TW491869B - Block oligomers containing 1-hydrocarbyloxy-2,2,6,6-tetramethyl-4-piperidyl groups as stabilizers for lower polyolefin - Google Patents

Abstract

A product obtainable by (1) reacting a compound of the formula (Α) with a compound of the formula (β) in a stoichiometric ratio to obtain a compound of the formula (γ); (2) reacting the compound of the formula (β) with the compound of the formula (γ) in a molar ratio of 0.4:1 to 0.75:1; (3) reacting the end groups of the formula (δ) being present in the product of the reaction (2) with e.g. dibutylamine in a molar ratio of 2:1.7 to 2:3; the reactions (1) to (3) being carried out in an organic solvent in the presence of an inorganic base; and (4) transferring the groups of the formula being present in the product of the reaction (3) to groups of the formula, said transfer being carried out by reacting the product of the reaction (3) with a hydroperoxide in a hydrocarbon solvent in the presence of a peroxide decomposing catalyst; R1 is in particular a hydrocarbyl radical, B is e.g. N-(2,2,6,6-tetramethyl-4-piperidyl)-butylamino, R is e.g. 2,2,6,6-tetramethyl-4-piperidyl and R2 is e.g. hexamethylene.

Description

491869 Λ 7 B? V. Description of the invention (ί) (Please read the notes on the back before filling out this page) The present invention relates to a compound containing 1-carbohydroxyl-2, 2, 6, 6-tetramethyl-4 Monoamidine-based specific block oligomers, and their use as organic light stabilizers, thermal stabilizers, and oxidative stabilizers, especially synthetic polymers, and organic materials that are stable about this. In addition, the present invention is further directed to an intermediate product. The stability of synthetic polymers M 2,2,6,6-tetramethylpyridine derivatives has been disclosed in, for example, US — A — 4,0 8,6, 2 0 4, US — A — 4,33 1, 586 ; US — A — 4,335, 2 4 2; US-A-4,234,707; US-A-4,459,395; US — A — 4,492,791; US-A-5,204 , 473; EP-A-53, 77 5; EP — A — 357, 22 3; EP — A — 37 7, 3 24; EP — A — 462, 069; EP — A — 782, 994, and GB — A -2,301,106. The invention particularly relates to a product obtained from: 1) a compound of formula (α) printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

CI / Ya Β should be anti-chemical compound Lu Shi I and this paper size applies Chinese National Standard (CNS) A4 specification (210X 297 mm) 491869 Α7 Β7 V. Description of the invention (> Η-Ν-R ‘

R Ν——Η

H.C (β) Ν——Η The reaction ratio is a stoichiometric ratio, and M gives a compound of formula (7): α Ν Ν

Ν-R 丨 Β

cl (γ) (Please read the notes on the back before filling out this page) 印 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 2) The compounds of formula (/ 3) and formula (7) are reacted, and the mole ratio is 0 4: 1 to 0, 7 5: 1; preferably 0 5: 1 to 0 ♦ 7 5: 1 and especially 0 ♦ 5: 1; 3) the formula present in the reaction 2) the reaction product ( 3) terminal base

-CI (δ)

B and the compound of the following formula (€) -8 A paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 × 297 mm) 491869 A7 n ~ 8 repair jJ B7, the fifth and fifth invention description () A — Η (ξ) (reaction Mor ratio is 2 (terminal group) to 2: 3, preferably 2: 2 to 2: 2 + 6, especially 2: 2 to 2: 2 * 4); reaction 1) to 3) It is carried out in a stocking solvent and in the presence of an inorganic base; and 4) The group of formula (G — I) present in the reaction 3) tritium production: HC CH- h3c ch3 is converted into formula (G-II ) Group-based H3Cv CH3-(N-0-R1V; h3c ch3 The conversion is performed by the reaction of the product 3) and a hydrogen peroxide in a hydrocarbon solution and in the presence of a hydrogen peroxide decomposition solution; R ί is a hydrocarbon-based reactive group or a 0-R i is an oxy group; R 2 is a C 2-C i 2 alkylene, a C 4-C i 2 alkylene, and C 5--B-this paper size applies to Chinese national standards (CNS) A4 specification (210 X 297 mm) GI) (G-II) (Please read the notes on the back before filling this page) irOJ. -1 line-491869 hi B? V. Description of the invention (C 7 ring Alkylene, C 5-C 7 cycloalkylene di (ci-C 4 alkanes ), C i -C 4 alkylene di (C 5-C 7 cycloalkylene), phenylene di (C i -C 4 alkylene) or C 4-C i 2 alkylene, which is composed of 1, 4 a Diazine diyl, interrupted by -0-or > N-X i, X i is C i -C 1 Z yl or (C i -C i 2 alkoxy) carbonyl, or has the following definition of R4 One of the groups; or Rz is a group basis of the formula (I aa), (I a b) or (I a c):

(Bua) (Please read the notes on the back before filling out this page) • CH Factory CH——CH2- I〇 (lb) c = 〇I x2 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs X (lc) m is 2 or 3, X 2 is C i -C i 8 alkyl group, C 5 —C i 2 cycloalkyl group, which is not _ 1 0-This paper size applies to China National Standard (CNS) A4 specification (210X297) (Centi) 491869 Λ7 B? 5. Description of the invention (f) substituted or substituted by 1, 2 or 3 C i -C 4 alkyl; phenyl 'which is unsubstituted or substituted by 1 on phenyl , 2 or 3 C i -C 4, ¼ groups or C 1 -C 4 alkoxy groups; C 7-C 9 phenylalkyl, which is unsubstituted or substituted by 1 on a phenyl group, 2 or 3 C 1 -C 4 alkyl substituted; and the reactive groups X 3 are independent of C 2 -C! 2 alkylene; A is -0R 3, and n (R 4) (R 5 ), Or the group base of the formula (ί I): I, --4 ----- 衣-(Please read the precautions on the back before filling this page)

(id is printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. R 3, R 4 and R 5 (same or different) are c 1 -c 1 δ alkyl, C 5-C 1 2 cycloalkyl, which is not Substituted 1 ^ is substituted by 1 '2 or 3 C i —C 4 — groups; c 3 — C i S — group, which is unsubstituted or consists of 1, 2 or 3 C i -C 4 alkynyl or C 1 -C 4 alkoxy substituted; C 7-C 9 phenylalkane * 'which is unsubstituted or is substituted by 1, 2 or 3 C!-C 4 _ SK's 0-hydrofuryl group or Cz-C4 alkyl group, which is ^ on the 2nd, 3rd, or 4th ^ & Gan "Γ-C 4 alkyl) amine from 10 Η, C!- C 8 alkoxy, substituted by di (c 1 group or group group of formula (III); 11 This paper size applies Chinese National Standard (CNS) A4 specification (21〇 > < 297 mm) 491869 Λ7 Β7 5 Description of the invention (U)

γ / _Xn—- (HO \ _ / Y is a 0 —, —CH2 —, a ch2 ch2 — or> N — CH 3; and R 3 is additionally hydrogen or a N (R 4) (R 5) in addition Is a group group of formula (III); X is a 0—or > 1 R— R 6 is C i —C i 8 alkyl, C 3 —C i 8 alkenyl, C 5-C i 2 ring Alkyl, which is unsubstituted or substituted with 1, 2 or 3 C i -C 4 alkyl; C 7 -C 9 phenylalkyl, which is unsubstituted or substituted by 1 on phenyl , 2 or 3 C i -C 4 alkyl substituted; tetrahydrofuranyl, a group of the formula (G-I), or C 2 -C 4 alkyl, which consists of 10 at the 2, 3 or 4 position Η, C i —C 8 alkoxy, di (C i -C 4 alkyl) amino or group (III) substituted, printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the Please fill in this page again) R has one of the definitions of Re above, and B has one of the definitions of A above. The conversion of formula (G — I) to formula (G-II) can be similar, as described The method is performed in ϋ S — Α — 4,9 2 1, 9 6 2, which is incorporated herein by reference. R i It is defined according to the reaction 4) hydrocarbon solvent used in the present paper -12- applies China National Standard Scale (CNS) A4 size (210X 297 mm) 491 869

Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of Invention (") R 1 is preferably a hydrocarbon group having 5 to 18 carbon atoms. R 1 is especially CS — C 1 8 alkyl, C 5 — C 1 8 alkenyl, C 5 — C i 8 alkynyl, c 5 — C iz cycloalkyl, which are unsubstituted or substituted with C i -C 4 alkyl; c S — C i 2 Cycloalkenyl, which is unsubstituted or substituted with C i -C 4 alkyl; a bicyclic or tricyclic hydrocarbon group having 6 to 10 carbon atoms, or C 7 -C9 phenylalkyl, which is unsubstituted Substituted or substituted with ci-C 4 alkyl on the phenyl group; and the hydrocarbon solvent in reaction 4) is based on R i (C s-C ia complex, C 5-C 1 8 alkenyl, CS-Ci 8 block, CS — C 1 2 cycloalkyl, which is unsubstituted or substituted by ci-C 4 alkyl; c 5 — Ci 2 cycloalkenyl, which is unsubstituted Or substituted by c 1 -C 4 alkyl; a bicyclic or tricyclic hydrocarbon group having 6 to 10 carbon atoms' or C 7 -C 9 phenylalkyl, which is unsubstituted or on a phenyl group By C 1 -C 4 fluorenyl). Another according to the invention In a preferred embodiment, R 1 is heptyl, octyl, cyclohexyl, methylcyclohexyl, cyclooctyl, cyclohexenyl, α ~ methylbenzyl or 1,2,3,4 tetrahydrocycloalkane And the hydrocarbon solvent in reaction 4) is (according to R 1) heptane, octane, cyclohexane, methylcyclohexane, cyclooctane, cyclohexene, ethylbenzyl or tetraline (t etra 1 i η) 〇 According to a preferred embodiment, R i is octyl or cyclohexyl, and the hydrocarbon solvent of reaction 4) (according to R 1) is octane or cyclohexane. Contains no more than 1 Examples of alkyl groups with 8 carbon atoms are methyl, ethyl, -13- This paper size applies Chinese National Standard (CNS) A4 (210X297 mm) (Please read the precautions on the back before filling this page) m mi ϋϋ ϋϋ ϋ · ϋ ϋϋ Min i-ϋ--.mi — iia ^ i ϋϋ ι_ϋ · 1ιιϋ —ϋ ϋϋ —ϋϋΝ n_l ϋ — «ϋϋ · · ϋϋ ϋϋ — κι —ϋ J—! 4 4---I- ....... ..... I -51— I: I-491869 Λ7 B7 V. Description of the invention (fen) propyl, isopropyl, butyl, 2-butyl, isobutyl, pentyl , 2-pentyl, hexyl, heptyl, octyl, 2 Ethylhexyl group, a t-octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, hexadecyl and octadecyl. R i is preferably C 6 -C i 2 alkyl, especially heptyl or octyl. R 4, R 5 and R s are preferably C i -C 8 alkyl, especially C i -C 4 alkyl. An example of an alkyl group substituted by 10 fluorene is 2-hydroxyethyl. Examples of C 2 -C 4 alkyl substituted via C i -C 8 alkoxy, preferably C i -C 4 alkoxy, especially methoxy or ethoxy 2 -methoxyethyl Group, 2-ethoxyethyl, 3-methoxypropyl, 3-ethoxypropyl, 3-butoxypropyl, 3-octyloxypropyl and 4-monomethoxybutyl. Via a di (C i -C 4 alkyl) amino group, a preferred C 2 -C 4 alkyl group substituted by a dimethylamino group or a diethylamino group is an example of a 2-dimethylaminoethyl group, 2-ethylaminoethyl, 3-dimethylaminopropyl, 3-diethylaminopropyl, 3-dibutylaminopropyl and 4-diethylaminobutyl. Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the notes on the back before filling out this page) The formula (I I I) is preferably ^. A preferred example of a C 2 -C 4 alkyl group substituted by a group of formula (III) is-14- This paper is again applicable to China National Standard (CNS) A4 (210X297 mm) 491869 Λ7

V. Description of the invention (y) \ _ / N— (ch4t- ~ The group group is particularly good Γ ~ \., ^^ — (CH2) 2:-〇 Unsubstituted or via 1, 2 or 3 C Examples of Cs-Ci 2 cycloalkyl substituted with i-C 4 alkyl are cyclopentyl, methylcyclopentyl, dimethylcyclopentyl, cyclohexyl, methylcyclohexyl, dimethylcyclohexyl, trimethyl Cyclohexyl, tert-butylcyclohexyl, cyclooctyl, cyclodecyl and cycloundecyl. Unsubstituted or substituted cyclohexyl is preferred. Bicyclic rings having 6 to 10 carbon atoms A preferred example of a tricyclic hydrocarbon group is 1,2,3,4-tetrahydrocycloalkyl. The comparison of C s —C 1 2 cycloalkenyl which is unsubstituted or substituted with C i -C 4 alkyl. A good example is cyclohexenyl. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs. C Please read and read the notes on the back. Please fill in this text. Alkenyl, butenyl, hexenyl, ~ ι-alkenyl and octadecenyl. Among them, alkenyl whose carbon atom is saturated at the first position is preferred. 'Allyl' is particularly preferred. Example of alkynyl is pentyne Or octynyl ° Examples of phenyl substituted with 1, 2 or 3 C ί -C 4 alkyl or C! -C 4 alkoxy are methylphenyl'dimethylphenyl, trimethylbenzene Base-1 5-This paper size applies Chinese National Standard (CNS) Α4 specification (21〇 > < 297mm)

Five economics, Shao Central Bureau of quasi-branch staff consumer cooperative printed a description of the invention (γ) 'tert-butyl-phenyl, di-tert-butyl-phenyl, 3,5-di-tert-butyl-tert-4-methyl Phenyl, methoxyphenyl, ethoxyphenyl and butoxy (please read the notes on the back before filling this page). Examples of C 7 -C 9 phenylalkyl, unsubstituted or substituted with 1, 2 or 3 C ^ -C4 alkyl on phenyl are benzyl, methylbenzyl, ~ methylbenzyl , Trimethylbenzyl, tert-butylbenzyl, and 2-phenylacetamidine. Benzyl is preferred. Examples of alcoholic groups (fatty, cycloaliphatic or aromatic) containing not more than 12 carbon atoms are methyl, ethyl, propyl, propyl, butyl, pentyl, hexamyl, heptyl , Octyl and benzamyl. C 1 -C 8 alkyl and benzyl are preferred. * Ethyl is particularly preferred. Examples of (C i -C i 2 alkoxy) carbonyl are methoxycarbonyl, ethoxycarbonyl, propoxycarbonyl, butoxycarbonyl, pentoxycarbonyl, hexyloxycarbonyl, heptyloxycarbonyl, Octyloxycarbonyl, nonoxycarbonyl, decyloxycarbonyl, undecyloxycarbonyl and dodecyloxycarbonyl. Examples of alkylenes containing not more than 12 carbon atoms are ethylene, propylene, trimethyl, tetramethyl, pentamethyl, hexamethyl, octamethyl, dimethyl and dimethyl. Examples of R 2 are C 2 -C 8 alkylene or C 4 -C 8 alkylene, especially C 2 -C 6 alkylene, and preferably hexamethylene. An example of C 4 -C i 2 ethylenic is 3-hexene. An example of C 5 -C 7 cycloalkylene is cyclohexylene. The example of C 4 -C iz alkylene interrupted by 1,4 monopyrazinediyl is a 16- This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 491869 A7 B7 V. Description of the invention (丨ί)

(Please read the notes on the back before filling in this page) A CH2CH2CH2—N, ^ — CH2CH2CH2— 〇 Example of C 4 -C! 2 alkylene interrupted by 10—such as 1, 2, or 3—0— For 3-oxapentane-1'5-diyl, 4-oxaheptanyl-1'7-diyl'3'6-oxanyl-1,8'-diyl, 4,7-diyl Oxadecane-1,110-diyl, 4,9-dioxadodecane-1,12-diyl, 3,6,9-trioxaundecane-1,1 1-12 And 4,7,1 0 -trioxatridecyl-1,1 3 -diyl. An example of C 4-c 1 2 firing interrupted by > N — X i is:

One C Η 2 C Η 2 C Η 2-N (X 1) One C Η 2 C Η 2-N Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (X!) One C Η 2 CH 2 C Η 2 —, Especially one C Η 2 CH z CH z one N (C Η 3) one CH 2 CH z-N (C Η 3) ~ C Η 2 C Η 2 C Η 2-〇c 5 one C 7 cycloalkylene di (C i -C 4 alkylene) is exemplified by cyclohexylene. An example of C i -C 4 alkylene di (C 5-C 7 cycloalkylene) is A-17- This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) 491869 Λ7 B7 V. Description of the invention ( / >) An example of the printing of dicyclohexyl and isopropyl dicyclohexyl 0 by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs is an example of phenylene dimethyl (C 1 -C 4 burning). 5 R in the compound of formula (7) is preferably a group group of formula (G—I). The preferred products are among them: R 2 is C 2 -C 1 2 alkylene $ C 5 -C 7 cycloalkylene, C 5 — C 7 Naphthene (C 1 — C 4 calcined) C 1 — C 4 Naphthene (C 5 — C 7 cycloalkane) > Phenylene (C 1-C 4 calcined) Or C 4 -C 1 Z alkylene f which is interrupted by — 0 — or > N-X 1 > X 1 is C 1 -C 1 2 fluorenyl or (CI -C 1 2 alkoxy) Carbonyl > or has one of the definitions of R 4 above or RZ is — formula ( The group groups R 3 9 R 4 and R 5 (same or different) of I 1 b) are C 1 -C 1 8 alkyl 9 C 5 —C 1 2 cycloalkyl 9 which are unsubstituted or via 1 > 2 or 3 C 1 -C 4 alkyl substituted phenyl radicals which are unsubstituted or substituted via 1 »2 or 3 C 1 -C 4 alkyl or C 1 -C 4 alkyloxy C 7 -C 9 phenylalkyl 5 which is unsubstituted or substituted on the phenyl with 1 > 2 or 3 C 1 -C 4 alkyl and R 3 is additionally hydrogen or N (R 4 ) (R 5) is also a group group of formula (III). R 6 is C 1 —C 1 8 alkyl, C 5 -C 1 2 cycloalkyl, which is unsubstituted% or is represented by 1 > 2 or 3 A C 1 -C 4 heptyl substituted C 7 —C 9 phenylalkyl 9 which is unsubstituted 5 or -18-I .--------- ^^ on phenyl Clothing-(Please read the precautions on the back before filling this page), \ ST > This paper size applies to Chinese national standards (CN S) A4 size (210X297 mm) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 491869 A 7 B7 V. Description of the invention (丨 Poor)

