TW536614B - Refrigerator - Google Patents

Refrigerator Download PDF

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Publication number
TW536614B
TW536614B TW91104618A TW91104618A TW536614B TW 536614 B TW536614 B TW 536614B TW 91104618 A TW91104618 A TW 91104618A TW 91104618 A TW91104618 A TW 91104618A TW 536614 B TW536614 B TW 536614B
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TW
Taiwan
Prior art keywords
refrigerator
box
heat
vacuum
plate
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TW91104618A
Other languages
Chinese (zh)
Inventor
Chie Hirai
Kenji Takaichi
Yasuaki Tanimoto
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Matsushita Refrigeration
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Publication of TW536614B publication Critical patent/TW536614B/en

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  • Refrigerator Housings (AREA)

Abstract

A vacuum heat-insulation board made of inorganic fiber is employed as an incombustible heat-insulator to increase the incombustibility of an insulating material used in a refrigerating body. Further, by improving the incombustibility of an insulating material, it becomes possible to use combustible refrigerant in a refrigerator and yet to keep it with assured safety and energy saving at the same time.

Description

536614 A7536614 A7

536614 A7 -----------B7 五、發明説明(2 ) 一 ~ ~~- 乃益形重要:而習知之絕熱材料則無法對應該等課題。 本發明係用以解決前述習知之課題者,其目的在於實 見種省月b源性向之冰箱,該冰箱係於冰箱箱體令使用由 耐火性板狀無機纖維成形體構成之耐火性真空絕熱體,以 防因外部起火而延燒至冰箱箱體,且雖使用可燃性冷媒仍 可達安全之效用者。 發明之揭示 為解決前述課題,本發明之冰箱乃於絕熱箱體内設有 -真空絕熱體及一發泡樹脂絕熱體,該真空絕熱體係藉氣 體阻擋性薄膜被覆板狀無機纖維成形體並使内部減壓者。 藉由在絕熱箱體中配置一由前述板狀無機纖維成形體構成 之耐火性真空絕熱體,則耐火性較僅使用發泡樹脂體時更 為改善,結果可使絕熱箱體之耐火性提高。因此,可達到 促進絕熱箱體對外部延燒之耐火度之效果,並可得較習知 之冰相安全性高之冰箱。此外,藉由配置真空絕熱體,則 可減少絕熱箱體所使用之發泡樹脂體之量,又因絕熱性能 改善而可使絕熱箱體薄壁化。結果可再減少所用之發泡樹 脂體之總量。因此,隨使用之發泡樹脂體之量減少,萬一 延燒至絕熱材料時卻因有機氣體之產生量變少,而可得一 安全性更高之冰箱。 又,由於使用板狀無機纖維成形體,故可得一平面性 佳、輕量且生產性佳之冰箱箱體。 又,本發明之冰箱係於由内箱與外箱形成之空間中具 有絕熱材料,且於空間之外箱側使用由板狀無機纖維成形 本紙張尺度適用中國國家標準(CNS) A4規格(210X297公釐) C請先閲讀背面之注意事項再填寫本頁) %, .、一^1丨 -線丨 -5- 536614 A7 ----—_ —_ B7_ 五、發明説明-- _冓成之真空絕熱體者。此時,藉由在冰箱外側面配置耐 火丨生之真空絕熱體,則縱使由冰箱外部延燒而來,真空絕 熱體亦難以燃燒,因此難以使發泡樹脂體著火,且更為提 升箱體之耐火性。 又,由於門扇體亦使用由耐火性板狀無機纖維成形體 構成之絕熱材料,故可提高冰箱門扇體之絕熱部對冰箱外 部之延燒之耐火性。 又本發明之冰箱係具有一將冰箱内獨立分隔之分隔 孝目體並於分隔箱體中配置有由板狀無機纖維成形體構成 之真空絕熱體。因此,縱使於因外部之延燒而致使冰箱内 獨立之冷凍室或冷藏室任一方燃燒時,卻因分隔箱體難以 燃燒而可防止延燒蔓延至另一室,進而可得一安全性高之 冰箱。 又,本發明之冰箱係於用以構成冰箱箱體之外箱與内 相間所形成之密閉空間中配置板狀無機纖維成形體並使空 間内邛減壓者,且密閉空間内不具發泡樹脂體。因此,耐 火性可大幅提高,且因延燒時不會由發泡樹脂體產生有機 氣體而可使安全性躍升,又因可將絕熱箱體本身作為真空 絶熱箱體,故絕熱性能亦大幅提昇。 又,前述板狀無機纖維成形體係至少含有二氧化矽。 由於使用含二氧化石夕之無機纖維,因此可製得一财熱性佳 且價廉之真空絕熱體。 又,前述板狀無機纖維成形體係至少含有氧化鋁。由 於使用含氧化銘,或氧化銘含有率提高之無機纖維,因此 本紙張尺度適用中國國家標準(CNS) A4規格(210X297公釐) -6- 五、發明説明(4 ) 耐熱性更為提升,且以此構成之真空絕熱體之财火性亦更 加提高。 圖示之簡單說明 第1圖係本發明之實施型態丨之冰箱截面圖。 第2圖係本發明之實施型態」之真空絕熱體之截面圖。 第3圖係本發明之實施型態2之冰箱截面圖。 用以實施發明之最佳形態 以下,針對本發明之實施型態並利用圖示加以說明。 (實施型態1 ) 第1圖係本發明之實施型態1之冰箱截面圖。冰箱本體! T由絕熱箱體2、分隔箱體3、門扇體4,及用以構成冷陳猶 %之壓縮機5、凝結器6、毛細管7及蒸發器8所構成者。前 述絕熱箱體2與門扇體4,係由一將鐵板等加壓成形之外箱9 與一將ABS樹脂等成形之内箱1〇所構成者。 由前述絕熱箱體2與門扇體4形成之空間即冰箱之箱 内,並以分隔箱體3區隔為上下空間,上部係形成冷藏室 11,而下部則形成冷凍室12。 抑將前述壓縮機5、凝結器6、毛細管7、蒸發器8依序呈 f片、連接而^成一冷;東循環。本實施型態中冷束循環内 係封入有HC冷媒之異丁烷作為冷媒。前述蒸發器8係設於 冷凍至12中並構造成藉由擋板13將冷風送入冷藏室u。 又,亦可將該蒸發器8設於冷藏室11及冷凍室12二處,並將 其等呈直列或並列連接而形成冷凍循環。 絕熱箱之空間14與門扇體4之空間15中,係配置有真空 536614536614 A7 ----------- B7 V. Description of the Invention (2) A ~~~-It is important to be in shape: the conventional thermal insulation materials cannot cope with these problems. The present invention is to solve the above-mentioned conventional problems. The purpose of the present invention is to find a kind of month-saving refrigerator. The refrigerator is installed in the refrigerator box and uses a refractory vacuum insulation made of a refractory plate-shaped inorganic fiber formed body. To prevent it from being burned to the refrigerator cabinet due to external fire, and can still be used safely even though flammable refrigerant is used. DISCLOSURE OF THE INVENTION In order to solve the foregoing problem, the refrigerator of the present invention is provided with a vacuum insulation body and a foamed resin insulation body in a heat insulation box. The vacuum heat insulation system covers a plate-shaped inorganic fiber formed body with a gas barrier film and makes Internal decompression. By arranging a refractory vacuum insulation body composed of the aforementioned plate-shaped inorganic fiber formed body in the heat insulation box, the fire resistance is more improved than when only a foamed resin body is used, and as a result, the fire resistance of the heat insulation box can be improved. . Therefore, it can achieve the effect of promoting the fire resistance of the thermal insulation box to the external fire, and can obtain a refrigerator with a higher safety than the conventional ice phase. In addition, by arranging a vacuum insulation body, the amount of foamed resin body used in the heat insulation box can be reduced, and the heat insulation box can be thinned due to the improved heat insulation performance. As a result, the total amount of the foamed resin to be used can be further reduced. Therefore, as the amount of the foamed resin body used decreases, in the event of post-firing to the heat-insulating material, the amount of organic gas generated is reduced, and a refrigerator with higher safety can be obtained. In addition, since a plate-shaped inorganic fiber formed body is used, a refrigerator box having excellent flatness, light weight, and productivity can be obtained. In addition, the refrigerator of the present invention has a thermal insulation material in a space formed by an inner box and an outer box, and is formed by a plate-shaped inorganic fiber on the side of the box outside the space. (Mm) C Please read the notes on the back before filling this page)%,., A ^ 1 丨 -line 丨 -5- 536614 A7 ----—_ —_ B7_ V. Description of the invention-_ 冓 成Vacuum insulation body. At this time, by arranging a refractory vacuum heat insulator on the outer side of the refrigerator, even if it is burned from the outside of the refrigerator, the vacuum heat insulator is also difficult to burn, so it is difficult to ignite the foamed resin body, and to further enhance the box body. Fire resistance. In addition, since the door body also uses a heat-insulating material composed of a refractory plate-shaped inorganic fiber formed body, the fire resistance of the heat-insulating portion of the refrigerator door body to the external firing of the refrigerator can be improved. Moreover, the refrigerator of the present invention has a partition body that separates the interior of the refrigerator independently, and a vacuum insulation body composed of a plate-shaped inorganic fiber formed body is arranged in the partition box. Therefore, even if any one of the freezer compartment or the refrigerating compartment in the refrigerator is burned due to external burning, it is difficult to burn the partition box to prevent the burning from spreading to the other room, and a highly safe refrigerator can be obtained. . Moreover, the refrigerator of the present invention is a person who arranges a plate-shaped inorganic fiber formed body in a closed space formed between the outer box and the inner phase of the refrigerator box and decompresses the space, and the closed space does not have foaming resin. body. Therefore, the fire resistance can be greatly improved, and the safety can be jumped because no organic gas is generated by the foamed resin body during the post-firing, and the heat insulation performance can be greatly improved because the heat insulation box itself can be used as a vacuum heat insulation box. . The plate-like inorganic fiber forming system contains at least silicon dioxide. Due to the use of inorganic fibers containing sulphur dioxide, a vacuum thermal insulator with good thermal properties and low cost can be obtained. The plate-like inorganic fiber forming system contains at least alumina. Due to the use of inorganic fibers with an oxide inscription or an increase in the content of the oxide inscription, this paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm)-6-5. Description of the invention (4) The heat resistance is further improved, Moreover, the wealth of the vacuum insulation body constructed in this way is further improved. Brief Description of the Drawings Fig. 1 is a sectional view of a refrigerator according to an embodiment of the present invention. Fig. 2 is a cross-sectional view of the vacuum heat insulator according to the embodiment of the present invention. Fig. 3 is a sectional view of a refrigerator according to a second embodiment of the present invention. BEST MODE FOR IMPLEMENTING THE INVENTION Hereinafter, an embodiment of the present invention will be described with reference to the drawings. (Embodiment 1) FIG. 1 is a sectional view of a refrigerator according to Embodiment 1 of the present invention. Refrigerator body! T is composed of an adiabatic box 2, a partition box 3, a door body 4, and a compressor 5, a condenser 6, a capillary tube 7, and an evaporator 8 which are used to constitute a cold old battery. The aforementioned heat-insulating box 2 and door body 4 are composed of an outer box 9 formed by press-molding an iron plate or the like, and an inner box 10 formed of an ABS resin or the like. The space formed by the aforesaid heat-insulating box 2 and door body 4 is the inside of the refrigerator, and is divided by the partition box 3 as the upper and lower spaces. The upper part forms the refrigerating compartment 11 and the lower part forms the freezing compartment 12. Therefore, the compressor 5, the condenser 6, the capillary 7, and the evaporator 8 are sequentially formed into f pieces and connected to form a cold; eastern circulation. Isobutane with HC refrigerant is enclosed in the intermediate cooling beam cycle of this embodiment as the refrigerant. The aforementioned evaporator 8 is provided in the freezing to 12 and is configured to send cold air into the refrigerating compartment u through the baffle 13. Further, the evaporator 8 may be provided at two places of the refrigerating compartment 11 and the freezing compartment 12 and connected in parallel or in parallel to form a refrigeration cycle. The space 14 of the heat insulation box and the space 15 of the door body 4 are provided with a vacuum 536614.

