KR102124583B1 - Hair treatment agent and method of permanent wave using thereof - Google Patents

Abstract

The present invention relates to a hair treatment agent for perm treatment using L-arginine and a method for perm treatment using the same. More specifically, a step of applying a hair treatment agent including a solvent and L-arginine to hair, and applying the hair treatment agent It characterized in that it comprises the step of drying the dried hair, and applying a pumping agent to the dried hair, the operation of the firm. According to the present invention, it is possible to quickly complete the elastic firm, as well as to improve the curl forming force, fixing force, retention force, and has the advantage of preventing damage to the hair.

Description

Hair treatment agent for perm treatment using L-arginine and perm treatment method using the same {HAIR TREATMENT AGENT AND METHOD OF PERMANENT WAVE USING THEREOF}

The present invention relates to a hair treatment agent for perm treatment using L-arginine and a perm treatment method using the same, more specifically, to open the cuticle of the hair through L-arginine, to help the rapid penetration of the perm agent, to quickly resilient firm The present invention relates to a hair treatment agent for perm surgery using L-arginine which can be completed and a perm surgery method using the same.

The main component of hair is keratin, and keratin, a fibrous protein polymer composed of 18 different amino acids, is characterized by a cross-linking structure having one disulfide bond (-SS-) per 10 to 20 amino acid residues on average. This disulfide bond determines the tertiary structure of the protein by folding. Representative of the structure of keratin is cystine represented by the formula [HO ₂ CC(NH ₂ )HCH ₂ S-SCH ₂ C(NH ₂ )HCO ₂ H].

Typically, the waving agent (permanent waving agents) is composed of a first agent having a reducing agent as a main component and a second agent having an oxidizing agent (neutralizing agent) as a main component. The permanent waving (perm) mechanism of hair cuts disulfide bonds of cystine [HO ₂ CC(NH ₂ )HCH ₂ S-SCH ₂ C(NH ₂ )HCO ₂ H] using a first zein reducing agent as the most basic step. By doing so, it is reduced to cysteine [HO ₂ CC(NH ₂ )HCH ₂ SH] to deformably treat the appearance of the hair (reducing agent treatment step), and before or after such treatment, or simultaneously, apply mechanical tensile force to the hair to form a wave. By forming a wave on the hair using a roller or curl to maintain the furnace (tensile adding step), and then applying the second zein oxidizing agent as a subsequent step, the above reaction is reversed to convert cysteine to cystine again. It is to fix the wave shape (oxidation or fixing step).

The new form imparted to the hair by the chemical treatment as described above is remarkably strong in persistence and resistant to water or shampoo cleaning treatments for the hair, in contrast to simple and non-permeable hair modification treatments such as hair setting. It has a phosphorus effect. The hair modification technique by the chemical treatment described above can be applied to both straightening and unwrapping a straight hair or giving a wave to a straight hair (normal perm).

The first agent containing the reducing agent as a main component is usually provided in the form of a relatively viscous composition such as waving lotion, concentrate, cream, gel, etc. Typical examples of the reducing agent are cysteamine and its derivatives, thiolactic acid, thio Glycolic acid and its esters are thioglycolic acid and cysteine. Examples of additives include nonionic, anionic, cationic or amphoteric surfactants known in the art. In addition, other ingredients such as hair damage relievers, dandruff inhibitors, thickeners, suspending agents, ion blockers, opacifiers, dyes, sunscreens, fragrances, and preservatives are usually added, and solvents such as ethanol, propanol or isopropanol or glycerol It may include.

On the other hand, typical examples of the oxidizing agent as the second agent include dilute sodium bromate or aqueous hydrogen peroxide solution (a dilute aqueous solution of about 3% to 6%).

However, according to the conventional perm agent as described above, there are the following problems.

The representative agent of the reducing agent, thioglycolic acid and its esters, is effective in providing excellent reducing ability, but the fact that the perm procedure is typically performed at a high pH concentration. However, since the human skin surface is usually weakly acidic, the use of the perm solution at a high pH is extremely unpleasant, irritating, and causes a bad reaction. In particular, thioglycolic acid has a high reducing ability, so it has an excellent effect of pumping hair, but because it has a strong effect on hair compared to cysteine, it significantly damages hair, and is especially used for damaged hair such as discolored and dyed hair. This is limited.

