TW509578B - Oxidizing agent composition for hair - Google Patents

Oxidizing agent composition for hair Download PDF

Info

Publication number
TW509578B
TW509578B TW87117779A TW87117779A TW509578B TW 509578 B TW509578 B TW 509578B TW 87117779 A TW87117779 A TW 87117779A TW 87117779 A TW87117779 A TW 87117779A TW 509578 B TW509578 B TW 509578B
Authority
TW
Taiwan
Prior art keywords
group
hair
same
composition
weight
Prior art date
Application number
TW87117779A
Other languages
Chinese (zh)
Inventor
Kenichi Matsunaga
Original Assignee
Kao Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kao Corp filed Critical Kao Corp
Application granted granted Critical
Publication of TW509578B publication Critical patent/TW509578B/en

Links

Landscapes

  • Cosmetics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

To obtain the subject composition which shows excellent conditioning effect on hair with extremely reduced hair damage, as well as very low occurrence of reddening after discolorization; this composition is obtained by mixing (A) a straight or branched chain alkyl-type cationic surfactant, (B) an alcohol of higher carbon numbers, (C) an amino-modified silicone, and (D) hydrogen peroxide.

Description

509578 經濟部中央標隼局貝工消f合作社印製 A7 __________ Bl_____ 五、發明説明(1 ) 基愈領域 本發明係關於一種毛髮之染色及脱色用氧化劑组合物, 其對毛髮所造成的損害極小,於施用此物時及施用此物後 可對毛髮產生良妤的滋潤效果,龙且可抑制於染髮後發生 掉色的情形、亦可抑制於脱色後隨時s經過而冉現轉紅的 現象。 鼓遼背景 兩劑式之染髮劑與毛髮用脱色劑係由包含鹼性劑之第i 劑、及包含氧化劑之第2劑所組成。另外,爲增強脱色效 果’亦存在有包含第3劑活化劑之三劑式物。 然而’凡以此等藥劑處理毛髮後,會使毛髮失去柔潤性 ’毛髮呈乾燥狀態,且不再濕潤、具光澤、和柔款,而變 得不易梳順’上逑爲彼等藥劑所具有的缺點。 爲解決此等缺點,而經提出之解決方法有:於第2劑中 接進特定之第四銨化合物的方法(日本專利公報特開昭第 52-96749號)、摻進陽離子類聚合物的方法(日本專利公 報特開昭第54-49340號)、和摻進矽嗣衍生物的方法(日 本專利公報特開昭第61-55887號)等,可是上述方法之致 果並不充分,因此仍需要一種對毛髮所造成的損害極小、 且可產生良好滋滴效果之組合物。 疋以’本發明之目的係提供一種毛髮之染色及脱色用氧 化劑組合物,其不具有前述之缺點,並且可對毛髮產生良 好的滋潤效杲。 -4 - 本紙張尺度適用中國國家榡準 $ ) Λ4規格(210x297^了 ' (請先閲讀背面之注意事項再 — 本頁) ---訂 -I 1—e_____·- , 1 i i 509578 A7 B7 五、發明説明(2 本發明之發明人等發現,藉由將過氧化氫與陽離子性界 面活性劑、高竣數醇類、及胺基改質矽酮共同混合,即可 達成上逑目的,而且使用該組合物,於染髮後極少發生掉 色妗情形、於脱色後亦極少出現轉紅的現象,而完成本發 明。 亦即,本發明係提供一種毛髮之染色及税色用氧化劑組 合物,其特徵在於包含以下之成份⑻〜⑻: ⑻直鏈或支鏈之娱》基型陽離子性界面活性劑、 (b)高碳數醇類、 ⑹胺基改質矽鲷,友 (d)過氧化氫。 用以實施發明之最佳型態 舉例而言,作爲成份⑻之直鏈或支鏈之烷基型陽離子性 界面活性劑可爲表成一般式⑴之單垸基型第四铵鹽: R1 (請先閲讀背面之注意事項再^Γ本頁) 衣. :5^?本 、11 R-N-R3 R4509578 Printed by A7 __________ Bl_____ Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention (1) Field of the invention The present invention relates to an oxidant composition for dyeing and decoloring hair, which causes minimal damage to the hair. When applying this substance and after applying this substance, it can produce a good moisturizing effect on the hair, and it can suppress the phenomenon of discoloration after dyeing the hair, and it can also suppress the phenomenon of redness when it passes at any time after decolorization. Guliao background The two-part hair dye and decolorant for hair are composed of the i-th agent containing an alkaline agent and the second agent containing an oxidizing agent. In order to enhance the decoloring effect ', a three-component formula containing a third activator also exists. However, 'every time after treating the hair with such agents, the hair will lose its softness.' The hair is dry and no longer moist, shiny, and soft, and it will not be easy to comb. ' Shortcomings. In order to solve these disadvantages, the proposed solutions include: a method of receiving a specific fourth ammonium compound in the second agent (Japanese Patent Gazette No. 52-96749), and a method of incorporating a cationic polymer Methods (Japanese Patent Gazette No. 54-49340), and methods for incorporating silicon fluorene derivatives (Japanese Patent Gazette No. 61-55887), etc., but the results of the above methods are not sufficient, so There is still a need for a composition that causes minimal damage to the hair and produces a good nourishing effect.疋 The object of the present invention is to provide an oxidant composition for hair dyeing and decoloring, which does not have the aforementioned disadvantages, and can produce a good moisturizing effect on hair. -4-The size of this paper is applicable to Chinese national standards. $ Λ4 specification (210x297 ^ 了 '(Please read the precautions on the back before-this page) --- Order-I 1—e _____ ·-, 1 ii 509578 A7 B7 5. Description of the invention (2 The inventors of the present invention have discovered that by mixing hydrogen peroxide with a cationic surfactant, a high number of alcohols, and an amine-modified silicone, the above-mentioned purpose can be achieved. In addition, the use of the composition rarely causes discoloration after hair dyeing, and rarely occurs redness after decolorization, thereby completing the present invention. That is, the present invention provides an oxidant composition for hair coloring and taxation, It is characterized by containing the following ingredients ⑻ ~ ⑻: ⑻Straight-chain or branched-chain entertainment》 based cationic surfactants, (b) high carbon number alcohols, amine-based modified silicon snapper, (d) Hydrogen oxide. For the best form for carrying out the invention, for example, the linear or branched alkyl cationic surfactant as the component ⑻ may be a single hydrazone type fourth ammonium salt represented by the general formula ⑴ : R1 (Please read the precautions on the back before ^ Γ this page) Clothing.: 5 ^? Ben, 11 R-N-R3 R4

