TWI226897B - Stabilizers mixtures - Google Patents

Abstract

A stabilizer mixture containing the components (A) and (B) wherein component (A) is for example a compound of the formula (A-1), wherein A1 is hydrogen or C1-C4alkyl, A2 is a direct bond or C1-C10alkylene, and n1 is a number from 2 to 50; and component (B) is formed by two different low molecular weight sterically hindered amine compounds containing a group of the formula (I) or (II); with the proviso that components (A) and (B) are different.

Description

1226897 5. Description of the invention (丨) The present invention relates to a stabilizer mixture, which includes a specific sterically hindered amine ester or amidine, and two different low molecular weight sterically hindered amines. Examples of stabilizer mixtures containing sterically hindered amine mixtures are described in US-A-4,692,468, US-A-4,863,981, US-A-5,719,217, US-A-5,919,399, US-A-5,965,643, US-A-5,980,783, US-A-6,015,849 and US-A-6,020,406 · The present invention relates to a stabilizer mixture comprising ingredients (A) and (B), wherein ingredient (A) is a compound of formula (A-1)

Where A! Is hydrogen or CVC4 alkyl, A2 is a direct bond or Ci-C ^ alkylene 'and η! Is a number from 2 to 50; at least one formula (A-2-a) and (A-2- b) Compounds, 4 This paper size applies Chinese National Standard (CNS) A4 Regulations (210 X 297 mm) — I— --- I ---- Order --------- (Please read first Note on the back, please fill out this page again) 1226897 A7 B7 V. Description of the invention (>

(A-2-a)

(CH

C ο where ii2 and n2 * are a compound of formula (A-3) from 2 to 50

h3c ch. ——N H3C \ 〇 n3 A3

a4 CH2—CH — 〇 h3c ch3 N — CH, —CH —CH, — N OH A3-

H3C CH, a4 (A-2-b)

OH I CH ^ -CH- CHj — N Ο Η3 °; ch,, CH,

h3c A4 n3 (A-3) -------- Order --------- ^ 9. (Please read the precautions on the back before filling this page) where A3 and A4 are not related to each other Respectively hydrogen or C, C8 alkyl, or A3 and A4 to form a ^ C2-C14 fluorenyl group and the variable n3 are independent of each other and a number from 1 to 50; or this paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1226897 A7 B7 V. Description of the invention (i) Compound of formula (A-4) -CH,--C-CH, -CH-I IC = 0 C 2 0 0 A7 n4 (A-4) where n4 is a number from 2 to 50, A5 is hydrogen or CVCU alkyl, and substituents a6 and a7 are independently alkyl or a group of formula (aI) h3c ch3

n-a8 (aI) h3c ch3 where A8 is hydrogen, CrC8 alkyl, 0 ·, -OH, -CH2CN, CVCu alkoxy, C5-C12 cycloalkoxy, C3-C6 alkenyl, C7-C9 phenyl Alkyl, which is unsubstituted, or substituted with 1, 2, or 3 alkyl groups on the phenyl group; or CVC8 fluorenyl, but limited to at least 50% of the substituents. 7 is a group of formula (aI) And component (B) is formed by two different low molecular weight sterically hindered amine compounds containing the group of formula ⑴ or (II); ----------------- --- Order --------- (Please read the precautions on the back before filling this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (II) 1226897 A7 B7 h3c ch3 Ό 5. Description of the invention (4: H ^ C CH,

h3c ch3 ① -N h3c ch3 but its limitation is that components (a) and (B) are different. · The preferred ingredient (B) compound has a molecular weight of up to 1,000 g, for example 155 to 800 g / mole, or 155 to 1,000 g / mole, or 300 to 800 g / mole, or 300 To 1,000 g / mole. The two different component (B) compounds are preferably selected from the group consisting of the following groups, β-1)-compounds of formula (B-1)

〇II 〇—c- _ε2 (Bl) Γ Qing first read the precautions on the back before filling in this page) -------- Order ---- ΠΓΊι where Eι is hydrogen, Ci-C8 courtyard, 〇 · , -OH, -CH2CN, CVCis, oxy, c5-Cu cycloalkoxy, CrC6 alkenyl, CrC9 phenylalkyl, which are unsubstituted, or have 1, 2 or 3 C on phenyl " C4 alkyl substituted; or Cl-c8 amidino, mi is 1, 2 or 4, if mi 疋 1 is a C1-C25 academy, if mi 疋 2, E2 is a Ci-Ch academy or a formula ( bI) The basic paper size of the group applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1226897 A7 B7? —E4 E,

OH Ec

V. Description of the invention ((bI) where E3 is a C1-C10 academy or a C2-C10 dilute group 'E4 is a C1-C10 alkylene, and E5 and E6 are unrelated to each other CkC4 alkyl, cyclohexyl or methyl Cyclohexyl, and if it is 4, E2 is a C4-C10 tetra group; β-2) —the compound of formula (B_2) H2C-CH ——CH-CH2 (β-2) II II () E7 e7 e7 e7 Two of them Each substituent E7 is < 00- (0: 1-(: 2 () alkyl), and two substituents E7 are a group of formula (b-II), (b-II) where E8 has the definition as Ei One of them β-3) —the compound of formula (B-3) (B-3) -------------------- Order --------- (Please read the notes on the back before filling this page) -Ν

Among them, the paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1226897 A7 B7 V. Description of the invention (E 9 and E 1 0 form C2-C14 alkylene, — '-Z1-COO- Z2 group Z1 is C2-C14 academy, and z2 is CkC24 alkyl, and E12 has one of the definitions of Ei; β-4) —a compound of formula (B-4), E_u is hydrogen or

—

(B-4) wherein the substituents E13 are irrelevant to each other such as one of the definitions, the substituents E14 are irrelevant to hydrogen or q-Cu alkyl, and Ei5 is Ci-Cio or C3-C1G compound fork; β-5) —a compound of formula (B-5),

h3c ch, H3C CH,

(B-5) wherein the substituents E16 are irrelevant to each other, such as one of the β! Definition β-6)-compounds of formula (B-6) --------------- ----- Order ------ |! 4. (Please read the precautions on the back before filling this page) This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 1226897 A7 B7 V. Description of Invention (

18 (B-6)

E17 is C1-C24, and E18 has one as defined in E! Β-7) —a compound of formula (B-7) E ′ X / 21 N N (B-7) 0

0 of which E19, E2G and E21 are unrelated to each other (b-III) group basis h3c ch3

-CH—CH —CH2—NH OH

N — E ’22 h3c ch3 (b-III) where E22 has one of the definitions of Ei β-8)-a compound of formula (B-8),

CHZZC

(B-8) -------- Order --------- (Please read the precautions on the back before filling this page) This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 1226897 A7 B7 V. Description of the invention (where the substituents E23 are unrelated and have one of the definitions of £ 1 and E24 is gas, Ci-Ci2 or Ci-Ci2 oxygen; β -9) — Compounds of formula (B-9) HX CH, Ε2—Ν Ν h3c CH3

-E 26 (B-9) where m2 is 1, 2 or 3, E25 has one of the definitions of E :, and when m2 is 1, E26 is a group of ch2ch2-nhh ^) when m2 is 2 E26 is a C2-C22 courtyard support, and when m2 is 3, E26 is a group base of formula (b-IV), ^ 28 E28 —E2—N ^ N ^ iE— NammaN (b-IV) Ν— ^-^ 28 wherein the substituents E27 are unrelated to each other, c2-c12 alkylene, and the substituents E28 are unrelated to each other are q-Cu alkyl or c5-c12 cycloalkyl; β-10) — formula ( B-10) Compounds, 11 -------------------- Order ---------- (Please read the notes on the back before filling this page ) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 1226897 A7 B7

5. Description of the invention (〇

E '29 wherein the substituents E29 are independent of one another as defined in Ei, and E30 is C2-C22 alkylene, C5-C7 cycloalkylene, CVC4 alkylene di (C5-C7 cycloalkylene), Phenylene or phenylene di (G-C4 alkylene); or β-ll) —a compound of formula (B-11), (B-11) wherein E31 is CrCw alkyl, C5-C12 cycloalkyl, CVC4 alkyl -Substituted C5-C12 cycloalkyl, phenyl or alkyl-substituted phenyl, E32 is C3-C1G alkylene, E33 has one of the definitions of E !, and m3 is a number from 2 to 6 . One of the preferred embodiments of the present invention relates to a stabilizer mixture, in which the two component (B) compounds are selected from different classes. Examples of ingredients (B) are: 12 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -------------------- Order- -------- (Please read the notes on the back before filling this page) 1226897 A7 B7 V. Description of the invention (β) • One compound selected from β-1 and one selected from β-3, β- Compounds of 4, β-5, β-6, β-7, β-8, β-9, β-10 or (MI), preferably selected from β_3, β_5, β-6, β-10 or β- A compound of 11. • a compound selected from β-3 and a compound selected from β-4, β-5, β · 6, β-7, β-9, β-10 or β-11, preferably , Compounds selected from β_5, β-6, β-10 or β-11. • One compound selected from β-5 and one selected from β-6, β-7, β-8, β-9, β- A compound of 10 or β-11, preferably a compound selected from β-6, β-10 or β-11. • A compound selected from β-6 and a compound selected from (Mo or 0-11). • One compound selected from β-7 and one compound selected from β_8, β-10 or β-ll. • One compound selected from β-9 and one compound selected from (M0 or (Mi). A compound selected from β-10 and a compound selected from β-11 Examples of alkyl groups with up to 25 carbon atoms are methyl, ethyl, propyl 'isopropyl' n-butyl '-*-butyl, isobutyl, tertiary butyl, 2 -Ethylbutyl, n-pentyl, isopentyl, 1-methylpentyl, 1,3-monomethylbutyl 'n-hexyl, 1-methylhexyl, n-heptyl, isoheptyl , 1,1,3,3-tetramethylhexyl, 1-methylheptyl, 3-methylheptyl 'n-octyl, 2-ethylhexyl, 1,1,3-dimethylhexyl' 1 '1,3,3-tetramethylpentyl, nonyl, decyl, Ί ^ -alkyl, 1-methyl ^ -alkyl, dodecyl, 1, 1 13 This paper is applicable to China National Standard (CNS) A4 Specification (210 X 297 mm) -------- ^ --------- (Please read the precautions on the back before filling this page) 1226897 A7 _B7__ V. Description of the invention (), 3, 3 9 5, 5-hexamethylhexyl, tridecyl, tetradecyl, pentadecyl, cetyl, heptadecyl, octadecyl, pinane And fluorenedialkyl. A8, Ei, Es, Ei2, E13, Ei8, E22, E23, E25, E29 and E33 are one of the preferred definitions of Ci-q alkane , Especially methyl. Examples of alkoxy groups having up to 18 carbon atoms are methoxy, ethoxy, propoxy, isopropoxy, butoxy, isobutoxy, pentoxy, Isopentyloxy'hexyloxy'heptyloxy'octyloxy'decyloxy'undecyloxy, tetradecyloxy, hexadecyloxy and octadecyloxy. One of the better definitions of Ei is octyloxy. E24 is preferably Ci-Ce compound. Examples of c5-c12 cycloalkyl are cyclopentyl, cyclohexyl, cycloheptyl, cyclooctyl and cyclododecyl. .C5-C8 cycloalkyl, especially cyclohexyl, is preferred. G-C4 alkyl-substituted-c5-c12 cycloalkyl is, for example, methylcyclohexyl or dimethylcyclohexyl. Examples of c5-c12 cycloalkoxy are cyclopentyloxy, cyclohexyloxy, cycloheptyloxy, cyclooctyloxy, cyclodecoxy and cyclododecyloxy. C5-C8 cycloalkoxy, especially cyclopentyloxy and cyclohexyloxy are preferred.

Ci_Cio is an alkyl-substituted phenyl group such as methylphenyl '-^ methylphenyl, trimethylphenyl, or tert-butylphenyl. Examples of c7-c9 phenylalkyl are benzyl and phenylethyl. Examples of C7-C9 phenyl radicals (which are substituted on the phenyl group with 1, 2 or 3 Ci-c4 alkyl groups) are methylbenzyl, dimethylbenzyl, trimethylbenzene Methyl, or tert-butylbenzyl. Examples of alkenyl groups with up to 10 carbon atoms are allyl, 2 -methyl 14 ——Order --------- (Please read the precautions on the back before filling this page) This paper applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1226897 a7 __B7___ 5. Description of the invention (9) Allyl, butenyl, pentenyl and hexenyl. Allyl is preferred. Preferably, the carbon atom at the first position is saturated. Examples of fluorenyl groups containing no more than 8 carbon atoms are methyl fluorenyl, ethyl fluorenyl, propyl fluorenyl, butyl fluorenyl, pentyl fluorenyl, hexyl fluorenyl, heptyl fluorenyl, octyl fluorenyl, acryl fluorenyl, methacryl fluorenyl and Benzamidine.

Cr-Csfluorenyl, C3-C8alkenyl and benzamidine are preferred. Ethyl and propenyl are particularly preferred. Examples of alkylenes with up to 22 carbon atoms are methyl, ethylene, propylene, trimethyl, tetramethyl, pentamethyl, 2,2-dimethyltrimethyl, hexamethyl, trimethylhexamethyl Support, eight support and ten support.

An example of a CH c3-c1Q alkylidene group is a group group of Formula One. An example of a ch3 C4-C1G alkyltetrayl is 1,2,3,4-butane tetrayl. An example of a C5-C7 cycloalkylene is cyclohexylene. An example of G-C4 alkylene bis (C5-C7 cycloalkylene) is methylene dicyclohexane. An example of phenylene bis (< ^ < 4 alkylene) is methylene-phenylene-methylene or ethylene-phenylene-ethylene. γµ, n2, n2 * and n4 are preferably a number from 2 to 25, especially 2 to 20. n3 is preferably a number from 1 to 25, especially 1 to 20. m3 is preferably a number from 2 to 6, especially 2 to 4. The compounds of the above components (A) and (B) are conventional and have been produced commercially. All these compounds can be prepared by conventional methods. 15 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -------------------- Order --------- (Please read the precautions on the back before filling this page) 1226897 A7 _____B7 V. Description of the invention (Λ) The preparation of the component (A) is disclosed in, for example, US-A_ 4,233,412, US-A-4,340,534, WO-A-98 / 51,690 and EP-A-1,803. The preparation of component (B) compounds is disclosed in, for example, US-A-5,679,733, US-A-3,640,928, US-A-4,198,334, US-A-5,204,473, US-A-4,619,958, US-A-4,110,306, US-A- 4,1 10,334, US-A-4,689,416, US-A-4,408,051, SU-A- 768,175 (Derwent 88-138,751 / 20), US-A -5,049,604, US- A-4,769,457, US-A-4,356,307, US-A_4,619,956, US-A- 5,182,390, GB-A-2,269,819, US-A-4,292,240, US-A- 5,026,849, US-A-5,071 , 981, US-A-4,547,538, US-A-4,976,889 and US-A-5,051,458. Ingredient (A) is preferably TINUVIN 622 (RTM), HOSTAVIN N30 (RTM) or FERROAM 806 (RTM). The compound of component (B) is preferably selected from DASTIB 845 (RTM), TINUVIN 770 (RTM), TINUVIN 765 (RTM), TINUVIN 144 (RTM), TINUVIN 123 (RTM), ADK STAB LA 52 (RTM), ADK STAB LA 57 (RTM), ADK STAB LA 62 (RTM), ADK STAB LA 67 (RTM), HOSTAVIN N 20 (RTM), HOSTAVIN N 24 (RTM), SANDUVOR 3050 (RTM), DIACETAM 5 (RTM), SUMISORB TM 61 (RTM), UVINUL 4049 (RTM), SANDUVOR PR 31 (RTM), GOODRITE UV 3034 (RTM), GOODRITE UV 3150 (RTM), GOODRITE UV 3159 (RTM), GOODRITE 3110 x 128 (RTM), UVINUL 4050 H (RTM), 16 paper sizes are applicable to China National Standard (CNS) A4 (210 X 297 mm) -------------------- Order --- ------ ^^ 1 (Please read the notes on the back before filling this page) 1226897 A7 B7

h3c ch3 HO

5. Description of the invention (i) UVASIL 299 LM (RTM) and UVASIL 2000 LM (RTM). Saturated compounds (A-1), (A-2-a), (A-2-b), (A-4) and (B_11) compounds The definition of the free valent terminal group depends on the preparation method used. This terminal group can also be modified after the compound is prepared. Suppose that the compound of formula (A-1) is prepared from, for example, a compound of the formula N-CH-CH-OH H, C CH, Al where A! Is hydrogen or methyl and reacted with a dicarboxylic acid diester of the following formula Y-OOC-A ^ COO-Y, where Y is, for example, methyl, ethyl or propyl, and A: is as defined above, bonded to 2,2,6,6_tetramethyl ice The terminal group of the oxypyridin-1-yl group is hydrogen or -CO-A2-COO-Y, and the terminal group bonded to the difluorenyl group is -0-Y or

CH—CH —OH A1 In the compound of formula (A-2-a), the terminal group bonded to a nitrogen atom can be, for example, hydrogen, and the terminal group bonded to a 2-hydroxypropenyl group can be, for example, the following formula Qunji, 17 paper sizes are applicable to China National Standard (CNS) A4 specifications (210 x 297 public love -------- ^ --------- (Please read the precautions on the back first) (Fill in this page again) 1226897 A7 _B7 V. Description of Invention (6)

In the compound of the formula (A-2-b), the energy of the terminal group bonded to the dimethylene group is, for example, -0H, and the energy of the terminal group bonded to the oxygen atom is, for example, the hydrogen. This terminal group can also be a polyether group. In the compound of the formula (A-4), the terminal energy of the bond to -CH2- is, for example, hydrogen, and the terminal energy of the bond to -CH (C02A7) is, for example, -CH = CH-COOA7. In the compound of the formula (B-11), the terminal energy for bonding to a silicon atom is, for example, (E31) 3Si-0-, and the terminal energy for bonding to an oxygen atom is, for example, -Si (E3i) 3. Provided that m3 is a number from 3 to 6, the compound of formula (B-11) can also be a cyclic compound, that is, the free valence shown in the structural formula can form a direct bond. A8 is preferably hydrogen, Q-C4 alkyl, CVC ^ alkoxy, cyclohexyloxy, allyl, benzyl or ethenyl. .

Ei, Es, E! 2, Ei3, E16, Ei8, E22, E23, E25, E29 and E33. Preferred are hydrogen, G-C4 alkyl, alkoxy, cyclohexyloxy, allyl, benzyl. Or ethyl. 18 -------------------- Order -------- (Please read the notes on the back before filling this page) This paper size is applicable to China Standard (CNS) A4 specification (210x297 mm) 1226897 A7 B7 V. Description of the invention (A85 Eb E8, E12, E13, E16, E18, E22, E235 E25, E29 and E33 can be hydrogen or methyl, and E1 in addition Is q-Cs alkoxy. According to a preferred embodiment,

Ai is hydrogen or methyl, eight 2 is a ^ direct bond or C2-C6 academy, and ni is a number from 2 to 25; η2 and η2 * are a number from 2 to 25; Α3 and A4 are mutually exclusive The relevant ones are hydrogen or Ci-C4 alkyl, or A3 and A4 together form a C9-C13 alkylene group, and the variables n3 are independent of the numbers of 1 to 2 5; n4 is a 2 to 2 5 , A5 and A6 are unrelated to each other Q-C4 alkyl, and A7 is C1-C4 or a (aI) group group, but the limit is at least 50% of A7 is a (aI) group group . According to another preferred embodiment, mi is 1, 2 or 4, if mi is 1, E2 is a C12-C2Q alkyl group, if nii is 2, E2 is a C2-C1 () compound or a (bI) group group E3 is CVC4, E4 is C, C6 alkylene, and E5 and E6 are unrelated to Ci-Ce, respectively, and if mi is 4, E2 is (: 4_0: 8 alkyl tetrayl; two E7 is < 00- (01 ()-(: 15 alkyl), and two E7 are group bases of formula (b-II); 19 This paper size applies to China National Standard (CNS) A4 (210 X 297) (Li) -------------------- Order --------- (Please read the notes on the back before filling this page) 1226897 A7 _'_ B7_ V. Description of the invention (i)) E9 and E1G together form c9-c13 alkylene,

En is hydrogen or a -Zi-COO-Z group group, A is C2-C6 alkylene, and Z2 is C1 (rC16 alkyl; E 1 4 is hydrogen, and E15 is C2-C6 alkylene or C3-C5 Alkylidene

El7 is Ci0-Ci4 courtyard; E24 is CVC4 alkoxy; m2 is 1, 2 or 3; when m2 is 1, E26 is a ch2ch2-nh ~ {二) group group, although m2 is 2, E26 is a C2-C6 compound, and when it is 3, E26 is a group of formula (b-IV), E27 is unrelated to C2-C6 alkylene, and E28 is unrelated to alkyl or C5, respectively. -C8 cycloalkyl; E30 is C2-C8 alkylene; and E31 is C1-C4 alkyl, E32 is c3-c6 alkylene, and m3 is a number from 2 to 6. A particularly preferred embodiment of the present invention relates to a stabilizer mixture, wherein component (A) is of the formula (A-1-a), (A-2-a), (A-2-b), (A-3- a) or (A-4-a) compounds; 20 -------------------- Order --------- ^ 9. (Please read first Note on the back, please fill out this page again) This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 1226897 A7B7 V. Description of the invention (

N-CH0CH ^ —00C——CH0CH; ~ C0- where m is a number from 2 to 20; (A-l-a) n1

(A-2-a)

〇- (A-2-b) η * 2 where η2 and ϋ2 * are a number from 2 to 20; CH2 — (CH2) 9 h3c ch:

