JP2001064825A - Elastic yarn for sanitary product - Google Patents

Elastic yarn for sanitary product

Info

Publication number
JP2001064825A
JP2001064825A JP2000003952A JP2000003952A JP2001064825A JP 2001064825 A JP2001064825 A JP 2001064825A JP 2000003952 A JP2000003952 A JP 2000003952A JP 2000003952 A JP2000003952 A JP 2000003952A JP 2001064825 A JP2001064825 A JP 2001064825A
Authority
JP
Japan
Prior art keywords
yarn
elastic yarn
elastic
section
cross
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2000003952A
Other languages
Japanese (ja)
Other versions
JP4045711B2 (en
Inventor
Kosuke Iwata
浩介 岩田
Hideyuki Ohashi
英之 大橋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toyobo Co Ltd
Original Assignee
Toyobo Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyobo Co Ltd filed Critical Toyobo Co Ltd
Priority to JP2000003952A priority Critical patent/JP4045711B2/en
Priority to CNB001080695A priority patent/CN1139680C/en
Priority to KR1020000033672A priority patent/KR100592216B1/en
Priority to TW089112086A priority patent/TW581834B/en
Publication of JP2001064825A publication Critical patent/JP2001064825A/en
Application granted granted Critical
Publication of JP4045711B2 publication Critical patent/JP4045711B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/70Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyurethanes
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D4/00Spinnerette packs; Cleaning thereof
    • D01D4/02Spinnerettes
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/04Dry spinning methods

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Artificial Filaments (AREA)

Abstract

PROBLEM TO BE SOLVED: To simultaneously raise the adhesion of an elastic yarn to a substrate while maintaining unwinding properties of the elastic yarn. SOLUTION: This multifilament elastic yarn is obtained by dry spinning an elastic polymer and has a flat cross section of >=2 ratio (Ll/Ls) of the long side (Ll) to the short side (Ls) of a rectangle circumscribed with the filament cross section of the elastic yarn. Furthermore, unevennesses are preferably formed by an outer shape of the single filaments on the surface of the elastic yarn and the length ratio (L1/L2) of the perimeter (L1) of the rectangle circumscribed with the filament cross section of the elastic yarn to the perimeter (L2) of the filament cross section of the elastic yarn has <=0.9 degree of the unevennesses.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は紙おむつや生理用ナ
プキン等の衛材製品用の弾性糸に関し、詳しくは、衛材
製品において接着剤を介した基材との良好な接着性を保
持する弾性糸に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to elastic yarns for sanitary products such as disposable diapers and sanitary napkins, and more particularly, to elastic yarns for maintaining good adhesiveness to base materials via an adhesive in sanitary products. Regarding yarn.

【0002】[0002]

【従来の技術】近年、紙おむつや生理用ナプキンなどの
衛材用途の製品(以下、衛材製品と称する。)が多岐に
わたって商品開発され、それに対する品質要求もより厳
しくなっている。かかる衛材製品では、装着部位へのフ
ィット性を上げるため、弾性ポリマーを紡糸して得られ
た弾性糸を複合利用して伸縮性を付与することが行われ
る。かかる弾性糸は、通常、布帛、不織布又はシート等
からなる衛材製品の基材の伸縮性を付与したい部分に接
着剤を介して接着されている。
2. Description of the Related Art In recent years, a wide variety of products for sanitary use (hereinafter referred to as sanitary wares) such as disposable diapers and sanitary napkins have been developed in a wide variety of products, and the quality requirements for them have become more stringent. In such a sanitary ware product, in order to improve the fit to a mounting site, elasticity is imparted by using an elastic yarn obtained by spinning an elastic polymer in combination. Such an elastic yarn is usually bonded via an adhesive to a portion of a base material of a sanitary ware made of a cloth, a nonwoven fabric, a sheet, or the like, to which elasticity is to be imparted.

【0003】弾性糸を衛材製品に使用する場合、弾性糸
は通常チーズ状形態で捲き取った捲糸体から衛材製品に
供給され、伸張させながら解舒し、接着剤を塗布した布
帛、不織布又はシート等に導かれ、接着面に圧力を加え
ることで、布帛、不織布又はシート等と接着している。
When an elastic yarn is used in a sanitary ware product, the elastic yarn is usually supplied to the sanitary ware from a wound body wound in a cheese-like form, unwound while being stretched, and coated with an adhesive. It is guided to a nonwoven fabric or a sheet, etc., and is bonded to a cloth, a nonwoven fabric, a sheet, or the like by applying pressure to the bonding surface.

【0004】[0004]

【発明が解決しようとする課題】衛材製品用途に使用さ
れている弾性糸は、衛材製品にストレッチ性を付与する
ために伸張され、布帛、不織布又はシートからなる基材
に接着剤を介して接着される。そのため、伸張されて接
着された弾性糸と基材との接着力が不十分であると、弾
性糸が基材から剥離、収縮し、製造された衛材製品にお
いて、弾性糸の引き込みが生じて、製品の品質が悪化し
てしまう。
The elastic yarn used for the use of a sanitary ware product is stretched in order to impart a stretch property to the sanitary ware product, and is applied to a base material made of a cloth, a nonwoven fabric or a sheet via an adhesive. Glued. Therefore, if the adhesive force between the stretched and bonded elastic yarn and the base material is insufficient, the elastic yarn peels off and shrinks from the base material, and the drawn elastic yarn occurs in the manufactured safety material product. , The quality of the product will deteriorate.

【0005】また、チーズ形態に巻かれた弾性糸は、チ
ーズの内層で捲き締められるため、衛材製品の製造工程
において弾性糸の糸切れや供給張力が変動するなどの問
題を発生してしまう。そのため、解舒性の悪化や張力変
動を防止することを目的として、通常、表面を油剤で処
理している。このような弾性糸を衛材製品の布帛、不織
布等の基材に接着する場合、基材との接着性が不十分と
なり、上記したような問題が生じる。弾性糸の接着性低
下を避けるために、油剤付着量を下げていくと、弾性糸
チーズの解舒性が悪くなり、衛材製品の製造工程におい
て弾性糸の糸切れや供給張力が変動するという問題を生
ずる。また、弾性糸の接着性を向上しようと、接着剤の
塗布量を増やすと、製品コストが高くなると共に、衛材
製品の風合いや通気性が損なわれるという問題を生じて
しまう。
[0005] Further, since the elastic yarn wound in the cheese form is wrapped around the inner layer of the cheese, there arises a problem that the elastic yarn breaks or the supply tension fluctuates in the process of manufacturing the safety material product. . Therefore, the surface is usually treated with an oil agent for the purpose of preventing the unwinding property from being deteriorated and the tension from fluctuating. When such an elastic yarn is adhered to a base material such as a fabric or a non-woven fabric of a sanitary ware, the adhesion to the base material becomes insufficient, and the above-described problem occurs. If the amount of oil agent attached is reduced to avoid a decrease in the adhesiveness of the elastic yarn, the unwinding property of the elastic yarn cheese will deteriorate, and the yarn breakage and supply tension of the elastic yarn will fluctuate in the manufacturing process of the sanitary products. Cause problems. Further, if the amount of the adhesive applied is increased in order to improve the adhesiveness of the elastic yarn, the cost of the product is increased and the feeling and the air permeability of the sanitary ware are impaired.

【0006】本発明は上記のような事情に鑑みてなされ
たもので、弾性糸の解舒性を維持しながら、同時に基材
への接着性を高めることを目的とするものである。
The present invention has been made in view of the above circumstances, and has as its object to improve the adhesiveness to a base material while maintaining the unwinding property of an elastic yarn.