X (1)X (1)

經濟部中央標擎局負工消费合作社印裝 [式中R1係表示可經禮基取代之後數爲8〜36之直鏈或支 鏈之烷基、R2、R3與R4可相同或不同,係表示可經羥基取 代之碳數爲1〜3之烷基或苯甲基,而X係表示_素原手或 是碳數爲1或2之烷硫酸基。], 或是表成一般式⑵之二燒基型第四餘鹽: -5- 適用中國國家標準(CNS ) /\4規掐(210X297公疗 509578 A7 B7 3 五、發明説明( R5 · R—N-^—R7Printed by the Central Standards Bureau of the Ministry of Economic Affairs, Consumer Cooperatives [where R1 is a straight or branched alkyl group of 8 to 36, which can be replaced by a ritual base, R2, R3 and R4 may be the same or different. It represents an alkyl group or benzyl group having 1 to 3 carbon atoms which can be substituted by a hydroxyl group, and X represents a prime or an alkyl sulfate group having 1 or 2 carbon atoms. ], Or the fourth remaining salt of the basic formula of the second formula: -5- Applicable to the Chinese National Standard (CNS) / \ 4 Regulations (210X297 Public Therapy 509578 A7 B7 3) 5. Description of the invention (R5 · R —N-^ — R7

iBiB

[式中X所表示之意義係與前述相同、R5與长$可相同或不 同,係表示可經羥基取代之碳數爲8〜36之直鏈或支鏈之 烷基,而R7與y可相同或不同,係表示可經羥基取代之碳 數爲1〜3之烷基。;1 。 ,例而言,單烷基型第四銨鹽可爲氣化硬脂基三甲基銨 、氯化2-辛基月桂基三甲基銨等物。 舉例而言,二烷基型第四銨鹽可爲氣化二硬脂基二甲基 銨等物。 此等成份⑻可單獨使用或將兩種以上組合使用,爲充分 獲致本發明之效果,以及爲防止毛髮產生黏腻感,較佳係 於本發明之組合物中摻合〇1〜1〇重量%之(以下僅略示爲 0/〇 )成份⑻’而.摻合〇 1〜8 %係尤佳者。 舉例而g,作爲成份⑹之高碳數醇類可爲碳數爲1〇〜24 之直鏈或支鏈之脂肪族醇類,其中鯨蠟醇(cetyiaic〇li〇i) 經濟部中央標準局员工消费合作社印製 (2)[In the formula, the meaning of X is the same as the foregoing, R5 and long $ may be the same or different, it means a straight or branched alkyl group having 8 to 36 carbons which may be substituted by a hydroxyl group, and R7 and y may be The same or different, represents an alkyl group having 1 to 3 carbon atoms which can be substituted by a hydroxyl group. ;1 . For example, the monoalkyl-type fourth ammonium salt may be vaporized stearyl trimethylammonium, 2-octyllauryltrimethylammonium chloride, and the like. For example, the dialkyl type fourth ammonium salt may be a vaporized distearyldimethylammonium or the like. These ingredients can be used alone or in combination of two or more. In order to fully obtain the effect of the present invention and to prevent hair from feeling sticky, it is preferably blended in the composition of the present invention in an amount of 0 to 10 weight. % (Hereinafter only abbreviated as 0 / 〇) component ⑻ '. Blending 〇1 ~ 8% is particularly preferred. For example, g, the high carbon number alcohol as the component ⑹ can be a straight or branched chain aliphatic alcohol having a carbon number of 10 to 24, of which cetyl alcohol (cetyiaic〇li〇i) Central Bureau of Standards, Ministry of Economic Affairs Printed by Employee Consumer Cooperatives (2)

