TWI383434B - Method of lifting off and fabricaing array substrate for liquid crystal display device using the same - Google Patents

Method of lifting off and fabricaing array substrate for liquid crystal display device using the same Download PDF

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TWI383434B
TWI383434B TW097127497A TW97127497A TWI383434B TW I383434 B TWI383434 B TW I383434B TW 097127497 A TW097127497 A TW 097127497A TW 97127497 A TW97127497 A TW 97127497A TW I383434 B TWI383434 B TW I383434B
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patterned
layer
line
gate
conductive material
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TW097127497A
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TW200910420A (en
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Hee Young Kwack
Hyun Seok Hong
Joo Soo Lim
Hong Sik Kim
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Lg Display Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/027Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34
    • H01L21/0271Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising organic layers
    • H01L21/0272Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising organic layers for lift-off processes
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/26Processing photosensitive materials; Apparatus therefor
    • G03F7/42Stripping or agents therefor
    • G03F7/422Stripping or agents therefor using liquids only

Description

一種剝離方法與製備液晶顯示器中陣列基板之方法及其裝置Stripping method and method for preparing array substrate in liquid crystal display and device thereof

本發明係關於一種液晶顯示器,特別是有關於一種剝離方法及一種利用剝離方法來製備液晶顯示器(liquid crystal display device;LCD)之陣列基板之方法,進而防止影像品質之降低。The present invention relates to a liquid crystal display, and more particularly to a peeling method and a method for preparing an array substrate of a liquid crystal display device (LCD) by using a lift-off method, thereby preventing degradation of image quality.

液晶顯示器係利用液晶分子之非等向光學特性(optical anisotropy)及極化特性。由於液晶分子為薄長的形狀,所以其具有一特定配位方向(alignment direction),並且可藉由電場的施加來控制液晶分子的配位方向。換言之,當電場強度或方向改變時,液晶分子的配位方向則會跟著改變。由於液晶分子之非等向光學特性,所以當入射光經過液晶分子會產生折射,藉由控制光穿透率來顯示影像。Liquid crystal displays utilize the optical anisotropy and polarization characteristics of liquid crystal molecules. Since the liquid crystal molecules have a thin and long shape, they have a specific alignment direction, and the coordination direction of the liquid crystal molecules can be controlled by application of an electric field. In other words, when the electric field strength or direction changes, the coordination direction of the liquid crystal molecules changes. Due to the non-isotropic optical properties of the liquid crystal molecules, the incident light passes through the liquid crystal molecules to cause refraction, and the image is displayed by controlling the light transmittance.

液晶顯示器具有一作為開關元件之薄膜電晶體(thin film transistor;TFT),意指此液晶顯示器為一主動陣列型液晶顯示器(AM-LCD)。由於主動陣列型液晶顯示器具有高解析度與顯示動態影像之優良特性,所以其用途相當廣泛。The liquid crystal display has a thin film transistor (TFT) as a switching element, which means that the liquid crystal display is an active array type liquid crystal display (AM-LCD). Since the active array type liquid crystal display has high resolution and excellent characteristics for displaying moving images, its use is quite extensive.

第1圖為習知液晶顯示器陣列基板之平面示意圖。在第1圖中,畫素電極與共用電極皆設置在陣列基板上。此可能為共面轉換液晶顯示器(in-plane switching mode LCD device)。FIG. 1 is a schematic plan view of a conventional liquid crystal display array substrate. In Fig. 1, the pixel electrode and the common electrode are both disposed on the array substrate. This may be an in-plane switching mode LCD device.

如第1圖所示,陣列基板10包含顯示區DR及設置於顯示區DR週邊之非顯示區NDR。顯示區DR係為顯示影像的區域,且 係依液晶分子排列之改變而定。閘極線20與資料線30互相交錯,以定義出複數個畫素區。其次,共用線(common lines)50係形成於陣列基板10上,且共用線50與閘極線平行且以一距離分隔開。在非顯示區NDR,透過共用連接線70,提供共用線50一共用訊號。As shown in FIG. 1, the array substrate 10 includes a display area DR and a non-display area NDR provided around the display area DR. The display area DR is an area in which an image is displayed, and It depends on the change in the arrangement of the liquid crystal molecules. The gate line 20 and the data line 30 are interleaved to define a plurality of pixel regions. Next, common lines 50 are formed on the array substrate 10, and the common line 50 is parallel to the gate lines and separated by a distance. In the non-display area NDR, the common line 50 is supplied with a common signal through the common connection line 70.

倘若共用連接線70係與閘極線20於同一層所形成,則閘極線20之間則存在短路的問題。因此,共用連接線70需與資料線30於同一層所形成。共用連接線70透過共用接觸窗(common contact hole;CMH)而連接共用線50。If the common connection line 70 is formed in the same layer as the gate line 20, there is a problem of short circuit between the gate lines 20. Therefore, the common connection line 70 needs to be formed in the same layer as the data line 30. The common connection line 70 is connected to the common line 50 through a common contact hole (CMH).

在每一畫素區則設置有畫素電極(未繪示)、共用電極(未繪示)及薄膜電晶體T。畫素電極(未繪示)與共用電極(未繪示)則交互設置。薄膜電晶體T設置在閘極線20與資料線30之交界處,且其具有閘極電極、半導體層、源極電極及汲極電極。其中,閘極電極係自閘極線20延伸,源極電極則自資料線30延伸,而汲極電極則與源極電極相距一定距離。A pixel electrode (not shown), a common electrode (not shown), and a thin film transistor T are disposed in each pixel region. A pixel electrode (not shown) is alternately disposed with a common electrode (not shown). The thin film transistor T is disposed at the boundary between the gate line 20 and the data line 30, and has a gate electrode, a semiconductor layer, a source electrode, and a drain electrode. The gate electrode extends from the gate line 20, the source electrode extends from the data line 30, and the drain electrode is at a distance from the source electrode.

閘極墊42係設置於閘極線20之末端,而資料墊44則設置於資料線30之末端,閘極墊42與資料墊44分別透過閘捲帶式封裝(tape carrier package;TCP)與資料捲帶式封裝,而連接閘閘驅動單元(未繪示)與資料驅動單元(未繪示)。此外,雖然第1圖未繪示,靜電保護電路線(static electricity protecting circuit line)與各種訊號線係設置於非顯示區。The gate pad 42 is disposed at the end of the gate line 20, and the data pad 44 is disposed at the end of the data line 30, and the gate pad 42 and the data pad 44 are respectively passed through a tape carrier package (TCP) and The data is tape-and-reel package, and the gate drive unit (not shown) and the data drive unit (not shown) are connected. In addition, although not shown in FIG. 1, a static electricity protecting circuit line and various signal lines are disposed in the non-display area.

共用連接線70會將共用訊號產生單元所產生的共用訊號,轉換至共用線50。因此共用連接線70比每一共用線50具有較寬的線寬。The shared connection line 70 converts the shared signal generated by the shared signal generating unit to the shared line 50. Therefore, the common connection line 70 has a wider line width than each of the common lines 50.

換句話說,為了減少罩幕製程而衍生出一種剝離方法。然而,由於各種訊號線與圖案化金屬,例如共用連接線70、閘極墊42、資料墊44、靜電保護電路線(未繪示)、用於偵測短路問題之多圖案化檢查線(multi pattern search line;MPS)及輔助線(dummy line)等,具有相對較大的線寬,所以在剝離製程中會產生許多問題。特別是,因為在移除圖案化光阻時所使用的剝離液(stripper)並不會滲透到上述訊號線與圖案化金屬之中間部位,所以無法完全移除掉不需要的圖案化光阻。In other words, a stripping method is derived to reduce the masking process. However, due to various signal lines and patterned metal, such as the common connection line 70, the gate pad 42, the data pad 44, the electrostatic protection circuit line (not shown), and the multi-patterned inspection line for detecting the short circuit problem (multi Pattern search line; MPS) and dummy lines have a relatively large line width, so many problems occur in the stripping process. In particular, since the stripper used in removing the patterned photoresist does not penetrate into the middle of the signal line and the patterned metal, the unnecessary patterned photoresist cannot be completely removed.

前述問題如接下來的圖式之說明解釋。第2圖,係第1圖之A部分的局部放大圖。第3A-3C圖,係第2圖沿著線段III-III之剖面製程示意圖。第2圖與第3A-3C圖中顯示出當共同連接線,當訊號線與金屬線發生問題時,例如,位於非顯示區之閘極墊電極、資料墊電極、靜電保護電路線(未繪示)、多圖案化檢查線(MPS)及輔助線(dummy line)。The foregoing problems are explained in the description of the following figures. Fig. 2 is a partially enlarged view of a portion A of Fig. 1. Figure 3A-3C is a schematic view of the cross-sectional process along line III-III in Figure 2. Figure 2 and Figure 3A-3C show the common connection line. When there is a problem with the signal line and the metal line, for example, the gate pad electrode, the data pad electrode, and the electrostatic protection circuit line in the non-display area (not drawn) Show), multi-patterned inspection line (MPS) and dummy line.

第2圖中之共同連接線70係以剝離製造方法所形成的。由於用於剝離方法中的剝離液容易地滲入到共同連接線70中的感光圖案化之邊緣部分D與E中,所以,則能完全地移除感光圖案化。其中,前述的感光圖案化例如為圖案化光阻。不過,剝離液卻不 容易滲入到中間部分F。接著,感光層與感光圖案化較佳係分別為PR層與PR圖案化。因此,在剝離製程之後,仍餘留有感光圖案化。剩下的感光圖案化則會對接下來的製程或影像顯示品質,造成嚴重影響。而且,當具有相對大的線寬時,則此問題會更為嚴重。The common connection line 70 in Fig. 2 is formed by a peeling manufacturing method. Since the stripping liquid used in the stripping method easily penetrates into the photosensitive patterned edge portions D and E in the common connecting line 70, the photosensitive patterning can be completely removed. The aforementioned photosensitive patterning is, for example, a patterned photoresist. However, the stripping solution is not Easy to penetrate into the middle part F. Next, the photosensitive layer and the photosensitive patterning are preferably patterned by the PR layer and the PR, respectively. Therefore, after the stripping process, photosensitive patterning remains. The remaining sensitization patterning will have a serious impact on the quality of the subsequent process or image display. Moreover, this problem is more serious when there is a relatively large line width.

接下來,將會更仔細說明剝離方法中所產生的問題。如第3A圖所示,於基板10上形成一閘絕緣層145。在非顯示區(NDR)中,閘絕緣層145上形成一金屬層60與一圖案化光阻82,此圖案化光阻82係相對部分的金屬層60而形成於金屬層60上。Next, the problems that arise in the stripping method will be explained more closely. As shown in FIG. 3A, a gate insulating layer 145 is formed on the substrate 10. In the non-display area (NDR), a metal layer 60 and a patterned photoresist 82 are formed on the gate insulating layer 145. The patterned photoresist 82 is formed on the metal layer 60 by a portion of the metal layer 60.

接著,如第3B圖所示,利用圖案化光阻82作為蝕刻罩幕,蝕刻金屬層60,並且暴露出部分的閘絕緣層45。由於過蝕科金屬層60,所以圖案化光阻82之寬度較共同線70之寬度大。而後,一薄膜層50,例如保護層,係形成於圖案化光阻82與暴露的閘絕緣層45上。如前所述,由於過蝕刻之故,圖案化光阻82具有比共同線70較寬的寬度,所以介於圖案化光阻82與共同線70間之薄膜層50的邊緣部分為不連續。Next, as shown in FIG. 3B, the metal layer 60 is etched using the patterned photoresist 82 as an etch mask, and a portion of the gate insulating layer 45 is exposed. Due to the etched metal layer 60, the width of the patterned photoresist 82 is greater than the width of the common line 70. A thin film layer 50, such as a protective layer, is then formed over the patterned photoresist 82 and the exposed gate insulating layer 45. As described above, the patterned photoresist 82 has a wider width than the common line 70 due to over-etching, so that the edge portion of the thin film layer 50 between the patterned photoresist 82 and the common line 70 is discontinuous.

隨後,如第3C圖所示,剝離液會滲透到薄膜層50的不連續的部份中,以進行剝離方法。此時,則能同時移除圖案化光阻82以及位於圖案化光阻82上之薄膜層50。在此例子中,因為剝離液容易滲透到共同線之邊緣部分D與E中,所以,在邊緣部分D與E之圖案化光阻82與位於圖案化光阻82的薄膜層50,則能完全 被移除掉。然而,剝離液不容易滲透到共同線70之中間部分F中,因此,幾乎無移除掉位於中間部分F之圖案化光阻82以及其上的薄膜層50。剩餘的圖案化光阻82則會造成嚴重的影響。Subsequently, as shown in Fig. 3C, the stripping liquid penetrates into the discontinuous portion of the film layer 50 to perform the peeling method. At this time, the patterned photoresist 82 and the thin film layer 50 on the patterned photoresist 82 can be removed at the same time. In this example, since the stripping liquid easily penetrates into the edge portions D and E of the common line, the patterned photoresist 82 at the edge portions D and E and the film layer 50 at the patterned photoresist 82 can be completely Was removed. However, the stripping liquid does not easily penetrate into the intermediate portion F of the common line 70, and therefore, the patterned photoresist 82 located at the intermediate portion F and the film layer 50 thereon are hardly removed. The remaining patterned photoresist 82 can have a severe impact.

換言之,在陣列基板上具有第一到第四個非顯示區域。例如,分別位於第一與第二非顯示區域之閘極墊與資料墊。當位於第三與第四區域上形成畫素電極之材料層時,則會產生許多如相鄰畫素區的短路與腐蝕之問題。然而,因為非顯示區域具有相對大的線寬,所以,會餘留圖案化光阻與畫素電極之材料層,進而降低影像顯示的品質。In other words, there are first to fourth non-display areas on the array substrate. For example, the gate pad and the data pad are respectively located in the first and second non-display areas. When the material layers of the pixel electrodes are formed on the third and fourth regions, many problems such as short circuit and corrosion of adjacent pixel regions are generated. However, since the non-display area has a relatively large line width, the material layer of the patterned photoresist and the pixel electrode is left, thereby degrading the quality of the image display.

因此,本發明提供一種剝離方法以及一種能解決因限制與先前技術之缺點所致之一或多個問題之方法,來製備液晶顯示器之陣列基板的方法。Accordingly, the present invention provides a method of stripping and a method of fabricating an array substrate for a liquid crystal display that solves one or more of the problems due to limitations and disadvantages of the prior art.