絕熱體與發泡樹脂絕熱體17。本實施型態中之發泡樹脂絕 熱體17係硬質胺甲酸乙酯泡膠,並以環戊烷作為發泡劑而 使之毛/包。此外’分隔箱體3中係配置有真空絕熱體16。 /本實施型態中之真空絕熱體16,係用板狀無機纖維成 /體=為“材並以氣體阻擋性薄膜被覆該芯材,且將内 4減壓而形成真空絕熱體16。該板狀無機纖維成形體之構 成材料亚無特別限定,而有氧化域維、m維、二氧 化石夕纖維、氧化錯纖維、玻璃織、岩棉、硫_纖維、碳 化矽纖維、鈦酸鉀纖維、硫酸鎂纖維等無機纖維,亦可線 定為單一素材。又,無機纖維之纖維直徑,若以絕熱性能 之觀點而言,宜於10μηι以下,更理想者於5μηι以下,而以 在3μηι以下特別理想。 又,雖可僅為纖維質,但為形成聚集體亦可使用無機 黏結劑或有機黏結劑。前述無機黏結劑並無特別限制,而 可使用膠體一氧化矽、水玻璃、低溶點玻璃、氧化鋁溶膠、 矽樹脂等公知之材料。 又,前述有機黏結齊j並無特別限制,而可使用紛系樹 脂、環氧系樹脂、脲系樹脂等熱固型樹脂;或,甲基丙婦 酸酯、乙基丙烯酸酯、丁基丙烯酸酯、氰基丙烯酸g旨、甲 基丙烯酸甲酯、甲基丙烯酸乙酯、甲基丙烯酸丁酯、氛基 甲基丙烯酸酯等丙稀酸系樹脂;聚對苯二甲酸乙二酉旨、I 對苯二甲酸丁二酯、聚對萘二甲酸乙二酯等聚酯;聚内婦、 聚乙烯、聚苯乙烯、聚乙酸乙烯、聚乙烯醇、聚丙稀跨、 或,聚醯胺系樹脂等熱塑性樹脂等公知之材料。 本紙張尺度適用中國國家標準(CNS) A4規格(210X297公釐) (請先閲讀背面之注意事項再填寫本頁) •、^τ— 【線----- -8- 五、發明説明(6 ) 有機黏尨劑之含量,若由耐火性,或無機纖維 經:段時間後之產生氣體,或密度等觀點而言,則宜於1〇 %以下’更理想者於5%以下。該等黏結劑亦可使用2種或 更夕種之此合物’進而,可將一般所用之助塑劑、熱穩定 d光女疋^、填充材料等混合後使用。以上舉例者可混 合使用,或以水或公知之有機溶媒稀釋後使用。 前述無機纖維可藉由塗布t述黏結劑或其稀釋液,或 將㈣纖維浸潰於前述黏結劑或其稀釋液中,而使黏結劑 附著/、上其後,若黏結劑為稀釋液則於依需要將其溶媒 乾燥後’藉壓縮或加熱壓縮而形成板狀無機纖維成形體。 又藉由々無機纖維分散於前述黏結劑之稀釋液中,再加 以抄製亦可製得成形體。 σ 利用如上者製作之板狀無機纖維成形體之密度雖無特 別限制3,但由可維持成形體之形狀之觀點言之則宜'於 80kg/m以上,而由絕熱性能之觀點言之則宜於4时0化3 以下特別疋在15〇kg/m3以上且在3〇〇kg/m3以下更為理想。 第2圖所示者係真空絕熱體16之截面圖。板狀無機纖維 成形體1 8係填充於作為外被材料之氣體阻擋性薄膜丨9中, 且内部減壓至30Pa左右。 則述氣體阻擔性薄膜係包覆芯材以於内部設置氣密部 者於材料組成上並無特別限制,舉例言之,有將最外層 為I對笨二甲酸乙二酯,中間層為鋁(以下稱A1)箔,最 内層為高密度聚乙烯樹脂所構成之塑膠積層膜,與最外層 為聚對苯二甲酸乙二酯樹脂、中間層為具有八丨蒸鍍層之乙 五 "發明説明( 埽-乙烯醇共聚物樹脂(商品义ρνΛ τ VAL ’KURARAY(株)製), 最内層為高密度聚乙烯樹脂 者等。 構成之塑膠積層膜作成袋狀 外被材料之構造上之转料 « L 隻^ ^ 之特徵,最外層係用以對應衝擊 寺’中間層係用以確保翕辦阳讲 雉俅巩體阻擋性,而最内層係用以藉熱 炫·合而密閉。因此,口两Afc、去t A達到該等目的,則全數公知材Thermal insulator and foamed resin insulator 17. The foamed resin insulator 17 in this embodiment is a hard urethane foam, and cyclopentane is used as a foaming agent to make the wool / bag. A vacuum insulator 16 is disposed in the 'dividing box 3'. / The vacuum heat insulator 16 in this embodiment is made of a plate-shaped inorganic fiber, and the core material is covered with a gas barrier film, and the inner 4 is decompressed to form the vacuum heat insulator 16. The The constituent materials of the plate-shaped inorganic fiber formed body are not particularly limited, and there are oxidation domain dimension, m dimension, stone dioxide fiber, oxidized fiber, glass weave, rock wool, sulfur fiber, silicon carbide fiber, and potassium titanate. Inorganic fibers such as fibers and magnesium sulfate fibers can also be made into a single material. In addition, the fiber diameter of inorganic fibers is preferably 10 μηι or less, more preferably 5 μηι or less, and 3 μηι in terms of thermal insulation performance. The following is particularly desirable. Although it may be only fibrous, an inorganic binder or an organic binder may be used to form an aggregate. The aforementioned inorganic binder is not particularly limited, and colloidal silica, water glass, low Known materials such as melting point glass, alumina sol, silicone resin, etc. In addition, the aforementioned organic bonding j is not particularly limited, and thermosetting resins such as various resins, epoxy resins, and urea resins can be used; , Methacrylic acid ester, ethyl acrylate, butyl acrylate, cyanoacrylic acid, methyl methacrylate, ethyl methacrylate, butyl methacrylate, etc. Dilute acid resin; polyesters such as polyethylene terephthalate, butylene terephthalate, polyethylene terephthalate, etc .; poly housewives, polyethylene, polystyrene, polyvinyl acetate , Polyvinyl alcohol, polypropylene span, or thermoplastic resins such as polyamide resins, etc. This paper size applies to China National Standard (CNS) A4 specification (210X297 mm) (Please read the precautions on the back before reading) (Fill in this page) •, ^ τ— [Line ----- -8- V. Description of the invention (6) The content of organic viscose, if it is caused by fire resistance, or inorganic fiber: after a period of time, From the viewpoints of density or density, it is preferably less than 10%, and more preferably less than 5%. These adhesives can also use two or more kinds of this compound. Furthermore, the commonly used plasticizers can be used. Agent, heat-stable d-light urns, fillers, etc. are used after mixing. For the above examples, you can mix It can be used together or diluted with water or a known organic solvent. The inorganic fibers can be coated by coating the adhesive or its diluent, or immersed in the aforementioned adhesive or its diluent to make the fibers stick. After the adhesive is attached, if the adhesive is a diluent, the solvent is dried as needed to form a plate-shaped inorganic fiber formed body by compression or heating. The inorganic fiber is dispersed in the aforementioned adhesive by rhenium inorganic fibers. In the diluent, it can be prepared by further copying. Σ Although the density of the plate-shaped inorganic fiber formed body produced as described above is not particularly limited3, it is preferable from the viewpoint of maintaining the shape of the formed body ' It is more than 80 kg / m, and from the viewpoint of thermal insulation performance, it is preferable to be less than or equal to 4:00, and more preferably more than 150 kg / m3 and less than 300 kg / m3. The one shown in FIG. 2 is a cross-sectional view of the vacuum heat insulator 16. The plate-shaped inorganic fiber molded body 18 is filled in a gas barrier film 9 as an outer cover material, and the internal pressure is reduced to about 30 Pa. There is no particular limitation on the material composition of the gas-barrier film that covers the core material to provide an air-tight part inside. For example, the outer layer is I-p-ethylene dibenzoate, and the middle layer is Aluminum (hereinafter referred to as A1) foil, the innermost layer is a plastic laminated film composed of a high-density polyethylene resin, the outermost layer is a polyethylene terephthalate resin, and the middle layer is ethylene glycol with an eighth vapor deposition layer. &Quot; Description of the invention (埽 -vinyl alcohol copolymer resin (commercially produced ρνΛ τ VAL 'KURARAY Co., Ltd.), the innermost layer is high-density polyethylene resin, etc. The structure of the plastic laminated film is made into a bag-like outer cover material. The characteristics of the transfer material «L only ^ ^, the outermost layer is used to correspond to the impact temple 'the middle layer is used to ensure the sclera barrier of the Yangbanyangyang, and the innermost layer is used to close by heat and close. Therefore, if both Afc and t A are used to achieve these goals, then all known materials

