TWI321850B - - Google Patents

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TWI321850B
TWI321850B TW95123911A TW95123911A TWI321850B TW I321850 B TWI321850 B TW I321850B TW 95123911 A TW95123911 A TW 95123911A TW 95123911 A TW95123911 A TW 95123911A TW I321850 B TWI321850 B TW I321850B
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region
film
gate
insulating film
element isolation
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TW95123911A
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TW200802859A (en
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Taiji Ema
Kazuhiro Mizutani
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Fujitsu Microelectronics Ltd
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九、發明說明: 發明領域 本發明係有關於一種半導體裝置及半導體裝置之製造 方法’特別是有關於一種於複數活性區域上具有高度不同 之構造物之半導體裝置及半導體裝置之製造方法。半導體 裝置典蜇為包含具有浮閘之非依電性記憶體胞元及邏輯電 路之MOS電晶體。 【先前技術3 發明背景 在半導體積體電路裝置(1C)中,邏輯電路為減低耗費電 力,而以具有η通道MOS(NMOS)電晶體及p通道m〇s(PMOS) 電晶體之互補式MOS(CMOS)電路形成。隨著半導體積體電 路裝置(ic)之高積體化、高速化之要求,作為IC構成要件之 電晶體逐漸細微化。當依比例規則細微化時,電晶體之動 作速度提高’動作電壓降低。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a semiconductor device and a method of fabricating the same, and more particularly to a semiconductor device and a semiconductor device manufacturing method having structures having different heights in a plurality of active regions. The semiconductor device is a MOS transistor including a non-electric memory cell having a floating gate and a logic circuit. [Prior Art 3] In the semiconductor integrated circuit device (1C), the logic circuit is to reduce power consumption, and a complementary MOS having an n-channel MOS (NMOS) transistor and a p-channel m〇s (PMOS) transistor (CMOS) circuit formation. With the demand for high integration and high speed of the semiconductor integrated circuit device (ic), the transistor which is an IC component is gradually miniaturized. When the scale rule is fined, the operating speed of the transistor is increased and the operating voltage is lowered.

LOCOS(l〇cal oxidation of silicon)之元件隔離區域當 從目標之氧化矽膜厚厚度逐漸減少之鳥嘴部形成使活性區 域狹小之無用面積’而妨礙積體度提高。因而廣泛使用STI (shallow trench isolation)。 sti之元件隔離區域如以下作成。將碎基板表面熱氣 化’形成緩衝氧化矽膜,於其上以化學氣相沉積(CVD)沉積 氮化石夕膜。形成具有對應元件隔離區域之開口圖案之光阻 圖案,將氮化矽膜、氧化矽膜蝕刻。以經形成圖案之氮化 石夕膜作為光罩’將梦基板㈣’而形成元件隔離溝。以元 件隔離溝分隔活性區域1元件隔離溝表面熱氧化後,藉 高密度«(HDP)CVD等以氧化石夕膜埋入元件隔離溝。藉化 學機械研磨(CMP)去除氮化矽膜上之氧化矽膜。在此,氮化 矽臈具有CMP用阻止層(stopper)之功能。CMp後之晶圓表 面平坦化。以熱磷酸去除露出之氮化矽膜,以稀氫氟酸將 氧化矽膜蝕刻去除,而露出活性區域表面。 於STI形成後,將活性區域表面熱氧化而形成離子植入 用氧化矽膜,進行配合各晶體之井形成用、通道阻絕用、 閾值調整狀離子獻。於料植人後,將齡氧化石夕膜 蝕刻去除。重新將活性區域熱氧化而形成閘氧化矽膜。當 形成厚度不同之閘氧化石夕膜時,將一部份之閘氧化石夕膜钱 刻去除,形成新之閘氧化矽膜。於閘氧化矽膜上沉積聚矽 等閘電極層,而以使用光阻罩之蝕刻來形成圖案。 STI之元件隔離區域表面較活性區域表面高。在緩衝氧 化石夕膜之钱刻中,當進行過度餘刻時,亦餘刻STI氧化膜, 使露出之活性區域周邊之STI氧化矽膜後退,同時,形成從 活性區域表面向下凹陷之凹部。當反複進行熱氧化、熱氧 化矽膜蝕刻之步驟時,活性區域周邊之STI氧化矽膜更後 退,同時,從活性區域表面向下凹陷之凹部凹陷更深。 當晶圓上之元件隔離區域之分佈密度不同時,在密度 低之區域,在CMP時產生凹形扭曲。當產生凹形扭曲時, 在該區域STI從基板表面突出之突出量減少。The element isolation region of the LOCOS (l〇cal oxidation of silicon) forms an unnecessary area which narrows the active area from the bird's mouth portion whose thickness is gradually reduced from the target, and hinders the increase in the degree of integration. Therefore, STI (shallow trench isolation) is widely used. The element isolation area of sti is as follows. The surface of the broken substrate is thermally vaporized to form a buffered yttria film on which a nitriding film is deposited by chemical vapor deposition (CVD). A photoresist pattern having an opening pattern corresponding to the element isolation region is formed, and the tantalum nitride film or the hafnium oxide film is etched. The element isolation trench is formed by forming a patterned nitride film as a photomask "dream substrate (4)". After the surface of the active trench is separated by the element isolation trench, the surface of the trench is thermally oxidized by a high-density «HDP CVD or the like to embed the component isolation trench. The yttrium oxide film on the tantalum nitride film is removed by chemical mechanical polishing (CMP). Here, tantalum nitride has a function as a stopper for CMP. The wafer surface after CMp is flattened. The exposed tantalum nitride film is removed by hot phosphoric acid, and the hafnium oxide film is removed by etching with dilute hydrofluoric acid to expose the surface of the active region. After the formation of the STI, the surface of the active region is thermally oxidized to form a cerium oxide film for ion implantation, which is used for forming a well for each crystal, for blocking a channel, and for adjusting a threshold. After the implant is implanted, the aged oxide oxide film is etched away. The active region is thermally oxidized again to form a cerium oxide film. When a gate oxide film of different thickness is formed, a part of the gate oxide film is removed to form a new gate oxide film. A gate electrode layer such as a germanium is deposited on the gate oxide film, and a pattern is formed by etching using a photoresist mask. The surface of the element isolation region of the STI is higher than the surface of the active region. In the buffering of the oxidized oxide film, when the excessive residue is performed, the STI oxide film is also left, so that the STI yttrium oxide film around the exposed active region retreats, and at the same time, the concave portion which is recessed downward from the surface of the active region is formed. . When the steps of thermal oxidation and thermal oxidization of the ruthenium film are repeated, the STI ruthenium oxide film around the active region is further retracted, and at the same time, the concave portion recessed downward from the surface of the active region is deeper. When the distribution density of the element isolation regions on the wafer is different, in the region where the density is low, concave distortion occurs during CMP. When a concave twist is generated, the amount of protrusion of the STI protruding from the surface of the substrate in the region is reduced.

曰本專利公開公報2003-297950號指出在包含DRAM 記憶體胞元及周邊電路區域之積體電路裝置中,當形成STI 時,因圖案密度之差在周邊電路區域產生凹形扭曲,而氧 化矽膜尚度產生高低差,在周邊電路區域中,當相對於矽 基板表面之STI高度為20nm時,閘絕緣膜之缺陷密度最小, 而在δ己憶體胞元區域中,當sti高度為〇nm時,閘絕緣膜之 缺陷密度最小,因而提出於STI氧化矽膜之CMP後,以光罩 覆蓋周邊電路區域,將記憶體胞元區域之钱刻,使其較 周邊電路區域之STI高度低約20nm。藉此選擇性蝕刻,STI 從/舌性區域表面之突出量在周邊電路區域約2〇nm,在記憶 體胞元區域約〇nm,而可實現上述最佳之STI高度。 曰本專利公開公報2006-32700號指出在DRAM記憶體 胞元區域與周邊電路區域中,當STI相對於矽基板表面之突 出量有差時’光微影技術之範圍減少,而提出在形成811, 進而於各活性區域植入離子之步驟中,使用同一光罩,將 離子植入記憶體胞元區域,蝕刻記憶體胞元之STI,將所有 晶圓區域内之STI突出量平均化。當選擇性蝕刻周邊電路區 域之記憶體胞元區域時,STI之突出量均一化。日本專利公 開公報2003-297950號同樣將將記憶體胞元之STI蝕刻,使 突出量減少,但其目的、蝕刻之時間、蝕刻量不同。 該等提案係有關於將DRAM記憶體胞元與周邊電路區 域積體化時之STI突出量調整者。 混合搭載可改寫之非依電性半導體記憶體之邏輯半導 體裝置形成稱為CPLD(complex programmable logic devic e)、FPGA(field programmable gate array)之製品分野,藉 其可程式之特徵’而發展至形成大市場。可改寫之非依電 性半導體記憶體之典型例為將 以NMOS電晶體之閘絕緣膜 及以其上之閑電極形成之絕緣閘電極構造置換成層疊通道 絕緣膜、、子閉電極、閘間絕緣膜、控制閘之閘電極構造的 快閃記憶體胞元。由於於浮閘電極寫人/刪除f荷,或以控 制電極之電壓藉由浮閘電極控制通道,故動作電壓增高。 在混合搭載非依電性記憶體之邏輯半導體裝置中,除 了㈣減_元外’亦將用以控制㈣記憶體胞元之高 電壓電晶體及供高性能邏輯電路之低電壓電晶體層疊於同 一半導體晶片上。形成閾值低之電晶體及閾值高之電晶體 需改變閾值調整用離子植入之條件。當在麵〇§區域、pM OS區域分別進行獨立之離子植人時,為了高電壓動作(^〇 S、低電壓動作CMOS之4種電晶體,需4片光罩及8次之離 子植入。 國際專利公開公報W02004/093192號揭示除了形成快 閃記憶體外,尚形成在高電壓動作、低電壓動作具有高閾 值及低閾值之NMOS電晶體及PMOS電晶體以及外部輸入 信號用中電壓N Μ 0 S電晶體及P Μ 0 S電晶體共計丨丨種電晶 體之步驟。提出以3片光罩、4次之離子植入進行3種1<^1〇8 (或PMOS)電晶體用之離子植入之方法。 於動作電壓不同之電晶體區域形成厚度不同之多種閉 絕緣臈。為形成厚閘氧化矽膜及薄閘氧化矽膜先於所有舌 性區域表面形成厚閘氧化矽膜,在形成薄閘氧化矽獏之區 域選擇性地去除厚閘氧化矽膜。之後,形成薄閘氧化石夕膜 為形成3鮮度之卩找化頻驗行2&f錢切酿刻步 驟及之後之閘氧化矽膜形成步驟。於蝕刻氧化矽膜時,進 行過度蝕刻,亦將活性區域周圍之元件隔離區域之氧化矽 膜蝕刻。當反複進氧化矽膜蝕刻時,元件隔離區域具有在 與活性區域之邊界無法忽視之凹部。 快閃記憶體之閘電極於浮閘上具有藉由〇N〇膜(氧化 石夕膜/氮化石夕膜/氧化石夕膜)而層疊控制閘之構造。浮閘為呈 電性浮遊狀態之閘電極,一般以聚矽形成,以2次之蝕刻步 驟形成圖案。以ΟΝΟ膜覆蓋表面之聚石夕層之触刻未必容 易。活性區域之周邊為具有凹部或突出之STI包圍,在斜面 上形成圖案使困難性增加。由於快閃記憶體之控制閘電極 形成於浮閘上,故表面較周圍電路之MOS電晶體之閘電極 高0 將快閃記憶體區域及邏輯電路區域積體化之半導體裝 置產生與將DRAM記憶體胞元區域及邏輯電路區域積體化 之半導體裝置不同之問題。 專利文獻1:日本專利公開公報2003-297950號 專利文獻2 :曰本專利公開公報2006-032700號 專利文獻3 :國際公開WO2004/093192號公報 【發明内容】 發明概要 對新的問題要求新的解決技術。 本發明之目的在於提供一種可解決新問題之半導體裝 置及半導體裝置之製造方法。 1321850 本發明之另一目的在於提供一種產率高之半導體裝置 及半導體裝置之製造方法。 本發明之再另一目的在於提供一種光微影製程之範圍 大之半導體裝置及半導體裝置之製造方法。 5 本發明之又另一目的在於提供一種可防止導電性材料 之殘渣產生問題之半導體裝置及半導體裝置之製造方法。 根據本發明之一觀點,提供一種半導體裝置,其係包 含有具有第1區域及第2區域之半導體基板、由形成於前述 半導體基板之元件隔離溝及埋入該元件隔離溝之絕緣膜形 10 成,且分隔前述第1區域與前述第2區域之複數活性區域之 STI元件分離區域、形成於前述第1區域之活性區域上至周 圍之STI元件隔離區域,並具有第1高度之第1構造物及形成 於前述第2區域之活性區域上至周圍之STI元件隔離區域, 並具有較前述第1高度低之第2高度之第2構造物;前述第1 15 區域之STI元件隔離區域之表面較前述第2區域之STI元件 隔離區域之表面低。 根據本發明之另一觀點,提供一種半導體裝置之製造 方法,其係包含有以下步驟: (a) 於具有第1區域及第2區域之半導體基板形成具有分 20 隔複數活性區域之元件隔離區域形狀開口之光罩絕緣膜形 圖案; (b) 將前述光罩絕緣膜圖案作為蝕刻光罩,蝕刻半導體 基板,而形成用以分隔複數活性區域之元件隔離溝; (c) 埋入前述元件隔離溝,沉積元件隔離材料膜; 10 1321850 (d) 將前述元件隔離材料膜以化學機械研磨,形成元件 隔離區域,同時,露出前述光罩絕緣膜圖案; (e) 於前述步驟(d)之後,形成覆蓋前述第2區域之光阻 圖案,將前述第1區域之前述元件隔離區域蝕刻,去除前述 5 活性區域上之厚度之一部份; (f) 於前述步驟(e)之後,去除前述光罩絕緣膜圖案; (g) 於前述步驟⑴之後,形成從前述第1區域之活性區 域上延伸至其周圍之前述元件隔離區域上並具有第1高度 之第1構造物; 10 (h)於前述步驟(f)之後,形成從前述第2區域之活性區 域上延伸至其周圍之前述元件隔離區域上並具有較第1高 度低之第2高度之第2構造物。 可解決新的課題。 可抑制在非平坦面上形成圖案。 15 可抑制蝕刻之殘渣。 可減少高低差,而擴大光微影製程之範圍。 圖式簡單說明 [第1-1圖]/[第1-2圖]/[第1-3]/[第1-4圖]第1A圖-第II 圖、第1K圖係顯示本發明第1實施例之半導體裝置製程之截 20 面圖。第1J圖係顯示閘電極之配置之平面圖。 [第2-1圖]/[第2-2圖]/[第2-3]第2A圖-第2F圖係顯示本 發明第2實施例之半導體裝置製程之截面圖。 [第3圖]第3A圖、第3B圖係顯示本發明第3實施例之半 導體裝置製程之截面圖。 11 1321850 第95123911號申請案說明書修正頁’ 月切日修(免正替换y [第4圖]第4圖係具體實施例之具有丨丨種電晶體之半導 體裝置之截面圖。 [第5-1圖]/[第5_2圖]/[第5-3]/[第5_4圖;|/[第5·5]第5八圖 -第5J圖係顯示第4圖所示之半導體裝置製程之截面圖。 5 [第6_ 1圖]/[第6-2圖]7[第6-3]第6Α圖-第6Η圖係說明混 合搭載快閃記憶體及邏輯電路之半導體積體電路裝置之新 課題之截面圖。