TWI220385B - Hair-treatment fermentation composition - Google Patents

Hair-treatment fermentation composition Download PDF

Info

Publication number
TWI220385B
TWI220385B TW089109842A TW89109842A TWI220385B TW I220385 B TWI220385 B TW I220385B TW 089109842 A TW089109842 A TW 089109842A TW 89109842 A TW89109842 A TW 89109842A TW I220385 B TWI220385 B TW I220385B
Authority
TW
Taiwan
Prior art keywords
hair
test
treatment
rice bran
wave
Prior art date
Application number
TW089109842A
Other languages
Chinese (zh)
Inventor
Akihiko Kimura
Atsushi Takada
Toshitaka Okada
Original Assignee
Toyo Hakko Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyo Hakko Co Ltd filed Critical Toyo Hakko Co Ltd
Application granted granted Critical
Publication of TWI220385B publication Critical patent/TWI220385B/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/04Preparations for permanent waving or straightening the hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9783Angiosperms [Magnoliophyta]
    • A61K8/9789Magnoliopsida [dicotyledons]
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9783Angiosperms [Magnoliophyta]
    • A61K8/9794Liliopsida [monocotyledons]
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/85Products or compounds obtained by fermentation, e.g. yoghurt, beer, wine

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Botany (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Mycology (AREA)
  • Microbiology (AREA)
  • Biotechnology (AREA)
  • Engineering & Computer Science (AREA)
  • Cosmetics (AREA)
  • Hair Curling (AREA)

Abstract

The present invention relates to a hair-treatment fermentation composition which contains a fermented rice bran/soybean extract, has excellent effects of protecting the hair, waving the hair and retaining the waved hair style, and relieves an offensive smell originating in perming agents. In test performed on hair that has been treated with commercially available perming agents, by applying the hair-treatment composition of the present invention to the hair, the moisture content and the cysteic acid content of the hair are measured. As a result, the hair shows little change in the moisture content due to the change in the environmental humidity and capability of retaining moisture enhanced, as compared to a control group. Also, the composition shows an enhanced effect of inhibiting the formation of cysteic acid by hydrolyzed keratin. When the hair treatment composition in accordance with the present invention is used in perming, the hair is effectively waved and the waved hair style can be sustained. Moreover, the composition relieves the cold smell originating mainly in sulfur components in perming agents.

Description

發明說明(μ ) 【技術領域】 本發明係關於含有米糠、黃豆發酵萃取物的頭髮處理用 劑組成物。本發明之頭髮處理用劑組成物,適於利用i為頭 髮的保濕、保護的處理劑上,或提高燙髮波浪的燙髮效率及 減少硫黃等之不舒服臭味。 【背景技術】 頭髮主要由角脘蛋白質所構成。在構成胱胺酸蛋白質的 聚乙缔縮氣敗裡’作為氨基酸含有半脱胺酸’藉由此半耽胺 酸互相以二硫化物結合,架建起多數的角腚蛋白質並重重纏 繞在一起。因此,頭髮強韌而具有彈性,儘管附加物理外力 仍能立刻恢復原來的性質。 頭髮中含有水份,此水份對於頭髮的物性,觸感帶來重 大的影響。亦即,如果因燙髮波浪或染色、脫色等的化學處 理或紫外線而使頭髮受損,即喪失頭髮中的水份,結果造成 頭髮乾硬,不辦低鮮、光滑度、破壞,而且降低其 強度。 U此,修復因烫髮波浪或染色、脫色等的化學處理或^ 外線等之觀娜部份,賴輕制髮具綺、光滑度 彈性,為保持頭髮的美觀,以往即有各_應之處理蜜;0" t此類之處糊,雖雖即—有加水轉騎、,加水分病 角脘,加水分解絲等蛋白質加水分解物 髮或染色,色等之今; 更1性、護髮性優良’對頭髮更溫和的處理劑之開發 此外,如上_,闕紅二麵物(s_s) 1220385 經濟部智慧財產局員工消費合作社印製 A7 —~ --^---- 五、發明說明(2·) 蛋白質,所以其強動具有彈性,儘管附加物理外力仍能立刻 恢復原來的性質。因此,以往為有美麗的演出,藉由將頭髮 燙成固定形狀,而實行燙差波浪。 烫髮的實行方式如下。亦即,首先將欲燙之頭髮捲於適 當器具之周圍,其次,藉由在頭髮上塗抹遠原劑,以還原方 式切斷二硫化物之架橋。然後,過一段時間後消除還原劑, 添加氧化劑,和在相鄰的聚乙缔縮氨酸鏈成對的半胱胺酸殘 基<間產生新二硫化物之結合。經由以上程序,新二硫化物 之架橋使頭髮纖維的小單環的盤管扭曲,所以可長時間維持 以燙髮形成的固定形狀。 由於憂髮’係為長期維持頭髮的固定形狀所實施,因此 針對此目的之烫髮劑,需要擁有優良的波浪形成力及保持力 Ο 而且’在费髮時所使用的燙髮劑成份,通常使用硫乙二 f或其鹽類(銨鹽,單已醇胺鹽),甘油單硫乙二醇,硫乳 酸或其酯類,無機亞硫酸鹽。但,由於在這些燙髮劑,如上 述特別含有綱化合物,gj此在賴處雜,具有所謂主要 從硫磺成份而產生的不舒服臭味留在頭髮的問題。 一 #一万面,在含有米糠類、黃豆類及礙源的培養基接種納 旦囷或^轉菌,已㈣往在發酵培養後簡得的米祿、黃 a發酵萃取物中’具有各種的生理作用。例如,活性氧消除 作^,氧化防止作用(特開平6_284872號公報),血液中乙 醇濃度減少作用(特開平Μ·7號公報)等的作用。 但,這些米糠、黃豆發酵萃取物的用途,都只是檢討有 本紙張尺度適用^研家鮮 -----------裝 -----丨—訂-------I — (請先閱讀背面之注意事項再填寫本頁) 1220385 經濟部智慧財產局員工消費合作社印製 Ά7 五、發明說明(3·) ~ 關配藥於生物體内時所產生的效果,在適用於頭髮方 提及有關對頭髮性質帶來的影響。 万’未 本發明係鑑於上述現狀所做,其目的在於提供和習知之 處理劑比較,顯示優良的保濕效果、護髮效果, 自 句且,在灰 髮處理時形成波浪形狀及發择保持效果,為同時可抑制由燙 髮劑而產生的硫續等不舒服臭味的頭髮處理用劑組成物。 【發明揭示】 ' ° 本發明之發明者們繼續檢討有關各種米糠、黃豆發酵萃 取物的生理作用,結果發現將以往即已知具有防止氧化、、舌 性氧抑制作用的米糠、黃豆發酵萃取物添加於處理劑,較含 有加水分解膠原或加水分解角脘等的習知之處理劑顯示優 良的保濕效果,護髮效果,而且,在燙髮處理時發揮優良的 波浪形成及保持效果,同時可抑制由燙髮劑而產生的硫磺等 不舒服臭味,達到完成本發明。 本第1發明之頭髮處理用劑組成物,其特徵為,在含有 米糠類、黃豆類及碳源的培養基接種納豆菌或乾草桿菌5含 有在發酵培養後所獲得的米糠、黃豆發酵萃取物。 所謂「米糠、黃豆發酵萃取物」,係指在含有米糠、黃 豆類及碳源的培養基接種納豆菌或乾草桿菌,發酵培養後所 獲得的萃取物。上述「米糠、黃豆發酵萃取物」,可用培養 後所獲得之培養發酵液過濾後的液體,或實施此液脫色等後 處理等的液體,或將其濃縮之濃縮液。此外,利用噴霧乾燥 等眾所周知之方法消除溶媒的固體物或加以粉末化的粉末 物也可以。 •--I-------—^w ^ i I ----^訂 i 丨! — I ! (請先閱讀背面之注意事項再填寫本頁}Description of the Invention (μ) [Technical Field] The present invention relates to a hair treatment agent composition containing rice bran and soybean fermented extract. The hair treatment agent composition of the present invention is suitable for using i as a moisturizing and protecting treatment agent for the hair, or to improve the perm efficiency of the perm wave and reduce the unpleasant odor such as sulfur. [Background Art] Hair is mainly composed of keratin proteins. In the polyethylenic gascondensate that constitutes the cystine protein, 'containing semi-deaminate as an amino acid', by which the semi-peptamines are combined with each other as disulfides, most keratin proteins are built and entangled together . Therefore, the hair is strong and elastic, and it can immediately restore its original properties despite the external physical force. Hair contains moisture, which has a significant effect on the physical properties and feel of the hair. That is, if the hair is damaged by chemical treatment or ultraviolet rays such as perming waves, dyeing, discoloring, etc., that is, the water in the hair is lost, resulting in dry and hard hair, without low freshness, smoothness, damage, and lowering it. strength. U this, repairing the perishable parts due to chemical treatment of perm waves, dyeing, discoloration, etc., etc. Lai Qingfa hair has beautiful, smooth and elastic, in order to maintain the beauty of the hair, in the past there are various _ Yingzhi Handling honey; 0 " t this kind of paste, although it is-there are water to turn riding, water keratoses, hydrolyzed silk and other protein hydrolysates hair or dyed, color and so on; more sex, care Development of a treatment agent with better hair quality for hair. In addition, as above, printed red dihedron (s_s) 1220385 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 — ~-^ ---- V. Invention It shows that (2 ·) protein, so its strong motion is elastic, and it can restore its original properties immediately despite the additional physical force. Therefore, in the past, for beautiful performances, the hair was scalded by scalding the hair into a fixed shape. The perm is implemented as follows. That is, first curl the hair to be perched around an appropriate appliance, and then, by applying a remote agent to the hair, cut the bridge of disulfide in a reducing manner. Then, after a period of time, the reducing agent is eliminated, an oxidizing agent is added, and a new disulfide bond is generated between the paired cysteine residues < of the adjacent polyethylene peptide chain. Through the above procedure, the bridge of the new disulfide twists the coils of the small single loop of the hair fiber, so it can maintain a fixed shape formed by perm for a long time. Since you are using "permanent hair" to maintain the fixed shape of the hair for a long time, a permanent wave agent for this purpose needs to have excellent wave-forming power and holding power. Also, "permanent hair ingredients used when hair is spent are usually used. Thioethylene f or its salts (ammonium salt, monohexanolamine salt), glycerol monothioethylene glycol, thiolactic acid or its esters, inorganic sulfite. However, since these perm agents contain the above-mentioned compounds in particular, gj is mixed here, and there is a problem that the unpleasant odor generated mainly from sulfur components remains in the hair. # 110,000 noodles, inoculate Nadan 囷 or 转 bacteria in a medium containing rice bran, soybeans, and hindering sources, and have simmered into the fermented extracts of Mi Lu and Huang a obtained after fermentation and cultivation. Physiological effects. For example, effects such as elimination of active oxygen, prevention of oxidation (Japanese Patent Application Laid-Open No. 6_284872), reduction of ethanol concentration in blood (Japanese Patent Application Laid-Open No. 7/284), and the like. However, the use of these rice bran and soybean fermented extracts is just a review of the paper standards applicable ^ Research home fresh ----------- equipment ----- 丨 -order ------ -I — (Please read the precautions on the back before filling out this page) 1220385 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs Ά7 V. Description of the Invention (3 ·) ~ The effect produced when the medicine is dispensed in the body, Applicable to hair side mentions about the effects on hair properties. The present invention is made in view of the above situation, and its purpose is to provide an excellent moisturizing effect and hair-care effect compared with conventional treatment agents. It is self-evident that a wavy shape and a hair-retaining effect are formed during gray hair treatment. It is a hair treatment agent composition that can simultaneously suppress unpleasant odors such as sulfur and the like generated by a permanent wave agent. [Disclosure of the invention] '° The inventors of the present invention continued to review the physiological effects of various rice bran and soybean fermented extracts. As a result, they discovered that rice bran and soybean fermented extracts, which have been known to have antioxidation and tongue oxygen inhibition effects, Adding to the treatment agent, it shows superior moisturizing effect and hair care effect than conventional treatment agents containing hydrolyzed collagen or hydrolyzed keratin, etc., and it also exhibits excellent wave formation and retention effects during perm treatment, and can also inhibit The unpleasant odor such as sulfur generated by the permanent wave agent has completed the present invention. The hair treatment agent composition according to the first invention is characterized by inoculating natto bacteria or bacillus 5 in a culture medium containing rice bran, soybeans, and a carbon source, and containing fermented rice bran and soybean soybean extracts after fermentation culture. The "fermented extract of rice bran and soybean" refers to an extract obtained by inoculating natto or bacillus in a culture medium containing rice bran, soybeans, and a carbon source, followed by fermentation and culture. The above-mentioned "rice bran and soybean fermented extract" may be a liquid obtained by filtering the culture fermentation broth obtained after the cultivation, or a liquid subjected to post-treatment such as decolorization of the liquid, or a concentrated liquid in which it is concentrated. It is also possible to eliminate a solid substance of the solvent or a powdered substance by a known method such as spray drying. • --I -------— ^ w ^ i I ---- ^ order i 丨! — I! (Please read the notes on the back before filling this page}