——N

H3 ^ CH3 〇 -CH,

N-CK-CH —CH; I OH ------------------- Order --------- (Please read the precautions on the back before filling in this Page) H3C CH;

H3C CH3 0 n3 ch2—jch2) 9 —ch2 〇 H.C 〇H, N —CH2-CH —CH2—N OH CH2-

H3C ch3

〇H 0 h3c; ch CH2-CH—CH2 —N

h3c (ch2) 9- ch2 CH, (CH2) 9- CH2 (A-3-a) where the variables n3 are independent of each other and are a number from 1 to 20; 21 This paper scale applies Chinese National Standard ) A4 specification (210 X 297 mm) n3 1226897 A7 B7 V. Description of the invention (CH, CH5—C—CH? 2 I 2 c = o I 〇I CH, -CH- 0 where n4 is one from 2 to 2 A number of 0, and at least 50% of A7 is a group basis of formula (aI), h3c ch3

n-a8 h3c ch3 (aI) (A bucket a) where A8 is hydrogen, CVCs alkyl, O ·, -OH, -CH2CN, Ci-Cu alkoxy, C5-C12 Yunyuan gas-based, C3-C6 A C7-C9 phenyl group, which is unsubstituted or substituted with a 1,2 or 3 G-C4 alkyl group on a phenyl group; or Ci_Cs group, and A7 is defined as an ethyl group; and ingredients (B) is formed from two different compounds: (B-1-a), (B-1-b), (B-1-c), (B_l_d), (B-2_a), ( B-3-a), (B-3-b), (B-4-a), (B-4-b), (B-5), (B-6-a), (B-7) , (B-8-a), (B-9-a), (B-9-b), (B-9-c), (B-10_a) and (B-ll-a); h3c, 〇 II -〇—C— (C15-C17alkyl) -------------------- Order -------- .SI (Please read the precautions on the back first (Fill in this page again) h3c

ChU 22 This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) 1226897 A7 B7 V. Description of the invention (π)

Η C2——C——ο ο ο Η 一 | C——C——ο CH · CH · -d 1Χ (Β- ο II C, ό. Ο ο ο

-C.C Ν——Ε Ν——Ε

, CH3H3C

ΝΙΕ

Where El is hydrogen, CrCs alkyl, 0 ·, -OH, -CH2CN, CVCm alkoxy, C5-C12 cycloalkoxy, C3-C6 alkenyl, C7-C9 phenylalkyl, which are unsubstituted Or substituted by 1, 2 or 3 alkyl on phenyl; or Ci-Cs acid; H2C-CH ——CH-CH, III | E7 e7 e7 E7 (B-2-a) ---- ---------------- Order -------- .si (Please read the notes on the back before filling this page) Among them, two E7 are -COO-Ci3H27 And two e7 are

n — e8 and E8 have the definition as Ei. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1226897 A7 B7. 5. Description of the invention (> \ one of; \ CH0

(CHjJg -N (B-3-a)

〇, CH0, CH2CH2—C-0— (C12-C14alkyl) (CH2) 9 (B-3-b)

ch2 o… c = o H3C

CH, h3c n ch Ε 12 where ε12 has one of the definitions of Ε !; h3c ch3 Η 0 Η Η 3 ° ν II I / _ < CH3 e-0 —N- 丨 丨 i / —CH2CH2 —C — N -(ΤΓΕΐ3 Η〆ch3 h3c ch3 ΗΧ \ Λ Η I CH3 0 H H3C \ I 3 II I / —V CH, / ε13-ν, > I --N · I 11 I /, --C——C—— N — 、, N — E13 h3c Γ ch3 ch3 r h3c \ ch3 where Eπ has one of the definitions of Ei; (B-4-a) (B-4-b) -------- order- -------- ^^ 1 (Please read the notes on the back before filling this page)

16 (B-5) 24 This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 1226897 A7 B7 V. Description of the invention

Where E16 has HocC as one of the definitions of Ei

18 (B-6-a) where E18 has one of the definitions of Ei 〇Λ. (B-7) • 19. II > Γ 'N,

y '〇 has 2〇 Among them, E19, E2G and E21 are unrelated to each other, which is a group group of formula (b-III) 2 in 2

(b-III) wherein E22 has one of the meanings; h3co

CHZZC

(B-8-a) -------------------- Order --------- ^^ 1 (Please read the notes on the back before filling (This page) Among them, E23 has one of the meanings of EiS; 25 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 1226897 A7 B7

V. Description of the invention (Qin H3C CH

E2l-N N——CH2CH2——NH

(B-9-a) h3c ch3 h3c ch3. E21— N _—CH2CH2—N ′ / N——E25 〇, H3CWCH3

Y (B-9-b) H3C CH, h3c CH, h3c ch3 H3C pH3 〇

(B-9-c) wherein E25 has one of the meanings of EiS; 〇 ο

-29 E29 has one of the definitions of Ei 26 This paper size is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) ------------------ --Order --------- (Please read the notes on the back before filling out this page) 1226897 A7 B7 V. Description of the invention (>) -Si——0- CH, (B-ll-a ) (CH2): 〇 H3e 乂 H3C N ch where m3 is a number from 2 to 6 and E33 has one of the definitions of Ei. A particularly preferred embodiment of the present invention relates to a stabilizer mixture, wherein one of the two different compounds forming the component (B) is a compound of the formula (B-1-b), wherein Ei is hydrogen. Another preferred embodiment of the present invention relates to a stabilizer mixture, wherein component (A) is a compound of formula (A-1-a), wherein η is a number from 2 to 20, or formula (A_2_a) or ( A_2_b) compounds, where n2 and n2 * are a number from 2 to 20; and one of the two different compounds forming the component (B) is a compound of formula (B-1-b), where Ei is hydrogen. A particularly preferred embodiment of the present invention relates to a stabilizer mixture, wherein component (A) is a compound of formula (A-1-a), where ni is a number from 2 to 20, or a formula (A_2_a) or (A_2_b ) Compounds, where n2 and n2 * are a number from 2 to 20; one of the two different compounds forming component (B) is a compound of formula (B-1-b), where Ei is hydrogen; and 27 paper sizes apply China National Standard (CNS) A4 Specification (210 X 297 mm) -------------------- Order --------- (Please read the back first Please note this page and fill in this page again) A7 1226897 ______B7 _ V. Description of the invention (X) Forming component (B) The other of two different compounds is a compound of formula (B-1-a), where E! Is hydrogen; (B -1-b), wherein E! Is methyl; (B-1-d), wherein Ei is nitrogen or methyl; (B-3-a) 5 wherein Ei2 is nitrogen; (B-3-b), Where E12 is hydrogen; (B-4-b), where E13 is hydrogen; (B-5) 'where E16 is hydrogen; (B-6-a)' where E18 is hydrogen or methyl; (B-8_a) , Where E23 is methyl; (B_9_c), where E25 is hydrogen or methyl; (B-10-a), where E29 is being hydrogen; or (B-11-a), which E33 is hydrogen. An example of a stabilizer mixture according to the present invention is a combination of the following commercial products:

1. TINUVIN 622 (RTM) + TINUVIN 770 (RTM) + TINUVIN 765 (RTM)

2. TINUVIN 622 (RTM) + TINUVIN 770 (RTM) + TINUVIN 144 (RTM)

3. TINUVIN 622 (RTM) + TINUVIN 770 (RTM) + TINUVIN 123 (RTM) 4. TINUVIN 622 (RTM) + TINUVIN 770 (RTM) + — compound of formula (B-3-a), where E12 is hydrogen 5. TINUVIN 622 (RTM) + TINUVIN 770 (RTM) + HOSTAVIN N 24 (RTM) 6. TINUVIN 622 (RTM) + TINUVIN 770 (RTM) + DIACETAM 5 (RTM)

7. TINUVIN 622 (RTM) + TINUVIN 770 (RTM) + ADK STAB LA 52 (RTM) 28 This paper size applies to China National Standard (CNS) A4 (210 x 297 mm) --------- --------- —Order --------- (Please read the notes on the back before filling this page) A7 1226897 B7 V. Description of the invention (less)

8. TINUVIN 622 (RTM) + TINUVIN 770 (RTM) + ADK STAB LA 57 (RTM)

9. TINUVIN 622 (RTM) + TINUVIN 770 (RTM) + ADK STAB LA 62 (RTM) 10. TINUVIN 622 (RTM) + TINUVIN 770 (RTM) + ADK STAB LA 67 (RTM) 11. TINUVIN 622 (RTM) + TINUVIN 770 (RTM) + GOODRITE UV 3034 (RTM) 12.TINUVIN 622 (RTM) + TINUVIN 770 (RTM) + GOODRITE UV 3150 (RTM) 13.TINUVIN 622 (RTM) + TINUVIN 770 (RTM) + GOODRITE UV 3159 ( RTM) 14. TINUVIN 622 (RTM) + TINUVIN 770 (RTM) +-compound of formula (B-9-a), where E25 is hydrogen

15. TINUVIN 622 (RTM) + TINUVIN 770 (RTM) + UVINUL 4049 (RTM) 16. TINUVIN 622 (RTM) + TINUVIN 770 (RTM) + compound of formula (B-10-a), where E29 is hydrogen 622 (RTM) + TINUVIN 770 (RTM) + compound of formula (Bla), where E! Is hydrogen 18.TINUVIN 622 (RTM) + TINUVIN 770 (RTM) + SUMISORB TM 61 (RTM) 19.TINUVIN 622 (RTM) + TINUVIN 770 (RTM) + SANDUVOR 3050 (RTM) 29 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ------------------- -Order --------- (Please read the precautions on the back before filling this page) 1226897 A7 B7 V. Description of the invention (20. TINUVIN 622 (RTM) + TINUVIN 770 (RTM) + SANDUVOR PR-31 (RTM)

21. TINUVIN 622 (RTM) + TINUVIN 770 (RTM) + UVASIL 299 LM (RTM)

22. TINUVIN 622 (RTM) + TINUVIN 770 (RTM) + UVASIL 2000 LM (RTM) 23. TINUVIN 622 (RTM) + TINUVIN 770 (RTM) + compound of formula (B-6-a), where E18 is hydrogen 24 TINUVIN 622 (RTM) + TINUVIN 770 (RTM) + compound of formula (B-6-a), where E18 is methyl 25. TINUVIN 622 (RTM) + TINUVIN 770 (RTM) + compound of formula (B_7), where E19 , E2q and E21 are a group of formula (b-III), where E22 is hydrogen

26. TINUVIN 622 (RTM) + TINUVIN 765 (RTM) + TINUVIN 144 (RTM)

27. TINUVIN 622 (RTM) + TINUVIN 765 (RTM) + TINUVIN 123 (RTM) 28. TINUVIN 622 (RTM) + TINUVIN 765 (RTM) + compounds of formula (B_3-a), where e12 is hydrogen 29.TINUVIN 622 ( (RTM) + TINUVIN 765 (RTM) HOSTAVIN N 24 (RTM) 30.TINUVIN 622 (RTM) + TINUVIN 765 (RTM) DIACETAM 5 (RTM)

31.TINUVIN 622 (RTM) + TINUVIN 765 (RTM) + ADK 30 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) --------------- ----- Order --------- (Please read the notes on the back before filling out this page) 1226897 A7 B7 V. Description of the invention (4) STAB LA 52 (RTM)

32. TINUVIN 622 (RTM) + TINUVIN 765 (RTM) + ADK STAB LA 57 (RTM)

33. TINUVIN 622 (RTM) + TINUVIN 765 (RTM) + ADK STAB LA 62 (RTM)

34. TINUVIN 622 (RTM) + TINUVIN 765 (RTM) + ADK STAB LA 67 (RTM) 3 5.TINUVIN 622 (RTM) + TINUVIN 765 (RTM) + GOODRITE UV 3034 (RTM) 36. TINUVIN 622 (RTM) + TINUVIN 765 (RTM) + GOODRITE UV 3150 (RTM) 37. TINUVIN 622 (RTM) + TINUVIN 765 (RTM) + GOODRITE UV 3159 (RTM) 38. TINUVIN 622 (RTM) + TINUVIN 765 (RTM) + formula (B_9- a) Compound where E25 is hydrogen

39. TINUVIN 622 (RTM) + TINUVIN 765 (RTM) + UVINUL 4049 (RTM) 40. TINUVIN 622 (RTM) + TINUVIN 765 (RTM) + compounds of the formula (B-10-a), where E29 is hydrogen 41. TINUVIN 622 (RTM) + TINUVIN 765 (RTM) + compounds of the formula (Bla) where E! Is hydrogen 42. TINUVIN 622 (RTM) + TINUVIN 765 (RTM) + SUMISORB TM 61 (RTM) 43. TINUVIN 622 (RTM) + TINUVIN 765 (RTM) + 31 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -------------------- Order --- ------ (Please read the precautions on the back before filling this page) 1226897 A7

• ~~ _BI V. Description of the Invention (d) SANDUVOR 3050 (RTM) 44. TINUVIN 622 (RTM) + TINUVIN 765 (RTM) + SANDUVOR PR-31 (RTM)

45. TINUVIN 622 (RTM) + TINUVIN 765 (RTM) + UVASIL 299 LM (RTM)

46. TINUVIN 622 (RTM) + TINUVIN 765 (RTM) + UVASIL 2000 LM (RTM) 47. TINUVIN 622 (RTM) + TINUVIN 765 (RTM) + compounds of the formula (B-6-a), where E18 is hydrogen 48. TINUVIN 622 (RTM) + TINUVIN 765 (RTM) + compound of formula (B-6-a), where E18 is methyl 49. TINUVIN 622 (RTM) + TINUVIN 765 (RTM) + compound of formula (B-7), where E19, E2〇 and E21 are a group of formula (b-III), where E22 is hydrogen.

50. TINUVIN 622 (RTM) + TINUVIN 144 (RTM) + TINUVIN 123 (RTM) 51. TINUVIN 622 (RTM) + TINUVIN 144 (RTM) + compound of formula (B-3-a), where E12 is 氲 52.TINUVIN 622 (RTM) + TINUVIN 144 (RTM) + HOSTAVIN N 24 (RTM) 53.TINUVIN 622 (RTM) + TINUVIN 144 (RTM) + DIACETAM 5 (RTM) 54.TINUVIN 622 (RTM) + TINUVIN 144 (RTM) + ADK STAB LA 52 (RTM) 32 This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) -------------------- Order- ------- (Please read the notes on the back before filling this page) 1226897 A7 B7 V. Description of the invention (

55. TINUVIN 622 (RTM) + TINUVIN 144 (RTM) + ADK STAB LA 57 (RTM)

56. TINUVIN 622 (RTM) + TINUVIN 144 (RTM) + ADK STAB LA 62 (RTM)

57. TINUVIN 622 (RTM) + TINUVIN 144 (RTM) + ADK STAB LA 67 (RTM) 58. TINUVIN 622 (RTM) + TINUVIN 144 (RTM) + GOODRITE UV 3034 (RTM) 59. TINUVIN 622 (RTM) + TINUVIN 144 (RTM) + GOODRITE UV 3150 (RTM) 60. TINUVIN 622 (RTM) + TINUVIN 144 (RTM) + GOODRITE UV 3159 (RTM) 61 .TINUVIN 622 (RTM) + TINUVIN 144 (RTM) +-Formula (B- 9-a) compound in which E25 is hydrogen

62. TINUVIN 622 (RTM) + TINUVIN 144 (RTM) + UVINUL 4049 (RTM) 63. TINUVIN 622 (RTM) + TINUVIN 144 (RTM) + — compound of formula (B-10-a), where E29 is hydrogen 64 · ΉΝυνΐΝ 622 (RTM) + TINUVIN 144 (RTM) +-compound of formula (Bla), where Ei is hydrogen 65. TINUVIN 622 (RTM) + TINUVIN 144 (RTM) + SUMISORB TM 61 (RTM) 66. TINUVIN 622 (RTM) + TINUVIN 144 (RTM) + SANDUVOR 3050 (RTM) 33 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -------- Order --------- (Please read the notes on the back before filling this page) A7 (B-3-a) compounds, where E12 is hydrogen 74.TINUVIN 622 (RTM) + TINUVIN 123 (RTM) + HOSTAVIN N 24 (RTM) 75.TINUVIN 622 (RTM) + TINUVIN 123 (RTM) + DIACETAM 5 (RTM) 76.TINUVIN 622 (RTM) + TINUVIN 123 (RTM) + ADK STAB LA 52 (RTM) 77.TINUVIN 622 (RTM) + TINUVIN 123 (RTM) + ADK STAB LA 57 (RTM) 78.TINUVIN 622 (RTM) + TINUVIN 123 (RTM) + ADK 34 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 1226897 ____B7 V. Description of the invention ( W) 67. TINUVIN 622 (RTM) + TINUVIN 144 (RTM) + SANDUVOR PR-31 (RTM)

68. TINUVIN 622 (RTM) + TINUVIN 144 (RTM) + UVASIL 299 LM (RTM)

69. TINUVIN 622 (RTM) + TINUVIN 144 (RTM) + UVASIL 2000 LM (RTM) 70. T1NUVIN 622 (RTM) + TINUVIN 144 (RTM) + — compound of formula (B-6-a), where E18 is hydrogen 71 TINUVIN 622 (RTM) + TINUVIN 144 (RTM) +-compound of formula (B-6-a), where E18 is methyl 72. TINUVIN 622 (RTM) + TINUVIN 144 (RTM) +-formula (B-7) Compounds in which E19, E2Q and E21 are groups of formula (b-III), and E22 is hydrogen. 73. TINUVIN 622 (RTM) + TINUVIN 123 (RTM) + formula ------------ -------- Order --------- (Please read the notes on the back before filling out this page) 1226897 A7 B7 V. Description of the invention (β) STAB LA 62 (RTM)

79. TINUVIN 622 (RTM) + TINUVIN 123 (RTM) + ADK STAB LA 67 (RTM) (Please read the notes on the back before filling this page) 80. TINUVIN 622 (RTM) + TINUVIN 123 (RTM) + GOODRITE UV 3034 (RTM) 8LTINUVIN 622 (RTM) + TINUVIN 123 (RTM) + GOODRITE UV 3150 (RTM) 82. TINUVIN 622 (RTM) + TINUVIN 123 (RTM) + GOODRITE UV 3159 (RTM) 83. TINUVIN 622 (RTM) + TINUVIN 123 (RTM) +-compound of formula (B-9-a), where E25 is hydrogen

84. TINUVIN 622 (RTM) + TINUVIN 123 (RTM) + UVINUL 4049 (RTM) 85. TINUVIN 622 (RTM) + TINUVIN 123 (RTM) + compounds of the formula (B-10-a), where E29 is hydrogen 86. TINUVIN 622 (RTM) + TINUVIN 123 (RTM) + compounds of formula (Bla), where E: is hydrogen 87. TINUVIN 622 (RTM) + TINUVIN 123 (RTM) + SUMISORB TM 61 (RTM) 88. TINUVIN 622 (RTM) + TINUVIN 123 (RTM) + SANDUVOR 3050 (RTM) 89. TINUVIN 622 (RTM) + TINUVIN 123 (RTM) + SANDUVOR PR-31 (RTM)

