TWM361504U - Multicolor structure of aluminum alloy surface - Google Patents

Multicolor structure of aluminum alloy surface Download PDF

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Publication number
TWM361504U
TWM361504U TW97223039U TW97223039U TWM361504U TW M361504 U TWM361504 U TW M361504U TW 97223039 U TW97223039 U TW 97223039U TW 97223039 U TW97223039 U TW 97223039U TW M361504 U TWM361504 U TW M361504U
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Taiwan
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oxide layer
substrate
aluminum alloy
color
aluminum
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TW97223039U
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Chinese (zh)
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Zhi-Xian Chen
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Zhi-Xian Chen
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Priority to TW97223039U priority Critical patent/TWM361504U/en
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M361504 四、 指定代表圖: (一) 本案指定代表圖為:第(四)圖。 (二) 本代表圖之元件符號簡單說明: (1)銘基材(11)第一氧化層 (12)保護層(13)外露部 (14)第二氧化層 五、 新型說明: 【新型所屬之技術領域】 [0001] 本創作係有關於一種is合金表面之多色結構5尤其 是指一種具有保護層,使得第二氧化層係不會形成於第 一氧化層之外表面以避免疊色之紹合金表面之多色結構 【先前技#f】 [0002] 按,一般之鋁合金很容易氧化,氧化層雖有一定之M361504 IV. Designated representative map: (1) The representative representative of the case is: (4). (2) Brief description of the symbol of the representative figure: (1) Ming substrate (11) First oxide layer (12) Protective layer (13) Exposed portion (14) Second oxide layer V. New description: TECHNICAL FIELD [0001] The present invention relates to a multi-color structure of an is alloy surface 5, in particular, a protective layer such that the second oxide layer is not formed on the outer surface of the first oxide layer to avoid overlapping Multi-color structure of the surface of the alloy [previous technique #f] [0002] According to the general aluminum alloy, it is easy to oxidize, although the oxide layer has a certain

鈍化作用,但長期曝露之結果,氧化層仍會剝落而喪失 保護作用,因此通常會於鋁合金之表面進行陽極處理, 目的即為利用其易氧化之特性,錯電化學方法控制乳化 層之生成,以防止銘材進一步氧化,同時增加表面的機 械性質,上述之陽極處理為一種電解過程,提供鍍層金 屬的金屬片有如陽極之作用,被鍍物之作用則有如陰極 ,而電解液通常為鍍層金屬的離子溶液,過程中係於陽 極與陰極間輸入電壓後,吸引電解液中的金屬離子游至 陰極,金屬離子還原後即鍍著其上,同時陽極的金屬片 再溶解,提供電解液更多的金屬離子,另外在某些情況 下將使用不溶性陽極,使得電鍍時必須添加電解液以補 表單編號A0101 第2頁/共10頁 M361504 充鍵著金屬離子。 [0003] 上述之鋁合金於進行陽極處理〔通常又可稱為裝飾 性陽極處理〕的時候,係於鋁合金之表面形成有一層亮 麗而耐腐蝕之皮膜,皮膜之膜厚約在6 β至15//左右 ,可兼具保護母材及美化之功能,同時也可利用其物理 性質或化學性質的改變提供原材料所無法提供的表面性 質,且皮膜係可依客戶的喜愛而選擇亮面處理或者霧面 處理(梨面處理),因為所形成之皮膜為多孔性質,具 有優秀的滲透性,可以將皮膜以有機或無機的染料浸泡 而渗入皮膜之毛細孔内,形成有各種顏色及花樣之成品 ,顏色有多樣的變化,是一般性陽極處理的特點,用於 以鋁材為原料的製品是最佳的外觀保護法。 [0004] 然而,上述之陽極處理方式在實際使用的時候會有 下列之缺失: [0005] 1.上述之陽極處理方式在需要進行多次之陽極處理Passivation, but as a result of long-term exposure, the oxide layer will still peel off and lose its protective effect. Therefore, it is usually anodized on the surface of the aluminum alloy. The purpose is to control the formation of the emulsion layer by using the characteristics of easy oxidation. In order to prevent further oxidation of the name material and increase the mechanical properties of the surface, the above-mentioned anode treatment is an electrolysis process, the metal sheet providing the plated metal acts as the anode, the object to be plated acts as the cathode, and the electrolyte is usually the plating layer. The metal ion solution is connected to the input voltage between the anode and the cathode, and then the metal ions in the electrolyte are attracted to the cathode. After the metal ions are reduced, the metal ions are plated thereon, and the metal piece of the anode is redissolved to provide an electrolyte. A large amount of metal ions, and in some cases an insoluble anode will be used, so that an electrolyte must be added during plating to fill the form number A0101 page 2 / total 10 pages M361504 charge metal ions. [0003] When the above-mentioned aluminum alloy is subjected to anodizing treatment (generally referred to as decorative anodizing treatment), a bright and corrosion-resistant film is formed on the surface of the aluminum alloy, and the film thickness of the film is about 6 β to 15// or so, it can protect both the base material and the beautification function. At the same time, it can also provide the surface properties that the raw materials cannot provide by changing its physical properties or chemical properties, and the film system can choose the glossy surface treatment according to the customer's preference. Or matte treatment (pear surface treatment), because the formed film is porous and has excellent permeability, the film can be immersed in an organic or inorganic dye to penetrate into the pores of the film to form various colors and patterns. Finished products, with a variety of colors, are the characteristics of general anodizing, and the products used for aluminum materials are the best appearance protection method. [0004] However, the above-mentioned anode treatment method has the following defects in actual use: [0005] 1. The above-mentioned anode treatment method requires a plurality of anode treatments.

