TWI570164B - Method of making environmentally friendly electronic board by recycling plastic waste - Google Patents
Method of making environmentally friendly electronic board by recycling plastic waste Download PDFInfo
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- TWI570164B TWI570164B TW104128270A TW104128270A TWI570164B TW I570164 B TWI570164 B TW I570164B TW 104128270 A TW104128270 A TW 104128270A TW 104128270 A TW104128270 A TW 104128270A TW I570164 B TWI570164 B TW I570164B
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
- Y02P20/143—Feedstock the feedstock being recycled material, e.g. plastics
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
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Description
本發明係有關一種回收廢棄物再利用之方法,尤指一種以廢棄物進行加工製作防水、高強度、耐酸鹼且輕量化材料的利用回收廢棄物製作電子板材方法。 The invention relates to a method for recycling waste, in particular to a method for producing electronic sheets by using waste to process water, high strength, acid and alkali resistant and lightweight materials using recycled waste.
習用電子板材中,常見者不外乎印刷電路板(PCB)或CNC應用端之鉆板及墊板,如電木板及酚醛墊板(尿素板)..等,惟,此等電子板材的強度雖高,但結構偏重且耐酸鹼性及防水性均略顯不足,再加上材質本身之特性導致無法回收再製的情況,因此並不環保。 In the use of electronic boards, the common ones are nothing more than printed circuit boards (PCBs) or CNC applications, such as electric boards and phenolic pads (urea boards), etc., but the strength of these electronic boards Although it is high, it is structurally heavy, and its acid and alkali resistance and water repellency are slightly insufficient. In addition, the characteristics of the material itself make it impossible to recycle and remanufacture, so it is not environmentally friendly.
而為解決上述電子板材之問題,本案申請人利用2014年11月28日向世界智慧財產權組織(World Intellectual Property Organization,簡稱WIPO)以PCT(專利合作條約Patent Cooperation Treaty)所申請的「利用回收廢棄物製作環保材料之製作方法」(PCT/CN2014/092495)專利申請案之習知技術,進行電子板材之製作,惟,受限於電子板材所需強度、重量耐酸鹼性及防水性之需求與一般建築、傢俱或文具之板材、板條、管件或板塊不同,致使以該習知技術所製成的電子板材不符需求。 In order to solve the above problem of electronic boards, the applicant used the “Recycling Wastes” applied for by the World Intellectual Property Organization (WIPO) on November 28, 2014 under the PCT (Patent Cooperation Treaty). The production of electronic boards is carried out by the prior art of the production of environmentally friendly materials (PCT/CN2014/092495), but is limited by the required strength, weight, acid and alkali resistance and water repellency of electronic boards. The boards, slats, fittings or plates of general construction, furniture or stationery are different, so that electronic boards made by this prior art do not meet the requirements.
由此可見,上述習用方式仍有諸多缺失,實非一良善之設計,而亟待加以改良。 It can be seen that there are still many shortcomings in the above-mentioned methods of use, which is not a good design, but needs to be improved.
本案發明人鑑於上述習用方式所衍生的各項缺點,乃亟思加以改良創新,並經多年苦心孤詣潛心研究後,終於成功研發完成本件利用回收廢棄物製作電子板材之方法。 In view of the shortcomings derived from the above-mentioned conventional methods, the inventor of the present invention has improved and innovated, and after years of painstaking research, he finally succeeded in researching and developing the method for making electronic sheets using recycled waste.
為解決上述習知技術之問題,本發明之一目的係在於提供一種製造可回收再利用之電子板材的利用回收廢棄物製作電子板材之方法。 In order to solve the above problems of the prior art, it is an object of the present invention to provide a method for producing an electronic sheet using recycled waste by manufacturing a recyclable electronic board.
為解決上述習知技術之問題,本發明之另一目的係在於提供一種高強度且重量輕,同時具備高耐酸鹼性及高防水的利用回收廢棄物製作電子板材之方法。 In order to solve the above problems of the prior art, another object of the present invention is to provide a method for producing an electronic sheet using recycled waste with high strength and light weight, and having high acid and alkali resistance and high water resistance.