枓皆可使用,進而在改盖之古、土 L 。 法上,可藉於最外層附以耐 4脂等而使耐刺傷性提升,或於中間層設置2層具有A1 瘵鍍層之乙烯-乙烯醇共聚物樹脂。 又,熱溶合之最内層,若由密封性或化學反應性而古 ,宜為高密度聚乙烯樹脂’但除此之外,亦可使用聚丙稀 树脂或聚丙烯腈樹脂等。 直 又,外被材料之袋形狀可為四方密封袋、三角袋 筒形袋、L字袋等,並無特別之限制。 又,以芯材之脫水、脫氣為目的時,並可於插入外被 材料前施以加熱處理。此時之加熱溫度,若以可行最低限 脫水而言,則宜於100°C以上。 户又,於進而使真空絕熱體16之可靠性提高時,亦可使 用氣體吸附劑或水分吸附劑等吸氣物質。 又,該吸附機構可為物理吸附、化學吸附、及吸留、 用 收附等中之任―項’但以可作為非蒸發性吸氣劑而行作 之物質為佳。 具體而言,則為合成沸石、活性碳、活性氧化鋁、 氧化矽凝膠、碳鈉鋁石、水滑石等物理吸附劑。 536614 A7 ---------— 67__—___ •五、發明説明(8 ) ^~ - 前述化學吸附劑係可利用鹼金屬或鹼土類金屬之氧化 物,或鹼金屬或鹼土類金屬之氫氧化物等,特別是,以氧 化鐘、氮氧化裡、氧化詞、A氧化舞、氧化Μ、氯氧化鎖、 氧化鋇、氫氧化鋇可行有效之作用。 又,硫酸鈣、硫酸鎂、硫酸鈉、碳酸鈉、碳酸鉀、氯 化鈣、碳酸鋰、不飽和脂肪酸、鐵化合物等亦可有效作用。 此外,單獨運用鋇、鎮、約、錄、鈦、錯、叙等物質或將 其合金化後之吸氣物質則更具效果。進而,由於前述吸氣 物質至少吸附去除氮、氧、水分、二氧化碳,因此將各種 混合後運用可更具效果。 如此一來,以板狀無機纖維成形體作為芯材而作成之 真工絕熱體16之用以顯示絕熱性能之導熱率,於3之減 壓條件下係0.0043 W/mK。另,以開孔胺甲酸乙酯或粉末之 二氧化矽作為芯材而作成之真空絕熱體之導熱率於3 〇Pa時 則為0.0065W/mK〜0.0075W/mK。因此,本實施型態之真 空絕熱體16與習知之真空絕熱體相較,則具有約15倍以上 之絕熱性能。如此,因絕熱性能非常高,則薄的真空絕熱 體16亦可確保完全之絕熱性能,因此可擴增冰箱本體丨之箱 内容積。 又’由於真空絕熱體丨6中使用有板狀無機纖維成形體 之芯材,則可製得薄且平面性佳之真空絕熱體丨6,因此可 使絕熱相體2之絕熱壁形成薄而平面性佳之狀態。 又,由於切斷、彎折、凹陷·突起部、貫通孔之形成 等加工性亦非常優異,故可容易製成以冰箱本體1之形狀為 本紙張尺度適用中國國家標準(CNS) A4規格(210X297公釐)枓 can be used, and then in the ancient, soil L. In law, stab resistance can be improved by attaching the outermost layer with 4 grease resistance, etc., or two layers of ethylene-vinyl alcohol copolymer resin with A1 瘵 coating on the middle layer. The innermost layer of heat fusion is preferably a high-density polyethylene resin if it has a tightness or chemical reactivity, but other than that, a polypropylene resin or a polyacrylonitrile resin may be used. Straight, the shape of the outer cover material can be a square sealed bag, a triangular bag, a cylindrical bag, an L-shaped bag, etc., and there are no particular restrictions. For the purpose of dehydration and deaeration of the core material, heat treatment may be performed before inserting the outer cover material. At this time, the heating temperature should be above 100 ° C if the dewatering is the lowest possible. When the reliability of the vacuum heat insulator 16 is further improved, a getter such as a gas adsorbent or a moisture adsorbent may be used. The adsorption mechanism may be any of "physical adsorption", "chemical adsorption", "storage", "acquisition", and the like, but is preferably a substance that can function as a non-evaporable getter. Specifically, it is a physical adsorbent such as synthetic zeolite, activated carbon, activated alumina, silica gel, sodalite, and hydrotalcite. 536614 A7 ---------— 67 __—___ • V. Description of the Invention (8) ^ ~-The aforementioned chemical adsorbent can use oxides of alkali metals or alkaline earth metals, or alkali metals or alkaline earth metals The hydroxides, etc., in particular, can be used as bell oxides, nitrous oxides, oxidized words, A oxide dances, M oxides, chlorine oxide locks, barium oxides, and barium hydroxides. In addition, calcium sulfate, magnesium sulfate, sodium sulfate, sodium carbonate, potassium carbonate, calcium chloride, lithium carbonate, unsaturated fatty acids, iron compounds, and the like can also effectively work. In addition, it is more effective to use barium, town, contract, record, titanium, titanium, and other materials or alloyed getter materials. Furthermore, since the aforementioned getter substance adsorbs and removes at least nitrogen, oxygen, moisture, and carbon dioxide, it is more effective to mix and use various kinds. In this way, the thermal conductivity of the real thermal insulator 16 produced by using the plate-shaped inorganic fiber formed body as a core material to display the thermal insulation performance is 0.0043 W / mK under a reduced pressure condition of 3. In addition, the thermal conductivity of a vacuum heat insulator made of open-cell urethane or powdered silicon dioxide as a core material is 0.0065 W / mK to 0.0075 W / mK at 30 Pa. Therefore, the vacuum thermal insulator 16 of this embodiment has a thermal insulation performance of about 15 times or more compared with the conventional vacuum thermal insulator. In this way, since the thermal insulation performance is very high, the thin vacuum thermal insulation body 16 can also ensure complete thermal insulation performance, so that the inner volume of the refrigerator body 丨 can be enlarged. Also, since the core material having a plate-shaped inorganic fiber formed body is used in the vacuum insulation body 6, a vacuum insulation body 6 having a thin and excellent planarity can be obtained, so that the heat insulation wall 2 can be formed into a thin and flat surface. Good sex. In addition, cutting, bending, dents, protrusions, and formation of through-holes are also very good in processability, so it can be easily manufactured with the shape of the refrigerator body 1 as the paper size and applicable Chinese National Standard (CNS) A4 specifications 210X297 mm)