In addition, reducing agents other than thioglycolic acid and its esters have less hair damage than thioglycolic acid and its esters, but this also causes hair damage, and have better curl forming and lasting power compared to thioglycolic acid and its esters compared to perm. There were disadvantages.

In addition, even with the use of such a reducing agent, in the case of resistant hair such as virgin hair, henna hair, and coated hair, curl forming power and fixing power were not good.

Conventionally, as a prior art for preventing damage to hair by a reducing agent, in Korean Patent Publication No. 10-2009-0099164, by containing black mud, the deodorizing effect and hair while maintaining the original wave formation effect of the firm composition Although it was possible to achieve a protective and moisturizing effect and a scalp irritation preventing effect, it was also impossible to prevent damage by a reducing agent by simply adding nutrition to the hair. In addition, in the case of such a perm composition, since the curl forming and fixing force are poor, it is difficult to perform treatment on resistant hair.

In addition, the Republic of Korea Patent No. 10-1728306 by preventing the damage to the hair by mixing the composition for protecting the hair containing an amino acid powder, adzuki beans, and sewage in a reducing agent, but due to this, the curl forming and fixing force is lowered to the resistant hair There was a disadvantage that the procedure was difficult.

KR 10-2009-0099164 A KR 10-1728306 B1

Therefore, the object of the present invention is to pre-treat the hair through a hair treatment agent containing L-arginine, and then to apply a perm agent, in order to solve the above-mentioned problems of the conventional perm agent, it helps the rapid penetration of the perm agent and is elastic. It is to provide a hair treatment agent for perm treatment using L-arginine and a perm treatment method using the same, which can quickly complete the perm.

Another object of the present invention is to provide a hair treatment agent for permeation treatment using L-arginine and a permeation treatment method using the same, which improves curl forming ability, fixation ability, and retention ability even when reducing the amount of reducing agent used, and can prevent hair damage. .

Another object of the present invention is to provide a hair treatment agent for perm surgery using L-arginine capable of stably forming and fixing curls even on resistant hair and a perm treatment method using the same.

The hair treatment agent for perm treatment using L-arginine of the present invention for achieving the above object is characterized by including a solvent and L-arginine.

It characterized in that it contains 0.1 to 5 parts by weight of L-arginine relative to 100 parts by weight of the solvent.

The solvent is characterized in that it is at least one of water, a graphene aqueous solution, and a polypeptide aqueous solution for hair clinics.

Characterized in that it further comprises 1-5 parts by weight of pear blossom extract and 1-5 parts by weight of Areca palm extract.

And the method of using the L-arginine for a hair treatment agent using a hair treatment agent includes the steps of applying the above-described hair treatment agent to the hair, drying the hair coated with the hair treatment agent, and applying a perm agent to the dried hair, And, it characterized in that it comprises a step of performing the firm.

It characterized in that L- arginine is mixed with a reducing agent in the perm.

According to the hair treatment agent for perm treatment using L-arginine of the present invention and the perm treatment method using the same, it is possible to quickly complete the elastic perm, as well as improve curl forming, fixing, and retention, and prevent hair damage. It has the advantage of being able to. In addition, there is an advantage that can reduce the odor of the reducing agent.

Hereinafter, the present invention will be described in detail.

First, the perm procedure performed in the present invention includes a permanent wave, as well as a permanent straight, and is applicable to various types of well-known firms.

Conventional perm agent not only has a high content of a reducing agent for a strong reducing action, but also creates a strong alkaline environment in the hair, causing severe damage to the hair. In addition, even when creating such a strong alkaline environment, it was difficult to form a stable curl in the case of resistant hair.

