經濟部智慧財產局員工消費合作社印製 1284594 五、發明說明（/ ) 〔發明所屬之技術領域〕 本發明係關於一種高鮮映性裝飾板積層用印刷樹脂薄 膜及積層有該樹脂薄膜之高鮮映性裝飾板，詳而言之係適 用於電冰箱的拉門、空調機的外殼等家電製品的外裝或鋼 製家具、電梯、建築物等的內裝般之高鮮映性的印刷模樣 特別要求的用途。 〔先前技術〕 Λ 本發明所稱之鮮映性，係代表著映像鮮映性，亦即映 照在裝飾面上之正反射像的鮮明度。該鮮映性的評價，係 藉由使用財團法人日本色彩硏究所製的攜帶用鮮明度光澤 計PGD-4型的測定來進行。 以往，作爲各種家具類或建築物內裝材料等所使用的 高鮮映裝飾板，係將 (1) 在構成基材之樹脂層上用一般方法施加印刷，爲保護印 刷層的表面而設置氨基醇酸樹脂、聚氨酯樹脂等塗層所構 成之裝飾薄膜， (2) 在構成基材之樹脂層上用一般方法施加印刷後，透過接 著劑層來積層透明的雙軸延伸聚酯膜所構成之裝飾薄膜， (3) 在聚氯乙烯膜上用一般方法施加印刷後，積層透明的聚 氯乙烯膜或雙軸延伸聚酯膜所構成之裝飾薄膜， 等等的裝飾薄膜，透過接著劑來積層於鍍鋅鋼板、合板或 MDF等基板上。 然而，積層上述（1)之裝飾薄膜後的裝飾板，由於裝飾 薄膜的強度不足，在實施V形開槽加工等的情形，加工時Ministry of Economic Affairs, Intellectual Property Office, Staff and Consumer Cooperatives, Printing 1284594 V. OBJECT DESCRIPTION OF THE INVENTION (Technical Fields of the Invention) The present invention relates to a printing resin film for high-precision decorative decorative layer and a high-preparity laminated resin film. In particular, the decorative panel is suitable for the exterior of home appliances such as sliding doors for refrigerators, outer casings of air conditioners, or high-precision printing patterns for interiors of steel furniture, elevators, and buildings. Specially required use. [Prior Art] Λ The vividness referred to in the present invention represents the vividness of the image, that is, the sharpness of the specular reflection image reflected on the decorative surface. The evaluation of the vividness was carried out by using a measurement of a portable brightness gloss meter PGD-4 manufactured by Nippon Color Research Co., Ltd., a consortium. In the past, the high-preservation decorative sheet used for various furniture or building interior materials is (1) printed on a resin layer constituting the substrate by a general method, and an amino group is provided to protect the surface of the printed layer. a decorative film composed of a coating such as an alkyd resin or a urethane resin, (2) a resin layer constituting the substrate is printed by a general method, and then a transparent biaxially stretched polyester film is laminated through the adhesive layer. Decorative film, (3) A decorative film composed of a transparent polyvinyl chloride film or a biaxially stretched polyester film, which is applied by printing in a general manner on a polyvinyl chloride film, and a decorative film which is laminated through an adhesive. On galvanized steel sheets, plywood or MDF substrates. However, in the decorative panel in which the decorative film of the above (1) is laminated, since the strength of the decorative film is insufficient, the V-grooving process or the like is performed, and processing is performed.
本紙張尺度適用中國國家標準（CNS)A4規格（210 X (請先閱讀背面之注意事項再填寫本頁)This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X (please read the notes on the back and fill out this page)
4 1284594 A7 —— B7 五、發明說明（上） 會有裝飾薄膜裂開、角落部的油墨易剝離之問題，而不適 用於V形開槽加工等用途。積層上述(2)之裝飾薄膜後的裝 飾板，雖耐污染性、耐溶劑性等的表面物性優異，但其表 面薄膜缺乏柔軟性故軟化溫度高，而在施加壓花加工時， 壓花將不易壓入。積層上述(3)之裝飾薄膜後的裝飾板，由 於是使用聚氯乙烯膜，耐污染性、耐溶劑性等表面物性不 佳，又在進行焚化廢棄處理時，將有產生氯化氫氣體般之 有毒氣體及其所引起的有害物質而污染環境之虞，又有在 焚化時會弄傷焚化爐之虞，而有很大的問題存在。 〔發明所要解決的課題〕 本發明係以解決上述問題爲目的，其課題係提供出一 種高鮮映裝飾板積層用印刷樹脂薄膜，其具有和以往之使 用聚氯乙烯樹脂膜的高鮮映裝飾膜板同等級以上的印刷鮮 映性’而具有樣式特性優異之構圖模樣，又耐污染性、耐 溶劑性等的表面物性優異，並提供出積層有該樹脂薄膜之 商鮮映裝飾板。 〔用以解決課題之手段〕 本發明之高鮮映裝飾板積層用印刷樹脂薄膜，係將接 著樹脂層、基材樹脂層、密實（solid)印刷層、圖樣印刷層 '透明的表面樹脂層由下而上依序積層而成； 或是將接著樹脂層、著色樹脂層、圖樣印刷層、基材 •植f脂層、透明的表面樹脂層由下而上依序積層而成； 或是將接著樹脂層、著色樹脂層、密實印刷層、圖樣 印刷層、基材樹脂層、透明的表面樹脂層由下而上依序積 5 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 丨丨J!.-----鵪 (請先閱讀背面之注意事項再填寫本頁) 訂---------線· 經濟部智慧財產局員工消費合作社印製 1284594 A7 B7 五、發明說明（》） 層而成。 又較佳爲，對前述基材樹脂層施加壓花加工，在該壓 花加工所形成的壓花凹部內充塡油墨來構成印刷層。 又較佳爲，前述表面樹脂層係採用雙軸延伸聚酯樹脂 膜，特別是聚苯二甲酸乙二醇酯樹脂、聚碳酸酯樹脂、丙 烯酸樹脂膜。 •又較佳爲’前述基材樹脂層係由聚苯二甲酸丁二醇酯 樹脂所構成。 本發明之高鮮映裝飾板，係在用以積層樹脂膜之基板 的至少片面上，積層申請專利範圍第.1〜7項中任一項之高 鮮映裝飾板積層用印刷樹脂薄膜； 或是前述基板和高鮮映裝飾板積層用印刷樹脂薄膜之 間是透過接著劑層來積層。 則述基板較佳爲金屬板、木質板或板材。 〔發明之實施樣態〕 經濟部智慧財產局員工消費合作社印製 本案的發明人等，爲了取代焚化時有產生有毒氣體及 其所引起的有害物質而有污染環境之虞的聚氯乙烯樹脂膜 ，針對所具的圖樣之高鮮映性及樣式特性優異、耐污染性 、耐溶劑性等的表面物性優異之裝飾板積層用且爲可印刷 之高鮮映樹脂膜進行努力硏究的成果，發現到，將共聚物 聚酯膜構成的接著樹脂層、聚苯二甲酸丁二醇酯膜構成之 可選擇性積層之著色樹脂層及作爲印刷基底之基材樹脂層 、圖樣印刷層、或是圖樣印刷層和密實印刷層、透明的表 面樹脂層由下而上依序積層，即可得出能滿足上述所要求 6 本紙張尺度適用中國國家標準（CNS)A4規格（210 x 297公楚） 經濟部智慧財產局員工消費合作社印製 12845944 1284594 A7 —— B7 V. INSTRUCTIONS (on) There is a problem that the decorative film is cracked and the ink in the corner portion is easily peeled off, and it is not suitable for V-grooving. The decorative sheet obtained by laminating the decorative film of the above (2) is excellent in surface physical properties such as stain resistance and solvent resistance, but the surface film lacks flexibility and the softening temperature is high, and when embossing is applied, the embossing will be Not easy to press. The decorative sheet laminated with the decorative film of the above (3) is made of a polyvinyl chloride film, and has poor surface properties such as stain resistance and solvent resistance, and is toxic like hydrogen chloride gas when it is incinerated and disposed. The gas and the harmful substances caused by it pollute the environment, and there is a problem that the incinerator will be injured when incinerated, and there are big problems. [Problems to be Solved by the Invention] The present invention has been made to solve the above problems, and an object of the present invention is to provide a printing resin film for high-preservation decorative laminate, which has a high-grade decorative decoration using a conventional polyvinyl chloride resin film. The film has the same patterning characteristics as the printing film of the same grade or higher, and has excellent pattern properties, such as stain resistance and solvent resistance, and provides a decorative panel which is laminated with the resin film. [Means for Solving the Problem] The printed resin film for high-preservation decorative laminate of the present invention is a surface resin layer which is transparent to the resin layer, the base resin layer, the solid printed layer, and the pattern printed layer. The bottom layer is sequentially laminated; or the resin layer, the colored resin layer, the pattern printed layer, the substrate, the f-lipid layer, and the transparent surface resin layer are sequentially layered from bottom to top; Then, the resin layer, the colored resin layer, the dense printed layer, the pattern printed layer, the base resin layer, and the transparent surface resin layer are sequentially stacked from bottom to top. 5 The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297). )J!.