【0007】[0007]

【課題を解決するための手段】本発明者らは、上記課題
を解決すべく、鋭意研究した結果、衛材製品における基
材と弾性糸との接着不良の問題は、基材と弾性糸との接
触面積の問題であり、弾性糸の形状を工夫することによ
り、解舒性を維持しながら接着性を高めることができる
ことを知見し、かかる知見に基づき本発明を完成させ
た。すなわち、本発明は下記の通りである。
Means for Solving the Problems The inventors of the present invention have conducted intensive studies in order to solve the above-mentioned problems, and as a result, the problem of poor adhesion between the base material and the elastic yarn in the sanitary ware product has been reported. The present inventors have found that by devising the shape of the elastic yarn, it is possible to increase the adhesiveness while maintaining the unwinding property, and based on this finding, completed the present invention. That is, the present invention is as follows.

【0008】(1)弾性ポリマーを乾式紡糸して得られ
たマルチフィラメント弾性糸であって、弾性糸の糸条断
面に外接させた長方形の長辺(Ll )と短辺(Ls )の
長さ比(Ll /Ls )が2以上の扁平断面を有すること
を特徴とする衛材製品用弾性糸。
(1) A multifilament elastic yarn obtained by dry-spinning an elastic polymer, wherein a long side (L l ) and a short side (L s ) of a rectangular shape circumscribed around the yarn cross section of the elastic yarn. An elastic yarn for a sanitary ware product having a flat section having a length ratio (L 1 / L s ) of 2 or more.

【0009】(2)弾性糸の糸条表面に弾性糸を構成す
る単糸の断面形状による凹凸が形成されており、弾性糸
の糸条断面に外接させた長方形の周長(L1)と弾性糸
の糸条断面の周長(L2)との長さ比(L1/L2)が
0.9以下である上記(1)記載の衛材製品用弾性糸。
(2) On the surface of the elastic yarn, irregularities due to the cross-sectional shape of a single yarn constituting the elastic yarn are formed, and the rectangular circumference (L1) circumscribed around the yarn cross-section of the elastic yarn and the elasticity The elastic yarn for a sanitary ware product according to the above (1), wherein a length ratio (L1 / L2) of the yarn cross section to the circumferential length (L2) is 0.9 or less.

【0010】(3)弾性糸表面に油剤が塗布され、該油
剤の塗布量が糸条重量に対して0.01〜5重量%であ
る上記(1)又は(2)に記載の衛材製品用弾性糸。
(3) The sanitary ware product according to (1) or (2), wherein an oil agent is applied to the surface of the elastic yarn, and the applied amount of the oil agent is 0.01 to 5% by weight based on the weight of the yarn. For elastic yarn.

【0011】(4)繊度が155〜2490デシテック
スの範囲にある上記(1)〜(3)のいずれかに記載の
衛材製品用弾性糸。
(4) The elastic yarn for a sanitary ware product according to any one of (1) to (3), wherein the fineness is in the range of 155 to 2490 dtex.

【0012】(5)弾性ポリマーがポリウレタンである
上記(1)〜(4)のいずれかに記載の衛材製品用弾性
糸。
(5) The elastic yarn for a sanitary ware product according to any one of the above (1) to (4), wherein the elastic polymer is polyurethane.

【0013】本発明において、弾性糸の糸条断面に外接
させた長方形の長辺(Ll )と短辺(Ls )とは、弾性
糸を両面テープで作業台上に固定し、かみそりの刃を用
いて、弾性糸の長さ方向と垂直に荷重490cN以上で
カットし、その断面を拡大鏡で拡大して写真撮影し、写
真に写った弾性糸断面に外接させた長方形の長辺と短辺
を測定したものである。
In the present invention, the long side (L l ) and the short side (L s ) of the rectangular shape circumscribed on the thread cross section of the elastic yarn are determined by fixing the elastic yarn on a work table with a double-sided tape, Using a blade, cut with a load of 490 cN or more perpendicular to the length direction of the elastic yarn, magnify the cross section with a magnifying glass, take a picture, and make the long side of the rectangle circumscribed to the elastic yarn cross section shown in the photograph. The short side was measured.

【0014】また、弾性糸の糸条断面に外接させた長方
形の周長(L1)と弾性糸断面の周長(L2)とは、上
記写真上で弾性糸断面に外接させた長方形の周長と写真
に写った弾性糸断面の周長である。なお、写真に写った
弾性糸断面に外接させることのできる長方形が複数存在
する場合は、Ll /Ls が最大となる長方形を採用す
る。
The perimeter (L1) of the rectangle circumscribed on the cross section of the elastic yarn and the perimeter (L2) of the cross section of the elastic yarn are defined as the perimeter of the rectangle circumscribed on the cross section of the elastic yarn in the above photograph. And the circumference of the cross section of the elastic yarn shown in the photograph. When there are a plurality of rectangles that can be circumscribed on the elastic yarn cross section shown in the photograph, the rectangle that maximizes L 1 / L s is adopted.

【0015】[0015]

【発明の実施の形態】本発明の衛材製品用弾性糸は、弾
性糸の糸条断面に外接させた長方形の長辺(Ll )と短
辺(Ls )の長さ比(Ll /Ls )が2以上の扁平断面
を有するマルチフィラメント弾性糸である。
BEST MODE FOR CARRYING OUT THE INVENTION The elastic yarn for sanitary ware of the present invention has a length ratio (L l ) of a long side (L l ) and a short side (L s ) of a rectangle circumscribed on the cross section of the elastic yarn. / L s ) is a multifilament elastic yarn having a flat cross section of 2 or more.

【0016】従来の乾式紡糸により得られる衛材製品用
弾性糸は、一般に、弾性ポリマーの溶液を、紡糸口金の
細孔を通して紡糸筒内に押し出し、複数の単糸を仮撚り
機によって交絡させて繊維長さ方向に融着することで目
標デニールの糸条を製造している。かかる製法で得られ
る弾性糸は、それが扁平化したものであっても、弾性糸
の糸条断面に外接させた長方形の長辺と短辺の長さ比は
2未満であった。本発明の衛材製品用弾性糸は、弾性糸
の糸条断面に外接させた長方形の長辺と短辺の長さ比
(長辺/短辺)が2以上の高い扁平度を有するものと
し、これによって、衛材製品基材への接触面積(同一繊
度での比較)を従来の弾性糸のそれよりも大きくして、
接着力を高めている。また、本発明の衛材製品用弾性糸
をおむつ等に使用した際、糸条が高い扁平度を有するの
で、衛材製品の身体への密着面積が増大し、排泄物の漏
れ防止能力が向上し、また、締めつけ力の分散により圧
迫感が軽減されるという利点も得られる。
The elastic yarn for sanitary products obtained by conventional dry spinning is generally obtained by extruding a solution of an elastic polymer into the spinning cylinder through the pores of a spinneret, and interlacing a plurality of single yarns with a false twisting machine. The target denier yarn is manufactured by fusing in the fiber length direction. Even if the elastic yarn obtained by such a manufacturing method is a flattened one, the ratio of the length of the long side to the short side of the rectangle circumscribed on the yarn cross section of the elastic yarn was less than 2. The elastic yarn for a sanitary ware of the present invention has a high flatness in which the length ratio (long side / short side) of a long side and a short side (long side / short side) circumscribed to the thread cross section of the elastic yarn is 2 or more. This allows the contact area (compared with the same fineness) to the base material of the safety material to be larger than that of the conventional elastic yarn.
Increases adhesive strength. Further, when the elastic yarn for sanitary products of the present invention is used for diapers and the like, the thread has a high flatness, so that the area of close contact of the sanitary products with the body is increased, and the ability to prevent excrement leakage is improved. In addition, there is an advantage that the feeling of oppression is reduced due to the dispersion of the tightening force.

