TW572952B - Stabilizer mixtures - Google Patents

Description

572952 A7 ____B7 ___ _ 5. Description of the invention (I) The present invention relates to a stabilizer mixture comprising an ester or amidine of a specific sterically hindered amine, a low molecular weight sterically hindered amine, and a high molecular weight sterically hindered amine. Stabilizer mixtures containing sterically hindered amine mixtures are for example described in US-A-4,692,468, US-A-4,863,981, US-A-5,719,217, US-A-5, 919,399, US-A-5,965,643, US-A-5,980,783, US-A-6,015,849 and US-A-6,020,406. The present invention relates to a stabilizer mixture comprising components (A), (B) and (C), wherein component (A) is a compound of formula (A-1),

Where Ai is hydrogen or alkyl and A2 is a direct bond or CrCi. Alkylene, and η! Are a number from 2 to 50; at least one compound of formula (A-2-a) and (A-2-b)

4 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) I--4- IIJIIII-— — — III — ^ «— — — — — — I — 111! 11 ♦ 1 (Please first Read the notes on the back and fill out this page) 572952 A7 B7 V. Description of the invention (>

(A-2-b) n2 where n2 and n2 * are a number from 2 to 50. Compound of formula (A_3) h3c CH3

a4 N — 〇ν H3C CH3 CH —CH ^ · h3c ch3

H3C CH3 o a4 h3c ch3 N one CHj one CH—CH2-N OH A3 —

H3C CK a4

OH I CH2 — CH-CH2 — N 0 h3C CH. / N —, outer

V

h3c a4 n3 (A-3) where A3 and A4 are unrelated to each other hydrogen or CrC8 alkyl, or A3 and A4 together form a C2-C14 alkylene group, and the variable n3 is unrelated to each other A number from 1 to 50; or a compound of formula (A-4) _CH-—CH ~ C = 0 L Αβ c = o I 〇I A7 · n4 This paper size applies to China National Standard (CNS) A4 (210 X 297) Mm) ---- r ---. G · --------- Order --------- line (Please read the notes on the back before filling this page ) (A-4)

572952 A7 ___B7_ V. Description of the invention (3) where n4 is a number from 2 to 50, A5 is hydrogen or C, C4 alkyl, eight 6 and A7 are unrelated to each other are C1-C4 academy or a formula (aI Group base

Among them are hydrogen, Ci-Cg amidino, 0 ·, -OH, -CH2CN 5 C1-C18 alkyloxy 'C5-Ci2 ^ oxy, C3-C6 alkyl, C7-C9 phenylalkyl, which are Unsubstituted, or substituted with 1, 2, or 3 CVC4 alkyl groups on the phenyl group; or CVCs fluorenyl groups, but limited to at least 50% of the 8-7 is a group group of the formula (aI); component (B) Is a low molecular weight sterically hindered amine compound containing a group of formula (I) or (II); and

H3C CH A 3 -V / — (1) h3c ch3 component (C) is a high molecular weight sterically hindered amine compound containing a group of hydrazone groups; but it is limited to components (A), (B) and (C) Is different. Preferably, the compound of component (B) has a molecular weight of up to 1,000 g / mole, for example 155 to 800 g / mole, or 155 to 1,000 g / mole, or 300 to 800 g / mole, or 300 to 1,00 () g / mole. 6 Applicable standard (CNS) A4 (21G χ 297 mm) for this paper size '" I — I — II — · — III · III — I — I · 11111111 (Please read the precautions on the back before filling this page ) 572952 A7 ____B7_ V. Description of the invention (+) Preferably, the high molecular weight sterically hindered amine compound (ingredient (C)) has more than 1,000 g / mole, preferably from more than 1,000 to 100 10,000 g / mole, such as up to 50,000 g / mole or sterically hindered amines up to 20,000 g / mole. Molecular weights of 1,500 to 15,000 g / mole or 1,500 to 5,000 g / mole are particularly preferred. The preferred molecular weight of ingredient (B) is also from more than 800, up to 100,000 g / mole, such as up to 50,000 g / mole or up to 20,000 g / mole. More than 800 Molecular weights up to 15,000 g / mole or more, and molecular weights up to 5,000 g / mole are also preferred. The compounds of the formula (A-2-a) and (A-2-b) can also be applied in the form of a mixture, wherein the two compounds are present in a ratio of 1: 2 0 to 2 0: 1, preferably 1: 1 0 to 1 0: 1. Ingredient (B) is preferably a compound of formula (B-1),

Where Eι is hydrogen, CrCs alkyl, OH, -OH, -CH2CN, CrC18 alkoxy, c5-c12 cycloalkoxy, c3-c6 alkenyl, c7-c9 phenylalkyl, which are unsubstituted , Or substituted by 1, 2 or 3 CrC4 alkyl groups on the phenyl group; or CrC8 fluorenyl group, 7 This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) '" " (Please read the notes on the back before filling this page)

572952 A7 _B7_ 5. Description of the invention (P) mi is 1, 2 or 4, if the call is 1, E2 is an alkyl group, if mi is 2, E2 is a CVCm alkylene group or a (b-I) group

F

E6 where E3 is CVCw alkyl or C2-C1 () alkenyl, E4 is CVCio alkylene, and E5 and E6 are unrelated to G-C4 alkyl, cyclohexyl or methylcyclohexyl 'and if ml is At 4 o'clock, E2 is a C4-C10 alkyltetrayl group; a compound of formula (B-2): a CH — CH — CH2 (B-2) e7 e7 e7 e7 (where two E7 are —COCKCrCzo alkyl groups), and two E7 is a group (b-II) group base (please read the precautions on the back before filling this page) -n ϋ nn · ϋ -10, I n ϋ— ϋ 1_1 Bn §ml I-

8 This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 public love) 572952 A7 B7 V. Description of invention (fc) where E8 has one of the meanings of EiS; a compound of formula (B-3)

3 (B- (Please read the notes on the back before filling out this page) where E9 and E1Q together form c2-c14 alkylene,

En is hydrogen or a formula of -Z ^ COO-Z: group group, Zi is a C2-C14 alkylene group, and Z2 is a G-C24 alkyl group, and E12 has one of the meanings of EiS; a compound of formula (B-4) HC CH- / ί14 〇II f4 H3C \\ CH, E13-N > 1 -N-II -e15 -c-I -N-N -E13 / H3C \ ch3 h3c \ ch3 As one of the meanings of EiS, E14 is independently related to hydrogen or G-Cu alkyl, and E15 is (ν〇: 1 () alkylene or C3-C1G alkylidene; a compound of formula (B-5) Paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 572952 A7 B7 V. Description of the invention (7)

-16 (B-5) in which E16 is independent of each other and has one of the definitions of E1, a compound of formula (B-6)

18 (B-6) (Please read the notes on the back before filling out this page) where Ei7 is C1-C24, and E18 has one of the definitions of Ei as a compound of formula (B-7), e21 (B- 7) Among them-e19, e2G and e21 are not related to each other (b-III) group basis -------- order --------- line one paper size applies Chinese national standards (CNS) A4 specification (210 X 297 mm) 572952 A7 B7 V. Description of the invention (§)