-----鹌(Please read the notes on the back and fill out this page) Order---------Line· Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperative Printed 1284594 A7 B7 V. Inventions (") Layers. Further preferably, the base resin layer is subjected to embossing, and the embossed concave portion formed by the embossing is filled with ink to form a printed layer. Further preferably, the surface resin layer is a biaxially stretched polyester resin film, particularly a polyethylene terephthalate resin, a polycarbonate resin or an acrylic resin film. Further preferably, the base material resin layer is composed of a polybutylene phthalate resin. The high-precision decorative sheet of the present invention is a printed resin film for a high-preserving decorative laminated layer according to any one of the above claims 1 to 7 in at least one surface of a substrate for laminating a resin film; or The printing substrate between the substrate and the high-preservation decorative layer is laminated through the adhesive layer. The substrate is preferably a metal plate, a wood plate or a plate. [Implementation of the invention] The inventor of the case, the inventor of the Ministry of Economic Affairs, the Intellectual Property Office, and the Consumer Cooperatives, in order to replace the toxic gas produced by the incineration, and the environmentally-friendly polyvinyl chloride resin film For the purpose of researching the high-precision and high-precision properties of the pattern, the surface properties of the decorative sheet, which is excellent in surface properties, such as excellent stain resistance and solvent resistance, and the high-reflection resin film that can be printed, It has been found that a resin layer composed of a copolymer polyester film and a polybutylene terephthalate film can be selectively laminated with a colored resin layer, a substrate resin layer as a printing substrate, a pattern printed layer, or The pattern printed layer and the dense printed layer and the transparent surface resin layer are sequentially layered from bottom to top, which can be used to meet the above requirements. 6 paper scale applicable to China National Standard (CNS) A4 specification (210 x 297 public Chu) Ministry of Economic Affairs, Intellectual Property Bureau, Staff Consumption Cooperative, Printing 1284594
五、發明說明（y) 的特性之裝飾板積層用的樹脂薄膜。又，在基材樹脂，= 加壓花加工來形成壓花凹部後，使用刮塗法在壓花凹部 塡油墨來設置刮塗印刷層亦可。 0 又，將上述樹脂薄膜積層於金屬板、合板、板材_ 構成之高鮮映裝飾板，除了樹脂薄膜之上述優異膜物性 ，同時展現出優異的樣式特性。 以下係說明本發明的內容。 圖1係顯示本發明的高鮮映裝飾板積層用印刷檨^曰= 膜的一例之截面圖；圖2及圖3係顯示本發明的高鮮映裝 飾板積層用印刷樹脂薄膜的其他例之截面圖；圖4及® 係顯示本發明的高鮮映裝飾板的例子之截面圖。1代表f 鮮映裝飾板積層用印刷樹脂薄膜，2代表基板，3代表接者 劑層，4代表接著樹脂層，5代表著色樹脂層，6a代表圖 樣印刷層，6b代表密實(solid)印刷層，7代表基材樹脂層 ，8代表刮塗印刷用壓花凹部，9代表刮塗印刷層，10代 表接著劑層，11代表表面樹脂層，12代表高鮮映裝飾板。 本發明的裝飾板積層用印刷樹脂薄膜1，如圖1所示 般在接著樹脂層4的上面積層基材樹脂層7，在基板樹脂 層7的上面積層表面樹脂層n，在該表面樹脂層11的裏 面全面設有圖樣印刷層6a和密實印刷層6b。 本發明的高鮮映裝飾板積層用印刷樹脂薄膜1 ’亦可 如圖2所示般，在接著樹脂層4的上面積層設有圖樣印刷 層6a之著色樹脂層5，再進一步積層基材樹脂層7，在該 基材樹脂層7的上面之藉由壓花加工所形成的壓花凹部8 7 本紙張尺度適用中國國家標準（CNS)A4規格（210 x 297公釐） " " C請先間讀背面之江意事頊再填窵本5. A resin film for a decorative laminate layer having the characteristics of (y). Further, after the base resin is pressed to form an embossed concave portion by press-forming, the ink is applied to the embossed concave portion by a doctor blade method to provide a doctor-printed layer. In addition, the above-mentioned resin film is laminated on a high-grade decorative plate composed of a metal plate, a plywood, and a plate material, and exhibits excellent pattern properties in addition to the above-described excellent film properties of the resin film. The contents of the present invention are described below. 1 is a cross-sectional view showing an example of a printing film for a high-preserving decorative layer of the present invention; and FIG. 2 and FIG. 3 are other examples of a printing resin film for a high-preserving decorative layer of the present invention. Cross-sectional views; Figures 4 and 2 show cross-sectional views of examples of the high-grade decorative panels of the present invention. 1 represents a printing resin film for f-staining decorative layer, 2 is a substrate, 3 is a carrier layer, 4 is a resin layer, 5 is a colored resin layer, 6a is a pattern printing layer, and 6b is a solid printing layer. 7 represents a base resin layer, 8 represents an embossed concave portion for blade coating printing, 9 represents a doctor-printed printing layer, 10 represents an adhesive layer, 11 represents a surface resin layer, and 12 represents a high-grade decorative sheet. The printed resin film 1 for a decorative laminate layer of the present invention is as shown in Fig. 1 in the upper layer substrate resin layer 7 of the resin layer 4, and on the upper surface layer of the substrate resin layer 7, a resin layer n on the surface resin layer. The inside of the 11 is provided with a pattern printed layer 6a and a dense printed layer 6b. The printed resin film 1' for a high-preserving decorative laminated layer of the present invention may be provided with a colored resin layer 5 of the pattern printed layer 6a on the upper surface layer of the resin layer 4 as shown in Fig. 2, and further laminated with a base resin. Layer 7, an embossed recess formed by embossing on the upper surface of the base resin layer 7 This paper scale applies the Chinese National Standard (CNS) A4 specification (210 x 297 mm) "" C Please read the back of the river and read the book first.
