TWI225766B - Heat dissipation plate for notebook computer CPU - Google Patents

Heat dissipation plate for notebook computer CPU Download PDF

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Publication number
TWI225766B
TWI225766B TW90109647A TW90109647A TWI225766B TW I225766 B TWI225766 B TW I225766B TW 90109647 A TW90109647 A TW 90109647A TW 90109647 A TW90109647 A TW 90109647A TW I225766 B TWI225766 B TW I225766B
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Taiwan
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heat transfer
transfer device
heat
patent application
scope
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TW90109647A
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Chinese (zh)
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Hongyuan Yang
Zhipeng Qu
Aixing Tong
Yufu Li
Douglas Chan
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New Qu Energy Ltd
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Abstract

This is a heal transfer plate which is made of a superconducting heat transfer medium disposed within a conduit to rapidly and efficiently transfer heat. The heat transfer plate is especially well suited to provide temperature regulation for computer CPUs.

Description

1225766 A7 B7 五、發明説明(1 ) 技術領域 本發明大致關於熱轉移之領域,'較特別的是本發明關於 一熱轉移板,其係由設於一導管内之超傳導熱轉移介質構 成,以利快速且有效地轉移熱於一 CPU與周侧大氣之間。 背景技藝 眾所周知影響電腦處理器穩定性及限制高性能CPUs進一 步改善之一項因素爲熱之生成及留置,各電腦處理器係封 裝以多數電晶體,各於處理器正常操作期間釋出熱。惟, 桌上型且特別是膝上型之電腦係受限於可提供風扇及塊狀 散熱器以將熱轉移出處理器之内部空間,諸解決方式並無 夠大之體積,且熱電阻與雜音高,及易因風扇之使用壽命 短而故障。 有效地自一處傳熱至另一處,特別是在電腦中,一直是 一大問題,保持一半導體晶片冷卻則需要快速做熱轉移及 去除。無論去除或留置熱,所用材料之熱轉移傳導率皆會 拘限熱轉移之效率。此外,當需要留置熱時,損失至環境 之熱會進一步降低熱轉移之效率。 經濟部中央標準局員工消費合作社印製 vm _ ml I j I - - - l 丈穴 111 si- 1-- ϋ« -----—ϋ ^ 、νφ (請先聞讀背面之注意事項再填寫本頁) 再者,在美國專利5,790,376號“用於一電子組件之散熱墊 結構”中,其揭述一散熱系統用於一筆記型電腦之處理器中 ,此系統係由鄰近於一處理器之金屬塊製成,其連接於一 相對於一外殼體壁而設之熱轉移墊。熱轉移墊具有一體成 型之中空管,其填注入淨水且各別封閉。處理器所生之熱 轉移至金屬塊,接著至熱轉移墊,以散熱至筆記型電腦外 之環境。 -4- 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 1225766 A7 B7- 五、發明説明(2 ) 吾人亦知使用一熱管做熱轉移,熱管之操作原理在於轉 移熱透過其内部容裝之大量流體載體轉移,及載體在一封 閉回路管内自液態至氣態之相態改變。熱係在管之一端利 用載體蒸發而吸收,而在另端利用載體氣體之冷凝而釋出 。儘管熱管比固體金屬桿更能改善熱轉移之效率,但是熱 管需要液體/氣體循環流動,且受限於載體之蒸發與冷凝之 相關溫度.,結果熱管之軸向熱傳導速度進一步受限於液體 蒸發之内熱量及液態與氣態之間之循環轉變速度。此外, 熱管本質上爲對流式,且有熱損之虞,因而降低熱效率。 經濟部中央標準局員工消費合作社印製 - 111 - - 1 - - ill - - - - I 士穴 -........... - - -- HI (請先聞讀背面之注意事項再填寫本頁) 一特別適用於核子反應爐之熱管改良係見述於美國專利 4,590,993號“用於無淨質量損失之大傳導通量的傳送之熱轉 移裝置”中。此裝置具有一對流體貯器,供定位於需傳送處 之間之各差異溫度處,一對導管具有一傳熱之材料壁,以 連接於流體貯器,較佳爲液體金屬例如汞、液體鋰或液體 鈉之熱轉移流體係填注入貯器與導管。液體金屬之擺動軸 向移動係由其中一貯器内之活塞或膜片產生,使得流體移 動範圍小於導管長度,此移動之功能在於交替移位貯器内 之流體,使液體金屬在一方向呈軸向移動通過導管,且將 熱轉移流體抽回到一貯器内,因此熱轉移流體在導管内以 相反方向移動。因此,在導管内流體係以一預定頻率在交 替之軸向中擺動,且具有一預定之潮汐位移或振幅。藉由 此配置方式,大量之熱即沿著導管在軸向自較熱貯器傳送 與轉移至導管壁面,假設流體係以相當高頻率擺動,且具 有一大潮汐位移。當流體在回程循環中擺動至較熱貯器時 -5- 本紙張尺度適用中國國家標準(CNS )八4規格(210X 297公釐) 1225766 A7 B7 五、發明説明(3 ) ,來自相對立貯器之較冷流體可拉入導管内,熱即自壁面 轉移至較冷流體。在後續擺動時,熱再自較熱貯器轉移至 相對立貯器。惟,在熱管時,此裝置會因爲構成貯器與導 管之材料之熱轉移傳導率以及逸至大氣之熱損而限制於效 率。 吾人已知利用輻射器及散熱器去除機械式電力操作中產 生之過量熱,通常循環通過一熱產生源之熱轉移流體會吸 收一部分由源產生之熱,流體隨後通過具有熱交換器之管 件,以吸收及輻射出流體所載之熱。冷卻時,流體回到熱 產生源,通常設有一風扇以吹送空氣至鰭片上方,因此散 熱器之能量輻射至通過鰭片之大量空氣。使用此裝置時, 熱轉移效率再次受限於構成輻射器或散熱器之材料之熱轉 移傳導率。 經濟部中央標準局員工消費合作社印製 II: ί - I 0 —I 1 _ I 1 := I -——I (請先閱讀背面之注意事項再填寫本頁)1225766 A7 B7 V. Description of the Invention (1) Technical Field The present invention relates generally to the field of heat transfer. 'The more specific is the present invention relates to a heat transfer plate, which is composed of a superconducting heat transfer medium provided in a duct. In order to quickly and efficiently transfer heat between a CPU and the surrounding atmosphere. BACKGROUND ART It is well known that one factor that affects the stability of computer processors and limits the further improvement of high-performance CPUs is the generation and retention of heat. Each computer processor is packaged with most transistors and each releases heat during the normal operation of the processor. However, desktop and especially laptop computers are limited by the ability to provide fans and block radiators to transfer heat out of the processor's internal space. The solutions are not large enough, and the thermal resistance and The noise is high, and it is easy to malfunction due to the short life of the fan. Effectively transferring heat from one place to another, especially in computers, has always been a problem. Keeping a semiconductor wafer cool requires rapid heat transfer and removal. Regardless of the heat removal or indwelling, the thermal transfer conductivity of the materials used will limit the efficiency of thermal transfer. In addition, when heat is required to be retained, the heat lost to the environment can further reduce the efficiency of heat transfer. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs vm _ ml I j I---l Zhangxue 111 si- 1-- ϋ «-----— ϋ ^, νφ (Please read the precautions on the back before reading (Fill in this page) Furthermore, in US Pat. No. 5,790,376, “Thermal Pad Structure for an Electronic Component”, it discloses that a heat dissipation system is used in the processor of a notebook computer. The device is made of metal blocks and is connected to a heat transfer pad disposed opposite a wall of an outer shell. The heat transfer pad has an integrally formed hollow tube, which is filled with purified water and closed individually. The heat generated by the processor is transferred to a metal block, and then to a heat transfer pad to dissipate heat to the environment outside the laptop. -4- This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) 1225766 A7 B7- V. Description of the invention (2) I also know that a heat pipe is used for heat transfer. The operating principle of the heat pipe is to transfer heat through it A large amount of the fluid carrier contained therein is transferred, and the carrier changes from a liquid state to a gaseous state in a closed loop tube. Heat is absorbed at one end of the tube by carrier evaporation and released at the other end by condensation of carrier gas. Although heat pipes can improve the efficiency of heat transfer more than solid metal rods, heat pipes require liquid / gas circulation and are limited by the temperature associated with the evaporation and condensation of the carrier. As a result, the axial heat conduction speed of the heat pipes is further limited by the liquid evaporation The speed of the heat and the cycle transition between liquid and gas. In addition, the heat pipe is convection in nature and there is a risk of heat loss, thereby reducing thermal efficiency. Printed by the Consumers' Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs-111--1--ill----I Shixue -..............---HI (Please read the note on the back first Please fill in this page again.) A heat pipe improvement particularly suitable for nuclear reactors is described in US Patent No. 4,590,993 "Heat Transfer Device for Transmission of Large Conductive Flux Without Net Mass Loss". This device has a pair of fluid reservoirs for positioning at different temperatures between the places to be transferred. A pair of conduits have a wall of material for heat transfer to connect to the fluid reservoir, preferably a liquid metal such as mercury, liquid A thermal transfer flow system of lithium or liquid sodium is filled into the reservoir and the catheter. The oscillating axial movement of the liquid metal is generated by a piston or a diaphragm in one of the reservoirs, so that the fluid movement range is smaller than the length of the catheter. The function of this movement is to alternately shift the fluid in the reservoir, so that the liquid metal presents in one direction. The axial movement is through the conduit and the heat transfer fluid is drawn back into a reservoir, so the heat transfer fluid moves in the conduit in the opposite direction. Therefore, the in-catheter flow system oscillates in the alternate axis at a predetermined frequency and has a predetermined tidal displacement or amplitude. With this configuration, a large amount of heat is transferred and transferred from the hot reservoir to the wall of the duct along the duct in the axial direction, assuming that the flow system oscillates at a relatively high frequency and has a large tidal displacement. When the fluid oscillates to the hotter container during the return stroke -5- This paper size applies to China National Standard (CNS) 8 4 specifications (210X 297 mm) 1225766 A7 B7 V. Description of the invention (3), from the relative standing storage The cooler fluid of the device can be drawn into the duct, and the heat is transferred from the wall surface to the cooler fluid. On subsequent swings, the heat is transferred from the warmer reservoir to the opposite reservoir. However, in the case of heat pipes, this device is limited in efficiency due to the heat transfer conductivity of the materials constituting the receptacle and the conduit and the heat loss to the atmosphere. We are known to use radiators and radiators to remove excess heat generated during mechanical electrical operation. Usually, the heat transfer fluid circulating through a heat generation source will absorb a portion of the heat generated by the source, and the fluid will then pass through a pipe with a heat exchanger. To absorb and radiate the heat contained in the fluid. When cooling, the fluid returns to the heat generating source. A fan is usually provided to blow air above the fins, so the energy of the radiator is radiated to a large amount of air passing through the fins. When using this device, the heat transfer efficiency is again limited by the heat transfer conductivity of the materials that make up the radiator or heat sink. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs II: ί-I 0 —I 1 _ I 1: = I -—— I (Please read the precautions on the back before filling this page)

Dickinson之5,5 42,471號美國專利中揭述一具有熱傳導纖 維之熱轉移元件,其即不需要熱轉移流體,此裝置具有延 伸於二物質之間之縱向熱傳導纖維,熱係轉移於二物質之 間以加大熱轉移。纖維係由環氧樹脂基質石墨纖維中之石 墨纖維組成,其係自一具有有機樹脂基質内之石墨纖維、 鋁基質内之石墨纖維、銅基質内之石墨纖維等之有機基質 組合物、或陶質基質組合物固化。 在本人之8910852 1.1號中國專利中揭露一無機介質熱傳 導裝置,此熱傳導裝置大幅改善材料之熱傳導能力,實驗 顯示此裝置可沿著一内含局部眞空之封閉金屬殼體轉移熱 ,且每秒5,000米之速率。在殼體之内壁上係一以三步驟施 -6- 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 1225766 A7 B7 經濟部中央標準局員工消費合作社印製 五、發明説明(4 ) 加之塗層,具有0.0 12至0.013毫米之理想總厚度,塗層之總 重里包含1.25%總、1.38%皱、及1.95%納。此熱傳導裝置不 含熱產生粉末,且未以超傳導方式轉移熱或防止熱損失至 大氣。 發明概述 本發明提供一優異之熱轉移裝置以協助CPU冷卻,本模 、、’且包括一典機超傳導組合’不需要風扇-儘管吾人仍可使用 之,因而增加熱輻射力與系統穩定性,以及比使用風扇之 以往模組更能減少雜音及振動。 本發明之另一目的在提供一製成CPU熱轉移裝置之方法 ’其將熱源之熱自一點轉移至另一點,而無任何實際熱損 失。 本發明之又一目的在提供一散熱器,係使用一超傳導熱 轉移介質,可快速且有效地自一熱產生CPU散熱。 本發明達成上述與其他目的及克服先前技藝缺點係藉由 提供一超傳導熱轉移裝置,以用於一膝上型電腦CPU,且 製備低廉、設計使用簡單、方便使用。 在本發明之一實施例中,裝置含有四組件:一中空熱轉 移塾’安裝鄰近於一電腦之CPU ; —中空熱板,曝現於電 腦外之大氣或安裝鄰近於電腦之一外壁;一中空撓性管, 將熱轉移墊連接至熱板;及一超傳導熱轉移介質,塗覆於 熱墊、撓性管、及熱轉移板之内表面。 介質係以三基本層施加於表面,此方法詳示於本人在 2000年10月17日獲頒之6,13 2,832號美國專利“超傳導熱轉移 本紙張尺度適用中國國家標準(CNS ) A4規格(210X 297公釐) I I I I n n I n I I 1 (諳先閲讀背面之注意事項再填寫本頁) 17 1225766 Α7 Β7 五、發明説明(5 ) 介質”之介質説明中,前二層係由曝現於導管内壁之溶液製 備。最初,主要包含鈉、鈹離子型式多種組合、一金屬如 錳或鋁、鈣、硼、及重鉻酸基之第一層係吸收至導管内壁 大約0.008至0.012毫米深度中。隨後,主要包含鈷、錳、皱 、鳃、鍺、銅、/?·鈦、鉀、硼、鈣離子型式多種組合、一 金屬如鋁及重鉻酸基之第二層係建立於第一層頂部上,且 實際形成一 0.008至0.012毫米厚度之膜於導管内壁上。最後 ’第二層爲粉末’包含氧化铑、重鉻酸鉀、氧化鐳、重絡 蟑鈉、重鉻酸銀、氧化鈹、鉻酸鳃、氡化硼、鈦及一金 屬重鉻酸,例如重鉻酸錳或重鉻酸鋁,其均勻分佈於内壁 上。此三層可施加於一導管,接著熱極性化以製成一超傳 導熱轉移裝置,可轉移熱而無任意淨熱損失,或者可施加 於具有小孔穴相對於一大表面積之一對板,以製成一可立 即自一熱源散熱之散熱器。 可以瞭解的是,文内所用之語法及術語僅爲了説明而非 侷限,因此,習於此技者可以瞭解到本文所依據之概念可 用於其他結構、方法及系統之設計,以實施本發明之多項 經濟部中央標準局員工消費合作社印製 装-- (讀先閔讀背面之注意事碩再填寫本頁) 目的’因此,重要的是含有此等效結構之聲明皆未脱離本 發明之精神範疇。 本發明之其他目的、優點及能力可由以下説明連同揭示 本發明較佳實施例之配合圖式而得知。 圖式簡單説明 本發明將可方便瞭解且上述目的及其他目的可由以下詳 細説明參考附圖後必得知,其中: 本紙張尺度適用中國國家標準(CNS )八4規格(21〇χ 297公釐) 1225766 A7 B7 五、發明説明(6 ) 圖1係本發明一超傳導熱轉移裝置之立體圖; 圖2係圖1裝置之截面圖; ; 圖3係用於圖1裝置之一栓塞立體圖; 圖4係本發明一散熱器之立體圖; 圖5係圖4散熱器之側視圖; 圖ό係圖4散熱器之截面圖; 圖7係用.於測試超傳導熱轉移裝置之舉例測試裝置; 圖8係本發明較佳實施例測試Νο·1結果之數據; 圖9係本發明較佳實施例測試ν〇·2結果之數據; 圖10係本發明較佳實施例測試νο·3結果之數據;及 圖1 1係本發明較佳實施例測試Νο·4結果之數據。 圖12係一舉例CPU散熱系統。