X 、其中鯨蠟醇(cetanol)、硬脂醇、鯨蠟基硬脂基醇以及 油醇係較佳者。 此等成伤(b)可早獨使用或將兩種以上组合使用,爲充分 獲致本發明之效果,以及爲防止毛髮產生黏€感、並防止 於清洗時糾結不順,較佳係於本發明之組合物中摻合〇1〜 20%之成份⑸,而摻合0 5〜1〇%係尤佳者。 舉例而言,作爲成份⑹之胺基改質矽酮可爲表成以下之 -6 本纸張尺度適用中國國家標準(CNS ) Λ4規格(210χ294>ΙΓ 509578 A7 B7 五、發明説明(4 一般式⑶者: R^2 ch3 -Si~〇 CHq R9 -Si-X, among which cetanol, stearyl alcohol, cetyl stearyl alcohol and oleyl alcohol are preferred. These wounds (b) can be used alone or in combination of two or more. In order to fully obtain the effects of the present invention, and to prevent hair from feeling sticky, and to prevent tangles and irregularities during washing, it is preferably the present invention. The composition is blended with an ingredient of 0 to 20%, and an amount of 0 to 10% is particularly preferred. For example, the amine-modified silicone as the ingredient ⑹ can be expressed as the following -6 The paper size applies the Chinese National Standard (CNS) Λ4 specification (210χ294 > Ι 509578 A7 B7 V. Description of the invention (4 General formula (3) R ^ 2 ch3 -Si ~ 〇CHq R9 -Si-

R 10 n •R9 (3) 經濟部中央標準局貝工消f合作社印製 [式中R9可相同或不同,係表示氫原子、羥基、甲基或甲 氧基、R1G係表示: .-(ΟΗ2)〇-(0〇2Η4)ρ-(〇^3Η6)α-ΝΗ〇2Η4-Ν(ί<11 )2 或-(CHOaoc^VCOC^Hdq'NHC^mRnh · Ζ·、 (R可相同或不同’係表示風原子、礙數爲1〜6之烴基 、Z係表示鹵素離子或是有機陰離子、〇係表示1〜6之數, 而p及q係表示〇〜6之數)、m係表示3〜300之數,而η係 表示1〜5 0之數。]。 於一般式⑶中,R9較佳爲幾基及甲基、r1〇較佳爲-<CH2)3-NHC2H4-NH2,而 n較佳爲 1 〜2〇。 上述之成份(c)可單獨使用或將兩種以上组合使用,爲充 分獲致本發明之效果,以及爲防止毛髮產生黏腻感,較佳 係於本發明之組合物中摻合〇·!〜15%之成份⑹,而摻合 1.0〜8.0%係尤隹者。 就染色·脱色效果而言、及就對頭皮之刺激性而言,較 佳係於本發明之組合物中摻合〇 5〜丨〇%之⑻成份過氧化氫 ’而摻合1.0〜&〇%係尤佳者。 於本發明之組合物中,除以上之必須成份之外,亦可因 應需要恭加使用於常用化粧品上之其他成份,例如乳化 Μ /合解化蜊、增黏劑、安定化劑、整髮基劑、香料等物 本纸張尺度適财目目家標 (210X 297^^ (請先閲讀背面之注意事項 —.........--..................- n : 項再本頁) 訂R 10 n • R9 (3) Printed by Bei Gongxiao Cooperative of the Central Bureau of Standards, Ministry of Economic Affairs [where R9 can be the same or different, and represents a hydrogen atom, a hydroxyl group, a methyl group or a methoxy group, and R1G represents: .- ( 〇Η2) 〇- (0〇2Η4) ρ- (〇 ^ 3Η6) α-ΝΗ〇2Η4-Ν (ί < 11) 2 or-(CHOaoc ^ VCOC ^ Hdq'NHC ^ mRnh · Z ·, (R may be the same or "Different" means wind atom, hydrocarbon group with number of 1 ~ 6, Z system means halogen ion or organic anion, 0 means number from 1 ~ 6, and p and q means number from 0 ~ 6), m system Represents a number from 3 to 300, and η represents a number from 1 to 50.]. In the general formula (3), R9 is preferably a aryl group and a methyl group, and r10 is preferably-< CH2) 3-NHC2H4- NH2, and n is preferably 1 to 20. The above-mentioned ingredient (c) can be used alone or in combination of two or more. In order to fully obtain the effect of the present invention and to prevent the hair from feeling sticky, it is preferably blended in the composition of the present invention. 15% of the ingredients, and blending 1.0 ~ 8.0% are particularly good. In terms of dyeing and decoloring effects, and in terms of irritation to the scalp, it is preferred that the composition of the present invention is blended with 0.5 to 5% of the hydrazone component hydrogen peroxide 'and 1.0 to & 〇% are the best. In the composition of the present invention, in addition to the above essential ingredients, other ingredients used in common cosmetics can also be added as needed, such as emulsified M / combined clams, tackifiers, stabilizers, hair styling Bases, spices, etc. The paper size is suitable for household items (210X 297 ^^ (Please read the precautions on the back first ... ...... ...... .........- n: items on this page)