12845941284594
五、發明說明（夂） 內，充塡入刮塗油墨而形成刮塗印刷層9，在該基材樹脂 層7的上面透過接著劑層10來積層表面樹脂層11。 (請先閱讀背面之注意事項再填寫本頁) 又，本發明的裝飾板積層用印刷樹脂薄膜1 ’亦可如 圖3所示般，在圖2之裝飾板積層用印刷樹脂薄膜1的著 色樹脂層5上’設置圖樣印刷層6a和密貫印刷層6b兩者 .圖4所顯示之高鮮映裝飾板12，係將圖2所示的裝飾 板積層用印刷樹脂薄膜1透過接著劑層3來積層於基板2 上。 圖5所顯示之高鮮映裝飾板12 ’係將圖3所示的裝飾 板積層用印刷樹脂薄膜1透過接著劑層3來積層於基板2 經濟部智慧財產局員工消費合作社印製 本發明所用之基材樹脂層7及著色樹脂層5，較佳爲 使用固有粘度(IV値)爲1·〇〜2.0之聚對苯二甲酸丁二醇酯 薄膜，基於製膜性的考量，固有粘度爲1.5以上更佳’又 基於耐水經時性(耐水劣化性)的考量，固有粘度以1·2以上 爲更佳。又，相同於著色樹脂層5，使用擠出機來進行基 材樹脂層7的製膜時，在樹脂中混練著色顏料來形成著色 樹脂層亦可。 圖樣印刷層6a，係例如表現出木紋、石紋、天然皮革 的表面紋路、布紋、抽象花紋等的模樣；密實印刷層6b， 則是用以遮蔽基材樹脂層7的全面並賦予圖樣印刷層6a的 印刷底色之印刷層，同時有助於基材樹脂層7和表面樹脂 層Π間的熱接著性。用以形成印刷層以及6b之油墨的展 8 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 經濟部智慧財產局員工消費合作社印製 1284594 Δ7 Α7 _____ Β7 五、發明說明（6) 色劑，能使用例如硝基纖維素、醋酸纖維素等纖維素衍生 物、聚酯型聚氨酯樹脂等公然周知者，其中基於密著及熱 接著性等兩觀點則以硝基纖維素-醇酸樹脂系油囊爲佳。 又，對基材樹脂層7選擇性地施以壓花加工來形成壓 花凹部8後，用刮塗法在壓花凹部8充塡油墨來設置刮塗 印刷層9時，壓花凹部8內所充塡的刮塗油墨，可使用塗 料或油墨。 所使用的塗料或油墨，例如以天然樹脂或其改質樹脂 類，纖維素衍生物類，聚酯系樹脂、丙烯酸系樹脂:聚^ 酯系樹脂等的合成樹脂類作爲展色劑的構成材料7再$展 色劑中添加著色顏料、體質顏料等來構成。所使.用的展色 劑，以聚氨酯般之2液硬化型爲適當。作爲刮塗法，可使 用刮刀法、輥塗法等以往所使用之任一刮塗法。 作爲表面樹脂層11，較佳爲使用以聚對苯二甲酸乙二 醇酯爲首之聚酯樹脂膜、聚碳酸酯膜、或是丙燦酸樹脂膜 ，其中以使用雙軸延伸聚酯膜爲更佳。該聚酯樹脂膜的特 徵在於，係由不含可塑劑及鹵素元素之聚酯樹脂所構成。 作爲接著樹脂層4的樹脂，較佳爲使用共聚物聚酯樹 脂。 該聚酯樹脂的構成材料之一例，係使用具備以下的組 成之共聚物聚酯樹脂等。亦即，作爲樹脂構成用之柔性鏈 段，較佳爲使用聚乙二醇、聚四甲二醇等的聚亞氧院基乙 二醇，或是聚ε -己內醯胺、壬二酸、癸二酸、十二烷二 酸、二聚物酸等具有HOOC-〔 CH2〕n-COOH分子構造 _____Ί——·—m--------β (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 χ 297公釐） 1284594 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明說明（？） 之脂肪酸二羧酸，和脂肪族及/或脂環族二元醇所構成之脂 肪族聚酯等。 又’作爲樹脂構成用之硬鏈段，較佳爲擇自對苯二甲 酸乙二醇酯、對苯二甲酸丁二醇酯、環己烷二對苯二甲酸 甲二醇酯、環己烷二甲撐環己烷二羧酸酯、丁烯2,6萘二 羧酸酯等的芳香族及/或脂環族酯單元中之至少之1所構成 〇 又，作爲醇成分，基於耐溶劑性的觀點以含有1，4 丁 二醇殘基爲佳，而在用以形成共聚物聚酯之所有醇成分中 ，1，4 丁二醇殘基較佳爲40莫耳％以上65莫耳％以下。 當要求和基板間具有更強的密著性時，若令接著樹脂 層4的樹脂成分之一部分含有離子鍵聚合物樹脂成分，則 可得良好的密著性。這時較佳爲，離子鍵聚合物樹脂成分 佔樹脂成分整體的1〜50重量％。 圖1所示之本發明的裝飾板積層用印刷樹脂薄膜1， 能用以下的方式來製作出。亦即，在共擠出所製膜出之雙 層膜構造之接著樹脂層4和基材樹脂層7的積層薄膜上面 ，重疊上設於表面樹脂層11的下面之圖樣印刷層6a和密 實印刷層6b所構成的印刷層，在維持共擠出積層膜和表面 樹脂層11的疊合下，藉由通過1對的熱輥子間來進行夾合 壓接同時進行熱融接積層，而製造出一片積層薄膜。藉由 在加熱下加壓以將表面樹脂層11的密實印刷層6b面融接 於基材樹目曰層7 ’而製作出一片商鮮映裝飾板積層用印刷 樹脂薄膜1。 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁)5. In the description of the invention (a), a doctor-printed layer 9 is formed by applying a doctor ink, and a surface resin layer 11 is laminated on the upper surface of the base resin layer 7 through the adhesive layer 10. (Please read the precautions on the back side and fill out this page.) The printed resin film 1' for decorative laminates of the present invention may also be colored as shown in Fig. 3, and the printing resin film 1 for the decorative laminate layer of Fig. 2 The resin layer 5 is provided with both the pattern printed layer 6a and the dense printed layer 6b. The high-preserving decorative sheet 12 shown in Fig. 4 transmits the decorative resin film 1 for the decorative laminate layer shown in Fig. 2 through the adhesive layer. 3 to laminate on the substrate 2. The high-preservation decorative sheet 12' shown in Fig. 5 is obtained by laminating the printed resin film 1 for the decorative laminate layer shown in Fig. 3 through the adhesive layer 3 on the substrate 2, and the Ministry of Economic Affairs, the Intellectual Property Office, the Consumer Cooperative, which is printed by the present invention. The base resin layer 7 and the colored resin layer 5 are preferably a polybutylene terephthalate film having an intrinsic viscosity (IV値) of 1·〇 to 2.0, and the intrinsic viscosity is based on the film forming property. It is more preferable that it is 1.5 or more, and it is based on the water-resistant time-dependent property (water deterioration resistance), and it is more preferable that it has an intrinsic viscosity of 1 or more. When the base resin layer 7 is formed by using an extruder in the same manner as the colored resin layer 5, the colored resin may be kneaded in the resin to form a colored resin layer. The pattern printed layer 6a is, for example, a pattern showing the surface texture, the texture of the natural leather, the texture, the abstract pattern, and the like; and the dense printed layer 6b is used to shield the entire surface of the base resin layer 7 and impart a pattern. The printing layer of the printing undercoat of the printed layer 6a contributes to the thermal adhesion between the base resin layer 7 and the surface resin layer. The paper size used to form the printing layer and the ink of 6b is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm). Ministry of Economic Affairs Intellectual Property Bureau Staff Consumption Cooperative Printed 1284594 Δ7 Α7 _____ Β7 V. Invention Description (6) For the toner, for example, a cellulose derivative such as nitrocellulose or cellulose acetate or a polyester urethane resin can be used, and nitrocellulose is used in terms of adhesion and thermal adhesion. An alkyd resin oil sac is preferred. Further, after the base resin layer 7 is selectively subjected to embossing to form the embossed concave portion 8, the embossed concave portion 8 is filled with ink to form the doctor-printed printing layer 9, and the embossed concave portion 8 is provided. For coating inks that are filled, paints or inks can be used. The coating material or the ink to be used is, for example, a synthetic resin such as a natural resin or a modified resin thereof, a cellulose derivative, a polyester resin, an acrylic resin, or a polyacrylate resin. 