TWI285261B - Mobile oil-analyzing apparatus and analyzing method thereof - Google Patents

Mobile oil-analyzing apparatus and analyzing method thereof Download PDF

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Publication number
TWI285261B
TWI285261B TW94147213A TW94147213A TWI285261B TW I285261 B TWI285261 B TW I285261B TW 94147213 A TW94147213 A TW 94147213A TW 94147213 A TW94147213 A TW 94147213A TW I285261 B TWI285261 B TW I285261B
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oil
infrared
database
oil product
carrier
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TW94147213A
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TW200724899A (en
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Han-Wen Chu
Cheng-Chuan Lu
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Ind Tech Res Inst
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Priority to TW94147213A priority Critical patent/TWI285261B/zh
Priority to AU2006202301A priority patent/AU2006202301B2/en
Priority to JP2006226664A priority patent/JP2007183242A/ja
Priority to US11/641,575 priority patent/US20070152155A1/en
Priority to KR20060131540A priority patent/KR100823942B1/ko
Publication of TW200724899A publication Critical patent/TW200724899A/zh
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Priority to US12/174,600 priority patent/US20080272303A1/en

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    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/35—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
    • G01N21/359—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light using near infrared light
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/35—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
    • G01N21/3577—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light for analysing liquids, e.g. polluted water
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/26—Oils; Viscous liquids; Paints; Inks
    • G01N33/28—Oils, i.e. hydrocarbon liquids
    • G01N33/2829—Mixtures of fuels
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N2201/00—Features of devices classified in G01N21/00
    • G01N2201/12—Circuits of general importance; Signal processing
    • G01N2201/129—Using chemometrical methods
    • G01N2201/1293—Using chemometrical methods resolving multicomponent spectra

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  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Food Science & Technology (AREA)
  • Medicinal Chemistry (AREA)
  • Investigating Or Analysing Materials By Optical Means (AREA)

