KR101443122B1 - permanent waving agents and method - Google Patents

Abstract

Disclosed are a permanent wave liquid composition and a method for molding a permanent wave. A natural mineral mixture solution is applied to hairs containing moisture, and a permanent agent mixed with a hair permanent reducing agent and a natural mineral mixture is coated on the hairs. At the same time as, before, or after the same, while a mechanical tensile force is applied to the hairs using a hair molding member, heating is performed for 20-50 minutes so that the hairs are naturally dried and a permanent wave is completed. An oxidizing agent for neutralizing the reducing agent is not separately used. The natural mineral mixture includes natural organic ion minerals, saponine, and polyphenol. It is preferable that the mixed ratio of the reducing agent, natural organic ion minerals, saponine, and polyphenol are respectively 77.0-95.0 wt%, 3.5-20.0 wt%, 1.0-5.0 wt%, and 0.1-1.0 wt%. An oxidizing agent is not used, so that oxidizing agent side effects can be prevented, and a permanent wave molding time can be reduced. By means of the natural organic ion minerals and polyphenol, hair damage can be minimized. Gloss, softness, and elasticity are provided to the hairs having the permanent wave. Also, permanent sustaining strength is improved.

Description

Permanent liquid compositions and permanent waving agents and methods

The present invention relates to a permanent liquid (or permanent) composition for permanent shaping of hair and a permanent shaping method using the permanent liquid composition. More specifically, the present invention relates to a permanent liquid composition And a permanent forming method. Here, the expression " permanent molding method " means any permanent method for waving, curling, straightening, or relaxing hair.

The hair is composed mainly of keratin, which is a fibrous protein polymer composed of 18 amino acids. Of the amino acids that make up keratin, cysteine accounts for about 16%. The keratin is characterized by a crosslinking structure with one disulfide bond (-S-S-) per 10 to 20 amino acid residues on average, and this disulfide bond determines the tertiary structure of the protein by folding. Representing the structure of keratin is cystine.

The shape of the hair is mainly formed by disulfide bonding of cystine and becoming cystine and immobilized. The permanent shaping of hair can be accomplished by (i) treating the hair with a perm solution (or treatment liquid) containing a reducing agent as a first agent to cut or cleave disulfide bonds of cystine in the keratin to reduce the cystine to cysteine, (A reducing agent treatment step), (ii) forming a wave on the hair using a roller or a curler for holding the hair in a wave form by applying a mechanical tensile force to the hair before or after the treatment, or (Iii) an operation (oxidation or fixing step) in which the hair is fixed in a wave form by applying disulfide bonds again between cysteines by applying a second oxidizing agent as a subsequent step and then converting the cysteine to cystine, Lt; / RTI >

By this method, the hair can be formed into a straight shape, or a wave can be formed. However, the conventional permanent molding method has a disadvantage in that it takes a lot of time because all of the above three steps must be performed.

A permanent liquid preparation containing a reducing agent as a main component is usually provided in the form of a relatively viscous composition such as a waving lotion, a concentrate, a cream, a gel and the like. As the reducing agent of the perm solution, for example, thioglycolic acid, cysteine, cysteamine, glyceryl thioglycolate, thiolactic acid and the like are used. Typically, a perm solution containing thioglycolic acid and a perm solution containing cysteine are used. Permanent liquids containing thioglycolic acid are excellent in the ability to perform permanent forming of hair by providing excellent reducing ability, but hair is remarkably damaged due to strong action against hair as compared with cysteine. Therefore, the use of hair is particularly limited in damaged hair, such as discolored or dyed hair. In addition, when thioglycolic acid is used, the degree of permanent formation of hair ends and hair follicles is different, and the hair becomes frizzy, the ends are cracked, and the hair frizz is increased. The permanent solution containing cysteine has a low degree of damage to hair but has a weak effect of permanent shaping of the hair, so it is difficult to wind the hair with a normal rod, and winding is required mainly by a fine rod, which limits its use . In addition, in the case of damaged hair, permanent molding is more difficult than healthy hair. In addition, when cysteine is used, the ends of the hair are cracked or broken, and gloss is lost. Also, even if cysteine, which is generally thought to be less damaging to hair, is subjected to 2 to 3 times of perming, a phenomenon in which the permanent molding is not performed afterwards occurs. The reason is that cysteine is formed by flaking ). Measures must be taken to prevent damage to hair caused by the use of reducing agents.