Japanese Patent Laid-Open Publication No. 2003-297950 discloses that in an integrated circuit device including a DRAM memory cell and a peripheral circuit region, when an STI is formed, a concave distortion occurs in a peripheral circuit region due to a difference in pattern density, and yttrium oxide is formed. The film has a height difference. In the peripheral circuit region, when the STI height is 20 nm with respect to the surface of the germanium substrate, the defect density of the gate insulating film is the smallest, and in the region of the delta memory cell, when the height of sti is 〇 In nm, the defect density of the gate insulating film is the smallest, so it is proposed that after the CMP of the STI yttrium oxide film, the peripheral circuit region is covered with a photomask, and the memory cell region is engraved to make it lower than the STI of the peripheral circuit region. About 20nm. By this selective etching, the amount of protrusion of the STI from the surface of the lingual region is about 2 〇 nm in the peripheral circuit region and about 〇 nm in the memory cell region, and the above-described optimum STI height can be achieved. Japanese Patent Laid-Open Publication No. 2006-32700 indicates that in the DRAM memory cell region and the peripheral circuit region, when the amount of protrusion of the STI with respect to the surface of the ruthenium substrate is poor, the range of the photo lithography technique is reduced, and it is proposed to form 811. Further, in the step of implanting ions in each active region, ions are implanted into the memory cell region using the same mask, and the STI of the memory cells is etched to average the STI protrusion amounts in all the wafer regions. When the memory cell region of the peripheral circuit region is selectively etched, the amount of protrusion of the STI is uniformized. In Japanese Patent Laid-Open Publication No. 2003-297950, the STI of the memory cell is also etched to reduce the amount of protrusion, but the purpose, the etching time, and the etching amount are different. These proposals are related to the adjustment of the STI protrusion amount when the DRAM memory cell is integrated with the peripheral circuit area. A logic semiconductor device in which a rewritable non-electrical semiconductor memory device is mixed is formed into a product division called a CPLD (complex programmable logic devic e) or an FPGA (field programmable gate array), and is developed to form by a programmable feature. Big market. A typical example of the rewritable non-electrical semiconductor memory is to replace the insulating gate structure formed by the gate insulating film of the NMOS transistor and the dummy electrode thereon with a laminated channel insulating film, a sub-closed electrode, and a gate. A flash memory cell of an insulating film and a gate electrode of a control gate. Since the floating gate electrode writes/deletes the f-charge, or the voltage of the control electrode is controlled by the floating gate electrode, the operating voltage is increased. In a logic semiconductor device in which a non-electrical memory is mixed, in addition to (4) minus _ yuan, a high voltage transistor for controlling (4) memory cells and a low voltage transistor for high performance logic circuits are stacked on each other. On the same semiconductor wafer. Forming a transistor with a low threshold and a transistor with a high threshold requires changing the conditions for ion implantation of the threshold adjustment. When independent ion implantation is performed in the area p § area and pM OS area, 4 pieces of reticle and 8 times of ion implantation are required for high voltage operation (4 电S, low voltage operation CMOS 4 kinds of transistors) International Patent Publication No. WO2004/093192 discloses that in addition to forming a flash memory, an NMOS transistor and a PMOS transistor having a high threshold and a low threshold with high voltage operation and low voltage operation and a medium voltage N 外部 for an external input signal are formed. The 0 S transistor and the P Μ 0 S transistor have a total of the steps of the transistor. It is proposed to use three kinds of photomasks and four times of ion implantation for three kinds of 1 <^1〇8 (or PMOS) transistors. Method for ion implantation: forming a plurality of kinds of closed insulating defects having different thicknesses in a region of a transistor having different operating voltages. To form a thick gate oxide film and a thin gate oxide film, a thick gate oxide film is formed on the surface of all tongue regions. Selectively remove the thick gate yttrium oxide film in the region where the thin gate yttrium oxide is formed. Thereafter, the thin gate oxidized oxide film is formed to form a 3 freshness 卩 化 频 验 验 2 & & & & & & & & & Gate yttria film formation step. When the ruthenium oxide film is etched, over-etching is performed, and the ruthenium oxide film of the element isolation region around the active region is also etched. When the ruthenium oxide film is repeatedly etched, the element isolation region has a recess that cannot be ignored at the boundary with the active region. The gate electrode of the flash memory has a structure in which a gate is controlled by a 〇N〇 film (the oxidized stone film/nitridium film/oxidized stone film) on the floating gate. The floating gate is a gate that is electrically floating. The electrode is generally formed by polyfluorene, and is patterned by a second etching step. The contact of the polycrystalline layer covering the surface with the ruthenium film is not necessarily easy. The periphery of the active region is surrounded by a STI having a concave portion or a protrusion, and is formed on the inclined surface. The pattern increases the difficulty. Since the control gate electrode of the flash memory is formed on the floating gate, the surface is higher than the gate electrode of the MOS transistor of the surrounding circuit. The semiconductor of the flash memory region and the logic circuit region is integrated. The device has a problem that is different from a semiconductor device in which a DRAM memory cell region and a logic circuit region are integrated. Patent Document 1: Japanese Patent Laid-Open Publication No. 2003-297950 Patent Document 2: PCT Patent Publication No. 2006-032700 Patent Document 3: International Publication No. WO2004/093192 SUMMARY OF INVENTION Summary of the Invention A new solution is required for a new problem. It is an object of the present invention to provide a new solution A semiconductor device and a method of manufacturing a semiconductor device. 1321850 Another object of the present invention is to provide a semiconductor device with high yield and a method for manufacturing the semiconductor device. Still another object of the present invention is to provide a range of photolithography processes. A semiconductor device and a method of manufacturing a semiconductor device. Further, another object of the present invention is to provide a semiconductor device and a method of manufacturing a semiconductor device which can prevent a problem of generation of a residue of a conductive material. According to an aspect of the invention, there is provided a semiconductor device including a semiconductor substrate having a first region and a second region, an element isolation trench formed in the semiconductor substrate, and an insulating film shape embedded in the element isolation trench 10 And forming an STI element isolation region of the plurality of active regions of the first region and the second region, and forming an STI element isolation region on the active region of the first region to a surrounding STI element isolation region, and having a first structure having a first height And a second structure formed on the active region of the second region to the surrounding STI element isolation region and having a second height lower than the first height; and a surface of the STI element isolation region of the first 15 region It is lower than the surface of the STI element isolation region of the second region. According to another aspect of the present invention, a method of fabricating a semiconductor device comprising the steps of: (a) forming an element isolation region having a plurality of active regions of 20 divisions in a semiconductor substrate having a first region and a second region; (b) etching the semiconductor substrate as the etching mask to form an element isolation trench for separating the plurality of active regions; (c) embedding the component isolation Ditch, deposition element isolation material film; 10 1321850 (d) The aforementioned element isolation material film is chemically mechanically polished to form an element isolation region while exposing the reticle insulating film pattern; (e) after the aforementioned step (d), Forming a photoresist pattern covering the second region, etching the element isolation region of the first region to remove a portion of the thickness of the 5 active regions; (f) removing the light after the step (e) a cover insulating film pattern; (g) after the foregoing step (1), forming the aforementioned element isolation region extending from the active region of the first region to the periphery thereof a first structure having a first height; 10 (h) after the step (f), forming the element isolation region extending from the active region of the second region to the periphery thereof and having a lower height than the first height The second structure of the second height. Can solve new problems. Patterning on a non-flat surface can be suppressed. 15 can suppress the residue of etching. It can reduce the height difference and expand the range of the photolithography process. BRIEF DESCRIPTION OF THE DRAWINGS [Fig. 1-1]/[1-2th]/[1-3]/[1-4th] 1A-II, 1K shows the present invention Fig. 20 is a cross-sectional view showing the process of the semiconductor device of the embodiment. Fig. 1J is a plan view showing the arrangement of the gate electrodes. [Fig. 2-1] / [2-2] / [2-3] Fig. 2A - Fig. 2F are cross-sectional views showing the process of the semiconductor device of the second embodiment of the present invention. [Fig. 3] Figs. 3A and 3B are cross-sectional views showing the process of the semiconductor device according to the third embodiment of the present invention. 11 1321850 Application No. 95123911 Amendment Page 'Monthly Cut Repair (No Correct Replacement y [Fig. 4] Fig. 4 is a cross-sectional view of a semiconductor device having a transistor of a specific embodiment. [5- 1]][5-2]/[5-3]/[5th-4]; |/[5·5] 5th-8th - 5th shows the semiconductor device process shown in FIG. Fig. 5 [Fig. 6-1] / [6-2] 7 [6-3] Fig. 6 - Fig. 6 shows a semiconductor integrated circuit device in which a flash memory and a logic circuit are mixed. A cross-sectional view of the new topic.