訂I 1------- (請先閲讀背面之注意事項再填寫本頁) -11- 五、發明説明(9 ) 可將1片真空絕熱體16 模型之真空絕熱體16。舉例言之, 沿冰箱本體i之絕熱箱體2之三侧面彎折而使用,且藉由作 成該形狀而使冰箱箱體之邊緣部亦得以真空絕熱體被覆, 故進而可製得-耐火性佳,且絕熱性優異之冰箱之絕熱箱 體2 〇 又,絕熱箱體2中亦可將較其他部位更需薄壁化之部位 以1片板材形成’而其餘部分則藉由層疊2片板材等而簡易 製成所需形狀。且’由於真空絕熱體16之芯材係呈板狀, 故於積層成必要厚度時亦可廣泛對應任何需求。 又,於真空絕熱體16上配置冰箱本體丨所需之管路或導 線等時,可於板狀無機纖維成形體上順管路等之形狀設一 凹槽再製作真空絕熱體16,或於製作真空絕熱_後設置 凹槽,並於該凹槽内配置管路等。此外,相對於沿箱體内 面之管路等,亦可直接強壓真空絕熱體而形成凹槽,並依 樣於箱體内面配置真空絕熱體16。如此一來,由於使用纖 維聚集體故易於成形,並可使凹槽之設置容易。 又,由於使用無機纖維,故於以冰箱本體丨之外箱9與 内相ίο所形成之空間14内發泡填充樹脂發泡體17時因溫度 上昇引致之真空絕熱體16之性能劣化,可較使用有機物之 芯材之真空絕熱材料得以受到控制。此時,使用無機粉末 之真空絕熱體,需於將無機粉末插入外被材料前先於内袋 中填充粉末。無機粉末若未預先填充於内袋中,則於使外 被材料内進行真空排氣時粉末將飛散。將粉末填充於内袋 而製作真空絕熱體時,需於進行真空絕熱體之形狀加工時 本紙張尺度適财關緖準(_Α4規格⑽ 536614 發明説明 先調整㈣之形狀。於使用才反狀之芯材時,形狀加工僅需 將板狀芯材切斷或彎折成需要之形狀即可製得所需形狀之 真空絕熱體,而使用粉末之真空絕熱體於將内袋調整成所 需形狀上,因内袋破裂或粉末偏於一邊而使形狀加工受 限,且作業效率極低。如此一來,由於使用板狀無機纖維 成形體之真空絕熱材料16係板狀之成形體,故相較於使用 無機粉末時,於製作真空絕熱體16時作業效率將大幅提 昇。又,可省略將粉末填充於内袋之使用粉末時所必須之 私序,且無粉末飛散之顧慮,因此作業環境亦大有改善。 進而,於真空絕熱體16破袋時芯材亦不飛散,故於銷毀冰 箱時亦不招致作業環境之惡化,且易於銷毁具有該真空絕 熱體16之冰箱。又,由於將非粉末而為纖維狀之物質作成 成形體’因此於形成成形體時纖維間之接觸點變多,而可 製得一易以黏結劑等加以固體化且製作容易之芯材。 本實施型態中,絕熱箱體2内係具有真空絕熱體丨6與發 泡樹脂絕熱體17。該發泡樹脂絕熱體係可使用硬質胺曱酸 乙酯泡膠、酚泡膠或苯乙烯泡膠等,但並非特別指定。又, 將如硬質胺曱酸乙酯泡膠發泡時所用之發泡劑,雖無特別 指定,但由保護臭氧層、防止地球溫室化之觀點言之,則 宜為環戊烷、異戊烷、正戊烷、異丁烷、正丁烷、水(礙 酸氣發泡)、偶氮化合物、氬等,特別是在絕熱性能上, 又以環戊烷特別理想。 本貫施型悲中’係將该真空絕熱體16配置於絕熱箱體2 之外箱9側,再於内箱10侧配置發泡樹脂絕熱體丨7。亦可將 本紙張尺度適用中國國家標準(CNS) A4規格(210X297公釐) (請先閲讀背面之注意事項再填窝本頁)Order I 1 ------- (Please read the precautions on the back before filling this page) -11- V. Description of the invention (9) A vacuum insulator 16 can be modeled as a vacuum insulator 16. For example, it is used by being bent along three sides of the heat insulation box 2 of the refrigerator body i, and by forming the shape, the edge portion of the refrigerator box can also be covered with a vacuum heat insulation body, so it can be made further-fire resistance Insulation box 2 of refrigerators with good and excellent heat insulation properties. Also, in the heat insulation box 2, parts that need to be thinner than other parts can be formed by one sheet, and the rest is formed by stacking two sheets. Easily made into the desired shape. In addition, since the core material of the vacuum heat insulator 16 is plate-shaped, it can also widely respond to any demand when laminated to a necessary thickness. In addition, when arranging the required piping or wires of the refrigerator body 丨 on the vacuum insulation body 16, a groove may be formed in the shape of the piping on the plate-shaped inorganic fiber formed body, and then the vacuum insulation body 16 may be made, or After the vacuum insulation is made, a groove is set, and a pipeline is arranged in the groove. In addition, the vacuum insulation body can also be directly pressed to form a groove with respect to the pipeline and the like along the inside of the case, and the vacuum insulation body 16 can also be arranged on the inside of the case. In this way, since the fiber aggregate is used, it can be easily formed, and the groove can be easily set. In addition, due to the use of inorganic fibers, the performance of the vacuum heat insulator 16 due to temperature rise when the resin foam 17 is foamed and filled in the space 14 formed by the refrigerator body 丨 the outer box 9 and the internal phase ο may be deteriorated. Vacuum insulation materials that are more organic than core materials can be controlled. At this time, the vacuum insulation using inorganic powder needs to be filled with powder in the inner bag before inserting the inorganic powder into the outer cover material. If the inorganic powder is not previously filled in the inner bag, the powder will be scattered when the outer material is evacuated. When filling the inner bag with powder to make a vacuum insulation, the size of the paper must be adjusted when the shape of the vacuum insulation is processed (_Α4⑽⑽536536) Description of the invention Adjust the shape of ㈣ before using it. For the core material, the shape processing only needs to cut or bend the plate-shaped core material to the required shape to obtain the vacuum insulation body of the desired shape, and the powdered vacuum insulation body is used to adjust the inner bag to the desired shape. On the other hand, because the inner bag is broken or the powder is on one side, the shape processing is limited, and the operation efficiency is extremely low. In this way, since the vacuum insulation material 16 which is a plate-shaped inorganic fiber formed body is a plate-shaped formed body, Compared with the use of inorganic powder, the work efficiency will be greatly improved when the vacuum insulation body 16 is made. In addition, the private order required when filling the powder in the inner bag can be omitted, and there is no concern about powder scattering, so the operating environment The core material does not fly away when the vacuum insulation body 16 is broken, so it does not cause deterioration of the working environment when the refrigerator is destroyed, and it is easy to destroy the vacuum insulation. The refrigerator of 16. In addition, since a non-powdered and fibrous material is used to form a molded body, the number of contact points between the fibers increases when the molded body is formed, and it is possible to produce a solidified product with an adhesive and the like, and it is easy to manufacture. In this embodiment, the heat insulation box 2 has a vacuum heat insulator 6 and a foamed resin heat insulator 17. The foamed resin heat insulation system can use hard amine ethyl acetate foam and phenol foam. Or styrene foam, etc., but it is not specifically specified. Moreover, the foaming agent used when foaming rigid ethyl amine foam foam is not specified, but from the viewpoint of protecting the ozone layer and preventing global warming Among them, it is preferably cyclopentane, isopentane, n-pentane, isobutane, n-butane, water (obstructing acid gas foaming), azo compounds, argon, etc., especially in terms of thermal insulation performance, and Cyclopentane is particularly ideal. This type of vacuum is used to place the vacuum heat insulator 16 on the outer box 9 side of the heat insulation box 2 and the foam resin heat insulator on the inner box 10 side. 7. This paper size applies to China National Standard (CNS) A4 (210X297 mm) ( (Please read the notes on the back before filling in this page)