1220385 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明說明(4·) 上述所謂「米糠類」係指米胚芽、脫脂米胚芽、米糠、 脫脂米糠等,上稍謂「黃絲」健職黃豆、金雞納粉 、黃豆粉、黃豆輛這些加水分解物等。此外,上述之「碳源 」’可使用一般所用者,可使用如葡萄糖、糊精、乳糖及澱 粉等的一種或兩種以上。通常這些添加比例,將米糠類設定 為100單位時,黃豆類係丨至20單位,最好是1〇至2〇單 位,碳源係20至80單位,最好是40至6〇單位。因為在這 些範圍時,對於菌的發育最理想。 上述之「培養基」,只要含有上述米糠類、黃豆類及碳 源,可繁殖納豆菌或乾轉菌者岐有_關。雖然通常 是液體培養基,但固體培養基也無妨。 而且,上述「納豆菌」及「乾草桿菌」,通常使用市售 的一般的育且菌或乾草桿菌。然而,儘管因自然,或亞硝基 胍等的化學質,X射線,料線等或因人為的變異方式獲得 ’菌學的性質為變異的黃豆菌或乾勤旱菌的變異株·,只要不 喪失含於本發明的米糠、黃豆發酵萃取物所產生的性質即可 利用。 上述發酵培養」,通常藉由通氣攪拌的方式進行。關 於此發酵培養的條件,雖然沒有特別限制,但通常酸驗值係 7·5至1〇,最好在8.5至1〇之間,培養溫度之程度係4〇至 =°C。調節培養基_雖時,可使用碳酸氫崎作為驗劑 等此外,可使用蛋白酶作為培養基原料。在此情況下, 由於可進而分解黃豆縮氨酸因此非常有用。 上述「米糠、黃豆發酵萃取物」的固體部份含有量 本紙張尺^適用中國國家標準(CNS)A4規格(210 x 297公^------- - (請先閱讀背面之注意事項再填寫本頁) —訂--------- 1220385 A7 ----—67 __ 五、發明說明"·) —^ -- (請先閱讀背面之注意事項再填寫本頁) 如本第2發明所示,若頭髮處理用劑組成物為1〇〇單位,則 其為〇篇單位以上,最好在咖單位以上更铜為刪 至二.5單位,最理想的是0.025至〇 〇5單位。米糖、黃豆發 酵卒取物的固體部份含有量未滿Ο·單位時,由於處理、 保濕等護髮效果降低因此不理想。 、利用本第1發明及本第2發明的頭髮處理用劑組成物處 理之已經芫成烫髮處理的頭髮,在相對溼度9〇%的水份量變 化率時,在下列實施例所述的試驗方法中,係6〇%以下,最 好是50%以下,更好的是45%以下,另外,利用不含有米 糠、黃豆發酵萃取物的頭髮處理用劑組成物處理之已經完成 燙髮處理的頭髮,在相對濕度90%之水份量變化率時,為 70%以下,最好為60%以下,更理想的是55%以下。 經濟部智慧財產局員工消費合作社印製 利用本第1發明及本第2發明的頭髮處理用劑組成物處 理之已經完成燙髮處理的頭髮,其半胱胺酸含量,在下列實 施例所述的諱驗方法中,對於僅燙髮處理的半胱胺酸含量為 80%以下,最好在75%以下,更理想的是70%以下,此外, 利用不含米糠、黃豆發酵萃取物的頭髮處理用劑組成物處理 之已完成燙髮處理的頭髮半胱胺酸含量為90%以下,最好在 80%以下。 本發明的頭髮處理用劑組成物,除作為處理劑獨立使用 以外,可作為各種頭髮處理用劑之添加劑,予先添加於燙髮 劑。此外,將本發明之頭髮處理用劑組成物中所含之米糠、 黃豆發酵萃取物作成粉末狀,濃縮物或水溶液的狀態另外獨 立準備,於使用時可將米槺、黃豆發酵萃取物添加、混合於 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 1220385 A7.1220385 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (4 ·) The so-called "rice bran" refers to rice germ, defatted rice germ, rice bran, and defatted rice bran, etc. Soybeans, soy flour, soy flour, soy flour and so on. In addition, the above-mentioned "carbon source" can be used generally, and one or two or more kinds such as glucose, dextrin, lactose and starch can be used. Generally, when these rice bran is set to 100 units, the soybeans are 20 to 20 units, preferably 10 to 20 units, and the carbon source is 20 to 80 units, and preferably 40 to 60 units. Because in these ranges, it is optimal for the development of bacteria. The "medium" mentioned above, as long as it contains the rice bran, soybeans, and carbon source, can be multiplied by natto bacteria or dry bacteria. Although usually a liquid medium, a solid medium is fine. In addition, as the "natto bacteria" and "dried bacillus", generally used commercially available fermented bacteria or dried bacillus are generally used. However, although it is obtained from natural, or chemical substances such as nitrosguanidine, X-rays, feed lines, etc., or from artificial variation, the 'mycological properties are mutant strains of soybeans or dry bacteria, as long as It can be used without losing the properties produced by the rice bran and soybean fermentation extract contained in the present invention. The above-mentioned "fermentation culture" is usually carried out by aeration and stirring. Although there are no particular restrictions on the conditions for this fermentation culture, the acid test value is usually from 7.5 to 10, preferably from 8.5 to 10, and the temperature of the culture is from 40 to = ° C. Conditioning medium_Although bicarbonate can be used as a test agent, etc. In addition, a protease can be used as a raw material of the medium. In this case, it is very useful because it can further decompose soy peptides. The solid content of the above "Rice Bran and Soybean Fermented Extract" The paper ruler ^ Applicable to China National Standard (CNS) A4 (210 x 297 mm) ^ --------(Please read the precautions on the back first (Fill in this page again) —Order --------- 1220385 A7 ----— 67 __ V. Description of the invention " ·) — ^-(Please read the notes on the back before filling this page) As shown in the second invention, if the hair treatment agent composition is 100 units, it is more than 0 units, and it is better to remove copper to 2.5 units or more, and most preferably 0.025. To 0.05 units. When the solid content of rice sugar and soybean fermented extract is less than 0 · units, it is not desirable because the hair-care effects such as treatment and moisturization are reduced. 2. The hair treated with the hair treatment composition of the first invention and the second invention has undergone perm treatment, and when the moisture content change rate is 90% relative humidity, the test described in the following example is performed. In the method, it is 60% or less, preferably 50% or less, and more preferably 45% or less. In addition, the hair that has been subjected to perm treatment is treated with a hair treatment agent composition that does not contain rice bran and soybean bean fermentation extract. When the relative humidity is 90%, the moisture content change rate is 70% or less, preferably 60% or less, and more preferably 55% or less. The cysteine content of hair that has been perm treated with the hair treatment agent composition of the first invention and the second invention is printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, as described in the following examples. In the taboo test method, the cysteine content of the perm-only treatment is 80% or less, preferably 75% or less, and more preferably 70% or less. In addition, hair treatment using rice bran and soybean-free fermented extract is not used. The content of cysteine in the hair after the permanent wave treatment is 90% or less, and preferably 80% or less. The hair treatment agent composition of the present invention can be used as an additive to various hair treatment agents in addition to being used independently as a treatment agent, and can be added to a permanent wave agent in advance. In addition, the rice bran and soybean fermented extract contained in the hair treatment agent composition of the present invention are powdered, and the state of the concentrate or aqueous solution is separately prepared. When used, rice fern and soybean fermented extract can be added, Mixed with this paper size: Applicable to China National Standard (CNS) A4 (210 X 297 mm) 1220385 A7.