„ 較佳實施例詳細説明 下詳 經濟部中央標率局員工消费合作社印製 ----------t衣-- (請先聞讀背面之注意事項再填寫本頁) 訂 爲了便於瞭解本發明之性質及必要目的,應參考以 細説明連同配合圖式,請參閱諸圖式,其中相同之參考編 號係指相對應之組件,首先請參閲圖丨、2 •一超導熱轉浐 裝置2包含一載體,例如含有一超導熱轉移介質6之導管4 孩介質可放入導管4之一孔穴8内,無關於構成導管4之材料 。雖然圖1中之導管4係呈筒形,但是本發明應涵蓋多種邢 狀與尺寸之導管。介質6承載導管4之生成熱轉移能力係^ 幅改善,且無後續之熱損失。若正確施加於導管4内,則介 質6實際上可由熱催化,而本身變成一熱產生器,介質6係 在大約38 C活化,且可操作至一最大溫度丨73〇。〇。俾管 非完全特定,但是相信介質6之熱產生能力係直接相關於介 -9- 1225766 經濟部中央標準局員工消費合作杜印製 Α7 Β7 五、發明説明(7 ) 貝6活化後< 質量損失,因爲介質6可自一熱源(圖中未示)立 即透過導管4而轉移熱量,導管4可曝露及操作於一環境内 ,該環境具有一源溫度且遠超過構成導管4之未處理材料之 熔化溫度。 因此,相信在介質6活化之初期階段期間,介質6係呈内 熱式反應,結果介質6可立即自熱源吸收可得之熱量,且隨 後儿即將熱轉移遍及導管4。若孔穴8之體積相關於導管4之 外表面10面積而呈較小,如圖4至6,介質6吸熱以提供一散 熱器12,而立即自熱產生源除熱。熱輻射係直接相關於熱 能、熱傳導速率、及熱傳導率,易言之,此決定熱體積(量) 可在各單位體積内轉移之速度(速率)。 若導管4或載體相關於一大外表面1〇面積而具有一小孔穴 ,則載體較能將熱分配於外表面1 〇。在熱產生源之溫度不 超過38°C之應用中,即介質6活化之溫度,熱係由介質6立 即吸收及擴散,而在熱產生源超過38r之應用中,散熱器 12仍有高效能,此因爲介質6可快速轉移熱至散熱器之外表 面14,且藉由熱輻射而有效率地散佈至大氣。 介質6係以至少三基本層施加,前二層係由溶液製備,各 溶液依序曝露於一内導管表面16或一内散熱器表面18。起 初第一層20吸收至内導管表面16或散熱器表面18内,接著 第二層22建立於第一層2〇頂面上,且實際形成一膜於内導 管表面16或散熱器表面18上。最後,第三層24爲粉末,係 均勻分佈於内導管表面16或散熱器表面18上。雖然在介質6 之探討上係以導管4做爲參考,但是介質6應用於散熱器12 -10· ϋ張尺度適用中國國家標準(CNS) A4規格(210>< 297公楚) ------- n I - m m I I 1 士^.....I - -- - ——II 丁 (請先閲讀背面之注意事項再填寫本頁) 1225766 五、發明説明( 内之情形亦相同。 第一層20係一抗腐 ,且理論上造成導管二:、Γ 管表面16之㈣ 吸熱u2(m以重新料,因此易於 物^ " 功能在防止内導管表面16產生氧化 物,例如當曝露於空氣中 導管矣严 飞中之水刀子時鐵金屬容易氧化,内 能在導减會造成腐㈣產生—餘,結果,當熱 :在:“:轉移時即增加熱負荷,導致導管4内之熱能蓄 Λ。1生此W時,介質6之壽命將減短。 第二層22亦即活性層’可防止產生氫及氧元素, ,氧化拘限於氧原子與導管4(載體)材料之間。同時在 %上’弟二層22可導熱通過内導管表面“,好比電沿著 ^線傳導。經實驗發現,熱可由介質⑽每秒15,_米之速 率傳導。第二層22亦有助於加速分子㈣及相關聯於第三 層24之摩擦,以提供一熱轉移路徑用於熱傳導。 經濟部中央標準局員工消費合作杜印製 第—層24可因其顏色及外觀而稱爲“黑粉,,層,據信當介 質6曝露於抓之最小活化溫度時,第三層以即產生熱,而 一旦介質6活化時,接觸於第一層2〇及第二層“之第三層Μ 之原子開始振盪。隨著熱源溫度上昇,據信振盪頻率亦會 增大,當活化溫度達到20(TC時,振盪頻率爲每秒23〇百萬 次,而當活化溫度高於350T時,頻率甚至會達到每秒28〇 百萬次。理論上,活化溫度越高,則振盪頻率越高,因此 可以感覺到負荷越高時導管之性能效率越高。熱轉移過程 期間,既無相態變換亦無介質6質量轉移。經實驗顯示,一 内含介質6之鋼製導官4具有一熱傳導率且高於銀之熱傳導 -11 - 本紙張尺度適用中國國家標準(CNS ) A4規格(210 X 297公釐) 1225766 A7 B7__·__ 五、發明説明(9 ) " 率大約20,000倍,及在實驗室環境下可達到一熱傳導率且 咼於銀之熱傳導率大約3 〇,〇 〇 〇倍。 使用期間,介質6在活化後會隨著使用而損失質量(由量 月έ轉換所致之減損),因此介質6具有一長但是有限之使用 哥命。經試驗顯示,在連續使用u〇,〇〇〇小時後,介質6之 i及为子振動頻率仍相同於初期活化時,惟,連續使用 120,00〇小.時後,介質6之量(質量)開始以每32小時大約〇5〇/〇 之速率下降,且分子振動頻率明顯減少大約6%。連續使用 大約123,200小時後,介質6即變成無效能,據信老化主要 是因第三層24減損或量能轉換所致,可以預期的是,降低 工作溫度可減緩第三層24之減損。第一層20及第二層22已 決定爲以高達每1〇,〇〇〇使用小時大約〇 〇〇1毫米之速率使 用0 爲了製備第一層20,一第一層溶液係製成且隨後施加於 内導管表面1 6,一代表性之第一層溶液係由以下步驟製成 ,較佳爲依以下順序進行: 0)將1 〇〇毫升蒸餾水置入一惰性容器内,例如破璃或較佳 爲陶器; 經濟部中央標準局員工消費合作社印製 n —ϋ ϋϋ UK— - I ml 1^1 m I n i HI ϋϋ - -I— nn--"J (諳先閱讀背面之注意事項再填寫本頁) (b) 將2.0與5.0公克之間之過氧化鈉溶入及混合於水内; (c) 將〇·〇與〇·5公克之間之氧化鈉溶入及混合於步驟(^之 溶液内; (d) 將〇·〇與〇·5公克之間之氧化皱溶入及混合於步驟(c)之 落液内; (e) 將〇 ·3與2 ·0公克之間之重絡酸金屬溶入及混合於步驟 -12- 本紙張尺度適用中國國家榡準(CNS ) A4規格(210X 297公釐) 1225766 A7 B7 輕濟部中夬榡準局員工消費合作杜印製 五、發明説明(1〇 ) (d)之溶液内,例如重絡酸鋁或較佳爲重絡酸鐵; (f) 將0.0與3.5公克之間之重鉻酸鈣溶入及混合於步驟(e) 之溶液内;及 (g) 將1.0與3 _0公克之間之氧化硼溶入及混合於步驟⑴之 ;谷液内,以製成第一層溶液。 步驟(a)至(g)較佳爲依上列順序、在〇。〇與3〇°C之間且較 佳爲5°C與·8Χ:之溫度、及相對濕度不大於4〇%狀態下進行。 ’’』、、加氧化皱及重絡故金屬之步驟可以倒置,以利於添加氧 化鈹之別先添加重路故金屬於第一層溶液,而不造成負面 效果。當介質6含有三氧二錳、氧化铑或氧化鐳時,過氧化 鈉或氧化鈉即可省略,但是介質6之生成熱轉移效率將降低 ,且介質6之壽命將減少大約丨年。對於第一層溶液之其餘 成分及上述例外,各成分應該以上列順序添加,若第一層 ’谷液之成分並非依上列順序組合,則溶液會變得不穩定及 造成一激變反應。 在製造第二層22所用溶液及收集第三層24所用化合物之 前,鍺及碳酸鐳先經歷一變性過程。欲變性1〇〇公克之铑粉 ,則在一容器内將2公克之純鉛粉混合於鍺粉,接著將裝有 铑粉及鉛粉之容器置入850。(:至9〇〇。(:之烤箱内至少4小時, 以形成氧化鍺,隨後將氧化铑分離於鉛。欲變性1〇〇公克之 灭酸鎘粕,則在一客器内將丨丨公克之純鉛粉混合於碳酸 鐳粉,接著將裝有碳酸鐳粉及鉛粉之容器置入75〇。〇至 800。。之烤箱内至少8小時,以形成氧化鐳。實驗期間, 11 m 1 - I - I n f} ϋ— - j '—— ---------- 、τ (請先聞讀背面之注意事項再填寫本頁) 鉑合係用於戈性過程,構成容器之材料應該相關於 • 13 -U.S. Patent No. 5,5,42,471 to Dickinson discloses a heat transfer element with heat transfer fibers, which does not require a heat transfer fluid. This device has longitudinal heat transfer fibers extending between two substances, and the heat transfer is between two Increase heat transfer between substances. The fiber is composed of graphite fibers in epoxy resin-based graphite fibers, and is composed of an organic matrix composition having graphite fibers in an organic resin matrix, graphite fibers in an aluminum matrix, graphite fibers in a copper matrix, or the like. The matrix composition is cured. In my Chinese patent No. 8910852 1.1, an inorganic medium heat conduction device is disclosed. This heat conduction device greatly improves the heat conduction capacity of the material. Experiments have shown that the device can transfer heat along a closed metal shell containing a partial hollow, and 5,000 per second The speed of meters. A three-step application is applied on the inner wall of the casing.-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 1225766 A7 B7 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. Note (4) In addition, the coating has an ideal total thickness of 0.012 to 0.013 mm, and the total weight of the coating includes 1.25% total, 1.38% wrinkle, and 1.95% nano. This heat-conducting device contains no heat-generating powder and does not transfer heat or prevent heat loss to the atmosphere in a superconducting manner. SUMMARY OF THE INVENTION The present invention provides an excellent heat transfer device to assist the CPU cooling. This model, 'and including a classic superconducting combination' does not require a fan-although we can still use it, thus increasing heat radiation and system stability , And can reduce noise and vibration more than previous modules using fans. Another object of the present invention is to provide a method for manufacturing a CPU heat transfer device, which transfers the heat of a heat source from one point to another point without any actual heat loss. Another object of the present invention is to provide a heat sink, which uses a superconducting heat transfer medium to quickly and efficiently generate heat from a CPU to dissipate heat. The present invention achieves the above and other objectives and overcomes the shortcomings of the prior art by providing a superconducting heat transfer device for a laptop computer CPU, which is inexpensive to manufacture, simple to design and use, and convenient to use. In one embodiment of the present invention, the device contains four components: a hollow heat transfer module, which is installed near a CPU of a computer; a hollow hot plate, which is exposed to the atmosphere outside the computer or installed near an external wall of the computer; A hollow flexible tube connects the heat transfer pad to the heat plate; and a superconducting heat transfer medium is coated on the inner surface of the heat pad, the flexible tube, and the heat transfer plate. The medium is applied to the surface with three basic layers. This method is shown in detail in US Patent No. 6,13,832 issued on October 17, 2000, "Superconducting Thermal Transfer. This paper applies Chinese National Standard (CNS) A4 specifications." (210X 297mm) IIII nn I n II 1 (谙 Please read the precautions on the back before filling this page) 17 1225766 Α7 Β7 V. Description of the Invention (5) Medium ", the first two layers are exposed Prepare solution on the inner wall of the catheter. Initially, a first layer consisting mainly of various combinations of sodium, beryllium ion types, a metal such as manganese or aluminum, calcium, boron, and dichromate was absorbed into the inner wall of the catheter to a depth of approximately 0.008 to 0.012 mm. Subsequently, a second layer system consisting mainly of cobalt, manganese, wrinkles, gills, germanium, copper, /? · Titanium, potassium, boron, and calcium ions, and a metal such as aluminum and dichromate was established on the first layer. On the top, a film with a thickness of 0.008 to 0.012 mm is actually formed on the inner wall of the catheter. The last 'second layer is powder' contains rhodium oxide, potassium dichromate, radium oxide, sodium bicrotate, silver dichromate, beryllium oxide, gill chromate, boron tritide, titanium, and a metal dichromate, such as Manganese dichromate or aluminum dichromate are evenly distributed on the inner wall. These three layers can be applied to a conduit and then thermally polarized to make a superconducting heat transfer device that can transfer heat without any net heat loss, or can be applied to a pair of plates with small holes relative to a large surface area, To make a heat sink that can immediately dissipate heat from a heat source. It can be understood that the grammar and terminology used in the text are only for description and not limitation. Therefore, those skilled in the art can understand that the concepts based on this article can be used in the design of other structures, methods and systems to implement the invention. Printed by many consumer cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs-(read the note on the back of Min Min, and then fill out this page) Purpose 'Therefore, it is important that the statements containing this equivalent structure do not depart from the present invention Spiritual category. Other objects, advantages and capabilities of the present invention will be apparent from the following description, together with the accompanying drawings that disclose preferred embodiments of the present invention. Brief description of the drawings The invention will be easy to understand and the above and other objects will be known from the following detailed description with reference to the accompanying drawings, of which: This paper size is applicable to the Chinese National Standard (CNS) 8-4 specification (21〇χ 297 mm) 1225766 A7 B7 V. Description of the invention (6) Figure 1 is a perspective view of a superconducting heat transfer device of the present invention; Figure 2 is a sectional view of the device of Figure 1; Figure 3 is a perspective view of a plug used in the device of Figure 1; Figure 4 Figure 5 is a perspective view of a heat sink of the present invention; Figure 5 is a side view of the heat sink of Figure 4; Figure 6 is a cross-sectional view of the heat sink of Figure 4; Figure 7 is an example test device for testing a superconducting heat transfer device; Figure 8 Fig. 9 is the data of the test No. 1 result of the preferred embodiment of the present invention; Fig. 9 is the data of the test v0 · 2 result of the preferred embodiment of the present invention; Fig. 10 is the data of the v0 · 3 result of the test of the preferred embodiment of the present invention; And FIG. 11 is the data of the test No. 4 result of the preferred embodiment of the present invention. Figure 12 shows an example CPU cooling system. „The preferred embodiment is described in detail below. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs ---------- t-shirt-- (Please read the precautions on the back before filling out this page) Order as To facilitate understanding of the nature and necessary purpose of the present invention, you should refer to the detailed description together with the matching drawings, please refer to the drawings, where the same reference number refers to the corresponding component, first refer to Figure 丨, 2 The transfer device 2 includes a carrier, such as a catheter 4 containing a superconducting heat transfer medium 6, and the medium can be placed in a hole 8 of the catheter 4, regardless of the material constituting the catheter 4. Although the catheter 4 in FIG. 1 is a tube Shape, but the present invention should cover a variety of Xing shape and size of the duct. The medium 6 carrying duct 4 has improved heat transfer capacity without any subsequent heat loss. If it is properly applied in the duct 4, the medium 6 is actually It can be thermally catalyzed and itself becomes a heat generator. The medium 6 is activated at about 38 C and can be operated to a maximum temperature. 