TWI386637B - 測定聚合物中分子重量分佈之方法 - Google Patents
測定聚合物中分子重量分佈之方法 Download PDFInfo
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- TWI386637B TWI386637B TW096142304A TW96142304A TWI386637B TW I386637 B TWI386637 B TW I386637B TW 096142304 A TW096142304 A TW 096142304A TW 96142304 A TW96142304 A TW 96142304A TW I386637 B TWI386637 B TW I386637B
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Links
- 238000000034 method Methods 0.000 title claims description 57
- 229920000642 polymer Polymers 0.000 title claims description 53
- 230000008569 process Effects 0.000 title claims description 19
- 238000002156 mixing Methods 0.000 claims description 47
- 238000001228 spectrum Methods 0.000 claims description 26
- 238000004364 calculation method Methods 0.000 claims description 11
- 239000002131 composite material Substances 0.000 claims description 10
- 230000009477 glass transition Effects 0.000 claims description 4
- 229920000459 Nitrile rubber Polymers 0.000 description 50
- 238000005259 measurement Methods 0.000 description 34
- 229920006168 hydrated nitrile rubber Polymers 0.000 description 32
- 230000000694 effects Effects 0.000 description 20
- 230000001419 dependent effect Effects 0.000 description 17
- 238000005984 hydrogenation reaction Methods 0.000 description 14
- 241001441571 Hiodontidae Species 0.000 description 10
- 238000002474 experimental method Methods 0.000 description 8
- 238000004458 analytical method Methods 0.000 description 6
- 230000009467 reduction Effects 0.000 description 6
- 239000004793 Polystyrene Substances 0.000 description 4
- 238000012512 characterization method Methods 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 210000003298 dental enamel Anatomy 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 229920002223 polystyrene Polymers 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000000875 corresponding effect Effects 0.000 description 3
- 238000004146 energy storage Methods 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 238000005649 metathesis reaction Methods 0.000 description 3
- 229920001195 polyisoprene Polymers 0.000 description 3
- 230000000717 retained effect Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 244000043261 Hevea brasiliensis Species 0.000 description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 2
- 230000002902 bimodal effect Effects 0.000 description 2
- 238000012790 confirmation Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 238000011326 mechanical measurement Methods 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920003052 natural elastomer Polymers 0.000 description 2
- 229920001194 natural rubber Polymers 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 229910052707 ruthenium Inorganic materials 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- 238000007086 side reaction Methods 0.000 description 2
- 230000003595 spectral effect Effects 0.000 description 2
- 229910052715 tantalum Inorganic materials 0.000 description 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 230000036962 time dependent Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000005315 distribution function Methods 0.000 description 1
- 238000004836 empirical method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000010297 mechanical methods and process Methods 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010408 sweeping Methods 0.000 description 1
- 230000009897 systematic effect Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N11/00—Investigating flow properties of materials, e.g. viscosity, plasticity; Analysing materials by determining flow properties
- G01N11/10—Investigating flow properties of materials, e.g. viscosity, plasticity; Analysing materials by determining flow properties by moving a body within the material
- G01N11/14—Investigating flow properties of materials, e.g. viscosity, plasticity; Analysing materials by determining flow properties by moving a body within the material by using rotary bodies, e.g. vane
- G01N11/142—Sample held between two members substantially perpendicular to axis of rotation, e.g. parallel plate viscometer