As the oxidizing agent, a neutralizing agent which is a second liquid of a permanent liquid is used in the form of an aqueous solution such as hydrogen peroxide, alkali bromic acid, perchlorate, polythionate and the like. However, these neutralizers severely damage the scalp or hair. Manufacturers of these products recommend using a neutralizing agent in a very short time and warn against applying to the scalp. However, in the actual field using permanent solution, the professional education of the practitioners (hairdressers) is insufficient or ignorant, and the emphasis is on curl formation. In addition, the practitioner (hairdresser) should wear the rubber gloves. If the neutralizing agent is applied to the hands due to tearing of the rubber gloves, the hands are oxidized (that is, aged) and severe necrosis may occur .

The present invention solves the problems such as hair damage due to the use of a reducing agent, and unlike the conventional permanent method of performing a combination of a reducing agent and an oxidizing agent as a neutralizing agent thereof, only the one reducing agent is used to maximize perfection molding 2 By using organic natural minerals instead of using oxidizing agent (sodium bromate or hydrogen peroxide), it is possible to prevent damages of hair and scalp and to significantly shorten the time of permanent forming, and to maintain the curl without using neutralizing agent (oxidizing agent) And a permanent solution composition for the permanent molding method.

According to an aspect of the present invention, there is provided a cysteine-containing disulfide-containing cystine A reducing agent for hair permer which can cut or cleave bonds to reduce cystine to make it possible to deform the outer shape of hair; A natural organic ion mineral which penetrates into hair and acts as a nutrient of hair, at least calcium, magnesium, zinc, potassium, iron, phosphorus, manganese, sodium, selenium and copper extracted from at least one organism of animals and plants. ; Saponin which is extracted from a plant and activated on the surface of hair to facilitate hair penetration of the reducing agent and the natural organic ion mineral; And a polyphenol which prevents oxidation of the active oxygen to prevent aging of the hair and the scalp. It is also possible to suppress hair damage through nutrition for the hair, The permanent shaping of the hair can be performed, and the time for permanent shaping of the hair can be shortened.

Wherein the mixing ratio of the reducing agent, the natural organic ion mineral, the saponin, and the polyphenol is in the range of 77.0 to 95.0 wt%, 3.5 to 20.0 wt%, 1.0 to 5.0 wt%, 0.1 to 1.0 wt%.

According to another aspect of the present invention, there is provided a method for preparing a natural mineral mixture, comprising: a first step of applying an aqueous solution of a natural mineral mixture in which natural mineral mixture is mixed with water to hair; After the first step, a permanent solution composition comprising the natural mineral mixture is applied to the hair to a reducing agent for hair permer which allows the cystine disulfide bond in hair to be cleaved or cleaved and reduced to cysteine so that the outer shape of the hair can be deformed ; A third step of applying a mechanical tensile force to the hair using a hair-forming member to hold the hair in a wavy or straight shape before, during or after the second step, or simultaneously with the second step; And a fourth step of performing heat treatment on the hair after the third step for 20 to 50 minutes, thereby suppressing hair damage through nutrition for the hair, and without separately using an oxidizing agent for neutralizing the reducing agent The permanent shaping of the hair can be performed, and the hair perming forming time can be shortened. The natural mineral mixture includes at least calcium, magnesium, zinc, potassium, iron, phosphorus, manganese, sodium, selenium and copper extracted from at least one organism of an animal or a plant. Natural organic ionic minerals that act as nutrients in the body; Saponin which is extracted from a plant and activated on the surface of hair to facilitate hair penetration of the reducing agent and the natural organic ion mineral; And polyphenols that prevent oxidation of the active oxygen to prevent aging of hair and scalp.

In the permanent forming method, the mixing ratio of the reducing agent, the natural organic ion mineral, the saponin, and the polyphenol may be 77.0 to 95.0 wt%, 3.5 to 20.0 wt%, 1.0 to 5.0 wt%, 0.1 to 1.0 wt%.