73. The tube is not completely specific, but it is believed that the heat generating capacity of the medium 6 is directly Related to 介 -9- 1225766 Production Cooperation of Employees of the Central Bureau of Standards, Ministry of Economic Affairs, Du printed A7 B7 V. Description of the invention (7) After the activation of the shell 6 < mass loss, because the medium 6 can transfer heat from a heat source (not shown) immediately through the duct 4, The conduit 4 can be exposed and operated in an environment that has a source temperature and far exceeds the melting temperature of the untreated material constituting the conduit 4. Therefore, it is believed that during the initial stage of the activation of the medium 6, the medium 6 is internally heated As a result, the medium 6 can immediately absorb the available heat from the heat source, and then the heat will be transferred throughout the duct 4. If the volume of the cavity 8 is relatively small relative to the area of the outer surface 10 of the duct 4, as shown in Figs. 4 to 6, The medium 6 absorbs heat to provide a heat sink 12 and immediately removes heat from the heat generation source. Thermal radiation is directly related to thermal energy, heat transfer rate, and heat conductivity. In other words, this determines the heat volume (amount) which can be in each unit volume The speed (rate) of internal transfer. If the catheter 4 or the carrier is associated with a large outer surface area of 10 and has a small hole, the carrier is better able to distribute heat to the outer surface 10. The temperature at the source of heat generation is not In applications over 38 ° C, that is, the temperature at which the medium 6 is activated, the heat is immediately absorbed and diffused by the medium 6, while in applications where the heat generation source exceeds 38r, the heat sink 12 still has high efficiency, because the medium 6 can quickly The heat is transferred to the outer surface 14 of the heat sink, and is efficiently diffused to the atmosphere by heat radiation. The medium 6 is applied in at least three basic layers, the first two layers are prepared from a solution, and each solution is sequentially exposed to an inner tube Surface 16 or an inner radiator surface 18. At first, the first layer 20 is absorbed into the inner duct surface 16 or the radiator surface 18, then the second layer 22 is established on the top surface of the first layer 20, and a film is actually formed on The inner duct surface 16 or the radiator surface 18. Finally, the third layer 24 is a powder and is evenly distributed on the inner duct surface 16 or the radiator surface 18. Although the discussion of the medium 6 is based on the catheter 4 as the reference, the medium 6 is applied to the radiator 12 -10. The Chinese standard (CNS) A4 specification (210 > < 297 Gongchu) for the flared scale applies --- ---- n I-mm II 1 person ^ ..... I---——II D (Please read the precautions on the back before filling out this page) 1225766 V. Description of the invention (the situation is the same) The first layer 20 is a kind of anti-corrosion, and theoretically results in the second conduit: Γ, the surface of the tube 16 absorbs heat u2 (m to reload, so it is easy to use) " The function is to prevent the inner conduit surface 16 from generating oxides, such as When exposed to a water knife in the air, the iron metal is susceptible to oxidation, and the internal energy will cause the decay of excess water. As a result, the heat load will increase when the heat transfer occurs: The thermal energy stored in 4 is Λ. 1 When this W is generated, the life of medium 6 will be shortened. The second layer 22, the active layer, can prevent the generation of hydrogen and oxygen elements, and the oxidation is limited to oxygen atoms and the tube 4 (carrier) Between materials. At the same time, the second layer 22 can conduct heat through the surface of the inner conduit, like electricity is conducted along the line It has been found through experiments that heat can be conducted at a rate of 15, 米 m per second by the medium ⑽. The second layer 22 also helps to accelerate the friction between the molecular ㈣ and the third layer 24 to provide a heat transfer path for heat conduction. The consumer cooperation of the Central Bureau of Standards of the Ministry of Economic Affairs for the production of Du-printed layer 24 can be called "black powder," because of its color and appearance. It is believed that when the medium 6 is exposed to the minimum activation temperature, the third layer will immediately Heat is generated, and once the medium 6 is activated, the atoms in contact with the first layer 20 and the second layer "third layer M" begin to oscillate. As the heat source temperature rises, it is believed that the oscillation frequency will also increase. When it reaches 20 ° C, the oscillation frequency is 23 million times per second, and when the activation temperature is higher than 350T, the frequency may even reach 28 million times per second. In theory, the higher the activation temperature, the more the oscillation frequency High, so you can feel the higher the performance efficiency of the catheter when the load is higher. During the heat transfer process, there is neither phase transition nor mass transfer of medium 6. Experiments have shown that a steel guide 4 containing medium 6 has a Thermal conductivity higher than that of silver -11-This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 1225766 A7 B7__ · __ V. Description of the invention (9) " The rate is about 20,000 times, and it can reach 1 in the laboratory environment. The thermal conductivity is about 30,000 times the thermal conductivity of silver. During use, the medium 6 will lose mass with the use after activation (the loss caused by the volume conversion), so the medium 6 has a Long but limited use of life. Tests have shown that after continuous use of u, 000 hours, the frequency of the vibration of the medium 6 and i is still the same as the initial activation, but continuous use of 120,00 hours. After that time, the amount (mass) of the medium 6 began to decrease at a rate of about 050/0 every 32 hours, and the molecular vibration frequency was significantly reduced by about 6%. After about 123,200 hours of continuous use, the medium 6 becomes ineffective. It is believed that the aging is mainly caused by the loss of the third layer 24 or the conversion of the amount of energy. It is expected that reducing the operating temperature can slow down the loss of the third layer 24 . The first layer 20 and the second layer 22 have been determined to use 0 at a rate of approximately 0.001 millimeters per 10,000 hours of use. To prepare the first layer 20, a first layer solution is made and then Applied to the surface of the inner catheter 16, a representative first layer solution is made by the following steps, preferably in the following order: 0) Put 100 ml of distilled water into an inert container, such as broken glass or Pottery is preferred; printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs n —ϋ ϋϋ UK—-I ml 1 ^ 1 m I ni HI ϋϋ--I— nn-" J (谙 Please read the notes on the back first (Fill in this page again) (b) Dissolve and mix sodium peroxide between 2.0 and 5.0 grams in water; (c) Dissolve and mix sodium oxide between 0.0 and 0.5 grams in step (In the solution of (^); (d) dissolve and mix the oxidized wrinkles between 0.0 and 0.5 g in the liquid of step (c); (e) dissolve 0.3 and 2.0 g The complex acid metal is mixed and mixed in step -12- This paper size is applicable to China National Standard (CNS) A4 (210X 297 mm) 1225766 A7 B7 Qingji Printed by the Consumers' Cooperative Bureau of the State Council. 5. Printed in the solution of the invention (10) (d), such as aluminum complexate or iron complexate. (F) Between 0.0 and 3.5 grams. Calcium dichromate is dissolved and mixed in the solution of step (e); and (g) boron oxide between 1.0 and 3 _0 g is dissolved and mixed in step ⑴; A layer of solution. Steps (a) to (g) are preferably in the order listed above, between 0.0 ° and 30 ° C, and preferably 5 ° C and · 8 ×: and the relative humidity is not greater than It is carried out at 40%. "", The steps of adding oxidized wrinkles and rewinding the metal can be reversed, which is beneficial for adding the beryllium oxide before adding the heavy metal in the first layer solution without causing negative effects. When the medium 6 contains manganese trioxide, rhodium oxide, or radium oxide, sodium peroxide or sodium oxide can be omitted, but the heat transfer efficiency of the medium 6 will be reduced, and the life of the medium 6 will be reduced by about 丨 years. The remaining components of a layer of solution and the above exceptions, each component should be added in the order listed above. The combination of the above sequence will make the solution unstable and cause a radical reaction. Before manufacturing the solution used in the second layer 22 and collecting the compounds used in the third layer 24, germanium and radium carbonate undergo a denaturation process. 〇g of rhodium powder, 2 grams of pure lead powder is mixed with germanium powder in a container, and then the container containing rhodium powder and lead powder is placed in 850. (: to 900.) (in the oven At least 4 hours to form germanium oxide, and then separate the rhodium oxide from lead. To denature 100 grams of cadmium acetic acid meal, mix 丨 丨 grams of pure lead powder with radium carbonate powder in a passenger vessel, and then Place the container containing radium carbonate powder and lead powder into 75 °. 〇 to 800. . In an oven for at least 8 hours to form radium oxide. During the experiment, 11 m 1-I-I nf} ϋ—-j '—— ---------- 、 τ (please read the notes on the back before filling this page) Platinum system is used for The temperamental process and the materials that make up the container should be related to • 13-

1225766 A7 _______B7 五、發明説明(11 ) 姥、氧化姥、碳酸鐳、氧化鐳及鉛而呈惰性。用於變性 過程中之錯較佳爲9 9 · 9 °/。純度,且可再生供後續之相似變 性過程使用。介質6利用一 PDM個人放射量測定器之靜態 及動悲後續測試並未於背景輻射上生成任意可偵測之輻 射性放射。 钦之一同位素係用於介質6中,在某些國家該同位素稱爲 B型鈥’而在美國則該同位素稱爲々_鈇。 第一層22係由施加於第一層2〇上方内導管表面16之溶液 衍生,相似於第一層溶液的是一代表性之第二層溶液係由 以下步驟製成,較佳爲依以下順序進行: (a) 將100毫升二次蒸餾之水置入一惰性容器内,例如玻璃 或較佳爲陶器; (b) 將0.2與0.5公克之間之氧化鈷溶入及混合於二次蒸館 之水内; (c) 將0·0與〇·5公克之間之三氧二錳溶入及混合於步驟(b) 之溶液内; (d) 將〇·〇與0.01公克之間之氧化鈹溶入及混合於步驟(〇之 溶液内; 經濟部中央標準局員工消費合作衽印製 . 4衣------1T (讀先閲讀背面之注意事項再填寫本頁) (e) 將〇·〇與〇·5公克之間之絡酸鳃溶入及混合於步驟(❼之 溶液内; (f) 將0·0與〇·5公克之間之碳酸鳃溶入及混合於步驟之 落液内; (g) 將0,0與0.2公克之間之氧化鍺溶入及混合於步驟⑴之 溶液内; -14- 本紙張尺度適用中關家標準((^)八4彡見格(21()/297公楚) ·〜--- 1225766 A7 _____B7 五、發明説明(12 ) (h)將0·0與〇·8公克之間之氧化銅溶入及混合於步驟(g)之 溶液内; . (1)將0.0與〇·6公克之間之鈦溶入及混合於步驟(h)之溶 液内; (j) 將1.0與1.2公克之間之重鉻酸鉀溶入及混合於步驟⑴之 溶液内; (k) 將0·.0與ι·〇公克之間之氧化硼溶入及混合於步驟⑴之 溶液内; (l) 將0.0與1.0公克之間之重鉻酸鈣溶入及混合於步驟(k) 之溶液内;及 (m) 將0·0與2.0公克之間之重鉻酸鋁溶入及混合於步驟⑴ 之溶液内,或較佳爲重鉻酸鎂,以製成第二層溶液。 經濟部中央標準局員工消費合作社印製 n n n I— n n m n I I n n m -I n T VT 、T (請先閱讀背面之注意事項再填寫本頁) 一次备餘之水較佳爲具有趨近於0之導電率,導電率越高 則干擾到介質6之靜電及造成熱傳導效率降低等問題越大。 步驟(a)至(m)較佳在〇。(:與30X:之間及相對濕度不大於4〇%狀 態下進行。當介質6含有氧化鍺或氧化鐳時,三氧二錳之量 可減少或省略,惟,介質6之壽命將減少,且熱傳導效率減 少大約0.2%。通常0 _鈦可在上列任意步驟中添加於第二層 溶液内,例外的是其不應該在步驟(b)添加於二次蒸餾之水 中’或做爲落液之最後成分,在步驟添加/^鈦或做爲溶 液之最後成分會造成第二層溶液不穩定。添加三氧二錳及 氧化鈹艾步驟可以倒置,以利氧化皱在添加三氧二錳之前 先添加於第二層溶液内。同樣,添加重鉻酸鉀及重鉻酸鈣 之步驟可以倒置,以利重鉻酸鈣在添加重鉻酸鉀之前先添 -15- 本纸張尺度適用中國國冬樣準(CNS ) A4規格(210X 297公楚) ~" 1225766 A7 B7 五、發明説明(13 ) 加於第二層溶液内。若第二層溶液之成分未依上列順序及 例外情形組合,則溶液會變得不穩定'及造成一激變反應。 製備第三層24之前,矽先以磁性貫穿而做處理,具有 99.999%理想純度之單晶矽粉係置入一非磁性之容器中且放 入一磁性共振器内至少3 7分鐘,較佳爲4 0至4 5分鐘,實驗 期間使用之磁性共振器爲一 0.5仟瓦、220伏及50赫茲之磁 性共振器·。若所用之矽具有低於99.999%之純度,則第三層 24中所需之矽量即增加,磁性共振器係用於增加矽之原子 電子層,由此增加介質6導熱之速度。 一代表性之弟二層2 4粉末係由以下步驟製成,較佳爲依 以下順序進行: (a) 將0·0與1.75公克之間之變性氧化铑置入一惰性容器内 ,例如玻璃或較佳爲陶器; (b) 將0.3與2.6公克之間之重鉻酸鈉混合於氧化鍺; ‘(c)將0.0與0_8公克之間之重鉻酸鉀混合於步驟(b)之混合 物; (d) 將0.0與3.1公克之間之變性氧化鐳混合於步驟(c)之混 合物; 經濟部中央標準局員工消費合作社印製 ; ^批衣 訂 (請先閲讀背面之注意事項再填寫本頁) (e) 將0.1與0.4公克之間之重鉻酸銀混合於步驟(d)之混合 物; (f) 將0.2與0.9公克之間之磁性貫穿處理之單晶矽混合於步 驟(e)之混合物; (g) 將0.0與0.01公克之間之氧化皱混合於步驟(f)之混合 物; -16- 本紙張尺度適用中國國家標準(CNS ) A4規格(210X 297公釐) 經濟部中央標準局員工消費合作社印製 1225766 A7 B7 ____ 五、發明説明(14 ) (h) 將0·〇與0.1公克之間之鉻酸鳃混合於步驟(g)之混合 物; , (i) 將0·0與Ο·!公克之間之氧化硼混合於步驟(h)之混合 物; (j) 將0.0與〇· 1公克之間之過氧化鈉混合於步驟⑴之混合 物; (k) 將〇·〇與1.25公克之間之鈦混合於步驟⑴之混合物; 及 (l) 將0.0與〇·2公克之間之重鉻酸鋁或較佳爲重鉻酸鎂混合 於步驟(k)之混合物,以製成第三層粉末。 第三層24粉末較佳爲在大約25 X:以下溫度混合,藉由低 溫混合則可改善介質6之熱傳導效率,此外,相對濕度應在 40〇/。