7 Add a coloring pigment, an extender pigment, etc. to the coloring agent. The color developing agent used is suitably a polyurethane-like two-liquid curing type. As the doctor blade method, any of the conventional blade coating methods such as a doctor blade method and a roll coating method can be used. As the surface resin layer 11, it is preferred to use a polyester resin film such as polyethylene terephthalate, a polycarbonate film, or a acrylic acid resin film in which a biaxially stretched polyester film is used. For better. The polyester resin film is characterized in that it is composed of a polyester resin containing no plasticizer or halogen element. As the resin following the resin layer 4, a copolymer polyester resin is preferably used. As an example of the constituent material of the polyester resin, a copolymer polyester resin or the like having the following composition is used. That is, as the flexible segment for resin composition, polyoxyethylene glycol such as polyethylene glycol or polytetramethylene glycol, or poly-ε-caprolactam or sebacic acid is preferably used. , azelaic acid, dodecanedioic acid, dimer acid, etc. have HOOC-[CH2]n-COOH molecular structure _____Ί——·-m--------β (please read the back note first) Please fill out this page again. This paper scale applies to China National Standard (CNS) A4 specification (210 297 297 mm). 1284594 Ministry of Economic Affairs Intellectual Property Office Staff Consumer Cooperative Print A7 B7 V. Invention Description (?) Fatty Acid Dicarboxylic Acid And an aliphatic polyester composed of an aliphatic and/or alicyclic diol. Further, as a hard segment for resin composition, it is preferably selected from ethylene terephthalate, butylene terephthalate, cyclohexane diterephthalate, and cyclohexane. At least one of an aromatic and/or alicyclic ester unit such as dimethylcyclohexanedicarboxylate or butene 2,6 naphthalene dicarboxylate is used as an alcohol component, and is based on a solvent resistant solvent. Preferably, the residue contains 1,4 butanediol residues, and among all the alcohol components used to form the copolymer polyester, the 1,4 butanediol residue is preferably 40 mol% or more and 65 mol. %the following. When it is required to have a stronger adhesion to the substrate, if one of the resin components of the resin layer 4 is contained, the ion-bonding polymer resin component is contained, and good adhesion can be obtained. In this case, it is preferred that the ionomer resin component accounts for 1 to 50% by weight of the entire resin component. The printed resin film 1 for a decorative laminate of the present invention shown in Fig. 1 can be produced in the following manner. That is, on the laminated film of the adhesive resin layer 4 and the base resin layer 7 of the two-layer film structure formed by co-extrusion, the pattern printed layer 6a and the dense printed printing provided on the lower surface of the surface resin layer 11 are superposed. The printed layer formed of the layer 6b is produced by laminating and pressing a pair of hot rolls while maintaining a hot-melt joint layer while maintaining the co-extruded laminated film and the surface resin layer 11 in a superposed manner. A laminated film. The surface of the dense printed layer 6b of the surface resin layer 11 is fused to the substrate tree layer 7' by pressurization under heating to produce a printed resin film 1 for a decorative layer. This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (please read the notes on the back and fill out this page)
A7 1284594 _ B7 _______ 五、發明說明（f ) (請先閱讀背面之注意事項再填寫本頁) 又，藉由將接著樹脂層4和混練有顏料5之著色樹脂 層5共擠出來製膜出雙層膜，之後在著色樹脂層5上施加 圖樣印刷層6a，再在其上方疊合基材樹脂層7，維持疊合 狀態下藉由通過1對的熱輥子間來進行夾合壓接同時進行 熱融接積層，而製造出一片積層薄膜。又這時，藉由使用 壓花輥作爲上述熱輥子，即可同時實施積層和壓花加工， 而得出在基材樹脂層7的表面形成刮塗印刷用壓花凹部8 ，再充塡刮塗油墨來設置刮塗印刷層9，藉以賦予高樣式 特性的構圖模樣。又，藉由在其上方透過接著劑層10來積 層表面樹脂層11，即可得出圖2所示之高鮮映裝飾板積層 用印刷樹脂薄膜1。又，由於著色樹脂層5及基材樹脂層7 之尺寸安定性佳，要抑制起因於張力或熱之伸縮變動也將 變得可能，而能得出印刷圖樣和壓花圖案諧調而具有高度 樣式特性之壓花裝飾薄膜。上述積層作業和壓花加工等過 程，能在和以往的聚氯乙烯樹脂薄膜相同的條件下進行作 業。 經濟部智慧財產局員工消費合作社印製 又，藉由在圖2之著色樹脂層5的表面設置密實印刷 層6b，在其上方再設置圖樣印刷層6a，使用如此般的樹脂 薄膜，即可得出圖3所示般之樣式特性更佳的裝飾板積層 用印刷樹脂薄膜1。 又，將上述方法所得的高鮮映裝飾板積層用印刷樹脂 薄膜1，透過接著劑層3來和基板2貼合，即可得出圖4 或圖5所示般的高鮮映裝飾板12。作爲基板2，例如可使 用木材單板、木材合板、碎料板、MDF等的木質板，鋼板 11 ϋ氏張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 1284594 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明說明（，） 、鋁合金板、鍍鋅或鍍鋅合金之鍍鋅鋼板等的金屬板，或 是石膏板、矽酸鈣板、石綿瓦板等的無機質所構成的板材 〇 用於高鮮映裝飾板積層用印刷樹脂薄膜1和基板2的 貼合之接著劑層3的接著劑，可使用一般的接著劑，而基 於用火上的安全、臭氣、價格上的考量’較佳爲例如醋酸 乙烯樹脂系、乙烯-乙烯基醋酸酯樹脂系、尿素樹脂系、 聚氨酯樹脂系等的乳膠型接著劑。 〔實施例〕 以下用實施例來更詳細地說明本發明。 (實施例1) 在厚25 //m的透明雙軸延伸聚對苯二甲酸乙二醇酯薄 膜(市人製）的片面上，使用硝基纖維素-醇酸系油墨（昭和 油墨製，SAM)，用凹版輪轉印刷機將圖樣印刷層及著色密 實印刷層以一列的方式進行印刷。接著，疊合上使用市售 之聚苯二甲酸丁二醇酯樹脂及共聚物聚苯二甲酸乙二醇酯 樹脂而經擠出製膜機所製作出之厚70#m的雙層未延伸薄 膜(厚度比=4 : 1)，在壓接輥的加熱溫度200°C、樹脂膜的 送進速度20m/min、壓接輥的咬壓l5kgf/cm2的條件下將兩 薄膜加熱壓接並積層，以製作出高鮮映裝飾板積層用印刷 樹脂薄膜。接著，在厚〇.5mm之電鍍鋅鋼板上以l〇g/m2的 塗佈量來塗佈聚酯系接著劑，將前述高鮮映裝飾板積層用 印刷樹脂薄膜以加熱溫度210°C、接著壓力15kgf/cm2、壓 接時間5秒的條件進行加熱壓接，而得出裝飾板。 12 木紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注音？事項再填寫本頁) 訂·--------線丨| 1284594 A7 B7 五、發明說明（π) (實施例2) 將市售的聚對苯二甲酸丁二醇酯樹脂中混練20重量％ 之乳色顏料後的著色樹脂、和共聚物聚苯二甲酸乙二醇酯 ’用擠出製膜機以厚度比=4 : 1所製作出之厚50//m的雙 層未延伸薄膜之聚苯二甲酸丁二醇酯樹脂側的片面上，使 用硝基纖維素-醇酸系油墨（昭和油墨製，SAM)並經凹版 輪轉機以一列的方式來印刷圖樣印刷層，將其和用市售的 聚苯二甲酸丁二醇酯樹脂經擠出製膜機所製膜出之厚70// m的透明未延伸薄膜對向擺置，在和實施例1的加熱壓接 中之積層條件相同條件下，以透明聚苯二甲酸丁二醇酯單 層膜爲壓花輥側，藉由通過壓花輥和矽膠輥所構成之壓接 用輥之間，以製作出在透明聚苯二甲酸丁二醇酯膜的表面 具有壓花凹部之3層膜。接著，在具有前述壓花凹部之面 上，用輥塗法塗佈2液硬化型聚氨酯系著色油墨(昭和油墨 製，PW-001)後，用刮刀將壓花凹部以外的部分所附著的 著色油墨刮除後，令積層薄膜表面所形成之壓花凹部內所 充塡的著色油墨固化，而製作出印刷樹脂薄膜。又，在該 印刷樹脂薄膜的壓花加工面上，將片面塗佈有環氧-酚醛 系接著劑之厚25//m的透明雙軸延伸透明聚苯二甲酸乙二 醇酯膜（帝人製）的接著劑塗佈面對向配置，在和實施例1 的加熱壓接中之積層條件相同條件下，藉由通過一對矽膠 輥所構成的壓接用輥之間來進行壓接，以製作出樣式特性 優異的高鮮映裝飾薄膜。接著，在厚6mm之木材合板上以 50g/m2的塗佈量來塗佈聚酯系接著劑，將前述高鮮映裝飾 13 (請先閱讀背面之注意事項再填寫本頁) d 訂--------- 經濟部智慧財產局員工消費合作社印制衣 7¾尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 1284594 A7 B7 五、發明說明（Μ ) 板積層用印刷樹脂薄膜以加熱溫度160°c、接著壓力 15kgf/cm2、壓接時間15秒的條件進行加熱壓接，而得出 高鮮映裝飾板。 (實施例3) 在和實施例2相同的聚苯二甲酸丁二醇酯樹脂和共聚 物聚苯二甲酸乙二醇酯樹脂的雙層未延伸薄膜的片面上， 將著色密實印刷層直接設於聚苯二甲酸丁二醇酯樹脂上， 再在其上方設置圖樣印刷層’除此外是用和實施例2同樣 的條件來印刷。又，和實施例2同樣地，將前述雙層未延 伸薄膜與相同於實施例2的透明聚苯二甲酸丁二醇酯未延 伸薄膜邊積層邊施加壓花加工後進行刮塗印刷，而製作出 印刷樹脂薄膜後，透過和實施例2同樣的接著劑來積層厚 25/zm的透明雙軸延伸聚苯二甲酸乙二醇酯薄膜（帝人製） ，而製作出樣式特性優異的高鮮映裝飾薄膜。接著，在厚 8mm之石膏板上以80g/m2的塗佈量來塗佈聚氨酯系接著劑 ，將前述高鮮映裝飾板積層用印刷樹脂薄膜以加熱溫度 18(TC、接著壓力15kgf/cm2、壓接時間20秒的條件進行加 熱壓接，而得出高鮮映裝飾板。 經濟部智慧財產局員工消費合作社印製 (實施例4) 和實施例2同樣地製作出印刷樹脂膜後，在該印刷樹 脂膜的壓花加工面上，將片面塗佈有環氧_酚醛系接著劑 之厚25//m的透明雙軸延伸聚碳酸酯膜(帝人製）的接著劑 塗佈面對向擺置，藉由以實施例1的加熱壓接中的壓接條 件相同條件來進行壓接，以製作出樣式特性優異的高鮮映 14 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 1284594 A7 B7 五、發明說明（p) (請先閱讀背面之注意事項再填寫本頁) 裝飾薄膜。