90. TINUVIN 622 (RTM) + TINUVIN 123 (RTM) + UVASIL 35 This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) A7 1226897 B7__ 5. Description of the invention (work) 299 LM (RTM) 9LTINUVIN 622 (RTM) + TINUVIN 123 (RTM) + UVASIL 2000 LM (RTM) 92. TINUVIN 622 (RTM) + TINUVIN 123 (RTM) + — compound of formula (B-6-a), where E18 is hydrogen 93. TINUVIN 622 (RTM) + TINUVIN 123 (RTM) + compound of formula (B-6_a), where E18 is methyl 94. TINUVIN 622 (RTM) + TINUVIN 123 (RTM) + — compound of formula (B-7), where E19, E20 and E2i are a group of formula (b-III), where E22 is hydrogen. 95 · ΉΝυνΐΝ 622 (RTM) +-compound of formula (B-3-a), where E12 is hydrogen + HOSTAVIN N 24 (RTM) 96 TINUVIN 622 (RTM) +-compound of formula (B-3-a), where E12 is hydrogen + DIACETAM 5 (RTM) 97. TINUVIN 622 (RTM) +-compound of formula (B-3-a), where E12 is Hydrogen + ADK STAB LA 52 (RTM) 98. TINUVIN 622 (RTM) +-compound of formula (B-3-a), where E12 is hydrogen + ADK STAB LA 57 (RTM) 99 · ΉΝυνΐΝ 622 (RTM) +-formula (B-3-a) compound in which E12 Hydrogen + ADK STAB LA 62 (RTM) 100. TINUVIN 622 (RTM) +-compound of formula (B-3-a), where E12 is hydrogen + ADK STAB LA 67 (RTM) 101. TINUVIN 622 (RTM) +-formula (B-3-a) compound, where E12 is hydrogen + GOODRITE UV 3034 (RTM) 36 This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) ---------- ---------- Order ------- (Please read the notes on the back before filling this page) A7 B7 1226897 V. Description of the invention (4) 102. TINUVIN 622 (RTM) + — Compound of formula (B-3-a), where E12 is hydrogen + GOODRITE UV 3150 (RTM) 103. TINUVIN 622 (RTM) +-compound of formula (B-3-a), where E12 is hydrogen + GOODRITE UV 3159 (RTM ) 104. TINUVIN 622 (RTM) +-compound of formula (B-3-a), where E12 is hydrogen +-compound of formula (B-9-a), where E25 is hydrogen 105. TINUVIN 622 (RTM) +-formula (B_3-a) compounds, where E12 is hydrogen + UVINUL 4049 (RTM) 106. TINUVIN 622 (RTM) +-compounds of formula (B-3-a), where Ei2 is hydrogen +-* formula (B-10-a ) Compound where E29 is hydrogen 107. TINUVIN 622 (RTM) + Compound of formula (B-3-a) where E12 is hydrogen + — (B-1-a) compounds where E! Is hydrogen 108. TINUVIN 622 (RTM) +-compounds of formula (B-3-a) where E12 is hydrogen + SUMISORB TM 61 (RTM) 109. T1NUVIN 622 (RTM ) + — Compound of formula (B_3-a), where E12 is hydrogen + SANDUVOR 3050 (RTM) 110. TINUVIN 622 (RTM) + — compound of formula (B-3-a), where E12 is hydrogen + SANDUVORPR_31 (RTM) 111 HNUVIN 622 (RTM) + — compound of formula (B-3_a), where E12 is hydrogen + UVASIL 299 LM (RTM) 112. TINUVIN 622 (RTM) + — compound of formula (B_3-a), where E12 is hydrogen + UVASIL 2000 LM (RTM) 113. TINUVIN 622 (RTM) +-compound of formula (B-3-a), of which E12 37 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ---- ---------------- Order --------- (Please read the notes on the back before filling out this page) A7 1226897 ___ B7___ V. Description of the invention (β) Is hydrogen +-compound of formula (B-6_a), where E18 is hydrogen 114. TINUVIN 622 (RTM) +-compound of formula (B-3-a), where E12 is hydrogen +-compound of formula (B-6-a) Where E18 is methyl 115. T1NUVIN 622 (RTM) +-a compound of formula (B-3_a) where E12 Hydrogen +-compound of formula (B-7), where E19, E2G and E21 are a group of formula (b-III), where E22 is hydrogen. 116. TINUVIN 622 (RTM) + HOSTAVIN N 24 (RTM) + DIACETAM 5 ( RTM) 117. TINUVIN 622 (RTM) + HOSTAVIN N 24 (RTM) + ADK STAB LA 52 (RTM) 118. TINUVIN 622 (RTM) + HOSTAVIN N 24 (RTM) + ADK STAB LA 57 (RTM) 119. TINUVIN 622 (RTM) + HOSTAVIN N 24 (RTM) + ADK STAB LA 62 (RTM) 120. TINUVIN 622 (RTM) + HOSTAVIN N 24 (RTM) + ADK STAB LA 67 (RTM) 121 .TINUVIN 622 (RTM) + HOSTAVIN N 24 (RTM) + GOODRITE UV 3034 (RTM) 122. TINUVIN 622 (RTM) + HOSTAVIN N 24 (RTM) + GOODRITE UV 3150 (RTM) 123. TINUVIN 622 (RTM) + HOSTAVIN N 24 (RTM) + GOODRITE UV 3159 (RTM) 124. TINUVIN 622 (RTM) + HOSTAVIN N 24 (RTM) + —Form 38 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ---------- --------- Order --------- (Please read the notes on the back before filling out this page) 1226897 A7 B7 V. Description of the invention ((B-9-a) compounds, of which Ε25 is hydrogen 125. TINUVIN 622 (RTM) + HOSTAVIN Ν 24 (RTM) + UVINUL 4049 (RTM) 126 TINUVIN 622 (RTM) + HOSTAVIN Ν 24 (RTM) +-compound of formula (B-10-a), where E29 is hydrogen 127. TINUVIN 622 (RTM) + HOSTAVIN N 24 (RTM) + formula (B-1- a) Fossil, where E! is hydrogen 128. TINUVIN 622 (RTM) + HOSTAVIN N 24 (RTM) + SUMISORB TM 61 (RTM) 129. TINUVIN 622 (RTM) + HOSTAVIN N 24 (RTM) + SANDUVOR 3050 (RTM ) 130. TINUVIN 622 (RTM) + HOSTAVIN N 24 (RTM) + SANDUVOR PR-31 (RTM) 131. TINUVIN 622 (RTM) + HOSTAVIN N 24 (RTM) + UVASIL 299 LM (RTM) 132. TINUVIN 622 (RTM ) + HOSTAVIN N 24 (RTM) + UVASIL 2000 LM (RTM) 133 · Ί1ΝυνΐΝ 622 (RTM) + HOSTAVIN N 24 (RTM) +-compound of formula (B-6-a), where E18 is hydrogen 134.TINUVIN 622 ( RTM) + HOSTAVIN Ν 24 (RTM) + compound of formula (B-6-a), where E18 is methyl 135 · ΉΝυνΐΝ 622 (RTM) + HOSTAVIN N 24 (RTM) +-compound of formula (B-7), where E19, E2〇, and E21 are group groups of formula (b-III), of which e22 is hydrogen. 39 This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) --------- ---------- Order --------- (Please read the notes on the back before filling (This page) 1226897 A7 _____B7_ V. Description of the invention (〇) 136. TINUVIN 622 (RTM) + DIACETAM 5 (RTM) + ADK STAB LA 52 (RTM) 137. TINUVIN 622 (RTM) + DIACETAM 5 (RTM) + ADK STAB LA 57 (RTM) 138. TINUVIN 622 (RTM) + DIACETAM 5 (RTM) + ADK STAB LA 62 (RTM) 139. TINUVIN 622 (RTM) + DIACETAM 5 (RTM) + ADK STAB LA 67 (RTM) 140. TINUVIN 622 (RTM) + DIACETAM 5 (RTM) + GOODRITE UV 3034 (RTM) 141. TINUVIN 622 (RTM) + DIACETAM 5 (RTM) + GOODRITE UV 3150 (RTM) 142. TINUVIN 622 (RTM) + DIACETAM 5 (RTM) + GOODRITE UV 3159 (RTM) 143. T1NUVIN 622 (RTM) + DIACETAM 5 (RTM) +-compound of formula (B_9_a), where E25 is hydrogen 144. TINUVIN 622 (RTM) + DIACETAM 5 (RTM) + UVINUL 4049 (RTM ) 145.1TINUVIN 622 (RTM) + DIACETAM 5 (RTM) +-compound of formula (B-10-a), where E29 is hydrogen 146. TINUVIN 622 (RTM) + DIACETAM 5 (RTM) + compound of formula (Bla), where E! Is hydrogen 147. TINUVIN 622 (RTM) + DIACETAM 5 (RTM) + SUMISORB TM 61 (RTM) This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) ------- ------------- --------- (Please read the notes on the back before filling this page) 1226897 A7 B7 V. Description of Invention (β) 148. TINUVIN 622 (RTM) + DIACETAM 5 (RTM) + SANDUVOR 3050 (RTM ) 149. TINUVIN 622 (RTM) + DIACETAM 5 (RTM) + SANDUVOR PR-31 (RTM) 150. TINUVIN 622 (RTM) + DIACETAM 5 (RTM) + UVASIL 299 LM (RTM) 151. TINUVIN 622 (RTM) + DIACETAM 5 (RTM) + UVASIL 2000 LM (RTM) 152. T1NUVIN 622 (RTM) + DIACETAM 5 (RTM) +-compound of formula (B-6_a), where E18 is hydrogen 153. TINUVIN 622 (RTM) + DIACETAM 5 ( RTM) + compound of formula (B-6-a), where E18 is methyl 154. TINUVIN 622 (RTM) + DIACETAM 5 (RTM) +-compound of formula (B-7), where E19, E2O and E21 are formulae (B-III) group base, where E22 is hydrogen. 155. TINUVIN 622 (RTM) + ADK STAB LA 52 (RTM) + ADK STAB LA 57 (RTM) 156. TINUVIN 622 (RTM) + ADK STAB LA 52 (RTM ) + ADK STAB LA 62 (RTM) 157. TINUVIN 622 (RTM) + ADK STAB LA 52 (RTM) + ADK STAB LA 67 (RTM) 158. TINUVIN 622 (RTM) + ADK STAB LA 52 (RTM) + GOODRITE UV 3034 (RTM) 159. TINUVIN 622 (RTM) + ADK STAB LA 52 (RTM) + copy Paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -------------------- Order --------- (Please Please read the notes on the back before filling this page) 1226897 A7 B7 V. Description of the invention (4) GOODRITE UV 3150 (RTM) 160. TINUVIN 622 (RTM) + ADK STAB LA 52 (RTM) + GOODRITE UV 3159 (RTM) 161 TINUVIN 622 (RTM) + ADK STAB LA 52 (RTM) + — Compound of formula (B_9_a), where E25 is hydrogen 162. TINUVIN 622 (RTM) + ADK STAB LA 52 (RTM) + UVINUL 4049 (RTM) 163. TINUVIN 622 (RTM) + ADK STAB LA 52 (RTM) + — compound of formula (B-10-a), where E29 is hydrogen 164. TINUVIN 622 (RTM) + ADK STAB LA 52 (RTM) + compound of formula (Bla), Where E! Is hydrogen 165. TINUVIN 622 (RTM) + ADK STAB LA 52 (RTM) + SUMISORB TM 61 (RTM) 166. TINUVIN 622 (RTM) + ADK STAB LA 52 (RTM) + SANDUVOR 3050 (RTM) 167. TINUVIN 622 (RTM) + ADK STAB LA 52 (RTM) + SANDUVOR PR-31 (RTM) 168. TINUVIN 622 (RTM) + ADK STAB LA 52 (RTM) + UVASIL 299 LM (RTM) 169. TINUVIN 622 (RTM) + ADK STAB LA 52 (RTM) + UVASIL 2000 LM (RTM) 170. TINUVIN 622 (RTM) + ADK STAB LA 52 (RTM) + — Compound of formula (B-6-a), where E18 is hydrogen 171. TINUVIN 622 (RTM) + ADK STAB LA 52 (RTM) + — 42 This paper applies the Chinese national standard (CNS) ) A4 size (210 X 297 mm) ------------------- Order --------- (Please read the notes on the back before filling in this Page) A7 B7 1226897 V. Description of the invention (< Compound of formula (B-6-a), where Ei8 is methyl 172. TINUVIN 622 (RTM) + ADK STAB LA 52 (RTM) + — Formula (B-7) Compound where E19, E20 and E21 are a group of formula (b-III), where E22 is hydrogen. 173. TINUVIN 622 (RTM) + ADK STAB LA 57 (RTM) + ADK STAB LA 62 (RTM) 174. TINUVIN 622 (RTM) + ADK STAB LA 57 (RTM) + ADK STAB LA 67 (RTM) 175. TINUVIN 622 (RTM) + ADK STAB LA 57 (RTM) + GOODRITE UV 3034 (RTM) 176. TINUVIN 622 (RTM) + ADK STAB LA 57 (RTM) + GOODRITE UV 3150 (RTM) 177. TINUVIN 622 (RTM) + ADK STAB LA 57 (RTM) + GOODRITE UV 3159 (RTM) 178. TINUVIN 622 (RTM) + ADK STAB LA 57 (RTM ) + — Compound of formula (B-9-a), where E25 is hydrogen 179. TINUVIN 622 (RTM) + ADK STAB LA 57 (RTM) + UVINU L 4049 (RTM) 180. TINUVIN 622 (RTM) + ADK STAB LA 57 (RTM) + — compound of formula (B-10-a), where E29 is hydrogen 181. TINUVIN 622 (RTM) + ADK STAB LA 57 (RTM ) + — Compound of formula (Bla), where Ei is hydrogen 182. TINUVIN 622 (RTM) + ADK STAB LA 57 (RTM) + SUMISORB TM 61 (RTM) 43 This paper standard applies to China National Standard (CNS) A4 specification (210 X 297 mm) -------------------- Order --------- (Please read the precautions on the back before filling this page) 1226897 A7 I —__ B7___ 5. Description of the Invention (W) 183. TINUVIN 622 (RTM) + ADK STAB LA 57 (RTM) + SANDUVOR 3050 (RTM) 184. TINUVIN 622 (RTM) + ADK STAB LA 57 (RTM) + SANDUVOR PR- 31 (RTM) 185. TINUVIN 622 (RTM) + ADK STAB LA 57 (RTM) + UVASIL 299 LM (RTM) 186. TINUVIN 622 (RTM) + ADK STAB LA 57 (RTM) + UVASIL 2000 LM (RTM) 187. TINUVIN 622 (RTM) + ADK STAB LA 57 (RTM) + compound of formula (B-6-a), where E18 is hydrogen 188. TINUVIN 622 (RTM) + ADK STAB LA 57 (RTM) + — formula (B-6 -a) a compound in which E18 is methyl 189. TINUVIN 622 (RTM) + ADK STAB LA 57 (RTM) + — formula (B -7) Compounds in which E19, E20 and E21 are a group of formula (b-III) where e22 is hydrogen. 190. TINUVIN 622 (RTM) + ADK STAB LA 62 (RTM) + ADK STAB LA 67 (RTM) 191. TINUVIN 622 (RTM) + ADK STAB LA 62 (RTM) + GOODRITE UV 3034 (RTM) 192. TINUVIN 622 (RTM) + ADK STAB LA 62 (RTM) + GOODRITE UV 3150 (RTM) 193. TINUVIN 622 (RTM) ) + ADK STAB LA 62 (RTM) + GOODRITE UV 3159 (RTM) 194. TINUVIN 622 (RTM) + ADK STAB LA 62 (RTM) + — This paper size applies to China National Standard (CNS) A4 (210 X 297 male) (Li) -------------. ^ W ^ -------- Order --------- (Please read the notes on the back before filling this page) 1226897 A7 B7 V. Description of the invention) Compound of formula (B-9-a), where E25 is hydrogen 195. TINUVIN 622 (RTM) + ADK STAB LA 62 (RTM) + UVINUL 4049 (RTM) 196. TINUVIN 622 (RTM) + ADK STAB LA 62 (RTM) + — compound of formula (B-10-a), where E29 is hydrogen 197. TINUVIN 622 (RTM) + ADK STAB LA 62 (RTM) + compound of formula (Bla), where E! Is hydrogen 198. TINUVIN 622 (RTM) + ADK STAB LA 62 (RTM) + SUMISORB TM 61 (RTM) 199. TINUVIN 622 (RTM) + ADK STAB LA 62 (RTM) + SANDUVOR 3050 (RTM) 200. TINUVIN 622 (RTM) + ADK STAB LA 62 (RTM) + SANDUVOR PR-31 (RTM) 201. TINUVIN 622 (RTM) + ADK STAB LA 62 (RTM ) + UVASIL 299 LM (RTM) 202. TINUVIN 622 (RTM) + ADK STAB LA 62 (RTM) + UVASIL 2000 LM (RTM) 203. TINUVIN 622 (RTM) + ADK STAB LA 62 (RTM) + — Formula (B -6-a) compound, wherein E18 is hydrogen 204. TINUVIN 622 (RTM) + ADK STAB LA 62 (RTM) +-compound of formula (B-6-a), wherein E18 is methyl 205. TINUVIN 622 (RTM) + ADK STAB LA 62 (RTM) + — Compounds of formula (B-7), where E19, E2〇 and E21 are groups of formula (b-III), of which e22 is hydrogen. 45 This paper is applicable to Chinese national standards (CNS ) A4 size (210 X 297 mm) -------------------- Order --------- (Please read the precautions on the back before filling (This page) 1226897 A7 B7 V. Description of invention (na) 206. TINUVIN 622 (RTM) + ADK STAB LA 67 (RTM) + GOODRITE UV 3034 (RTM) 207. TINUVIN 622 (RTM) + ADK STAB LA 67 (RTM) + GOODRITE UV 3150 (RTM) 208. TINUVIN 622 (RTM) + ADK STAB LA 67 (RTM) + GOODRITE UV 3159 (RTM) 209. TINUVIN 622 (RTM) + ADK STAB LA 67 (RTM) + — Compound of formula (B-9-a), where E25 is hydrogen 210. TINUVIN 622 (RTM) + ADK STAB LA 67 (RTM) + UVINUL 4049 (RTM) 211. TINUVIN 622 (RTM) + ADK STAB LA 67 (RTM) + — compound of formula (B-10-a), where E29 is hydrogen 212. TINUVIN 622 (RTM) + ADK STAB LA 67 (RTM) + — formula ( Bla) compound where E! Is hydrogen 213. TINUVIN 622 (RTM) + ADK STAB LA 67 (RTM) + SUMISORB TM 61 (RTM) 214. TINUVIN 622 (RTM) + ADK STAB LA 67 (RTM) + SANDUVOR 3050 ( RTM) 215. TINUVIN 622 (RTM) + ADK STAB LA 67 (RTM) + SANDUVOR PR-31 (RTM) 216. TINUVIN 622 (RTM) + ADK STAB LA 67 (RTM) + UVASIL 299 LM (RTM) 217. TINUVIN 622 (RTM) + ADK STAB LA 67 (RTM) + UVASIL 2000 LM (RTM) 46 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ----------- --------- Order --------- (Please read the notes on the back before filling this page) A7 1226897 ____B7___ V. Description of Invention (W) 218. TINUVIN 622 (RTM) + ADK STAB LA 67 (RTM) + compound of formula (B-6-a), where E18 is hydrogen 219. TINUVIN 622 (RTM) + ADK STAB LA 67 (RTM) + — compound of formula (B_6-a) where Ei8 is methyl 220. TINUVIN 622 (RTM) + ADK STAB LA 67 (RTM) + — compound of formula (B-7), where E19 , E2G and E21 are a group of formula (b-III), where E22 is hydrogen. 221. TINUVIN 622 (RTM) + GOODRITE UV 3034 (RTM) + GOODRITE UV 3150 (RTM) 222. TINUVIN 622 (RTM) + GOODRITE UV 3034 (RTM) + GOODRITE UV 3159 (RTM) 223. TINUVIN 622 (RTM) + GOODRITE UV 3034 (RTM) + a compound of the formula (B-9-a), where E25 is hydrogen 224. TINUVIN 622 (RTM) + GOODRITE UV 3034 (RTM) + UVINUL 4049 (RTM) 225. TINUVIN 622 (RTM) + GOODRITE UV 3034 (RTM) + a compound of the formula (B-10-a), where E29 is hydrogen 226. TINUVIN 622 (RTM) + GOODRITE UV 3034 (RTM) + a compound of formula (Bla) where Ei is hydrogen 227. TINUVIN 622 (RTM) + GOODRITE UV 3034 (RTM) + SUMISORB TM 61 (RTM) 228. TINUVIN 622 (RTM) + GOODRITE UV 3034 (RTM) + SANDUVOR 3050 (RTM) 229. TINUVIN 622 (RTM) + GOODRITE UV 3034 (RTM) + 47 This paper size applies to China National Standard (CNS) A4 (210 x 297 mm) ---------- ---------- Order ---- ----- (Please read the precautions on the back before filling this page) 1226897 A7 _B7 V. Description of the invention (/) SANDUVOR PR-31 (RTM) 230. TINUVIN 622 (RTM) + GOODRITE UV 3034 (RTM) + UVASIL 299 LM (RTM) 231. TINUVIN 622 (RTM) + GOODRITE UV 3034 (RTM) + UVASIL 2000 LM (RTM) 232. TINUVIN 622 (RTM) + GOODRITE UV 3034 (RTM) + Form (B-6-a) Compound where E18 is hydrogen 233. TINUVIN 622 (RTM) + GOODRITE UV 3034 (RTM) + compound of formula (B-6-a) where E18 is methyl 234. TINUVIN 622 (RTM) + GOODRITE UV 3034 (RTM) + A compound of formula (B-7), where E19, Em and E21 are a group of formula (b-III), where E22 is hydrogen. 235. TINUVIN 622 (RTM) + GOODRITE UV 3150 (RTM) + GOODRITE UV 3159 (RTM ) 236. TINUVIN 622 (RTM) + GOODRITE UV 3150 (RTM) + compound of formula (B_9_a), where E25 is hydrogen 237. TINUVIN 622 (RTM) + GOODRITE UV 3150 (RTM) + UVINUL 4049 (RTM) 238. TINUVIN 622 (RTM) + GOODRITE UV 3150 (RTM) + compound of formula (B-10-a), where E29 is hydrogen 239. TINUVIN 622 (RTM) + GOODRITE UV 3150 (RTM) + compound of formula (Bla), where Ei Hydrogen 240. TINUVIN 622 (RTM) + GOODRITE UV 3150 (RTM) + SUMISORB TM 61 (RTM) 48 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -------- ------------ ^ --------- (Please read the notes on the back before filling this page) 1226897 A7 B7 V. Description of the Invention (#) 241. TINUVIN 622 ( (RTM) + GOODRITE UV 3150 (RTM) + SANDUVOR 3050 (RTM) 242. TINUVIN 622 (RTM) + GOODRITE UV 3150 (RTM) + SANDUVOR PR-31 (RTM) 243. TINUVIN 622 (RTM) + GOODRITE UV 3150 (RTM) ) + UVASIL 299 LM (RTM) 244. TINUVIN 622 (RTM) + GOODRITE UV 3150 (RTM) + UVASIL 2000 LM (RTM) 245. TINUVIN 622 (RTM) + GOODRITE UV 3150 (RTM) + Form (B-6- a) Compound where E18 is hydrogen 246. TINUVIN 622 (RTM) + GOODRITE UV 3150 (RTM) + compound of formula (B-6_a) where E18 is methyl 247. TINUVIN 622 (RTM) + GOODRITE UV 3150 (RTM) + A compound of formula (B-7), in which E19, E2G and E21 are a group of formula (b-III), where E22 is hydrogen. 248. TINUVIN 622 (RTM) + GOODRITE UV 3159 (RTM) + formula (B-9 -a) a compound in which E25 is hydrogen 249. TINUVIN 622 (R TM) + GOODRITE UV 3159 (RTM) + UVINUL 4049 (RTM) 250. TINUVIN 622 (RTM) + GOODRITE UV 3159 (RTM) + compound of formula (B-10-a), where E29 is hydrogen 251. TINUVIN 622 (RTM ) + GOODRITE UV 3159 (RTM) + a compound of the formula (Bla) where Ei is hydrogen 252. TINUVIN 622 (RTM) + GOODRITE UV 3159 (RTM) + 49 This paper applies Chinese National Standard (CNS) A4 specifications (210 X 297 mm) -------- Order --------- (Please read the notes on the back before filling out this page) 1226897 A7 B7 V. Description of the invention (β) SUMISORB TM 61 (RTM ) 253. TINUVIN 622 (RTM) + GOODRITE UV 3159 (RTM) + SANDUVOR 3050 (RTM) 254. TINUVIN 622 (RTM) + GOODRITE UV 3159 (RTM) + SANDUVOR PR-31 (RTM) 255. TINUVIN 622 (RTM) + GOODRITE UV 3159 (RTM) + UVASIL 299 LM (RTM) 256. TINUVIN 622 (RTM) + GOODRITE UV 3159 (RTM) + UVASIL 2000 LM (RTM) 257. TINUVIN 622 (RTM) + GOODRITE UV 3159 (RTM) + A compound of formula (B-6-a), where E18 is hydrogen 258. TINUVIN 622 (RTM) + GOODRITE UV 3159 (RTM) + A compound of formula (B_6_a) 'where Eis is methyl 259. TINUVIN 622 (RTM) + GOODRI TE UV 3159 (RTM) + compounds of formula (B-7), where E19, E2G and E21 are groups of formula (b-III), where E22 is hydrogen · 260. TINUVIN 622 (RTM) +-formula (B-9 -a) a compound, wherein E25 is hydrogen + UVINUL 4049 (RTM) 261. T1NUVIN 622 (RTM) +-a compound of formula (B-9-a), wherein E25 is hydrogen +-a compound of formula (B-10-a), Where E29 is hydrogen 262. TINUVIN 622 (RTM) + — compound of formula (B_9-a), where E25 is hydrogen + — compound of formula (B-1-a), where Ei is hydrogen 263. TINUVIN 622 (RTM) + — Compound of formula (B_9-a), of which 50 paper sizes are applicable to China National Standard (CNS) A4 (210 X 297 mm) -------------------- Order --------- (Please read the precautions on the back before filling this page) 1226897 A7 B7 V. Description of the invention (4) E25 is hydrogen + SUMISORB TM61 (RTM) 264.TINUVIN 622 (RTM) + — Compound of formula (B-9-a), wherein E25 is hydrogen + SANDUVOR 3050 (RTM) 265eTINUVIN 622 (RTM) +-compound of formula (B-9-a), of which E25 Μ Μ + SANDUVOR PR-31 (RTM) 266 TINUVIN 622 (RTM) +-compound of formula (B_9-a), where E25 is hydrogen + UVASIL 299 LM (RTM) 267. T INUVIN 622 (RTM) +-compound of formula (B-9-a), where E25 is hydrogen + UVASIL 2000 LM (RTM) 268. TINUVIN 622 (RTM) +-compound of formula (B-9-a), where E25 is Hydrogen +-compound of formula (B-6-a), where E18 is hydrogen 269. TINUVIN 622 (RTM) +-compound of formula (B-9-a), where E25 is hydrogen +-formula (B-6-a) Compound 'where Ei8 is methyl 270. TINUVIN 622 (RTM) +-compound of formula (B-9-a), where E25 is hydrogen +-compound of formula (B-7), where E19, E2G and E21 are of formula (b -III) group base, where E22 is hydrogen · 271. TINUVIN 622 (RTM) + UVINUL 4049 (RTM) +-compound of formula (B-10-a), where E29 is hydrogen 272. TINUVIN 622 (RTM) + UVINUL 4049 (RTM) +-compound of formula (B-1-a), where Eι is hydrogen 273. TINUVIN 622 (RTM) + UVINUL 4049 (RTM) + SUMISORB TM 61 (RTM) 51 This paper is applicable to Chinese National Standard (CNS) A4 specification (210 X 297 mm) -------------------- Order --------- (Please read the precautions on the back before filling in this Page) A7 1226897 B7 V. Description of the invention () 274. TINUVIN 622 (RTM) + UVINUL 4049 (RTM) + SANDUVOR 3050 (RTM) 275. TINUVIN 6 22 (RTM) + UVINUL 4049 (RTM) + SANDUVOR PR-31 (RTM) 276. TINUVIN 622 (RTM) + UVINUL 4049 (RTM) + UVASIL 299 LM (RTM) 277. TINUVIN 622 (RTM) + UVINUL 4049 (RTM) ) + UVASIL 2000 LM (RTM) 278. TINUVIN 622 (RTM) + UVINUL 4049 (RTM) + — compound of formula (B-6_a), where E18 is hydrogen 279. TINUVIN 622 (RTM) + UVINUL 4049 (RTM) + — A compound of formula (B-6-a), wherein E18 is methyl 280. TINUVIN 622 (RTM) + UVINUL 4049 (RTM) +-compounds of formula (B_7) E19, E2G and E21 are a group of formula (b-III), Where e22 is hydrogen. 281. TINUVIN 622 (RTM) +-compound of formula (B-10-a), where ^ 29 is hydrogen +-compound of formula (Bla), where E! Is hydrogen 282. TINUVIN 622 (RTM) + — Compound of formula (B_10-a), where E29 is hydrogen + SUMISORB TM 61 (RTM) 283. TINUVIN 622 (RTM) + — Compound of formula (B-10-a), where E29 is hydrogen + SANDUVOR 3050 (RTM) 284 TINUVIN 622 (RTM) +-compound of formula (B-10-a), where E29 is hydrogen + SANDUVORPR-31 (RTM) 285. TINUVIN 622 (RTM) +-compound of formula (B-10-a), of which 52 This paper size applies to China National Standard (CNS) A4 (21 0 X 297 mm) ------------------- Order --------- (Please read the precautions on the back before filling this page) 1226897 Α7 Β7 Eι is hydrogen V. Description of the invention (θ E29 is hydrogen + UVASIL 299 LM (RTM) 286. TINUVIN 622 (RTM) +-compound of formula (B-10-a), where E29 is hydrogen + UVASIL 2000 LM (RTM) 287. TINUVIN 622 (RTM) +-compound of formula (B-10-a), where E29 is hydrogen +-compound of formula (B-6-a), where E18 is hydrogen 288. TINUVIN 622 (RTM) +-formula ( B-10-a) compound, wherein E29 is hydrogen +-compound of formula (B-6-a) 'wherein E18 is methyl 289. TINUVIN 622 (RTM) +-compound of formula (B-10-a), where E29 Is hydrogen +-compound of formula (B-7), where E19, E2g and E21 are a group of formula (b-III), where E22 is hydrogen · 290. TINUVIN 622 (RTM) +-formula (B-1-a) Compound, which is hydrogen + SUMISORB TM 61 (RTM) 291. TINUVIN 622 (RTM) + — compound of formula (B-1-a), where Ei is hydrogen + SANDUVOR 3050 (RTM) 292. TINUVIN 622 (RTM) + — A compound of formula (B_1-a), wherein E! Is hydrogen + SANDUVORPR-31 (RTM) 293. TINUVIN 622 (RTM) +-a compound of formula (B-1-a), E! Is hydrogen + UVASIL 299 LM (RTM) 294. TINUVIN 622 (RTM) +-compound of formula (B_l_a), where E! Is hydrogen + UVASIL 2000 LM (RTM) 295. TINUVIN 622 (RTM) +-formula ( B-1-a) compounds, in which the compound of formula (B-6_a), in which E18 is hydrogen 53 This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) --------- ---------- Order --------- (Please read the notes on the back before filling this page) 1226897 A7 B7 V. Description of the invention (< \) 296. TINUVIN 622 ( RTM) +-compound of formula (B_1-a), where E! Is hydrogen +-compound of formula (B-6-a), where E18 is methyl 297. TINUVIN 622 (RTM) +-formula (B-1-a ) Compounds, where Eι is a compound of formula (B · 7) where E19, E2Q and E21 are a group of formula (b-III), where e22 is hydrogen. 298. TINUVIN 622 (RTM) + SUMISORB TM 61 (RTM) + SANDUVOR 3050 (RTM) 299. TINUVIN 622 (RTM) + SUMISORB TM 61 (RTM) + SANDUVOR PR-31 (RTM) 300. TINUVIN 622 (RTM) + SUMISORB TM 61 (RTM) + UVASIL 299 LM ( RTM) 301. TINUVIN 622 (RTM) + SUMISORB TM 61 (RTM) + UVASIL 2000 LM (RTM) 302. TINUVIN 62 2 (RTM) + SUMISORB TM 61 (RTM) + — compound of formula (B-6-a), where E18 is hydrogen 303. TINUVIN 622 (RTM) + SUMISORB TM 61 (RTM) + — formula (B-6-a ) Compound, wherein E18 is methyl 304. TINUVIN 622 (RTM) + SUMISORB TM 61 (RTM) +-compounds of formula (B-7), wherein E19, E2G and E21 are a group of formula (b-III), where E22 It is hydrogen. 305. TINUVIN 622 (RTM) + SANDUVOR 3050 (RTM) + SANDUVOR PR-31 (RTM) 306. TINUVIN 622 (RTM) + SANDUVOR 3050 (RTM) + 54 This paper is applicable to the Chinese National Standard (CNS) A4 Specifications (210 X 297 mm) -------- Order --------- (Please read the precautions on the back before filling this page) 1226897 A7 __B7___ V. Description of the invention (〆) UVASIL 299 LM (RTM) 307. TINUVIN 622 (RTM) + SANDUVOR 3050 (RTM) + UVASIL 2000 LM (RTM) 308. TINUVIN 622 (RTM) + SANDUVOR 3050 (RTM) + — compound of formula (B-6-a), Where E18 is hydrogen 309. TINUVIN 622 (RTM) + SANDUVOR 3050 (RTM) + — compound of formula (B-6-a), where E18 is methyl 3 10.TTINUVIN 622 (RTM) + SANDUVOR 3050 (RTM) + — Compound of formula (B-7), wherein E19, E2O and E21 are one Group of formula (b-III), where E22 is hydrogen. 311. TINUVIN 622 (RTM) + SANDUVOR PR-31 (RTM) + UVASIL 299 LM (RTM) 312. TINUVIN 622 (RTM) + SANDUVOR PR-31 (RTM ) + UVASIL 2000 LM (RTM) 3 13.TINUVIN 622 (RTM) + SANDUVOR PR-31 (RTM) + — compound of formula (B-6-a), where E18 is hydrogen 314. TINUVIN 622 (RTM) + SANDUVOR PR -31 (RTM) + compound of formula (B_6_a), where E18 is methyl 315. TINUVIN 622 (RTM) + SANDUVOR PR-31 (RTM) + — compound of formula (B-7), where E19, E2q and E21 are formulae (B-III) group base, where E22 is hydrogen. 316. TINUVIN 622 (RTM) + UVASIL 299 LM (RTM) + — compound of formula (B-6-a), where E18 is hydrogen 3 17.TINUVIN 622 (RTM ) + UVASIL 299 LM (RTM) + — 55 This paper size applies to China National Standard (CNS) A4 (210 x 297 mm) -------------------- Order --------- (Please read the notes on the back before filling out this page) 1226897 A7 _______B7___ V. Description of the invention (妁) Compound of formula (B-6-a), where E18 is methyl 318. TINUVIN 622 (RTM) + UVASIL 299 LM (RTM) + compounds of formula (B-7), where E19, E2Q and E21 are Group of formula (b-III), where E22 is hydrogen · 319. TINUVIN 622 (RTM) + UVASIL 2000 LM (RTM) + a compound of formula (B-6-a), where E18 is hydrogen 320. TINUVIN 622 (RTM) + UVASIL 2000 LM (RTM) + — compound of formula (B-6-a), where E18 is methyl 321. TINUVIN 622 (RTM) + UVASIL 2000 LM (RTM) + — compound of formula (B-7), where E19 E20 and E21 are a group of formula (b-III), where E22 is hydrogen. 322. TINUVIN 622 (RTM) +-compound of formula (B-6-a), where E18 is hydrogen +-formula (B-6 -a) a compound in which E18 is methyl 323. TINUVIN 622 (RTM) +-a compound of formula (B-6-a), in which Ei8 is hydrogen +-a compound of formula (B_7) in which E19, E2 () and E21 are A group of formula (b-III), where E22 is hydrogen. 324. TINUVIN 622 (RTM) +-compound of formula (B-6-a), where E18 is methyl +-compound of formula (B-7), where E19 , E2〇 and E21 are a group of formula (b-III), where E22 is hydrogen. Other examples of stabilizer mixtures are in which in the above 1 to 3 2 4 combination, the commercial product TINUVIN 622 (RTM) is represented by the formula ( A-2-a) and / or (A-2-b) compounds are substituted for this paper. Home Standard (CNS) A4 Specification (210 X 297 Public Love) -------- Order --------- (Please read the precautions on the back before filling this page) 1226897 A7 B7 V. Invention Description (A)