-13- 536614 A7 _ B7 五、發明説明(11 ) 真空絕熱體16配置於外箱9内面,其後於外箱9與内箱1〇所 形成之空間14内發泡填充發泡樹脂絕熱體17而形成絕熱 壁。或可將使真空絕熱體16與發泡樹脂絕熱體17一體發泡 之絶熱體,以真空絕熱體16位處外箱9側之狀態而配置於外 箱9與内箱10所形成之空間14中。藉由在冰箱本體丨之外側 面配置耐火性之真空絕熱體16,則可使絕熱材料對冰箱本 體1外部之延燒之耐火化更加提升,並可提高安全性。 又,於冰箱本體1之背面、侧面、頂面配置多數由板狀 無機纖維成形體1 8所形成之耐火性真空絕熱體丨7,則使絕 熱箱體2全體之耐火性提升,進而可製成一安全性高之冰 孝目。又,藉由配置於絕熱箱體2之側面或背面或底面任一處 以上之僅與冷凍室12相對應之部分上,亦可有效貼近於成 本面或絕熱性能面。 又,本實施型態中,係於安裝於冰箱上之門扇體4中使 用板狀無機纖維成形體1 8。該門扇體4中所用之真空絕熱體 16’有於門扇體4之内侧面或外側面黏貼使用板狀無機纖維 成形體18之真空絕熱體16 ,並以發泡樹脂絕熱體17填充其 餘空間之方法。此外,並有先以真空絕熱體16與發泡樹脂 絕熱體17製成多層絕熱板,並將其夾於門扇體4内部或以膠 V等貼上等方法。進而,有於門扇體4内部配置板狀無機纖 維成形體1 8並將門扇體4内部真空排氣而使門扇體4本身形 成真空絕熱體之方法等。由於門扇體4中使用耐火性之真空 絕熱體16,因此萬一冰箱本體丨周邊起火燃燒,亦可達到難 以延燒至門扇體4之效果。 本紙張尺度適用中國國家標準(CNS) A4規格(210X297公釐) (請先閲讀背面之注意事項再填寫本頁)-13- 536614 A7 _ B7 V. Description of the invention (11) The vacuum heat insulator 16 is arranged on the inner surface of the outer box 9, and then foamed and filled with the foamed resin heat insulator in the space 14 formed by the outer box 9 and the inner box 10. 17 to form a thermal insulation wall. Alternatively, the vacuum insulator 16 and the foamed resin insulator 17 may be integrally foamed, and the vacuum insulator 16 may be placed in the space formed by the outer case 9 and the inner case 10 with the vacuum insulator 16 at the side of the outer case 9 14 in. By arranging the refractory vacuum heat insulator 16 on the outer side of the refrigerator body 丨, the refractory resistance of the heat-insulating material to the external firing of the refrigerator body 1 can be further improved, and the safety can be improved. In addition, arranging a plurality of refractory vacuum heat insulators formed of a plate-shaped inorganic fiber formed body 18 on the back, side, and top surfaces of the refrigerator body 1 can improve the fire resistance of the heat insulation box 2 as a whole. Become a high security filial piety. Moreover, it can be effectively placed close to the cost surface or the heat insulation performance surface by being arranged on the side corresponding to the freezer compartment 12 or more on the side surface, the back surface, or the bottom surface of the heat insulation box 2. In this embodiment, a plate-shaped inorganic fiber molded body 18 is used for the door body 4 mounted on the refrigerator. The vacuum heat insulator 16 ′ used in the door body 4 has a vacuum heat insulator 16 using a plate-shaped inorganic fiber formed body 18 adhered to the inner or outer side of the door body 4, and the remaining space is filled with a foamed resin heat insulator 17. method. In addition, there is a method of first forming a multi-layer heat insulation plate by using the vacuum heat insulator 16 and the foamed resin heat insulator 17 and sandwiching the heat insulation plate inside the door body 4 or pasting it with glue V or the like. Further, there is a method of arranging a plate-shaped inorganic fiber molded body 18 inside the door body 4 and vacuum-evacuating the inside of the door body 4 to form the door body 4 itself as a vacuum heat insulator. Since the refractory vacuum heat insulator 16 is used in the door body 4, if the surroundings of the refrigerator body 丨 fire and burn, the effect that it is difficult to extend to the door body 4 can be achieved. This paper size applies to China National Standard (CNS) A4 (210X297 mm) (Please read the precautions on the back before filling this page)