I 訂 9 I I I I II order 9 I I I I I

裝 • I 1 n (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 1220385 -------— __Β7_____ 五、發明說明(7·) 器具的上方圖。 【為實施發明之最佳形式】 茲依實施例具體地說明本發明。此外,本發明不限定下· 列具體實施例所示。 (1) 供試試樣之調製 以脫脂米糠30.0kg,脫脂黃豆5.0kg,植酸鈣鎂5.0kg ,葡萄糖15.0kg,磷酸氬鈉10.0kg,磷酸氫銨2.5kg,碳酸 氳麵45.0kg,除泡劑〇.25kg,水500kg作為培養基原料。此 外,酸鹼值係9左右。 以121°C,30分鐘殺菌上述培養基,隨後冷卻,接著接 種納豆菌(廠商:成瀨發酵化學研究所)〇,〇5kg,以40至 45°C通氣、揽拌使培養約48小時,獲得培養物。 之後,壓縮過濾此培養物,利用活性碳酸及波萊鐵脫臭 、脫色,獲得大致透明液體的米糠、黃豆發酵萃取精(固體 部份濃度5重量百分比)。此外,可使用粉末活性碳·(活性 碳S、活性碳K等)’粒狀活性碳(活性碳SG等)等各種 活性碳,而波萊鐵’則使用「波莱鐵Ν〇· 418〇」( DiKalineorient股份有限公司製)。然後,壓縮過滤此米糠、 黃豆發酵萃取精,消除活性碳等,接著,使此米糠、黃豆發 酵萃取精溶解於蒸顧水作為5%水溶液,並且,添加檸檬酸 ,藉由將其酸鹼值調整為5·01,調製成本實施例所使用之供 試試樣。 (2) 處理劍的試驗方法(第1實施例) ①對於頭髮中水份的影響 本紙張尺度適用家標準(CNS)A4規^ϋο X 297公爱"7 ----訂---------. 1220385Equipment • I 1 n (Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 1220385 -------— __Β7 _____ 5. Description of the invention (7 ·) The top view of the appliance . [Best Form for Implementing the Invention] The present invention will be specifically described with reference to examples. The present invention is not limited to the specific examples shown below. (1) The test samples were prepared with 30.0 kg of defatted rice bran, 5.0 kg of defatted soybeans, 5.0 kg of calcium phytate, 15.0 kg of glucose, 10.0 kg of sodium argon phosphate, 2.5 kg of ammonium hydrogen phosphate, and 45.0 kg of noodles. Foaming agent 0.25 kg, water 500 kg as the raw material of the culture medium. In addition, the pH is about 9. The above medium was sterilized at 121 ° C for 30 minutes, then cooled, and then inoculated with Natto bacteria (manufacturer: Naruse Fermentation Research Institute) 0.05 kg, aerated at 40 to 45 ° C, and stirred for about 48 hours to obtain Cultures. Thereafter, the culture was compressed and filtered, and deodorized and decolored with activated carbonic acid and bolete to obtain rice bran and soybean fermented extract (solid content concentration: 5 weight percent) in a substantially transparent liquid. In addition, various activated carbons such as powdered activated carbon ((activated carbon S, activated carbon K, etc.) 'granular activated carbon (activated carbon SG, etc.) can be used, and Pole Iron' uses "Pole Iron No. 418. "(Made by DiKalineorient Co., Ltd.). Then, the rice bran and soybean fermented extract are compressed and filtered to eliminate activated carbon. Then, the rice bran and soybean fermented extract are dissolved in distilled water as a 5% aqueous solution, and citric acid is added to the pH value. Adjusted to 5.01, the modulation sample used in this example is for trial. (2) Test method for handling swords (1st embodiment) ① Influence on moisture in hair This paper applies the home standard (CNS) A4 rule ^ ϋο X 297 public love " 7 ---- order --- ------. 1220385