1, 2 or 3 C 1 -C 4 alkynyl substituted; or a group group of formula (G-I) ^ is also a preferred product among them: R 2 is C 2 -Cl 〇 焼, cyclohexyl 5 ring Hexylene (Ci-C 4) alkylene) 'C 1 -C 4 fired bicyclohexylene or phenylene (c ί -C 4 alkylene); R 3, R 4 and RS (same or different ) Is C i -ci 2 alkyl, C s -C 7 cycloalkyl, which is unsubstituted or substituted with 1, 2 or 3 C i -C 4 alkyl; phenyl 'which is Unsubstituted or substituted with 1, 2 or 3 C ^ -C4 alkyl; benzyl, which is unsubstituted, or substituted with ci-C4 alkyl on phenyl; Or -N (R4) (R5) is additionally a group group of formula (III), and Rs is C: -Ci2alkyl, C5-C7cycloalkyl, which is unsubstituted , Or substituted with 1, 2 or 3 C i -C 4 alkyl; benzyl, which is unsubstituted, or substituted with 1, 2 or 3 C i -C 4 alkyl; or Is the group basis of the formula (G — 1). The better products are:

Rz is Cz-Cs; R 3, R 4 and R 5 (both same or different) are C i -C 8 alkyl, cyclohexyl, which is unsubstituted or substituted by methyl; Phenyl, which is unsubstituted or substituted by methyl; benzyl or -N (R4) (R5) is additionally 4-morpholinyl; and R6 is C! -C8 alkyl , Cyclohexyl, which is unsubstituted, or -1 9- This paper size applies to China National Standard (CNS) A4 (210X297 mm) (Read the notes on the back and fill out this page)

Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs, 1T 491869 Λ7 B7 V. Description of the invention (t small) Substituted by methyl; benzyl or a group base of the formula (G-I). Particularly preferred products are: where R i is octyl or cyclohexyl, and the hydrocarbon solvent in reaction 4) is (depending on R i) octane or cyclohexane; R 2 is C 2-C 6 Alkylene; A is a group of N (R 4) (R 5) or a group of formula (II); R 4 and R s (same or different) are C ^ -C 8 alkyl; or N (R 4 ) (R s) is additionally 4-morpholinyl; X is > N-R c '; R 6 is C 1 -C 8 alkyl; and B has one of the definitions of A. Also particularly good products are:

Ri is octyl or cyclohexyl, and the hydrocarbon solvent in reaction 4) is (depending on R i) octane or cyclohexane; R 2 is C 2 -C 6 alkylene; R is a formula (G — A group group of I); A is a group N (R 4) (R 5); R 4 and R s (same or different) are C i -C 8 alkyl groups; B is a group group of formula (II); X is > N-R s; R 6 is C i -C 8 alkyl. -20-This paper size is applicable to Chinese National Standard (CNS) A4 (210X297mm) (Please read the precautions on the back before filling in this page

1T 491869 Λ7 B7 _ V. Description of the invention ((€) is used to react 1), 2) and 3) Organic soluble surface, especially aromatic strip hydrocarbons or fatty strip ketones. Examples of aromatic fluorene hydrocarbons are toluene , Xylene, Trimethylbenzene 'Cumene, Dicumylbenzene and tert-Butylbenzene. Examples of fatty ketones are methyl ethyl ketone, methyl butyl ketone, methyl isobutyl ketone, Pentyl ketone, ethyl butyl ketone, di-n-propyl fluorene 'methylhexyl ketone and ethyl pentyl ketone In particular, water-insoluble compounds are preferred. The preferred solvents are toluene, xylene, methylbutyl ketone, and methyl isobutyl ring. Xylene and methyl isobutylphosphonium are particularly preferred. Examples of inorganic bases used in the method of the invention are sodium hydroxide, potassium hydroxide, sodium carbonate and potassium carbonate. Sodium hydroxide is preferred. The reactions i) to 3) are preferably carried out in an inert gas, especially under nitrogen.

Depending on the solvent used, the reaction temperature of reaction 1) is, for example, from 10 ° C to 90 ° C, preferably 20 to 90 ° C, especially 50 ° C, which is consumed by employees of the Central Standards Bureau of the Ministry of Economic Affairs Printed by the cooperative (please read the notes on the back before filling this page) to 8 5 0C. Reaction 2) Conveniently, it can be carried out in a closed system at a temperature of K such as 110 ° C to 200 ° C, preferably 130 ° C to 190 ° C, especially 1 5 ο υ Up to 16 0 ° c. When the reaction mixture is heated to the set temperature, the reaction pressure increases (this is because the reaction is performed in a closed system). Due to the low boiling point of the solvent used, the pressure in the reactor is generally -2 1- This paper size applies to China National Standard (CNS) A4 (210X297 mm) 491869 Λ7 B7

V. Description of the invention (1 U force is 3 to 8 bar, such as 4 to 6 bar. Reaction 3) It can be conveniently performed in a closed system at a temperature of M such as 110 to 180 ° C, preferably 1 30 ° C to 170 ° C, especially 14 0 ° C to 16 Ο Ό. Because of the high temperature, the pressure in the reactor is generally measured at 3 to 8 bar, such as 4 to 6 bar. If necessary, after completion of reaction 3), the compound of formula (ξ) and the last unreacted starting material can be removed from the final mixture by distillation or using ordinary purification techniques. The product of reaction 3) can be conveniently isolated before reaction 4). The peroxide decomposition catalyst used in reaction 4) is, for example, a metal carbonyl compound 'metal oxide, metal acetamidine pyruvate, or metal alkoxide' wherein the metal is selected from the group consisting of IVb, Vb of the periodic table, The metals of VI b, VII b and VIII are preferably vanadium (III) acetamidine propionate, cobalt carbonyl, chromium (VI), titanium isopropoxide (IV), titanium tetrabutoxide, molybdenum hexacarbonyl , Molybdenum trioxide and the like. The best catalyst is M03. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the notes on the back before filling this page) Suitable hydrogen peroxide is tert-butyl hydroperoxide, tert-pentyl hydroperoxide 'tert-hexyl peroxide Hydrogen, tert-octyl hydroperoxide, ethylbenzene peroxy ib hydrogen 'tetraline hydrogen peroxide or limonene (= isopropylbenzene) hydrogen peroxide. The best ft of hydrogen peroxide is tert-butyl hydroperoxide. In reaction 4), for each mol of sterically hindered amine of the formula (G-1) present in the product of reaction 3), 2 to 8 mol, preferably 3 to 6 mol of hydrogen peroxide, is used. · 〇〇1 ～ 〇 ♦ 1 mole, preferably -22-This paper size applies to China National Standard (CNS) A4 (210X297 mm) 491869 A7 B7

V. Description of the invention (I ί) to: 5 agents and solvents that are in contact with each other to dehydrogenate and carbonize oxygenated amines ο 2 mol to 5 ο 〇1 ♦ ο ο 0 better than 5, ο ο ο ο Mo , ο ο 3

(G- (Please read the precautions on the back before filling out this page)

The printing of employee consumer cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs is carried out at, for example, 75 ° C to 160 ° C ', preferably 100 ° C to 150 ° C. In reaction 4), when the sterically hindered amine group of the formula (G-1) is first treated with an aqueous hydrogen peroxide solution in the presence of a hydrogen peroxide decomposition catalyst and in an inert solvent (such as similarly described in US- A — 4, 6 9 1, 〇 1 5 method), the initial reaction products obtained in a very short time-2 3-This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 491869 Economy A7 B7 printed by the Consumer Standards Cooperative of the Ministry of Standards of the People's Republic of China (S) is equivalent to the N-oxy intermediate (~ 〇R i = oxy), which is highly dyed and can be separated independently. Therefore, other preferred embodiments of the present invention relate to a product obtained from the above reactions 1) to 4), wherein the reactive group 10-R1 is an oxygen group, and the carbonitride solvent used in the reaction 4) It is an inert organic solvent, preferably toluene or 1,2-dichloroethane. When the organic solvent of reaction 4) is a hydrocarbon compound having a unstable hydrogen atom, when a hydrogen peroxide which is far more than the molar amount required for the conversion of the amine group to the relative N-oxy derivative is retained, and when the reaction mixture Is additional heating to an appropriate temperature (preferably at 100 ° C to 150 ° C) at normal time, then the N-oxy compound (can be obtained from the original amine, or during the reaction process) As the starting intermediate) and the hydrocarbon solvent will further react to form the corresponding N-alkoxy derivative. In reaction 4), the original reaction mixture was colorless, but became highly stained when the N-oxyl intermediate was formed. When this N-oxyl compound is converted to a colorless N-alkoxyl product, the color disappears. Therefore, it is important for this method to have ~ internal color indicator K to show the extent of the reaction. When the reaction mixture becomes colorless, it means that the colored N-oxy intermediate is completely converted to the N ~ alkoxy product. An embodiment of the present invention also relates to a product obtained from a hydrogenation reaction 4) (wherein 0 R i is an oxygen group in the formula (G-II)) to obtain a product having a group of the formula (G-III) -24 A paper size is applicable to Chinese National Standard (CNS) Α4 specification (210X297 mm) J --------! (Please read the precautions on the back before filling this page), 1T 491869 Λ 7 Β7 V. Invention Explanation (//)

This hydrogenation reaction is performed according to conventional methods, for example, in an organic solvent such as methanol or ethanol, and in the presence of a hydrogenation catalyst, preferably palladium or P t 0 2 on carbon, as described in US-A — 4, 6 9 1 »0 1 50 0 If necessary, reaction 4) The product can be purified by one of the following methods: Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back first) Fill out this page again) a) Decompose the remaining peroxide and evaporate the solvent to obtain a crude solid product. This solid product is stirred with an inert solvent such as cyclohexane, octane, hexane, petroleum ether, xylene, toluene, acetone, methyl ethyl ketone, ethyl acetate, butyl acetate, tert-butyl alcohol, Tert-pentyl alcohol, isopropyl alcohol, ethanol, methanol, chloroform, dichloromethane, acetonitrile, diethyl ether, dibutyl ether and / or water. This mixture can be stirred while heating. After stirring, the mixture is cooled, the solid product is collected by filtration, and then dried. b) The residual peroxide is decomposed, the solvent is partially evaporated, and the residue is filtered to obtain a solid, which is washed with an inert solvent like one of the above solvents, and the obtained solid product can be quenched and then dried. c) The residual peroxide is decomposed, and the solvent is evaporated at a high temperature to obtain a melt. Mix the hot melt with an inert solvent, like one of the above solvents (-25-This paper size applies to Chinese National Standard (CNS) A4 (210X 297 mm) 491869 Λ7 B7 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Preparation of "_ 一 _ V. Description of the invention (I) 1 II can be quenched) > Filter to collect the precipitate $ and then dry it 0 Variations of this step 1 1 | The formula includes mixing the hot melt and the solvent m and cooling the mixture. Result 1 I __ * Precipitation > or mixed hot melt and solvent 9 and then add 埶% to make it £ 1 ψ 1 Please dissolve the solid in the solution and cool it to obtain the precipitate 0 Read back 1 1 1 I d) Decompose the residual peroxide solvent and evaporate it at high temperature 9 to obtain a molten 1 I m product. 0 This melt is dissolved in an inert solvent% like one of the above solvents (please note 1 I plus or without heating) ) Then distilled Some excess solvent was taken out and the result was concentrated. Then fill in the f 1 solution > this solution and-. After the second solvent was mixed at high temperature 9 like one of the above-mentioned leaching agents > so that the product precipitated out and collected the solid product by filtration. 9 and dry 0 1 1 more particularly the product of anti-trfst 懕 4) is preferably M purified by the following method 1 1: 1 ordered after reverse 4) is completed, the crude reaction mixture is cooled to 5 0 ° c 9 and 1 Treatment with 1 Μ 2 0% sodium sulfite aqueous solution until the concentration of residual peroxide 1 1 reduced to 0 ♦ 5% under 〇 separated the aqueous layer 5 added under reduced pressure 4 \ \ \ product 1 1 the product was concentrated 〇The crude product was dissolved in an excess of t-butyl alcohol. F The solution was heated under reduced pressure to remove the solvent.> The solid concentration was 50%. 0 Ί I slowly add this solution to cold methanol. Medium ♦ Precipitate 9 Alcohol 1 I Washing and drying under vacuum 0 1 Generally, the starting materials used in the above methods are conventional. 0 In the case of 1 1 which is not a commercial production, they can also be prepared similarly to the conventional methods 1 1 A compound of formula (α) of 0 1 I can be prepared, for example, by reacting cyanuric chloride II with a compound of formula B 1 1 I Η. The reaction is a stoichiometric ratio > and 1 1 I-26 1 " " 1 1 This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) 491869 Λ7 B7 ___ V. Description of the invention (〆 /) An organic solvent and an inorganic base are carried out. It is also appropriate to prepare the compound of the formula (α) using the same solvent and inorganic base of the above reactions 1) to 3). If desired, the reaction '1' can be carried out immediately after the starting material of formula (: α) is prepared without isolating the compound of formula (α). Some formula (/ 3) starting materials are described in, for example, W 0 — Α 9 5 / 21,157; US-A-4,316,83 7 and 113 —A-4,743,688. Other embodiments of the present invention are a product obtained from the above reactions 1) to 3). Among them, the nitrogen atom in the group group (please read the precautions on the back before filling this page)

Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs is C i -C 8 alkyl, c 2-c 8 hydroxyalkyl, 0,-0 ，, C 1-C 1 8 alkoxy (such as ci-C 1 8 焼 oxy or CS — Ci 2 cycloalkoxy), C 一 2 CN, C 3-C s alkenyl, C 3 — C 6 alkynyl, C 7 — C 9 phenylalkyl (which may be Unsubstituted or substituted with 1,2 or 3 C i -C 4 alkyl groups on the phenyl group); or C i -C 8 fluorenyl substituted products can be reacted similarly to the above reaction 1) to 3-2 7 -This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 491869 kl B7 5. The method of invention description (yy)) is prepared by using appropriate starting materials. The nitrogen atom is preferably substituted by a C 1 -C 4 alkyl group, especially methyl hydrazone, those starting materials containing a group of the formula,

It can be prepared, for example, by methods similar to those described in U S — A — 4,9 2 1, 9 6 2; US-A-5,021,577 and US — A-5,204, 4 7 3. The product of reaction 3) is not a single specific compound, but a compound having a molecular weight distribution. Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) The polydispersity (ρ 0 1 y d p s p r s i t y) indicates the molecular weight distribution of the polymer compound. In the present invention, the polydispersity is the ratio of the weight average molecular weight (M w) to the number average molecular weight (Mη). The closer the M w / M η value is to 1, the compound is fluorene-dispersed. Once there is only one molecular weight, and No molecular weight distribution. The narrow molecular weight distribution is characterized by a polydispersity (M w / M η) close to one. -28-The size of this paper applies Chinese National Standard (CNS) A4 specification (210X 297mm) 491869 Λ7 B7 V. Description of the invention (3 should be the same as 1 to 1 ♦ Special 1X, degree 7 scattered ♦ 1 cent to 1 3 of the product ♦ 1 or better than 6 * 0. to 3 should be the opposite meaning. Note 6 Requires% ermo_ 5 less than, for example, including the wrong end of the product group. Ermo 1 Yu Shao: Concentration of the ear-produced parasitism 2 The cover of the line is covered with du MW Special Terminal A λ, γB (Please read the precautions on the back before filling this page) Printed by the Consumers Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs system

When R reactions 1) and 2) proceed, a by-product of the ring structure compound of the following formula can be formed

Η R

I Ν- Β 弋, Ν Ν: Ν-

H3C meaning I CH, h3c n " ^ ch;

H 29 This paper size applies Chinese National Standard (CNS) A4 specification (210 '乂 297 mm) 491869 Λ7 B7 V. Description of the invention (〆 [〇From US — A — 4, 4 4 2, 2 5 0 It can be known that The compounds are conventional and may be present in the product of reaction 3) in an amount of less than 15 mol%. The product of reaction 3) preferably comprises a monodisperse compound of formula (M-I), M — II) Monodisperse compounds, a mixture of monodisperse compounds of formula (M—III), and monodisperse compounds of formula (M—IV), these compounds differ only in the number of repeating units, (please (Read the notes on the back before filling out this page)

This paper size applies to Chinese National Standard (CNS) Α4 specification (210X 297 mm) 491869 Λ7 Β7 V. Description of invention (y <)

(Please read the notes on the back before filling this page) The printed reaction groups A, B, R and R 2 of the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs are as defined above, and the total amount of compounds of formula (M-I) 15 to 45 mole%, such as 20 to 45 mole% or 25 to 45 mole%, or 30 to 45 mole%, or 30 to 40 mole%, a compound of formula (M-II) The total amount is 15 to 35 mol%, such as 15 to 30 mol%, or 15 to 25 mol%, or 20 to 25 mol%, and the total amount of the compound of formula (M-III) It is 3 to 18 mole%, such as 3 to 12 mole%, or 5 to 12 mole% (relative to the total mixture, = 100 mole%). The preferred mixture is a monodisperse compound containing formula (M — I V): -31- This paper size is applicable to Chinese National Standard (CNS) A4 specification (210 × 297 mm) 491869 Λ7 Β7

5. Description of the invention (A) r-7γ-α ΝγΝ and wherein the total amount of the compound of formula (M-IV) is 1 to 15 mole%, such as 1 to 10 mole%, or 1 to 5 mole% (Relative to total mixture) (1000 mole%). Reaction 4) is about the group of formula (G-1) in a mixture containing compounds of formula (M-1), (M-II), (M-III) and (M-IV): (Gl) ( Please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (G — II)

(G-ll) Ⅰ 32-This paper size applies to Chinese National Standard (CNS) Α4 size (2K) × 297 mm) 491869 Λ7 Β7 V. Description of the invention (4)

