TWI391217B - Recycling method of waste interbonded polyethylene - Google Patents

Recycling method of waste interbonded polyethylene Download PDF

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TWI391217B
TWI391217B TW98109885A TW98109885A TWI391217B TW I391217 B TWI391217 B TW I391217B TW 98109885 A TW98109885 A TW 98109885A TW 98109885 A TW98109885 A TW 98109885A TW I391217 B TWI391217 B TW I391217B
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polyethylene
waste
recycling
cross
linked polyethylene
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TW98109885A
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TW201034826A (en
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Hsin Hua Sheng Technology Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

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  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)

Description

廢交連聚乙烯之回收再製方法Recycling method for waste cross-linked polyethylene

本發明係有關於一種「廢交連聚乙烯之回收再製方法」,尤指一種可將廢電纜、電線內的交連聚乙烯擷取出,俾回收再製,且該再製品的材料物性乃與初始原料相近之方法者。The invention relates to a “recycling method for waste cross-linked polyethylene”, in particular to a cross-linked polyethylene crucible in a waste cable or a wire, which is recycled and remanufactured, and the material property of the reworked product is similar to the initial raw material. Method.

塑膠由於清潔、衛生,能滿足人類各式各樣的需求,且其價格便宜,可快速大量的生產,而其優良的物性亦能取代金屬、木材等有限資源,所以塑膠用品才會大量的被使用,且充斥在我們的日常生活中;其中「交連聚乙烯」(XLPE:CROSS-Linked Polyethylene)更是被大量使用在電纜、電線的領域中,而所謂的交連聚乙烯乃是在電纜、電線絕緣層成型時,摻以少許「交連劑」之PE,加熱後使其分子結構產生交連,並使聚乙烯分子件產生架橋作用而相互連結形成熱固性聚合物,由於這種交連聚乙烯在電氣、機械、耐熱、耐化學藥品及抗濕特性上性能卓越,故相當適合應用在電纜、電線上。Because plastics are clean and hygienic, they can meet all kinds of human needs. They are cheap and can be produced quickly and in large quantities. Their excellent physical properties can also replace limited resources such as metal and wood. It is used in our daily life; among them, "XLPE: CROSS-Linked Polyethylene" is used in the field of cables and wires, and the so-called cross-linked polyethylene is in cables and wires. When the insulating layer is formed, a small amount of "crosslinking agent" PE is added, and after heating, the molecular structure is crosslinked, and the polyethylene molecular members are bridged to form a thermosetting polymer, since the crosslinked polyethylene is electrically, It is excellent in mechanical, heat-resistant, chemical-resistant and moisture-resistant properties, so it is suitable for use on cables and wires.

又,因為目前環保意識抬頭,抗蝕性佳的塑膠類材料最好要將其回收,且由於交連聚乙烯的壽命可達15至20年左右,經濟效益極高,故回收塑料也就成為經濟及環保併重的重要課題。Moreover, because the current awareness of environmental protection is on the rise, plastic materials with good corrosion resistance should be recycled, and since the life of cross-linked polyethylene can reach 15 to 20 years, the economic benefits are extremely high, so recycling plastics becomes an economy. And important issues that are both environmentally important.

是以,如何有效的將電纜、電線中的廢交連聚乙烯擷取、回收,並據以製成再製品,該再製品的材料物性並與初始原料相近,俾有效降低廢塑膠產品隨意丟棄對環境與經濟所造成的衝擊,乃係本發明人所欲解決之技術問題點。Therefore, how to effectively extract and recycle the waste cross-linked polyethylene in cables and wires, and make a re-product according to the material property of the re-product, which is similar to the original raw material, and effectively reduce the random discarding of waste plastic products. The impact caused by the environment and the economy is the technical problem that the inventors want to solve.

是以,本發明人即有鑑於此,乃思及創作的意念,遂以多年的經驗加以設計,經多方探討並試作樣品試驗,及多次修正改良,乃推出本發明。Therefore, the present inventors have invented the present invention in view of the above, the idea of creation and creation, the design of many years of experience, the examination of various samples and trials, and the many modifications and improvements.