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N11/00—Investigating flow properties of materials, e.g. viscosity, plasticity; Analysing materials by determining flow properties
- G01N11/10—Investigating flow properties of materials, e.g. viscosity, plasticity; Analysing materials by determining flow properties by moving a body within the material
- G01N11/14—Investigating flow properties of materials, e.g. viscosity, plasticity; Analysing materials by determining flow properties by moving a body within the material by using rotary bodies, e.g. vane
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N11/00—Investigating flow properties of materials, e.g. viscosity, plasticity; Analysing materials by determining flow properties
- G01N11/10—Investigating flow properties of materials, e.g. viscosity, plasticity; Analysing materials by determining flow properties by moving a body within the material
- G01N11/14—Investigating flow properties of materials, e.g. viscosity, plasticity; Analysing materials by determining flow properties by moving a body within the material by using rotary bodies, e.g. vane
- G01N11/142—Sample held between two members substantially perpendicular to axis of rotation, e.g. parallel plate viscometer
- G01N2011/145—Sample held between two members substantially perpendicular to axis of rotation, e.g. parallel plate viscometer both members rotating
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N2203/00—Investigating strength properties of solid materials by application of mechanical stress
- G01N2203/0014—Type of force applied
- G01N2203/0025—Shearing
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N2203/00—Investigating strength properties of solid materials by application of mechanical stress
- G01N2203/0058—Kind of property studied
- G01N2203/0092—Visco-elasticity, solidification, curing, cross-linking degree, vulcanisation or strength properties of semi-solid materials
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N2203/00—Investigating strength properties of solid materials by application of mechanical stress
- G01N2203/0058—Kind of property studied
- G01N2203/0092—Visco-elasticity, solidification, curing, cross-linking degree, vulcanisation or strength properties of semi-solid materials
- G01N2203/0094—Visco-elasticity
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N2203/00—Investigating strength properties of solid materials by application of mechanical stress
- G01N2203/02—Details not specific for a particular testing method
- G01N2203/0202—Control of the test
- G01N2203/0212—Theories, calculations
- G01N2203/0218—Calculations based on experimental data
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/44—Resins; Plastics; Rubber; Leather
- G01N33/445—Rubber
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Medicinal Chemistry (AREA)
- Molecular Biology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Investigating Or Analysing Materials By Optical Means (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102006053390A DE102006053390A1 (de) | 2006-11-10 | 2006-11-10 | Verfahren zur Bestimmung einer Molekulargewichtsverteilung in einem Polymer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW200839210A TW200839210A (en) | 2008-10-01 |
| TWI386637B true TWI386637B (zh) | 2013-02-21 |
Family
ID=39144287
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW096142304A TWI386637B (zh) | 2006-11-10 | 2007-11-09 | 測定聚合物中分子重量分佈之方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US7917308B2 (https=) |
| EP (1) | EP1921436A3 (https=) |
| JP (1) | JP2008157922A (https=) |
| KR (1) | KR20080042742A (https=) |
| CN (1) | CN101178348A (https=) |
| DE (1) | DE102006053390A1 (https=) |
| TW (1) | TWI386637B (https=) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101458246B (zh) * | 2009-01-08 | 2012-01-11 | 浙江大学 | 测量线形聚合物分子量分布的方法 |
| CN102466604B (zh) * | 2010-11-04 | 2013-07-31 | 中国石油天然气股份有限公司 | 聚乙烯分子量的测定方法 |
| MY177937A (en) * | 2013-10-16 | 2020-09-28 | Arlanxeo Deutschland Gmbh | Determination of the degree of branching |