以下,且相對濕度最好在3〇%與35%之間。通常氧化鐳 與/9 -鈦可在上列任意步驟中添加於第三層24粉末内,例外 的是其不應該添加做爲最初或最後成分,添加氧化錯或々_ 鈦做爲最初或最後之粉末成分會使介質6變得不穩定及造成 一激變反應。添加重鉻酸鉀及重鉻酸銀之步驟可以倒置, 以利重絡酸銀在添加重絡酸钾之前先恭加於第三層2 4粉末 。同樣,添加鉻酸鳃及氧化皱之步驟可以倒置,以利氧化 皱在添加絡酸鳃之前先添加於第三層24粉末。若第^:芦24 粉末之成分未依上列順序及例外情形組合,則介質6會變得 不穩定及造成一激變反應。 第三層24粉末可以貯存以延長時間周期,爲了防止光、線 與濕度所致之惡化,第三層24粉末應貯存於由惰性材料且 -17- 本紙張尺度適用中國國家標準(CNS ) A4規格(210χ297公釐) ---_- (請先閱讀背面之注意事項再填寫本頁) 裝- 12257661225766 A7 _______B7 V. Description of the invention (11) Rhenium, thorium oxide, radium carbonate, radium oxide and lead are inert. The error used in the denaturation process is preferably 9 9 · 9 ° /. Pure and reproducible for subsequent similar modification processes. The subsequent static and dynamic testing of Medium 6 using a PDM personal dosimeter did not generate any detectable radiative radiation on the background radiation. Chin isotope is used in medium 6, in some countries this isotope is called type B 'and in the United States it is called 々_ 鈇. The first layer 22 is derived from the solution applied to the inner tube surface 16 above the first layer 20. Similar to the first layer solution is a representative second layer solution made by the following steps, preferably according to the following steps: Sequentially: (a) Place 100 ml of secondary distilled water in an inert container, such as glass or preferably pottery; (b) Dissolve and mix cobalt oxide between 0.2 and 0.5 g in secondary distillation In the water of the museum; (c) Dissolve and mix trioxane between 0.0 and 0.5 g in the solution in step (b); (d) Dissolve between 0.0 and 0.01 g Beryllium oxide is dissolved and mixed in the step (0 solution; printed by the consumer cooperation of the Central Bureau of Standards of the Ministry of Economic Affairs. 4 clothing ------ 1T (read the precautions on the back before filling in this page) (e ) Dissolve and mix the acid gills between 0. 0 and 0.5 g in the step (❼ solution; (f) dissolve and mix the gills between 0. 0 and 0.5 g in Step into the liquid; (g) Dissolve and mix germanium oxide between 0,0 and 0.2 grams in the solution of Step ⑴; -14- This paper size applies the Zhongguanjia standard ((^)彡 4 彡 格 (21 () / 297 公 楚) · ~ --- 1225766 A7 _____B7 V. Description of the Invention (12) (h) Dissolve and mix copper oxide between 0 · 0 and 0.8g In the solution in step (g);. (1) dissolving and mixing titanium between 0.0 and 0.6 g in the solution in step (h); (j) adding chromium between 1.0 and 1.2 g Potassium acid is dissolved and mixed in the solution of step (i); (k) Boron oxide between 0 · 0 and ι · 0 g is dissolved and mixed in the solution of step (i); (l) 0.0 and 1.0 g Calcium dichromate is dissolved in and mixed in the solution in step (k); and (m) aluminum dichromate between 0.0 and 2.0 g is dissolved and mixed in the solution in step ⑴, or Magnesium dichromate is preferred to make a second layer solution. Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs nnn I— nnmn II nnm -I n T VT, T (Please read the precautions on the back before filling in this (Page) It is preferred that the water that has been prepared at one time has a conductivity close to 0, and the higher the conductivity, the greater the problems that interfere with the static electricity of the medium 6 and cause a decrease in heat conduction efficiency. Steps (a) to (m) are better In 〇 (: And 30X: between and relative humidity is not greater than 40%. When the medium 6 contains germanium oxide or radium oxide, the amount of trioxane can be reduced or omitted, but the life of the medium 6 will be reduced, And the heat conduction efficiency is reduced by about 0.2%. Usually 0 _ titanium can be added to the second layer solution in any of the steps listed above, except that it should not be added to the water of secondary distillation in step (b) 'or as a drop. The last component of the solution, adding titanium in the step or as the last component of the solution will cause the second layer of solution to be unstable. The steps of adding manganese trioxide and beryllium oxide can be inverted to facilitate the oxidation of wrinkles in the second solution before adding manganese trioxide. Similarly, the steps of adding potassium dichromate and calcium dichromate can be reversed, so that calcium dichromate can be added before adding potassium dichromate. -15- This paper size applies to China National Winter Standard (CNS) A4. (210X 297 Gongchu) ~ " 1225766 A7 B7 V. Description of the invention (13) Add to the second layer of solution. If the components of the second layer of the solution are not combined in the order listed above and exceptions, the solution will become unstable 'and cause a radical reaction. Before the third layer 24 is prepared, the silicon is processed by magnetic penetration. A single crystal silicon powder with an ideal purity of 99.999% is placed in a non-magnetic container and placed in a magnetic resonator for at least 37 minutes, preferably For 40 to 45 minutes, the magnetic resonator used during the experiment was a 0.5 仟, 220 volt, and 50 Hz magnetic resonator. If the silicon used has a purity of less than 99.999%, the amount of silicon required in the third layer 24 is increased, and the magnetic resonator is used to increase the atomic electronic layer of silicon, thereby increasing the speed of heat conduction of the medium 6. A representative two-layer 24 powder is made by the following steps, preferably in the following order: (a) Put a denatured rhodium oxide between 0 · 0 and 1.75 grams in an inert container, such as glass Or preferably pottery; (b) mixing sodium dichromate between 0.3 and 2.6 grams in germanium oxide; '(c) mixing potassium dichromate between 0.0 and 0-8 grams in the mixture in step (b) (D) Blend denatured radium oxide between 0.0 and 3.1 g with the mixture in step (c); Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs; ^ Order for clothing (please read the precautions on the back before filling in this Page) (e) Blend silver dichromate between 0.1 and 0.4 g in the mixture in step (d); (f) Blend single crystal silicon with magnetic penetration treatment between 0.2 and 0.9 g in step (e) (G) Blend oxidized wrinkles between 0.0 and 0.01 g with the mixture in step (f); -16- This paper size applies the Chinese National Standard (CNS) A4 (210X 297 mm) Central Standard of the Ministry of Economic Affairs Printed by the Bureau's Consumer Cooperatives 1225766 A7 B7 ____ V. Description of Invention (14) (h) will be 0 · 〇 Mixed with 0.1 g of chromic gills in the mixture of step (g);, (i) mixed boron oxide between 0 · 0 and 0 ·! G in the mixture of step (h); (j) 0.0 Mixed with 0.1 g of sodium peroxide in the mixture in step (i); (k) mixed between 0.0 and 1.25 g of titanium in the mixture in step (i); and (l) 0.0 and 0.2 g Aluminium dichromate or preferably magnesium dichromate is mixed with the mixture in step (k) to make a third layer of powder. The third layer 24 powder is preferably mixed at a temperature of about 25 X or less. The heat conduction efficiency of the medium 6 can be improved by mixing at a low temperature. In addition, the relative humidity should be 40 ° /. Below, and the relative humidity is preferably between 30% and 35%. Usually radium oxide and / 9-titanium can be added to the third layer 24 powder in any of the steps listed above. The exception is that it should not be added as the initial or final component, and oxide or titanium is added as the first or last. The powder composition makes the medium 6 unstable and causes a radical reaction. The steps of adding potassium dichromate and silver dichromate can be reversed, so that silver double complex acid is added to the third layer of 2 4 powder before adding potassium double complex acid. Similarly, the steps of adding chromate gills and oxidized wrinkles can be reversed, so that the oxidized wrinkles are added to the third layer 24 powder before adding the acid gills. If the components of No. ^: lu 24 powder are not combined in the order and exceptions listed above, the medium 6 will become unstable and cause a radical reaction. The third layer of 24 powder can be stored for an extended period of time. In order to prevent deterioration caused by light, line and humidity, the third layer of 24 powder should be stored in an inert material and -17- This paper size applies to Chinese National Standard (CNS) A4 Specifications (210x297 mm) ---_- (Please read the precautions on the back before filling in this page) Pack-1225766

發明説明(15 ) 經濟部中央標準局員工消費合作社印製 較佳爲玻,製成之暗色密料器貯存,―渴氣吸收材科亦 可放入聍器内,只要濕氣吸收材料係惰性於且不混合於第 三層2 4粉末即可。 、 :旦製備第一層20及第二層22溶液與第三層24粉末,超 傳導熱轉移裝置2即可製成。導管4可爲多種金屬或非金屬 材料之一者,且無論如何皆應具有極微之氧化於内導管表 面16上,較佳爲無氧化。建議導管4應清潔、乾燥及盔任音 氧化物或氧基鹽,特別是導管4係由金屬製成時,此可藉: 噴沙、弱酸清洗 '或弱基質清洗等習知處理達成。用於清 潔及處理導管4之任意材料應完全去除,且内導管表面咐 應在添加介質6至導管4前先乾燥。此外,導管4之壁厚應選 擇以考量每年至少O.i毫米之磨損率,此磨損係由第三層Μ 之分子振盪所致。以鋼而言,壁厚應至少3毫米,而較軟材 料顯然需較厚。導管4可相當地加長,事實上,經發現導管 4之性能效率係隨著長度而增加。. 一代表性之超傳導熱轉移裝置2係由以下步驟製成: (a) 將第一層溶液置入一第一層溶液容器内; (b) 將具有孔穴8之導管4浸入第一層溶液内,使第一層溶 液%入孔穴8,導管4較佳爲非水平設置,且以底端26朝下 置入第一層溶液内,·溫度爲〇tS3(rC之間且時間至少8小 時’使第一層溶液可以穿過導管4之壁面至0.008與〇〇12毫 米之間深度; (c) 以周側狀態自然地乾燥導管4,以形成第一層2〇於孔穴 8内; -18- 本紙張尺度適财國國家標準(CNS )八4規格(210X29^^7 ^------1T (請先閔讀背面之注意事碩再填寫本頁) 1225766 A7 B7 五、發明説明(π ) (d) 將第二層溶液置入一第二層溶液容器内; (e) 將具有第一層20之導管4浸入第二層溶液内,使第二層 溶液填入孔穴8,導管4較佳爲非水平設置,且以底端26朝 下置入第二層溶液内,溫度爲55°C至65°C之間,較佳爲6(rc ’且時間至少4小時; (f) 以周側狀態自然地乾燥導管4,以利於孔穴8内形成一 具有0.008·與0.012毫米之間厚度之第二層22 ; (g) 利用一精確熔接技術將一端蓋28熔接至相對立於底 端26之導管4末端,較佳爲在氦或氬氣中進行螺旋電弧熔 接; (h) 較佳係利用步驟(g)之方法在底端26熔接一具有一孔32 之注入帽蓋30,注入帽蓋具有2.4與3 ·5毫米之間之直徑,較 佳爲3.0毫米; (i) 將底端26加熱至一不超過120°C之溫度,較佳爲4〇°C ; (j) 將第三層24粉末以每4〇0,000立方米孔穴8體積至少1立 方米之量注入孔32内; (k) 將栓塞34插入孔32内,栓塞較佳爲實心之錐形,如圖 3所示; 經濟部中央標隼局員工消費合作社印製 穿-- (讀先閱讀背面之注意事項再填寫本頁) ⑴加熱底端26至80°C與125°C之間; (m)自孔3 2去除栓塞3 4且不超過3秒,較佳爲2秒,隨後將 栓塞34插入孔32内;及 (η)封合栓塞34於孔32内,較佳爲利用步驟(g)之方法,以 形成超傳導熱轉移裝置2。 若步驟⑴中之底端26溫度超過60°C,則在第三層24粉末 -19- 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) /66 Α7 Β7 五 輕濟部中央榡準局員工消費合作社印製 發明説明(17 ) 注入孔穴8之前’底端26應先降溫至至少机。在此步驟之 後,底端26變成熱極性化,易言之,底端26呈極性化以自 熱源接收熱’及將熱轉移出底端2 6。 步驟⑽中自孔32去除栓塞34之目的在自導管4之孔穴^ 釋出芝氣及水分子,當去哈於愛 除柽基34時可看見藍色氣體逸離 孔32。惟,若检塞34插人孔32之前即μ見藍色氣體逸離 孔32’表示第三層⑽末已逸至大氣,且步驟⑴至㈣需重 覆。若步驟⑴可在部分眞空下於—無濕氣環境中完成,步 驟⑴至(m)即可省略,但是吾人不做此建議。 一氧一錳氧化鍺、及氧化鐳並不需要於介質6之所有應 用中,當超傳導熱轉移裝置2曝露於高壓蒸汽環境中且導管 4係由高碳鋼製成時,此三成分才用於介質6中。在此特殊 例子中’高壓係定義爲〇.92百萬帕斯卡以上。當超傳導熱 轉移裝置2並非用於高壓蒸汽環境中,三氧二錳、氧化铑、 及氧化鐳即不需要且可自介質6中省略,即使導管4係由高 $鋼製成。此外,當三氧二錳、氧化铑、及氧化鐳係自介 質6中省略時,第三層24粉末應以每2〇〇,〇〇〇立方米孔穴^體 積至少1立方米第三層粉末之量提供。 如上所述,散熱器12使用超傳導熱轉移介質6,一代表性 之散熱器12係由以下步驟製成: (a) 將第一層溶液置入一第一層溶液容器内; (b) 將第一板36及第二板38浸入第一層溶液内,使第一層 溶液覆蓋第一板36及第二板38各者之至少—側,溫度爲〇。〇 至3 0 C之間且時間至少8小時,使第一層溶液可以穿過覆蓋 -20- 本紙張尺度適用中國國家標準(CNS ) A4規格(210 X 297公釐) I 111 n 1) 4衣 11 訂 (請先閲讀背面之注意事項再填寫本頁) 1225766 五、發明説明(18 側40至〇·〇08與〇 〇 12毫米之 毛木又間冰度,第一板36及第二板38且 有匹配緣42,且當第一妬〜n斤 ,、 且田弟板36及第二板38放在一起時,可相 關於第一板36及第二板38之表面積而形成-較小體積之孔 穴8,第-板36及第=板38至少—者具有—在24紅5毫米 之間之開孔4 4,較佳爲3 · 〇毫米; ⑷以周側狀態自然地乾燥一板刊及第二板38,以形成第 層20於$板36及第二板38之第一層覆蓋側上; ⑷將第:層溶液置人_第二層溶液容器内; (e)將第一板36及第二板38浸入第二層溶液内,使第二層 溶液接觸到第-層2〇,溫度爲饥至机之間,較佳爲^ ,且時間至少4小時; ,⑴以周側狀態自然地乾燥第一板36及第二板38,以利於 第一層20上形成一具有〇.〇〇8與〇〇12毫米之間厚度之第二層 22 ; (g) 利用一精確熔接技術將第一板36及第二板38沿著匹配 緣42熔接,較佳爲在氦或氬氣中進行螺旋電弧熔接,使第 一層覆蓋側40相互面對; 經濟部中央標準局員工消費合作社印製 I I I ϋ H —^衣 I I H 訂 (請先閲讀背面之注意事項再填寫本頁) (h) 4r第二層24粉末以每4〇〇,〇〇〇立方米孔穴體積至少1立 方米之量通過孔44以注入孔穴8内;及 (1)幸父佳爲利用步驟(g)之方法封合開孔44,以形成散熱器 12 〇 散熱器12可用相同於超傳導熱轉移裝置2之方法製成,亦 即散熱咨12可呈熱極性化,但是此並非必要。同樣地,用 於起傳導熱轉移裝置2及散熱器12製造中之溶接步驟可利用 -21 - 本紙張尺度適用中國國家標準(CNS)A4規格(210X 297公董) 五、發明説明(19 ) 膠水、黏著劑及/或環氧樹脂完成,較佳爲御 及環,脂。此外,所有溶接皆應進行至举管::端: 汪入帽盍30、第一板36或第二板38之厚 而现、 接後應實施一漏洩測試,例如氦眞空漏洩測試,衣度處’熔 構成超傳導熱轉移裝置2之導管4: 及柱塞34或散熱器12之第一㈣及第::38之=帽蓋3〇 彼此相容·,此可避免相關於不 f有材料應 收:問4與相關於陽極反應之腐姓問題,特別是材料破裂 。&疋〈材料亦應相容於及可承受於供超傳導 或散熱器12㈣之㈣環境,例如,若超料轉移裝= 係在一酸性環境中操作,則該材料 " 本發明可參考以下説明實例而瞭解,::上述説明,可 以瞭解的是針對本發明組件之最佳度量關係,包括尺寸㈣ 化、材料、形狀、型式、操作功能與方式、組裝及使用p 其應可爲習於此技者熟知,且説明書令所述及之所有 關係應由本發明涵蓋。 ’ ,當一冷源曝露於導管4之任—端時,超料熱轉移介質6 亦:傳導冷溫轉移,而當導管4以其—端接觸於_195。〇之液 體氮時,冷溫轉移即可成功轉移過導管。 以下實例説明第一層20、第二層22及第三層24之多種成 刀,且其已知可用於製備超傳導熱轉移裝置2或散熱器12, 諸成分較佳爲依上述之量及上述各別步驟之表列順序添加 至各層20、22、24。 