-14- 536614-14- 536614

五、發明説明(l2 ) 進而,本實施型態中係具有一用以將冰箱本體丨内獨立 分隔之分隔箱體3,且該分隔箱體3中設有真空絕熱體16。 亦可於分隔箱體3内部僅配置真空絕熱體16並將周圍被覆 由ABS;bi脂或pp樹脂等構成之分隔箱體外框2〇,而形成分 隔箱體。 又’可將真空絕熱體、發泡樹脂絕熱體與分隔箱體外 框一體成形而作成分隔箱體,或此時可使分隔箱體外框與 内箱一體成形。或可預先以真空絕熱體與發泡樹脂絕熱體 製成絕熱板並放入分隔箱體外框内而形成分隔箱體,只要 為使用由板狀無機纖維成形體構成之真空絕熱體之分隔箱 體即無特別限制。藉由將分隔箱體作成如上構造,且於絕 熱箱體之内箱侧配置以板狀無機纖維成形體構成之真空絕 熱體,則可製得一安全性高之冰箱,該冰箱於外部起火燃 燒時,縱使冷藏室前面部之門扇開放而使箱内燃燒,仍可 防止火勢延燒至以分隔箱體分隔之另一空間。 又’以分隔箱體3區隔之冰箱本體1内可分為冷藏室 11、冷凍室12,甚且其等之位置關係並非只定為頂部冷;東 器、中間冷凍器、底部冷凍器等,進而大型冰箱等亦於橫 向具有分隔箱體,左右任一室皆可為冷藏室、冷凍室。 本實施型態之真空絕熱體16之配置方法,係欲先於真 空絕熱體16之一面,或於外箱9内側之真空絕熱體丨6黏貼位 置’或於前述兩方塗布熱熔液,其後將真空絕熱體16緊壓 入外箱9,並藉施加壓力而使真空絕熱體16黏上絕熱箱體 2 ’之後將外相10與内箱9所形成之空間14以由硬質胺甲酸 本紙張尺度適用中國國家標準(CNS) A4規格(210X297公董) (請先閲讀背面之注意事項再填寫本頁)V. Description of the Invention (l2) Furthermore, in this embodiment, a partition box 3 for separating the interior of the refrigerator body independently is provided, and a vacuum insulation body 16 is provided in the partition box 3. It is also possible to form a partition box by arranging only the vacuum heat insulator 16 inside the partition box 3 and covering the outer frame 20 of the partition box made of ABS; bi-resin or pp resin. Also, the vacuum insulation body, the foamed resin insulation body and the partition box outer frame can be integrally formed to form the partition box body, or at this time, the partition box outer frame and the inner box can be integrally formed. Alternatively, a vacuum insulation body and a foamed resin insulation body can be made into a heat insulation plate in advance and placed in the outer frame of the separation box to form a separation box body, as long as the separation box body is a vacuum insulation body composed of a plate-shaped inorganic fiber formed body. That is, there is no particular limitation. By constructing the partition box as described above, and arranging a vacuum insulation body composed of a plate-shaped inorganic fiber formed body on the inner box side of the heat insulation box, a highly safe refrigerator can be manufactured, which fires and burns on the outside At this time, even if the door at the front of the refrigerating compartment is opened to burn the inside of the box, the fire can still be prevented from burning to another space separated by the partition box. Also, the refrigerator body 1 divided by the partition box 3 can be divided into a refrigerating compartment 11 and a freezing compartment 12, and the positional relationship among them is not limited to only the top cold; the east, the intermediate freezer, the bottom freezer, etc. In addition, large refrigerators and the like also have partition boxes in the horizontal direction, and any one of the left and right rooms can be a refrigerating room and a freezing room. The configuration method of the vacuum insulation body 16 of this embodiment mode is to apply the hot melt liquid to one side of the vacuum insulation body 16 or the vacuum insulation body 6 inside the outer box 9 or to the above two sides, Then, the vacuum heat insulator 16 is tightly pressed into the outer box 9, and the vacuum heat insulator 16 is adhered to the heat insulator 2 by applying pressure. Then, the space 14 formed by the outer phase 10 and the inner box 9 is made of hard amine formic acid paper. Standards are applicable to China National Standard (CNS) A4 specifications (210X297 public directors) (Please read the precautions on the back before filling this page)

