TWI338056B - - Google Patents

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TWI338056B
TWI338056B TW097140159A TW97140159A TWI338056B TW I338056 B TWI338056 B TW I338056B TW 097140159 A TW097140159 A TW 097140159A TW 97140159 A TW97140159 A TW 97140159A TW I338056 B TWI338056 B TW I338056B
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Taiwan
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substrate
oxide layer
aluminum alloy
anode
degreased
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TW097140159A
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Chinese (zh)
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TW201016891A (en
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Priority to TW097140159A priority Critical patent/TW201016891A/en
Priority to EP09168633A priority patent/EP2177647B1/en
Priority to DE602009000954T priority patent/DE602009000954D1/en
Priority to AT09168633T priority patent/ATE503042T1/en
Publication of TW201016891A publication Critical patent/TW201016891A/en
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02Anodisation
    • C25D11/04Anodisation of aluminium or alloys based thereon
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02Anodisation
    • C25D11/022Anodisation on selected surface areas
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02Anodisation
    • C25D11/04Anodisation of aluminium or alloys based thereon
    • C25D11/12Anodising more than once, e.g. in different baths
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02Anodisation
    • C25D11/04Anodisation of aluminium or alloys based thereon
    • C25D11/14Producing integrally coloured layers

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
  • Chemical Treatment Of Metals (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
  • Laminated Bodies (AREA)
  • Forging (AREA)

Abstract

A method for forming multicolor aluminum alloy part has steps of preparing, surface treating, forming, processing and reprocessing. Preparing comprises providing an aluminum alloy substrate and cleaning with water. Surface treating comprises disposing the substrate in a first electrolytic solution to form a base oxide layer by anodizing. Forming comprises applying a membrane of transparent, acid-proof, insulating plastic on the substrate. Processing has locally removing an area of the membrane and corresponding oxide layer from the substrate and cleaning. Reprocessing has disposing the clean substrate in a subsequent electrolytic solution to form a subsequent oxide layer by anodizing on areas of the substrate exposed by local removal of an area of the membrane.

