1309227 玖、發明說明： 【發明所屬之技術領域】 本發明是有關於一種淨水劑的製造方法，特別是指一 種耐沖泡、粒度均-，且可節省製造成本的冷塑陶曼渡材 5 之製法。 【先前技術】 隨著科技時代的進步，地球之水資源因大量垃圾的土 埋' 農藥肥n污水的毒害··.等等’造成原水污濁不堪 飲用’導致水源需要經過消毒、殺菌處理之後才能飲用， 1〇 纟衍生的社會成本無料算，而且，經過處理後之品質良 好的原水已漸難以確保，故自來水中的氣含量亦有逐漸增 加的趨勢，相對的水中的氯臭越來越濃而難以飲用。 此外，在科學實證驗明下，含有多量妈離子之驗性飲 用欠對健康有益已廣為眾知，其原理是以珊蝴石等礦物為 15 &材’利用電解法或燒結法獲得含多㈣、鈉、卸等之驗 離子，藉以將自來水中的鹽酸成份中和’其反應式如下：1309227 玖, the invention description: [Technical field of the invention] The present invention relates to a method for producing a water purifying agent, in particular to a cold-molded Tauman crossing material which is resistant to brewing, has a uniform particle size, and can save manufacturing costs. 5 method of production. [Prior Art] With the advancement of the technology era, the earth's water resources are buried in the soil of a large amount of garbage. 'Pesticide fertilizers, sewage, poison, etc.' cause the raw water to be filthy and unsatisfactory, so that the water source needs to be disinfected and sterilized. Drinking, 1〇纟 derived social cost is unpredictable, and the quality of the raw water after treatment has gradually become difficult to ensure, so the gas content in tap water also gradually increases, the relative chlorine in the water is getting thicker It is difficult to drink. In addition, under scientific evidence, the use of a large amount of mother ions is widely known to be beneficial to health. The principle is that minerals such as sapphire are 15 & Multi-(iv), sodium, unloading, etc., to neutralize the hydrochloric acid component in tap water. The reaction formula is as follows:
CaC03 + 2HC1 Ca2+ +2C1_ +C02 丨 + H20 目前運用此法的文獻除了上述的電解法外，亦可見諸 於公告第273540號「淨水劑」發明案，如圖1所示，其主 2〇 $是將貝殼及珊瑚砂等原物料施以高溫煅燒後，以成為在 碳酸妈表層附著有附量氧_的淨水素材，接著 ，再將該淨水素#碎解成多數顆粒狀，而能獲得由99.5%〜 ㈣碳酸妈及0.5%〜m重量之氧化妈組成的淨水劑，且氧 化舞是附著於碳_之表面，利用此物劑溶於水中後可達 1309227 二-文驗中和，除了改善了水中酸性成份外，也因除去了氯 - 孔等臭異物，因此也大符提昇了飲用時的口感。 _ 值得注意的是’由於碳酸鈣粒子的比表面積（以bet法 測定）過小時’會使得存在於粒子表面的氧化鈣變得較厚 二兩者難有充份的混合強度，反之，若比表面積太大時， 氧化鈣初期溶出量過多造成PH值過高，無法繼續使用，基 於上2述的原因’淨水劑粒子的比表面積數值必須在〇〇5〜 50nl /g範圍左右較佳。然而，由於上述的淨水粒是直接對素 材碎擊取得，因此很難控制每一顆粒大小尺寸（比表面積春 )的均—性，如此一來，溶出鈣量的性能便很難取得較精 準憑量基準。 此外，碎解後尺寸過小的淨水粒也只能直接棄置，造 成成本的浪費，雖有業者嘗試包裝後再利用，但使用上仍 未臻理想’故習知淨水劑的製法，實值得吾人予以改進突 破。 【發明内容】 因此，本發明之目的，即在提供一種充泡耐久性佳、# 粒度均一，且節省製造成本的冷塑陶瓷濾材之製法。 於是，本發明之冷塑陶U材之製法，包含下列步驟： 一、備料：取用適量之珊蝴砂、貝殼為原物料，並經過清潔 表面處理—爪燒.將上述原物料經過高溫炮燒，以獲得 碳酸舞及氧㈣為主成份之礦石基材。三、研磨：將前述之 礦石基材予以碎解、研磨成粉末狀顆粒，並且使每一顆粒介 於1_網目/英寸2〜100奈米（’meter)的尺寸大小 5 1309227 。四、潤濕：在前述的礦石粉末喷送水液，使其表面略呈稠 糊狀。五、搓揉造粒：以振動方式使礦石粉末凝結為顆粒狀 素材，並控制在0.5〜2公分之顆粒大小。以及六、蔭乾： 將前述的顆粒素材在濕度45〜60% 、溫度25〜3(rc^^境 5 下，予以自瞻，歷時約24〜48小時以上，可獲得硬： 且粒度均一的顆粒狀淨水劑濾材。 【實施方式】 有關本發明之前述及其他技術内容、特點與功效，在 以下配合參考圖式之一較佳實施例的詳細說明中，將可清 1 〇 楚的明白。 '月 如圖2、圖3所示，本發明之冷塑陶瓷濾材之製法，其 —較佳實施例是包含下列步驟： 【步驟-】備料：取用適量之珊瑚砂、貝殼（可視欲處 理的水質狀況加入石灰、活性碳、麥飯石等其中一種，或 15 任種以上的組合）為原物料，並經過清潔原物料表面處 以遽除原物料中粉塵微粒、雜質。 山【步驟二】煅燒：將上述原物料經過高溫煅燒，以獲得 碳酸鈣及氧化鈣為主成份之礦石基材1〇。 【步驟一】研磨·將别述之礦石基材予以粉碎後， 2〇 再經過一研磨裝置80研磨成粉末狀礦石粉末2〇，並且使每 —顆粒介於1000網目/英寸2〜1〇〇奈米（nan〇 meter)的尺 寸大小。 ^【步驟四】潤濕：在前述的礦石粉末20予以充份攪拌 後置入一盛置裝置30内，在其上方喷送水液，使礦石粉末 6 1309227 20表面略呈稠糊狀β ίο 〜【步驟五】搓揉造粒：在礦石粉末川表面的水液未乾 综月]gP利用一振動機4〇以振動方式驅使礦石粉末在 該盛置裝置30上滚動’而可產生搓揉效果，使呈粉末狀的 礦石粉末20藉著表面沾附的水液，以逐步的凝結聚合成顆 粒狀素材50 ’並利用一接續在該振動機4〇底側的筛網^ 控制每i粒素材5G在G·5〜2公分之顆粒大小，在此作業 中，粒徑過小的素材則再經噴水後重覆上述的搓揉造粒動 作’直至符合所需尺寸’反之，粒徑過大的顆粒素材50則 再經過粉碎回收，並置人該盛置裝置30内，以備重覆使用 【步驟六】隱乾：將前述的素材5G在濕度45%〜60% :度25〜30 C的環境下，予以自然蔭乾’歷時約24〜48 J 了以上可獲知硬化且粒度均一的顆粒狀淨水齊1 6〇渡材 (見圖4)。 