TW505522B - Hair oxidizing composition - Google Patents

Abstract

An oxidizing composition comprises (A), (B), and (C): (A) a straight chain or branched alkyl cationic surfactant, (B) 8-hydroxyquinoline, and (C) hydrogen peroxide; which shows excellent conditioning effect to hair during application, generates good conditioning effect to hair after use, and dyeing and oxidizing effect reduces scarcely over time.

Description

505522 A7 B7 V. Description of the invention (This product, field, please read _ Read the back-Attention-Matters before filling out this page. This invention is a kind of oxidant composition for dyeing and decoloring hair, which is caused by hair The damage is very small, it can produce a good moisturizing effect on the hair when applying this object and after it is shaken, and the dyeing effect and the clever color effect are rarely reduced at any time. The decoloring agent is composed of the first agent containing an alkaline agent and the second agent containing an oxidant. In addition, in order to enhance the decolorization effect, there are also three-agent formulas containing an activator such as persulfate as a strategy 3. -Order, however, after treating the hair with these agents, the hair will lose its softness and dryness, and will no longer be moist, shiny, and soft, and will not be easy to comb. Disadvantages of medicaments. Printed by the Central Bureau of Standards of the Ministry of Economic Affairs, Bei Gong Xiao F Cooperative, in order to solve these shortcomings, the proposed solutions are: the second method of incorporating a specific fourth ammonium compound (Japanese Patent Publication No. 52 96749), a method of incorporating a cationic polymer (Japanese Patent Publication No. 5449340), and a method of doping a fluorene silicone derivative (Japanese Patent Publication No. 61- No. 55887), etc., but the effect of the above method is not sufficient. Therefore, there is still a need for a composition that has minimal damage to hair and can produce a good moisturizing effect. The object of the present invention is to provide a method for dyeing and decoloring hair The oxidant composition is used to eliminate the disadvantages of the head's milk, and it can have a good moisturizing effect on the hair. ^ The invention ^ shows that the paper size is suitable for China National Sample -4-(CNS) (210 × 297 ^ > ^ 505522 kl B7

V. Description of the invention (Z The inventors of the present invention have discovered that by mixing hydrogen peroxide with a cationic surfactant and 8-hydroxyzolin, it is more preferably further mixed with high-carbon alcohols and / or amines. The above-mentioned purpose can be achieved by mixing base-modified silicone together, and using the composition, the dyeing effect and decoloring effect are rarely reduced at any time, and the present invention is completed. That is, the present invention provides a method for dyeing and decoloring hair. The oxidant composition is characterized by comprising the following components ⑻ ~ (c): ⑻ linear or branched alkyl cationic surfactants, (b) 8-Likehan 4, and ⑹ hydrogen peroxide. For example, the best 赉 bear for carrying out the invention, for example, the linear or branched alkyl cationic surfactant as the ingredient ⑻ can be a monoalkyl type fourth ammonium salt expressed as the general formula ··· ( Please read the notes on the back *, and then fill in this page, -port R1 R ^ * N—R3 R4

X 印 Printed by Shellfish Consumer Cooperative, Central Bureau of Standards, Ministry of Economic Affairs [where R1 is a linear or branched alkyl group with 8 to 36 carbon atoms that can be substituted by a hydroxyl group, R2, R3 and R4 may be the same or different , Represents an alkyl group or benzyl group having a number of 1 to 3 after being substituted by a hydroxyl group, and X represents a prime atom or an alkyl sulfate group having a carbon number of 1 or 2. ], Or a dialkyl type fourth ammonium phosphonium represented by the general formula: R5 R-N-R7