經濟部中央標準局負工消f合作社印製 509578 A 7 —--—_ B7 五、發明説明(5 ) 。另外,3F可摻合成份(c)以外之矽酮衍生物,Μ如環狀矽 嗣、聚醚改質♦酮、燒基改質麥酮等物,藉此可進一步提 昇感觸性。 本發月之氧化劑组合物之値較佳係調爲2〜6 ,而調爲 3〜5係尤佳者。 本發明之氧化劑組合物可根據通常的方法製造,其形態 並毋而特別限制,舉例而言,可製成透明液狀、乳液狀、 乳霜狀、凝膠狀、糊狀、噴霧、噴霧泡沫狀等。 、當使用本發明之氧化劑組合物以處理毛髮時,於單劑式 之清沉了例如可於洗髮後將本發明之氧化劑组合物施用 於頭友上,田置3〜5分鐘後再加以洗淨即可;再者,於二 劑式之情況下,例如可將本發明之氧化劑組合物(第㈣ )與包含鹼性劑之組合物、或是包含鹼性劑、染料先質及 成色劑(coupier)之组合物(第1劑)混合,將此混合液 施用於頭髮上,留置3〜5分鐘後再加以沖去即可。另外, 本發明之毛髮處理劑通常較佳係適用於15〜4〇τ下。 實例 實例1〜3及比較例1〜4 調配製出示於表1之第丨劑及示於表2之第2劑,並評估 彼等之性能。 (製造方法) 以習知方法製造第i劑及第2劑中之比較例】。除此之外 者,係藉由下述之方法調配製成:先於丙二醇中加入陽離 子性界面活性劑、高碳數醇類及凡士林,再加熱至赃予 -8 ~ 一本纸張尺度適用中國國家標準(CNS ) Λ4規格(210Χ 297:Γ>]ΓΪ~~~ ~ -- (請先閲讀背面之注意事項再填寫本頁)Printed by the Central Bureau of Standards of the Ministry of Economic Affairs and Cooperatives 509578 A 7 -----_ B7 V. Description of Invention (5). In addition, 3F can be compounded with silicone derivatives other than the component (c), such as cyclic siloxane, polyether modified ketone, and burn-based modified ketone, to further improve the touch. The oxidant composition of this month is preferably adjusted to 2 ~ 6, and more preferably 3 ~ 5. The oxidant composition of the present invention can be produced according to a common method, and its form is not particularly limited. For example, it can be made into a transparent liquid, emulsion, cream, gel, paste, spray, spray foam. Like 2. When using the oxidant composition of the present invention to treat hair, it can be settled in a single-dose type. For example, the oxidant composition of the present invention can be applied to the head friend after shampooing, and then applied for 3 to 5 minutes. Washing is enough; in the case of the two-dose formula, for example, the oxidizing agent composition (No. ㈣) of the present invention and a composition containing an alkaline agent, or an alkaline agent, a dye precursor and color formation Mix (coupier) composition (first agent), apply this mixture to the hair, leave it for 3 to 5 minutes, and then rinse it. In addition, the hair treatment agent of the present invention is generally preferably applied at 15 to 40 τ. Examples Examples 1 to 3 and Comparative Examples 1 to 4 were prepared as the second agent shown in Table 1 and the second agent shown in Table 2, and evaluated their performance. (Manufacturing method) The comparative example among the i agent and the second agent was manufactured by a conventional method]. Otherwise, it is prepared by the following method: firstly add cationic surfactant, high carbon number alcohol and petroleum jelly to propylene glycol, and then heat it to -8 ~ 1 paper size Chinese National Standard (CNS) Λ4 specification (210χ 297: Γ >] ΓΪ ~~~~-(Please read the precautions on the back before filling this page)

、1T, 1T

509578 A7 B7 經濟部中央標準局貝工消f合作社印製 五、發明说明(6 以溶解,另外,將磷酸與水加熱至7(TC予以溶解,而後將 上述溶解物加入其中。之後攪摔3〇分鐘,持續攪拌炎將溫 度冷卻至40 C ’再加入剩餘之成份。 (評估方法〉 ♦梳順度、乾燥狀態、柔軟度及光潤度 將各8公克之第1劑(表1 )與第2劑(表么)混合,取其 10公克塗布於黑髮束(曰本人毛髮1〇公克。以下亦肖)上 ,放置30分鐘。以水沖洗,再以洗髮精洗淨、乾燥}次, 之後,使用未經處理之黑髮束作爲對照組,根據下述之基 準加以評估。其結杲係併示於表2。 ◎:較對照組佳 〇··與對照組相同 △:較對照组稍差 X :較對照組差 •脱色後隨時日經過之轉紅情形 將各8公克之第1劑(表1)與第2劑(表2)混合,取並 ㈣克塗布於黑髮束上,放置30分鐘。以水流清洗該物:、 再以市售之洗髮精重覆洗淨及乾燥之程序4次,盘聪 僅以洗髮精洗淨及乾燥"欠之物比較,而根據下述之基 加以評估。 平 Ο :與剛脱色後相同 X ··較剛脱色後稍呈紅色 9- 本纸張尺度適用中國國家標丰(CNtS )六4坭格(21〇、χ297公石- (請先閱讀背面之注意事項再^Γ本頁)509578 A7 B7 Printed by the Central Standards Bureau of the Ministry of Economic Affairs, Bei Gong Xiao Co., Ltd. Fifth, the description of the invention (6 to dissolve, in addition, the phosphoric acid and water are heated to 7 (TC to dissolve, and then the above dissolved matter is added to it. Then stir 3 〇minutes, continue to stir the inflammation, cool the temperature to 40 ° C, and then add the remaining ingredients. (Evaluation method> ♦ Comb smoothness, dry state, softness and gloss will be the first agent (Table 1) and Mix 2 doses (tables), apply 10 grams of it to black hair bundles (say 10 grams of my hair. The following is also Xiao), leave it for 30 minutes. Rinse with water, then wash with shampoo and dry} times After that, untreated black hair bundles were used as a control group, and evaluated according to the following criteria. The results are shown in Table 2. :: Better than the control group... Same as the control group. △: Compared with the control group. Slightly worse in the group X: worse than the control group. • The redness at any time after depigmentation. Mix 8 grams of the first agent (Table 1) with the second agent (Table 2). And leave it on for 30 minutes. Wash the item with water :, and then repeat the washing with commercially available shampoo And drying process 4 times, Pan Cong only compared with shampoo washing and drying "quote, and evaluated on the basis of the following. Flat 0: the same as immediately after decoloring X · · slightly after decoloring Red 9- This paper size applies to China National Standard Feng (CNtS) six 4 square grid (21〇, χ297 male stone-(Please read the precautions on the back before ^ Γ this page)