關於本發明其他的特徵及優點,將簡述說明如下。在詳細說明與權利範圍及附加的圖式中,透過結構說明進而實現且達到本發明之目的與其他優點。Other features and advantages of the present invention will be briefly described below. The objectives and other advantages of the invention will be realized and at the

為了達到本發明之功效,如此中所述,本發明為一種剝離方法,係包含於基板上形成第一材料層;於第一材料層上形成具有一第一與第二孔洞之圖案化光阻;利用圖案化光阻作為圖案化罩幕,圖案化第一材料層,以形成一具有第一與第二溝槽之圖案化材料,第一溝槽與第二溝槽係分別相對第一孔洞與第二孔洞;於 具有圖案化光阻與第一、第二溝槽之基板的完整表面上形成第二材料層;同時移除圖案化光阻上的圖案化光阻與第二材料層,其中位於第一與第二溝槽間之部分圖案化材料,以及位於第一與第二溝槽側邊之部分圖案化材料,整體看來係構成一線。In order to achieve the effects of the present invention, the present invention is a stripping method comprising forming a first material layer on a substrate; forming a patterned photoresist having a first and second holes on the first material layer. Using patterned photoresist as a patterned mask, patterning the first material layer to form a patterned material having first and second trenches, the first trench and the second trench respectively being opposite to the first hole With the second hole; Forming a second material layer on the entire surface of the substrate having the patterned photoresist and the first and second trenches; simultaneously removing the patterned photoresist and the second material layer on the patterned photoresist, wherein the first and the first A portion of the patterned material between the two trenches, and a portion of the patterned material on the sides of the first and second trenches, as a whole, form a line.

在本發明之另一實施例中,為一種製造液晶顯示器之陣列基板的方法,係包含於基板上形成一閘極線與閘電極,基板包含一顯示區與位於顯示區周圍之第一至第四非顯示區;閘電極係設置於顯示區;形成資料線、資料墊、半導體層、源極電極與汲極電極,資料線與閘極線交錯設置,資料墊設置於資料線之一末端且係位於第一非顯示區上,半導體層係設置於閘電極上,源極電極連接該資料線且係設置於半導體層上,汲極電極與該源極電極區隔開且設置於半導體層上;於具有資料線、資料墊、源極電極與汲極電極之基板的完整表面上形成一絕緣材料層;形成一第一圖案化光阻與一第二圖案化光阻,第一圖案化光阻係相對源極與汲極電極,第二圖案化光阻具有第一與第二孔洞,第一圖案化光阻暴露一部份之汲極電極,第一與第二孔洞分別對應資料墊之第一與第二部分;以第一與第二圖案化光阻為圖案罩幕,圖案化絕緣材料層,以形成一保護層與一第一圖案化保護層,保護層暴露出部分之汲極電極,第一圖案化保護層具有第一與第二溝槽,第一與第二溝槽分別暴露出資料墊之第一與第二部分;於具有第一與第二圖案化光阻、保護層及第一圖案化保護層之基板的一完整表 面上,形成一導電材料層;以及,以剝離方法同時移除位於第一與第二圖案化光阻上之第一與第二圖案化光阻及導電材料層。In another embodiment of the present invention, a method for fabricating an array substrate of a liquid crystal display includes forming a gate line and a gate electrode on the substrate, the substrate including a display area and first to first regions located around the display area Four non-display areas; the gate electrode is disposed in the display area; forming a data line, a data pad, a semiconductor layer, a source electrode and a drain electrode, the data line and the gate line are alternately arranged, and the data pad is disposed at one end of the data line and The semiconductor layer is disposed on the gate electrode, the source electrode is connected to the data line and is disposed on the semiconductor layer, and the drain electrode is spaced apart from the source electrode region and disposed on the semiconductor layer Forming an insulating material layer on a complete surface of the substrate having the data line, the data pad, the source electrode and the drain electrode; forming a first patterned photoresist and a second patterned photoresist, the first patterned light The first patterned photoresist has first and second holes, the first patterned photoresist exposes a portion of the drain electrode, and the first and second holes respectively correspond to the data pad First And a second portion; patterning the insulating material layer with the first and second patterned photoresist as a pattern mask to form a protective layer and a first patterned protective layer, the protective layer exposing a portion of the drain electrode, The first patterned protective layer has first and second trenches, the first and second trenches respectively exposing the first and second portions of the data pad; and having the first and second patterned photoresists, the protective layer and a complete table of the substrate of the first patterned protective layer Forming a layer of conductive material on the surface; and simultaneously removing the first and second patterned photoresist and conductive material layers on the first and second patterned photoresists by a lift-off method.

在本發明之另一實施例中,為一種液晶顯示器之陣列基板之製備方法,係包含於基板上形成一閘極線與一閘極墊,閘極墊設置於閘極線之一末端;依序形成一閘絕緣層、一本質非晶矽層、一雜質摻雜非晶矽層及一金屬層於基板之一完整表面上,基板上包含閘極線與閘極墊;圖案化金屬層、雜質摻雜非晶矽層、本質非晶矽層及閘絕緣層,以暴露出閘極墊及形成與閘極線交錯之一資料線,進而定義一畫素區與位於資料線一末端之一資料墊;於基板具有資料線與資料墊之完整表面上形成一導電材料層;形成一第一圖案畫光阻與一第二圖案畫光阻,圖案畫光阻包含複數個第一與第二孔洞,第二圖案畫光阻包含複數個第三與第四孔洞,第一與第二孔洞分別對應閘極墊之第一與第二部分,第三與第四孔洞分別對應資料墊之第三與第四部分;以第一與第二圖案化光阻作為罩幕,圖案化導電材料層,以形成一第一圖案化導電材料與一第二圖案化導電材料,第一圖案化導電材料具有複數個第一與第二溝槽,第二圖案化導電材料具有複數個第三與第四溝槽,第一與第二溝槽分別暴露閘極墊之第一與第二部分,第三與第四溝槽分別暴露資料墊之第三與第四部分;於具有第一、第二圖案化光阻及第一、第二、第三與第四溝槽之基板的一完整表面上,形成一保護層;以剝離製程,同時移除該第一、該第二圖案化光 阻及位於其上之保護層。In another embodiment of the present invention, a method for fabricating an array substrate of a liquid crystal display includes forming a gate line and a gate pad on the substrate, and the gate pad is disposed at one end of the gate line; Forming a gate insulating layer, an intrinsic amorphous germanium layer, an impurity doped amorphous germanium layer and a metal layer on a complete surface of the substrate, the substrate comprising a gate line and a gate pad; a patterned metal layer, The impurity is doped with an amorphous germanium layer, an intrinsic amorphous germanium layer and a gate insulating layer to expose the gate pad and form a data line interlaced with the gate line, thereby defining a pixel region and one end of the data line a data pad; forming a conductive material layer on the entire surface of the substrate having the data line and the data pad; forming a first pattern drawing photoresist and a second pattern drawing photoresist, and the pattern drawing photoresist comprises a plurality of first and second The hole, the second pattern drawing photoresist comprises a plurality of third and fourth holes, the first and second holes respectively corresponding to the first and second portions of the gate pad, and the third and fourth holes respectively correspond to the third of the data pads And the fourth part; patterning with the first and second Blocking as a mask, patterning a layer of conductive material to form a first patterned conductive material and a second patterned conductive material, the first patterned conductive material having a plurality of first and second trenches, and a second patterning The conductive material has a plurality of third and fourth trenches, the first and second trenches respectively exposing the first and second portions of the gate pad, and the third and fourth trenches respectively exposing the third and fourth portions of the data pad a portion; forming a protective layer on a complete surface of the substrate having the first and second patterned photoresists and the first, second, third, and fourth trenches; and removing the first The second patterned light Blocks the protective layer located on it.

有關本發明的特徵與實作,茲配合圖示作實施例詳細說明如下。The features and implementations of the present invention are described in detail below with reference to the accompanying drawings.

以下將以圖式與詳細說明本案之較佳實施例。The preferred embodiment of the present invention will be described in detail below with reference to the drawings.

第4圖,係本發明之一實施例之包含溝槽之線的部分平面示意圖。第5A-5C圖,係於第4圖沿著線段V-V之剖面製程示意圖。Figure 4 is a partial plan view showing a line containing a groove in an embodiment of the present invention. Figure 5A-5C is a schematic view of the cross-section process along line V-V in Figure 4.

如第4圖所示,線170上形成複數個第一溝槽172與複數個第二溝槽174。每一第一溝槽172與第二溝槽174為條狀或長方形。線170可以為共同連接線、閘極墊、資料墊、靜電保護電路線、MPS線及輔助線(dummy line)的其中之一。線170具有相對較寬的線寬。例如,線170具有大於約200微米之線寬。第一構槽172係排列在第一列且彼此互相隔開。第二溝槽174係排列在第二列且彼此互相隔開。於藉由剝離方法製造線170之後,則能完全移除線170中間部分之圖案化保護層或圖案化光阻。然而,在遠離介於第一溝槽172與第二溝槽174間之一部份的地方,會殘留圖案化保護152與156(或圖案化光阻)。更詳細的說明如下,並且請同時參照第5A-5C圖。As shown in FIG. 4, a plurality of first trenches 172 and a plurality of second trenches 174 are formed on line 170. Each of the first trenches 172 and the second trenches 174 is strip-shaped or rectangular. The line 170 may be one of a common connection line, a gate pad, a data pad, an electrostatic protection circuit line, an MPS line, and a dummy line. Line 170 has a relatively wide line width. For example, line 170 has a line width greater than about 200 microns. The first grooving grooves 172 are arranged in the first row and spaced apart from each other. The second trenches 174 are arranged in the second column and are spaced apart from each other. After the line 170 is fabricated by the lift-off method, the patterned protective layer or patterned photoresist of the intermediate portion of the line 170 can be completely removed. However, away from a portion between the first trench 172 and the second trench 174, patterned guards 152 and 156 (or patterned photoresist) may remain. A more detailed explanation is as follows, and please refer to the 5A-5C drawing at the same time.

如第5A圖所示,於基板100上形成第一材料層175。隨後,於第一材料層175上形成一光阻層180。考慮其他情況,可利用沉積具有氧化矽與氮化矽其中之一的無機絕緣材料,於基板100與 第一材料層175之間而形成一閘極絕緣層(未繪示)。第一材料層175可以為透明導電材料之第一層與透明導電金屬材料之第二層的至少其中之一。透明導電材料之第一層可以為銦錫氧化物(ITO)或銦鋅氧化物(IZO)。導電金屬材料之第二層可以為銅(Cu)、鉬(Mo)、鈦鉬合金(Mo-Ti)、鋁(Al)、鋁合金或鉻(Cr)。第5A圖顯示第一材料層175包含形成於其上之光阻層180。As shown in FIG. 5A, a first material layer 175 is formed on the substrate 100. Subsequently, a photoresist layer 180 is formed on the first material layer 175. Considering other cases, an inorganic insulating material having one of yttrium oxide and tantalum nitride may be deposited on the substrate 100 A gate insulating layer (not shown) is formed between the first material layers 175. The first material layer 175 may be at least one of a first layer of a transparent conductive material and a second layer of a transparent conductive metal material. The first layer of transparent conductive material may be indium tin oxide (ITO) or indium zinc oxide (IZO). The second layer of conductive metal material may be copper (Cu), molybdenum (Mo), titanium molybdenum alloy (Mo-Ti), aluminum (Al), aluminum alloy or chromium (Cr). Figure 5A shows that the first material layer 175 comprises a photoresist layer 180 formed thereon.

接著,於光阻層180上設置一罩幕190,此罩幕190具有互相交錯排列之一透明區(transmissive area;TA)及阻障區(blocking area;BA)。考慮其他種可能的情況,亦可用一半色調(half-tone)罩幕,此半色調罩幕不僅可以具有透明區與阻障區,亦可具有一半透明區(half-transmissive area)。Next, a mask 190 is disposed on the photoresist layer 180. The mask 190 has a transmissive area (TA) and a blocking area (BA) interlaced with each other. Considering other possible situations, a half-tone mask can be used. The halftone mask can have not only a transparent region and a barrier region but also a half-transmissive area.

接著,如第5B圖所示,透過罩幕190而曝光光阻層180並且顯影。因此,較佳地移除相對於半透明區TA之光阻層180,進而暴露出第一材料層175之一部份。相對於阻障區BA之光阻層180仍餘留於第一材料層175之上,以形成第一至第三圖案化光阻182、184、186。Next, as shown in FIG. 5B, the photoresist layer 180 is exposed through the mask 190 and developed. Therefore, the photoresist layer 180 with respect to the translucent area TA is preferably removed, thereby exposing a portion of the first material layer 175. The photoresist layer 180 with respect to the barrier region BA remains on the first material layer 175 to form first to third patterned photoresists 182, 184, 186.

隨後,暴露出來的第一材料層175則透過第一至第三圖案化光阻182、184及186來圖案化,進而形成第一至第三圖案化線170a、170b及170c。再者,介於第一與第二圖案化線170a、170b間的第一部份係定義為第一溝槽172,而介於第二與第三圖案化線170b、170c間的第二部份係定義為第二溝槽174。第一至第三圖 案化線170a、170b及170c之末端部分係互相連接,以形成一線170。在此實施例中,第一材料層175係過蝕刻,如此一來,第一至第三圖案化光阻182、184、186之寬度則分別比第一至第三圖案化線170a、170b及170c之寬度大。前述係指一底切(undercut)結構。Subsequently, the exposed first material layer 175 is patterned through the first to third patterned photoresists 182, 184, and 186 to form first to third patterned lines 170a, 170b, and 170c. Furthermore, the first portion between the first and second patterned lines 170a, 170b is defined as a first trench 172 and the second portion between the second and third patterned lines 170b, 170c The part is defined as a second groove 174. First to third The end portions of the case lines 170a, 170b, and 170c are interconnected to form a line 170. In this embodiment, the first material layer 175 is over-etched, such that the widths of the first to third patterned photoresists 182, 184, 186 are respectively greater than the first to third patterned lines 170a, 170b and The width of 170c is large. The foregoing refers to an undercut structure.