Description

128^261 r 九、發明說明： 【發明所屬之技術領域】 本發明有關於-種石油產品品質之分析技術，而特別 有關於一種移動式近紅外光油品品質檢測裝置。 【先前技術】
民國88年以鈿我國石油產銷進出口均由國營之中國石油 a司經營，政府透過行政體系即可達成各項品質管理目的；惟 近年來，我國經濟和社會結構轉變、國際石油市場及國内油品 仏而N勢亦發生極大變化，為配合經濟自由化、國際化政策之 推=，油。口口進口已全面開放。因此’為健全石油市場未來發展 及官理制度，政府也已制定石油管理法並於9〇年9月於立法 院三讀通過，且於90年1G月正式公布。我國目前也正式成 為世界貿易組織（WTO)之會員國之―’國外知名大薇之產品 將陸續登台，與國内供油廠商爭奪國内油品市場，為使業者能 在公平競爭的基礎上，並維心油市場麵㈣及增進民生^ 祉之目的下，對加油站的加強管理實有其必要性。 政府於九十年十月十-日公布之r石油管理法」第五章有 關業務監督中第二十九條及九十-年—月十六日發布之「加油 站設置管理規則」中之第三十二中明文規定，石油製品應符合 國家標準始得銷售。同時，主管機關得派員或委託專業檢驗機 構查驗前項業者銷售之石油製品品質，業者不得妨礙、拒絕或 規避。以此法源依據賦予主管機關對業者銷售之石油制。、、口 有查驗權，以落實石油管理之意旨。 衣παπ口貝 〇424-A21262TWF(N2)；P02940039TW；kingandchen 5 12§5261 八門碗、l原局為取㈣者及消費大眾之公信力，於89年度經 二广亚獲得評審委員認同“業技術研究院承接能源會
女祀 油口 口所上人 A 、二口口貝檢驗中心規劃及管理」之計劃，因而建立了經 心·民國=驗室認證體系（CNLA)認可之『油品品質檢驗中 之幾專貝於國内加油站油品物性及化性品質之檢驗。雖然在 吕每末/、°十抽驗約2500餘家加油站將各加油站之油品帶 回:驗至，分別以多種檢測儀器，例如：硫分析儀、密度分析 、]火,刀析儀、蒸顧分析儀、十六烧指數分析儀、辛烧值 =儀^分析儀、甲苯分㈣及含氧量分析儀，將取樣之油 I:一檢測，一系列檢測約耗費一天時間，檢驗其是否合乎國 ^標準，但礙於有限的設備與經費下，仍無法有效率的:速對 全國所有加油站在同一年度中作全面性的抽驗。 ^ 所以如何在有限的設備與經費下提昇抽驗率，促使不法業 著知難而退，不敢以身試法，進而使得社會大眾了解政府主管 為關月b源局早已為維護大眾的權盈進行相關措施，實為我國石 油管理的當務之急。 【發明内容】 、有鑑於此，本發明的目的就在於提供一種能快速檢測 油品品質的方法及裝置。利用已建立之油品檢測技術，配 合近紅外光光譜儀(NIR)快速分析的特性，建立一有效之快 速篩選分析方法，期以解決傳統分析方法需花費較長時間 之限制及提昇抽驗率，而達到國内加油站全面篩選^最： 目的0 0424-A21262TWF(N2);P02940039TW；kingandchen 1285261 r 為達成上述目的，本發明提供一種移動式油品檢測裝 置，包括：一載具；一資料庫，包括複數家加油站油品之 近紅外光光譜資料，以建立近紅外光光譜資料與油品品質 參數之相關性；以及一近紅外光光譜儀，配置於該載具上， 利用該貧料庫進行油品檢測。 本發明提供一種油品檢測方法，包括：（a)提供一移動 式油品檢測裝置，包括一載具；一資料庫，包括複數家加 油站油品之近紅外光光譜資料，以建立近紅外光光譜資料 與油品品質參數之相關性；以及一近紅外光光譜儀，配置 於該載具上，利用該資料庫進行油品檢測；（b)以該載具將 該近紅外光光譜儀移動至所欲檢測之加油站；（c)取樣自該 加油站之油品，以該近紅外光光譜儀對於該油品進行檢 測；以及（d)將量測所得之近紅外光光譜與該資料庫進行比 對，並將該近紅外光光譜轉換成相對應之品質參數。 【實施方式】 為了維護國内油品品質，保障國人用油權利，以及嚇 阻不法商人謀取不法利益，經濟部能源局於民國八十八年 起逐年編列預算，委多工業技術研究院化學工業研究所， 對國内各公民營加油站之油品品質進行全面性的抽測，以 達保障合法業者與維護消費大眾權益之目的，落實管理督 導之政策’傳統之檢測方法是將各加油站之油品取樣回貫 驗室，再以各種油品分析儀器針對油品品質判定的幾個重 要指標進行分析與檢測，但受限於有限的經費及設備，一 0424-A21262TWF(N2)；P02940039TW；kingandchen 7

Claims (1)

