496752 A7 B7 五、發明說明（1 ) 【發明之背景】 (發明之領域） (請先閱讀背面之注意事項再填寫本頁) 本發明係有關使用於膠版印刷之處理潤版藥水之潤版 藥水循環處理裝置以及潤版藥水循環處理方法。 【先前之技術】 在膠版印刷之中，潤版藥水之管理非常重要。潤版藥 水循環裝置係在將預設各成分濃度之淸淨潤版藥水，以一 定之流量且一定之溫度供向印刷單元之藥水槽，將通過藥 水槽之潤版藥水回收，再將其再生成新鮮之潤版藥水供向 藥水槽。在最近之膠版轉輪式印刷機之中，連續式之潤版 藥水循環裝置常被利用，爲了安定汲水，使用有機劑之異 丙醇（I P A )。因將此I p A添加於潤版藥水中，降低 潤版藥水之表面張力，而能以少量之潤版藥水將非畫線部 均一地潤濕。也就是，藉由I P A版面之沾水性很好，而 維持印刷之品質。另外，因爲在勞動安全衛生的面來看， 經濟部智慧財產局員工消費合作社印製 I P A有其問題，必須將使用量限制到最小或者也有實行 不用I P A之潤版藥水。不管其中任何一種潤版藥水之管 理將變成更重要。 第5圖爲以往之潤版循環藥水裝置1 〇 1之例的系統 圖。 在第5圖，藉由潤版藥水混合裝置1 〇 2，將潤版藥 水之原液與水 '甲醇等以正確的比例混合，將新的潤版藥 水送入潤版藥水循環裝置1 0 1。潤版藥水循環裝置 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -4- 496752 A7 ____B7 五、發明說明（2 ) 1 〇 1係將從印刷單元之藥水槽1 0 3所回來之潤版藥7欠 的污染，在過濾裝置1 〇 4去除，再回送到潤版藥水循環 裝置10 1內之藥水箱內（圖中未顯示）。 藥水箱中之潤版藥水的量減少時，藉由浮球閥1 0 5 從潤版藥水混合裝置1 0 2補充新的潤版藥水。藥水箱內 之潤版藥水係藉由冷卻裝置（圖中未顯示）維持所設之溫 度。甲醇溫度控制1 0 6係爲了控制容易蒸發之甲醇的濃 度。 在甲醇濃度控級裝置1 0 6中將藥水箱中之潤版藥水 連續地送入平常藉由將水中之P Η値做爲監視，而檢測出 氫離子濃度，補充分必要量之甲醇於潤版藥水之中維持其 甲醇濃度。 作爲I Ρ Α之代替品而使用腐蝕液之情形也有必要管 .理溫度以及濃度將潤版藥水之濃度與蒸發率保持一定。甲 醇的情形藉由比重計來控制濃度。一方面，作爲I Ρ A之 代替品而使用腐蝕液之情形，係利用潤版藥水之導電率比 經濟部智慧財產局員工消費合作社印製 ，潤粉狀 在從層 外化紙淨 形將隙 另變、淸 情只空 。 使水之 的，之 度而墨體 1 材器 濃物由全 ο 濾濾 制機有 1 1 孔過 控有含 ο 置_多通 可生因 1 裝等染 而產中置 環器污 ， 內水裝 循濾的 度 1 藥環 水過水 濃 ο 版循 藥綿藥 之 1 潤版 版海版 液置在潤 潤用潤 縮裝，以。之使之 濃環他所要往係來 性循其，重以，回 鹼水。染地述 4 所 或藥性污常上 ο 3 液版特之非，1 ο 飽潤之成持是置 1 腐在水所維但裝槽 於有藥等的 濾水 例也版油態 過藥 霧！ hi訂---------線！· (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -5- 496752 A7 _ ________________ B7 五、發明說明（3 ) (請先閱讀背面之注意事項再填寫本頁) 之物理性過濾而去除。因此，其不純物之除去能力將依存 過濾器之粗細程度，通常只能將1 〇 0 // m爲止之不純物 除去。 假設在過濾之網目變小藉以提高不純物之除去能力， 因爲通過空隙層將增加潤版藥水之壓力，將不能以所設定 之流量使潤版藥水循環。當不能以所預定之流量使藥水循 環潤版藥水將失去正常的機能，印刷品質將低下。另外， 倘若過濾器之網且過細，因爲因不純物而使網目阻塞，而 有頻繁地淸洗過濾器之必要。 另外，在如此之以往的潤版循環裝置1 0 1中，因其 過濾能力之界限將潤版藥水循環使用約2〜3個月後，因 潤版藥水之污濁與應敗到不能作爲潤版藥水的程度。在此 ，雖然要進行更換潤版藥水，但是以往之只有物理性過濾 潤版藥水之廢液中的生物化學氧要求量（B〇D )、化學 氧要求量（C〇D )、正己烷値以及懸濁物質（ 經濟部智慧財產局員工消費合作社印製 S S )等將不能通過法定排水基準。因此，潤版藥水廢液 將成爲產業廢棄物不能將其排放到河川等中。結果將成爲 必須委託專門業者作廢液處理，而其之處理將花費很高之 代價。 在此，本發明中提供不用加壓於潤版藥水中，藉由除 去潤版藥水中之B〇D、C〇D、正己烷値以及S S等之 成分，可能不用將潤版藥水廢棄而能再生利用之潤版循環 處理裝置以及潤版藥水循環處理方法。 -6 - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 496752 A7 _ B7 五、發明說明（4 ) 【發明之槪要】 (請先閱讀背面之注意事項再填寫本頁) 本發明之潤版藥水處理裝置係爲將使用於膠版印刷之 潤版藥水循環淨化處理之潤版藥水循環處理裝置，其特徵 爲在將潤版藥水循環之循環路的途中，具備有利用Z 一電 位之吸著利用之電位吸著過濾裝置，與利用活性碳之吸著 作用之活性碳過濾裝置。 --線· 經濟部智慧財產局員工消費合作社印製 藉此，因爲含於潤版藥水中之墨水、紙粉或油等之微 粒子一般顯不負電位，因此在電位吸著過濾裝置內之電位 吸著過濾器中具有正電位之Z -電位，而能吸收通常多孔 性濾材所形成之過濾器無法除去之微粒子。另外，根據如 此之電位吸著作用，不用將通過電位吸著過濾器之潤版藥 水加壓就能減低微粒子成分。並且，藉由通過活或炭過濾 器而能將潤版藥水脫色以及脫臭。也就是，能維持所預定 之流量並減低B.〇D、C〇D、（正己烷値）値以及S S. 等之成分，而且已脫色以及脫臭之潤版藥水能長期間使用 不用廢棄就能再利用。結果不會產生潤版藥水之廢液，因 爲不須要委記外部作廢液處理，所以能降低用於膠版印刷 之潤版藥水的運轉成本。另外，使用如此精製之潤版藥水 而進行膠版印刷亦能提升印刷品質。 特別是在循環路中，各別在上側設置電位吸著過濾器 ，及在下側設置活性碳過濾裝置而構成’將含於潤版藥水 中之墨水、紙粉或油等之微粒子藉由電位吸著過濾裝置除 去後，藉由通過活性碳過濾裝置，使得活性碳過濾裝內之 活性碳過濾器的壽命能得以飛躍性的延長。 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公楚） 經濟部智慧財產局員工消費合作社印製 496752 A7 B7 五、發明說明（5 ) 並且，最好具備有檢測循環路之導入口與導出口側之 間的差壓的差壓檢測裝置，與對應於差壓檢測裝置之檢測 結果發出警報之警報裝置。 藉由檢測循環路之導入口側與導出口側之間的差而發 出警報，將電位過濾器以及活性碳過濾器之交換時期告訴 操作者，能夠防止潤版藥水之流量超過設定値，而使得操 作者能簡單地進行潤版藥水之管理。 在此，希望循環路之導入口側與導出口側之間的差壓 在2 · 2 k g / c m 2以下。藉此，成爲能最有效利用電位 吸著過濾裝置以及活性碳過濾裝置之潤版藥水流量，而能 容易維持印刷的品質。超過2 · 2 k g / c m 2的情形，因 電位吸著過濾或者活性碳過濾裝置之網目阻塞而不能充分 進行淨化處理。 本發明之藉由水循環處理裝置所進行之潤版藥水循環 處理方法，其特徵爲使用於膠版印刷之將潤版藥水循環淨 化處理之潤版藥水循環處理方法，將潤版藥水藉由Z -電 位之吸著作用過濾，再藉由活性碳之吸著作用過濾、循環 。藉此，將潤版藥水所含之墨水、紙粉或油等微粒子藉由 Z -電位吸著除去，再藉由活性碳脫色、精製，而能將潤 版藥水半永久性的使用。 【圖面之簡單說明】 第1圖 爲本發明之實施形態中，潤版藥水循環處 理裝置之槪略圖（a)爲平面圖、（b)爲正面圖。 ! #1,訂 --------線 — _ (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -8- 496752 經 濟 部 智 慧 財 產 局 員 工 消 f 合 作 社 印 製 A7 B7 五、發明說明（6 ) 第2圖 顯示於第1圖之潤版藥水循環處理裝置之 系統圖。 第3圖 顯示於第1圖之收容在電位吸者過漉裝置 之盒內的電位吸著卡匣之一部分切割詳細圖。 第4圖 顯示於第1圖之活性碳過濾裝置之詳細縱 斷面圖。 第5圖 顯不以往之潤版樂水循環裝置之例之系統 圖。 