(A-2-a) (A-2-b) (Please read the notes on the back before filling out this page) where n2 and n2 * are numbers from 2 to 20. Examples of other stabilizer mixtures are where the commercial product TINUVIN 622 (RTM) is replaced by a compound of formula (A-4-a) in the above-mentioned combinations 1 to 3 2 4

I -CH plant C—CH, —CH ——

I I household 0 i = 〇

A I I ο ch3 D-A7

Where n4 is a number from 2 to 20, and at least 50% of A7 is a monoradical group, and the remaining A7 is an ethyl group. 57 This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) A7 1226897 ____ B7__ V. Description of the invention (β) A particularly advantageous combination is 1, 4, 7, 8, 12, 13 and 15 to 24, and the relative combination where TINUVIN 622 (RTM) is replaced by (A_2-a) and / or (A-2-b) compounds. A particularly advantageous combination is 3, 4, 8, 17 and 31. The commercial product TINUVIN 622 (RTM) is equivalent to the compound (A-Ια) 0 The commercial product TINUVIN 770 (RTM) is equivalent to the compound (B-l_b), where Ei is hydrogen. The commercial product TINUVIN 765 (RTM) is equivalent to compound (B-1-b), where E! Is methyl. The commercial product TINUVIN 123 (RTM) is equivalent to compound (B-1-b), where E! Is octyloxy. The commercial product TINUVIN 144 (RTM) is equivalent to compound (B-Ιο), where Ei is methyl. The commercial product ADK STAB LA 57 (RTM) corresponds to compound (B-1-d), where Ei is hydrogen. The commercial product ADK STAB LA 52 (RTM) is equivalent to compound (B-1-d), where E! Is methyl. The commercial product ADK STAB LA 67 (RTM) is equivalent to compound (B-2-a), where E8 is hydrogen. The commercial product ADK STAB LA 62 (RTM) is equivalent to compound (B-2-a), where Ei is a radical. The commercial product HOSTAVIN N 24 (RTM) is equivalent to compound (B-3-b), where E12 is hydrogen. 58 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -------- ^ --------- (Please read the precautions on the back before filling this page ) 1226897 A7 B7 V. Description of the invention (&); The commercial product SANDUVOR 3050 (RTM) is equivalent to the compound (B-3-bl) shown below, where E12 is hydrogen. The commercial product DIACETAM5 (RTM) is equivalent to compound (B-4-a), where E13 is argon. The commercial product SUMISORB ™ 61 is equivalent to compound (B-4-b), where E13 is hydrogen. The commercial product UVINUL 4 (M9 (RTM) is equivalent to compound (B-5), where E16 is hydrogen. The commercial product SANDUVOR PR 31 (RTM) is equivalent to compound (B-8-a), where E23 is methyl. The commercial product GOODRITE 3034 (RTM) is equivalent to compound (B-9-b), where E25 is hydrogen. The commercial product GOODRITE 3150 (RTM) is equivalent to compound (B-9-c), where E25 is gas. Commercial The product GOODRITE 3159 (RTM) is equivalent to compound (B-9-c), where E25 is methyl. · Commercial products UVASIL 299 LM (RTM) or UVASIL 2000 LM (RTM) contain one compound (B-11-a) As an active ingredient, R16 is hydrogen. The compound (B-3-bl) has the structure as described below: 59 This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) ----- --- ^ --------- (Please read the precautions on the back before filling this page) 1226897 Α7 Β7 V. Description of the invention (< Ί) 〇, CH2CH ^ —C—〇—C12alkyl

The stabilizer mixture of the present invention is suitable for stabilizing organic substances against degradation caused by light, heat or oxidation. Examples of these organic substances are as listed below: 1. polymers of mono- and diolefins, for example, polypropylene, polyisobutylene, polybutadiene-1, poly-4-methylpent-1-ene, Polyisoprene or polybutadiene, and polymers of cycloolefins, such as cyclopentene or norbornene, other polyethylenes (if required, they can be crosslinked), such as high density polyethylene (HDPE ), High density and high molecular weight polyethylene (HDPE-HMW), high density ultra high molecular weight polyethylene (HDPE-UHMW), medium density polyethylene (MDPE), low density polyethylene (LDPE), linear low density polyethylene (LLD PE), (VLDPE) and (ULDPE). Polyolefins, that is, polymers of monoolefins, like the monoolefin polymers exemplified in the preceding paragraph, especially polyethylene and polypropylene can be prepared by different methods, especially the following method = a) free Reactive group polymerization (usually under high pressure and temperature).

b) Catalyst polymerization reaction using a catalyst, which usually contains one or more than one IVb, Vb, VIb or VI II on the periodic table. The paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) ) -------- Order --------- (Please read the notes on the back before filling this page) 1226897 B7 V. Description of the invention ( 0) metals, these metals usually have one or more types, typically oxides, halides, alcohol esters, esters, ethers, amines, alkylates, alkenyls and / or aryls, which may be redundant One or σ is covalent. These metal complexes may be in a free state or fixed on a substrate ' typically on activated magnesium chloride, titanium chloride (I I I), aluminum or silicon oxide. These catalysts can be soluble or insoluble in the polymer matrix, and these catalysts can be used in the polymerization reaction themselves, or can use an activator, typically a metal alloy 'metal hydride, metal alkyl halide Metal alkyl oxide or metal alkylspirane, the metal may be an element of Group I a, II a, and / or IIIA of the periodic table, and the activator may be further modified with an ester, ether, amine or silane ether. These catalyst systems are often called Phillips, Standard