為達成上述之目的,本發明利用回收廢棄物製作電子板材之方法,主要係將回收之廢棄聚丙烯(PP)、聚對苯二甲酸乙二醇酯(PET)或其混合物材質之塑料寶特瓶、製品或材料進行粉碎加工,以形成1~10mm的顆粒,然後再與回收粉碎之廢棄稻殼劑量調配混合後,以180~250℃的溫度進行加熱熔融捏合混煉,並待其冷卻固結後,進行切粒粉碎形成塑殼粒,然後,再以將塑殼粒作為材料,利用射出成型機以180~250℃的溫度射出成型,或利用壓出成型機或擠出成型機以180~250℃的溫度壓出或擠出成型,進行電子板材之成型動作。 In order to achieve the above object, the present invention utilizes a method for producing electronic sheets by recycling waste, and is mainly a plastic material of recycled polypropylene (PP), polyethylene terephthalate (PET) or a mixture thereof. The bottle, product or material is pulverized to form granules of 1~10mm, and then mixed with the waste pulverized waste rice husk, and then heated, melted and kneaded at a temperature of 180~250 °C, and cooled and solidified. After the knot, the pellets are pulverized to form the molded shell particles, and then the molded shell pellets are used as the material, and are injection molded at a temperature of 180 to 250 ° C by an injection molding machine, or 180 by using an extrusion molding machine or an extrusion molding machine. The temperature of ~250 ° C is extruded or extruded to perform the molding operation of the electronic sheet.
其中,該回收粉碎之廢棄稻殼粒徑為10~325目之間。 Wherein, the recycled and crushed waste rice husk has a particle size of between 10 and 325 mesh.
其中,回收之廢棄聚丙烯(PP)、聚對苯二甲酸乙二醇酯(PET)或其混合物材質之塑料寶特瓶、製品或材料:回收粉碎之廢棄稻殼之混合重量百分比為35%~65%:65%~35%,且該重量百分比為35%~65%:65%~35%中上限總合為100%的任意實數比例。 The plastic bottle, product or material of the recycled waste polypropylene (PP), polyethylene terephthalate (PET) or a mixture thereof: the recycled weight percentage of the crushed waste rice husk is 35% ~65%: 65%~35%, and the weight percentage is 35%~65%: 65%~35% of the upper limit is 100% of any real ratio.
上述回收之廢棄聚丙烯(PP)、聚對苯二甲酸乙二醇酯(PET)或其混合物材質之塑料寶特瓶、製品或材料及回收粉碎之廢棄稻殼,可添加其他如矽粉或碳酸鈣粉末..等微量添加物進行加熱熔融捏合混煉,且添加之其他如矽粉或碳酸鈣粉末..等微量添加物之重量百分比係由回收之廢棄聚丙烯(PP)、聚對苯二甲酸乙二醇酯(PET)或其混合物材質之塑料寶特瓶、製品或材料及回收粉碎之廢棄稻殼兩者或其中之一的重量百分比中扣除。 The plastic bottle, product or material of the above-mentioned recycled waste polypropylene (PP), polyethylene terephthalate (PET) or a mixture thereof and the waste crushed waste rice hull may be added with other powders or powders. Calcium carbonate powder: The same amount of additives are heated, melted, kneaded and kneaded, and other weight percentages such as powder or calcium carbonate powder added are collected from recycled polypropylene (PP) and polyparaphenyl. The weight percentage of either or both of the plastic bottle, product or material of the polyethylene terephthalate (PET) or a mixture thereof and the recovered crushed waste rice hull is deducted.
上述回收之廢棄聚丙烯(PP)、聚對苯二甲酸乙二醇酯(PET)或其混合物材質之塑料寶特瓶、製品或材料及回收粉碎之廢棄稻殼,可添加1%~15%任意實數重量百分比的瀝青添加物進行加熱熔融捏合混煉,且添加之瀝青重量百分比係由回收之廢棄聚丙烯(PP)、聚對苯二甲酸乙二醇酯(PET)或其混合物材質之塑料寶特瓶、製品或材料及回收粉碎之廢棄稻殼兩者或其中之一的重量百分比中扣除。 Adding 1% to 15% of the plastic bottle, product or material of the recycled waste polypropylene (PP), polyethylene terephthalate (PET) or a mixture thereof and the recycled and crushed waste rice husk Any real weight percentage of the asphalt additive is subjected to heat-melting, kneading and kneading, and the added asphalt weight percentage is a plastic material of recycled waste polypropylene (PP), polyethylene terephthalate (PET) or a mixture thereof. Deducted from the weight percentage of either or both of the PET bottles, products or materials and recycled crushed waste rice husks.
