581834 Α7 Β7 五、發明說明（ 經濟部智慧財產局員工消費合作社印製 材經 料對装性布部 子且， 品織基且形 内 生中 材故對彈織的 筒伸等 製不與.，倩 絲 衛品 生，高的不性 以拉板。 料、絲縮.的 子 之製 衛發提得 /縮 常以片接 材帛性收出 筒 等料 . 等開為所帛伸 通予或黏 生布彈 、拉 以 墊材 。品品絲布具 絲，布板 ，衛由的離被 .為 棉生絲 生、商製纺由不 性品織片 使於接剝絲 偽 生衛性 衛)½料物在使 彈製不或 .為接黏材性 ， 衛關彈 用pDn)材合常中 ，料、布 絲黏、基彈 絲 用有之 理 I 生聚通材 時材帛織 性劑伸自生 性 . 理傜性 生 t 衛性絲基 品生布不 .彈接拉會産 彈 生 ，接 或 Μ 該彈性之 製衛之、 之黏 ，絲會 之 或之黏 布 Μ 。使彈品料給劑帛 途由此性中 態 1 布 15好 尿 g 求用該製 。材應接布 j 用經因彈品 形 域尿詳，良 於at要利。料接生供黏與題品，。，製。絲 領種更持 關M:質故性材黏衛物有，問製伸材時料化子 術一 ，保 多T品，縮生以於絲覆力的料拉基分材惡筒 技關絲材 很:^的性伸衛予用捲塗壓決材以的充生質成 之有性基 有“苛合有成劑使的入加解生 '予成不衛品曲 屬偽彈與&].，品嚴適具所接絲取-導施欲衛而所力的之捲 所明用劑^來製為之以等黏性捲並面所於性板接造品 ， 明發品接^年之較位 g 板由彈態 、接明用縮片黏製製且 發本製黏 h 近途有部複片經將狀解黏發使伸或之所使而 [ 料由[-7用此置絲或分 絲，舒在 f .具布材於而 ---J-----------,、^.-------^ ---------I、 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 經濟部智慧財產局員工消費合作社印製 581834 A7 ___B7__^_ 五、發明說明（2 ) 層捲曲，於衛生材料製品之製造工程中會産生彈性絲斷 ' 絲倩形或供應張力産生變動情形等之間題。因此，以防 止舒解1性惡化或張力變動為目的，通常以油劑處理表面。 使該彈性絲黏接於衛生材料製品之布帛、不織布等基 材時，基材之黏接性不充分，會産生上逑之問題。 為避免彈性絲之黏，接性降低時，不易降低油劑附箸量 而使彈性絲筒子絲之舒解性惡化，於衛生材料製品之製· 造工程中會産生彈性絲斷絲情形或供應張力産生變動情 形等問題。 此外，於提高彈性絲之黏接性哼，黏接劑之塗覆量容 易增加致使製品成本提高，且産生損害衛生材料製品之 質_或通氣桂的問題。 ' 〔解決問題的手段〕 ’ 本發明有鑑於上逑之事情，係以維持彈性絲之舒‘解性 且同時提高對基材之黏接性為目的。 本發明人等為解決上述之課題，再三深入硏究的結果 ,發現衛生材料製品中基材與彈性絲之黏接不良問題係 為基材與彈性絲之接觸面積的問題，藉由針對·彈性絲之 形狀，可維持舒解性與提高黏接性，基於該見解遂而完 成本發明。 換言之，本發明係如下所述。 (1 ) 一種衛生材料製品用彈性絲，其恃徵為使彈性聚 合物乾式紡絲所得的多絲彈性絲，具有外接於彈性絲之 絲條截面之長方形長邊（L 1 )與短邊（L s )之長度比（LI. / L s ) -4 - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) --------訂·--------線— 581834 A7 B7 五、發明說明（ 絲 性 絲 多 /ΠΝ 面 截 乎 0 之 上 以 2 為 一 出維 ，押纖 絲，朝 性孔絡 彈細交 用 之 以 品板予 製絲機 料噴絲 材過撚 生通由 衛液藉 的溶絲 得.之單 所物條 絲 # 數 紡聚使 式性旦 乾彈 ， 知使内 習偽筒 由言絲 藉而纺 般至 所面 法截 製條 該絲 以之 〇 絲 條性 絲彈 之於 爾接 尼外 旦 ， 標者 目化 得平 製扁 以，為 ， 使 虫 ΠΜΤ lcm0U 熔絲 向 性 方彈 長的 的得 。絲 面性 截·彈 平於 扁接 之外 上有 以具 CS3 為 於偽 小絲 bh性 度彈 長 用 之品 邊製 短料 與.材 邊.生 長 衛 形’之 方明 長發 的本 以 古冋 { 之積 上面 以觸 2 接 為之 fch材 度基 長品 之製 邊料 短材 與生 邊衛 長對 形使 方此 長藉 的且 ^ TJ lffi， 截者 條度 絲平 之扁 力 接 高 提 可 並 大 絲 性 OP 之 知 習 較 等 布 尿 於 用 使 絲 性 ?| 用 品 製 料 材 生 衛 之 '明 較‘發 比本 度將 纖 ， 一 且 同而 密繫 之散 身分 本由 品 Μ 製可 料且 材能 生功 衛漏 對防 故之 ，物 度.泄 平排 0 高 高提 具可 條 ， 絲大 於增 由積 ， 面 時接 方 長 的 面 截 條 絲 之 -絲 性 σΕηι δ 於 接 外 中 〇 絲 感性 迫彈 壓 之 輕明 減發 來本 力於· 緊 解 舒 之 絲 子 筒 自 LS低。 1/降佳 丨 有較 比會圍 度時範 長大之 之過8 \—#/ \ S 惟 2 (L,以 邊高 ， 短愈此 與度因 1)強。 (L接向 邊黏傾 長之的 形材性 基 對 時 大 愈 (請先閱讀背面之注意事項再填寫本頁) 訂---------線| 經濟部智慧財產局員工消費合作社印製 有 如 例 制 限 的 別 恃 有 沒 法 方 的 絲 性 " 之 明 。 發法 本方 造之 製述 下 單單 全的 的‘出 出押 押具 板模. 絲自 噴 使 自 須 之必 一了 //Λ— ， 進絡 絲交 纺以 式予 乾機 知絲 習撚 以以 ，起 之一 言法 換無 絲 熔 / 束 集 上· Ρ 導 在 Ρ 導 拭 擦- 間 6 之- 機 取 捲 與 筒 絲 纺 在 絲 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 581834 A7 B7 五、發明說明（ 絲具 之用 束使 集如 絲例 單 ， 使制 ， 限 處的 此別 C 持 條有 絲沒 之質 度材 平或 扁狀 高形 得之 •可 口 此導 0 用 〇 束 融收 口者 導化 之面 孔截 圓 平 以扁 是地 其定 尤安 ，向 材方 部長 之絲 孔使 口可 導 ， 形時 圓絲 或單 溝拭 口擦 導面 形内 U 孔 而部 小之 擦絲 摩入 觸導 接面 之内 條孔 絲 口 與導 就之 質 孔 材圓 之述 口 上 導在 ， ο 外佳 另較 〇 •製 求瓷 企陶 為以 偽 古口 佳 較 同 不 而 等 束 5m條 1X 之 以單 徑 及 直 度 之纖 孔之 圓絲 , 性 時彈 材視 為 者 佳 更 徑 直 之 孔 圖 若 單 生 發 易 容 時 ΐ絲 時方 m 一了 1—- yyl 於進 小間 時 長 且 形 情 拭 擦 之 絲 面 内 孔 圖 對 高 提 會 於 大 徑 直 孔 圓 若 形 情 斷 切 長 板 條 絲 絲 噴 在 自 間 使 絲 有 單 如 生 例 産 ， 會 法 ’ 方分 。 ί 充題另 不問之 觸之絲 接融性 之 '熔彈 間地 '之 絲定明 單安發 ,法本 時無得 Ε 向裝 5 -1 方 交於 絲 , 單拭 使擦 機口 絲·導 撚在 以條 群絲 各之 ，上 上以 以 2 群該 二 ， 成後 分條 絲絲 單之 條上 數 以 的 2 出成 押絡 全 使 絡 六乂 〇 起 法一 方絲 的單 條全 絲的 度絲 纖紡 之使 的不 @ ， 成時 形示 以例 絲等 合此 上用 口使 導 (請先閱讀背面之注意事項再填寫本頁) --------訂---------線丨 經濟部智慧財產局員工消費合作社印製 容 ί 可邊 ， 長 行形 進方 以 長 予的 束面 集截 絲條 使絲 上之 口絲LS 導性1/ 在彈U ， 於比 化接度 ‘體外長 一 有之 、具 S 融得(L 熔製邊 絲地短 單易與 扁 的 度 平 扁 高 之 上 以 2 為 凹間 留之 殘絲 而單 面於 表由 之 ， 絲條 單絲 因的 為得 面所 表法 條方 絲之 且者 而前 ，以 條是 絲其 之尤 面 。 截者 平凸 的條 箸絲 顯使 現以 呈 凸 而.凹· 面面 表表 之與 絲化 單平 因扁 ， 面面 ？ 