After the conversion, the compounds of formula (P-I), (P-II), (P-III), and (P-IV) in the product of the next reaction are equivalent to the initial formula (M-I), ( M-II), (M-III) and (M-IV) compounds because the backbone of these compounds is not affected during the reaction. Therefore, other embodiments of the present invention relate to a monodisperse compound containing formula (P-I), a monodisperse compound of formula (P-II), a monodisperse compound of formula (P-III), and a formula (P-IV) ) 箪 A mixture of dispersion compounds. These compounds differ only in the number of repeating units, (please read the notes on the back before filling this page) Printed by Standards Bureau's Consumer Cooperative

Α · (Ρ-) This paper size applies to Chinese National Standard (CNS) Α4 specification (210X297 mm) 491869 Λ7 B7 V. Description of the invention

• N

N N. / 丫 B *

N

N -in

A * 1 N (P-

N ----------- ^ 衣-(Please read the precautions on the back before filling this page)

-N

Γ N N. R *

* A — N

N (p-l

， 1Tir · Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5 ， 4% to ears 3 to 5 or 4 > to% 5 ears 1 to 5 amount 4 to 2% of 5 ears or 2 ears ο Combine% 4, turn ear to 丨 Mo ο 15 3 I 4 or P to, (ο% Formula 2 ear such as 5, 2% to ear ο Mo 2 5 or 3, to% 5 ear 1 Mo is 5 amount 2 total 1 to 5 in total, chemical composition%) Ear I Mo I ο I 3 Ρ to (5 Formula 1) This paper size applies Chinese National Standard (CNS) A4 specification (210X 297 mm) 491869 A7 B7 V. Description of the invention U /) mole%, and the total amount of the compound of formula (P-III) is 3 to 18 mole%, such as 3 to 12 mole%, or 5 to 12 mole% (calculated relative to the total mixture) , = 100 mole%); and R i is hydrogen, a hydrocarbyl reactive group, or a 0-R i is an oxy group; R 2 is a C 2 -C i 2 alkylene, C 4 -C iz alkylene, C 5-C 7 cycloalkylene, C 5-C 7 cycloalkylene di (C i -C 4 alkylene), C i-C. 4 alkylene di (C 5-C 7 cycloalkylene), phenylene Two (C i —C 4 alkylene) or C 4 -C 1 2 alkylene, which is composed of 1, 4 Diradical, interrupted by 0 — or> N_Xi, Xi is 匚 ^ C i 2 enantiomer or (C i -C i 2 alkoxy) carbonyl, or has one of the definitions of R 4 under M; Or R 2 is printed by (I a a), (I a b) or (I a c) printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

一 CH? —CH—CH? —— I 〇I c = 〇I X2 -35- (la) (lb) ϋϋ 1 ^ ιϋ emMfmmf n ^ em 1 · ^ — ^ — —-HI βίβ ίΜ ^ I — ^ ϋ— a —.—— emtMmmmmMm \ Hi · — l_i_la.i — ^ ϋ n · ^ — (Please read the precautions on the back before filling in this one hundred. This paper size applies to Chinese National Standard (CNS) A4 specification (210X297) (Centi) 491869 Λ7 B7 V. Description of the invention UG) κ ×: (IC) m is 2 or 3, X 2 is C i -C i 8 alkyl, C 5 -C i 2 cycloalkyl, which is not * 2 or 3 C i -C 4 alkyl substituted; phenyl substituted or substituted, which is unsubstituted or substituted with 1, 2 or 3 CC i -C 4 alkoxy; C 7-C 9 Phenylalkyl, which is unsubstituted or substituted with 1, 2 or 3 C i -C 4 alkyl groups on the phenyl group; and the reactive groups X 3 are independently C 2-C i 2 Alkylene; A meter is -0R3, -N (R4) (R?), Or a group group of formula (0-IV): C 4 alkyl or------------ (please (Read the notes on the back before filling out this page)

, 1T printed by HX CH, Consumer Cooperatives of Central Standards Bureau, Ministry of Economic Affairs,

(G-IV) R 3, R 4 and R 5 (same or different) are C i -C i 8 alkyl, C 5 -C i 2 cycloalkyl, which are unsubstituted or consisting of 1, 2 Or 3 -36-This paper size applies Chinese National Standard (CNS) A4 (210X297 mm) 491869 Λ7 B7 5. Description of the invention (I) C i -C 4 alkyl substituted; C 3 — C i 8 Alkenyl, phenyl, which is unsubstituted or substituted with 1, 2 or 3 C i -C 4 alkyl or C i -C 4 alkoxy; C 7 -C 9 arylalkyl, Is unsubstituted or substituted on the phenyl group by 1, 2 or 3 C i -C 4 alkyl groups; tetrahydrofuranyl or C 2 -C 4 alkyl groups which are at the 2, 3 or 4 position 10Ο, C i -C 8 alkoxy, bis (C i -C 4 alkyl) amino or a group of formula (III); (Please read the notes on the back before filling this page)

Y is a 0 —, a CHz —, a CH2 CHz — or> N-C Η 3; and R 3 is additionally hydrogen or a N (R 4) (R 5) is also a group group of formula (III); X is a 0 — or> N — Re; printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs, R 6 is C i -C i 8 alkyl, C 3 — C i 8 alkenyl, C 5 — C i 2 cycloalkyl, which is unsubstituted or substituted with 1, 2 or 3 C i -C 4 alkyl; C 7-C 9 phenylalkyl, which is unsubstituted or on phenyl Substituted by 1, 2 or 3 C! -C4 alkyl groups; tetrahydrofuranyl, a group group of formula (G-II), -37-This paper size applies to Chinese National Standard (CNS) A4 specification (210X 297 mm) ) 491869 A7 B7 V. Description of the invention (0)

(G-II) or C 2 -C 4 alkyl, which is at the 2, 3 or 4 position by 10 Η C 1-C 8 alkoxy, bis (C i -C 4 alkyl) amino or Group III) is substituted; R * has one of Rs as defined above, and B has one of A as defined above. The preferred mixture is a single-part compound containing formula (P — I V): A ·-丨 Factory N YA N 巳 * R *

CH3 CH,

NyN B * (P-IV) 丨. 11 Clothes Order ~ (Please read the notes on the back before filling this page) Printed by A, B, R, Ri and Ruler 2 is as defined above, and the total amount of the compound of formula (P-IV) is 1 to 15 mole%, such as 1 to 10 mole%, or 1 to 5 mole% (relative to the total mixture) ( -3 8 ~ This paper size is in accordance with Chinese National Standard (CNS) A4 specification (210X297 mm) 491869 A7 B7 V. Description of the invention) = 1 mol%). The preferred mixture is: where R i is octyl or cyclohexyl; R 2 is C 2 -C 1 alkylene; R is a group group of formula (G — II); A ※ is a N (R 4) (R 5); R 4 and R 5 (same or different) are C! -C 8 alkyl; B is a group group of formula (G-IV); X is> NR 6 meters; and Re is Ci —C8 alkyl. In the mixture of the present invention, the reactive group R i can be regarded as a linking group between two or more compounds of formula (P-I), (P-II), (P-III) and / or (P-IV) In this case, a bridging group of the formula (L-I) is formed between the compounds on the surface: -----.------ ^^ 衣-(Please read the precautions on the back before filling (This page)

, 1T __ Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs

The meaning of R ^ ※ can be deduced from the definition of R i. These two reactions -39- This paper size applies the Chinese National Standard (CNS) A4 specification (210X 297 mm) 491869 hi ______ B7 V. Description of the invention ( The difference between the $ f) groups is that R 1 has one or two other bridging valences. Therefore, when R i is cyclohexyl, it is equivalent to R 1 to be cyclohexanediyl or cyclohexanetriyl. R i is octyl In this case, R i corresponds to octanediyl or octanetriyl. The product of the present invention and the above-mentioned mixture can effectively improve the light, heat and oxidation resistance of organic substances, especially synthetic polymers and copolymers. In particular, low color interaction and good luster can be observed on polypropylene 'especially polypropylene fibers, especially polypropylene fibers in the presence of flame retarders and low density polyethylene (LDPE for agricultural use) )membrane. It is particularly noteworthy that the products of the present invention and the above-mentioned mixtures themselves are flame resistance agents. Examples of organic substances that can be stabilized are: Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 1 ♦ Mono- and di-olefin polymers, for example, polypropylene, polyisobutylene, polybutadiene-1ene, poly-4onemethyl Polypentene-1, polyisoprene or polybutadiene, and polymers of cycloolefins, such as cyclopentene or orbornene (η 〇rb 〇rnene), other polyethylene (if required, it can be cross-linked (Such as high density polyethylene (Η DPE), high density and high molecular weight polyethylene (HD PP E — Η MW), high density ultra high molecular weight polyethylene (Η DPE — IJHMW), medium density polyethylene (MDPE ), Low-density polyethylene (LD PE), linear low-density polyethylene (LLD PE), (VLD PE) and (ULD PE). Polyolefins, that is, polymers of monoolefins, like the previous paragraph The monoolefin polymers, especially polyethylene and polypropylene, can be prepared by different methods, especially the following method: -40- ^ Paper size applies to China National Standard (CNS) A4 specification (210X297 Mm) ~ 〇oy Central Ministry of Economy Board printed prospective employees consumer cooperative Λ7 B V. Description of the Invention (py) -? A) reaction of a free radical polymerization (normally under high pressure and temperature). b) Catalytic polymerization using a catalyst. This catalyst usually contains one or more metals of group IVb, Vb, VIb or VI on the periodic table. These metals usually have one or more types, typically oxidation. Substances, liides, alcohol esters, esters, ethers, amines, alkylates, alkenylates and / or arylates, which may be 7Γ- or σ-covalent. These metal complexes can be in a free state or fixed on a substrate, typically in activated magnesium chloride 'titanium chloride (I I I), aluminum or silicon oxide. These catalysts can be soluble or insoluble in the polymer matrix, and these catalysts can be used in the polymerization reaction themselves, or an activator can be used, typically metal alkyl compounds, metal hydrides, metal alkyl halides , Amidinoalkyl oxide or metal alkyloxane, the metal may be an element of Group I a, II a, and / or III A of the periodic table, and the activator may further be ester, ether, amine or silane alkyl These catalyst strips are commonly referred to as Phillips, Standard Oil Indiana, Ziegler (-Natta), TNZ (DuPont), " with 11000110 or unilateral catalyst (3 5 (:). 2 ♦ A mixture of polymers mentioned in 1), for example, a mixture of polypropylene and polyisobutylene, a mixture of polypropylene and polyethylene (for example, PP / HOPE ^ PP / LDPPE), and a mixture of different types of polyethylene (for example, LDPE / HDPE). 3 * Copolymers of monoolefins and diolefins, or copolymers with other ethylene monomers, such as ethylene / propylene copolymers, linear low-strength polyethylene (LLD Ρ Ε) and mixtures thereof and low-strength polyethylene (LD ρ) Ε), acrylic-4 1-This paper size applies to China National Standard (CNS) Α4 specification (210X297 mm) ~ ---------- • clothing ------ 1T ----- -(Please read the notes on the back before filling this page) 491869 A7 B7 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (♦ 6) 1 1 / butane-1 monoene copolymer 9 propylene / isobutylene copolymerization Product 5 ethylene / butene 1 1 I 1 monoene copolymer 5 ethylene / hexene copolymer ethylene methylpentene copolymer 1 1 I product ethylene / heptene copolymer 9 ethylene / octene copolymer% propylene / butadiene 1 I olefin copolymer 9 isobutylene / isoprene copolymer > ethylene / fluorenyl propylene reading back 1 f acid ester copolymer% and its copolymer with carbohydrate oxides > or ethylene / surface 1 I Acrylic copolymer and its m XXXL (ionized) and ethylene and propylene and dimer formed from 1 1 I diene > like hexadiene > dicyclopentadiene or ethylene diene 1 Mixture of orbornene and the copolymer, and 逑 1) Mixture of the polymer on this page, such as f polypropylene / ethylene / propylene copolymer> LDPE 1 1 / ethylene-ethylene acetate copolymer (EVA ) > LDPE / Ethylene 1 I Monoacrylic Copolymer (EAA) LLDPE / EVA > LL 1 Order DPE / EAA and polyalkylene 1 m oxygen 1 I carbonized copolymer with staggered or scattered structure > and and Mixtures of other polymers, such as polyamines 0 1 1 4 ♦ Hydrocarbon resins (e.g. C 5 -C 9) > Including those with 1 to 1 grade of hydrogenation (such as adhesives) and polyolefins and Starch mixture 0 1 5 * polybenzene Ene > poly (P monomethylbenzylethylene), poly (a monomethylbenzene I ethylene) 〇1 | 6 * Styrene or alpha monomethylstyrene and a diene or acrylic acid derivative co-polymer such as 9 Styrene / Butadiene 9 Styrene / Acrylonitrile 5 Styrene 1 1 / Burnt Methacrylate Styrene / Butadiene / Alkyl Acrylate 1 1 Ethylene / Butadiene / Alkyl Acrylate 9 Styrene / maleic anhydride 1 I 9 Styrene / acrylonitrile / methacrylate > High impact 1 1 I impact strength mixture of styrene copolymer 9 and another polymer f such as 5 polyacrylate > 1 1 I-42 1 1 This paper size applies to Chinese National Standard (CNS) A4 (210X 297 mm) 491869 A7 B7 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (M) 1 1 Diene polymerization Or ethylene / propylene / diene— * · polymer 1 and 1 1 I block copolymers of styrene like styrene / butadiene / styrene $ styrene / isoprene 1 1 I m-diene / styrene styrene / ethylene / butene / styrene or styrene Please read E 1 1 / Ethylene / Propylene / Styrene 0 Read back 1 ί 7 ♦ Graft of styrene or a — methylstyrene It- ,, polymer > For example on poly 1 I butadiene Styrene, on polybutadiene ethylene, or on polybutadiene matters 1 I Styrene on acrylonitrile copolymer 5 Styrene and propylene on butadiene Rewrite 1 Or methacrylonitrile) ·, styrene on polybutadiene 9 acrylonitrile and methacrylic acid ester on this page 5 styrene and maleic anhydride on polybutadiene 1 1 ϊ on polybutadiene Styrene acrylonitrile and maleic anhydride or maleic 1 1 ene diimide 5 benzene on polybutadiene Ethylene and cis-butene diimide 1 Styrene and alkyl acrylate or methacrylate ordered on polybutadiene > styrene and acrylonitrile on 1 I ethylene / propylene / diene-polymer ; Styrene and acrylonitrile on polyalkylene 1 1 I acrylate or polyalkylmethacrylate 5 Styrene and acrylonitrile 9 on acrylic 1 / butadiene copolymer and listed in 6 1 *) Mixture of copolymers > Example > Copolymer mixture of conventional ABS 5 Μ Β S 5 ASIA or AES polymer 〇1 I 8 * Halogen-containing polymer f like polypentadiene chloride > Chlorinated rubber 9 1 Chlorinated or vulcanized chlorinated polyethylene f Ethylene and chlorinated ethylene copolymers Epichlorohydrin 1 1 Homo- and copolymers 9 Especially polymers containing halogenated vinyl compounds 9 For example 1 1 > Poly Ethylene Chloride > Polyethylene Dichloride Compounds polyethylene fluoride polyethylene 1 I diene fluoride 5 and copolymers 9 like ethylene chloride / ethylene dichloride 1 1 I 5 ethylene chloride / ethylene acetate or ethylene dichloride / ethylene acetate 1 1 I-43 1 1 This paper size is applicable to Chinese National Standard (CNS) A4 (21 0 '乂 297 mm) 491869 A7 B7 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of invention (Ψ) Pan 1 1 Copolymer 〇1 1 I 9 ♦ Polymer prepared from a $ β-unsaturated acid and suitable derivative% 1 1 I Like polyacrylate and polymethacrylate Polymethylmethacrylate > Polypropylene Please read J. I. Immune amines and polyacrylonitrile 9 M butyl acrylate into shock modifiers. Read the back 1 ί 10 ♦) 9) and the formation of other unsaturated carbohydrates 1 | Polymers such as acrylic meals / Ding Er Ethylene copolymer 5 Acrylonitrile / Alkyl Acrylic acid 1 I ester copolymer 5 Acrylonitrile / Alkoxy acrylate or Acrylonitrile / Vinyl halide and then fill in the F 1 compound copolymer or acrylonitrile / Alkyl propylene m / Butadiene- * Polymers 〇 Page 1 1 ♦ Polymers derived from unsaturated alcohols and amines or their ugly derivatives 1 1 or its acetals For example, polyvinyl alcohol polyvinyl acetate polyethylene stearin 1 1 Acid_ > Polyvinyl benzoate 9 Polyethylene maleate% Polybutylene 1 Polyaldehyde, polyallyl peptidate or polyallyl melamine and its first 1 Copolymers of olefins mentioned in point 1 I 0 1 1 12 • Homopolymers and copolymers of cyclic ethers 9 like polyolefin diols polyethylene oxide 1 1 compounds J polypropylene oxides or their dioxolane groups Copolymer of ether 〇1 13 * polyacetal 5 like polyoxymethylene and Those polyoxymethylenes > which contain acetylene oxide as a co-monomer M 埶 plastic polyurethane > acrylic or M B 1 1 S modified polyacetal 〇1 14 ♦ Polyphenylene Oxides and sulfides $ and polystyrene oxides and styrene 1 1 Polymer or polyamine mixtures 0 1 1 15 ♦ Polyurethane derived from hydroxyl terminated polyethers 5 Polyester or polybutylene 1 I Diene on the side> and aliphatic or aromatic polyisocyanate on the other side> and 1 1 I Its precursor 0 1 1 -44- 1 1 This paper size applies Chinese National Standard (CNS) A4 specification (210X297) (Centi) 491869 Α7 Β7 V. Description of the invention (^), etc., diacid phthalate, and p-paraben 6 6 phenylpeptide p-hydrocarbon or amine \ misoisoidene ♦, alkyd 4 bis Polymer difluorene, I amine with hexa-Hexyl group, 2ΓΠ di- unsubstituted amine ammonium methylamine 41 by propane or formamidine tetramer by amine \, A has three Poly-linked poly or brewed 6 2 six I or or poly, 1 from its 4 alcohols, and 9 amines ;, and adipic acid such as uglylamine 4; Aminated polyacrylic acid, poly, poly 2 random or polysaccharides ο Group 1 |, amine poly 1 1 scented polyisopropyl alcohol dicohol \ amine aromatic, and alkylene di 6 _ such as benzene Ionene and derivatization, poly-derivative examples: 1 from ethylamine and 6, acid, m, poly- 2/2 acid peptide agent | 物 和 聚 化 6 1 two pairs of poly-polymers such as amine amines \ , 6 Brewing 2 and / or amine hydrocarbon ether 1 cohesion 1 amine or olefin polymerization (please read the notes on the back before filling this page) Printed copolymers of the consumer cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs; and M Polyamine or copolyamide modified by EPD Μ or ABS; and polyamines concentrated in the preparation process (RI Μ polyamine system) ♦ Polyurea, polyimide, polyamine Imine and polybenzimidazole. 1 8 · Polyesters derived from dicarboxylic acids and diols and / or hydroxygallic acid or equivalent lactones, for example, polyethylene paratitanate, polybutene peptidate, poly-1 4, 4-dimethyl alcohol cyclohexane p-esters and polyhydroxybenzoates, and block copolyether esters derived from hydroxyl terminated polyethers; and M polycarbonate modified or M BS modified Polyester. 1 9 ♦ Polycarbonate and polyester carbonate. 2 0 ♦ Poly, polyether mill and polyether 聚. 2 1 ♦ Crosslinked polymer derived from aldehyde on one side, phenol, urea and melamine on the other side, such as phenol / formaldehyde resin, urea / formaldehyde resin, and honey-4 5-This paper size applies to China Standard (CNS) A4 size (210X297 mm) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 491869 Μ ________ B? 5. Description of the invention (heart 〇) Amine / formaldehyde resin. 2, 2 · Dry and non-drying alkyd resins. 2 3 · Unsaturated polyester resins derived from saturated and unsaturated dicarboxylic acids, polyhydric alcohols, and ethylene compounds as crosslinking agents, and their low-flammability halogen-containing modifiers. 2 4 · Cross-linked acrylic resin derived from substituted acrylate, for example, epoxy acrylic resin, urethane acrylic resin or polyester acrylate 0 2 5. Alkyd resin, poly resin and melamine resin Linked acrylic resin, urea resin, polyisocyanate or epoxy resin. 2 6 * Crosslinked epoxy resin derived from aliphatic, cycloaliphatic, heterocyclic or aromatic oxypropane compounds, such as products obtained from bisphenol A and bisphenol F ethers It can be cross-linked with traditional hardeners, like anhydrides or amines (either in the presence or absence of accelerators). 2 7 · Natural polymers, such as cellulose, rubber, gelatin, and their homologous derivatives modified chemically, such as cellulose acetate, cellulose propionate and sulbutin butyrate, or cellulose ether , Like methyl cellulose; and turpentine and its derivatives. 2 8 ♦ A mixture (polymer mixture) of the above polymers, such as pp / e PDM, polyacrylamide / EPDiM or ABS, PVC / EVA, PVC / ABS, PVC / MBS, PC / ABS, PB TP / ABS, PC / ASA, PC / PBT, PVC /

