TWI426066B - 經共蒸餾用於二氯丙醇回收之方法與裝置 - Google Patents
經共蒸餾用於二氯丙醇回收之方法與裝置 Download PDFInfo
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- TWI426066B TWI426066B TW097113157A TW97113157A TWI426066B TW I426066 B TWI426066 B TW I426066B TW 097113157 A TW097113157 A TW 097113157A TW 97113157 A TW97113157 A TW 97113157A TW I426066 B TWI426066 B TW I426066B
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- mixture
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- ester
- catalyst
- distillation
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- 239000003225 biodiesel Substances 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
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- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- BMRWNKZVCUKKSR-UHFFFAOYSA-N butane-1,2-diol Chemical compound CCC(O)CO BMRWNKZVCUKKSR-UHFFFAOYSA-N 0.000 description 1
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- 125000003963 dichloro group Chemical group Cl* 0.000 description 1
- UYAAVKFHBMJOJZ-UHFFFAOYSA-N diimidazo[1,3-b:1',3'-e]pyrazine-5,10-dione Chemical compound O=C1C2=CN=CN2C(=O)C2=CN=CN12 UYAAVKFHBMJOJZ-UHFFFAOYSA-N 0.000 description 1
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- YQEMORVAKMFKLG-UHFFFAOYSA-N glycerine monostearate Natural products CCCCCCCCCCCCCCCCCC(=O)OC(CO)CO YQEMORVAKMFKLG-UHFFFAOYSA-N 0.000 description 1
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- 239000001087 glyceryl triacetate Substances 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
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- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
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- 125000005647 linker group Chemical group 0.000 description 1
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- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 150000002843 nonmetals Chemical class 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 229960003424 phenylacetic acid Drugs 0.000 description 1
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- 150000003008 phosphonic acid esters Chemical class 0.000 description 1
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- 229920000647 polyepoxide Polymers 0.000 description 1
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- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
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- 239000001632 sodium acetate Substances 0.000 description 1
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- 239000007790 solid phase Substances 0.000 description 1
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- 125000001424 substituent group Chemical group 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
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- 238000011144 upstream manufacturing Methods 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/009—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping in combination with chemical reactions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/14—Fractional distillation or use of a fractionation or rectification column
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/14—Fractional distillation or use of a fractionation or rectification column
- B01D3/143—Fractional distillation or use of a fractionation or rectification column by two or more of a fractionation, separation or rectification step
- B01D3/146—Multiple effect distillation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/34—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping with one or more auxiliary substances
- B01D3/36—Azeotropic distillation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/34—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping with one or more auxiliary substances
- B01D3/38—Steam distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B61/00—Other general methods
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
- C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
- C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
- C07C29/82—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation by azeotropic distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/34—Halogenated alcohols
- C07C31/36—Halogenated alcohols the halogen not being fluorine
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
Applications Claiming Priority (1)
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| US92310207P | 2007-04-12 | 2007-04-12 |
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| TWI426066B true TWI426066B (zh) | 2014-02-11 |
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| TW097113157A TWI426066B (zh) | 2007-04-12 | 2008-04-11 | 經共蒸餾用於二氯丙醇回收之方法與裝置 |