表截 I 條因 絲由 在藉 絡之 交古口 全換 完 C 有凸 沒凹 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 581834 A7 B7 五、發明說明（ 條 絲 物 曲 捲 絲的 性 得 DP 厅 在om βDo ugN· ο ο f 2 量 曲 重捲 之地 X確 物正581834 Α7 Β7 V. Description of the Invention (The printed materials, warp and printed materials of the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, the printed materials, warp materials, and cloth materials are based on the woven base and endogenous materials, so they are not compatible with the elastic woven tube extension., Qiansi Weipinsheng, high inability to pull the board. Material, silk shrink. The child's system of hair extraction / shrinkage is usually made of sheet material and flexible take-up tube and other materials. Or viscose cloth, stretched with padding. Pinpin silk cloth with silk, cloth board, quilt quilt. It is raw cotton, and it is made by commercial fabrics. The material used in the material is not elastic. For the adhesion, the pDn material used for guarding ammunition is normal. The material, the cloth is sticky, and the basic elastic material is reasonable. The weaving agent is self-extracting. The natural fabric is not made of hygienic silk. The elastic cloth will produce elasticity, and it will adhere to the elasticity of the defending, sticky, or silky fabric. . Make the ammunition dosing way from this state 1 cloth 15 good urine g demand this system. The material should be connected to the cloth j. The shape of the warp caused by warfare is good, which is better than at. Material delivery for sticky and quiz. ,system. Silk collars are more relevant. M: There are old-fashioned stickies on the material. When the material is stretched, the material is used to protect the T product. The material is based on the material coverage of the wire. The silk material is: the sexual basis of the sexual extension of the coating of the compressive material with the coil of the sexual extension of the sexual base is "the addition of the harsh ingredients to make it into the detoxification." &]., the product is strictly suitable for the use of the wire to take-guide the desire to defend the volume of the agent ^ to make it with an equal viscosity volume and the surface of the sex board connection products, Mingfa The comparative g-plate of the product is made of elastic, bonded, and shrink-bonded, and the hair is made. H Some parts of the short-distance compound are de-bonded and stretched to make it stretched. [料 由 [ -7 Use this to set or divide the silk, Shu in f. With cloth material --- J ----------- ,, ^ .------- ^ ---- ----- I. (Please read the precautions on the back before filling this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 581834 A7 ___ B7 __ ^ _ V. Description of the invention (2) The layer is curled, which will cause elastic filament break in the manufacturing process of sanitary material products. The tension should be changed. Therefore, in order to prevent degradation of tension or tension changes, the surface is usually treated with an oil. When the elastic yarn is bonded to a substrate such as a fabric or a non-woven fabric of a sanitary material Insufficient adhesiveness of the base material will cause the problem of scooping. To avoid the stickiness of the elastic yarn, when the adhesiveness is reduced, it is not easy to reduce the amount of oil agent attached and the elasticity of the elastic bobbin yarn is deteriorated. In the production and manufacturing process of material products, problems such as broken filaments or changes in supply tension may occur. In addition, in order to improve the adhesion of elastic filaments, the amount of adhesive coating is likely to increase, resulting in higher product costs. And the problem of damaging the quality of the sanitary material product or ventilating guinea. '[Solution to