TWI316534B - - Google Patents

Info

Publication number

TWI316534B

TWI316534B TW93112033A TW93112033A TWI316534B TW I316534 B TWI316534 B TW I316534B TW 93112033 A TW93112033 A TW 93112033A TW 93112033 A TW93112033 A TW 93112033A TW I316534 B TWI316534 B TW I316534B

Authority

TW

Taiwan

Prior art keywords

group

resin

circuit

film

bonding agent

Prior art date

2001-11-14

Links

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• Global Dossier
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• 239000011230 binding agent Substances 0.000 claims description 48
• 239000002245 particle Substances 0.000 claims description 39
• 238000006243 chemical reaction Methods 0.000 claims description 25
• 229920005989 resin Polymers 0.000 claims description 24
• 239000011347 resin Substances 0.000 claims description 24
• 229920001971 elastomer Polymers 0.000 claims description 20
• 239000005060 rubber Substances 0.000 claims description 20
• 239000000853 adhesive Substances 0.000 claims description 16
• 230000001070 adhesive effect Effects 0.000 claims description 16
• 239000007767 bonding agent Substances 0.000 claims description 15
• -1 hexafluoroantimonate Chemical compound 0.000 claims description 14
• 239000003822 epoxy resin Substances 0.000 claims description 9
• 229920000647 polyepoxide Polymers 0.000 claims description 9
• 230000020169 heat generation Effects 0.000 claims description 7
• 238000010438 heat treatment Methods 0.000 claims description 7
• 239000013034 phenoxy resin Substances 0.000 claims description 6
• 229920006287 phenoxy resin Polymers 0.000 claims description 6
• 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 3
• 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 3
• 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
• 125000000018 nitroso group Chemical group N(=O)* 0.000 claims description 3
• 229920000768 polyamine Polymers 0.000 claims description 3
• 229920005992 thermoplastic resin Polymers 0.000 claims description 3
• 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 claims description 2
• NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical group FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims description 2
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
• 229920001225 polyester resin Polymers 0.000 claims description 2
• 239000004645 polyester resin Substances 0.000 claims description 2
• 238000003825 pressing Methods 0.000 claims description 2
• 125000003396 thiol group Chemical group [H]S* 0.000 claims description 2
• 229920000642 polymer Polymers 0.000 claims 6
• 125000004093 cyano group Chemical group *C#N 0.000 claims 2
• 150000004714 phosphonium salts Chemical class 0.000 claims 2
• KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical group F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims 1
• 125000005131 dialkylammonium group Chemical group 0.000 claims 1
• 125000005208 trialkylammonium group Chemical group 0.000 claims 1
• 239000000758 substrate Substances 0.000 description 21
• 239000000463 material Substances 0.000 description 13
• 239000010931 gold Substances 0.000 description 11
• 239000010410 layer Substances 0.000 description 11
• 239000000243 solution Substances 0.000 description 11
• KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 7
• 239000003795 chemical substances by application Substances 0.000 description 7
• 239000011521 glass Substances 0.000 description 7
• 229910052707 ruthenium Inorganic materials 0.000 description 7
• 229910052737 gold Inorganic materials 0.000 description 6
• 239000000203 mixture Substances 0.000 description 6
• PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
• 230000000052 comparative effect Effects 0.000 description 5
• 239000011256 inorganic filler Substances 0.000 description 5
• 229910003475 inorganic filler Inorganic materials 0.000 description 5
• 238000000034 method Methods 0.000 description 5
• 229910000679 solder Inorganic materials 0.000 description 5
• QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
• 239000004593 Epoxy Substances 0.000 description 4
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
• PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 4
• 230000035939 shock Effects 0.000 description 4
