200530130 玫、發明說明： 【發明所屬之技術領域】 本^明疋有關於-種淨水劑的製造方法，特別是指一 種耐冲/包、粒度均_，且可節省製造成本的冷塑陶究遽材 【先前技術】 &著科技時代的進步，地球之水資源因大量垃圾的土 里辰藥肥料、工業污水的毒害··等等，造成原水污濁不堪 飲用_ ’導致水源需要經過消毒、殺菌處理之後才能飲用， 10 '、行生的社會成本無法計算，而且，經過處理後之品質良 好的原水已漸難以確保，故自來水中的氯含量亦有逐漸增 加的趨勢，相對的水中的氯臭越來越濃而難以飲用。 此外，在科學實證驗明下，含有多㈣離子之驗性飲 用水對健康有益已廣為眾知，其原理是以珊蝴石等礦物為 15 I材’利用電解法或燒結法獲得含多㈣、鈉、鉀等之驗 離子，藉以將自來水中的鹽酸成份中和，其反應式如下：200530130 Rose, description of the invention: [Technical field to which the invention belongs] The present invention relates to a method for manufacturing a water purifying agent, particularly a cold-plastic ceramic that is resistant to shocks / bags, has a uniform particle size, and can save manufacturing costs. Studying the materials [Previous technology] & With the advancement of the scientific and technological era, the water of the earth is polluted by the poisonous soil and fertilizers of industrial waste, industrial sewage, etc., making the raw water dirty and drinkable _ 'The water source needs to be disinfected It can only be consumed after sterilization treatment. 10 ', the social cost of traveling can not be calculated, and it is difficult to ensure the good quality of raw water after treatment. Therefore, the chlorine content in tap water is also gradually increasing. The smell of chlorine is getting stronger and harder to drink. In addition, under the scientific and empirical verification, it is widely known that the test drinking water containing polyfluoride ions is beneficial to health. The principle is based on the use of minerals such as chrysanthemum as 15 I materials. The test ions of tritium, sodium, potassium, etc. are used to neutralize the hydrochloric acid component in tap water. The reaction formula is as follows:
CaC03 + 2HC1 — Ca2+ +2Cr +C02 个 + h20 目前運用此法的文獻除了上述的電解法外，亦可見諸 於公告第273540號「淨水劑」發明案，如圖j所示，其主 10 要是將貝殼及珊瑚砂等原物料施以高溫烺燒後，以成為在 碳酸鈣表層附著有〇_5%〜10%重量氧化鈣的淨水素材，接著 ，再將該淨水素材碎解成多數顆粒狀，而能獲得由995%〜 90%碳酸鈣及0.5%〜1⑽重量之氧化鈣組成的淨水劑，且氧 化鈣是附著於碳酸鈣之表面，利用此物劑溶於水中後可、 200530130 到酸驗中和，除了改善了水中酸性成份外，也因除去了氯‘ 氣等臭異物，因此也大符提昇了飲用時的口感。 值得注意的是，由於碳酸鈣粒子的比表面積（以BET法 ’貝】疋）過小時’會使得存在於粒子表面的氧化約變得較厚 ’兩者難有充份的混合強度，反之，若比表面積太大時， 氧化莉初期溶出量過多造成PH值過高，無法繼續使用，基 於上述的原因，淨水劑粒子的比表面積數值必須在0 05〜 50m /g範圍左右較佳。然而，由於上述的淨水粒是直接對素 ίο 15 20 材碎擊取得，因此很難控制每一顆粒大小尺寸（比表面積鲁 )的均性，如此一來，溶出妈量的性能便很難取得較精 準憑量基準。 此外’碎解後尺寸過小的淨水粒也只能直接棄置，造 成成本的浪費，雖有業者嘗試包裝後再利用，但使用上仍 未臻理想，故習知淨水劑的製法，實值得吾人予以改進突 破。 【發明内容】 因此，本發明之目的，即在提供一種充泡耐久性佳、鲁 粒度均一’且節省製造成本的冷塑陶瓷濾材之製法。 於是，本發明之冷塑陶瓷濾材之製法，包含下列步驟： 一、備料：取用適量之珊瑚砂、貝殼為原物料，並經過清潔 表面處理。二、燒結：將上述原物料經過高溫燒結，以獲得 碳酸鈣及氧化鈣為主成份之礦石基材。三、研磨：將前述之 礦石基材予以碎解、研磨成粉末狀顆粒，並且使每一顆粒介 於1000網目/英寸2〜100奈米（nano)的尺寸大小。四；、丨 5 200530130 潤濕：在前述的礦石粉末噴送水液，使其表面略呈稠糊狀。 五、搓揉造粒：以振動方式使礦石粉末凝結為顆粒狀素材， 並控制在0· 5〜2公分之顆粒大小。以及六、蔭乾：將前述 的顆粒素材在濕度45〜60% 、溫度25〜30°C的環境下，予 以自然蔭乾，壢時約24〜48小時以上，可獲得硬化且粒度 均一的顆粒狀淨水劑濾材。 【實施方式】 有關本發明之前述及其他技術内容、特點與功效，在 ίο 15 以下配合參考圖式之一較佳實施例的詳細說明巾，將可清 楚的明白。 如圖2、圖3所示，本發明之冷塑陶㈣、材之製法，其 一較佳實施例是包含下列步驟： 【步驟-】備料：取用適量之珊瑚砂、貝殼（可視欲處 理的水質狀況加入石灰、活性碳、麥飯石等其中 任-種以上的組合）為原物料，並經過清潔原物料表面^ 理’以濾除原物料中粉塵微粒、雜質。 U初料經過高溫燒結 碳酸鈣及氧化鈣為主成份之礦石基材1〇。 【步称三】研磨：將前述之礦石基材ig予以粉碎後 再經過-研磨裝置80研磨成粉末狀礦石粉末2〇，並且使 一顆粒介於麵網目/英寸2〜_奈米（職。）的尺寸 後置人一盛置裝置3。内，在其上方=水:予：= 20 200530130 20表面略呈稠糊狀。 