the problem]' The present invention is based on the matter of the last thing, it is to maintain the comfort of the elastic yarn and improve the adhesion to the substrate at the same time. In order to solve the above-mentioned problems, the inventors have repeatedly researched, and found that the problem of poor adhesion between the substrate and the elastic yarn in the sanitary material product is the substrate and the elasticity. With regard to the contact area, the shape of the elastic wire can maintain relaxation and improve adhesion, and the present invention has been completed based on this knowledge. In other words, the present invention is as follows. (1) A sanitary material The elastic yarn for products is characterized by a multi-filament elastic yarn obtained by dry spinning an elastic polymer, and has a length ratio of a rectangular long side (L 1) to a short side (L s) of a cross section of a wire circumscribing the elastic yarn. (LI. / L s) -4-This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page) -------- Order · -------- Thread — 581834 A7 B7 V. Description of the invention (Silk silk is more than / ΠN plane is above 0 and 2 is a dimension, fibrils are pressed, and the pores are elastically fine The product board is used to make the spinning machine material. The spinner material is twisted through the dissolving yarn borrowed by Weiye. 的 单 所 物 条 丝 # The number of spinning polysilicon dry bombs is known to make the inner tube The word silk is used to cut the strip as far as it can be cut. The silk is silk and the elasticity of the silk is connected to the foreign country. The subject is visualized. Made flat to flat, as the insect ΠΜΤ lcm0U side of the projectile fuse is too long. The silk surface is cut and flattened outside the flat joint. It has a short side with a CS3 for pseudo-small silk bh elasticity and long length. It is made of Fangming long hair with a wood edge and a growth shape. Based on the product of the ancient 冋 {and the contact 2 on the fch material basis, the short material and the long side of the raw edge are opposite to each other, so that the long borrowed and ^ TJ lffi, The knowledge of flat force connecting high-lift and large silky OP can be used to urinate and use silk? | The loose identity is made by the product M. The material can be used to protect the power and prevent leakage. The material is flat. The drain is flat and the height is high. The wire is larger than the increase by product. -Silkiness σΕηι δ is connected to the outer silk. The lightness of the silky perceptual pressure is reduced and the strength of the silk tube is reduced from LS. 1 / Jiajia 丨 has a ratio of 8 that is larger than the range when it grows up. \ — # / \ S It is only 2 (L, with edge height, and shortness is better than degree factor 1). (L is connected to the side and sticks the long shape of the shape of the base material to the day and time (please read the precautions on the back before filling out this page) Order --------- Line | Intellectual Property Bureau of the Ministry of Economic Affairs Staff Consumption The cooperative prints the silk-like nature of the law that has no way of being legally restricted ". The law issued by the law makes the order of the" out of the security tooling mold. " I have // Λ—, enter the silk interlacing machine with a pre-drying machine to know the silk to twist, in one word, change the non-filament fusion / bundling · P guide on the P guide wipe-room 6 of-machine Take-up and reel spinning are applicable to China National Standard (CNS) A4 (210 X 297 mm) at the paper size. 581834 A7 