TW509578B - Oxidizing agent composition for hair - Google Patents

Abstract

To obtain the subject composition which shows excellent conditioning effect on hair with extremely reduced hair damage, as well as very low occurrence of reddening after discolorization; this composition is obtained by mixing (A) a straight or branched chain alkyl-type cationic surfactant, (B) an alcohol of higher carbon numbers, (C) an amino-modified silicone, and (D) hydrogen peroxide.

Description

509578 Printed by A7 __________ Bl_____ Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention (1) Field of the invention The present invention relates to an oxidant composition for dyeing and decoloring hair, which causes minimal damage to the hair. When applying this substance and after applying this substance, it can produce a good moisturizing effect on the hair, and it can suppress the phenomenon of discoloration after dyeing the hair, and it can also suppress the phenomenon of redness when it passes at any time after decolorization. Guliao background The two-part hair dye and decolorant for hair are composed of the i-th agent containing an alkaline agent and the second agent containing an oxidizing agent. In order to enhance the decoloring effect ', a three-component formula containing a third activator also exists. However, 'every time after treating the hair with such agents, the hair will lose its softness.' The hair is dry and no longer moist, shiny, and soft, and it will not be easy to comb. ' Shortcomings. In order to solve these disadvantages, the proposed solutions include: a method of receiving a specific fourth ammonium compound in the second agent (Japanese Patent Gazette No. 52-96749), and a method of incorporating a cationic polymer Methods (Japanese Patent Gazette No. 54-49340), and methods for incorporating silicon fluorene derivatives (Japanese Patent Gazette No. 61-55887), etc., but the results of the above methods are not sufficient, so There is still a need for a composition that causes minimal damage to the hair and produces a good nourishing effect.疋 The object of the present invention is to provide an oxidant composition for hair dyeing and decoloring, which does not have the aforementioned disadvantages, and can produce a good moisturizing effect on hair. -4-The size of this paper is applicable to Chinese national standards. $ Λ4 specification (210x297 ^ 了 '(Please read the precautions on the back before-this page) --- Order-I 1—e _____ ·-, 1 ii 509578 A7 B7 5. Description of the invention (2 The inventors of the present invention have discovered that by mixing hydrogen peroxide with a cationic surfactant, a high number of alcohols, and an amine-modified silicone, the above-mentioned purpose can be achieved. In addition, the use of the composition rarely causes discoloration after hair dyeing, and rarely occurs redness after decolorization, thereby completing the present invention. That is, the present invention provides an oxidant composition for hair coloring and taxation, It is characterized by containing the following ingredients ⑻ ~ ⑻: ⑻Straight-chain or branched-chain entertainment》 based cationic surfactants, (b) high carbon number alcohols, amine-based modified silicon snapper, (d) Hydrogen oxide. For the best form for carrying out the invention, for example, the linear or branched alkyl cationic surfactant as the component ⑻ may be a single hydrazone type fourth ammonium salt represented by the general formula ⑴ : R1 (Please read the precautions on the back before ^ Γ this page) Clothing.: 5 ^? Ben, 11 R-N-R3 R4

X (1)

Printed by the Central Standards Bureau of the Ministry of Economic Affairs, Consumer Cooperatives [where R1 is a straight or branched alkyl group of 8 to 36, which can be replaced by a ritual base, R2, R3 and R4 may be the same or different. It represents an alkyl group or benzyl group having 1 to 3 carbon atoms which can be substituted by a hydroxyl group, and X represents a prime or an alkyl sulfate group having 1 or 2 carbon atoms. ], Or the fourth remaining salt of the basic formula of the second formula: -5- Applicable to the Chinese National Standard (CNS) / \ 4 Regulations (210X297 Public Therapy 509578 A7 B7 3) 5. Description of the invention (R5 · R —N-^ — R7