C實施方式;J 較佳實施例之詳細說明 1〇 首先,參照第6八圖_第6G圖,說明根據習知技術之包 含快閃記憶體及邏輯電路之積體電路製造方法。 如第6A圖所示,將矽基板丨表面熱氧化,形成氧化矽膜 2後,於其上以化學氣相沉積(CVD)沉積氮化矽膜3。使用光 阻圖案使氮化石夕膜3、氧化石夕膜形成圖案,保留覆蓋活性區 B域之形狀之氧化石夕膜2、氮化石夕膜3。將氮化石夕膜冰為钱刻 光罩’將石夕基板姓刻,而形成元件隔離溝。將元件隔離溝 表面氧化後’以高密度電漿(HDp)CVD埋入氧化碎膜4。從 氧化石夕膜4表面進行化學機械研磨(CMP),錯氮化石夕膜3 表面水平面上之氧化矽膜4。 如第6B圖所不,以熱磷酸將氮化石夕臈敍刻去除。以稀 氫氟酸將露出之緩衝氧化石夕膜侧去除。此外,STI之氧化 石夕膜:稍微_。*可獲得隆起之STi_㈣區域周圍 ^構ie H將活性區域表面熱氧化而形成離子植入用 乳化石夕膜,配合各活性區域進行井形成用' 通道阻絕層形 12 成用、閾值控制用之離子植人。於離子植人後,去除犧牲 氧化石夕膜。活性區域周邊之STI之段差部(具有非平坦面之 部份)擴大至外側。 如第6C圖所示,將活性區域表面熱氧化,形成快閃記 憶體用通道氧化碎膜6。亦顯示藉反複進行之氧化石夕膜银 刻,在活性區域周邊於STI形成凹部之狀態。 如第6D圖所示,覆蓋通道氧化矽膜6,以CVD沉積聚 矽膜7,使用光阻圖案蝕刻,在閘寬度方向(圖中橫方向)上 形成圖案。在形成於STI周緣部之段差部垂直且完全蝕刻聚 矽膜7並不易。 如第6E圖所示,形成覆蓋聚矽膜7之ΟΝΟ膜8。舉例言 之,覆蓋聚矽膜7,於晶圓全面以CVD沉積氧化矽膜、氮化 石夕膜後,將氮化矽膜表面熱氧化,而形成氧化矽膜。於所 期之活性區域上形成具有開口之光阻圖案RP41,進行邏輯 電路區域之閾值控制用之離子植入。之後,去除光阻圖案 RP41 〇 如第6F圖所示,於去除ΟΝΟ膜8之區域形成具有開口之 光阻圖案RP42,將露出之ΟΝΟ膜蝕刻去除。藉此蝕刻步 驟’蝕刻快閃記憶體區域以外之STI,而使其表面降低。之 後,去除光阻圖案RP42。 如第6G圖所示,以CVD沉積用以形成閘電極之聚砂膜 9°以使用覆蓋周邊電路區域,且在快閃記憶體區域具有控 制閘電極形狀之光阻圖案之蝕刻使控制閘形成圖案,進% 亦使0Ν0膜8、浮閘7形成圖案。進行離子植入,形成快閃 記憶體之祕/祕區域。❹覆蓋_記龍區域且在周 邊電路區域具有閑電極形狀之光阻圖案,使邏輯電路之問 電極形成圖案。於祕電路崎離子植人,_成源極/淡 極區域。 5 糾圖係概略顯示快閃記憶體及周邊電路之MOS電晶 體之沒極電極形狀的平面I在左側所示之快閃記憶體 中,於控制問CG下配置浮閘FG,浮閘扣之圖中上下邊依 控制閘CG之上下邊形成圖案。於勉刻前,浮閉fg於閘寬度 方向形成圖案,而在控制閘⑺間等其他區域中,呈浮間 1〇層、ΟΝΟ膜、控制閘層層疊之狀態。#以银刻未完全隔離 浮閘時,便產生短路。然而,由於閘側壁上之〇Ν〇膜在外 觀上垂直方向之厚度增厚,故完全蝕刻去除並不易。 第6Η圖係顯示όνο膜未完全去除,殘留壁狀,且其下 部留有浮閘之聚矽膜7之狀態。當聚矽膜7相鄰之浮閘短路 15 時’便產生缺陷記憶體。即使僅剩餘ΟΝΟ膜8,薄壁狀之 ΟΝΟ膜仍可成為垃圾產生源。 快閃記憶體胞元之控制閘載置於浮閘上,且在存在於 較活性區域高之位置之STI上位於最高。另一方面,快閃記 憶體區域以外之STI表面在第6F圖所示之ΟΝΟ臈及通道氧 20化石夕膜之餘刻步驟中餘刻後降低,且閘電極下不具有浮 閘’故閘電極層表面最低之部份亦遠較快閃記憶體區域之 最高部份低。即,快閃記憶體區域全體較邏輯區域高,當 觀看半導體晶片全體時,快閃記憶體區域形成如梯形之區 域。於具有此高低差之基板上形成絕緣膜,形成接觸孔、 14 1321850 金屬配線等,形成多層配線構造,而僅此步驟差異,便導 致多層配線形成步驟之實貝焦點冰度減少。 以下’參照第1A圖-第1K圖,朗本發明第i實施例之 半導體裝置之製造方法。第1A圖-第II圖係顯示主要製程之 5截面圖,第1J圖係顯示閘電極形狀之平面圖’第1K圖係控 制閘間之截面圖。 如第1Α圖所示,將矽基板1表面熱氧化,形成厚度1〇η m之緩衝氧化矽膜2後’於其上以CVD沉積厚度u〇nm之氮 化矽膜3。使用光阻圖案’使氮化石夕膜3、氧化矽膜2形成圖 10 案,而以覆蓋活性區域之形狀保留以緩衝氧化石夕膜2、氮化 石夕膜3之層疊形成之光罩絕緣膜圖案.將氮化矽膜3作為敍 刻光罩’將石夕基板姓刻深度300nm’而形成元件隔離溝。以 HDPCVD將氧化㈣沉積厚度55Gnm,埋人元件隔離溝。從 氧化矽膜4表面進行CMP,去除氮化矽膜3表面水平面上之 15 氧化矽膜4。 • 如第1B圖所示’形成具有快閃記憶體開口區域之光阻 矽臈4突出, 而經飯刻之氧化矽膜4之凹部矣面承。法ΜC. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT 1 First, a method of manufacturing an integrated circuit including a flash memory and a logic circuit according to the prior art will be described with reference to Figs. 6-8 to 6G. As shown in Fig. 6A, the surface of the tantalum substrate is thermally oxidized to form a tantalum oxide film 2, on which a tantalum nitride film 3 is deposited by chemical vapor deposition (CVD). The nitride film 3 and the oxidized stone film are patterned by using a resist pattern, and the oxidized stone film 2 and the nitrided film 3 covering the shape of the active region B region are retained. The nitriding film of the nitriding stone is used as a money mask. The stone slab substrate is engraved to form an element isolation trench. After the surface of the element isolation trench is oxidized, the oxidized fragmentation film 4 is buried by high-density plasma (HDp) CVD. Chemical mechanical polishing (CMP) is performed from the surface of the oxidized stone film 4, and the ruthenium oxide film 4 is formed on the surface of the surface of the nitriding film 3. As shown in Fig. 6B, the nitriding stone is removed by hot phosphoric acid. The exposed buffered oxidized stone was removed by dilute hydrofluoric acid. In addition, STI's oxidized stone film: slightly _. * Around the STi_(4) area where the bulge can be obtained, the surface of the active area is thermally oxidized to form an emulsified stone film for ion implantation, and the active area is used for the formation of a channel for the well formation, and the threshold value is used for control. Ion implantation. After the ions are implanted, the sacrificial oxidized oxide film is removed. The step of the STI (the portion having the non-flat surface) around the active region is expanded to the outside. As shown in Fig. 6C, the surface of the active region is thermally oxidized to form a channel oxidized particle 6 for a flash memory. Also shown is a state in which a concave portion is formed in the STI around the active region by repeating the oxidized oxide film. As shown in Fig. 6D, the channel oxide film 6 is covered, and the polyimide film 7 is deposited by CVD, and etching is performed using a photoresist pattern to form a pattern in the gate width direction (the horizontal direction in the drawing). It is not easy to vertically and completely etch the polyimide film 7 at the step formed at the peripheral portion of the STI. As shown in Fig. 6E, a ruthenium film 8 covering the ruthenium film 7 is formed. For example, the polysilicon film 7 is covered, and after the yttrium oxide film and the nitriding film are deposited by CVD, the surface of the tantalum nitride film is thermally oxidized to form a yttrium oxide film. A photoresist pattern RP41 having an opening is formed on the active region to perform ion implantation for threshold control of the logic circuit region. Thereafter, the photoresist pattern RP41 is removed. As shown in Fig. 6F, a photoresist pattern RP42 having an opening is formed in a region where the ruthenium film 8 is removed, and the exposed ruthenium film is etched and removed. By this etching step, the STI outside the flash memory region is etched to lower the surface. Thereafter, the photoresist pattern RP42 is removed. As shown in FIG. 6G, the polysilicon film for forming the gate electrode is deposited by CVD to 9° to cover the peripheral circuit region, and the etching of the photoresist pattern having the shape of the gate electrode in the flash memory region is used to form the control gate. The pattern, the % of the pattern, also forms the pattern of the 0 Ν 0 film 8 and the floating gate 7. Ion implantation is performed to form the secret/secret area of the flash memory. The photoresist layer covering the _marking area and having the free electrode shape in the peripheral circuit region forms a pattern of the electrodes of the logic circuit. In the secret circuit, the ion is implanted, _ into the source / light pole area. 5 The correction system outlines the plane I of the shape of the electrode of the MOS transistor of the flash memory and the peripheral circuit. In the flash memory shown on the left side, the floating gate FG is arranged under the control CG. In the figure, the upper and lower sides are patterned according to the upper side of the control gate CG. Before the engraving, the floating fg is patterned in the width direction of the gate, and in the other regions such as the control gate (7), the floating layer 1 〇 layer, the enamel film, and the control gate layer are stacked. # When the silver gate is not completely isolated, the short circuit occurs. However, since the thickness of the ruthenium film on the sidewall of the gate is increased in the vertical direction, it is not easy to completely remove the ruthenium. Fig. 6 is a view showing a state in which the όνο film is not completely removed, the wall is left, and the polysilicon film 7 having the floating gate is left. When the floating gate adjacent to the polysilicon film 7 is short-circuited 15, a defective memory is generated. Even if only the ruthenium film 8 remains, the thin-walled ruthenium film can be a source of garbage generation. The control gate of the flash memory cell is placed on the floating gate and is at the highest STI present in the higher active region. On the other hand, the STI surface outside the flash memory region is reduced after the engraving step of the ΟΝΟ臈 and channel oxygen 20 fossil film shown in FIG. 6F, and there is no floating gate under the gate electrode. The lowest portion of the surface of the electrode layer is also much lower than the highest portion of the flash memory region. That is, the entire flash memory region is higher than the logic region, and the flash memory region forms a region such as a trapezoid when viewing the entire semiconductor wafer. An insulating film is formed on the substrate having such a height difference, and a contact hole, a 14 1321850 metal wiring or the like is formed to form a multilayer wiring structure, and only a difference in this step leads to a reduction in the focus of the multilayer wiring forming step. Hereinafter, a method of manufacturing a semiconductor device according to the first embodiment of the present invention will be described with reference to Figs. 1A to 1K. Fig. 1A - Fig. II are sectional views showing the main process, and Fig. 1J is a plan view showing the shape of the gate electrode. Fig. 1K is a sectional view of the control gate. As shown in Fig. 1, the surface of the tantalum substrate 1 is thermally oxidized to form a buffered hafnium oxide film 2 having a thickness of 1 μm, and a niobium nitride film 3 having a thickness of u〇nm is deposited thereon by CVD. The photoresist pattern 3 is used to form the nitride film 3 and the hafnium oxide film 2 in the form of FIG. 10, and the photomask insulating film formed by laminating the oxide oxide film 2 and the nitride film 3 is formed in a shape covering the active region. Pattern. The tantalum nitride film 3 is used as a masking mask to form a component isolation trench with a depth of 300 nm. The oxide (4) was deposited by HDPCVD to a thickness of 55 Gnm, and the element isolation trench was buried. The ruthenium oxide film 4 on the surface of the surface of the tantalum nitride film 3 is removed by CMP from the surface of the tantalum oxide film 4. • As shown in Fig. 1B, the photoresist 矽臈4 having the open area of the flash memory is formed to protrude, and the concave portion of the ruthenium oxide film 4 which has been etched by the rice is covered. Law

圖案则’將HDPCVD氧化賴4钱刻達活性區域表面上之 : ]約4〇nm。在快閃記憶體區域中,氮化矽膜3從氧化 不,以熱磷酸將氮化矽膜3蝕刻去除。以稀 之緩衝氧化矽膜2蝕刻去除。STI亦同時蝕 15 1321850 ^51239〗1號申請案說明'^^~ 98. 刻The pattern is then etched by HDPCVD to the surface of the active area: ] about 4 〇 nm. In the flash memory region, the tantalum nitride film 3 is etched away, and the tantalum nitride film 3 is etched away by hot phosphoric acid. It is removed by etching with a thin buffered yttrium oxide film 2. STI also eclipses 15 1321850 ^51239〗 No. 1 application description '^^~ 98. Engraved

______jU 而在邏輯電路區域可獲得隆起之STI包圍活性區域周圍 之構每。之後ϋ性區域表面熱氧化而形成離子植入用 氧切膜’配合各活性區域進行絲助、通道阻絕層形 成用、間值控湘之離子植人。於離子植人後,去除犧牲 氧化石夕膜。奶之氧化補4亦_,而使活性區域周圍之 凹部加深。將活性區域表面熱氧化,形成厚度101nm左右之 快閃記憶龍元料道氧化销6。在㈣記㈣區域中, 在第1B圖之步驟,STI表面因_而下降,因氧化賴之姓 10 刻STI表面進-步下降。若去除活性區域周圍之凹部活性 區域周圍之段差便小。 如第1D圖所示,覆蓋氧化石夕膜6,以CVD沉積厚度9〇腿 之聚石夕膜7,使用光阻圖案姓刻,而在間寬度方向(圖中橫 方向)上形成圖案。由於快閃記憶體區域之STi表面下降, 而使段差小,故垂直且完全蝕刻聚矽膜7便容易。 15 如第1E圖所示,形成覆蓋聚矽膜7之ΟΝΟ膜舉例言 之,覆蓋聚矽膜7而於晶圓全面以CVD沉積厚度約1〇nm之 氮化矽膜,將氮化矽膜表面熱氧化,而形成厚度約5nm之氧 化矽膜。ΟΝΟ膜8全體之厚度約15nm。於所期之活性區域 上形成具有開口之光阻圖案RP12 ,進行邏輯電路區域之閾 20值控制用之離子植入。之後,去除光阻圖案RP12。______jU is obtained in the logic circuit area where the swelled STI surrounds the active area. Then, the surface of the inert region is thermally oxidized to form an oxygen-cut membrane for ion implantation, and the active regions are used for silk assisting, channel blocking layer formation, and ion-controlled ion implantation. After the ions are implanted, the sacrificial oxidized oxide film is removed. The oxidation of the milk is also _, and the recess around the active area is deepened. The surface of the active region is thermally oxidized to form a flash memory dragon element with a thickness of about 101 nm. In the (4) (4) region, in the step of Figure 1B, the STI surface is degraded by _, and the STI surface is stepped down due to the oxidation of the surname. If the removal of the area around the active area of the recess around the active area is small, the difference will be small. As shown in Fig. 1D, the oxidized stone film 6 was covered, and a concentrating film 7 having a thickness of 9 〇 was deposited by CVD, and a pattern was formed in the inter-width direction (horizontal direction in the drawing) by using a photoresist pattern. Since the STi surface of the flash memory region is lowered and the step is small, it is easy to vertically and completely etch the polyimide film 7. 15 As shown in FIG. 1E, a tantalum film covering the polysilicon film 7 is formed by, for example, covering the polysilicon film 7 and depositing a tantalum nitride film having a thickness of about 1 nm on the wafer by CVD. The surface is thermally oxidized to form a hafnium oxide film having a thickness of about 5 nm. The thickness of the entire ruthenium film 8 is about 15 nm. A photoresist pattern RP12 having an opening is formed on the active region to perform ion implantation for controlling the threshold value of the logic circuit region. Thereafter, the photoresist pattern RP12 is removed.