-22 (b-III) in which E22 has one of the definitions of Ei-a compound of formula (B-8)

CHUZC

(B-8) (Please read the notes on the back before filling out this page) where E23 is unrelated and has one of the meanings of EiS, and E24 is hydrogen, CVC ^ alkyl or CVCu alkoxy. B-9) Compound h3c ch3 Ε2—Ν Ν — h3c ch3 -------- order --------- line one-26 (B-9) where m2 is 1 '2 or 3 E25 has one of the definitions of Ei, and this paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 572952 A7 _B7_ V. Description of the invention (?) When m2 is 1, E26 is a ^ Formula CH2CHj-NH- ^, when m2 is 2, E26 is a C2-C22 academy, and when m2 is 3, E26 is a formula (b-IV) group base I28 ^ -e2-n ^ n ^ ne — Nγn (b-IV) 巳 28 where E27 is unrelated to c2-c12 alkylene, and E28 is unrelated to CVCu alkyl or (35 < 12 cycloalkyl; or (B- 10) Compounds (please read the notes on the back before filling this page)

〇 〇

Among them, E29 is independent of each other as one of the definitions of E1, and E30 is C2-C22 alkylene, C5-C7 cycloalkylene, G-C4 alkylene di (C5-C7 cycloalkylene), phenylene or Benzene di (CrQ alkylene). The component (C) is preferably a compound of the formula (C-1). 12 The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm> 572952 A7 B7. V. Invention Explanation (r)

N ——R2—N

N—Rs I r4-bi (Cl) where Ri, R3, R4 and R5 are unrelated to each other are hydrogen, C1-C12 alkyl, C5-C12 cycloalkyl, CVC4-alkyl-substituted c5-c12 ring Alkyl, phenyl, phenyl, which is substituted with -0H and / or q-Cio alkyl; C7-C9 phenyl group, C7-C9 phenyl group, which is -OH on phenyl And / or alkyl substituted; or a group of formula (cI)

(cI) and 2 are C2-C18's C5-C7 ring academy or C1-C4 academy— (C5-C7 ring academy), or Rr R2 and R3 together form with the nitrogen atom to which they are bonded A 5- to 10-membered heterocyclic ring, or R4 and R5, together with the nitrogen atom to which they are bonded, form a 5- to 10-membered heterocyclic ring, R6 is hydrogen: CVC8 alkyl, 0 ·, -0H, -CH2CN, CVCu alkoxy, c5-c12 cycloalkoxy, c3-c6 alkenyl, c7-c9 phenylalkyl, which are unsubstituted or have 1, 2 or 3 from 13 on phenyl This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page) -------- Order --------- 572952 A7 ___ B7_ V. Description of the Invention (M) CrG alkyl substituted; or CrCs 醯, and h is a number from 2 to 50, but it is limited to at least one substituent Ri, R ;, R4 and R5 Is a group of formula (cI); compound X of formula (C-2);, Ν, ΝγΝ χ2 r7

• N_ IR, γ-χ8 NγN X7 (C-2) where R7 and Ru are unrelated to each other hydrogen or CrCn alkyl, and R8, R9 and Rh) are unrelated to C2-C1G alkylene, Not related to Xi, X2, X3, X4, X5, X6, X7 and x8 are the group bases of formula (c-II),

(c-II) wherein R12 is hydrogen, crc12 alkyl, c5-c12 cycloalkyl, alkyl-substituted C5-C12 cycloalkyl, phenyl, -OH- and / or CrC1 () alkyl-substituted Phenyl, C7-C9phenylalkyl, C7-C9phenylalkyl 'which is substituted on the phenyl via -0H and / or Ci-Cw alkyl; or a group group of formula (cI) above, And 14 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ---- ^ — · ------------- ^ -------- -^ (Please read the precautions on the back before filling out this page) 572952 A7 B7 V. Description of the invention (R13 has one of the definitions of R6-a compound of formula (C-3) -Si-0-〇 (C-3 )

H3C h3c, CH, CH, where Rh is CVCio alkyl, C5-C12 cycloalkyl, (VC4 alkyl-substituted C5-C12 cycloalkyl, phenyl or CrCio alkyl-substituted phenyl, Rl5 is C3 -Ci0, R16 has one of the definitions of R6, and b2 is a number from 2 to 50; a compound of formula (C-4)

(Please read the notes on the back before filling this page)

-------- Order --------- Line I This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 572952 Μ; χν ^ 〇:-b4 A7 B7 V. Description of the invention (Π)

Rl7 and R21 are not related to each other by a direct bond or a -N (X9) -CO-XnrCO- ^ Xn) -group group, of which X9 and Xn are not related by hydrogen, Ci-Cs courtyard, C5 -Ci2 cycloalkyl group 'phenyl' C7-C9 phenylalkyl or a group of formula (cI), x10 is a direct bond or CVC4 alkylene, having one as defined in R6,

Rl9, R2G, R23 and 24 which are unrelated to each other are hydrogen, Ci_C30 alkyl, 05-(: 12 cycloalkyl or phenyl, feet 22 is hydrogen, C1-C3. Yuan 'C5-C12 ring courtyard Phenyl, C7-C9 phenylalkyl or a group of formula (〇1), and b3 is a number from 1 to 50; a compound of formula (C-5).

II • C R25 〒H R26 One CH One C—0 One 0 =? C = 0 I 0 ϊ 1 0 Ϊ H3C \] η% H3c, 〇cCH3 Η〆γ human ch3 η3〆Wide ch3 R3〇R30 (C- 5) Among them, R25, R26 _, R27, R28, and Hua9 are not related to each other by a direct bond or crc1Q alkylene, R30 has one of the definitions of R6, and 16 (Please read the precautions on the back before filling (This page) Order --------- line 1 paper size applicable to Chinese National Standard (CNS) A4 specifications (210 X 297 mm) 572952 A7 B7 V. Description of invention (W) b4 is from 1 to A number of 50; or a product (C-6), which is a product obtained by reacting a polyamine of formula (C-6-1) with monocyanuric chloride, and a reaction of a compound of formula (c_6-2): 2N- — (〇Η2) ^ γ-ΝΗ —— (CH2) —NH —— (CH2) —NH2 Η —N ——R31

H3C \ | I ^ CH. H3〇 ^^ n ^ ch. (C-6-1) (C-6-2)