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| US (2) | US8420870B2 (cg-RX-API-DMAC7.html) |
| EP (1) | EP2137123A1 (cg-RX-API-DMAC7.html) |
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| KR (1) | KR20100016455A (cg-RX-API-DMAC7.html) |
| CN (1) | CN101657404B (cg-RX-API-DMAC7.html) |
| TW (1) | TWI426066B (cg-RX-API-DMAC7.html) |
| WO (1) | WO2008128010A1 (cg-RX-API-DMAC7.html) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| TW201518267A (zh) * | 2007-04-12 | 2015-05-16 | Dow Global Technologies Llc | 用於二氯丙醇的共沸回收之方法與設備 |
| TWI432407B (zh) * | 2007-04-12 | 2014-04-01 | Dow Global Technologies Llc | 回收二氯丙醇之多階方法和裝置 |
| US8471077B2 (en) * | 2008-04-09 | 2013-06-25 | Dow Global Technologies Llc | Process and apparatus for efficient recovery of dichlorohydrins |
| EP2448898A1 (en) | 2009-07-03 | 2012-05-09 | Akzo Nobel Chemicals International B.V. | Process for preparing dichlorohydrin |
| FR2964096A1 (fr) * | 2010-08-27 | 2012-03-02 | Solvay | Procede d'epuration d'une saumure |
| JP5756183B2 (ja) * | 2010-12-10 | 2015-07-29 | ダウ グローバル テクノロジーズ エルエルシー | １，３−ジクロロ−２−プロパノールを２，２’−オキシビス（１−クロロプロパン）廃棄ストリームから単離するためにオレフィンを共沸添加剤として用いるための装置及び方法 |
| JP7220597B2 (ja) * | 2019-03-14 | 2023-02-10 | オルガノ株式会社 | 有機溶剤の蒸留精製装置及び蒸留精製方法 |
| CN116948690B (zh) * | 2022-04-20 | 2025-04-01 | 中国石油化工股份有限公司 | 劣质柴油多产高芳石脑油及btx的加氢处理方法及装置 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW200533638A (en) * | 2003-11-20 | 2005-10-16 | Solvay | Process for producing an organic compound |
| TW200642999A (en) * | 2005-05-20 | 2006-12-16 | Solvay | Process for preparing a chlorohydrin |
| TW200904786A (en) * | 2007-04-12 | 2009-02-01 | Dow Global Technologies Inc | Multi-stage process and apparatus for recovering dichlorohydrins |
| TW200906779A (en) * | 2007-04-12 | 2009-02-16 | Dow Global Technologies Inc | Process and apparatus for azeotropic recovery of dichlorohydrins |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE197308C (cg-RX-API-DMAC7.html) | ||||
| JPS60258171A (ja) * | 1984-06-04 | 1985-12-20 | Showa Denko Kk | エピクロルヒドリンの製造方法 |
| CZ20032346A3 (cs) | 2003-09-01 | 2005-04-13 | Spolek Pro Chemickou A Hutní Výrobu,A.S. | Způsob přípravy dichlorpropanolů z glycerinu |
| EA200800128A1 (ru) * | 2003-11-20 | 2008-04-28 | Солвей (Сосьете Аноним) | Способ получения хлорированного органического соединения, эпихлоргидрина и эпоксидных смол из возобновляемого сырья |
| US7906690B2 (en) * | 2004-07-21 | 2011-03-15 | Dow Global Technologies Inc. | Batch, semi-continuous or continuous hydrochlorination of glycerin with reduced volatile chlorinated hydrocarbon by-products and chloracetone levels |
| JP2008507526A (ja) | 2004-07-21 | 2008-03-13 | ダウ グローバル テクノロジーズ インコーポレイティド | 多ヒドロキシル化脂肪族炭化水素又はそのエステルのクロロヒドリンへの転化 |
| EP1762556A1 (en) * | 2005-05-20 | 2007-03-14 | SOLVAY (Société Anonyme) | Process for producing dichloropropanol from glycerol |
| CN100509726C (zh) | 2007-01-26 | 2009-07-08 | 江苏工业学院 | 一种从甘油制备二氯丙醇的方法 |
-
2008
- 2008-04-11 KR KR1020097023552A patent/KR20100016455A/ko not_active Ceased
- 2008-04-11 WO PCT/US2008/059976 patent/WO2008128010A1/en not_active Ceased
- 2008-04-11 TW TW097113157A patent/TWI426066B/zh not_active IP Right Cessation
- 2008-04-11 CN CN2008800117408A patent/CN101657404B/zh not_active Expired - Fee Related
- 2008-04-11 JP JP2010503222A patent/JP2010523701A/ja active Pending
- 2008-04-11 US US12/595,500 patent/US8420870B2/en not_active Expired - Fee Related
- 2008-04-11 EP EP08745562A patent/EP2137123A1/en not_active Withdrawn
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2013
- 2013-03-15 US US13/835,184 patent/US8926916B2/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW200533638A (en) * | 2003-11-20 | 2005-10-16 | Solvay | Process for producing an organic compound |
| TW200642999A (en) * | 2005-05-20 | 2006-12-16 | Solvay | Process for preparing a chlorohydrin |
| TW200904786A (en) * | 2007-04-12 | 2009-02-01 | Dow Global Technologies Inc | Multi-stage process and apparatus for recovering dichlorohydrins |
| TW200906779A (en) * | 2007-04-12 | 2009-02-16 | Dow Global Technologies Inc | Process and apparatus for azeotropic recovery of dichlorohydrins |
Also Published As
| Publication number | Publication date |
|---|---|
| US8926916B2 (en) | 2015-01-06 |
| CN101657404B (zh) | 2013-11-06 |
| KR20100016455A (ko) | 2010-02-12 |
| TW200906778A (en) | 2009-02-16 |
| JP2010523701A (ja) | 2010-07-15 |
| US20100137653A1 (en) | 2010-06-03 |
| US8420870B2 (en) | 2013-04-16 |
| EP2137123A1 (en) | 2009-12-30 |
| WO2008128010A1 (en) | 2008-10-23 |
| CN101657404A (zh) | 2010-02-24 |
| US20130202497A1 (en) | 2013-08-08 |
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