【0017】本発明の弾性糸において、糸条断面に外接
させた長方形の長辺(Ll )と短辺(Ls )の長さ比
(Ll /Ls )が大きい程、基材への接着強度は高くな
るが、大きすぎると、チーズからの解舒性が低下する傾
向を示す。よって、2〜8の範囲内とするのが好まし
い。
In the elastic yarn of the present invention, the longer the length ratio (L 1 / L s ) of the long side (L l ) and the short side (L s ) of the rectangle circumscribed on the yarn cross section, the larger the ratio to the substrate. However, if it is too large, the unwinding property from cheese tends to decrease. Therefore, it is preferable to be in the range of 2 to 8.

【0018】本発明の弾性糸を製造する方法は特に制限
されないが、例えば、以下の方法を挙げることができ
る。すなわち、従来の乾式紡糸で行われていた、紡糸口
金から押し出された全単糸を一括して仮撚り機で交絡す
る作業は行わず、口金から押し出された単糸を、紡糸筒
と捲き取り機の間で、ガイドに擦らせてガイド上で集束
させて融着する。これによって、高い扁平度の糸条を得
ることができる。ここで、単糸を集束する糸収束用ガイ
ドの形状や材質は特に限定されないが、例えば、U字の
ガイド溝や丸孔のガイド孔を有する部材が用いられ、特
に、丸孔のガイド孔の内面で単糸を擦らせるようにする
と、糸長さ方向に安定に扁平断面化がなされ、好まし
い。また、ガイドの材質は糸条との接触摩擦が小さくな
る点でセラミックス製が好ましい。上記丸孔のガイド孔
の内面で糸をガイドする部材の場合、丸孔の直径は1〜
15mmの範囲が好ましく、2〜5mmの範囲が特に好
ましい。弾性糸の繊度及び単糸の本数等によっても異な
るが、丸孔の直径が1mm未満であると、丸孔の内面へ
の糸摩擦が高くなって、長時間紡糸を行うと単糸切れが
発生しやすくなり、丸孔の直径が15mmより大きくな
ると、単糸同士の接触が不十分になって、単糸同士が糸
条長さ方向に安定に融着されなくなるおそれがある。
The method for producing the elastic yarn of the present invention is not particularly limited, and examples thereof include the following method. In other words, the work of entangling all the single yarns extruded from the spinneret collectively by the false twisting machine, which was performed in the conventional dry spinning, is not performed, and the single yarn extruded from the spinneret is wound up with a spinning cylinder. Between the machines, they are rubbed against the guide, focused on the guide and fused. Thereby, a high flatness yarn can be obtained. Here, the shape and material of the yarn convergence guide for bundling the single yarn are not particularly limited. For example, a member having a U-shaped guide groove or a round hole guide hole is used. When the single yarn is rubbed on the inner surface, a flat cross section is stably formed in the yarn length direction, which is preferable. The material of the guide is preferably made of ceramics in that the contact friction with the yarn is reduced. In the case of a member that guides the yarn on the inner surface of the guide hole of the round hole, the diameter of the round hole is 1 to
A range of 15 mm is preferred, and a range of 2 to 5 mm is particularly preferred. Depending on the fineness of the elastic yarn and the number of single yarns, etc., if the diameter of the round hole is less than 1 mm, the yarn friction on the inner surface of the round hole will increase, and if the spinning is performed for a long time, the single yarn will break. When the diameter of the round hole is larger than 15 mm, the contact between the single yarns becomes insufficient, and the single yarns may not be stably fused in the yarn length direction.

【0019】本発明の弾性糸を得る別の方法としては、
紡糸口金から押し出された複数の単糸を2以上の群に分
け、各群毎で単糸を仮撚り機で交絡して2以上の糸条と
した後、該2以上の糸条をガイドに擦らせてガイド上で
合糸(融着)して目的の繊度の糸条を形成する方法が挙
げられる。
Another method for obtaining the elastic yarn of the present invention is as follows.
The plurality of single yarns extruded from the spinneret are divided into two or more groups, and in each group, the single yarns are entangled with a false twisting machine to form two or more yarns, and the two or more yarns are used as guides. A method of forming a yarn having a desired fineness by rubbing and combining (fusing) on a guide.

【0020】これら例示の方法を用いると、紡糸された
全単糸を一括して交絡せず、全単糸の融着、一体化を、
ガイド上で糸を集束することにより行うので、糸条断面
に外接させた長方形の長辺(Ll )と短辺(Ls )の長
さ比(Ll /Ls )が2以上の扁平度の高い扁平断面の
糸条が容易に得られ、しかも、糸条表面には単糸の表面
による凹凸が残されたものとなる。特に、前者の方法で
得られる糸条は、単糸同士を全く交絡させないので、糸
条表面に単糸の表面による凹凸が顕著に現れる。すなわ
ち、断面扁平化と表面凹凸による糸条表面積の拡大とに
よって、従来の弾性糸に比して接着剤への接触面積(同
一繊度での比較)が飛躍的に拡大することとなる。な
お、糸条表面の凹凸度が高いほど糸条の表面積は大きく
なり、接着力の向上が期待できる。よって、糸条断面に
外接させた長方形の周長(L1)と糸条断面の周長(L
2)との長さ比(L1/L2)で表される凹凸の度合い
が0.9以下であるのが好ましく、0.85以下であれ
ばより好ましく、0.80以下であればとりわけ好まし
い。しかし、糸条表面の凹凸度が高いほど、単糸同士の
融着が弱く、単糸がばらけやすくなるので、上記長さ比
(L1/L2)は0.4以上であるのが好ましい。
When these exemplified methods are used, all the spun single yarns are not entangled at once, and the fusion and unification of all the single yarns are performed.
Since the yarn is bundled on the guide, the length ratio (L 1 / L s ) of the long side (L 1 ) and the short side (L s ) of the rectangle circumscribed on the yarn cross section is 2 or more. A highly flat yarn having a flat cross section can be easily obtained, and the yarn surface has irregularities due to the surface of the single yarn. In particular, in the yarn obtained by the former method, since the single yarns are not entangled at all, irregularities due to the surface of the single yarns are remarkably shown on the yarn surface. That is, due to the flattening of the cross section and the increase in the yarn surface area due to the surface unevenness, the contact area (comparison with the same fineness) with the adhesive is dramatically increased as compared with the conventional elastic yarn. In addition, the surface area of the yarn increases as the degree of unevenness of the yarn surface increases, and an improvement in the adhesive strength can be expected. Therefore, the circumference (L1) of the rectangle circumscribing the yarn cross section and the circumference (L1) of the yarn cross section
The degree of unevenness represented by the length ratio (L1 / L2) to 2) is preferably 0.9 or less, more preferably 0.85 or less, and particularly preferably 0.80 or less. However, the higher the degree of unevenness of the yarn surface, the weaker the fusion between the single yarns and the easier the single yarns are to be separated, so that the length ratio (L1 / L2) is preferably 0.4 or more.

【0021】また、上記例示の方法で、本発明の弾性糸
を得る場合、紡糸口金の最も遠く離れた細孔間の寸法
(A)と紡糸口金から糸集束用ガイドまでの距離(B)
との比(B/A)を、10より大きくするのが好まし
い。(B/A)が10以下であると、ガイドへ入る単糸
の角度が大きく、ガイドとの摩擦による糸切れが生じる
危険性がある。
When the elastic yarn of the present invention is obtained by the above-described method, the distance between the furthest pores of the spinneret (A) and the distance from the spinneret to the yarn collecting guide (B)
The ratio (B / A) is preferably larger than 10. If (B / A) is 10 or less, the angle of the single yarn entering the guide is large, and there is a risk that the yarn may break due to friction with the guide.