符號說明】 1，1 0 1 潤版藥水循環裝置 10 2 潤版藥水混合裝置 1 2，1 0 3 潤版藥水槽 1 0 4 過濾裝置 105 浮球閥 10 6 甲醇濃度控制裝置 2 電位吸著 3 活性碳過濾裝置、 4 線上幫浦 5 差壓發信機 6 警示燈 8 a 導入口 8 b 導出口 9 a〜9 d 循環路 I I I I —ί — — — — — — — I I I l· I I J ^ . I I — — — — — — I I (請先閱讀背面之注意事項再填寫本頁) -9 - 經濟部智慧財產局員工消費合作社印製 496752 A7 ____B7____ 五、發明說明（7 ) 1 〇 a ’ 1 0 b 連結路 1 1 潤版部 1 3 ’ 1 4，1 5 滾輪 2 〇 電位吸著卡匣 2 1 觸媒 ^ 2 分離器 2 3 腐蝕膜 2 4 環狀墊片 2 5 芯 3 0 盒子 3 1 活性碳卡匣 3 2 纖維不織布 3 3 顆粒活性碳 3 4 膠膜過濾網 3 5 代謝過濾網 【較佳實施例之說明】 第1圖爲本發明之實施形態中潤版循環處理裝置之槪 略圖，（a)爲平面圖、（b)爲正面圖’第2圖爲第1 圖所示潤版藥水循環處理裝置之系統圖。 在本發明之實施形態中之潤版藥水處理裝置1 ，係在 用於膠版轉輪印刷機，在藉由將潤版藥水從導入口 8 a ( 上游側）導入，導出口 8 b (下游側）導出之循環路9 a 〜9 d途中，按照順序配置將潤版藥水強制循環之作爲幫 本紙張尺度適用中國國家標準(CNS)A4規格（210 x 297公釐） --------------------r---:訂--------線--Aw (請先閱讀背面之注意事項再填寫本頁) 496752 A7 B7 五、發明說明（8 ) 浦裝置之線幫浦4與利用Z -電位之吸著作用之電位吸著 過濾裝置2 ，與利用活或炭之吸著作用之活性碳過濾裝置 0 並且，在潤版循環處理裝置1中，具備有在電位吸著 過濾裝置2以及活性碳過濾裝置3之更外側，也就是檢測 導入口 8 a側與導出口 8 b側之循環路9 b、9 d間之差 壓而發出檢測訊號之作爲差壓檢測裝置之差壓發信機5與 對應於此差壓發信機5之檢測訊號之檢測程度而發出警報 之作爲警報裝置的警示燈6，與控制線上幫浦4與差壓發 信機5與警示燈6之控制盤。 第3圖爲第1圖所示，收容在電位吸著過濾裝置之盒 內之電位吸著卡匣的一部分切斷詳細圖。 電位吸著過濾裝置2係作爲在盒內可交換之電位吸著 .過濾器，收容電位吸著卡匣2 0之構件。電位吸著卡匣 2 0係將主要由樹脂，纖維素所構成之觸媒2 1 ，聚丙烯 製之分離器2 2以及腐餓膜2 3所形成之單元挾著纖維制 之環狀墊片2 4以纖維製芯組裝而成。 經濟部智慧財產局員工消費合作社印製 一般在異相接觸界面會產生電位差，產生在粒子界因 電氣二重層而發生之電位中，有不擔任動的部分（固定層 )，與擔任動的部分（擴散層）。在異相之間只有相對運 動之情形’將在界面會引起之電氣現象稱爲界面配動電現 象，在此存在之電位稱爲界面動電位或者Z -電位。 Z電位係與廷德爾（散射）現象或布郎運動相同爲因 微細粒子特性之物理現象，一般在液體中微粒子或微生物 -11 - ---：---,-----— II __ (請先閱讀背面之注意事項再填寫本頁) 線- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 經濟部智慧財產局員工消費合作社印製 496752 A7 - B7 五、發明說明（9 ) 等係顯示負電位。潤版藥水中所含墨水、紙粉或油等微粒 子也顯示負電位，對此在電位吸著過濾裝置2內之觸媒 2 1因持有正之Z —電位性質，能吸收通常以〇 . 2 // m 膜過濾器也不能除去之這此微粒子將以除去。另外，根據 如此之電位吸著作用，不用加壓使潤版藥水通過電位吸著 過濾裝置2就能除去微粒子成分。 第4圖爲第1圖所示活性碳過濾裝置之詳細縱斷面圖 。第4圖中之箭號爲潤版藥水所流之方向。活性碳過濾裝 置3係在盒子3 0內收容爲可以交換作爲活性碳過濾器之 活性碳卡匣3 1。活性碳卡匣3 1爲在纖維不織布3 2內 收容顆粒活性碳3 3，膠膜過濾網3 4以及代謝過濾網 3 5再加以熱膜。 顆粒活性碳3 3係爲高品質很硬粒子之粒狀活性碳， 能有效果的吸收潤版藥水中之有機物、色、臭氣以及混濁 等。膠膜過濾網3 4以及代謝過濾網3 5係由纖維以及三 聚氰樹脂所形成。膠膜過濾3 4將吸著潤版藥水中之垃圾 、銹以及其他沈澱物，代謝過濾網3 5係防止顆粒活性碳 3 3之流出。藉由膠膜過濾網3 4所過濾之潤版藥水，係 藉由顆粒活性碳3 3吸著含於潤版藥水中之有機物等。 但是，膠版轉輪印刷機之潤版藥水部1 1 ，因爲係設 置在版1 6上’具有藥水槽與從到版1 6順序設置之複數 輥1 3、1 4、1 5。如第2圖所示，潤版藥水循環處理 裝置1係與膠版轉印刷機的潤版藥水部1 1之藥水槽藉由 連接路l〇a、10b而連接。連接路10a、l〇b與 本紙張尺度適用中國國家標準（CNS)A4規格（210 x 297公爱) -12 - --^丨丨1-丨丨丨丨丨！ ---h丨丨訂-丨、丨丨----I I (請先閱讀背面之注意事項再填寫本頁) 496752 A7 — B7 五、發明說明（10 ) (請先閱讀背面之注意事項再填寫本頁} 潤版藥水循環處理裝置1係各別連接在導入口 8 a與導出 口 8 b。藥水槽1 2內之潤版藥水係一連通過連接器 l〇a ，循環路9a〜9d連接路l〇b而循環。 藥水槽內之潤版藥水係藉由線上幫浦4強制地送入循 環路9 a內，藥水槽1 2內之潤版藥水隔著連接路1 0 a ’藉由導入口 8 a進入循環路9 a之內，通過循環路9 a 導入電位吸著過濾裝置2內。在電位吸著過濾裝置2內藉 由Z -電位之吸著作用，吸著、除去含於潤版藥水中之墨 水、紙粉或油等微粒子成分。藉由如此之利用電位吸著作 用而吸著、除去微粒子成分，不用加壓通過電位吸著過濾 裝置2之潤版藥水就能除去微粒子成分。並且，藉著循環 路9 C導入活性碳過濾裝置3內之潤藥水被脫色以及脫臭 ，藉由循環路9 d以及連接路1 0 b回送到藥水槽1 2之 內。 經濟部智慧財產局員工消費合作社印製 如此一來藉由具備在循環路途9 a〜9 d途中之電位 吸著過濾裝置2與活性碳過濾裝置3，能在維持所預定之 流量下減低B〇D、C〇D、正己烷値以及S S等成分， 並且加以脫色以及脫臭之潤版藥水能長期間使用，不用廢 棄就能再利用。結果不會發生潤版藥水之廢液，因爲設有 委託外部作廢液處理之必要，所以可以抑制用於膠版印刷 之潤版藥水之運轉成本。另外，使用如此精製後之潤版藥 水來進行膠版印刷也可以提升印刷品質。 特別是，在本實施形態之潤版藥水循處理裝置1中’ 係由各別在循路9 a〜9 d之上流側設置電位吸著過濾裝 -13- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 496752 A7 __ B7 五、發明說明（彳彳） 置2以及在下流側設置活性碳過濾裝置3而構成，因爲將 潤版藥水中所含之墨水、紙粉或油等微粒子，藉由電位吸 著過濾裝置2除去之後通過活性碳過濾裝置3，所能活性 碳卡匣3 1之壽命得以飛躍性的延長。 在此，本實施形態中藉由具備在潤版藥水循環處理裝 置1之差壓，發信機5檢測循環路9 b、9 d間之差壓， 當此差壓超過2 · 2 kg/cm2時點亮警示燈6並發出警 報。電位吸著過濾裝置2內之因觸媒2 1達到其界限點時 差壓將急速上昇，檢測此差之上昇，藉以將電位吸著過濾 裝置2之交換時期告知操作者，而防止潤版藥水之流量超 過所設定之數値。另外，有關活性碳過濾裝置3也利用差 壓之上昇檢測吸著能力的界限，同樣地被使用。 --.---·------------r---，訂· --------線-- (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -14 -496752 A7 B7 V. Description of the invention (1) [Background of the invention] (Field of invention) (Please read the notes on the back before filling out this page) This invention is a fountain solution for processing fountain solutions used in offset printing. Circulation treatment device and method for circulation treatment of dampening solution. [Previous technology] In offset printing, the management of fountain solution is very important. The fountain