實例1 1225766 A7 B7 五、發明説明(2〇 ) 針對製成第一層20,在100毫升之蒸餾水中添加5.0公克 過氧化鈉、0.5公克氧化納、2.0公克重鉻酸鎂或重鉻酸銘、 2·5公克重鉻酸鈣及3.0公克氧化硼。 針對製成第二層2 2 ’在1 〇 〇毫升二次蒸餘之水中添加〇. 5 公克氧化姑、0.5公克三氧二錳、〇.5公克碳酸鳃、〇.2公克 氧化雜、0.8公克氧化鋼、0.6公克/5-欽及1.2公克重絡酸钾 〇 針對製成第三層24,併合1·75公克氧化鍺、1.25公克f鈦 、3· 1公克氧化鐳、2.6公克重絡酸鈉、〇·4公克重絡酸銀及 〇.9公克單晶矽粉末。 實例2 針對製成第一層20,在1〇〇毫升之蒸餾水中添加5 〇公克 過氧化鈉、0.5公克氧化皱、2.0公克重絡酸鎮、2.0公克重 絡酸鈣及3.0公克氧化硼。 針對製成第一層2 2 ’在1 〇 〇毫升二次蒸館之水中添加〇 · 5 公克氧化姑、0.5公克鉻酸鳃、〇·8公克氧化銅、〇·6公克0 — 鈥及1·2公克重鉻酸鉀。 經濟部中央標準局員工消費合作社印製 裝-- (請先閲讀背面之注意事項再缜寫本頁) 針對製成第三層24,併合1.6公克重鉻酸鈉、〇 8公克重鉻 酸鉀、0.4公克重鉻酸銀及0.9公克單晶矽粉末。 實例3 針對製成第一層20,在1 〇〇毫升之蒸餾水中添加5 〇公克 過氧化鈉、0·5公克氧化鈹、2.0公克重鉻酸鎂、3.5公克重 鉻酸鈣及3.0公克氧化硼。 針對製成第二層22,在1〇〇毫升二次蒸餾之水中添加〇·5 -23- 本紙張尺度通用中國國家標準(CNS )八4^格(210Χ29?公釐) 1225766 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明(21) 公克氧化鈷、0.5公克鉻酸鳃、0.8公克氧化銅、0.6公克/5-敛及12公克重鉻酸鉀。 針對製成第三層24,併合1.6公克重鉻酸銅、〇.8公克重絡 酸卸、〇·6公克重鉻酸銀及0.9公克單晶矽粉末。 實例4 針對製成第一層2 0,在10 0毫升之蒸館水中添加2 · 0公克 過氧化鈉·、0.3公克氧化鈹、2.0公克重鉻酸鎂及1.〇公克氧 化硼。 針對製成第二層2 2,在10 0毫升二次蒸館之水中添加〇. 5 公克氧化鈷、0.5公克鉻酸鳃、0·4公克A-鈦及1.〇公克重鉻 酸卸。 針對製成第三層24,併合0.5公克重鉻酸鈉、〇.8公克重鉻 酸卸、0.1公克重鉻酸銀、〇·3公克單晶矽粉末、〇.〇1公克氧 化鈹、0.1公克鉻酸鳃、01公克氧化硼及〇1公克過氧化 納〇 實例5 針對製成第一層20,在100毫升之蒸餾水中添加2.0公克 過氧化鈉、0.3公克氧化鈹、2.0公克重鉻酸鎂及1 .〇公克氧 化硼。 針對製成第二層22,在100毫升二次蒸餾之水中添加〇.3 公克氧化鈷、0.3公克鉻酸鳃、1.0公克重鉻酸鉀及ι·〇公克 重鉻酸鈣。 針對製成第三層24,併合0.3公克重鉻酸鈉、〇· 1公克重鉻 fe:銀、〇. 8公克重絡酸_、〇. 2公克單晶碎粉末、〇 · 〇 1公克氧 -24- 本紙張尺度適用中國國家標準(CNS ) A4規格(210X 297公釐) (請先閔讀背面之注意事項再填寫本頁) Γ 1225766 經濟部中央標準局員工消費合作社印製 Α7 Β7 五、發明説明(22 ) 化鈹、〇. 1公克絡酸總、0.1公克氧化硼、〇 · 2公克/?-鈥及0 · 1 公克過氧化鈉。 實例6 針對製成第一層20,在1〇〇毫升之蒸餾水中添加2.0公克 過氧化鈉、0.3公克氧化鈹、I·0公克氧化硼及1.〇公克重鉻 酸鈣。 針對製成第二層22,在1〇〇毫升二次蒸餾之水中添加0·3 公克氧化姑、0.01公克氧化鈹、1·〇公克之二鉻化鉀、1.0公 克氧化硼及2.0公克重鉻酸鎂。 針對製成第三層24,併合0.3公克重鉻酸鈉、〇·1公克重鉻 酸銀、0.8公克重絡酸钟、0.2公克單晶碎粉末、0.1公克絡 酸鳃、0.01公克氧化鈹、0.1公克氧化硼、0.1公克過氧化鈉 、〇·2公克鈦及0.2公克重鉻酸鎂。 實例7 針對製成第一層20,在100毫升之蒸餾水中添加2.0公克 過氧化納、0.3公克重絡酸缓及1.0公克氧化爛。 針對製成第二層22,在100毫升二次蒸餾之水中添加〇.2 公克氧化姑、1.0公克重絡酸妈、1.0公克重絡酸钟、0.5公 克氧化硼、1.0公克重鉻酸鎂及0.01公克氧化鈹。 針對製成第三層24,併合0.3公克重鉻酸鈉、〇·〇5公克重 絡故銀、0.8公克重絡酸钟、0.2公克早晶秒粉末、0.1公克 鉻酸鳃、0.01公克氧化皱、〇· 1公克氧化硼、0.1公克過氧化 納、0.2公克鈥及0·2公克重路酸鍰。 實驗 •25- 本紙張尺度適用中國國家標準(CNS ) Α4規格(210X 297公釐)~ ' ' I - - - - - 1 11 ! — j ! mu (請先鬩讀背面之注意事項再填寫本頁) 1225766 A7 B7 經濟部中央標準局員工消費合作社印製 五、發明説明(23 ) 1·導論 f加數毫克適當量之無機熱超傳導介質之第三層24粉末 至官件,例如導管4,或平坦中層彳,例如板36、38,以產 、超傳導裝置2。例如’第三層24粉末添加入導管4之孔 产或板3 6 3 8之間,且在後續加熱以去除殘留水份及 氣後再封閉孔八6,义匕將產纟一熱超傳導裝置2。隨後之 測試結果証明第三層24爲-超傳導介質,且由第三層24製 成之熱傳導裝置係一熱超傳導之熱管。 事實上,一習知熱管共用一相似外形於一熱超傳導之熱 而^起一些誤解,因此,其對二者之差異性與相似性 需有一簡單説明。一習知熱管係使用在吸收大熱量時液體 蒸發而放熱時氣體冷卻之技術,以利將熱自管件之熱端攜 至冷端,熱管之軸向熱傳導速度依取決於液體蒸發熱之値 及液fljSL與氣體一種型式間之循環速度。熱管之軸向熱傳導 速度亦受限於載體材料之類型與量,以及熱管操作之溫度 與壓力(不能過高)·本熱超傳導熱轉移裝置2係由熱超傳導 介貝製成’其軸向熱傳導係在加熱及活化時藉由熱超傳導 介質之分子高速移動而達成,本熱超傳導熱轉移裝置2之熱 傳導速度遠大於任意金屬棒或任意相似尺寸對流熱管者, 而其内部壓力則遠低於相同溫度之任意對流熱管者。本熱 超傳導熱轉移裝置2之適用溫度上限係在導管4材料之容許 溫度上限以外。 本熱超傳導熱轉移裝置2若非在所有熱轉移領域可影響最 大,特別是在熱使用比,本熱超傳導熱轉移裝置2亦可用於 -26- 本紙張尺度適用中國國家標隼(CNS ) A4規格(210x297公釐) ---------装------1T (請先閱讀背面之注意事項再填寫本頁j 1225766 A7 B7 五、發明説明(24 ) 太陽能及地熱能之發展與使用中,及用於低能量熱之再 生。 , 2.測試方法與原理 金屬棒之熱傳導速度係取決於棒之熱傳導率、溫度梯度 及垂直於溫度梯度之截面積,金屬具有比非金屬高之熱傳 導率’而在金屬之中又以銀具有最高之大約41 5 w/mK熱傳 導率。 本熱起傳導熱轉私裝置2係一全新之發展,且無前例可舉 例説明及測試其性質,顯然使用其實際或相關熱傳導率與 軸向及徑向熱通量之測量做爲其性質說明方爲科學及合乎 邏輯。惟,此並不改變在熱超傳導裝置之熱傳導率測量方 法上無前例可用之事實。 用於測試本熱超傳導熱轉移裝置2之测試方法係採用一改 良之Forbes方法,其中一熱超傳導熱管做爲一半無限桿,假 定桿參考表面之溫度爲TQK,相距於參考表面達到χ米之二 截面之溫度爲ΤΚ,相鄰於桿表面且經過本身與桿之間熱對 流之流體(水)之溫度爲TtK,桿之熱傳導率爲kw/mK,表 之對流熱轉移係數爲h W/m2K,桿之周長爲p米,及桿之截 (请先閲讀背面之注意事項再填寫本頁) -裝 訂 經濟部中央標隼局員工消費合作社印製Description of the invention (15) The consumer cooperative of the Central Standards Bureau of the Ministry of Economic Affairs prints preferably glass, and makes a dark-colored dense container for storage. “The thirst-absorbing material can also be placed in the urn, as long as the moisture-absorbing material is inert It is not necessary to mix the powder in the third layer 24. : Once the first layer 20, the second layer 22 solution and the third layer 24 powder are prepared, the superconducting heat transfer device 2 can be made. The catheter 4 may be one of a variety of metallic or non-metallic materials, and in any case should have minimal oxidation on the inner catheter surface 16, preferably non-oxidized. It is suggested that the catheter 4 should be cleaned, dried, and helmeted. Any oxide or oxygen salt, especially when the catheter 4 is made of metal, this can be achieved by conventional treatments such as sandblasting, weak acid cleaning 'or weak substrate cleaning. Any material used to clean and handle the catheter 4 should be completely removed, and the surface of the inner catheter should be dried before adding the medium 6 to the catheter 4. In addition, the wall thickness of the catheter 4 should be selected to take into account a wear rate of at least 0.1 mm per year. This wear is caused by molecular oscillations in the third layer M. For steel, the wall thickness should be at least 3 mm, while softer materials obviously need to be thicker. The catheter 4 can be considerably lengthened. In fact, it has been found that the performance efficiency of the catheter 4 increases with length. A representative superconducting heat transfer device 2 is made by the following steps: (a) placing a first layer of solution into a first layer of a solution container; (b) immersing a conduit 4 having a cavity 8 into the first layer In the solution, let the first layer of solution enter the cavity 8, and the conduit 4 is preferably non-horizontal, and placed in the first layer of the solution with the bottom end 26 facing downward. The temperature is 0 tS3 (between rC and at least 8 hours). Hours' so that the first layer of solution can pass through the wall surface of the duct 4 to a depth between 0.008 and 012 mm; (c) The duct 4 is naturally dried in a peripheral state to form the first layer 20 in the cavity 8; -18- The size of this paper is suitable for National Standards (CNS) of the country of wealth (8) 4 specifications (210X29 ^^ 7 ^ ------ 1T (please read the cautions on the back before filling in this page) 1225766 A7 B7 V. Description of the invention (π) (d) Put the second layer of solution into a second layer of solution container; (e) Immerse the conduit 4 with the first layer 20 into the second layer of solution, so that the second layer of solution fills the cavity 8. The conduit 4 is preferably non-horizontal and is placed in the second layer of solution with the bottom end 26 facing downward. The temperature is between 55 ° C and 65 ° C, preferably 6 (rc 'and the time is at least 4 hours; (f) The duct 4 is naturally dried in a peripheral state, so that a second layer 22 having a thickness between 0.008 · and 0.012 millimeters is formed in the cavity 8; (g) One end is covered with a precision welding technique 28 Welding to the end of the duct 4 opposite to the bottom end 26, preferably spiral arc welding in helium or argon; (h) Preferably, the method of step (g) is used to weld on the bottom end 26 with a hole 32 The injection cap 30 has a diameter between 2.4 and 3.5 mm, preferably 3.0 mm; (i) The bottom end 26 is heated to a temperature not exceeding 120 ° C, preferably 4 °. ° C; (j) Inject the third layer of 24 powder into the hole 32 in an amount of at least 1 cubic meter per 8 volumes of 40,000 cubic meters of holes; (k) Insert the plug 34 into the hole 32, the plug is preferably solid Tapered, as shown in Figure 3; Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs-(Read the precautions on the back before filling out this page) ⑴Heating the bottom end of 26 to 80 ° C and 125 ° C (M) removing the plug 34 from the hole 32 and not exceeding 3 seconds, preferably 2 seconds, and then inserting the plug 34 into the hole 32; and (η) sealing the plug 34 to the hole 32 It is preferable to use the method of step (g) to form the superconducting heat transfer device 2. If the temperature of the bottom end 26 in step 超过 exceeds 60 ° C, then the powder 24 in the third layer is used. National Standard (CNS) A4 (210X297 mm) / 66 Α7 Β7 Printed by the Consumers ’Cooperative of the Central Government Bureau of the Ministry of Light Industry printed a description of the invention (17) Before the hole 8 is injected, the bottom end 26 should be cooled down to at least the machine. After this step, the bottom end 26 becomes thermally polarized. In other words, the bottom end 26 is polarized to receive heat from the heat source 'and transfer the heat out of the bottom end 26. The purpose of removing the embolism 34 from the hole 32 in step 在 is to release the gas and water molecules from the hole ^ of the catheter 4. When removing the base 34, the blue gas can be seen to escape from the hole 32. However, if the plug 34 sees a blue gas escape hole 32 'before it is inserted into the hole 32, it means that the third layer has escaped to the atmosphere, and steps ⑴ to ㈣ need to be repeated. If step ⑴ can be completed in a part of the air in a moisture-free environment, steps ⑴ to (m) can be omitted, but I do not make this recommendation. Monooxygen manganese germanium oxide and radium oxide are not required in all applications of medium 6. When the superconducting heat transfer device 2 is exposed to a high pressure steam environment and the duct 4 is made of high carbon steel, these three components are only used. Used in medium 6. In this particular example, the 'high pressure system' is defined as 0.92 million Pascals or more. When the superconducting heat transfer device 2 is not used in a high-pressure steam environment, trioxane, rhodium oxide, and radium oxide are unnecessary and can be omitted from the medium 6, even if the conduit 4 is made of high-steel. In addition, when trioxane, rhodium oxide, and radium oxide are omitted from the medium 6, the third layer of powder 24 should have a volume of at least 1 cubic meter per 20,000 cubic meters of pore volume. The amount provided. As mentioned above, the heat sink 12 uses a superconducting heat transfer medium 6. A representative heat sink 12 is made by the following steps: (a) placing the first layer of solution into a first layer of solution container; (b) The first plate 36 and the second plate 38 are immersed in the first layer of solution, so that the first layer of solution covers at least one side of each of the first plate 36 and the second plate 38, and the temperature is 0. 