B7 V. Description of the invention The limit of this type of C strips is flat or flat and high-shaped. • Delicious this guide 0 Use a bundle of 0 to melt the face of the closer to flatten it to make it flat. The silk hole of the director of the wood side makes the mouth guideable. When it is shaped, a round wire or a single groove wipes the mouth. The inner surface of the guide surface is U-shaped, and the small part of the wire is rubbed into the inner hole of the guide surface and the hole of the quality hole material is guided. Ο The outer is better than the other. For the pseudo-gukoujia than to bundle 5m pieces of 1X round filaments with single diameter and straightness, the elastic material is regarded as the better and the straighter hole. The square m has a 1 --- yyl The hole inside the silk surface is long and the shape is wiped when it enters the small room. The high-rise will be in a large diameter straight hole. If the shape is cut, the long strips of silk are sprayed in the room to make the silk have. Just as in the case of production, the law will be divided. Ί The question of the touchless touch of the meltable 'melt bomb' will be issued in a single order. When the square crosses the silk, a single wipe will make the wiper mouth silk and guide the twists on each of the groups of silk, and the two groups will be the two, and the divided silk will be divided into two. A single full-filament fiber spinning of a full-strand yarn No @ ， Chengshi shape shows the example of silk and so on. You can use this as a guide (please read the precautions on the back before filling this page) -------- Order --------- line丨 Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. The edge-shaped, long-row-shaped side of the wire with a long beam set to cut the wire to make the mouth on the wire LS Conductive 1 / in the U, in comparison with Degree 'external length, with S melting (L melting edge wire short and easy to flat and flat high above flat flat with 2 as the remaining space left in the recess and one side on the surface by it, thread Monofilament is the first and foremost square strip of silk, because strip is the best aspect. The truncated and convex strips of the reel appear to be convex. Concavity and surface appearance and silkification Shan Ping is flat and flat? Table I. The reason is that the wire is completely replaced at the turn of the borrowed line. C The surface of the paper is embossed. The paper size applies the Chinese National Standard (CNS) A4 (210 X 297 mm). The properties of the material winding coil DP Hall in om βDo ugN · ο ο f 2 The place where the volume is rewinding X is positive
棍始 曲為 捲等 以此 且以 劑 ， 油量 覆重 塗之 上 Y \—/ 量 S 之· X 物 曲 捲 /V 1 \/ 量 重 c 之 值 Υ 的物 得曲 所(¾ 算 丨 let、/ 式(¾ 算量 計著 之附 述劑 下油 以 物 曲 捲 量 重 之 聚 ， 用等 使.膠 可橡 物成 合 合 聚 、 性物 彈性 的彈 料酯 原聚 之 、 絲物 性性 彈彈 絲烴 多蹄 明聚 .發 、 本酯 為酸 做甲 胺 學物 化合 、 聚 的性 理彈 物之 、 等 質此 性 C 理佳 物較 之酯 等酸 性甲 復胺 恢聚 ' 以 度 言 強而 沖 等 拉性 就久 其耐 尤的 聚 共 之 酯 酸 氡 異 二 與 醇 聚 用 使 ο 可 用 ， 使時 合 酯 混酸 上 甲 以胺 種聚 二 用 可使 不 己 聚 以 〇 醇 者聚 長醚 延聚 鏈的 以表 予代 物為 合醇 化二 胺甲 由四 Μ 聚 .物乙 聚有 共如 該例 或醇 ''聚 物 己聚 聚酯 、 聚 醇之 聚表 酯代 内為 己等 聚物 以，應 .， 反 醇之 聚醛 Κ甲 聚亞 的酸 表碳 代與 為醇 酯酯 烯聚 乙之 酸酯 二 内 醇二 丙 \ 醇二 乙 與 酯 烯 乙 酸 使 古子 聚 酯 酸 己於 與 。 物等 合物 混應 .應反 反的 的酸 得羧 所二 使機 再有 ，之 應等 反酸 醇二 元；癸 多 、 之酸 等二 醇壬 戊 、 新酸 、二 (請先閱讀背面之注意事項再填寫本頁) 訂- •線- 經濟部智慧財產局員工消費合作社印製 學此 化 〇 、佳 的較 理醇 物聚 、酯 性聚 物用 之使 等以 性 古口 復而 恢性 、 水 度耐 強是 伸其 拉尤 就 、 中性 之久 等耐 此的 為 量 子· 分 .〇 其 用 ， 使 言 合而、。 混性00 上續23 以持一 種的00 2 性15 或縮為 種伸者 1 之佳 用絲較 使性 、 可彈00 醇就40 聚醇 ~ 之聚00 等‘10 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 29.7公釐） 經濟部智慧財產局員工消'f合作社印製 581834 ,A7 B7 5 ^ 五、發明說明（） 二異氡酸例如有4, 4夂二苯基甲烷二異氛酸酯、1,5-蔡基二異氰酸酯、1,4 -亞苯基二異氰酸酯、2 ,4 -亞甲苯 •基二異氰酸酯、2, 6 -亞甲苯基二異氡酸酯等芳香族二異 氛酸酯、六亞甲基二異氡酸酯、1,4 -環己基二異氛酸酯 、4,4夂二環己基二異氡酸酯、異佛爾酮二異氡酸酯等 之脂肪族二異氡酸酯。