CPE, PVC / Acrylic, p 0μ / thermoplastic pu R, P -46-This paper size is applicable to China National Standard (CNS) A4 specification (21 × 297 mm) ϋ · —— I In -I-n II _ (Please read the precautions on the back before filling this page) Order __ Printed by the Employees' Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 491869 Λ7 —---—_____ V. Description of Invention (Less 丨)

C / thermoplastic ρ υ R, ρ 〇μ / acrylate, ρ 〇μ / Μ Β S 'Ρ Ρ 〇 / HI ρ S, ρ ρ 〇 / ρ a 6 ♦ 6 and copolymer, ρ A / HDPE, Α / PP, PA / PPO, PPTT / PC / ABS or PBT / PET / PC. 2 9 ♦ Naturally occurring and synthetic organic substances, which are pure compounds or mixtures of compounds, such as mineral oils, animal and vegetable fats, oils and waxes, or synthetic ester-based oils, fats and waxes (eg, Peptide esters, adipic acid § "Ophthalate" trimelate) and mixtures of synthetic esters and mineral oils in any weight ratio, typically those used as spin compositions, and aqueous emulsions of the substances Thing. 30. Aqueous emulsions of natural or synthetic rubbers, such as natural latexes or emulsions of carboxylic acid styrene / butadiene copolymers. The invention therefore also relates to a composition comprising an organic substance which is sensitive to degradation by light, heat or oxidation and the product or mixture of the invention. The organic substance is preferably a synthetic polymer, more preferably a polymer selected from the aforementioned groups. Polyolefins are preferred, and polyethylene and polypropylene are particularly preferred. Another embodiment of the present invention is a method for stabilizing an organic substance and resisting degradation due to light, heat, or oxidation, including adding the product or mixture of the present invention to the organic substance. Depending on the nature of the stabilized substance, the end use and other additives are δ present, and the product or mixture of the present invention can be used in various amounts. -47- This paper size is in accordance with China National Standard (CNS) Α4 specification (210X297 mm 1 'ϋ— »· ϋϋ ^ —- ϋ aful m ^ i ϋ—ϋ iMmmmt meetMt · Βϋ— in (Please read the note on the back first (Fill in this page again)

1T # 1. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 491869 B7 V. Description of the invention (less >) Generally speaking, it is appropriate to use, for example, 〇. 〇1 to 5% by weight: ¾ ratio of this The product or mixture of the invention (relative to the weight of the material being stabilized), preferably 0. 05 to 2%, especially 0. 05 to χ. The product of the invention or a mixture thereof may be, for example, polymerized or the The substances are added to the polymeric substance before, at the time or after the cross-linking. In addition, they can be added to the polymeric substance in the form of pure substances or coated in rhenium, oil or polymer. Generally speaking, the product or mixture of the present invention can be added to the polymer material in various ways, such as dry mixing of powder type, or wet mixing of solution or suspension type, and can also contain concentrations from 2 * 5 to 2 5 % By weight The parent product of the product or mixture of the invention is added; in these operations the polymer used can be powder, granular, solution, suspension, or M latex type applications. M The products or mixture-stabilizing substances of the present invention can be used to produce molded articles, films, ribbons, monofilaments, fibers, surface coatings and the like. If desired, other conventional additives suitable for synthetic polymers can be added to organic substances containing the products or mixtures of the present invention, such as antioxidants, UV absorbers, nickel stabilizers, pigments, fillers, plasticizers, and corrosion inhibitors. And metal deactivators. Specific examples of this traditional additive are: 1 · Antioxidant: 1 ♦ 1 ♦ Alkylated monophenols, for example, 2,6-di-tert-butyl-1 4 -48- This paper size applies Chinese National Standard (CNS) Α4 Specifications (210 × 297 mm) ϋ—Jl ^^ i In —ϋ — ^ 1 · ϋϋ ϋϋ · I (Please read the notes on the back before filling this page) Order -__ Printed by the Employees' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Preparation 491869 A7 B7 V. Description of the invention (^ order) Monomethylphenol, 2-butyl-1,4-dimethylphenol, 2,6-di-tert-butyl-4, n-butylphenol, 2,6-di-tert-butyl-4 4-ethylphenol, 2,6-di-tert-butyl-4 4-isobutylphenol, 2,6-dicyclopentyl-4 4-methylphenol, 2- (α-methylcyclohexyl) -4,6-dimethylphenol, 2,6-octacosyl-4 monomethylphenol, 2,4,6-tricyclohexylphenol, 2,6 —Di-tert-butyl-4 4-methoxymethylphenol, 2,6-di-nononyl-4 monomethylphenol, 2,4-dimethyl-6 — (1,1-methylundecyl) Alkane-1yl) phenol, 2,4 dimethyl A 6 - (1 'methyl-1- yl heptadecane a) phenol, 2, 4 one hundred twenty-one methyl-6 - (1' -methyltridec burning a 1 a 'one-yl) phenol and mixtures thereof. 1 ♦ 2 ♦ Alkylthiomethylphenol, for example, 2,4-dioctylthiomethyl-6-tert-butylphenol, 2,4 dioctylthiomethyl-6-methylphenol, 2 , 4-dioctylthiomethyl-6-ethylphenol, 2,6-dodecanylthiomethyl-4 nonylphenol. 1 · 3 ♦ Hydroquinone and its alkylated hydroquinones, for example, 2,6-di-tert-butyl-4 4-methoxyphenol, 2,5-di-tert-butyl p-benzene Diphenol, 2,5-di-tert-pentylhydroquinone, 2,6-di-benzyl-4 octadecyloxyphenol, 2,6-di-succinic-butylhydroquinone , 2,5-di-tert-butyl-4-hydroxyanisole, 3,5-di-tert-butyl-4-hydroxyanisole, 3,5-di-tert-butyl-4-hydroxyanisole Base stearate, bis (3,5-di-tert-butyl-4-hydroxyphenyl) adipate. -4 9-This paper size is in accordance with Chinese National Standard (CNS) Α4 size (210X 297 mm) I ---------- Φ-- (Please read the precautions on the back before filling this page), 1T printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 491869 Λ7 B7 V. Description of the invention (㈣ >) 1 ♦ 4 * Tocopherols, for example, α-tocopherol, monotocopherol, 7-tocopherol, 3-tocopherol and Its mixture (vitamin E). 1 · 5 · hydroxylated thiodiphenyl ether, for example, 2,2 'monothiobis (6 -tert-butyl -4 -methylphenol), 2,2' monothiobis (4 -octylphenol) , 4,4 'monothiobis (6-tert-butyl-3-methylphenol), 4,4' monothiobis (6-tert-2-methylphenol), 4,4, monothiobis ( 3,6-bis-sec-pentylphenol), 4,4'-bis (2,6-dimethyl-4 4-hydroxyphenyl) disulfide. 1 · 6 ♦ Alkylene bisphenols, for example, 2,2'-methylenebis (6-tert-butyl-4-methylphenol), 2,2'-methylenebis (6-tert-butyl-1 4-ethylphenol), 2, 2'-methylenebis [4-methyl-6- (cx-methylcyclohexyl) phenol], 2,2'-methylenebis (4-methyl-6- Cyclohexylphenol), 2,2'-Methylenebis (6-nonyl-4 monomethylphenol), 2,2'-Methylenebis (4,6-di-tert-butylphenol), 2, 2 '1 ethylidene bis (4,6-di-tert-butylphenol), 2, 2 # 1 ethylidene bis (6 -tert-butyl-4-isobutylphenol), 2, 2 ^ Bis [6- (α-methylbenzyl) -4 4-nonylphenol], 2,2'-methylidene [6- (a, cx-dimethylbenzyl) -4 4-nonylphenol] , 4,4 'monomethylbis (2,6-di-tert-butylphenol), 4,4' monomethylbis (6-tert-butyl-2-methylphenol), 1,1- Bis (5-tert-butyl-4, hydroxy-2-methylphenyl) butane, 2,6-bis (3-tert-butyl-5-methyl-2-hydroxy Benzyl) -4 methylol, 1,1,3-tris (5-tert-butyl-4) This paper size is applicable to China National Standard (CNS) A4 specification (210X297 mm) — »-fc- ----- Clothing-(Please read the precautions on the back before filling out this page), 1T 491869 A7 B7 V. Description of the invention (—Hydroxy-2—methylphenyl) butane, 1, 1, 1 ( 5-tert-butyl-1, 4-mer, 2-methylphenyl), 3-n-dodecylhydrothiobutane, ethylene diether bis [3,3-bis (3 ^ -tert-butyl) Phenyl-4, monohydroxyphenyl) butyrate], bis (3-tert-butyl-4 4-hydroxy-5-methyl-phenyl) dicyclopentanyl, bis [2 — (3'-tert-one Butyl- 2′-hydroxy-5′-methylbenzyl) 6-tert-butyl-4 4-methylphenyl) p-titanate, 1,1 bis (3,5-dimethyl) —2-hydroxyphenyl) butane, 2,2-bis (3,5-di-tert-butyl-4-4-hydroxyphenyl) propane, 2,2-bis- (5-tert-butyl- 4-hydroxy- 2 -methylphenyl)-4 -η-dodecyl hydrogen Burn-yl-butoxy, 1, 1, 5,5 - forty-one (5 - a t-butyl-4 - hydroxy-2 - methylphenyl) pentane. 1 ♦ 7 · 0 — · Ν — and S — stupid methyl compounds, such as 3,5,3,5,14-tert-butyl-4,4,1-dihydroxy-dibenzol Central Standard Printed by the Bureau's Consumer Cooperative (please read the precautions on the back before filling this page). Ether, octadecyl-4, hydroxy-3,5-dimethylbenzyl hydrothioacetate, Trinity (3,5-di-tert-butyl-4-hydroxybenzyl) amine, bis (4-tert-butyl-3-hydroxy-2,6-dimethylbenzyl) dithio pair Phthalate, bis (3,5-di-tert-butyl-4-hydroxybenzyl) sulfide, isooctyl-3,5-di-tert-butyl-4-hydroxybenzylhydrosulfide Acetate. 1 ♦ 8 · Hydroxybenzyl malonates, such as bis (octadecyl) -2,2-bis- (3,5-di-tert-butyl-2-hydroxybenzyl)- Malonate, octadecyl-1 — (3-tert-butyl-51-51-) This paper is in accordance with China National Standard (CNS) A4 (210 × 297 mm) 491869 Λ7 B? Central Ministry of Economic Affairs Printed by the Consumer Cooperatives of the Standards Bureau 5. Description of the invention (1Μ 1 1 I 4 — hydroxy — 5 —methylbenzyl) — malonic acid ester 9 1,2 dodecyl 1 1 1 hydrothioethyl — 2 2 — bis— (3 S 5 1,2-tert-butyl- 4 ^^ N 1 I monohydroxybenzyl) malonate 9 bis-C 4 -1 (1, 1 9 3 3 Please first j 1 、, I — tetramethylbutyl) phenyl) 2 2 ϊ 2 a pair (3 5 1 m — tertiary 1 1 back [face I butyl — 4 — hydroxybenzyl) malonate 〇1 I meaning 1 I 1 * 9 ♦ aromatic Hydroxybenzyl compounds ♦ For example, 1 9 3 5 one or two matters 1 I one (3 5 5 —di-tert-butyl — 4 monohydroxybenzyl) one 2 4 1 4 one pair (3 9 5 —di-tert-butyl-1 4 / ten '' 1 1 monohydroxybenzyl) — 2 3 y 5 > 6 tetramethyl cage 3 2, 4 9 1 1 6 — Bis (3 5 12 —t-butyl — 4 monohydroxybenzyl) phenol 1 1 I 〇1 Order 1 ♦ 1 0 ♦ Diazine compounds, such as 2 $ 4 — Bis (octylhydrothio) ) 1 I — 6 — (3 9 5 — Di-tert-butyl- 4-hydroxyaniline) — 1 1 1 I 3) 5 — Diazine, 2 —Octylhydrothio — 4, 6 —Bis ( 3 5 5 1 1 bis-tert-butyl- 4 -hydroxy-anilino)-1 3 5-tri 1 m azine > 2-octylhydrosulfanyl-4 > 6-bis (3, 5- Di-tert-butyl I-I-4 monohydroxyphenoxy) — 1% 3 9 5 monotriazine 2 5 4 9 6 1 I — bis (3 9 5 -di-tert-butyl- 4 -hydroxyphenoxy) — 1% 1 2 t 3 —triazine > 1 9 3 5 5 one tri — (3 9 5 One two-tert-butyl 1 1 group one 4- 4-hydroxybenzyl) isocyanurate 9 1 > 3 5 one two one (1 I 4-t-butyl- 3-hydroxy one 2 9 6 one two Monomethyl benzyl) iso-1 1 I cyanurate> 2, 4, 6 di (3 5 di-tert-butyl- 4 1 1 I monohydroxyphenylethyl) 1 3 i 5 — Triazine > 1 9 3 9 5 — — ^ 1 1-• 52 1 1 This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) 491869 Λ7 B? V. Description of the invention (qry) One ( 3,5-di-tert-butyl-4 4-hydroxyphenylpropanyl) hexahydro-1,3,5-triazine, 1,3,5-trione (3,5-dicyclohexyl-4 —Hydroxybenzyl) isocyanurate. 1 ♦ 1 1 ♦ benzylphosphonates, for example, dimethyl-2,5-di-tert-butylbutyl-4 monohydroxybenzylphosphonate, diethyl-3,5-di-tert Monobutyl-4 monohydroxybenzyl phosphonate, octadecyl 3,5 tert-butyl-tetrabutyl mono-4 monohydroxy-benzyl phosphonate, octacosyl 5-tert-one Calcium salt of monoethyl 4-butyl-hydroxy 3-methylbenzyl monophosphonate, monoethyl ester of 3, 5-di-tert-butyl 4-hydroxybenzyl monophosphonic acid. 1 ♦ 1 2 ♦ -aminoaminophenols, for example, 4-monohydroxy_lauryl tetanil, 4-monohydroxystearyl tetanil, octyl-N — (3,5 —di-tert-butyl- 4-1 Hydroxyphenyl) carbamate. 1 · 13, / 3— (3,5—Di-tert-butyl-4 4-hydroxyphenyl) propionic acid and mono- or polyhydric alcohol esters, such as with methanol, ethanol, stearyl alcohol, 1, 6-hexanediol, 1,9 mono-nonanediol, ethylene glycol, 1,2-propanediol, neopentyl glycol, thiodiethylene glycol, consumption by employees of the Central Standards Bureau of the Ministry of Economic Affairs Printed by the cooperative (please read the notes on the back before filling this page) Gynecol, triethylene glycol, pentaerythritol, tris (hydroxyethyl) isocyanurate, N, N 'bis (hydroxyethyl ) Ethylenediamine, 3-thiaundecanol, 3-pentadecanol, trimethylhexanediol, trimethylolpropane, 4 monohydroxymethyl-1 monophosphorus-2, 6 , 7-trioxabicyclo [2 ♦ 2 ♦ 2] octane. 1 · 14 ♦ / 9 1 (5-tert-butyl-1, 4-hydroxy-1, 3-methylbenzene- 53-) This paper size applies to China National Standard (CNS) A4 specification (210X 297 mm) 491869 ΑΊ B7 V. Description of the invention (Old) esters of propionic acid and mono- or polyhydric alcohols, such as, and methanol, ethanol, stearyl alcohol, 1,6-hexanediol, 1,9 monononane-diol, ethylene Diols, 1,2-propanediol, neopentyl glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol, pentaerythritol, tris (hydroxyethyl) isocyanurate, N , FsT —bis (hydroxyethyl) ethylenediamine diamine, 3-thiaundecanol, 3-thiapentadecanol, trimethylhexanediol, trimethylolpropane, 4-monohydroxy Methyl- 1-phospho-2,6,7-trioxabicyclo [2 · 2 ♦ 2] octane. 1 ♦ 15 ♦ An ester of 3,5-dicyclohexyl-4 monohydroxyphenyl) propionic acid and a single or polyhydric alcohol, such as with methanol, ethanol, stearyl alcohol, 1,6-hexane Diols, 1,9 mono-nonanediol, ethylene glycol, 1,2-propanediol, neopentyl glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol, pentaerythritol, Trinity (hydroxyethyl) isocyanurate, N, N 'bis (hydroxyethyl) ethylenediamine diamine, 3 — at undecane I, 0II (Please read the precautions on the back before filling Page) Order alcohol 1 alkane I pentayl. Deca-methane 111-kisyl I Hydroxyl J 3 I 2 54 ♦ Alcohol, 2 Hexyl methyltrisphine 2 6 7 Alkyl alcohol C-based cyclomethylbis I Oxytriazine 2-. Printed acid by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs , Acetic acid 1 group, phenolyl hydroxy octadecyl I, alcoholic ethyl butyl, I alcohol * tertiary and I as di, I ester 5, alcohol 3 hydrogen ♦ poly 6 or 1 I. mono 1 and ene Alcohol ethylene diene, enol ethylene dialkyl nonanesulfide I > 9 alcohols, di 1 groups, pentanol neodi, alkanol hexamethylene I alkane 6 propane