第1F圖所示,於去除〇N◦膜8之區域形成具有開口之光 阻圖案RP13,將露出之ΟΝΟ膜8蝕刻去除》進一步,將露 出之通道氧化矽膜6蝕刻去除。藉此蝕刻,快閃記憶體區域 以外之STI亦去除,而使其表面降低。惟,邏輯區域之STI 16 1321850 表面高度較快閃記憶體區域之STI表面高度高。之後,去除 光阻圖案RP13。 如第1G圖所示,以熱氧化於邏輯區域之活性區域表面 形成氧化矽之閘絕緣膜G1。當形成3種厚度之閘絕緣獏時, 5 反複進行2次熱氧化、選擇性熱氧化蝕刻後,再熱氧化,而 從厚氧化矽膜依序形成薄氧化矽膜。因而邏輯區域之STI 表面降低,亦可呈較快閃記憶體區域之STI表面高之狀態。 又’即使較快閃記憶體區域低,相較於習知技術,其差亦 '缩小。活性區域周圍之凹部加深。 10 如第1Η圖所示,以CVD沉積用以形成閘電極之聚矽膜 9 ’使用覆蓋邏輯區域且在快閃記憶體區域具有控制閘電極 形狀之光阻圖案RP14,蝕刻聚矽膜9,進而亦蝕刻ΟΝΟ膜 '浮閘7 ’使快閃記憶體之閘電極形成圖案。在此階段, 邏輯電路區域為光阻圖案RP14覆蓋,而未蝕刻。進行離子 植入’而形成快閃記憶體之源極/汲極區域。之後,去除光 阻圖案RP14。進行閘電極側面之氧化等處理,作成快閃記 憶體構造。 如第II圖所示,新形成覆蓋快閃記憶體區域並具有邏 輯電路區域之閘電極形狀之光阻圖案RP15,蝕刻聚矽膜9, 2〇使邏輯電路區域之閘電極形成圖案。之後,進行邏輯電路 之離子植入,形成源極/汲極區域。之後,去除光阻圖案 RP15 〇 第1J圖係概略顯示快閃記憶體及MOS電晶體之閘電極 己置的平面圖。於圖中縱方向配置細長之活性區域AR。 17 在邏輯電路中,MOS電晶體之閘電極g橫亙活性區域AR, 而於sti元件隔離區域上延伸。在快閃記憶體中,浮閘FG、 控制閘CG橫亙活性區域而於STI元件隔離區域上延伸。在 控制閘CG間之區域中,浮閘FG及控制閘CG完全蝕刻,而 5不存在殘渣。並不期待有第6H圖所示之0N0膜8、聚矽膜7 之殘渣。由於在快閃記憶體區域中,活性區域及周邊之STI 段差小,故可輕易進行未遺留殘渣之姓刻。 第1K圖係顯示沿第丨j圖之χ2_χ2線之控制閘CG間之區 域的截面圖》由於基層表面之段差小,故控制閘、浮閘之 10完全触刻容易’可防止浮閘間之短路。此外,第^圖第U 圖係沿X1-X1線之截面圖。 之後,進行電極形成、絕緣膜形成、多層配線形成步 驟等。快閃記憶體區域之STI表面下降,邏輯區域之閘電極 表面水平面在快閃記憶體區域之閘電極表面水平面之分佈 範圍内’在第1H圖、第II圖之步驟中,由於聚石夕膜9之高低 差較習知技術減少,故光微影技術之焦點深度問題減小。 當進行使快閃記憶體區域之表面下降之處理時,於 快閃記憶體區域與邏輯區域間形成段差,此段差部上之膜 形成、去除有產生問題之可能性。參照第2八圖_第邛圖,以 2〇與第1實施形不同之點為中心說明第2實施例之半導體裝置 之製造方法。 。第2A圖與第1A圖相同。將石夕基板i表面熱氧化,形成 緩衝氧化矽膜2後,於其上以CVD沉積氮化矽膜3。使用光 阻圖案,使氮化㈣3、氧化賴2形成圖案,將氮化石夕膜3 18 作為钱刻光罩’將石夕基板餘刻,形成元件隔離溝。以HDP CVD將氧化⑪削沉積,埋人元件隱溝。從氧化碎膜4表 面進行CMP ’去除氮化石夕膜3表面水平面上之氧化石夕膜4。 如第2B圖所示,於周邊留有空隙,形成使快閃記憶體 5區域開口之光阻圖案RP21,將HDPCVD氧化矽膜4蝕刻達活 性區域表面上之厚度之中間。快閃記憶體區域之STI表面下 降而於退離快閃δ己憶體區域之活性區域之位置形成段差 5。之後,去除光阻圖案RP21,與第丨實施例同樣地將氮化 矽膜3、緩衝氧化矽膜2蝕刻去除。將露出之活性區域熱氧 10化’而形成快閃記憶體區域用之通道氧化石夕膜。 如第2C圖所示,覆蓋通道氧化矽膜6,沉積聚矽膜7, 使用光阻圖案蝕刻,使浮閘在閘寬度方向上形成圖案。在 此’為覆蓋段差部5而留有聚梦膜之仿真體7d。由於段差部 5遠離快閃記憶體區域之活性區域而形成,故可輕易使間7 15 與分開之仿真體7d形成圖案。 如第2D圖所示,形成覆蓋聚矽膜7之ΟΝΟ膜8。於所期 之活性區域上形成具有開口之光阻圖案RP23,進行邏輯電 路區域之閾值控制用之離子植入。形成覆蓋快閃記憶體區 域,越過段差部5上之聚矽膜7之段差到達平坦部之光阻圖 20 案RP23,將露出之ΟΝΟ膜蝕刻去除。進一步,將露出之通 道氧化矽膜6蝕刻去除。雖為與第1F圖所示之蝕刻步驟相同 之步驟,但ΟΝΟ膜之蝕刻在不含形成於快閃記憶體區域與 邏輯記憶體區域間之段差的平坦面上進行’故蝕刻可輕易 進行。之後,去除光阻圖案RP23。以熱氧化於邏輯區域之 19 1321850 活性區域表面形成閘絕緣膜。以CVD沉積形成閘電極之聚 矽膜。 如第2E圖所示’在快閃記憶體區域具有控制閘之圖 案,而在段差部形成覆蓋聚矽層7、ΟΝΟ膜8之光阻圖案RP 5 24。邏輯電路區域為光阻圖案Rp24所覆蓋《以使用光阻圖 案RP24之触刻使控制閘形成圖案,進一步,亦使όνο膜8、 浮閘7形成圖案。在段差部5,使聚矽膜9形成圖案以覆蓋聚 矽層7、ΟΝΟ膜8之形狀。進行離子植入,形成快閃記憶體 之源極/汲極區域。之後,去除光阻圖案RP24。 10 如第2F圖所示,新形成覆蓋快閃記憶體區域、段差部, 並具有邏輯電路區域之閘電極形狀之光阻圖案Rp25,將聚 矽膜9蝕刻,使邏輯電路區域之閘電極形成圖案。之後,進 行邏輯電路之離子植入,而形成源極/汲極區域。 根據本實施例,在於進行使快閃記憶體區域之STI表面 15下降之處理時形成之快閃記憶體區域與邏輯區域間的段差 部,積極地留有浮閘用聚矽膜、ΟΝΟ膜、控制閘用聚矽膜, 〇N〇膜呈為聚石夕膜挾持之形狀。而可防止όνο膜之触刻殘 /查、剝離,而減低垃圾產生之可能性。 供快閃記憶體區域之STI部份钱刻用之光罩可與其他 2〇步驟之光罩兼用。參照第3Α圖、第3Β圖,說明第3實施例 之製造方法。 。第3Α圖與第1Α圖相同。將矽基板丨表面熱氧化,形成 緩衝氧化矽膜2後,於其上以CVD沉積氮化矽膜3。使用光 阻圖案,使氮化矽膜3、氧化矽膜2形成圖案,將氮化矽膜3 20 1321850 作為姓刻光罩’將石夕基板_,形成元件隔離溝。以咖 CVD將氧化石夕膜4沉積’埋入元件隔離溝。從氧化石夕膜4表 面進行CMP,去除氮化妙膜3表面水平面上之氧化石夕膜4。 如第3B圖所示,形成使快閃記憶體區域開口之光阻圖 5案RP31。將此光阻圖案RP31作為光罩,對快閃記憶體之活 性區域進行閾值控制用離子植入。將相同之光阻圖案Rp^ 作為蝕刻光罩,將HDPCVD氧化矽膜4蝕刻達活性區域表面 上之厚度中間。之後,去除光阻圖案RP31。其他之步驟與 第1實施例相同。藉兼用離子植入光罩及蝕刻光罩,可抑制 10 光罩數之增加。 以下,說明本發明之具體實施形態。主邏輯電路以12 V動作之低電壓CMOS電晶體構成,輸入輸出電路以2 5¥至 3.3V動作之中電壓CMOS電晶體構成,非依電性記憶體控制 電路以5V、10V動作之高電壓CMOS電晶體構成。低電壓電 15晶體、高電壓電晶體分別有高閾值、低閾值2種《包括非依 電性記憶體在内,使用共11種之電晶體。 如第4圖所示’於半導體基板1〇形成n型井8〇、84、88、 Ρ型井82、86,於η型井80内形成ρ型井78。於ρ型井78内形 成以高電壓動作之快閃記憶體胞元(Flash cell)、η通通高 20 電壓低閾值電晶體(N-HV Low Vt)及η通道高電壓高間值 電晶體(N-HVHigh Vt)。於η型井80内形成以高電壓動作之? 通道高電壓低閾值電晶體(P-HV Low Vt)及ρ通道高電壓 高閾值電晶體(P-HVHigh Vt)。於ρ型井82、n型井84内形成 以中電壓動作之η通道中電壓電晶體(N-MV)及pit道中電 21 壓電晶體(P-MV)。於p型井86内形成以低電壓動作之η通道 低電壓高閾值(N-LVHigh Vt)及η通道低電壓低閾值電晶體 (N-LV Low Vt),於η型井88内形成ρ通道低電壓高閾值電晶 體(P-LV HighV)及ρ通道低電壓低閾值電晶體(P-LV Low Vt) » η通道中電壓電晶體(n-MV)及ρ通道中電壓電晶體(P-MV)為構成輸入輸出電路之電晶體,為2.5v動作或3_3V動 作等之電晶體。2.5V動作及3.3V動作係指閘絕緣膜之厚 度、閾值電壓控制條件、LDD條件相互不同,而不需同時 搭載兩者,僅搭載其中任一者為一般情形。以下,就第4圖 所示之半導體裝置之製造方法作說明。 如第5A圖所示,以第3實施例說明之步驟於矽基板1〇 上形成氧化矽膜12、氮化矽膜14之圖案,將矽基板1〇蝕刻, 形成疋件隔離溝後,埋入氧化矽膜。以CMP去除氮化矽膜1 4水平面上之氧化矽膜。形成STI元件隔離區域22 。在此狀 態,於基板形成露出記憶體區域之光阻圖案15。將光阻圖 案作為光罩將閾值控制用離子以加速能量4〇keV、劑量 6Xl〇13cm2植入,而形成ρ型區域54。 將光阻圖案15作為姓刻光罩,而將STI氧化石夕膜22姓刻 40nm而去除。記憶體區域之奶氧化矽膜表面下降而形 成段差20。 去除光阻圖案15,在所有區域將氮化石夕膜14、氧化石夕 膜12钱刻去除。此姓刻步驟後之步驟基本上與第旧施例相 同。為使圖式簡略化,之後省略段差20而顯示。 如第5B圖所示,藉STI氧化矽膜22分隔活性區域。以熱 氧化形成氧化矽犧牲膜。 於快閃記憶體胞元(Flash cell)形成區域及η通道高電 壓電晶體(N-HV)形成區域形成η型埋入雜質層28。η型埋入 5 雜質層28為藉將磷(ρ+)離子以加速能量2MeV、劑量2xl013c m·2之條件植入而形成。於快閃記憶體胞元(Flash cell)形成 區域、η通道電晶體(N-HV、N-MV、N-LV)形成區域形成p 型井用雜質層32、34。ρ型井用雜質層32係藉將硼(Β+)離子 以加速能量400keV、劑量1.5x1013cm-2之條件植入而形 10 成。ρ型井用雜質層34係藉將硼離子以加速能量lOOkeV、劑 量2><1012cm_2之條件植入而形成。 於η通道高電壓高閾值電晶體(N-HV High Vt)形成區 域、η通道中電壓電晶體(N-MV)形成區域、η通道低電壓形 成區域(N-LV)形成區域形成ρ型井用雜質層40。ρ型井用雜 15 質層40藉將硼離子以加速能量1 OOkeV、劑量6χ 1012cm·2之條 件植入而形成。 於ρ通道電晶體(P-HV、P-MV、P-LV)形成區域形成η 型井用雜質層44。η型井用雜質層44係藉將磷離子以加速能 量600keV、劑量3xl013cm·2植入而形成。以此條件,可獲得 20 閾值電壓約-0.2V之ρ通道高電壓低閾值電晶體(P-HVLowAs shown in Fig. 1F, a photoresist pattern RP13 having an opening is formed in a region where the 〇N ◦ film 8 is removed, and the exposed ruthenium film 8 is etched away. Further, the exposed channel yttrium oxide film 6 is etched and removed. By this etching, the STI other than the flash memory region is also removed, and the surface thereof is lowered. However, the STI 16 1321850 surface height of the logic region is higher than the STI surface height of the flash memory region. Thereafter, the photoresist pattern RP13 is removed. As shown in Fig. 1G, a gate oxide insulating film G1 of yttrium oxide is formed by thermal oxidation on the surface of the active region of the logic region. When three kinds of gate insulating germanium are formed, 5 thermal oxidation and selective thermal oxidation etching are repeated twice, and then thermally oxidized, and a thin tantalum oxide film is sequentially formed from the thick tantalum oxide film. Therefore, the STI surface of the logic region is lowered, and the STI surface of the flash memory region is also high. Moreover, even if the flash memory area is low, the difference is reduced as compared with the prior art. The recess around the active area is deepened. 10, as shown in FIG. 1, the polysilicon film 9' deposited by CVD to form a gate electrode is etched using a photoresist pattern RP14 covering the logic region and having a gate electrode shape in the flash memory region, Further, the ruthenium film 'floating gate 7' is also etched to pattern the gate electrode of the flash memory. At this stage, the logic circuit region is covered by the photoresist pattern RP14 without being etched. Ion implantation is performed to form the source/drain regions of the flash memory. Thereafter, the photoresist pattern RP14 is removed. The oxidation of the side surface of the gate electrode is performed to form a flash memory structure. As shown in Fig. II, a photoresist pattern RP15 covering the flash memory region and having the gate electrode shape of the logic circuit region is newly formed, and the gate film 9 is etched to pattern the gate electrode of the logic circuit region. Thereafter, ion implantation of the logic circuit is performed to form a source/drain region. Thereafter, the photoresist pattern RP15 is removed. 〇 The 1J diagram schematically shows a plan view of the gate electrodes of the flash memory and the MOS transistor. The elongated active area AR is arranged in the longitudinal direction in the figure. 17 In the logic circuit, the gate electrode g of the MOS transistor extends across the active region AR and extends over the isolation region of the sti element. In the flash memory, the floating gate FG and the control gate CG extend across the active region and extend over the STI element isolation region. In the region between the control gates CG, the floating gate FG and the control gate CG are completely etched, and 5 there is no residue. The residue of the 0N0 film 8 and the polysilicon film 7 shown in Fig. 6H is not expected. Since the STI segment difference between the active region and the periphery is small in the flash memory region, the surname of the residue remaining can be easily performed. The 1K figure shows a cross-sectional view of the area between the control gates CG along the χ2_χ2 line of the 丨j diagram. Since the step difference of the surface of the base layer is small, the control gate and the floating gate 10 are completely easy to touch, which prevents the floating gate. Short circuit. In addition, Fig. U is a cross-sectional view taken along the line X1-X1. Thereafter, electrode formation, formation of an insulating film, formation of a multilayer wiring, and the like are performed. The STI surface of the flash memory region is lowered, and the surface level of the gate electrode surface of the logic region is within the distribution of the surface level of the gate electrode surface of the flash memory region. In the steps of FIG. 1H and FIG. The height difference of 9 is less than that of the prior art, so the focus of the photolithography technology is reduced. When the process of lowering the surface of the flash memory region is performed, a step is formed between the flash memory region and the logic region, and the film formation and removal on the step portion may cause a problem. The method of manufacturing the semiconductor device of the second embodiment will be described with reference to the second embodiment of Fig. 2 and the second embodiment, which is different from the first embodiment. . Figure 2A is the same as Figure 1A. After the surface of the stone substrate i is thermally oxidized to form the buffer yttrium oxide film 2, the tantalum nitride film 3 is deposited thereon by CVD. Using the photoresist pattern, the nitride (4) 3 and the oxide oxide 2 are patterned, and the nitride film 3 18 is used as a money mask to engrave the stone substrate to form an element isolation trench. The oxidation 11 is deposited by HDP CVD, and the components are buried. The oxidized stone film 4 on the surface of the surface of the nitride film 3 is removed by CMP' from the surface of the oxidized film 4. As shown in Fig. 2B, a gap is left in the periphery to form a photoresist pattern RP21 which opens the area of the flash memory 5, and the HDPCVD oxide film 4 is etched to the middle of the thickness on the surface of the active region. The STI surface of the flash