以形成多種色澤時,必須在各次之陽極處理間對於鋁合 金進行切削、拋光或雷射雕刻等表面處理,以去除前次 陽極處理所產生之皮膜,以便在表面處理處形成另一色 澤之皮膜,但表面處理時往往須使用切削液或冷卻液, 使得表面處理後之鋁合金將殘留油潰,導致於下次陽極 處理時,產生於油潰上之另一皮膜將容易脫落,造成陽 極處理不良率之上升。 [0006] 2.上述之陽極處理方式由於新產生之皮膜將具有容 易脫落之缺陷,不僅是將影響到整體之顯色效果,也容 表單編號Α0101 第3頁/共10頁 M361504 易發生疊色之情形,甚至於造成整體強度之下降。 【新型内容】In order to form a plurality of colors, it is necessary to perform surface treatment such as cutting, polishing or laser engraving on the aluminum alloy between the respective anode treatments to remove the film produced by the previous anodizing treatment, so as to form another color at the surface treatment. The film, but the surface treatment often requires the use of cutting fluid or coolant, so that the surface treated aluminum alloy will residual oil collapse, resulting in the next anode treatment, the other film produced on the oil collapse will easily fall off, resulting in anode The increase in the rate of treatment failure. [0006] 2. The above-mentioned anodizing treatment method has a defect that it is easy to fall off due to the newly produced film, and not only affects the overall color development effect, but also forms No. 1010101 Page 3/10 pages M361504 In this case, even the overall strength is reduced. [New content]

[0007] 是故,本創作鑑於上述之缺點,以提供一種鋁合金 表面之多色結構,該多色結構係在第一氧化層之外表面 形成有一保護層,以保護鋁基材之底色,並局部移除鋁 基材表面之第一氧化層、保護層而形成有銘基材之外露 部,再進行第二次之陽極處理而在各外露部分別形成有 一第二氧化層,令鋁基材之外表面呈現有二種以上之色 澤,使得第二氧化層係不會形成於第一氧化層之外表面 ,以避免發生疊色之情形。[0007] Therefore, in view of the above disadvantages, the present invention provides a multi-color structure of an aluminum alloy surface, which is formed with a protective layer on the outer surface of the first oxide layer to protect the ground color of the aluminum substrate. And partially removing the first oxide layer and the protective layer on the surface of the aluminum substrate to form a exposed portion of the surface of the substrate, and performing the second anodizing treatment to form a second oxide layer on each exposed portion, respectively, to make the aluminum base The outer surface of the material exhibits two or more colors, so that the second oxide layer is not formed on the outer surface of the first oxide layer to avoid the occurrence of color duplication.