如第4圖所示,第一與第二溝槽172、174相對應之一部份,此線係在線170之寬度W間移除掉,以便於提高剝離方法的特性。考慮線170之電器特性,第一與第二圖案化溝槽172、174係互相分隔開,第一與第二溝槽172、174係互相平行,且分別排列於第一與第二列。其次,相鄰的兩溝槽具有相同距離。由於第一與第二溝槽172、174,於剝離方法中所使用的剝離液容易地滲入到第一與第二溝槽172、174中。As shown in FIG. 4, one of the first and second trenches 172, 174 is removed from the width W of the line 170 to facilitate the characteristics of the stripping method. Considering the electrical characteristics of the line 170, the first and second patterned grooves 172, 174 are spaced apart from each other, and the first and second grooves 172, 174 are parallel to each other and are arranged in the first and second columns, respectively. Second, the adjacent two grooves have the same distance. Due to the first and second grooves 172, 174, the stripping liquid used in the peeling method easily penetrates into the first and second grooves 172, 174.

此後,於具有第一至第三圖案化光阻182、184、186之基板100上,形成第二材料層150。第二材料層150係由至少其中之一透明導電材料、導電金屬材料及一保護層所形成。透明導電材料可以為ITO或IZO。導電金屬材料可以為銅(Cu)、鉬(Mo)、鈦鉬合金(Mo-Ti)、鋁(Al)、鋁合金或鉻(Cr)。保護層可以為有機絕緣材料或無機絕緣材料。舉例來說,保護層可以由氧化矽或氮化矽所組成。第二材料層150係利用濺鍍方法而沉澱。Thereafter, on the substrate 100 having the first to third patterned photoresists 182, 184, 186, a second material layer 150 is formed. The second material layer 150 is formed of at least one of a transparent conductive material, a conductive metal material, and a protective layer. The transparent conductive material may be ITO or IZO. The conductive metal material may be copper (Cu), molybdenum (Mo), titanium-molybdenum alloy (Mo-Ti), aluminum (Al), aluminum alloy or chromium (Cr). The protective layer may be an organic insulating material or an inorganic insulating material. For example, the protective layer may be composed of tantalum oxide or tantalum nitride. The second material layer 150 is precipitated by a sputtering method.

如上所述,因為第一至第三圖案化光阻182、184、186之寬度,分別比第一至第三圖案化線170a、170b及170c之寬度大, 所以在每一第一至第三圖案化光阻182、184、186以及每一第一至第三圖案化線170a、170b及170c彼此間之周圍附近,第一至第三圖案化光阻182、184、186之邊緣部分係暴露在外的。因此,在每一第一至第三圖案化光阻182、184、186以及每一第一至第三圖案化線170a、170b及170c之間所形成第二材料層150係為不連續的。As described above, since the widths of the first to third patterned photoresists 182, 184, and 186 are larger than the widths of the first to third patterned lines 170a, 170b, and 170c, respectively, Therefore, first to third patterned photoresists 182 are in the vicinity of each of the first to third patterned photoresists 182, 184, 186 and each of the first to third patterned lines 170a, 170b, and 170c. The edge portions of 184 and 186 are exposed. Accordingly, the second material layer 150 formed between each of the first to third patterned photoresists 182, 184, 186 and each of the first to third patterned lines 170a, 170b, and 170c is discontinuous.

接著,如第5C圖所示,透過不連續的第二材料層,剝離液會滲透到第一至第三圖案化光阻182、184、186中。然後,第一與第三圖案化光阻182、186及位於其上的第二材料層150則會同時被移除。相對於第一與第二溝槽172、174中之第二材料層150則會殘留其中,以形成第一圖案化材料158。其中,此第二圖案化材料158係位於第一與第二圖案化線170a、170b之間,以及位於第二與第三圖案化線170b、170c之間。Next, as shown in FIG. 5C, the stripping liquid penetrates into the first to third patterned photoresists 182, 184, 186 through the discontinuous second material layer. Then, the first and third patterned photoresists 182, 186 and the second material layer 150 located thereon are simultaneously removed. The second material layer 150 of the first and second trenches 172, 174 may remain therewith to form a first patterned material 158. The second patterned material 158 is located between the first and second patterned lines 170a, 170b and between the second and third patterned lines 170b, 170c.

藉由剝離方法,位於第二圖案化線170b上的第二圖案化光阻184,以及位於第二圖案化光阻184上的第二材料層150則會完全被移除掉。然而,分別位於第一與第三圖案化線170a、170c上之第一與第三圖案化光阻182、186,以及位於第一與第三圖案化光阻182、186上之保護層152、156,則會殘留部分。相較於習知技術,雖然上述剝離方法具有較大的效果,不過前述剝方法仍然存在些許問題。此問題可能係由溝槽的排列結構所導致。By the stripping method, the second patterned photoresist 184 on the second patterned line 170b and the second material layer 150 on the second patterned photoresist 184 are completely removed. However, the first and third patterned photoresists 182, 186 on the first and third patterned lines 170a, 170c, respectively, and the protective layer 152 on the first and third patterned photoresists 182, 186, 156, there will be a part. Although the above peeling method has a large effect compared to the prior art, the aforementioned peeling method still has some problems. This problem may be caused by the arrangement of the grooves.

第6圖,係第4圖中部分H之平面放大示意圖。如第6圖所 示,在剝離方法中,剝離液會沿著箭頭方法而滲透到第一與第二溝槽172、174之邊緣處(於第6圖中,當剝離液滲入到每一邊緣時,此箭頭係指向第一與第二溝槽的角落)。因此,與第一與第二圖案化光阻172、174分隔開來的第一與第三圖案化光阻182、186,會無法完全移除,仍有部分殘留。此現象則對隨後製程以及LCD裝置造成影響。特別是,殘留的圖案化光阻會在研磨一對準層中所使用的研磨料造成損害,如此,則導致線缺陷。其次,殘留的圖案化光阻與液晶分子會產生一化學反應,進而影響影像。Fig. 6 is a plan enlarged view of a portion H in Fig. 4. As shown in Figure 6 It is shown that in the stripping method, the stripping liquid penetrates to the edges of the first and second grooves 172, 174 along the arrow method (in Fig. 6, when the stripping liquid penetrates into each edge, the arrow line is Pointing to the corners of the first and second grooves). Therefore, the first and third patterned photoresists 182, 186 separated from the first and second patterned photoresists 172, 174 may not be completely removed, and some portions remain. This phenomenon has an impact on subsequent processes and LCD devices. In particular, the residual patterned photoresist can cause damage to the abrasive used in grinding an alignment layer, thus causing line defects. Second, the residual patterned photoresist reacts with the liquid crystal molecules to cause a chemical reaction, which in turn affects the image.

以下說明,將以各實施例來解決前述問題。第7圖,係本發明之一實施例中具有溝槽之線的部分平面示意圖。第8圖,係第7圖沿著線段VIII-VIII之剖面製程示意圖。In the following description, the foregoing problems will be solved by the respective embodiments. Figure 7 is a partial plan view showing a line having a groove in an embodiment of the present invention. Figure 8, is a schematic view of the cross-sectional process along line VIII-VIII of Figure 7.

如第7圖所示,複數個第一溝槽273與複數個第二溝槽274係形成於線270上。複數個第三溝槽273係以第(2N-1)欄排列,以彼此分隔開來,而複數個第二溝槽274係以第(2N)欄排列,以彼此分隔開來。其中,前述N為正整數。每一第二溝槽274則對應兩相鄰第一溝槽273之正面部分,而每一第一溝槽273係對應兩相鄰第二溝槽274之一正面部分。線270具有約大於200微米之線寬。由於第7圖之第一與第二溝槽273、274,每個線270的位置係在第一溝槽與第二溝槽273、274的距離,具有相對低的偏移量。因此,則可避免發生剝離方法中而殘留的圖案化光阻之問題。As shown in FIG. 7, a plurality of first trenches 273 and a plurality of second trenches 274 are formed on line 270. The plurality of third grooves 273 are arranged in the (2N-1)th column to be spaced apart from each other, and the plurality of second grooves 274 are arranged in the (2N)th column to be spaced apart from each other. Wherein, the aforementioned N is a positive integer. Each of the second trenches 274 corresponds to a front portion of two adjacent first trenches 273, and each of the first trenches 273 corresponds to a front portion of two adjacent second trenches 274. Line 270 has a line width greater than about 200 microns. Due to the first and second trenches 273, 274 of Figure 7, the position of each line 270 is at a distance from the first trench to the second trench 273, 274, with a relatively low offset. Therefore, the problem of the patterned photoresist remaining in the peeling method can be avoided.

如第7圖所示之線270,係以下列方法所製備。如第8A圖所 示,於基板200上形成一第一材料層260。接著,利用塗佈光阻的方式,於第一材料層260上形成一光阻層280。考慮其他可能的情況,可利用沉積一具有氧化矽與氮化矽其中之一的無機絕緣材料,於基板200與第一材料層260之間,形成一閘絕緣層(未繪示)。第一材料層260可以為透明導電材料之第一層與透明導電金屬材料之第二層的至少其中之一。透明導電材料之第一層可以為銦錫氧化物(ITO)或銦鋅氧化物(IZO)。導電金屬材料之第二層可以為銅(Cu)、鉬(Mo)、鈦鉬合金(Mo-Ti)、鋁(Al)、鋁合金或鉻(Cr)。第8A圖顯示第一材料層260包含形成於其上之光阻層280。Line 270, as shown in Figure 7, was prepared in the following manner. As shown in Figure 8A A first material layer 260 is formed on the substrate 200. Next, a photoresist layer 280 is formed on the first material layer 260 by applying a photoresist. Considering other possible cases, a gate insulating layer (not shown) may be formed between the substrate 200 and the first material layer 260 by depositing an inorganic insulating material having one of yttrium oxide and tantalum nitride. The first material layer 260 may be at least one of a first layer of a transparent conductive material and a second layer of a transparent conductive metal material. The first layer of transparent conductive material may be indium tin oxide (ITO) or indium zinc oxide (IZO). The second layer of conductive metal material may be copper (Cu), molybdenum (Mo), titanium molybdenum alloy (Mo-Ti), aluminum (Al), aluminum alloy or chromium (Cr). Figure 8A shows that the first material layer 260 includes a photoresist layer 280 formed thereon.

接著,於光阻層280上設置一罩幕290,此罩幕290具有互相交錯排列之一透明區(transmissive area;TA)及阻障區(blocking area;BA)。考慮其他種可能的情況,亦可用一半色調(half-tone)罩幕,此半色調罩幕不僅可以具有透明區與阻障區,亦可具有一半透明區(half-transmissive area)。Next, a mask 290 is disposed on the photoresist layer 280. The mask 290 has a transmissive area (TA) and a blocking area (BA) interlaced with each other. Considering other possible situations, a half-tone mask can be used. The halftone mask can have not only a transparent region and a barrier region but also a half-transmissive area.

接著,如第8B圖所示,透過罩幕290而曝光光阻層280並且顯影。因此,可較佳地移除相對於半透明區TA之光阻層280,進而暴露出第一材料層260之一部份,如第8B圖所示。相對於阻障區BA之光阻層280仍餘留於第一材料層260之上,以形成第一至第四圖案化光阻282、284、286、288,如第8B圖所示。Next, as shown in FIG. 8B, the photoresist layer 280 is exposed through the mask 290 and developed. Therefore, the photoresist layer 280 with respect to the translucent area TA can be preferably removed, thereby exposing a portion of the first material layer 260, as shown in FIG. 8B. The photoresist layer 280 with respect to the barrier region BA remains on the first material layer 260 to form first to fourth patterned photoresists 282, 284, 286, 288, as shown in FIG. 8B.

隨後,如第8C圖所示,暴露出來的第一材料層260則透過第一至第四圖案化光阻282、284、286、288來圖案化,進而形成第 一至第二溝槽273、274。分別對應第一圖案化至第四圖案化光阻282、284、286、288之第一至第四圖案化線270a、270b、270c、270d,係互相隔開。第一至第四圖案化線270a、270b、270c、270d之末端部分係互相連接,以形成一線270。介於第一至第四圖案化線270a、270b、270c、270d之間的空間係定義為第一與第二溝槽273、274。Subsequently, as shown in FIG. 8C, the exposed first material layer 260 is patterned through the first to fourth patterned photoresists 282, 284, 286, and 288 to form a first One to second grooves 273, 274. The first to fourth patterned lines 270a, 270b, 270c, and 270d corresponding to the first to fourth patterned photoresists 282, 284, 286, and 288, respectively, are spaced apart from each other. End portions of the first to fourth patterning lines 270a, 270b, 270c, 270d are connected to each other to form a line 270. A space between the first to fourth patterning lines 270a, 270b, 270c, 270d is defined as first and second grooves 273, 274.

第一與第二溝槽273、274相對應之一部份,此線係在線270之寬度W間移除掉,以便於提高剝離方法的特性。第一與第二溝槽273、274係排列成如第7圖。The first and second grooves 273, 274 correspond to a portion of the line 270 which is removed between the widths W of the wires 270 in order to improve the characteristics of the stripping method. The first and second grooves 273, 274 are arranged as shown in Fig. 7.

詳觀之,每一第一與第二溝槽273、274為條狀。第三溝槽273係以第(2N-1)欄排列,以彼此分隔開來,而第二溝槽274係以第(2N)欄排列,以彼此分隔開來(前述N為正整數)。每一第二溝槽274則對應兩相鄰第一溝槽273之正面部分,而每一第一溝槽273係對應兩相鄰第二溝槽274之一正面部分。每一線270的位置係在第一溝槽與第二溝槽273、274的距離,具有相對低的偏移量。因此,剝離方法中所使用的剝離液可以輕易地滲透到線270的一完整區域中之圖案化光阻。考慮線270區域及電器特性的扭曲,則設置第一與第二溝槽273、274。In detail, each of the first and second grooves 273, 274 is strip-shaped. The third grooves 273 are arranged in the (2N-1)th column to be spaced apart from each other, and the second grooves 274 are arranged in the (2N)th column to be separated from each other (the aforementioned N is a positive integer) ). Each of the second trenches 274 corresponds to a front portion of two adjacent first trenches 273, and each of the first trenches 273 corresponds to a front portion of two adjacent second trenches 274. The position of each line 270 is at a distance from the first trench to the second trench 273, 274 with a relatively low offset. Therefore, the stripping liquid used in the stripping method can easily penetrate the patterned photoresist in a complete region of the line 270. The first and second grooves 273, 274 are provided in consideration of the distortion of the line 270 area and electrical characteristics.