Description

1338056 九、發明說明: 【發明所屬之技術領域】 本發明係關於一種鋁合金的陽極表面處理方法,尤指 一種可於紹合金表面進行多色處理的方法,其概應隸屬於 %極處理之應用’運用於鋁合金產品之技術領域範嘴。 【先前技術】 心’ %極處理是化成皮膜技術(C〇nversi〇n Coating) 中的一種方法,主要係利用化學或電化學的處理方式,於 金属的表面生成一種含有該金屬成份的皮膜層,例如:鋅 的鉻酸鹽皮膜處理、鋼鐵的磷酸鹽皮膜處理及鋁合金的陽 極處理等,目前業界係利用鋁合金產品易氧化的特性,透 過陽極處理的電化學方法控制氧化層之生成,以防止鋁材 進一步氧化,另外,為了使鋁材不同部位上產生各種色澤 來增加美觀效果,會於鋁材上進行多次的陽極處理,使其 外表面形成多彩的效果; 然而,目前既有的多次陽極處理,卻仍存在以下缺失: 一、在各次的陽極處理之間,皆需對於鋁材進行切削 等處理,藉以加工出所需形狀及去除前次陽極處理所留下 的巩化層’以便於切削處形成不同色彩的氧化層,然而, 於切削時’常需配合切削液進行使用,若加工後未對於鋁 材進行清洗,則鋁材外表面附著些許的油漬,於下一次的 陽極處理時,t蓋於油潰的部位,即無法有效地將氧化層 附著於ig材上造成加工效果不佳。 二 '如業界既有之陽極處理,於第一次陽極處理後, 5 1338056 若未在陽極處理處形成一保護層’則於再次陽極處理的電 極過程中’會將第一次陽極處理的氧化層給部份電極下 來’造成加工瑕疯。 二、如業界既有之陽極處理’於第一次陽極處理後, 右未在陽極處理處形成一保護層,則於再次陽極處理的電 極過程中,會將第二次的氧化層,疊合在第一次陽極處理 的氧化層上,造成疊色之瑕疵情形。 四、 如業界既有之陽極處理,於第一次陽極處理後, 於氧化層上形成一油墨層予以保護,但此油膜層於再次切 削過程’容易於切口邊緣產生撕裂現象之加工瑕疵。 五、 如業界既有之陽極處理,於第一次陽極處理後, 於氧化層上形成一油墨層予以保護,但此油膜層於再次陽 極處理後’需加以清除,徒增加工程序。 有鑑於上述既有陽極處理所存在的缺失及不足,誠有 加以改進之處。 【發明内容】 因此,本發明人有鑑於既有陽極處理技術的缺失與不 足,對於鋁合金表面處理的製造及品質的維持上的困難, 特經過不斷的研究與試驗,終於發展出—種能改進現有缺 失之本發明。 為達到上述目的,本發明係提供一種紹合金之陽極多 色表面處理方法’其係包括有: (一)準備基材:將一处^ 4人進仃者色加工的鋁合金基材, 透過一加工機進行基材輪廓 郭外形的加工,於外形加工後, 6 1338056 除油脫脂處理。 藉由上述的流程所製造出的彩色基材,透過於基材氧 化層㈣成-由透明耐酸絕緣塑料所構成之薄膜,使基材 在進行後續的加工及陽極處理時,有效避免於加工時切削 线其他油潰附著於基材表面,進而產生覆蓋於油潰上的 乳化層產生脫落的現象,使經陽極處理所形成的氧化層能 緊密地附著於基材外表面上,藉以形成一穩固且耐磨的保 4結構’且於基材上形成薄膜後重複加工處理及表面再次 •處理的的製作流程,即可在氧化層未脫落的基材上準確地 呈現多彩的視覺效果,相對提高鋁合金的陽極加工效率及 品質之目的者。 【實施方式】 本發明提供一種鋁合金之陽極多色表面處理方法,其 係將經過第一次陽極處理後的鋁合金基材,於基材的表外 面形成一薄膜後,在進行相關的加工及陽極處理,可有效 Φ避免於加工時切削液或其他油漬附著於基材表面,使陽極 處理所形成的氧化層能緊密地附著於基材外表面上,藉以 形成一穩固且耐磨的保護結構,且可準確地於基材外表面 形成色彩效果,進而提高鋁合金的陽極加工效率及品質之 目的者。 本發明係關於一種鋁合金之陽極多色表面處理方法, 為能詳細瞭解本創作的技術特徵及實用功效,並可依照說 明書的内容來實施,玆進一步以圖式(如第一圖)所示的 較佳實施例,詳細說明如后: 8 1338056 準確地於基材外表面形成一種以上的色彩。 ;1 )及(二)的流程後,可使基材於表 面處理後形成皁一顏色,並且將前述完成單色陽極處理的 基材且於基材上形成薄膜後重複(四)及(五)的製作 "“王,即可於基材上呈現多彩的視覺效果。 藉由上述之技術手段,本發明鋁合金之陽極多色表面 處理方法,係至少具有下列之優點及功效:1338056 IX. Description of the Invention: [Technical Field] The present invention relates to an anode surface treatment method for an aluminum alloy, and more particularly to a method for performing multicolor treatment on the surface of a smelting alloy, which is generally affiliated with the % pole treatment. Application 'The mouth of the technical field of application of aluminum alloy products. [Prior Art] The '% pole treatment is a method in C〇nversi〇n Coating, which mainly uses a chemical or electrochemical treatment to form a coating layer containing the metal component on the surface of the metal. For example, zinc chromate treatment, zinc phosphate treatment of steel and anode treatment of aluminum alloy, etc., the current industry uses the characteristics of aluminum alloy products to easily oxidize, through the electrochemical treatment of anode treatment to control the formation of oxide layer, In order to prevent further oxidation of the aluminum material, in addition, in order to increase the appearance of various colors on the aluminum material to enhance the aesthetic effect, the anode material is subjected to multiple anode treatments to form a colorful effect on the outer surface; however, there are currently The multiple anode treatments still have the following defects: 1. Between each anode treatment, the aluminum material needs to be processed by cutting, etc., in order to process the desired shape and remove the remaining alum treatment. The layer 'is easy to form oxide layers of different colors at the cutting point. However, when cutting, it is often necessary to use the cutting fluid for use. After the processing, the aluminum material is not cleaned, and some oil stains are attached to the outer surface of the aluminum material. When the next anode treatment, t is covered in the oil collapsed portion, that is, the oxide layer cannot be effectively attached to the ig material to cause the processing effect. Not good. Second, as the industry has anodized, after the first anodizing, 5 1338056, if a protective layer is not formed at the anode treatment, then the first anodized oxidation will be carried out during the re-anodized electrode process. The layer gives the partial electrode down' causing processing to go crazy. Second, if the industry has anodized treatment, after the first anodizing treatment, the right does not form a protective layer at the anode treatment, in the process of re-anodizing the electrode, the second oxide layer will be superposed. On the first anodized oxide layer, a collapsed color is created. 