1285顧147213號申請專利範圍修正本十、申請專利範圍： 修正日期：96.2.2 %年k月4曰修嗖)正替換頁 1·一種油品檢測方法，包括： (a)提供一移動式油品檢測裝置，包括 一載具； 資料庫，包括複數家加油站油品之近紅外光光譜資 、建立近、、、工外光光谱資料與油品品質參數之相關性；、 、 近紅外光光瑨儀’配置於該載具上，利用該資料庫 進行油品檢測； ' 、（b)以該載具將該近紅外光光譜儀移動至所欲檢測之 TTr? \rl-» Λ U · …⑷取樣自該加油站之油品’以該近紅外光光譜儀對於 δ亥油品進行檢測；以及 ⑷將量測所得之近紅外光光譜與該資料庫進行比 對’並將該近紅外光光譜轉換成相對應之品質參數。
料， 以及 2·如申請專·圍第丨項所述之油品檢測方法， 在取得該加油站之油品後，於該載具停止㈣下進行量測。 3. 如申請專利範圍第1項所述之油品檢測方法，其中 在取得該加油站之油品後，於該載具移動狀態下進行量測。 4. 如巾料利範_丨項所叙油品檢财法， 以紅外光光譜儀檢測之波長範圍㉟6〇〇nm_26〇〇nm。 5.如中料利範圍第丨項所述之油品檢測方法 Λ近、、’工外光光瑨儀掃瞄汽油之波長範 1100iun-1670nm。 ’其中 圍約 〇424-A21262TWF1(N2)；P〇2940039TW；kingandchen 14 V1285261 p— 一年V月:Λ>曰修(更)正替換頁 士 6.如申請專利範圍第^述之油品檢測方法，其中 °玄近紅外光光譜儀掃瞄汽油之波長範圍約 1790nm-21〇〇nm。 > 、7·如申請專利範圍第！項所述之油品檢測方法，其中 °玄近紅外光光譜儀掃瞄柴油之波長範圍約 1100nm-1670nm。 ;8·如申凊專利範圍帛丨項所述之油品檢測方法，其中 _ / I、、、工外光光瑨儀掃瞄柴油之波長範圍約 1825nin-2200nni。 9. 如申請專利範圍第！項所述之油品檢測方法，其中 檢測步驟（C)至(d)過程約5分鐘。 10. 如申請專利第i項所述之油品檢測方法，其中更包 括重複(b)至（d)之步驟抽驗複數家加油站之油品。 11·種私動式油品檢測裝置，包括： 一載具； Φ 資料庫，包括複數家加油站油品之近紅外光光譜資 料，以建立近紅外光光譜資料與油品品質參數之相關^ ;、 以及 、一近紅外光光譜儀，配置於該載具上，利用該資料庫 進行油品檢測。 U·如申請專利範圍第u項所述之移動式油品檢測裝 置，其中該载具包括··汽車、箱型車或貨車。 =·如中請專利範㈣U項所述之移動式油品檢測裝 ，，、中該資料庫是根據複數種油品分析儀器對該複數家 〇424-A21262TWF1(N2)；P〇294〇〇39TW：kingandchen ,1285261 月~修必正替換頁 :油站油品之分析數據;紅外光_所建 Μ.如申請專利範圍第13項所述之 置，其中該複數種油品分析儀器包括：硫分二〆則震 析儀、閃火點分析儀、蒗 、、锥度分 辛〜、笨分析儀二儀十及^^ 八中μ近、，，工外光光譜儀之檢測對象包括汽油或柴油。 =如巾請專·圍第U韻述之軸式油品 :低該载具移動時對於該近紅外光光譜儀所產=二 ϋ中請專利範圍第16項所述之移動式油品檢測裝 y中雜震平台包括：—用來放置該近紅外光光譜儀 之底座，以及複數個避震器置於該底座之下方。 0424-A21262TWF1(N2)；P02940039TW；kingandchen 16 I285£6il47213 號圖式修正頁 I a
1285261
涵
18 I2852&1 47213號專利說明書修正頁 丨楚i曰期：能·2·泛 * ι· . Ί .丨 ______一..... .*·------- 一 ……'一 -，一- 七、指定代表圖： (一） 本案指定代表圖為：第（5)圖。 (二） 本代表圖之元件符號簡單說明： 500〜移動式油品檢測裝置； 501〜載具； 503〜近紅外光光譜儀； 504〜避震器； 505〜避震平台。 八、本案若有化學式時，請揭示最能顯示發明特徵的化學式： 無0 0424-Α21262TWF1 (N2)；P02940039TW；kingandchen
TW94147213A 2005-12-29 2005-12-29 Mobile oil-analyzing apparatus and analyzing method thereof TWI285261B (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
TW94147213A TWI285261B (en) 2005-12-29 2005-12-29 Mobile oil-analyzing apparatus and analyzing method thereof
AU2006202301A AU2006202301B2 (en) 2005-12-29 2006-05-31 Mobile Fuel Analysis Apparatus and Method Thereof
JP2006226664A JP2007183242A (ja) 2005-12-29 2006-08-23 移動式燃料分析装置および該移動式燃料分析装置を用いた燃料の品質を測定する方法
US11/641,575 US20070152155A1 (en) 2005-12-29 2006-12-19 Mobile fuel analysis apparatus and method thereof
KR20060131540A KR100823942B1 (ko) 2005-12-29 2006-12-21 이동 연료 분석 장치와 그 방법
US12/174,600 US20080272303A1 (en) 2005-12-29 2008-07-16 Mobile fuel analysis apparatus and method thereof

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Application Number Priority Date Filing Date Title
TW94147213A TWI285261B (en) 2005-12-29 2005-12-29 Mobile oil-analyzing apparatus and analyzing method thereof

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TWI285261B true TWI285261B (en) 2007-08-11

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JP (1) JP2007183242A (zh)
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AU (1) AU2006202301B2 (zh)
TW (1) TWI285261B (zh)

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AU2006202301A1 (en) 2007-07-19
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