解決問題之技術特點:Technical features to solve the problem:

本發明之廢交連聚乙烯之回收再製方法,其廢電纜、電線係依序經過分離、刨解、粉碎、二次加工、混合、溶合、射出成型等流程,而可完成回收再製之方法,其中:分離,係將廢電纜、電線以切割機縱剖成半圓管狀的回收塑料,該回收塑料乃具有一般聚乙烯的表層材、為交連聚乙烯的中層材及以絕緣耐熱聚乙烯構成的內層材,且當廢電纜、電線縱剖成回收塑料時,其內部之金屬導線將能同步被抽離,刨解,係以刨皮機將回收塑料的表層材與內層材刨除,俾留下中層材後製,粉碎,係將交連聚乙烯材質的中層材輥壓粉碎成粗顆粒,二次加工,該粉碎後之粗顆粒再加工成為細顆粒,混合,將細顆粒加入一般PE或PP混鍊改質,俾用來調整出最適合該再製品之物性,溶合,將混鍊改質後之塑膠料提煉造粒,俾製造出新粒,射出成型,將新粒利用射出成型機完成再製品;藉此,係能構成該廢交連聚乙烯之回收再製方法者。In the recycling and re-manufacturing method of the waste cross-linked polyethylene of the invention, the waste cable and the electric wire are sequentially subjected to separation, disintegration, pulverization, secondary processing, mixing, melting, injection molding and the like, and the method for recycling and re-forming can be completed. Wherein: separation, the waste cable and the electric wire are longitudinally cut into a semi-circular tubular recycled plastic by a cutting machine, and the recycled plastic is a surface material of a general polyethylene, a middle layer material of cross-linked polyethylene, and an inner layer made of insulating heat-resistant polyethylene. Laminate, and when the waste cable and electric wire are longitudinally cut into recycled plastic, the inner metal wire will be simultaneously extracted and dismantled, and the surface layer and the inner layer of the recycled plastic will be removed by the planer. After the middle layer material is made and pulverized, the middle layer material of the cross-linked polyethylene material is rolled and crushed into coarse particles, and the secondary processing is performed, and the pulverized coarse particles are further processed into fine particles, mixed, and the fine particles are added to general PE or PP. The mixed chain is modified, and the bismuth is used to adjust the physical properties which are most suitable for the reworked product, to dissolve, to refine the granulated plastic material after the mixed chain is modified, to produce new granules, to shoot and shape, and to use the new granules to use the injection molding machine. The rework product is completed; thereby, it can constitute the recycling method of the waste cross-linked polyethylene.

對照先前技術之功效:Compare the efficacy of the prior art:

(一)本發明之廢交連聚乙烯之回收再製方法,在原物料日益高漲的時代,以廢電纜、電線回收之交連聚乙烯完成再製品之加工,將能大幅降低再製品之材料購買成本,回收再製後亦較環保者。(1) The recycling and recycling method of the waste cross-linked polyethylene of the present invention, in the era of increasing raw materials, the processing of re-products by the waste polyethylene and the recycled polyethylene of the electric wire can greatly reduce the material purchase cost of the re-products, and recycle It is also more environmentally friendly after remanufacturing.

(二)本發明之廢交連聚乙烯之回收再製方法,其透過混合之流程,將能調整出最適合再製品之物性,以提高回收廢交連聚乙烯再利用之附加價值者。(2) The recycling method of the waste cross-linked polyethylene of the present invention, through the mixing process, can adjust the physical properties most suitable for the re-product, so as to increase the added value of recycling the waste cross-linked polyethylene.

為使 貴審查委員對本發明之目的、特徵及功效能夠有更進一步之瞭解與認識,以下茲請配合【圖式簡單說明】詳述如后:In order to enable your review committee to have a better understanding and understanding of the purpose, features and effects of the present invention, please refer to the following [Simplified Description of the Drawings] for details:

通常根據本發明,請由第一圖持續搭配至第八圖所示觀之,其廢電纜、電線(10)係依序經過分離(1)、刨解(2)、粉碎(3)、二次加工(4)、混合(5)、溶合(6)、射出成型(7)等流程,而可完成回收再製之方法,其中:Generally, according to the present invention, the first figure is continuously matched to the view shown in the eighth figure, and the waste cable and the electric wire (10) are sequentially separated (1), planed (2), crushed (3), and Secondary processing (4), mixing (5), melting (6), injection molding (7) and other processes, and recycling methods can be completed, wherein:

分離(1),係將廢電纜、電線(10)以切割機(20)縱剖成半圓管狀的回收塑料(30),該回收塑料(30)乃具有一般聚乙烯的表層材(31)、為交連聚乙烯的中層材(32)及以絕緣耐熱聚乙烯構成的內層材(33),且當廢電纜、電線(10)縱剖成回收塑料(30)時,其內部之金屬導線將能同步被抽離;Separating (1), the waste cable and the electric wire (10) are longitudinally cut into a semicircular tubular recycled plastic (30) by a cutter (20), and the recycled plastic (30) is a surface layer (31) of a general polyethylene. The intermediate layer (32) of the cross-linked polyethylene and the inner layer (33) made of the insulating heat-resistant polyethylene, and when the waste cable and the electric wire (10) are longitudinally sectioned into the recycled plastic (30), the inner metal wire thereof will be Can be extracted synchronously;

刨解(2),係以刨皮機(40)將回收塑料(30)的表層材(31)與內層材(33)刨除,俾留下中層材(32)後製;Planing (2), the topsheet (31) and the inner layer (33) of the recycled plastic (30) are removed by a planing machine (40), and the intermediate layer (32) is left behind;

粉碎(3),係將交連聚乙烯材質的中層材(32)輥壓粉碎成粗顆粒(50);Crushing (3), the intermediate layer (32) of cross-linked polyethylene material is rolled and pulverized into coarse particles (50);

二次加工(4),該粉碎後之粗顆粒(50)再加工成為細顆粒(60);Secondary processing (4), the pulverized coarse particles (50) are further processed into fine particles (60);

混合(5),將細顆粒(60)加入一般PE(聚乙烯)或PP(聚丙烯)(70)混鍊改質,俾用來調整出最適合該再製品(90)之物性(如抗張、抗折、抗衝擊強度或合膠黏度等);Mixing (5), adding the fine particles (60) to the general PE (polyethylene) or PP (polypropylene) (70) mixed chain, and adjusting the physical properties (such as anti-resistant) which are most suitable for the re-product (90). Tensile, flexural strength, impact strength or adhesive viscosity, etc.);

溶合(6),將混鍊改質後之塑膠料提煉造粒,俾製造出新粒(80);Dissolving (6), refining and granulating the plastic material after the mixed chain modification, and producing new particles (80);

射出成型(7),將新粒(80)利用射出成型機完成再製品(90),即構成該廢交連聚乙烯之回收再製方法者。Injection molding (7), the new pellet (80) is completed by an injection molding machine (90), that is, the recycling method for the waste cross-linked polyethylene.

藉由上述廢交連聚乙烯之回收再製方法具有下列之優點:(一)在原物料日益高漲的時代,以廢電纜、電線(10)回收之交連聚乙烯完成再製品(90)之加工,將能大幅降低再製品(90)之材料購買成本,回收再製後亦較環保者;(二)其透過混合(5)之流程,將能調整出最適合再製品(90)之物性,以提高回收廢交連聚乙烯再利用之附加價值者。The recycling method of the above-mentioned waste cross-linked polyethylene has the following advantages: (1) in the era of increasing raw materials, the processing of re-products (90) by the cross-linked polyethylene recovered by the waste cable and the electric wire (10) will be able to Significantly reduce the purchase cost of materials for re-products (90), and be more environmentally friendly after recycling. (2) Through the process of mixing (5), it will be able to adjust the physical properties of the most suitable re-products (90) to improve recycling. The added value of cross-linked polyethylene reuse.

唯以上所述者,僅為本發明之一較佳實施例而已,當不能以之限定本發明實施之範圍;即大凡依本發明申請專利範圍所作之均等變化與修飾,皆應仍屬本創作專利涵蓋之範圍內。The above is only a preferred embodiment of the present invention, and the scope of the present invention is not limited thereto; that is, the equal variation and modification of the scope of the patent application of the present invention should still belong to the present creation. Within the scope of the patent.

本發明部份:Part of the invention:

(1)...分離(1). . . Separation

(2)...刨解(2). . . Planing

(3)...粉碎(3). . . Crush

(4)...二次加工(4). . . Secondary processing

(5)...混合(5). . . mixing

(6)...溶合(6). . . Fusion

(7)...射出成型(7). . . Injection Molding

(10)...廢電纜、電線(10). . . Waste cable, wire

(20)...切割機(20). . . Cutting Machine

(30)...回收塑料(30). . . Recycled plastic

(31)...表層材(31). . . Surface material

(32)...中層材(32). . . Middle layer

(33)...內層材(33). . . Inner layer

(40)...刨皮機(40). . . Planing machine

(50)...粗顆粒(50). . . Coarse particles

(60)...細顆粒(60). . . Fine particles

(70)...一般PE或PP(70). . . General PE or PP

(80)...新粒(80). . . New grain

(90)...再製品(90). . . Rework

第一圖:係本發明之方塊流程圖。First Figure: is a block flow diagram of the present invention.