接著，和實施例2同樣地在厚6mm的木材合板 上加熱壓接前述高鮮映裝飾板積層用印刷樹脂薄膜’而得 出高鮮映裝飾板。 (實施例5) 和實施例3同樣地製作出印刷樹脂膜後，在該印刷樹 脂膜的壓花加工面上，將片面塗佈有環氧-酚醛系接著劑 之厚25/zm的透明雙軸延伸丙烯酸樹脂膜的接著劑塗佈面 對向擺置，藉由以實施例1的加熱壓接中的壓接條件相同 條件來進行壓接，以製作出樣式特性優異的高鮮映裝飾薄 膜。接著，和實施例3同樣地在厚8mm的石膏板上加熱壓 接前述高鮮映裝飾板積層用印刷樹脂薄膜，而得出高鮮映 裝飾板。 (樹脂薄膜之特性評價） 針對實施例1、2、3、4及5所製作出的高鮮映裝飾 板，進行下列特性的評價。 (壓花加工性） 經濟部智慧財產局員工消費合作社印製 本發明的裝飾板積層用印刷樹脂薄膜之刮塗印刷用壓 花加工性的優劣，係依據施加壓花加工後之樹脂薄膜的基 板樹脂層之表面粗糙程度來判斷。本發明中，係使用形成 有平均表面粗度(Ra)ll 的凹凸之彫刻輥來施加壓花加 工，而對加工後的樹脂薄膜之著色樹脂層的表面用肉眼來 觀察，並以下述3階段的基準來評價壓花加工性的優劣。 〇：良好，△:稍不良，X :不良 又，上述評價基準，係將聚氯乙烯樹脂膜的表面粗度 15 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公爱Γ 1284594 Α7 Β7A7 1284594 _ B7 _______ V. Inventive Note (f) (Please read the note on the back side and fill out this page) Further, the film is formed by coextruding the resin layer 4 and the colored resin layer 5 in which the pigment 5 is kneaded. After the two-layer film is applied, the pattern printing layer 6a is applied to the colored resin layer 5, and the base resin layer 7 is superposed thereon, and the sandwiching and crimping is performed by passing between the pair of hot rolls while maintaining the overlapping state. A thermal fusion layer is formed to produce a laminated film. At this time, by using the embossing roll as the above-mentioned hot roll, lamination and embossing can be simultaneously performed, and it is obtained that the embossed concave portion 8 for blade coating printing is formed on the surface of the base resin layer 7, and then the embossing is applied. The ink is used to set the doctor-printed layer 9 to impart a patterning pattern of high pattern characteristics. Further, by laminating the surface resin layer 11 through the adhesive layer 10 thereon, the printing resin film 1 for a high-preserving decorative laminated layer shown in Fig. 2 can be obtained. Moreover, since the dimensional stability of the colored resin layer 5 and the base resin layer 7 is good, it is possible to suppress the change in tension due to tension or heat, and it is possible to obtain a high pattern in which the printed pattern and the embossed pattern are harmonized. An embossed decorative film of the character. The laminating operation and the embossing process can be carried out under the same conditions as the conventional polyvinyl chloride resin film. In addition, a printed layer 6b is provided on the surface of the colored resin layer 5 of Fig. 2, and a pattern printed layer 6a is placed on the surface of the colored resin layer 5 of Fig. 2, and a resin film is used. A printed resin film 1 for a decorative laminate layer having a better pattern characteristic as shown in Fig. 3 is obtained. Moreover, the high-precision decorative laminate film-forming resin film 1 obtained by the above method is passed through the adhesive layer 3 to be bonded to the substrate 2, whereby the high-preservation decorative sheet 12 as shown in FIG. 4 or FIG. 5 can be obtained. . As the substrate 2, for example, a wood veneer, a wood plywood, a particle board, a wood board such as MDF, or the like, and a steel plate 11 can be used in the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1284594 Property Bureau employee consumption cooperative printed A7 B7 V. Invention description (,), aluminum alloy plate, galvanized or galvanized alloy galvanized steel plate, etc., or gypsum board, calcium silicate board, stone wool board, etc. The sheet material composed of the inorganic material is used as an adhesive for the adhesive layer 3 of the printed resin film 1 and the substrate 2 which is used for the high-preservation decorative layer, and a general adhesive can be used, and it is safe based on fire. The odor and the price considerations are preferably latex-type adhesives such as a vinyl acetate resin, an ethylene-vinyl acetate resin, a urea resin, or a polyurethane resin. [Examples] Hereinafter, the present invention will be described in more detail by way of examples. (Example 1) A nitrocellulose-alkyd ink (manufactured by Showa Ink) was used for the surface of a transparent biaxially-stretched polyethylene terephthalate film (manufactured by Seomic Co., Ltd.) having a thickness of 25 // m. SAM), the pattern printing layer and the colored compact printing layer are printed in a row by a gravure rotary printing press. Next, a double layer of 70#m thick which was produced by using an extrusion film forming machine using a commercially available polybutylene phthalate resin and a copolymer polyethylene terephthalate resin was laminated. The film (thickness ratio = 4:1) was heated and crimped under the conditions of a heating temperature of the pressure roller of 200 ° C, a feed speed of the resin film of 20 m/min, and a bite pressure of the pressure roller of 15 kgf/cm 2 . The layer is laminated to produce a printed resin film for high-grade decorative laminate. Then, a polyester-based adhesive was applied to a galvanized steel sheet having a thickness of 5 mm at a coating weight of 10 μg/m 2 , and the printing resin film for the high-preserving decorative laminate layer was heated at a temperature of 210 ° C. Then, the pressure was 15 kgf/cm 2 and the pressure bonding time was 5 seconds, and the pressure plate was heated and pressed to obtain a decorative sheet. 