or electrolytic plating. In the electroless plating of the present embodiment, a known electroless plating technique can be used. For example, an electroless plating technique used in a printed wiring board or the like can be used, and electroless plating is preferably electroless copper plating.

[氧化處理][Oxidation treatment]

本實施形態中,較佳為對顯影處理後的金屬銀部以及藉由物理顯影及/或電鍍處理而形成的導電性金屬部實施氧化處理。In the present embodiment, it is preferable that the metal silver portion after the development treatment and the conductive metal portion formed by the physical development and/or the plating treatment are subjected to an oxidation treatment.

藉由進行氧化處理,例如於在透光性部上稍許沈積有金屬的情形時,可將該金屬去除而使透光性部的透射性幾乎為100%。When the oxidation treatment is performed, for example, when a metal is slightly deposited on the light-transmitting portion, the metal can be removed to make the transmittance of the light-transmitting portion almost 100%.

[導電性金屬部][Electrically conductive metal part]

本實施形態的導電性金屬部的線寬(第1導電部13A以及第2導電部13B的線寬)的下限較佳為1μm以上、3μm以上、4μm以上或5μm以上,上限較佳為10μm以下、9μm以下、8μm以下。當線寬小於上述下限值時,導電性變得不充分,用於觸控面板100時檢測感度變得不充分。另一方面,若線寬超過上述上限值,則由導電性金屬部引起的條紋(moire)變顯著,或用於觸控面板100時視認性變差。再者,藉由設定於上述範圍內,導電性金屬部的條紋得到改善,視認性變得特佳。線間隔(此處為小格子18的彼此相向的邊的間隔)較佳為30μm以上500μm以下,更佳為50μm以上400μm以下,最佳為100μm以上350μm以下。另外,導電性金屬部亦可具有線寬較200μm更寬的部分以進行接地等。The lower limit of the line width (the line width of the first conductive portion 13A and the second conductive portion 13B) of the conductive metal portion of the present embodiment is preferably 1 μm or more, 3 μm or more, 4 μm or more, or 5 μm or more, and the upper limit is preferably 10 μm or less. , 9 μm or less, and 8 μm or less. When the line width is less than the above lower limit value, the conductivity becomes insufficient, and the detection sensitivity becomes insufficient when used for the touch panel 100. On the other hand, when the line width exceeds the above upper limit value, the moire caused by the conductive metal portion becomes conspicuous, or when the touch panel 100 is used, the visibility is deteriorated. Further, by setting within the above range, the streaks of the conductive metal portion are improved, and the visibility is particularly excellent. The line spacing (here, the interval between the sides of the small lattices 18 facing each other) is preferably 30 μm or more and 500 μm or less, more preferably 50 μm or more and 400 μm or less, and most preferably 100 μm or more and 350 μm or less. Further, the conductive metal portion may have a portion having a line width wider than 200 μm to perform grounding or the like.

本實施形態的導電性金屬部就可見光透射率的方面而言,開口率較佳為85%以上,更佳為90%以上,最佳為95%以上。所謂開口率,是指除了第1大格子14A、第1連接部16A、第2大格子14B、第2連接部16B、小格子 18等導電部以外的透光性部分佔整體的比例,例如線寬為15μm、間距為300μm的正方形的格子狀的開口率為90%。In the conductive metal portion of the present embodiment, the aperture ratio is preferably 85% or more, more preferably 90% or more, and most preferably 95% or more in terms of visible light transmittance. The aperture ratio means the first large lattice 14A, the first connection portion 16A, the second large lattice 14B, the second connection portion 16B, and the small lattice. The proportion of the light-transmitting portion other than the conductive portion such as 18 is as a whole, and for example, a square lattice-like aperture ratio of a line width of 15 μm and a pitch of 300 μm is 90%.

[透光性部][Translucent part]

所謂本實施形態的「透光性部」,是指第1導電片10A以及第2導電片10B中導電性金屬部以外的具有透光性的部分。透光性部的透射率如上所述,第1透明基體12A以及第2透明基體12B的將光吸收及反射的作用除外的380nm~780nm的波長區域下的透射率的最小值所表示的透射率為90%以上,較佳為95%以上,更佳為97%以上,進而更佳為98%以上,最佳為99%以上。The "translucent portion" of the present embodiment refers to a portion having light transmissivity other than the conductive metal portion in the first conductive sheet 10A and the second conductive sheet 10B. As described above, the transmittance of the translucent portion is the transmittance of the minimum value of the transmittance in the wavelength region of 380 nm to 780 nm excluding the effects of light absorption and reflection by the first transparent substrate 12A and the second transparent substrate 12B. It is 90% or more, preferably 95% or more, more preferably 97% or more, still more preferably 98% or more, and most preferably 99% or more.

關於曝光方法,較佳為介隔玻璃遮罩的方法或利用雷射繪圖的圖案曝光方式。As for the exposure method, a method of interposing a glass mask or a pattern exposure method using laser drawing is preferred.

[第1導電片10A(10Aa)以及第2導電片10B(10Ba)][First conductive sheet 10A (10Aa) and second conductive sheet 10B (10Ba)]

本實施形態的第1導電片10A(10Aa)以及第2導電片10B(10Ba)中的第1透明基體12A以及第2透明基體12B的厚度較佳為5μm~350μm,更佳為30μm~150μm。若為5μm~350μm的範圍,則可獲得所需的可見光的透射率,且操作亦容易。The thickness of the first transparent substrate 12A and the second transparent substrate 12B in the first conductive sheet 10A (10Aa) and the second conductive sheet 10B (10Ba) of the present embodiment is preferably 5 μm to 350 μm, and more preferably 30 μm to 150 μm. If it is in the range of 5 μm to 350 μm, the required transmittance of visible light can be obtained, and the operation is also easy.

第1透明基體12A以及第2透明基體12B上設置的金屬銀部的厚度可根據第1透明基體12A以及第2透明基體12B上塗佈的含銀鹽的層用塗料的塗佈厚度而適當決定。金屬銀部的厚度可自0.001mm~0.2mm中選擇,較佳為30μm以下,更佳為20μm以下,進而佳為0.01μm ~9μm,最佳為0.05μm~5μm。另外,金屬銀部較佳為圖案狀。金屬銀部可為一層,亦可為二層以上的多層構成。於金屬銀部為圖案狀、且為二層以上的多層構成的情形時,可賦予不同感色性以可於不同波長下感光。藉此,若改變曝光波長進行曝光,則可於各層上形成不同圖案。The thickness of the metal silver portion provided on the first transparent substrate 12A and the second transparent substrate 12B can be appropriately determined depending on the coating thickness of the coating material for the silver salt-containing layer applied on the first transparent substrate 12A and the second transparent substrate 12B. . The thickness of the metal silver portion may be selected from 0.001 mm to 0.2 mm, preferably 30 μm or less, more preferably 20 μm or less, and further preferably 0.01 μm. ~9 μm, preferably 0.05 μm to 5 μm. Further, the metallic silver portion is preferably in the form of a pattern. The metal silver portion may be one layer or may be composed of two or more layers. When the metal silver portion is in the form of a pattern and is composed of a plurality of layers of two or more layers, different color sensitivities can be imparted so that light can be received at different wavelengths. Thereby, if the exposure wavelength is changed and exposure is performed, different patterns can be formed on each layer.

關於導電性金屬部的厚度,於觸控面板的用途中厚度越薄則顯示面板的視角越廣故而較佳,就視認性提昇的觀點而言亦要求薄膜化。就此種觀點而言,由導電性金屬部所承載的導電性金屬所形成的層的厚度較佳為小於9μm,更佳為0.1μm以上且小於5μm,進而佳為0.1μm以上且小於3μm。Regarding the thickness of the conductive metal portion, the thinner the thickness of the display panel in the use of the touch panel, the better the viewing angle of the display panel is, and the thinning is also required from the viewpoint of improving visibility. From this point of view, the thickness of the layer formed of the conductive metal carried by the conductive metal portion is preferably less than 9 μm, more preferably 0.1 μm or more and less than 5 μm, and further preferably 0.1 μm or more and less than 3 μm.

本實施形態中,藉由控制上述含銀鹽的層的塗佈厚度而形成所需厚度的金屬銀部,進而藉由物理顯影及/或電鍍處理而可自如地控制由導電性金屬粒子形成的層的厚度,故即便是具有小於5μm、較佳為小於3μm的厚度的第1導電片10A(10Aa)以及第2導電片10B(10Ba),亦可容易地形成。In the present embodiment, the metal silver portion having a desired thickness is formed by controlling the coating thickness of the silver salt-containing layer, and the conductive metal particles are freely controlled by physical development and/or plating treatment. Since the thickness of the layer is such that the first conductive sheet 10A (10Aa) and the second conductive sheet 10B (10Ba) having a thickness of less than 5 μm, preferably less than 3 μm, can be easily formed.

再者,本實施形態的第1導電片10A(10Aa)或第2導電片10B(10Ba)的製造方法中,未必一定要進行電鍍等步驟。其原因在於,本實施形態的第1導電片10A(10Aa)或第2導電片10B(10Ba)的製造方法中,可藉由調整銀鹽乳劑層的塗佈銀量、銀/黏合劑體積比而獲得所需的表面電阻。再者,視需要亦可進行砑光處理等。Further, in the method of manufacturing the first conductive sheet 10A (10Aa) or the second conductive sheet 10B (10Ba) of the present embodiment, it is not always necessary to perform steps such as plating. The reason for this is that in the method for producing the first conductive sheet 10A (10Aa) or the second conductive sheet 10B (10Ba) of the present embodiment, the silver amount and the silver/binder volume ratio of the silver salt emulsion layer can be adjusted. And get the required surface resistance. Further, calendering treatment or the like may be performed as needed.

(顯影處理後的硬膜處理)(hard film treatment after development treatment)

對銀鹽乳劑層進行顯影處理後,較佳為浸漬於硬膜劑中而進行硬膜處理。硬膜劑例如可列舉戊二醛(glutaraldehyde)、己二醛(adipaldehyde)、2,3-二羥基-1,4-二噁烷等二醛類以及硼酸等日本專利特開平2-141279號中記載的硬膜劑。After the silver salt emulsion layer is subjected to development treatment, it is preferably immersed in a hard coating agent to perform a hard film treatment. Examples of the hardener include glutaraldehyde, adipaldehyde, dialdehyde such as 2,3-dihydroxy-1,4-dioxane, and boric acid, etc., in Japanese Patent Laid-Open No. Hei 2-141279 The hardener described.

[積層導電片][Laminated conductive sheet]

對於積層導電片,亦可賦予抗反射膜126。此時,可較佳地採用上述圖8A~圖8C所示的第1構成例~第3構成例。The antireflection film 126 can also be provided for the laminated conductive sheet. In this case, the first to third configuration examples shown in FIGS. 8A to 8C described above can be preferably used.

抗反射膜126例如是在第1積層導電片50A上形成硬塗層122以及抗反射層124(參照第1構成例以及第2構成例)、或在第1積層導電片50A上形成透明膜130、硬塗層122以及抗反射層124而製作(參照第3構成例)。The anti-reflection film 126 is formed, for example, by forming the hard coat layer 122 and the anti-reflection layer 124 on the first build-up conductive sheet 50A (see the first configuration example and the second configuration example), or forming the transparent film 130 on the first build-up conductive sheet 50A. The hard coat layer 122 and the anti-reflection layer 124 are produced (see the third configuration example).

以下,以第3構成例為主體,對抗反射膜126的較佳態樣進行說明。Hereinafter, a preferred embodiment of the antireflection film 126 will be described with reference to the third configuration example.