solution circulation device is to supply the clean fountain solution with a predetermined concentration of each component to the medicine tank of the printing unit at a certain flow rate and temperature, and recover the fountain solution through the medicine tank, and then regenerate it. Make fresh fountain solution for the potion. In recent offset printing presses, continuous dampening solution circulation devices are often used. In order to stabilize the pumping, isopropyl alcohol (I P A), an organic agent, is used. Since this I p A is added to the fountain solution, the surface tension of the fountain solution is reduced, and the non-lined parts can be uniformly wetted with a small amount of fountain solution. That is, the water quality of the IPA layout is very good, and the printing quality is maintained. In addition, from the aspect of labor safety and health, the printing of I P A by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs has its problems. It is necessary to limit the use to a minimum or implement a moisturizing solution without I P A. Regardless of the management of any of these fountain solutions, it will become even more important. Fig. 5 is a system diagram of an example of a conventional dampening circulation medicine device 101. In FIG. 5, the fountain solution is mixed with a fountain solution mixing device 102, and the original solution of the fountain solution is mixed with water, methanol, etc. at a correct ratio, and a new fountain solution is sent to the fountain solution circulation device 101. Dampening potion circulation device This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) -4- 496752 A7 ____B7 V. Description of the invention (2) 1 〇1 is the potion tank from the printing unit 1 0 The contamination from the fountain solution 7 returned by 3 is removed in the filtering device 104, and then returned to the medicine tank in the fountain solution circulation device 101 (not shown in the figure). When the amount of dampening potion in the potion tank is reduced, a new dampening potion is replenished from the dampening potion mixing device 1 0 2 by a float ball valve 105. The dampening potion in the potion tank is maintained at a set temperature by a cooling device (not shown). Methanol temperature control 106 is to control the concentration of methanol which is easy to evaporate. In the methanol concentration-controlling device 106, the dampening solution in the medicine tank is continuously sent into the usual way. The hydrogen ion concentration is detected by monitoring PΗ 値 in the water, and the necessary amount of methanol is replenished. The concentration of methanol is maintained in the version of the potion. It is also necessary to manage the use of a corrosive liquid as an alternative to IPA. The temperature and concentration of the dampening solution should be kept constant in concentration and evaporation rate. In the case of methanol, the concentration is controlled by a hydrometer. On the one hand, in the case of using corrosive liquid as a substitute for IPA, the conductivity of the dampening potion is printed by the consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. Another change, love is empty. Make the water, and the degree of ink, and the concentration of 1 material in the ink body from the whole filter filter machine has 1 1 hole control and contain ο set _ multi-pass can produce due to 1 set and other dyes, the middle ring device is dirty, The degree of filtration of the internal water is 1 degree of medicine, and the water is concentrated in water. The version 1 of the version of the medicine is a damp version of the sea version of the liquid. Make it strong, he wants to go