memory region is lowered to form a step 5 at the position of the active region retreating from the flash δ hexon region. Thereafter, the photoresist pattern RP21 is removed, and the tantalum nitride film 3 and the buffered hafnium oxide film 2 are removed by etching in the same manner as in the third embodiment. The exposed active region is thermally oxygenated to form a channel oxidized oxide film for the flash memory region. As shown in Fig. 2C, the channel oxide film 6 is covered, the polysilicon film 7 is deposited, and the photoresist pattern is etched to form a pattern in the gate width direction. Here, the dummy body 7d is left as the step portion 5 is covered. Since the step portion 5 is formed away from the active region of the flash memory region, the gap 7 15 can be easily patterned with the separated dummy body 7d. As shown in Fig. 2D, the ruthenium film 8 covering the ruthenium film 7 is formed. A photoresist pattern RP23 having an opening is formed on the active region to perform ion implantation for threshold control of the logic circuit region. A region covering the flash memory region is formed, and the step of the polysilicon film 7 over the step portion 5 reaches the flat portion of the photoresist pattern RP23, and the exposed film is etched and removed. Further, the exposed channel yttria film 6 is etched away. Although it is the same step as the etching step shown in Fig. 1F, the etching of the tantalum film is performed on a flat surface which does not include a step formed between the flash memory region and the logical memory region, so etching can be easily performed. Thereafter, the photoresist pattern RP23 is removed. A gate insulating film is formed on the surface of the active region by thermal oxidation in the logic region 19 1321850. A polysilicon film of a gate electrode is deposited by CVD. As shown in Fig. 2E, the pattern of the control gate is provided in the flash memory region, and the photoresist pattern RP 5 24 covering the polyimide layer 7 and the germanium film 8 is formed in the step portion. The logic circuit area is covered by the photoresist pattern Rp24. The gate is patterned by the etch of the photoresist pattern RP24, and further, the όνο film 8 and the floating gate 7 are patterned. In the step portion 5, the polysilicon film 9 is patterned to cover the shape of the polysilicon layer 7 and the ruthenium film 8. Ion implantation is performed to form the source/drain regions of the flash memory. Thereafter, the photoresist pattern RP24 is removed. 10 As shown in FIG. 2F, a photoresist pattern Rp25 covering the flash memory region and the step portion and having the gate electrode shape of the logic circuit region is newly formed, and the polyimide film 9 is etched to form the gate electrode of the logic circuit region. pattern. Thereafter, ion implantation of the logic circuit is performed to form a source/drain region. According to the present embodiment, the step portion between the flash memory region and the logic region formed when the STI surface 15 of the flash memory region is lowered is actively placed, and the polysilicon film and the ruthenium film for the floating gate are actively left. The ruthenium film is used to control the gate, and the 〇N〇 film is in the shape of a concentrating film. It can prevent the όνο film from being scratched/checked and peeled off, reducing the possibility of garbage generation. The STI part of the flash memory area for flash memory can be used with other 2-step masks. The manufacturing method of the third embodiment will be described with reference to Figs. 3 and 3D. . The third map is the same as the first one. After the surface of the tantalum substrate is thermally oxidized to form a buffered hafnium oxide film 2, the tantalum nitride film 3 is deposited thereon by CVD. Using the photoresist pattern, the tantalum nitride film 3 and the tantalum oxide film 2 are patterned, and the tantalum nitride film 3 20 1321850 is used as the surname mask to form the element isolation trench. The oxidized stone film 4 was deposited by the CVD into the element isolation trench. The oxidized stone film 4 on the surface of the surface of the oxidized film 3 was removed by CMP from the surface of the oxidized stone film 4. As shown in Fig. 3B, a photoresist pattern RP31 which opens the flash memory region is formed. This photoresist pattern RP31 is used as a mask to perform ion implantation for threshold control of the active region of the flash memory. The same photoresist pattern Rp^ is used as an etching mask, and the HDPCVD yttrium oxide film 4 is etched to the middle of the thickness on the surface of the active region. Thereafter, the photoresist pattern RP31 is removed. The other steps are the same as in the first embodiment. By using both the ion implantation mask and the etching mask, the number of 10 masks can be suppressed. Hereinafter, specific embodiments of the present invention will be described. The main logic circuit is composed of a low-voltage CMOS transistor operating at 12 V, and the input/output circuit is composed of a voltage CMOS transistor operating from 2 5 ¥ to 3.3 V. The non-electric memory control circuit is operated at a high voltage of 5 V and 10 V. CMOS transistor construction. Low-voltage electric 15 crystal and high-voltage transistors have high threshold and low threshold, respectively. "A total of 11 kinds of transistors are used including non-electrical memory. As shown in Fig. 4, n-type wells 8〇, 84, 88 and Ρ-type wells 82 and 86 are formed on the semiconductor substrate 1 to form a p-type well 78 in the n-type well 80. A flash cell (Flash cell), a η pass-through high voltage low threshold transistor (N-HV Low Vt), and an n-channel high voltage high-interval transistor (high-voltage operation) are formed in the p-type well 78 ( N-HVHigh Vt). Is it formed at a high voltage in the n-type well 80? Channel high voltage low threshold transistor (P-HV Low Vt) and ρ channel high voltage high threshold transistor (P-HVHigh Vt). In the p-type well 82 and the n-type well 84, a voltage transistor (N-MV) in the n-channel and a 21-piezoelectric crystal (P-MV) in the pit channel are formed. An n-channel low-voltage high-threshold (N-LVHigh Vt) and an n-channel low-voltage low-threshold transistor (N-LV Low Vt) operating at a low voltage are formed in the p-type well 86 to form a p-channel in the n-type well 88. Low-voltage high-threshold transistor (P-LV HighV) and ρ-channel low-voltage low-threshold transistor (P-LV Low Vt) » η-channel voltage-transistor (n-MV) and ρ-channel voltage-transistor (P- MV) is a transistor that constitutes an input/output circuit, and is a transistor of 2.5V operation or 3_3V operation. The 2.5V operation and the 3.3V operation mean that the thickness of the gate insulating film, the threshold voltage control condition, and the LDD condition are different from each other, and it is not necessary to carry both of them at the same time, and only one of them is a general case. Hereinafter, a method of manufacturing the semiconductor device shown in Fig. 4 will be described. As shown in Fig. 5A, the pattern of the hafnium oxide film 12 and the tantalum nitride film 14 is formed on the tantalum substrate 1 by the steps described in the third embodiment, and the tantalum substrate 1 is etched to form a germanium isolation trench, and then buried. Into the ruthenium oxide film. The ruthenium oxide film on the level of the tantalum nitride film 14 is removed by CMP. An STI element isolation region 22 is formed. In this state, the photoresist pattern 15 exposing the memory region is formed on the substrate. The resist pattern was used as a mask to implant the threshold control ions at an acceleration energy of 4 〇 keV and a dose of 6×1 〇 13 cm 2 to form a p-type region 54. The photoresist pattern 15 was used as a surname mask, and the STI oxidized stone film 22 was removed by 40 nm. The surface of the milk cerium oxide film in the memory region is lowered to form a step difference of 20. The photoresist pattern 15 is removed, and the nitride film 14 and the oxidized stone film 12 are removed in all areas. The steps after this last name step are basically the same as the old one. In order to simplify the drawing, the step difference 20 is omitted and displayed. As shown in Fig. 5B, the active region is separated by the STI yttrium oxide film 22. A cerium oxide sacrificial film is formed by thermal oxidation. The n-type buried impurity layer 28 is formed in a flash cell formation region and an n-channel high-voltage piezoelectric crystal (N-HV) formation region. The n-type buried 5 impurity layer 28 is formed by implanting phosphorus (ρ+) ions at an acceleration energy of 2 MeV and a dose of 2xl013c m·2. The p-type well impurity layers 32, 34 are formed in a flash cell formation region, an n-channel transistor (N-HV, N-MV, N-LV) formation region. The p-type well impurity layer 32 is formed by implanting boron (Β+) ions at an acceleration energy of 400 keV and a dose of 1.5 x 1013 cm-2. The p-type well impurity layer 34 is formed by implanting boron ions at an acceleration energy of 100 keV, a dose of 2 >< 1012 cm_2. Forming a p-type well in a n-channel high-voltage high-threshold transistor (N-HV High Vt) formation region, a η channel voltage transistor (N-MV) formation region, and an η channel low voltage formation region (N-LV) formation region The impurity layer 40 is used. The p-type well impurity layer 40 is formed by implanting boron ions at an acceleration energy of 1 00 keV and a dose of 6 χ 1012 cm·2. An n-type well impurity layer 44 is formed in the p-channel transistor (P-HV, P-MV, P-LV) formation region. The n-type well impurity layer 44 is formed by implanting phosphorus ions at an acceleration energy of 600 keV and a dose of 3 x 1013 cm·2. Under this condition, a ρ channel high voltage low threshold transistor with a threshold voltage of about -0.2 V can be obtained (P-HVLow).