<透明膜130><Transparent film 130>

透明膜130是用於顯示裝置108的視認者側表面,故要求其為透光率高、且透明性優異的無色的膜。此種透明膜130較佳為使用塑膠膜。形成塑膠膜的聚合物可列舉:醯化纖維素(例如富士膠片(股)製造的TAC-TD80U、TD80UF等三乙醯纖維素,二乙醯纖維素,乙醯丙醯纖維素,乙醯丁醯纖維素)、聚醯胺、聚碳酸酯、聚酯(例如聚對苯二甲酸乙二酯、聚萘二甲酸乙二酯)、聚苯乙烯、聚烯烴、降冰片烯系樹脂(Arton:商品名,JSR(股)製造)、 非晶質聚烯烴(Zeonex:商品名,日本Zeon(股)製造)、(甲基)丙烯酸系樹脂(Acrypet VRL20A:商品名,三菱麗陽(股)製造,日本專利特開2004-70296號公報或日本專利特開2006-171464號公報記載的含環結構的丙烯酸系樹脂)等。其中,較佳為三乙醯纖維素、乙醯丙醯纖維素、乙醯丁醯纖維素、聚對苯二甲酸乙二酯、聚萘二甲酸乙二酯,特佳為三乙醯纖維素。Since the transparent film 130 is used for the viewer side surface of the display device 108, it is required to be a colorless film having high light transmittance and excellent transparency. Such a transparent film 130 is preferably a plastic film. Examples of the polymer forming the plastic film include deuterated cellulose (for example, TAC-TD80U, TD80UF, etc. manufactured by Fujifilm Co., Ltd., triethylene phthalate cellulose, diethyl phthalocyanine, acetaminophen cellulose, acetaminophen醯 cellulose), polyamide, polycarbonate, polyester (eg polyethylene terephthalate, polyethylene naphthalate), polystyrene, polyolefin, norbornene resin (Arton: Product name, JSR (share) manufacturing), Amorphous polyolefin (Zeonex: trade name, manufactured by Zeon, Japan), (meth)acrylic resin (Acrypet VRL20A: trade name, manufactured by Mitsubishi Rayon Co., Ltd., Japanese Patent Laid-Open No. 2004-70296 Or a ring-shaped acrylic resin described in JP-A-2006-171464. Among them, preferred is triethyl hydrazine cellulose, acetamidine cellulose, acetamidine cellulose, polyethylene terephthalate, polyethylene naphthalate, and particularly preferred is triacetyl cellulose. .

<硬塗層122><hard coating 122>

為了賦予抗反射膜126的物理強度,較佳為於該抗反射膜126上設置硬塗層122。硬塗層122亦可由2層以上的積層構成。In order to impart physical strength to the anti-reflection film 126, it is preferable to provide a hard coat layer 122 on the anti-reflection film 126. The hard coat layer 122 may also be composed of two or more layers.

關於硬塗層122的折射率,根據用以獲得抗反射性的膜的光學設計,折射率較佳為在1.48~1.90的範圍內,更佳為1.50~1.80,進而佳為1.52~1.65。本實施形態中,於硬塗層122上具有至少一層低折射率層,因此若折射率較該範圍過小則抗反射性下降,若過大則有反射光的色調變強的傾向。Regarding the refractive index of the hard coat layer 122, the refractive index is preferably in the range of 1.48 to 1.90, more preferably 1.50 to 1.80, and further preferably 1.52 to 1.65, depending on the optical design of the film for obtaining antireflection. In the present embodiment, since at least one low refractive index layer is provided on the hard coat layer 122, when the refractive index is too small, the antireflection property is lowered, and if it is too large, the color tone of the reflected light tends to be strong.

關於硬塗層122,就對抗反射膜126賦予充分的耐久性、耐衝擊性的觀點而言,硬塗層122的厚度通常是設為0.5μm~50μm左右,較佳為1μm~20μm,更佳為2μm~15μm,最佳為3μm~10μm。另外,硬塗層122的強度於鉛筆硬度試驗中,較佳為2H以上,更佳為3H以上,最佳為4H以上。進而,於依照JISK5400而進行的Taber試驗中,試驗前後的試驗片的磨損量越少越好。The hard coat layer 122 has a thickness of usually 0.5 μm to 50 μm, preferably 1 μm to 20 μm, more preferably from the viewpoint of imparting sufficient durability and impact resistance to the antireflection film 126. It is 2 μm to 15 μm, preferably 3 μm to 10 μm. Further, the strength of the hard coat layer 122 is preferably 2H or more, more preferably 3H or more, and most preferably 4H or more in the pencil hardness test. Further, in the Taber test conducted in accordance with JIS K5400, the amount of wear of the test piece before and after the test is preferably as small as possible.

硬塗層122較佳為藉由電離放射線硬化性化合物的交聯反應、或聚合反應而形成。例如,亦可藉由將含有電離放射線硬化性的多官能單體或多官能低聚物的組成物塗佈於透明膜130上,並使多官能單體或多官能低聚物進行交聯反應或聚合反應而形成。電離放射線硬化性的多官能單體或多官能低聚物的官能基較佳為光、電子束、放射線聚合性的物質,其中較佳為光聚合性官能基。光聚合性官能基可列舉(甲基)丙烯醯基、乙烯基、苯乙烯基、丙烯基等不飽和聚合性官能基等,其中較佳為(甲基)丙烯醯基。關於具體的化合物,可使用日本專利特開2006-30740號公報的段落[0087]以及[0088]中記載的單體,且可使用該公報的段落[0089]中記載的硬化方法。光聚合的情形時,可使用該公報的段落[0090]~[0093]中記載的光聚合起始劑。The hard coat layer 122 is preferably formed by a crosslinking reaction or a polymerization reaction of an ionizing radiation curable compound. For example, a composition containing an ionizing radiation-curable polyfunctional monomer or a polyfunctional oligomer may be applied to the transparent film 130 to crosslink the polyfunctional monomer or the polyfunctional oligomer. Or formed by polymerization. The functional group of the ionizing radiation-curable polyfunctional monomer or polyfunctional oligomer is preferably a light, electron beam, or radiation polymerizable substance, and among them, a photopolymerizable functional group is preferable. The photopolymerizable functional group may, for example, be an unsaturated polymerizable functional group such as a (meth)acryl fluorenyl group, a vinyl group, a styryl group or a propylene group. Among them, a (meth) acrylonitrile group is preferred. For the specific compound, the monomers described in paragraphs [0087] and [0088] of JP-A-2006-30740 can be used, and the curing method described in paragraph [0089] of the publication can be used. In the case of photopolymerization, the photopolymerization initiator described in paragraphs [0090] to [0093] of the publication can be used.

硬塗層122中,為賦予內部散射性,亦可含有平均粒徑為1.0μm~10.0μm,較佳為1.5μm~7.0μm的消光粒子,例如無機化合物的粒子或樹脂粒子。該些粒子可使用日本專利特開2006-30740號公報的段落[0114]中記載的粒子。The hard coat layer 122 may contain matting particles having an average particle diameter of 1.0 μm to 10.0 μm, preferably 1.5 μm to 7.0 μm, for example, particles of an inorganic compound or resin particles, in order to impart internal scattering properties. For the particles, the particles described in paragraph [0114] of JP-A-2006-30740 can be used.

為了控制硬塗層122的折射率,可於硬塗層122的黏合劑中添加高折射率單體或不產生光散射的大小的無機微粒子(一次粒子的直徑為10nm~200nm)或者此兩者。無機微粒子除了具有控制折射率的效果以外,亦具有抑制由交聯反應導致的硬化收縮的效果。無機微粒子可使用日本專利特開2006-30740號公報的段落[0120]中作為無機填 料而記載的化合物。In order to control the refractive index of the hard coat layer 122, a high refractive index monomer or inorganic fine particles of a size that does not cause light scattering (the primary particles have a diameter of 10 nm to 200 nm) or both may be added to the adhesive of the hard coat layer 122. . In addition to the effect of controlling the refractive index, the inorganic fine particles have an effect of suppressing the hardening shrinkage caused by the crosslinking reaction. The inorganic fine particles can be used as an inorganic filler in the paragraph [0120] of JP-A-2006-30740. The compound described.

<抗反射層124><Anti-reflection layer 124>

抗反射膜126是於上述硬塗層122上形成有抗反射層124的膜(有時亦包括下層的透明膜130),由於利用光學干涉,故抗反射層124較佳為具有以下所述的折射率及光學厚度。抗反射層124可僅為一層,而於謀求更低的反射率時,亦可將多個抗反射層124積層而形成。關於多個抗反射層124的積層,可將具有不同折射率的光學干涉層交替積層,亦可將具有不同折射率的光學干涉層積層2層以上。具體而言,常使用於硬塗層122上僅設置低折射率層的態樣,於硬塗層122上依序設置高折射率層、低折射率層的態樣,於硬塗層122上依序設置中折射率層、高折射率層、低折射率層的態樣。再者,折射率層的低、中、高是折射率的相對大小關係的表現。另外,低折射率層的折射率較佳為,設定得較上述硬塗層122的折射率更低。當低折射率層與硬塗層122的折射率差過小時,抗反射性下降,若過大則有反射光的色調變強的傾向。低折射率層與硬塗層122的折射率差較佳為0.01以上、0.40以下,更佳為0.05以上、0.30以下。The anti-reflection film 126 is a film in which the anti-reflection layer 124 is formed on the hard coat layer 122 (and sometimes includes the lower transparent film 130). Since optical interference is utilized, the anti-reflection layer 124 preferably has the following structure. Refractive index and optical thickness. The anti-reflection layer 124 may be only one layer, and when a lower reflectance is sought, a plurality of anti-reflection layers 124 may be laminated. Regarding the lamination of the plurality of anti-reflection layers 124, optical interference layers having different refractive indices may be alternately laminated, or two or more layers of optical interference layers having different refractive indices may be laminated. Specifically, a state in which only a low refractive index layer is provided on the hard coat layer 122, and a high refractive index layer and a low refractive index layer are sequentially disposed on the hard coat layer 122 on the hard coat layer 122. The medium refractive index layer, the high refractive index layer, and the low refractive index layer are sequentially disposed. Furthermore, the low, medium and high refractive index layers are representations of the relative magnitude relationship of the refractive indices. Further, the refractive index of the low refractive index layer is preferably set to be lower than the refractive index of the hard coat layer 122. When the difference in refractive index between the low refractive index layer and the hard coat layer 122 is too small, the antireflection property is lowered, and if it is too large, the color tone of the reflected light tends to be strong. The difference in refractive index between the low refractive index layer and the hard coat layer 122 is preferably 0.01 or more and 0.40 or less, more preferably 0.05 or more and 0.30 or less.

各層的折射率與厚度較佳為滿足以下條件。The refractive index and thickness of each layer preferably satisfy the following conditions.

即,低折射率層的折射率較佳為1.20~1.46,更佳為1.25~1.42,特佳為1.30~1.38。另外,低折射率層的厚度較佳為50nm~150nm,更佳為70nm~120nm。That is, the refractive index of the low refractive index layer is preferably from 1.20 to 1.46, more preferably from 1.25 to 1.42, and particularly preferably from 1.30 to 1.38. Further, the thickness of the low refractive index layer is preferably from 50 nm to 150 nm, more preferably from 70 nm to 120 nm.

為了於高折射率層上積層低折射率層而製作抗反射 膜126,高折射率層的折射率較佳為1.55~2.40,更佳為1.60~2.20,進而佳為1.65~2.10,最佳為1.80~2.00。Antireflection is made to laminate a low refractive index layer on the high refractive index layer The refractive index of the film 126 and the high refractive index layer is preferably from 1.55 to 2.40, more preferably from 1.60 to 2.20, further preferably from 1.65 to 2.10, and most preferably from 1.80 to 2.00.

於自透明膜130(或觸控面板100)起以由近至遠的順序積層中折射率層、高折射率層、低折射率層而製作抗反射膜126時,高折射率層的折射率較佳為1.65~2.40,更佳為1.70~2.20。中折射率層的折射率是以成為低折射率層的折射率與高折射率層的折射率之間的值的方式調整。中折射率層的折射率較佳為1.55~1.80。再者,高折射率層、中折射率層的厚度可設定為與折射率的範圍相應的光學厚度。When the anti-reflection film 126 is formed by laminating the medium refractive index layer, the high refractive index layer, and the low refractive index layer from the transparent film 130 (or the touch panel 100) in a near-to-far manner, the refractive index of the high refractive index layer It is preferably 1.65 to 2.40, more preferably 1.70 to 2.20. The refractive index of the medium refractive index layer is adjusted so as to be a value between the refractive index of the low refractive index layer and the refractive index of the high refractive index layer. The refractive index of the medium refractive index layer is preferably from 1.55 to 1.80. Further, the thickness of the high refractive index layer and the medium refractive index layer can be set to an optical thickness corresponding to the range of the refractive index.

[低折射率層][Low refractive index layer]

上述低折射率層較佳為於形成層後進行硬化。低折射率層的霧度較佳為3%以下,更佳為2%以下,最佳為1%以下。The low refractive index layer is preferably hardened after forming a layer. The haze of the low refractive index layer is preferably 3% or less, more preferably 2% or less, and most preferably 1% or less.