12 Wood paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) (Please read the phonetic note on the back side and then fill out this page) Order ·--Line 丨 | 1284594 A7 B7 V. INSTRUCTION DESCRIPTION (π) (Example 2) A colored resin obtained by kneading 20% by weight of an opal pigment in a commercially available polybutylene terephthalate resin, and a copolymer of polyethylene terephthalate Ester-Use of nitrocellulose on the side of the polybutylene terephthalate resin side of a two-layer unstretched film of 50//m thick prepared by an extrusion film making machine with a thickness ratio of 4:1 - Alkyd ink (made by Showa Ink, SAM) and printed in a row by a gravure rotary machine, and used in a commercially available polybutylene phthalate resin through an extrusion film machine The transparent unstretched film having a thickness of 70/m was formed to face up, and under the same conditions as those in the thermocompression bonding of Example 1, a transparent polybutylene terephthalate film was used. The embossing roll side is formed between the pressure-bonding rolls formed by the embossing roll and the silicone roll to produce the transparent polybutylene Ester film 3 having a surface-layer film of the embossed depressions. Then, the two-liquid-curable urethane-based coloring ink (PW-001, manufactured by Showa Ink) was applied to the surface of the embossed concave portion by a roll coating method, and then the color of the portion other than the embossed concave portion was adhered by a doctor blade. After the ink is scraped off, the colored ink filled in the embossed concave portion formed on the surface of the laminated film is cured to form a printed resin film. Further, on the embossed surface of the printing resin film, a transparent biaxially-oriented transparent polyethylene terephthalate film having a thickness of 25/m thick coated with an epoxy-phenolic adhesive was applied (manufactured by Teijin The adhesive coating is applied in the face-to-face configuration, and is crimped by a pair of pressure-sensitive adhesive rolls formed by a pair of silicone rollers under the same conditions as those in the thermal pressure bonding of the first embodiment. A high-grade decorative film with excellent pattern characteristics is produced. Next, a polyester-based adhesive is applied to a wood plywood having a thickness of 6 mm at a coating amount of 50 g/m 2 , and the above-mentioned high-color decorative 13 (please read the back of the back sheet and fill in the page) d ------- Ministry of Economic Affairs Intellectual Property Bureau Employees Consumption Cooperatives Printed clothing 73⁄4 scale Applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 1284594 A7 B7 V. Invention description (Μ) Printing of laminate layer The resin film was heat-compressed under the conditions of a heating temperature of 160 ° C, a pressure of 15 kgf / cm 2 , and a pressure bonding time of 15 seconds to obtain a high-grade decorative sheet. (Example 3) On the sheet surface of the double-layered unstretched film of the same polybutylene phthalate resin and copolymer polyethylene terephthalate resin as in Example 2, the colored dense printed layer was directly provided. On the polybutylene phthalate resin, a pattern printed layer was placed thereon, except that printing was carried out under the same conditions as in Example 2. Further, in the same manner as in Example 2, the double-layered unstretched film and the transparent polybutylene terephthalate film of Example 2 were laminated and embossed, and then subjected to squeegee printing to prepare a pattern. After printing a resin film, a transparent biaxially-stretched polyethylene terephthalate film (manufactured by Teijin) having a thickness of 25/zm was laminated by the same adhesive as in Example 2 to produce a high-quality image having excellent pattern characteristics. Decorative film. Next, a urethane-based adhesive was applied to a gypsum board having a thickness of 8 mm at a coating amount of 80 g/m 2 , and the printing resin film for the high-preserving decorative laminate layer was heated at a temperature of 18 (TC, followed by a pressure of 15 kgf/cm 2 ). The pressure-bonding time was 20 seconds, and the high-precision decorative plate was obtained under the conditions of a pressure-bonding time of 20 seconds. Printed by the Ministry of Economic Affairs, Intellectual Property Office, Staff Cooperatives (Example 4) After the printing resin film was produced in the same manner as in Example 2, The embossed surface of the printing resin film was coated with an adhesive coated with a transparent biaxially stretched polycarbonate film (manufactured by Teijin) having a thickness of 25/m thick coated with an epoxy-phenolic adhesive. The arrangement was carried out by the same conditions as those under the crimping conditions in the thermocompression bonding of Example 1, to produce a high-precision pattern having excellent pattern characteristics. The paper size was applicable to the Chinese National Standard (CNS) A4 specification (210). X 297 mm) 1284594 A7 B7 V. Inventive Note (p) (Please read the precautions on the back side and fill out this page) Decorative film. Then, in the same manner as in Example 2, the above-mentioned 6 mm thick wood plywood was heated and crimped as described above. High-resistance decorative board laminate printing resin In the same manner as in Example 3, a printing resin film was produced in the same manner as in Example 3, and then the sheet surface was coated with epoxy-phenolic resin on the embossed surface of the printing resin film. The adhesive coating of the transparent biaxially stretched acrylic resin film of the thickness of 25/zm of the adhesive was placed facing the surface, and the pressure bonding was carried out under the same conditions as in the crimping conditions in the heat crimping of Example 1, A high-rise decorative film having excellent pattern characteristics was produced. Then, in the same manner as in Example 3, the printing resin film for the high-grade decorative decorative layer was heated and pressure-bonded on a gypsum board having a thickness of 8 mm to obtain a high-grade decorative sheet. (Evaluation of Characteristics of Resin Film) The following characteristics were evaluated for the high-precision decorative panels produced in Examples 1, 2, 3, 4, and 5. (embossing processability) Ministry of Economic Affairs Intellectual Property Bureau employee consumption cooperative The embossability of the squeegee printing of the printing resin film for decorative decorative layer of the present invention is determined by the degree of surface roughness of the substrate resin layer of the resin film after embossing. In the present invention, Use shape The surface of the colored resin layer of the processed resin film was observed with the naked eye by an embossing roll having an unevenness of the average surface roughness (Ra) of ll, and the embossing was evaluated by the following three-stage standard.优: good, △: slightly bad, X: bad, the above evaluation criteria, the surface roughness of the polyvinyl chloride resin film 15 paper size applies to the Chinese National Standard (CNS) A4 specifications (210 X 297公爱Γ 1284594 Α7 Β7