R 32 where b ,, b " 5 and b " 5 are not related to each other, a number from 2 to 12 is ammonia 'C1-C12 courtyard, C5-C12 ring courtyard' phenyl or C7-c9 benzene Alkyl, and R32 have one of the definitions of R6. Examples of alkyl groups with up to 30 carbon atoms are methyl, ethyl, propyl, isopropyl, n-butyl, second-butyl, isobutyl, tert-butyl, 2-ethylbutyl , N-pentyl, isopentyl, 1-methylpentyl, '1,3-dimethylbutyl, n-hexyl, 1-methylhexyl, n-heptyl, isoheptyl, 1, 1,3,3-tetramethylbutyl, 1-methylheptyl, 3-methylheptyl, n-octyl, 2-ethylhexyl, 1,1,3-trimethylhexyl, 1, 1,3,3-tetramethylpentyl, nonyl, decyl, undecyl, 1-methylundecyl, dodecyl, 1, 1, 3, 3, 5, 17 paper Standards are applicable to China National Standard (CNS) A4 (210 X 297 mm) -------! ------------- ^ --------- (Please Read the notes on the back before filling this page) 572952 A7 _ B7__ V. Description of the Invention (ιί) 5-Hexamethylhexyl, tridecyl, tetradecyl 'pentadecyl' hexadecyl, ten Heptadecyl, octadecyl, fluorenyl, fluorenyl, and fluorenyltrialkyl · A8, Ei, E8, E1Z, En, Em, Eu, Ευ, E23, E25, E29 'R6, Rl 3' Rl6 '' Rl8 '' R30 One preferred definition of R32 is a G-C: 4-alkyl, especially methyl. More preferred is butyl. Examples of alkoxy groups with up to 18 carbon atoms are methoxy'ethoxy, propoxy, isopropoxy, butoxy, isobutoxy, pentyloxy, isopentyloxy, hexane Oxy, heptyloxy, octyloxy, decyloxy, dodecyloxy, tetradecyloxy, hexadecyloxy and octadecyloxy. One of the preferred definitions of Ei is octyloxy. E24 is preferably C1-C4 alkoxy and one of the preferred definitions of R6 is propoxy. Examples of C5-C12 cycloalkyl are cyclopentyl, cyclohexyl, cycloheptyl 'cyclooctyl and cyclododecyl. C5-C8 cycloalkyl, especially cyclohexyl, is preferred. Examples of G-C4 alkyl-substituted c5-c12 cycloalkyl are methylcyclohexyl or dimethylcyclohexyl. Examples of c5-c12 cycloalkoxy are cyclopentyloxy, cyclohexyloxy, cycloheptyloxy, cyclooctyloxy, cyclodecoxy and cyclododecyloxy. C5-(: 8 cycloalkoxy, especially cyclopentyloxy and cyclohexyloxy are preferred. Examples of -0H- and / or CrC1G alkyl-substituted phenyl are methylphenyl, diyin Phenyl, trimethylphenyl, tert-butylphenyl or 3,5-di-tert-butyl-4-hydroxyphenyl. Examples of C7-C9phenylalkyl are benzyl and phenyl Ethyl. The size of this paper applies to China National Standard (CNS) A4 (210 X 297 mm) ------- * ------------- Order ------ --- Line 1AW. (Please read the precautions on the back before filling out this page) A7 572952 V. Description of the invention (…) rr! Its households have a value of -0H and / or 1 on phenyl (3 carbon atoms are substituted, examples are methylbenzyl, dimethylbenzyl, trimethylbenzyl, tert-butylbenzyl or 3,5-di-tert-butyl 4-Hydroxybenzyl. Examples of alkenyl groups with up to 10 carbon atoms are allyl, 2-methallyl, butenyl, pentenyl and hexenyl. Allyl is preferred Ground. The carbon atom in the first position is preferably saturated. Examples of fluorenyl groups containing no more than 8 carbon atoms are methyl, ethyl, and propyl Butyl, pentamyl, hexyl, heptyl, octyl, acryl, methacryl, and benzyl. Cl_C8 alkyl, CrCs, and benzyl are preferred. Ethyl And propenyl are particularly preferred. Examples of alkylenes with up to 22 carbon atoms are methylene, ethylene, propylene, trimethyl, tetramethyl, pentamethyl, 2,2-dimethyltrimethyl Hexamethylene, hexamethylene, trimethylhexamethylene, octamethyl and octamethyl. Examples of ch3 C3-C1 () compound are one j one. Examples of ch3 C4-C1g alkyltetrayl are 1,2,3, 4-butane tetrayl. An example of a C5-C7 cycloalkylene is cyclohexylene. An example of an alkylene di (C5-C7 cycloalkylene) is methylene dicyclohexane. Phenylene di (Ci-C4 alkylene) ) Is an example of methylene-phenylene-methylene or ethylene-phenylene-ethylene. When Rt, R2 and R3 together form a 5 to 10-membered heterocyclic ring with the nitrogen atom to which it is bonded, An example of this ring is 19 paper sizes that apply the Chinese National Standard (CNS) A4 specification (__21〇X 297 public love) '' (Please read the precautions on the back before filling this page) ---- 11--Order- -------- Line 1 A7 572952 V. Description of the invention (ο)