、1T 509578 A7 B7 五、發明説明(7 ) 經濟部中央標隼局員工消費合作社印製 表1 成份 重量% 氨(28%) 6.0 乙醇 15.0 丙二醇 10.0 油酸 2.0 油酸二乙醇醯胺 3.0 聚氧乙婦基(20)辛基月桂基醚 12.0 氯化銨 適量 純化水 剩餘量 總計 100.0 (請先閱讀背面之注意事項再 丨«I! -項再本頁1T 509578 A7 B7 V. Description of the invention (7) Printed by the Consumer Cooperatives of the Central Bureau of Standards, Ministry of Economic Affairs, Table 1 Ingredient weight% Ammonia (28%) 6.0 Ethanol 15.0 Propylene glycol 10.0 Oleic acid 2.0 Diethanolamine oleate 3.0 Polyoxygen Ethyl (20) octyl lauryl ether 12.0 Ammonium chloride Appropriate amount of purified water Remaining total 100.0 (Please read the precautions on the back first, then «I!-Item on this page

-10- 本纸張尺度適用中國國家標準(CNS ) /以坭格(210X 297公泠) 509578 A7 B7 五、發明説明(8 ) 表2 經濟部中央標攀局貝工消费合作社印製 實例 比較例 1 2 3 1 .2 3 4 氯化硬脂基三甲基銨 3.0 3.0 .一 — 3.0 3.0 — 氣化二硬脂基二甲基銨 1.0 一 一 — 1.0 — 一 氯化2 -辛基月桂基三甲基銨 一 2.0 4.0 一 — 2.0 4.0 烷硫酸銨 '— -- 一 1.5 一 — — 過氧化氫(35%) 17.0 17.0 17.0 17.0 17.0 17.0 17.0 乙醇 1.5 — 1.0 2.0 一 —— — 硬脂醇 — 2.0 1.0 一 — 2.0 1.0 凡士林 0.5 0.5 0.5 — 0.5 0.5 0.5 胺基改質矽酮 (東道康寧公司製造之SM8702C) 1.5 1.5 1.5 — 1.5 — — 丙二醇 5.0 5.0 5.0 — 5.0 — 5.0 對經基苯甲酸甲酯 一 — — 0.1 一 — — 磷酸 適量* :適量, 適量* 適量’ 適量· 適量’ 適量· 純化水 剩餘量 軻餘量 剩餘量 剩餘量 剩餘量 剩餘量 积餘量 梳順度 ◎ ◎ '© △ 〇 △ △ 乾燥狀態 〇 © ◎ X △ 〇 X 柔軟度 ◎ © X △ 〇 △ 光潤度 :〇 ◎ 〇 X Δ 〇 X 脱色後隨時日經過之轉紅情形 〇 〇 〇 X X X X * :將pH値調至3.5之量 -11 - 本紙張尺度適用中國國家標李(CNS ) Λ4规格(210X 297公兑) 509578 經濟部中央標隼局員工消費合作社印製 五、 A7 _______ B7發明説明(9 ) 漏合等量之第1劑(表3 )與第2劑(表4 ),塗布於約2 公克之山羊毛上,於30Ό下放置3〇分鐘後,將其清洗、洗 髮及潤絲,再予以乾燥。於4(rc、75%RH下放置2週,而 發現概順度良好、並未呈乾燥狀態,且幾乎未出現褪色的 表3 成份 重量% 甲苯-2,5-二胺 0.5 間胺酚 0.5 氨(28%) 6.0 乙醇 15.0 丙二醇 10.0 油酸 2.0 油酸二乙醇醢胺 3.0 聚氧乙晞基(20)辛基月桂基醚 12.0 氯化铵 適量 純化水 剩餘量 總計 loo.o (讀先閲讀背面之注意事項再^Γ本頁-10- This paper size applies to Chinese National Standards (CNS) / Yingge (210X 297 Gong) 509578 A7 B7 V. Description of Invention (8) Table 2 Comparison of Printing Examples of the Shellfish Consumer Cooperative of the Central Bureau of Standards, Ministry of Economic Affairs Example 1 2 3 1. 2 3 4 Stearyltrimethylammonium chloride 3.0 3.0. Mono-3.0 3.0 — Gasified distearyldimethylammonium 1.0 — 1 — 1.0 — 2-octyl lauryl monochloride Trimethylammonium-2.0 4.0 --- 2.0 4.0 Alkyl ammonium sulfate '----1.5--hydrogen peroxide (35%) 17.0 17.0 17.0 17.0 17.0 17.0 17.0 ethanol 1.5-1.0 2.0--stearyl alcohol — 2.0 1.0 — 2.0 1.0 Vaseline 0.5 0.5 0.5 — 0.5 0.5 0.5 Amine-modified silicone (SM8702C manufactured by Dow Corning) 1.5 1.5 1.5 — 1.5 — — Propanediol 5.0 5.0 5.0 — 5.0 — 5.0 Paraben Ester 1 — 0.1 1 — — Phosphoric acid amount *: Right amount, right amount * Right amount 'Right amount · Right amount' Right amount · Purified water remaining amount 轲 Remaining amount remaining amount remaining amount remaining amount remaining amount combing degree ◎ ◎ '© △ 〇 △ △ Dry state 〇 © ◎ X △ 〇X Softness ◎ © X △ 〇 △ Luminosity: 〇 ◎ 〇X Δ 〇X After the decolorization, it will turn red at any time. 〇〇XXXX *: Adjust the pH to 3.5. -This paper size applies to Chinese National Standard Lithium (CNS) Λ4 specification (210X 297). 509578 Printed by the Consumers' Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs. A7 _______ B7 Invention Description (9) Missing the same amount of the first agent (Table 3) and the second agent (Table 4), coated on about 2 grams of goat wool, left at 30 分钟 for 30 minutes, washed, shampooed and conditioned, and then dried. Placed at 4 ° C, 75% RH for 2 weeks, but found to be generally smooth, not in a dry state, and almost no discoloration. Table 3 Ingredient weight% toluene-2,5-diamine 0.5 m-aminophenol 0.5 Ammonia (28%) 6.0 Ethanol 15.0 Propylene glycol 10.0 Oleic acid 2.0 Diethanolamine oleate 3.0 Polyoxyethylammonium (20) octyl lauryl ether 12.0 Ammonium chloride Appropriate amount of purified water remaining total loo.o (read first read Note on the back again ^ Γ This page