【0022】本発明の弾性糸の繊度は特に限定されない
が、一般に155〜2490デシテックス(140〜2
240デニール)、好ましくは470〜940デシテッ
クス(420〜840デニール)である。また、単糸の
繊度は一般に9〜22デシテックス(8〜20デニー
ル)、好ましくは11〜17デシテックス(10〜15
デニール)である。また、単糸は丸型断面でも異形断面
でもよい。
Although the fineness of the elastic yarn of the present invention is not particularly limited, it is generally 155 to 2490 dtex (140 to 2).
240 denier), preferably 470-940 dtex (420-840 denier). The fineness of the single yarn is generally 9 to 22 dtex (8 to 20 denier), preferably 11 to 17 dtex (10 to 15 denier).
Denier). The single yarn may have a round cross section or an irregular cross section.

【0023】本発明の弾性糸は、捲き取り機で捲き取ら
れて最終的にチーズにされるが、チーズからの糸の解舒
性が良好となるよう、捲き取り機で捲き取られる前に油
剤が塗布される。かかる油剤の付着量は糸条重量に対し
て0.01〜5重量%が好ましい。上記範囲にすると接
着性、解舒性ともに良好なものとなる。
The elastic yarn of the present invention is wound up by a winder and finally made into cheese. Before the yarn is wound up by the winder so that the yarn can be easily unwound from the cheese. An oil agent is applied. The amount of the oil agent attached is preferably 0.01 to 5% by weight based on the weight of the yarn. When the content is in the above range, the adhesiveness and the unwinding property are both good.

【0024】上記油剤の付着量は、弾性糸(糸条)に油
剤を塗布することなくそのまま捲き取りローラで正確に
20000m捲き取って得られる捲回体Xの重量と、弾
性糸(糸条)に油剤を塗布して捲き取りローラで正確に
20000m捲き取って得られる捲回体Yの重量とを測
定し、これらを下記の計算式に当てはめて得られる値で
ある。 油剤付着量(%)={(捲回体Yの重量)−(捲回体X
の重量)}/(捲回体Xの重量)×100
The adhesion amount of the oil agent is determined by the weight of the wound body X obtained by winding the elastic yarn (yarn) exactly 20,000 m by the winding roller without applying the oil agent, and the elastic yarn (yarn). The weight of the wound body Y obtained by applying an oil agent to the sample and winding it up by 20,000 m with a winding roller is measured, and these values are obtained by applying the following formulas. Oil adhesion (%) = {(weight of wound body Y) − (winded body X
Weight)} / (weight of wound body X) × 100

【0025】本発明のマルチフィラメント弾性糸の原料
となる弾性ポリマーとしては、ポリウレタン、ポリオレ
フィンエラストマー、ポリエステルエラストマー、合成
ゴム等を使用できるが、特に強伸度、回復性等の物性、
物理的、化学的な耐久性等の点からポリウレタンが好ま
しい。これらの弾性ポリマーは2種以上を混合して使用
できることは言うまでもない。
As the elastic polymer used as a raw material of the multifilament elastic yarn of the present invention, polyurethane, polyolefin elastomer, polyester elastomer, synthetic rubber and the like can be used.
Polyurethane is preferred in terms of physical and chemical durability. Needless to say, these elastic polymers can be used as a mixture of two or more kinds.

【0026】ポリウレタンを使用する場合、ポリオール
とジイソシアネートの共重合体、又は、該共重合体がア
ミン化合物によって鎖延長されたものが使用される。
When a polyurethane is used, a copolymer of a polyol and a diisocyanate or a copolymer obtained by extending the chain of the copolymer with an amine compound is used.

【0027】ポリオールとしては、ポリテトラメチレン
グリコールに代表されるポリエーテルポリオール;ポリ
エチレンアジペートに代表されるポリエステルポリオー
ル;ポリカプロラクトンポリオール、ポリカプロラクト
ンのようなポリエステルグリコールとアルキレンカーボ
ネートとの反応物などで例示されるポリエステルポリカ
ーボネートポリオール;エチレンカーボネートをエチレ
ングリコール、プロピレングリコール、ブチレングリコ
ール、ネオペンチルグリコールなどの多価アルコールと
反応させ、次いでえられた反応混合物をアジピン酸、ア
ゼライン酸、セバシン酸等の有機ジカルボン酸と反応さ
せた物などが挙げられる。これらのうち強伸度、回復性
等の物性、物理的、化学的な耐久性、特に、耐水性に優
れる点からポリエーテルポリオールを用いるのが好まし
い。これらのポリオールは1種で用いても、2種以上を
混合してもさしつかえない。ポリオールは弾性糸の伸縮
性の持続性の点から、その分子量が1000〜400
0、好ましくは1500〜2300の範囲のものを用い
るのがよい。
Examples of the polyol include a polyether polyol represented by polytetramethylene glycol; a polyester polyol represented by polyethylene adipate; a polycaprolactone polyol, and a reaction product of a polyester glycol such as polycaprolactone with an alkylene carbonate. Polyester polycarbonate polyol; ethylene carbonate is reacted with a polyhydric alcohol such as ethylene glycol, propylene glycol, butylene glycol, neopentyl glycol, and the like, and the resulting reaction mixture is reacted with an organic dicarboxylic acid such as adipic acid, azelaic acid, sebacic acid, and the like. Reaction products are exemplified. Among these, it is preferable to use a polyether polyol from the viewpoint of excellent physical properties such as high elongation and recoverability, physical and chemical durability, and particularly excellent water resistance. These polyols may be used alone or in combination of two or more. The polyol has a molecular weight of 1000 to 400 from the viewpoint of the durability of elastic yarn.
0, preferably in the range of 1500-2300.

【0028】ジイソシアネートとしては、4,4’−ジ
フェニルメタンジイソシアネート、1,5−ナフタレン
ジイソシアネート、1,4−フェニレンジイソシアネー
ト、2,4−トリレンジイソシアネート、2,6−トリ
レンジイソシアネート等の芳香族ジイソシアネート、ヘ
キサメチレンジイソシアネート、1,4−シクロヘキサ
ンジイソシアネート、4,4’−ジシクロヘキシルメタ
ンジイソシアネート、イソホロンジイソシアネート等の
脂肪族ジイソシアネートがあげられる。これらのうち、
弾性糸の強度が高くなる点で、4,4’−ジフェニルメ
タンジイソシアネートを用いるのが好ましい。これらの
ジイソシアネートは1種で用いても、2種以上を混合し
てもさしつかえない。
Examples of the diisocyanate include aromatic diisocyanates such as 4,4'-diphenylmethane diisocyanate, 1,5-naphthalene diisocyanate, 1,4-phenylene diisocyanate, 2,4-tolylene diisocyanate, and 2,6-tolylene diisocyanate; Aliphatic diisocyanates such as hexamethylene diisocyanate, 1,4-cyclohexane diisocyanate, 4,4'-dicyclohexylmethane diisocyanate, and isophorone diisocyanate. Of these,
It is preferable to use 4,4'-diphenylmethane diisocyanate in that the strength of the elastic yarn is increased. These diisocyanates may be used alone or in combination of two or more.