於此等之中就使彈性絲之強度高 而言，以4, 4·-二苯基甲烷二異氡酸酯較佳。此等之二 異氡酸酯可1種使用、亦可以2種以上混合使用。 胺化合物通常使用脂肪族、脂環族或芳香族二胺。具 體而言，例如有乙二胺、1,2 -丙烯二胺、1,3 -丙烯二胺 、1，4 -丁烯二胺、2, 3 -丁烯二胺、1,3•丁烯二胺、六亞 甲基二胺、環己基二胺、亞苯基二胺、亞甲苯基二胺、 亞二甲苯基二胺、3, 3f -二氯-4 ,4 -聯苯胺、2, 6 -二胺基 吼啶、4,4' -二胺基二苯基甲烷等。此等之胺化合物可1 種使用、亦可以2種以上混合使用。 - 末端密封所使用的末端密封劑例如有二甲胺、單乙醇 胺、正丙胺、正丁胺、二乙胺、甲醇、丙醇（1-丙醇、 2-丙醇）、丁醇（卜丁醇、2-丁醇）等。末端密封，可以 於鏈延長後添加，亦可以於預聚物反應時（例如聚醇與 二異氰酸酯之反應時）添加，亦可以於鏈延長時添加。. 彈性絲所塗覆的油劑傜可使用二甲基聚矽氧烷、二甲 基聚矽氧烷之使部分甲基以其他的烷基、苯基、胺基等 取代的改性聚矽氣烷等之聚矽氣烷油、礦物油等。 為使本發明之多絲彈性絲黏接於衛生材料製品之基材 -10- k·-------訂---------. (請先閱讀背面之注意事項再填寫本頁) 士鉍棋圮疮沾田Φ圃固宕煙進枴格iWO X㈧7公蝥） 祖824 A7 . B7___ 五、發明說明（9 ) 所使用的黏接劑，可使.用在該範圍内對彈性絲之衛生材 料製品的基材黏接所使用的習知黏接劑，沒有特別的限 制，以乙烯基聚合物条、飽和聚酯系、或聚醯胺糸之熱 熔融型黏接劑較佳。 [實施例] 於下述中，藉由實施例與比較例更詳細地說明本發明。 而且，實施例與比較例中彈性Μ之黏接性的評估係以 下述方法進行。 (1)使用薄目之衛生材料用途用東洋纺绩（股）製聚酷不 織布，且將其载成縱1 2 c m X橫3 c ra。不織布之毛商或 ί申縮性傜為黏接性不齊之原因，故統一黏接面予以評 ft 〇 (2 )在彈性絲無緊張下不予以緩和，於厚紙上並排5條 且以玻璃紙帶貼覆。 (3 )使由乙烯、丙烯、丁二烯、苯乙烯共聚物所成的熱 熔融黏接劑在1 7 ϋ度下熔解，自吐出機且將吐出量設 定為5g/分以使Ί單性絲與並排阽覆於厚紙之彈性絲朝 垂直方向、以3 0 c m /分之速度移動，使熱熔融黏接劑 以線狀塗覆。然後，使（1 )式所示的不織布以2 k g / c in 2 之壓力壓制1 0秒鐘以製得黏接性測定用試樣。上迷之· 試樣作成偽使用J Τ頓西（譯音）（股）製A S Μ - 1 5黏接力評 估機。 (4 )使直至（3 )所得的試樣保持於2 [) °C之房間内保管4小 時，且使不織布與彈性絲緊緊地固定，以歐里恩迪克 -1 1 - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) 訂---------線| 經濟部智慧財產局員工消費合作社印製 581834 A7 ___B7___ 五、發明說明（1〇) (譯音）股份有限公司製測定機ϋ - 1 5 7 3予以上下方向拉 伸，並記錄不織布與彈性絲於圖表紙上且予以剝離。 (請先閱讀背面之注意事項再填寫本頁) 此時，自圖表紙中讀取彈性絲與不織布剝離所需的強 度，以該值做為黏接力（c Ν )。The starting song is a roll and so on, and the amount of oil is over-coated with Y \ — / the amount of S · X Wuqu volume / V 1 \ / the value of the weight c of the Wudeququ (¾ calculation丨 let, / formula (¾ Calculation of the amount of the description of the oil under the weight of the volume of the volume of the aggregate, use, etc .. Rubber and rubber can be agglomerated, the elasticity of the elastic material, the original polyester, the silk The physical properties of the elastic bombardment silk hydrocarbon hoofed polyamines. The hair and the esters are acidic methylamine compounds, the polysynthetic elastomers, and isocratic C are better than the esters and other acidic methamidoamines. In terms of strength and strength, it has a long-lasting resistance, such as poly-esters, polyisoesters, and iso-alcohols, which can be used for polymerization of polyisocyanates and alcohols, so that the esters of mixed acids can be mixed with amines to make them non-polymerized. 〇 Alcohol is a polyether ether extended chain with the pre-substituted product as the melamine. Diamine A is polymerized with tetramethylol. The product is polymerized with the same example or alcohol, polymer, polyester, and polyester. In the generation, it is an equal polymer, and should be, the polyalcohol of polyalcohol of polyalcohol of the reverse alcohol, and the alcohol is carbon. Esterene, polyethylene glycol dilactone, dipropylene, alcohol diethyl, and ester acetic acid make the ancient polyester polyester acid mixed with other compounds. The acid should be reversed and the acid should be reacted again. Yes, you should wait for the inverse acid alcohol binary; Decado, the acid, such as glycols nonyl, neo-acid, di (please read the precautions on the back before filling this page) Order-• Line-Staff of Intellectual Property Bureau, Ministry of Economic Affairs Consumption cooperative printing studies, good quality alcohol polymer, ester polymer used to restore the ancient history of recovery, water resistance is stretched out, neutral and so on. This is the quantum. It is used for the same purpose. Mixed 00 00 