CK D, CH; rCH2 CH; rCH / 2 I \ 2 Μ / 2 _ΚΙ! \ Κ 4 \ Ν /, -N \ Bu / CH; rCH, CH; rCK 6-membered heterocyclic ring is preferred. When R4 and R5 together form a 5- to 10-membered heterocyclic ring with the nitrogen atom to which they are bonded, examples of this ring are 1-pyrrolidinyl, piperidinyl, mandanyl, 1-tonazine , 4-methyl-1-morphazinyl, 1-hexahydroazepine, 5,5,7-trimethyl-1-heptazinyl or 4,5,5,7-tetramethyl -1-mepiperazinyl. Morinki is particularly good. One of the preferred definitions of R19 and R23 is phenyl. R26 is preferably a direct bond. , N2, n2 * and n4 are preferably a number from 2 to 25, especially a number from 2 to 20. n3 is preferably a number from 1 to 25, especially a number from 1 to 20, and b2 is preferably a number from 2 to 25, especially a number from 2 to 20. 1 b3 and b4 are preferably numbers from 1 to 25, especially numbers from 1 to 20. b'5 and b '' '5 are preferably 3, and b''5 is preferably 2. The compounds of the above components (A), (B) and (C) are mainly conventional and have been commercialized. All these compounds can be prepared by conventional methods. The preparation of the component (A) is described in, for example, US-A-4, 233, 20 This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 572952 A7 ____B7_ _ V. Description of the invention (α) 412, US-A-4, 340, 534, WO-A-98 / 51, 690 and EP-A. 1,803. The preparation of the component (B) compound is described in, for example, US-A-5,679,733 , US-A-3,640,928, US-A-4,198,334, US-A-5,204,473, US-A-4,619,958, US-A-4,110,306 , US-A-4, 110, 334, US-A_4, 689, 416, US-A-4, 408, 051, SU-A-768, 175 (Derwent 88-138, 751/20), US-A -5,049,604, US-A-4,769,457, US-A-4,356,307, US-A-4,619,956, US-A-5,182,390, GB-A -2,269,819, US-A-4,292,240, US-A-5,026,849, US-A-5,071,981, US-A-4,547,538 and US-A -4,976,889. The preparation of the component (C) compound is described in, for example, US-A-4, 086, 204 j US-A_6, 046 '3 04' US-A-4 '331' 586, US-A-4, 108, 829, US-A-5, 051, 458, WO-A-94 / 12, 544 (Derwent 94-177, 274/22), DD-A-262, 439 (Derwent 89-122, 983/17), US- A-4, 857, 595, US_A-4, 529, 760 and US-A-4, 477, 615 and CAS 136, 504-96-6. The product (C-6) can be prepared by conventional methods, for example, in the presence of anhydrous lithium carbonate, sodium carbonate or potassium carbonate in an organic solvent, such as 1,2-dichloroethane, toluene, xylene , Benzene, dioxane or tert-pentyl alcohol, in the temperature range T 2 0 ° C to + 10 ° C, preferably from -10 ° C to + 10 ° C, especially 0 ° C Between + 1 0 ° C, the reaction formula (C-6-1) polyamine and hydrogen urethane chloride from 2 to 8 hours, the reaction mole ratio is 1: 2 to 1 z 21 This paper size applies Chinese national standards ( CNS) A4 specification (210 X 297 mm) -------------------- Order--------- Cord (Please read the precautions on the back first (Fill in this page again) 572952 A7 ____B7 _ V. Description of the invention (〇) 4 and then reacting the resulting product with 2, 2, 6, 6-tetramethyl-4 4-piperidylamine of formula (c-6-2) To get. The molar ratio of 2,2,6,6 —tetramethyl-4-piperidylamine and polyamine of formula (C-6- 丨) is, for example, 4: 1 to 8: 1,2,2,6,6 — Tetramethyl-4 piperidylamine can be added all at once, or in several hours. The polyamine of formula (C-6-1): cyanuric chloride and the pair of formula: (C-6_2) The molar ratio of 2,2,6,6-tetramethyl-4-P sinimidine is preferably ι : 3: 5 to ι: 3: 6 ·. The following example illustrates the way to prepare a preferred product (C-6-a). Firm offer! 2 3 · 6 g (0.128 mol) of cyanuric chloride, 7.3 g (0 · 0 4 2 6 mol) of N, N, -bis [3-aminopropyl] Ethylene diamine and 18 g (0.13 mol) of anhydrous potassium carbonate were reacted at 5 ° C: in 250 ml of 1,2-dichloroethane for 3 hours. The reaction mixture was kept in the chamber. Heat for another 4 hours at room temperature, add 27.2 g (0.112 mol) of N- (2,2,6,6-tetramethyl-4-piperidyl) butylamine, and add The resulting mixture was heated at ° C for 2 hours, and then 18 g (0.13 mol) of anhydrous potassium carbonate was added, and the mixture was heated at 60 ° C for 6 hours. The solvent was slightly vacuumed (200 mbar) and distilled. And replace with xylene. 18.2 g (0.085 mole) of N_ (2,2,6,6-tetramethyl-4- 4-meridinyl) butylamine and 5.2 g (0. 1 3 Mol) powdered sodium hydroxide, heating the mixture under reflux for 2 hours, and heating for another 12 hours, during which the water produced is azeotropically removed. The mixture is filtered, the solution is washed with water and dried Na2S04, the solvent is evaporated, and the residue At 120 — 130 ° C and under vacuum (0.1 mbar) Dry, you can get a desired product in the form of a colorless resin. 22 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page)-Order- ------- Line · 572952 A7 B7 V. Description of the invention (/) Generally speaking, the product (C-6) can be expressed by the formula (C-6-α), (C-6-β) or (C -6-γ) represented by the compound, which may also be a mixture of these three compounds.

HN (CH2), 2-12

N (CH2) 2-12?-(^ 2Τ2ΝΗ K31 N N CH3 h3c > [A] < ch ch3 h3c N ch3 h3c

IN h3c / \ ch3 H3C HX N CH, H3C

R 32

R 32 R, 32

CH, read the note on the back (C-6-α) ί (CH2) 2-12 N / N ^ N ^ n-R3 (ch2x 2-12 (CH2), 2-12 R31 h3c > tVh, h3c n ch3 R32 R31 h3c A ch3 h3c Λι 〇η ^ 3〇Λ ch3 h3c Λ, 〇h

N ΟΗΉΧ N R h3c N C— r32 r: ch3 h3c n ch2 R32 (C-6-β) 23 This paper size applies to China National Standard (CNS) A4 (210 x 297 mm) 572952 A7 B7

The formula (C-6-α) is better defined as

HN (ch2). 3

N (ch2) 2-

N — (CH2) 3— NH

N " N 〇4H9-n n-H9C4 N " N rH n N " NW / / Yanyan name 4, / NNNNN Η3〇Λ〇Η3 Η3 ° Λ〇Η3 Η3 ° Λ〇Η3 Η3 ° Λ0Η3Η3 ^ / \ h3c ν CH, h, cn ^ ch. hc n ^ ch. HX _ ch3 h3c ^ ch3 h3c γ ch3 h3c η Η h

IH C4H9-n CH3 ch3 (Please read the precautions on the back before filling in this page) 5 Orders --------- line. The formula (C-6-β) is better defined as 24 paper sizes applicable China National Standard (CNS) A4 specification (210 χ 297 mm) 572952 A7 B7 V. Description of the invention (Η3 ° Λ 〇 Η h3c n ch3 H n-H9C4 (ch2l

N " N C4H9-n n-H9C4 N " N C4H9-n

IN " IN " H3C CH3 H3C CH3 H3C CK H.C ^ N ^ rH. HX N CH, HX N ^ CH HX N CK

H3C n ch3 h3c ^ ch3 h3c Η H

CH3H3C Η H formula (C-6-γ) is better defined as

(Please read the notes on the back before filling out this page)-------- ^ --------- ^. In the above formulas (C-6-α) to (C-6-γ Among the compounds), b5 is preferably 2 to 20, especially 2 to 10. Ingredient (A) is preferably TINUVIN 622 (RTM), HOSTAVINN30 (RTM) or FERROAM 806 (RTM). Ingredient (B) is preferably DASTIB 845 (RTM), TINUVIN 770 (RTM), TINUVIN 765 (RTM), TINUVIN 144 (RTM), TINUVIN 123 (RTM), ADK STAB LA 52 (RTM), 25 paper sizes Applicable to China National Standard (CNS) A4 (210 X 297 mm) 572952 A7 B7 V. Description of the invention () (Please read the notes on the back before filling this page) ADK STAB LA 57 (RTM), ADK STAB LA 62 (RTM), ADK STAB LA 67 (RTM), HOSTAVIN N 20 (RTM), HOSTAVIN N 24 (RTM), SANDUVOR 3050 (RTM), DIACETAM 5 (RTM), SUMISOR TM 61 (RTM), UVINUL 4049 (RTM) , SANDUVOR PR 31 (RTM) ^ GOODRITE UV 3034 (RTM), GOODRITE UV 3150 (RTM), GOODRITE UV 3159 (RTM), GOODRITE 3110 x 128 (RTM) or UVINUL 4050 H (RTM). Composition (C) is better The locations are CHIMASSORB 944 (RTM), CHIMASSORB 2020 (RTM), CYASORB UV 3346 (RTM), CYASORB UV 3 529 (RTM), DASTIB 1082 (RTM), CHIMASSORB 119 (RTM), UVASIL 299 (RTM), UVASIL 125 ( RTM), UVASIL 2000 (RTM), UVINUL 5050 H (RTM), LICHTSCHUTZSTOFF UV 31 (RTM), LUCHEM HA B 18 (RTM), ADK STAB LA 63 (RTM), ADK STAB LA 68 (RTM) or UVASORB HA 88 (RTM). Saturated formula (Al), (A-2-a), (A-2-b), (A-4), (Cl), (C-3), (C-4), (C-5), The definitions of the (C-6-α), (C-6-β) and (C-6-γ) free valency terminal groups depend on the preparation method used. This terminal group can also be adjusted after the compound is prepared. If the compound of formula (A-1) is, for example, a compound of formula