在此實施例中,利用等向濕式蝕刻來圖案化第一材料層260。在第一至第四圖案化光阻282、284、286、288之下,過蝕刻第一材料層260,如此,分別相較於第一至第四圖案化線270a、270b、 270c、270d,第一至第四圖案化光阻282、284、286、288則具有較大的線寬。換言之,在每一個第一至第四圖案化光阻282、284、286、288以及第一至第四圖案化線270a、270b、270c、270d彼此間之周圍附近,第一至第四圖案化光阻282、284、286、288的邊緣部分係暴露在外的。在剝離方法中,剝離液會滲入至第一至第四圖案化光阻282、284、286、288暴露的邊緣部分處。In this embodiment, the first material layer 260 is patterned using isotropic wet etching. Under the first to fourth patterned photoresists 282, 284, 286, 288, the first material layer 260 is over-etched, as such, compared to the first through fourth patterned lines 270a, 270b, respectively. 270c, 270d, the first to fourth patterned photoresists 282, 284, 286, 288 have a larger line width. In other words, first to fourth patterning is performed in the vicinity of each of the first to fourth patterned photoresists 282, 284, 286, 288 and the first to fourth patterning lines 270a, 270b, 270c, 270d The edge portions of the photoresists 282, 284, 286, 288 are exposed. In the lift-off method, the stripper may penetrate into the exposed edge portions of the first to fourth patterned photoresists 282, 284, 286, 288.

其後,於具有第一至第四圖案化光阻282、284、286、288之基板上形成第二材料層250。第二材料層250由至少其中之一透明導電材料、導電金屬材料及一保護層所形成。透明導電材料可以為ITO或IZO。導電金屬材料可以為銅(Cu)、鉬(Mo)、鈦鉬合金(Mo-Ti)、鋁(Al)、鋁合金或鉻(Cr)。保護層可以為有機絕緣材料或無機絕緣材料。舉例來說,保護層可以由氧化矽或氮化矽所組成。第二材料層150係利用濺鍍方法而沉澱。特別是,保護層可以由濺鍍方法而沉澱,而非由電漿化學氣相沉積方法而形成。Thereafter, a second material layer 250 is formed on the substrate having the first to fourth patterned photoresists 282, 284, 286, 288. The second material layer 250 is formed of at least one of a transparent conductive material, a conductive metal material, and a protective layer. The transparent conductive material may be ITO or IZO. The conductive metal material may be copper (Cu), molybdenum (Mo), titanium-molybdenum alloy (Mo-Ti), aluminum (Al), aluminum alloy or chromium (Cr). The protective layer may be an organic insulating material or an inorganic insulating material. For example, the protective layer may be composed of tantalum oxide or tantalum nitride. The second material layer 150 is precipitated by a sputtering method. In particular, the protective layer may be precipitated by a sputtering method instead of being formed by a plasma chemical vapor deposition method.

一般而言,液晶顯示器的保護層係藉由電漿化學氣相沉積方法,以無機絕緣材料所沉積而成,然而,因為電漿化學氣相沉積方法需要相對高的溫度,例如高於約350度C,又加上第一至第四圖案化光阻282、284、286、288的耐熱特性約為150度C,所以,利用電漿化學氣相沉積方法會對第一至第四圖案化光阻282、284、286、288造成損害。當以電漿化學氣相沉積方法來沉積保護層時,第一至第四圖案化光阻282、284、286、288會崩塌,且其 會被保護層完全地覆蓋。在此實施例中,因為剝離液部會滲入到第一至第四圖案化光阻282、284、286、288,所以在剝離方法中會產生出許多問題。再者,殘留的圖案化光阻與液晶顯示分子會產生一化學反應,進而產生影像缺陷。為了解決這些問題,以濺鍍方法來沉澱保護層,其操作溫度需小於約150度C。In general, the protective layer of a liquid crystal display is deposited by an inorganic insulating material by a plasma chemical vapor deposition method, however, since the plasma chemical vapor deposition method requires a relatively high temperature, for example, higher than about 350. The degree C, plus the first to fourth patterned photoresists 282, 284, 286, 288 have a heat resistance of about 150 degrees C, so the first to fourth patterns are patterned by the plasma chemical vapor deposition method. Photoresist 282, 284, 286, 288 cause damage. When the protective layer is deposited by a plasma chemical vapor deposition method, the first to fourth patterned photoresists 282, 284, 286, 288 may collapse, and Will be completely covered by the protective layer. In this embodiment, since the peeling liquid portion penetrates into the first to fourth patterned photoresists 282, 284, 286, and 288, many problems occur in the peeling method. Furthermore, the residual patterned photoresist reacts with the liquid crystal display molecules to cause a chemical defect. In order to solve these problems, the protective layer is deposited by sputtering to have an operating temperature of less than about 150 degrees C.

當以溫度小於第一至第四圖案化光阻282、284、286、288耐熱溫度之濺鍍方法來沉澱保護層第二材料層250時,則不會對第一至第四圖案化光阻282、284、286、288產生損害。其次,第二材料層250可以沉積在可饒性基板上,例如塑膠基板。When the protective layer second material layer 250 is deposited by a sputtering method having a temperature lower than the first to fourth patterned photoresists 282, 284, 286, 288, the first to fourth patterned photoresists are not 282, 284, 286, 288 produced damage. Second, the second material layer 250 can be deposited on a reproducible substrate, such as a plastic substrate.

接著,如第8D圖所示,以剝離液於具有第二材料層250與第一至第四圖案化光阻282、284、286、288之基板200上進行剝離製程。因此,一至第四圖案化光阻282、284、286、288及位於其上之第二材料層250則能同時被移除。第二材料層相對第一與第二溝槽273、274則殘留其上,以形成一圖案化材料250。Next, as shown in FIG. 8D, a lift-off process is performed on the substrate 200 having the second material layer 250 and the first to fourth patterned photoresists 282, 284, 286, and 288 with a stripping liquid. Thus, the first to fourth patterned photoresists 282, 284, 286, 288 and the second material layer 250 thereon can be removed simultaneously. The second material layer remains thereon relative to the first and second trenches 273, 274 to form a patterned material 250.

在此實施例中,第一溝槽273與第二溝槽274則可以如第7圖所示排列。也就是說,每一第二溝槽274係對應兩相鄰的第一溝槽273間之一空間。因此,剝離液容易滲入至第一至第四圖案化光阻282、284、286、288之完整部分。亦即,由於第一與第二溝槽273、274係排列如第7圖所示,所以可以改善剝離製程方法之特性。其次,因為圖案化光阻上之材料層係以濺鍍方法而形成,所以在剝離方法中不會產生損害。In this embodiment, the first trench 273 and the second trench 274 may be arranged as shown in FIG. That is, each second trench 274 corresponds to a space between two adjacent first trenches 273. Therefore, the stripping liquid easily penetrates into the entire portions of the first to fourth patterned photoresists 282, 284, 286, and 288. That is, since the first and second grooves 273, 274 are arranged as shown in Fig. 7, the characteristics of the peeling process can be improved. Secondly, since the material layer on the patterned photoresist is formed by a sputtering method, no damage occurs in the peeling method.

第9圖,係第7圖中部分I之放大示意圖。如第9圖所示,在剝離製程方法中,剝離液會沿著箭頭方向,滲透到第一與第二溝槽273、274之邊緣部分(係當剝離液滲入其所有邊緣處時,此箭頭所指向第一與第二溝槽之角落)。因為第一與第二溝槽273、274係交互排列,所以在線270每一區域之第一至第四圖案化光阻282、284、286、288以及第二材料層,可以於剝離製程中容易地移除掉。Figure 9 is an enlarged schematic view of a portion I of Figure 7. As shown in Fig. 9, in the peeling process, the stripping liquid penetrates into the edge portions of the first and second grooves 273, 274 in the direction of the arrow (when the stripping liquid penetrates all the edges thereof), the arrow Pointed to the corners of the first and second grooves). Because the first and second trenches 273, 274 are alternately arranged, the first to fourth patterned photoresists 282, 284, 286, 288 and the second material layer of each region of the line 270 can be easily removed in the stripping process. Remove it.

第4-9圖係顯示第一與第二溝槽為條狀之示意圖。然而,其亦可為其他各種形狀。第10A-10F圖,係本發明之實施例中各溝槽的示意圖。如上所述,在第10A-10F圖中之線370係由訊號線與具有線寬大於約20微米之圖案化金屬其中之一所組成。Figures 4-9 show a schematic view of the first and second grooves being strip-shaped. However, it can also be in various other shapes. 10A-10F are schematic views of the grooves in the embodiment of the present invention. As noted above, line 370 in Figures 10A-10F is comprised of one of a signal line and a patterned metal having a line width greater than about 20 microns.

如第10A圖所示,至少一溝槽371係設置於線370上。溝槽371為鋸齒狀。如第10B圖所示,溝槽372可為交叉狀。兩交叉狀係互為斜線。亦即,溝槽372係在兩線交叉的部分處可為鈍角或銳角。如第10C圖所示,溝槽373可為十字形狀。溝槽373之線係以互相垂角的方式交叉。如第10D圖所示,溝槽374包含第一與第二溝槽線374a、374b,且此溝槽374係為萬字(weathercock shape)之形狀。亦即第一與第二構槽線374a、374b以互相垂角的方式交叉,並且在第一與第二構槽線374a、374b之延伸線上以互相垂直的方式相隔開來。如第10E圖所示,溝槽375中具有一擋牆,此擋牆為圖案化條狀且具有一開口。如第10F圖所示,溝槽 376為一鑽石形狀。在其他實施例中,溝槽可以為三角形、方形或其他形狀等其中之一。溝槽係形成於具有相對大的線寬之線上,以提高剝離製程中的特性。溝槽係以島狀(island shape)設置,以維持線的電器特性。線可以為閘極墊、資料墊、MPS線、靜電保護電路線或輔助線(dummy line)之其中之一。As shown in FIG. 10A, at least one groove 371 is disposed on the line 370. The groove 371 is serrated. As shown in FIG. 10B, the grooves 372 may be cross-shaped. The two intersecting lines are diagonal to each other. That is, the groove 372 may be an obtuse or acute angle at a portion where the two lines intersect. As shown in FIG. 10C, the groove 373 may have a cross shape. The lines of the grooves 373 intersect at a mutually perpendicular angle. As shown in FIG. 10D, the groove 374 includes first and second groove lines 374a, 374b, and the groove 374 is in the shape of a weathercock shape. That is, the first and second groove lines 374a, 374b intersect at a mutually perpendicular angle and are spaced apart from each other perpendicularly on the extension lines of the first and second groove lines 374a, 374b. As shown in FIG. 10E, the groove 375 has a retaining wall which is patterned and has an opening. As shown in Figure 10F, the trench 376 is a diamond shape. In other embodiments, the grooves may be one of a triangle, a square, or other shape. The trench is formed on a line having a relatively large line width to improve characteristics in the lift-off process. The trenches are arranged in an island shape to maintain the electrical properties of the wires. The line may be one of a gate pad, a data pad, an MPS line, an electrostatic protection circuit line, or a dummy line.

因為於剝離製程中所使用的剝離液,可透過溝槽容易地滲入到圖案化光阻中,所以剝離製程中則不存在問題。再者,又因為以具有相對低溫的濺鍍方法,於圖案化光阻上沉積材料層,所以則可避免損害圖案化光阻上。Since the peeling liquid used in the peeling process can easily penetrate into the patterned photoresist through the groove, there is no problem in the peeling process. Moreover, since the material layer is deposited on the patterned photoresist by a sputtering method having a relatively low temperature, damage to the patterned photoresist can be avoided.

接著,則詳細說明利用前述剝離製程來製造液晶顯示器之陣列基板的方法。Next, a method of manufacturing an array substrate of a liquid crystal display by the above-described lift-off process will be described in detail.

第11圖,係本發明之實施例中之液晶顯示器之陣列基板之平面示意圖。第12A-12F圖,係沿著第11圖線段XII-XII之部分剖面結構製程示意圖。第13A-13F圖,係沿著第11圖線段XIII-XIII之部分剖面結構製程示意圖。第14A-14F圖,係沿著第11圖線段XIIV-XIIV之部分剖面結構製程示意圖。Figure 11 is a plan view showing an array substrate of a liquid crystal display device in an embodiment of the present invention. Fig. 12A-12F is a schematic diagram of a part of the cross-sectional structure process along line XII-XII of Fig. 11. Figure 13A-13F is a schematic diagram of a part of the cross-sectional structure process along line XIII-XIII of Figure 11. Figure 14A-14F is a schematic diagram of the process of the section along the line XIIV-XIIV of Figure 11.

如第11圖所示,液晶顯示器之基板410包含一顯示區與非顯示區。非顯示區係設置於畫素區P之顯示區域的周圍。如第11圖所示,非顯示區具有複數個部份,且每一部分具有至少一溝槽。或者,每一部份具有複數個溝槽,且兩相鄰的溝槽互相隔開。前述之部分可以為閘極墊、資料墊、MPS線、靜電保護電路線或輔 助線(dummy line)、輔助部(dummy area)、閘極線或資料線之其中之一。詳言之,閘極線420係形成於陣列基板400之基板410上。資料線440係橫越閘極線420,以定義出畫素區P。薄膜電晶體Tr包含了閘極電極422、半導體層(未繪示)、源極電極442以及汲極電極444,此薄膜電晶體Tr係形成於畫素區P上。畫素電極460連接薄膜電晶體Tr,且亦形成於畫素區P上。閘極電極422與源極電極442係分別連接閘極線420與資料線440,汲極電極444與源極電極442分隔開。畫素電極460係覆蓋圖案化金屬448,且覆蓋閘極線420,以形成儲存電容Cst。圖案化金屬448係電性連接畫素電極460與閘極線420其中之一。As shown in FIG. 11, the substrate 410 of the liquid crystal display includes a display area and a non-display area. The non-display area is disposed around the display area of the pixel area P. As shown in Fig. 11, the non-display area has a plurality of portions, and each portion has at least one groove. Alternatively, each portion has a plurality of grooves and the two adjacent grooves are spaced apart from each other. The foregoing part may be a gate pad, a data pad, an MPS line, an electrostatic protection circuit line or a secondary One of a dummy line, a dummy area, a gate line, or a data line. In detail, the gate line 420 is formed on the substrate 410 of the array substrate 400. The data line 440 is traversed across the gate line 420 to define the pixel area P. The thin film transistor Tr includes a gate electrode 422, a semiconductor layer (not shown), a source electrode 442, and a drain electrode 444, and the thin film transistor Tr is formed on the pixel region P. The pixel electrode 460 is connected to the thin film transistor Tr and is also formed on the pixel region P. The gate electrode 422 and the source electrode 442 are connected to the gate line 420 and the data line 440, respectively, and the drain electrode 444 is separated from the source electrode 442. The pixel electrode 460 covers the patterned metal 448 and covers the gate line 420 to form a storage capacitor Cst. The patterned metal 448 is electrically connected to one of the pixel electrode 460 and the gate line 420.