上述回收之廢棄聚丙烯(PP)、聚對苯二甲酸乙二醇酯(PET)或其混合物材質之塑料寶特瓶、製品或材料及回收粉碎之廢棄稻殼,可添加1%~15%任意實數重量百分比的瀝青及其他如矽粉或碳酸鈣粉末..等微量添加物進行加熱熔融捏合混煉,且添加之瀝青及其他如矽粉或碳酸鈣粉末..等微量添加物之重量百分比係由回收之廢棄聚丙烯(PP)、聚對苯二甲酸乙二醇酯(PET)或其混合物材質之塑料寶特瓶、製品或材料及回收粉碎之廢棄稻殼兩者或其中之一的重量百分比中扣除。 Adding 1% to 15% of the plastic bottle, product or material of the recycled waste polypropylene (PP), polyethylene terephthalate (PET) or a mixture thereof and the recycled and crushed waste rice husk Any real weight percentage of bitumen and other micro-additives such as tantalum powder or calcium carbonate powder, etc., heated, melt-kneaded and kneaded, and the weight percentage of added bitumen and other trace additives such as tantalum powder or calcium carbonate powder A plastic PET bottle, product or material recovered from recycled waste polypropylene (PP), polyethylene terephthalate (PET) or a mixture thereof, and recycled or crushed waste rice husk Deducted from the weight percentage.
S01~S05‧‧‧流程步驟 S01~S05‧‧‧ Process steps
S031~S033‧‧‧加熱熔融捏合混煉流程步驟 S031~S033‧‧‧heat melt-kneading mixing process steps
S11~S15‧‧‧流程步驟 S11~S15‧‧‧ Process steps
圖1係為本發明利用回收廢棄物製作電子板材之方法流程圖;圖2係為本發明加熱熔融捏合混煉之流程圖;圖3係為本發明另一實施例之方法流程圖。 1 is a flow chart of a method for producing an electronic sheet by using recycled waste according to the present invention; FIG. 2 is a flow chart of the heat-melt-kneading and kneading of the present invention; and FIG. 3 is a flow chart of a method according to another embodiment of the present invention.
以下結合附圖對本發明進一步說明:請參閱圖1,本發明利用回收廢棄物製作電子板材之方法,主要係將回收之廢棄聚丙烯(PP)、聚對苯二甲酸乙二醇酯(PET)或其混合物材質之塑料寶特瓶、製品或材料粉碎加工製成1~10mm之顆粒回收廢棄物顆粒(S01),並將回收廢棄稻殼粉碎加工並控制粒徑在10~325目之間(S02),接著,將粉碎加工回收之廢棄聚丙烯(PP)、聚對苯二甲酸乙二醇酯(PET)或其混合物材質之塑料寶特瓶、製品或材料,與粉碎之廢棄稻殼60%:40%之重量比進行加熱熔融捏合混煉(S03),然後將捏合熔煉後形成的半成品進行粗碎及細碎而形成塑殼粒(S04),最後利用射出成型機、壓出或擠出成型機將塑殼粒以180~250℃之溫度進行熔融並注射至模具成形為電子板材(S05)。 The present invention will be further described below with reference to the accompanying drawings: Referring to Figure 1, the present invention uses a method for producing electronic sheets by recycling waste, mainly for recycling waste polypropylene (PP) and polyethylene terephthalate (PET). The plastic bottle, product or material of the mixture material is pulverized and processed into pellets of 1~10mm particle recovery waste (S01), and the waste rice husk is crushed and processed to control the particle size between 10 and 325 mesh ( S02), next, a plastic PET bottle, product or material of waste polypropylene (PP), polyethylene terephthalate (PET) or a mixture thereof, and pulverized waste rice husk 60 %: 40% by weight is subjected to heat-melt kneading and kneading (S03), and then the semi-finished product formed by kneading and smelting is coarsely crushed and finely divided to form a molded shell (S04), and finally, an injection molding machine, extrusion or extrusion is used. The molding machine melts the molded shell particles at a temperature of 180 to 250 ° C and injects them into a mold to form an electronic sheet (S05).
請參閱圖2,本發明利用回收廢棄物製作電子板材之方法的另一實施例中,加熱熔融捏合混煉步驟係將粉碎加工後的回收之廢棄聚丙烯(PP)、聚對苯二甲酸乙二醇酯(PET)或其混合物材質之塑料寶特瓶、製品或材料,以180~250℃的溫度加熱熔煉為黏稠狀(S031),然後再將粉碎加工後的稻殼加入熔煉為黏稠狀的粉碎加工後的回收之廢棄聚丙烯(PP)、聚對苯二甲酸乙二醇酯(PET)或之塑料寶特瓶、製品或材料中(S032),進行加熱熔融捏合混煉(S033),以形成半成品並進行粗碎及細碎而形成塑殼粒。 Referring to FIG. 2, in another embodiment of the method for producing an electronic board by using recycled waste, the heating, melt-kneading and kneading step is to recycle the recycled waste polypropylene (PP) and polyethylene terephthalate. A plastic bottle, product or material of a glycol ester (PET) or a mixture thereof is heated and smelted to a viscous state (S031) at a temperature of 180 to 250 ° C, and then the pulverized rice husk is added and smelted into a viscous shape. After the pulverized processed waste polypropylene (PP), polyethylene terephthalate (PET) or plastic bottle, product or material (S032), heat-melting and kneading (S033) To form a semi-finished product and to carry out coarse crushing and fine crushing to form a plastic shell particle.