[0008] 本創作之鋁合金表面之多色結構較佳實施例的特徵 在於,其主要係將紹基材透過一加工機進行輪靡外形之 加工後,將鋁基材浸於除油劑中以超音波清洗之方式去 除銘基材外表面所附著之切削液或油潰等,並以水洗之 方式清除鋁基材表面之雜質,且將清洗乾淨之鋁基材浸 入一電解液中進行陽極處理而形成有一第一氧化層,第 一氧化層之外表面喷上一層抗UV、防腐、防氧化、抗強 酸之透明液體金油,再烘乾透明液體金油而在第一氧化 層之外表面形成有一保護層,以保護銘基材之底色,並 進行外形輪靡之加工修邊〔切削 '拋光或雷射雕刻〕而 局部移除铭基材表面之第一氧化層、保護層,使得銘基 材自第一氧化層、保護層局部外露而形成有鋁基材之外 露部,且將鋁基材再次浸於除油劑中進行超音波清洗而 去除切削液或油潰等,再將清洗乾淨之鋁基材浸入另一 電解液中進行第二次之陽極處理而在鋁基材之各外露部 表單編號A0101 第4頁/共10頁 M361504 分別形成有一第二氧化層’令鋁基材之外表面呈現有二 種以上之色澤。 _] 減本創作之銘合金表面之多色結構其一較佳實施 例,該氧化層係使用草酸陽極處理液〔〇xalic acid anodixing Electrolyte〕所形成而為黃色鍍層〔 yellow coatings〕。 _ 減本創作之紹合金表面之多色結構另一較佳實施[0008] The preferred embodiment of the multicolor structure of the aluminum alloy surface of the present invention is characterized in that the aluminum substrate is immersed in the degreaser after processing the rim shape through a processing machine. Ultrasonic cleaning is used to remove the cutting fluid or oil collapse attached to the outer surface of the substrate, and the impurities on the surface of the aluminum substrate are removed by water washing, and the cleaned aluminum substrate is immersed in an electrolyte for anode Forming a first oxide layer, the outer surface of the first oxide layer is sprayed with a transparent liquid gold oil resistant to UV, corrosion, oxidation, and strong acid, and then drying the transparent liquid gold oil outside the first oxide layer. A protective layer is formed on the surface to protect the underlying color of the substrate, and to perform the trimming of the shape rim (cutting 'polishing or laser engraving>) to partially remove the first oxide layer and the protective layer on the surface of the substrate. The exposed substrate is partially exposed from the first oxide layer and the protective layer to form an exposed portion of the aluminum substrate, and the aluminum substrate is again immersed in the degreaser for ultrasonic cleaning to remove the cutting fluid or oil collapse, etc. Will be cleaned The substrate is immersed in another electrolyte for the second anodization treatment, and each exposed portion of the aluminum substrate is shown in Form No. A0101, page 4/10, M361504, respectively, and a second oxide layer is formed to make the outer surface of the aluminum substrate There are more than two colors. _] Reducing the multicolor structure of the surface of the alloy of the present invention. In a preferred embodiment, the oxide layer is formed of yellow coatings using an oxalate anodizing electrolyte. _ Reducing the multi-color structure of the surface of the alloy

例,該氧化層係使用磺化有機酸〔sulf〇natedFor example, the oxide layer is a sulfonated organic acid.