Accordingly, the present invention opens the cuticle of the hair through the hair treatment agent for perm surgery to improve the disadvantages of the conventional perm agent and creates an environment of weak alkali so that the reducing agent of the perm agent quickly penetrates into the hair, thereby forming curling force and fixing force. It is to make it excellent. In addition, through this, even if only a small amount of reducing agent is used, a quick perm operation is possible. In addition, by including L-arginine, which is one of amino acids, as the hair treatment agent, damage to the hair is not caused.

For this purpose, the hair treatment agent for perm treatment of the present invention is characterized by including a solvent and L-arginine.

First, the L-arginine is a natural L-amino acid, and is one of amino acids constituting keratin constituting hair. In addition, the L-arginine is strong and the aqueous solution is alkaline. Therefore, the hair treatment agent for the perm treatment of the present invention is to open the cuticle of the hair due to the alkalinity of the L-arginine, and prevent the damage of the hair by penetrating the L-arginine into the hair.

Next, the solvent is for dissolving the L-arginine so that it can be applied to the hair, and most simply water can be used. In addition, since it is possible to use an aqueous solution of graphene, an aqueous solution of a polypeptide for hair clinics, etc. in addition to water, it may be one or more of water, an aqueous solution of graphene and an aqueous solution of polypeptides for hair clinics.

The graphene aqueous solution means that 2 to 5% by weight of graphene powder is mixed with 95 to 98% by weight of water, and the graphene is graphite oxide, reduced graphite oxide, and yes It may be any one or more of the pin oxide (graphene oxide). Here, the particle size of the graphene powder is not limited, and may be, for example, about 1 to 50 μm.

The graphene aqueous solution serves to prevent the loss of protein and damage to the hair even if the hair cuticle is opened by preventing the loss of protein of the hair by forming a film on the hair to form a film on the hair.

And the aqueous solution of the polypeptide for hair clinics is a product that is usually used for hair clinics, and any of commercially available products can be used.

The polypeptide is a polymer of 10 or more amino acids formed by peptide bonds, and serves to restore damaged hair when an aqueous polypeptide solution for hair clinic containing the same is applied to the hair.

Therefore, when using an aqueous solution of graphene or an aqueous solution of a polypeptide for a hair clinic as the solvent, damage to the hair can be further prevented.

In the present invention, it is preferable that the solvent and L-arginine contain 0.1 to 5 parts by weight of the L-arginine with respect to 100 parts by weight of the solvent. If the content of the L-arginine is less than 0.1 parts by weight, the cuticle cannot be sufficiently opened. This is because the damage to hair may be caused during the perm procedure because the perm procedure is excessive due to excessive alkalizing when necessary.

According to the hair treatment agent for perm treatment including L-arginine and a solvent as described above, by opening the cuticle of the hair before application of the reducing agent, so that the reducing agent can quickly penetrate into the hair, thereby shortening the perm treatment time. , It has the advantage that it can improve the curl forming force, fixing force. In addition, it has the advantage of being able to stably form curls on resistant hair, and also to prevent damage to hair. In addition, there is an advantage of reducing the amount of reducing agent used.

On the other hand, the hair treatment agent of the present invention may further include 1-5 parts by weight of pear extract and 1-5 parts by weight of Areca palm extract. At this time, the weight part is based on 100 parts by weight of the solvent.

The extract of the Western Pear Blossom means that the Western Pear Blossom is extracted and filtered using a solvent. In addition to protecting the hair through the extract of the Western Pear Blossom, it is possible to reduce the peculiar smell of the reducing agent during the perm procedure. More specifically, the extract of the Western Pear Blossom is more specifically, water, ethanol, and a solvent of any one of these mixtures are added to the Western Pear Blossom by 1-10 weight fold, extracted at 20-90° C. for 6 hours to 3 days, and filtered. In addition, if necessary, a process of drying and grinding may be further added.

The Pyrus Communis is a rose family, and is a species of wild pear from the central part of Europe that has been improved in areas with little rain in summer. The leaves are egg-shaped or long oval-shaped, and the petiole is thin and long. The fruit is usually a bottle-shaped cone, but has many variations. Pick the mature ones and cook again. It has few stone cells, has excellent aroma and taste, and is currently the most dominant variety in the world.