Ethylamine ethylenediyl hydroxybis (ethylene I) triyl, ethanol I tetrakispentyl hydroxy quaternary {, bisol I diene, ene N ethyl, tri N 1,, burn 2 alcohol ester mono, diacid undecyl urinary _, Acetonitrile | Alcohol Diiso3 This paper size is applicable to Chinese National Standard (CNS) Α4 size (210X 297 mm) 491869 Α7 Β7 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention {^) 1 1 I Alcohol 5 3 —thiapentadecyl dimethyl hexanediol dimethyl alcohol propane y 1 1 1 4 monohydroxymethyl 1 1 phosphorus — 2 > 6 > 7 monooxybicyclic C 2 ♦ 2 1 I please 1) ♦ 2 J octane. 1 I 1 + 1 7 • β _ (3 5-1 tert-butyl-4-hydroxyphenyl read back 1 f 1) amine of propionic acid y > NN — — Bis (3 5 1 2 1 Tertiary 1 D 1 1 1 4 1 hydroxybenzyl propazar) Methylene di. Amine% Ν N — — Bis (3 matters 1 1 5 5 — — Tert-butyl — 4 monohydroxyphenylpropanthine) Dimethylenediamine Fill in this NN, a bis (3, 5 bis tert-butyl — 4 monohydroxyl phenyl page 1 I propionate) Hydrazine N N / — Double C 2 — (3 — Plant 3 9 5 One Two — Tertiary 1 1 I — Butyl — 4 Monohydroxyphenyl) Propionate) Ethyl] Oxygen: nt hexamethylamine 0 1 1 1 1 8 * Ascorbic acid (vitamin C) 1 order 1 ♦ 1 9 ♦ amine antioxidants $ Example > N * N / — Di-isopropyl — 1 | ρ — Phenylenediamine 9 N 9 N / — Diamine 1 Butyl — P monophenylene diamine 1 I 5 Ν > Ν / one bis (1 9 4 dimethylpentyl) -P monophenylene diamine 1 1 I 9 Ν > Ν / — bis (1 — Ethyl — 3 —methylpentyl) mono-P-phenylene I diamine N 9 Ν / monobis (1 monomethylheptyl) — P monophenylene diamine > 1 Ν > Ν / one two Cyclohexyl — P Monophenylenediamine N > N / Monodiphenyl I Single P Monophenylene Diamine j N , N-bis (2-naphthyl) -P-benzyl-1 I diamine N-isopropyl-N / monophenyl-P-phenylenediamine N- (1 1 1 3 -__. Methyl Butyl) — N / monophenyl — P — phenylenediamine> N 1 1 mono (1 —methylheptyl) — N / monophenyl — ρ — phenylenediamine 9 N — 1 I cyclohexyl Mono-N / -Phenyl-P-Phenylenediamine 4 Mono (P-Toluene 1 1 I 醯) Mono-diphenylamine% N > N / Mono-dimethyl-N > N / 112 1 1 I 5ί Bu 1 1 This paper size applies to the Chinese National Standard (CNS) Α4 specification (21 〇297297 mm) 491869 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs A7 Β7 V. Description of the invention) Monobutyl-P-benzene Diamine, diphenylamine 'N monoallyl diphenylamine, 4 isopropoxy diphenylamine, N —phenyl — 1 naphthylamine, N — (4 tert-octylbenzene A) naphthylamine, 1-naphthylamine, 2-naphthylamine, octyl difluorenylamine, such as P, P / -di-tert-octyl Diphenylamine, 4-mono-n-aminoaminophenol, 4-monobutylaminoaminophenol, 4-monomethylaminophenol, 4-h-diaminoaminophenol, 4-18methylaminophenol 'Bis (4-monomethoxyphenyl) amine, 2, 6-di-tert-butyl-1, 4-dimethylaminomethylphenol, 2,4'-diaminodiphenylmethane' 4 , 4, diaminodiphenylmethane, Ν, Ν, Ν ', Ν'-tetramethyl-1,4,4'-diaminodibenzyl methylbenzene, 1,2-bis [(2-methyl Phenyl) amino] ethane, 1,2-bis (phenylamino) propane, (0-tolyl) biguanide, bis [4-mono (1,, 3'-dimethylbutyl) Phenyl] amine, tertiary mono-octylated N-benzyl-1 pentylamine, fluorene- and dialkylated tert-butyl / tert-octyl diphenylamine mixtures, mono- and di-alkyl Mixtures of nonyldiphenylamines, mono- and difluorenated dodecyldiphenylamines, mono- and dialkylated isopropyl / isohexyldiphenylamines, single And dialkylated tert-butyldiphenylamine mixture, 2,3-dihydro-3,3-di Methyl mono-4,4-dibenzothiazine, phenothiazine, single and dialkylated tert-butyl / tert-octylphenazine mixture, mono- and dialkylated tert-octyl Phenylphenazine mixture, N-allylphenoxazine, Ν, Μ, Ν ', Μ'-tetraphenyl-1,4-diaminobutane-2-ene, ν, N-bis (2, 2,8,6-tetramethyl-pyridine-4, 1-yl ~ hexamethylene diamine, bis (-5 6-This paper size applies to China National Standard (CNS) Α4 specification (210X297 mm) " 一 ϋϋ & WHI— mi —Lrl ϋϋ —B ^ i I ιϋ_— ϋϋ · ϋ (Please read the notes on the back before filling out this page), 1T 491869 B7 V. Description of invention (β) Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 2 2 6 > 6-tetramethylpyridine-4-yl) sebacic acid S, 2 9 2, 6 S 6 tetramethylpyridine — 4-monoone > 2 2 6 > 6 tetramethyl € Pyridine — 4 — Alcohol 〇2 ♦ UV absorber and light stabilizer 2 * 1 * 2 Mono (2, — hydroxyphenyl) benzodiazolyl 5 For example $ 2 — (2 9 monohydroxy — 5 > — methylphenyl) — benzotriazolyl, 2 — (3 > 9 5 di-tert-butyl- 2 > — hydroxyphenyl) Benzotriazolyl f 2 mono (5 > mono-tert-butyl mono 2 > monohydroxyphenyl) benzo-oxazolyl, 2-(2, monohydroxy-5-(1 9 1 > 3 $ 3 monotetramethylbutyl) phenyl) benzotriazolyl 2 — (3 j 5, mono-tert-butyl-2-, monohydroxyphenyl) 5 -chloromonobenzodiazolyl 3 2- (3 t-tert-butyl-2, -hydroxy-5, monomethylphenyl) -5-chloro-benzotriazolyl $ 2-(3 > sec-mono-butyl-5 Mono-tert-butyl- 2 -hydroxybenzyl) benzotriazolyl 9 2-(2 -hydroxyl-4 > monooctyloxyphenyl) benzotriazolyl > 2 mono (3 > 9 5- Di-tert-pentyl-2, monohydroxyphenyl) benzotriazolyl 2 one (3,5, one bis- (a, a — dimethylbenzyl)-2 > monohydroxyphenyl) benzotriazolyl > 2 — (3, — tert-butyl — 2, — hydroxy — 5 — (2 octyl Oxycarbonylethyl) phenyl) — 5 —chloro —benzotriazolyl 2 mono (3 9 —tert-butyl-1 5 9 —C 2 mono (2 monoethylhexyloxy) monoethyl> — 2 —Hydroxyphenyl) -5 -chloro-benzodiazolyl 9 2-(3 9 -tert-butyl -2 -hydroxy -5, 1 (2 -methoxycarbonylethyl) phenyl) One 5 one chloro-benzene-57- 丨 *-L · -------- (Please read the precautions on the back before filling this page)