| DE102014213850B4 (de) * | 2014-07-16 | 2018-01-18 | Bayerische Motoren Werke Aktiengesellschaft | Verfahren und Vorrichtung zum Bestimmen von Werkstoffeigenschaften |
| CN105675440A (zh) * | 2014-11-20 | 2016-06-15 | 中国石油天然气股份有限公司 | 快速确定纤维型聚丙烯专用料分子量分布的检测方法 |
| WO2017161292A1 (en) * | 2016-03-17 | 2017-09-21 | Mohseni Alaeddin | Unified performance test for viscoelastic materials |
| CN105928828A (zh) * | 2016-04-21 | 2016-09-07 | 陈盈洁 | 一种影响油液粘度的颗粒智能识别的方法 |
| KR20210104663A (ko) | 2018-12-17 | 2021-08-25 | 아란세오 도이치란드 게엠베하 | Peg 아크릴레이트-hnbr 공중합체의 생성 공정 |
| KR102246834B1 (ko) * | 2019-08-19 | 2021-04-30 | 에쓰대시오일 주식회사 | 고분자 결정화도의 측정 방법 및 장치 |
| ES2988262T3 (es) * | 2022-02-14 | 2024-11-19 | Borealis Ag | Método y aparato para adaptar ajustes operativos para una medición de barrido de frecuencia de un producto polimérico |
| CN115931807B (zh) * | 2022-12-21 | 2025-08-05 | 南京大学 | 一种采用非辐射能量转移技术实时检测流场中接枝在表面的高分子链构象的方法 |
| EP4406634A1 (en) | 2023-01-30 | 2024-07-31 | Basf Se | A process for size exclusion chromatography of a not fully soluble polymeric substance, and a reference substance for size exclusion chromatography of a polymeric substance |
| TW202540903A (zh) * | 2024-04-03 | 2025-10-16 | 美商陶氏全球科技公司 | 基於流變學之建模來識別線性聚合物之分子量分佈 |
| CN119000428B (zh) * | 2024-08-23 | 2025-10-03 | 中国热带农业科学院农产品加工研究所 | 一种天然橡胶生胶固有分子量分布类型的测试方法 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050244974A1 (en) * | 2004-04-13 | 2005-11-03 | Garcia-Franco Cesar A | High throughput property testing of olefin copolymers using rheological determinations |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02167563A (ja) * | 1988-09-20 | 1990-06-27 | Mitsubishi Kasei Corp | 電子写真トナー |
| JPH05240854A (ja) * | 1991-04-30 | 1993-09-21 | Tonen Corp | ポリプロピレン分子量分布の測定法 |
| US6313241B1 (en) * | 1997-10-01 | 2001-11-06 | Cryovac, Inc. | Narrow molecular weight distribution copolymers containing long chain branches and process to form same |
| JP3918267B2 (ja) * | 1997-12-19 | 2007-05-23 | 株式会社プライムポリマー | ポリオレフィン樹脂組成物、発泡用ポリオレフィン樹脂組成物および発泡体 |
| JPH11327209A (ja) * | 1998-05-18 | 1999-11-26 | Ricoh Co Ltd | 静電荷像現像用トナー |
| JP2001206994A (ja) * | 1999-09-02 | 2001-07-31 | Sumitomo Chem Co Ltd | 熱可塑性エラストマー組成物及び成形体 |
| JP2002178469A (ja) * | 2000-12-11 | 2002-06-26 | Kanegafuchi Chem Ind Co Ltd | 制振性多層フィルム |
| EP1472295B1 (en) * | 2002-02-08 | 2010-03-24 | Exxonmobil Chemical Patents Inc. | Multimodal ethylene, alpha-olefin and diene polymers, processes for making and devices comprising such compositions |
| GB0508255D0 (en) * | 2005-04-25 | 2005-06-01 | Lucite Int Uk Ltd | Acrylic blends |
| KR101031973B1 (ko) * | 2005-10-26 | 2011-04-29 | 캐논 가부시끼가이샤 | 토너 |
-
2006
- 2006-11-10 DE DE102006053390A patent/DE102006053390A1/de not_active Withdrawn
-
2007
- 2007-11-05 EP EP07119997A patent/EP1921436A3/de not_active Withdrawn
- 2007-11-06 US US11/982,912 patent/US7917308B2/en not_active Expired - Fee Related
- 2007-11-09 KR KR1020070114238A patent/KR20080042742A/ko not_active Ceased
- 2007-11-09 JP JP2007292264A patent/JP2008157922A/ja not_active Ceased
- 2007-11-09 TW TW096142304A patent/TWI386637B/zh not_active IP Right Cessation
- 2007-11-12 CN CNA2007101881571A patent/CN101178348A/zh active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050244974A1 (en) * | 2004-04-13 | 2005-11-03 | Garcia-Franco Cesar A | High throughput property testing of olefin copolymers using rheological determinations |
Non-Patent Citations (1)
| Title |
|---|
| M. B. PEIROTTI, Estimation of the molecular weight distribution of linear homopolymer blends from linear viscoelasticity for bimodal and high polydisperse samples, Latin American Applied Research, 2003, Vol. 33, pages 185-194 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101178348A (zh) | 2008-05-14 |
| KR20080042742A (ko) | 2008-05-15 |
| EP1921436A3 (de) | 2011-05-25 |
| TW200839210A (en) | 2008-10-01 |
| US20080162055A1 (en) | 2008-07-03 |
| EP1921436A2 (de) | 2008-05-14 |
| US7917308B2 (en) | 2011-03-29 |
| DE102006053390A1 (de) | 2008-05-15 |
| JP2008157922A (ja) | 2008-07-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Annulment or lapse of patent due to non-payment of fees |