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[In the formula, the meaning of X is the same as the foregoing, R5 and long $ may be the same or different, it means a straight or branched alkyl group having 8 to 36 carbons which may be substituted by a hydroxyl group, and R7 and y may be The same or different, represents an alkyl group having 1 to 3 carbon atoms which can be substituted by a hydroxyl group. ;1 . For example, the monoalkyl-type fourth ammonium salt may be vaporized stearyl trimethylammonium, 2-octyllauryltrimethylammonium chloride, and the like. For example, the dialkyl type fourth ammonium salt may be a vaporized distearyldimethylammonium or the like. These ingredients can be used alone or in combination of two or more. In order to fully obtain the effect of the present invention and to prevent hair from feeling sticky, it is preferably blended in the composition of the present invention in an amount of 0 to 10 weight. % (Hereinafter only abbreviated as 0 / 〇) component ⑻ '. Blending 〇1 ~ 8% is particularly preferred. For example, g, the high carbon number alcohol as the component ⑹ can be a straight or branched chain aliphatic alcohol having a carbon number of 10 to 24, of which cetyl alcohol (cetyiaic〇li〇i) Central Bureau of Standards, Ministry of Economic Affairs Printed by Employee Consumer Cooperatives (2)

X, among which cetanol, stearyl alcohol, cetyl stearyl alcohol and oleyl alcohol are preferred. These wounds (b) can be used alone or in combination of two or more. In order to fully obtain the effects of the present invention, and to prevent hair from feeling sticky, and to prevent tangles and irregularities during washing, it is preferably the present invention. The composition is blended with an ingredient of 0 to 20%, and an amount of 0 to 10% is particularly preferred. For example, the amine-modified silicone as the ingredient ⑹ can be expressed as the following -6 The paper size applies the Chinese National Standard (CNS) Λ4 specification (210χ294 > Ι 509578 A7 B7 V. Description of the invention (4 General formula (3) R ^ 2 ch3 -Si ~ 〇CHq R9 -Si-

R 10 n • R9 (3) Printed by Bei Gongxiao Cooperative of the Central Bureau of Standards, Ministry of Economic Affairs [where R9 can be the same or different, and represents a hydrogen atom, a hydroxyl group, a methyl group or a methoxy group, and R1G represents: .- ( 〇Η2) 〇- (0〇2Η4) ρ- (〇 ^ 3Η6) α-ΝΗ〇2Η4-Ν (ί < 11) 2 or-(CHOaoc ^ VCOC ^ Hdq'NHC ^ mRnh · Z ·, (R may be the same or "Different" means wind atom, hydrocarbon group with number of 1 ~ 6, Z system means halogen ion or organic anion, 0 means number from 1 ~ 6, and p and q means number from 0 ~ 6), m system Represents a number from 3 to 300, and η represents a number from 1 to 50.]. In the general formula (3), R9 is preferably a aryl group and a methyl group, and r10 is preferably-< CH2) 3-NHC2H4- NH2, and n is preferably 1 to 20. The above-mentioned ingredient (c) can be used alone or in combination of two or more. In order to fully obtain the effect of the present invention and to prevent the hair from feeling sticky, it is preferably blended in the composition of the present invention. 15% of the ingredients, and blending 1.0 ~ 8.0% are particularly good. In terms of dyeing and decoloring effects, and in terms of irritation to the scalp, it is preferred that the composition of the present invention is blended with 0.5 to 5% of the hydrazone component hydrogen peroxide 'and 1.0 to & 〇% are the best. In the composition of the present invention, in addition to the above essential ingredients, other ingredients used in common cosmetics can also be added as needed, such as emulsified M / combined clams, tackifiers, stabilizers, hair styling Bases, spices, etc. The paper size is suitable for household items (210X 297 ^^ (Please read the precautions on the back first ... ...... ...... .........- n: items on this page)