、 1T # 1. This paper size is applicable to Chinese National Standard (CNS) A4 (210X 297mm) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 491869 A7 V. Description of Invention (β) Triazolyl, 3, 1-tert-butyl-2, 1-hydroxy-5 '-(2-methoxycarbonylethyl) phenyl) benzotriazolyl, 2- (3'-tert-butyl-2'-hydroxy Mono-5 '-(2-octyl monooxycarbonylethyl) phenyl) benzotriazolyl, 2- (3'-tert-butylbutyl-5 * — [2- (2-ethylhexyloxy) carbonyl Ethyl] -2'-hydroxyphenyl) benzotriazolyl, 2- (3'dodecyl-2'-hydroxy-5'monomethylphenyl) benzo-triazolyl, and 2 — (3 'mono-tert-butyl-2' mono-hydroxy-5, mono- (2-isooctyloxycarbonylethyl) phenylbenzotriazolyl 2,2 'monomethylidene-bis [4 a (1 , 1,3,3-tetramethylbutyl) -6-benzotriazolyl-2-ylphenol]; 2- [3,1-tert-butyl-5 '-(2-methoxy Carbonylethyl) -Z, Hydroxymonophenyl]-2 Η —benzotriazolyl and an esterification product of polyethylene glycol 300, [R — C Η 2 C Η 2 — C 〇0 (C Η ζ) 3] 2 — of which R = 3, -tert-butyl-4'-hydroxyl-2H-benzotriazolyl-2-ylphenyl, 2- [2'-hydroxyl 3 / 3- (α, α-dimethylbenzyl Radicals) -5, 1 (1,1,3,3-tetramethylbutyl) -phenyl] benzotriazole; 2-[2 y -hydroxyl 3, 1 (1,1,3,3- Tetramethylbutyl)-5 '— (α, α-dimethylbenzyl) -phenyl] benzotriazole. 2 * 2 ♦ 2-Hydroxybenzophenone, for example, 4 -hydroxy * 4- Methoxy, 4 octyloxy, 4 decyloxy, 4 dodecyloxy, 4 monodecyloxy, 4, 2 ', 4' a trihydroxy and 2 'trimethyl, 4, 4 'One dimethoxy derivative. -58- This paper size applies to Chinese National Standard (CNS) A4 (210X 297 mm) — ^ 1-f — II n ϋ ϋ-(Please read the precautions on the back before (Fill in this page), 1T 491869 hi ----- B7 V. Description of the invention (0) 2 '3 · Esters of substituted or unsubstituted benzoic acid, such as 4-tert-butyl-phenylsalicylate, phenylsalicylate, octylphenylsalicylate, benzoylhydrazone Resorcinol, bis (4-t-tert-butylbenzidine), resorcinol, m-benzyl-1, 2,4-di-t-butylbenzyl, 3,5-di-t-tert-butyl 4-Cyclo-4-hydroxybenzoate, hexadecyl 3,5-di-tert-butyl-4 4-hydroxybenzoate octadecyl 3,5-di-tert-butyl-4 Hydroxybenzoate, 2 monomethyl-4,6-di-tert-butylphenyl 3,5-di-tert-butyl-4 4-hydroxymonobenzoate 0 2,4 ♦ Aromatic ester For example, ethyl ^ -cyano-00-diphenyl acrylate, isooctyl (fluorene ~ cyano-1, / 3-di-phenyl acrylate, methylσ-carbomethoxycinnamate, Methyl α-cyano-θ 0 -methyl-P-methoxy-cinnamate, butyl α-cyano / 3, / 5-methyl-P-methoxy-cinnamate, methyl 〇: —Carbonmethoxy-P —methoxymethoxycinnamic acid g and N — (/ 3 —carbon A group Θ - cyanovinyl) a 2 - methylindole 11. Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page) 2 ♦ 5 ♦ Nickel compounds ♦ For example 2, 2, a thio one pair one [4 one (1, 1, 1, 3 , 3-tetra-methylbutyl) phenol] nickel complexes, such as 1: 1 or 1: 2 complexes, with or without additional reactive groups, such as η-butylamine, triethanolamine or η- Cyclohexyldiethanolamine, nickel dibutyldithiothiocarbamate, nickel salt of monoalkyl ester of 4-hydroxy-3,5-di-tert-butylbenzylphosphonic acid, such as methyl or ethyl Esters, nickel complexes of ketooximes, such as 2-hydroxy-4, 4-methylphenylundecyl ketoxime, 1-59- This paper size applies to China National Standard (CNS) A4 specifications (210X297 mm) Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 491869 A7 B7 V. Description of the Invention (Xu) Phenyl-4. Lauryl-1 5-Hydroxypyrazolyl _ complex, with or without additional reactive groups. 2 * 6 · St'erica 115r hindered amines, such as bis (2,2,6,6-tetramethylmonopiperidinyl) sebacate, bis (2,2,6,6 —Tetramethylmonopyridyl) succinate, bis (1,2,2,6,6 —pentamethyl # pyridyl) sebacate, bis (1,2,2,6,6— Pentamethylpyridinyl) η-butyl-3,5-di-tert-butylbutyl-4 monohydroxybenzylmalonate, 1- (2-hydroxyethyl) -2,2,6, Concentrate of 6-tetramethyl-1,4-hydroxybutyridinesuccinic acid, N, N, a bis (2,2,6,6-tetramethyl-1,4-pyridinyl) hexamethylenediamine and 4 Mono-tert-octylamino-2,6-dichloro-1,3,5-triazine, tri- (2,2,6,6-tetramethyl-4 4-3 stilbene), four ( 2,2,6,6-tetramethyl-4-pyridinyl) -1,2,3,4-butane-tetracarboxylic acid ester, i, 1,1- (1,2-ethanediyl) Bis (3,3,5,5-tetramethylpyrazine_), 4-a benzyl with 2,2,6,6-tetramethylpyridine, 4-stearylmethyloxy-2,2, 6, 6-tetramethylmeridine, bis (1,2,2,6,6-pentamethylpyridinyl)-2 -η-butyl- 2-(2-hydroxy-1,3,5-di-tert-yl Monobutyl benzyl) malonate, 3-n-octyl-7,7,9,9-tetramethyl-1,3,8-triazaspiro [4 ♦ 5] decane-2 , 4,2,2 I, bis (: 1 octyloxy-2,2,6,6-tetra-methylpiperidinyl) sebacate, bis (1 octyloxy-2,2 ， 6,6 —Tetramethylpyridinyl) -60- This paper size applies to Chinese National Standard (CNS) A4 specification (210X297 mm) 丨 · # 丨 丨 (Please read the precautions on the back before filling this page) Printed by the Consumer Standards Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 491869 Λ7 B7 V. Description of the invention (1 ^) Concentrate of succinate, Ν, Ν * —Bis (2,2,6,6-tetramethyla Concentrate of 4-monopyridinyl) hexamethylenediamine and 4-morpholino-2,6-dichloro-1,3,5-triazine, 2-chloro-4, 6-bis (4— η-butyl-amino-2,2,6,6-tetramethylimidinyl) -1,3 Concentrate of 5-triazine and 1,2-bis (3-aminopropylamino) -ethane, 2-chloro-4,6-di- (4-a-n-butylamino-1,2,2 , 6,6-Pentamethylpyridinyl) -1,3,5-triazine and 1,2-bis (3-aminopropylamino) ethane, 8-ethanyl- 3-12 Alkyl-7,7,9,9-Tetramethyl-1,3,8-triazaspiro [4 ♦ 5] decane-2,4-dimethyl 1,3-dodecyl-1 1 (2,2,6,6-tetramethyl-1-4-pyridyl) pyrrolidine-2,5-di-2,3-dodecyl-1 1- (1,2,2,6,6-5) Mixture of methyl-4 4-pyridyl) pyrrolidine-2,5-dione, 4-hexadecyloxy and 4-octadecyloxy-2,2,6,6-tetramethyl # pyridine ， Ν, Ν / —Bis (2,2,6,6—tetramethyl-1 4-pyridinyl) hexamethylenediamine and 4-monocyclohexylamino-1,6-dichloro-1,3 Condensation products of 1,5-triazine, 1,2-bis (3-aminopropylamino) ethane and 2, 4,6-trichloro-1,3,5-triazine and 4-monobutylene Condensation product of amino-2,2,6,6-tetramethylpyridine (CAS Reg. No. [136504-96-6]); N-(2,2,6,6-tetramethyl-1) 1-pyridinyl) -n-dodecylbutanediimide, N- (1,2,2,6,6-pentamethyl-4 piperidinyl) -n-dodecylbutane醯 亚 -6 The paper size is applicable to the Chinese National Standard (CNS) Α4 specification (210X 297 mm) (Please read the precautions on the back before filling this page), 1T 491869 Λ7 B7 Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs Preparation of the invention 5. Description of the invention (0) 罾 1 1 I Amine > 2 — Eleven t endyl-7 9 7 > 9, 9, 9-tetramethyl-1 1-oxa 1 1 1 1 3 > 8 1- _ Acryl-4-oxo-spiro [4 * 5 decane 5 7 > 7 #, *, 1 I please 1 1 9 9 9 one tetramethyl one 2 one ring ten — ** alkyl — 1 one oxygen one 3 9 8 — read first 1 I diacid 4 — oxyspiro r 4 ♦ 5 3 reaction product of decane and epichlorohydrin 9 1 read back 1 side I 5 1 Bis (1% 2 > 2 6 > 6 1 pentamethyl-1 4 monopyridyloxy Note 1 I 1 1 carbonyl) 1 2 — (4 monomethoxyphenyl) ethylene > N 9 N / One Pair One Matter 1 I Mesa-N y N — Bis (2 9 2, 6 5 6 Tetramethyl — 4 Refill this 4 pyridyl group) -Λ- * Methylenediamine 4 Monomethoxy Monomethylene monomalonic acid and 1 2 pages 1 I ί 2 6, 6 Dipentamethyl-4-hydroxypyridine diester f PolyC methyl 1 1 I Propyl-3 3 oxygen 4 1 (2 2 5 6 6 —Tetramethyl-1 4 —Nine 1 1 pyridyl) Siloxane 9 Maleic acid — α-olefin copolymer and 2, 2 > 6 1 Order $ 6 — Tetramethyl 1 4 — Amine Pyridine or 1 9 2 $ 2 > 6 9 6 one five 1 I methyl-4 monoamine piperidine 0 1 1 I 2 * 7 * ethylene dimethylene diamine such as 4 9 4, dioctyl Alkoxyoxy 1 1 .¾ Amine > 2, 2, 2-—dioctyloxy-5 5 f one-two-tert- Oxygen 1 —donyl aniline t 2, 2 > — dodecyloxy-1 5 9 5 y — di • 1 I — tert-butoxym taniline 2-ethoxy-2, ethoxyfluorene Tetanil 9 Ν Ν, a bis (3-dimethylaminopropyl) ethylenediSI diamine 9 2 1 monoethoxy-5 — tert-butyl-2, —ethoxybenzidine and its 2 1 1 monoethoxy-2, —ethyl-5 54, 1,2-tert-butoxyfluoridine 1 1 mixture of aniline > and ortho- and meta-methoxy substituted oxetanilide 1 Mixture of I and 0 — and P monoethoxy — disubstituted oxygen m taniline 0 1 1 I 2 * 8 2 — (2 monohydroxyphenyl) — 1 3 * 5 — diazine Example 1 1 -62 >-1 1 This paper size applies Chinese National Standard (CNS) A4 specification (210X 297 mm) 491869 A7 B? V. Description of the invention (q) Such as 2, 4, 6-Trinity (2-Hydroxyl 4 4 octane) Alkoxy-phenyl) -1,3,5 —Triazine, 2-(2-hydroxy-4 4-octyloxyphenyl) — 4,6 —bis (2,4-dimethylphenyl) — 1,3,5 —triazine, 2 — ( 2,4-dihydroxyphenyl) -4,6-bis (2,4-dimethylphenyl) -1,3,5-triazine, 2,4-bis (2-hydroxy-4 4-propyl) Oxyphenyl) -6- (2,4-dimethylphenyl) -1,3,5-triazine, 2- (2-hydroxy-4 4-octyloxyphenyl) -4,6- Bis (4-monomethylphenyl) -1,3,5 monotriazine, 2- (2-hydroxy-4 dodecyl monooxyphenyl)-4,6-bis (2,4 one two (Methylphenyl) -1,3,5-triazine, 2- [2-hydroxy-1 4- (2hydroxy-1 3-butyloxy-propoxy) phenyl] -4,6-bis (2 4,4-dimethyl) -1,3,5-triazine, 2- [2-hydroxy-1 4- (2-hydroxy-3-octyloxy-propyloxy) phenyl] -4,6 —Bis (2,4-dimethyl) -1,3,5-triazine, 2— [4-((dodecyloxy / tridecyloxy-2—hydroxypropoxy) 2-Hydroxymonophenyl] -4,6-bis (2,4-dimethylphenyl) -1,3,5-triazine, 2- printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read first Note on the back page, please fill in this page) [2-Hydroxy-4 4- (2-Hydroxy-3-Dodecyloxy-Propoxy) phenyl] -4,6-Bis (2,4-Dimethyl Phenyl) -1,3,5-triazine, 2- (2-hydroxy-1, 4-hexyloxy) phenyl-4, 6-diphenyl-1, 3, 5-triazine, 2-(2 — Hydroxy-4 4-methoxyphenyl) -1,4,6-diphenyl-1,3,5-triazine, 2,4,6-tris [2-hydroxy-1 4- (3-butoxy-2 —Jingji-63- This paper size applies to Chinese National Standard (CNS) A4 specification (210X 297 mm) 491869 A7 V. Description of the invention (made) Monopropoxy) phenyl] -1,3,5-triazine , 2- (2-hydroxyphenyl) -4- (4-methoxymethoxyphenyl) -6-benzyl-1,3,5-tri-B-qin, 2- {2-hydroxy-1 4-a [3- — (2-ethylhexyl- 1-oxy)-2 -hydroxypropyl Oxy] phenyl} -4,6-bis (2 '4 -1 ^ methylzhuyl) -1,3,5-di 嗦 ° 3 ♦ Metal deactivator, such as n, N, diphenyl Ethylenediamine, N-salicyl-N, salicylidene, N, N, bis (salyl) hydrazine, N, N, bis (3, 5-di-tert-butyl-4) Monohydroxyphenyl monopropyl) hydrazine, 3-salicylamino-1,2,4, triazole, bis (benzylidene) ethylene dione, dipyridine, panteanilide, Isopeptide acyl group, dimer hydrazone, sebacaridine bisphenyl hydrazone, N, N, 1,2 ethyl fluorenyl hexamethylene dihydrazide hydrazine, N * N 'bis (: salicyl hydrazine) Dimethylhydrazine, N, N 'One pair (salicyl) with thiopropylated dihydrazine. Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the notes on the back before filling out this page) 4 ♦ Phosphites and phosphonates ♦ For example, triphenyl phosphite, dicyl alkyl phosphite, Phenyldialkylphosphite, tris- (nonylphenyl) phosphite, trilaurylphosphite, tris-octadecylphosphite, disarylene pentaerythritol diphosphite, Trinity (2,4 121-butyl-cyl) phosphite, diisodecyl pentaerythritol diphosphite, bis (2,4-1,2-tert-butylphenyl) pentaerythritol diphosphite, bis (2,6-di-tert-butyl-4-methylfluorenyl) pentaerythritol diphosphite, diisodecyloxy pentaerythritol diphosphite, bis (2,4-di-tert-butyl 6-methylphenyl) pentaerythritol diphosphite, -6 4-This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 491869 Λ7 _ B? I —__________—______ 5. Description of the Invention (7 /) Double (2, 4, 6-Trinity ( Monobutylphenyl) pentaerythritol diphosphite_, tristearyl ffi sorbitol triphosphite, four (2,4 di-tert-butylphenyl) 4,4 'monobiphenylene diphosphonic acid Ester, 6-isooctyloxy-2,4,8,1104-tetra-tert-butyl-1 2H-di cage [d, g] -1,3,2-dioxophosphate, 6-fluoro Substitute 2,4,8,10-tetra-t-butyl-12-methyl-diphenyl [d, g] -1,3,2-dioxin'bis (2'4 one two one Tert-Butyl-6-methylphenyl) methyl phosphite, bis (2,4,1,2-tert-butyl-6-methylphenyl) ethylphosphite, 2,2 ', 2 & quot ~ Nitrogen [Triethyldi (3,3 ', 5,5'-tetra-t-tert-butyl-1,1, biphenyl-2,2'-diyl) phosphite], 2 Monoethylhexyl (3,3,5,5,5'-tetra-tert-butyl-1, 1'-biphenyl-2,2'-diyl) phosphite. 5-Hydroxylamine, for example, N, N —dibenzylhydroxylamine, N, N —diethylammonium amine, N, N —dioctylammonium amine 'N' N —dilauryl Hydroxylamine, N, N ~ di (tetradecyl) hydroxylamine, N, N-di (hexadecyl) hydroxylamine, N, N-di (octadecyl) ylamine, N ——h Hexadecyl-N-octadecylhydroxyamine 'N-heptadecyl-N-octadecylhydroxyamine, N, N-dialkylhydroxyamine from hydrogenated tallowamine 0 6 ♦ nitrone, for example , N-benzyl-"-phenyl-nitrate, N-ethyl-α-methyl-nitrate, N-octyl-α-heptyl-nitronone, N-lauryl-α-undecane N-tetradecyl-N-tetradecyl_α-tridecane-65- This paper size applies Chinese National Standard (CNS) A4 specification (210X297 mm) ϋϋ · -I .—— ··-i ·- · —— ϋ—ϋ il ^^ i 111 · —.Hi —ϋ (Please read the precautions on the back before filling out this page), 1T 5 A7 B7 Invention Description printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (" ) -Nitroketone, N-hexadecyl-α-pentadecyl-one-nitrone, N-octadecyl-α-h heptyl-one-nitrone, N-hexadecyl-α- Heptadecanyl mononitrate, N—octadecyl-10 (-15 N-heptazone, N-heptyl-α-heptademinyl-nitrazine, N-octadecyl-cx-hexadecyl-nitronone, derived from hydrogenated tallowamine N, N-di The nitrate of alkylhydroxylamine. 7. Thio synergists, for example, dilauryl thiodipropionate or distearyl thiopropionate. 8. Peroxide cleaners, such as esters of monothiodipropionic acid, such as lauryl, stearyl, tetradecyl or tridecyl, hydrothiobenzimidazolyl or 2-hydrothiobenzene Zinc salt of imidazole, zinc dibutyl dithiocarbamate, octacosyl disulfide, pentaerythritol tetraol (four-dodecyl hydrogenthio) propionate. 9 ♦ Polyamine stabilizers, such as copper salts combined with iodide and / or phosphorus compounds, and salts of divalent manganese. 1 0 ♦ Basic co-stabilizers, such as melamine, polyvinyl ftfc-pyrrolidone, dicyandiamide, tri-allyl cyanurate, urea derivatives, hydrazine derivatives, amines, polyfluorenes Amines, polyurethanes, higher fatty acid alkali metals or alkaline earth metals, for example, calcium stearate, zinc stearate, magnesium adipate, magnesium stearate, sodium mateate and potassium hexadecanoate * Antimony pyrotarate or zinc pyrotarate. 1 1 • Nucleic acid agents, for example, inorganic substances, like talc, metal oxides> like titanium dioxide or magnesium oxide, phosphates, carbonates or sulfates of preferred alkaline earth metals; organic compounds, like mono- or polycarboxylic acids and Its salts, for example, -66- This paper size applies to Chinese National Standard (CNS) Α4 specification (210X297 mm) —Jn I-III--(Please read the precautions on the back before filling this page)

1T 491869 Μ B7 V. Description of the invention U /) 4 Mono-tert-butyl benzyl, adipic acid, diphenylacetic acid, sodium succinate, or sodium formate; polymer compounds such as ionic copolymers Ionomers) ° 1 2 * Filling and reinforcing agents, for example, calcium carbonate, silicate, glass fiber, asbestos, talc, high-sensitivity clay, mica, barium sulfate, metal oxides and hydroxides, carbon black, graphite , Powder or fiber of wood powder or other natural products, synthetic fiber. 1 3 ♦ Other additives, such as plasticizers, lubricants, emulsifiers, colorants, flow additives, catalysts, flow control agents, optical brighteners, fire retardants, antistatic agents and foaming agents (b 1 〇 wingagents). 1 4 ♦ Benzofuranone and indole, for example, described in US-A-4, 3 2 5, 8 6 3; I) S-A-4, 3 3 8, 2 4 4, US-A -5, 1 7 5, 3 1 3; US-A-5, 2 1 6, 0 5 2, ϋ S-A-5, 2 5 2, 6 4 3, DE-A-4,316,611; DE + 4, 3 1 6,6 2 2; DE-A-4, 3 1 6, 8 7 6; EP + 0,589,839 or EP-A-0,591,102 or 3- [4— (2-acetethoxyethoxy) Phenyl] -5,7-di-tert-Γ-benzo-benzofuran-2 -_, 5'7-di-tert-butyl-3-3- [4-mono (2-stearyloxyethoxy) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page)) Phenyl] benzofuran-2-one, 3, 3 '—bis [5, 7-two one, one Butyl-3- (4-[[2-hydroxyethoxy] phenyl) benzo-anan- 2-keto], 5,7-di-tert-butyl-3- (4-ethoxyphenyl) Benzofuran-2-one, 3-(4-ethylenoxy- 3, 5-dimethylbenzyl) -5,7-di-tert-butyl-benzfuran-2-one, 3- (3, 5 Dimethyl-1,4-trimethylethyloxy)-67-This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) Printed by the Employees' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 491869 A7 B7 Explanation (P) -5,7-1,2-tert-butyl-benzofuran-2-Xing I, 3-(3,4-dimethylphenyl) -5,7-di-tert-butylbenzene Benzofuran-2, 2-pyrene, 3- (2'3-^^ methylbenzyl) -5'7-?-Tert-butyl-benzofuran-2-one. The ratio of the product or mixture of the present invention to the conventional additives may be, for example, 1: 0 to 5 to 1: 5. The products or mixtures of the present invention can also be used as stabilizers, especially as light stabilizers, such as stabilizers for most cypress reprints and other substances known in the art of reprinting, as disclosed in Reseach D isc 1 〇sure 1 9 9 0, 3 1 4 2 9 (pages 4 7 4 to 4 8 0). In the present invention, the examples of M diarrhea are explained in more detail. All parts and percentages are calculated by M weight unless otherwise specified. In the structure of the chemical formula of the following example, η 'represents the number of repeating units in the molecule and the resulting product is not uniform. The starting materials disclosed in Example 1 A are characterized by a number average molecular weight Mn and a polydispersity Mw / Mη. GPC (gel permeation chromatography) was used as an analytical step to separate molecules of different sizes and obtain an average molecular weight (Mw, Mη) and a molecular weight distribution of the polymer. This technique is well known and described in, for example, 〃Μ〇der II Size — Exclusion Liquid Chromatography55, edited by WW Yan et al. Et al., Published by J. Wiley & Sons, IY. USA, 1 9 7 9 pages 4-8, 249-283¾ 315-340 〇-68- This paper size applies to Chinese National Standard (CNS) A4 (210X297 mm) I--......-I (Please read the note on the back first (Fill in this page again)

Aw ...

1.1T printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 491869 Λ7 B7 V. Description of the invention The GPC analysis in the uw example below is performed in a PLC instrument, Model ® TSPAS-1 0 0 0, the device has UV 1 0 0 0 UV / VIS detector, wavelength 250 nm, the column used is 〃 GPC — SS-250x7 * 7mm X 3 / 8〃, ® V aic 〇- M icr 〇ge 1-3 mixed gel. The eluent was tetrahydrofuran (flow rate: 1 ml / min)-⑮ Uvasol (⑫ Merck-1 · 0 0 0 16) + 0 · 02 mole / liter of diethanolamine (㊣ Fluka 3 1 5 9 0 ). 0 ♦ 5 g of sample was dissolved in 100 ml of eluent. The injection volume was 20 // 1 and the chromatography time was 15 minutes. Example I-1: Preparation of compounds of formula

In a solution containing 2 2 1 · 2 grams (1 * 2 moles) of fluorouric acid and 1 2 8 6 grams of xylene, add 2 5 within 3 hours under stirring and nitrogen atmosphere. 4 ♦ 8 grams (1 ♦ 2 moles) of N — -69-This paper size applies to Chinese National Standard (cns) A4 (210X297 mm) ί ~ |, 0II (Please read the precautions on the back before filling in this Page), 1T printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 491869 Λ7 B7 V. Description of the invention When the temperature is maintained at about 30 ° C, a thick but still agitable suspension is obtained and maintained at the temperature shown for 15 minutes. Next, add a mixture containing 1 7 6 ♦ 3 g of Na 〇 Η 3 0% (% w / v) aqueous solution and 2 0 0 g of water over 1 hour, maintaining the temperature at about 3 0 ° C, the reaction mixture Maintained at about 3012 * 5 hours. During this time, all solids were dissolved and a suspension was formed. The alkaline solution was then separated. The remaining xylene solution was heated to 5 ου, and 2 3 6 · 8 g (0. 6 mol) of N, N / —bis (2,2, 6,6-tetramethyl-1, 4- (pyridinyl) -1,6-hexanediamine, followed by adding 1 7 6 ♦ 3 g of Na a 0 Η 30% (% w / ν) aqueous solution in 2 hours . During the addition, the temperature was maintained at about 50 ° C, and then the temperature rose to about 80 ° C in 1 hour. Maintain the reaction mixture at 80 ° C for 1 h with stirring for 5 hours. The alkaline aqueous solution was separated at about 80 t), and 3,80 grams of xylene (68-82 ° 0 / 200-120111 dagger) was distilled under vacuum in an organic solution (maintained at about 80υ), Add 1 1 8 * 4 grams (0.3 mole) of N, N'-bis (2,2,6,6-tetramethyl-1,4-pyridyl) -1,6-hexane within 5 minutes Alkylenediamine, then, stir the reaction mixture for 5 minutes, and add 92 g of Na 2 O 3 0% (% w / ν) aqueous solution (temperature is about 80) within 5 minutes -70- This paper size applies to China National Standard (cns) A4 specification (210X297 mm) (Please read the precautions on the back before filling this page)