-15- 536614 A7 ___B2___ 五、發明説明(13 ) —- 乙_泡膠構成之發泡樹脂絕熱體17進行發泡填充。 (請先閱讀背面之注意事項再填寫本頁) 又,於將真空絕熱體16配置於絕熱箱體2之側面時,為 使該真空絕熱體16配合絕熱箱體2之形狀,例如沿機械室^ 之形狀而可於第1圖右下部配置一具切口部之真空絕熱㉙ !6。又,此時真空絕熱體可覆蓋絕熱箱體之側面全體了 : 可僅覆蓋與漏熱大之冷凍室9相對應之絕熱箱體部,亦可以 多數真空絕熱體覆蓋側面。 又,用以分離設於冰箱本體1之背面下部之機械室21 與冷凍室12之絕熱箱體2之絕熱部上所設之真空絕熱體 16 ,係彎折成沿機械室21之形狀。由於該真空絕熱體μ係 以無機纖維成形體18作為芯材,因此彎折加工非常容易, 且生產性佳。 又,第2圖所示之真空絕熱體16之製造方法係顯示於 下。真空絕熱體16係藉由將厚度5mm之板狀無機纖維成形體 18以14(TC乾燥1小時後插入外被材料19中,且將内部抽成 真空後密封開口部而形成者。前述板狀無機纖維成形體所 用之無機纖維之化學組成係,二氧化矽約6〇%,氧化鋁約 18%,氧化鈣約17%,其餘無機物約5%,而纖維直徑約以㈤ 〜3μηι。而,相對於此,並使用約5%之丙烯酸系黏結劑作 為黏結劑,且該成形體於大氣壓力下之密度 則述外被材料19,一面係由以聚對苯二甲酸乙二酯 (12μΠ1)作為表面保護層,中間部為鋁箔(6μιη),及以 咼密度聚乙烯(50μηι)為熱封層所組成之積層膜,而另一 面係由以I對笨二甲酸乙二酯(丨2μΐΏ )為表面保護層,中 本紙張尺度適用中國國豕檩準(〇^5) A4規格(210X297公I) -16- 536614 五、發明説明(l4 間⑷為於乙烯·乙婦醇共聚物樹脂組成物(J 5 pm )内側施 以鋁療鍍之薄膜層,及以高密度聚乙烯(5〇μηι)為熱封層 所組成之積層膜。 又,前述外被材料19為提高耐受傷性,乃於表面保護 層上形成一耐綸樹脂層。此外,該外被材料19之袋形狀係 使用四方密封者。 (實施型態2 ) 第3圖係本發明之實施型態2之冰箱截面圖。冰箱本體ι 係以外I目22、内箱23及其空間中由板狀無機纖維成形體j 8 配置成之絕熱箱體24所構成者。前述絕熱箱體24中係將2 片以上之板狀無機纖維重疊使用。前述外箱22與内箱23係 由厚度0.5麵之鐵板所構成,且接縫係以熔接進行密封以保 内敎氣密性。又,同樣以鐵板等形成分隔箱㈣。該分 隔箱體25内,亦裝有板狀無機纖維成形體18。此外,前述外 箱22、分隔箱體25上各設有排氣孔%、”,以使内部可進 行真空排氣,由此將絕熱箱體24、分隔箱體25内部抽成直 空後,再以溶接封住排氣孔26、27以保内部之氣密性。此 時’為求冰箱背面之平面性,前述排氣孔26之突起部可於 可保氣密性之範圍内將之切除。門扇體28,係以厚度Μ 腿之鐵板形成外框,且於内部配置板狀無機纖維成形體以 後將内。ρ進仃真空排氣’並將排氣孔29以炫接加以密封。 又,蒸發器8係配置於冰箱本體丨之箱内,並與外部之 冷凍循環零件裝管連接。此時,該等 j ° / I e綠與絕熱箱體24係 以絕,、、、箱體24之内箱23與外箱22之接縫部分%、η溶接, 本紙張尺度適财關家標準(哪)从規格(21()><297公嫠) 536614 A7 --- --~~—_B7 五、發明説明(15 ) — 〜---—— 以保絕熱箱體24内部之氣密性。 板狀無機纖維成形體18係沿前述管線之形狀而形成凹 陷’並於該處埋設管路,由於呈板狀故形狀加卫非常容易, 二可輕易進行凹陷之形成。該無機纖維之紹含有率約18 由於3加鋁含有率並提高結晶性將使耐熱溫度上昇, 因此若將以銘含有率更大之無機纖維構成之板狀無機纖維 成形體18用於冰箱上’則可製得—安全性高之冰箱。此外, 為保絕熱箱體24或門扇體28内部之真空度,亦可於内部配 置氣體吸附劑。 猎由如此之構造,且絕熱壁上不具發泡樹脂絕熱體, 則使冰箱之安全性躍升。此係由於萬一冰箱外部延燒,卻 因不具有機性之絕熱材料而可抑制火勢延燒至絕熱材料, 或可抑制發泡樹脂絕熱體產生有機氣體。此時,外箱與内 箱之氣體阻擋性佳,且具優異之低導熱度物質,但實際上 非常薄之鐵板、不銹鋼板等金屬板即具有有效之效果。將 外箱與内箱之内部真空排氣時亦可保持冰箱表面之平面 性。又生產時僅需將板狀無機纖維成形體而非無機粉體等 插入外箱與内箱間再將内部抽成真空即可,故生產性或作 業性極佳。又,由於使用無機纖維,因此真空絕熱體内經 一段時間後並無氣體產生,而絕熱箱體之長期可靠性亦得 以提升。 又,藉由使板狀無機纖維成形體作成至少含二氧化矽 之構造,則可得一耐熱性佳且價廉之板狀無機纖維成形體。 又,藉由使板狀無機纖維成形體作成至少含氧化鋁之 本紙張尺度適用中國國家標準(CNS) A4規格(210X297公釐) (請先閱讀背面之注意事項再填寫本頁)-15- 536614 A7 ___B2___ V. Description of the invention (13) —- B_ Foam resin heat insulator 17 composed of B_foam is filled with foam. (Please read the precautions on the back before filling in this page.) Also, when the vacuum heat insulator 16 is arranged on the side of the heat insulation box 2, in order to make the vacuum heat insulator 16 fit the shape of the heat insulation box 2, for example, along the machine room ^ Shape, a vacuum insulation ㉙! 6 with a cutout can be arranged in the lower right of Figure 1. At this time, the vacuum insulation body can cover the entire side surface of the heat insulation box: it can cover only the heat insulation box portion corresponding to the freezer compartment 9 with large heat leakage, and most of the vacuum heat insulation bodies can also cover the sides. In addition, the vacuum heat insulator 16 provided on the heat insulation part of the heat insulation part 2 of the heat insulation box 2 of the freezer compartment 12 and the machine room 21 provided at the lower part of the back of the refrigerator body 1 is bent into a shape along the machine room 21. Since the vacuum heat insulator μ uses the inorganic fiber formed body 18 as a core material, the bending process is very easy and the productivity is excellent. The manufacturing method of the vacuum heat insulator 16 shown in Fig. 2 is shown below. The vacuum heat insulator 16 is formed by inserting a plate-shaped inorganic fiber formed body 5 having a thickness of 5 mm into a cover material 19 after drying at 14 ° C for 1 hour, and evacuating the inside to seal the opening portion. The aforementioned plate shape The chemical composition of the inorganic fibers used in the inorganic fiber formed body is about 60% of silicon dioxide, about 18% of alumina, about 17% of calcium oxide, and about 5% of the remaining inorganic matter, and the fiber diameter is about ㈤ ~ 3μηι. In contrast, an acrylic adhesive of about 5% is used as the adhesive, and the density of the formed body under atmospheric pressure is described as a cover material 19, and one side is made of polyethylene terephthalate (12 μΠ1) As a surface protection layer, the middle part is an aluminum foil (6 μιη), and a laminated film composed of 咼 density polyethylene (50 μηι) as a heat-seal layer, and the other side is made of I-ethylene dibenzate (2 μΐΏ). As the surface protective layer, the Chinese paper standard is applicable to China National Standard (0 ^ 5) A4 specification (210X297 male I) -16- 536614 V. Description of the invention (14) is composed of ethylene · ethinol copolymer resin (J 5 pm) with aluminum coating on the inside, A laminated film composed of high-density polyethylene (50 μηι) as a heat-seal layer. In addition, the outer cover material 19 is formed on the surface protective layer to improve abrasion resistance. In addition, the outer layer The shape of the bag of the material 19 is a square seal. (Embodiment Mode 2) Figure 3 is a cross-sectional view of a refrigerator according to Embodiment Mode 2 of the present invention. The refrigerator body is outside the head 22, the inner box 23 and its space. A plate-shaped inorganic fiber formed body j 8 is configured by a heat-insulating box 24. In the heat-insulating box 24, two or more plate-shaped inorganic fibers are overlapped and used. The outer box 22 and the inner box 23 are formed by thickness. It consists of a 0.5-sided iron plate, and the seams are sealed by welding to ensure the airtightness of the inner part. Also, a partition box ㈣ is also formed by an iron plate or the like. The partition box 25 is also equipped with a plate-shaped inorganic fiber molding. Body 18. In addition, the above-mentioned outer box 22 and the partition box 25 are provided with exhaust holes%, "so that the interior can be evacuated by vacuum, thereby the interior of the heat-insulating box 24 and the partition box 25 is drawn straight. After emptying, the exhaust holes 26 and 27 are sealed by welding to ensure the airtightness inside. 'In order to obtain the flatness of the back of the refrigerator, the protrusions of the aforementioned exhaust holes 26 can be cut off within the range that can maintain air tightness. The door body 28 is formed by an iron frame with a thickness of M legs and is internally formed. After arranging the plate-shaped inorganic fiber formed body, ρ is vacuum-evacuated, and the vent hole 29 is sealed with a dazzle connection. The evaporator 8 is arranged in the box of the refrigerator body and is frozen with the outside. The circulating parts are connected by pipes. At this time, the j ° / I e green and the heat insulation box 24 are insulated, and the joints between the inner box 23 and the outer box 22 of the box 24 are melted. Paper standards (where) from the standard (21 () > < 297) 536614 A7 ----~~ --_ B7 V. Description of the invention (15) — ~ ---—— The airtightness of the heat insulation box 24 is maintained. The plate-shaped inorganic fiber formed body 18 is formed into a depression along the shape of the aforementioned pipeline, and the pipeline is buried there. The shape of the plate is very easy to defend, and the depression can be easily formed. The content rate of this inorganic fiber is about 18. Since the addition of aluminum and the increase in crystallinity will increase the heat resistance temperature, if a plate-shaped inorganic fiber formed body 18 made of inorganic fibers with a higher content rate is used in a refrigerator, 'It can be made-a refrigerator with high security. In addition, in order to maintain the vacuum degree inside the thermal insulation box 24 or the door body 28, a gas adsorbent may be arranged inside. With such a structure and the absence of a foamed resin insulator on the heat insulation wall, the safety of the refrigerator is greatly improved. This is because in the event of external firing of the refrigerator, it is possible to suppress fire to thermal insulation due to non-organic thermal insulation materials, or to suppress the generation of organic gases from foamed resin insulation. At this time, the outer box and the inner box have good gas barrier properties and have excellent low thermal conductivity substances, but actually very thin metal plates such as iron plates and stainless steel plates have effective effects. When the interior of the outer box and the inner box are evacuated, the flatness of the surface of the refrigerator can be maintained. In production, it is only necessary to insert a plate-shaped inorganic fiber formed body instead of an inorganic powder into the outer box and the inner box, and then evacuate the interior, so the productivity or workability is excellent. In addition, due to the use of inorganic fibers, no gas is generated in the vacuum insulation body over a period of time, and the long-term reliability of the insulation box is also improved. In addition, by forming the plate-shaped inorganic fiber formed body into a structure containing at least silicon dioxide, a plate-shaped inorganic fiber formed body having excellent heat resistance and low cost can be obtained. In addition, by making the plate-shaped inorganic fiber formed body into a paper containing at least alumina, the paper size is in accordance with the Chinese National Standard (CNS) A4 (210X297 mm) (Please read the precautions on the back before filling in this page)