用以形成本發明的低折射率層的較好組成物較佳為至少包含以下任一種的組成物。可列舉:(1)含有具有交聯性或聚合性的官能基的含氟聚合物的組成物、(2)以含氟的有機矽烷材料的水解縮合物為主成分的組成物、(3)含有具有2個以上的乙烯性不飽和基的單體及具有中空結構的無機微粒子的組成物。A preferred composition for forming the low refractive index layer of the present invention is preferably a composition containing at least one of the following. (1) a composition containing a fluorine-containing polymer having a crosslinkable or polymerizable functional group, (2) a composition containing a hydrolysis-condensation product of a fluorine-containing organodecane material as a main component, and (3) A composition containing a monomer having two or more ethylenically unsaturated groups and inorganic fine particles having a hollow structure.

(1)具有交聯性或聚合性的官能基的含氟化合物(1) A fluorine-containing compound having a crosslinkable or polymerizable functional group

具有交聯性或聚合性的官能基的含氟化合物可列舉 含氟單體與具有交聯性或聚合性的官能基的單體的共聚物。A fluorine-containing compound having a crosslinkable or polymerizable functional group can be enumerated A copolymer of a fluorine-containing monomer and a monomer having a crosslinkable or polymerizable functional group.

上述共聚物中,主鏈僅由碳原子構成、且含有含氟乙烯基單體聚合單元及側鏈上具有(甲基)丙烯醯基的聚合單元而成的共聚物可使用日本專利特開2004-45462號公報的段落[0043]~[0047]中記載的P-1~P-40。另外,為了改良耐擦傷性及滑動性而導入有聚矽氧成分的含氟聚合物、側鏈上具有含有聚矽氧烷部位的聚合單元且主鏈上具有氟原子的接枝聚合物可使用日本專利特開2003-222702號公報的段落[0074]~[0076]的表1以及表2中記載的化合物,主鏈上含有來源於聚矽氧烷化合物的結構單元的含乙烯性不飽和基的氟聚合物可使用日本專利特開2003-183322號公報中記載的化合物。In the above copolymer, a copolymer in which a main chain consists only of carbon atoms and which contains a polymerized unit of a fluorine-containing vinyl monomer and a polymerized unit having a (meth)acryloyl group on the side chain can be used in Japanese Patent Laid-Open 2004. P-1 to P-40 described in paragraphs [0043] to [0047] of the '45 publication. Further, a fluorine-containing polymer having a polyfluorene component introduced therein to improve scratch resistance and slidability, a graft polymer having a polymerized unit containing a polyoxyalkylene moiety in a side chain, and a fluorine atom in the main chain can be used. The compounds described in Tables 1 and 2 of the paragraphs [0074] to [0076] of JP-A-2003-222702, wherein the main chain contains an ethylenically unsaturated group derived from a structural unit of a polyoxyalkylene compound. As the fluoropolymer, a compound described in JP-A-2003-183322 can be used.

對於上述聚合物,亦可如日本專利特開2000-17028號公報所記載般適當併用具有聚合性不飽和基的硬化劑。另外,如日本專利特開2002-145952號公報所記載般與含氟的多官能的具有聚合性不飽和基的化合物併用亦較佳。多官能的具有聚合性不飽和基的化合物的例子可列舉上述具有2個以上的乙烯性不飽和基的單體。另外,日本專利特開2004-170901號公報所記載的有機矽烷的水解縮合物亦較佳,特佳為含有(甲基)丙烯醯基的有機矽烷的水解縮合物。該些化合物特別於對聚合物本體使用具有聚合性不飽和基的化合物時,與耐擦傷性改良的併用效果大而較佳。For the above-mentioned polymer, a curing agent having a polymerizable unsaturated group can be suitably used in combination as described in JP-A-2000-17028. Further, as described in JP-A-2002-145952, it is also preferred to use a compound having a polyfunctional polymerizable unsaturated group containing fluorine. Examples of the polyfunctional polymerizable unsaturated group-containing compound include the above-mentioned monomers having two or more ethylenically unsaturated groups. In addition, a hydrolysis condensate of an organic decane described in JP-A-2004-170901 is also preferable, and a hydrolysis condensate of an organic decane containing a (meth) acryloyl group is particularly preferable. These compounds are particularly preferable when a compound having a polymerizable unsaturated group is used for the polymer main body, and the effect of improving the abrasion resistance is large.

於聚合物自身單獨不具有充分的硬化性時,可藉由調 配交聯性化合物而賦予必要的硬化性。例如於聚合物本體含有羥基時,較佳為使用各種胺基化合物作為硬化劑。用作交聯性化合物的胺基化合物例如為合計含有2個以上的羥基烷基胺基以及烷氧基烷基胺基的任一種或兩種的化合物,具體而言,例如可列舉三聚氰胺系化合物、脲系化合物、苯代三聚氰胺系化合物、甘脲系化合物等。該些化合物的硬化時,較佳為使用有機酸或其鹽。When the polymer itself does not have sufficient hardenability alone, A cross-linking compound is added to impart the necessary hardenability. For example, when the polymer body contains a hydroxyl group, it is preferred to use various amine compounds as a hardener. The amine-based compound to be used as the cross-linking compound is, for example, a compound containing two or more of a hydroxyalkylamino group and an alkoxyalkylamino group in combination, and specific examples thereof include a melamine-based compound. A urea compound, a benzoguanamine compound, a glycoluril compound, or the like. When these compounds are hardened, it is preferred to use an organic acid or a salt thereof.

(2)含氟的有機矽烷材料的水解縮合物(2) Hydrolysis condensate of fluorine-containing organic decane material

以含氟的有機矽烷化合物的水解縮合物為主成分的組成物亦是折射率低、塗膜表面的硬度高而較佳。較佳為使氟化烷基於單末端或兩末端含有水解性的矽烷醇的化合物與四烷氧基矽烷的縮合物。具體組成物於日本專利特開2002-265866號公報、日本專利特開2002-317152號公報中有所記載。The composition containing the hydrolysis condensate of the fluorine-containing organodecane compound as a main component is preferably a refractive index low and a high hardness on the surface of the coating film. A condensate of a compound in which a fluorinated alkyl group contains a hydrolyzable stanol at a single terminal or both ends and a tetraalkoxy decane is preferred. The specific composition is described in Japanese Laid-Open Patent Publication No. 2002-265866, and Japanese Patent Laid-Open No. 2002-317152.

(3)含有具有2個以上的乙烯性不飽和基的單體與具有中空結構的無機微粒子的組成物(3) A composition containing a monomer having two or more ethylenically unsaturated groups and inorganic fine particles having a hollow structure

進而,作為其他的較佳態樣,可列舉由低折射率的粒子與黏合劑形成的低折射率層。低折射率粒子為有機或無機均可,較佳為內部具有孔隙的粒子。關於中空粒子的具體例,於日本專利特開2002-79616號公報中記載有二氧化矽系粒子(例如參照段落[0041]~[0049])。粒子折射率較佳為1.15~1.40,更佳為1.20~1.30。黏合劑可列舉上述硬塗層122的項中所述的具有2個以上的乙烯性不飽和基的單體。Further, as another preferable aspect, a low refractive index layer formed of particles having a low refractive index and a binder may be mentioned. The low refractive index particles may be organic or inorganic, and are preferably particles having pores inside. As a specific example of the hollow particles, cerium oxide-based particles are described in JP-A-2002-79616 (see, for example, paragraphs [0041] to [0049]). The refractive index of the particles is preferably from 1.15 to 1.40, more preferably from 1.20 to 1.30. The binder may be a monomer having two or more ethylenically unsaturated groups as described in the above item of the hard coat layer 122.

低折射率層中,較佳為添加上述硬塗層122的項中所述的聚合起始劑(例如參照日本專利特開2006-30740號公報的段落[0090]~[0093])。含有自由基聚合性化合物的情形時,相對於該化合物100重量份可使用1重量份~10重量份、較佳為1重量份~5重量份的聚合起始劑。In the low refractive index layer, a polymerization initiator described in the section of the above-mentioned hard coat layer 122 is preferably used (for example, refer to paragraphs [0090] to [0093] of JP-A-2006-30740). In the case of containing a radically polymerizable compound, 1 part by weight to 10 parts by weight, preferably 1 part by weight to 5 parts by weight, based on 100 parts by weight of the compound, of a polymerization initiator can be used.

低折射層中可併用無機粒子。為了賦予耐擦傷性,可使用具有低折射率層的厚度的15%~150%、較佳為30%~100%、更佳為45%~60%的粒徑的微粒子。Inorganic particles may be used in combination in the low refractive layer. In order to impart scratch resistance, fine particles having a particle diameter of 15% to 150%, preferably 30% to 100%, more preferably 45% to 60%, of the thickness of the low refractive index layer may be used.

低折射率層中,為了賦予防汙性、耐水性、耐化學品性、潤滑性等特性,可適當添加公知的聚矽氧烷系或氟系的防污劑、潤滑劑等。In the low refractive index layer, a known polyoxyalkylene-based or fluorine-based antifouling agent, a lubricant, or the like can be appropriately added in order to impart characteristics such as antifouling property, water resistance, chemical resistance, and lubricity.

[高折射率層/中折射率層][High refractive index layer / medium refractive index layer]

對於抗反射膜126,可如上述般於低折射率層與硬塗層122之間設置折射率高的層而提高抗反射性。For the anti-reflection film 126, a layer having a high refractive index can be provided between the low refractive index layer and the hard coat layer 122 as described above to improve the antireflection property.

高折射率層以及中折射率層較佳為由含有高折射無機微粒子及黏合劑的硬化性組成物所形成。此處可使用的高折射率無機微粒子可使用為了提高硬塗層122的折射率而可含有的高折射率的無機微粒子。高折射率的無機微粒子例如可較佳地列舉:二氧化矽粒子、TiO2 粒子等無機化合物的粒子;丙烯酸粒子、交聯丙烯酸粒子、聚苯乙烯粒子、交聯苯乙烯粒子、三聚氰胺樹脂粒子、苯代三聚氰胺樹脂粒子等樹脂粒子。The high refractive index layer and the medium refractive index layer are preferably formed of a curable composition containing high refractive inorganic fine particles and a binder. As the high refractive index inorganic fine particles which can be used herein, high refractive index inorganic fine particles which can be contained in order to increase the refractive index of the hard coat layer 122 can be used. The inorganic fine particles having a high refractive index are preferably, for example, particles of an inorganic compound such as cerium oxide particles or TiO 2 particles; acrylic particles, crosslinked acrylic particles, polystyrene particles, crosslinked styrene particles, melamine resin particles, and the like. Resin particles such as benzomelamine resin particles.

高折射率層以及中折射率層較佳為,於在分散介質中分散有無機粒子的分散液中,較佳為進一步添加基質形成 所必需的黏合劑前驅物(例如,下文將述的電離放射線硬化性的多官能單體或多官能低聚物等)、光聚合起始劑等而形成高折射率層以及中折射率層形成用的塗佈組成物,例如於透明膜上塗佈高折射率層以及中折射率層形成用的塗佈組成物,藉由電離放射線硬化性化合物(例如多官能單體或多官能低聚物等)的交聯反應或聚合反應進行硬化而形成。The high refractive index layer and the medium refractive index layer are preferably formed by further adding a matrix to the dispersion in which the inorganic particles are dispersed in the dispersion medium. A binder precursor (for example, an ionizing radiation-curable polyfunctional monomer or a polyfunctional oligomer to be described later), a photopolymerization initiator, or the like to form a high refractive index layer and a medium refractive index layer are formed. A coating composition for coating a high refractive index layer and a coating composition for forming a medium refractive index layer on a transparent film by ionizing a radiation curable compound (for example, a polyfunctional monomer or a polyfunctional oligomer) The crosslinking reaction or the polymerization reaction is hardened to form.

進而,較佳為,使高折射率層以及中折射率層的黏合劑於層塗佈的同時或塗佈後與分散劑進行交聯反應或聚合反應。Further, it is preferred that the binder of the high refractive index layer and the medium refractive index layer be subjected to a crosslinking reaction or a polymerization reaction with the dispersing agent at the same time as or after the coating.