【0029】アミン化合物としては、通常、脂肪族、脂
環族又は芳香族ジアミンが使用される。具体的には、エ
チレンジアミン、1,2−プロピレンジアミン、1,3
−プロピレンジアミン、1,4−ブチレンジアミン、
2,3−ブチレンジアミン、1,3−ブチレンジアミ
ン、ヘキサメチレンジアミン、シクロヘキサンジアミ
ン、フェニレンジアミン、トリレンジアミン、キシレン
ジアミン、3,3’−ジクロル−4,4−ビフェニルア
ミン、2,6−ジアミノピリジン、4,4’−ジアミノ
ジフェニルメタン等が挙げられる。これらのアミン化合
物は1種で用いても、2種以上を混合してもさしつかえ
ない。
As the amine compound, an aliphatic, alicyclic or aromatic diamine is usually used. Specifically, ethylenediamine, 1,2-propylenediamine, 1,3
-Propylene diamine, 1,4-butylenediamine,
2,3-butylenediamine, 1,3-butylenediamine, hexamethylenediamine, cyclohexanediamine, phenylenediamine, tolylenediamine, xylenediamine, 3,3′-dichloro-4,4-biphenylamine, 2,6-diamino Pyridine, 4,4′-diaminodiphenylmethane and the like can be mentioned. These amine compounds may be used alone or in combination of two or more.

【0030】末端封止に用いる末端封止剤としては、例
えば、ジメチルアミン、、モノエタノールアミン、n−
プロピルアミン、n−ブチルアミン、ジエチルアミン、
エタノール、プロパノール(1−プロパノール、2−プ
ロパノール)、ブタノール(1−ブタノール、2−ブタ
ノール)等が挙げられる。末端封止剤は、鎖延長後に添
加してもよいが、プレポリマー反応時(例えば、ポリオ
ールとジイソシアネートの反応時)に添加してもよく、
鎖延長時に添加してもよい。
Examples of the terminal blocking agent used for terminal blocking include dimethylamine, monoethanolamine, n-
Propylamine, n-butylamine, diethylamine,
Examples thereof include ethanol, propanol (1-propanol, 2-propanol), and butanol (1-butanol, 2-butanol). The terminal blocking agent may be added after the chain extension, but may be added at the time of the prepolymer reaction (for example, at the time of the reaction between the polyol and the diisocyanate).
You may add at the time of chain extension.

【0031】弾性糸に塗布する油剤としては、ジメチル
シリコーン、ジメチルシリコーンのメチル基の一部を他
のアルキル基、フェニル基、アミノ基等で置換した変性
シリコーン等のシリコーンオイル、鉱物油等が使用され
る。
As the oil agent to be applied to the elastic yarn, dimethyl silicone, a silicone oil such as a modified silicone in which a part of the methyl group of the dimethyl silicone is substituted with another alkyl group, a phenyl group, an amino group, or the like, a mineral oil, or the like is used. Is done.

【0032】本発明のマルチフィラメント弾性糸を衛材
製品の基材に接着するために用いる接着剤は、この種の
分野で弾性糸の衛材製品の基材ヘの接着用に使用されて
いる公知の接着剤を使用でき、特に限定はされないが、
ビニル重合体系、飽和ポリエステル系、又はポリアミド
系のホットメルト型接着剤が好ましい。
The adhesive used for bonding the multifilament elastic yarn of the present invention to the base material of a sanitary product is used in this type of field for bonding the elastic yarn to the base material of the sanitary product. Known adhesives can be used and are not particularly limited,
A vinyl polymer-based, saturated polyester-based, or polyamide-based hot melt adhesive is preferred.

【0033】[0033]

【実施例】以下、実施例と比較例により本発明を更に詳
しく説明する。
The present invention will be described below in more detail with reference to examples and comparative examples.

【0034】なお、実施例及び比較例中の弾性糸の接着
性の評価は以下の方法で行った。 (1)薄目付けの衛材用途用の東洋紡績(株)製ポリエ
ステル不織布を用意し、これを縦12cm×横3cmに
裁断する。不織布の毛羽面や伸縮性は接着性のばらつき
の原因となるので接着する面を統一して評価する。 (2)弾性糸を無緊張下で緩和されることなく厚紙上に
5本並べてセロハンテープで貼りつける。 (3)エチレン、プロピレン、ブタジエン、スチレン共
重合体からなるホットメルト接着剤を170度で溶解
し、吐出機から5g/分の吐出量となるように設定し、
弾性糸を貼り付けた厚紙を並べた弾性糸と垂直方向に、
30m/分の速度で移動させて、ホットメルト接着剤を
線状に塗布する。直後に(1)に示した不織布を、2k
g/cm2 の圧力で10秒間圧着して、接着性測定用サ
ンプルを得る。以上のサンプル作成はJTトーシ(株)
製ASM−15接着力評価機を用いて行った。 (4)上記(3)までのようにして得られたサンプルを
20℃に保った部屋で24時間保管し、不織布と弾性糸
をしっかり固定、株式会社オリエンテック製測定機U−
1573にて上下方向に引っ張り不織布と弾性糸をチャ
ート紙に記録しながら剥離する。その際、弾性糸と不織
布との剥離に要した強度をチャート紙から読み取り、そ
の値を接着力(cN)とする。 (5)接着性の経時変化の確認として、両者を接着して
から20℃に保った部屋で100時間保存し(4)と同
様な手法で剥離する。 ※紙おむつ製品における弾性糸の問題である引き込みが
殆ど起こらない接着力は150cNであり、150cN
以上を合格レベルとした。
The evaluation of the adhesiveness of the elastic yarns in the examples and comparative examples was performed by the following method. (1) A polyester nonwoven fabric manufactured by Toyobo Co., Ltd. for use as a thin material for sanitary materials is prepared and cut into a length of 12 cm and a width of 3 cm. Since the fluff surface and elasticity of the nonwoven fabric cause variations in the adhesiveness, the surface to be adhered is unified and evaluated. (2) Five elastic yarns are arranged on a cardboard without being relaxed under no tension, and attached with a cellophane tape. (3) A hot melt adhesive composed of an ethylene, propylene, butadiene, and styrene copolymer is melted at 170 ° and set so as to have a discharge rate of 5 g / min from a discharge machine.
In the vertical direction, the elastic yarn with the thick paper with the elastic yarn attached
The hot melt adhesive is applied linearly while moving at a speed of 30 m / min. Immediately after that, the nonwoven fabric shown in (1) was
The sample is pressure-bonded at a pressure of g / cm 2 for 10 seconds to obtain a sample for measuring adhesiveness. The above sample was created by JT Toshi Corporation
The test was performed using an ASM-15 adhesive strength evaluation machine manufactured by Asahi Kasei. (4) The sample obtained as described in (3) above was stored in a room kept at 20 ° C. for 24 hours, and the nonwoven fabric and the elastic yarn were firmly fixed.
At 1573, the nonwoven fabric and the elastic yarn are pulled up and down and peeled off while being recorded on the chart paper. At this time, the strength required for the separation of the elastic yarn and the nonwoven fabric is read from the chart paper, and the value is defined as the adhesive strength (cN). (5) As a check of the change over time in the adhesiveness, the two are bonded and then stored in a room kept at 20 ° C. for 100 hours, and peeled off in the same manner as in (4). * Adhesive strength at which pull-in, which is a problem of elastic yarns in disposable diaper products, hardly occurs is 150 cN.
The above was regarded as a pass level.