Vt)。於ρ通道高電壓高閾值電晶體(P-HV High Vt)形成區 域形成閾值電壓控制用雜質擴散層48、於ρ通道中電壓電晶 體(Ρ-MV)形成區域及P通道低電壓電晶體(P-LV)形成區域 形成通道阻絕層50。閾值電壓控制用雜質層48及通道阻絕 23 層50係藉將磷離子以加速能量24〇keV、劑量5x 1〇i2cm·2之條 件植入而形成。以此條件,可獲得閾值電壓約_〇6Vip通 道高電壓高閾值電晶體(P-HVHigh Vt)。於離子植入結束 後,去除氧化矽犧牲膜。 5 如第5C圖所示,以900〜1050°C之溫度進行30分鐘之熱 氧化’而於活性區域上形成膜厚1〇11111之通道氧化矽膜56。 覆蓋通道氧化矽膜56,於基板上以CVD法使膜厚90nm之嶙 摻雜聚矽膜成長。以光微影技術及乾蝕刻使磷摻雜聚矽膜 形成圖案,而於快閃記憶體胞元(Flash cdl)形成區域形成由 10磷摻雜聚矽膜構成之浮閘58 » 於形成有浮閘58之基板上以CVD法使膜厚5nm之氧化 石夕膜及膜厚10nm之氮化矽膜成長。將氮化矽膜之表面以% 〇°C熱氧化90分鐘,以於表面使厚度5nm左右之氧化膜成 長’而形成全體厚度15nm左右之ΟΝΟ膜(氧化矽膜/氮化矽 15 膜/氧化矽膜)60。 如第5D圖所示,於電晶體區域進行閾值控制用離子植 入’獲得所期之閾值。於η通道中電壓電晶體(N_MV)形成 區域形成閾值電壓控制用雜質層64。閾值電壓控制用雜質 層64係藉將棚離子以加速能量3〇keV、劑量5xl012cm-2植入 20而形成,而獲得約+0.3〜+0.4V之閾值電壓。於p通道中電 壓電晶體(P-MV)形成區域形成閾值電壓控制用雜質層68。 閾值電壓控制用雜質層68係藉將砷(As+)離子以加速能量15 OkeV、劑量3xl012cm_2之條件植入而形成,而獲得約_〇.3— 0.4之閾值電壓。 24 1321850 於η通道低電壓高閾值電晶體(N-LV High)形成區域形 成閾值電壓控制用雜質層72。閾值電壓控制用雜質72係藉 將硼離子以加速能量10keV、量5xl012cm-2之條件植入而 形成,而獲得約+0.2V之閾值電壓。於p通道低電壓高閾值 5 電晶體(P-LVHigh Vt)形成區域形成閾值電壓控制用雜質 層76。閾值電壓控制用雜質層76係藉將砷離子以加速能量1 OOkeV、劑量5xl012cm·2之條件植入而形成,可獲得約_〇.2V 之閾值電壓。 接著’藉光微影技術形成覆蓋快閃記憶體胞元(Flash 10 cell)形成區域且露出其他區域之光阻膜92。藉乾蝕刻將光 阻膜92作為光罩,將ΟΝΟ膜60蝕刻,而去除快閃記憶體胞 元(Flash cell)形成區域以外之ΟΝΟ膜60。然後,藉使用氫 氟酸水溶液之濕蝕刻將光阻膜92作為光罩,將通道氧化石夕 膜56蝕刻,而去除快閃記憶體胞元(Flash cell)形成區域以外 15之通道氧化石夕膜56 ^之後,藉灰化去除光阻膜92。 如第5E圖所示,以850°C之溫度進行熱氧化,而於活性 區域上形成膜厚13nm之氧化矽膜94。形成覆蓋快閃記憶體 胞元(Flash cell)及高電壓電晶體(Ν·Ην、ρ·Ην)區域並露出 其他區域之光阻膜96。藉使用氫氟酸水溶液之濕蝕刻將光 20阻膜96作為光罩,蝕刻氧化矽膜94,而去除中電壓電晶體(Ν _MV、P-MV)形成區域及低電壓電晶體(N-LV、P-LV)形成 區域之氧化矽膜94。之後,藉灰化去除光阻臈%。 如第5F圖所示,以85(rc之溫度進行熱氧化,而於中電 壓電晶體(Ν·ΜV、Ρ·ΜV)形祕域及低電壓電晶體(N_LV、 25 P-LV)形成區域之活性區域上形成膜厚4 5nm之氧化矽膜 98。此外,在此熱氧化步驟中,氧化矽膜94之膜厚亦增加。 藉光微影技術形成覆蓋快閃記憶體胞元(Flash cell)形 成區域、焉電壓電晶體(N-HV、Ρ-HV)形成區域、中電壓電 晶體(N-MV ' P-MV)形成區域並露出低電壓電晶體(n-LV、 P-LV)形成區域之光阻臈1〇0。藉使用氫氟酸水溶液之濕蝕 刻將光阻膜100作為光罩’儀刻氧化矽膜98,而去除低電壓 電晶體(N-LV、P-LV)形成區域之氧化矽膜98。之後,藉灰 化去除光阻膜100。 如第5G圖所示,以850°C之溫度進行熱氧化,而於低電 壓電晶體(N-LV、P-LV)形成區域之活性區域上形成由膜厚 2.2nm之氧化矽膜構成之閘絕緣膜102〇此外,在此熱氧化 步驟中,氧化矽膜94、98之膜厚亦增加,而於高電壓電晶 體(N-HV、P-HV)形成區域形成膜厚共i6nm之閘絕緣膜,於 中電壓電晶體(N-MV、P-MV)形成區域形成膜厚共5.5nm之 閘絕緣膜。 以CVD法使膜厚i8〇nm之聚矽膜1〇8成長。接著,以電 漿CVD法於聚矽膜1〇8上使膜厚30nm之氮化矽膜110成 長。此外,若氮化矽膜為兼具使下層之聚矽膜108形成圖案 時之反射防止及蝕刻光罩時,亦同時具有於將後述快閃記 憶體胞元之閘電極側面氧化時,保護邏輯部份之閘電極的 功能。 以光微影技術及乾蝕刻使快閃記憶體胞元(Flash cell) 形成區域之氧化矽膜110、聚矽膜1〇8、ΟΝΟ膜60及浮閘58 1321850 形成圖案,而形成快閃記憶體胞元(Flash cell)之閘電極112。 如第5H圖所示,將快閃記憶體胞元(Flash cell)之閘電 極112之側面熱氧化l〇nm左右,進行源極/没極區域之離子 植入。再將閘電極112之側面熱氧化1 Onm左右。接著,以熱 5 CVD法將氮化矽膜沉積後,蝕刻此氮化矽膜及氮化矽膜11 0,而於閘電極112之側壁部份形成由氮化矽膜構成之側壁 絕緣膜116,同時,露出聚矽膜108之表面。接著,以光微 影技術及乾蝕刻使高電壓電晶體(N-HV、P-HV)形成區域、 中電壓電晶體(N-MV、P-MV)形成區域及低電壓電晶體(N-10 LV、P-LV)形成區域之聚矽膜1〇8形成圖案,而形成由聚矽 膜108構成之閘電極118。 如第51圖所示,形成邏輯電路之各電晶體之源極/汲極S /D。形成p通道低電壓電晶體(Ρ-LV)之源極/汲極區域之延伸 區。舉例言之,將硼離子以加速能量〇.5keV、劑量3.6X101 15 4crrT2及將砷離子以加速能量8〇keV、劑量各6.5xl012cm-2而 從基板法線傾斜28度之4方向進行離子植入而形成,而作為 附口袋之延伸區。形成η通道低電壓電晶體(N-LV)之源極/ 汲極區域之延伸區。舉例言之,將砷離子以加速能量3keV、 劑量l.lxl015cm-2及將氟化硼離子(BF2+)以加速能量35ke 20 v、劑量9.5xl012cm·2而從基板法線傾斜28度之4方向進行離 子植入而形成,而作為附口袋之延伸區。 形成p通道中電壓電晶體(P-MV)之源極/汲極區域之延 伸區。舉例言之,將氟化硼離子以加速能量1〇keV、劑量7 xl013cm_2之條件植入而形成。形成n通道中電壓電晶體(N- 27 MV)之源極/祕區域之延伸區,例言之,藉糾離子以 加速能量lOkeV、劑量2χΐπ13Λ -2 ^ 2 10 cm之條件及將磷離子以加速 能量碰eV、劑量3x1QlW之條件進行離子植人而形成。 形成P通道高電壓電晶體(p_HV)之源極/没極區域之延 伸舉例。之’將說化蝴離子以加速能斷eV、劑量45χΐ〇 cm之條件植入而形成。形成n通道高電壓電晶體(N_間 之源極/汲極區域之延伸區。舉例言之,藉將雜子以加速 能量35keV、劑量4χ10%-2之條件進行離子植入而形成。 以熱CVD法沉魏切職,將絲切賴刻,而 於閘電極之側壁部份形成由氧化矽膜構成之側壁絕緣膜 144。 以光阻膜作為光罩,進行離子植入,形成快閃記憶體 胞元(Flash cell)及n通道電晶體之源極/汲極區域。藉此離子 植入’快閃記憶體胞元及η通道之沒極電極摻雜成η型。源 極/汲極區域係藉將碌離子以加速能量1〇keV、劑量 6><1015cm·2之條件植入而形成。 形成P通道電晶體之源極/汲極區域。藉此離子植入,p 通道電晶體之閘電極摻雜為p型。源極/汲極區域152係藉將 硼離子以加速能量5keV、劑量4xl〇i5cm·2之條件植入而形 成。藉眾所皆知之自動對準金屬石夕化物製程將閘電極上及 源極/沒極上自動對準碎化β如此進行而於妙基板1〇完成1 1 種電晶體。 於形成有電晶體之妙基板10上沉積絕緣膜154,形成接 觸孔,埋入導電性插頭158 »於絕緣膜154上形成第丨層金屬 配線160。 如第5J圖所示,反複進行絕緣膜之沉積、配線等之形 成,而形成所期層數之多層配線層162 ^於多層配線層162 上沉積絕緣膜164,形成接觸孔,埋入導電性插頭168。於 5形成有配線層170'塾(pad)電極172等之絕緣膜164上形成鈍 化膜174,使墊電極開口。如此進行完成半導體装置。此外, 快閃記憶體胞it、邏輯電晶體、多層配線之製程可使用眾 所周知之製程。舉例言之,可參照日本專利公開公報2〇〇5_ 142362號之[用以實施發明之最佳形態]之攔。 10 以11種電晶體構成了混合搭載快閃記憶體之半導體裝 置,但不以此為限。電晶體之種類可適當增減。記憶體亦 不限於快閃記憶體。 依以上之實施例說明了本發明,本發明不以此為限。 於以STI元件隔離區域分隔之複數活性區域上形成高度不 15同之構造物而形成圖案時可廣泛應用。說明了將快閃記憶 體及MOS電晶體之閘電極作為高度不同之構造物,對層數 不同之導電體例如單層構造與層疊構造混合之導電體構造 應有效。又,該業者應明瞭亦可選擇各種作成之電路。可 進行其他各種變形、改良、組合等。 20 可適用於於以STI元件隔離區域分隔之複數活性區域 上形成高度不同之構造物之半導體積體電路。可適用於包 含具有浮閘之非依電性記憶體之半導體裝置。 【闽式簡單說明3Vt). Forming a threshold voltage control impurity diffusion layer 48 in a p-channel high voltage high threshold transistor (P-HV High Vt) formation region, a voltage transistor (Ρ-MV) formation region in the p channel, and a P channel low voltage transistor ( The P-LV) formation region forms a channel barrier layer 50. The threshold voltage control impurity layer 48 and the channel block 23 layer 50 are formed by implanting phosphorus ions at an acceleration energy of 24 〇 keV and a dose of 5 x 1 〇 i 2 cm 2 . Under this condition, a threshold voltage of about _〇6Vip channel high voltage high threshold transistor (P-HVHigh Vt) can be obtained. After the ion implantation is completed, the cerium oxide sacrificial film is removed. 5 As shown in Fig. 5C, thermal oxidation was carried out for 30 minutes at a temperature of 900 to 1050 ° C to form a channel yttrium oxide film 56 having a film thickness of 1 〇 11111 on the active region. The channel yttrium oxide film 56 was covered, and a ruthenium-doped polyfluorene film having a film thickness of 90 nm was grown on the substrate by a CVD method. The phosphor-doped polyfluorene film is patterned by photolithography and dry etching, and a floating gate 58 formed of a 10 phosphorus-doped polyfluorene film is formed in a flash memory cell (Flash cdl) formation region. On the substrate of the floating gate 58, a cerium oxide film having a thickness of 5 nm and a tantalum nitride film having a thickness of 10 nm were grown by a CVD method. The surface of the tantalum nitride film is thermally oxidized at % 〇 ° C for 90 minutes to grow an oxide film having a thickness of about 5 nm on the surface to form a ruthenium film having a total thickness of about 15 nm (yttrium oxide film / tantalum nitride film 15 / oxidation) Diaphragm) 60. As shown in Fig. 5D, the threshold control ion implantation is performed in the transistor region to obtain the desired threshold. The threshold voltage control impurity layer 64 is formed in the voltage transistor (N_MV) formation region in the η channel. The threshold voltage control impurity layer 64 is formed by implanting shed ions at an acceleration energy of 3 〇 keV and a dose of 5 x 1012 cm -2 to obtain a threshold voltage of about +0.3 to +0.4 V. The impurity voltage layer 68 for threshold voltage control is formed in the p-channel forming region of the piezoelectric film (P-MV). The threshold voltage control impurity layer 68 is formed by implanting arsenic (As+) ions at an acceleration energy of 15 OkeV and a dose of 3 x 1012 cm 2 to obtain a threshold voltage of about _〇.3 - 0.4. 24 1321850 An impurity layer 72 for threshold voltage control is formed in the n-channel low-voltage high-threshold transistor (N-LV High) formation region. The threshold voltage control impurity 72 is formed by implanting boron ions at an acceleration energy of 10 keV and an amount of 5 x 1012 cm -2 to obtain a threshold voltage of about +0.2 V. The threshold voltage control impurity layer 76 is formed in the p-channel low voltage high threshold 5 transistor (P-LVHigh Vt) formation region. The threshold voltage control impurity layer 76 is formed by implanting arsenic ions at an acceleration energy of 100 keV and a dose of 5 x 1012 cm 2 , and a threshold voltage of about 〇 2 V can be obtained. Next, the light lithography technique is used to form a photoresist film 92 covering the flash memory cell forming region and exposing other regions. The photoresist film 92 is used as a mask by dry etching, and the ruthenium film 60 is etched to remove the ruthenium film 60 other than the region in which the flash memory cells are formed. Then, the photoresist film 92 is used as a mask by wet etching using a hydrofluoric acid aqueous solution, and the channel oxide film 56 is etched to remove the channel oxide oxide outside the flash memory cell formation region. After the film 56^, the photoresist film 92 is removed by ashing. As shown in Fig. 5E, thermal oxidation was carried out at a temperature of 850 ° C to form a hafnium oxide film 94 having a film thickness of 13 nm on the active region. A photoresist film 96 covering a flash cell and a high voltage transistor (Ν·Ην, ρ·Ην) region and exposing other regions is formed. The photo-resist film 96 is used as a mask by wet etching using a hydrofluoric acid aqueous solution to etch the hafnium oxide film 94, and the medium voltage transistor (Ν _MV, P-MV) formation region and the low voltage transistor (N-LV) are removed. , P-LV) forms a yttrium oxide film 94 in the region. After that, the photoresist is removed by ashing. As shown in Fig. 5F, thermal oxidation is performed at a temperature of 85 (rc), and a region is formed in a medium voltage transistor (Ν·ΜV, Ρ·ΜV) and a low voltage transistor (N_LV, 25 P-LV). A ruthenium oxide film 98 having a film thickness of 45 nm is formed on the active region. Further, in this thermal oxidation step, the film thickness of the ruthenium oxide film 94 is also increased. The light lithography technique is used to form a covered flash memory cell (Flash cell) Formation region, 焉 voltage transistor (N-HV, Ρ-HV) formation region, medium voltage transistor (N-MV 'P-MV) formation region and exposed low voltage transistor (n-LV, P-LV) The photoresist of the formation region is 〇0. The photoresist film 100 is used as a mask to etch the ruthenium oxide film 98 by wet etching using a hydrofluoric acid aqueous solution, and the low voltage transistor (N-LV, P-LV) is removed. A region of the ruthenium oxide film 98 is formed. Thereafter, the photoresist film 100 is removed by ashing. As shown in FIG. 5G, thermal oxidation is performed at a temperature of 850 ° C, and at a low voltage transistor (N-LV, P-LV). a gate insulating film 102 formed of a ruthenium oxide film having a film thickness of 2.2 nm is formed on the active region of the formation region. Further, in the thermal oxidation step, the film thickness of the ruthenium oxide films 94 and 98 is also increased. In the high voltage transistor (N-HV, P-HV) forming region, a gate insulating film having a film thickness of i6 nm is formed, and a film thickness of 5.5 nm is formed in a region where a medium voltage transistor (N-MV, P-MV) is formed. The gate insulating film is grown by a CVD method