through the nature of the exchanges, emphasis on, return to alkaline water. The dyeing place is described in 4 places or the medicine is often on the ο 3 liquid version of the special, 1 ο fullness of the holding is set to 1 rot in the water, but installed in the tank with medicine and other examples of water filtration version of the oil mist !! hi order --------- line! · (Please read the precautions on the back before filling this page) This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) -5- 496752 A7 _ ________________ B7 V. Description of the invention (3) (Please Read the precautions on the back before filling out this page) to remove it. Therefore, its ability to remove impurities depends on the thickness of the filter, and usually only removes impurities up to 100 // m. It is assumed that the mesh size in the filtration is reduced to improve the removal ability of impurities, because the pressure of the dampening potion will increase through the void layer, and the dampening potion will not be circulated at the set flow rate. When the liquid circulation fountain solution cannot be used at the predetermined flow rate, the normal function will be lost and the printing quality will be low. In addition, if the mesh of the filter is too thin, it is necessary to clean the filter frequently because the mesh is blocked by impurities. In addition, in such a conventional dampening circulation device 101, the dampening solution was circulated and used for about 2 to 3 months due to the limitation of its filtering ability. Due to the soiling and failure of the dampening solution, it could not be used as a dampening solution Degree of potion. Here, although the fountain solution needs to be replaced, in the past, only the biochemical oxygen requirement (BOD), chemical oxygen requirement (COD), and n-hexane in the waste liquid of the fountain solution were physically filtered. And suspended substances (printed by SS from the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs) will not pass the legal drainage standards. Therefore, the fountain solution waste liquid will become industrial waste and it cannot be discharged into rivers and the like. As a result, specialized operators must be entrusted to dispose of the waste liquid, which will cost a lot of money. Here, the present invention provides that it is possible to remove the components of BOD, COD, n-hexane, and SS from the fountain solution without pressurizing the fountain solution. Dampening circulation processing device and method for recycling dampening solution. -6-This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 496752 A7 _ B7 V. Description of the invention (4) [Summary of invention] (Please read the notes on the back before filling in this Page) The fountain solution of the present invention is a fountain solution circulation treatment device for the purification treatment of the fountain solution used in offset printing. It is characterized in that it is used on the way to circulate the fountain solution. Z-potential adsorption filter device, and activated carbon filter device using activated carbon. --Line Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. Because the particles of ink, paper powder or oil contained in fountain solution generally show no negative potential, the potential in the potential absorption filter device The suction filter has a positive Z-potential and can absorb fine particles that cannot be removed by a filter formed by a generally porous filter material. In addition, according to this potential absorption function, the particulate component can be reduced without pressurizing the fountain solution passing through the potential absorption