Oil Indiana, Ziegler (-Natta), TNZ (DuPont), metallocene or single-sided catalyst (S S C). 2 · A mixture of polymers mentioned in 1), for example, a mixture of polypropylene and polyisobutylene, a mixture of polypropylene and polyethylene (for example, p P / HDPE, PP / LDPPE), and a mixture of different types of polyethylene ( (Eg LDPE / HDPE). 3. Copolymers of mono- and diolefins, or copolymers with other ethylene monomers, such as ethylene / propylene copolymers, linear low-strength polyethylene (LLDPE) and mixtures thereof, and low-strength polyethylene (ld PE), Propylene / butane-1-ene copolymer, propylene / isobutylene copolymer, ethylene / but-1-ene copolymer, ethylene / hexene copolymer, ethylene / methylpentene copolymer, ethylene / heptene copolymer, ethylene / Octene copolymer, propylene / butadiene copolymer, isobutylene / isoprene copolymer, ethylene / fluorenyl ------------- I ---- order --- ------ (Please read the precautions on the back before filling this page) 61 1226897 A7 _B7___ V. Description of the invention (β) Acrylate copolymer, and its copolymer with carbon monoxide, or ethylene / Acrylic copolymers, their salts (ions), and terpolymers of ethylene and propylene and monodiene, such as hexadiene, dicyclopentadiene or ethylenedi-orbornene; and the copolymer Mixtures and mixtures of polymers mentioned in 1) above, for example, polypropylene / ethylene / propylene copolymers, LD PE / ethylene-ethylene Ester Copolymer (EVA), LDPE / Ethylene-Acrylic Copolymer (EAA), LEVADPE / EVA, LLDPE / EAA and Poly-Academium-Carbon Monoxide Copolymers with a Staggered or Dispersed Structure, and Others Mixtures of polymers, such as polyamide 04 hydrocarbon resins (such as C 5 -C 9), including their hydrogenated modifiers (such as adhesives), and mixtures of polyolefins and starch. 5. Polystyrene, poly (P-methylstyrene), poly-methylstyrene). 6. Copolymers of styrene or α-methylstyrene and diene or acrylic acid derivatives, for example, styrene / butadiene, styrene / acrylonitrile, styrene / alkylmethacrylate, styrene / butadiene Diene / alkyl acrylate, styrene / butadiene / alkyl methacrylate, styrene / maleic anhydride, styrene / acrylonitrile / methacrylate; high impact strength mixture of styrene copolymer And another polymer, such as polyacrylate, a diene polymer or an ethylene / propylene / diene terpolymer; and a block copolymer of styrene, such as styrene / butadiene / styrene, Styrene / 62 -------- Order --------- ^^ 1 (Please read the precautions on the back before filling this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 1226897 A7 _ B7___ V. Description of the invention (P) Isoprene / styrene, styrene / ethylene / butene / styrene or styrene / ethylene / propylene / styrene. 7. Graft copolymers of styrene or α-methylstyrene, for example, styrene on polybutadiene, on polybutadiene-styrene or on polybutadiene-acrylonitrile copolymer Styrene on polybutadiene and acrylonitrile (or methacrylonitrile); styrene, acrylonitrile and methacrylic acid on polybutadiene; benzene on polybutadiene Ethylene and maleic anhydride; styrene, acrylonitrile and maleic anhydride or maleimide on polybutadiene; styrene and maleimide on polybutadiene Imines; styrene and alkyl acrylate or methacrylate on polybutadiene; styrene and acrylonitrile on ethylene / propylene / diene terpolymer; polyalkyl acrylate or polyalkyl Styrene and acrylonitrile on methacrylate; styrene and acrylonitrile on acrylate / butadiene copolymers, and mixtures with the copolymers listed in item 6), for example, the conventional ABS, MB S 'ASA Or copolymer blends of AES polymers. 8 · Halogen-containing polymers like polychlorinated pentadiene, chlorinated rubber, chlorinated or vulcanized chlorinated polyethylene, copolymers of ethylene and chlorinated ethylene, epichlorohydrin homo- and copolymers, especially those containing Polymers of halogenated ethylene compounds, such as polyethylene chloride, polyethylene chloride, polyethylene fluoride, polyethylene fluoride, and copolymers thereof, like ethylene chloride / ethylene dichloride, ethylene Chloride / ethylene acetate or ethylene dichloride / ethylene acetate copolymer. 9 · Polymers prepared from α, Θ -unsaturated acids and their derivatives, such as polyacrylates and polymethacrylates; polymethacrylates, 63 -------- order-- ------- ^^ 1 (Please read the precautions on the back before filling this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 1226897 A7 B7 ----— * _ -------------- V. Description of the invention (W) Polyacrylamide and polyacrylonitrile are modified by butyl acrylate. 10. Copolymers formed between the monomers of 9) and other unsaturated monomers, such as acrylonitrile / butadiene copolymer, acrylonitrile / alkyl propionate copolymer, acrylonitrile / co-oxygen Co-based propionate or propionitrile / ethylene halide copolymer or acrylonitrile / alkyl methacrylate / butadiene terpolymer. 11. Polymers derived from unsaturated alcohols and amines or their halogenated derivatives or acetals, such as polyvinyl alcohol, polyvinyl acetate, polyethylene stearate, polyvinyl benzoate, Polyethylene maleate, polyethylene butyral, polyallyl phthalate or polyallyl melamine; and copolymers thereof with the olefins mentioned in point 1 above. 1 2 Homopolymers and copolymers of cyclic ethers, such as polyolefin diols, polyethylene oxides, polypropylene oxides, or copolymers with dioxolan ethers. 1 3 · Polyacetals, like polyoxymethylene and those polyoxymethylenes, contain ethylene oxide as a comonomer, modified polyacetals with thermoplastic polyurethane, acrylate or MBS. 1 4 · Polyphenylene oxides and sulfides, and mixtures of polystyrene oxides and styrene polymers or polyamides. 1 5 · Polyurethane derived from hydroxyl-terminated polyether, polyester or polybutadiene on one side, and aliphatic or aromatic polyisocyanate on the other side, and its precursors. 16. Polyamines and copolymers derived from diamines and dicarboxylic acids and / or amine carboxylic acids or equivalent lactams, such as polyamine 4, polyamine 6, polyamine 6 / 6, 6/10, 6/9, 6/12, 4/64 This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 male f) -------- ^ ---- ----- (Please read the precautions on the back before filling this page) 1226897 A7 __ V. Description of the invention (π) 6, 1 2/1 2, Polyamine 1 1, Polyamine 1 2, by m —Xylendiamine and adipic acid-based aromatic polyamines; polyamines derived from hexamethylenediamine and iso-peptides or / and p-peptides, with or without elastomers as modification Agents, for example, poly-2,4,4-trimethylhexamethylene p-amine or poly-m-styrene isoamidine; and the above-mentioned polyamines and polyolefins, olefin copolymers, ionized compounds, Or chemically bonded or grafted elastomers; or polyethers, such as block copolymers with polyethylene glycol, polypropylene glycol, or polytetramethylene glycol; and polyamides modified with EPDM or ABS, or Copolyamide; and concentrated in the preparation process (RI M polyamine system) Amides. 1 7 • Polyurea, polyimide, polyamido-imino, and polybenzimid. Oral sitting. 18. Polyesters derived from dicarboxylic acids and glycols and / or hydroxycarboxylic acids or equivalent lactones, for example, polyethylene terephthalate, polybutene terephthalate, poly-1, 4-Dimethanol cyclohexane peptidate and polyhydroxybenzoate, and block copolyetheresters derived from hydroxyl terminated polyethers; and polymers modified with polycarbonate or modified with BS ester. 19. Polycarbonate and polyester carbonate. 2 0 · Polyboron, polyether and polyetherketone. 2 1 · Crosslinked polymers derived from aldehyde on one side, phenol, urea and melamine on the other side, like phenol / formaldehyde resin, urea / formaldehyde resin, and melamine / formaldehyde resin. 2 2 · Dried and non-dried alkyd resins. 2 3 · Saturated and unsaturated dicarboxylic acids and polyhydric alcohols and 65 with ethylene compound This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -------- ^- ------- (Please read the precautions on the back before filling this page) 1226897 ΚΙ _Β7 ___ V. Description of the invention (θ) Unsaturated polyester resin 5 derived from the cross-linking agent and its low flammability Sexual halogen-containing modifiers. 2 4 · A crosslinked acrylic resin derived from a substituted acrylate, for example, epoxy acrylic resin 5 urethane acrylic resin or polyester acrylate. 2 5 β alkyd resin, polyester resin and melamine resin crosslinked acrylic resin, urea resin, polyisocyanate or epoxy resin. 2 6 · Crosslinked epoxy resins derived from aliphatic, cycloaliphatic, heterocyclic or aromatic oxypropane compounds, such as products obtained from bisphenol A and bisphenol F ethers It can be cross-linked with traditional hardeners, like anhydrides or amines (either in the presence or absence of accelerators). 2 7 · Natural polymers, like cellulose, rubber, gelatin and similar chemically modified derivatives, such as cellulose acetate, cellulose propionate and cellulose butyrate, or cellulose ethers, like methyl Cellulose, and turpentine and its derivatives. 2 8 · Blends (Polyblends) of the above polymers, such as PP / EP DM, Polyamide / E PDM or ABS, PVC / EV A, PVC / ABS, PVC / MBS, PC / ABS, PBTP / ABS, PC / ASA, PC / PBT, PV C / CPE, PVC / acrylate, POM / thermoplastic PUR, PC / thermoplastic PUR, POM / acrylate, P OM / M BS, PPO / HIPS, PP0 / PA6 · 6 and copolymer, PA / HDPE, PA / PP, PA / PPO, PBT / PC / ABS or PBT / PET / PC. 66 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -------- Order --------- (Please read the precautions on the back before filling this page ) 1226897 A7 ____B7 ...___ Five, say the month and month (b ^) X j 9 · Naturally occurring and synthetic organic substances' It is a pure monomeric compound or a mixture of these compounds, for example, mineral oil, animal and Vegetable fats, or synthetic ester-based oils and waxes (such as tt esters, adipates, phosphates, or trimellitates), and mixtures of synthetic esters and mineral oils in any weight ratio, typically It is used in textile compositions' and aqueous emulsions of these substances. 30. Aqueous emulsions of natural or synthetic rubbers, such as natural rubber latexes or latexes of carboxylated styrene / butadiene copolymers. Therefore, the present invention also relates to a composition including a pair of organic substances that are sensitive to degradation due to light, heat, or oxidation, and the aforementioned stabilizer mixture. Another embodiment of the present invention relates to a method for stabilizing an organic substance against degradation caused by light, heat, or oxidation, including adding λ to the organic substance as the stabilizer mixture described above. The organic substance is preferably a synthetic polymer, especially the aforementioned substances. Polyolefins are preferred, and particularly preferred are polyethylene, polypropylene, polyethylene copolymers and polypropylene copolymers. The ingredients (A) and (B) may be added to the organic substance separately or mixed with each other before adding. The amount of each of the components (A) and (B) in the organic substance is preferably from 0.005 to 5%, especially from 0.001 to 1% or 0.05 to 1% (relative to Depending on the weight of organic matter). The weight ratio of the component (Α) :( Β) is preferably 10: 1 to 1: 100, especially 10: 1 to 1:10 or 5: 1 to 1: 5. Other weight ratio 67 This paper size is applicable to China National Standard (CNS) A4 (210 X 297 male 1) -------------------- Order ------ --- (Please read the notes on the back before filling this page) 1226897