五、發明說明(8·) 在本第1實施例所使用的試驗群用處理劑的處方如下: 硅酮油 流動石堪 十六烷醇 1.5% 十八燒醇 1·〇% 氯化十八烷三甲銨 〇·7% 甘油 3.0% 加水分解角脘液 4.0% 以上述(1)調整之供試試樣10% 擰檬酸 適量(將酸驗值調整為7) 合計 100ml 此外,相對於上述以(1)調製的供試試樣’以同量的 水配合,作為對照群用處理劑。 將以硫乙二醇酸鹽為有效成份的冷卻二液式燙髮用劑 (大理花股份有限公司製rvenezel波浪燙髮」)處理的試驗 頭髮剪齊為15cm長度,以5%月桂酸硫酸鈉洗滌其約l〇g 以後,以水充份沖洗,以毛巾擦掉水份以後,將此試驗顏髮 裝入燒杯,注入以上述(1)調製的供試試樣至能夠浸泡試 驗頭髮。然後,在恆溫槽中以25。(:放置5分鐘後,取出試 驗頭髮,以毛巾擦掉水份。 接著對於試驗群的試驗頭髮,將上述試驗群用處理劑 20g塗敷於試驗頭髮整體使之親和,在恆溫槽中以4〇〇c放置 10分鐘,充份水洗後,以毛巾擦掉水份。一方面,對於對 照群的試驗頭髮,使用上逑對照群用處理劑2〇 和上述 ΐ紙張尺中國國家標準(CNS)A4規格 (請先閱讀背面之注意事項再填寫本頁)5. Description of the invention (8 ·) The formulation of the treatment agent for the test group used in the first example is as follows: silicone oil flowing stone cetyl alcohol 1.5% octadecyl alcohol 1.0% octadecyl chloride Trimethylammonium 〇.7% Glycerin 3.0% Hydrolyzed keratolytic solution 4.0% 10% of the test sample adjusted according to the above (1) Amount of citric acid (adjust the acid value to 7) 100ml in total The test sample prepared in (1) was mixed with the same amount of water as a treatment agent for the control group. The test hair treated with a cooling two-liquid perm agent (rvenezel wave perm by Dali Flower Co., Ltd.) containing thioglycolate as an active ingredient was trimmed to a length of 15 cm, and washed with 5% sodium laurate. After about 10 g, rinse thoroughly with water, wipe off the water with a towel, put this test hair into a beaker, and inject the test sample prepared in (1) above to soak the test hair. Then, take 25 in a thermostatic bath. (: After leaving for 5 minutes, remove the test hair and wipe off the water with a towel. Next, for the test hair of the test group, apply 20 g of the treatment agent for the test group to the entire test hair to make it compatible. 〇〇c Leave for 10 minutes, wash thoroughly with water, and wipe off the water with a towel. On the one hand, for the test hair of the control group, use the treatment agent 20 of the upper control group and the above-mentioned Chinese paper rule (CNS). A4 specifications (Please read the precautions on the back before filling this page)

m* 裝-------一訂--------- P 經濟部智慧財產局員工消費合作社印製 1220385 A7m * Pack ------- one order --------- P Printed by Consumer Consumption Cooperative of Intellectual Property Bureau, Ministry of Economy 1220385 A7

經濟部智慧財產局員工消費合作社印製 試驗群相同的順序實施處理。 然後,將對照群及試驗群的試驗頭髮設定為4等份,測 定以溫度25°C,相對溼度20、40、65及90%的條件下放置 3小時後的各試驗頭髮的重量(wb),其次,以l〇5°c乾燥 測定結束後的頭髮至悝量,測定此乾燥後的各試驗頭髮的重 量(Wa)〇 試驗頭髮的水份量(%)係根據重量法求出( FRAGRANCE JOURNAL 臨時增刊 NO· 13 (1994)第 128 頁〜第129頁)。表一及圖一顯示此試驗結果。此外,在表一 ,所謂試驗頭髮的水分量(%)及水份量變化率(%),係 指以下式顯示的數值。 水份量(%) = (Wb-Wa) Xl00/Wb 水份量變化率(%) = (Wx-W2G) Xl〇〇/W20 w20:在相對濕度20%的水份量 Wx:相對濕度X%的水份量 ②對於半胱胺酸含量的影響 以和上述①相同的順序作處理劑之處理,以25°C,相 對濕度65%乾燥的對照群及試驗群的各種試驗頭髮,根據酸 加水分解法測定半胱胺酸含量(/zmol/g)。亦即,在試驗頭 髮10mg中添加6N鹽酸2m卜以真空封管以後,減壓乾固 以ll〇°C加水分解24小時者,以氨基酸分析器(日本電子 股份有限公司製「JLC-300」)測定以檸檬酸鈉緩衝液( Na+0.2N,酸鹼值2.2)稀釋,過濾者。 而且,作為比較例,未以燙髮劑處理的試驗頭髮,和’燙 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -----------Φ裝--------訂---------, (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 1220385 A7 B7 ----~---- 五、發明說明(10·) 髮劑處理後,以5%月桂酸硫酸鈉溶液洗滌後,以水充份 洗,以25Ό,相對濕度65%乾燥的試驗頭髮,也以和^千〔 相同順序測定半脱胺酸含量(#mol/g)。 以下的表一及圖^一顯不以上的測定結果。 (3)燙髮劑的試驗方法(第2實施例) ①—波浪效率的測定、評估 為評估本實施例的燙髮劑的燙髮形成力,根據作為燙髮 劑的波紋效果測定法被最通用的試驗法曲線法(參閱D hPrinted by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, the test group is processed in the same order. Then, the test hairs of the control group and the test group were set to 4 equal parts, and the weight (wb) of each test hair after being left for 3 hours under the conditions of a temperature of 25 ° C and a relative humidity of 20, 40, 65, and 90% was measured. Next, the hair after drying measurement was finished at 105 ° C to the amount of hair, and the weight (Wa) of each test hair after drying was measured. The moisture content (%) of the test hair was determined according to the gravimetric method (FRAGRANCE JOURNAL Temporary Supplement No. 13 (1994), pages 128 to 129). Table 1 and Figure 1 show the results of this test. In Table 1, the moisture content (%) and the moisture content change rate (%) of the test hair refer to the values shown in the following formulas. Water content (%) = (Wb-Wa) Xl00 / Wb Water content change rate (%) = (Wx-W2G) X100 / W20 w20: Water content at 20% relative humidity Wx: Water at relative humidity X% The effect of the amount ② on the content of cysteine is treated in the same order as in the above ①. The test hairs of the control group and the test group dried at 25 ° C and 65% relative humidity are measured according to the acid hydrolysis method. Cysteine content (/ zmol / g). That is, after adding 6N hydrochloric acid 2m to 10 mg of test hair and sealing the tube with vacuum, the solution was dried under reduced pressure and solidified at 110 ° C for 24 hours. The amino acid analyzer ("JLC-300" manufactured by Japan Electronics Co., Ltd.) was used. ) Determination was diluted with sodium citrate buffer (Na + 0.2N, pH value 2.2), and filtered. Moreover, as a comparative example, the test hair that was not treated with a permanent wave agent, and the size of the ironing paper are applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) ----------- Φ pack -------- Order ---------, (Please read the notes on the back before filling this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 1220385 A7 B7 ---- ~ ---- V. Description of the invention (10 ·) After the hair treatment, the test hair was washed with 5% sodium laurate solution, washed with water, dried at 25 ° F, and 65% relative humidity. Thousands [Semi-deaminated acid content (# mol / g) was determined in the same order. The following Table 1 and Figure ^ 1 show the above measurement results. (3) Test method of perm agent (second embodiment) ①—Measurement and evaluation of wave efficiency In order to evaluate the perm formation force of the perm agent of this example, it is the most commonly used test method according to the wave effect measurement method of perm agent. Curve method (see D h