【0035】(実施例1)分子量が1,950のポリテ
トラメチレンエーテルグリコール975部に、4,4'
−ジフェニルメタンジイソシアネート250部を加え攪
拌し、反応させることでプレポリマーを得、次いで該プ
レポリマーをジメチルアセトアミドに溶解させた後、
1,2−プロピレンジアミンを加えて鎖延長し、ジエチ
ルアミンで末端封止をおこない、ポリウレタン溶液を得
た。
Example 1 975 parts of polytetramethylene ether glycol having a molecular weight of 1,950 was added with 4,4 ′
-250 parts of diphenylmethane diisocyanate was added, stirred and reacted to obtain a prepolymer, and then the prepolymer was dissolved in dimethylacetamide.
1,2-propylenediamine was added to extend the chain, and the terminal was blocked with diethylamine to obtain a polyurethane solution.

【0036】図2に示す、長辺長さ25cm、短辺長さ
10cmのノズルホルダー1aに、7ホールの丸型ノズ
ル1bを上下2列に4個づつ配列した紡糸口金1を用
い、該紡糸口金1をその長軸がゴデットローラ5a、5
bの長軸方向と平行となるように設置した(図1)。ポ
リウレタン溶液を紡糸口金1を通して240℃の熱風が
流れる紡糸筒2内に押し出し、得られた56本の単糸
を、紡糸筒2の下方に設置されたセラミックス製の糸集
束用ガイド3の丸孔のガイド孔3aの内面に擦らせて扁
平状に集束させながら単糸間を融着し、糸集束用ガイド
3とゴデットローラ5aの間に設置した油剤付与設備4
によって油剤を塗布しながら、ゴデットローラ5a、5
bで300m/分で捲き取って油剤が0.05重量%付
着したポリウレタン弾性糸のチーズ6Aを得た。
Using a spinneret 1 in which four 7-hole round nozzles 1b are arranged in four rows in upper and lower rows on a nozzle holder 1a having a long side length of 25 cm and a short side length of 10 cm shown in FIG. The base 1 has a long axis whose godet rollers 5a, 5a
b was set so as to be parallel to the long axis direction (FIG. 1). The polyurethane solution is extruded through a spinneret 1 into a spinning tube 2 in which hot air of 240 ° C. flows, and the obtained 56 single yarns are rounded in a round hole of a ceramic yarn collecting guide 3 installed below the spinning tube 2. The single agent yarns are fused while being bunched in a flat shape by rubbing against the inner surface of the guide hole 3a, and the oil agent applying equipment 4 installed between the yarn collecting guide 3 and the godet roller 5a.
The godet rollers 5a, 5a
The resultant was wound at 300 m / min at b to obtain a polyurethane elastic yarn cheese 6A to which an oil agent was attached at 0.05% by weight.

【0037】糸集束用ガイド3の丸孔のガイド孔は孔直
径が3mm、孔長が3mmである。紡糸口金1の最も遠
く離れた細孔間の寸法(A)、紡糸口金1から糸集束用
ガイド3までの距離(B)の関係は、B/Aが31.6
である。油剤にはジメチルシリコーンを用いた。得られ
たポリウレタン弾性糸の繊度は940デシテックスで、
糸条断面に外接させた長方形の長辺(Ll )と短辺(L
s )の長さ比(Ll /Ls )は6.4で、糸条断面に外
接させた長方形の周長(L1)と糸条断面の周長(L
2)との長さ比(L1/L2)は0.75であった。こ
のようにして得られたポリウレタン弾性糸を用いて前記
の接着性評価テストを行った。その結果を表1に示す。
The round guide hole of the yarn collecting guide 3 has a hole diameter of 3 mm and a hole length of 3 mm. The relationship between the dimension (A) between the furthest pores of the spinneret 1 and the distance (B) from the spinneret 1 to the yarn focusing guide 3 is such that B / A is 31.6.
It is. Dimethyl silicone was used as the oil agent. The fineness of the obtained polyurethane elastic yarn is 940 dtex,
The long side (L l ) and short side (L l ) of the rectangle circumscribed on the yarn section
s ) has a length ratio (L 1 / L s ) of 6.4, and the rectangular circumference (L1) circumscribed around the yarn cross section and the circumference (L 1) of the yarn cross section
The length ratio (L1 / L2) to 2) was 0.75. The adhesion evaluation test described above was performed using the polyurethane elastic yarn thus obtained. Table 1 shows the results.

【0038】(実施例2)油剤付着量を3重量%にした
以外は実施例1と同様にして、繊度が940デシテック
スで、糸条断面に外接させた長方形の長辺(Ll )と短
辺(Ls )の長さ比(Ll /Ls )が6.2、糸条断面
に外接させた長方形の周長(L1)と糸条断面の周長
(L2)との長さ比(L1/L2)が0.76のポリウ
レタン弾性糸を得た。このポリウレタン弾性糸を用いて
前記の接着性評価テストを行った。結果を下記表1に示
す。
(Example 2) In the same manner as in Example 1 except that the amount of the oil agent was changed to 3% by weight, the fineness was 940 dtex, and the long side (L l ) of the rectangle circumscribed around the yarn cross section was short. side length ratio (L s) (L l / L s) is 6.2, the peripheral length of the rectangle is circumscribing the yarn cross-section (L1) and the yarn length ratio of the circumferential length (L2) of the section A polyurethane elastic yarn having (L1 / L2) of 0.76 was obtained. Using the polyurethane elastic yarn, the above-mentioned adhesion evaluation test was performed. The results are shown in Table 1 below.

【0039】(実施例3)図3の装置を用い、上記実施
例1と同様のポリウレタン溶液を用いて弾性糸をを製造
した。紡糸口金1、紡糸筒2は図1と同じものである。
糸集束用ガイド3’はセラミックス製のU字型ガイド
(図4)であり、U字溝の幅(x)が5mm、U字溝の
長さ(y)が3mmである。紡糸口金1(図2参照)の
丸型ノズル1bの右側4個のノズルと左側4個のノズル
から押し出される単糸を、それぞれ紡糸筒2の下方に配
置した2つの仮撚り機7a、7bを通して、2本の断面
形状がほぼ円形の糸条を形成し、次いで、仮撚り機7
a、7bの15cm下で、これら2本の糸条をU字具か
らなる糸集束用ガイド3’で集束して1本の糸条を形成
し、該糸条を、糸集束用ガイド3’とゴデットローラ5
aの間に設置した油剤付与設備4によって油剤を塗布し
ながらゴデットローラ5a、5bで300m/分で捲き
取って、油剤が0.05重量%付着した繊度が940デ
シテックスのポリウレタン弾性糸のチーズ6Bを得た。
B/Aを実施例1と同じ31.6にした。得られたポリ
ウレタン弾性糸の糸条断面に外接させた長方形の長辺
(Ll )と短辺(Ls )の長さ比(Ll /Ls )は2.
2で、糸条断面に外接させた長方形の周長(L1)と糸
条断面の周長(L2)との長さ比(L1/L2)は0.
70であった。このポリウレタン弾性糸を用いて前記の
接着性評価テストを行った。結果を下記表1に示す。
Example 3 Using the apparatus shown in FIG. 3, an elastic yarn was produced using the same polyurethane solution as in Example 1 above. The spinneret 1 and the spinning cylinder 2 are the same as those in FIG.
The yarn collecting guide 3 ′ is a ceramic U-shaped guide (FIG. 4), in which the width (x) of the U-shaped groove is 5 mm and the length (y) of the U-shaped groove is 3 mm. Single yarns extruded from the four nozzles on the right side and the four nozzles on the left side of the round nozzle 1b of the spinneret 1 (see FIG. 2) are passed through two false twisting machines 7a and 7b respectively arranged below the spinning tube 2. The two cross-sections form a substantially circular yarn, and then the false twisting machine 7
15 cm below a and 7b, these two yarns are bundled by a yarn gathering guide 3 'made of a U-shaped member to form one yarn, and the yarn is formed into a yarn gathering guide 3'. And Godet Roller 5
While the oil agent is being applied by the oil agent application equipment 4 installed between the two, the godet rollers 5a and 5b wind up the wound at 300 m / min with the godet rollers 5a and 5b, and the polyurethane elastic yarn cheese 6B having a fineness of 940 dtex with the oil agent adhered to 0.05% by weight. Obtained.
B / A was set to 31.6 as in Example 1. The length ratio (L 1 / L s ) of the long side (L 1 ) and the short side (L s ) of the rectangle circumscribed on the yarn cross section of the obtained polyurethane elastic yarn is 2.
In 2, the length ratio (L1 / L2) of the circumference (L1) of the rectangle circumscribed to the yarn cross section and the circumference (L2) of the yarn cross section is 0.
70. Using the polyurethane elastic yarn, the above-mentioned adhesion evaluation test was performed. The results are shown in Table 1 below.