It is preferable that the extract of the pear flower is included in 1 to 5 parts by weight in the hair treatment agent of the present invention, because its content is less than 1 part by weight, the effect is negligible, and if it exceeds 5 parts by weight, curl forming power may be lowered. to be.

The Areca palm extract means that the leaves of Areca palm are extracted and filtered using a solvent, to protect the hair through the Areca palm extract, increase curl formation, and remove the odor of the reducing agent during the perm procedure. The extract of Areca palm is more specifically, water, ethanol, and a solvent of any one of these mixtures are added to the leaves of Areca palm by 1 to 10 weight times, extracted at 20 to 90° C. for 6 to 3 days, and filtered. . In addition, if necessary, a process of drying and grinding may be further added.

Areca palm (Chrysalidorcarpus lutescens) is an air-purifying plant that is a kind of thorn-free palm. The stem is relatively thin and smooth, green to yellow-green, with small leaves facing, and the axis of the leaves with yellow and black spots. Contaminants absorbed by the leaves are used as metabolites of plants, some of which are removed and some of them move to the roots, which are used as a source of nutrients for soil microorganisms. In the case of formaldehyde, it is absorbed into the plant through the pores of the leaves and then converted to formic acid and carbon dioxide in turn, and through the photosynthesis process, its toxicity is removed as it is used as a metabolite of photosynthesis.

The extract of Areca palm is preferably included in 1 to 5 parts by weight in the hair treatment agent of the present invention, because if the content is less than 1 part by weight, the effect is negligible, and even if it exceeds 5 parts by weight, no further enhanced effect is exhibited. to be.

Hereinafter, the method for performing the firm treatment according to the present invention will be described in detail.

First, the hair treatment agent described above is applied to the hair. At this time, the application amount is not limited, so it is sufficient if the hair is sufficiently moistened with the hair treatment agent.

Next, the hair to which the hair treatment agent is applied is naturally dried or dry dried. However, the drying step may be omitted if necessary, and the implementation is not limited.

In addition, the dried hair is used to complete a perm procedure using a conventional perm agent.

Here, the method of performing the perm using the perm agent follows a known method, for example, after applying a reducing agent and leaving it, after shampooing, after designing, neutralizing and shampooing by applying a neutralizing agent (oxidant) Is enough. In addition, the reducing agent used is sufficient as long as it is a normal alkali pump, and the type is not limited.

At this time, L-arginine may be mixed with the reducing agent in the reducing agent in a ratio of 100:0.1 to 2 by weight, and in this case, it may have more excellent curl forming ability and fixation ability, and the treatment time (the time left after the reduction agent is applied and the design procedure) After that, it will be possible to shorten the standing time) by 10~60%.

According to the treatment method according to the present invention, as described above, it is possible to quickly complete the elastic firm, as well as to improve the curl forming force, fixing force, retention force, and has the advantage of preventing damage to the hair. In addition, there is an advantage that the treatment time can be significantly shortened.

Hereinafter, the present invention will be described in more detail through examples.

(Example 1)

A hair treatment agent was prepared by mixing 3 g of L-arginine with 500 g of water.

(Example 2)

10 g of graphite was dissolved in 250 ml of sulfuric acid and stirred. Then, 30 g of potassium permanganate was slowly added dropwise and stirred uniformly for 1 day. After the stirring was completed, the reaction was terminated by pouring 1 L of water, and hydrogen peroxide was added to remove unreacted potassium permanganate. Then, washed with 5% hydrochloric acid, washed with distilled water, neutralized to a pH of about 5 to 6, and dried to obtain 10 g of dark brown graphene.

The graphene was crushed and crushed to about 1 to 50 µm, and this was mixed with 490 g of water. In addition, 3 g of L-arginine was mixed with 500 g of the graphene aqueous solution to prepare a hair treatment agent.

(Example 3)

After purchasing a commercially available product, an aqueous polypeptide solution for hair clinics, 3 g of L-arginine was mixed with 500 g of the aqueous solution to prepare a hair treatment agent.

(Examples 4 to 6)

Prepared in the same manner as in Examples 1 to 3, 10 g of pear extract and 10 g of areca palm extract were additionally mixed in each to prepare a hair treatment agent.