-18- 536614 A7 ______B7 五、發明説明(π ) " ~〜 -- 構造,而氧化鋁含有率越多則絕熱材料之耐熱性越古,則 可使板狀無機纖維成形體之耐火性提升。又, 、 做狀無機纖 維成形體亦可具有其他成分,其餘無機物可為氧化鈣、氧 化錤、氧化鐵、氧化鈦、氧化侧、氧化鈉、氧化餘、硫酸 約、硫酸鎂、碳化矽、鈦酸奸、氧化鉻、氧化鋅等,並無 特別指定。 ^ 又,本實施型態之冰箱係使用對地球溫室化之影響較 少之HC冷媒作為冷媒。如前述般,若使用可燃性冷媒則與 習知之使用HCFC冷媒或CFC冷媒時相比,對火災等之對策 乃更為重要,但藉使用本實施型態中所述無機纖維成形體 之絕熱體則可提供安全性更高之冰箱。因此,將可提供一 種安全性與地球環境保護可並存之冰箱。 產業上之可利用性 如上所述之本發明之冰箱,係構造成於絕熱箱體中使 用板狀無機纖維成形體,進而具有一以氣體阻播性薄膜被 覆並將内部減壓之真空絕熱體。因此,耐火性較使用僅具 發泡樹脂體之絕熱材料得以改善,結果將提高絕熱箱體之 耐火性。因此,可達到絕熱箱體對外部延燒之耐火化效果, 並可製得一安全性較習知之冰箱高之冰箱。 【元件標號表】 1…冰箱本體 5···壓縮機 2···絕熱箱體 6···凝結器 3…分隔箱體 7·.·毛細管 4…門扇體 8…蒸發器 本紙張尺度適用中國國家標準(CNS) A4規格(210X297公釐) (請先閲讀背面之注意事項再填寫本頁) 、可| I線— -19- 536614 A7 B7 五、發明説明(Π ) 9…外箱 10…内箱 11.. .冷藏室 12.. .冷凍室 13.. .擔板 14.. .絕熱箱之空間 15.. .門扇體之空間 16…真空絕熱體 17.. .發泡樹脂絕熱體 18.. .板狀無機纖維成形體 19···氣體阻擋性薄膜(外被材料) 20…分隔箱體外框 21.. .機械室 22…外箱 2 3…内箱 24.. .絕熱箱體 25.. .分隔箱體 26、27、29·· j非氣 28.. .門扇體 30、31···接縫部分 (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準(CNS) A4規格(210X297公釐) -20--18- 536614 A7 ______B7 V. Description of the invention (π) " ~~-Structure, and the more the alumina content, the older the heat resistance of the thermal insulation material, the higher the fire resistance of the plate-shaped inorganic fiber formed body . In addition, the shaped inorganic fiber formed body may have other components, and the remaining inorganic substances may be calcium oxide, hafnium oxide, iron oxide, titanium oxide, oxidized side, sodium oxide, residual oxide, sulfuric acid, magnesium sulfate, silicon carbide, and titanium. Sour acid, chromium oxide, zinc oxide, etc. are not specified. ^ In addition, the refrigerator of this embodiment uses HC refrigerant, which has less influence on global warming, as the refrigerant. As mentioned above, if a flammable refrigerant is used, it is more important to take measures against fires than when the conventional HCFC refrigerant or CFC refrigerant is used, but by using the thermal insulation of the inorganic fiber formed body described in this embodiment Can provide a more secure refrigerator. Therefore, a refrigerator that can coexist with safety and global environmental protection will be provided. INDUSTRIAL APPLICABILITY The refrigerator of the present invention as described above is configured to use a plate-shaped inorganic fiber formed body in a heat-insulating box, and further has a vacuum heat-insulating body covered with a gas-barrier film and decompressing the inside. . Therefore, the fire resistance is improved as compared with the use of a heat insulating material having only a foamed resin body, and as a result, the fire resistance of the heat insulation box is improved. Therefore, the refractory effect of the adiabatic cabinet on the external burning can be achieved, and a refrigerator with higher safety than the conventional refrigerator can be obtained. [Nomenclature of components] 1 ... Fridge body 5 ... compressor 2 ... insulation box 6 ... condenser 3 ... partition box 7 ... capillary tube 4 ... door fan 8 ... evaporator China National Standard (CNS) A4 specification (210X297 mm) (Please read the notes on the back before filling this page), OK | I line — -19- 536614 A7 B7 V. Description of the invention (Π) 9… Outer box 10 … Inner box 11 ... refrigerating chamber 12 ... freezer chamber 13 ... stretcher board 14 .. space for thermal insulation box 15 .. space for door body 16 .... vacuum heat insulator 17..foam resin insulation Body 18... Plate-shaped inorganic fiber formed body 19... Gas barrier film (outer cover material) 20 .. Outer frame of partition box 21.... Machine room 22. Outer box 2 3. Inner box 24.. Box 25 .. Separated boxes 26, 27, 29 ... J non-gas 28 .. Door body 30, 31 ... Seam part (Please read the precautions on the back before filling this page) This paper size Applicable to China National Standard (CNS) A4 specification (210X297 mm) -20-

Claims (1)

種冰箱,係具有一使一壓縮機、一冷凝器、一毛細管、 及一蒸發器環狀連接之冷凍循環者; 而’前述冷凍循環内係裝有具可燃性之冷媒,且具 有一由面對冰箱内部之内箱與面對冰箱外部之外箱形成 之絕熱箱體,前述絕熱箱體之空間内至少配置有—由板 狀無機纖維成形體構成之絕熱材料,而該絕熱材料係一 藉氣體阻擋性薄膜被覆前述板狀無機纖維成形體並使内 部減壓之真空絕熱體。 如申請專利範圍第i項之冰箱,其中該絕熱箱體之空間 内進而裝設有一發泡樹脂體。 如申請專利範圍第2項之冰箱,其中該絕熱箱體之前述 外箱側係裝設有前述真空絕熱材料。 如申請專利範圍第1至3項中任一項之冰箱,其中安裝於 冰相上之門扇體之前述絕熱箱體之空間内係配置有前 述真空絕熱材料。 如申印專利範圍第2項之冰箱,其係具有一將冰箱内隔 成相互獨iL空間之分隔箱冑,且該分隔箱體之空間内配 置有前述真空絕熱體。 如申,月專利範圍第5項之冰箱,其中該分隔箱體係藉E 前述絕熱箱體而一體形戒者。 一種冰箱,係具有一使一壓縮機、一凝結器、一毛細管 及一蒸發器環狀連接之冷凍循環者; 而,該冰箱並具有一由面對冰箱内部之内箱與面對 冰箱外部之外箱形成之絕熱箱體,且於前述絕熱箱體之 536614 A8 B8 C8 D8 申請專利範圍 空間内至少配查一由板狀益掩 对…、棧纖維成形體構成之絕熱材 料,並使内部減壓 8.如申請專利範圍第i項或第7項之冰箱, 纖維成形體係至少含有二氧化石夕。 9·如申請專利範圍第1項或第7項之冰箱, 纖維成形體係至少含有氧化銘。 其中該板狀無機 其中該板狀無機 (請先閲讀背面之注意事項再填寫本頁}A refrigerator is provided with a refrigeration cycle that connects a compressor, a condenser, a capillary tube, and an evaporator in a ring; and the 'refrigeration cycle described above is provided with a flammable refrigerant and has a free surface. For the inner box formed inside the refrigerator and the outer box facing the outside of the refrigerator, at least the space of the aforesaid box is provided with a heat-insulating material composed of a plate-shaped inorganic fiber formed body, and the heat-insulating material is a loan The gas-barrier film covers the aforementioned plate-shaped inorganic fiber formed body, and a vacuum insulator having a reduced internal pressure. For example, the refrigerator in the scope of application for patent item i, wherein a space of the heat insulation box is further provided with a foamed resin body. For example, the refrigerator in the second scope of the patent application, wherein the above-mentioned outer side of the heat-insulating box is provided with the aforementioned vacuum heat-insulating material. For example, in the refrigerator of any one of the scope of application for patents, the space of the aforementioned heat insulation box of the door body installed on the ice phase is provided with the aforementioned vacuum insulation material. For example, the refrigerator in the scope of application for the second patent, which has a partition box 将 which separates the interior of the refrigerator into a separate iL space, and the space of the partition box is provided with the aforementioned vacuum heat insulator. If applied, the refrigerator of item 5 of the monthly patent scope, wherein the partition box system is integrally formed by the aforementioned insulated box. A refrigerator is provided with a refrigerating cycle which connects a compressor, a condenser, a capillary tube and an evaporator in a ring; and the refrigerator also has an inner box facing the inside of the refrigerator and a refrigerator facing the outside of the refrigerator. The thermal insulation box formed by the outer box, and at least one thermal insulation material consisting of plate-shaped shields, stacked fiber formed bodies, etc. shall be checked in the 536614 A8 B8 C8 D8 patent application space of the aforementioned thermal insulation box, and the interior shall be reduced. 8. If the refrigerator in the scope of application of item i or item 7 of the patent application, the fiber forming system contains at least stone dioxide. 9. If the refrigerator in the scope of the application for item 1 or item 7, the fiber forming system contains at least an oxide name. Which the plate-shaped inorganic which the plate-shaped inorganic (Please read the precautions on the back before filling in this page} 、一叮| 本紙張尺度適用中國國家標準(CNS) A4規格(210X297公釐) -22-, Yiding | This paper size applies to China National Standard (CNS) A4 specifications (210X297 mm) -22-
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