如此而製作的高折射率層以及中折射率層的黏合劑,例如成為上述較佳的分散劑與電離放射線硬化性的多官能單體或多官能低聚物進行交聯或聚合反應、使分散劑的陰離子性基進入至黏合劑中的形態。進而,高折射率層以及中折射率層的黏合劑中,陰離子性基具有維持無機粒子的分散狀態的功能,交聯或聚合結構對黏合劑賦予皮膜形成能力,改良含有無機粒子的高折射率層以及中折射率層的物理強度、耐化學品性、耐候性。The binder of the high refractive index layer and the medium refractive index layer produced in this manner is, for example, the above-mentioned preferred dispersant, which is crosslinked or polymerized with an ionizing radiation curable polyfunctional monomer or polyfunctional oligomer to cause dispersion. The anionic group of the agent enters the form of the binder. Further, in the binder of the high refractive index layer and the medium refractive index layer, the anionic group has a function of maintaining the dispersed state of the inorganic particles, and the crosslinking or polymerizing structure imparts a film forming ability to the binder, and improves the high refractive index of the inorganic particles. The physical strength, chemical resistance, and weather resistance of the layer and the medium refractive index layer.

高折射率層的黏合劑是相對於該高折射率層的塗佈組成物的固體成分量而添加5wt%~80wt%。The binder of the high refractive index layer is added in an amount of 5 wt% to 80 wt% with respect to the solid content of the coating composition of the high refractive index layer.

高折射率層中的無機粒子的含量較佳為相對於高折射率層的重量而為10wt%~90wt%,更佳為15wt%~80wt%,特佳為15wt%~75wt%。無機粒子亦可於高折射率層內併用兩種以上。The content of the inorganic particles in the high refractive index layer is preferably from 10% by weight to 90% by weight, more preferably from 15% by weight to 80% by weight, even more preferably from 15% by weight to 75% by weight based on the weight of the high refractive index layer. The inorganic particles may be used in combination of two or more kinds in the high refractive index layer.

當高折射率層上具有低折射率層時,高折射率層的折射率較佳為高於透明膜130的折射率。When the high refractive index layer has a low refractive index layer, the refractive index of the high refractive index layer is preferably higher than that of the transparent film 130.

使用高折射率層作為光學干涉層時的膜厚較佳為30nm~200nm,更佳為50nm~170nm,特佳為60nm~150nm。The film thickness when the high refractive index layer is used as the optical interference layer is preferably from 30 nm to 200 nm, more preferably from 50 nm to 170 nm, and particularly preferably from 60 nm to 150 nm.

高折射率層以及中折射率層的霧度越低越好。較佳為5%以下,更佳為3%以下,特佳為1%以下。The lower the haze of the high refractive index layer and the medium refractive index layer, the better. It is preferably 5% or less, more preferably 3% or less, and particularly preferably 1% or less.

設有低折射率層的抗反射膜126的較佳的積分反射率較佳為3.0%以下,更佳為2.0%以下,最佳為1.5%以下0.3%以上。The preferred integrated reflectance of the antireflection film 126 having the low refractive index layer is preferably 3.0% or less, more preferably 2.0% or less, and most preferably 1.5% or less and 0.3% or more.

另外,就防汙性提昇的觀點而言,較佳為減少低折射率層表面的表面自由能量。具體而言,較佳為將含氟化合物或具有聚矽氧烷結構的化合物用於低折射率層。另外,亦可於低折射率層上與低折射率層相區分而另設置含有下述化合物的防汙層。Further, from the viewpoint of improving the antifouling property, it is preferred to reduce the surface free energy of the surface of the low refractive index layer. Specifically, a fluorine-containing compound or a compound having a polysiloxane structure is preferably used for the low refractive index layer. Further, an antifouling layer containing the following compound may be further provided on the low refractive index layer to distinguish it from the low refractive index layer.

關於具有聚矽氧烷結構的添加劑,添加以下添加劑亦較佳:含反應性基的聚矽氧烷{例如“KF-100T”、“X-22-169AS”、“KF-102”、“X-22-3701IE”、“X-22-164B”、“X-22-5002”、“X-22-173B”、“X-22-174D”、“X-22-167B”、“X-22-161AS”(商品名),以上為信越化學工業(股)製造;“AK-5”、“AK-30”、“AK-32”(商品名),以上為東亞合成(股)製造;「Silaplane FM0725」、「Silaplane FM0721」(商品名),以上為Chisso(股)製造等}。另外,亦可較佳地使用日本 專利特開2003-112383號公報的表2、表3所記載的聚矽氧系化合物。該些聚矽氧烷較佳為以低折射率層總固體成分的0.1wt%~10wt%的範圍而添加,特佳為1wt%~5wt%的情況。Regarding the additive having a polyoxane structure, it is also preferred to add the following additives: a polyoxyalkylene containing a reactive group {for example, "KF-100T", "X-22-169AS", "KF-102", "X" -22-3701IE", "X-22-164B", "X-22-5002", "X-22-173B", "X-22-174D", "X-22-167B", "X-22 -161AS" (trade name), the above is manufactured by Shin-Etsu Chemical Co., Ltd.; "AK-5", "AK-30", "AK-32" (trade name), and the above is manufactured by East Asia Synthetic Co., Ltd.; Silaplane FM0725", "Silaplane FM0721" (trade name), the above is Chisso (share) manufacturing, etc.}. In addition, it is also preferable to use Japan. The polyfluorene-based compound described in Tables 2 and 3 of JP-A-2003-112383. These polyoxyalkylenes are preferably added in the range of 0.1% by weight to 10% by weight based on the total solid content of the low refractive index layer, and particularly preferably in the range of 1% by weight to 5% by weight.

[抗反射膜126的製作方法][Manufacturing Method of Anti-Reflection Film 126]

抗反射膜126可利用以下的塗佈方式來形成,但不限於該些塗佈方式。The anti-reflection film 126 can be formed by the following coating methods, but is not limited to the coating methods.

(塗佈的準備作業)(preparation of coating)

首先,製備含有用以形成硬塗層122或抗反射層124等各層的成分的塗佈液。通常,塗佈液以有機溶劑系為主,故必需將含水量抑制為2%以下,且加以密閉而抑制溶劑的揮發量。所使用的有機溶劑是根據各層所使用的材料而選擇。為了獲得塗佈液的均勻性而適當使用攪拌機或分散機。First, a coating liquid containing a component for forming each layer of the hard coat layer 122 or the anti-reflection layer 124 is prepared. In general, since the coating liquid is mainly an organic solvent, it is necessary to suppress the water content to 2% or less, and to seal the solvent to suppress the amount of volatilization of the solvent. The organic solvent used is selected depending on the materials used for each layer. A mixer or a disperser is suitably used in order to obtain uniformity of the coating liquid.

所製備的塗佈液較理想為於塗佈前進行過濾以不發生塗佈故障。過濾的過濾器較佳為使用在不將塗佈液中的成分去除的範圍內孔徑儘可能小的過濾器,過濾壓力亦是於1.5MPa以下的範圍內適當選擇。經過濾的塗佈液較佳為於即將塗佈前進行超音波分散、脫泡並保持分散物的分散狀態。The prepared coating liquid is desirably filtered before coating to prevent coating failure. The filter to be filtered is preferably a filter having a pore diameter as small as possible within a range in which the components in the coating liquid are not removed, and the filtration pressure is appropriately selected within a range of 1.5 MPa or less. The filtered coating liquid is preferably subjected to ultrasonic dispersion, defoaming, and maintaining a dispersed state of the dispersion immediately before coating.

透明膜130亦可於塗佈前實施用以矯正基底變形的加熱處理、或者用以改良塗佈性或改良與塗設層的接著性的表面處理。表面處理的具體方法可列舉電暈放電處理、輝光放電處理、火焰處理、酸處理、鹼處理或紫外線照射處 理。另外,如日本專利特開平7-333433號公報所記載般,亦可較佳地利用設置底塗層的處理。The transparent film 130 may also be subjected to a heat treatment for correcting the deformation of the substrate or a surface treatment for improving the coatability or improving the adhesion to the coating layer before coating. Specific methods of surface treatment include corona discharge treatment, glow discharge treatment, flame treatment, acid treatment, alkali treatment or ultraviolet irradiation. Reason. Further, as described in Japanese Laid-Open Patent Publication No. Hei 7-333433, the treatment of providing an undercoat layer can be preferably used.

進而,較佳為設置除塵步驟作為塗佈的前步驟,該除塵步驟中使用的除塵方法可使用日本專利特開2010-32795號公報的段落[0119]中記載的方法。另外,就提高除塵效率、抑制垃圾附著的方面而言,特佳為於進行此種除塵步驟之前將透明膜130上的靜電去除。此種除電方法可使用日本專利特開2010-32795號公報的段落[0120]中記載的方法。進而,亦可利用上述公報的段落[0121]以及[0123]記載的方法來確保透明膜130的平面性、改良接著性。Further, it is preferable to provide a dust removing step as a pre-coating step, and the dust removing method used in the dust removing step can be carried out by the method described in paragraph [0119] of JP-A-2010-32795. Further, in terms of improving the dust removing efficiency and suppressing the adhesion of the garbage, it is particularly preferable to remove the static electricity on the transparent film 130 before the dust removing step. Such a method of removing electricity can be carried out by the method described in paragraph [0120] of JP-A-2010-32795. Further, the planarity of the transparent film 130 and the improved adhesion can be ensured by the methods described in paragraphs [0121] and [0123] of the above publication.

(塗佈步驟)(coating step)

抗反射膜126的各層可藉由以下的塗佈方法來形成,但不限於該些方法。可使用浸漬塗佈法、氣刀塗佈法、廉幕塗佈法、輥塗佈法、線棒塗佈法、凹版塗佈法或擠壓塗佈法(模塗佈法)(參照美國專利第2681294號說明書、國際公開第05/123274號手冊)、微凹版塗佈法等公知方法,其中較佳為微凹版塗佈法、模塗佈法。關於微凹版塗佈法,於日本專利特開2010-32795號公報的段落[0125]以及[0126]中有所記載,關於模塗佈法,於上述公報的段落[0127]以及[0128]中有所記載,本實施形態中亦可使用該些方法。就生產性的方面而言,較佳為使用模塗佈法以20m/分鐘以上的速度塗佈。The respective layers of the anti-reflection film 126 can be formed by the following coating methods, but are not limited to the methods. A dip coating method, an air knife coating method, an air curtain coating method, a roll coating method, a wire bar coating method, a gravure coating method, or an extrusion coating method (die coating method) may be used (refer to the US patent) A known method such as the specification of No. 2681294, International Publication No. 05/123274, and a micro gravure coating method is preferably a micro gravure coating method or a die coating method. The micro gravure coating method is described in paragraphs [0125] and [0126] of Japanese Patent Laid-Open Publication No. 2010-32795, and the die coating method is described in paragraphs [0127] and [0128] of the above publication. It is described that these methods can also be used in the present embodiment. In terms of productivity, it is preferably applied by a die coating method at a rate of 20 m/min or more.

(乾燥步驟)(drying step)

抗反射膜126較佳為於透明膜130上直接或介隔其他 層而塗佈後,用網(web)搬送至經加熱的區域(zone)中以將溶劑乾燥。The anti-reflection film 126 is preferably directly or separately on the transparent film 130. After coating the layers, they are transferred to a heated zone by a web to dry the solvent.

作為將溶劑乾燥的方法,可利用各種方法。具體方法可列舉日本專利特開2001-286817號公報、日本專利特開2001-314798號公報、日本專利特開2003-126768號公報、日本專利特開2003-315505號公報、日本專利特開2004-34002號公報等的記載技術。As a method of drying the solvent, various methods can be utilized. Specific examples of the method include Japanese Patent Laid-Open No. 2001-216817, Japanese Patent Laid-Open No. 2001-314798, Japanese Patent Laid-Open No. 2003-126768, Japanese Patent Laid-Open No. 2003-315505, and Japanese Patent Laid-Open No. 2004- The technique described in the publication No. 34002.

關於乾燥區域的溫度條件,可使用日本專利特開2010-32795號公報的段落[0130]中記載的條件,關於乾燥風的條件,可使用該公報的段落[0131]中記載的條件。As for the temperature condition of the dry region, the conditions described in paragraph [0130] of JP-A-2010-32795 can be used, and the conditions described in paragraph [0131] of the publication can be used for the conditions of the dry air.