X (2) -5- This paper size applies Chinese National Standard (CNS) Λ4 gauge (210 X 297 public) 505522 Α7 B7 V. Description of the invention (3) [The meaning of X in the formula is the same as above, R5 * R6 may be the same or different, which means a straight or branched chain alkyl group having 8 to 36 carbon atoms which may be substituted by a hydroxyl group, and R7 and the same or different may indicate that the carbon number which may be substituted by a hydroxyl group is 1 Burning base of ~ 3. ]. For example, the 4 monoalkyl type fourth ammonium salt may be vaporized stearyl trimethylammonium, vaporized 2-octyllauryltrimethylammonium, and the like. For example, the dialkyl type fourth ammonium salt may be a vaporized distearyldimethyl ether and the like. These ingredients ⑻ can be used alone or in combination of two or more. In order to fully obtain the effect of the present invention and to prevent the hair from feeling sticky, it is preferable to blend in the composition of the present invention from 0.1 to 1- 0% by weight (only abbreviated as% below) of the component ⑻, and blending 0 to 8% is particularly preferred. In order to achieve the effect of inhibiting the decomposition of hydrogen peroxide, it is preferred that the composition of the present invention is blended with 0.005 ~ 5.0% of the ingredient ⑹8-hydroxyquinoline, and blended with 002 ~ 〇, 1% is particularly preferred. / In terms of dyeing and decoloring effects, and in terms of irritation to the scalp, it is preferred that the composition of the present invention is blended with 0.5 to 10% of the hydrazone component hydrogen peroxide 'and 1.0 to 8.0%. Department of the best. Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs • Clothing — (Please read the note t * on the back of ruthenium before filling in this page to order in the composition of the present invention. Blend the following high carbon number alcohols and / or amine amino modified silicones. For example, the high carbon number alcohols as component (d) may be a straight chain having 10 to 24 carbon atoms. Or branched chain aliphatic alcohols, among which cetyl alcohol (eetylaic 0h〇i), middle alcohol (eetanOl), stearyl alcohol, base stearyl alcohol and oleyl alcohol are better. __ -6_ 本Paper scales and financial accounts (CNS) Taiwan (210χϋΡ7 505522 A7 B7 V. Description of invention (4) These ingredients are printed on the shelling consumer cooperatives of the Central Bureau of Standardization of the Ministry of Economic Affairs. They can be used alone or in combination of two or more. In order to fully obtain the effect of the present invention, and to prevent the hair from feeling sticky, and to prevent tangles and irregularities during washing, it is preferred that 20% of the ingredient (d) be blended in the composition of the present invention and blended. 〇5 ～ 10 ％ are especially good. For example, s, as the component of the amino modified silicone can be expressed as The general formula ⑶ is: R9 ^ ⑶ CH3I. -S i- ^ O- CH, m -Si- R1 [wherein R9 may be the same or different, which represents a hydrogen atom, a hydroxyl group, and Ri (> represents: (CH2) ^ (〇c2H4) p. (〇C3H6) q «NHC2H4-N (Rn) 2 or-(CH2V (〇C2H4) ir (〇C3H6) ^ NH (^ H4_N + (RU) 3 (R can be the same Or different, is a hydrogen atom, a hydrocarbon group having a carbon number of 1 to 6, Z is a halogen ion or an organic anion, 0 is a number of 6 to 6, and P and q are numbers in Table 7F 0 to 6}, m represents a number from 3 to 300, and n represents a number from 1 to 50.] In the general formula (3), R9 is preferably a super group and a methyl group, R10 is preferably _, and η is preferably 1 to 20. The above ingredients ⑹ can be used alone or in combination of two or more, in order to fully obtain the effect of the present invention, and to prevent the hair from feeling sticky, it is preferably blended in the composition of the present invention. 〖5% of the ingredients ⑹, and blending 1.0 ~ 8.0% is particularly preferred α in the composition of the present invention, in addition to the above essential ingredients, can also be methyl or methyl

Z (Please read the red note ^-Matters before filling out this page),-0 -7- This paper size is applicable to China National Standard (CNS) Λ4 specification (210X 297 public power) Printed by the Consumer Cooperative 505522 A7 —---- ~ -_B7 V. Description of the Invention (5) A: Requirement: Add other ingredients used in commonly used granulated products, such as emulsifying II, ': dehydration agent, Adhesives, stabilizers other than ingredient (b), hair styling bases: Example :: The other 1 'can also be blended with other derivatives other than ㈣, clothing nets, polyether modified mash, burnt-based modified wheat Ketones and other substances can further improve the sensitivity. The pH of the oxidizing agent composition of the present invention is preferably adjusted to 2 ~ 6, and 3 ~ 5 is particularly preferred. Λ, the oxidant composition of the present invention can be produced according to a common method, and its form is not particularly limited. For example, it can be made into a transparent liquid, emulsion, cream, gel, paste, spray , Spray foam. 'When using the oxidizing agent composition of the present invention to treat hair, in the case of a single-dose type <', for example, the oxidizing agent composition of the present invention can be applied to a person after shampooing: on the field 4 to 3 to 5 minutes before It may be washed; in the case of the two-dose formula, for example, the oxidant composition (second agent) of the present invention and a composition containing an alkaline agent, or an alkaline agent or a dye precursor may be used. And the coupler (coupler) composition (the first agent) mixed, apply this mixture to the hair, leave it for 3 to 5 minutes and then rinse it. In addition, the hair treatment agent of the present invention is generally preferably applied at 15 to 40 ° C. Examples Examples 1 to 4 and Comparative Example 1 prepared the first agent shown in Table 1 and the second agent shown in Table 2, and evaluated their performance. (Manufacturing method) A 1st agent is manufactured by a conventional method. The second agent is prepared by the following method: -8-Chinese National Standard (CNS) Λ4 specification (210X 297 public) for this paper (Please read the precautions of Rainbow before filling this page), 1T-505522 A7 B7 V. Description of the invention (6): Add cationic surfactant, high alcohol number and petrolatum to propylene glycol, and heat to 70 ° C to dissolve. In addition, 8 · Likiline and linoleic acid It is heated to 70 ° C with water to dissolve, and the above-mentioned dissolved matter is added thereto. After stirring for 30 minutes, keep stirring and cool to 40X, then add the remaining ingredients. (Evaluation method) • Comb smoothness, dryness, softness, and glossiness. Each 8 g of the first agent (Table 1) and the second agent (Table 2) were mixed, and 10 grams of this was applied to the black hair bundle ( My hair is 10 grams. The same applies below.) Leave on for 30 minutes, rinse with water, wash with shampoo, and dry i times. Then, use untreated black hair bundles as a control group. Be evaluated. The results are shown in Table 2. ◎ 1 is better than the control group. The same as the control group. △: Slightly worse than the control group. X: Poorer than the control group. • Color and brightness. Printed by the Consumer Cooperatives of the Central Standardization Bureau of the Ministry of Economic Affairs ... 1 nn — i-----mn · — ·--泸 (Please read the precautions on the back side before filling out this page