接觸閘極電極(未繪示)之閘極墊424,係透過閘極墊接觸洞(gate pad contact hole;GPC)設置於閘極線420一端之上;接觸資料墊(未繪示)之資料墊446,係設置於資料線440一端之上。閘極墊424與資料墊446係設置於非顯示區上,且位於畫素區P之顯示區的周圍。The gate pad 424 contacting the gate electrode (not shown) is disposed on one end of the gate line 420 through a gate pad contact hole (GPC); and the data of the contact pad (not shown) The pad 446 is disposed on one end of the data line 440. The gate pad 424 and the data pad 446 are disposed on the non-display area and are located around the display area of the pixel area P.

於非顯示區上,形成第一至第四溝槽HP1、HP2、HP3、HP4。於形成閘極墊424之第一非顯示區上,形成第一溝槽HP1;於形成閘極墊424之第二非顯示區上,形成第二溝槽HP2。在面對第二非顯示區之第三非顯示區上,形成第三溝槽HP3;在面對第一非顯示區之第四非顯示區上,形成第四溝槽HP4。由於第一至第四溝槽HP1、HP2、HP3、HP4,部分材料層可於剝離製程中容易 地被移除掉。在移除部分材料層之過程中,則可定義出畫素電極460。第一至第四溝槽HP1、HP2、HP3、HP4可以為如第4、7及10A-10F圖之形狀。On the non-display area, first to fourth grooves HP1, HP2, HP3, and HP4 are formed. A first trench HP1 is formed on the first non-display region forming the gate pad 424, and a second trench HP2 is formed on the second non-display region forming the gate pad 424. On the third non-display area facing the second non-display area, a third groove HP3 is formed; on the fourth non-display area facing the first non-display area, a fourth groove HP4 is formed. Due to the first to fourth grooves HP1, HP2, HP3, HP4, part of the material layer can be easily removed in the stripping process The ground was removed. The pixel electrode 460 can be defined during the removal of a portion of the material layer. The first to fourth grooves HP1, HP2, HP3, HP4 may have shapes as shown in Figs. 4, 7, and 10A-10F.

陣列基板係以下列製程所製備。第12A-12F圖,係為具有薄膜電晶體之開關區TrA的畫素區P之示意圖。第13A-13F圖,係為形成閘極墊之閘極墊區GPA之示意圖。第14A-14F圖,係為形成資料墊之資料墊區DPA之示意圖。The array substrate was prepared in the following process. 12A-12F is a schematic view of a pixel region P having a switching region TrA of a thin film transistor. Figures 13A-13F are schematic diagrams showing the gate pad area GPA of the gate pad. Figure 14A-14F is a schematic diagram of the data pad area DPA forming the data pad.

如第12A、13A及14D圖所示,係為第一罩幕製程,於基板上,利用至少一銅(Cu)、鉬(Mo)、鈦鉬合金(Mo-Ti)、鋁(Al)、鋁合金或鉻(Cr)沉積第一金屬層(未繪示)。圖案畫第一金屬層,以形成一閘極線(未繪示)、自閘極線延伸到開關區TrA之閘極電極422及於閘極墊區GPA連接閘極線之閘極墊424。接著,於包含閘極線、閘極電極422與閘極墊424之基板上,形成一由氧化矽或氮化矽之閘絕緣層426。As shown in Figures 12A, 13A and 14D, the first mask process is performed on the substrate using at least one of copper (Cu), molybdenum (Mo), titanium-molybdenum alloy (Mo-Ti), aluminum (Al), A first metal layer (not shown) is deposited on the aluminum alloy or chromium (Cr). The first metal layer is patterned to form a gate line (not shown), a gate electrode 422 extending from the gate line to the switching region TrA, and a gate pad 424 connecting the gate line to the gate pad region GPA. Next, on the substrate including the gate line, the gate electrode 422 and the gate pad 424, a gate insulating layer 426 made of tantalum oxide or tantalum nitride is formed.

如第12B、13B及14B圖所示,係顯示第二罩幕製程。如第12B、13B及14B圖所示,於閘絕緣層426上,依序形成本質非晶矽層428、一雜質摻雜非晶矽層430及第二金屬層432。第二金屬層432可以為銅(Cu)、鉬(Mo)、鈦鉬合金(Mo-Ti)、鋁(Al)、鋁合金或鉻(Cr)。於第二金屬層432上形成第一光阻層480,接著,於第一光阻層480上設置一具有透明區TA、半透明區HTA(half-transmissive area)及一阻障區BA之罩幕M。半透明區HTA 之透光度係小於透明區TA之透光度,但大於阻障區BA。半透明區HTA(half-transmissive area)對應閘極電極422之中間部份及閘極墊424之兩側,阻障區BA係對應閘極電極422之兩側與資料墊,而半透明區HTA則係對應其他的部分。第一光阻層480係透過罩幕M而被曝光顯影。As shown in Figures 12B, 13B and 14B, the second mask process is shown. As shown in FIGS. 12B, 13B and 14B, an intrinsic amorphous germanium layer 428, an impurity doped amorphous germanium layer 430 and a second metal layer 432 are sequentially formed on the gate insulating layer 426. The second metal layer 432 may be copper (Cu), molybdenum (Mo), titanium-molybdenum alloy (Mo-Ti), aluminum (Al), aluminum alloy, or chromium (Cr). A first photoresist layer 480 is formed on the second metal layer 432. Then, a mask having a transparent region TA, a half-transmissive area (HTA), and a barrier region BA is disposed on the first photoresist layer 480. Curtain M. Translucent area HTA The transmittance is smaller than the transmittance of the transparent region TA, but larger than the barrier region BA. The half-transmissive area (HTA) corresponds to the middle portion of the gate electrode 422 and the two sides of the gate pad 424. The barrier area BA corresponds to both sides of the gate electrode 422 and the data pad, and the translucent area HTA It corresponds to other parts. The first photoresist layer 480 is exposed and developed through the mask M.

因此,如第12C、13C及14C圖所示,對應阻障區BA之第一圖案畫光阻482a具有第一高度,對應半透明區HTA之第二圖案畫光阻482b則具有第二高度,且第二高度係小於第一高度。換言之,對應透明區TA之第一光阻層480可較佳地被移除掉,以暴露出部分之第二金屬層432。接著,利用第一與第二光阻482a、482b作為圖案化罩幕,依序圖案化暴露出的第二金屬層432與位於其下之雜質摻雜非晶矽層430、本質非晶矽層428及閘絕緣層426。因此,對應畫素區P之部分的基板410會暴露出來,閘極墊424也會透過閘極墊接觸洞GPC而暴露出來。資料墊446係自第二金屬層432形成於資料墊區DPA上。再者,形成一圖案化金屬材料432a、一雜質摻雜非晶矽層430與一本質非晶矽層428。Therefore, as shown in FIGS. 12C, 13C and 14C, the first pattern drawing photoresist 482a corresponding to the barrier area BA has a first height, and the second pattern drawing photoresist 482b corresponding to the translucent area HTA has a second height. And the second height is less than the first height. In other words, the first photoresist layer 480 corresponding to the transparent region TA can be preferably removed to expose a portion of the second metal layer 432. Then, using the first and second photoresists 482a, 482b as patterned masks, sequentially exposing the exposed second metal layer 432 and the impurity-doped amorphous germanium layer 430 underneath, the intrinsic amorphous germanium layer 428 and gate insulating layer 426. Therefore, the substrate 410 corresponding to the portion of the pixel region P is exposed, and the gate pad 424 is also exposed through the gate pad contact hole GPC. A data pad 446 is formed from the second metal layer 432 on the data pad area DPA. Furthermore, a patterned metal material 432a, an impurity doped amorphous germanium layer 430 and an intrinsic amorphous germanium layer 428 are formed.

隨後,如第12D、13D及14D圖所示,於第一與第二圖案化光阻482a、482b上進行灰化(ashing),以移除第二圖案化光阻482b並且自第一圖案化光阻482a第形成三圖案化光阻482c。第三圖案化光阻482c具有高於第一圖案化光阻482a之高度(如第12C與14C圖所示)。移除暴露的金屬材料層432a與位於其下之圖案化雜 質摻雜非晶矽432a,以暴露出部分之圖案化本質非晶矽428a。因此,源極電極442與與其分隔開之汲極電極444係形成於圖案化金屬材料432a上。自圖案化雜質摻雜非晶矽432a而形成毆姆接觸層434b。位於源極電極442與汲極電極444間之圖案化本質非晶矽428a則暴露出來,以定義出一主動層434a。閘極電極422、閘絕緣層426、包含主動層434a與歐姆接觸層434b之半導體層434、源極電極442以及汲極電極444則於開關區TrA,構成電晶體Tr。Subsequently, as shown in FIGS. 12D, 13D and 14D, ashing is performed on the first and second patterned photoresists 482a, 482b to remove the second patterned photoresist 482b and patterned from the first The photoresist 482a first forms a three-patterned photoresist 482c. The third patterned photoresist 482c has a higher height than the first patterned photoresist 482a (as shown in Figures 12C and 14C). Removing the exposed metal material layer 432a from the patterned impurity underneath The amorphous germanium 432a is doped to expose a portion of the patterned intrinsic amorphous germanium 428a. Therefore, the source electrode 442 and the drain electrode 444 spaced apart therefrom are formed on the patterned metal material 432a. The amorphous germanium 432a is doped from the patterned impurity to form the ohmic contact layer 434b. A patterned intrinsic amorphous germanium 428a between source electrode 442 and drain electrode 444 is exposed to define an active layer 434a. The gate electrode 422, the gate insulating layer 426, the semiconductor layer 434 including the active layer 434a and the ohmic contact layer 434b, the source electrode 442, and the drain electrode 444 form a transistor Tr in the switching region TrA.

如第12E-12F、13E-13F及14E-14F圖所示,為第三罩幕製程。如第12E、13E及14E圖所示,移除第三圖案化光阻482c,接著於絕緣材料層(未繪示)上形成絕緣材料層與第四圖案化光阻484。第四圖案化光阻484對應開關區TrA與閘極墊424邊界。在剖面圖中,在閘極墊區GPA之第四圖案化光阻484係互相分隔開來。在開關區Tr之第四圖案化光阻484暴露出汲極電極444之一部份。在閘極墊區GPA中介於相鄰兩第四圖案化光阻484之間的空間則定義出一第一溝槽HP1。此外,第四圖案化光阻484係形成於資料墊446上。於資料墊446上之第四圖案化光阻484係對應資料墊446之中間及其兩邊。介於相鄰兩第四圖案化光阻484之間的空間則定義出一第二溝槽HP2。圖中,部分之第四圖案化光阻看起來像是互相分隔開來。然而,第一與第二溝槽HP1、HP2對應第四圖案化光阻484上之孔洞,如此,在每一區之第四圖案 化光阻484則為一完整體。As shown in Figures 12E-12F, 13E-13F and 14E-14F, it is a third mask process. As shown in FIGS. 12E, 13E, and 14E, the third patterned photoresist 482c is removed, and then an insulating material layer and a fourth patterned photoresist 484 are formed on the insulating material layer (not shown). The fourth patterned photoresist 484 corresponds to the boundary between the switching region TrA and the gate pad 424. In the cross-sectional view, the fourth patterned photoresist 484 in the gate pad region GPA is spaced apart from each other. A fourth patterned photoresist 484 in the switching region Tr exposes a portion of the drain electrode 444. A space between the adjacent two fourth patterned photoresists 484 in the gate pad region GPA defines a first trench HP1. In addition, a fourth patterned photoresist 484 is formed on the data pad 446. The fourth patterned photoresist 484 on the data pad 446 corresponds to the middle of the data pad 446 and its two sides. A space between adjacent two fourth patterned photoresists 484 defines a second trench HP2. In the figure, some of the fourth patterned photoresists appear to be separated from each other. However, the first and second trenches HP1, HP2 correspond to the holes in the fourth patterned photoresist 484, such that the fourth pattern in each region The photoresist 484 is a complete body.

雖然未繪示,不過在面對資料墊區DPA與閘極墊區GPA之非顯示區中,仍具有其他第四圖案化,如此則能於非顯示區中分別定義出第三與第四溝槽。Although not shown, in the non-display area facing the data pad area DPA and the gate pad area GPA, there are still other fourth patterns, so that the third and fourth grooves can be respectively defined in the non-display area. groove.

隨後,以第四圖案化光阻484作為罩幕,藉由圖案化絕緣材料層(未繪示)來形成保護層450。在此實施例中,絕緣材料層(未繪示)係過蝕刻,如此第四圖案化光阻之端部則自保護層450突出。也就是說,第四圖案化光阻484之線寬較保護層450之線寬來得大。其可能為一底切結構。Subsequently, with the fourth patterned photoresist 484 as a mask, the protective layer 450 is formed by patterning a layer of insulating material (not shown). In this embodiment, the insulating material layer (not shown) is over-etched, such that the ends of the fourth patterned photoresist protrude from the protective layer 450. That is to say, the line width of the fourth patterned photoresist 484 is larger than the line width of the protective layer 450. It may be an undercut structure.