(硬化步驟)(hardening step)

抗反射膜126可於溶劑乾燥後或乾燥後期,以網的形式通過藉由電離放射線及/或熱而使各塗膜硬化的區域,使塗膜硬化。上述電離放射線並無特別限制,可根據形成皮膜的硬化性組成物的種類而自紫外線、電子束、近紫外線、可見光、近紅外線、紅外線、X射線等中適當選擇,較佳為紫外線、電子束,特別就操作簡便且容易獲得高能量的方面而言,較佳為紫外線。The anti-reflection film 126 can cure the coating film by a region in which the respective coating films are hardened by ionizing radiation and/or heat in the form of a web after the solvent is dried or in the late drying stage. The ionizing radiation is not particularly limited, and may be appropriately selected from ultraviolet rays, electron beams, near ultraviolet rays, visible light, near infrared rays, infrared rays, X rays, etc., depending on the type of the curable composition forming the film, and is preferably ultraviolet rays or electron beams. Particularly, in terms of ease of handling and high energy availability, ultraviolet rays are preferred.

關於使紫外線硬化性化合物進行光聚合的紫外線的光源,可使用日本專利特開2010-32795號公報的段落[0133]中記載的光源,關於電子束,可該上述公報的段落[0134]中記載的電子束。另外,關於照射條件、照射光量、照射時間,可使用該公報的段落[0135]以及[0138]中記載的條件。進而,關於照射前後的膜的膜面溫度、氧濃度、氧濃 度的控制方法,可使用該公報的段落[0136]、段落[0137]、段落[0139]~段落[0144]中記載的條件、方法。A light source described in paragraph [0133] of JP-A-2010-32795, which is described in the paragraph [0134] of the above-mentioned publication, can be used as a light source for ultraviolet light to photopolymerize an ultraviolet curable compound. Electron beam. Further, regarding the irradiation conditions, the amount of irradiation light, and the irradiation time, the conditions described in paragraphs [0135] and [0138] of the publication can be used. Further, regarding the film surface temperature, oxygen concentration, and oxygen concentration of the film before and after the irradiation For the degree of control method, the conditions and methods described in paragraph [0136], paragraph [0137], paragraph [0139] to paragraph [0144] of the publication can be used.

(用以進行連續製造的操作)(for continuous manufacturing operations)

為了連續地製造抗反射膜126,進行以下步驟:連續地送出輥狀的透明膜130;塗佈塗佈液並加以乾燥;使塗膜硬化;以及捲取具有經硬化的層的該透明膜130。In order to continuously manufacture the anti-reflection film 126, the following steps are performed: continuously feeding a roll-shaped transparent film 130; applying a coating liquid and drying; hardening the coating film; and winding the transparent film 130 having a hardened layer .

上述步驟可於形成各層時分別進行,亦可設置多個塗佈部-乾燥室-硬化部(所謂串聯方式)而連續進行各層的形成。The above steps may be carried out separately for forming each layer, or a plurality of coating portions-drying chambers-hardened portions (so-called tandem systems) may be provided to continuously form the respective layers.

為了製作抗反射膜126,較佳為在如上述般進行塗佈液的精密過濾操作的同時,在潔淨度高的空氣環境下進行塗佈部的塗佈步驟以及於乾燥室中進行的乾燥步驟,且於進行塗佈之前將透明膜130上的垃圾、塵埃充分去除。塗佈步驟以及乾燥步驟的空氣潔淨度較理想為根據美國聯邦標準209E的空氣潔淨度的標準而為10級(0.5μm以上的粒子為353個/m3 以下)以上,更佳為1級(0.5μm以上的粒子為35.5個/m3 以下)以上。另外,空氣潔淨度更佳為於塗佈-乾燥步驟以外的送出、捲取部等中亦高。In order to produce the antireflection film 126, it is preferred to carry out the coating step of the coating portion and the drying step in the drying chamber in a clean environment with high cleanliness while performing a precision filtration operation of the coating liquid as described above. The garbage and dust on the transparent film 130 are sufficiently removed before coating. The air cleanliness of the coating step and the drying step is preferably 10 or more (particles of 0.5 μm or more or 353 particles/m 3 or less) or more preferably 1 level according to the standard of air cleanliness according to US Federal Standard 209E. The particles of 0.5 μm or more are 35.5 pieces/m 3 or less) or more. Further, the air cleanliness is preferably higher in the delivery, the winding portion, and the like other than the coating-drying step.

為了維持圖像的清晰性,抗反射膜126較佳為除了將其表面形狀調整得儘可能平滑以外,調整透射圖像清晰度。抗反射膜126的透射圖像清晰度較佳為60%以上。透射圖像清晰度通常為表示透過膜而映出的圖像的模糊程度的指標,該值越大表示通過膜而見到的圖像越清晰良好。透射圖像清晰度較佳為70%以上,更佳為80%以上。In order to maintain the sharpness of the image, the anti-reflection film 126 preferably adjusts the transparency of the transmission image in addition to adjusting the surface shape as smooth as possible. The transmission image sharpness of the anti-reflection film 126 is preferably 60% or more. The transmission image sharpness is generally an index indicating the degree of blurring of the image reflected by the film, and the larger the value, the clearer the image seen through the film. The transmission image sharpness is preferably 70% or more, more preferably 80% or more.

抗反射膜126可用作顯示裝置108的視認側的表面膜。關於顯示裝置108,可應用於各種液晶顯示裝置、電漿顯示器、有機電致發光(Electroluminescence,EL)、觸控面板等各種顯示裝置。視使用抗反射膜126的顯示裝置108的最表面的性質不同,可於抗反射膜126的透明膜130的不具有塗佈層之側的表面(以下有時記作背面)上設置黏接劑層,或使透明膜130的上述背面凝膠化後貼合於觸控面板100。The anti-reflection film 126 can be used as a surface film on the viewing side of the display device 108. The display device 108 can be applied to various display devices such as various liquid crystal display devices, plasma displays, organic electroluminescence (EL), and touch panels. Depending on the nature of the outermost surface of the display device 108 using the anti-reflection film 126, an adhesive may be provided on the surface of the transparent film 130 of the anti-reflection film 126 that does not have the coating layer (hereinafter sometimes referred to as the back surface). The layer or the back surface of the transparent film 130 is gelated and bonded to the touch panel 100.

關於使透明膜130的上述背面凝膠化的方法,可使用日本專利特開2010-32795號公報的段落[0149]~段落[0160]中記載的技術。For the method of gelling the back surface of the transparent film 130, the technique described in paragraphs [0149] to [0160] of JP-A-2010-32795 can be used.

再者,本發明可與下述表1以及表2中記載的公開公報以及國際公開手冊的技術適當組合使用。將「日本專利特開」、「號公報」、「號手冊」等的表述省略。Furthermore, the present invention can be suitably used in combination with the techniques disclosed in Tables 1 and 2 below and the techniques of the International Publication Manual. The expressions "Japanese Patent Special", "No. Bulletin", "No. Manual" and the like are omitted.

[實例][Example]

以下,列舉本發明的實例對本發明加以更具體說明。再者,以下實例中所示的材料、使用量、比例、處理內容、處理順序等,只要不偏離本發明的主旨則可適當變更。因此,本發明的範圍不應由以下所示的具體例限定性地解釋。Hereinafter, the present invention will be more specifically described by way of examples of the invention. In addition, the materials, usage amounts, ratios, processing contents, processing order, and the like shown in the following examples can be appropriately changed without departing from the gist of the present invention. Therefore, the scope of the invention should not be construed as being limited by the specific examples shown below.

關於比較例1以及比較例2、實例1~實例6的導電 片,測定表面電阻以及透射率,並評價條紋以及視認性。將比較例1以及比較例2、實例1~實例6的詳細情況及測定結果以及評價結果示於表3中。Conduction of Comparative Example 1 and Comparative Example 2, Examples 1 to 6 Sheet, surface resistance and transmittance were measured, and streaks and visibility were evaluated. The details, measurement results, and evaluation results of Comparative Example 1 and Comparative Example 2, and Examples 1 to 6 are shown in Table 3.

<實例1~實例6、比較例1、比較例2><Example 1 to Example 6, Comparative Example 1, Comparative Example 2>

(鹵化銀感光材料)(silver halide photosensitive material)

製備相對於水介質中的Ag 150g而含有明膠10.0g、且含有球近似徑平均為0.1μm的碘溴氯化銀粒子(I=0.2mol%、Br=40mol%)的乳劑。An emulsion containing 10.0 g of gelatin and containing silver iodobromochloride particles having an approximate spherical diameter of 0.1 μm (I = 0.2 mol%, Br = 40 mol%) was prepared in an amount of 150 g of Ag in an aqueous medium.

另外,於乳劑中以濃度為10-7 (mol/mol銀)的方式添加K3 Rh2 Br9 以及K2 IrCl6 ,於溴化銀粒子中摻雜Rh離子及Ir離子。於該乳劑中添加Na2 PdCl4 ,進而使用氯化金酸及硫代硫酸鈉進行金硫敏化後,與明膠硬膜劑一起以銀的塗佈量達到10g/m2 的方式塗佈於第1透明基體12A以及第2透明基體12B(此處均為聚對苯二甲酸乙二酯(PET))上。此時,Ag/明膠體積比是設定為2/1。Further, K 3 Rh 2 Br 9 and K 2 IrCl 6 were added to the emulsion at a concentration of 10 -7 (mol/mol silver), and the silver bromide particles were doped with Rh ions and Ir ions. Na 2 PdCl 4 was added to the emulsion, and gold sulphur sensitization was carried out using chloroauric acid and sodium thiosulfate, and then coated with a gelatin hardener at a coating amount of 10 g/m 2 of silver. The first transparent substrate 12A and the second transparent substrate 12B (here, both of polyethylene terephthalate (PET)). At this time, the Ag/gelatin volume ratio was set to 2/1.

於寬度為30cm的PET支持體上以25cm的寬度塗佈20m,以保留塗佈的中央部24cm的方式於兩端各切下3cm,獲得輥狀的鹵化銀感光材料。20 m was coated on a PET support having a width of 30 cm on a width of 25 cm, and 3 cm was cut at both ends so as to keep the center portion of the coating at 24 cm, thereby obtaining a roll-shaped silver halide photosensitive material.

(曝光)(exposure)

關於曝光圖案,第1導電片10A採用圖1以及圖4所示的圖案,第2導電片10B採用圖4以及圖6所示的圖案,對A4尺寸(210mm×297mm)的第1透明基體12A以及第2透明基體12B進行曝光。曝光是介隔上述圖案的光罩使用將高壓水銀燈作為光源的平行光來進行曝光。Regarding the exposure pattern, the first conductive sheet 10A has the pattern shown in FIGS. 1 and 4, and the second conductive sheet 10B has the pattern shown in FIGS. 4 and 6 for the first transparent substrate 12A of A4 size (210 mm × 297 mm). And the second transparent substrate 12B is exposed. The exposure is a mask that is interposed with the above pattern, and exposure is performed using parallel light using a high pressure mercury lamp as a light source.

(顯影處理)(development processing)

‧顯影液1L配方‧ Developer 1L formula

.固定液1L配方. Fixative 1L formula

使用上述處理劑,利用富士膠片公司製造的自動顯影機FG-710PTS,於顯影35℃ 30秒、固定34℃ 23秒、水洗流水(5L/min)20秒的處理條件下對經曝光的感光材料進行處理。Using the above treatment agent, the exposed photosensitive material was treated under the conditions of development of 35 ° C for 30 seconds, fixed 34 ° C for 23 seconds, and water-washed running water (5 L / min) for 20 seconds using an automatic developing machine FG-710PTS manufactured by Fujifilm. Process it.

(實例1)(Example 1)

所製作的第1導電片10A以及第2導電片10B的導電部(第1導電圖案22A、第2導電圖案22B)的線寬為1μ m、小格子18的一邊的長度為50μm、大格子(第1大格子14A以及第2大格子14B)的一邊的長度為3mm。The line width of the conductive portions (the first conductive pattern 22A and the second conductive pattern 22B) of the first conductive sheet 10A and the second conductive sheet 10B to be produced is 1 μ. m, the length of one side of the small lattice 18 is 50 μm, and the length of one side of the large lattice (the first large lattice 14A and the second large lattice 14B) is 3 mm.

(實例2)(Example 2)

除了使導電部的線寬為5μm、小格子18的一邊的長度為50μm以外,與實例1同樣地製作實例2的第1導電片以及第2導電片。The first conductive sheet and the second conductive sheet of Example 2 were produced in the same manner as in Example 1 except that the line width of the conductive portion was 5 μm and the length of one side of the small lattice 18 was 50 μm.

(實例3)(Example 3)

除了使導電部的線寬為9μm、小格子18的一邊的長度為150μm、大格子的一邊的長度為5mm以外,與實例1同樣地製作實例3的第1導電片以及第2導電片。The first conductive sheet and the second conductive sheet of Example 3 were produced in the same manner as in Example 1 except that the line width of the conductive portion was 9 μm, the length of one side of the small lattice 18 was 150 μm, and the length of one side of the large lattice was 5 mm.