• 239000000126 substance Substances 0.000 description 4
• XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
• HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
• 239000002313 adhesive film Substances 0.000 description 3
• 239000011248 coating agent Substances 0.000 description 3
• 238000000576 coating method Methods 0.000 description 3
• 230000000694 effects Effects 0.000 description 3
• 238000011049 filling Methods 0.000 description 3
• 239000007888 film coating Substances 0.000 description 3
• 238000009501 film coating Methods 0.000 description 3
• 238000005259 measurement Methods 0.000 description 3
• DIOQZVSQGTUSAI-UHFFFAOYSA-N n-butylhexane Natural products CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 3
• 230000009257 reactivity Effects 0.000 description 3
• 150000003839 salts Chemical class 0.000 description 3
• 239000002904 solvent Substances 0.000 description 3
• PXKLMJQFEQBVLD-UHFFFAOYSA-N Bisphenol F Natural products C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
• 229920002799 BoPET Polymers 0.000 description 2
• VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
• UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
• PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
• 239000012790 adhesive layer Substances 0.000 description 2
• 229910021529 ammonia Inorganic materials 0.000 description 2
• 238000005452 bending Methods 0.000 description 2
• 230000015572 biosynthetic process Effects 0.000 description 2
• IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
• 230000008859 change Effects 0.000 description 2
• 210000000078 claw Anatomy 0.000 description 2
• 229910052802 copper Inorganic materials 0.000 description 2
• 230000006378 damage Effects 0.000 description 2
• ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
• 239000010419 fine particle Substances 0.000 description 2
• 125000000524 functional group Chemical group 0.000 description 2
• 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 2
• 238000009413 insulation Methods 0.000 description 2
• 150000002500 ions Chemical class 0.000 description 2
• 229920003986 novolac Polymers 0.000 description 2
• 229920000139 polyethylene terephthalate Polymers 0.000 description 2
• 239000005020 polyethylene terephthalate Substances 0.000 description 2
• 239000002344 surface layer Substances 0.000 description 2
• VHUQXPJHMISKGS-UHFFFAOYSA-N 1-(chloromethoxy)propane Chemical compound CCCOCCl VHUQXPJHMISKGS-UHFFFAOYSA-N 0.000 description 1
• KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
• PMATZTZNYRCHOR-CGLBZJNRSA-N Cyclosporin A Chemical compound CC[C@@H]1NC(=O)[C@H]([C@H](O)[C@H](C)C\C=C\C)N(C)C(=O)[C@H](C(C)C)N(C)C(=O)[C@H](CC(C)C)N(C)C(=O)[C@H](CC(C)C)N(C)C(=O)[C@@H](C)NC(=O)[C@H](C)NC(=O)[C@H](CC(C)C)N(C)C(=O)[C@H](C(C)C)NC(=O)[C@H](CC(C)C)N(C)C(=O)CN(C)C1=O PMATZTZNYRCHOR-CGLBZJNRSA-N 0.000 description 1
• 108010036949 Cyclosporine Proteins 0.000 description 1
• 229920000877 Melamine resin Polymers 0.000 description 1
• 229920000459 Nitrile rubber Polymers 0.000 description 1
• 239000005062 Polybutadiene Substances 0.000 description 1
• 239000004698 Polyethylene Substances 0.000 description 1
• 239000004642 Polyimide Substances 0.000 description 1
• 239000004743 Polypropylene Substances 0.000 description 1
• 240000006394 Sorghum bicolor Species 0.000 description 1
• 235000011684 Sorghum saccharatum Nutrition 0.000 description 1
• 208000027418 Wounds and injury Diseases 0.000 description 1
• 239000002250 absorbent Substances 0.000 description 1
• 238000010521 absorption reaction Methods 0.000 description 1
• 230000004913 activation Effects 0.000 description 1
• 230000002411 adverse Effects 0.000 description 1
• 238000007605 air drying Methods 0.000 description 1
• 125000002723 alicyclic group Chemical group 0.000 description 1
• PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
• 150000001450 anions Chemical class 0.000 description 1
• 239000007864 aqueous solution Substances 0.000 description 1
• 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
• 235000010290 biphenyl Nutrition 0.000 description 1
• 239000004305 biphenyl Substances 0.000 description 1
• 239000004841 bisphenol A epoxy resin Substances 0.000 description 1
• 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