隨後,利用一透明導電材料,例如ITO或IZO,在第四圖案化光阻484與保護層450上,沉積以形成透明導電材料層452。如上所述,由於第四圖案化材料484之尾端係自保護層450突出,所以在第四圖案化光阻484與保護層450之周圍,有不連續的透明導電材料層452。當利用溫度高於350度C以上之電漿化學氣相沉積法來沉積透明導電材料層452時,會第四圖案化光阻484造成損害,進而在剝離製程中產生缺陷。因此,透明導電材料層452係利用具有溫度小於150度C之濺鍍法所形成。Subsequently, a transparent conductive material layer 452 is deposited on the fourth patterned photoresist 484 and the protective layer 450 using a transparent conductive material such as ITO or IZO. As described above, since the trailing end of the fourth patterned material 484 protrudes from the protective layer 450, there is a discontinuous layer of transparent conductive material 452 around the fourth patterned photoresist 484 and the protective layer 450. When the transparent conductive material layer 452 is deposited by plasma chemical vapor deposition at a temperature higher than 350 C, the fourth patterned photoresist 484 is damaged, thereby causing defects in the stripping process. Therefore, the transparent conductive material layer 452 is formed by a sputtering method having a temperature of less than 150 degrees C.

其後,以剝離液來進行一剝離製程。剝離液會透過透明導電材料層之不連續結構而滲入到第四圖案化光阻中,如此一來,則可移除掉第四圖案化光阻484與位於其上之透明導電材料層452。在此實施例中,第一與第二溝槽HP1、HP2以及第三與第四 溝槽(未繪示)活化剝離製程。詳言之,在非顯示區之第四圖案化光阻484具有大於約200微米之線寬。因此,如果可利用先前技術之剝離方法來移除第四圖案化光阻484與位於其上之透明導電材料層452,則第四圖案化光阻484與位於其上之透明導電材料層452則無法完整地移除。然而,由於本發明之第一與第二溝槽HP1、HP2以及第三與第四溝槽(未繪示)之故,所以則可以解決先前技術中剝離方法所產生的問題。Thereafter, a stripping process is performed with a stripper. The stripping solution penetrates into the fourth patterned photoresist through the discontinuous structure of the transparent conductive material layer, so that the fourth patterned photoresist 484 and the transparent conductive material layer 452 located thereon can be removed. In this embodiment, the first and second grooves HP1, HP2 and the third and fourth A trench (not shown) activates the strip process. In particular, the fourth patterned photoresist 484 in the non-display area has a line width greater than about 200 microns. Therefore, if the fourth patterned photoresist 484 and the transparent conductive material layer 452 located thereon can be removed by the prior art stripping method, the fourth patterned photoresist 484 and the transparent conductive material layer 452 located thereon Cannot be completely removed. However, due to the first and second grooves HP1, HP2 and the third and fourth grooves (not shown) of the present invention, the problems caused by the peeling method of the prior art can be solved.

由於剝離製程,如第12F、13F與14F圖所示,連接汲極電極444之畫素電極460係形成於畫素區P。構過閘極墊接觸洞GPC而連接閘極墊424之閘極電墊電極462,係形成於閘極墊接觸洞GPC上,連接資料墊446之資料墊電極且對應第二溝槽HP2,係形成於資料墊區DPA。而且,相對第一溝槽HP1之透明導電材料層452係殘留,以形成島狀之第一剝離圖案化452a。雖然未繪示,不過,殘留的透明導電材料層452會形成具有島狀之第四剝離圖案化,且其係形成於資料墊446與面對資料墊區DPA與閘極墊區GPA之非顯示區的周圍。Due to the lift-off process, as shown in FIGS. 12F, 13F, and 14F, the pixel electrode 460 connected to the drain electrode 444 is formed in the pixel region P. The gate pad electrode 462, which is connected to the gate pad contact hole G424 and connected to the gate pad 424, is formed on the gate pad contact hole GPC, and is connected to the data pad electrode of the data pad 446 and corresponds to the second trench HP2. Formed in the data pad area DPA. Further, the transparent conductive material layer 452 with respect to the first trench HP1 remains to form an island-shaped first peeling pattern 452a. Although not shown, the residual transparent conductive material layer 452 forms a fourth peeling pattern having an island shape, and is formed on the data pad 446 and the non-display surface facing the data pad area DPA and the gate pad area GPA. Around the area.

液晶顯示器之陣列基板係以上述方法所製備,並且包含本發明之剝離製程。The array substrate of the liquid crystal display is prepared by the above method and comprises the stripping process of the present invention.

接著為本發明之另一實施例中製備液晶顯示器之陣列基板的方法,此方法亦使用前述的剝離方法。此實施例中所使用的元件符號與前一實施例之第12A-12H、13A-13H及14A-14H圖相似, 簡述如下。Next, a method of preparing an array substrate of a liquid crystal display according to another embodiment of the present invention, which also uses the aforementioned stripping method. The component symbols used in this embodiment are similar to the 12A-12H, 13A-13H, and 14A-14H diagrams of the previous embodiment. Briefly described below.

第15A-15H圖,係為本發明之此實施例中製造一具有開關區之畫素區的方法之剖面示意圖。第16A-16H圖,係為本發明之此實施例中製造閘極墊區的方法之剖面示意圖。第17A-17H圖,係為本發明之此實施例中製造資料墊區的方法之剖面示意圖。15A-15H is a schematic cross-sectional view showing a method of manufacturing a pixel region having a switching region in this embodiment of the present invention. 16A-16H are cross-sectional views showing a method of fabricating a gate pad region in this embodiment of the present invention. 17A-17H is a schematic cross-sectional view showing a method of manufacturing a data pad region in this embodiment of the present invention.

如第15A、16A及17A圖所示,為第一罩幕製程,於基板510上形成第一金屬層(未繪示)。圖案畫第一金屬層,以形成一閘極線(未繪示)、自閘極線延伸到開關區TrA之閘極524電極522及於閘極墊區GPA連接閘極線之閘極墊524。接著,於包含閘極線、閘極電極522與閘極墊524之基板上,形成一閘絕緣層526。As shown in FIGS. 15A, 16A and 17A, for the first mask process, a first metal layer (not shown) is formed on the substrate 510. The first metal layer is patterned to form a gate line (not shown), a gate 524 electrode 522 extending from the gate line to the switching region TrA, and a gate pad 524 connecting the gate line to the gate pad GPA. . Next, a gate insulating layer 526 is formed on the substrate including the gate line, the gate electrode 522, and the gate pad 524.

第15B-15D、16B-16D及17B-17D圖所示,係顯示第二罩幕製程。如第15B、16B及17B圖所示,於閘絕緣層526上,依序形成本質非晶矽層528、一雜質摻雜非晶矽層530及第二金屬層532。於第二金屬層532上形成第一光阻層580,接著,以具有透明區、半透明區(half-transmissive area)及一阻障區之罩幕,圖案化第一光阻層580,以形成具有不同高度之第一與第二圖案化光阻582a、582b。The second mask process is shown in Figures 15B-15D, 16B-16D and 17B-17D. As shown in FIGS. 15B, 16B and 17B, an intrinsic amorphous germanium layer 528, an impurity doped amorphous germanium layer 530 and a second metal layer 532 are sequentially formed on the gate insulating layer 526. Forming a first photoresist layer 580 on the second metal layer 532, and then patterning the first photoresist layer 580 with a mask having a transparent region, a half-transmissive area, and a barrier region, to First and second patterned photoresists 582a, 582b having different heights are formed.

隨後,如第15C、16C及17C圖所示,利用第一與第二光阻582a、582b作為圖案化罩幕,依序圖案化第二金屬層532、雜質摻雜非晶矽層530、本質非晶矽層528及閘絕緣層526。接著,進行灰化製程,以形成第三圖案化光阻582c。藉由第三圖案化光阻 582c而暴露的第二金屬層532、雜質摻雜非晶矽層530、本質非晶矽層528,係利用第三圖案化光阻582c來圖案化,以便在閘極墊524之兩側形成圖案化金屬532a、圖案化雜質摻雜非晶矽530a、圖案化本質非晶矽528a。Subsequently, as shown in FIGS. 15C, 16C and 17C, the first and second photoresists 582a, 582b are used as patterned masks, and the second metal layer 532, the impurity-doped amorphous germanium layer 530, and the essence are sequentially patterned. An amorphous germanium layer 528 and a gate insulating layer 526. Next, an ashing process is performed to form a third patterned photoresist 582c. Third patterned photoresist The exposed second metal layer 532, the impurity doped amorphous germanium layer 530, and the intrinsic amorphous germanium layer 528 are patterned by the third patterned photoresist 582c to form a pattern on both sides of the gate pad 524. The metal 532a, the patterned impurity doped amorphous germanium 530a, and the patterned amorphous amorphous germanium 528a.

因此,如第15D、16D、17D圖所示,圖案化本質非晶矽528a、圖案化雜質摻雜非晶矽530a、圖案化金屬532a堆疊於開關區TrA,而且圖案化本質非晶矽528a、圖案化雜質摻雜非晶矽530a及資料墊546堆疊於資料墊區DPA。Therefore, as shown in FIGS. 15D, 16D, and 17D, the patterned intrinsic amorphous germanium 528a, the patterned impurity doped amorphous germanium 530a, and the patterned metal 532a are stacked on the switching region TrA, and the patterned amorphous germanium 528a, The patterned impurity doped amorphous germanium 530a and the data pad 546 are stacked on the data pad region DPA.

如第15E-15H、16E-16H及17E-17H圖所示,為第三罩幕製程。如第15E、16E及17E圖所示,形成透明導電材料層552,且具有不同高度之第四與第五圖案化材料584a、584b係形成於透明導電材料層552上。As shown in Figures 15E-15H, 16E-16H and 17E-17H, it is a third mask process. As shown in FIGS. 15E, 16E, and 17E, a transparent conductive material layer 552 is formed, and fourth and fifth patterned materials 584a, 584b having different heights are formed on the transparent conductive material layer 552.

隨後,如第15F、16F及17F圖所示,透明導電材料層552、圖案化金屬材料532a及圖案化雜質摻雜非晶矽530a係利用第四與第五圖案化光阻584a、584b來進行圖案化,以形成源極電極542、汲極電極544、於源極電極542與汲極電極544下之毆姆接觸層543b、以及主動層534a。閘極電極522、閘絕緣層526、包含歐姆接觸層534b與主動層534a之半導體層534、源極電極542以及汲極電極544則於開關區TrA,構成電晶體Tr。其後,利用灰化製程,自第四圖案化光阻584a形成第六圖案化光阻584c。在閘極墊524上,位於第六圖案化光阻584c間之空間定義第一溝槽 HP1,在資料墊526上,位於第六圖案化光阻584c間之空間定義第二溝槽HP2。圖中,部分之第六圖案化光阻584c看起來像是互相分隔開來。然而,第一與第二溝槽HP1、HP2對應第六圖案化光阻584c之孔洞,如此,在每一區之第六圖案化光阻584c則為一完整體。透明導電材料層552係利用第六圖案化光阻584c來進行圖案化,以形成一連接汲極電極544之畫素電極560、閘極墊524上之圖案化透明導電材料552a以及資料墊546。在此實施例中,因為透明導電材料層552係過蝕刻,第六圖案化光阻584c則自圖案化透明導電材料552a之尾端突出。Subsequently, as shown in FIGS. 15F, 16F and 17F, the transparent conductive material layer 552, the patterned metal material 532a and the patterned impurity doped amorphous germanium 530a are performed by the fourth and fifth patterned photoresists 584a, 584b. The patterning is performed to form a source electrode 542, a drain electrode 544, a source contact layer 543b under the source electrode 542 and the drain electrode 544, and an active layer 534a. The gate electrode 522, the gate insulating layer 526, the semiconductor layer 534 including the ohmic contact layer 534b and the active layer 534a, the source electrode 542, and the drain electrode 544 form a transistor Tr in the switching region TrA. Thereafter, a sixth patterned photoresist 584c is formed from the fourth patterned photoresist 584a using an ashing process. On the gate pad 524, a space between the sixth patterned photoresist 584c defines a first trench The HP1, on the data pad 526, defines a second trench HP2 in the space between the sixth patterned photoresist 584c. In the figure, a portion of the sixth patterned photoresist 584c appears to be spaced apart from each other. However, the first and second trenches HP1, HP2 correspond to the holes of the sixth patterned photoresist 584c, such that the sixth patterned photoresist 584c in each region is a complete body. The transparent conductive material layer 552 is patterned by the sixth patterned photoresist 584c to form a pixel electrode 560 connecting the drain electrode 544, the patterned transparent conductive material 552a on the gate pad 524, and the data pad 546. In this embodiment, since the transparent conductive material layer 552 is over-etched, the sixth patterned photoresist 584c protrudes from the trailing end of the patterned transparent conductive material 552a.

其後,如第15G、16G及17G圖所示,利用濺鍍方法,以氮化矽或氧化矽來形成保護層。一般而言,液晶顯示器中的保護層係透過電漿化學氣相沉積法,以沉積無機絕緣材料而形成的。然而,因為電漿化學氣相沉積法所需一相對高的溫度,例如高於350度C以上,所以對第六圖案化光阻584c造成損害。因此,保護層550係利用具有溫度小於150度C之濺鍍法所形成。Thereafter, as shown in FIGS. 15G, 16G, and 17G, a protective layer is formed by tantalum nitride or hafnium oxide by a sputtering method. In general, the protective layer in a liquid crystal display is formed by plasma chemical vapor deposition to deposit an inorganic insulating material. However, because the plasma chemical vapor deposition method requires a relatively high temperature, for example, above 350 degrees C, damage is caused to the sixth patterned photoresist 584c. Therefore, the protective layer 550 is formed by a sputtering method having a temperature of less than 150 degrees C.

由於在畫素電極560與第六圖案化光阻584c之間以及圖案化透明導電材料552a與第六圖案化光阻584c之間,其周圍的保護層550為不連續結構,所以在剝離方法中剝離液透過不連續結構滲入到第六圖案化光阻584c。因此,則可同時移除第六圖案化光阻584c與位於其上之保護層550。特別是,由於第一與第二溝槽HP1、HP2,剝離方法對閘極墊524與資料墊546具有大的影響力, 其線寬約大於200微米。Since the protective layer 550 around the pixel electrode 560 and the sixth patterned photoresist 584c and between the patterned transparent conductive material 552a and the sixth patterned photoresist 584c are discontinuous, in the stripping method The stripper penetrates into the sixth patterned photoresist 584c through the discontinuous structure. Therefore, the sixth patterned photoresist 584c and the protective layer 550 located thereon can be simultaneously removed. In particular, due to the first and second trenches HP1, HP2, the stripping method has a large influence on the gate pad 524 and the data pad 546, Its line width is greater than about 200 microns.