如圖4所示，本發明成品可置入一筒狀的混合單元7〇 内使用，當乾淨的水經過該混合單元7〇内上層活性碳71 的過遽後，可除去水中的氯異味，再經過置人該混合單元 70内部之淨水#丨6G產生離子交換作用，達到祕中和之效 用。 藉由上述裝造方法以使得該淨水劑粒子在生產時具有 以下優點： ^ 本發明製程是將煅燒後的原物料研磨成奈米級的 粉末後，再予搓揉造粒，製成的成品粒度較為均-，且成 1309227 品内碳酸鈣及氧化鈣成份能完全地融合，因此溶解鈣的析 出量較為平均，飲用水的PH值可控制在一定的範圍内，且 因奈米級的粉末粒子間吸附結合力大增，故沖泡性持久。 二、再者，在製程中，粒徑過小的顆粒素材5〇可再經 喷水後施以搓揉造粒動作，不浪費原物料，而粒徑過大的 顆粒素材测再經過粉碎回收，以備重覆❹，故可大幅 降低製造成本。 10 15 惟以上所述者’僅為本發明之一較佳實施例而已，當 不=以此限定本發明實施之範圍，即大凡依本發明申請專 :乾圍及新型說明書内容所作之簡單的等效變化與修飾， 皆應仍屬本發明專利涵蓋之範圍内。 【圖式簡單說明】 圖1是-流程方塊圖，說明一種習知淨水劑 法步驟； '、^圖2疋一流程方塊圖，說明本發明冷塑陶究濾材之製 去的方法步驟； 农 製造：是:平面圖’說明本發明冷塑陶撫之，法的 圖4是一剖視圖，說明本發明w 、θ入〜 滹 贫明置入一混合早兀内進行 W水的貫施態樣。 丁 20 1309227 【圖式之主要元件代表符號說明】 10… * _…礦石基材 50…· .....素材 2 0 *… .....礦石粉末 60… .....淨水劑 30 ·· ••…盛置裝置 70… ••…混合單元 40 ···· .....振動機 71 ···· * ·…活性石厌 41…· …篩網 80 ··.· ••…研磨裝置 9CaC03 + 2HC1 Ca2+ +2C1_ +C02 丨+ H20 In addition to the above electrolysis method, the literature using this method can also be found in the invention of the "Water Purifying Agent" No. 273540, as shown in Figure 1, the main 2〇 $ is to use a raw material such as shells and coral sand to be calcined at a high temperature, so as to become a water purification material with an attached amount of oxygen attached to the surface of the carbonated mother, and then the purified water is broken into a plurality of particles. Can get a water purifying agent composed of 99.5% ~ (four) carbonic acid mother and 0.5% ~ m weight of oxidation mother, and the oxidative dance is attached to the surface of carbon, using this agent to dissolve in water up to 1309227 II - test Neutralization, in addition to improving the acidic components in the water, is also due to the removal of chlorine-holes and other stinky foreign matter, so it also enhances the taste of drinking. _ It is worth noting that 'because the specific surface area of the calcium carbonate particles (measured by the beta method) is too small, the calcium oxide present on the surface of the particles becomes thicker and the two are difficult to have sufficient mixing strength. When the surface area is too large, the initial amount of calcium oxide is too large to cause the pH to be too high to be used. For the reason described above, the specific surface area of the water purifying agent particles must be in the range of about 5 to 50 nl / g. However, since the above-mentioned clean water particles are directly obtained from the material shattering, it is difficult to control the uniformity of each particle size (the specific surface area of spring), so that the performance of the dissolved calcium amount is difficult to obtain more accurate. Basis basis. In addition, the clean water particles with too small size after disintegration can only be disposed of directly, resulting in waste of cost. Although some operators try to use it after packaging, it is still not ideal for use. Therefore, it is worthwhile to make the water purification agent. We have made breakthroughs in improvement. SUMMARY OF THE INVENTION Accordingly, it is an object of the