〇 to 30 C for at least 8 hours, so that the first layer of solution can pass through the cover -20- This paper size applies Chinese National Standard (CNS) A4 specifications (210 X 297 mm) I 111 n 1) 4 Clothing 11 order (please read the precautions on the back before filling this page) 1225766 V. Description of the invention (18 sides of 40 to 〇08 and 〇12 mm of wool and ice, the first board 36 and the second The plate 38 also has a matching edge 42, and when the first jealousy ~ n catty, and the Tiandi plate 36 and the second plate 38 are put together, it can be formed in relation to the surface area of the first plate 36 and the second plate 38- Smaller volume of holes 8, the first plate 36 and the third plate 38 have at least—openings between 24 red and 5 mm 4 4, preferably 3.0 mm; ⑷ naturally dried in a peripheral state A board and a second board 38 to form the first layer 20 on the first layer covering side of the second board 36 and the second board 38; ⑷ Put the first layer solution into the second layer solution container; (e) The first plate 36 and the second plate 38 are immersed in the second layer of solution, so that the second layer of solution contacts the first layer 20, the temperature is between hunger and the machine, preferably ^, and the time is at least 4 hours; ⑴ The first plate 36 and the second plate 38 are naturally dried in the peripheral state to facilitate the formation of a second layer 22 having a thickness between 0.08 and 012 mm on the first layer 20; (g) using a The precise welding technology welds the first plate 36 and the second plate 38 along the matching edge 42, preferably by spiral arc welding in helium or argon, so that the first covering sides 40 face each other; the Central Standards Bureau of the Ministry of Economic Affairs Printed by Employee Consumption Cooperative III ϋ H — ^ clothing IIH (please read the precautions on the back before filling this page) (h) 4r second layer of 24 powder with a pore volume of at least 1 per 40,000 cubic meters An amount of cubic meters is injected into the hole 8 through the hole 44; and (1) Xingfujia uses the method of step (g) to seal the opening 44 to form a heat sink 12. The heat sink 12 can be the same as superconducting heat transfer The method of device 2 is made, that is, the heat dissipation device 12 can be thermally polarized, but this is not necessary. Similarly, the welding steps used in the manufacturing of the conductive heat transfer device 2 and the heat sink 12 can be used -21-This paper Standards apply to China National Standard (CNS) A4 specifications (210X 297 public directors) 19) Glue, adhesive and / or epoxy resin finish, preferably ring and grease. In addition, all welding should be carried out to the lift pipe :: end: Wang into the cap 30, the first plate 36 or the second plate It should be thick, and then a leak test should be performed, such as a helium purge air leak test. The tube is melted to form the superconducting heat transfer device 2 of the conduit 4: and the plunger 34 or the first and second parts of the radiator 12 :: 38 of = caps 30 are compatible with each other. This can avoid problems related to material receivables: Q4 and the problem of rot names related to anode reactions, especially material cracking. & 疋 The material should also be compatible with and able to withstand the environment of 12 传导 for superconducting or heat sinks. For example, if the material transfer device is operated in an acidic environment, the material can be referenced in the present invention. Let ’s understand it with the following examples: The above description can understand the best measurement relationship for the components of the present invention, including size, material, shape, type, operating function and method, assembly and use. It is well known to those skilled in the art, and all relations mentioned in the specification should be covered by the present invention. ′, When a cold source is exposed to any one of the ends of the duct 4, the superheat transfer medium 6 is also: conductive cold temperature transfer, and when the duct 4 is in contact with _195 at its end. In the case of liquid nitrogen of 〇, cold-temperature transfer can successfully transfer through the catheter. The following examples illustrate the various types of knives of the first layer 20, the second layer 22, and the third layer 24, and they are known to be used for preparing the superconducting heat transfer device 2 or the heat sink 12, and the components are preferably in the above-mentioned amounts and The list of the above individual steps is added to each layer 20, 22, 24 in order. Example 1 1225766 A7 B7 V. Description of the invention (20) For the first layer 20, add 5.0 g of sodium peroxide, 0.5 g of sodium oxide, 2.0 g of dichromate or dichromate to 100 ml of distilled water. , 2.5 grams of calcium dichromate and 3.0 grams of boron oxide. To make the second layer 2 2 ', add 100 g of oxidized oxygen, 0.5 g of manganese trioxane, 0.5 g of gill carbonate, 0.2 g of oxidized impurities, 0.8 g Grams of oxidized steel, 0.6 grams / 5-chin, and 1.2 grams of potassium complex complex. 〇 To make the third layer 24, combined 1.75 grams of germanium oxide, 1.25 grams of titanium, 3.1 grams of radium oxide, 2.6 grams of complex Sodium, 0.4 g of silver complexate and 0.9 g of single crystal silicon powder. Example 2 To make the first layer 20, 50 g of sodium peroxide, 0.5 g of wrinkled oxide, 2.0 g of acid complex, 2.0 g of calcium complex acid, and 3.0 g of boron oxide were added to 100 ml of distilled water. In order to make the first layer 2 2 ', add 0.5 g of oxidized oxygen, 0.5 g of chromic gill, 0.8 g of copper oxide, 0.6 g of 0 —' and 1 · 2 grams of potassium dichromate. Printed by the Consumer Standards Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs-(Please read the notes on the back before writing this page) To make the third layer 24, combined with 1.6 grams of sodium dichromate and 08 grams of potassium dichromate , 0.4 g of silver dichromate and 0.9 g of single crystal silicon powder. Example 3 To make the first layer 20, 50 g of sodium peroxide, 0.5 g of beryllium oxide, 2.0 g of magnesium dichromate, 3.5 g of calcium dichromate, and 3.0 g of oxide were added to 100 ml of distilled water. boron. To make the second layer 22, add 100 · 5 -23 to 100 ml of twice-distilled water. This paper is a standard of China National Standards (CNS) of 8 4 ^ grid (210 × 29? Mm) 1225766 Central Standard of the Ministry of Economic Affairs Printed by the Consumer Cooperative of the Bureau A7 B7 V. Description of the invention (21) grams of cobalt oxide, 0.5 grams of gill chromate, 0.8 grams of copper oxide, 0.6 grams / 5-convergence, and 12 grams of potassium dichromate. The third layer 24 was made and combined with 1.6 g of copper dichromate, 0.8 g of complex acid unloading, 0.6 g of silver dichromate, and 0.9 g of single crystal silicon powder. Example 4 To make a first layer of 20, 2.0 g of sodium peroxide, 0.3 g of beryllium oxide, 2.0 g of magnesium dichromate, and 1.0 g of boron oxide were added to 100 ml of steamed hall water. For the second layer 22, 0.5 g of cobalt oxide, 0.5 g of chromic gill, 0.4 g of A-titanium, and 1.0 g of dichromic acid were added to 100 ml of water in the secondary steaming room. The third layer 24 is made and combined with 0.5 g of sodium dichromate, 0.8 g of dichromate, 0.1 g of silver dichromate, 0.3 g of single crystal silicon powder, 0.01 g of beryllium oxide, 0.1 G of chromic acid gills, 01 g of boron oxide and 0 g of sodium peroxide. Example 5 To make the first layer 20, add 2.0 g of sodium peroxide, 0.3 g of beryllium oxide, and 2.0 g of dichromic acid to 100 ml of distilled water. Magnesium and 1.0 g of boron oxide. For making the second layer 22, 0.3 g of cobalt oxide, 0.3 g of gill chromate, 1.0 g of potassium dichromate, and 1 g of dichromate were added to 100 ml of twice-distilled water. For the third layer 24, 0.3 g of sodium dichromate, 0.1 g of dichromium fe: silver, 0.8 g of dibasic acid, 0.2 g of single crystal crushed powder, and 0.01 g of oxygen were combined. -24- This paper size applies to Chinese National Standard (CNS) A4 (210X 297mm) (Please read the notes on the back before filling out this page) Γ 1225766 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Α7 Β7 Five Description of the invention (22) Beryllium, 0.1 g of total acid, 0.1 g of boron oxide, 0.2 g /?-'And 0.1 g of sodium peroxide. Example 6 To make the first layer 20, 2.0 g of sodium peroxide, 0.3 g of beryllium oxide, 1.0 g of boron oxide, and 1.0 g of calcium dichromate were added to 100 ml of distilled water. For the second layer 22, 0.3 g of oxidized oxide, 0.01 g of beryllium oxide, 1.0 g of potassium dichromate, 1.0 g of boron oxide, and 2.0 g of heavy chromium were added to 100 ml of twice-distilled water. Acid magnesium. For the third layer 24, 0.3 g of sodium dichromate, 0.1 g of silver dichromate, 0.8 g of dichromate, 0.2 g of single crystal powder, 0.1 g of gallium acid gallium, 0.01 g of beryllium oxide, 0.1 grams of boron oxide, 0.1 grams of sodium peroxide, 0.2 grams of titanium, and 0.2 grams of magnesium dichromate. Example 7 To make the first layer 20, 2.0 g of sodium peroxide, 0.3 g of reconstituted acid and 1.0 g of oxidized decay were added to 100 ml of distilled water. For making the second layer 22, add 0.2 g of oxidized oxide, 1.0 g of reconstituted acid, 1.0 g of reconstituted acid, 0.5 g of boron oxide, 1.0 g of dichromated magnesium, and 0.01 g of beryllium oxide. For the third layer 24, 0.3 g of sodium dichromate, 0.05 g of resilver silver, 0.8 g of gallium acid bell, 0.2 g of early crystal powder, 0.1 g of chromic gill, and 0.01 g of wrinkle 0.1 gram of boron oxide, 0.1 gram of sodium peroxide, 0.2 gram ', and 0.2 gram of acid. Experiment • 25- This paper size applies Chinese National Standard (CNS) Α4 size (210X 297 mm) ~ 'I-----1 11! — J! Mu (Please read the notes on the back before filling in this Page) 1225766 A7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (23) 1. Introduction f Add a few milligrams of the appropriate amount of the third layer of inorganic thermal superconducting medium 24 powder to official parts, such as catheters , Or a flat middle layer, such as plates 36, 38, to produce a superconducting device 2. For example, 'the third layer of 24 powder is added between the holes of the duct 4 or the plate 3 6 3 8 and after subsequent heating to remove residual moisture and gas, and then the holes 8 6 are closed, the protagonist will produce a thermal superconductivity Device 2. The subsequent test results proved that the third layer 24 was a superconducting medium, and the heat conducting device made of the third layer 24 was a heat superconducting heat pipe. In fact, a conventional heat pipe shares a similar shape with the heat of a thermal superconductor and misunderstands it. Therefore, it is necessary to have a simple explanation of the differences and similarities between the two. It is known that the heat pipe uses the technology of liquid evaporation when absorbing large heat and gas cooling during heat release, so as to carry heat from the hot end of the pipe to the cold end. The axial heat conduction speed of the heat pipe depends on the heat of liquid evaporation and Circulation speed between liquid fljSL and gas. The axial heat conduction speed of the heat pipe is also limited by the type and amount of the carrier material, and the temperature and pressure of the heat pipe operation (not too high). The thermal superconducting heat transfer device 2 is made of thermal superconducting media. Directional heat conduction is achieved by the high-speed movement of molecules of a thermal superconducting medium during heating and activation. The thermal conduction speed of this thermal superconducting heat transfer device 2 is much greater than that of any metal rod or convection heat pipe of similar size, and its internal pressure is Any convection heat pipe far below the same temperature. The upper limit of the applicable temperature of the thermal superconducting heat transfer device 2 is outside the upper limit of the allowable temperature of the material of the duct 4. The thermal superconducting thermal transfer device 2 can have the greatest impact in all thermal transfer fields, especially in the heat use ratio. The thermal superconducting thermal transfer device 2 can also be used for -26- This paper is applicable to the Chinese National Standard (CNS) A4 specifications (210x297 mm) --------- install ------ 1T (Please read the notes on the back before filling in this page j 1225766 A7 B7 V. Description of the invention (24) Solar and geothermal In the development and use of energy, and for the regeneration of low-energy heat. 2. Test methods and principles The heat conduction speed of a metal rod depends on the thermal conductivity of the rod, the temperature gradient, and the cross-sectional area perpendicular to the temperature gradient. The metal has a specific ratio Non-metal has high thermal conductivity 'and silver among metals has the highest thermal conductivity of about 41 5 w / mK. This thermal transfer thermal transfer device 2 is a new development, and there is no previous example to illustrate and test. For its properties, it is obviously scientific and logical to use its actual or related thermal conductivity and axial and radial heat flux measurements as its property description. However, this does not change the method of measuring thermal conductivity in thermal superconducting devices Go forward Available facts. The test method used to test this thermal superconducting heat transfer device 2 is a modified Forbes method, in which a thermal superconducting heat pipe is used as a semi-infinite rod, assuming that the temperature of the reference surface of the rod is TQK, separated from The temperature of the reference surface reaching the cross section of χ m is TK, the temperature of the fluid (water) adjacent to the rod surface and passing through the thermal convection between itself and the rod is TtK, the thermal conductivity of the rod is kw / mK, and the convective heat of the table The transfer coefficient is h W / m2K, the perimeter of the rod is p meters, and the section of the rod (please read the precautions on the back before filling this page)-printed by the Staff Consumer Cooperative of the Central Bureau of Standards, Ministry of Economic Affairs