請參閱圖3,為本發明之另一實施例,其主要係將回收之廢棄聚丙烯(PP)、聚對苯二甲酸乙二醇酯(PET)或其混合物材質之塑料寶特瓶、製品或材料粉碎加工製成1~10mm之顆粒回收廢棄物顆粒(S11),並將回收廢棄稻殼粉碎加工並控制粒徑在10~325目之間(S12),接著,將粉碎加工回收之廢棄聚丙烯(PP)、聚對苯二甲酸乙二醇酯(PET)或其混合物材質之塑料寶特瓶、製品或材料,與粉碎之廢棄稻殼及瀝青依50%:40%:10%之重量百分比進行加熱熔融捏合混煉(S13),然後將捏合熔煉後形成的半成品進行粗碎及細碎而形成塑殼粒(S14),最後利用射出成型機、壓出或擠出成型機將塑殼粒以180~250℃之溫度進行熔融並注射至模具成形為電子板材(S15)。 Please refer to FIG. 3 , which is another embodiment of the present invention, which is mainly a plastic PET bottle and a product of recycled polypropylene (PP), polyethylene terephthalate (PET) or a mixture thereof. Or the material is pulverized and processed into pellets of 1~10mm particle recovery waste (S11), and the waste rice husk is crushed and processed to control the particle size between 10 and 325 mesh (S12), and then the waste processed by the crushing process is discarded. Polypropylene (PP), polyethylene terephthalate (PET) or a mixture of plastic bottles, products or materials, and crushed waste rice husks and asphalt 50%: 40%: 10% The weight percentage is subjected to heat-melting kneading and kneading (S13), and then the semi-finished product formed by kneading and smelting is coarsely crushed and finely divided to form a molded shell (S14), and finally molded by an injection molding machine, extrusion or extrusion molding machine. The pellet is melted at a temperature of 180 to 250 ° C and injected into a mold to form an electronic sheet (S15).
由於本發明利用回收廢棄物製作電子板材之方法,係利用加熱熔煉使回收之廢棄聚丙烯(PP)、聚對苯二甲酸乙二醇酯(PET)或其混合物材質之塑料寶特瓶、製品或材料與回收粉碎之廢棄稻殼及碳酸鈣結合,相較習知之電子板材,除了具有增強製成之成品的整體結構強度外,且可將成型之電子板材重新熔融再製,因此,依本發明之方法製作出之電子板材,同時兼具有回收再製及輕量化之優點,並具有防水防濕及耐酸鹼之功效。 The method for producing an electronic sheet by using the recycled waste according to the present invention is a plastic PET bottle and a product made of the waste polypropylene (PP), polyethylene terephthalate (PET) or a mixture thereof by heating and smelting. Or the material is combined with the recycled crushed waste rice husk and calcium carbonate. Compared with the conventional electronic plate, in addition to the overall structural strength of the finished product, the formed electronic plate can be remelted and reprocessed. The electronic sheet produced by the method has the advantages of recycling, recycling and light weight, and has the functions of waterproof, moistureproof and acid and alkali resistance.
上列詳細說明係針對本發明之一可行實施例之具體說明,惟該實施例並非用以限制本發明之專利範圍,凡未脫離本發明技藝精神所為之等效實施或變更,均應包含於本案之專利範圍中。 The detailed description of the preferred embodiments of the present invention is intended to be limited to the scope of the invention, and is not intended to limit the scope of the invention. The patent scope of this case.
S01~S05‧‧‧流程步驟 S01~S05‧‧‧ Process steps
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CN1356351A (en) * | 2000-10-27 | 2002-07-03 | 索尼公司 | Additive for resin, resin containing additive and preparing process thereof |
CN101139453A (en) * | 2007-08-23 | 2008-03-12 | 钟林 | Circulating mix-smelting plastic-wood composite material, production method and freight pallet manufactured by the same |
CN102149526A (en) * | 2008-09-12 | 2011-08-10 | 杰富意钢铁株式会社 | Method for producing pulverized waste plastic and solid fuel or mineral reduction material |
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CN1356351A (en) * | 2000-10-27 | 2002-07-03 | 索尼公司 | Additive for resin, resin containing additive and preparing process thereof |
CN101139453A (en) * | 2007-08-23 | 2008-03-12 | 钟林 | Circulating mix-smelting plastic-wood composite material, production method and freight pallet manufactured by the same |
CN102149526A (en) * | 2008-09-12 | 2011-08-10 | 杰富意钢铁株式会社 | Method for producing pulverized waste plastic and solid fuel or mineral reduction material |
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