5. Examples of the invention description (to) are 1: 1 to 1:10, such as 1: 2 to i: 5. The weight ratio of the two components forming the component (B) is, for example, 1: 10 to 10: 1 or 1: 5 to 5: 1, preferably 丨: 2 to 2: i, especially 1 ^ 1 ° Conventional methods are added to the organic substance, for example, before or during molding, or a dissolved or dispersed compound is added to the organic substance, and if necessary, the solvent may be evaporated next. These ingredients can be added to organic matter in the form of powders, granules, precursors containing these ingredients (for example, concentrations ranging from 2.5 to 25% by weight). If necessary, the compounds of ingredients (A) and (b) can be mixed with each other before being added to the organic substance, which can be added to the polymer before the polymer is polymerized, during the polymerization, or before the crosslinking. The organic substance stabilized in the present invention can be applied in various types, such as a film, a fiber, a ribbon, a molding composition, a contour, or an adhesive used as a coating, an adhesive, or an adhesive. The stabilized material may additionally include various conventional additives, such as ... 1. Anti-argonizing agent! __ · 1 Monolated monophenol, for example, 2,6-di-tert-butyl-4 monomethylphenol, 2- Butyl-4,6-dimethylphenol, 2,6-di-tert-butyl-4-4-n-butylphenol, 2,6-di-tert-butyl-4 4-ethylfluorene '2' 6-t-tert-butyl-4 iso-isofluorene, 2,6-dicyclopentyl-4-methyl, 2- (α-methylcyclohexyl) ~ 4,6-dimethylfluorene ， 2,6- 218 radixyl-4-methyl hydrazone, 2,4,6-tricyclohexyl phenol, 2,6-di-tert-butyl-1 4 68 This paper is applicable to Chinese national standards ( CNS) A4 size (210 X 297 mm) -------------------- Order --------- (Please read the precautions on the back first (Fill in this page) 1226897 A7 ^ _ B7____ 5. Description of the invention (W) —methoxymethylphenol, 2,6-di-nonyl-4 4-methylphenol, 2 '4-dimethyl-2 — — ( 1,1-methyl i ^ -alkane-l-yl) phenol, 2,4-dimethyl- 6- (I9-methylheptadecan-l-yl) phenol, 2,4-di-methyl- 6— (1, Monomethyltridecane-1,1-yl) phenol and mixtures thereof. 1 · 2 · Alkylthio, some cresol, for example, 2,4-dioctylthiomethyl-6-tert-butylphenol, 2,4-dioctylthiomethyl-6-methylphenol '2 , 4-dioctylthiomethyl-6-ethylphenol, 2,6-dodecanylthiomethyl 4-nonylphenol. 1 · 3 · Hydroquinone and its alkylated hydroquinones, such as 2,6-di-tert-butyl-4-methoxyphenol, 2,5-di-tert-butyl-p-benzene Diphenol, 2,5-di-tert-pentylhydroquinone, 2,6-di-diphenyl-4-octadecanoic acid, 2, β-di-tert-butylhydroquinone , 2,5-Di-tert-butyl-4-hydroxyanisole, 3,5-Di-tert-butyl-4-hydroxyanisole, 3,5-Di-tert-butyl-4-hydroxyanisole Base stearate, bis (3,5-di-tert-butyl-4-hydroxyphenyl) adipate. 1 · 4 · tocopherols, for example, α-tocopherol, hydrazone-tocopherol, r-tocopherol, (5-tocopherol and mixtures thereof (vitamin 15) ° 1 · 5 · hydroxysulphur diphenyl ether , For example, 2,2′-thiobis (6-tert-butyl-4-methylphenol), 2,2, -thiobis (4-octylphenol), 4,4, monothiobis (Θ- Tert-butyl-3-methylphenol), 4,4, -thiobis (δ-tert-2-methylphenol), 4,4, monothiobis (3,6-di-sec-pentylphenol) ), 4, 4 'pair (2, 6 69 -------- Order --------- (Please read the notes on the back before filling out this page) This paper size applies to China Standard (CNS) A4 specification (210 X 297 mm) 1226897 A7 _B7___ V. Description of the invention (i) Monodimethyl-4 monohydroxyphenyl) disulfide. 1 · 6 · Alkylene bisphenol, for example, 2 , 2'-Methylenebis (6-tert-butyl-4-methylphenol), 2,2, -methylbis (6-tert-butyl-4-ethylphenol), 2,2 'a Methylenebis [4-methyl-6- (α-methylcyclohexyl) phenol], 2,2'-methylenebis (4-methyl-6-cyclohexyl) Phenol), 2,2'-methylenebis (6-nonyl-4-methylphenol), 2,2'-methylenebis (4,6-di-tert-butylphenol), 2,2 ' —Ethylene bis (4,6-di-tert-butylphenol), 2,2 'one ethylidene bis (6—tert-butyl-4—isobutylphenol), 2,2' one methylidene bis [6- (α-methylbenzyl) -4-nonylphenol], 2,2'-methylenebis [6- (α, α-dimethylbenzyl) -4-nonylfluorene], 4 , 4 'monomethylbis (2,6-di-tert-butylphenol), 4,4' monomethylbis (6-tert-butyl-2-methylphenol), 1,1 mono ( 5-tert-butyl-1, 4-hydroxy-2, methylphenyl) butane, 2,6-bis (3-tert-butyl-5, methyl-2, 2-hydroxybenzyl), 4-methyl Phenol, 1,1,3-tris (5-tert-butyl-1,4-hydroxy-2-methylphenyl) butane, 1,1, bis (5-tert-butyl-1,4-meryl-2) —Methylphenyl)-3 -η —dodecylhydrothiobutane, ethylene diether bis [3,3-bis (3'-tert-butyl-4'-hydroxyphenyl) butyrate Benzene 4-Cyclo-5-methyl-phenyl) dicyclopentanyl, bis [2- (3'-tert-butyl-2'-hydroxy-5'-methylbenzyl) -6-tert-butyl One 4-methylphenyl) terephthalate, 1,1-bis (3,5-dimethyl-2-hydroxyphenyl) butane, 2,2-bis- (3 70 This paper size applies China National Standard (CNS) A4 Specification (210 X 297 mm) -------- Order --------- (Please read the notes on the back before filling this page) 1226897 A7 ___B7_ 5 Description of the invention (d), 5-di-tert-butyl-4-hydroxyphenyl) propane, 2,2-bis- (5-tert-butyl-4-hydroxy-2-methylphenyl)- 4-n-dodecylhydrothiobutane 5 1,1 9 5,5 -tetra- (5-tert-butyl-4 amenthyl 2-methylphenyl) pentanyl. 1 · 7 8〇 一 · Ν—and S—benzyl metabolites, such as 3,5,3 '9 59 —tetra-t-butyl-4,4' diacryl-diphenylmethyl ether , Octadecyl-1, 4-hydroxy-1, 3,5-dimethylbenzyl hydrothioacetate, tris- (3,5-di-tert-butyl-1, 4-hydroxybenzyl) amine, Bis (4-tert-butyl-3-hydroxy-2,6-dimethylbenzyl) dithio-peptide, bis (3,5-di-tert-butyl-4-hydroxybenzene (Methyl) sulfide, isooctyl-3,5-di-tert-butyl-4 4-hydroxybenzyl hydrothioacetate. 1 · 8 · Methylbenzyl malonate, such as di-octadecyl- 2,2-bis- (3 '5-di-tert-butyl-2-hydroxybenzyl)- Malonate, dioctadecyl- 2-(3 -tert-butyl-4 -hydroxy-5 -methylbenzyl) monomalonate, dodecyl hydrothioethyl -2,2-bis- (3,5-di-tert-butyl-4-hydroxybenzyl) malonate, bis- [4-((1,1,3,3-tetramethylbutyl) Phenyl) phenyl] -2,2-bis (3,5-di-tert-butyl-4 4-hydroxybenzyl) malonate. 1 · 9 · Aromatic hydroxybenzyl compounds • For example 1,3,5-trione (3,5-di-tert-butyl-4 4-hydroxybenzyl) -2,4,6-trimethyl Phenylbenzene, 1,4 bis (3,5-di-tert-butyl-4-hydroxybenzyl) -2,3,5,6-tetramethylbenzene, 2,4, 71 ---- ---------------- ^ --------- ^ 9. (Please read the precautions on the back before filling this page) This paper size applies Chinese national standards ( CNS) A4 specification (210 X 297 mm) ^ 226897 A7, ___B7 t, description of the invention (0) 6 ~ tri- (3,5-di-tert-butyl-4 monohydroxybenzyl) acid 0 (please Read the notes on the back before filling out this page) 1 ^ 1 0. Triazine compounds, such as 2,4-bis (octylhydrothio) -6- (3,5-di-tert-butyl-4 4-hydroxyaniline)-1 '3,5-triazine, 2- Octylhydrosulfanyl-4,6-bis (3,5 ~ di-tert-butyl-4 4-hydroxy-aniline) -1,3,5-triazine, 2-octylhydrothio-4, 6-bis (3,5-di-tert-butyl ~ 4-hydroxyphenoxy) -1,3,5-triazine, 2,4,6 ~ tris (3,5-di-tert-butyl) Mono-4-hydroxyphenoxy) -1,2,3-triazine, 1,3,5-tri- (3,5-di-tert-butyl ~ 4 monohydroxybenzyl) isocyanurate , 1,3,5-tris (4-tert-butyl-3-hydroxy-2,6-di-methylbenzyl) isocyanurate, 2,4,6-tris (3,5 -Di-tert-butyl-4 4-hydroxyphenylethyl) -1,3,5-triazine, 1,3,5-tri- (3,5-di-tert-butyl-4 4-hydroxybenzene Propyl hydrazone) hexahydro-1,3,5-triazine, 1,3,5-trione (3,5-dicyclohexyl-4 4-hydroxybenzyl) isocyanurate. "·· 1 1 · A benzyl phosphonate, for example, dimethyl-2,5-di-tert-butyl-1, 4-hydroxybenzyl phosphonate, diethyl-3,5-dione Tert-Butyl-4 monohydroxybenzyl phosphonate, octacosyl 3,5 tert-butyl-tert-butyl-4 monohydroxy benzyl phosphonate, octacosyl 5-tert- Calcium salt of monobutyl mono 4-hydroxy 3-methylbenzyl-phosphonate, monoethyl ester of 3, 5-di-tert-butyl 4- 4-hydroxybenzyl monophosphonic acid. 72 This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 1226897 A7 ____B7__ V. Description of the invention (factory) 丄 · 1 2 · 醯 棊 Huangji acid 1, such as' 4 ~ hydroxy 醯 laurate Tetanil 5 4 -Tyranilide stearic acid, octyl ~] NyJ — (3, g —di-tert-butyl-4 monohydroxyphenyl) carbamate. j. 1 3 a 5 -Di- 4 -Hydroxybenzene) Ester of propane and mono- or polyhydric alcohol 9 such as with methanol, ethanol, stearyl alcohol, 1,6-hexanediol, 1, 9 Monononanediol, ethylene glycol, 1,2-propanediol, neopentyl glycol, thiodiethylene glycol, diethylene glycol 'diethylene-'pentaerythritol' Η ~ (Ethyl ethyl) Isocyanurate, N, N 'bis (hydroxyethyl) ethylenediamine diamine, 3-n-undecanol, 3-thiopentadecanol, trimethylhexanediol, trimethyl Alcohol propane, 4 monohydroxymethyl-1 monophosphoryl 2,6,7-trioxabicyclo [2 • 2 · 2] octane. 1 · 1 4 · Esters of mono- (5-tert-butyldi-4-hydroxy-1, 3-methylbenzene) propionic acid and mono- or polyhydric alcohols, such as, and methanol, ethanol, stearyl alcohol , 1,6-hexanediol, 1,9-nonane-diol, ethylene glycol, 1,2-propanediol, neopentyl glycol, thiodiethylene glycol, diethylene glycol, Triethylene glycol, pentaerythritol, tris (hydroxyethyl) isoamyluric acid vinegar 'Ν, N -bis (tris (ethylethyl)) ethane-brown-1 ^ female' 3 -thiaundecanol, 3 -thiadeca Pentadecanol, trimethylhexanediol, trimethylolpropane, 4 monohydroxymethyl-1 monophosphoryl 2,6,7-trioxabicyclo [2 · 2 · 2] octane. 1 · 1 Fi · θ — (3, Fi —Bicyclic fluorene, a 4-monohydroxyphenyl) propionate and a mono- or polyhydric alcohol ester, such as with methanol, ethanol, stearyl alcohol, 1, 6 — Hexanediol, 1,9-nonanediol, ethylene glycol, 1, 73 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -------- Order- -------- (Please read the notes on the back before filling this page) 1226897 A7 _B7___ V. Description of the invention (M) (Please read the notes on the back before filling this page) 2-Propanediol, Neopentyl glycol, thiodiethylene glycol 5 diethylene glycol, triethylene glycol, pentaerythritol, tri- (hydroxyethyl) isocyanurate, N, N'-bis (hydroxyethyl) ethyl Diamine diamine, 3-thiaundecanol 9 3-thiapentadecanol, trimethylhexanediol, trimethylolpropane, 4-monomethylol-1 monophosphoryl-2, 6, 7-trioxabicyclo [2 · 2 · 2] octane. 1 · 1 6 · 3,5 -di-tert- ·· Dingmou—4—Hydroxybenzyl acetate and mono- or polyhydric alcohol esters, such as with methanol, ethanol, stearyl alcohol, 1, 6-hexane Diols, 1,9 monononanediol, ethylene glycol, 1,2-propanediol, neopentyl glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol, pentaerythritol, triethylene glycol Mono (hydroxyethyl) isocyanurate, Ν, Ν '-bis (hydroxymonoethyl) ethylenediaminediamine, 3-undecyl alcohol, 3-thiapentadecanyl alcohol, trimethylhexanoate Alkanediol, trimethyl alcohol propane, 4 monohydroxymethyl-1 monophospho-2,6,7-trioxabicyclo [2 · 2 • 2] octane. 1 · 1 7 · Shiamine (3,5-di-tert-butyl-4-hydroxy-phenyl) propionic acid ammonium, such as N, N, a bis (3,5-di-tert-butyl) 4-Amino-1,4-hydroxyphenylpropylammonium) hexamethylene diamine, Ν, Ν '-Bis (3,5-di-tert-butyl-4-4-hydroxyphenylpropylammonium) trimethylenediamine, NH, N' —Bis (3,5 — — * —tert-butyl-4 monomene—phenylpropionamidine) hydrazine, Ν, Ν ^ —bis [2 — (3 — [3,5-di-tert-butyl-1 4 Monohydroxyphenyl] propanyloxy) ethyl] oxamine (Naugard ® XL-1, supplied by Uniroyal) 〇 1 · 1 8 · Ascorbic acid (Vitamin C) 74 This paper applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1226897 A7 _ —__ B7 _ 15. Description of the invention (#) 1,19 • Amine antioxidant, for example, N, N ^ —diisopropyl-P-phenylene di Amine, N, N, 1,2 sec-butyl-p-phenylene diamine, N, N — -bis (1,4-dimethylpentyl) —p —phenylene diamine, N, N — -Bis (1-ethyl-3-methylpentyl) -P-phenylenediamine, N, N > -bis 1-methylheptyl) -p-phenylene diamine, N, N > -dicyclohexyl-p-phenylene diamine, n, N ^ -diphenyl-p-phenylene diamine, N, N ——bis (2-naphthyl) -P-phenylenediamine, N-isopropyl-N > -phenyl-p-phenylenediamine, N- (1,3-dimethylbutyl) ) -N / -phenyl-p-phenylenediamine, N- (1-methylheptyl) -N > -phenyl-p-phenylenediamine, N-cyclohexyl-N > -benzene -P-phenylene diamine, 4-((P-toluenesulfonyl) -diphenylamine, N, N > -dimethyl-N, -di-sec-butyl-P-phenylenediamine, Diphenylamine, N-allyldiphenylamine, 4-isopropoxydiphenylamine, N-phenyl-1, naphthylamine 'N- (4-tert-octylphenyl) -1 —Czechylamine, N—phenyl—2-naphthylamine ’octylated monophenylamine, such as p ′ ρ − —tertiary monooctyl monophenylamine, 4-n-butylamine Phenol, 4-monobutylaminoamino phenol '4-monononylaminophenol, 4-dodecylaminophenol, 4 octamethylaminophenol' bis (4-methoxyphenyl) amine, 2,6-di-tert-butyl-4-dimethylaminomethylphenol, 2,4 / di-diaminodiphenylmethane '4,4,4-diaminodiphenylmethane, N , Ν, Ν >, Ν / —tetramethyl-4,4 / —diaminodiphenylmethane, 1,2—bis [(2-methylphenyl) amino] ethane, 1,2 -Bis (phenylamino) propane, (0-tolyl) biguanide, bis [4- (1 >, 3 > -dimethyl 75) This paper is sized to the Chinese National Standard (CNS) A4 specifications ( 210 X 297 mm) -------- Order --------- (Please read the notes on the back before filling out this page) 1226897 A7 B7 ____ 5. Description of the invention (Bamboo) Butyl ) Phenyl] amine, tertiary mono-octyl N-phenyl-1-naphthylamine, mono- and dialkylated tert-butyl / tert-octyl diphenylamine mixtures, mono- and Dialkylated nonyldiphenylamine mixtures, mono- and dialkylated dodecyldiphenylamine mixtures, mono- and dialkylated isopropyl / isohexyldiphenylamine mixtures , Mono- and dialkylated tert-butyldiphenylamine mixtures, 2,3-dihydro-3,3-dimethyl 4H — 1,4-benzothiazine, phenothiazine, single and dialkylated tert-butyl / tert-octylphenothiazine mixture, mono- and dialkylated tert-octylphene Thiazine mixture, N-allylphenothiazine, N, N, N —, N / — tetraphenyl-1,4-diaminobutane-2-ene, N, N—bis (2, 2, 6,6-tetramethyl-pyridine-4-yl-hexamethylenediamine, bis (2,2,6,6-tetramethylneado-4-yl) sebacate, 2, 2, 6 , 6-tetramethyl-neo-co-4-tetramethyl, 2,2,6,6-tetramethyl-coe-co-4-cohol. 2 · UV absorber and light stabilizer 2 · 1 · 2-(2 via phenyl) benzotriazole, for example, 2-(2 'trivalent radical-5' -methylphenyl) -benzotriazolyl , 2- (3 ', 5'-di-tert-butyl-2'-transylphenyl) benzotriyl, 2- (5, -tert-butyl-2'-hydroxyphenyl) benzene Pyridyl, 2- (2,1-hydroxy · -5 '-(l, l, 3,3-tetramethylbutyl) phenyl) benzo-triazolyl, 2- (3,, 5, 12-tert-butyl-2, monohydroxyphenyl) -5-chloro-benzotriazolyl, 2- (3,1-tert-butyl-1 2-transyl group ~ 5 'monomethylphenyl ) 1-Chloro-benzotriazolyl, 2-(3, -sec-butyl-5, 76 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ---- ---------------- Order --------- (Please read the notes on the back before filling this page) 1226897 A7 B7 ----- One by one_ __ V. Description of the invention (%) Mono-tert-butyl- 2′-hydroxyphenyl) benzotriazolyl, 2 ~ (2, trimethyl- 4′-halfoxyphenyl) benzodiazyl'2 -(3,, 5, one-di-tert-pentyl-2, -hydroxyphenyl) benzotrifluorene, 2 one (3,, 5 'one double one (0 :, "-dimethylbenzyl Group) ~ 2, monohydroxyphenyl) benzotriazolyl, 2-(39-tert-butyl-mesityl-5 '-(2-octyloxyfluorenylethyl) benzyl) ~ 5 -chloro Monobenzotrifluorenyl, 2- (3'-tert-butyl-5 '~ [2-((2-ethylhexyloxy) -ethyl]-2'-hydroxyphenyl) chloro-benzo-benzo Triazolyl, 2- (3, t-tert-butyl-2 '~ Cyclo-5'-(2-methoxycurylethyl) phenyl) -5-fluorenated monobenzotriazolyl, 2-(3, -tert-butyl-2'-hydroxy ~ 5,-(2-methoxycarbonylethyl) phenyl) benzotriazolyl, 2 ~ (3, -tert-butyl-2 , -Hydroxy-5, mono (2-octyl monooxycarbonylethyl) phenyl) benzotriazolyl, 2- (3'-tert-butyl ~ 5, _ [2- (2-ethylhexyl (Oxy) chinoethyl] -2′-monophenylphenyl) benzotriazolyl, 2- (3′-dodecyl-2′-hydroxy-5, monomethylphenyl) benzo A trisoxy group, and 2- (3'-tert-butyl- 2'-hydroxy-5 '-(2-isooctyloxycarbonylethyl) phenylbenzotriazolyl 2,2'-methylene A mixture of [4- (1,1,3,3-tetramethylbutyl) -6-benzotriazolyl-2-ylphenol]; 2- [3'-tert-butyl-5 ' — (2-methoxycarbonylethyl)-2′-hydroxy-phenyl]-2H-benzotriazolyl and an esterification product of polyethylene glycol 300, [R — CH2CH2 — C〇〇 (CH2) 3] 2 —where r = 3, —tert-butyl—4, —hydroxyl_5, — — 77 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ------ -^ --------- (Please read the notes on the back before filling out this page) 1226897 A7 ____B7___ 5. Description of the invention (<) Benzotriazolyl 2- 2-phenylphenyl, 2 — [2 > -Hydroxy-3-(α, α -dimethylbenzyl) -5 -1 (1,1,3,3-tetramethylbutyl) -benzyl] benzodifluorene; 2-[2 -Cyto3-(1,1,3,3-tetramethylbutyl) -5 >-(α, α -dimethylbenzyl) -benzene Group] benzotriazole. _ £ · 2 · 2-Hydroxybenzophenone, for example, 4-monohydroxy, 4-methoxy, 4-octyloxy, 4-decyloxy, 4-dodecyloxy, 4-benzyl Oxy, 4,2 ', 4'_trihydroxy and 2'-hydroxy-4,4'-dimethoxy derivatives. 2 · 3 · Ester of substituted or unsubstituted benzoic acid, such as 4-tert-butyl-phenylsalicylate, phenylsalicylate, octylphenylsalicylate, benzoylhydrazone Resorcinol, Bis (4-tert-butylbenzylhydrazone), Resorcinol, Benzobenzylresorcinol, 2,4-Di-tert-butylphenyl 3,5-di-tert-butyl Amino 4-hydroxybenzoate, cetyl 3,5-di-tert-butyl-4-octadecyl 3,5-di-tert-butyl- 4- Hydroxybenzoate, 2-methyl-4,6-di-tert-butylphenyl 3,5-di-tert-butyl-4, hydroxy-benzoate 0 2 · 4 · aromatic ester , Such as ethyl α-cyano-mono-, di-diphenyl acrylate, isooctyl α-cyano- / 5, A-di-phenyl acrylate, methyl α-carbomethoxycinnamate , Methyl ^ monocyano-5, / 3-methyl-p-methoxy-cinnamate, butyl α-cyano / 3, in case of methyl-P-methoxy-cinnamate , Methylα-carbomethoxy-P-methoxycinnamate and N-carbomethoxy-Θ-cyanoethyl Alkenyl) -78 This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) -------- ^ --------- (Please read the precautions on the back first (Fill in this page again) 1226897 A7 ____ B7___ V. Description of the invention (bucket) 2—Methylindole. • 5 • Nickel compounds • For example 2, 2 9 —Thio-bis— [4 -— (1,1 $ 3,3-tetra-methylbutyl) phenol] nickel complex, such as 1: 1 or 1 : 2 complexes with or without additional reactive groups, such as η-butylamine, triethanolamine or η-cyclohexyldiethanolamine, nickel dibutyldithiothiocarbamate '4 '5-Di-tert-butyl benzylphosphonic acid nickel salts of monoalkyl esters, such as methyl or ethyl esters, nickel complexes of ketoxime, such as 2-hydroxy-4 methylmethyl ^^ Monoalkyl ketoxime, a nickel complex of 1-phenyl-4-lauryl-5-hydroxypyrazolyl, with or without additional reactive groups. 2 · ft · Ethylenediamine diamine, for example 4,4'-dioctyloxyoxopanidine, 2,2 '-dioctyloxy-5,5'-di-tert-butoxy-amidine Tefaniline, 2,2'-docosadecyloxy-5,5, -di-tert-butoxypanetilanilide, 2-ethoxy- 2'-ethoxytetrabanilide, N, N ' A bis (3-dimethylaminopropyl) ethylenediamine diamine, 2 monoethoxy-5 tert-butyl-1 2'-ethoxyfluorenil and its 2 ethoxy-2, A mixture of monoethyl-5,4,1,2-tert-butoxyanilide, and a mixture of o- and m-methoxydisubstituted oxotetanil, and 0- and P-ethoxy -Disubstituted oxotetanil. 2 ^ 7 · 2 — (-Hydroxybenzene) -1,3 · 5-triazine, such as 2,4,6-trione (2-hydroxy-4 -octyloxy-phenyl) -1, 3,5-triazine, 2- (2-hydroxy-4-octyloxyphenyl) ~ 4,6-bis (2,4-dimethylphenyl) -1,3,5-triazine, 2 — (2,4 dihydroxyphenyl) — 4,6 —bis (2 79 This paper is in accordance with the national standard (CNS) A4 specification (21〇χ 297 issued 1 ---------- ---------- Order --------- (Please read the notes on the back before filling out this page) A7 1226897 _B7___ V. Description of the invention 〇Ί), 4-dimethylbenzene Yl) -1,3,5-triazine, 2,4-bis (2-Cyclo-4-propyloxyphenyl) -6- (2'4-monomethylphenyl) -1,3 , 5—triamidine, 2— (2-Cyclo-4—octyloxyphenyl) —4,6—bis (4-methylphenyl) —1,3,5—triazine, 2— ( 2-hydroxy-4-dodecyl monooxyphenyl) -4,6-bis (2,4-dimethylphenyl) -1,3,5-triazine, 2- [2-hydroxy- 4 mono (2hydroxy-3 -butyloxy-propoxy) Radical] -4,6—bis (2,4-dimethyl) -1,3 ′ 5—three exposures, 2- [2-radical-4— (2-radyl-3—octyloxy— Propyloxy) phenyl] -4,6-bis (2,4-dimethyl) -1,3,5-triazine, 2- [4- (dodecyloxy / tridecyloxy) —2 —Cyclopropoxy) —2—Cyclo-phenyl] —4,6—bis (2,4-dimethylphenyl) —1,3,5-triazine, 2— [2- Hydroxy-4— (2-hydroxy-1,3-dodecyloxy-propoxy) phenyl] -1,4,6-bis (2,4-dimethylphenyl) -1,3,5-triazine ， 2 — (2 —hydroxy-4 —hexyloxy) phenyl —4, 6 —diphenyl —1,3,5 —triazine, 2 — (2 —hydroxy-4 —methoxyphenyl) — 4,6-diphenyl-1,3,5-triazine, 2,4,6-di [2-Cyclo-4- (3-butoxy-2—Cyclo-propoxy) phenyl ] 1,3,5-triazine, 2- (2-hydroxyphenyl) -4- (4-methoxyphenyl) -6-phenyl-1 '3, 5-triazine, 2 — { 2 —hydroxy-4 — [3 — (2-ethylhexyl 1-oxy) - 2 - hydroxypropoxy] phenyl} a 4,6 - bis (2,4-dimethylphenyl) -1,3,5-triazine. 80 -------- Order --------- (Please read the precautions on the back before filling this page) This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) ) 1226897 A7 ________B7_____ 5. Description of the invention (redundant) i .: Metal deactivating agent, such as N, N'-diphenylethylenediaminediamine, Ν-salicyl-N'-salicylhydrazine, Ν, Ν , A bis (salicyl) hydrazine, Ν, Ν, -bis (3,5 -di-tert-butyl-4-hydroxyphenyl-propanthion) hydrazine, 3 -salicylamino-1,2,4- Triazole, bis (benzylidene) ethanedihydrazine, hydrazine, hydrazidine, isophthalamidine, dihydrazine, sebacamide, bisphenylhydrazine, Ν, Ν, bis —Ethyl hexamethylene dihydrazide, N, N 'one bis (salicyl) hydrazine, N, N'—bis (salicyl) monothiopropanyl dihydrazine. Li_: phosphites and phosphonates · such as triphenylphosphite, diphenylalkylphosphite, phenyldialkylphosphite, tri- (nonylphenyl) phosphite, tri Lauryl phosphite, tris-octadecyl phosphite, distearyl pentaerythritol diphosphite, tris (2,4-di-tert-butylphenyl) phosphite, diisodecyl Pentaerythritol diphosphite, bis (2,4-di-tert-butylphenyl) pentaerythritol diphosphite, bis (2,6-di-tert-butyl-4-methylphenyl) pentaerythritol di Phosphite, diisodecyloxy pentaerythritol diphosphite, bis (2 '4-di-tert-butyl-6-methylphenyl) pentaerythritol diphosphite, bis (2,4,6- Trinity (tert-butylphenyl) pentaerythritol diphosphite, tristearyl sorbitol triphosphite, four (2 '4 twelve-tert-butylphenyl) 4, 4, biphenyl Bisphosphonate, 6-isooctyloxy-2,4,8,1 0-tetra-tert-butyl- 12Η-diphenyl [d, g] -1,3,2-dioxolidine, 6-Fluoro-2 '4 8,10-tetra-tert-butyl-12-methyl-one [Hex, g 81 -------- ^ --------- (Please read the precautions on the back before (Fill in this page) The size of this paper is applicable to the Chinese National Standard (CNS) A4 (210 X 297 mm) 1226897 A7 ------- B7___ V. Description of the Invention (called) 〔1,3,2-Dioxin Iphosin, bis (2,4-di-tert-butyl-6-methylphenyl) methyl phosphite, bis (2,4-di-tert-butyl-6-methylphenyl) Ethylphosphite, 2, 2 /, 2 x 1-nitroazine [triethyl di (3, 3 >, 5 5 5 tetra-tert-butyl-1, 1 > mono-biphenyl-2, 2 > -diyl) phosphite], 2 monoethylhexyl (3,3 >, 5,5 mono-tetra-t-butyl-1, 1 > monobiphenyl-2,2 di ) Phosphite, 5-butyl-5-ethyl-2- (2, 4, 6-tri-tert-butylphenoxy) -1,3,2-dioxaphosphorane. Particularly preferred Are the following phosphites: tris (2,4-di-tert-butylphenyl) phosphite (Irgafos ® 168, Ciba-Geigy), tris (nonylphenyl) phosphite,

C (CH3) 3/3 (ch3) 3c ^^ c (ch3) 3 pc '

(A) H3C-C \ H / P —F

(V / ^ / ^ C (CH3) 3 (ch3) 3c (ch3) 3c

P ——〇——CH2CH (C4H9) CH2CH3 (Please read the precautions on the back before filling out this page) (ch3) 3c (C) c (ch3) 3 82 This paper size applies to China National Standard (CNS) A4 specifications 210 X 297 mm) 1226897 A7 B7 V. Description of the invention (β (ch3) 3c

⑼ (ch3) 3c

CH, P_ 0_C18H37 (E) (F) H37ClT-〇 —P,

DO CH 3 h3c—9—ch3

(Please read the notes on the back before filling this page) h3c P — 〇CH2CH3 (G) 5 • Leg amines, for example, N, N —dibenzylhydroxylamine derived from hydrogenated tallowamine, N, N —diethyl Hydroxylamine, N, N-dioctylhydroxylamine, N'N-dilaurylhydroxylamine, n, N-di (tetradecyl) hydroxylamine, N, N-di (hexadecyl) hydroxyl Amine, N, N — two (eighteen "carboxyl) succinylamine, N-sixteen yuan radical-N-eighteen yuan radical Amine 'N-seventeen yuan radical-N-eighteen yuan radical Amine, N, N—a radical based amine. 6. Nitrones, for example, N-benzyl-α-phenyl-nitronone derived from hydrogenated tallowamine, N-ethyl-α-methyl-nitronone, N-octyl-α-83 Applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 1226897 A7 —__— Β7 ^ _ 5. Description of the invention (Si) Heptyl-nitronone 5 N -Lauryl ~ α-undecyl mononitrate Ketone 5 N _tetradecyl-α-tridecyl mononitrone, N-hexadecyl-α-pentadecyl mononitrone, N-octadecyl ~ α heptadecyl-1 Nitrone, N-hexadecyl-α-heptadecyl ~ nitronone, N-octadecyl-pentadecyl-nitrone, N-heptadecyl-α-heptadecyl-nitrate Ketones, N 18 ^ Ukiyl-ten /, _ Wu Ji ~ nitrone, Ν, Ν-diamino hydroxylamine nitrone. Thio .. Basket agents, such as ' dilaurylthiodipropionate or distearylthiopropionate. Wan_1 peroxy northern substance ', such as esters of / 3-thiodipropionic acid, such as lauryl, stearyl, tetradecyl or tridecyl ester, hydrothiobenzimidazole or Zinc salt of 2-hydrothiobenzimidazole, zinc dibutyl dithiocarbamate, di (octadecyl) disulfide, pentaerythritol four (0-dodecyl hydrothio) propionate. Ugly dimeric amine stabilizers, such as copper salts combined with iodide and / or phosphorus compounds, and salts of divalent manganese. Stabilizers such as melamine, polyvinylpyrrolidone, dicyandiamide, tri-allyl cyanurate, urea derivatives, hydrazine derivatives, amines, polyamides, polyurea Alkanes, higher fatty acid alkali or alkaline earth metal salts, for example, calcium stearate, zinc stearate, magnesium adipate, magnesium stearate, sodium ricinole and potassium hexadecanoate, pyrocatechin Antimony or zinc pyrocatechuate.丄 · M acid agents, for example, inorganic substances, like talc, metal oxides, magnesium oxide, phosphates, carbonates, or sulfates like titanium dioxide or preferably alkaline earth metals; organic compounds, such as mono- or polycarboxylic acids and Its salts, for example, 84 paper sizes are applicable to the Chinese National Standard (CNS) A4 specifications (21G X 297 male f 'a -------- order --------- (please read the back first Please note this page and fill in this page again) 1226897 A7 —______ B7___ V. Description of the invention (P) 4 Mono-tert-butylbenzyl, adipic acid, diphenylacetic acid, sodium succinate, or sodium benzoate; polymer compounds , Like ionic copolymers (ionomers). Particularly preferred is 1,2: 4-bis (3 ', 4'-dimethylbenzylidene) sorbitol, 1,3: 2, 4-bis (p-methyldiphenylidene) sorbitol, and 1,3: 2, 4-bis (benzylidene) sorbitol. 1 2 • Filling and reinforcing agents, for example, calcium carbonate, silicon Acid salt, glass fiber, asbestos, talc, high-sensitivity clay, mica, barium sulfate, metal oxides and hydroxides, carbon black, graphite, wood powder and other natural Product powder or fiber, synthetic fiber. 1 3 · Other additives, such as plasticizers, lubricants, emulsifiers, colorants, flow additives, catalysts, flow control agents, optical brighteners, fire retardants, antistatic Agents and blowing agents. 1 4 • Benzorones and fluorenes, such as those described in still-eight-4,325,863; US-A-4,338,244, US-A-5,175,313; US- A- 5,216,052, US-A-5,252,643, DE-A-4,316,611; DE-A- 4,316,622; DE-A-4,316,876; EP-A-0,589,839 or EP-A- 0,591,102 or 3 — [4 — (2 — Acetyloxyethoxy) phenyl] -5,7-di-tert-butyl-benzofuran-2-one, 5,7-di-tert-butyl-3- [4- (2-hard Aliphatic ethoxyethoxy) phenyl] benzofuran-2-one, 3,3 ^ -bis [5, 7-di-tert-butyl- 3-(4-[2 -hydroxyethoxy] Phenyl) benzofuran-2-one], 5,7-di-tert-butyl-3- (4-ethoxyphenyl) benzofuran-2-one, 3- (4-ethylacetoxy) —3,5- 二 85 This paper standard applies to China National Standard (CNS) A4 (210 X 297 mm) -------- ^ --------- ^ 9— (Please read the notes on the back before filling out this page) 1226897 A7 ________B7_ V. Description of the Invention ) Methylbenzyl) 5 ′ 7-di-tert-butyl-benzopyran- 2′-fluorene ′ 3 — (3 ′ 5 ——methyl-4—dimethylethyloxy) -5, 7-di-tert-butyl-benzofuran-2-one, 3- (3,4-dimethylphenyl) -5,7-di-tert-butylbenzofuran 2-one 5 3 — (2,3-Dimethylphenyl) -5,7-di-tert-butyl-benzofuran-2-one. The ratio of the total weight of ingredients (A) and (B) to the weight of conventional additives is, for example, 100: 1 to 1: 100 or 10: 1 to 1:10. The following examples will illustrate the invention in more detail. All percentages and parts are by weight unless otherwise specified. (Please read the precautions on the back before filling out this page.) Light sample agents for Examples 1 and 2: XINUVTN 622 ^ ΤΜΛ

