TWI404679B - 製造顏料用二氧化鈦之方法 - Google Patents
製造顏料用二氧化鈦之方法 Download PDFInfo
- Publication number
- TWI404679B TWI404679B TW096130890A TW96130890A TWI404679B TW I404679 B TWI404679 B TW I404679B TW 096130890 A TW096130890 A TW 096130890A TW 96130890 A TW96130890 A TW 96130890A TW I404679 B TWI404679 B TW I404679B
- Authority
- TW
- Taiwan
- Prior art keywords
- aluminum chloride
- inert
- solids
- gas
- solid
- Prior art date
Links
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title claims abstract description 62
- 238000000034 method Methods 0.000 title claims abstract description 41
- 239000004408 titanium dioxide Substances 0.000 title claims abstract description 30
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims abstract description 225
- 239000007787 solid Substances 0.000 claims abstract description 82
- 239000007789 gas Substances 0.000 claims abstract description 64
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims abstract description 46
- 239000007800 oxidant agent Substances 0.000 claims abstract description 19
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 9
- 230000003647 oxidation Effects 0.000 claims abstract description 7
- 239000000049 pigment Substances 0.000 claims description 25
- 238000000859 sublimation Methods 0.000 claims description 20
- 230000008022 sublimation Effects 0.000 claims description 20
- 238000004519 manufacturing process Methods 0.000 claims description 17
- 239000011261 inert gas Substances 0.000 claims description 15
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 11
- 229910052782 aluminium Inorganic materials 0.000 claims description 10
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 9
- 238000005243 fluidization Methods 0.000 claims description 4
- 238000009991 scouring Methods 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 2
- 238000005660 chlorination reaction Methods 0.000 claims description 2
- 239000000460 chlorine Substances 0.000 claims description 2
- 229910052801 chlorine Inorganic materials 0.000 claims description 2
- 229910052684 Cerium Inorganic materials 0.000 claims 3
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims 3
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims 2
- 230000001590 oxidative effect Effects 0.000 claims 1
- 238000012546 transfer Methods 0.000 abstract description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 11
- 239000000203 mixture Substances 0.000 description 11
- 230000008016 vaporization Effects 0.000 description 7
- 230000007797 corrosion Effects 0.000 description 6
- 238000005260 corrosion Methods 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- 238000007792 addition Methods 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000011143 downstream manufacturing Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 229910001510 metal chloride Inorganic materials 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 238000005092 sublimation method Methods 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- 238000009834 vaporization Methods 0.000 description 2
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 230000002730 additional effect Effects 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 description 1
- 229910001626 barium chloride Inorganic materials 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910052956 cinnabar Inorganic materials 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 230000003685 thermal hair damage Effects 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000006200 vaporizer Substances 0.000 description 1
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/04—Oxides; Hydroxides
- C01G23/047—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/04—Oxides; Hydroxides
- C01G23/047—Titanium dioxide
- C01G23/07—Producing by vapour phase processes, e.g. halide oxidation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/36—Compounds of titanium
- C09C1/3607—Titanium dioxide
- C09C1/3653—Treatment with inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/522,702 US20080069764A1 (en) | 2006-09-18 | 2006-09-18 | Process for making pigmentary titanium dioxide |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW200817284A TW200817284A (en) | 2008-04-16 |
| TWI404679B true TWI404679B (zh) | 2013-08-11 |
Family
ID=39188832
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW096130890A TWI404679B (zh) | 2006-09-18 | 2007-08-21 | 製造顏料用二氧化鈦之方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20080069764A1 (cg-RX-API-DMAC7.html) |
| EP (1) | EP2069242A2 (cg-RX-API-DMAC7.html) |
| JP (1) | JP5536453B2 (cg-RX-API-DMAC7.html) |
| CN (1) | CN101535184B (cg-RX-API-DMAC7.html) |
| AU (1) | AU2007297813B2 (cg-RX-API-DMAC7.html) |
| TW (1) | TWI404679B (cg-RX-API-DMAC7.html) |
| WO (1) | WO2008036158A2 (cg-RX-API-DMAC7.html) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102079885B (zh) * | 2010-12-25 | 2014-04-16 | 锦州钛业有限公司 | 氯化法多功能型二氧化钛颜料的制备方法 |
| JP6049696B2 (ja) * | 2012-03-30 | 2016-12-21 | 石原産業株式会社 | 二酸化チタン粒子の製造方法 |