CH factory CH —〇H 2 I A, 26 This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 572952

A7 ____ Β7_ V. Description of the Invention (W) where Aι is hydrogen or methyl, and a dicarboxylic acid diester of the formula Y-OOC_A2-COO-Y, where Y is, for example, methyl, ethyl or Propyl, and A2 are as defined above, and the terminal group bonded to 2,2,6,6-tetramethyl-4-oxonadin-1-yl is hydrogen or < 0-octa 2-COO -Y, and the terminal group bonded to the difluorenyl group is -0-Y or

CH—CH —0H

I In the compound of formula (A-2-a), the terminal group bonded to a nitrogen atom is, for example, hydrogen and the terminal group bonded to 2-hydroxypropylene are, for example,

Group base. In the compound of the formula (A-2-b), the terminal energy for bonding to a dimethylene group is, for example, -0H, and the terminal energy for bonding to an oxygen atom is, for example, hydrogen. The terminal group can also be a polyether group. In the compound of formula (A-4), the terminal energy of the terminal group bonded to the -CH2- group is, for example, hydrogen and the terminal energy of the terminal group bonded to the -CH (C02A7) group is, for example, -CH = CH- COOA7 〇27 This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page) -------- Order ------ --- line · 572952 A7 _B7_ V. Description of the Invention (/) Suppose that the compound of formula (C-1) is a compound of formula

N——R5

I r4 (please read the notes on the back before filling out this page) where X is, for example, halogen, especially chlorine, and R4 and R5 are as defined above, which can be prepared by reacting with the compound of the formula

′, 3 where I, R2 and r3 are as defined above, and the terminal group bonded to the diamine group is hydrogen or

N ^ / N fjl — R5 R4 and the terminal group bonded to the triazinyl group is X or

When x is a halogen, when the reaction is completed, it is advantageous to substitute, for example, -0H or a monoamine group. Examples of the above amine groups are pyrrolidin-1-yl, morpholine, -NH2, -N (CrC8) alkyl) 2 and -NR (CrC8alkyl), wherein R is hydrogen or a group of formula (c-I). 28 This paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) 572952 A7 B7 V. Description of the invention (d) Compounds of formula (C-1) also include compounds of the following formula, N, λ5 * R "Jrr —?

r4 *

Where Ri, R2, R3, R4, R5 are as defined above, and R4 * has one of the definitions of R4, and R5 * has one of the definitions of R5. One of the particularly preferred compounds of formula (C-1) is N 1 5 > 1--N (〇 ^) 6 — N-\-γ '7! -N — (CH,) «-N

HA LCH3 H3C ί 1 CH3 CH3 Η3〇ΑΝCH3 ^ H3C I I 0¾ H3C N CH3 H3C N CH, I I Η 1 b1

---------------- II ^ · 111111 丨 I (Please read the precautions on the back before filling this page) The preparation of this compound is disclosed in US-A-6,046,304 Example 1 0. In the compound of formula (C-3), the terminal energy of the terminal group bonded to the silicon atom is' for example, (R14) 3Si-0-, and the terminal energy of the terminal group bonded to the oxygen atom is, for example, -Si (R14 ) 3. Provided that t > 2 is a number from 3 to 10, the compound of formula (C-3) can also be a form of a cyclic compound, that is, the free valence in the structural formula forms a direct bond. 29 This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 572952 A7 B7 V. Description of the invention (> 7) In the compound of formula (C-4), it is bonded to 2,5-two The terminal group of the pendant pyrrolidine ring is, for example, 'hydrogen' and the terminal group bonded to -C (R23) (R24)-is, for example, 1 1 or — ~ T—Ί 0, ya ', 〇

R CH, '18 In the compound of formula (05), the terminal group bonded to the carbonyl group is, for example (Please read the precautions on the back before filling this page)

h3c ^ vn ^ < ^ ch R 22

And the terminal group bonded to the oxygen atom is, for example, 〇 II • CH—R2 ~ t—C—0 I 27 c = o

〇 II -C—Rii ~ 〒H_ 〇 二 c " ^ 26 ~

In compounds of the formula-(C-6-α) '(C-6-β) and (C-6-γ), the terminal group bonded to the triazine is, for example, C1 or the formula. Standard (CNS) A4 specification (21 × 297 mm) 572952 A7 B7 V. Description of invention (4

The group group, and the terminal group bonded to the amine group are, for example, hydrogen or a

IN IN, 31,

H3C is literally H3c N CH3

h3c ^ i L-CH3 h3c into Guangch3 R32 (Please read the precautions on the back before filling this page)-Group A8 is preferably hydrogen, C1-C4 courtyard, Ci-Cio courtyard's cyclohexyloxy Group, allyl, benzyl or ethenyl. E1, e8, E12, E13, Ei6, E18, E22 'E23' e25 and E29 are preferably hydrogen, Cj-C 4 alkyl, Cr C10 oxygen 'rm bad hexyloxy, allyl, benzyl Or ethyl. R6, R13, R16, R18'R30 and preferably argon, C1-C4 alkyl'Cl-ClO alkoxy, cyclohexyloxy, allyl, benzyl or ethynyl. Ag 'Eι, E8, Ei2, E13, E16, Ei8, E22, E23, e25, E29, R6, Rl3' R16, Rl8 'R30 and R32 Special ---------- Order -------- -Line- other than hydrogen or methyl and Ei and R6 are additionally CrCs alkoxy groups. According to a preferred embodiment,

Ai is hydrogen or methyl, A2 is a direct bond or c2-c6 alkylene, and 31 This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 572952 A7 _B7_ V. Description of the invention (4) ! 1 丨 is a number from 2 to 25; Π2 and n2 * are a number from 2 to 25; A3 and A4 are unrelated to each other hydrogen or GG alkyl, or A3 and A4 together form a C9- Cl3 courtyard support, and the variable n3 are unrelated to each other from a number from 1 to 25; m is a number from 2 to 25, and 8 5 and Α ° are not related to each other are C1-C4 courtyard, and A7 Is a GG alkyl group or a group of formula (aI) but provided that at least 50% of A7 is a group of formula (aI). According to another preferred embodiment, mi is 1, 2, or 4, and if mi is 1, E2 is C12-C2. Yuan 5 If πυ is 2, E2 is C2-Ch) alkylene or a group of formula (bI) E3 is CVC4 alkyl, E4 is Cl-C6, and E5 and E6 are independent of each other and Ci- C4 alkyl, and if mi is 4, E2 is 0 (: 8 alkyl tetrayl; two E? Are -COCMGo-C ^ alkyl), and two E? Are a group of formula (b-II); E9 and Eh) together form OCu alkylene,