KirbyJProceedings of the Scientific Section,26,12 [1956]), 評估本實施例的燙髮劑的波浪效果。 以5%月桂酸硫鈉液洗滌剪齊為長度2〇cm的試驗頭髮( 從同一人物採取)以後,以水充份沖洗,以室溫使其自然乾 燥’乾燥後’將試驗頭髮作成一束20條的髮束,以接著劑 固定於接近髮根那一端。 將上述髮束固定於圖六所示的波浪器具。此在本第2 實施例所使用的波浪器具1係如圖六所示;由波浪形成部 11,髮束固定部12及桿13所構成。此波浪形成部u,髮 束固定部12及样13皆為塑膠製。波浪器具1的大小係縱 10mm,橫70mm,厚度6mm之長方體形狀,其中,波浪形 成部11係橫50mm,髮束固定部12係橫ΙΟηπη。此外,桿 13係3mm0的圓柱形狀,相鄭的桿間隔(圓的中心間的距 離)係6mm。 將固定髮束的波浪器具裝入玻璃器盤,注入以上述(1 )調製的供試裁樣至能夠浸泡髮束。在恆溫槽中將上述髮束 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) ------------^--------^-------- (請先閱讀背面之注意事項再填寫本頁) 波浪效率(%) =100—【100X (B-A) / (C_A)】 1220385 五、發明說明(1¾) 以坑,放置5分鐘後,丟棄供試試樣’接著將以15%供 試試樣配合的市錢髮劑(第丨劑)注人至能夠浸泡髮束。 然後,在恆溫槽中以坑放置上述髮束15分鐘後,水洗以 後>王入以m供試試樣配合的市售费髮劑(第2劑),同樣 地以25 c,放置is分鐘,充份水洗。將此髮束作 ’取代供試試樣將使用水者作為触群。以後,從器具中將 髮束拆除,測定卿成的波紋距離(頂部5個部份^距離) 根據下式求&波紋效率(%)。結果顯示於以下的表三及 A:器具的第1支桿及第6支桿的間隔(因器具而固定) 所形成的波浪距離(頂部5個部份的距離) 筆直伸出B時的距離(因器具而一定) 此外,這次使用的市售燙髮劑(第1劑及第2劑),使 用以硫乙二醇酸鹽為有效成份的冷卻二液式燙髮用劑(大理 花股份有限公司製「venezel波浪费髮」)。 ②波浪保持率的測定、評估 將依上述①的處理附加波紋的試驗群及對照群的髮束浸潰 於20%月桂酸硫酸鈉溶液,在恆溫槽中以60。(:,放置1小 時(虐待試驗)。水洗後,測定試驗及對照群的髮束,所保 持的波紋距離(頂部5個部份的距離),根據上述公式計算 波紋效率,從此波紋效率,根據以下公式求出波紋保持率。 結果顯示於以下的表三及圖三。Kirby J Proceedings of the Scientific Section, 26, 12 [1956]), to evaluate the wave effect of the permanent wave agent of this example. Wash and cut the test hair with a length of 20 cm (taken from the same person) with 5% sodium laurate solution, rinse it with water, and let it dry naturally at room temperature. 20 hair tresses are fixed to the end near the root with adhesive. The hair bundle is fixed to the wave appliance shown in FIG. The wave appliance 1 used in the second embodiment is shown in Fig. 6; it is composed of a wave forming portion 11, a hair fixing portion 12 and a rod 13. The wave forming portion u, the hair-fixing portion 12 and the sample 13 are made of plastic. The size of the wave device 1 is a rectangular parallelepiped shape with a length of 10 mm, a width of 70 mm, and a thickness of 6 mm. Among them, the wave-forming portion 11 is 50 mm in width, and the tresses fixing portion 12 is 10 nπη. In addition, the rod 13 has a cylindrical shape of 3 mm0, and the phase distance (distance between the centers of the circles) of the corresponding rods is 6 mm. The wave appliance that fixes the hair bundle is put into a glass dish, and the test sample prepared according to the above (1) is injected until the hair bundle can be soaked. Apply the above-mentioned hair strands in a thermostatic bath to the paper size of China National Standard (CNS) A4 (210 X 297 mm) ------------ ^ -------- ^- ------- (Please read the notes on the back before filling in this page) Wave efficiency (%) = 100— [100X (BA) / (C_A)] 1220385 V. Description of the invention (1¾) Place in a pit After 5 minutes, discard the test sample, and then inject 15% of the test sample with the commercial hair preparation (the first agent) to be able to soak the hair tress. Then, place the hair tress in a constant temperature bath for 15 minutes, and after washing with water, Wang Rong used a commercially available hairspray (second agent) with a sample size of m. Similarly, it was placed at 25 c for 15 minutes. , Fully washed. Make this hair bundle ’instead of using the test sample to use water as a contact group. After that, the hair bundle was removed from the device, and the ripple distance (the distance of the top 5 parts) was measured. The & ripple efficiency (%) was calculated according to the following formula. The results are shown in the following Tables 3 and A: The distance between the 1st and 6th poles of the appliance (fixed by the appliance) The wave distance (distance of the top 5 parts) The distance when straight out of B (It depends on the appliance.) In addition, the commercially available permanent wave agent (the first and second agents) used this time uses a cooling two-liquid permanent wave agent with thioglycolate as an active ingredient (Dalihua Co., Ltd. System "venezel wave waste hair"). (2) Measurement and evaluation of wave retention rate The hair bundles of the test group and the control group which were added with waves according to the above (1) were immersed in a 20% sodium laurate solution, and 60 in a thermostatic bath. (:, Leave it for 1 hour (abuse test). After washing, measure the hair bundles of the test and control groups, and maintain the ripple distance (distance of the top 5 parts), and calculate the ripple efficiency according to the above formula. The following formula was used to obtain the ripple retention ratio. The results are shown in Table 3 and Figure 3 below.