Preferably, the first step is performed in a state where the moisture content of the hair is 40 to 50%.

In addition, it is preferable that the water and the natural mineral mixture of the natural mineral mixture aqueous solution are mixed at a ratio of 0.5: 1.5 to 1.5: 0.5 by weight.

The method may further include a fifth step of naturally abandoning the hair-forming member for 20 to 30 minutes after the heat treatment in the fourth step, and then finishing after shampooing the hair-forming member.

The remover solution according to the present invention opens the cuticle to inhibit the damage of keratin, which is a hair protein, to prevent the hair from becoming frayed, cracked and broken, and to shorten the permanent molding time.

According to the present invention, it is not necessary to use an oxidizing agent for neutralizing the reducing agent. A satisfactory level of curl (permanent forming) duration can be obtained without using an oxidizing agent, and side effects due to the use of the oxidizing agent can be avoided.

In addition, damage to hair can be minimized by the natural organic ionic minerals and polyphenol contained in the remover liquid composition, the hair formed by the permanent formation is glossy and soft, the elasticity is improved, and the durability is also excellent. Especially, in the case of thin hair, the natural organic ion mineral effect gives the hair elasticity and provides excellent curl retention.

As a side effect, the smell from the reducing agent was also significantly reduced. It is presumably due to the effect of minerals.

Hereinafter, the present invention will be described in more detail.

The permanent liquid composition according to the present invention is prepared by mixing a natural mineral mixture developed by the inventor with a reducing agent which has been used in the past. As mentioned above, any one of the conventional reducing agents such as thioglycolic acid, cysteine, cysteamine, glyceryl thioglycolate, thiolactic acid and the like can be selected as the reducing agent. This reducing agent cuts or cleaves disulfide bonds of cystine in the keratin of hair and reduces it to cysteine, which makes it possible to deform the shape of hair. Natural minerals are composed of natural organic ion minerals mixed with saponin, which acts as a natural surfactant, and polyphenols, which act as antioxidants.

Natural organic ionic minerals are substances that penetrate into hair and act as necessary nutrients for hair, extracted from plant and animal organisms. At least potassium, calcium, sodium, phosphorus, selenium, iron, magnesium, copper, manganese and the like. It is mainly organic minerals extracted from animal bones and plant leaves. Raw materials of vegetable organic ion minerals include mulberry leaf, upper limb, jujube leaf, ogapi, rice, barley, seaweed, kelp. Examples of raw materials for animal organic ion minerals include bovine bone, pig bone, chicken bone, seashell, mussel, shellfish, and abalone.

Saponin is collectively referred to as trietylphene and steroid-based glycosides widely distributed in plants. Saponin has a high fat decomposition ability and can act as a surfactant for the hair surface. This action promotes the absorption of hair reducing agents and natural organic ion minerals into the hair.

Polyphenol is a substance that acts as an antioxidant that plays a role in protecting various cells and physiological functions in the human body by preventing the oxidation function of naturally occurring active oxygen during physiological metabolism. Therefore, when polyphenol is used as a permanent molding material, it suppresses oxidizing function of active oxygen in the hair, thereby suppressing the aging of hair and scalp and keeping it young and healthy.

The natural organic ion mineral component, saponin, and polyphenol may be extracted from different raw materials, but they may be simultaneously extracted using a raw material containing a large amount thereof. For example, mulberry leaves, upper leaves, silkworms, and the like contain a large amount of natural organic ion minerals, saponins, and polyphenols, and natural minerals can be prepared from these materials.