filter. In addition, the dampening solution can be decolored and deodorized by passing through a live or charcoal filter. That is, it can maintain the predetermined flow rate and reduce the components of B.OD, CoD, (n-hexane 値) 値 and S S., and the decolorizing and deodorizing fountain solution can be used for a long period of time without waste. Can be reused. As a result, no waste liquid of dampening solution is generated, because the external liquid waste treatment does not need to be commissioned, so the running cost of dampening solution for offset printing can be reduced. In addition, the use of such refined fountain solution for offset printing can also improve printing quality. Especially in the circulation path, a potential suction filter is installed on the upper side and an activated carbon filter device is installed on the lower side to constitute 'the particles of ink, paper powder or oil contained in the fountain solution are absorbed by the potential. After the filtering device is removed, the life of the activated carbon filter in the activated carbon filtering device can be greatly extended by passing through the activated carbon filtering device. This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 Gongchu) Printed by the Employees' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 496752 A7 B7 V. Description of the invention (5) And it is better to have the introduction of a detection loop A differential pressure detection device for the differential pressure between the port and the outlet port side, and an alarm device that issues an alarm corresponding to the detection result of the differential pressure detection device. By detecting the difference between the inlet side and the outlet side of the circulation path, an alarm is issued, and the operator is informed of the exchange time of the potential filter and the activated carbon filter, which can prevent the flow rate of the dampening solution from exceeding the set value. The operator can simply manage the dampening potion. Here, it is desirable that the differential pressure between the inlet port side and the outlet port side of the circulation path is 2 · 2 k g / cm 2 or less. This makes it possible to make the most effective use of the potential absorbing filter device and the activated carbon filter device as the fountain solution flow rate, and it is possible to easily maintain the printing quality. In the case of exceeding 2 · 2 k g / cm 2, the purification treatment cannot be performed sufficiently because the mesh of the potential adsorption filter or the activated carbon filter device is blocked. The dampening potion circulation treatment method performed by a water circulation processing device of the present invention is characterized in that the dampening potion circulation treatment method for circulating and purifying the dampening potion is used in offset printing, and the dampening potion is passed through a Z-potential The suction filter is filtered, and then the activated carbon filter is filtered and recycled. In this way, particles such as ink, paper powder, or oil contained in the fountain solution can be removed by Z-potential adsorption, and then decolorized and refined by activated carbon, so that the fountain solution can be used semi-permanently. [Brief description of the drawing] Fig. 1 is a schematic view of a fountain solution circulation processing device in the embodiment of the present invention (a) is a plan view, and (b) is a front view. ! # 1, order -------- line — _ (Please read the notes on the back before filling in this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -8 -496752 Employees of the Intellectual Property