Acid遍酸混合之陽極處理液所形成而為青 銅色〔bronze〕、金色〔g〇id〕、灰色〔gray〕或黑色 〔black〕之陽極處理錄層。 【實施方式】 _ 為令本創作所利之技油容、創作目的及其達成 之功效有更完整且清楚的揭露,祕下詳細說明之,並 睛一併參閱所揭之圖式及圖號: [0012] f先’請參照第所示’本射之紹合金表面之 多色結構係具有—銘基材⑴,紹基材⑴透過一加工機 進订外形輪廓之加工後,將加玉過之銘基材⑴浸於除油 hJ中X超曰波a洗之方式去除鋁基材(丨)外表面所附著之 切削液或油潰等’並以水洗之方式清誠基材⑴表面之 雜質,且將清洗乾淨之基材⑴浸人—電解液中進行陽 極處.形成有—第—氧化層⑴)’以作為域材⑴之 底色’此時若是使用草酸陽極處理液〔oxalic acid anodixing Electrolyte 將可得黃色鍍層〔ye〗l〇w 表單蝙號A0101 第5頁/共10頁 M361504 c 〇 a t i n g s〕,比傳統硫酸陽極處理液〔c 〇 n v e η ΐ i ο n a 1 sulfuric acid anodizing electrolyte〕之鍍層硬 ,而石黃化有機酸〔sulfonated Organic Acid〕與硫酸 混合之陽極處理液則可得青銅色〔bronze〕、金色〔 gold〕、灰色〔gray〕或黑色〔black〕之陽極處理鍍 層,此鍍層較傳統硫酸陽極處理液的鍍層緻密〔dense〕 且硬〔hard〕,請一併參照第二圖所示,並於第一氧化 層(11)之外表面喷上一層抗UV、防腐、防氧化、抗強酸An anodic treatment layer formed of an anodizing solution mixed with acid and a bronze color, a gold color, a gray color, or a black color. [Embodiment] _ In order to make the creative oil, the purpose of creation and the effect of the achievement of this creation more complete and clear, the secret details are explained in detail, and the drawings and drawings are disclosed together: [0012] f first 'please refer to the first one's multi-color structure of the surface of the alloy to have the original substrate (1), the substrate (1) through a processing machine to order the outline of the processing, will add jade The substrate of the inscription (1) is immersed in the degreasing hJ in the form of X-wave super-wave washing to remove the cutting fluid or oil from the outer surface of the aluminum substrate (丨) and clean the surface of the substrate (1) by water washing. Impurities, and the cleaned substrate (1) is immersed in the electrolyte - the anode is formed in the electrolyte. The -oxide layer (1) is formed as the background color of the domain material (1). If oxalic acid is used at this time, oxalic acid is used. Anodixing Electrolyte will be available in yellow plating [ye] l〇w form bat number A0101 page 5 / 10 pages M361504 c 〇atings], than traditional sulfuric acid anodizing solution [c 〇nve η ΐ i ο na 1 sulfuric acid anodizing electrolyte 〕The coating is hard, and the stone is yellow. An anodic treatment liquid mixed with sulfonated organic acid and sulfuric acid can obtain an anodized coating of bronze, gold, gray or black, which is more conventional than conventional sulphuric acid anodizing solution. The coating is dense and hard. Please refer to the second figure and spray a layer of anti-UV, anti-corrosion, anti-oxidation and anti-acid on the outer surface of the first oxide layer (11).

之透明液體金油〔clear coat〕,例如橡膠透明漆、石夕 膠透明漆或乳膠透明漆等,再烘乾透明液體金油而在第 一氧化層(11)之外表面硬化形成有一保護層(12),以保 護鋁基材(1)之底色〔第一氧化層(11)〕’請一併參照第 二圖所示,並於鋁基材(1)進行外形輪廓之加工修邊〔切 削、拋光或雷射雕刻〕而局部移除鋁基材(1)表面之第一 氧化層(11)、保護層(12),使得鋁基材(丨)自第一氧化 層(11)、保護層(12)局部外露而形成有鋁基材(1)之外Transparent liquid gold, such as rubber clear paint, Shishi plastic clear paint or latex transparent paint, and then dried transparent liquid gold oil and hardened on the surface of the first oxide layer (11) to form a protective layer (12), in order to protect the base color of the aluminum substrate (1) [first oxide layer (11)]', please refer to the second figure, and the contour of the aluminum substrate (1) is trimmed. [Cutting, polishing or laser engraving] to partially remove the first oxide layer (11) and the protective layer (12) on the surface of the aluminum substrate (1) such that the aluminum substrate (丨) is from the first oxide layer (11) The protective layer (12) is partially exposed to form an aluminum substrate (1)