to form a polyimide film 1〇8 having a film thickness of i8 μm. Then, a tantalum nitride film 110 having a film thickness of 30 nm is grown on the polyimide film 1〇8 by a plasma CVD method. When the tantalum nitride film is a reflection preventing and etching mask that forms a pattern of the lower polysilicon film 108, the protective logic portion is also provided when the gate electrode side of the flash memory cell described later is oxidized. The function of the gate electrode is formed by photolithography and dry etching to form the yttrium oxide film 110, the polysilicon film 1〇8, the ruthenium film 60 and the floating gate 58 1321850 in the flash cell formation region. a pattern is formed to form a gate electrode 112 of a flash memory cell. As shown in FIG. 5H, the side surface of the gate electrode 112 of the flash memory cell is thermally oxidized by about 10 nm. Ion implantation in the source/drain region is performed. The side of the gate electrode 112 is thermally oxidized by about 1 Onm. Then, the nitridation is performed by thermal 5 CVD. After the film is deposited, the tantalum nitride film and the tantalum nitride film 110 are etched, and the sidewall insulating film 116 made of a tantalum nitride film is formed on the sidewall portion of the gate electrode 112, and the surface of the polyimide film 108 is exposed. Next, a high voltage transistor (N-HV, P-HV) formation region, a medium voltage transistor (N-MV, P-MV) formation region, and a low voltage transistor are formed by photolithography and dry etching (N- The 10 LV, P-LV) formation region of the polyimide film 1 〇 8 is patterned to form the gate electrode 118 composed of the polyimide film 108. As shown in Fig. 51, the source/drain S/D of each transistor of the logic circuit is formed. An extension of the source/drain region of the p-channel low voltage transistor (Ρ-LV) is formed. For example, boron ions are ion implanted at an acceleration energy of 55 keV, a dose of 3.6×10 15 15 4 rrT2, and an arsenic ion at an acceleration energy of 8 〇 keV, a dose of 6.5×10 12 cm −2 , and a tilt of 28 degrees from the substrate normal. It is formed as an extension of the attached pocket. An extension of the source/drain region of the n-channel low voltage transistor (N-LV) is formed. For example, the arsenic ion is tilted by 28 degrees from the substrate normal at an acceleration energy of 3 keV, a dose of l.lxl15 cm-2, and a boron fluoride ion (BF2+) at an acceleration energy of 35 ke 20 v and a dose of 9.5 x 1012 cm 2 . It is formed by ion implantation and serves as an extension of the attached pocket. An extension region of the source/drain region of the voltage transistor (P-MV) in the p-channel is formed. For example, boron fluoride ions are formed by implanting under conditions of an acceleration energy of 1 〇 keV and a dose of 7 x 10 13 cm 2 . Forming an extension region of the source/secret region of the voltage transistor (N-27 MV) in the n-channel, for example, by correcting the ion to accelerate the energy lOkeV, the dose of 2 χΐπ13 Λ -2 ^ 2 10 cm, and the phosphorus ion The acceleration energy is formed by ion implantation by the conditions of eV and dose 3x1QlW. An example of the extension of the source/nomogram region of the P-channel high voltage transistor (p_HV) is formed. It will be formed by implanting a butterfly ion to accelerate the break of eV and a dose of 45 χΐ〇 cm. Forming an n-channel high-voltage transistor (the extension region of the source/drain region between N_. For example, the hetero-ion is formed by ion implantation at an acceleration energy of 35 keV and a dose of 4 χ 10% -2. The thermal CVD method is used to cut the wire, and the sidewall insulating film 144 composed of the yttrium oxide film is formed on the sidewall portion of the gate electrode. The photoresist film is used as a mask to perform ion implantation to form a flash. The memory cell (Flash cell) and the source/drain region of the n-channel transistor, whereby the ion-implanted 'flash memory cell and the η channel's electrodeless electrode are doped into an n-type. Source/汲The polar region is formed by implanting the ions at an acceleration energy of 1 〇 keV, a dose of 6 < 1015 cm · 2. The source/drain region of the P-channel transistor is formed. By ion implantation, p-channel The gate electrode of the transistor is doped p-type. The source/drain region 152 is formed by implanting boron ions at an acceleration energy of 5 keV and a dose of 4xl 〇i5 cm·2. The metal-lithium alloy process automatically aligns the fragmentation electrode on the gate electrode and the source/no-pole. 1〇1 transistor is completed. An insulating film 154 is deposited on the substrate 10 on which the transistor is formed, a contact hole is formed, and a conductive plug 158 is buried to form a second layer metal wiring 160 on the insulating film 154. As shown in FIG. 5J, the deposition of the insulating film, the wiring, and the like are repeated to form the multilayer wiring layer 162 of the desired number of layers. The insulating film 164 is deposited on the multilayer wiring layer 162 to form a contact hole, and the conductive plug 168 is buried. A passivation film 174 is formed on the insulating film 164 on which the wiring layer 170' pad electrode 172 or the like is formed, and the pad electrode is opened. Thus, the semiconductor device is completed. Further, the flash memory cell, the logic transistor, For the process of the multilayer wiring, a well-known process can be used. For example, it can be referred to the "Best Form for Carrying Out the Invention" of Japanese Patent Laid-Open Publication No. Hei. No. 5-142362. The semiconductor device of the flash memory is not limited thereto. The type of the transistor can be appropriately increased or decreased. The memory is not limited to the flash memory. The present invention has been described based on the above embodiments, and the present invention does not It can be widely used when forming a pattern on a plurality of active regions separated by STI element isolation regions to form a pattern having a height of not the same. It is described that the gate electrodes of the flash memory and the MOS transistor are used as structures having different heights. It is effective to construct an electric conductor having a different number of layers, for example, a single-layer structure and a laminated structure. Further, the manufacturer should be able to select various circuits, and various other modifications, improvements, combinations, etc. can be performed. A semiconductor integrated circuit suitable for forming structures having different heights on a plurality of active regions separated by an STI element isolation region, and is applicable to a semiconductor device including a non-electrical memory having a floating gate. [闽 style simple description 3

[第1-1圖]/[第1-2圖]/[第1-3]/[第1-4圖]第1A圖-第II 29 1321850 圖、第1K圖係顯示本發明第1實施例之半導體裝置製程之截 面圖。第1J圖係顯示閘電極之配置之平面圖。 [第2-1圖]/[第2-2圖]/[第2-3]第2A圖·第2F圖係顯示本 發明第2實施例之半導體裝置製程之截面圖。 5 [第3圖]第3A圖、第3B圖係顯示本發明第3實施例之半 導體裝置製程之截面圖。 [第4圖]第4圖係具體實施例之具有11種電晶體之半導 體裝置之截面圖。 [第 5-1 圖]/[第 5-2 圖]/[第 5-3]/[第 5-4 圖]/[第 5-5]第 5A圖 10 -第5J圖係顯示第4圖所示之半導體裝置製程之截面圖。 [第6-1圖]/[第6-2圖]/[第6-3]第6A圖第6H圖係說明混 合搭載快閃記憶體及邏輯電路之半導體積體電路裝置之新 課題之截面圖。 【主要元件符號說明】 1 夕基板 2.. .緩衝氧化矽膜 3.. .氮化矽膜 4.. .氧化矽膜 5.. .段差 6.. .通道氧化石夕膜 7.. .聚矽膜 7d...仿真體 8.. .ΟΝΟ 膜 9.. .聚矽膜 10.. 基板 12…氧化矽膜 14.. .氮化矽膜 15.. .光阻圖案 20.. .段差 22.. .5.I元件隔離區域 28 ...η型埋入雜質層 32.. . ρ型井用雜質層 34.. . ρ型井用雜質層 40.. . ρ型井用雜質層 44.. . η型井用雜質層 48.··閾值電壓控制用雜質層 30 1321850 50...通道阻絕層 152...源極/汲極區域 54…p型區域 154…絕緣膜 56...通道氧化矽膜 158...導電性插頭 58...浮閘 160...第1層金屬配線 60. "ΟΝΟ 膜 162...多層配線層 64...閾值電壓控制用雜質層 164,..絕緣膜 68...閾值電壓控制用雜質層 168...導電性插頭 72...閾值電壓控制用雜質層 170...配線層 76...閾值電壓控制用雜質層 172...墊電極 78·.·ρ型井 174...鈍化膜 80... η型井 RP11...光阻圖案 82_·.ρ型井 RP12...光阻圖案 84··. η型井 RP13...光阻圖案 86···ρ型井 RP14...光阻圖案 88... η型井 RP15...光阻圖案 92...光阻膜 RP21...光阻圖案 94…氧化矽膜 RP23…光阻圖案 96...光阻膜 RP24...光阻圖案 98…氧化矽膜 RP25...光阻圖案 100...光阻膜 RP31...光阻圖案 102...閘絕緣膜 RP41...光阻圖案 108...聚矽膜 RP42...光阻圖案 110...氮化矽膜 G...閘電極 112...閘電極 CG...控制閘 116...側壁絕緣膜 FG…浮閘 118.. .閘電極 144.. .侧壁絕緣膜 AR...活性區域 31[Fig. 1-1] / [1-2] / [1-3] / [1-4] Fig. 1A - II 29 1321850 Fig. 1K shows the first embodiment of the present invention A cross-sectional view of a semiconductor device process. Fig. 1J is a plan view showing the arrangement of the gate electrodes. [Fig. 2-1] / [2-2] / [2-3] Fig. 2A and Fig. 2F are cross-sectional views showing the process of the semiconductor device of the second embodiment of the present invention. [Fig. 3] Figs. 3A and 3B are cross-sectional views showing the process of the semiconductor device of the third embodiment of the present invention. [Fig. 4] Fig. 4 is a cross-sectional view showing a semiconductor device having 11 kinds of transistors in a specific embodiment. [Fig. 5-1] / [5-2] / [5-3] / [5-4] / [5-5] 5A Fig. 10 - Fig. 5J shows Fig. 4 A cross-sectional view of the illustrated semiconductor device process. [Fig. 6-1] / [6-2] / [6-3] Fig. 6A, Fig. 6H is a cross section showing a new subject of a semiconductor integrated circuit device in which a flash memory and a logic circuit are mixed. Figure. [Main component symbol description] 1 夕 substrate 2.. buffered yttrium oxide film 3.. yttrium nitride film 4.. yttrium oxide film 5.. . Step difference 6.. . Channel oxidized stone film 7.. Polythene film 7d...Simulation body 8..ΟΝΟ Film 9.. Polyimide film 10.. Substrate 12... Cerium oxide film 14.. Tantalum nitride film 15... Resistive pattern 20.. Step difference 22.. 5.I. Element isolation region 28 ... η type buried impurity layer 32.. ρ type well impurity layer 34.. ρ type well impurity layer 40.. ρ type well impurity Layer 44.. η type well impurity layer 48.·Thickness voltage control impurity layer 30 1321850 50... channel barrier layer 152... source/drain region 54...p-type region 154...insulation film 56 ... channel yttrium oxide film 158... conductive plug 58... floating gate 160... first layer metal wiring 60. "ΟΝΟ film 162...multilayer wiring layer 64... threshold voltage control Impurity layer 164, insulating film 68...threshold voltage control impurity layer 168...conductive plug 72...threshold voltage control impurity layer 170...wiring layer 76...threshold voltage control impurity Layer 172... pad electrode 78···p type well 174...passivation film 80... n type well RP11...resist pattern 82 _·.ρ-type well RP12...resist pattern 84··. η-type well RP13...resist pattern 86···ρ-type well RP14...resist pattern 88... η-type well RP15. .. photoresist pattern 92... photoresist film RP21... photoresist pattern 94... ruthenium oxide film RP23... photoresist pattern 96... photoresist film RP24... photoresist pattern 98... ruthenium oxide film RP25. .. photoresist pattern 100... photoresist film RP31... photoresist pattern 102... gate insulating film RP41... photoresist pattern 108... polysilicon film RP42... photoresist pattern 110.. . The tantalum nitride film G... gate electrode 112... gate electrode CG... control gate 116... sidewall insulating film FG... floating gate 118.. gate electrode 144.. sidewall insulating film AR. ..active area 31