如第15H、16H及17H圖所示,於開關區TrA之保護層550覆蓋並保護暴露的部分主動層534a。相對第一與第二溝槽HP1、HP2之保護層550則殘留在閘極墊區GPA上。閘極墊電極562係設置於第一溝槽HP1之間,且形成的透明導電材料、接觸閘極墊524。在者,相對第二溝槽HP2之保護層550殘留於自料墊區DPA。資料墊電極564係設置於第二溝槽HP2之間,以其形成的透明導電材料,接觸資料墊546。As shown in Figures 15H, 16H and 17H, the protective layer 550 in the switching region TrA covers and protects the exposed portion of the active layer 534a. The protective layer 550 opposite to the first and second trenches HP1, HP2 remains on the gate pad region GPA. The gate pad electrode 562 is disposed between the first trenches HP1 and is formed of a transparent conductive material and a contact pad pad 524. In the case, the protective layer 550 of the second trench HP2 remains in the self-pad area DPA. The data pad electrode 564 is disposed between the second trenches HP2, and is formed of a transparent conductive material to contact the data pad 546.

當以本發明之剝離方法而具有相對大的線寬時形成線或圖案化,例如約為200微米以上,則藉由複數個溝槽而避免發生如殘留的圖案化光阻等問題。When a line or pattern is formed with a relatively large line width by the stripping method of the present invention, for example, about 200 μm or more, problems such as residual patterned photoresist are prevented by a plurality of grooves.

再者,因為設置於圖案化光阻上之材料層係利用具有相對低溫的濺鍍方法所形成,所以對圖案化光阻不造成損害。Furthermore, since the material layer provided on the patterned photoresist is formed by a sputtering method having a relatively low temperature, the patterned photoresist is not damaged.

再者,利用剝離方法所製備的液晶顯示器之陣列基板具有較佳的品質。Furthermore, the array substrate of the liquid crystal display prepared by the stripping method has better quality.

雖然本發明以前述之實施例揭露如上,然其並非用以限定本發明,任何熟習相像技藝者,在不脫離本發明之精神和範圍內,當可作些許之更動與潤飾,因此本發明之專利保護範圍須視本說明書所附之申請專利範圍所界定者為準。While the present invention has been described above in the foregoing embodiments, it is not intended to limit the invention, and the invention may be modified and modified without departing from the spirit and scope of the invention. The scope of patent protection shall be subject to the definition of the scope of the patent application attached to this specification.

10、100、200‧‧‧陣列基板、基板10, 100, 200‧‧‧ array substrate, substrate

145‧‧‧閘絕緣層145‧‧‧Brake insulation

152、156‧‧‧圖案化保護、保護層152, 156‧‧‧ patterned protection, protective layer

150、250‧‧‧第二材料層150, 250‧‧‧ second material layer

158‧‧‧第二圖案化材料158‧‧‧Second patterned material

170、270、370‧‧‧線Lines 170, 270, 370‧‧

170a、270a‧‧‧第一圖案化線170a, 270a‧‧‧ first patterned line

170b、270b‧‧‧第二圖案化線170b, 270b‧‧‧ second patterned line

170c、270c‧‧‧第三圖案化線170c, 270c‧‧‧ third patterned line

270d‧‧‧第四圖案化線270d‧‧‧fourth patterned line

172、273‧‧‧第一溝槽172, 273‧‧‧ first trench

174、274‧‧‧第二溝槽174, 274‧‧‧ second trench

175、260‧‧‧第一材料層175, 260‧‧‧ first material layer

180、280‧‧‧光阻層180, 280‧‧ ‧ photoresist layer

182、282、482a、582a‧‧‧第一圖案化光阻182, 282, 482a, 582a‧‧‧ first patterned photoresist

184、284、482a、582b‧‧‧第二圖案化光阻184, 284, 482a, 582b‧‧‧ second patterned photoresist

186、286、482c、582c‧‧‧第三圖案化光阻186, 286, 482c, 582c‧‧‧ third patterned photoresist

288、584a‧‧‧第四圖案化光阻288, 584a‧‧‧ fourth patterned photoresist

584b‧‧‧第五圖案化光阻584b‧‧‧ fifth patterned photoresist

584c‧‧‧第六圖案化光阻584c‧‧‧ sixth patterned photoresist

190’280‧‧‧罩幕190’280‧‧ ‧ curtain

20、420‧‧‧閘極線20, 420‧‧ ‧ gate line

30、440‧‧‧資料線30, 440‧‧‧ data line

371~376‧‧‧溝槽371~376‧‧‧ trench

374a‧‧‧第一溝槽線374a‧‧‧First groove line

374b‧‧‧第二溝槽線374b‧‧‧Second groove line

400‧‧‧陣列基板400‧‧‧Array substrate

410‧‧‧基板410‧‧‧Substrate

42、424、524‧‧‧閘極墊42, 424, 524‧‧ ‧ gate pads

426、526‧‧‧閘絕緣層426, 526‧‧ ‧ brake insulation

422、522‧‧‧閘極電極422, 522‧‧ ‧ gate electrode

428、528‧‧‧本質非晶矽層428, 528‧‧‧ Essential amorphous layer

428a、528a‧‧‧圖案化本質非晶矽428a, 528a‧‧‧ patterned essentially amorphous

430、530‧‧‧雜質摻雜非晶矽層430, 530‧‧‧ impurity doped amorphous layer

430a、530a‧‧‧圖案化雜質摻雜非晶矽430a, 530a‧‧‧ patterned impurities doped with amorphous germanium

432、532‧‧‧第二金屬層432, 532‧‧‧ second metal layer

432a‧‧‧圖案化金屬材料432a‧‧‧patterned metal materials

434a、534a‧‧‧主動層434a, 534a‧‧‧ active layer

434b、543b‧‧‧毆姆接觸層434b, 543b‧‧‧ 殴m contact layer

44、446、546‧‧‧資料墊44, 446, 546‧‧‧ data pad

442、542‧‧‧源極電極442, 542‧‧‧ source electrode

444、544‧‧‧汲極電極444, 544‧‧‧汲electrode

448‧‧‧圖案化金屬448‧‧‧patterned metal

45、526‧‧‧閘絕緣層45, 526‧‧ ‧ brake insulation

450、550‧‧‧保護層450, 550‧‧ ‧ protective layer

452、552‧‧‧透明導電材料層452, 552‧‧‧ Transparent conductive material layer

452a‧‧‧第一剝離圖案化452a‧‧‧First stripping patterning

552a‧‧‧圖案化透明導電材料552a‧‧‧patterned transparent conductive material

460、560‧‧‧畫素電極460, 560‧ ‧ pixel electrodes

462‧‧‧閘極電墊電極462‧‧‧Gate pole electrode

480、580‧‧‧第一光阻層480, 580‧‧‧ first photoresist layer

484‧‧‧第四圖案化光阻484‧‧‧ Fourth patterned photoresist

50‧‧‧共用線、薄膜層50‧‧‧Shared line, film layer

510‧‧‧基板510‧‧‧Substrate

534‧‧‧半導體層534‧‧‧Semiconductor layer

532a‧‧‧圖案化金屬532a‧‧‧patterned metal

552a‧‧‧圖案化透明導電材料552a‧‧‧patterned transparent conductive material

562‧‧‧閘極墊電極562‧‧‧ gate pad electrode

564‧‧‧資料墊電極564‧‧‧data pad electrode

584a‧‧‧第四圖案化材料584a‧‧‧fourth patterned material

584b‧‧‧五圖案化材料584b‧‧‧5 patterned materials

60‧‧‧金屬層60‧‧‧metal layer

70‧‧‧共用連接線、共同線70‧‧‧Common cable, common line

82‧‧‧圖案化光阻82‧‧‧patterned photoresist

BA‧‧‧阻障區BA‧‧‧Block area

CMH‧‧‧共用接觸窗CMH‧‧ shared contact window

Cst‧‧‧儲存電容Cst‧‧‧ storage capacitor

D~F‧‧‧部分D~F‧‧‧Parts

DR‧‧‧顯示區DR‧‧‧ display area

DPA‧‧‧資料墊區DPA‧‧‧data pad area

GPA‧‧‧閘極墊區GPA‧‧‧ gate pad area

GPC‧‧‧閘極墊接觸洞GPC‧‧‧Gate pad contact hole

HP1‧‧‧第一溝槽HP1‧‧‧ first trench

HP2‧‧‧第二溝槽HP2‧‧‧ second trench

HP3‧‧‧第三溝槽HP3‧‧‧ third trench

HP4‧‧‧第四溝槽HP4‧‧‧fourth groove

HTA‧‧‧半透明區HTA‧‧‧translucent area

NDR‧‧‧非顯示區NDR‧‧‧ non-display area

M‧‧‧罩幕M‧‧‧ mask

P‧‧‧畫素區P‧‧‧Photo District

TA‧‧‧透明區TA‧‧‧Transparent Zone

Tr‧‧‧薄膜電晶體、電晶體Tr‧‧‧thin film transistor, transistor

TrA‧‧‧開關區TrA‧‧ switch area

W‧‧‧寬度W‧‧‧Width

第1圖為習知液晶顯示器陣列基板之平面示意圖。FIG. 1 is a schematic plan view of a conventional liquid crystal display array substrate.

第2圖,係第1圖之A部分的局部放大圖。Fig. 2 is a partially enlarged view of a portion A of Fig. 1.

第3A-3C圖,係第2圖沿著線段III-III之剖面製程示意圖。Figure 3A-3C is a schematic view of the cross-sectional process along line III-III in Figure 2.

第4圖,係本發明之一實施例之包含溝槽之線的部分平面示意圖。Figure 4 is a partial plan view showing a line containing a groove in an embodiment of the present invention.

第5A-5C圖,係於第4圖沿著線段V-V之剖面製程示意圖。Figure 5A-5C is a schematic view of the cross-section process along line V-V in Figure 4.

第6圖,係第4圖中部分H之平面放大示意圖。Fig. 6 is a plan enlarged view of a portion H in Fig. 4.

第7圖,係本發明之一實施例中具有溝槽之線的部分平面示意圖。Figure 7 is a partial plan view showing a line having a groove in an embodiment of the present invention.

第8圖,係第7圖沿著線段VIII-VIII之剖面製程示意圖。Figure 8, is a schematic view of the cross-sectional process along line VIII-VIII of Figure 7.

第9圖,係第7圖中部分I之放大示意圖。Figure 9 is an enlarged schematic view of a portion I of Figure 7.

第10A-10F圖,係本發明之實施例中各溝槽的示意圖。10A-10F are schematic views of the grooves in the embodiment of the present invention.

第11圖,係本發明之實施例中之液晶顯示器之陣列基板之平面示意圖。Figure 11 is a plan view showing an array substrate of a liquid crystal display device in an embodiment of the present invention.

第12A-12F圖,係沿著第11圖線段XII-XII之部分剖面結構製程示意圖。Fig. 12A-12F is a schematic diagram of a part of the cross-sectional structure process along line XII-XII of Fig. 11.

第13A-13F圖,係沿著第11圖線段XIII-XIII之部分剖面結構製程示意圖。Figure 13A-13F is a schematic diagram of a part of the cross-sectional structure process along line XIII-XIII of Figure 11.

第14A-14F圖,係沿著第11圖線段XIIV-XIIV之部分剖面結構製程示意圖。Figure 14A-14F is a schematic diagram of the process of the section along the line XIIV-XIIV of Figure 11.

第15A-15H圖,係為本發明之此實施例中製造一具有開關區之畫素區的方法之剖面示意圖。15A-15H is a schematic cross-sectional view showing a method of manufacturing a pixel region having a switching region in this embodiment of the present invention.

第16A-16H圖,係為本發明之此實施例中製造閘極墊區的方法之剖面示意圖。16A-16H are cross-sectional views showing a method of fabricating a gate pad region in this embodiment of the present invention.

第17A-17H圖,係為本發明之此實施例中製造資料墊區的方法之剖面示意圖。17A-17H is a schematic cross-sectional view showing a method of manufacturing a data pad region in this embodiment of the present invention.

400‧‧‧陣列基板400‧‧‧Array substrate

410‧‧‧基板410‧‧‧Substrate

420‧‧‧閘極線420‧‧ ‧ gate line

422‧‧‧閘極電極422‧‧‧gate electrode

424‧‧‧閘極墊424‧‧‧Gate pad

442‧‧‧源極電極442‧‧‧ source electrode

444‧‧‧汲極電極444‧‧‧汲electrode

446‧‧‧資料墊446‧‧‧Material pads

448‧‧‧圖案化金屬448‧‧‧patterned metal

460‧‧‧畫素電極460‧‧‧ pixel electrodes

Cst‧‧‧儲存電容Cst‧‧‧ storage capacitor

HP1‧‧‧第一溝槽HP1‧‧‧ first trench

HP2‧‧‧第二溝槽HP2‧‧‧ second trench

HP3‧‧‧第三溝槽HP3‧‧‧ third trench

HP4‧‧‧第四溝槽HP4‧‧‧fourth groove

GPC‧‧‧閘極墊接觸洞GPC‧‧‧Gate pad contact hole

P‧‧‧畫素區P‧‧‧Photo District

Tr‧‧‧薄膜電晶體、電晶體Tr‧‧‧thin film transistor, transistor

Claims (19)