面積爲fm2,熱轉移之主差等式 d2T/dx2-(h p)(k f) (1-1^)=0 此爲一異差等式,假設Θ = T-T (1) Μ等式(1)可由假設 m =hp/kf而變成一同質等式,吾人得到 d2 Θ /dx2-m2 θ =0 針對筒形物,m2=4h/(kd。),d。爲筒形物之直徑 -27- 本紙張尺度適用中國國家標準(CNS ) A4規格(210X 297公釐) (2) 1225766 A7 B7 五、發明説明(26 ) T0=水之出口溫度(K) 水之入口溫度(Κ) *The area is fm2, and the main difference equation for thermal transfer is d2T / dx2- (hp) (kf) (1-1 ^) = 0 This is a heterodyne equation, assuming Θ = TT (1) Μ equation (1) From the assumption that m = hp / kf, it becomes a homogeneous equation, and we get d2 Θ / dx2-m2 θ = 0. For cylindrical objects, m2 = 4h / (kd.), D. The diameter of the tube is -27- This paper size applies to the Chinese National Standard (CNS) A4 specification (210X 297 mm) (2) 1225766 A7 B7 V. Description of the invention (26) T0 = Water outlet temperature (K) Water Inlet temperature (Κ) *

Qi- = d0 Lh)tIn (14) 其中L =桿之長度(米) d〇 =桿之外徑(米) h=對流熱轉移係數(W/m2K) )tin-=( θ Θ L)/ln( Θ J Θ L) 當測得上述値時,一熱超傳導熱管之有效熱傳導率可計 算且熱通量亦可計算。 3.測試裝置 根據上述測試原理及數學模式,如圖7所示,可組合一測 試裝置,其包含熱超傳導熱管1 〇2、冷卻水箱管1 04、熱電 偶106、壓力錶108、水蒸氣加熱室丨1〇、冷凝水集收器Π2 、及眞空閥1 14。 4·測試結果 經濟部中央標準局員工消費合作社印製 ---------^-- (諳先閱讀背面之注意事項再填寫本頁) 使用飽和水蒸氣做爲熱源以活化裝置2内之熱超傳導介質 24係有多項優點,飽和水蒸氣具有較高之熱轉移係數,且 飽和水洛氣直接接觸於不含接觸熱電阻之裝置2熱表面。在 控制下保持飽和水蒸氣壓力意指在控制下保持加熱溫度, 且可提供熱超傳導熱轉移裝置2以一穩定之熱通量。、在動 率及冷卻水入口溫度指定後,測試系統將達到一穩定平衡 ,測得之所有物理量皆呈穩定且重覆良好。 一 以下表格説明測量結果之四個代表 + — 衣f生祆鮮,及圖8-11繪 表揭示諸結果。 -29- 1225766 A7 ____B7 五、發明説明(27 ) 測量結果 編號 軸向熱通量徑向熱通 量有效熱傳導 K/kAg (W/m) (W/m) 率(W/mK) 1 8.618xl06 4.396χ1〇^ 1.969xl06 4.746xl〇3 2 8·363χ106 4·267χ1〇4 3.183xl06 7·672χ1〇3 3 8.260χ106 4·214χ1〇4 2.624xl05 6.324x1〇2 4 .8.831χ106 4.505χ1〇4 3.235xl04 7.795x1〇2 冷卻段之官表面t溫度分佈曲線、有效熱傳導率、對流 熱轉移係數以及熱傳導速度係在不同冷卻水流動率下取2 ’儘管諸値顯示出特定之差異,但是其亦指出熱管爲熱超 傳導性。 經濟部中央標準局員工消費合作社印製 n in ml II—i ϋ— ·ϋι m ml (. , In ϋϋ —ϋ ϋ·— ϋϋ ϋϋ (請先聞讀背面之注意事項再填寫本頁}Qi- = d0 Lh) tIn (14) where L = length of the rod (m) d〇 = outside diameter of the rod (m) h = convective heat transfer coefficient (W / m2K)) tin-= (θ Θ L) / ln (Θ J Θ L) When the above 値 is measured, the effective thermal conductivity of a heat superconducting heat pipe can be calculated and the heat flux can also be calculated. 3. Test device According to the above test principle and mathematical mode, as shown in Figure 7, a test device can be combined, which includes a thermal superconducting heat pipe 10, a cooling water tank tube 104, a thermocouple 106, a pressure gauge 108, and water vapor. Heating chamber 丨 10, condensate collector Π2, and empty valve 114. 4 · Test results Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs --------- ^-(谙 Read the precautions on the back before filling this page) Use saturated water vapor as a heat source to activate the device 2 The internal thermal superconducting medium 24 has a number of advantages. Saturated water vapor has a high heat transfer coefficient, and saturated water gas directly contacts the thermal surface of the device 2 without contact thermal resistance. Maintaining the saturated water vapor pressure under control means keeping the heating temperature under control, and can provide the thermal superconducting heat transfer device 2 with a stable heat flux. After the designation of the kinetic energy and the cooling water inlet temperature, the test system will reach a stable equilibrium, and all the measured physical quantities are stable and repeat well. The following table shows the four representatives of the measurement results. -29- 1225766 A7 ____B7 V. Description of the invention (27) Measurement result number Axial heat flux Radial heat flux Effective heat conduction K / kAg (W / m) (W / m) Rate (W / mK) 1 8.618xl06 4.396x1〇 ^ 1.969xl06 4.746xl03 2 8.363χ106 4 · 267χ1〇4 3.183xl06 7.672χ1〇3 3 8.260χ106 4 · 214χ1〇4 2.624xl05 6.324x1〇2 4 .8.831χ106 4.505χ1〇4 3.235xl04 7.795x1〇2 The surface temperature distribution curve, effective thermal conductivity, convective heat transfer coefficient, and thermal conduction speed of the cooling surface of the cooling section are taken under different cooling water flow rates. 'Although the various displays show specific differences, it also indicates that the heat pipe For thermal superconductivity. Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs n in ml II—i ϋ— · ϋm ml (., In ϋϋ —ϋ ϋ · — ϋϋ ϋϋ (Please read the precautions on the back before filling out this page)

冷卻水流動率之變化會造成溫度分佈變化,但是熱傳導 速度不變,此意指加熱段中之熱傳導速度已到達其上限, 加熱段之熱傳導面積未設計得很大係因爲低估了熱管之熱 傳導能力。溫度分佈變化造成關係式中之斜率见之値與符號 改變。對流熱轉移係數改變意指有效熱傳導率亦改變,熱 管之熱超傳導率係由諸項變化確定。當m具有一正號時,冷 卻水之出口溫度接近熱管底部之溫度(在χ吲處),一對流^ 交換器可以僅在逆流狀態下取得此一高熱轉移效率。若冷 卻水流動率增大,則冷卻水之出口溫度接近於另一端者J x = L處),一對流熱交換器可以僅在熱傳導面積呈無限大時 取得此一高熱轉移效率。 圖12説明本發明實體結構之一變化型式,料導敛轉^ 介質6(此圖中未示)置入由熱板12〇、挽性導管124 ^熱^ -30- ΐ氏張尺度適用中國國家標準(CNSy^^.2丨Gx 297公餐-------- 1225766 經濟部中央標準局員工消費合作社印製 A7 五、發明説明(28 ) 126組立之封閉體積内。儘管超傳導熱轉移介質可利用任意 開,以施加於系.统,例如當各別孔皆斷接於導管124時可通 過桃性導管124之-斷接端、或通過熱板12〇上之孔⑴、或 H、t 126上(孔134 ’但是_填注孔122仍可提供以協助 施加熱轉移介質6至系統之内部孔穴。_旦熱轉移介質⑽ 加至系統時,系統之整體熱傳導率將增大。 、% ’王孔122可以自行封閉,例如且不限定的有鴨嘴闕,填 /王孔122亦可以由-官栓或帽蓋封閉。儘管此封閉件不需要 有,何特殊之熱特徵,但是爲了利用整個表面積做爲一散 熱益,則此封閉件具有—高熱傳導率爲佳。若封閉件係由 金屬如銅製成,則可輕易達成,因爲此封閉件將傳送大量 亦需處理之熱,將至少—部分封閉件隔絕即有利於使用, 特別是使用者抓持處。此封閉件不僅有助於防止任意熱轉 移介質腐蚀或損失,亦可防止外部粒子汗染内部孔穴而影 響到系統之熱轉移特徵。 系統之組件-熱塾126、導管124、及板隱較佳爲高熱 傳導率之材料製成,例如且不限定的有包括鋼之金屬。惟 ,組件另可由不同熱傳導率之材料製成,例如若熱板12〇安 裝於膝上型電腦上之一 LCD螢幕背部,則共有利於令面向 LCD螢幕之板12〇側面以一低熱傳導率之材料製成,以利隔 絕LCD勞幕於加熱所致之損害,而背對㈣勞幕之板側面 再以一高熱傳導率之材料製成,以利散熱。 cpu性能之一重大拘限爲操作溫度,母板13〇具有至少一 CPU 128安裝於上,本發明較佳實施例之熱墊126係接觸或 31 - 本纸張尺度適用中國國家標準(CNS ) A4規格(21〇χ297公爱) ^------tr------ (請先閣讀背面之注意事項再填寫本頁) 1225766 經濟部中央標準局員工消費合作社印製 Α7 Β7 五、發明説明(29 ) 接近於CPU 128,由CPU 128散發之大量熱則轉移至熱塾 126,熱墊126中之熱基本上隨即流至,三個位置。 可以接受之原理爲熱轉移係相對於數項特徵,包括表面 積及熱傳導率,本發明裝置藉由提供遠大於CPU者之散熱 表面積及熱傳導率,以利自CPU 128散熱。 若無本發明裝置,CPU即傳熱至母板且直接到大氣, 惟’雖然本發明裝置使用時CPU仍然傳熱至母板及大氣, 但是亦傳熱至熱墊1 26,熱墊再傳熱至大氣、撓性導管 124及熱轉移介質6。撓性導管傳熱至熱板120及大氣,熱 轉移介質6傳熱至撓性導管124及熱板12〇,熱板丨2〇傳熱 至大氣。雖然未要求,但是一般而言熱板12〇表面積越大 越有利,因爲其可遠離CPU 128周側之拘束空間,且通風 較爲良好。使用本發明裝置之最終結果爲CPU 128之熱幾 乎均勻擴散於本發明裝置,且以較高熱通量通過一大表 面積至大氣。 一或多牧CPU可使用本發明裝置,其係將額外熱墊放置 於額外CPUs附近内,及經由撓性導管將熱墊接於熱板,或 僅利用單一熱墊,但是其大得足以跨過多牧CPUs。 儘管此裝置詳述爲配合一 CPu使用,其另可用於任意產 生熱之電力組件或非電力組件,而僅施加熱墊於組件。 此外’本發明裝置可用於冷卻以及加熱,裝置將熱塾及 熱塾附近任意組件之溫度達到熱墊周側之溫度,此功能性 並無關於熱板是否在熱墊之較高或較低溫度。欲冷卻組件 時,應有一低於組件溫度之周側熱板溫度,而欲加熱組件 -32- 本紙張尺度適用中國國家標準(CNS ) A4規格Υϋ97公楚) ---------^------1Τ------1 (請先閔讀背面之注意事領再填寫本頁)The change of the cooling water flow rate will cause the temperature distribution to change, but the heat conduction speed will not change. This means that the heat conduction speed in the heating section has reached its upper limit. The heat conduction area of the heating section is not designed to be large because the heat conduction capacity of the heat pipe is underestimated . The change in temperature distribution causes the slope and sign in the relationship to change. A change in the convective heat transfer coefficient means that the effective thermal conductivity also changes. The thermal superconductivity of the heat pipe is determined by various changes. When m has a positive sign, the outlet temperature of the cooling water is close to the temperature at the bottom of the heat pipe (at χind), and a pair of convection exchangers can achieve this high heat transfer efficiency only in a countercurrent state. If the cooling water flow rate increases, the outlet temperature of the cooling water is close to the other end (J x = L). The convection heat exchanger can achieve this high heat transfer efficiency only when the heat conduction area is infinite. FIG. 12 illustrates a variation of the physical structure of the present invention. Material 6 is converged ^ The medium 6 (not shown in the figure) is placed by a hot plate 12o, a pull duct 124 ^ heat ^ -30--Zhang scale applicable to China National Standard (CNSy ^^. 2 丨 Gx 297 Public Meal -------- 1225766 Printed by A7, Consumer Cooperatives, Central Standards Bureau, Ministry of Economic Affairs, V. Invention Description (28) Within the closed volume of 126 sets. Although superconducting The heat transfer medium can be arbitrarily opened to be applied to the system. For example, when the respective holes are disconnected from the conduit 124, the peach-shaped conduit 124 can be connected through the -disconnected end, or through the holes on the hot plate 120. Or H, t 126 (hole 134 'but filling hole 122 can still be provided to assist in applying heat transfer medium 6 to the internal holes of the system. _ Once the heat transfer medium ⑽ is added to the system, the overall thermal conductivity of the system will increase Large. ”King hole 122 can be closed by itself, for example, and without limitation, duckbill, filling / king hole 122 can also be closed by-official bolt or cap. Although this closure does not need to have any special thermal characteristics , But in order to use the entire surface area as a heat dissipation benefit, this closure has-high heat transfer The conductivity is good. If the closure is made of metal such as copper, it can be easily achieved, because this closure will transmit a large amount of heat that also needs to be processed, and it is beneficial to use at least-part of the insulation, especially for the user to grasp This closure not only helps to prevent corrosion or loss of any heat transfer medium, but also prevents external particles from sweating the internal pores and affecting the heat transfer characteristics of the system. The components of the system-heat pump 126, duct 124, and plate It is preferably made of a material with high thermal conductivity, such as, but not limited to, metal including steel. However, the component can be made of a material with different thermal conductivity, such as if the hot plate 12 is installed on a laptop computer. The back of an LCD screen is beneficial to make the 120 side of the panel facing the LCD screen made of a material with low thermal conductivity, in order to isolate the damage caused by the heating of the LCD screen, while facing away from the side of the panel It is made of a material with high thermal conductivity to facilitate heat dissipation. A major limitation of CPU performance is the operating temperature. The motherboard 13 has at least one CPU 128 installed on it. The heat pad 126 of the preferred embodiment of the present invention Contact or 31-This paper size applies Chinese National Standard (CNS) A4 specification (21〇χ297 公 爱) ^ ------ tr ------ (Please read the precautions on the back before filling in this Page) 1225766 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (29) Close to CPU 128, a large amount of heat emitted by CPU 128 is transferred to thermal pad 126, and the heat in thermal pad 126 is basically immediately Flow to, three positions. The acceptable principle is that the heat transfer is relative to several characteristics, including surface area and thermal conductivity. The device of the present invention provides heat dissipation surface and thermal conductivity much