1T I-Black hair bundles were treated in the same manner as described above, and the latter was used as a control group. After being stored at 40 ° C for 3 months, the color brightness was evaluated based on the following criteria. The results are shown in Table 2. 〇: Same as the control group △: Slightly fading compared to the control group x: Fading slightly compared to the control group ______ _ 9-This paper rule (CNS) size 8 4 (210X297 cm) 505522 A7 B7 V. Invention Instructions (7) Printed by the Central Bureau of Standards, Ministry of Economic Affairs, Shelley Consumer Cooperatives Table 1 Ingredients by weight% Ammonia (2 8%) 6.0 Ethanol 15.0 Propylene Glycol 10.0 Oleic Acid 2.0 Diethanolamine Oleate 3.0 Polyoxyethylene (20) Octyl Lauryl 眯 12.0 ammonium chloride amount of purified water new balance total 100.0 (Please read the precautions on the back before filling this page ΙΦ

-1T -10- This paper size applies to China National Standard (CNS) 6-4 specifications (210 X 297 KRW) 505522 Printed by the Bayer Consumer Cooperative of the Central Bureau of the Ministry of Economic Affairs

Examples Comparative Examples 1 2 3 4 1 2 3 4 Stearyltrimethylammonium chloride 3.0 2.0 4.0 one-to-one 3.0 4.0 distearyldifluorenyl ammonium chloride 1.0 1,0 1.0 one-to-one 1.0 1.0 chloride 2. · Octyllauryltrimethylammonium—1.0—4.0 ———. Dimethyldipropylammonium monochloride ———— Q.5—Ammonium alkane sulfate —; — 1.5 1 — Hydrogen peroxide (3 5%) 17.0 17.0 17.0 17.0 17.0 17.0 17.0 17'0 8-Jingji Jun # 0.1 0.1 0.1 0.1 One 0.1 One — Ethanol 1.5 — 2.0 1.5 2.0 0.5 — — Vaseline 0.5 0.5 0.5 0.5 One — 0.5 0.5 Amino Modified S3 (SMS702C manufactured by Dow Corning) 1.5 — — 1.5 — 111 — Propanediol 5.0 5.0 5.0 5.0 — · 5.0 5.0 5.0 Methyl parahydroxybenzoate — — 0.1 — 0.1 — Monophosphate # Proper amount # right amount * right amount * right amount * right amount 'right amount * right amount # purified water remaining amount remaining amount remaining amount remaining amount remaining amount remaining amount remaining amount 樜 smoothness ◎ 〇 △ △ △ Δ 〇 dry state ◎ ○ ◎ 〇XX Δ Δ Softness ◎ 〇 ◎ XXXX Luminosity 0 〇〇〇〇X △ △ △ Color brightness 〇〇〇〇Δ Δ XX A7 B7 V. Description of the invention (8) Table 2 *: Adjust the pH to the amount of 3.5 -11-this paper & Dimensions are applicable to Chinese National Standards (CNS) Λ4 specifications (210X 297 ^^) (Please read the note on the back side ** before filling out this page)