露部(13),外露部⑽係成—預設之造型,且將銘基材 ⑴再次浸於除油射進行超音波清洗而去除切削液或油 潰等’請-併參照第四圖所示,再將清洗乾淨之銘基材 ⑴浸入另-電解液中進行第二次之陽極處理而在銘基材 ⑴之各外露部⑴)分別形成有另一色之第二氧化層 (⑷’請-併參照第五圖所示,令减材⑴之外表面呈 現有二種以上之色澤’並由於第一氧化層(⑴之外表面 輸-保護層(⑵,使得第二氧化層(⑷係不會形成 於第一氧化層(1 1 )之外岁 情形。 4面’以確實的避免發生疊色之 表單編號A0101 第6頁/共10頁 M361504 剛然而前述之實施例或圖式並非限定本創作之製作方 法、產品結構、尺寸或排列方式’任何所屬技術領域中 =通常知識者之適當變化或修飾,皆應視為不脫離本 創作之專利範脅。 [0014] 由上述之元件組成與實施說明可知 結構相較之下,本創作具有以下之優點 ’本創作與現有The exposed part (13) and the exposed part (10) are formed into a preset shape, and the inscription substrate (1) is again immersed in the oil removal for ultrasonic cleaning to remove the cutting fluid or oil collapse, etc. Please refer to the fourth figure. In addition, the cleaned substrate (1) is immersed in another electrolyte to perform a second anode treatment, and the exposed portions (1) of the substrate (1) are respectively formed with a second oxide layer of another color ((4)' - and referring to the fifth figure, the surface of the reduced material (1) exhibits two or more colors 'and because of the first oxide layer ((1), the outer surface of the protective layer ((2), so that the second oxide layer ((4)) It is not formed in the case of the first oxide layer (1 1 ). The 4 face 'is surely avoids the coloring of the form No. A0101 Page 6 / 10 pages M361504. However, the foregoing embodiments or drawings are not limited. The method of manufacture, product structure, size or arrangement of the present invention is to be considered as a non-existent change or modification of the present invention in any technical field. [0014] It consists of the above-mentioned components. Compared with the implementation description, the structure is comparable to this creation. The following advantages of 'the present prior Creation

15 /‘本_相料3綠體金財第-氧化層之外表 面形成有-保護層,以保護城材之底色,並局部移除 =基材表面之第—氧化層、保護層而形成有㈣材之外 ^ ’再進行第二次之陽域理•各外露部分別形成 有-第二氧化層,令域材之外表面呈現有二種以上之色澤、,使得第二氧化層係不會形成於第—氧化層之外表 面,以避免發生疊色之情形。 [0016]15 / 'This _ phase material 3 green body Jincai - the outer surface of the oxide layer is formed with a protective layer to protect the base color of the city material, and partial removal = the first surface of the substrate - oxide layer, protective layer Formed with (four) material ^ ' and then the second time of the positive domain area · each exposed part is formed with a second oxide layer, so that the outer surface of the domain material has more than two kinds of color, so that the second oxide layer It is not formed on the outer surface of the first oxide layer to avoid the occurrence of color overlap. [0016]