Continued 23 To hold a kind of 00 2 sex 15 or shrink to a kind of stretcher 1 The best use of silk is more flexible and can be 00 alcohol As for the paper size of 40 pol ~~ 00, etc., the paper size of this paper applies the Chinese National Standard (CNS) A4 specification (210 X 29.7 mm). It is printed by the staff of the Intellectual Property Bureau of the Ministry of Economic Affairs and printed by the cooperative 581834, A7 B7 5 ^ V. Description of the invention () Diisofluoric acid is, for example, 4,4-diphenylmethane diisocyanate, 1,5- Aromatic diisocyanates such as 1,4-diphenylene diisocyanate, 2,4-methylphenylene diisocyanate, 2,6-methylphenylene diisocyanate, and hexamethylene Aliphatic diisocyanates such as diisocyanate, 1,4-cyclohexyl diisocyanate, 4,4 dicyclohexyl diisocyanate, isophorone diisocyanate, and the like. Among these, 4, 4 · -diphenylmethane diisocyanate is preferred in order to increase the strength of the elastic yarn. These two isophosphonates may be used singly or in combination of two or more kinds. The amine compound is usually an aliphatic, cycloaliphatic or aromatic diamine. Specific examples include ethylenediamine, 1,2-propylenediamine, 1,3-propylenediamine, 1,4-butenediamine, 2,3-butenediamine, 1,3butene Diamine, hexamethylenediamine, cyclohexyldiamine, phenylenediamine, tolyldiamine, xylylenediamine, 3, 3f -dichloro-4,4-benzidine, 2, 6-diaminopyridine, 4,4'-diaminodiphenylmethane and the like. These amine compounds may be used singly or in combination of two or more kinds. -End-sealing agents used for end-sealing include dimethylamine, monoethanolamine, n-propylamine, n-butylamine, diethylamine, methanol, propanol (1-propanol, 2-propanol), butanol (butin Alcohol, 2-butanol), etc. The ends are sealed and can be added after the chain extension. It can also be added during the prepolymer reaction (for example, the reaction between a polyol and a diisocyanate) or it can be added during the chain extension. . The oil agent coated by elastic yarns can be modified polysilicone with dimethylpolysiloxane and dimethylpolysiloxane in which some methyl groups are replaced with other alkyl groups, phenyl groups, amino groups, etc. Polysiloxane gas, mineral oil, etc. In order to make the multifilament elastic wire of the present invention adhere to the base material of sanitary material products -10- k · ------- order ---------. (Please read the precautions on the back before (Fill in this page) Shi Bismuth Chess sores Zhan Tian 圃 固 固 固 WO WO iWO X㈧7 公 蝥) Zu 824 A7. B7___ 5. Description of the invention (9) The adhesive used can be used in this range Conventional adhesives used for bonding substrates of sanitary material products of elastic yarns are not particularly limited. They are bonded by hot-melt type of vinyl polymer strips, saturated polyesters, or polyamides. Agent is preferred. [Examples] Hereinafter, the present invention will be described in more detail with reference to examples and comparative examples. The evaluation of the adhesiveness of the elasticity M in the examples and comparative examples was performed by the following method. (1) The use of thin sanitary materials is made of Toyobo Textile Co., Ltd., and it is placed in a length of 12 cm x 3 horizontal ra. Non-woven woolen fabrics or shrinkable fabrics are the reason for the uneven adhesiveness, so the unified adhesive surface is evaluated ft 〇 (2) No elasticity is eased without tension on the elastic filaments, 5 pieces are lined up on thick paper and cellophane is used. With overlay. (3) The hot-melt adhesive made of ethylene, propylene, butadiene, and styrene