The manufacturing method is as follows. First, mulberry leaves and upper limbs are collected, washed, dried and crushed. Mulberry used as a material is cultivated by foliar fertilization or drip irrigation of four kinds of fertilizer containing calcium chloride, phosphoric acid, and boron in cultivation. In addition, silkworms are grown with mulberry leaves of mulberry grown in this way to produce mineral-reinforced silkworms and dry them. Jujube leaves also contain a lot of natural minerals, saponins and polyphenols, so they can be used as a raw material instead of or in addition to mulberry leaves. Then, about 10 to 20% by weight of dried silkworm, about 30 to 50% by weight of mulberry leaf, and about 30 to 50% by weight of upper surface are mixed and calcined at a temperature of 1000 캜 or higher and then pulverized to 200 mesh or less. 0.1 to 8.0% by weight of the pulverized raw material and 92.0 to 99.9% by weight of purified water are mixed to produce a natural organic ion mineral liquid. This mineral liquid is a strong alkaline solution with a pH of about 10 to 13. Finally, a mixture of various organic herbicides, such as dried silkworm, mulberry leaf, top, oedi, jujube, and marine oil, is added to the natural organic ion mineral solution to extract the animal juice and then cooled to obtain a natural mineral mixture.

The natural mineral mixture thus obtained contains the components of the kind shown in the table below and the component content (mg / L) per liter of the raw material. Natural minerals, saponins, and polyphenols can be extracted from natural materials at the same time, so the production cost can be reduced.

ingredient content ingredient content potassium 1031.0 iron 0.039 calcium 655.6 magnesium 0.031 salt 27.43 Copper 23.79 zinc 1.208 manganese 0.0007 sign 1.140 Saponin 399 selenium 79.43 Polyphenol 75

Meanwhile, the mixing ratio of the reducing agent and the natural mineral mixture contained in the permanent liquid composition according to the present invention is preferably 77.0 to 95.0 wt%, more preferably 5.0 to 23.0 wt%. If the reducing agent is less than 77.0 wt%, the persistent molding performance is lowered, and the cost of the natural mineral mixture is higher than that of the reducing agent. If the amount of the reducing agent is more than 95.0 wt%, the components of the natural mineral mixture are relatively decreased and the effect provided by these components is weakened. The content of the natural mineral mixture is determined to be 5.0 ~ 23.0 wt% depending on the content of the reducing agent. In addition, it is preferable that the natural organic ion mineral, saponin, and polyphenol contained in the natural mineral mixture include about 3.5 to 20.0%, about 1.0 to 5.0%, and about 0.1 to 1.0%, respectively, by weight.

On the other hand, the use of the permanent liquid composition according to the present invention does not require the use of an oxidizing agent for neutralizing the reducing agent. The method of permanent forming the hair using the permanent liquid composition of the present invention is performed as follows.

(i) Step 1: First, an aqueous solution of a natural mineral mixture is applied to the hair. For example, a mixture of water and a natural mineral (4 to 5 ml) is mixed in a ratio of 0.5: 1.5 to 1.5: 0.5 by weight to prepare an aqueous solution of a mineral mixture. The aqueous solution of the natural mineral mixture can be applied to the hair by spraying it into the sprayer vessel or by spraying the hair with a tool such as a brush. At this time, when the aqueous solution of the natural mineral mixture is applied to the hair, water is sprayed on the hair or the head is wound in advance to coat the hair with 40 to 50% moisture, .

(ii) Step 2: After applying the aqueous solution of the natural mineral mixture, the permanent solution composition of the present invention in which the natural mineral mixture is mixed with the reducing agent for hair permer is prepared, and the permanent solution composition is applied to the hair. The reducing agent cuts or cleaves the disulfide bond of cystine in the keratin of hair and reduces it to cysteine, so that the appearance of hair can be deformed.

(iii) Step 3: Apply the mechanical tension to the hair using a hair-forming member such as a roller or a curl or plate to hold the hair in a wave or straight form after application as above. Applying a mechanical tensile force to the hair may be performed before or simultaneously with step 2.

(iv) Step 4: After step 3, heat treatment is carried out immediately. The heat treatment is preferably performed at a temperature of about 35 to 50 캜. The heat treatment time is about 20 to 50 minutes. It is desirable to increase the heat treatment time more as the hair becomes thin or the degree of damage of the hair becomes greater. After the test, the heat treatment time and the heat treatment temperature can be flexibly applied depending on the hair condition.

(v) Step 5: After the heat treatment in step 4, leave it for 20 to 30 minutes, check the degree of hair formation, loosen the hair-forming member, and finish after shampooing. When finishing, it is better to spray the natural mineral mixture aqueous solution used in step 1 on the hair with an atomizer.