【0040】(比較例1)図5の装置を用いて、上記実
施例1と同様のポリウレタン溶液を用いて弾性糸を製造
した。図5において、紡糸口金1、紡糸筒2は図1と同
じものである。紡糸筒2の下方に設置した仮撚り機7
に、紡糸口金1から押し出された56本の単糸を通して
交絡、融着して糸条とし、仮撚り機7の下方に設置した
オイル付与設備で油剤を塗布しながらゴデットローラ5
a、5bで300m/分で捲き取って、油剤が0.05
重量%付着した繊度が940デシテックスのポリウレタ
ン弾性糸のチーズ6Cを得た。得られたポリウレタン弾
性糸の糸条断面に外接させた長方形の長辺(Ll )と短
辺(Ls )の長さ比(Ll /Ls )は1.1で、糸条断
面に外接させた長方形の周長(L1)と糸条断面の周長
(L2)との長さ比(L1/L2)は0.61であっ
た。このポリウレタン弾性糸を用いて前記の接着性評価
テストを行った。結果を下記表1に示す。
Comparative Example 1 Using the apparatus shown in FIG. 5, an elastic yarn was produced using the same polyurethane solution as in Example 1 above. In FIG. 5, a spinneret 1 and a spinning cylinder 2 are the same as those in FIG. False twisting machine 7 installed below spinning cylinder 2
Then, 56 single yarns extruded from the spinneret 1 are entangled and fused to form a yarn, and the godet roller 5 is applied while applying an oil agent by an oil application facility installed below the false twisting machine 7.
a, 5b, wound up at 300m / min.
A 6% polyurethane elastic yarn cheese 6C having a fineness of 940 decitex adhered by weight% was obtained. The length ratio (L 1 / L s ) of the long side (L l ) and the short side (L s ) of the rectangle circumscribed to the cross section of the obtained polyurethane elastic yarn is 1.1, and The length ratio (L1 / L2) of the circumference (L1) of the circumscribed rectangle to the circumference (L2) of the yarn cross section was 0.61. Using the polyurethane elastic yarn, the above-mentioned adhesion evaluation test was performed. The results are shown in Table 1 below.

【0041】[0041]

【表1】 [Table 1]

【0042】表1から分かるように、実施例の弾性糸は
接着剤を塗布した不織布と高い接着力で接着し、100
時間経過後もその高い接着力を維持していた。一方、比
較例は24時間後の接着力が合格レベル(150cN)
に達していたが、100時間後は接着力は150cNよ
りも低くなっていた。
As can be seen from Table 1, the elastic yarn of the embodiment adheres to the non-woven fabric coated with the adhesive with a high adhesive strength.
Even after a lapse of time, the high adhesive strength was maintained. On the other hand, in the comparative example, the adhesive strength after 24 hours was a pass level (150 cN).
, But after 100 hours, the adhesive strength was lower than 150 cN.

【0043】[0043]

【発明の効果】以上の説明により明らかなように、本発
明の衛材製品用弾性糸は、接着剤を塗布した基材への接
着力が従来よりも向上し、また、チーズからの解舒性も
良好である。よって、弾性糸の引き込みのない信頼性の
高い衛材製品を安定に製造することができる。
As is apparent from the above description, the elastic yarn for a sanitary ware of the present invention has improved adhesion to a substrate to which an adhesive has been applied as compared with conventional elastic yarns, and unwinds from cheese. The properties are also good. Therefore, it is possible to stably manufacture a highly reliable sanitary ware product without drawing in the elastic yarn.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の弾性糸を製造する装置の一例の模式図
である。
FIG. 1 is a schematic view of an example of an apparatus for producing an elastic yarn of the present invention.

【図2】図1の装置の紡糸口金の詳細図である。FIG. 2 is a detailed view of a spinneret of the apparatus of FIG.

【図3】本発明の弾性糸を製造する装置の他の例の模式
図である。
FIG. 3 is a schematic view of another example of an apparatus for producing an elastic yarn of the present invention.

【図4】図3の装置のU字型ガイドの詳細図である。FIG. 4 is a detailed view of a U-shaped guide of the apparatus of FIG. 3;

【図5】従来の弾性糸の製造装置の模式図である。FIG. 5 is a schematic view of a conventional elastic yarn manufacturing apparatus.

【符号の説明】[Explanation of symbols]

1 紡糸口金 1a ノズルホルダー 2 紡糸筒 3、3’ 糸集束用ガイド 4 油剤付与設備 5a、5b ゴデットローラ 6A、6B、6C 弾性糸チーズ 7、7a、7b 仮撚り機 DESCRIPTION OF SYMBOLS 1 Spinneret 1a Nozzle holder 2 Spinning cylinder 3, 3 'Guide for yarn bundling 4 Oil supply equipment 5a, 5b Godet roller 6A, 6B, 6C Elastic yarn cheese 7, 7a, 7b False twisting machine

Claims (5)

【特許請求の範囲】[Claims] 【請求項1】 弾性ポリマーを乾式紡糸して得られたマ
ルチフィラメント弾性糸であって、弾性糸の糸条断面に
外接させた長方形の長辺(Ll )と短辺(L s )の長さ
比(Ll /Ls )が2以上の扁平断面を有することを特
徴とする衛材製品用弾性糸。
1. A polymer obtained by dry spinning an elastic polymer.
Multifilament elastic yarns
The long side of the circumscribed rectangle (Ll) And short side (L s) Length
Ratio (Ll/ Ls) Has two or more flat sections.
Elastic yarn for sanitary products.
【請求項2】 弾性糸の糸条表面に弾性糸を構成する単
糸の断面形状による凹凸が形成されており、弾性糸の糸
条断面に外接させた長方形の周長(L1)と弾性糸の糸
条断面の周長(L2)との長さ比(L1/L2)が0.
9以下である請求項1記載の衛材製品用弾性糸。
2. The elastic yarn has surface irregularities due to the cross-sectional shape of a single yarn constituting the elastic yarn formed on the surface of the elastic yarn, and has a rectangular circumference (L1) circumscribed around the yarn cross-section of the elastic yarn and an elastic yarn. The ratio of length (L1 / L2) to the circumference (L2) of the yarn cross section is 0.
The elastic yarn for a sanitary ware product according to claim 1, wherein the number is 9 or less.
【請求項3】 弾性糸表面に油剤が塗布され、該油剤の
塗布量が糸条重量に対して0.01〜5重量%である請
求項1又は2に記載の衛材製品用弾性糸。
3. The elastic yarn for a sanitary ware product according to claim 1, wherein an oil agent is applied to the surface of the elastic yarn, and the applied amount of the oil agent is 0.01 to 5% by weight based on the weight of the yarn.
【請求項4】 繊度が155〜2490デシテックスの
範囲にある請求項1〜3のいずれかに記載の衛材製品用
弾性糸。
4. The elastic yarn for a sanitary ware product according to claim 1, wherein the fineness is in a range of 155 to 2490 dtex.
【請求項5】 弾性ポリマーがポリウレタンである請求
項1〜4のいずれかに記載の衛材製品用弾性糸。
5. The elastic yarn for a sanitary ware product according to claim 1, wherein the elastic polymer is polyurethane.
JP2000003952A 1999-06-21 2000-01-12 Elastic yarn for hygiene products Expired - Fee Related JP4045711B2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP2000003952A JP4045711B2 (en) 1999-06-21 2000-01-12 Elastic yarn for hygiene products
CNB001080695A CN1139680C (en) 1999-06-21 2000-06-12 Elastic filament used for hygienic articles
KR1020000033672A KR100592216B1 (en) 1999-06-21 2000-06-19 Elastomeric yarn for sanitary material product
TW089112086A TW581834B (en) 1999-06-21 2000-06-20 Elastic yarn for hygienic article