copolymer is melted at 17 degrees Fahrenheit, and the discharge amount is set to 5 g / min from the extruder to make the unitary unisexual The silk and the elastic yarn covered on the thick paper side by side are moved in a vertical direction at a speed of 30 cm / min, so that the hot-melt adhesive is applied in a linear shape. Then, the nonwoven fabric represented by the formula (1) was pressed at a pressure of 2 kg / c in 2 for 10 seconds to obtain a sample for measuring adhesiveness. The test sample was fabricated using J T Dunxi (transliteration) (AS) M-15 adhesive force evaluation machine. (4) Keep the sample obtained at (3) in a room at 2 [) ° C for 4 hours, and fix the non-woven fabric and the elastic yarn tightly. Use Oriondick-1 1-This paper size applies China National Standard (CNS) A4 Specification (210 X 297 mm) (Please read the notes on the back before filling out this page) Order --------- Line | Printed by the Employees ’Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 581834 A7 ___B7___ V. Description of the invention (10) (Transliteration) Co., Ltd. measuring machine ϋ-1 5 7 3 Stretch up and down, and record the non-woven fabric and elastic yarn on the chart paper and peel it off. (Please read the precautions on the back before filling this page) At this time, read the strength required for peeling the elastic yarn from the non-woven fabric from the chart paper, and use this value as the adhesive force (c Ν).
(5 )確認黏接性之經時變化，使兩者黏接並保持於2 0 °C 之房間內保存1 〇 〇小時，以與（4 )相同的手法剝離。 ※於尿布製品中幾乎不會引起彈性絲拉出問題之黏接 力為.1 5 0 c N，以1 5 0 c N以上為合格水準。 (實施例1 ) 在分子‘量為1，9 5 0之聚四亞甲醚醇中加入2 5 ϋ份H -二苯基甲烷二異氯酸酯並予以攪拌、反應，製得聚合物 ，再將該預聚物溶解於二甲基乙禪胺後，加入1，2 -丙烯 二胺予以鐽延長，且以二乙胺進行末端密封，製得聚胺 甲酸酯溶液。 使用在第2圖所示之長邊長2 5 c m、短邊·長1 Q c m之噴嘴 夾1 a中上下二列各配置有4値七孔圓形噴嘴1 b之噴絲.板 ，且使該噴絲板之長軸以導絲锟5 a、 5 b之長軸方向平行 經濟部智慧財產局員工消費合作社印製 設置’（第1圖）。使聚.胺甲酸酯溶液通過噴絲板1 ,押至 流通有2 4 0 °C熱風之紡絲筒2 ·中，且使所得的5 6條單絲 在設置於紡絲筒2下方之陶瓷製絲集束用導口 3之圓孔 導_孔3 a内面擦拭，集束成扁平狀且使單絲間熔融，藉 由設置於絲集束用導口 3,與導絲锟5a間之油劑給予設備 4塗覆油劑，以導絲锟5a、5b以3ϋ()πι/分捲取，製得附 箸0 . 0 5重量％油劑之聚胺甲酸酯彈性絲之筒子絲6 A。 -1 2 _ 本紙張尺度適用中國國家標準（CNS)A4規格（210 x 297公釐） 581834 A7 _B7 五、發明說明（13) 之黏接性試驗評估。結果如下逑表1所示。 表1 實施例1 實施例2 贸施例3 比較例1 L,/Ls 6.4 * 6.2 2.2 1.1 L1/L2 0.75 0.76 0.70 0.61 油劑附著量(重 1%) 0.05 3.00 0.05 0.05 黏接24小時後 之剝離強度 (cN) 428 242 236 153 黏接1〇〇小時 後之剝離強度 (cN) 417 220 221 138 (請先閱讀背面之注意事項再填寫本頁) 由表1可知，實施例之彈性絲偽予塗覆有黏接劑之不 纈布以高黏接力黏接，互經過1 ο ϋ小時後仍可維持其高 黏接力。另外，比較例之2 4小時後之黏接力雖可達到合 格的水準（1 5 Q c Ν )，惟1 () 0小時後之黏接力較1 5 0 c Ν為低。 珀上逑之説明可知，本發明之衛生材料製品用彈性絲 對塗覆有黏接劑之基材的黏接力較以往提高，且自筒子 絲之舒解性佳。因此，可安定地製造不會拉出彈性絲且 信賴性高的衛生材料製品。 經濟部智慧財產局員工消費合作社印製 [圖式簡單說明] 第1圖偽為製造本發明彈性絲之裝置例的模式圖。 第2圖傺為第1圖之裝置的紡絲模具之詳細圖。 第3圖傺為製造本發明彈性絲之另一裝置例的模式圖。 第4圖係為第3圖之裝置的紡絲模具之詳細圖。 -1 5 - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 58-1834 A7 B7 五、發明說明（） 第5圖偽為習知彈性絲之製造裝置的模式圖。 [符號説明] a 5 板夾筒 絲嘴絲 噴噴纺 P 入 導 用 備 束設 集予 絲賦 一劑 入油 0^ b 5 c · 6 b 7 、 . B . 、 6 na 7 A 、 6 7 T 筒 絲機 性為 輥彈撚 絲 (請先閱讀背面之注意事項再填寫本頁) -I -------訂----------線丨 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐）(5) Confirm the change of adhesion with time, make them adhere and keep them in a room at 20 ° C for 1000 hours, and peel them by the same method as (4). ※ In diaper products, the adhesion force that hardly causes the problem of the elastic yarn pull-out is .150 c N, and the acceptance level above 150 c N is acceptable. (Example 1) To polytetramethylene ether alcohol having a molecular weight of 1,950, 25 parts of H-diphenylmethane diisochlorate was added and stirred to react to obtain a polymer. After the prepolymer was dissolved in dimethylethylamine, 1,2-propanediamine was added to extend the length of the prepolymer, and diethylamine was used for end sealing to obtain a