^ 1869 Λ7 Β7 V. Description of the invention U <) i Then, the reaction mixture was transferred to a pressurized reactor. 300 g of water and 170 g of xylene were added. Nitrogen inertization reactor, the temperature rises to 160 TJ in 2 hours * Maintain the mixture at 160 ° C for 9 hours (pressure 5 · 4 bar) 0 After cooling to 60, add in 5 minutes 8 9 * 0 g (0 ♦ 6 9 mol) of di-n-butylamine, followed by adding 8 6 ♦ 4 g of Na 30% (% w / v) aqueous solution in 5 minutes. The reactor H compound was closed again and heated to 160 ° C 'within 1 hour and maintained at 160 ° () for 4 hours (5 bar pressure). After cooling to 600 ° C, 130 grams of Toluene and 150 grams of water, the mixture was heated to 90 ° C with stirring and the aqueous solution was separated. The organic phase M 4 000 grams of water was washed twice and azeotropically dried. The solution was cooled to about 30 t ' Filtration and concentration under vacuum (1 2 5-2 3 0; i 0/3 50-1 mbar) c. The molten product can be obtained as a solid ° The melting point of this product is 1 3 3-1 3 7 ° C. Μ π (by GPC = Gel Permeation Chromatography Chromatography) = 2 2 0 0 g / mole. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) M w / Μ η = 1 ♦ 6 GPC analysis shows the spectrum as shown in Figure 1. Analysis of the product obtained: η / = 1 compound: 39 9 mole% η / = 3 compound: 20 mole% η / = 5 compound: 9 ♦ 3 Mole% -7 1- This paper size applies to the Chinese National Standard (CNS) A4 specification (210 × 297 mm) 491869 A7 B7 V. Description of the invention (L㈠ Π / = 7 compound : Preparation of the compound of the formula: 4 * 4 mole% Example I-2

J-* ------ Hi clothing— (Please read the precautions on the back before filling in this page)

1T printed by a consumer co-operative of the Central Standards Bureau of the Ministry of Economic Affairs in a solution containing 5 5 ♦ 3 g (0 ♦ 3 mol) of cyanuric chloride and dissolved in 250 ml of methyl isobutyl ketone 5 ° C) Add 6 3 ♦ 7 g (0 · 3 mol) of N — (2, 2, 6, 6-tetramethyl-1 4 #pyridyl) -n-butylamine, keep the temperature while adding For about 5. Then 40 ml of water was added together with a Na 0 Η 30% (% w / v) aqueous solution. After the addition, the reaction mixture was heated to room temperature, and a mixture containing 5 9 ♦ 2 g ( 0 ♦ 1 5 mole) N, N / one bis (2,2,6,6-tetramethyl-1,4-piperidinyl) -1,6-hexanediamine dissolved in 1 2 5 ml methyl isobutyl Based solution. -72- This paper size applies Chinese National Standard (CNS) A4 (210X 297 mm) 491869 Λ7 B7 V. Description of the invention () Then heat the mixture to 60 ° C, and then add 40 ml of water (maintained at 60 ° C for 1 hour). (Please read the notes on the back before filling this page) Add 40 grams of NaOHSO% (% w / v) aqueous solution, and heat the mixture to 70 ° C. After 1/2 hour, distill out 2 0 0 under a slight vacuum Ml of methyl isobutyl ketone and 30 ml of water. Here kept in an organic mixture of 70 υ, 2 9 · 6 g (0.075 mol) of N, N '-(2,2,6,6 -tetramethyl-4 amidinyl) -1 , 6-hexanediamine, and 20 g of Na 0 a 30% (% w / v) aqueous solution was added. Then, the reaction mixture was transferred to a pressurized reactor, and 50 ml of methyl isobutyl ketone | and 40 ml of water were added. After the reactor was sealed, the nitrogen was inertized to the reactor, and the temperature was raised to 160. ° C. The temperature was maintained at 160 ° C for 4 hours (under 6 b a r pressure). After cooling to 60 ° C, 3 6 · 6 g (0 ♦ 17 mol) of N- (2,2,6,6-tetramethyl-1,4-pyridyl) -n-butylamine was added. And 20 grams of Na 0 Η 30% (% w / v) aqueous solution. Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. The reactor was resealed. The mixture was heated to 140 ° C and maintained at 140 t for 4 hours (under 5 b a r pressure). After cooling to 50 ° C, 125 ml of methyl isobutyl ketone and 100 ml of water were added. The alkaline aqueous phase was separated, and the organic phase was washed once with 100 ml of water. The organic phase was concentrated under vacuum at κ 2 20 ° C / 20 m b a r. -73- This paper size is in accordance with Chinese National Standard (CNS) A4 (2l0x297mm) — 491869 hi B7 V. Description of the invention (Heart 9) After cooling, a solid can be obtained from the molten product, melting point = 1 7 2 — 1 7 4 ° C. M η (measured by G PC) = 2 0 8 0 g / mol Mw // iMn = 1 * 52 G PC analysis shows the map shown in FIG. 2. Analysis of the obtained product: π / = 1 compound: 31 1 mole% η < = 3 compound: 23 mole% η / = 5 compound: 5 mole% ny = 7 compound: [莫Ear% Example 1: Preparation of the following formula (please read the precautions on the back before filling this page) c4h9 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs H9C4-N-

This paper size applies to China National Standard (CNS) A4 (210X297 mm). Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economy. There are 40 * 0 grams (16.16 mols) of the product of I-1, 0.40 g of M03, and 320 ml of cyclohexane. The mixture was heated to reflux temperature, and 80 2 ♦ 4 g (0 ♦ 6 4 mol) of 70% tert-butyl hydrogen peroxide was added in 30 minutes. Water was collected by azeotropic distillation and refluxed for 1 hour. The reaction mixture was transferred to a magnetically stirred glass pressure bottle and maintained at 130 ° C for 5 hours. The reaction mixture was cooled to 70 ° C, and 000,000 was filtered out. The solution of 20,000 g of Na 2 S 0 3 in the filtrate was dissolved in 100 ml of water and washed for 1 hour (60 ° C). The layers were dried and the organic phase M M g S 0 4 was dried, reducing the total volume to about 100 ml. The solution was dissolved in 500 ml of methanol (5 Torr), and the precipitate was filtered off and dried to a weight of 52.8 g (95% of theory). The melting point of the obtained product ranges from 1 4 0 to 1 7 0 υ. 1 Η NMR: 0 ♦ 8 5 — 2 ♦ 4 0 ppm (composite mixture); 3 ♦ 2 5 — 3 ♦ 3 5 ppm (s, width, NC Η 2); 3 * 62ppm (s, width, NOC); 4 * 9 — 5 · 4 ppm (s, width, NCH) 0 1 3 CNMR: 8 1 * 8 ppm (N 0 CH); 16 5 ppm (tri-C). The proton ratios at 3 ♦ 25, 3 · 62, and 4 * 90ppm are 2: -75- This paper size applies the Chinese National Standard (CNS) A4 specification (210X 297 mm) ί 01 — (Please read the precautions on the back first Fill out this page again), 1T #f 491869 Λ7 B7 V. Description of the invention (?) 0 Example 1 A: Preparation of the compound of the following formula

L-^ --------- (Please read the notes on the back before filling out this page) A mixture printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs, including 8 8 5 grams (3 * 5 4 Mo Ear) Example I-1 Product, 6 0 0 g (7 1 · 4 mol) of cyclohexane and 2 2 g of molybdenum trioxide were heated to reflux temperature. Add a solution containing 3360 grams of 70% tert-butyl hydroperoxide solution (26. 1 mole) in 1 to 2 hours and remove the water azeotropically. The reaction mixture was transferred to a pressurized reactor and heated at 30 ° C (30-50 psig, 2 · 1-3 · 5 b a r) until the red color disappeared. The crude reaction product was cooled and treated with an aqueous solution of sodium sulfite, which destroyed the residual peroxide. The aqueous layer was separated, and the organic phase layer was concentrated to a melt under reduced pressure, and then it was slowly fed into a cold methanol. After filtration, an off-white-76- This paper size applies to China National Standard (CNS) A4 (210X297 mm) 491869 Λ7 B7 V. Description of the invention (7 //) Average penetration value of colored solid product 4 2 5 nm 4 7 5 π m 1 〇% toluene): 2 1 · 8%; 4 5 0 6 2 ^ 6 96 3 7 ^ 4 96 Example 1-B: Preparation of a compound of the formula c4h9 h9c4-N-

c4h9 ^ -N ——C4H9

(Please read the precautions on the back before filling out this page.) The steps of the repeating example 1-A are printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs, but during purification, the molten product obtained after removing cyclohexane is K Shuyi. Butyl alcohol was diluted and concentrated to 50% solids. Cool the solution and quickly add cold methanol. After filtration, the average penetration value of the off-white solid product (10% toluene) is obtained: 4 2 5 nm = 5 7 · 〇%; 4 5 Ο 475nm = 79, 7% -77- 7 5% This paper size applies Chinese National Standard (CNS) A4 specification (210X 297 mm) 491869 A7 B7 V. Description of the invention

The Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs printed a mechanically stirred 1 ♦ 0 liter 4-neck flask, charged with 4 〇 ♦ 〇 g (〇.16 mol) of 1-1 product, 0.4 g of Μ 0 3, and 302 ml of n-octane. The mixture was heated to reflux temperature, and 8 2 ♦ 4 g (0 ♦ 6 4 mol) of t-butyl hydroperoxide was added over 30 minutes. Water was collected by azeotropic distillation and refluxed continuously for 90 minutes. The reaction mixture was transferred to a magnetically stirred pressure bottle and heated at 130 ° C for 3 hours. M03 was filtered, and the solution of M20g of Naz S03 dissolved in 100ml of water was washed and poured for 30 minutes (60 ° C). The different phases were separated. The organic phase was 100ml of water. Wash and then saturate Ν a C 1 in 100 ml, and then μ μg S 0 4 -78- this paper ruler; ΐ apply Chinese National Standard (CNS) A4 specification (210X297 mm 1 ~~ 491869 Λ7 B7 five 2. Description of the invention (p) Dry, then evaporate to a total volume reduced to about 100 ml. The solution is dissolved in 500 ml of methanol (5υ), and the precipitate (soft glass body) is in a vacuum oven (5 5 ° C) After drying for 1 hour, the product (now a hard broken glass body) was pulverized by a pulverizer, and then dried to 47.4 g (78% of the theoretical value). The melting point of the obtained product was in the range of 140-170 ° C. 1 Η NMR: 0 ♦ 8 2 — 2 ♦ 4 0 ppm (composite mixture); 3 * 2 5-3 · 4 0 ppm (s, width, NC Η 2); 3 ♦ 6 0 — 3 ♦ 9 2 ppm ( Compound, N 0 C Η and NCH2 of NC4H9); 4.90-5.40ρργ (composite, NC Η). 1 3 CNMR: 7 8 · 6 — 8 3 ♦ 4 ppm (Triple absorption peak, N 0 C Η) ; 1 6 5 ppm (three C) and the 3 ♦ 2 5 4 * 9 0 p p m proton ratio of 2: 1 (Read precautions to fill out the back of the page) •.

1 2 cases of AI under the 1T compound type. Printed by CJ Hy

n

Η 8 όIC This paper size applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 491869 A7 B7 V. Description of the invention (a mixture including 1 3 0 4 g (5 · 2 1 Moore) Example I ai The product, 1.0 kg (90. 2 mol) of octane and 4.0 mg of molybdenum trioxide 'was heated to reflux temperature. Add 1 8 7 3 g 7 in 1 to 2 hours A solution of 0% tert-butyl hydroperoxide in water (30 mol) and azeotropic distillation to remove the water. The reaction mixture was heated at a stream temperature and under pressure until the red color disappeared. And sulfite: treatment of sodium hydroxide solution to destroy the residual g of peroxide. Dilute the water solution 丨 night calendar 5 there are several phases under _ ® 丨 agriculture · condensation ~ contain the melt, and then Feed slowly into a cold methanol, and then filter to obtain an off-white solid product. Average penetration value (10% toluene): 425 nm = 39 * 3%; 450nm = 75 * 1% 475) 1311 = ^ 87 * 3 96 I—mmt— u I— m--n I (Please read the notes on the back before filling out this page} Customized product type B 1 2 Ministry of Economic Affairs Bureau of Standards real employees consumer cooperatives printed C H "

c ·

A Ns c / V I quasi I standard I country country I secondary use moderate one foot per piece of paper K

I. centipede 7 9 2 X 491869 Λ7 B7 V. Description of the invention (彳 <) The Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs printed the procedure of Repeating Example 2-A, but during purification, the octane was removed The melt M was diluted with tert-butyl alcohol and concentrated to 50% solids. The solution was cooled, and cold methanol was added quickly, and an off-white solid product was obtained after mashing. Average penetration value (10% toluene): 425nm = 59 * 8%; 450nm = 8 2 * 5 96 4 7 5 nm = 9 1 ♦ 2 96 Example I—A ·· Photostabilizing effect on polypropylene dimensional 2 ♦ 5 grams of stabilizers from Table 1, 1 gram of tris (2,4-di-tert-butylphenyl) phosphite, 1 gram of monoethyl 3,5-di-tert-butyl-1-4 Calcium hydroxybenzyl monophosphonate, 1 g of calcium stearate and 2 ♦ 5 g of titanium dioxide in a slow mixer and 1000 g of polypropylene powder (with melt index = 12 g / 1 min) , Measured at 230 ° C and 2.16 kg)). Polymer mixtures can be obtained by extruding the mixture at 2000-230 ° C, and then converted into fibers (Θ leonard-Sumirago (VA) using a guided type device (P i 1 〇t-type). , Italy), and operate under the following conditions: -81- -------- #! (Please read the precautions on the back before filling this page)

、 1T This paper size is applicable to Chinese National Standard (CNS) A4 specification (210X297 mm) 491869 A7 __B7 V. Description of invention㈠ 2 3 0-2 4 5 υ 2 5 5-2 6 0 ° C 1: 3 ♦ 5 1 1 denier / filament extrusion temperature: extrusion head temperature: stretch ratio: linear density: Μ The fiber prepared by this method is fixed on a white board, and the temperature is 6 5 WR WeatherHeter (ASTM 1) 2 5 6 5- 85) Medium exposure, blackboard temperature is 6 3 "1C. After the sample has been exposed for various times, use a constant speed tensiometer to measure the residual toughness, and then calculate the time required for exposure to half the initial toughness (T $.). Table T 5 0 (hours) 3 4 9 0 Stabilizer Example 1-1 Compounds The compounds of Table 1 show good light stability in polypropylene fibers. Example I-B: Interaction of pigments in polypropylene test boards Central of the Ministry of Economic Affairs Printed by the Standards Bureau ’s Consumer Cooperative (please read the precautions on the back before filling out this page) 5 ♦ 6 2 5 grams of stabilizer in Table 2, 1 3 ♦ 5 0 0 grams Pigmen t. Blue 15 “Flush” (5 0% mixed in polyethylene) and 2 5 · 8 7 5 g polypropylene powder (with melt Index is about χ 4, measured at 2 3 Ο υ and 2 ♦ 16 kg) added to a Haake internal mixer (room temperature) (Haake Buchler Rheochord System 40, using 60 cc 3 R heo in ixer). Rotary speed of crooked blade -8 2- This paper size applies to China National Standard (CNS) A4 (210X297 mm) 491869 A7 B7 V. Description of the invention) (Please read the notes on the back before filling This page) is at 5 RP Μ (revolutions per minute), and a 5 kg ladle is used to seal the bowl mouth. The temperature rises to 180 ° C and is maintained at 180 ° C. The total time is 30 The mixture was removed after 30 minutes at 180 ° C and cooled to room temperature. The resulting mixture, called a concentrate, was reused. 0 ♦ 9 0 0 g of this concentrate, 3 ♦ 6 0 0 g Titanium dioxide " Flush " (50% mixture / polyethylene), and 40 · 500 grams of polypropylene powder (having a melt index of about 14, measured at 230 ° C and 2.16 kg ) Add to a ® HAAKE mixing bowl container at a temperature of 160 ° C, rotate the crooked knife and then rotate it at 20 RP Μ, use a 5 cm The pound of rice dumplings sealed the mouth of the bowl, the temperature rose to 170 ° C, and R P M rose to 125. The total time is 30 minutes. The molten mixture was removed at 170 ° C, transferred to a hand-operated tool (room temperature) and formed into a circular test plate with a diameter of 1 mm X 2 5 mm. 'The resulting mixture was called a 〃reduction (1 etd 0 wn) 〃 'And this test board is called the "lower test board". The color difference printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs, (de 11 a E) (CIE color difference equation) The measurement includes Table 2 stabilizer sample dropdown test board and stabilizer-free control reduction (1 etd 〇w η) de 11 a E (CIE color difference equation) of the test board, this measurement is made using Applied Color Systems

Spectrophotometer M o d e 1 C S-5 (U S A) is performed. The measurement parameter is 4 00 — 700 nm — scan, small area inspection, reaction ’fluorescence D 6 5, 10 degrees observation. -8 3-This paper size applies Chinese National Standard (CNS) A4 (21 × 297 mm) 491869 Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs Λ7 B7 V. Description of the invention (the body) The above method conditions are simulated pigments Stabilizer concentrate (parent) manufacturing and subsequent reduction (1 et -d 0 wn) (dilution) into the final plastic article. Higher de e 11 a E values represent pigment aggregation and poor dispersion. (1611 & E value 0 · 5 or less can not be seen by the eyes ° Table 2:

Stabilizer D e 11 a E Example I-1 Compound 0 ♦ 5 In polypropylene test panels, the stabilizers in Table 2 show low pigment interactions. This is advantageous. Example I-C: For the light stabilization of polypropylene tapes 1 g of each compound of Table 3, 1 g of tris (2,4-di-tert-butylphenyl) phosphite, 5 g of pentaerythritol tetra [3- (3,5-di-tert-butyl-1,4-trimethylphenyl) propionate] and 1 g of calcium stearate and 100 g of polypropylene powder (having a melt index of 2 · 1 (Measured at 2 30 ° C and 2 ♦ 16 kg) mixed in an accelerated mixer. The mixture is extruded into polymer granules from 200 to 2 2 0, which is then extruded using a semi-industrial-type device Stretched into 50 um thick and 2 · 5 mm wide tape (® L e ο nard-SU in irag 〇 (VA)-11 a 1 y) 'and operate under the following conditions: -84 a paper size applicable China National Standard (CNS) M specifications (210 × 297 mm) J_. Touch 丨 — (Please read the precautions on the back before filling this page)

、 1T 491869 A7 B7 V. Description of the invention (y /) Extrusion temperature: 2 1 0 — 2 3 0