4. If the industry has an anodizing treatment, after the first anodizing treatment, an ink layer is formed on the oxide layer to protect it, but the oil film layer is processed in the re-cutting process, which is easy to tear at the edge of the slit. 5. If the industry has anodized treatment, after the first anodizing treatment, an ink layer is formed on the oxide layer to protect it, but the oil film layer needs to be removed after being treated again. In view of the above-mentioned defects and deficiencies in the existing anode treatment, improvements have been made. SUMMARY OF THE INVENTION Therefore, the present inventors have finally developed a kind of energy through continuous research and experiment in view of the lack of existing anodizing techniques and the difficulty in maintaining the surface treatment of aluminum alloys and maintaining quality. The invention of the existing deficiency is improved. In order to achieve the above object, the present invention provides an anode multi-color surface treatment method for the alloy, which includes: (1) preparing a substrate: an aluminum alloy substrate processed by a person who is processed into a color A processing machine performs the processing of the outline of the substrate profile, and after the shape processing, 6 1338056 degreased and degreased. The color substrate produced by the above process is transparent to the substrate oxide layer (4) to form a film made of transparent acid-resistant insulating plastic, so that the substrate is effectively prevented from being processed during subsequent processing and anodizing. The other oil line on the cutting line adheres to the surface of the substrate, thereby causing the phenomenon that the emulsion layer covering the oil collapse is detached, so that the oxide layer formed by the anode treatment can closely adhere to the outer surface of the substrate, thereby forming a stable surface. And the wear-resistant structure of the structure 4, and the process of repeating the processing and the surface re-treatment after forming the film on the substrate can accurately display the colorful visual effect on the substrate on which the oxide layer has not fallen off, and relatively improve The purpose of aluminum alloy anode processing efficiency and quality. [Embodiment] The present invention provides an anode multi-color surface treatment method for an aluminum alloy, which is characterized in that after the first anodized aluminum alloy substrate is formed on the outer surface of the substrate, a related film is processed. And the anode treatment can effectively prevent the cutting fluid or other oil stains from adhering to the surface of the substrate during processing, so that the oxide layer formed by the anode treatment can closely adhere to the outer surface of the substrate, thereby forming a stable and wear-resistant protection. The structure can accurately form a color effect on the outer surface of the substrate, thereby improving the anode processing efficiency and quality of the aluminum alloy. The invention relates to an anode multi-color surface treatment method for an aluminum alloy, in order to understand the technical features and practical effects of the creation in detail, and can be implemented according to the contents of the specification, and further illustrated by a diagram (as shown in the first figure). A preferred embodiment, as described in detail below: 8 1338056 Accurately forms more than one color on the outer surface of the substrate. After the processes of 1) and (2), the substrate may be subjected to a surface treatment to form a soap color, and the substrate after the completion of the monochromatic anodization is formed and the film is formed on the substrate (4) and (5) The production of "Wang" can present a colorful visual effect on the substrate. By the above technical means, the anode multi-color surface treatment method of the aluminum alloy of the present invention has at least the following advantages and effects:

、遮盍基材:本發明鋁合金之陽極多色表面處理方 法係藉由於形成氧化層的基材外表面形成一由透明耐酸 絕緣塑料所構成之薄膜’使基材在進行後續的加工及陽極 夺有效避免於加工時切削液或其他油潰附著於基材 表面b進而產生覆盍於油潰上的氧化層產生脫落的現象, 使經陽極處理所形成的氧化層能緊密地附著於基材外表面 上’藉以形成一穩固且耐磨的保護結構。Concealing substrate: The anode multi-color surface treatment method of the aluminum alloy of the invention forms a film composed of transparent acid-resistant insulating plastic by the outer surface of the substrate forming the oxide layer, so that the substrate is subjected to subsequent processing and anode Effectively avoiding the phenomenon that the cutting fluid or other oil is adhered to the surface b of the substrate during processing, and the oxide layer covering the oil collapse is detached, so that the oxide layer formed by the anode treatment can closely adhere to the substrate. 'on the outer surface' to form a stable and wear-resistant protective structure.

一氧化層 二、色彩效果:本發明鋁合金之陽極多色表面處理方 法,於基材上形成薄膜後重複加工處理及表面再次處理的 的製作流程,即可在氧化層未脫落的基材上準確地呈現多 彩的視覺效果,有效避免產生疊色之現象。 事實上’根據本發明所作之不同修正及變化,若對於 热習該項技術者而言,未偏離本發明的範圍與精神者,亦 被涵蓋於本發明的申請專利範圍之内,雖然本發明已敘述 特定的較佳具體事實,必須瞭解的是本發明不應被不當地 限制於該等特定具體事實上。 【圖式簡單說明】 10 1338056 第一圖係本發明之铭合金之陽極多色表面處理方法之 流程圖。 【主要元件符號說明】 無Oxide layer 2, color effect: the anode multi-color surface treatment method of the aluminum alloy of the invention, the process of repeating processing and surface re-treatment after forming a film on the substrate, can be on the substrate on which the oxide layer is not detached Accurately present colorful visual effects, effectively avoiding the phenomenon of overlapping colors. In fact, the various modifications and variations of the present invention are intended to be included within the scope of the present invention without departing from the scope and spirit of the invention. Having described certain preferred specific facts, it must be understood that the present invention should not be unduly limited to the specific details. BRIEF DESCRIPTION OF THE DRAWINGS 10 1338056 The first figure is a flow chart of an anode multicolor surface treatment method for the alloy of the present invention. [Main component symbol description] None

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Claims (1)