En is hydrogen or a -Zi-COO-Z: group group,

Zi is C2-Q6 alkylene, and Z2 is ClO-Cl6 courtyard;

El4 is nitrogen, and 32 paper sizes are applicable to China National Standard (CNS) A4 specifications (210 X 297 mm) (Please read the precautions on the back before filling this page) Order ·· | Line · 572952 A7 ____ B7 ___ Five , Description of the invention ()

El5 is a C2-C6 stirrup or a C3-C5 courtyard fork;

El7 is Cl0-Cl4; E24 is 0C4 alkoxy; m2 is 1, 2 or 3; when in2 is 1, E26 is a ch2ch "nhh ^) group group; when iru is 2, Em Is C2-C6 academy, and when m2 is 3, E26 is a group of formula (b-IV) E27 is unrelated to C2-C6 alkylene, and E28 is unrelated to GG alkyl or ( ^ Cycloalkyl; and E30 is C2-C8 courtyard support. According to another preferred embodiment

Ri and R3 are unrelated to each other by a formula (cI) group group, R2 is a C2-C8 academy, and R4 and R5 are unrelated to each other are hydrogen, G-Cu alkyl, Cs-C8 cycloalkyl, or a formula ( cI) the group group, or R4 and r5, together with the nitrogen atom to which they are bonded form a 5- to 10-membered heterocyclic ring, and h is a number from 2 to 25; R7 and Rn are unrelated to each other, respectively Hydrogen or alkyl,

Rs, R9 and Ri. Irrelevant are C2-C4 alkylene, and ′ X2 ′ χ3, χ4 ′ χ5 ′ χ6 ′ χ7 and χ8 which are irrelevant to each other are group groups of formula (c-II),

Rn is 氲, Ci-C% courtyard foundation, CVG circle courtyard foundation or monotype (cI) group foundation 33 (Please read the precautions on the back before filling this page)-This paper size applies to China National Standard (CNS) A4 specifications ( 210 X 297 mm) 572952 A7 _B7_ V. Description of the invention (〃)

Rl4 is Cl-C4 Academy '(Please read the notes on the back before filling this page)

Rl5 is C3-C6, and b2 is a number from 2 to 25;

Rn and R21 are not related to each other by a direct bond or the following group group -N (X9) -CO-Xi〇-CO-N (Xh)-^ x9 and Xn are not related to each other hydrogen or GG alkyl group , Χι. Is a direct key,

Rl9 and Ru are C1-C25 fluorenyl or phenyl, R20 and R24 are nitrogen or C1-C4 radical 5 R22 is G-C25 alkyl or a group of formula (cI), and b3 is a number from 1 to 25 ; R25 5 R26 'R27' R28 and R29 are unrelated to each other by a direct bond or G-C4 alkylene, and b4 is a number from 1 to 25;-line b'5, b " 5 and b & quot '5 unrelated to each other are a number from 2 to 4, and

Rn is hydrogen, G-C4 alkyl, G-G cycloalkyl, phenyl or benzoyl. A particularly preferred embodiment of the present invention relates to a stabilizer mixture, wherein component (A) is of the formula (A-1-a), (A-2-a), (A-2-b), (A-3 -a) or (A-yea) compounds; 34 This paper size applies the Chinese National Standard (CNS) A4 (210 X 297 mm) 572952 A7 B7 V. Description of the invention (β

Where IM is a number from 2 to 20; 0H h3c xch,

H3C ch3 ΌΗ2—CH — CH Factory N

3 〇

-Π2 (Ala) n1 (A-2-a) Π2 (A-2-b) (Please read the precautions on the back before filling this page) --I ---- Order -------- -. Where η2 and η2 * are a number from 2 to 20;

h3c ch;

H3C CH3 ο

(^ 一 「叫 9 -CH, N —Ch ^ —CH —CHj—N 0 HX CH, OH CHj-

H3C ch3

OH I CHj — CH—CHj — N (CH2) r 35 This paper size applies to Chinese National Standard (CNS) A4 (210 x 297 mm) O H3C. Ch3 I, ch3

h3c (CH2) 9 — Ch (A-3-a) n3 572952 A7 B7 V. Description of the invention (0) Where the variables n3 are unrelated to each other and are numbers from 1 to 20;

One CK I -CH2—c—CH- 2 I 2 c = oI 〇I CK -CH-

I c = o 〇 A7 Π4 where n4 is a number from 2 to 20, and at least 50% of the people 7 are a group basis of (a-I)

(aI) (A-4-a) where A8 is hydrogen, CVQ alkyl, OH, -OH, -CH2CN, < ^-(: 18 alkoxy, C5-C12 cycloalkoxy, C3-C6 Alkenyl, C7-C9 phenylalkyl, which is unsubstituted or substituted with 1, 2 or 3 CrC4 alkyl groups on the phenyl group; or CrC8fluorenyl, and the remaining A7 is ethyl; ingredients (B) is a formula (B-1-a), (B-1-b), (B-1-c), (B-1-d), (B-2-a), (B-3- a), (B-3-b), (B-4-a), (B-4-b), (B-5), (B-6-a), (B-7), (B- 8-a), (B-9-a), (B-9-b), (B-9-c) or (B-10-a) compounds; 36 This paper is applicable to Chinese National Standard (CNS) A4 Specifications (210 X 297 mm) (Please read the precautions on the back before filling out this page) ------- Order --------- line · 572952 A7 B7 V. Description of the invention (A)

Ο—C— (C15-C17alkyl)

〇II (B-l-a) h3c ch3

〇II

〇 II 0—C— (CH2) 8—c—o

: c I 〇 〇: H 4 c, c

CH

(CH OH 11 (B- (Please read the notes on the back before filling this page)

CH (CH c (HX2IC. Ο ο CH—C — ο CH- -d) 11 (B- ο C——ο ο C- o 6

N——E

N——E-line · where Ei is hydrogen, Ci-C8 alkyl, 0 ·, -OH, -CH2CN, (^ / ^ alkoxy, C5-C12 cycloalkoxy, C3-C6 alkenyl, C7 -C9 phenylalkyl, which is unsubstituted, or substituted with 1, 2, or 3 CVC4 alkyl groups on the phenyl group; or (^ -cardiacyl; chloro-CH-CH-CH2 (B- 2-a) E7 e7 e7 e7 37 This paper size applies to the Chinese National Standard (CNS) A4 (210 x 297 mm) 572952 A7 B7 V. Description of the invention (of which two E7 are -COO-C13H27 and two e7 are

N — E8 and E8 have one of the definitions of Ei;

(B-3-a) (Please read the notes on the back before filling this page) 〇

CH II / C CH2CH ^ —C—0— (C12-C14alkyl) (9 ^ 2) 9 \ · Where E12 has one of the meanings of EiS; (B-3-b) CH,, C = 0

