TWI293960B - Grafting of nitroxyl terminated oligomers or polymers onto thermoplastic polymers - Google Patents

Grafting of nitroxyl terminated oligomers or polymers onto thermoplastic polymers Download PDF

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Publication number
TWI293960B
TWI293960B TW092116512A TW92116512A TWI293960B TW I293960 B TWI293960 B TW I293960B TW 092116512 A TW092116512 A TW 092116512A TW 92116512 A TW92116512 A TW 92116512A TW I293960 B TWI293960 B TW I293960B
Authority
TW
Taiwan
Prior art keywords
group
alkyl
acid
polymer
butyl
Prior art date
Application number
TW092116512A
Other languages
English (en)
Chinese (zh)
Other versions
TW200413411A (en
Inventor
Jochen Fink
Michael Roth
Rudolf Pfaendner
Original Assignee
Ciba Sc Holding Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Sc Holding Ag filed Critical Ciba Sc Holding Ag
Publication of TW200413411A publication Critical patent/TW200413411A/zh
Application granted granted Critical
Publication of TWI293960B publication Critical patent/TWI293960B/zh

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
    • C08G81/02—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C08G81/021—Block or graft polymers containing only sequences of polymers of C08C or C08F
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/02—Stable Free Radical Polymerisation [SFRP]; Nitroxide Mediated Polymerisation [NMP] for, e.g. using 2,2,6,6-tetramethylpiperidine-1-oxyl [TEMPO]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polymerisation Methods In General (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)
TW092116512A 2002-06-20 2003-06-18 Grafting of nitroxyl terminated oligomers or polymers onto thermoplastic polymers TWI293960B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP02405514 2002-06-20

Publications (2)

Publication Number Publication Date
TW200413411A TW200413411A (en) 2004-08-01
TWI293960B true TWI293960B (en) 2008-03-01

Family

ID=29797352

Family Applications (1)

Application Number Title Priority Date Filing Date
TW092116512A TWI293960B (en) 2002-06-20 2003-06-18 Grafting of nitroxyl terminated oligomers or polymers onto thermoplastic polymers

Country Status (10)

Country Link
US (1) US7632891B2 (enExample)
EP (1) EP1513882A2 (enExample)
JP (1) JP4374579B2 (enExample)
KR (1) KR20050013135A (enExample)
CN (1) CN100396705C (enExample)
AU (1) AU2003279358A1 (enExample)
CA (1) CA2487721A1 (enExample)
MX (1) MXPA04012671A (enExample)
TW (1) TWI293960B (enExample)
WO (1) WO2004000890A2 (enExample)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2514167A1 (en) * 2003-02-10 2004-08-19 Ciba Specialty Chemicals Holding Inc. Comb copolymers with defined side chains and process for their manufacture
WO2005021630A1 (en) * 2003-08-27 2005-03-10 Ciba Specialty Chemicals Holding Inc. Composition and process for the controlled synthesis of block copolymers
DE602006017187D1 (de) * 2005-04-04 2010-11-11 Basf Se Verfahren zur herstellung von stern- und blockcopolymeren über epoxidfunktionelle alkoxyamine
DE602006008453D1 (de) * 2005-05-03 2009-09-24 Basf Se Verfahren zur herstellung von kammblockcopolymeren aus epoxidfunktionalisierten nitroxylethern und anionisch polymerisierbaren monomeren
CN101528876B (zh) * 2006-08-18 2012-08-15 联邦科学及工业研究组织 聚合物涂层及其形成方法
WO2015191721A1 (en) * 2014-06-11 2015-12-17 Fina Technology, Inc. Chlorine-resistant polyethylene compound and articles made therefrom
CN104945552A (zh) * 2015-05-14 2015-09-30 桂林理工大学 盐酸克伦特罗分子印迹聚合物及其制备方法
US9926388B2 (en) 2015-06-15 2018-03-27 Braskem America, Inc. Long-chain branched polymers and production processes
CN115380054B (zh) * 2020-04-14 2025-05-13 巴斯夫欧洲公司 胺改性聚合物、用于其制备的可控自由基聚合及其实施
CN113136147A (zh) * 2021-05-07 2021-07-20 浙江祥邦科技股份有限公司 一种柔性组件用截止型热塑性poe封装胶膜及其制备方法
CN116769117B (zh) * 2023-06-19 2024-11-19 四川之江高新材料股份有限公司 含磷阻燃型n-苯基马来酰亚胺的制备法及其在耐热阻燃abs树脂中的应用

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU571240B2 (en) * 1983-07-11 1988-04-14 Commonwealth Scientific And Industrial Research Organisation Alkoxy-amines, useful as initiators
US4879349A (en) 1987-11-05 1989-11-07 Shell Oil Company Selective hydrogenation process
DE4328004A1 (de) * 1993-08-20 1995-02-23 Basf Ag Verfahren zur Herstellung von schlagzähen und transparenten thermoplastischen Werkstoffen und Mittel hierfür
US5773510A (en) * 1995-03-30 1998-06-30 Xerox Corporation Processes for the preparation of branched polymers
FR2754535A1 (fr) * 1996-10-16 1998-04-17 Atochem Elf Sa Polymeres greffes a viscosite controlee
FR2769316B1 (fr) * 1997-10-03 1999-12-03 Atochem Elf Sa Copolymere greffe par polymerisation radicalaire en presence de radicaux stables, sa preparation et ses applications
DE69927839T2 (de) * 1998-09-03 2006-05-11 Ciba Speciality Chemicals Holding Inc. Propfung von äthylenisch ungesättigten monomeren auf polymeren
CA2341372A1 (en) * 1998-09-03 2000-03-16 Ciba Specialty Chemicals Holding Inc. Grafting of ethylenically unsaturated monomers onto polymers
WO2001012721A1 (en) * 1999-08-12 2001-02-22 Ciba Specialty Chemicals Holdings Inc. Polymer blends with improved impact resistance
US7323528B2 (en) * 2002-07-19 2008-01-29 Cid Centro De Investigacion Y Desarrollo Tecnologico, S.A. De C.V. Block copolymers containing functional groups

Also Published As

Publication number Publication date
AU2003279358A1 (en) 2004-01-06
CN100396705C (zh) 2008-06-25
WO2004000890A3 (en) 2004-05-27
CA2487721A1 (en) 2003-12-31
MXPA04012671A (es) 2005-03-23
US20050215720A1 (en) 2005-09-29
JP2005530014A (ja) 2005-10-06
US7632891B2 (en) 2009-12-15
CN1735631A (zh) 2006-02-15
JP4374579B2 (ja) 2009-12-02
EP1513882A2 (en) 2005-03-16
KR20050013135A (ko) 2005-02-02
WO2004000890A2 (en) 2003-12-31
TW200413411A (en) 2004-08-01
AU2003279358A8 (en) 2004-01-06

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