、1T -12- 本纸張尺度適用中國國家標隼(CNS ) Λ4規格(210X 297公玢) 509578 A7 ----- B7 五、發明説明(1()) 表4 成份 重量% 氣化2 -辛基月桂基三甲基铵 4.0 過氧化氫(35%) 17.0 乙醇 ι.α < 硬膳醇 1.0 凡士林 0.5 胺基改質碎嗣 1.5 (東遒康寧公司製造之SM8702C) 丙二醇 5.0 磷酸 適量# 純化水 剩餘量 總計 100.0 * :將pH値調至3.5乏量 (請先閲讀背面之注意事項再 __ 本頁)、 1T -12- This paper size is applicable to Chinese National Standard (CNS) Λ4 specification (210X 297 gong) 509578 A7 ----- B7 V. Description of the invention (1 ()) Table 4 Ingredient weight% Gasification 2 -Octyl lauryl trimethylammonium 4.0 Hydrogen peroxide (35%) 17.0 Ethanol.α < Stearyl alcohol 1.0 Vaseline 0.5 Amino modified mash 1.5 (SM8702C manufactured by Toho Corning) Propanediol 5.0 Phosphoric acid amount # The total amount of purified water is 100.0 *: Adjust the pH to 3.5 depletion (please read the precautions on the back first, then __ this page)

、1T, 1T

經濟部中央標隼局員工消f合作社印製 先於甘油加入陽離子性界面活性劑及高碳數醇類,將該 物加熱至70°C予以溶解,並將磷酸與水加熱至7〇乇予以溶 解’而後將上述溶解物加入其中。之後攪拌3 〇分鐘,持續 攪拌並將溫度冷卻至40。(:,再加入剩餘之成份,以調配製 出示於表5之單劑式脱色用组合物。 __ , -13· 本紙張尺度適用中國國家標隼(CNS ) Λ4坭格(210X 297公泠) 509578 五 經濟部中央標準局貝工消費合作社印製 A7 B7 發明説明(η ) 表5 成份 .重量% 氯化硬脂基三甲基銨 3.0 氯化二硬脂基二甲基銨 1.0 乙醇 1.5 胺基改質矽酮 1.5 (東道康寧公司製造之SM8702C) 甘油 10.0 對羥基苯甲酸甲酯 0.1 過氧化氫(35%) 7.5 磷酸 適量* 純化水 剩餘量 總計 100.0 * :將pH値調至3·5之量 以洗髮精洗淨黑髮束(曰本人毛髮10公克)、並以毛巾 擦乾後,塗布10公克之上述組合物,於30°c下放置5分鐘 ,之後以水流清洗,並予以乾燥1次。 重覆該操作程序5次,而毛髮之梳順度良好、並未呈乾 燥狀態,且相當柔軟。 產業可利用性 本發明之毛髮之染色及脱色用氧化劑組合物對毛髮所造 成的損害極小,於施用此物時及施用此物後可對毛髮產生 良好的滋潤效果,並且於染髮後極少發生掉色的情形、於 脱色後亦極少隨時日經過而出現轉紅的現象。 -14 ~ 本纸張尺度適用中國國家標準(CNS ) Λ4^格(210X 297公片)The staff of the Central Bureau of Standards of the Ministry of Economic Affairs, the Co-operative Society, printed a cationic surfactant and a high-carbon alcohol before glycerin, heated it to 70 ° C to dissolve it, and heated phosphoric acid and water to 70 ° C. Dissolve 'and then add the above-mentioned solute. After stirring for 30 minutes, stirring was continued and the temperature was cooled to 40 ° C. (:, Then add the remaining ingredients to prepare the single-agent decoloring composition shown in Table 5. __, -13 · This paper size is applicable to the Chinese national standard (CNS) Λ4 grid (210X 297) 509578 A7 B7 printed by the Shellfish Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy of the People's Republic of China Description of the invention (η) Table 5 Composition. Wt% Stearyl trimethylammonium chloride 3.0 Distearyldimethylammonium chloride 1.0 Ethanol 1.5 Amine Modified Silicone 1.5 (SM8702C manufactured by Dow Corning) glycerol 10.0 methyl parahydroxybenzoate 0.1 hydrogen peroxide (35%) 7.5 appropriate amount of phosphoric acid * total remaining amount of purified water 100.0 *: adjust pH 値 to 3.5 The amount of hair was washed with shampoo (10 g of my hair) and dried with a towel. Then, 10 g of the above composition was applied, left at 30 ° C for 5 minutes, and then washed with water and applied. Dry once. Repeat this procedure 5 times, and the combing of the hair is good, not in a dry state, and quite soft. Industrial Applicability The oxidant composition for dyeing and decoloring the hair of the present invention causes the hair The damage is minimal. When using this substance and after applying this substance, it can have a good moisturizing effect on the hair, and it will rarely fade after dyeing, and it will rarely turn red after passing by. -14 ~ This paper size Applicable to Chinese National Standard (CNS) Λ4 ^ grid (210X 297 films)