| CN107055607A (zh) * | 2017-06-30 | 2017-08-18 | 攀钢集团研究院有限公司 | 一种用于钛白粉的生产系统 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2791547A (en) * | 1951-05-17 | 1957-05-07 | Exxon Research Engineering Co | Conversion of hydrocarbons with finely divided particles in a fluidized bed |
| US3174873A (en) * | 1960-04-25 | 1965-03-23 | British Titan Products | Entrainment of vapours in gases |
| US4892850A (en) * | 1986-11-07 | 1990-01-09 | Kureha Chemical Industry Co., Ltd. | Tough corundum-rutile composite sintered body |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE629765A (cg-RX-API-DMAC7.html) * | ||||
| BE633119A (cg-RX-API-DMAC7.html) * | ||||
| US2790704A (en) * | 1953-01-19 | 1957-04-30 | Du Pont | Process for producing a vaporized mixture of aluminum and titanium halides |
| US2824050A (en) * | 1954-08-25 | 1958-02-18 | Thann Fab Prod Chem | Preparation of gaseous streams comprising ticl4 and alcl3 |
| US3022137A (en) * | 1959-03-26 | 1962-02-20 | American Cyanamid Co | Combustion of titanium tetrachloride with oxygen |
| US3073712A (en) * | 1959-08-19 | 1963-01-15 | Laporte Titanium Ltd | Manufacture of titanium dioxide |
| BE613119A (cg-RX-API-DMAC7.html) | 1961-01-25 | |||
| GB992414A (en) * | 1961-09-27 | 1965-05-19 | British Titan Products | Production of titanium dioxide by vapour phase oxidation |
| GB987335A (en) * | 1962-03-20 | 1965-03-24 | Aluminium Lab Ltd | Method of evaporating aluminium trihalides |
| US4514373A (en) * | 1983-12-06 | 1985-04-30 | Toth Aluminum Corporation | Purification of aluminum chloride |
| US4910009A (en) * | 1988-05-06 | 1990-03-20 | Teledyne Industries, Inc. | Ultra high purity halides and their preparation |
| EP0427878B1 (de) * | 1989-11-13 | 1992-09-02 | KRONOS TITAN-Gesellschaft mbH | Verfahren und Vorrichtung zur Herstellung von Titandioxid |
| US5544817A (en) * | 1994-01-25 | 1996-08-13 | Kerr-Mcgee Chemical Corporation | Zirconium silicate grinding method and medium |
| DE19514663A1 (de) * | 1995-04-20 | 1996-10-24 | Kronos Titan Gmbh | Metallchloridgenerator |
| US5824146A (en) * | 1997-07-03 | 1998-10-20 | E. I. Du Pont De Nemours And Company | Method for making a photodurable aqueous titanium dioxide pigment slurry using a high level of aluminum co-oxidant |
| US6036999A (en) * | 1997-07-03 | 2000-03-14 | Zhao; Qian Qiu | Method of preparing grinding media consisting essentially of sintered TiO2 particles |
| JP2001039704A (ja) * | 1998-06-25 | 2001-02-13 | Ishihara Sangyo Kaisha Ltd | 金属酸化物の製造方法 |
| CN1294081C (zh) * | 1999-12-27 | 2007-01-10 | 昭和电工株式会社 | 氧化铝粒子、其制造方法、含有该粒子的组合物和研磨用氧化铝料浆 |
| US6419893B1 (en) * | 2000-09-18 | 2002-07-16 | Kerr-Mcgee Chemical Llc | Process for producing and cooling titanium dioxide |
| US7255815B2 (en) * | 2003-03-24 | 2007-08-14 | Carbo Ceramics Inc. | Titanium dioxide scouring media and method of production |
| US7119039B2 (en) * | 2003-03-24 | 2006-10-10 | Carbo Ceramics Inc. | Titanium dioxide scouring media and method of production |
| US20050119398A1 (en) * | 2003-09-11 | 2005-06-02 | Lu Zhang | Plasma synthesis of metal oxide nanoparticles |
| US20050249659A1 (en) * | 2004-05-04 | 2005-11-10 | Flynn Harry E | Scour media for titanium dioxide production |
| US6969498B1 (en) * | 2004-05-07 | 2005-11-29 | Riley Medical, Inc. | Surgical instrument bracket assembly |
| US20070072783A1 (en) * | 2005-09-26 | 2007-03-29 | Tronox Llc | Scour medium for titanium dioxide production |
-
2006
- 2006-09-18 US US11/522,702 patent/US20080069764A1/en not_active Abandoned
-
2007
- 2007-08-20 JP JP2009528229A patent/JP5536453B2/ja not_active Expired - Fee Related
- 2007-08-20 CN CN2007800346262A patent/CN101535184B/zh not_active Expired - Fee Related
- 2007-08-20 EP EP07837049A patent/EP2069242A2/en not_active Withdrawn
- 2007-08-20 WO PCT/US2007/018369 patent/WO2008036158A2/en not_active Ceased
- 2007-08-20 AU AU2007297813A patent/AU2007297813B2/en not_active Ceased
- 2007-08-21 TW TW096130890A patent/TWI404679B/zh not_active IP Right Cessation
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2791547A (en) * | 1951-05-17 | 1957-05-07 | Exxon Research Engineering Co | Conversion of hydrocarbons with finely divided particles in a fluidized bed |
| US3174873A (en) * | 1960-04-25 | 1965-03-23 | British Titan Products | Entrainment of vapours in gases |
| US4892850A (en) * | 1986-11-07 | 1990-01-09 | Kureha Chemical Industry Co., Ltd. | Tough corundum-rutile composite sintered body |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2008036158A8 (en) | 2010-08-12 |
| TW200817284A (en) | 2008-04-16 |
| WO2008036158A3 (en) | 2008-06-19 |
| US20080069764A1 (en) | 2008-03-20 |
| JP5536453B2 (ja) | 2014-07-02 |
| EP2069242A2 (en) | 2009-06-17 |
| AU2007297813A1 (en) | 2008-03-27 |
| AU2007297813B2 (en) | 2011-12-01 |
| WO2008036158A2 (en) | 2008-03-27 |
| JP2010505007A (ja) | 2010-02-18 |
| CN101535184A (zh) | 2009-09-16 |
| CN101535184B (zh) | 2013-04-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Annulment or lapse of patent due to non-payment of fees |