polyurethane solution. A spinneret plate with 4 値 7-hole circular nozzles 1 b in the upper and lower two rows of the nozzle holder 1 a with a long side of 25 cm in length and a short side of 1 Q cm in length shown in Fig. 2 is used, and Make the long axis of the spinneret parallel to the long axis directions of the guide wires 锟 5 a and 5 b and print and set it to the employee's consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs (Figure 1). The polyurethane solution was passed through the spinneret 1 and pressed into a spinning cylinder 2 with hot air flowing at 2 40 ° C, and the obtained 56 monofilaments were placed below the spinning cylinder 2. The inner surface of the circular hole guide hole 3a of the guide wire 3 for ceramic wire bundles is wiped, and the bundles are flattened to melt the monofilaments. The oil agent is provided between the guide wire 3 for wire bundles and the guide wire 锟 5a. Oil was applied to the device 4 and the guide wires a5a, 5b were taken up at 3ϋ (ϋπι / minute) to obtain a bobbin silk 6 A of polyurethane elastic yarn with 0.5% by weight oil. . -1 2 _ This paper size is in accordance with China National Standard (CNS) A4 (210 x 297 mm) 581834 A7 _B7 V. Evaluation of the adhesion test of invention description (13). The results are shown in Table 1 below. Table 1 Example 1 Example 2 Trade Example 3 Comparative Example 1 L, / Ls 6.4 * 6.2 2.2 1.1 L1 / L2 0.75 0.76 0.70 0.61 Oil adhesion amount (weight 1%) 0.05 3.00 0.05 0.05 Peel strength (cN) 428 242 236 153 Peel strength (cN) after 100 hours of bonding 417 220 221 138 (Please read the precautions on the back before filling this page) From Table 1, it can be seen that the elastic silk of the embodiment is false The pre-coated non-valer cloth is adhered with high adhesive force, and the high adhesive force can be maintained even after 1 ο ϋ hours of each other. In addition, although the adhesive force after 24 hours of the comparative example can reach a satisfactory level (1 5 Q c Ν), the adhesive force after 1 (0) hours is lower than that of 150 0 c Ν. It can be seen from the description of Permanente that the adhesive force of the elastic yarn for sanitary material products of the present invention on the substrate coated with the adhesive is higher than that in the past, and the self-releasing property of the silk is good. Therefore, it is possible to stably manufacture a sanitary material product having high reliability without pulling out the elastic yarn. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs [Simplified Illustration] Figure 1 is a schematic diagram of an example of a device for manufacturing the elastic yarn of the present invention. Fig. 2 (i) is a detailed view of the spinning mold of the apparatus of Fig. 1. FIG. 3 is a schematic view of another example of an apparatus for manufacturing the elastic yarn of the present invention. Fig. 4 is a detailed view of the spinning mold of the apparatus of Fig. 3. -1 5-This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 58-1834 A7 B7 V. Description of the invention () Figure 5 is a schematic diagram of a conventional elastic yarn manufacturing device. [Symbol description] a 5 plate collet, silk nozzle, silk-jet spinning, P, guide, preparation set, wire, oil, 0 ^ b 5 c · 6 b 7,. B., 6 na 7 A, 6 7 T bobbin is made of roll-twisted yarn (please read the precautions on the back before filling this page) -I ------- Order ---------- Line 丨 Ministry of Economics Intellectual Property The paper size printed by the Bureau ’s Consumer Cooperatives applies the Chinese National Standard (CNS) A4 (210 X 297 mm)