Mixture (A-2V compound (A-2-a) and (A-2-b), 4: 1 weight ratio

86 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 1226897 A7 B7 V. Description of the invention (

〇-

h3c ch3

TTNIJVIN 770 (; RTMV

〇 II

〇 II 〇a c— (CH2) 8—c—o

(A-2-b) -------------------- Order --------- (Please read the notes on the back before filling this page)

TTNTJVTN 765 iRTMV

TTNIJVIN 123 TRTMV 87 This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 1226897 A7 B7 V. Description of the invention (0)

0 0 II II 0—C —- (CH2) 8—c—〇

TTNTIVTN 144 iRTM): 〇II 〇 一 c

c4h9 c —

CHCH A L BA T sKDA]

M TR 8 8 This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page) 1226897 A7 B7 V. Description of the invention

c——c——o 2 H 〇 〇H--D c-c-o

? H o II • c — · o o H2 II c―c―o

2 6A L BA T sK D A

Μ TR

c- 2 H

E CH—E7 CH- CH——E7 where two E7 are -COO-C13H27 and two E7 are

ADK STAR Τ, Α 67 iRTMI; HX 1 —CH I —CH — I —CH I 1 E7 1 E7 1 E7 1 E7 where two E7 are -COO-C13H27 and two e7 are

89 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) -------- ^ --------- (Please read the precautions on the back before filling this page ) 1226897 A7 B7 V. Description of the invention (

SANDTTVO ^ TRTMlL 〇 \ 2 CH2CH ^ C—〇 C12H25

(CH2) 9 \ —NX (Please read the notes on the back before filling this page)

HO ^ TAVIN N 24 iRTMll 〇 xh9 (9 ^ 2) 9 ^ —n "

CHXH9—C—〇 一 (C12-C14alkyl) TIVTNTTT, 4n4Q H (^ RTMll) This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 1226897 A7 B7 V. Description of the invention (

Compound (B-6-a-lli H25C12

Compound (B-6-a-2) L 〇 HX CH, H25C12

(Please read the notes on the back before filling this page) SANDTTVOP PT? FRTMll ΗΧΟ

CHZH

noonRTTF TTV iRTMli 91 This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 1226897 V. Description of the invention (h3c ch3 A7 B7

° ^ yCH3 Η——N N—CH2CH—N N ——H 〇 H3C ch3 h3c & nOODRiTF TTV 1150 iRTMll Η3 \ Γ // ° H-N \ / N_ H3C CH,

h3c ch3 h3c ch3

(Please read the notes on the back before filling this page)

E2〇 Among them, E19, E2G and E21 are group bases of the following formula. The paper size applies to the Chinese National Standard (CNS) A4 (210 X 297 mm) 1226897 A7 _ _ B7 V. Description of the invention (Γ)

Example 1: Light stabilized 100 parts of polypropylene homopolymer film with unstabilized polypropylene powder (melt index: 2.4 g / 10 minutes at 230 ° C and 2 160 g) -Brabender plastometer (200 ° C) and 0. 05 parts of pentaerythritol-tetrakis {3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionate}, 0 · 0.5 parts of tri {2,4-tert-butylphenyl} phosphite, 0 · 1 part of calcium stearate, 0 · 2 5 parts of titanium dioxide (anatase) and the stability shown in Table 1 The agent systems were homogenized together for 10 minutes. The obtained material was pressed for 6 minutes (260 ° C) in two aluminum plates of a laboratory-grade press to obtain a 0.5 mm thick film, which was then rapidly cooled in a water-cooled press. To room temperature. This 0.5 mm thick film was then cut into 6 Omm x 2 5 mm samples and placed in a WEATHER-OMETER Ci 65 (blackboard temperature 6 3 soil 2 ° C, no water spray) and exposed. These samples were periodically removed from the exposure apparatus and the carbonyl content was measured by an infrared spectrometer. The exposure time (To ") is equivalent to the formation of a carbonyl absorption of 0.1. It is a measure of the efficiency of a light stabilizer system. Higher T〇.i means better. 93 This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) ------------ (Please read the precautions on the back before filling this page) Order ---- ----- ΜΨ. 1226897 A7 B7 V. Description of the invention (1 丨) Table 1: Light stabilizer system T (U (hour) The amount of light stabilizer used is (each) 0.075% *). T ( The amount of light stabilizer used in the light stabilizer system combined with U (hours) and ΉΝΜΝ 622 (RTM) is (per one) 0.05% *). No 185-TINUVIN 770 (RTM) + TINUVIN 765 (RTM) 1780 3095 TINUVIN 770 (RTM) + TINUVIN 144 (RTM) 1990 2815 TINUVIN 770 (RTM) + TINUVIN 123 (RTM) 1780 2650 TINUVIN 770 (RTM) + HOSTAVIN N 20 (RTM) 2760 3205 TINUVIN 770 (RTM) + ADK STAB LA 57 ( (RTM) 2245 3045 TINUVIN 770 (RTM) + GOODRITE UV 3034 (RTM) 2440 3570 TINUVIN 770 (RTM) + GOODRITE UV 3150 (RTM) 2715 3230 TINUVIN 770 (RTM) + compound (B-6-al) 1930 3095 TINUVIN 770 (RTM) + compound (B-6-a-2) 2000 3400 TINUVIN 770 (RTM) + compound (B-10-al) 3510 3940 TINUVIN 770 (RTM) + compound (Bla-1) 1715 3520 TINUVIN 770 (RTM) + SANDUVOR 3050 (RTM) 1630 3040 TINUVIN 770 (RTM) + SANDUVOR PR-31 (RTM) 1885 2730 HOSTAVIN N 20 (RTM) + ADK STAB LA 57 (RTM) 2485 2765 HOSTAVIN N 20 ( RTM) + Compound (B-6-al) 2625 3010 HOSTAVIN N 20 (RTM) + UVINUL 4049 H (RTM) 2655 3245 HOSTAVIN N 20 (RTM) + Compound (Bla-1) 2510 3055 HOSTAVIN N 20 (RTM) + SANDUVOR PR-31 (RTM) 2120 3140 ADK STAB LA 57 (RTM) + TINUVIN 765 (RTM) 2290 2705 ADK STAB LA 57 (RTM) + GOODRITE UV 3150 (RTM) 2305 2930 ADK STAB LA 57 (RTM) + Compound ( B-6-a-2) 2255 2745 ADK STAB LA 57 (RTM) + UVINUL 4049 H (RTM) 2400 2735 (Please read the precautions on the back before filling out this page) 94 This paper size applies to Chinese National Standards (CNS) A4 specification (210 X 297 mm) 1226897 A7 B7 V. Description of invention (ADK STAB LA 57 (RTM) + SANDUVOR PR-31 (RTM) 1670 2655 GOODRITEUV 3150 (RTM) + compound (B-6-al) 2390 3040 G〇〇DRITEUV 3150 (RTM) + Compound (B-6-a-2) 2155 2670 GOODRITE UV 3150 (RTM) + SANDUVOR PR-31 (RTM) 2075 2840 (B each a-1) + TINUVIN 765 (RTM) 2230 3010 Compound (B-6-al) + Compound (B-6-a-2) 2235 2980 Compound (B-6-al) + UVINUL 4049 H ( RTM) 2465 3235 compound (B-6-al) + compound (B small a-1) 2225 2775 compound (B-10-al) + UVINUL 4049 H (RTM) 3430 4055 compound (B-10-al) + SANDUVOR PR-31 (RTM) 2710 3255 compound (Blal) + TINUVIN 765 (RTM) 2365 3060 compound (Blal) + UVINUL 4049 H (RTM) 2475 3205 compound (Bla-1) + SANDUVOR PR-31 (RTM) 1845 2550 compound (Blal) + Compound (B-6-a-2) 2240 2650 *) The total concentration of light stabilizer is 0.15%. Example 2: Light stabilization of polypropylene homopolymer film 100 parts unstabilized polypropylene Powder (Melting Index: 3.8 g / 10 min at 230 ° C and 2160 g) in a Brabender plastometer (200 ° C) and 0.5 parts of pentaerythritol-tetra {3-( 3,5-di-tert-butyl-4 monohydroxyphenyl) propionate}, 0.5 parts of tris {2,4-tert-butyl-butylphenyl} phosphite, 0.1 Parts of calcium stearate, 0.25 parts of titanium dioxide (a natase) and the stabilizer systems shown in Tables 2 to 2 (i) were homogenized together for 10 minutes. The obtained material was pressed for 6 minutes (260 t) on two aluminum plates of a laboratory-grade press to obtain a 0.5 mm thick film, which was then rapidly cooled in a water-cooled press to Room temperature. Then cut this 0.5mm thick film into 60 mm X 2 5 mm samples, and place them in a WEATHER-OMETER Ci 65 (blackboard temperature 6 3 ± 2 ℃, no water spray. This paper is suitable for Chinese countries Standard (CNS) A4 specification (210 X 297 mm) (Please read the precautions on the back before filling this page) -------- Order ----- 1226897 A7 _B7_ V. Description of the invention (Lat) Sprinkle) exposure. These samples were periodically removed from the exposure apparatus and the carbonyl content was measured by an infrared spectrometer. The exposure time (Tο ") is equivalent to the formation of 0.1 · carbonyl absorption, which is a measure of the efficiency of a light stabilizer system. The higher To "means better. Table 2A: Light stabilizer systems T (H (hours) T (U (hours) T (U (hours) T (U (hours)) The amount of light stabilizers used is (each) 0.1% *). And TINUVIN 622 (RTM) combined light stabilizer system and TINUVIN 622 (RTM) combined light stabilizer system and TINUVIN 622 (RTM) combined light stabilizer system The amount of light stabilizer in the light stabilizer system is 0.05% each, The amount of TINUVIN 622 (RTM) is 0.10% *). The amount of light stabilizer in the light stabilizer system is 0.075% each, and the amount of TINUVIN 622 (RTM) is 0.05% *). The light in the light stabilizer system The amount of stabilizer is 0.09% each and the amount of TINUVIN 622 (RTM) is 0.02% *). * No 300 TINUVIN 770 (RTM) + TINUVIN 144 (RTM) 4635 7530 7585 6235 TINUVIN 770 (RTM) + TINUVIN 123 ( (RTM) 4935 7940 7170 7130 TINUVIN 770 (RTM) + HOSTAVIN N 24 (RTM) 5105 7455 7030 6890 TINUVIN 770 (RTM) + ADK STAB LA 52 (RTM) 6710 6945 7865 8010 96 This paper is compatible with the Chinese National Standard (CNS) A4 size (210 X 297 mm) -------------------- Order --------- (Please read the notes on the back first (Fill in this page again) 1226897 A7 B7 V. Description of Invention (W) TINUVIN 770 (RTM) -f ADK STAB LA 57 (RTM) 5450 7225 7225 7280 TINUVIN 770 (RTM) + ADK STAB LA 67 (RTM) 5915 6700 7190 7025 TINUVIN 770 (RTM) + GOODRITE UV 3034 (RTM) 6925 > 8340 > 8340 7360 TINUVIN 770 (RTM) + GOODRITE UV 3150 (RTM) 6325 7965 7625 7025 TINUVIN 770 (RTM) + compound (Bla-1) 6040 7400 7540 7025 TINUVIN 770 (RTM) + SANDUVOR 3050 (RTM) 5070 7005 6990 5735 TINUVIN 770 (RTM) + SANDUVOR PR-31 (RTM) 5745 7470 6765 6705 *) The total concentration of light stabilizer is 0.20%. Table 2B: Light stabilizer system T (U (hour) The amount of light stabilizer used is 0.1% each *). T (U (hour) and mixture (A-2) combined light stabilizer system light stabilizer The amount of light stabilizer in the system is 0.075% each, and the amount of the mixture (A_2) is 0.05% *) · No 300-TINUVIN 770 (RTM) + TINUVIN 144 (RTM) 4635 6025 TINUVIN 770 (RTM) + TINUVIN 123 (RTM) 4935 6080 TINUVIN 770 (RTM) + HOSTAVIN N 24 (RTM) 5105 6005 97 -------------------- Order --------- (Please read the precautions on the back before filling this page) This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) 1226897 A7 B7 V. Description of Invention () TINUVIN 770 (RTM) + ADK STAB LA 57 (RTM) 5450 6800 TINUVIN 770 (RTM) + GOODRITE UV 3034 (RTM) 6925 7735 TINUVIN 770 (RTM) + compound (B-6-a-2) 6530 7335 TINUVIN 770 (RTM) + compound (Bla-1 ) 6040 6905 TINUVIN 770 (RTM) + SANDUVOR 3050 (RTM) 5070 > 6495 *) The total concentration of light stabilizer is 0.20%. Table 2C: Light stabilizer system To ”(hours) The amount of light stabilizer used is 0.1% each *). T (U (hour) and TINUVIN 622 (RTM) combined light stabilizer system in light stabilizer system The amount of light stabilizer is 0.075% each, and the amount of TINUVIN 622 (RTM) is 0.05% *). No 315-TINUVIN 770 (RTM) + TINUVIN 765 (RTM) 4815 > 7260 TINUVIN 770 (RTM) + TINUVIN 144 (RTM) 5695 7145 TINUVIN 770 (RTM) + TINUVIN 123 (RTM) 4670 7080 TINUVIN 770 (RTM) + HOSTAVIN N 24 (RTM) 5390 6710 TINUVIN 770 (RTM) + ADK STAB LA 52 (RTM) 6655 > 7260 TINUVIN 770 (RTM) + ADK STAB LA 62 (RTM) 5040 6760 TINUVIN 770 (RTM) + ADK STAB LA 67 (RTM) 5010 6205 98 This paper is sized for China National Standard (CNS) A4 (210 X 297 mm) -------------------- Order --------- Line (Please read the precautions on the back before filling this page) 1226897 A7 B7 V. Invention Explanation (outside) TINUVIN 770 (RTM) + compound (B-10-al) 5825 > 7260 TINUVIN 770 (RTM) + it compound (Bla-1) 6125 7215 TINUVIN 770 (RTM) + SANDUV or 3050 (RTM) 56 90 > 7260 TINUVIN 770 (RTM) + SANDUV or PR-31 (RTM) 5100 6475 *) The total concentration of light stabilizer is 0.20%. I Table 2D: Light stabilizer system T. ”(Hours) T (U (hours) each of the amount of light stabilizer used is α% *). Light stabilizer system combined with TINUVIN 622 (RTM) The amount of light stabilizer in the light stabilizer system is 0.075%, and the amount of TINUVIN 622 (RTM) is 0.05% *). No 315-TINUVIN 765 (RTM) + TINUVIN 144 (RTM) 4930 7180 TINUVIN 765 (RTM) + TINUVIN 123 (RTM) 4640 > 7260 TINUVIN 765 (RTM) + HOSTAVIN N 20 (RTM) 6580 > 7260 TINUVIN 765 (RTM) + HOSTAVIN N 24 (RTM) 5325 7040 TINUVIN 765 (RTM) + ADK STAB LA 52 (RTM) 5605 > 7260 TINUVIN 765 (RTM) + ADK STAB LA 57 (RTM) 5360 6905 TINUVIN 765 (RTM) + ADK STAB LA 62 (RTM) 4620 > 7260 TINUVIN 765 (RTM) + ADK STAB LA 67 (RTM) 4840 6625 99 ------- -Order --------- (Please read the notes on the back before filling out this page) This paper size applies to China National Standard (CNS) A4 (210 χ 297 mm) 1226897 A7 B7 V. Description of the invention (Β) TINUVIN 765 (RTM) + GOODRITE UV 3034 (RTM) 6550 > 7260 TINUVIN 765 (RTM) + GOODRITE UV 3150 (RTM) 5715 > 7260 TINU VIN 765 (RTM) + compound (B-6-al) 5105 > 7260 TINUVIN 765 (RTM) + compound (Blal) 6145 > 7260 TINUVIN 765 (RTM) + SANDUV or 3050 (RTM) 5425 > 7260 TINUVIN 765 (RTM) + SANDUV or PR-31 (RTM) 4920 6675 *) The total concentration of light stabilizer is 0.20%. Table 2E: Light stabilizer systems T (U (hours) T (U (hours) The amount of light stabilizers used is each 0.1% *). Light stabilizer system combined with TINUVIN 622 (RTM) Light stabilizer system The amount of light stabilizer is 0.075% each, and the amount of TINUVIN 622 (RTM) is 0.05% *). No 330 TINUVIN 144 (RTM) + TINUVIN 123 (RTM) 3185 5765 TINUVIN 144 (RTM) + HOSTAVIN N 20 (RTM) 4295 6150 TINUVIN 144 (RTM) + HOSTAVIN N 24 (RTM) 3725 5720 TINUVIN 144 (RTM) + ADK STAB LA 52 (RTM) 4195 5635 TINUVIN 144 (RTM) + ADK STAB LA 57 (RTM) 4870 6350 TINUVIN 144 (RTM) + ADK STAB LA 62 (RTM) 2815 5695 100 -------------------- Order --------- (Please read the back first Please note this page before filling in this page) This paper size is in accordance with Chinese National Standard (CNS) A4 (210 χ 297 mm) 1226897 A7 B7 V. Description of Invention (#) TINUVIN 144 (RTM) + ADK STAB LA 67 (RTM) 3910 4940 TINUVIN 144 (RTM) + GOODRITE UV 3034 (RTM) 4185 6115 TINUVIN 144 (RTM) + GOODRITE UV 3150 (RTM) 4290 5725 TINUVIN 144 (RTM) + Compound (B-6-a -l) 5515 6565 TINUVIN 144 (RTM) + compound (B-6-a-2) 5100 6810 TINUVIN 144 (RTM) + compound (B-10-al) 5380 6585 TINUVIN 144 (RTM) + compound (Blal) 5470 6305 TINUVIN 144 (RTM) + SANDUVOR 3050 (RTM) 4030 5200 TINUVIN 144 (RTM) + SANDUVOR PR-31 (RTM) 3105 5890 *) The total concentration of light stabilizer is 0.20%. > Table 2R Light stabilizer system T (U (hour) T (U (hour) The amount of light stabilizer used is each 0.1% *). Light stabilizer system light stabilizer combined with TINUVIN 622 (RTM) The amount of light stabilizer in the system is 0.075% each, and the amount of TINUVIN 622 (RTM) is 0.05% *). Without 330 TINUVIN 123 (RTM) + HOSTAVIN N 20 (RTM) 4455 5715 TINUVIN 123 (RTM) + HOSTAVIN N 24 (RTM) 3490 5265 TINUVIN 123 (RTM) + ADK STAB LA 52 (RTM) 4620 5610 101 -------------------- Order ------ --- Line (Please read the precautions on the back before filling this page) This paper size is applicable to China National Standard (CNS) A4 (210 χ 297 mm) 1226897 B7 V. Description of Invention (彳 1) TINUVIN 123 (RTM ) + ADK STAB LA 57 (RTM) 4275 5670 TINUVIN 123 (RTM) + ADK STAB LA 62 (RTM) 3380 5185 TINUVIN 123 (RTM) + ADK STAB LA 67 (RTM) 3470 5355 TINUVIN 123 (RTM) + GOODRITE UV 3034 (RTM) 4520 > 6280 TINUVIN 123 (RTM) + GOODRITEUV3150 (RTM) 4260 5635 TINUVIN 123 (RTM) + compound (B-6-al) 4760 6145 TINUVIN 123 (RTM) + Compound (B each a-2) 5115 6365 TINUVIN 123 (RTM) + Compound (B-10-al) 5785 6700 TINUVIN 123 (RTM) + Compound (Bla-1) 4345 6115 TINUVIN 123 (RTM) + SANDUVOR 3050 ( (RTM) 3650 5040 TINUVIN 123 (RTM) + SANDUVOR PR-31 (RTM) 3655 5390 TINUVIN 123 (RTM) + compound (B-7-1) 4305 5205 *) The total concentration of light stabilizer is 0.20% 0 Table 2G: Light stabilizer system T (U (hours) Tα! (Hours) The amount of light stabilizer used is 0.1% each *). Light stabilizer system combined with TINUVIN 622 (RTM) Light stabilizer system The amount of each is 0.075%, and the amount of TINUVIN 622 (RTM) is 0.05% *). No 325 102 (Please read the precautions on the back before filling this page) This paper size applies to China National Standard (CNS) A4 specifications (210 χ 297 mm) 1226897 A7 B7 V. Description of the invention (1 °) HOSTAVIN N 20 (RTM) + HOSTAVIN N 24 (RTM) 3695 4565 HOSTAVIN N 20 (RTM) + ADK STAB LA 52 (RTM) 4375 5525 HOSTAVIN N 20 (RTM) + ADK STAB LA 57 (RTM) 4485 5535 HOSTAVIN N 20 (RTM) + ADK STAB LA 62 (RTM) 3810 5 315 HOSTAVIN N 20 (RTM) + ADK STAB LA 67 (RTM) 3655 5045 HOSTAVIN N 20 (RTM) + GOODRITE UV 3034 (RTM) 5005 5610 HOSTAVIN N 20 (RTM) + GOODRITE UV 3150 (RTM) 3950 5050 HOSTAVIN N 20 (RTM) + Compound (B-6-al) 5025 > 5890 HOSTAVIN N 20 (RTM) + Compound (B-6-a-2) 5465 > 5890 HOSTAVIN N 20 (RTM) + Compound (B-10- al) 5405 > 5890 HOSTAVIN N 20 (RTM) + Compound (Bla-1) 5410 > 5890 HOSTAVIN N 20 (RTM) + SANDUVOR 3050 (RTM) 3985 5090 HOSTAVIN N 20 (RTM) + SANDUVOR PR-31 (RTM ) 4085 5255 HOSTAVIN N 20 (RTM) + Compound (B-7-1) 4200 5220 -------------------- Order --------- Line (please read the notes on the back before filling this page) *) The total concentration of light stabilizer is 0.20%. Table 2H: 103 This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 1226897 A7 B7: Description of the invention (el) Light stabilizer system T0 "(hours) T. ”(Hours) The amount of light stabilizer used is 0.1% each *). The amount of light stabilizer in the light stabilizer system combined with TINUVIN 622 (RTM) is 0.075% each, and ΉΝυνίΝ 622 (RTM) is 0.05% *). Without 325 ADK STAB LA 57 (RTM) + HOSTAVIN N 24 (RTM) 4035 5020 ADK STAB LA 57 (RTM) + ADK STAB LA 52 (RTM) 3855 4985 ADK STAB LA 57 (RTM) + GOODRITE UV 3150 (RTM) 4320 4890 ADK STAB LA 57 (RTM) + SANDUVOR PR-31 (RTM) 3970 4430 ADK STAB LA 57 (RTM) + Compound (B-7-1) 3765 4475 *) Light The total concentration of the stabilizer is 0.20%. 104 (Please read the precautions on the back before filling out this page) The paper size applies to China National Standard (CNS) A4 (210 x 297 mm)