(實例4)(Example 4)

除了使導電部的線寬為10um、小格子18的一邊的長度為300μm、大格子的一邊的長度為6mm以外,與實例1同樣地製作實例4的第1導電片以及第2導電片。The first conductive sheet and the second conductive sheet of Example 4 were produced in the same manner as in Example 1 except that the line width of the conductive portion was 10 μm, the length of one side of the small lattice 18 was 300 μm, and the length of one side of the large lattice was 6 mm.

(實例5)(Example 5)

除了使導電部的線寬為15μm、小格子18的一邊的長度為400μm、大格子的一邊的長度為10mm以外,與實例1同樣地製作實例5的第1導電片以及第2導電片。The first conductive sheet and the second conductive sheet of Example 5 were produced in the same manner as in Example 1 except that the line width of the conductive portion was 15 μm, the length of one side of the small lattice 18 was 400 μm, and the length of one side of the large lattice was 10 mm.

(實例6)(Example 6)

除了使導電部的線寬為20μm、小格子18的一邊的長度為500μm、大格子的一邊的長度為10mm以外,與實例1同樣地製作實例6的第1導電片以及第2導電片。The first conductive sheet and the second conductive sheet of Example 6 were produced in the same manner as in Example 1 except that the line width of the conductive portion was 20 μm, the length of one side of the small lattice 18 was 500 μm, and the length of one side of the large lattice was 10 mm.

(比較例1)(Comparative Example 1)

除了使導電部的線寬為0.5μm、小格子18的一邊的 長度為40μm、大格子的一邊的長度為3mm以外,與實例1同樣地製作比較例1的第1導電片以及第2導電片。In addition to making the line width of the conductive portion 0.5 μm, one side of the small lattice 18 The first conductive sheet and the second conductive sheet of Comparative Example 1 were produced in the same manner as in Example 1 except that the length was 40 μm and the length of one side of the large lattice was 3 mm.

(比較例2)(Comparative Example 2)

除了使導電部的線寬為25μm、小格子18的一邊的長度為500μm、大格子的一邊的長度為10mm以外,與比較例1同樣地製作比較例2的第1導電片以及第2導電片。The first conductive sheet and the second conductive sheet of Comparative Example 2 were produced in the same manner as in Comparative Example 1, except that the line width of the conductive portion was 25 μm, the length of one side of the small lattice 18 was 500 μm, and the length of one side of the large lattice was 10 mm. .

(表面電阻測定)(surface resistance measurement)

為了確認檢測精度的好壞,使用Dia Instruments公司製造的Loresta GP(型號MCP-T610)串聯四探針探測器(ASP)對第1導電片10A以及第2導電片10B的表面電阻率測定任意10處,求出測定所得的值的平均值。In order to confirm the accuracy of the detection, the surface resistivity of the first conductive sheet 10A and the second conductive sheet 10B was measured using a Loresta GP (Model MCP-T610) tandem four-probe detector (ASP) manufactured by Dia Instruments. The average value of the measured values was obtained.

(透射率的測定)(Measurement of transmittance)

為了確認透明性的好壞,使用分光光度計對第1導電片10A以及第2導電片10B測定透射率。In order to confirm the transparency, the transmittance was measured for the first conductive sheet 10A and the second conductive sheet 10B using a spectrophotometer.

(條紋的評價)(evaluation of stripes)

對於比較例1以及比較例2、實例1~實例6,於第2導電片10B上積層第1導電片10A而製作積層導電片,其後,於液晶顯示裝置的顯示畫面上貼附積層導電片而構成觸控面板。其後,將觸控面板設置於轉盤上,驅動液晶顯示裝置而使其顯示白色。於該狀態下將轉盤於偏角-45°~+45°之間旋轉,對條紋進行目測觀察、評價。In Comparative Example 1 and Comparative Example 2, and Examples 1 to 6, a first conductive sheet 10A was laminated on the second conductive sheet 10B to form a laminated conductive sheet, and then a laminated conductive sheet was attached to the display screen of the liquid crystal display device. And constitute a touch panel. Thereafter, the touch panel is placed on the turntable to drive the liquid crystal display device to display white. In this state, the turntable was rotated between angling angles -45° to +45°, and the stripes were visually observed and evaluated.

條紋的評價是以距液晶顯示裝置的顯示畫面1.5m的觀察距離而進行,將條紋不顯現時評價為○,條紋極少量 地可見且為無問題的水準時評價為△,條紋明顯時評價為×。The evaluation of the streaks was performed at an observation distance of 1.5 m from the display screen of the liquid crystal display device, and when the streaks were not displayed, it was evaluated as ○, and the streaks were extremely small. The horizontal time which is visible and is problem-free is evaluated as Δ, and when the streaks are obvious, it is evaluated as ×.

(視認性的評價)(evaluation of visibility)

於上述條紋的評價之前,將觸控面板設置於轉盤上,驅動液晶顯示裝置而使其顯示白色時,以肉眼確認是否存在粗線或黑色的斑點,另外確認觸控面板的第1大格子14A以及第2大格子14B的邊界是否顯眼。Before the evaluation of the stripe, the touch panel is placed on the turntable, and when the liquid crystal display device is driven to display white, it is visually confirmed whether there is a thick line or a black spot, and the first large grid 14A of the touch panel is confirmed. And whether the boundary of the second large lattice 14B is conspicuous.

根據表3可知,比較例1中,雖然條紋以及視認性的評價均良好,但比較例1的表面電阻為1kΩ/sq.以上,導電性低,可能檢測感度變得不充分。比較例2中,雖然導電性以及透射率均良好,但條紋明顯,易由肉眼識別導電部自身,視認性惡化。As is clear from Table 3, in Comparative Example 1, although the evaluation of the streaks and the visibility was good, the surface resistance of Comparative Example 1 was 1 kΩ/sq. or more, and the conductivity was low, and the detection sensitivity was insufficient. In Comparative Example 2, although both the conductivity and the transmittance were good, the streaks were conspicuous, and the conductive portion itself was easily recognized by the naked eye, and the visibility was deteriorated.

相對於此,實例1~實例6中,實例1~實例5中的導電性、透射率、條紋、視認性均良好。實例6中,雖然條紋的評價以及視認性的評價差於實例1~實例5,但條紋為極少量地可見且無問題的水準的程度,不存在難以看到 顯示裝置的顯示圖像的情況。On the other hand, in Examples 1 to 6, the conductivity, the transmittance, the streaks, and the visibility in Examples 1 to 5 were good. In Example 6, although the evaluation of the streaks and the evaluation of the visibility were inferior to those of Examples 1 to 5, the degree of streaks which were extremely small and visible without problems was not difficult to see. The case where the display image of the device is displayed.

再者,本發明的導電片、導電片的使用方法以及靜電電容式觸控面板並不限於上述實施形態,當然可於不偏離本發明主旨的情況下採用各種構成。In addition, the conductive sheet of the present invention, the method of using the conductive sheet, and the capacitive touch panel are not limited to the above-described embodiments, and of course, various configurations can be employed without departing from the gist of the present invention.

10A、10Aa‧‧‧第1導電片10A, 10Aa‧‧‧1st conductive sheet

10B、10Ba‧‧‧第2導電片10B, 10Ba‧‧‧2nd conductive sheet

12A‧‧‧第1透明基體12A‧‧‧1st transparent substrate

12B‧‧‧第2透明基體12B‧‧‧2nd transparent substrate

13A‧‧‧第1導電部13A‧‧‧1st Conductive Department

13B‧‧‧第2導電部13B‧‧‧2nd Conductive Department

14A‧‧‧第1大格子14A‧‧‧1st large grid

14B‧‧‧第2大格子14B‧‧‧2nd plaid

16A‧‧‧第1連接部16A‧‧‧1st connection

16B‧‧‧第2連接部16B‧‧‧2nd connection

18‧‧‧小格子18‧‧‧Small lattice

20‧‧‧中格子20‧‧‧ medium lattice

20a~20h‧‧‧第1中格子~第8中格子20a~20h‧‧‧1st plaid~8th plaid

22A‧‧‧第1導電圖案22A‧‧‧1st conductive pattern

22B‧‧‧第2導電圖案22B‧‧‧2nd conductive pattern

24A‧‧‧第1絕緣部24A‧‧‧1st insulation

24B‧‧‧第2絕緣部24B‧‧‧2nd insulation

26a、26b‧‧‧頂點部分26a, 26b‧‧‧ vertices

28a~28h‧‧‧第1邊部~第8邊部28a~28h‧‧‧1st to 8th

30‧‧‧直線部30‧‧‧ Straight line

32‧‧‧梳齒32‧‧‧ comb teeth

40a‧‧‧第1結線部40a‧‧‧1st line

40b‧‧‧第2結線部40b‧‧‧2nd line

41a‧‧‧第1端子配線圖案41a‧‧‧1st terminal wiring pattern

41b‧‧‧第2端子配線圖案41b‧‧‧2nd terminal wiring pattern

42a‧‧‧凹部42a‧‧‧ recess

42b‧‧‧凸部42b‧‧‧ convex

50A‧‧‧第1積層導電片50A‧‧‧1st laminated conductive sheet

50B、50Ba‧‧‧第2積層導電片50B, 50Ba‧‧‧2nd laminated conductive sheet

100‧‧‧觸控面板100‧‧‧ touch panel

106‧‧‧保護層106‧‧‧Protective layer

108‧‧‧顯示裝置108‧‧‧Display device

110‧‧‧顯示面板110‧‧‧ display panel

110a‧‧‧顯示畫面110a‧‧‧Display screen

112‧‧‧感測器部112‧‧‧Sensor Department

114‧‧‧端子配線部114‧‧‧Terminal wiring department

116a‧‧‧第1端子116a‧‧‧1st terminal

116b‧‧‧第2端子116b‧‧‧2nd terminal

118a‧‧‧第1對準標記118a‧‧‧1st alignment mark

118b‧‧‧第2對準標記118b‧‧‧2nd alignment mark

120‧‧‧透明黏接劑120‧‧‧Transparent adhesive

120A‧‧‧第1透明黏接劑120A‧‧‧1st transparent adhesive

120B‧‧‧第2透明黏接劑120B‧‧‧2nd transparent adhesive

122‧‧‧硬塗層122‧‧‧hard coating

124‧‧‧抗反射層124‧‧‧Anti-reflective layer

126‧‧‧抗反射膜126‧‧‧Anti-reflective film

128‧‧‧保護樹脂層128‧‧‧Protective resin layer

130‧‧‧透明膜130‧‧‧Transparent film

140‧‧‧感光材料140‧‧‧Photosensitive materials

142a‧‧‧第1感光層142a‧‧‧1st photosensitive layer

142b‧‧‧第2感光層142b‧‧‧2nd photosensitive layer

144a‧‧‧第1光144a‧‧‧1st light

144b‧‧‧第2光144b‧‧‧2nd light

146a‧‧‧第1光罩146a‧‧‧1st mask

146b‧‧‧第2光罩146b‧‧‧2nd mask

148a‧‧‧第1光源148a‧‧‧1st light source

148b‧‧‧第2光源148b‧‧‧2nd light source

150a‧‧‧第1準直透鏡150a‧‧‧1st collimating lens

150b‧‧‧第2準直透鏡150b‧‧‧2nd collimating lens

152a‧‧‧第1曝光圖案152a‧‧‧1st exposure pattern

152b‧‧‧第2曝光圖案152b‧‧‧2nd exposure pattern

Lf‧‧‧投影距離Lf‧‧‧projection distance

Pm、Ps‧‧‧排列間距Pm, Ps‧‧‧ arrangement spacing

S1~S3‧‧‧步驟S1~S3‧‧‧ steps

Wc1、Wc2‧‧‧寬度Wc1, Wc2‧‧‧ width

圖1是表示第1導電片上形成的第1導電圖案的圖案例的平面圖。FIG. 1 is a plan view showing a pattern example of a first conductive pattern formed on a first conductive sheet.

圖2是將第1導電片省略一部分而表示的剖面圖。Fig. 2 is a cross-sectional view showing a part of the first conductive sheet omitted.

圖3是表示觸控面板的構成的分解立體圖。3 is an exploded perspective view showing the configuration of a touch panel.