present invention to provide a method for producing a cold-molded ceramic filter material which has excellent foaming durability, uniform particle size, and cost savings. Therefore, the method for preparing the cold-plastic ceramic U material of the present invention comprises the following steps: 1. Preparation: use an appropriate amount of sand and shells as raw materials, and clean the surface treatment - claw burning. The above raw materials are passed through a high temperature gun. Burn to obtain ore substrate with carbon dance and oxygen (4) as the main component. 3. Grinding: The aforementioned ore substrate is disintegrated, ground into powdery granules, and each granule is passed through a size of 1 1 mesh/inch 2 to 100 nanometers ('meter) 5 1309227. 4. Wetting: The water is sprayed on the ore powder to make the surface slightly thick. 5. Granulation of granules: The ore powder is condensed into granular material by vibration, and the particle size is controlled at 0.5 to 2 cm. And six, the shade: the above-mentioned particle material in the humidity of 45~60%, temperature 25~3 (rc^^ environment 5, self-viewing, lasting about 24~48 hours, can get hard: and uniform particle size Granular water purifying agent filter. [Embodiment] The above-mentioned and other technical contents, features and effects of the present invention will be clearly understood in the following detailed description of a preferred embodiment of the reference drawings. As shown in FIG. 2 and FIG. 3, the method for manufacturing the cold-plastic ceramic filter material of the present invention, the preferred embodiment comprises the following steps: [Step--] Preparation: use appropriate amount of coral sand and shells (visually The treated water quality condition is added to one of lime, activated carbon, medical stone, or a combination of more than 15 kinds of raw materials, and the surface of the raw material is cleaned to remove dust particles and impurities in the raw material. [Step 2] Calcination: The above raw materials are calcined at a high temperature to obtain an ore substrate containing calcium carbonate and calcium oxide as the main component. [Step 1] Grinding, the ore substrate described above is pulverized, and then subjected to a grinding. Set 80 to a powdered ore powder 2 〇, and make each particle between 1000 mesh / inch 2 ~ 1 nanometer (nan〇meter) size. ^ [Step 4] Wetting: in the aforementioned ore The powder 20 is thoroughly stirred and placed in a holding device 30, and the water liquid is sprayed thereon to make the surface of the ore powder 6 1309227 20 slightly thick paste β ίο 〜 [Step 5] 搓揉 granulation: in ore powder The water on the surface of the Sichuan River is not dry.] The gP uses a vibrating machine to vibrate the ore powder on the holding device 30 to generate a sputum effect, so that the powdered ore powder 20 is The water adhered to the surface is gradually aggregated into a granular material 50' and the particle size of the 5 G at 5·2 cm is controlled by a screen which is connected to the bottom side of the vibrating machine 4 In this operation, if the material with too small