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP11-174718 1999-06-21
JP17471899 1999-06-21
JP2000003952A JP4045711B2 (en) 1999-06-21 2000-01-12 Elastic yarn for hygiene products

Publications (2)

Publication Number Publication Date
JP2001064825A true JP2001064825A (en) 2001-03-13
JP4045711B2 JP4045711B2 (en) 2008-02-13

Family

ID=26496225

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2000003952A Expired - Fee Related JP4045711B2 (en) 1999-06-21 2000-01-12 Elastic yarn for hygiene products

Country Status (4)

Country Link
JP (1) JP4045711B2 (en)
KR (1) KR100592216B1 (en)
CN (1) CN1139680C (en)
TW (1) TW581834B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017200900A1 (en) * 2016-05-20 2017-11-23 Invista North America S.A R.L. Non-round solution spun spandex filaments and methods and devices for production thereof
WO2020153375A1 (en) * 2019-01-22 2020-07-30 旭化成株式会社 Polyurethane elastic fiber and fabric containing same
TWI705163B (en) * 2019-06-21 2020-09-21 勤倫有限公司 Cutting method of elastic film material and elastic thread

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8168034B2 (en) * 2008-09-30 2012-05-01 Uni-Charm Corporation Manufacturing method of absorbent article
CN103194810B (en) * 2013-04-07 2016-01-06 浙江四海氨纶纤维有限公司 A kind of spandex winding process for the speed-raising of Nisshinbo dry spinning fine denier filament
CN111441120A (en) * 2020-04-20 2020-07-24 杭州舒尔姿氨纶有限公司 Production method and application of heavy denier spandex yarn containing parallel multi-strand yarn
CN111962190B (en) * 2020-08-18 2021-12-28 华峰化学股份有限公司 Polyurethane elastic fiber with anti-skid elastic performance and preparation method thereof
CN111973346A (en) * 2020-09-03 2020-11-24 贵州卡布婴童用品有限责任公司 Pressure-reducing waistline of paper diaper and manufacturing process thereof

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11151782A (en) * 1997-09-18 1999-06-08 Tonen Kagaku Kk Stretchable composite film, elastic string, and elastic yarn
KR19990066300A (en) * 1998-01-23 1999-08-16 한형수 Manufacturing method of elastic yarn for diaper

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017200900A1 (en) * 2016-05-20 2017-11-23 Invista North America S.A R.L. Non-round solution spun spandex filaments and methods and devices for production thereof
KR20190020656A (en) * 2016-05-20 2019-03-04 에이앤에이티 유케이 리미티드 Non-circular solution radial spandex filament and its production method and apparatus
JP2019516877A (en) * 2016-05-20 2019-06-20 エイアンドエイティー ユーケー リミテッド Non-circular solution spun spandex filaments and methods and apparatus for making the same
JP2022031796A (en) * 2016-05-20 2022-02-22 ザ ライクラ カンパニー ユーケー リミテッド Non-round solution-spun spandex filaments and methods and devices for producing the same
KR102445642B1 (en) 2016-05-20 2022-09-21 더 라이크라 컴퍼니 유케이 리미티드 Non-circular solution spun spandex filament and method and apparatus for production thereof
JP7216177B2 (en) 2016-05-20 2023-01-31 ザ ライクラ カンパニー ユーケー リミテッド Non-circular solution-spun spandex filaments and method and apparatus for making same
WO2020153375A1 (en) * 2019-01-22 2020-07-30 旭化成株式会社 Polyurethane elastic fiber and fabric containing same
TWI705163B (en) * 2019-06-21 2020-09-21 勤倫有限公司 Cutting method of elastic film material and elastic thread

Also Published As

Publication number Publication date
TW581834B (en) 2004-04-01
KR100592216B1 (en) 2006-06-23
JP4045711B2 (en) 2008-02-13
KR20010049574A (en) 2001-06-15
CN1139680C (en) 2004-02-25
CN1278025A (en) 2000-12-27

Similar Documents

Publication Publication Date Title
JP6751284B2 (en) Stretchable composite material with good feel
JP5272229B2 (en) Split type composite fiber, aggregate thereof, and fiber molded body using the split type composite fiber
JP2001064825A (en) Elastic yarn for sanitary product
JP2016016536A (en) Elastic material having good fittability
US20190193032A1 (en) Spunbonded nonwoven fabric and production method therefor
JP2002129428A (en) Elastic yarn for sanitary product
JP2005320636A (en) Method for producing stretchable nonwoven fabric for disposable paper diaper
JP2002348737A (en) Hot melt adhesive composite fiber and fibrous formed material by using the same
TWI794412B (en) Nonwoven or fabric elasticized with a multiplicity of fiber strands in a close proximity, manufacturing method thereof, and fiber article of manufacture
JP2004149971A (en) Hot melt-type adhesive fiber and method for producing the same
KR100591582B1 (en) Elastomeric fiber package in which physical properties are minimally differentiated among layers and between transfer tail and spool and method for preparing the same
JP3016837B2 (en) Raw yarns useful for long and short composite yarns
KR100455624B1 (en) A package of an elastic yarn with excellent adhesive strength
JPH09279453A (en) Unidirection-stretchable nonwoven cloth and its production
TW201839193A (en) Method for producing uncrimped short fibers and wet-laid nonwoven fabric comprising obtained uncrimped short fibers
JP3921735B2 (en) Method for supplying elastic yarn for disposable diapers
JPH0978435A (en) Composite nonwoven fabric
JP4468025B2 (en) Split composite fiber and polyamide fiber structure
JP3016838B2 (en) Raw yarns useful for long and short composite yarns
JPH10216433A (en) Nonwoven fabric for take-up type air filter
JP2000328348A (en) Splittable type conjugate fiber and formed fiber product using the same
JP2968441B2 (en) Manufacturing method of polyetherester elastic yarn
JP2001146636A (en) Multifilament elastic yarn and method for producing the same
JP2001164435A (en) Covered elastic yarn
JPH09301632A (en) Elastic yarn wound cheese

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20050422

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20070517

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20070522

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20070713

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20071030

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20071112

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20101130

Year of fee payment: 3

R151 Written notification of patent or utility model registration

Ref document number: 4045711

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R151

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20111130

Year of fee payment: 4

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20111130

Year of fee payment: 4

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20121130

Year of fee payment: 5

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20121130

Year of fee payment: 5

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20131130

Year of fee payment: 6

LAPS Cancellation because of no payment of annual fees