五、發明說明（G 經濟部智慧財產局員工消費合作社印製 (Ra: //m)用東京精密社製SUSFCOM表面粗度計並依據 JIS B0601來測定，而以平均表面粗度的情形作爲壓 花加工性的合格基準，當具有和平均表面粗度4^m的聚 氯乙烯樹脂膜的表面同等級以上的外觀時判定爲良好（〇） ，當相較於聚氯乙烯樹脂膜的表面係具有較差但實用上不 成問題的外觀時判定爲稍不良（△)，而無法施以壓花加工 者則判定爲不良（X)。 (耐污染性） 在實施例1、2及3所製作出的裝飾板之最表層的樹 脂膜面上，用黑色油性奇異筆畫圖後放置24小時，之後用 含浸有乙醇之布來擦拭，用肉眼觀察樹脂膜面所殘存的奇 異筆的程度，依據以下的基準來進行評價。 ◎:完全看不出有奇異筆痕。 〇：有實用上沒有問題之極少的奇異筆殘存。 △:有實用上會產生問題之少量奇異筆殘存。 X:有相當程度之奇異筆殘存。 (耐溶劑性） 在實施例1、2及3所製作出之裝飾板的最表層樹脂 膜面上，放置含浸有丁酮之海綿，經24小時放置後，用肉 眼觀察膜表面的變色及膨脹產生的程度，依據以下基準來 進行評價。 ◎ 〇 △ 完全看不出有變色或膨脹的產生。 有實用上沒有問題之極少的變色或膨脹的產生。 有實用上會產生問題之少量變色或膨脹的產生。 16 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 請 先 閱 讀 背 意 事 項 再V. Description of the invention (G: Ministry of Economic Affairs, Intellectual Property Office, employee consumption cooperative printing (Ra: //m) is measured by the SUSFCOM surface roughness meter manufactured by Tokyo Seimi Co., Ltd. and measured according to JIS B0601, and the average surface roughness is used as the pressure. The basis of the flower processing property was judged to be good when it had an appearance of the same level or more as the surface of the polyvinyl chloride resin film having an average surface roughness of 4 μm, compared to the surface system of the polyvinyl chloride resin film. When the appearance was poor but practically not problematic, it was judged to be slightly defective (?), and if it was not possible to apply the embossing, it was judged to be defective (X). (Stain resistance) It was produced in Examples 1, 2 and 3. The surface of the resin film on the outermost layer of the decorative board is placed on the surface of the resin sheet with black oily scent for 24 hours, then wiped with a cloth impregnated with ethanol, and the degree of the singular pen remaining on the surface of the resin film is visually observed, according to the following The evaluation is based on the standard. ◎: There are no strange pen marks at all. 〇: There are very few singular pens that have no practical problems. △: There are a few strange pens that have problems in practical use. X: There are considerable degrees. The singular pen remained. (Solvent resistance) On the surface of the outermost resin film of the decorative sheets produced in Examples 1, 2 and 3, a sponge impregnated with methyl ethyl ketone was placed, and after being placed for 24 hours, the surface of the film was observed with the naked eye. The degree of discoloration and swelling is evaluated according to the following criteria: ◎ 〇 △ There is no visible discoloration or swelling. There is little problem of discoloration or expansion which is practically problem-free. A small amount of discoloration or expansion occurs. 16 The paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm). Please read the back-to-back items first.
η 頁I I I I I I 訂 線 1284594 B7 五、發明說明（％) X:有相當程度之變色或膨脹的產生。 (耐水變質性） 假定將本發明的裝飾板在高溫多濕的狀態下經過長時 間的情形（例如用於組合式廁所的內裝材時等），用杜邦衝 擊試驗法來評價長時間接觸水時的樹脂膜之耐水變質性。 將實施例1、2、3、4及5所製作出之高鮮映裝飾板 積層用印刷樹脂薄膜，積層於厚0.5mm之鍍鋅鋼板來做爲 試驗片。將該試驗片裁切成60mmX60mm的大小，在保持 於38±2°C的溫度下之脫鹽水中浸漬1個月後於室溫下乾 燥，使用杜邦衝擊試驗機，依據JIS K 5400的條件(衝擊部 大小1/2吋φ，重lkg，落下高度50cm)來施加衝擊。用肉 眼觀察施加衝擊後的樹脂膜之狀態，用以下的5階來進行 評價。 ◎:樹脂膜看不出有裂痕。 〇:樹脂膜的一部分發現細小的裂痕。 △:在樹脂膜的壓花加工部全體皆發現細小的裂痕。 X:在樹脂膜的壓花加工部全體皆發現大的裂痕。 X X :在整個樹脂膜上有顯著的裂痕。 上述評價中，◎及〇不會有使用上的問題。又，本試 驗係採10片的試驗片來實施。 (鮮映性） 將實施例1、2、3、4及5所製作出的高鮮映裝飾板 積層用印刷樹脂薄膜積層於厚0.5mm之鍍鋅鋼板來做爲試 驗片。將該試驗片表面之鮮映度，用財團法人日本色彩硏 17 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) 訂---------線-』 經濟部智慧財產局員工消費合作社印製 經濟部智慧財產局員工消費合作杜印製 1284594 A7 ------— R7_ 五、發明說明（G ) 究所製的攜帶用鮮明度光澤計PGD - 4型來測定。又，本 發明所稱之鮮映性’係代表著映像鮮映性，亦即映照在裝 飾面上之正反射像的鮮明度；而高鮮映則指前述鮮映度爲 0.8以上的情形。 這些高鮮映性裝飾板的特性評價係整理如下。 壓花加工性 耐污染性 耐溶劑性 耐水變質性 鮮映性 實施例1 〇 ◎ ◎ ◎ 0.9 實施例2 〇 〇 ◎ ◎ 0.9 實施例3 〇 〇 ◎ ◎ 0.9 實施例4 〇 〇 ◎ ◎ 0.9 實施例5 〇 〇 ◎ ◎ 0.9 如上表所示般，本發明的裝飾板係在壓花性、耐污染 性、耐溶劑性、耐水變質性、鮮映性等各方面都顯示優異 的特性。 〔發明效果〕 本發明的高鮮映裝飾板積層用印刷樹脂薄膜係採上述 般的構成’由於聚對苯二甲酸丁二醇酯構成之基材樹脂層 及著色樹脂層對熱、張力之伸縮變動少而具有優異的尺寸 安定性，故可得出印刷精度佳的印刷物。 又，由於能用和以往之聚氯乙烯樹脂膜相同的製造方 法和製造條件來得出裝飾薄膜，故不需要增設新設備或改 造設備等設備上的投資，而能和以往的聚氯乙烯樹脂膜相 同的，表現出印刷圖樣和壓花圖案諧調而具有高度樣式特 18 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁)η page I I I I I I Ordering line 1284594 B7 V. Description of invention (%) X: There is a considerable degree of discoloration or expansion. (Water resistance deterioration) It is assumed that the decorative sheet of the present invention is subjected to a long period of time in a high-temperature and high-humidity state (for example, when used for interior fitting of a combined toilet), and the DuPont impact test method is used to evaluate long-term contact with water. The water resistance of the resin film at the time. The high-precision decorative laminated resin film produced in Examples 1, 2, 3, 4 and 5 was laminated on a galvanized steel sheet having a thickness of 0.5 mm to prepare a test piece. The test piece was cut into a size of 60 mm×60 mm, immersed in desalted water maintained at a temperature of 38±2° C. for one month, and then dried at room temperature, using a DuPont impact tester according to the conditions of JIS K 5400 (shock The size of the part is 1/2 吋φ, the weight is lkg, and the drop height is 50 cm) to apply an impact. The state of the resin film after the impact was observed with the naked eye, and the evaluation was carried out by the following five steps. ◎: No cracks were observed in the resin film. 