Order --------- line ·

〇II ch2ch2-c-

(B-4-a) 38 This paper size applies to Chinese National Standard (CNS) A4 specifications (210 X 297 mm) 572952 A7 B7 V. Description of the invention (^)

13 (B-4-b) where E13 has one of the meanings of EiS;

16 (B-5) (Please read the notes on the back before filling out this page) See E16 which has one of the definitions of Ei

18 (B-6-a)

Where E18 has one of the definitions of E! 'X (B-7)

Ε, 〇 II E21, N,, N

cr i, 〇 e2〇 Among them, E19, E2q, and E21 are unrelated to each other (b-III) group basis 39 ------- 1T --------- ^ great! ----------------- This paper size applies to China National Standard (CNS) A4 (210 x 297 mm) 572952 A7 B7 V. Description of the invention () 2 in 2

22 where E22 has one of the definitions of Ei: h3co

CHZZC

-a) -8- (B- (Please read the notes on the back before filling this page) where E23 has one of the definitions of Ei: h3c ch3 Ν λ Ε2—Ν Ν——CH2CH2—ΝΗ

-a) -9- (B- h3c ch3 h3c ch3 CH. —Ν N——CH2CH2—Ν N E25 λ- " ^ -9- (B- ------- order ------ ---line·

h3c CHU h3c CH3 This paper size applies to Chinese National Standard (CNS) A4 (210 x 297 mm) 572952 A7 B7

V. Description of the invention (W H3C ΡΗ3 ο

〇, H3c, CH,

N——CH, CH --- N 7 < (B-9-c) h3c

CK h3c ch3 〇, H3C, CH, N——CH2CH2—N N—E ?,

H3c CH3 where E25 has one of the definitions of Ei:

(CH T • N onch-

10- (B- (Please read the notes on the back before filling out this page)

CH where E29 has one of the meanings of EiS; component (C) is a formula (C-1_a), (Clb) '(Clc), (Cld), (C-2-a), (C-3-a ), (C-4-a), (C-4_b), (C-4-c) or (C-5-a) compound or a product (C-6-a);

(Cla) 41 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ϋ nn ϋ n-^-OJf n ϋ ϋ · ϋ n ϋ ϋ I-572952 A7 _B7 V. Description of the invention () ?)

(C-l-b)

(C-l-c) (Please read the notes on the back before filling this page)

(Cld) where the ratio is a number from 2 to 20, and R6 is hydrogen, CVQ alkyl, 0, -OH, -CH2CN, ^-(^ alkoxy, C5-C12 cycloalkoxy, C3- C6 alkenyl, C7-C9 phenylalkyl, which is unsubstituted or substituted with 1, 2 or 3 CrCU alkyl groups on the phenyl group; or C! -C8 acid group; 42 This paper applies China National Standard (CNS) A4 Specification (210 X 297 mm) 572952 A7 B7 V. Description of the Invention (Noon.) Η—Ν · Ν < ^ Ν

c4h9 h9c4,

Η9〇4

NIR

NIR 2 (C-2—a) where Rn has one of the definitions of R6

(C-3-a) (Please read the notes on the back before filling this page)

Where b2 is a number from 2 to 20, and R16 has the same meaning as defined in R6

HIC——c——c Factory 丨 H 2 3 Η Η 3 b --- 1 ---- Order · ----- I --- 4- (C- 43 This paper size applies to Chinese National Standard (CNS ) A4 specification (210 X 297 mm) 572952 A7 B7 V. Description of invention U 丨)

Where b3 is one from one; to the number 20, and R18 has as defined in R6

b4 (Please read the notes on the back before filling this page) ----------------. (C-5-a) where b4 is a number from 1 to 20, and R3Q has one of the definitions of R6; 44 This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 572952 A7 B7 V. Description of the invention (outside >) One product (C-6-a ), The product obtained by the reaction of polyamine of formula (C-6-la) and cyanuric chloride is reacted with a compound of formula (C-6-2-a) to obtain H2N- (CH2) -NH- (CH2) -—NH —— (CH2) —NH2 (C-6-la) (C-6-2-a) Η — Ν-C4H9

H3C attacked CH, h3c ^^ n ^ ch.