第二圖:係本發明之分離狀態圖。Second Figure: A diagram of the separation state of the present invention.

第三圖:係本發明之刨解狀態圖。Third Figure: is a plan view of the present invention.

第四圖:係本發明粉碎成粗顆粒之狀態圖。Fig. 4 is a view showing a state in which the present invention is pulverized into coarse particles.

第五圖:係本發明粗顆粒加工成細顆粒之狀態圖。Fig. 5 is a view showing the state in which the coarse particles of the present invention are processed into fine particles.

第六圖:係本發明之混合狀態圖。Figure 6 is a diagram of the mixed state of the present invention.

第七圖:係本發明成型出新粒之狀態圖。Figure 7 is a state diagram of the new particles formed by the present invention.

第八圖:係本發明完成再製品之狀態圖。Figure 8 is a diagram showing the state of the finished product of the present invention.

(1)...分離(1). . . Separation

(2)...刨解(2). . . Planing

(3)...粉碎(3). . . Crush

(4)...二次加工(4). . . Secondary processing

(5)...混合(5). . . mixing

(6)...溶合(6). . . Fusion

(7)...射出成型(7). . . Injection Molding

Claims (2)

一種廢交連聚乙烯之回收再製方法,其廢電纜、電線係依序經過分離、刨解、粉碎、二次加工、混合、溶合、射出成型等流程,而可完成回收再製之方法,其中:分離,係將廢電纜、電線以切割機縱剖成半圓管狀的回收塑料,該回收塑料乃具有一般聚乙烯的表層材、為交連聚乙烯的中層材及以絕緣耐熱聚乙烯構成的內層材,且當廢電纜、電線縱剖成回收塑料時,其內部之金屬導線將能同步被抽離;刨解,係以刨皮機將回收塑料的表層材與內層材刨除,俾留下中層材後製;粉碎,係將交連聚乙烯材質的中層材輥壓粉碎成粗顆粒;二次加工,該粉碎後之粗顆粒再加工成為細顆粒;混合,將細顆粒加入一般PE混鍊改質,俾用來調整出最適合該再製品之物性;溶合,將混鍊改質後之塑膠料提煉造粒,俾製造出新粒;射出成型,將新粒利用射出成型機完成再製品,即構成該廢交連聚乙烯之回收再製方法者。The invention discloses a method for recycling and recycling waste cross-linked polyethylene, wherein the waste cable and the electric wire are sequentially separated, disintegrated, pulverized, reprocessed, mixed, fused, and injection molded, and the recycling and re-preparation method can be completed, wherein: Separation, the waste cable and the electric wire are longitudinally cut into a semi-circular tubular recycled plastic by a cutting machine, which is a surface material of general polyethylene, a middle layer material of cross-linked polyethylene, and an inner layer material made of insulating heat-resistant polyethylene. When the waste cable and electric wire are longitudinally cut into recycled plastic, the inner metal wire will be able to be separated at the same time; the planing machine will remove the surface layer and the inner layer of the recycled plastic by the planer, leaving the middle layer After the material is smashed, the middle layer of the cross-linked polyethylene material is crushed into coarse particles; after the secondary processing, the pulverized coarse particles are processed into fine particles; mixing, adding the fine particles to the general PE mixed chain modification俾 is used to adjust the physical properties most suitable for the re-product; solvating, refining and granulating the plastic material after the mixed chain modification, and manufacturing new granules; injection molding, using the injection molding machine to complete the new granules Product, i.e., constituting the waste deposit polyethylene recovered even by re-molding method. 根據申請專利範圍第1項所述之廢交連聚乙烯之回收再製方法,其中,混合時亦可加入一般PP與細顆粒混鍊改質者。According to the recycling method of the waste crosslinked polyethylene according to the first aspect of the patent application, in the case of mixing, a general PP and a fine particle mixed chain may be added.
TW98109885A 2009-03-26 2009-03-26 Recycling method of waste interbonded polyethylene TWI391217B (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5865085A (en) * 1995-05-12 1999-02-02 Vollenweider; Eric High volume wire stripper
TW356445B (en) * 1996-06-17 1999-04-21 Finacor Anstalt Plastic recycling and production process and the plastic material produced therefrom

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5865085A (en) * 1995-05-12 1999-02-02 Vollenweider; Eric High volume wire stripper
TW356445B (en) * 1996-06-17 1999-04-21 Finacor Anstalt Plastic recycling and production process and the plastic material produced therefrom

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