Printed by the Central Bureau of Standards of the Ministry of Economic Affairs and Cooperatives 509578 A 7 -----_ B7 V. Description of Invention (5). In addition, 3F can be compounded with silicone derivatives other than the component (c), such as cyclic siloxane, polyether modified ketone, and burn-based modified ketone, to further improve the touch. The oxidant composition of this month is preferably adjusted to 2 ~ 6, and more preferably 3 ~ 5. The oxidant composition of the present invention can be produced according to a common method, and its form is not particularly limited. For example, it can be made into a transparent liquid, emulsion, cream, gel, paste, spray, spray foam. Like 2. When using the oxidant composition of the present invention to treat hair, it can be settled in a single-dose type. For example, the oxidant composition of the present invention can be applied to the head friend after shampooing, and then applied for 3 to 5 minutes. Washing is enough; in the case of the two-dose formula, for example, the oxidizing agent composition (No. ㈣) of the present invention and a composition containing an alkaline agent, or an alkaline agent, a dye precursor and color formation Mix (coupier) composition (first agent), apply this mixture to the hair, leave it for 3 to 5 minutes, and then rinse it. In addition, the hair treatment agent of the present invention is generally preferably applied at 15 to 40 τ. Examples Examples 1 to 3 and Comparative Examples 1 to 4 were prepared as the second agent shown in Table 1 and the second agent shown in Table 2, and evaluated their performance. (Manufacturing method) The comparative example among the i agent and the second agent was manufactured by a conventional method]. Otherwise, it is prepared by the following method: firstly add cationic surfactant, high carbon number alcohol and petroleum jelly to propylene glycol, and then heat it to -8 ~ 1 paper size Chinese National Standard (CNS) Λ4 specification (210χ 297: Γ >] ΓΪ ~~~~-(Please read the precautions on the back before filling this page)

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509578 A7 B7 Printed by the Central Standards Bureau of the Ministry of Economic Affairs, Bei Gong Xiao Co., Ltd. Fifth, the description of the invention (6 to dissolve, in addition, the phosphoric acid and water are heated to 7 (TC to dissolve, and then the above dissolved matter is added to it. Then stir 3 〇minutes, continue to stir the inflammation, cool the temperature to 40 ° C, and then add the remaining ingredients. (Evaluation method> ♦ Comb smoothness, dry state, softness and gloss will be the first agent (Table 1) and Mix 2 doses (tables), apply 10 grams of it to black hair bundles (say 10 grams of my hair. The following is also Xiao), leave it for 30 minutes. Rinse with water, then wash with shampoo and dry} times After that, untreated black hair bundles were used as a control group, and evaluated according to the following criteria. The results are shown in Table 2. :: Better than the control group... Same as the control group. △: Compared with the control group. Slightly worse in the group X: worse than the control group. • The redness at any time after depigmentation. Mix 8 grams of the first agent (Table 1) with the second agent (Table 2). And leave it on for 30 minutes. Wash the item with water :, and then repeat the washing with commercially available shampoo And drying process 4 times, Pan Cong only compared with shampoo washing and drying "quote, and evaluated on the basis of the following. Flat 0: the same as immediately after decoloring X · · slightly after decoloring Red 9- This paper size applies to China National Standard Feng (CNtS) six 4 square grid (21〇, χ297 male stone-(Please read the precautions on the back before ^ Γ this page)

1T 509578 A7 B7 V. Description of the invention (7) Printed by the Consumer Cooperatives of the Central Bureau of Standards, Ministry of Economic Affairs, Table 1 Ingredient weight% Ammonia (28%) 6.0 Ethanol 15.0 Propylene glycol 10.0 Oleic acid 2.0 Diethanolamine oleate 3.0 Polyoxygen Ethyl (20) octyl lauryl ether 12.0 Ammonium chloride Appropriate amount of purified water Remaining total 100.0 (Please read the precautions on the back first, then «I!-Item on this page