Extrusion head temperature: 2 4 0 — 2 6 0 ° C Stretch ratio: 1: 6 Μ The tape prepared by this method is fixed on a white board after '6-1 WR Weather-O-Meter (ASTM D 2 5 6 5-85), the blackboard temperature is 6 3.0. After the sample has been exposed for various times, use a constant speed tensiometer to measure the residual toughness, and then calculate the time (hours) required for the exposure to half the initial toughness (T 50). Table 3: Stabilizer T 50 (hours) Example I-1 Compound 3170 The compounds listed in Table 3 show good light stability for polypropylene tapes. Example I-D: Antioxidant effect of polypropylene board Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) 1 gram of each of the compounds listed in Table 4 and 1 gram Calcium stearate was mixed with 1 000 g of polypropylene powder (having a melt index of 4 · 3 (measured at 2 3 0 ° C and 2 · 16 kg) in a slow mixer. The mixture was mixed at 2 0 0 — Extruded into polymer pellets at 2 2 0 ° C, and then made into a 1 mm thick test plate by M injection molding at 2 2 0 ° C. Then use DIN 5 3 4 5 1 mold to punch this test plate and Deyi-85-This paper size is in accordance with Chinese National Standard (CNS) A4 (210X297 mm) 491869 Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs B7 V. Description of invention (π) Test block Exposure in a powerful circulating air oven at a temperature of 1 3 5 ° C. Periodically 1 8 0. Fold this test block 'to check the time (hours) it takes to break. Table 4: Time required for the stabilizer to break ( Hours >

Example I 1 Compound 1 8 3 G The compound of Table 4 shows excellent antioxidative effect on polypropylene test panels. Examples I-E: Color of polypropylene test panel after oven aging 5 grams of compounds listed in Table 5, 1 Grams of tris [2,4-di-tert-butylphenyl] phosphite, 1 gram of pentaerythritol tetrakis [3-tris (3'5-di-tert-butyl-4-hydroxybenzyl) propionate] And 1 g of calcium stearate in a slow mixer with 1000 g of polypropylene powder (having a melt index of 2 · 1 (measured at 230 ° C and 2 ♦ 16 kg)) . The resulting mixture was extruded twice at 2000-220 t to obtain polymer pellets, and then pressed at 230 ° C for 6 minutes to form a 1 mm thick test plate. Expose the test board in a powerful circulating air oven for 7 days (120 ° C). After the oven is exposed to the test, it shall be in accordance with ASTMD 1 9 2 5 ® -86- This paper is in accordance with China National Standard (CNS) Α4 specification (210 × 297 mm).% 丨 丨 (Please read the precautions on the back before filling this page), 1T 491869 Λ7 B? I. Description of the invention (MINOLTA CR 210 colorimeter (MINOLTA-Japan) measures the yellowing index of the test board (YI) 〇 Table 5: YI values obtained by stabilizers according to ASTM D 1 9 2 5 Example I-1 Compound 8 ♦ 7 Μ The polypropylene test panel stabilized by the compounds listed in Table 5 has a good yellowing index after oven aging. (Please read the precautions on the back before filling this page) Example of printing by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs I-F: Rotary molded linear low-density polyethylene (Hexene-Copolymer, © Quantum MP 6 3 5-6 6 1 μ I = 6 · 5 dg / mi η, · density = 0 · 935 g / c P), containing 0 ♦ 〇 5% zinc stearate, 0 ♦ 5% 5% pentaerythritol tetra [3 — ( 3,5-di-tert-butyl-4 4-hydroxybenzyl) propionate] and 0 ♦ 1 0 % Of tris [2,4-di-t-butylbenzyl] phosphite, mixed with M dry-mixing method and 0 1.7 1% of the compound of Example I-1, and then synthesized at 2 3 4 ° C Granular. Use a Reduct, i ο η E ngineering Μ ode 1 50 0 P! 1 verizer to grind this fully formulated resin (particle size 100 mesh and 35 mesh). The ground resin is placed in Yiaotao In a tin mold (1 6 〃 X 1 6 〃 X 6 〃), and a two-axis fixed rotation (FSP Μ 2 0⑬C 1 amshe 11) in a laboratory-grade rotary molder in a gas-heated oven. Processing conditions are: : 15 minutes (2 8 8 ° C) _ 8 7 _ This paper size applies to Chinese National Standard (CNS) A4 specification (210X 297 mm), τ Γ 491869 Λ7 _ B7 V. Description of the invention (彡 〆) (Conditions) 1), or 12 minutes (3 1 6 υ) (Condition 2). A) The color-determined molded box is cut into 2 〃 X 2 〃 test pieces and placed in a Blue μ strong-cycle oven K 1 2 0 ° C exposure. Yellowing is determined according to the reflection mode of a s T M D 1 9 2 5 on an A ρ ρ 1 i e d C ο 1 o r S y s t e m s spectrometer

Index Q Samples containing the compound of Example I-1 exhibited low color differences after molding and heat aging. b) UV light is stable and active, another 2 〃 X 2 〃 test board is cut out from the molded box, and in —® Atlas Xenon-Arc-Weather-O-Meter according to ASTM G26, at 63 ° Cpbt, 0 * 35kW / cm2 (34 0 nm) exposure, using ®Dynatup Model 8 2 50 Drop T ower to periodically determine the impact strength change The more effective the system is. Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page). According to the definition of the above, there is a test board containing the compound of Example I-1. Example A:

Dyeing thermoplastic olefin (TP 0) particles are composed of mixed polyolefin mixture (polypropylene containing ethylene-propylene copolymer; ® ο 1 ytr 〇pe τ PP _ 8 8-Ϊ paper size applies to Chinese National Standard (CNS) A4 specifications (210X297 mm) " Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 491869 kl B7 V. Invention Description (518-01, Price ® A. Schulman, Inc .; Akron, Ohio, US A) and the table below The additives are listed in a ® Superior / MPM 1 〃 single-roll extruder (24: 1 L / D) with all-in-one rolls, and are mixed at a temperature of Μ, and then cooled in a water bath. Before molding, the additives are dried and mixed in a tumble dryer. Additives: 0 · 2 5% *) R ed 3 B (red pigment 1 7 7, color index 6 5 3 0 0), 0.05% *) Pentaerythritol tetra [3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionate] 0.05% tris [2,4-di-tert-butylphenyl] phosphite, 0.2 % *) Of 2- (2'-hydroxy-3 ', 5'-di-tert-pentylphenyl) benzotriazole 0.2% *) bis (buthoxy-2,2,6 , 6-tetramethyl-4 -morphinyl) Sebacate 0.1% *) calcium stearate, about 10% *) talc, and stabilizers of Table 6 *) According to the weight percentage of the polyolefin mixture, the granules were about 190 ° It is molded into a 1 · 5 2 4 mm thick, 2 〃 X 2 〃 test board in a ® BOY 3 0M injection molding machine under C. The test board is fixed on a metal frame and in a ® Atlas Ci65 Xenon Arc Weather-0-Bieter with a blackboard temperature of 70 ° C, 0 · 55 watts. / Meters 2, 3 4 0 nm, 50 relative humidity, Intermittent M light-89-This paper size is applicable to Chinese National Standard (CNS) Α4 size (210X 29 < 7 mm) (Please read the precautions on the back before filling this page)

Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 491869 Λ7 B7 V. Description of Invention (_) / Dark Cycle and Water Exposure (® S 〇 c i e ty of Automotive Engineers -S A E J 1 9 6 0 Test Procedure-Exterior

Automotive conditions) 〇 Gloss is based on A S T M D 5 2 3 in ® BYK-GARDNER Haze / Gloss Meter M 6 0. measuring. The results are shown in Table 6. Table 6: Pentaerythritol tetra [3-(3,5-di-tert-butyl- _ 9 0-0-0 5% *) This paper size applies Chinese National Standard (CNS) A4 specification (21〇297297 mm) ) (Please read the notes on the back before filling this page)

1, 1T stabilizer in We a the gloss retention-0-Meter after holding 0 hours (about ΰ k J / δ ΐ 2 * *) 1 8 9 Q hours (about 2 5 0 0 kJ / in2 **) 0 · 0 5% *) pentaerythritol tetra [3-(3,5 -di-tert-butyl-4-hydroxyphenyl) propionate 5 0. 05% * tris [2,4 -di- Tert-butylphenyl] phosphite 0.20% *) Example 1 Compound 100.0¾ 9 0.5¾ 491869 hi B7 V. Description of the invention (/) 4-hydroxyphenyl) propionate, 0.05% * of three [2,4-Di-tert-butylphenyl] phosphite 0.20% *) Example 2 Compound 100.0% 91.9¾ 0. 5% *) Di (hydrogenated tall oil) Hydroxylamine 100.0 % 8 7.3% 0.2 Q% *) Example 1 Compound • One by one ----0. 0.5% *) bis (hydrogenated tall oil) hydroxylamine 100.0% 8 8.0¾ 0.2 0.2% * ) Example 2 Compound—One * One · 1 — · I— (Please read the notes on the back before filling this page)

, 1T *) Weight percentage (calculated based on polyolefin mixture) **) Incident energy, expressed (34Gnin under test capsule) Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs with formula 6 containing stabilizers than those without stabilizers S2: & Stomach K% _ solution has much larger resistance. Example B: A fiber grade polypropylene containing 0 ♦ 0 5 wt% calcium stearate and 0 ′ 0 5 wt% di (hydrogenated tall oil) hydroxylamine is stabilized as a base and stabilized as shown in Table 7 The agent is dry-mixed, and then the paper size applies to the Chinese National Standard (CNS) A4 specification (210X297 mm) 491869 Λ7 B7 at the scale of 2 3 4 -91- 5. The description of the invention (office) is melted to form granules at ° C. This fully granulated resin is then spun into fibers using a ® Hills Lab Grade Fiber Extruder at 2 46 ° C or 27 4 ° C. This 41-denier fiber bundle M 1: 3 ♦ 2 was stretched to obtain a fiber of 6 1 5/41 1 denier. The stabilized polypropylene was knitted with Socks 〃 on Lawson-Hemphill Analysis K nit, t, er, and then at ® Atlas X e η on-A ϊ * c-W eather-0 mete rvi: SAE 1 8 8 5 Interior Automotive conditions 8 9 ° Cb pt, 0 ♦ 5 5 kW / cm2, 3 4 0 nm, no water spray cycle exposure. In this test, the sock weaved with a blunt glass rod and a scratched glass rod was determined by observing its physical properties. The longer it takes for the fissure to occur, the more effective the stabilizer is. The results are shown in Table 7. Table 7: JL # 丨 丨 (Please read the precautions on the back before filling in this page) Order Stabilizer Dramatic Cracking Breaking Dramatic Cracking Spinning at 2 4 6 ° C Spinning at 2 7 4 ° C Spinning #f Economy Central Printed by the Consumer Bureau of the Standards Bureau without 192 2 hours 9 6 hours. ♦ 25% by weight. 6 0 0 hours 4 0 8 hours. Example 1 Compound-92- This paper applies Chinese National Standard (CNS) A4. Specifications (210X297 mm) 491869 Λ7 B7 V. Description of the invention (Clever) 0 ♦ 25% by weight 660 0 0 4 0 8 hour fraction Example 2 Compound III, 0 丨 (Please read the precautions on the back first (Fill in this page again), 11 Printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs-93- This paper size applies to China National Standard (CNS) A4 (210X297 mm) 491869 GPC analysis chart Figure 2 is the GPC analysis chart of the product of Example 1-2

Claims (1)

491869 A8 B8 C8 D8 Preparation £ 9L 2, 1 * A method comprising a substituted 2,2,6,6 -tetramethyl-4 4-fluorenyl block oligofluorene, this method includes: 1 ) The formula (α) of the compound Cl, / N, / CI Ν ΝΝΝ Β and the formula (/ 3) is reacted. This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) 491869 A8 B8 C8 D8 VI. Patent application scope (please read the precautions on the back before writing this page) 2) Reverse formula, β 、) Hewei Wei and Formula (7) Compound pound, the reaction mole ratio is 0 ♦ 4: 1 to 0 * 7 5: 1; 3) Exist in reaction 2) Formula (3) terminal group in reaction The reaction between Β and the compound of the following formula (ξ): A-Η The mole fcb reaction is reduced to 2: 1 ♦ 7 to 2: 3; the reactions 1) to 3) are performed in a solution of SI and the presence of an inorganic base ; And 4) the formula (G-I) group base that exists in the reaction 3) product: This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 491869 A8 B8 C8 D8 patent application scope G-l) is transformed into the formula (G-group basis: (Please read the notes on the back before filling in this page) The conversion is performed by reaction 3) the product and a hydrogen peroxide in a hydrocarbon solvent and the presence of a peroxide decomposition catalyst; ) Is performed at a temperature of 10Ό to 90Ό, reluctantly 2) is performed at a temperature of 1 10t to 220, reaction 3) is performed at a temperature of 110u to 1801; reactions 2) and 3) are performed at a pressure of 3 to 8 bar And (3) the group base of formula (G — 1) in the peroxidase reaction, (GI) This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 491869 A8B8C8D8 々, the scope of patent application is 2 to 8 moles of hydrogen peroxide per week, 0 ♦ 〇 〇 1 to 〇 ♦ 1 Moore's catalyst for decomposition of europium peroxide, and 5 to 30 moles of hydrocarbon solvents; Ri is Cs—Ci 8 complex or Cs—Ci 2 cyclohexyl, and the hydrocarbons in reaction 4) The compound solvent is based on Ri, which is Cs—C 1 8 or CS—C i 2 ring synthesis; Rz is Cz—Cs calcined, R is a group of formula (G—i); A is a N (R4) (Rs), or group (II) group base; (Please read the precautions on the back before filling this page) -R 4 and R s (same or different) are C i -C 3 alkyl; B is a group group of formula (II); X is > NR g; and RS is C i-C 8 fluorenyl c 2 * If the method according to item 1 of the patent scope is claimed, wherein the organic solvents in 1) to 3) are aromatic hydrocarbons or fatty ketones, and the inorganic base is sodium hydroxide, potassium hydroxide, sodium carbonate Or potassium carbonate. 3 + If you ask for the method of item 1 of the patent scope, where: This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 491869 A8 B8 C8 D8 6. The scope of patent application R i is octyl or Cyclohexyl, and the hydrocarbon solvent (depending on R i) of reaction 4) is octane or cyclohexane. 4 + The method according to item 1 of Zhuanzhan Fanyuan, in which: the peroxide decomposition catalyst is a metal carbonyl compound, a metal hafnium oxide, a metal isapropionate or a metal alkoxide, wherein the metal is selected from Periodic table of the metal 5 V b 5 V b VI VI b, VII b and V II II + 0 + method such as the first item in the cold range, where: Hydrogen peroxide is Syria-butyl hydrogen peroxide, And the peroxide decomposition catalyst is M 003 0 6 *-a mixture that is stable around lower carbon number polyolefins and resistant to degradation caused by light, heat or oxygen. This mixture contains monodisperse of formula (P-I) Compounds, monodisperse compounds of the formula (P-II), monodisperse compounds of the formula (P-III), and monodisperse compounds of the formula (P-IV). These compounds differ only in that they repeat Qin Yuan. The paper size is applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) (please read the precautions on the back before writing this page) 491869 A8 B8 C8 D8 Patent Application Scope This paper size applies the Chinese National Standard (CNS) A4 specification (210 χ 297 mm) 491869 A8B8C8D8 Patent application scope The total amount of compounds of formula (P-I) is 15 to 45 mol%, formula (P-II) The total amount is 15 to 35 mole%. The total amount of the compound of formula (P-III) is 3 to 18 mole% relative to the total mixture (1: 100%)); and Ri is Cs — Ci 3 healds or Cs — C i 2 ring healds; R 2 is C 2 — CS support; R is a group (G-II) group (please read the notes on the back before filling this page) (G-II), \ 二 口 A meter is a N (R4) (R s), or a group basis of the formula (G- IV) (G-IV) This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) 491869 098825 ABCD VI. Patent application scope R 4 and RS (same or different) are C ί a CS alkyl B is a group group of formula (G-IV); X meter is > N-R 6 meter; and R 6 is a mixture of Cl-C 8 comprehensive group 0 7 + 5ΠΦ 谞 patent scope item 6 Monodisperse chemical compounds containing formula (P-IV), (Please read the precautions on the back before filling this page) A · N. R * A * NN \\ g ermo 5 IX to 1 is the amount of ο, 物 1 T 合 1 共 I mixed P ((the general formula is in the opposite phase CP containing inclusions into a more complex antiphase 0 ( Causes% to 5 to oxygen 1 or ο heat ♦ ... ο light and hydrocarbon-resistant olefins to stabilize the fixed number of carbons by low-weight heavier hydrocarbon olefins poly-carbons low Fanli special Φ such as the blend Item 8 8 This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 491869 A8 B8 C8 D8 6. Scope of patent application (please read the precautions on the back before writing this page) 9 ♦ If ΦPlease refer to the composition of item 8 of the patent, wherein the lower carbon number poly hydrocarbon is polyethylene or polypropylene. 1 0 ♦ —a method for stabilizing the lower carbon number polyolefin to resist degradation caused by light, heat or oxidation , Including a mixture of 0 to 0 1 to 5% (relative to lower carbon number polyolefins) in the more carbon number poly (hydrocarbon) poly (hydrocarbons), as in the application for the special section 6 of the special park. 1 1 * If not, please Method of patent scope M1, which only includes the step -t \ Ο \ '王) 王 d; ύ 12 * section Φ 谞 of the scope of patent scope 11 Method, wherein the product obtained in step 3) has a polydispersity ^ / ϋ value of 1 * 1 to 1 * 7 1 3 *-a mixture for stabilizing lower carbon number polyolefins against degradation caused by light, heat or oxidation, The mixture contains a compound of formula (M-I-a), a monodisperse compound of formula (M-II-a), and a mono-dispersion compound of formula (M-I ίI-a). These compounds are different. Only the difference in the number of repeating units, -3-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 491869 Α8 Β8 C8 D8 Ν- R r2- h3c h3c N " Ίϊ—Α N r B (M-l-a) „N ^ il—A N r B A N r B γί (please read the precautions on the reverse side before writing this page), \ two mouth Z and F 5 total 3 reaction groups defined by A, B, R, and formula (M — I — a ) Compound & Formula (M — II — a) Compound I 15 to 45 mole% in the first scope of the patent application, the amount is 15 to 35 mole%-10-This paper size applies Chinese national standards (CNS) A4 specification (210 X 297 mm) 491869 A8 B8 C8 D8 Patent application scope and formula (M — III compound total amount is 3 to 18 mol% (relative to the total mixture -11- This paper size applies China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before writing this page)