The hair permanent forming operation may be performed in the same manner as described above. If the permanent solution composition is applied to the hair in step 2, the polypeptide chain of hair keratin is not broken, but only the bridge bonds between the chains are broken and then newly bonded. When the hair gets wet, the bonds that bind the chain are broken off, which causes the hair to swell, stretch well, and become less resistant. When setting, this property is used to wet the hair with water, then to hold the shape and dry. This principle is also used for permanent shaping of hair. That is, before applying the permanent liquid composition to the hair (Step 2), water mixed with the natural mineral mixture is sprayed onto the hair (Step 1). When the hair is soaked in water, the leg joint is broken, and as the moisture escapes from the hair, the broken leg bonds are newly formed again, and the shape is dried. In particular, the aqueous solution of natural minerals is a strongly alkaline solution (approximately pH 10 to 13), which makes the hair more bloated than water. When the hair is wetted with a strong mineral acid aqueous solution of a strong alkali, ionic bonds and hydrogen bonds between the chains are broken, and a reducing agent, natural minerals, saponin and polyphenol are easily penetrated into the hair. The reducing agent penetrating the surface of the hair cuts or cleaves disulfide bonds of cystine in the keratin of the hair and reduces it to cysteine so that the contour of the hair is deformably treated. In this state, the polyphenol and saponin components added to the natural mineral mixture play a role in connecting broken bridges. Note, however, that when using a mixture of natural minerals in a reducing agent, if the mixture is used after 12 hours, the permanent forming mechanism may not work due to the reduction reaction. Therefore, it is preferable to use the natural mineral mixture in the reducing agent within 12 hours. Taking this into consideration, it is preferable to prepare the natural mineral mixture and the reducing agent on a single-use basis when manufacturing the permanent liquid composition of the present invention.

Next, the permanent liquid composition of the present invention is subjected to a permanent forming treatment according to the above-described method for healthy hair, fine hair, and people with damaged hair due to frequent perms, so that the state of hair (gloss, elasticity, , Damage) and persistence of permanent. This will be described in detail as follows.

Example  One

Permanent molding was performed on 15 female customers with healthy hair as follows. First, 15 of the hair was sprayed with enough water to make the hair wet. Next, 5 ml of water and 5 ml of natural organic ion mineral were sprayed onto the wet hair. Next, 15 kinds of mixed solutions were prepared by adding natural organic ion minerals from 3 ml to 1 ml or 2 ml by increasing the amount of natural organic ion minerals to 80 ml of a reducing agent containing thiocholic acid. The mixture was applied to 15 hairs, The hair was heat-treated at a temperature of 40 ° C for 30 minutes. Then, it was allowed to stand for 20 ~ 30 minutes depending on the condition of the hair, and after the curl test, the roller was unfastened and finished after shampooing.

The results of observing the permanent molded hair through this process over time are summarized in the table below.

≪ Permanent Forming Result on Health Hair > customer Perm
reducing agent mineral
mixture Permanent molding result burnish elasticity Permanent persistence Softness damaged One 80 ml 3 ml △ △ ○ △ none 2 80 ml 4 ml ○ ○ ○ ○ none 3 80 ml 5 ml ○ ○ ○ ○ none 4 80 ml 7 ml ○ ○ ○ ○ none 5 80 ml 9 ml ○ ○ ○ ○ none 6 80 ml 11 ml ○ ○ ○ ○ none 7 80 ml 13 ml ○ ○ ○ ○ none 8 80 ml 15 ml ○ ○ ○ ○ none 9 80 ml 17 ml ○ ○ ○ ○ none 10 80 ml 19 ml ○ ○ ○ ○ none 11 80 ml 21 ml ○ ○ ○ ○ none 12 80 ml 23 ml ○ ○ ○ ○ none 13 80 ml 24 ml ○ ○ ○ ○ none 14 80 ml 25 ml ○ ○ △ ○ none 15 80 ml 27 ml ○ ○ △ ○ none

When the amount of the mineral mixture was less than 3 ml, the hair was not damaged and the permanent duration (about 2 months or more) was also good, but it was evaluated to be normal in the shine, elasticity and softness of the hair. It was confirmed that the mixing amount of the mineral mixture should be 4 ml or more, which is a good level in the shine, elasticity and softness of the hair. When the mixing amount of the mineral mixture was increased to be more than about 25 ml, the relative amount of the perming reducing agent was decreased, and it was confirmed that the persistence of the permanent shaping hair was lowered.