-10- This paper size applies to Chinese National Standards (CNS) / Yingge (210X 297 Gong) 509578 A7 B7 V. Description of Invention (8) Table 2 Comparison of Printing Examples of the Shellfish Consumer Cooperative of the Central Bureau of Standards, Ministry of Economic Affairs Example 1 2 3 1. 2 3 4 Stearyltrimethylammonium chloride 3.0 3.0. Mono-3.0 3.0 — Gasified distearyldimethylammonium 1.0 — 1 — 1.0 — 2-octyl lauryl monochloride Trimethylammonium-2.0 4.0 --- 2.0 4.0 Alkyl ammonium sulfate '----1.5--hydrogen peroxide (35%) 17.0 17.0 17.0 17.0 17.0 17.0 17.0 ethanol 1.5-1.0 2.0--stearyl alcohol — 2.0 1.0 — 2.0 1.0 Vaseline 0.5 0.5 0.5 — 0.5 0.5 0.5 Amine-modified silicone (SM8702C manufactured by Dow Corning) 1.5 1.5 1.5 — 1.5 — — Propanediol 5.0 5.0 5.0 — 5.0 — 5.0 Paraben Ester 1 — 0.1 1 — — Phosphoric acid amount *: Right amount, right amount * Right amount 'Right amount · Right amount' Right amount · Purified water remaining amount 轲 Remaining amount remaining amount remaining amount remaining amount remaining amount combing degree ◎ ◎ '© △ 〇 △ △ Dry state 〇 © ◎ X △ 〇X Softness ◎ © X △ 〇 △ Luminosity: 〇 ◎ 〇X Δ 〇X After the decolorization, it will turn red at any time. 〇〇XXXX *: Adjust the pH to 3.5. -This paper size applies to Chinese National Standard Lithium (CNS) Λ4 specification (210X 297). 509578 Printed by the Consumers' Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs. A7 _______ B7 Invention Description (9) Missing the same amount of the first agent (Table 3) and the second agent (Table 4), coated on about 2 grams of goat wool, left at 30 分钟 for 30 minutes, washed, shampooed and conditioned, and then dried. Placed at 4 ° C, 75% RH for 2 weeks, but found to be generally smooth, not in a dry state, and almost no discoloration. Table 3 Ingredient weight% toluene-2,5-diamine 0.5 m-aminophenol 0.5 Ammonia (28%) 6.0 Ethanol 15.0 Propylene glycol 10.0 Oleic acid 2.0 Diethanolamine oleate 3.0 Polyoxyethylammonium (20) octyl lauryl ether 12.0 Ammonium chloride Appropriate amount of purified water remaining total loo.o (read first read Note on the back again ^ Γ This page

、 1T -12- This paper size is applicable to Chinese National Standard (CNS) Λ4 specification (210X 297 gong) 509578 A7 ----- B7 V. Description of the invention (1 ()) Table 4 Ingredient weight% Gasification 2 -Octyl lauryl trimethylammonium 4.0 Hydrogen peroxide (35%) 17.0 Ethanol.α < Stearyl alcohol 1.0 Vaseline 0.5 Amino modified mash 1.5 (SM8702C manufactured by Toho Corning) Propanediol 5.0 Phosphoric acid amount # The total amount of purified water is 100.0 *: Adjust the pH to 3.5 depletion (please read the precautions on the back first, then __ this page)