At this time, the pear flower extract was dried at 60° C. and added 3 L of purified water to 1 kg of pear flower powdered to about 100 mesh, extracted at 60° C. for 2 days, filtered (Whatman NO5, whatman international Ltd, UK), and reduced pressure. Concentrated and lyophilized to obtain pear blossom extract.

The Areca palm extract was dried at 60° C. and added 3 L of purified water to 1 kg of leaves of Areca palm powdered to about 100 mesh, extracted 2 days at 60° C. and filtered (Whatman NO5, whatman international Ltd, UK), and reduced pressure. Concentrated and lyophilized to obtain Areca palma extract.

(Test Example 1)

Twenty-four women with long hair with coated hair were selected. And 12 people were divided into 6 groups of 4 people.

First, Group 1 divides the hair into left and right sides, and the left side of the hair is coated with 200 g of the hair treatment agent prepared in Example 1, dried and dried, and then applied with an alkali pump (reducing agent, Shiseido Cultivator) for 10 minutes. It was left and shampooed. Next, the shampooed hair was dried and wound with a rod to give a wave, and after 10 minutes, an oxidizing agent was applied to neutralize for 15 minutes. Finally, the hair was dried by shampooing. And the right side of the hair was treated in the same manner as the left side as a control, but the hair treatment agent of Example 1 was not used, and was left for 15 minutes after the application of the alkali pump. At this time, the amount of the alkali pump and the oxidizing agent was the same on the left and right.

And the second group, the second embodiment, the third group, the third embodiment, the fourth group, the fourth embodiment, the fifth group, the fifth embodiment, and the sixth embodiment, the sixth embodiment, the same procedure as in the first group. Did.

Then, after the procedure, the glossiness, hair elasticity, hair moisturizing, odor (depletion degree of odor relief), curl formation and fixation power, and satisfaction of the procedure felt by the respondents were scored using a 5-point comparison method, and the results are shown in Table 1. At this time, the score is hair gloss, hair elasticity, hair moisturizing, odor, curl formation and fixation power, and the satisfaction of the procedure is very improved or excellent as the score is higher, and the score is lower is not good.

Test Example 1 results division Hair shine Hair elasticity Moisturizing hair smell Curl formation, fixing force Treatment satisfaction Example 1 left 3.1 3.3 3.3 2.9 4.2 3.8 Right 3.0 2.8 2.8 2.8 2.1 2.2 Example 2 left 3.5 3.6 3.5 3.0 4.2 4.2 Right 3.1 2.9 2.8 2.9 2.2 2.2 Example 3 left 3.3 3.4 3.4 2.9 4.3 4.1 Right 2.9 3.0 2.7 2.9 2.1 2.2 Example 4 left 3.5 3.7 3.8 4.0 4.2 4.2 Right 3.0 2.8 2.7 2.8 2.0 2.3 Example 5 left 4.1 4.2 4.2 4.1 4.3 4.4 Right 3.1 2.9 2.8 2.9 2.1 2.3 Example 6 left 4.0 4.0 4.2 4.0 4.3 4.4 Right 3.0 2.9 2.7 2.9 2.1 2.2

As can be seen from Table 1, the respondents of Examples 1 to 6 were all treated with the hair treatment agent of the present invention, while the hair gloss, hair moisturizing, and hair elasticity were slightly improved, high curl formation and It was confirmed that the fixation force and procedure satisfaction were shown. Particularly, in Examples 1 to 6, in the formation and fixation of curls, there was a large difference from the control group, and as a result, it was confirmed that the procedure satisfaction was also large. In addition, Examples 4 to 6 are high in hair shine, elasticity, moisturizing and smell compared to the test groups of Examples 1 to 3 (left), confirming that the overall procedure satisfaction is also higher than those of Examples 1 to 3. Could.

(Test Example 2)

Twenty-four women with long hair with damaged hair were selected. And 12 people were divided into 6 groups of 4 people.