Bureau of the Ministry of Economic Affairs printed by the cooperative A7 B7 V. Description of the invention (6) Figure 2 shows the system diagram of the fountain solution circulation treatment device in Figure 1. Fig. 3 is a detailed cut-away view of a part of the potential suction cartridge contained in the case of the potential suction device as shown in Figure 1. Fig. 4 is a detailed sectional view of the activated carbon filtering device shown in Fig. 1. Fig. 5 is a system diagram showing an example of a conventional dampening water circulation device. Explanation of symbols] 1, 1 0 1 fountain solution circulation device 10 2 fountain solution mixing device 1 2, 1 0 3 fountain solution tank 1 0 4 filter device 105 float valve 10 6 methanol concentration control device 2 potential adsorption 3 activity Carbon filter device, 4-line pump, 5 differential pressure transmitter, 6 warning light, 8 a inlet, 8 b, outlet, 9 a ~ 9 d, circulation path IIII —ί — — — — — — — III l · IIJ ^. II — — — — — — II (Please read the notes on the back before filling out this page) -9-Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 496752 A7 ____B7____ 5. Description of Invention (7) 1 〇a '1 0 b Link Road 1 1 Dampening section 1 3 '1 4, 1 5 Roller 2 〇 Potential suction cartridge 2 1 Catalyst ^ 2 Separator 2 3 Corrosion film 2 4 Ring gasket 2 5 Core 3 0 Box 3 1 Activated carbon Cassette 3 2 Non-woven fabric 3 3 Granular activated carbon 3 4 Membrane filter 3 5 Metabolic filter [Description of the preferred embodiment] FIG. 1 is a schematic diagram of a dampening circulation processing device in the embodiment of the present invention, ( a) is a plan view, (b) is a front view, 'the second figure is the dampening shown in the first figure System diagram of medicine circulation treatment device. The dampening solution treatment device 1 according to the embodiment of the present invention is used in an offset rotary printing press. The dampening solution is introduced from the inlet 8 a (upstream side), and the outlet 8 b (downstream side). ) On the way out of the circulation path 9 a ～ 9 d, arrange the forced circulation of dampening potion in order according to the order. The paper size applies the Chinese National Standard (CNS) A4 specification (210 x 297 mm) ------- ------------- r ---: Order -------- line--Aw (Please read the notes on the back before filling this page) 496752 A7 B7 V. Invention Explanation (8) The pump line 4 and the potential adsorption filter device 2 using the Z-potential absorption function, and the activated carbon filter device 0 using the live or carbon absorption function, and processed in a dampening cycle. The device 1 is further provided on the outer side of the potential adsorption filter device 2 and the activated carbon filter device 3, that is, the differential pressure between the circulation paths 9b and 9d on the side of the inlet 8a and the outlet 8b is detected. The differential pressure transmitter 5 as a differential pressure detection device which sends out a detection signal and an alarm corresponding to the detection level of the detection signal of the differential pressure transmitter 5 The warning lamp 6 is an alarm device, and the control panel of the pump 4 and the differential pressure transmitter 5 and the warning lamp 6 on the control line. Fig. 3 is a detailed cut-away view of a part of the potential absorbing cassette contained in the case of the potential absorbing filter device as shown in Fig. 1. The potential suction filter device 2 is a component of the potential suction filter which can be exchanged in the box and contains the potential suction cartridge 20. Potential absorbing cartridge 20 is a unit made of resin and cellulose catalyst 2 1, polypropylene separator 2 2 and rot film 2 3 which are made of ring gasket made of fiber. 