ίο 【步称五】搓揉造粒：在礦石粉末2q表面的水液未乾 综刖，即利用-振動機40以振動方式驅使礦石粉末別在 該盛置裝置30上滾動，而可產生搓揉效果，使呈粉末狀的 礦石籾末20藉者表面沾附的水液，以逐步的凝結聚合成顆 粒狀素材5G ’並利用_接續在該振動機4()底側的篩網w 控制每-顆粒素材50纽5〜2公分之顆粒大小，在此作業 中，粒徑過小的素㈣再㈣水後重覆上述的搓揉造粒動 作’直至符合所需尺寸，反之，粒徑過大的顆粒素材％則 再經過粉碎时，並置人«置裝置内，Μ重覆使用 【步称六】$乾：將前述的素材5G在濕度〜6〇% /皿度25 30 C的環境下’予以自然蔭乾，壢時約％〜48 J τ以上可獲得硬化且粒度均一的顆粒狀淨水劑6〇濾材 15 (見圖 4)。 > 如圖4所不，本發明成品可置入一筒狀的混合單元7〇 内使用’當乾淨的水經過該混合單元7G内上層活性碳71 的過濾後可除去水中的氯異味，再經過置入該混合單元 70内4之淨水劑6G產生離子交換作用，達到驗中和之效 20 用。 藉由上述製造方法以使得該淨水劑粒子在生產時具有 以下優點： 一、本發明製程是將燒結後的原物料研磨成奈米級的 粉末後，再予搓揉造粒，製成的成品粒度較為均一，且成 200530130 品内碳酸媽及氧化I弓成份能完全地融合，因此溶解转的才斤 出Ϊ較為平均’飲用水的PH值可控制在一定的範圍内，且 因奈米級的粉末粒子間吸附結合力大增，故沖泡性持久。 二、再者，在製程中，粒徑過小的顆粒素材5〇可再經 喷水後施以搓揉造粒動作，不浪費原物料，而粒徑過大的 顆粒素材50則再經過粉碎回收，以備重覆使用，故可大幅 降低製造成本。 惟以上所述者，僅為本發明之一較佳實施例而已，當 不能以此限定本發明實施之範圍，即大凡依本發明申請專參 利範圍及新型說明書内容所作之簡單的等效變化與修飾， 皆應仍屬本發明專利涵蓋之範圍内。 【圖式簡單說明】 圖1是一流程方塊圖，說明一種習知淨水劑的製作方 法步驟； 圖2疋机私方塊圖，說明本發明冷塑陶瓷濾材之製 法的方法步驟； 圖3疋一平面圖，說明本發明冷塑陶曼遽材之製法的· 製造方式；及 圖4是剖視圖，說明本發明置入一混合單元内進行 慮水的實施態樣。 8 200530130 【圖式之主要元件代表符號說明】 10·… 礦石基材 50. · * 素材 20…· 礦石粉末 60. · • 淨水劑 30· · · 盛置裝置 70. · • 混合單元 4〇 .… 振動機 71· * 4 活性碳 4卜… 師網 80*. •研磨裝置 9CaC03 + 2HC1 — Ca2 + + 2Cr + C02 pieces + h20 In addition to the above-mentioned electrolytic method, the literatures using this method can also be found in the invention of "Water Purifier" No. 273540, as shown in Figure j. If raw materials such as shells and coral sand are subjected to high-temperature sintering, it becomes a water purification material with 0-5% to 10% by weight of calcium oxide attached to the surface of the calcium carbonate, and the water purification material is then broken into Most of them are granular, and can obtain water purifying agent composed of 995% ~ 90% calcium carbonate and 0.5% ~ 1% by weight of calcium oxide, and calcium oxide is adhered to the surface of calcium carbonate. , 200530130 In addition to neutralizing the acid test, in addition to improving the acidic components in the water, it also removes odorous foreign substances such as chlorine, so it greatly improves the taste when drinking. It is worth noting that, because the specific surface area of the calcium carbonate particles (by the BET method ') is too small', the oxidation existing on the surface of the particles becomes thicker. 'The two are difficult to have sufficient mixing strength, otherwise, If the specific surface area is too large, the initial dissolution amount of oxidant will cause the pH value to be too high to continue to be used. Based on the above reasons, the specific surface area value of the water purification agent particles must preferably be in the range of 0 05 ~ 50m / g. However, since the above-mentioned water purification particles are directly obtained by crushing raw materials, it is difficult to control the uniformity of each particle size (specific surface area). As a result, the performance of the dissolution amount is difficult. Obtain a more accurate benchmark. In addition, the size of the water purification particles that are too small after disintegration can only be discarded directly, resulting in a waste of costs. Although some operators have tried packaging and reused, they are still not ideal in use. Therefore, it is worthwhile to know how to make water purification agents. I make improvements and breakthroughs. [Summary of the Invention] Therefore, an object of the present invention is to provide a method for manufacturing a cold-plastic ceramic filter material with excellent foaming durability, uniform particle size, and saving manufacturing costs. Therefore, the method for manufacturing a cold-plastic ceramic filter material of the present invention includes the following steps: 1. Material preparation: Take appropriate amount of coral sand and shells as raw materials, and go through clean surface treatment. 