First, Group 1 divides the hair into left and right sides, and the left side of the hair is coated with 200 g of the hair treatment agent prepared in Example 1, dried and dried, and then applied with an alkali pump (reducing agent, Shiseido Cultivator) for 10 minutes. It was left and shampooed. Next, the shampooed hair was dried and wound with a rod to give a wave, and after 10 minutes, an oxidizing agent was applied to neutralize for 15 minutes. Finally, the hair was dried by shampooing. And the right side of the hair was treated in the same manner as the left side as a control, but the hair treatment agent of Example 1 was not used, and was left for 15 minutes after the application of the alkali pump.

And the second group, the second embodiment, the third group, the third embodiment, the fourth group, the fourth embodiment, the fifth group, the fifth embodiment, and the sixth embodiment, the sixth embodiment, the same procedure as in the first group. Did.

However, when the treatment of the left hair, only 60% of the amount of the alkali pump was used, and when the treatment of the right hair, the alkali pump was used 100%.

And after the procedure, the gloss, hair elasticity, hair moisturizing, odor (reduction of odor relief), curl formation and fixation power, and satisfaction with the procedure felt by the respondents were scored using a 5-point comparison method, and the results are shown in Table 2. At this time, the score is hair gloss, hair elasticity, hair moisturizing, odor, curl formation and fixation power, and the satisfaction of the procedure is very improved or excellent as the score is higher, and the score is lower is not good.

Test Example 2 results division Hair shine Hair elasticity Moisturizing hair smell Curl formation, fixing force Treatment satisfaction Example 1 left 3.4 3.5 3.5 2.9 4.0 3.8 Right 2.1 2.2 2.1 2.8 2.2 2.2 Example 2 left 3.7 3.8 3.8 3.0 4.1 4.3 Right 2.1 2.2 2.1 2.9 2.2 2.2 Example 3 left 3.6 3.5 3.6 2.9 4.2 4.2 Right 2.2 2.3 2.4 2.9 2.0 2.1 Example 4 left 3.7 3.9 3.9 4.0 4.1 4.1 Right 2.2 2.1 2.2 2.8 2.0 2.1 Example 5 left 4.3 4.2 4.2 4.1 4.2 4.3 Right 2.1 2.1 2.0 2.9 2.1 2.2 Example 6 left 4.3 4.0 4.2 4.0 4.2 4.3 Right 2.0 2.2 2.1 2.9 2.0 2.2

As shown in Table 2, it was confirmed that Examples 1 to 6 of the present invention showed satisfactory curl formation and fixation force even when the amount of the reducing agent was reduced.

As described above, the present invention has been described in detail using preferred embodiments, but the scope of the present invention is not limited to specific embodiments, and should be interpreted by the appended claims. In addition, those skilled in the art should understand that many modifications and variations are possible without departing from the scope of the present invention.

Claims (5)

L-arginine 0.1 to 5 parts by weight based on 100 parts by weight of the solvent,
The solvent is at least one of a graphene solution in which 2 to 5% by weight of graphene powder is mixed with 95 to 98% by weight of water, a polypeptide aqueous solution for hair clinics,
1 to 5 parts by weight of pear flower extract after adding 1 to 10 parts by weight of water, ethanol, or a mixture thereof to the pear flower, and extracting it at 20 to 90° C. for 6 to 3 days; And
To the leaves of Areca palm, water, ethanol and a solvent of any one of these mixtures are added 1 to 10 times by weight, and after extracting for 6 hours to 3 days at 20 to 90°C, the filtered Areca palm extract further contains 1 to 5 parts by weight Characterized in that the L- arginine perm hair treatment agent for perm surgery.
delete delete The step of applying the hair treatment agent of claim 1 to the hair,
Drying the hair to which the hair treatment agent is applied,
A method of using a hair treatment agent for perm treatment using L-arginine, characterized in that it comprises the step of applying a perm agent containing a reducing agent and an oxidizing agent to the dried hair.
The method of claim 4,
L-arginine in the reducing agent in a ratio of 100:0.1 to 2 by weight, characterized in that the L-arginine perm for the perm treatment method using a hair treatment agent for perm treatment.