Example 2

For ten female customers with thin hair (weak and shiny hair), the permanent molding was performed in the following procedure. First, the hair was sprayed with enough water by spraying on 10 hairs, and the hair was wetted with water. Then, 5 ml of water and 5 ml of natural organic ion mineral were sprayed on the hair wet with water. Next, a mixed solution prepared by mixing 5 ml of natural organic ion mineral with 80 ml of a reducing agent containing thiocholic acid was prepared and applied to each of 10 hairs, and the hair was heat-treated at a temperature of 40 캜 using a roller. During the heat treatment, the heat treatment time was gradually increased from 5 minutes. After the heat treatment, it was left to stand for 20 ~ 30 minutes depending on the hair condition. After the curl test, the roller was loosened, and the hair was finished after shampooing.

The results of observing the permanent molded hair through this process over time are summarized in the table below.

≪ Permanent Forming Result on Fine Hair > customer Perm
reducing agent mineral
mixture Permalink here burnish elasticity Permanent persistence Softness damaged Heat treatment One 80 ml 5 ml ○ ○ X ○ none 5 minutes 2 80 ml 5 ml ○ ○ X ○ none 10 minutes 3 80 ml 5 ml ○ ○ ○ ○ none 15 minutes 4 80 ml 5 ml ○ ○ ○ ○ none 20 minutes 5 80 ml 5 ml ○ ○ ○ ○ none 25 minutes 6 80 ml 5 ml ○ ○ ○ ○ none 30 minutes 7 80 ml 5 ml ○ ○ ○ ○ none 32 minutes 8 80 ml 5 ml ○ ○ ○ ○ none 34 minutes 9 80 ml 5 ml ○ ○ ○ ○ none 36 minutes 10 80 ml 5 ml ○ ○ ○ ○ none 38 minutes

In the case of thin hair, heat treatment for 15 minutes or more was satisfactory in permanent sustaining power, but it was found that when the heat treatment was performed for a shorter time, the duration of molded hair was weak.

Example 3

Permanent molding was performed on 13 female customers with damaged hair due to frequent permanent molding and the following process. Thirteen hairs were sprayed with enough water to soak the hair in water. Then, 5 ml of water and 5 ml of natural organic ion mineral were sprayed onto the wet hair. Then, a mixed solution prepared by adding natural organic ion minerals from 5 ml to 2 ml each to 80 ml of a reducing agent containing thiocholic acid was prepared and applied to each of 13 hairs. Using a roller, the mixture was heated to 40 ° C . During the heat treatment, the heat treatment time was increased from 5 minutes to 5 minutes. After the heat treatment, it was left to stand for 20 ~ 30 minutes depending on the hair condition. After the curl test, the roller was loosened, and the hair was finished after shampooing.

The results of observing the permanent molded hair through this process over time are summarized in the table below.

≪ Permanent Forming Result on Damaged Hair > customer
Perm
reducing agent mineral
mixture Permalink here burnish elasticity Permanent persistence Softness damaged Heat treatment One 80 ml 5 ml X X X X none 5 minutes 2 80 ml 7 ml X X X X none 10 minutes 3 80 ml 9 ml △ X X X none 15 minutes 4 80 ml 11 ml △ △ X X none 20 minutes 5 80 ml 13 ml △ △ X ○ none 25 minutes 6 80 ml 15 ml ○ ○ ○ ○ none 30 minutes 7 80 ml 17 ml ○ ○ ○ ○ none 35 minutes 8 80 ml 19 ml ○ ○ ○ ○ none 40 minutes 9 80 ml 21 ml ○ ○ ○ ○ none 45 minutes 10 80 ml 23 ml ○ ○ ○ ○ none 50 minutes 11 80 ml 25 ml ○ ○ ○ ○ none 55 minutes 12 80 ml 27 ml ○ ○ △ ○ none 60 minutes 13 80 ml 29 ml ○ ○ △ ○ none 60 minutes