[0017] 2,本創作之第二氧化層係不會形成於第—氧化層之 外表面’使得第-氧化層與第二氧化層係可根據輕部 ^形狀而形成預設之造型舆色澤,並可提高陽極處理之 良率,同時亦提升整體之強度。 綜上所述,本創作實施例確能達到所預期之使用功 t又其㈣露之具體構造,不僅未曾見諸於同類產品 ,亦未W公開於中請前,誠已完全符合專利法之規定 Γ要求’支依法提出新型專利之巾請,®請惠予審查, 並賜准專利,則實感德便。 [0018] 【圖式簡單說明】 第一圖:本創作之第一製造步驟圖 表單編號A0101 第7頁/共10頁 M361504 [0019] 第二圖 :本創作之第二製造步驟圖 [0020] 第三圖 :本創作之第三製造步驟圖 [0021] 第四圖 :本創作之第四製造步驟圖 [0022] 第五圖 :本創作之立體圖 【主要元件符號說明】 [0023] (1)鋁基材(11)第一氧化層 (12)保護層(13)外露部 • (14)第二氧化層 表單編號A0101 第8頁/共10頁[0017] 2. The second oxide layer of the present invention is not formed on the outer surface of the first oxide layer, so that the first oxide layer and the second oxide layer can form a predetermined shape according to the shape of the light portion. And can improve the yield of anode treatment, while also improving the overall strength. In summary, the present embodiment can achieve the expected use of the work and its (four) exposed concrete structure, not only has not seen in the same kind of products, nor has it been disclosed before the middle of the request, Cheng has fully complied with the patent law It is stipulated that it is required to 'provide a new type of patent towel according to law. Please give us a review and grant a patent. [0018] [First description of the drawing] First drawing: First manufacturing step of the creation drawing Form No. A0101 Page 7 / Total 10 pages M361504 [0019] Second drawing: Second manufacturing step diagram of the present creation [0020] The third figure: the third manufacturing step of the creation [0021] The fourth picture: the fourth manufacturing step of the creation [0022] The fifth picture: the perspective of the creation [the main component symbol description] [0023] (1) Aluminum substrate (11) First oxide layer (12) Protective layer (13) Exposed portion • (14) Second oxide layer Form No. A0101 Page 8 of 10

Claims (1)

M361504 六、申請專利範圍: 種鋁合金表面之多色結構,係具有鋁基材,鋁基材之 外表面形成有第—氧化層,第一氧化層之外表面形成有保護 層並局部移除第一氧化層、保護層而形成有鋁基材之外露 部,外露部形成有第二氧化層。 2.如申請專利範圍第1項所述之鋁合金表面之多色結構,其 中’該氧化層係由草酸陽極處理液〔〇xalic acid anodixing Electrolyte〕所形成。 3 _如申睛專利範圍第1項所述之銘合金表面之多色結構,其 中’ 5亥氧化層係由確化有機酸〔sulfonated Organic Acid〕與硫酸〔suifuric acid〕混合之陽極處理液所形 成。 4. 如申請專利範圍第1項所述之铭合金表面之多色結構,其 中’該保護層係由透明液體金油〔clear coat〕所構成。 5. 如申請專利範圍第4項所述之鋁合金表面之多色結構,其 中’該透明液體金油〔clear coat〕為抗強酸之橡膠透明 漆。 6 ·如申請專利範圍第4項所述之銘合金表面之多色結構,其 中,該透明液體金油〔clear coat〕為抗強酸之石夕膠透明 漆。 7 ·如申請專利範圍第4項所述之鋁合金表面之多色結構,其 中’該透明液體金油〔clear coat〕為抗強酸之乳膠透明 漆。 表單编號A01G1 第9頁/共10頁M361504 VI. Scope of Application: The multi-color structure of the aluminum alloy surface has an aluminum substrate. The surface of the aluminum substrate is formed with a first oxide layer. The outer surface of the first oxide layer is formed with a protective layer and is partially removed. An exposed portion of the aluminum substrate is formed on the first oxide layer and the protective layer, and a second oxide layer is formed on the exposed portion. 2. The multicolor structure of the surface of an aluminum alloy according to claim 1, wherein the oxide layer is formed of oxalate anodizing electrolyte. 3 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ . 4. A multi-color structure of the surface of the alloy of the alloy described in claim 1 wherein the protective layer consists of a clear liquid coat. 5. The multicolor structure of the surface of the aluminum alloy according to item 4 of the patent application, wherein the transparent liquid is a rubber transparent paint resistant to strong acid. 6) The multi-color structure of the surface of the alloy of the alloy described in claim 4, wherein the clear liquid is a strong acid-resistant lacquer transparent lacquer. 7. The multicolor structure of the surface of the aluminum alloy according to item 4 of the patent application, wherein the transparent liquid coat is a strong acid resistant latex clear paint. Form No. A01G1 Page 9 of 10
TW97223039U 2008-12-22 2008-12-22 Multicolor structure of aluminum alloy surface TWM361504U (en)

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