圖4是將第1積層導電片省略一部分而表示的分解立體圖。4 is an exploded perspective view showing a part of the first laminated conductive sheet omitted.

圖5A是將第1積層導電片的一例省略一部分而表示的剖面圖。FIG. 5A is a cross-sectional view showing an example in which a part of the first laminated conductive sheet is omitted.

圖5B是將第1積層導電片的其他例省略一部分而表示的剖面圖。FIG. 5B is a cross-sectional view showing a part of the first multilayered electrically conductive sheet, partially omitted.

圖6是表示第2導電片上形成的第2導電圖案的圖案例的平面圖。6 is a plan view showing an example of a pattern of a second conductive pattern formed on a second conductive sheet.

圖7是將第1導電片與第2導電片組合而形成第1積層導電片的例子省略一部分而表示的平面圖。FIG. 7 is a plan view showing an example in which a first laminated conductive sheet is formed by combining a first conductive sheet and a second conductive sheet.

圖8A是表示賦予有抗反射膜的第1構成例的示意圖。8A is a schematic view showing a first configuration example in which an antireflection film is provided.

圖8B同樣是表示第2構成例的示意圖。Fig. 8B is a schematic view showing a second configuration example.

圖8C同樣是表示第3構成例的示意圖。Fig. 8C is a schematic view showing a third configuration example.

圖9是將第2積層導電片省略一部分而表示的分解立體圖。Fig. 9 is an exploded perspective view showing a part of the second laminated conductive sheet omitted.

圖10是表示第2積層導電片的第1導電片上形成的第1導電圖案的圖案例的平面圖。FIG. 10 is a plan view showing a pattern example of a first conductive pattern formed on a first conductive sheet of a second laminated conductive sheet.

圖11是表示第2積層導電片的第2導電片上形成的第2導電圖案的圖案例的平面圖。FIG. 11 is a plan view showing a pattern example of a second conductive pattern formed on the second conductive sheet of the second build-up conductive sheet.

圖12是將第1導電片與第2導電片組合而形成第2觸控面板用導電片的例子省略一部分而表示的平面圖。FIG. 12 is a plan view showing an example in which a part of the first conductive sheet and the second conductive sheet are combined to form a second conductive sheet for a touch panel.

圖13是表示變形例的積層導電片的第1導電片上形成的第1導電圖案的圖案例的平面圖。FIG. 13 is a plan view showing a pattern example of a first conductive pattern formed on a first conductive sheet of a laminated electrically conductive sheet according to a modification.

圖14是表示變形例的積層導電片的第2導電片上形成的第2導電圖案的圖案例的平面圖。FIG. 14 is a plan view showing a pattern example of a second conductive pattern formed on a second conductive sheet of a laminated electrically conductive sheet according to a modification.

圖15是表示本實施形態的透明導電性膜的製造方法的流程圖。Fig. 15 is a flow chart showing a method of producing the transparent conductive film of the embodiment.

圖16A是將所製作的感光材料省略一部分而表示的剖面圖。Fig. 16A is a cross-sectional view showing a part of the produced photosensitive material omitted.

圖16B是表示對感光材料的兩面同時曝光的說明圖。Fig. 16B is an explanatory view showing simultaneous exposure of both surfaces of a photosensitive material.

圖17是表示使照射至第1感光層的光不到達第2感光層、且使照射至第2感光層的光不到達第1感光層而進行第1曝光處理以及第2曝光處理的狀態的說明圖。17 is a state in which the light irradiated to the first photosensitive layer does not reach the second photosensitive layer, and the light irradiated to the second photosensitive layer does not reach the first photosensitive layer, and the first exposure process and the second exposure process are performed. Illustrating.

10A‧‧‧第1導電片10A‧‧‧1st conductive sheet

13A‧‧‧第1導電部13A‧‧‧1st Conductive Department

14A‧‧‧第1大格子14A‧‧‧1st large grid

16A‧‧‧第1連接部16A‧‧‧1st connection

18‧‧‧小格子18‧‧‧Small lattice

20a~20d‧‧‧第1中格子~第4中格子20a~20d‧‧‧1st plaid~4th plaid

22A‧‧‧第1導電圖案22A‧‧‧1st conductive pattern

24A‧‧‧第1絕緣部24A‧‧‧1st insulation

26a、26b‧‧‧頂點部分26b26a, 26b‧‧‧ vertex part 26b

28a~28d‧‧‧第1邊部~第4邊部28a~28d‧‧‧1st side to 4th side

30‧‧‧直線部30‧‧‧ Straight line

32‧‧‧梳齒32‧‧‧ comb teeth

Pm、Ps‧‧‧排列間距Pm, Ps‧‧‧ arrangement spacing

50A‧‧‧第1積層導電片50A‧‧‧1st laminated conductive sheet

Claims (21)