According to the results of this example, it was confirmed that the heat treatment for 30 minutes or more in the case of damaged hair was satisfactory, but the curl persistence was weak in less than 30 minutes. There was no further hair damage due to heat treatment, but in the case of fully damaged hair, it was excluded from the experiment. Also, when the amount of the mineral mixture was more than 27 ml, the permanent holding power tended to be weakened.

Claims (7)

Which is selected from the group consisting of cysteine, thioglycolic acid, cysteine, cysteamine, glyceryl thioglycolate, and thiolactic acid. The disulfide bond of the cystine in the keratin of the hair is cut or cleaved to reduce the cystine to the outer shape of the hair. Reducing agents for hair permers;
A natural organic ion that penetrates into hair and acts as a nutrient of hair, at least calcium, magnesium, zinc, potassium, iron, phosphorus, manganese, sodium, selenium and copper extracted from at least one organism of animals and plants. mineral;
Saponin which is extracted from a plant and activated on the surface of hair to facilitate hair penetration of the reducing agent and the natural organic ion mineral; And
It contains polyphenols that prevent oxidative function of active oxygen and prevent aging of hair and scalp,
The permanent formation of the hair can be performed without suppressing the hair damage through nutrition supply to the hair and without separately using a reducing agent for neutralizing the reducing agent so that the permanent shaping time of the hair can be shortened. ≪ / RTI > The method of claim 1, wherein the mixing ratio of the reducing agent, the natural organic ion mineral, the saponin, and the polyphenol is 77.0 to 95.0 wt%, 3.5 to 20.0 wt%, 1.0 to 5.0 wt%, 0.1 to 1.0 wt% % By weight based on the total weight of the composition. A first step of applying an aqueous solution of a natural mineral mixture obtained by mixing a natural mineral mixture with water to the hair;
After the first step, a permanent solution composition comprising the natural mineral mixture is applied to the hair to a reducing agent for hair permer which allows the cystine disulfide bond in hair to be cleaved or cleaved and reduced to cysteine so that the outer shape of the hair can be deformed ;
A third step of applying a mechanical tensile force to the hair using a hair-forming member to hold the hair in a wavy or straight shape before, during or after the second step, or simultaneously with the second step; And
And a fourth step of performing heat treatment on the hair for 20 to 50 minutes after the third step,
Wherein the natural mineral mixture comprises at least calcium, magnesium, zinc, potassium, iron, phosphorus, manganese, sodium, selenium and copper extracted from at least one organism of animals and plants, Natural organic ion minerals that act as nutrients; Saponin which is extracted from a plant and activated on the surface of hair to facilitate hair penetration of the reducing agent and the natural organic ion mineral; And a polyphenol which prevents oxidation of the active oxygen to prevent aging of hair and scalp,
The hair can be permanently formed without inhibiting the hair damage through nutrition for the hair and without using an oxidizing agent for neutralizing the reducing agent so that the permanent shaping time of the hair can be shortened. Way. 4. The method according to claim 3, wherein the mixing ratio of the reducing agent, the natural organic ion mineral, the saponin, and the polyphenol is 77.0 to 95.0 wt%, 3.5 to 20.0 wt%, 1.0 to 5.0 wt%, 0.1 to 1.0 wt% %. ≪ / RTI > The permanent-shaping method of hair according to claim 3 or 4, wherein the first step is performed in a state where the hair has moisture content of 40 to 50%. The permanent shaping method of hair according to claim 3 or 4, wherein the water and the natural mineral mixture of the natural mineral mixture aqueous solution are mixed at a ratio of 0.5: 1.5 to 1.5: 0.5 by weight. The method as claimed in claim 3 or 4, further comprising a fifth step of naturally abandoning the hair-forming member for 20 to 30 minutes after the heat treatment in the fourth step, and then finishing after shampooing the hair- Of the hair.