• 229910000019 calcium carbonate Inorganic materials 0.000 description 1
• 239000000378 calcium silicate Substances 0.000 description 1
• 229910052918 calcium silicate Inorganic materials 0.000 description 1
• OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
• CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 1
• 229910000420 cerium oxide Inorganic materials 0.000 description 1
• 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 1
• 229960001265 ciclosporin Drugs 0.000 description 1
• 239000011247 coating layer Substances 0.000 description 1
• 239000000571 coke Substances 0.000 description 1
• 239000004020 conductor Substances 0.000 description 1
• 239000007822 coupling agent Substances 0.000 description 1
• 229930182912 cyclosporin Natural products 0.000 description 1
• 210000003298 dental enamel Anatomy 0.000 description 1
• 230000006866 deterioration Effects 0.000 description 1
• QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 1
• GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
• 238000007598 dipping method Methods 0.000 description 1
• 239000000945 filler Substances 0.000 description 1
• 239000007789 gas Substances 0.000 description 1
• 238000002309 gasification Methods 0.000 description 1
• 230000009477 glass transition Effects 0.000 description 1
• 230000003301 hydrolyzing effect Effects 0.000 description 1
• 150000002466 imines Chemical class 0.000 description 1
• 239000012535 impurity Substances 0.000 description 1
• 208000014674 injury Diseases 0.000 description 1
• JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
• 239000007788 liquid Substances 0.000 description 1
• 239000004850 liquid epoxy resins (LERs) Substances 0.000 description 1
• 235000012054 meals Nutrition 0.000 description 1
• 238000000691 measurement method Methods 0.000 description 1
• JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
• 239000002923 metal particle Substances 0.000 description 1
• 230000005012 migration Effects 0.000 description 1
• 238000013508 migration Methods 0.000 description 1
• 239000012046 mixed solvent Substances 0.000 description 1
• 238000002156 mixing Methods 0.000 description 1
• 125000001624 naphthyl group Chemical group 0.000 description 1
• 150000002815 nickel Chemical class 0.000 description 1
• 150000001451 organic peroxides Chemical class 0.000 description 1
• 239000003960 organic solvent Substances 0.000 description 1
• BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
• 239000001301 oxygen Substances 0.000 description 1
• 229910052760 oxygen Inorganic materials 0.000 description 1
• 238000002161 passivation Methods 0.000 description 1
• ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
• 229920001568 phenolic resin Polymers 0.000 description 1
• 239000005011 phenolic resin Substances 0.000 description 1
• 238000007747 plating Methods 0.000 description 1
• 229920006122 polyamide resin Polymers 0.000 description 1
• 229920002857 polybutadiene Polymers 0.000 description 1
• 238000006068 polycondensation reaction Methods 0.000 description 1
• 229920000728 polyester Polymers 0.000 description 1
• 229920000573 polyethylene Polymers 0.000 description 1
• 229920001721 polyimide Polymers 0.000 description 1
• 229920006254 polymer film Polymers 0.000 description 1
• 239000002861 polymer material Substances 0.000 description 1
• 230000000379 polymerizing effect Effects 0.000 description 1
• 229920001155 polypropylene Polymers 0.000 description 1
• 229920001296 polysiloxane Polymers 0.000 description 1
• 239000011148 porous material Substances 0.000 description 1
• 239000000843 powder Substances 0.000 description 1
• 230000002265 prevention Effects 0.000 description 1
• 230000008569 process Effects 0.000 description 1
• 210000003296 saliva Anatomy 0.000 description 1
• 229910052709 silver Inorganic materials 0.000 description 1
• 235000011121 sodium hydroxide Nutrition 0.000 description 1
• 239000007787 solid Substances 0.000 description 1
• 239000004575 stone Substances 0.000 description 1
• 159000000008 strontium salts Chemical class 0.000 description 1
• 229920003048 styrene butadiene rubber Polymers 0.000 description 1
• 229910052718 tin Inorganic materials 0.000 description 1
• 239000002966 varnish Substances 0.000 description 1
• 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1