1338056 十、申請專利範圍: 1 一種鋁合金之陽極多色表面處理方法,其包含·· (―)準備基材:將-欲進行著色加工的鋁合金基材, 透過一加工機進行基犲輪廓外形的加工’料形加工後, 將基材進行除油脫脂,#以將附著於基料表面的切削液 及油漬進行清洗’待除油脫脂後將基材進行水洗藉以清除 其表面的雜質; (二) 表面處理:將清洗乾淨的基材放人—電解液中進 行陽極處理,使基材的外表面形成一氧化層; (三) 形成薄Μ ··於’經過陽極處理後的基材外表面形成 -由透明耐酸絕緣塑料所構成之薄膜,使基材的氧化層外 形成一保護層,進而讓基材得到一遮蓋效果; 曰 “(四)加工處i里:將經形成薄膜的基材進行外形加工, 稭以將覆蓋於基材外表面的薄膜及氧化層進行局部的移 除,使基材局部的外表面外露出氧化層及薄膜外待局部 加工後,將基材進行除油脫脂及清洗以清除油潰及雜質; 以及 (五)表面再次處理:將清洗乾淨的基材再放入另一電 解液中進行陽極處ίΐ ’使基材經加工處理的局部外表面形 成另-氧化層,使基材外表面呈現一種以上的色彩效果。 2 .如申請專利範圍第!項所述之鋁合金之陽極多色 表面處理方法’其中於表面處理的製程中,當氧化層形成 於基材的外表面後’將基材至電解液中取出進行洪乾,使 該氧化層可穩固地附著於基材外表面。 121338056 X. Patent application scope: 1 An anode multi-color surface treatment method for aluminum alloy, comprising: (-) preparing a substrate: an aluminum alloy substrate to be subjected to coloring processing, and a base profile through a processing machine After the shape processing, the substrate is degreased and degreased, #cleaning the cutting fluid and oil stains attached to the surface of the base material. After the oil is degreased, the substrate is washed with water to remove impurities on the surface; (2) Surface treatment: the cleaned substrate is placed in an electrolyte - anodizing in an electrolyte to form an oxide layer on the outer surface of the substrate; (3) forming a thin layer · · after the anodized substrate The outer surface is formed - a film made of transparent acid-resistant insulating plastic, which forms a protective layer outside the oxide layer of the substrate, thereby giving the substrate a covering effect; 曰 "(4) Processing place i: film-forming The substrate is processed in a shape, and the straw is used to partially remove the film and the oxide layer covering the outer surface of the substrate, so that the outer surface of the substrate is exposed outside the oxide layer and the film is to be partially processed. Afterwards, the substrate is degreased and degreased and cleaned to remove oil collapse and impurities; and (5) the surface is treated again: the cleaned substrate is placed in another electrolyte at the anode to make the substrate processed. The partial outer surface of the treatment forms an additional oxide layer, so that the outer surface of the substrate exhibits more than one color effect. 2. The anode multi-color surface treatment method of the aluminum alloy described in the scope of the patent application, wherein the surface treatment In the process, when the oxide layer is formed on the outer surface of the substrate, the substrate is taken out to the electrolyte to be dried, so that the oxide layer can be firmly adhered to the outer surface of the substrate.
TW097140159A 2008-10-20 2008-10-20 Anode multi-color surface treatment method for aluminum alloy TW201016891A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
TW097140159A TW201016891A (en) 2008-10-20 2008-10-20 Anode multi-color surface treatment method for aluminum alloy
EP09168633A EP2177647B1 (en) 2008-10-20 2009-08-25 Method of forming multicolor aluminium alloy
DE602009000954T DE602009000954D1 (en) 2008-10-20 2009-08-25 A method of forming a multicolor aluminum alloy
AT09168633T ATE503042T1 (en) 2008-10-20 2009-08-25 METHOD FOR FORMING A MULTICOLOR ALUMINUM ALLOY

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TW097140159A TW201016891A (en) 2008-10-20 2008-10-20 Anode multi-color surface treatment method for aluminum alloy

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TWI338056B true TWI338056B (en) 2011-03-01

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AT (1) ATE503042T1 (en)
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EP3741882A1 (en) 2019-05-21 2020-11-25 Bang & Olufsen A/S A method of providing a coloured, anodised aluminium surface

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JPS58110694A (en) * 1981-12-23 1983-07-01 Katsushika Press Kogyosho:Kk Multi-color treatment of aluminum surface
JPS6067691A (en) * 1983-09-21 1985-04-18 Seiko Epson Corp Preparation of multi-colored clock case
JPS6075599A (en) * 1983-09-30 1985-04-27 Nippon Denso Co Ltd Formation of multicolor pattern of anodized film
RU2072000C1 (en) * 1993-08-23 1997-01-20 Институт химии Дальневосточного отделения РАН Method of multicolored dying of aluminium and aluminium-alloy objects
US20050109623A1 (en) * 2003-09-10 2005-05-26 Bao Sheng Corporation Multi-color anodizing processes

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TW201016891A (en) 2010-05-01

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