〇: A small crack was found in a part of the resin film. △: Fine cracks were found in the entire embossed portion of the resin film. X: A large crack was found in the entire embossed portion of the resin film. X X : Significant cracks on the entire resin film. In the above evaluation, ◎ and 〇 will not have problems in use. Further, this test was carried out by taking 10 test pieces. (Surface) The high-preservation decorative laminate produced in Examples 1, 2, 3, 4 and 5 was laminated on a galvanized steel sheet having a thickness of 0.5 mm by using a printing resin film as a test piece. The freshness of the surface of the test piece shall be in accordance with the Chinese National Standard (CNS) A4 specification (210 X 297 mm) on the paper scale of the Japanese color. (Please read the note on the back and fill in this page) ---------Line-』 Ministry of Economic Affairs Intellectual Property Bureau Staff Consumer Cooperatives Ministry of Printing and Economy Ministry Intellectual Property Bureau Staff Consumption Cooperation Du Printing 1284594 A7 ------- R7_ V. Invention Description (G) The portable lightness meter PGD-4 was used for the measurement. Further, the term "deep-reflection" as used in the present invention represents the vividness of the image, that is, the sharpness of the specular reflection image reflected on the decorative surface, and the high-precision image indicates that the vividness is 0.8 or more. The evaluation of the characteristics of these high-precision decorative panels was organized as follows. Embossing processability, stain resistance, solvent resistance, water resistance, and water repellency. Example 1 〇 ◎ ◎ 0.9 Example 2 〇〇 ◎ ○ 0.9 Example 3 〇〇 ◎ ○ 0.9 Example 4 〇〇 ◎ ◎ 0.9 Example 5 〇〇 ◎ ◎ 0.9 As shown in the above table, the decorative sheet of the present invention exhibits excellent characteristics in terms of embossability, stain resistance, solvent resistance, water resistance deterioration, and vividness. [Effect of the Invention] The printing resin film for a high-preserving decorative laminated layer of the present invention adopts the above-described general structure. The base resin layer and the colored resin layer composed of polybutylene terephthalate stretch and contract with heat and tension. With a small variation and excellent dimensional stability, it is possible to obtain a printed matter with excellent printing accuracy. Moreover, since the decorative film can be obtained by the same manufacturing method and manufacturing conditions as the conventional polyvinyl chloride resin film, it is not necessary to add investment in equipment such as new equipment or retrofit equipment, and it can be combined with the conventional polyvinyl chloride resin film. The same, showing the printing pattern and embossing pattern harmonized and highly styled. This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (please read the back note and fill out this page)
1284594 A7 B7 五、發明說明（) 性之構圖模樣。 又，由於在基材樹脂層和表面樹脂層之構成樹脂中不 含可塑劑，將不致產生可塑劑的滲出所致之表面污染等問 題，因此耐污染性、耐溶劑性、耐水性等的表面物性相當 優異。 又，在焚化廢棄時，由於不致產生氯化氫氣體般之有 毒氣體，故完全沒有環境污染之虞，而具有優異的環保性 〇 〔圖式之簡單說明〕 圖1係顯示本發明的高鮮映裝飾板積層用印刷樹脂薄 膜的一例之截面圖。 圖2係顯示本發明的高鮮映裝飾板積層用印刷樹脂薄 膜的另一例之截面圖。 圖3係顯示本發明的高鮮映裝飾板積層用印刷樹脂薄 膜的另一例之截面圖。 圖4係顯示本發明的高鮮映裝飾板的一例之截面圖。 圖5係顯示本發明的高鮮映裝飾板的另一例之截面圖 〇 〔符號說明〕 Γ···高鮮映裝飾板積層用印刷樹脂薄膜 2…基板 3…接著劑層 4…接著樹脂層 5…著色樹脂層 19 本紙張尺度適用中國國家標準（CNS)A4規格（210 x 297公爱7 ·!!———m (請先閱讀背面之注意事項再填寫本頁) -------訂---------線' 經濟部智慧財產局員工消費合作社印製 -ϋ ϋ ϋ I · A7 1284594 ___B7 五、發明說明（17 ) 6a…圖樣印刷層 6b…密實印刷層 7…基材樹脂層 8…刮塗印刷用壓花凹部 9…刮塗印刷層 10…接著劑層 Π…表面樹脂層 12…高鮮映裝飾板 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐）1284594 A7 B7 V. Description of invention () Composition of the character. In addition, since the plasticizer is not contained in the constituent resin of the base resin layer and the surface resin layer, there is no problem such as surface contamination due to bleeding of the plasticizer, and thus the surface such as stain resistance, solvent resistance, water resistance, and the like The physical properties are quite excellent. In addition, in the case of incineration and disposal, since no toxic gas such as hydrogen chloride gas is generated, there is no environmental pollution at all, and it has excellent environmental protection. [Simplified description of the drawings] Fig. 1 shows the high-preservation decoration of the present invention. A cross-sectional view of an example of a printed resin film for a laminate layer. Fig. 2 is a cross-sectional view showing another example of the printing resin film for high-reflection decorative sheet of the present invention. Fig. 3 is a cross-sectional view showing another example of the printing resin film for high-preservation decorative sheet of the present invention. Fig. 4 is a cross-sectional view showing an example of a high-grade decorative panel of the present invention. Fig. 5 is a cross-sectional view showing another example of the high-reflection decorative sheet of the present invention. [Illustration] 印刷··········································· 5...Colored resin layer 19 This paper size applies to China National Standard (CNS) A4 specification (210 x 297 public 7)!!!—m (Please read the back note first and then fill in this page) ----- --Book --------- Line 'Ministry of Economics Intellectual Property Bureau employee consumption cooperative printing -ϋ ϋ ϋ I · A7 1284594 ___B7 V. Invention description (17) 6a... pattern printing layer 6b... compact printing layer 7...Substrate Resin Layer 8...Printing embossing recess 9 for blade coating...Brushing printing layer 10...Binder layer Π...Surface resin layer 12...High fresh decorative panel (please read the back note first and then fill in this page) The Ministry of Economic Affairs, Intellectual Property Bureau, Staff and Consumer Cooperatives, printed this paper scale, applicable to China National Standard (CNS) A4 specification (210 X 297 mm)