2. Sintering: The above raw materials are sintered at high temperature to obtain an ore substrate with calcium carbonate and calcium oxide as the main components. 3. Grinding: The aforementioned ore substrate is disintegrated and ground into powder particles, and each particle is between 1000 mesh / inch and 2 to 100 nanometers in size. IV ;, 丨 5 200530130 Wetting: spray water solution on the aforementioned ore powder to make its surface slightly thick. V. Kneading and granulation: The ore powder is coagulated into a granular material by vibration, and the particle size is controlled to be 0.5 to 2 cm. And six, dry dry: the aforementioned granular material in the environment of humidity 45 ~ 60%, temperature 25 ~ 30 ° C, the natural shade dry, for about 24 to 48 hours or more, to obtain hardened and uniform particle size Water purification agent filter material. [Embodiment] Regarding the foregoing and other technical contents, features, and effects of the present invention, a detailed description of a preferred embodiment with reference to the drawings below 15 will be clearly understood. As shown in Fig. 2 and Fig. 3, a preferred embodiment of the method for manufacturing cold-plastic ceramsite and wood according to the present invention includes the following steps: [Step-] Material preparation: Take an appropriate amount of coral sand and shells (if you want to process it) Water quality conditions include any combination of lime, activated carbon, maifan stone, etc.) as raw materials, and clean the surface of the raw materials to filter out dust particles and impurities in the raw materials. U primary material is sintered at a high temperature. Calcium carbonate and calcium oxide-based ore substrate 10. [Step three] Grinding: After the aforementioned ore base material ig is pulverized, it is ground into a powdery ore powder 20 by a grinding device 80, and a particle is interposed between the surface mesh / inch 2 to _ nanometer. ) The size of the rear-mounted device 3. Inside, above it = Water: I: = 20 200530130 20 The surface is slightly thick. ίο [Step five] Kneading and granulation: The water liquid on the surface of the ore powder 2q is not dried, that is, the vibrating machine 40 is used to drive the ore powder not to roll on the holding device 30 in a vibration manner, so that rubbing can be generated. The kneading effect makes the powdery ore powder 20 adhere to the liquid on the surface of the borrower, and gradually aggregates to aggregate into a granular material 5G ', and is controlled by a sieve w connected to the bottom of the vibrator 4 (). The particle size is 5 to 2 cm per 50-granular material. In this operation, the small grains with too small grain size are drenched with water and repeat the above-mentioned kneading and granulation action until