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The staff of the Central Bureau of Standards of the Ministry of Economic Affairs, the Co-operative Society, printed a cationic surfactant and a high-carbon alcohol before glycerin, heated it to 70 ° C to dissolve it, and heated phosphoric acid and water to 70 ° C. Dissolve 'and then add the above-mentioned solute. After stirring for 30 minutes, stirring was continued and the temperature was cooled to 40 ° C. (:, Then add the remaining ingredients to prepare the single-agent decoloring composition shown in Table 5. __, -13 · This paper size is applicable to the Chinese national standard (CNS) Λ4 grid (210X 297) 509578 A7 B7 printed by the Shellfish Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy of the People's Republic of China Description of the invention (η) Table 5 Composition. Wt% Stearyl trimethylammonium chloride 3.0 Distearyldimethylammonium chloride 1.0 Ethanol 1.5 Amine Modified Silicone 1.5 (SM8702C manufactured by Dow Corning) glycerol 10.0 methyl parahydroxybenzoate 0.1 hydrogen peroxide (35%) 7.5 appropriate amount of phosphoric acid * total remaining amount of purified water 100.0 *: adjust pH 値 to 3.5 The amount of hair was washed with shampoo (10 g of my hair) and dried with a towel. Then, 10 g of the above composition was applied, left at 30 ° C for 5 minutes, and then washed with water and applied. Dry once. Repeat this procedure 5 times, and the combing of the hair is good, not in a dry state, and quite soft. Industrial Applicability The oxidant composition for dyeing and decoloring the hair of the present invention causes the hair The damage is minimal. When using this substance and after applying this substance, it can have a good moisturizing effect on the hair, and it will rarely fade after dyeing, and it will rarely turn red after passing by. -14 ~ This paper size Applicable to Chinese National Standard (CNS) Λ4 ^ grid (210X 297 films)

Claims (1)

509578 Patent No. 87117779 g Chinese Patent Application Amendment 6. Scope of patent application Public mouth ii An oxidant composition for hair dyeing and decoloring, which is characterized by containing the following ingredients ⑻ ~ ⑹: 直 The linear or branched chain represented by the following formula (1) or formula (2) Alkyl-type cationic surfactant 0 · 1-10 ％ by weight: R ^ N—R3 R4 X ⑴ [wherein R1 represents a linear or branched alkane having 8 to 36 carbon atoms which can be substituted by a hydroxyl group Group, R2, "can be the same as or different from rule 4, is an alkyl or benzyl group having 1 to 3 carbon atoms which can be substituted by a hydroxyl group, and X represents a prime atom or a carbon number of 1 or 2垸 sulfate group.], R5 R ^ -N—R7 R8 X (2) [wherein the meaning of X is the same as the above, rS and trans S may be the same or different, and it represents a carbon that may be substituted by a light group. A straight or branched alkyl group having a number of 8 to%, and ... and! ^ May be the same or different, and represents an alkyl group having 1 to 3 carbon atoms which can be substituted by several groups.]; ⑹ carbon number 1〇 -24-chain linear or branched aliphatic alcohols 0.1 to 20% by weight ·, amine-modified silicone represented by the following formula (3) 0 · 1-1 5% by weight: CH3I -Si—οI CFh R9 -Si- R 10 -R9 (3) [wherein R9 may be the same or different and represents a hydrogen atom, a hydroxyl group, a methyl group 509578 A8 B8 C8 ___ — _ D8 6. Scope of patent application 1 " ~~. Or methoxy, R1G series means:-(CH2) 0- (OC2H4) p- (OC3H6) q.NHC2H4-N (R11) 2 or (CH2) 0- (〇C2H4) p- (〇C3H6) q-NHC2H4-N + (Rli) 3 · 2Γ, (R11 may be the same or different, which means a hydrogen atom and a carbon number of 1 to 6 Hydrocarbon group, Z system means # element ion or organic anion, 0 system means number of i ~ 6, and p and q system means number of 0 ~ 6), ^ system means number of 3 ~ 300, and η system means 1 ~ 50 number. ]; (D) Hydrogen peroxide 0.5-10% by weight. 2. The composition according to item 丨 of the scope of application for a patent, which comprises an ingredient of 0 to 8 wt%, an ingredient of 0.5 to 10 wt%, and an ingredient of i to 80 wt% (c) , And 1.0 ~ 8.0% by weight of the ingredients ⑹. 3. The composition according to item 丨 or 2 of the scope of patent application, which is used in combination with a composition containing each alkaline agent, or a composition containing a test agent, a dyestuff precursor, and a coupler By. -2- This paper size applies to China National Standard (CNS) A4 (210X297 mm) '—-