505522 A7 B7 5. Description of the invention (9 males: Table 3) and the second agent (Table 4), apply to about 2 hairs and moisturize, and then dry. Can be stained with bright color, and :: military washing is also excellent in consistency. ≪ Table 3 Ingredients Toluene-; 2,5-diamine m-phenol phenol ammonia (28%) ethanol malonate oleic acid oleic acid diethyl alcohol amine polyoxyethylene (20) octyl lauryl ether chloride Ammonium chloride weight% 0.5 0.5 6.0 15.0 10.0 2.0 3.0 12.0 Appropriate amount printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

Remaining amount ----- 100.0 -12- This paper size applies to Chinese National Standard (CNS) Λ4 gauge (210 X 297 ^ 505522 A7 B7 V. Description of the invention (1〇) Example 6 Table 4 Ingredient weight Q / 〇 Gasification of 2-octyl danyl trimethylammonium 4.0 Hydrogen peroxide (35%) 17.0 8-Pycnogenol 0.1 Ethanol 1.5 Vaseline 0.5 Amino modified silicone 1.5 (SM8702C manufactured by Dow Corning Corporation) Propylene glycol 5.0 _酸 proper 量 # Purified water remaining | Total 100.0 * ·· Adjust the pH to 3.5 (please read the precautions on the back before filling this page) _ 衣

iT The Central Bureau of Standards, Ministry of Economic Affairs, Shellfish Consumer Cooperatives, India. Add cationic surfactants and high-carbon alcohols to glycerol before heating it to 7 (TC to dissolve it, and heat phosphoric acid and water to 70%): Dissolve, and then add the above dissolved matter. After stirring for 30 minutes, continue to stir and cool the temperature to 40 ° C, and then add the remaining ingredients to prepare the single-agent decoloring composition shown in Table 5. The ΙΨ -13 This paper size applies to the Chinese National Standard (CNS) Λ4 specification (210X 297 Gong 505522 A7 B7 ~------------ V. Description of the invention (11) Table 5 Ingredient weight% Stearyl trimethylammonium chloride Distearyldimethylammonium chloride Ethyl glycerol p-hydroxybenzoate methyl hydrogen peroxide (35%) 8-hydroxyquinoline phosphate purified water 3.0 ί · 0 1.5 10.0 0.1 7.5 Appropriate amount + 0.1 Remaining amount totals 100,0 * · Adjust the pH to 3 · 5 (please read the precautions on the back before filling in this page) Wash the black hair with shampoo (Japanese hair 10g ) 'After drying with a towel, apply 10 g of the above composition and leave it at 3 (rc for 5 minutes') It was then washed with water and dried once. The procedure was repeated 5 times, and the combability of the hair was good, not dry, and quite soft. Printed by the Consumers Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs ^ _3: Utilization The oxidant composition for dyeing and decoloring the hair of the present invention has very little damage to the hair. It can produce a good moisturizing effect on the hair when applying this substance and after applying this substance, and has very little dyeing effect and decoloring effect. Decrease over time and time. -14- This paper size applies Chinese National Standard (CNS) Λ 4% grid (210X29? Public)

Claims (1)

505522 AB c D Patent Application No. 87117776 Chinese Application for Amendment to Patent Scope (March 91) Acupoint, Shenqing Patent Fanyuan1 · An oxidant composition for hair dyeing and decoloring, which is characterized by containing the following ingredients⑻ ~ (C): (a) A linear or branched alkyl cationic surfactant with a weight of 0. 1 to 10, and (b) 0.00 5 to 5 weight. 8-hydroxyquinoline, and (c) 0.5 to 10% by weight of hydrogen peroxide. 2. The composition according to item 1 of the patent application scope, which further comprises ⑻ high carbon number alcohols. 3. The composition according to item 1 or 2 of the scope of patent application, which further comprises fluorene-based modified mash. 4. The composition according to item 1 of the scope of the patent application, which comprises 0.3 to 8% by weight of component ⑻, 0.02 to 0.1% by weight of component ⑸, and 10 to 80% by weight of component (C). 5 · The composition according to item 2 of the patent application scope, which comprises an ingredient of 0 to 10 wt%, an ingredient of 0.005 to 5 wt%, and an ingredient of 0.5 to 10 wt% (c) And 0.1 to 20% by weight of the ingredient (d). 6. The composition according to item 3 of the scope of patent application, which comprises the component ⑻1 to 10% by weight, the component 〇05 to 5% by weight, and 0.5 to 10% by weight. (C), and 5% to 5% by weight of ⑹. 7. The composition according to item 丨 of the scope of patent application, which is combined with a composition containing a basic agent, or a composition containing a basic agent, a dye precursor, and a coupler. This paper size applies to China National Standard (CNS) A4 (210X297 mm)