they meet the required size; otherwise, the grain size is too large. % Of the granular material is pulverized again and placed in the device «M repeated use [step six] $ dry: the aforementioned material 5G in an environment of humidity ~ 60% / dish temperature 25 30 C ' It can be dried with natural shading, and when it is about% ~ 48 J τ, the hardened and uniform particle size water purification agent 60 filter material 15 can be obtained (see Figure 4). > As shown in Figure 4, the finished product of the present invention can be placed in a cylindrical mixing unit 70 and used when the clean water passes through the upper activated carbon 71 in the mixing unit 7G to remove the chlorine odor in the water. The water purifying agent 6G placed in the mixing unit 70 generates ion exchange effect, and achieves the effect of neutralization. Through the above manufacturing method, the water purifying agent particles have the following advantages during production: 1. The process of the present invention is made by grinding the sintered raw material into a nano-level powder, and then kneading and granulating it. The particle size of the finished product is relatively uniform, and the components of carbon dioxide and oxidized I bow in 200530130 products can be completely fused, so that the weight of the dissolved product is relatively average. The pH value of drinking water can be controlled within a certain range, and due to nanometer Adhesion between the first-level powder particles is greatly increased, so the brewing property is durable. Second, in the manufacturing process, the particle material 50 with a small particle size can be rubbed and granulated after spraying water, without wasting raw materials, and the particle material 50 with a large particle size is recycled after being crushed. In case of repeated use, the manufacturing cost can be greatly reduced. However, the above is only a preferred embodiment of the present invention. When the scope of implementation of the present invention cannot be limited in this way, that is, a simple equivalent change made in accordance with the scope of the patent application of the present application and the content of the new specification. And modifications should still fall within the scope of the invention patent. [Brief description of the drawings] FIG. 1 is a flow block diagram illustrating the steps of a conventional water purification agent manufacturing method; FIG. 2 is a block diagram of a machine, illustrating the method steps of the method for manufacturing a cold plastic ceramic filter material of the present invention; FIG. 3 疋A plan view illustrating the manufacturing method and manufacturing method of the cold-plastic Taurman cypress according to the present invention; and FIG. 4 is a cross-sectional view illustrating an embodiment of the present invention in which a water-repellent structure is placed in a mixing unit. 8 200530130 [Description of the main symbols of the drawings] 10 ·… Ore base material 50. · * Material 20… · Ore powder 60. · • Water purification agent 30 · · · Holder 70. · • Mixing unit 4〇 .... Vibrator 71 · * 4 Activated carbon 4 bu ... Division network 80 *. • Grinding device 9