波浪保持率(%) =q〇〇XD/E 本紙張尺度適用帽國家標準(CNS)A4規格(21G χ撕公爱}" 螬 fmWave retention rate (%) = q〇〇XD / E This paper size is applicable to the national standard (CNS) A4 size of the cap (21G χ tear public love) " 螬 fm

Μ--------1---------. (請先閱讀背面之注意事項再填寫本頁) -fill 1220385 1 2 B7 五、發明說明(I2·) D:虐待試驗後的波浪效率(%) E:虐待試驗前的波浪效率(%) ③冷卻·臭味的測定、評估 將和上述①相同順序處理之試驗頭髮用室溫使之自然 乾燥。將試驗頭髮〇.lg裝入味覺感應器,用測定瓶密封, 以25°C放堇60分鐘,使用味覺感應器(FRAGRANCE SENSOR SF-105,相互藥工股份有限公司製),以密閉式飽 和法測定氣相鄰的臭氣,評估冷卻臭味。然後’以25°C保 存試驗頭髮,繼續測定10日。測定結果顯示於以下的表四 及圖四。 此外,同時依官能檢查實施冷卻臭味的評估,自實施變 髮後起實施10日,期間以25°C保存試驗頭髮。以丨〇人貧 施檢查,以下列評估點顯示臭氣強度。此測定結果(顯示評 估點的人數)顯示於表五,評估點合計顯示於圖五。 臭氣強度 評估點 無臭 勉強可察覺之臭味 可判fe/f臭味種類的程度 3 容易察覺之臭味 4 強烈臭味 5 297公釐) -----------裝--------訂--------- (請先閱讀背面之注意事項再填寫本頁} 經 濟 部 智 慧 財 產 局 員 工 消 費 合 作 社 印 製 1220385 A7 B7 五、發明說明U3.) 表1 相對溼度(%) 對照群 試驗群 水分含有量 (%) 變化率(%) 水分含有量 (%) 變化率(%) 20 8.3 0 10.0 0 40 9.4 13 10.6 6 65 12.5 51 12.1 21 90 15.2 83 14.1 41 表2 半胱胺酸含量(/zmol/g)' 未處理燙髮 172 僅處理燙髮 288 對照群 243 試'群 186 -----------裝--------訂—丨丨— (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 表3 對照群 試驗群 波浪效率(%) 51.7 65.0 標準偏差 1.27 1.37 波浪保持率(%) 68.2 79.8 標準偏差 1.27 1.37 太紙張尺唐i®用中國國家標準(CNS)A4規格(210 X 297公釐) 1220385 A7 B7 五、發明說明(14.) 表4 經過曰數⑻ 測定值(Hz) 對照群 拭驗群 0 155 117 1 124 78 2 89 54 3 75 28 4 58 22 5 39 20 6 29 19 7 25 21 8 .20 18 9 21 19 10 18 18 ^wi ^ I---I I I --I I I I I (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) -18 - 1220385 A7 B7 五、發明說明(I5·) 表5 (對照群) 經過曰數⑻ 評估點 1 2 3 4 5 合計 0 5 5 45 1 2 5 3 41 2 2 4 4 32 3 2 5 3 31 4 3 5 2 29 5 3 6 1 28 6 1 4 5 24 7 2 7 1 19 8 5 5 15 9 8 2 12 10 9 1 11 經濟部智慧財產局員工消費合作社印製 (試驗群) 經過曰數(曰) 評估點 1 2 3 4 5 合計 0 4 5 1 37 1 2 5 3 31 2 3 6 1 28 3 1 4 5 24 4 2 4 4 22 5 2 5 3 21 6 3 5 2 19 7 2 7 1 19 8 4 6 16 9 1 9 1 11 10 10 10 — — — — — —--I I ^ !1111 ^ίιιιιιι (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) _ 10 - 經濟部智慧財產局員工消費合作社印製 1220385 —-------— 五、發明說明(16·) (4)實施例的效果 如果頭髮有損傷,即降低頭髮的水份保持能力,結 增加因環境中水份變化的頭髮中水份變化。亦即,在^燥環 境下頭髮巾的水份量減少,以致絲絲,而若在濕潤 環境下頭髮中水份量過多,則形成缺乏彈性的頭髮。因此, 隨著環境中水份變化的頭髮中水份變化,成為評估頭髮損傷 的基準。 ' 由表一及圖一即可明白,如果比較以往使用的含有加水 分解角脘之處理劑處理的對照群,和再併用米糠、黃豆發酵 萃取物的試驗群,在對照群中,如果相對濕度從2〇%變為 90%,即增加約83%的頭髮中水份量,相對地在試驗群中, 止於增加的41%程度,水份量變化小。 由此結果即可明白,添加米糠、黃豆發酵萃取物的處理 劑處理的試驗群,在低濕度環境下的乾燥及在高濕度下的水 份吸收被抑制,隨著環境中水分變化的頭髮中水份變化小,· 因處理劑而增強水份保持能力。 如果因燙髮劑處理的二硫化物結合(s名結合)恢復不 完全,SH基即被氧化形成s〇3H基產生半胱胺酸。結果弄 壞頭髮的構造,容易引起頭髮成份的溶離造成損傷。因此, 頭髮中的半胱胺酸含有量,成為頭髮損傷評估的基準。 由表二及圖二即可明白,將實施燙髮處理的頭髮半胱胺 含有量288/zmol/g和未處理烫髮的頭髮(172/m〇1/g)做 比較,顯π相當大的數值。然後,在以往即被使用的含有加 水分解角脘之處理劑處理的對照群中,含量為243//m〇1/g 本紙張尺度適用中國國家標準(CNS)A4規格⑽x 297公董) (請先閲讀背面之注意事項再填寫本頁)Μ -------- 1 ---------. (Please read the notes on the back before filling out this page) -fill 1220385 1 2 B7 V. Description of the Invention (I2 ·) D: Abuse Wave efficiency after the test (%) E: Wave efficiency before the abuse test (%) ③ Measurement and evaluation of cooling and odor The test hair treated in the same order as the above-mentioned ① was dried naturally at room temperature. The test hair 0.1 g was placed in a taste sensor, sealed in a measuring bottle, and the cord was placed at 25 ° C for 60 minutes. A taste sensor (FRAGRANCE SENSOR SF-105, manufactured by Hugo Pharmaceutical Co., Ltd.) was used to saturate in a closed manner. The method measures the adjacent odor and evaluates the cooling odor. Then, the test hair was stored at 25 ° C, and the measurement was continued for 10 days. The measurement results are shown in Table 4 and Figure 4 below. At the same time, the evaluation of cooling odor was performed based on the sensory inspection, and the test hair was stored at 25 ° C for 10 days after the change. Examination was performed with ○ 0 people poor, and the odor intensity was displayed at the following evaluation points. The measurement results (the number of people who displayed the evaluation points) are shown in Table 5, and the total number of evaluation points is shown in Figure 5. Odor intensity evaluation point No odor, barely detectable odor, degree of fe / f odor type can be judged 3, easily detectable odor 4, strong odor 5 297 mm) ----------- pack- ------- Order --------- (Please read the notes on the back before filling out this page} Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy 1220385 A7 B7 V. Invention Description U3.) Table 1 Relative humidity (%) Control group test group water content (%) change rate (%) water content (%) change rate (%) 20 8.3 0 10.0 0 40 9.4 13 10.6 6 65 12.5 51 12.1 21 90 15.2 83 14.1 41 Table 2 Cysteine content (/ zmol / g) 'Untreated perm 172 Only perm 288 Control group 243 Test' Group 186 ----------- pack ------ --Order— 丨 丨 — (Please read the precautions on the back before filling out this page) Printed by the Intellectual Property Bureau, Ministry of Economic Affairs, Employee Consumption Cooperatives Table 3 Control group test group wave efficiency (%) 51.7 65.0 Standard deviation 1.27 1.37 Wave retention (%) 68.2 79.8 Standard Deviation 1.27 1.37 Tai Chi Paper Ruler for Chinese Standard (CNS) A4 (210 X 297 mm) 1220385 A7 B7 、 Explanation of the invention (14.) Table 4 Number of measured values (Hz) Control group swab group 0 155 117 1 124 78 2 89 54 3 75 28 4 58 22 5 39 20 6 29 19 7 25 21 8 .20 18 9 21 19 10 18 18 ^ wi ^ I --- III --IIIII (Please read the precautions on the back before filling out this page) Printed on paper scales of the Intellectual Property Bureau of the Ministry of Economic Affairs, Employee Consumer Cooperatives, the Chinese national standard (CNS ) A4 specification (210 X 297 mm) -18-1220385 A7 B7 V. Description of the invention (I5 ·) Table 5 (Control group) Number of passing points Evaluation point 1 2 3 4 5 Total 0 5 5 45 1 2 5 3 41 2 2 4 4 32 3 2 5 3 31 4 3 5 2 29 5 3 6 1 28 6 1 4 5 24 7 2 7 1 19 8 5 5 15 9 8 2 12 10 9 1 11 Consumption by employees of the Intellectual Property Bureau of the Ministry of Economic Affairs Printed by the cooperative (experimental group) Elapsed number (say) Evaluation point 1 2 3 4 5 Total 0 4 5 1 37 1 2 5 3 31 2 3 6 1 28 3 1 4 5 24 4 2 4 4 22 5 2 5 3 21 6 3 5 2 19 7 2 7 1 19 8 4 6 16 9 1 9 1 11 10 10 10 — — — — — —-- II ^! 1111 ^ ίιιιιιι (Please read the back first Please pay attention to this page, please fill in this page) This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) _ 10-Printed by the Consumers' Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs 1220385 —-------— V. Description of the invention (16 ·) (4) Effect of the embodiment If the hair is damaged, it will reduce the hair's moisture retention ability, and increase the moisture change in the hair due to the change of the moisture in the environment. That is, the moisture content of the hair towel is reduced in a dry environment, so that it becomes silky, and if the moisture content in the hair is excessive in a humid environment, hair with inelasticity is formed. Therefore, the change in moisture in the hair as the moisture in the environment changes becomes the benchmark for assessing hair damage. '' From Table 1 and Figure 1, it can be understood that if the control group treated with the hydrolyzed keratin treatment agent used in the past is compared with the test group that is combined with rice bran and soybean fermentation extract, if the relative humidity is in the control group, From 20% to 90%, that is, about 83% of the water in the hair was increased, and in the test group, the increase in water content was only 41%, and the change in water content was small. From this result, it can be understood that in the test group treated with the treatment agent added with rice bran and soybean fermented extract, drying in a low-humidity environment and water absorption under a high-humidity were suppressed, and the hair changed with the moisture in the environment. Moisture change is small, · Water retention ability is enhanced by treatment agent. If the disulfide bond (s-name bond) is not completely restored due to the perm agent treatment, the SH group is oxidized to form a so3H group to produce cysteine. As a result, the structure of the hair is damaged, and it is easy to cause the hair ingredients to dissolve and cause damage. Therefore, the content of cysteine in hair becomes the benchmark for evaluating hair damage. As can be seen from Table 2 and Figure 2, when comparing the cysteamine content of hair perforated with 288 / zmol / g and untreated perm hair (172 / m〇1 / g), it shows that π is quite large. Value. Then, the content of the control group treated with the hydrolyzed keratin-containing treatment agent in the past was 243 // m01 / g. This paper standard is applicable to the Chinese National Standard (CNS) A4 specification (x 297). ( (Please read the notes on the back before filling out this page)