2 4 Assembled with fiber core. Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, a potential difference will generally occur at the out-of-phase contact interface. Among the potentials due to the electrical double layer in the particle boundary, there are parts that do not act (fixed layer) and parts that act ( Diffusion layer). In the case where there is only relative movement between different phases', the electrical phenomenon caused at the interface is called the interface kinetic phenomenon, and the potential existing here is called the interface kinetic potential or Z-potential. Z potential system is the same as Tyndall (scattering) phenomenon or Brownian motion. It is a physical phenomenon due to the characteristics of fine particles. Generally, particles or microorganisms are in the liquid. 11----: ---, ------ II __ (Please read the precautions on the back before filling out this page) Line-This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 496752 A7-B7 V. Description of the invention (9) and others show a negative potential. 2 Particles such as ink, paper powder, or oil contained in the fountain solution also show negative potential. The catalyst 2 in the potential adsorption filter device 2 1 has a positive Z-potential property, and can absorb about 0.2. // m membrane filter can not remove these particles will be removed. In addition, according to such a potential absorption function, the particulate component can be removed without passing the fountain solution through the potential absorption filter device 2 under pressure. Fig. 4 is a detailed longitudinal sectional view of the activated carbon filter device shown in Fig. 1. The arrow in Figure 4 indicates the direction of the fountain solution. The activated carbon filter device 3 is contained in a box 30 for an activated carbon cassette 31 which can be exchanged as an activated carbon filter. The activated carbon cassette 3 1 contains granular activated carbon 3 3 in a fibrous non-woven fabric 3 2, a plastic membrane filter 3 4 and a metabolic filter 3 5 and a hot film. Granular activated carbon 3 3 is granular activated carbon with high quality and very hard particles, which can effectively absorb organic matter, color, odor and turbidity in fountain solution. The membrane filter 34 and the metabolic filter 35 are formed of fiber and melamine resin. The membrane filter 3 4 will absorb the garbage, rust and other sediments in the fountain solution, and the metabolic filter 3 5 will prevent the outflow of granular activated carbon 3 3. The dampening potion filtered by the membrane filter 34 is the organic matter and the like contained in the dampening potion by the granular activated carbon 3 3. However, the dampening potion part 1 1 of the offset rotary printing press is provided on the plate 16 'and has a potion tank and a plurality of rollers 1 3, 1 4 and 15 which are sequentially arranged from the plate 16. As shown in FIG. 2, the fountain solution circulation processing device 1 is connected to the fountain tank of the fountain solution section 11 of the offset printing press via connection paths 10a and 10b. The connecting lines 10a, 10b and this paper size are applicable to the Chinese National Standard (CNS) A4 specification (210 x 297 public love) -12--^ 丨 丨 1- 丨 丨 丨 丨 丨! --- h 丨 丨 Order- 丨, 丨 丨 ---- II (Please read the precautions on the back before filling this page) 496752 A7 — B7 V. Description of the invention (10) (Please read the precautions on the back before Fill out this page} The dampening solution circulation