Claims (1)

1226897 Scope of patent application A8 B8 C8 D8 〇- where 112 and n2 * are a number from 2 to 50; a compound of formula (A-3) a ~ _ H3C CH. H3C CH3 ο -α4 N-CH2-CH—CH: I OH H3C CH. A3 H3C CH3 n3 —A4 N — CH2 —CH—CH2 — N OH A3 — 0 h3c ch3 H3C CH: a4 (A-2-b) (Please read the notes on the back before filling this page) ^ O H3C, ck CH—CH— CH2 N V h3c CH, (A-3) where A3 and A4 are unrelated to each other hydrogen or C, C8 alkyl, or A3 and a4 together form a C2-C14 academy group, and the variables n3 are not related to each other are A number from 1 to 50; or a compound of formula (A-4) The paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1226897 VI. Application scope A8 B8 C8 D8 -CH0- a5- C-CH, I c = oI 〇I 8 6 l2—〒H- c bis 〇A7 n4 (A-4) where n4 is a number from 2 to 50, As is hydrogen or a C1-C4 compound, and is substituted The groups A6 and a7 which are not related to each other are an alkyl group or a group of formula (aI) (please read the precautions on the back before filling this page) h3c ch3 (aI) n-a8 h3c ch3 where A8 is hydrogen and CrQ alkyl , 0_, -0H, -CH2CN, CVCu alkoxy, C5-C12 cycloalkoxy, C3-C6 alkenyl, C7-C9 phenylalkyl, which are unsubstituted, or the phenyl group consists of 1, 2 or 3 alkyl substituted; or CVC8 fluorenyl, but limited to at least 50% of the substituents 7 is a group of formula (aI); and component (B) is composed of two compounds containing formula ⑴ or (II Stereo hindered amine compounds of different low molecular weight Formation; HX CH, HX CH3 〇One (I) HX CH, -NN —— (Π) AH, C CH, This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) Α8 1226897 1 D8 6. The scope of patent application, but its limitation is that the components (A) and (B) are different. 2. As for the stabilizer mixture in the scope of patent application item 1 > where two different components (B) compounds are selected From β-l) — Compound of formula (B-1) L h3c ch3 ”, where E! ^ 0-? -OH? .- CH2CN? C5-C12 cyclooxyl, C3-C6 alkenyl, C7-C9 phenylalkyl, which are unsubstituted, or in Phenyl is substituted by 1, 2 or 3 CrQ alkyl; or CrC8 fluorenyl, which is 1, 2 or 4, if m] is 1, E2 is CVC25, if m! Is 2, E2 is CVCm Or group (bI) group base (please read the precautions on the back before filling this page) F e6 where E3 is Cl-ClQ or C2-Cl () dilute, E4 is Cl-ClO alkylene, and E5 and E6 are unrelated to CrQ alkyl, cyclohexyl or methylcyclohexyl, And 4 This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1226897 Patent application scope A8 B8 C8 D8 Suppose m] is 4, E2 is C4-C1G four-base β-2) —formula ( B-2) the compound YX-CH * CH · ch2 (B-2) in which two substituents E7 is -COCKCVC alkyl), and two substituents E7 are a group of formula (b-II), (b-II) (Please read the notes on the back before filling out this page) where E8 has one of the definitions of E! β-3) —Compound of formula (B-3) Ε, η (B-3) Where E9 and Eio — form a C2-C14 academy ', Εη is hydrogen or mono-Z ^ COO-Z] group Z! Is C2-C14 alkylene, and Z2 is CkC24 alkyl, and El2 has E! Definition One of them; β-4) —a compound of formula (B-4), the paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) 1226897 patent application scope A8 B8 C8 D8 -15 -13 (B-4) in which the substituents E13 are unrelated to each other have one of the meanings, and the substituents E14 are unrelated to each other are hydrogen or < ^ < 12 alkyl, and Ei5 is Ci-CiG Academy or C3-C1G courtyard fork; β-5) —a compound of formula (B-5), 16 (Β-5) (Please read the precautions on the back before filling out this page) where the substituents E] 6 are independent of each other and have one of the meanings; β · 6) —the compound of formula (B-6) (B-6) where Eΐ7 is the base, and E18 has one as defined in E!> 7) —The compound of formula (B-7) The paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 (Mm) 1226897 Patent application scope A8 B8 C8 D8 i (B-7) -19. II / E21 Ί \ Τ 0 0 where Ei95 E20 and e21 are irrelevant to each other _ group (b-III) group basis, h3c ch3 V 3 ——CHr -CH—CH— -NH—N—E22 (b-III) OH V \ h3c ch3 where E22 has one of the definitions of E! β-8) —a compound of formula (B-8), CHZZZC (Please read the notes on the back before filling out this page) Among them, the substituents E23 which are not related to each other have one of the WE! Definitions and E24 is nitrogen, Ci_Ci2 or C1-C12, or oxygen; β-9) —Compounds of formula (B-9) The paper size applies to Chinese National Standard (CNS) A4 specifications (210 X 297 mm) 1226897 6. Application scope h3c ch3 A8 B8 C8 D8 E2—N N- -26 (B-9 ) Where m2 is 1, 2, or 3, E25 has one of the definitions of Ei, and when m2 is 1, E26 is a group of ch2ch "nhH ^) When m2 is 2, E26 is a C2-C22 alkane Support, and when m2 is 3, E26 is a group of formula (b_IV), E ^ 28 _E ^ — Ν ΜyV Ν 丫 Ν Ε27 ^ 28 ^ 28 Η—Εζ (b-IV) (Please read the notes on the back first Fill out this page again) where the substituents E27 are unrelated to c2-c12 alkylene, and the substituents E28 are unrelated to CrCu alkyl or c5-c12 cycloalkyl, respectively; β-) ο) — formula (B -10) compound, 〇〇 -29 (B-10). The paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) A8 B8 C8 D8 1226897 6. Scope of patent application (Please read the precautions on the back before filling this page) Replace The groups E29 are independent of one another as defined in E1, and E30 is C2-C22 alkylene, C5-C7 cycloalkylene, C! -C4 alkylene di (C5-C7 cycloalkylene), benzene Or phenylene (CVC4 alkylene); or 乂 i 'β-ll) — compounds of formula (B-11), Where E31 is CVCn alkyl, 05-(: 12 cycloalkyl, CVC4 alkyl-substituted Q c12 cycloalkyl, phenyl or alkyl-substituted phenyl, E32 is C3-C1G academy 'E33 has as One of the definitions of E !, and m3 is a number from .2 to 6. 3. If the stabilizer mixture of the scope of the patent application is in item 1, where A! Is hydrogen or methyl, A2 is a direct bond or C2-C6 alkylene, and is a number from 2 to 25; n2 and n2 * are a number from 2 to 25; A3 and A4 are independently related to hydrogen or alkyl, or A3 and A4 are formed together A C9-C13 alkylene group, and this paper size applies Chinese National Standard (CNS) A4 specifications (210 X 297 mm) 1226897 6. Scope of patent application (please read the precautions on the back before filling this page) Variable n3 mutual Irrelevant numbers are 1 to 2 5; n4 is a number from 2 to 25; A5 and A6 are unrelated to CVC4 alkyl, and A7 is C1-C4 fluorenyl or a group of formula (aI) 'But the limitation is that at least 50% of the people 7 are a group of formula (a_I). 4. If the stabilizer mixture of the scope of patent application No. 2 is 1, 2 or 4, if mi is 1, E2 is C12 -C2G alkyl, false When mi is 2, E2 is a C2-C1G alkylene group or a group of formula (bI), E3 is a C1-C4 alkyl group, E4 is a cvc6 alkylene group, and C5 and E6 are unrelated to each other. If _ is 4, E2 is 〇4-0: 8 alkyl tetrayl; two e7 s-coo- (c1 (rc15 alkyl), and two E7 are group of formula (b-II); E9 and E1Q C9-c13 alkylene is formed, En is hydrogen or a -Z ^ COO-Z group group, Z is a C2-C6 compound, and Z2 is a Ci0-Ci6 group; e14 is hydrogen, and E15 is C2 -C6 courtyard rubbing or C3-C5 courtyard fork; Ei7 is CwCm courtyard base; E24 is C "C4 courtyard oxygen; This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) A8 1226897 Rong D8 Six The scope of patent application m2 is 1, 2 or 3, when ηΐ2 is 1, E26 is a formula CH2CHj ~ NH ~ ^ = D group base 'When ηΐ2 is 2, E26 is C2-C6 courtyard support' and f when m2 When it is 3, E26 is a group of formula (b-IV), E27 is unrelated to C2-C6 alkylene, and E28 is unrelated to CrQ alkyl or 05-08 cycloalkyl; E30 is C2 -C8 courtyard; and E31 is C1-C4 courtyard, E32 is c3-c6 alkylene, and m3 is a number from 2 to 6. 5. The stabilizer mixture according to item 1 of the application, wherein the component (A) is of the formula (A-1-a), (A-2-a), (A-2-b), (A-3- a) or (A-4-a) compounds; Plant h3c, / CH3 — ——Ο— (Ν—ch2ch2—ooc—ch2ch—CO (Ala) where n! is a number from 2 to 20; (Please read the precautions on the back before filling this page) (A-2-a) This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 1226897 6. Scope of patent application A8 B8 C8 D8 0- (A-2-b) where n2 and n2 * are a number from 2 to 2 0; CH2 —— (CH2) 9 H3C CH; N-CH, -CH—CH: h3c CH. Ch2— (CH2) 9 -CH, I h3c ck h3c ch3 —ch2 N —CH2—CH—CH2 — N OH CH2-0 H.C CH3 N 1 H3C CH, (CH2) 9-CH2 (Please read the precautions on the back before filling this page) YA H 0 H3C · CH, CH-CH—CH2 —N CH, N_ h3c ch3 (CH2) r CH2 n3 (A-3-a) where the variables n3 are independent of each other from a number from 1 to 20; CH, (A-4-a) = 0 -CH Factory C— CH2—CH- II 9 = ° i— ΐ— ch3 ° \ A7 where n4 is a number from 2 to 20, and at least 50% of A7 is a group basis of formula (aI), (aI) 12 This paper size applies to Chinese National Standard (CNS) A4 specification (210 X 297 mm) A8 B8 C8 D8 1226897 6. Scope of patent application where A8 is hydrogen, cvc8 alkyl, 0, -OH, -CH2CN In the following, oxy, c5-c12 cycloalkoxy, c3-c6 alkenyl, c7-c9 phenylalkyl, which are unsubstituted or have 1, 2 or 3 cvc4fluorenyl groups on the phenyl group Substituted; or CrCsfluorenyl, and A7 is defined as ethyl; and component (B) is formed from two different compounds: (B_1-a), (B-1-b), (B- 1-c), (B-1_d), (B-2-a), (B-3-a), (B-3-b), (B-4-a), (B-4-b) , (B-5), (B-6-a), (B-7),. (B-8-a), (B-9-a), (B-9-b), (B-9 -c), (B-10-a) and (B-ll-a); (Please read the notes on the back before filling this page) 〇—C— (C15-C17alkyl) 0 0 II II 0—C —— (CH2) g—c—o 〇II N—E, l3C ch3 gas N h3c ch3 13 This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) A81226897 I 6. Scope of patent application ο Η --C — C — 〇 ο c-cIC——ο CH · ό 〇 -d lx (B- 〇 Where E! Is hydrogen, CkCs alkyl, 0 ·, -OH, -CH2CN, cvc18 alkoxy, C5-C12 cycloalkoxy, C3-C6 alkenyl, C7-C9 phenylalkyl, which are not Substituted or substituted with 1,2 or 3 CVC4 alkyl on phenyl; or CrC8fluorenyl; 1 "~ (B-2-a) HX-CH · • CH. • CH. (Please read the notes on the back before filling out this page) E7 I Among them, two E7 are -COO-C13H27 and two e7 are N—Eδ and E8 have one of the definitions of El; (B-3-a) 14 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 1226897 Patent application scope A8 B8 C8 D8 CH2CH—C—O —— (C12-C14alkyl) (B-3-b) where E12 has one of the definitions of E !; • 13 13 (B-4-a) (B bucket b) (Please read the precautions on the back before filling out this page) Among them E13 has one of the meanings; 16 '3 ^ ^ π3 (B-5) where E16 has one of the definitions of E! -18 (B-6-a), of which E18 has one of the definitions of E! 15 This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1226897 6. Scope of patent application ^ 20 (B-7) where E19, E2G and E21 are uncorrelated (b-III) (Please read the notes on the back before transcribing this page) E22 has one of the meanings; (B-8-a) ο-CMNO 3 2 E H3C CH where E23 has one of the definitions of E! HX CH3 y ^ ° / -λ / N —CH2CH2——ΝΗ—,] (B-9-a) H3C CH, h3c ch3 CH, A0 E —NN—CH2CH—N, one E25 λ person (B-9-b) h3c ch3 H, C CH: 16 This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1226897 6. Apply for a patent Range A8 B8 C8 D8 ¥, E2T—N, H3C CH, YN λ N——CHXH; —N y ^ CH3, N —E25 h3c 'ch3 〇v h3cv ch7 N——CH2CH2- 7 <, N—E25 h3c ch3 (B-10-a) (Please read the notes on the back before copying this page) (B-ll-a) m3 where m3 is a number from 2 to 6 and E33 has one of the definitions of E !. > 6. If the stabilizer mixture of item 1 of the scope of patent application, where 8 is 17 people, this paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1226897 〇Bs8 D8 Please read the notes on the back before filling out this page) Hydrogen, CVC4 alkyl, cvc ^ alkoxy, cyclohexyloxy, allyl, benzyl or ethenyl. .JT 7. For example, the stabilizer mixture of item 2 of the scope of patent application, in which E !, E8, Ei2, E13, E16, E18, E22, E23, E25, E29 and E33 are hydrogen, CVC4 alkyl, heart-heart. Alkoxy, cyclohexyloxy, allyl, benzyl or ethenyl. 8. If the stabilizer mixture of item 5 of the patent application scope, wherein A8, El5 Eg, E12, E] 3, E16, E18, E22, E23, E25, E29 and E33 are hydrogen or methyl, and Ei is additionally ( ^ -Heartylalkoxy. 9. The stabilizer mixture according to item 5 of the scope of application, wherein one of the two forming components (B) is a compound of formula (B-1-b), wherein E! Is hydrogen. 10 For example, the stabilizer mixture of the scope of application for item 5, wherein component (A) is a compound of formula (A-1-a), where η is a number from 2 to 20, or formula (A-2-a) or (A-2-b) compounds, where n2 and n2 * are a number from 2 to 20; and one of the two different compounds forming component (B) is a compound of formula (B-1-b), where E! It is hydrogen. 11. For example, the stabilizer mixture of item 5 of the scope of patent application, wherein the particularly preferred embodiment of the present invention is about a stabilizer mixture, whose __18_ This paper size applies to China National Standard (CNS) A4 specifications (210 X 297 mm) A8 1226897 I Sixth, the component (A) in the scope of patent application is a compound of formula (A_1-a), where η! Is a number from 2 to 20, or a formula (A -2-a) or (A-2-b) compounds, where η2 and η2 * are a number from 2 to 20; f forms one of two different compounds of component (B) which is of the formula (B-1- b) a compound in which E! is hydrogen; and the other of two different compounds forming component (B) is a compound of formula (B-1-a), where E] is hydrogen; (B-1-b), in which E ! Is methyl; (B-1-d), where E! Is hydrogen or methyl; (B-3_a), where E12 is hydrogen; (B-3-b), where E12 is hydrogen; (B-4 -b), where E13 is hydrogen; (B-5), where E16 is hydrogen; (B_6-a), where E18 is hydrogen or methyl; (B-8-a), where E23 is methyl; (B -9-c), where E25 is hydrogen or methyl; (B-10-a), where E29 is being hydrogen; or (B-11-a), where E33 is hydrogen. Item of the stabilizer mixture, wherein component (A) is a compound of formula (A-1-a), wherein ⑴ is a number from 2 to 20, and component (B) is a compound of formula (B-1-b), where E ! Is hydrogen, and component (C) is a compound of formula (B-1-b), where E! Is octyloxy; or component (A) is a compound of formula (A-1-a), where η! Is a compound from Numbers from 2 to 20 Ingredient (B) is a compound of formula (B-1-b), where E! • is hydrogen, and ingredient (C) is a compound of formula (B-3-a), where E12 is hydrogen '; or _19_ paper size Applicable to China National Standard (CNS) A4 specification (210 X 297 mm) ......... 0, ....... ........ Order ............ LINE®- (Please read the precautions on the back before filling out this page) A8 1226897 § D8 VI. Patent Application Scope ( Please read the notes on the back before filling out this page) Ingredient (A) is a compound of formula (A-1-a), where η! Is a number from 2 to 20, and ingredient (B) is of formula (B-1- b) compound <, wherein E is hydrogen, and component (C) is a compound of formula (B-1-d), where E! is hydrogen: or component (A) is a compound of formula (A-1-a), Where ⑴ is a number from 2 to 20, component (B) is a compound of formula (B-1-b), where E! Is argon, and component (C) is a compound of formula (B-1-a), where Ε ! Is hydrogen; or component (A) is a compound of formula (A-1-a), where IM is a number from 2 to 20, component (B) is a compound of formula (B-1-b), where E is Methyl, and ingredients C) is a compound of the formula (B-1-d), where Epsilon! Methyl. 13. A composition comprising a pair of organic substances that are degraded by light, heat or oxidation, and a stabilizer mixture as described in the first patent application. 14. The composition of claim 13 in which the organic substance is a synthetic polymer. 15. The composition according to item 13 of the patent application scope, wherein the organic substance ‘is a polyolefin. _20_ This paper size is in accordance with China National Standard (CNS) A4 (210 X 297 mm) 1226897 § D8 VI. Patent Application Park (please read the notes on the back before filling this page) 16. If the scope of patent application is the first The composition of 3, wherein the organic substance is polyethylene, polypropylene, polyethylene copolymer, or polypropylene # polymer. 17. A method for stabilizing an organic substance against degradation caused by light, heat, or oxidation, comprising adding to the organic substance a stabilizer mixture as described in item 1 of the scope of the patent application. 18. The stabilizer mixture of claim 2, wherein the two compounds of component (B) are selected from different groups. 21 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 1226897 A8 B8 C8 VI. Application for patent scope 1. A stabilizer mixture including ingredients (A) and (B), where the ingredient (A ) Is a compound of formula (A-1) (A-1) where Aι is hydrogen or C1-C4 radical, A2 is a direct bond or Q-Ch alkylene, and η] is a number from 2 to 50; at least one formula (A-2-a) and (A-2-b) Compound (Please read the precautions on the back before copying this page) (A-2-a) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)