一種剝離方法,包含:形成一第一材料層於一基板上;形成一圖案化光阻於該第一材料層上,該圖案化光阻包含複數個第一孔洞與複數個第二孔洞;以該圖案化光阻作為圖案罩幕,圖案化該第一材料層,以形成具有複數個第一溝槽與複數個第二溝槽之一圖案化材料,該些第一與第二溝槽分別相對該些第一與第二孔洞,其中該圖案化光阻之寬度大於該些第一與第二溝槽之間的該圖案化材料之寬度;形成一第二材料層於具有該圖案化光阻、該些第一與該第二溝槽之該基板的一完整表面上;以及移除該圖案化光阻與位於該圖案化光阻上之該第二材料層;其中,位於該些第一與第二溝槽間之一部份的該圖案化材料,與位於該些第一與第二溝槽側邊之一部份的該圖案化材料,整體地構成一線。 A stripping method includes: forming a first material layer on a substrate; forming a patterned photoresist on the first material layer, the patterned photoresist comprising a plurality of first holes and a plurality of second holes; The patterned photoresist is patterned as a pattern mask to pattern the first material layer to form a patterned material having a plurality of first trenches and a plurality of second trenches, the first and second trenches respectively The width of the patterned photoresist is greater than the width of the patterned material between the first and second trenches; forming a second material layer having the patterned light Blocking a complete surface of the substrate of the first and second trenches; and removing the patterned photoresist and the second material layer on the patterned photoresist; wherein, the The patterned material between a portion of the first trench and the second trench is integrally formed with the patterned material at a portion of the first and second trench sides. 如請求項1所述之剝離方法,其中每一第一與第二溝槽係選自於條狀、鋸齒狀、交叉狀以及萬字(weathercock shape)所組成之一。 The stripping method of claim 1, wherein each of the first and second grooves is selected from the group consisting of a strip, a zigzag, a cross, and a weathercock shape. 如請求項1所述之剝離方法,其中該第二材料層包含至少一保護層、一透明導電材料層與一金屬導電材料層。 The stripping method of claim 1, wherein the second material layer comprises at least one protective layer, a transparent conductive material layer and a metal conductive material layer. 如請求項1所述之剝離方法,其中形成該第二材料層之該步驟包含利用濺鍍方法而沉澱該材料。 The stripping method of claim 1, wherein the step of forming the second material layer comprises precipitating the material by a sputtering method. 如請求項1所述之剝離方法,其中該線具有大於200微米之一線寬。 The stripping method of claim 1, wherein the line has a line width greater than 200 microns. 一種液晶顯示器之陣列基板之製備方法,包含:形成一閘極線與一閘電極於一基板上,該基板具有一顯示區與一第一至第四非顯示區,該第一至第四非顯示區係位於該顯示區之周圍,該閘電極設置於該顯示區上;形成一資料線、一資料墊、一半導體層、一源極電極與一汲極電極於該基板上,該資料線與該閘極線交錯設置,該資料墊設置於該資料線之一端且於該第一非顯示區上,該半導體層設置於該閘極電極上,該源極電極與該資料線連接且設置於半導體層上,該汲極電極與該源極電極區隔開且設置於該半導體層上;於具有該資料線、該資料墊、該源極電極與該汲極電極之該基板的一完整表面上,形成一絕緣材料層;形成第一圖案化光阻與一第二圖案化光阻,該第一圖案化光阻係相對該源極與該汲極電極,該第二圖案化光阻具有複數個第一與第二孔洞,該第一圖案化光阻暴露一部份之該汲極電極,該些第一與第二孔洞分別對應該資料墊之第一與第二部分; 以該第一與該第二圖案化光阻為圖案罩幕,圖案化該絕緣材料層,以形成一保護層與一第一圖案化保護層,該保護層暴露出部分之該汲極電極,該第一圖案化保護層具有複數個第一與第二溝槽,該些第一與第二溝槽分別暴露出該資料墊之該第一與第二部分;於具有該第一與該第二圖案化光阻、該保護層及該第一圖案化保護層之該基板的一完整表面上,形成一導電材料層,該導電材料層具有一不連續結構;及以剝離方法同時移除位於該第一與第二圖案化光阻上之該第一與該第二圖案化光阻及該導電材料層。 A method for fabricating an array substrate of a liquid crystal display, comprising: forming a gate line and a gate electrode on a substrate, the substrate having a display area and a first to fourth non-display area, the first to fourth non- The display area is located around the display area, and the gate electrode is disposed on the display area; forming a data line, a data pad, a semiconductor layer, a source electrode and a drain electrode on the substrate, the data line Interleaved with the gate line, the data pad is disposed at one end of the data line and on the first non-display area, the semiconductor layer is disposed on the gate electrode, and the source electrode is connected to the data line and is disposed On the semiconductor layer, the drain electrode is spaced apart from the source electrode region and disposed on the semiconductor layer; and a complete substrate of the substrate having the data line, the data pad, the source electrode and the drain electrode Forming an insulating material layer on the surface; forming a first patterned photoresist and a second patterned photoresist, the first patterned photoresist is opposite to the source and the drain electrode, and the second patterned photoresist Having a plurality of first and second holes The first patterned photoresist exposing a portion of the drain electrodes, the plurality of first and second holes, respectively first and second portions of the information should pad; Patterning the insulating material layer with the first and the second patterned photoresist as a pattern mask to form a protective layer and a first patterned protective layer, the protective layer exposing a portion of the drain electrode, The first patterned protective layer has a plurality of first and second trenches, the first and second trenches respectively exposing the first and second portions of the data pad; and having the first and the second Forming a conductive material layer on the entire surface of the substrate, the protective layer and the first patterned protective layer, the conductive material layer having a discontinuous structure; and simultaneously removing the The first and second patterned photoresists and the conductive material layer on the first and second patterned photoresists. 如請求項6所述之液晶顯示器之陣列基板之製備方法,其中該導電材料層為一透明導電材料或一不透光金屬導電材料。 The method for preparing an array substrate of a liquid crystal display according to claim 6, wherein the conductive material layer is a transparent conductive material or an opaque metal conductive material. 如請求項6所述之液晶顯示器之陣列基板之製備方法,其中形成該第一與第二圖案化光阻之步驟包含形成一第三圖案化光阻,該第三圖案化光阻具有複數個第三與第四孔洞,該些第三與第四孔洞係分別對應每一該第二、該第三與該第四非顯示區之第三與第四部分;該圖案化該絕緣材料層之步驟包含形成一第二圖案化保護層,該第二圖案化保護層具有複數個第三與第四溝槽,該些第三與第四溝槽分別暴露出該第二、第三與第四非顯示區之第三部份與第四部分;以及 該剝離步驟包含移除該第三圖案化光阻與位於該第三圖案化光阻上之該透明導電材料。 The method for fabricating an array substrate of a liquid crystal display according to claim 6, wherein the step of forming the first and second patterned photoresists comprises forming a third patterned photoresist, the third patterned photoresist having a plurality of Third and fourth holes, the third and fourth holes respectively corresponding to the third and fourth portions of each of the second, third and fourth non-display regions; the patterned layer of insulating material The step includes forming a second patterned protective layer having a plurality of third and fourth trenches, the third and fourth trenches exposing the second, third, and fourth portions, respectively The third and fourth parts of the non-display area; The stripping step includes removing the third patterned photoresist and the transparent conductive material on the third patterned photoresist. 如請求項8所述之液晶顯示器之陣列基板之製備方法,其中每一該第一、第二、第三及第四溝槽包含條狀、鋸齒狀、交叉狀以及萬字(weathercock shape)其中之一。 The method of fabricating an array substrate of a liquid crystal display according to claim 8, wherein each of the first, second, third, and fourth grooves comprises a strip shape, a zigzag shape, a cross shape, and a weathercock shape. one. 如請求項6所述之液晶顯示器之陣列基板之製備方法,其中每一該資料墊與該第二、第三及第四非顯示區具有大於200微米之一線寬。 The method of fabricating an array substrate of a liquid crystal display according to claim 6, wherein each of the data pads and the second, third, and fourth non-display regions have a line width greater than 200 micrometers. 一種液晶顯示器之陣列基板之製備方法,包含:於一基板上形成一閘極線與一閘極墊,該閘極墊設置於該閘極線之一端;依序形成一閘絕緣層、一本質非晶矽層、一雜質摻雜非晶矽層及一金屬層於該基板之一完整表面上,該基板上包含該閘極線與該閘極墊;圖案化該金屬層、該雜質摻雜非晶矽層、該本質非晶矽層及該閘絕緣層,以暴露出該閘極墊及形成與該閘極線交錯之一資料線,進而定義一畫素區與位於該資料線一端之一資料墊;形成一導電材料層於該基板具有該資料線與該資料墊之該完整表面上;形成一第一圖案畫光阻與一第二圖案畫光阻,該圖案畫光阻包含複數個第一與第二孔洞,該第二圖案畫光阻包含複數個 第三與第四孔洞,該些第一與第二孔洞分別對應該閘極墊之該第一與第二部分,該些第三與第四孔洞分別對應該資料墊之該第三與第四部分;以該第一與第二圖案化光阻作為罩幕,圖案化該導電材料層,以形成一第一圖案化導電材料與一第二圖案化導電材料,該第一圖案化導電材料具有複數個第一與第二溝槽,該第二圖案化導電材料具有複數個第三與第四溝槽,該些第一與第二溝槽分別暴露該閘極墊之該第一與第二部分,該些第三與第四溝槽分別暴露該資料墊之該第三與第四部分;於具有該第一、該第二圖案化光阻及該第一、該第二、該第三與該第四溝槽之該基板之一完整表面上,形成一保護層,該保護層具有一不連續結構;及以剝離製程,同時移除該第一、該第二圖案化光阻及位於該第一、該第二圖案化光阻上之該保護層。 A method for fabricating an array substrate of a liquid crystal display, comprising: forming a gate line and a gate pad on a substrate, wherein the gate pad is disposed at one end of the gate line; forming a gate insulating layer and an essence in sequence An amorphous germanium layer, an impurity doped amorphous germanium layer and a metal layer on a complete surface of the substrate, the substrate comprising the gate line and the gate pad; patterning the metal layer, the impurity doping An amorphous germanium layer, the intrinsic amorphous germanium layer and the gate insulating layer to expose the gate pad and form a data line interlaced with the gate line, thereby defining a pixel region and one end of the data line a data pad; forming a conductive material layer on the substrate having the data line and the complete surface of the data pad; forming a first pattern drawing photoresist and a second pattern drawing photoresist, the pattern drawing photoresist comprises a plurality of First and second holes, the second pattern drawing photoresist comprises a plurality of Third and fourth holes, the first and second holes respectively corresponding to the first and second portions of the gate pad, and the third and fourth holes respectively correspond to the third and fourth portions of the data pad And patterning the conductive material layer with the first and second patterned photoresists as a mask to form a first patterned conductive material and a second patterned conductive material, the first patterned conductive material having a plurality of first and second trenches, the second patterned conductive material having a plurality of third and fourth trenches, the first and second trenches respectively exposing the first and second gates of the gate pad a portion of the third and fourth trenches respectively exposing the third and fourth portions of the data pad; and having the first, the second patterned photoresist and the first, the second, the third Forming a protective layer on a complete surface of the substrate with the fourth trench, the protective layer having a discontinuous structure; and removing the first, the second patterned photoresist and located in a stripping process The first, the second patterned photoresist is on the protective layer. 如請求項11所述之液晶顯示器之陣列基板之製備方法,其中該導電材料層為一透明導電材料或一不透光金屬導電材料。 The method for preparing an array substrate of a liquid crystal display according to claim 11, wherein the conductive material layer is a transparent conductive material or an opaque metal conductive material. 如請求項11所述之液晶顯示器之陣列基板之製備方法,其中形成該閘極線與該閘極電之步驟包含形成連接該閘極線之一閘極電極;圖案化該金屬層、該雜質摻雜非晶矽層、該本質非晶矽層及該閘絕緣層之步驟包含形成一圖案化本質非晶矽、一圖案化 雜質摻雜非晶矽及一圖案化金屬層堆疊於該閘極電極上;圖案化導電材料層之步驟包含移除該暴露的圖案化金屬與一部份的圖案化雜質摻雜非晶矽,以及於該畫素區形成一畫素電極,且連接一部份之該圖案化金屬;以及移除該第一、第二圖案化光阻及該保護層之步驟包含移除該第三圖案化光阻與位於該第三圖案化光阻層上之該保護層。 The method for fabricating an array substrate of a liquid crystal display according to claim 11, wherein the step of forming the gate line and the gate electrode comprises forming a gate electrode connecting the gate line; patterning the metal layer, the impurity The step of doping the amorphous germanium layer, the intrinsic amorphous germanium layer and the gate insulating layer comprises forming a patterned intrinsic amorphous germanium, a patterning An impurity doped amorphous germanium and a patterned metal layer are stacked on the gate electrode; and the step of patterning the conductive material layer includes removing the exposed patterned metal and a portion of the patterned impurity doped amorphous germanium, And forming a pixel electrode in the pixel region, and connecting a portion of the patterned metal; and removing the first and second patterned photoresist and the protective layer comprises removing the third pattern The photoresist and the protective layer on the third patterned photoresist layer. 如請求項11所述之液晶顯示器之陣列基板之製備方法,其中每一該第一、第二、第三及第四溝槽包含條狀、鋸齒狀、交叉狀以及萬字(weathercock shape)其中之一。 The method of fabricating an array substrate of a liquid crystal display according to claim 11, wherein each of the first, second, third, and fourth grooves comprises a strip shape, a zigzag shape, a cross shape, and a weathercock shape. one. 如請求項11所述之液晶顯示器之陣列基板之製備方法,其中每一該閘極墊與該資料墊具有大於200微米之一線寬。 The method of fabricating an array substrate of a liquid crystal display according to claim 11, wherein each of the gate pads and the data pad has a line width greater than 200 microns. 如請求項15所述之液晶顯示器之陣列基板之製備方法,其中形成該保護層之步驟包含利用濺鍍方法。 The method of fabricating an array substrate of a liquid crystal display according to claim 15, wherein the step of forming the protective layer comprises using a sputtering method. 一種液晶顯示器,包含:一基板,包含一顯示區與一非顯示區,該非顯示區具有複數個部分,每一該些部分具有至少一溝槽,其中該些部份其中之一為閘極墊、資料墊、MPS線、靜電保護電路線、輔助線(dummy line)、輔助部(dummy area)或閘極線。 A liquid crystal display comprising: a substrate comprising a display area and a non-display area, the non-display area having a plurality of portions, each of the portions having at least one trench, wherein one of the portions is a gate pad , data pad, MPS line, electrostatic protection circuit line, dummy line, dummy area or gate line. 如請求項17所述之液晶顯示器,其中該些溝槽係為一材料所填滿,該材料為透明導電材料、一不透光金屬導電材料或一保護材料。 The liquid crystal display according to claim 17, wherein the trenches are filled with a material which is a transparent conductive material, an opaque metal conductive material or a protective material. 如請求項17所述之液晶顯示器,其中該些部分其中之一具有複數個溝槽,且兩兩相鄰之該些溝槽互相分隔開。 The liquid crystal display of claim 17, wherein one of the portions has a plurality of grooves, and the two adjacent grooves are spaced apart from each other.
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