五、發明說明(I7·) ’和實施k;髮處理的頭髮做比較,減少約17%。相對地,在 併用米糠、黃豆發酵萃取物的試驗群中顯示i 86 # mol/g,和 未處理燙髮大致同程度的數值,而且,和實施燙髮處理過的 頭髮相比較,減少約37%,此外,和對照群比較也減少约 24/% 〇 從以上即可明白,藉由將本實施例的米糠、黃豆發酵萃 取物添加於處理劑’因加水分解角胱而增強半胱胺酸的抑制 生長效果,結果復原至和未處理憂髮的頭髮大致相同。 如果根據表三及圖三,比較對照群和試驗群的波浪效率 ’即顯示試驗群的波浪效率65%,較對照群(51.7%)大約 26%的數值。波浪效率大,表示所形成的波浪距離(頂部$ 個部份的距離)小,亦即,燙髮劑的效果強。 此外’如果比較對照群和試驗群的波浪保持率,即顯示 試驗群的波浪保持率79·8%,較對照群(68·2%)大17〇/〇的 數值。波浪保持率大,表示相對於虐待試驗前的波浪效果試 驗後的波浪效果大,亦即,經過虐待試驗仍然保持波浪的形 狀。 由以上即可明白,藉由在燙髮劑中併用米糠、黃豆發酵 萃取物在爹髮處理時有效地形成波浪,而且,可保持所形 成的波紋形狀。 由表四及圖四即可明白,如果根據味覺感應器測定之燙 髮處理後的冷卻臭味比較對照群和試驗群,在對照群中從燙 髮處理時起測定值高,而且儘管經過數日冷卻臭味的降低比 例仍小,測定值達到平常狀態需花費六日。相對地,在試驗 1220385V. Description of the invention (I7 ·) ′ Compared with the treatment of k; hair, the reduction is about 17%. On the other hand, in the test group using rice bran and soybean fermented extract in combination, i 86 # mol / g showed a value approximately the same as that of the untreated perm, and compared with the hair subjected to the perm treatment, it was reduced by about 37%. In addition, compared with the control group, it was also reduced by about 24 /%. 〇 From the above, it can be understood that by adding the rice bran and soybean fermentation extract of this example to the treatment agent, cysteine inhibition was enhanced by hydrolyzing keratin The growth effect was restored to about the same as untreated hair. According to Table 3 and Figure 3, comparing the wave efficiency of the control group and the test group ′ shows that the wave efficiency of the test group is 65%, which is about 26% higher than the control group (51.7%). The high wave efficiency means that the distance of the wave (the distance of the top part) is small, that is, the effect of the permanent wave is strong. In addition, if the wave retention rate of the control group and the test group is compared, it means that the wave retention rate of the test group is 79.8%, which is a value of 17/0 larger than that of the control group (68.2%). A large wave retention rate indicates a large wave effect after the wave effect test before the abuse test, that is, the wave shape is maintained after the abuse test. From the above, it can be understood that the use of rice bran and soybean fermented extract in a permanent wave agent effectively forms waves during the hair treatment, and also maintains the formed wave shape. As can be understood from Table 4 and Figure 4, if the cooling odor after perm treatment measured by the taste sensor is compared with the control group and the test group, the measured value in the control group from the time of the perm treatment is high, and despite cooling for several days, The reduction rate of odor is still small, and it takes six days for the measured value to reach the normal state. In contrast, in test 1220385

經濟部智慧財產局員工消費合作社印製Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs

群中從燙髮處理時起測定值低,而且,冷卻臭味的降低比例 大,經過三日後測定值已經達到平常狀態。 而且’如果由表五及圖五,比較有關依官能試驗的燙髮 處理後的冷卻臭味對照群和試驗群,即發現和上述表四和圖 四相同的傾向。亦即,在對照群中從燙髮處理時起評估點( 合計值)高,而且儘管經過數日冷卻臭味的降低比例仍小, 儘管由半數以上者評估至(評估點2以下)不太感覺冷卻臭 味卻需花費六曰。相對地,在試驗群從燙髮處理時起評估點 (合計值)低,而且,冷卻臭味的降低比例大,經過三日後 經由半數以上者評估不太感覺冷卻臭味。 由以上即可明白,如果燙髮劑併用米糠、黃豆發酵萃取 物即可抑制燙髮劑主要從硫磺成份而產生的冷卻臭味。 【產業上之利用可能性】 如果根據本第1發明及第2發明的頭髮處理用劑組成物 ,藉由併用米糠、黃豆發酵萃取物,和習知之處理劑或烫髮 劑比較,即顯示優良的保濕效果、護髮效果,而且,在烫髮 波浪處理時形成優良的波浪及發揮保持效果,同時可抑制從 赛邊劑而來的硫磺等不舒服臭味。結果可作為處理劑或烫髮 劑等的各種頭髮處理用劑合適地利用。 *tr--------- (請先閱讀背面之注意事項再填寫本頁)In the group, the measured value was low from the perm treatment, and the reduction rate of cooling odor was large. After three days, the measured value had reached the normal state. Furthermore, if Table 5 and Fig. 5 are compared with the cooling odor control group and the test group after perm treatment according to the functional test, the same tendency as that of Table 4 and Fig. 4 is found. That is, in the control group, the evaluation point (total value) is high from the time of the perm treatment, and although the reduction rate of the odor is still small after several days of cooling, although it is not felt to be evaluated by more than half of them (below the evaluation point 2) It takes six months to cool the odor. In contrast, in the test group, the evaluation point (total value) was low from the perm treatment, and the reduction rate of cooling odor was large. After three days, more than half of the evaluations did not feel cooling odor. From the above, it can be understood that if the perm agent is used in combination with rice bran and soybean fermented extract, the cooling odor generated mainly by the sulfur component of the perm agent can be suppressed. [Industrial Applicability] If the hair treatment agent composition according to the first invention and the second invention is used in combination with rice bran and soybean fermented extract, it will be superior to conventional treatment agents or perm agents. It has a moisturizing effect and a hair-care effect. In addition, it forms an excellent wave and shows a retaining effect during the perm wave treatment. At the same time, it can suppress uncomfortable odors such as sulfur from the side effect agent. As a result, it can be suitably used as various hair treatment agents such as a treatment agent and a permanent wave agent. * tr --------- (Please read the notes on the back before filling this page)