particle size is sprayed, the above-mentioned granule granulation operation is repeated until it meets the required size. On the contrary, the particle material 50 having an excessively large particle size is pulverized and recovered. In the holding device 30, for repeated use [Step 6] Stealth: The above-mentioned material 5G is subjected to natural shade drying under the environment of humidity 45%~60%: degree 25~30 C. The time is about 24~48 J. The granular water with uniform particle size can be obtained. 1 6 〇 crossing material (see Figure 4). As shown in Figure 4, the finished product of the present invention can be placed in a cylindrical mixing unit 7 ,, when clean water passes through the mixing unit 7 〇 inner upper activated carbon 71 After the mashing, the chlorine odor in the water can be removed, and the ion exchange effect is generated by the purified water #丨6G placed inside the mixing unit 70, thereby achieving the effect of the secret neutralization. The water purifying agent is made by the above-mentioned packaging method. The particles have the following advantages in production: ^ The process of the invention is to grind the calcined raw materials into nanometer-sized powders, and then granulate the granules, and the finished product has a uniform particle size, and is formed into 1309227 carbonic acid. Calcium and calcium oxide components can be completely fused, so the amount of dissolved calcium is relatively average, the pH value of drinking water can be controlled within a certain range, and the adsorption and binding force between the nano-sized powder particles is greatly increased, so brewing Sexually persistent. Second, in the process, the particle material with too small particle size can be granulated after spraying water, and the raw material is not wasted, and the particle material with excessive particle size is pulverized and recycled. The equipment is overhauled, so the manufacturing cost can be greatly reduced. 10 15 However, the above description is only a preferred embodiment of the present invention, and does not limit the scope of implementation of the present invention, that is, the simple application of the invention according to the present invention: the content of the dry and new instructions Equivalent variations and modifications are still within the scope of the invention. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a flow block diagram showing a conventional water purifying agent method step; ', Fig. 2, a flow block diagram showing the method steps of the cold plastic ceramsite filter material of the present invention; Agricultural production: Yes: Plan view 'Describes the cold plastic pottery of the present invention, and FIG. 4 of the method is a cross-sectional view showing the W, θ into ~ 滹 明 置 置 置 置 置 置 置 置 置 置 置 置 置 置 置 置 置 置 置 置. Ding 20 1309227 [Description of the main components of the figure] 10... * _...Ore substrate 50...·...Material 2 0 *.....Ore powder 60........Clean water Agent 30 ··••...Storage device 70...••...Mixed unit 40 ····································································· · ••...grinding device 9