treatment device 1 is connected to the inlet 8 a and the outlet 8 b respectively. The dampening solution in the medicine tank 12 is connected through the connector 10a and the circulation paths 9a to 9d. The circulation of the dampening potion in the potion tank is sent to the circulation path 9 a by the online pump 4 forcibly, and the dampening potion in the potion pot 12 is connected through the connecting path 1 0 a ' The introduction port 8a enters the circulation path 9a, and is introduced into the potential adsorption filter device 2 through the circulation path 9a. In the potential adsorption filter device 2, the Z-potential absorption function is used to adsorb and remove Particle components such as ink, paper powder, or oil in the fountain solution. By using the potential absorption function to absorb and remove the particles, the particles can be removed without pressurizing the fountain solution through the potential absorption filter device 2. In addition, the lotion introduced into the activated carbon filter device 3 through the circulation path 9 C is decolorized And deodorization, it is sent back to the medicine tank 12 by the circulation path 9 d and the connection path 10 b. It is printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs so that it is equipped with the circulation path 9 a to 9 d The potential adsorption filter device 2 and activated carbon filter device 3 can reduce components such as BOD, COD, n-hexane, and SS while maintaining a predetermined flow rate, and can decolorize and deodorize the fountain solution. Used for a long period of time, it can be reused without being discarded. As a result, the waste liquid of dampening solution will not occur. Because it is necessary to entrust external waste liquid treatment, the running cost of dampening solution for offset printing can be suppressed. In addition, Offset printing can also be improved by using the thus-refined fountain solution for offset printing. In particular, in the fountain solution circulation processing device 1 according to the present embodiment, the flow side is respectively above the flow path 9 a to 9 d. Set potential adsorption filter device-13- This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) 496752 A7 __ B7 V. Description of the invention (彳 彳) Set 2 and set activated carbon on the downstream side The filter device 3 is formed because the particles such as ink, paper powder, or oil contained in the fountain solution are removed by the potential adsorption filter device 2 and passed through the activated carbon filter device 3. The life can be extended dramatically. Here, in this embodiment, the differential pressure between the fountain solution circulation processing device 1 and the transmitter 5 detects the differential pressure between the circulation paths 9 b and 9 d. When it exceeds 2 · 2 kg / cm2, the warning light 6 will be turned on and an alarm will be issued. When the potential absorption filter 2 has reached the threshold due to the catalyst 21, the differential pressure will rise rapidly, and the increase in this difference will be detected to absorb the potential The operator is informed of the exchange period of the filtering device 2 to prevent the flow rate of the dampening solution from exceeding the set number. In addition, the activated carbon filter device 3 is also used to detect the limit of the adsorption capacity by the increase in the differential pressure. --.--------------- r ---, order · -------- line-(Please read the precautions on the back before filling this page) Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, the paper size is applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) -14-