本紙張尺度適用中國準(CNS)A4規格(21〇 297公釐)This paper size applies to China Standard (CNS) A4 (21〇 297 mm)

Claims (1)

1220385 申請專利範圍1220385 Patent Application Scope 現 ,翁 第89109842號專利案申請專利範圍修正本 1. 一種頭髮處理用發酵組成物,其特徵為,在含有100單 位之米糖類,1至20單位之黃豆類及20至80單位之碳 源的培養基接種納豆菌或乾草桿菌,含有以PH值7.5至 10,溫度40°C至45°C實行通氣攪拌之發酵培養後所穫得 之米糠、黃豆發酵萃取物。 2. 根據申請專利範圍第1項所述之頭髮處理用發酵組成 物,其中,若頭髮處理用劑組成物為100單位,則上述 米糠、黃豆發酵萃取物的固體部份含有量為0.005單位以 上0 (請先聞讀背面之注意事項再填寫本買) 訂 私 線 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) -23-At present, Weng No. 89109842 patent application amendments to the scope of patent application 1. A fermentation composition for hair treatment, characterized by containing 100 units of rice sugar, 1 to 20 units of soybeans and 20 to 80 units of carbon source The culture medium is inoculated with natto bacteria or hay bacillus, and contains fermented rice bran and soybean bean extracts obtained after fermentation and aeration with a pH of 7.5 to 10 and a temperature of 40 ° C to 45 ° C. 2. The hair treatment fermentation composition according to item 1 of the scope of the patent application, wherein if the hair treatment agent composition is 100 units, the solid content of the rice bran and soybean fermentation extract is 0.005 units or more 0 (Please read the precautions on the back before filling in this purchase) Order printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, Employees' Cooperatives, printed on this paper, applicable to China National Standard (CNS) A4 (210X297 mm) -23-
TW089109842A 1999-05-24 2000-05-22 Hair-treatment fermentation composition TWI220385B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11143229A JP2000327538A (en) 1999-05-24 1999-05-24 Agent composition for hair treatment

Publications (1)

Publication Number Publication Date
TWI220385B true TWI220385B (en) 2004-08-21

Family

ID=15333915

Family Applications (1)

Application Number Title Priority Date Filing Date
TW089109842A TWI220385B (en) 1999-05-24 2000-05-22 Hair-treatment fermentation composition

Country Status (5)

Country Link
JP (1) JP2000327538A (en)
KR (1) KR20010079544A (en)
AU (1) AU4779400A (en)
TW (1) TWI220385B (en)
WO (1) WO2000071087A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112022792A (en) * 2020-09-27 2020-12-04 黑龙江省中医药科学院 Preparation method of edible traditional Chinese medicine hair dye with homology of medicine and food

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003012475A (en) * 2001-07-03 2003-01-15 Hiroko Kondo Shampoo agent and treatment agent
CN101431980B (en) * 2006-05-02 2012-08-01 株式会社东洋发酵 Fermented product composition, cosmetic composition and method of producing the same
JP5554909B2 (en) * 2008-08-27 2014-07-23 ホーユー株式会社 Hair treatment composition
KR101104958B1 (en) * 2008-12-18 2012-01-19 권오현 Cosmetic composition for hair
KR101662603B1 (en) * 2013-12-18 2016-10-06 (주)제니트리 Cosmetic composition for prevention of depilation and improvement of hair growth having fermented peptone having activator of dermal papilla cell and geminal matrix cell, and formulation having the same
KR101443122B1 (en) * 2013-12-27 2014-09-24 김건영 permanent waving agents and method
KR101971643B1 (en) * 2017-04-28 2019-04-24 주식회사 마크로케어 Composition for Improving Condition of Damaged Hair and Preparation Method Thereof
JP7109935B2 (en) * 2018-02-20 2022-08-01 株式会社ミルボン Methods for evaluating hair damage and methods for testing compounds or compositions

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2640349B2 (en) * 1987-10-15 1997-08-13 株式会社三光生物科学研究所 Hair restoration
JP2553906B2 (en) * 1988-04-01 1996-11-13 株式会社三光生物科学研究所 Hair nourishment
JPH069474B2 (en) * 1990-03-20 1994-02-09 有限会社ビセイケン Method for producing alcohol-fermented fermented product and alcohol-fermented fermented food
DK292D0 (en) * 1991-11-29 1992-01-02 Tanisake Kk MEDITERRANEAN
JP3737526B2 (en) * 1994-03-08 2006-01-18 株式会社創研 Cosmetics from rice bran

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112022792A (en) * 2020-09-27 2020-12-04 黑龙江省中医药科学院 Preparation method of edible traditional Chinese medicine hair dye with homology of medicine and food
CN112022792B (en) * 2020-09-27 2022-12-09 黑龙江省中医药科学院 Preparation method of edible traditional Chinese medicine hair dye with homology of medicine and food

Also Published As

Publication number Publication date
JP2000327538A (en) 2000-11-28
KR20010079544A (en) 2001-08-22
AU4779400A (en) 2000-12-12
WO2000071087A1 (en) 2000-11-30

Similar Documents

Publication Publication Date Title
EP2123250A1 (en) Hair-shape controlling composition
JP2010105964A (en) Aftertreatment agent for permanent wave and hair color
TWI220385B (en) Hair-treatment fermentation composition
JP4611105B2 (en) Hair treatment agents containing peptides
JP6131220B2 (en) Use of fermented dairy products for skin treatment
JP2003081785A (en) Treatment agent for permanent wave and method for forming permanent wave by using the same agent
JPS61158912A (en) Composition for amelioration of skin
JP3648180B2 (en) Permanent wave second agent composition and two-bath permanent wave agent
JP2008088105A (en) Cosmetic for skin or hair
KR101428576B1 (en) Autolysate of Lugworm Marphysa sanguinea for Hair Improving and Composition of Hair Cosmetics Using Them Thereof
JP2009161519A (en) Cosmetic base material and hair cosmetic
JP2003300843A (en) Hair treatment agent and hair treatment method
JP5049758B2 (en) Hair treatment agent
JP2005247692A (en) Hair cosmetic
Kolar et al. Hair straighteners
KR101664333B1 (en) Cosmetic composition for hair styling using reducing substance and marine collagen peptide
JP2003040727A (en) Hair cosmetic
JP2003277241A (en) Hair cosmetics
JP2010215540A (en) Straight hair-forming cosmetic
JP4344644B2 (en) Cosmetic base material
JPS60112710A (en) Hair treatment composition
JP3638892B2 (en) Permanent wave agent
JP2010215539A (en) Curl-forming cosmetic
JPH02138206A (en) Hair dyeing agent composition
JP2004175684A (en) Cosmetic

Legal Events

Date Code Title Description
MM4A Annulment or lapse of patent due to non-payment of fees