一種導電片,其特徵在於包括:基體(12A)、及形成於上述基體(12A)上的導電部(13A),上述導電部(13A)具有由金屬細線形成的2個以上的導電性的大格子(14A)、及將相鄰接的上述大格子(14A)間加以電性連接的由金屬細線形成的連接部(16A),各上述大格子(14A)分別是由2個以上的小格子(18)組合而構成,藉由上述大格子(14A)的組合而構成電路,於將上述小格子(18)的間距設為Ps時,上述連接部(16A)的寬度Wc滿足Wc>Ps/,而且,上述連接部(16A)具有下述構成:鄰接的2個中格子個別以一個邊連接,且上述2個中格子的一個邊為共有。A conductive sheet comprising: a base body (12A); and a conductive portion (13A) formed on the base body (12A), wherein the conductive portion (13A) has two or more conductive layers formed of thin metal wires a lattice (14A) and a connecting portion (16A) formed of a thin metal wire electrically connecting the adjacent large lattices (14A), each of the large lattices (14A) being composed of two or more small lattices (18) A combination is formed by a combination of the large lattices (14A), and when the pitch of the small lattices (18) is Ps, the width Wc of the connecting portion (16A) satisfies Wc>Ps/ Further, the connecting portion (16A) has a configuration in which two adjacent squares are individually connected by one side, and one side of the two middle squares is shared. 如申請專利範圍第1項所述之導電片,其中2個以上的上述大格子(14A)經由上述連接部(16A)排列於第1方向上,從而構成1個導電圖案(22A),2個以上的上述導電圖案(22A)排列於與上述第1方向正交的第2方向上,於相鄰接的上述導電圖案(22A)之間,配置有不存在上述小格子(18)的電性絕緣的絕緣部(24A),藉由上述導電圖案(22A)、上述絕緣部(24A)的排 列而構成上述電路。 The conductive sheet according to claim 1, wherein the two or more large lattices (14A) are arranged in the first direction via the connecting portion (16A) to form one conductive pattern (22A), two The conductive patterns (22A) are arranged in a second direction orthogonal to the first direction, and electrical properties of the small lattices (18) are not disposed between the adjacent conductive patterns (22A). The insulating insulating portion (24A) is arranged by the conductive pattern (22A) and the insulating portion (24A) The above circuit is constructed in columns. 如申請專利範圍第1項所述之導電片,其中上述大格子(14A)的一邊的長度為3mm~10mm。 The conductive sheet according to claim 1, wherein a length of one side of the large lattice (14A) is 3 mm to 10 mm. 如申請專利範圍第1項所述之導電片,其中上述小格子(18)的一邊的長度為30μm~500μm。 The conductive sheet according to claim 1, wherein a length of one side of the small lattice (18) is 30 μm to 500 μm. 如申請專利範圍第1項所述之導電片,其中上述小格子(18)的彼此相向的邊的間隔為30μm~500μm。 The conductive sheet according to claim 1, wherein an interval between the mutually opposing sides of the small lattice (18) is 30 μm to 500 μm. 如申請專利範圍第1項所述之導電片,其中上述金屬細線的線寬為10μm以下。 The conductive sheet according to claim 1, wherein the metal thin wire has a line width of 10 μm or less. 一種導電片,其特徵在於包括:基體(12A)、形成於上述基體(12A)的一個主面上的第1導電部(13A)、及形成於上述基體(12A)的另一主面上的第2導電部(13B),上述第1導電部(13A)具有由金屬細線形成的2個以上的導電性的第1大格子(14A)、及將相鄰接的上述第1大格子(14A)間加以電性連接的由金屬細線形成的第1連接部(16A),上述第2導電部(13B)具有由金屬細線形成的2個以上的導電性的第2大格子(14B)、及將相鄰接的上述第2大格子(14B)間加以電性連接的由金屬細線形成的第2連接部(16B), 各上述第1大格子(14A)以及各上述第2大格子(14B)分別是由2個以上的小格子(18)組合而構成,上述第1大格子(14A)經由上述第1連接部(16A)排列於第1方向上,從而構成1個第1導電圖案(22A),藉由上述第1大格子(14A)與上述第2大格子(14B)的組合而構成電路,於將上述小格子(18)的間距設為Ps時,上述第1連接部(16A)的寬度Wc1以及上述第2連接部(16B)的寬度Wc2滿足Wc1>Ps/Wc2>Ps/,而且,上述第1連接部(16A)以及上述第2連接部(16B)個別具有下述構成:鄰接的2個中格子個別以一個邊連接,且上述2個中格子的一個邊為共有。A conductive sheet comprising: a base body (12A); a first conductive portion (13A) formed on one main surface of the base body (12A); and a main surface formed on the other main surface of the base body (12A) In the second conductive portion (13B), the first conductive portion (13A) has two or more conductive first large lattices (14A) formed of thin metal wires, and the first large lattice (14A) adjacent thereto a first connection portion (16A) formed of a thin metal wire electrically connected to each other, wherein the second conductive portion (13B) has two or more second conductive large lattices (14B) formed of thin metal wires, and a second connecting portion (16B) made of a thin metal wire electrically connected between the adjacent second large lattices (14B), each of the first large lattices (14A) and each of the second large lattices (14B) Each of the first large lattices (14A) is arranged in the first direction via the first connecting portion (16A) to form one first conductive pattern ( 22A), a circuit is formed by combining the first large lattice (14A) and the second large lattice (14B), and when the pitch of the small lattice (18) is Ps, the first connection Wc1 width portion (16A) and the second connecting portion (16B) satisfies the Wc2 Wc1> Ps / Wc2>Ps/ Further, the first connecting portion (16A) and the second connecting portion (16B) each have a configuration in which two adjacent squares are individually connected by one side, and one side of the two middle squares is shared. 如申請專利範圍第7項所述之導電片,其中上述第1大格子(14A)經由上述第1連接部(16A)排列於第1方向上,從而構成由金屬細線形成的1個第1導電圖案(22A),2個以上的上述第2大格子(14B)經由上述第2連接部(16B)排列於與上述第1方向正交的第2方向上,從而構成由金屬細線形成的1個第2導電圖案(22B),於相鄰接的上述第1導電圖案(22A)之間,配置有不存在上述小格子(18)的電性絕緣的第1絕緣部(24A),於相鄰接的上述第2導電圖案(22B)之間,配置有 不存在上述小格子(18)的電性絕緣的第2絕緣部(24B),藉由上述第1導電圖案(22A)、上述第2導電圖案(22B)、上述第1絕緣部(24A)、上述第2絕緣部(24B)的排列而構成上述電路。 The conductive sheet according to claim 7, wherein the first large lattice (14A) is arranged in the first direction via the first connecting portion (16A) to constitute one first conductive line formed of thin metal wires. In the pattern (22A), two or more of the second large lattices (14B) are arranged in the second direction orthogonal to the first direction via the second connecting portion (16B), and one of the thin metal wires is formed. In the second conductive pattern (22B), between the adjacent first conductive patterns (22A), the first insulating portion (24A) in which the small lattice (18) is not electrically insulated is disposed adjacent to each other Between the second conductive patterns (22B) connected to the second conductive pattern (22B) The second insulating portion (24B) that is electrically insulated from the small lattice (18) is not present, and the first conductive pattern (22A), the second conductive pattern (22B), and the first insulating portion (24A) are The arrangement of the second insulating portions (24B) constitutes the above-described circuit. 如申請專利範圍第7項所述之導電片,其中上述金屬細線的線寬為10μm以下。 The conductive sheet according to claim 7, wherein the metal thin wire has a line width of 10 μm or less. 如申請專利範圍第7項所述之導電片,其中上述第1大格子(14A)的邊部的直線部與上述第2大格子(14B)的邊部的直線部間之投影距離(Lf)是根據上述小格子(18)的尺寸而設定。 The conductive sheet according to claim 7, wherein a projection distance (Lf) between a straight portion of a side portion of the first large lattice (14A) and a straight portion of a side portion of the second large lattice (14B) It is set according to the size of the above small lattice (18). 如申請專利範圍第10項所述之導電片,其中上述投影距離(Lf)為100μm~400μm。 The conductive sheet according to claim 10, wherein the projection distance (Lf) is 100 μm to 400 μm. 如申請專利範圍第7項所述之導電片,其中上述第1導電部(13A)具有:連接於各上述第1導電圖案(22A)的端部的第1端子配線圖案(41a),及形成於上述基體(12A)的一個主面的1條邊的長度方向中央部分、且與對應的上述第1端子配線圖案(41a)連接的多個第1端子(116a);上述第2導電部(13B)具有:連接於各上述第2導電圖案(22B)的端部的第2端子配線圖案(41b),及形成於上述基體(12A)的另一主面的1條邊的長度方向中央部分、且與對應的上述第2端子配線圖案(41b)連接的多個第2端子(116b)。 The conductive sheet according to claim 7, wherein the first conductive portion (13A) has a first terminal wiring pattern (41a) connected to an end portion of each of the first conductive patterns (22A), and is formed. a plurality of first terminals (116a) connected to the corresponding first terminal wiring pattern (41a) at a central portion in the longitudinal direction of one side of one main surface of the base body (12A); and the second conductive portion (13B) a second terminal wiring pattern (41b) connected to an end portion of each of the second conductive patterns (22B), and a central portion in the longitudinal direction of one side of the other main surface of the base body (12A) A plurality of second terminals (116b) connected to the corresponding second terminal wiring pattern (41b). 如申請專利範圍第12項所述之導電片,其中 自上表面觀看時,排列有多個上述第1端子(116a)的部分與排列有多個上述第2端子(116b)的部分相鄰接。 The conductive sheet of claim 12, wherein When viewed from the upper surface, a portion in which the plurality of first terminals (116a) are arranged is adjacent to a portion in which the plurality of second terminals (116b) are arranged. 如申請專利範圍第12項所述之導電片,其中各上述第1導電圖案(22A)的端部與對應的上述第1端子配線圖案(41a)分別經由第1結線部(40a)而連接,各上述第2導電圖案(22B)的端部與對應的上述第2端子配線圖案(41b)分別經由第2結線部(40b)而連接,多個上述第1結線部(40a)沿著上述第2方向而直線狀地排列,多個上述第2結線部(40b)沿著上述第1方向而直線狀地排列。 The conductive sheet according to claim 12, wherein an end of each of the first conductive patterns (22A) and the corresponding first terminal wiring pattern (41a) are connected via a first junction portion (40a), respectively. The end of each of the second conductive patterns (22B) and the corresponding second terminal wiring pattern (41b) are connected via a second junction portion (40b), and the plurality of first junction portions (40a) are along the first The two second line connecting portions (40b) are linearly arranged along the first direction in a linear manner in two directions. 如申請專利範圍第8項所述之導電片,其中上述第1絕緣部(24A)與上述第2絕緣部(24B)將上述基體(12A)夾在中間而相向,自上表面觀看時,上述第1絕緣部(24A)與上述第2絕緣部(24B)的相向部分的形狀為多邊形狀。 The conductive sheet according to claim 8, wherein the first insulating portion (24A) and the second insulating portion (24B) are opposed to each other with the base body (12A) interposed therebetween, and when viewed from the upper surface, The shape of the opposing portion of the first insulating portion (24A) and the second insulating portion (24B) is polygonal. 如申請專利範圍第15項所述之導電片,其中上述多邊形狀為正方形狀。 The conductive sheet according to claim 15, wherein the polygonal shape is a square shape. 如申請專利範圍第15項所述之導電片,其中上述多邊形狀為楔形狀。 The conductive sheet of claim 15, wherein the polygonal shape is a wedge shape. 如申請專利範圍第1項所述之導電片,其中上述小格子(18)為多邊形狀。 The conductive sheet according to claim 1, wherein the small lattice (18) is polygonal. 如申請專利範圍第18項所述之導電片,其中上述小格子(18)為正方形狀。 The conductive sheet of claim 18, wherein the small lattice (18) is square. 一種導電片的使用方法,其是使用第1導電片(10A)與第2導電片(10B)的導電片的使用方法,上述第1導電片(10A)上形成有由金屬細線形成的2個以上的導電性的第1大格子(14A)、及將相鄰接的上述第1大格子(14A)間加以電性連接的由金屬細線形成的第1連接部(16A),各上述第1大格子(14A)分別是由2個以上的小格子(18)組合而構成,於將上述小格子(18)的間距設為Ps時,上述第1連接部(16A)的寬度Wc1滿足Wc1>Ps/,上述第2導電片(10B)上形成有由金屬細線形成的2個以上的導電性的第2大格子(14B)、及將相鄰接的上述第2大格子(14B)間加以電性連接的由金屬細線形成的第2連接部(16B),各上述第2大格子(14B)分別是由2個以上的小格子(18)組合而構成,於將上述小格子(18)的間距設為Ps時,上述第2連接部(16B)的寬度Wc2滿足Wc2>Ps/,該導電片的使用方法的特徵在於:上述第1導電片(10A)中,2個以上的上述第1大格子(14A)經由上述第1連接部(16A)排列於第1方向上,從而構成1個第1導電圖案(22A),上述第2導電片(10B)中,2個以上的上述第2大格子(14B)經由上述第2連接部(16B)排列於與上述第1方向正交的第2方向上,從而構成1個第2導電圖案 (22B),而且,上述第1連接部(16A)以及上述第2連接部(16B)個別具有下述構成:鄰接的2個中格子個別以一個邊連接,且上述2個中格子的一個邊為共有,藉由將上述第1導電片(10A)與上述第2導電片(10B)組合,以將上述第1導電片(10A)的上述第1連接部(16A)與上述第2導電片(10B)的上述第2連接部(16B)組合以形成上述小格子(18)的排列的方式配置。A method of using a conductive sheet, which is a method of using a conductive sheet using a first conductive sheet (10A) and a second conductive sheet (10B), wherein the first conductive sheet (10A) is formed with two thin metal wires The first large lattice (14A) having the above conductivity and the first connecting portion (16A) formed of a thin metal wire electrically connecting the adjacent first large lattices (14A), each of the first Each of the large lattices (14A) is composed of a combination of two or more small lattices (18). When the pitch of the small lattices (18) is Ps, the width Wc1 of the first connecting portion (16A) satisfies Wc1> Ps/ The second conductive sheet (10B) is formed with two or more conductive second large lattices (14B) formed of thin metal wires and electrically connected between the adjacent second large lattices (14B). The second connection portion (16B) formed of thin metal wires is connected, and each of the second large lattices (14B) is composed of a combination of two or more small lattices (18), and the pitch of the small lattices (18) is set. When Ps is set, the width Wc2 of the second connecting portion (16B) satisfies Wc2>Ps/ In the method of using the conductive sheet, in the first conductive sheet (10A), two or more of the first large lattices (14A) are arranged in the first direction via the first connecting portion (16A), thereby One of the first conductive patterns (22A) is formed, and in the second conductive sheet (10B), two or more of the second large lattices (14B) are arranged in the first direction via the second connecting portion (16B). In the second direction of the intersection, one second conductive pattern (22B) is formed, and the first connecting portion (16A) and the second connecting portion (16B) each have the following configuration: two adjacent middle lattices Each of the two intermediate lattices is shared by one side, and the first conductive sheet (10A) is combined with the second conductive sheet (10B) to bond the first conductive sheet (10A). The first connecting portion (16A) is disposed in combination with the second connecting portion (16B) of the second conductive sheet (10B) so as to form an arrangement of the small lattices (18). 一種靜電電容式觸控面板,其特徵在於包含如申請專利範圍第1項所述之導電片。 An electrostatic capacitive touch panel comprising the conductive sheet according to claim 1 of the patent application.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI650699B (en) * 2014-03-28 2019-02-11 日商富士軟片股份有限公司 Conductive laminate and touch panel using the same

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101665210B1 (en) * 2011-09-13 2016-10-11 군제 가부시키가이샤 Touch panel
KR20140096307A (en) 2011-10-25 2014-08-05 유니-픽셀 디스플레이스, 인코포레이티드 Scratch resistant touch sensor
JP5748647B2 (en) * 2011-12-22 2015-07-15 富士フイルム株式会社 Conductive sheet and touch panel
KR101451075B1 (en) 2011-12-16 2014-10-15 후지필름 가부시키가이샤 Electroconductive sheet and touch panel
JP5777251B2 (en) * 2011-12-16 2015-09-09 富士フイルム株式会社 Conductive sheet for touch panel and touch panel
JP5509186B2 (en) * 2011-12-16 2014-06-04 富士フイルム株式会社 Touch panel and conductive sheet for touch panel
JP6056861B2 (en) * 2011-12-23 2017-01-11 エルジー・ケム・リミテッド Touch panel and display device including the same
JP2013186632A (en) * 2012-03-07 2013-09-19 Toppan Printing Co Ltd Film-like touch panel sensor and manufacturing method thereof
WO2013140859A1 (en) * 2012-03-22 2013-09-26 シャープ株式会社 Electrode sheet, touch panel, and display apparatus
SG11201407551SA (en) * 2012-05-21 2015-01-29 Toray Industries Substrate and touch panel member using same
KR101598249B1 (en) 2013-01-29 2016-02-26 삼성전기주식회사 Touch Panel
CN103149749B (en) * 2013-02-06 2016-05-25 敦泰电子有限公司 A kind of electrode structure and liquid crystal indicator
JP6186805B2 (en) * 2013-03-28 2017-08-30 大日本印刷株式会社 Touch panel
JP5882538B2 (en) 2013-04-18 2016-03-09 シャープ株式会社 Sensor sheet, sensor sheet module, touch sensor panel module, and electronic device
CN103226414B (en) * 2013-05-02 2015-04-08 深圳欧菲光科技股份有限公司 Touch screen and preparation method thereof
JP6013397B2 (en) 2013-05-10 2016-10-25 サムソン エレクトロ−メカニックス カンパニーリミテッド. Touch sensor
KR101580372B1 (en) 2013-05-10 2015-12-28 삼성전기주식회사 Touch Sensor
CN104345929B (en) * 2013-07-25 2018-01-12 南昌欧菲光科技有限公司 Touch-screen
WO2015060059A1 (en) * 2013-10-22 2015-04-30 富士フイルム株式会社 Conductive film, touch panel, and display device
JP5850967B2 (en) * 2014-03-17 2016-02-03 富士フイルム株式会社 Conductive sheet for touch panel and touch panel
JP6009488B2 (en) 2014-03-28 2016-10-19 富士フイルム株式会社 Sheet-like conductor and touch panel using the same
KR102199344B1 (en) * 2014-05-30 2021-01-06 엘지이노텍 주식회사 Touch window
KR102255415B1 (en) 2015-03-30 2021-05-21 동우 화인켐 주식회사 Touch sensor
EP3276684A4 (en) * 2015-05-01 2018-12-19 Toshiba Hokuto Electronics Corp. Light-emitting module
JP2017220033A (en) * 2016-06-07 2017-12-14 コニカミノルタ株式会社 Transparent planar device and method for producing transparent planar device
JP6646107B2 (en) * 2018-06-22 2020-02-14 富士フイルム株式会社 Transfer film and transparent laminate, method for producing them, capacitance input device, and image display device

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003271311A (en) * 2002-03-18 2003-09-26 Alps Electric Co Ltd Coordinate input device and liquid crystal display device using the same
US7129935B2 (en) * 2003-06-02 2006-10-31 Synaptics Incorporated Sensor patterns for a capacitive sensing apparatus
US20050030048A1 (en) * 2003-08-05 2005-02-10 Bolender Robert J. Capacitive sensing device for use in a keypad assembly
TW200901014A (en) * 2007-06-28 2009-01-01 Sense Pad Tech Co Ltd Touch panel device
TWM344544U (en) * 2007-12-25 2008-11-11 Cando Corp Sensory structure of touch panel
US8284332B2 (en) * 2008-08-01 2012-10-09 3M Innovative Properties Company Touch screen sensor with low visibility conductors
JP5174575B2 (en) * 2008-07-31 2013-04-03 グンゼ株式会社 Touch panel

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI650699B (en) * 2014-03-28 2019-02-11 日商富士軟片股份有限公司 Conductive laminate and touch panel using the same

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