Claims (1)

509578 第87117779號專利申請案 g 中文申請專利範圍修正本⑼年3月、509578 Patent No. 87117779 g Chinese Patent Application Amendment 六、申請專利範圍 公 口 ii 一種毛髮之染色及脫色用氧化劑組合物,其特徵在於包 含以下之成份⑻〜⑹: ⑻下式(1 )或式(2 )所示之直鏈或支鏈之烷基型陽離子性 界面活性劑0 · 1 - 1 〇重量% : R^N—R3 R4 X ⑴ 〔式中R1係表示可經羥基取代之碳數為8〜36之直 鏈或支鏈之烷基、R2、“與尺4可相同或不同,係表 π可經羥基取代之碳數為1〜3之烷基或苯甲基,而X 係表示自素原子或是碳數為1或2之垸硫酸基。〕, R5 R^-N—R7 R8 X (2) 〔式中X所表示之意義係與前述相同、rS與反S可 相同或不同,係表示可經輕基取代之碳數為8〜%之 直鏈或支鏈之烷基,而…與!^可相同或不同,係表 示可經幾基取代之碳數為1〜3之烷基。〕;⑹碳數1〇-24之直鏈或支鏈脂肪族醇類〇. 1-20重量% ·, ㈡下式(3 )所示之胺基改質矽酮0 · 1 - 1 5重量% : CH3I -Si—οI CFh R9 -Si- R 10 -R9 (3) 〔式中R9可相同或不同,係表示氫原子、羥基、甲基6. Scope of patent application Public mouth ii An oxidant composition for hair dyeing and decoloring, which is characterized by containing the following ingredients ⑻ ~ ⑹: 直 The linear or branched chain represented by the following formula (1) or formula (2) Alkyl-type cationic surfactant 0 · 1-10 % by weight: R ^ N—R3 R4 X ⑴ [wherein R1 represents a linear or branched alkane having 8 to 36 carbon atoms which can be substituted by a hydroxyl group Group, R2, "can be the same as or different from rule 4, is an alkyl or benzyl group having 1 to 3 carbon atoms which can be substituted by a hydroxyl group, and X represents a prime atom or a carbon number of 1 or 2垸 sulfate group.], R5 R ^ -N—R7 R8 X (2) [wherein the meaning of X is the same as the above, rS and trans S may be the same or different, and it represents a carbon that may be substituted by a light group. A straight or branched alkyl group having a number of 8 to%, and ... and! ^ May be the same or different, and represents an alkyl group having 1 to 3 carbon atoms which can be substituted by several groups.]; ⑹ carbon number 1〇 -24-chain linear or branched aliphatic alcohols 0.1 to 20% by weight ·, amine-modified silicone represented by the following formula (3) 0 · 1-1 5% by weight: CH3I -Si—οI CFh R9 -Si- R 10 -R9 (3) [wherein R9 may be the same or different and represents a hydrogen atom, a hydroxyl group, a methyl group 509578 A8 B8 C8 ___— _ D8 六、申請專利範圍 一 "~— .或甲氧基、R1G係表示: -(CH2)0-(OC2H4)p-(OC3H6)q.NHC2H4-N(R11)2 或·(CH2)0-(〇C2H4)p-(〇C3H6)q-NHC2H4-N + (Rli)3 · 2Γ、 (R11可相同或不同,係表示氫原子、碳數為1〜6之 烴基、Z係表示#素離子或是有機陰離子、〇係表示i 〜6之數,而p及q係表示〇〜6之數)、^係表示3〜 300之數,而η係表示1〜50之數。〕; (d)過氧化氫〇 · 5 - 1 0重量%。 2·根據申請專利範圍第丨項之組合物,其係包含〇1〜8重量 %之成份⑻、〇·5〜1〇重量%之成份⑹、i 〇〜8〇重量% 之成份(c),及1.0〜8.0重量%之成份⑹。 3.根據申請專利範圍第丨或2項之组合物,其係與包各鹼性 劑之組合物、或是包含驗性劑、染科先質及:色劑 (coupler )之組合物組合使用者。 -2- 本紙張尺度適用中國國家標準(CNS) A4規格(210X297公釐) '—-509578 A8 B8 C8 ___ — _ D8 6. Scope of patent application 1 " ~~. Or methoxy, R1G series means:-(CH2) 0- (OC2H4) p- (OC3H6) q.NHC2H4-N (R11) 2 or (CH2) 0- (〇C2H4) p- (〇C3H6) q-NHC2H4-N + (Rli) 3 · 2Γ, (R11 may be the same or different, which means a hydrogen atom and a carbon number of 1 to 6 Hydrocarbon group, Z system means # element ion or organic anion, 0 system means number of i ~ 6, and p and q system means number of 0 ~ 6), ^ system means number of 3 ~ 300, and η system means 1 ~ 50 number. ]; (D) Hydrogen peroxide 0.5-10% by weight. 2. The composition according to item 丨 of the scope of application for a patent, which comprises an ingredient of 0 to 8 wt%, an ingredient of 0.5 to 10 wt%, and an ingredient of i to 80 wt% (c) , And 1.0 ~ 8.0% by weight of the ingredients ⑹. 3. The composition according to item 丨 or 2 of the scope of patent application, which is used in combination with a composition containing each alkaline agent, or a composition containing a test agent, a dyestuff precursor, and a coupler By. -2- This paper size applies to China National Standard (CNS) A4 (210X297 mm) '—-
TW87117779A 1997-12-26 1998-10-27 Oxidizing agent composition for hair TW509578B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP9360584A JPH11193223A (en) 1997-12-26 1997-12-26 Hair dyeing and oxidizing agent composition for decolorization