larger than those of the CPU to facilitate heat dissipation from the CPU 128. . Without the device of the present invention, the CPU transfers heat to the motherboard and directly to the atmosphere, but 'Although the CPU still transfers heat to the motherboard and the atmosphere when the device of the present invention is used, it also transfers heat to the heat pad 126, which is then transferred Heat to the atmosphere, flexible duct 124 and heat transfer medium 6. The flexible pipe transfers heat to the hot plate 120 and the atmosphere, the heat transfer medium 6 transfers heat to the flexible pipe 124 and the hot plate 120, and the hot plate 20 transfers heat to the atmosphere. Although not required, in general, the larger the surface area of the hot plate is, the more beneficial it is, because it can be far away from the confined space on the 128 side of the CPU, and the ventilation is better. The end result of using the device of the present invention is that the heat of the CPU 128 is almost uniformly diffused in the device of the present invention, and passes through a large surface area to the atmosphere with a high heat flux. One or more CPUs can use the device of the present invention, which is to place additional thermal pads in the vicinity of additional CPUs and connect the thermal pads to the hot plate through a flexible conduit, or use only a single thermal pad, but it is large enough to cross Overgrazing CPUs. Although this device is detailed for use with a CPu, it can also be used for any heat-generating electrical or non-electrical component, with only a thermal pad applied to the component. In addition, the device of the present invention can be used for cooling and heating. The device will heat the temperature of any component near the thermal pad to the temperature on the peripheral side of the thermal pad. This functionality does not matter whether the hot plate is at a higher or lower temperature than the thermal pad. . When you want to cool the module, you should have a peripheral hot plate temperature that is lower than the module temperature, and you want to heat the module -32- This paper size applies to Chinese National Standard (CNS) A4 specification (97g) --------- ^ ------ 1Τ ------ 1 (Please read the note on the back before filling in this page)

Claims (1)

1225766 第〇9〇 1 〇9647號專利申請案 中文申睛專利範圍替換本(92年4月) A BCD1225766 Patent Application No. 0909 No. 0647647 Chinese Patent Replacement (April 1992) A BCD 申請專利範圍Patent application scope 1. 瞥 示 j 本 案2 修· 正 後 是3 · 變 更原4· 實 質 内s $ 5· 6. 7. 8. 一種熱轉移裝置,包含: a) —熱墊,包含一外熱誓表面積及一内熱整孔穴; —導管,包含一外導管表面積、一内導管孔穴、一第 一端及一第二端; 0 —熱板,包含一外熱板表面積及一内熱板表面積; d) —體積,包含内熱墊孔穴、内導管孔穴、及内熱板表 面積;及 e) —熱轉移介質; 其中熱墊係鄰近於至少一組件,及其中熱轉移介質係位 於體積内,及其中熱轉移介質具有一熱傳導率且大致大 於銀者。 如申請專利範圍第1項之熱轉移裝置 一超傳導熱轉移介質。 如申請專利範圍第1項之熱轉移裝置 含重鉻酸鈉、重鉻酸銀、及單晶矽。 如申凊專利範圍第3項之熱轉移裝置 單晶矽已由一磁性共振步驟處理。 如申請專利範圍第4項之熱轉移裝置 該磁性共振步驟期間呈粉末狀。 如申凊專利範圍第5項之熱轉移裝置 大於99.999%純度。 如申請專利範圍第1項之熱轉移裝置, 有一熱傳導率,且大致增加而大於一活化溫度 如申請專利範圍第7項之熱轉移裝置,其中熱轉移介質包 其中熱轉移介質係 其中熱轉移介質包 其中該重鉻酸銀及 其中|亥單晶碎係在 其中該單晶矽具有 其中熱轉移介質具 本紙張尺度適用中國國家標準(CNS) A4規格(210X297公爱) A8 B81. A glance at this case 2 revision · after the correction is 3 · change the original 4 · within the substance s $ 5 · 6. 7. 8. A heat transfer device, including: a)-a heat pad, including an external heat oath surface area and An inner thermal shaping hole;-a duct including an outer duct surface area, an inner duct hole, a first end and a second end; 0-a hot plate including an outer heating plate surface area and an inner heating plate surface area; d) -The volume, including the inner thermal pad holes, the inner duct holes, and the inner heat plate surface area; and e)-a heat transfer medium; wherein the heat pad is adjacent to at least one component, and the middle heat transfer medium is located in the volume, and the middle heat The transfer medium has a thermal conductivity that is substantially greater than that of silver. For example, the heat transfer device of the scope of application for a patent is a superconducting heat transfer medium. For example, the heat transfer device of the first patent application scope contains sodium dichromate, silver dichromate, and single crystal silicon. For example, the single crystal silicon of the thermal transfer device of claim 3 of the patent scope has been processed by a magnetic resonance step. For example, the thermal transfer device of the patent application No. 4 is powdery during the magnetic resonance step. For example, the heat transfer device in the scope of application of patent No. 5 has a purity of more than 99.999%. For example, the heat transfer device in the scope of patent application 1 has a thermal conductivity, which increases approximately and is greater than an activation temperature. The heat transfer device in the scope of patent application 7, wherein the heat transfer medium includes a heat transfer medium in which the heat transfer medium is Including the silver dichromate and its | Hai single crystal broken system in which the single crystal silicon has a heat transfer medium with this paper size applicable to Chinese National Standard (CNS) A4 specifications (210X297 public love) A8 B8 含重鉻酸鈉、重鉻酸銀、及單晶矽。 9·請專利範圍第8項之熱轉移裝置,其中該重鉻酸銀及 單晶碎已由一磁性共振步驟處理。 10. 如申請專利範圍第9項之熱轉移裝置,其中該單晶矽係在 孩磁性共振步驟期間呈粉末狀。 11. 如申請專利範圍第8項之熱轉移裝置,其中該單晶矽具有 大於99.999%純度。 ^ 12. 如申請專利範圍第1項之熱轉移裝置,其中至少一組件係 一電力組件。 13. 如申請專利範圍第丨項之熱轉移裝置,其中有正熱通量通 過至少一組件之表面。 14·如申請專利範圍第〗項之熱轉移裝置’其中有負熱通量通 過至少一組件之表面。 1 5·如申請專利範圍第丨項之熱轉移裝置,其中至少一組件係 一 CPU。 、 W·如申請專利範圍第丨項之熱轉移裝置,其中熱墊係至少一 邵分為金屬。 Η·如申請專利範圍第1項之熱轉移裝置,其中熱墊係至少一 邵分為銅。 18·如申請專利範圍第丨項之熱轉移裝置,其中熱墊係安裝於 至少一組件。 19.如中請專利範圍第丨項之熱轉移裝置,其中熱板係至少一 邵分為金屬。 2〇·如申請專利範圍第}項之熱轉移裝置,其中熱板係至少一 -2 - 本紙張尺度適用中國國家標準(CNS) A4規格(210X297公釐) 〜/Ό〇Contains sodium dichromate, silver dichromate, and single crystal silicon. 9. The thermal transfer device according to item 8 of the patent, wherein the silver dichromate and the single crystal fragments have been processed by a magnetic resonance step. 10. The heat transfer device according to item 9 of the application, wherein the single crystal silicon system is in a powder form during the magnetic resonance step. 11. The heat transfer device according to item 8 of the patent application, wherein the single crystal silicon has a purity of greater than 99.999%. ^ 12. If the heat transfer device according to item 1 of the patent application scope, at least one of the components is an electrical component. 13. The heat transfer device of the scope of application for patent application, wherein a positive heat flux passes through the surface of at least one component. 14. The heat transfer device according to the scope of the patent application, wherein a negative heat flux passes through the surface of at least one component. 15 · If the heat transfer device according to item 丨 of the patent application scope, at least one of the components is a CPU. W. For example, the heat transfer device in the scope of patent application, wherein the thermal pad is at least one Shao divided into metal. Η · If the heat transfer device of the scope of patent application No. 1, wherein the heat pad is at least one Shao into copper. 18. The heat transfer device according to item 丨 of the application, wherein the heat pad is installed on at least one component. 19. The heat transfer device according to item No. 丨 in the patent application, wherein the hot plate is at least one shaw divided into metals. 2〇 If the heat transfer device of the scope of the application for the patent item}, where the hot plate is at least one -2-This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) ~ / Ό〇 部分為銅。 2 1 .如申請專利範圍第1項之熱轉移裝置,其中熱墊包含一熱 蟄王體及一熱整孔。 一.u申凊專利範圍第21項之熱轉移裝置,其中導管之第一 端係連接於熱墊孔。 “ i申明專利範圍第1項之熱轉移裝置,其中熱板包含一熱 板主體及一熱板孔。 二4·如申請專利範圍第23項之熱轉移裝置,其中熱板主體包 含至少二銅板。 25. 如申請專利範圍第23或24項之熱轉移裝置,其中熱板主 體包含至少一容室。 26. 如申凊專利範圍第以項之熱轉移裝置,其中至少一容室 係由壓鑄製成。 27. 如申凊專利範圍第23項之熱轉移裝置,其中導管之第二 端係連接於熱板孔。 28·如申請專利範圍第1項之熱轉移裝置,進一步包含一填注 29·如申請專利範圍第28項之熱轉移裝置,其中填注孔係自 行封閉。 30.如申凊專利範圍第28項之熱轉移裝置,進一步包含一封 閉件。 3 1 ·如申請專利範圍第3〇項之熱轉移裝置,其中封閉件係至 少一部分為金屬。 32.如申請專利範圍第3〇項之熱轉移裝置,其中封閉件係可 本紙張尺度適用中國國家標準(CNS) Α4規格(21〇Χ297公釐) 1225766 A8 B8 C8 --— —____D8、申請專利範圍Some are copper. 2 1. The heat transfer device according to item 1 of the scope of patent application, wherein the heat pad comprises a thermal scorpion king body and a thermal shaping hole. 1. The heat transfer device of U.S. Patent No. 21, wherein the first end of the conduit is connected to the heat pad hole. "I declares that the heat transfer device in the first item of the patent scope, wherein the hot plate includes a hot plate body and a hot plate hole. 2.4. For the heat transfer device in the 23rd aspect of the patent application, where the hot plate body contains at least two copper plates 25. If the heat transfer device of the scope of application for the patent No. 23 or 24, wherein the main body of the hot plate includes at least one container. 26. For the heat transfer device of the scope of the patent application for Shen, at least one of the chambers is made of die casting. 27. For example, the heat transfer device of item 23 of the patent application, wherein the second end of the conduit is connected to the hole of the hot plate. 28. For the heat transfer device of item 1 of the patent application, further including a filling 29. If the heat transfer device of the scope of patent application No. 28, the filling hole is closed by itself. 30. The heat transfer device of the scope of patent application No. 28, further includes a seal. 3 1 If the scope of patent application The heat transfer device of item 30, wherein the closure member is at least a part of a metal. 32. For the heat transfer device of item 30 of the patent application scope, wherein the closure member is applicable to the Chinese National Standard (CNS) for this paper size 4 Size (mm 21〇Χ297) 1225766 A8 B8 C8 --- -____ D8, the scope of patented 移除地位於填注孔上。 3上如申請專利範圍第30項之熱轉移裝置,其中封閉 帽蓋。 34·如申請專利範圍第30項之熱轉移裝置,其中封 栓塞。 35·如申請專利範圍第3〇項之熱轉移裝置,其中封閉件係 封件。 、 ’其中熱板係比至少 ’其中熱板係鄰近地 36.如申請專利範圍第1項之熱轉移裝置 一組件較曝露於周側大氣。 3 7 .如申凊專利範圍第1項之熱轉移裝置 位於一顯示幕。 38_如申請專利範圍第w之熱轉移裝置,其中熱轉移裝置係 位於一攜帶式電腦内。 39.如申請專利範圍第^頁之熱轉移裝置,其中熱板係位於一 電腦殼罩外。 4〇·如申請專利範圍第!項之熱轉移裝置,其中熱墊、導管、 及;板係連接及包含一封閉之孔穴。 41.如申請專利範圍第4〇項之熱轉移裝置,其中封閉之孔穴 係建構以靜態地容裝熱轉移介質。 42·如申請專利範圍第4〇項之熱轉移裝置,其中封閉之孔穴 並未主動循環熱轉移介質。 -4- 本紙張尺度適用中國國家標準(CNS) A4規格(21〇 χ 297公釐)The removal ground is on the filling hole. 3 The heat transfer device according to item 30 of the above application, wherein the cap is closed. 34. The heat transfer device according to item 30 of the patent application, wherein the plug is sealed. 35. The heat transfer device of claim 30, wherein the closure is a seal. ”Where the hot plate is at least than’ where the hot plate is adjacent to the ground 36. The heat transfer device of item 1 of the scope of patent application A component is more exposed to the surrounding atmosphere. 37. The heat transfer device of item 1 of the patent application is located on a display screen. 38_ The heat transfer device according to the scope of application for patent w, wherein the heat transfer device is located in a portable computer. 39. The heat transfer device on page ^ of the patent application, wherein the hot plate is located outside a computer casing. 4〇 · If the scope of patent application is the first! The thermal transfer device of claim, wherein the thermal pad, the conduit, and the plate are connected and contain a closed cavity. 41. The heat transfer device of claim 40, wherein the closed pores are constructed to statically contain the heat transfer medium. 42. The heat transfer device according to item 40 of the patent application, wherein the closed cavity does not actively circulate the heat transfer medium. -4- This paper size is in accordance with Chinese National Standard (CNS) A4 (21 × 297 mm)
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