Claims (1)

十、申請專利範圍: ^〜-- 1. 一種半導體裝置,係包含有: 1321850 半導體基板,係具有第1區域及第2區域者. STI元件隔離區域,係由形成於前述半導體美板之 兀件隔離溝及埋入該元件隔離溝之絕緣膜形成,且分隔 前述第1區域與前述第2區域之複數活性區域者; 第1構造物,係形成於前述第丨區域之活性區域上至 φ 周圍之STI元件隔離區域,並具有第1高度者;及 第2構造物,係形成於前述第2區域之活性區域上至 周圍之STI元件隔離區域,並具有較前述第丨高度低之第 2高度者, 又,前述第1區域之STI元件隔_區域之表面較前述 第2區域之STI元件隔離區域之表面低, 且,前述第1區域為記憶體胞元區域,前述第2區域 為邏輯電路區域,記憶體胞元區域之STI表面高度與活 Φ 性區域表面高度大致相等。 2·如申請專利範圍第㈣之半導體裝置,其中前述第ι及第 2構造物含有層數不同之導電體。 ^申請專利範圍第1項之半導體裝置,其係具有形成於 别述複數活性區域表面並且厚度不同之閘絕緣膜、及形 成於與前述各雜區域邊界之前元相離區域的X. Patent application scope: ^~-- 1. A semiconductor device comprising: 1321850 semiconductor substrate, having the first region and the second region. The STI device isolation region is formed after the semiconductor chip. The isolation trench and the insulating film embedded in the element isolation trench are formed, and the plurality of active regions separating the first region and the second region are formed; and the first structure is formed on the active region of the second region to φ The surrounding STI element isolation region has a first height; and the second structure is formed on the active region of the second region to the surrounding STI element isolation region, and has a second lower than the first height Further, the surface of the STI element isolation region of the first region is lower than the surface of the STI element isolation region of the second region, and the first region is a memory cell region, and the second region is logic In the circuit area, the STI surface height of the memory cell region is substantially equal to the surface height of the active Φ region. 2. The semiconductor device of claim 4, wherein the first and second structures comprise electrical conductors having different numbers of layers. The semiconductor device of claim 1, which has a gate insulating film formed on a surface of a plurality of active regions and having different thicknesses, and a region which is formed in a region apart from a boundary of each of the aforementioned impurity regions 物為具有浮閘、 牛導體裝置,其中前述第1構造 閘間絕緣膜及控制閘之非依電性記憶體 32 1321850 之閘電極’且前述第2構造物為MOS電晶體之閘電極。 5·如申請專利範圍第4項之半導體裝置,其中前述STI元件 隔離區域在前述記憶體胞元區域與前述邏輯電路區域 之邊界區域具有段差,且該半導體裝置包含有覆蓋前述 段差’並由與前述浮閘相同之材料形成之虛擬浮閘。 6.如申請專利範圍第5項之半導體裝置,更包含有部份形 成於前述虛擬浮閘上,並由與前述閘間絕緣膜相同之材 料形成之虛擬閘間絕緣膜;及形成於前述虛擬閘間絕緣 膜及前述虛擬浮閘上,並由與前述控制閘相同之材料形 成之虛擬控制閘。 7· —種半導體裝置,包含具有互相厚度不同之閘絕緣膜的 記憶體胞元區域及邏輯電路區域,且記憶體胞元區域及 邏輯電路區域利用由埋入形成於半導體基板之溝所構成 之元件隔離膜而分隔,並且該元件隔離膜在與活性區域 之邊界具有凹部,又,記憶體胞元區域之元件隔離膜之 高度較前述邏輯電路區域之元件隔離膜之高度低。 8. —種半導體裝置之製造方法,包含有以下步驟: (a) 於具有第1區域及第2區域之半導體基板形成具 有用以分隔複數活性區域之元件隔離區域形狀開口之 光罩絕緣膜形圖案; (b) 將則述光罩絕緣膜圖案作為钱刻光罩,餘刻半導 體基板,而形成用以分隔複數活性區域之元件隔離溝; (c) 埋入前述元件隔離溝,以沉積元件隔離材料膜; (d) 利用化學機械研磨將前述元件隔離材料膜形成 33 1321850 元件隔離區域,且,露出前述罩絕緣膜圖案; (e)於前述步驟(d)之後,形成覆蓋前述第2區域之光 阻圖案,將前述第1區域之前述元件隔離區域蝕刻,除 去前述活性區域上之厚度之一部份; ⑴於前述步驟(e)之後,去除前述光罩絕緣膜圖案; (g) 於前述步驟⑴之後,形成從前述第1區域之活性 區域上延伸至其周圍之前述元件隔離區域上並具有第1 高度之第1構造物;及 (h) 於前述步驟⑴之後,形成從前述第2區域之活性 區域上延伸至其周圍之前述元件隔離區域上並具有較 第1高度低之第2高度之第2構造物, 又,前述第1區域為記憶體胞元區域,前述第2區域 為邏輯電路區域,且,記憶體胞元區域之STI表面高度 與活性區域表面高度大致相等。 9. 如申請專利範圍第8項之半導體裝置之製造方法,其中 前述步驟(g)及(h)形成層數不同之導電體。 10. 如申請專利範圍第8項之半導體裝置之製造方法,其 更包含以下步驟: ⑴於前述步驟(g)前,在前述複數活性區域上形成記 憶體胞元用閘絕緣膜; ⑴去除前述第2區域之前述記憶體胞元用閘絕緣 膜;及 (k)於前述第2區域之活性區域上形成MOS電晶體 用閘絕緣膜。 34 1321850 11. 如申請專利範圍第10項之半導體裝置之製造方法,更包 含以下步驟: (1)使用前述步驟(e)之光阻圖案,於前述第1區域進 行閾值控制用離子植入。 12. 如申請專利範圍第10項之半導體裝置之製造方法,其中 前述步驟(g)包含以下步驟: (g-Ι)覆蓋前述記憶體胞元用閘絕緣膜,形成浮閘層 (g-2)使前述浮閘層在閘寬度方向上形成圖案; (g-3)覆蓋前述閘寬度方向業經形成圖案之浮閘 層,而於半導體基板上形成閘間絕緣膜; (g-4)使前述閘間絕緣膜形成圖案; (g-5)覆蓋前述業經形成圖案之閘間絕緣膜,而於基 板上形成閘電極層; (g-6)使前述閘電極層形成圖案,且在閘長度方向上 使前述閘間絕緣膜、前述浮閘層形成圖案。 13. 如申請專利範圍第12項之半導體裝置之製造方法,其中 前述步驟(h)包含以下步驟: (h-1)與前述步驟(g-5) —同在前述第2區域於前述 MOS電晶體用閘絕緣膜上形成閘電極層; (h-2)在前述第2區域中使前述閘電極層形成圖案。 14. 如申請專利範圍第12項之半導體裝置之製造方法,其中 前述步驟(e)於前述元件隔離區域形成段差,且前述步驟 (g-2)於前述元件隔離區域之段差上保留虛擬浮閘。 15. 如申請專利範圍第14項之半導體裝置之製造方法,其中 35 1321850 前述步驟(g-4)於前述虛擬浮閘之部份表面上保留虛擬 閘間絕緣膜,且前述步驟(g-6)於前述虛擬浮閘、前述虛 擬閘間絕緣膜上保留虛擬閘。The device is a gate electrode having a floating gate and a cattle conductor device, wherein the first structure gate insulating film and the control gate are non-electrical memory 32 1321850 and the second structure is a gate electrode of the MOS transistor. 5. The semiconductor device of claim 4, wherein the STI element isolation region has a step difference between a boundary region of the memory cell region and the logic circuit region, and the semiconductor device includes a step covering the aforementioned step A virtual floating gate formed by the same material as the aforementioned floating gate. 6. The semiconductor device of claim 5, further comprising: a dummy inter-gate insulating film formed on the dummy floating gate and formed of the same material as the gate insulating film; and formed in the dummy A dummy control gate formed on the inter-gate insulating film and the dummy floating gate and formed of the same material as the aforementioned control gate. A semiconductor device comprising a memory cell region and a logic circuit region having gate insulating films having different thicknesses from each other, wherein the memory cell region and the logic circuit region are formed by a trench formed by embedding in the semiconductor substrate The element isolation film is separated, and the element isolation film has a concave portion at a boundary with the active region, and the height of the element isolation film of the memory cell region is lower than the height of the element isolation film of the logic circuit region. 8. A method of manufacturing a semiconductor device comprising the steps of: (a) forming a mask insulating film shape having an opening of an element isolation region for separating a plurality of active regions in a semiconductor substrate having a first region and a second region; (b) using the reticle insulating film pattern as a mask, and engraving the semiconductor substrate to form an element isolation trench for separating the plurality of active regions; (c) embedding the component isolation trench to deposit the device (d) forming the element isolation material film into a 33 1321850 element isolation region by chemical mechanical polishing, and exposing the cover insulating film pattern; (e) after the step (d), forming the second region a photoresist pattern, wherein the element isolation region of the first region is etched to remove a portion of the thickness of the active region; (1) after the step (e), removing the mask insulating film pattern; (g) After the step (1), forming a first structure having a first height from the element isolation region extending from the active region of the first region to the periphery thereof; (h) after the step (1), forming a second structure having a second height lower than the first height from the element isolation region extending from the active region of the second region to the periphery thereof, and the second structure The 1 region is a memory cell region, the second region is a logic circuit region, and the STI surface height of the memory cell region is substantially equal to the surface height of the active region. 9. The method of fabricating a semiconductor device according to claim 8, wherein the steps (g) and (h) form a conductor having a different number of layers. 10. The method of manufacturing a semiconductor device according to claim 8, further comprising the steps of: (1) forming a memory cell gate insulating film on the plurality of active regions before the step (g); (1) removing the foregoing a gate insulating film for the memory cell in the second region; and (k) a gate insulating film for the MOS transistor formed on the active region of the second region. The method of manufacturing a semiconductor device according to claim 10, further comprising the steps of: (1) performing ion implantation for threshold control in the first region using the photoresist pattern of the above step (e). 12. The method of manufacturing a semiconductor device according to claim 10, wherein the step (g) comprises the steps of: (g-Ι) covering the memory cell insulating film for the memory cell to form a floating gate layer (g-2) a pattern in which the floating gate layer is formed in the gate width direction; (g-3) a floating gate layer covering the gate width direction to form a pattern, and a gate insulating film is formed on the semiconductor substrate; (g-4) a gate insulating film is patterned; (g-5) covering the previously patterned gate insulating film to form a gate electrode layer on the substrate; (g-6) forming the gate electrode layer into a pattern and in the gate length direction The gate insulating film and the floating layer are patterned in the upper portion. 13. The method of manufacturing a semiconductor device according to claim 12, wherein the step (h) comprises the steps of: (h-1) and the aforementioned step (g-5) - in the foregoing second region in the aforementioned MOS A gate electrode layer is formed on the gate insulating film for a crystal; (h-2) the gate electrode layer is patterned in the second region. 14. The method of fabricating a semiconductor device according to claim 12, wherein the foregoing step (e) forms a step difference in the element isolation region, and the step (g-2) retains a dummy floating gate on a step difference of the element isolation region. . 15. The method of manufacturing a semiconductor device according to claim 14, wherein the step (g-4) retains a dummy inter-gate insulating film on a portion of the surface of the dummy floating gate, and the foregoing step (g-6) A dummy gate is left on the dummy floating gate and the aforementioned dummy gate insulating film. 3636
TW95123911A 2006-06-30 2006-06-30 Semiconductor device and semiconductor device manufacturing method TW200802859A (en)

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