Publications (1)

Publication Number Publication Date
TW509578B true TW509578B (en) 2002-11-11

Family

ID=18470043

Family Applications (1)

Application Number Title Priority Date Filing Date
TW87117779A TW509578B (en) 1997-12-26 1998-10-27 Oxidizing agent composition for hair

Country Status (2)

Country Link
JP (1) JPH11193223A (en)
TW (1) TW509578B (en)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7179302B2 (en) 2001-03-20 2007-02-20 The Procter & Gamble Company Oxidative treatment of hair with reduced hair damage
US7186275B2 (en) 2001-03-20 2007-03-06 The Procter & Gamble Company Compositions suitable for the treatment of hair comprising chelants and methods for reducing oxidative hair damage
US20030005526A1 (en) * 2001-05-15 2003-01-09 Stephen Casperson Two-part aqueous composition for oxidative coloration of hair
FR2831816B1 (en) * 2001-11-08 2004-07-16 Oreal USE OF PARTICULAR AMINO SILICONE IN PRE- OR AFTER-TREATMENT OF KERATINIC FIBER DISCOLORATIONS
GB0209136D0 (en) * 2002-04-22 2002-05-29 Procter & Gamble Durable hair treatment composition
JP2004189717A (en) * 2002-11-27 2004-07-08 Shiseido Co Ltd Hair dye composition
JP4116936B2 (en) * 2003-07-03 2008-07-09 花王株式会社 Oxidative hair dye or decolorant composition
JP4086742B2 (en) * 2003-09-12 2008-05-14 ホーユー株式会社 Hair cosmetic composition
JP4072114B2 (en) * 2003-11-07 2008-04-09 株式会社資生堂 Oxidative hair dye composition
EP1591102A1 (en) 2004-04-30 2005-11-02 The Procter & Gamble Company Process and kit-of-parts for improved hair conditioning after coloring, bleaching or perming
JP4863408B2 (en) 2009-03-06 2012-01-25 株式会社 資生堂 Hair treatment composition

Also Published As

Publication number Publication date
JPH11193223A (en) 1999-07-21

Similar Documents

Publication Publication Date Title
TW199175B (en)
JP6611476B2 (en) Hair dye composition
WO2006109877A1 (en) Hair cosmetic
JP5064664B2 (en) Cation-modified Karaya gum and cosmetic composition containing the substance
TWI736624B (en) Hair treatment agent
TW509578B (en) Oxidizing agent composition for hair
US10335358B2 (en) Hair cosmetic
JP2002029937A (en) Cosmetic for hair
WO2018180515A1 (en) Hair dye composition
WO2003105792A1 (en) Cosmetic hair preparation
JP5209833B2 (en) Hair cosmetics
JP5475310B2 (en) Hair cosmetics that do not wash away
TW505522B (en) Hair oxidizing composition
JP2017019748A (en) Hair cosmetic
US20200179257A1 (en) Conditioning compositions containing cationic compounds, a silane compound and silica particles and methods for use
JP2019182799A (en) Oxidative hair dye composition, oxidative hair dye kit and oxidative hair dyeing method
TWI826462B (en) hair cosmetics
JP2010013404A (en) Hair cosmetic
JP2020121937A (en) Hair dying composition
JP2015034139A (en) Hair smoothness-imparting agent, and hair cosmetics containing the same
JP2001097827A (en) Hair cosmetic
WO2018180516A1 (en) Hair dye composition
JP2012232919A (en) Hair cleaning agent composition
JP6718705B2 (en) Hair cosmetics
JPH0615456B2 (en) Hair cosmetics