R 32 wherein R 32 has one of the definitions of R 6. A particularly preferred embodiment of the present invention also relates to a stabilizer mixture, wherein component (A) is a compound of formula (A-1-a), where η! Is a number from 2 to 20, or a formula (A_2_a) or ( A-2-b) compounds, where n2 and n2 * are a number from 2 to 20, component (B) is a compound of formula (B-1-b), where Ei is hydrogen 'and component (C) is a formula ( C-1-a) compounds where the ratio is a number from 2 to 20 and R6 is hydrogen, or a compound of formula (C-1-b) where R6 is hydrogen or propoxy and the ratio is one from 2 To a number of 20, or a compound of formula (C-1-d), wherein R6 is hydrogen or methyl, and br is a number of 2 to 20, or a compound of formula (C-2-a), wherein Rn is a form Or a compound of formula (C-3-a), wherein R16 is hydrogen, and b2 is a number from 2 to 20, or a compound of formula (C-4-a), wherein R18 is hydrogen, and b3 is A number from 1 to 20, or a product (C-6-a). 45 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling out this page)------ Order · -------- · 572952 A7 ____B7___ 5. Description of the invention (〇) Another particularly preferred embodiment of the present invention is a stabilizer mixture, wherein component (A) is a compound of formula (A-ha), where ~ is a number from 2 to 20 , Or a compound of formula (A-2-a) or (A-2-b), where n2 and n2 * are numbers from 2 to 20, and component (B) is a compound of formula (B-1-b), where Ei is hydrogen, and component (C) is a compound of formula (C-1-a), where the ratio is a number from 2 to 20, and R6 is hydrogen. An example of the stabilizer mixture of the present invention is a combination of the following commercial products: 1. TINUVIN 622 (RTM) + CHIMASSORB 944 (RTM) + TINUVIN 770 (RTM) 2. TINUVIN 622 (RTM) + CHIMASSORB 944 (RTM) + TINUVIN 765 (RTM) 3. TINUVIN 622 (RTM) + CHIMASSORB 944 (RTM) + TINUVIN 144 (RTM) 4. TINUVIN 622 (RTM) + CHIMASSORB 944 (RTM) + TINUVIN 123 (RTM) 5. TINUVIN 622 (RTM) + CHIMASSORB 944 (RTM) + compound of formula (B-3-a), where & 2 is hydrogen 6. TINUVIN 622 (RTM) + CHIMASSORB 944 (RTM) + HOSTAVIN N 24 (RTM) 7. TINUVIN 622 (RTM) + CHIMASSORB 944 (RTM) + DIACETAM 5 (RTM) 8. TINUVIN 622 (RTM) + CHIMASSORB 944 (RTM) + ADK STAB LA 52 (RTM) 9. TINUVIN 622 (RTM) + CHIMASSORB 944 (RTM) + ADK STAB LA 57 (RTM) 10. TINUVIN 622 (RTM) + CHIMASSORB 944 (RTM) + ADK STAB LA 62 (RTM) 11. TINUVIN 622 (RTM) + CHIMASSORB 944 (RTM) + ADK STAB LA 67 (RTM) 12. TINUVIN 622 (RTM) + CHIMASSORB 944 (RTM) + GOODRITE UV 3034 (RTM) 13. TINUVIN 622 (RTM) + CHIMASSORB 944 (RTM) + GOODRITE UV 3150 (RTM) 14. TINUVIN 622 (RTM) + CHIMASSOR B 944 (RTM) + GOODRITE UV 3159 (RTM) 15. TINUVIN62i (RTM) + CHIMASSORB 944 (RTM) + compound of formula (B-9-a), where E25 is hydrogen 16. TINUVIN 622 (RTM) + CHIMASSORB 944 ( (RTM) + UVINUL 4049 (RTM) 46 This paper size applies to China National Standard (CNS) A4 (210 x 297 mm) (Please read the precautions on the back before filling this page) Order -------- -Line. 572952 A7 ___B7_ V. Description of the invention (correction) 17. Ding 拊 11 ¥ ^ 622 (1 ^^) + (^ 1) ^ 人 3301 ^ 944 (1 ^ 1 ^) + Formula 1 (^) Compound , Of which £ 29 is hydrogen 18. TINUVIN622 (RTM) + CHIMASS〇RB944 (RTM) + compound of formula (B-1-a), where & is hydrogen (please read the precautions on the back before filling this page) 19. TINUVIN 622 (RTM) + CHIMASSORB 944 (RTM) + SUMISOR TM 61 (RTM) 20. TINUVIN 622 (RTM) + CHIMASSORB 944 (RTM) + SANDUVOR 3050 (RTM) 21. TINUVIN 622 (RTM) + CHIMASSORB 944 (RTM) + SANDUVOR PR-31 (RTM) 22. TINUVIN 622 (RTM) + CHIMASSORB 119 (RTM) + TINUVIN 770 (RTM) 23. TINUVIN 622 (RTM) + CHIMASSORB 119 (RTM) + TINUVIN 765 (RTM) 24. TINUVIN 622 (RTM) + CHIMASSORB 119 (RTM) + TINUVIN 14 4 (RTM) 25. TINUVIN 622 (RTM) + CHIMASSORB 119 (RTM) + TINUVIN 123 (RTM) 26. TINUVIN 622 (RTM) + CHIMASSORB 119 (RTM) + compound of formula (B-3-a), where E12 is Hydrogen 27. TINUVIN 622 (RTM) + CHIMASSORB 119 (RTM) + HOSTAVIN N 24 (RTM) 28. TINUVIN 622 (RTM) + CHIMASSORB 119 (RTM) + DIACETAM 5 (RTM) 29. TINUVIN 622 (RTM) + CHIMASSORB 119 (RTM) + ADK STAB LA 52 (RTM) 30. TINUVIN 622 (RTM) + CHIMASSORB 119 (RTM) + ADK STAB LA 57 (RTM) 31. TINUVIN 622 (RTM) + CHIMASSORB 119 (RTM) + ADK STAB LA 62 (RTM) 32. TINUVIN 622 (RTM) + CHIMASSORB 119 (RTM) + ADK STAB LA 67 (RTM) 33. TINUVIN 622 (RTM) + CHIMASSORB 119 (RTM) + GOODRITE UV 3034 (RTM) 34. TINUVIN 622 (RTM) ) + CHIMASSORB 119 (RTM) + GOODRITE UV 3150 (RTM) 35. TINUVIN 622 (RTM) + CHIMASSORB 119 (RTM) + GOODRITE UV 3159 (RTM) TINUVIN 622 (RTM) + CHIMASSORB 119 (RTM) + formula (B- 9-a) compound where E25 is hydrogen 37. TINUVIN 622 (RTM) + CHIMASSORB 119 (RTM) + UVINUL 4049 (RTM) 38. TINUVIN 622 (RTM) + CHIMASSORB 119 (RTM) + formula (B-10-a ) Compound, E29 is hydrogen 39. TINUVIN 622 (RTM) + CHIMASSORB 119 (RTM) + compound of formula (Bla), where & is hydrogen 40. TINUVIN 622 (RTM) + CHIMASSORB 119 (RTM) + SUMISOR TM 61 (RTM) 41 . TINUVIN 622 (RTM) + CHIMASSORB 119 (RTM) + SANDUVOR 3050 (RTM) 42. TINUVIN 622 (RTM) + CHIMASSORB 119 (RTM) + SANDUVOR PR-31 (RTM) 43. TINUVIN 622 (RTM) + CHIMASSORB 2020 ( RTM) + TINUVIN 770 (RTM) 47 This paper size applies to Chinese National Standard (CNS) A4 (210 x 297 mm) 572952 A7 _B7_ V. Description of the invention (β) 44. TINUVIN 622 (RTM) + CHIMASSORB 2020 (RTM ) + TINUVIN 765 (RTM) 45. TINUVIN 622 (RTM) + CHIMASSORB 2020 (RTM) + TINUVIN 144 (RTM) 46. TINUVIN 622 (RTM) + CHIMASSORB 2020 (RTM) + TINUVIN 123 (RTM) 47. TINUVIN 622 ( RTM) + CHIMASSORB 2020 (RTM) + compound of formula (B-3-a), where E12 is hydrogen 48. TINUVIN 622 (RTM) + CHIMASSORB 2020 (RTM) + HOSTAVIN N 24 (RTM) 49. TINUVIN 622 (RTM) + CHIMASSORB 2020 (RTM) + DIACETAM 5 (RTM) 50. TINUVIN 622 (RTM) + CHIMASSORB 2020 (RTM) + ADK STAB LA 52 (RTM) 51. TINUVIN 62 2 (RTM) + CHIMASSORB 2020 (RTM) + ADK STAB LA 57 (RTM) 52. TINUVIN 622 (RTM) + CHIMASSORB 2020 (RTM) + ADK STAB LA 62 (RTM) 53. TINUVIN 622 (RTM) + CHIMASSORB 2020 ( RTM) + ADK STAB LA 67 (RTM) 54. TINUVIN 622 (RTM) + CHIMASSORB 2020 (RTM) + GOODRITE UV 3034 (RTM) 55. TINUVIN 622 (RTM) + CHIMASSORB 2020 (RTM) + GOODRITE UV 3150 (RTM) 56. TINUVIN 622 (RTM) + CHIMASSORB 2020 (RTM) + GOODRITE UV 3159 (RTM) 57. TINUVIN 622 (RTM) + CHIMASSORB 2020 (RTM) + compound of formula (B-9-a), where E25 is hydrogen 58. TINUVIN 622 (RTM) + CHIMASSORB 2020 (RTM) + UVINUL 4049 (RTM) 59. TINUVIN 622 (RTM) + CHIMASSORB 2020 (RTM) + compound of formula (B-10-a), where ν is hydrogen 60. TINUVIN 622 ( RTM) + CHIMASSORB 2020 (RTM) + compound of formula (Bla), where & is hydrogen 61. TINUVIN 622 (RTM) + CHIMASSORB 2020 (RTM) + SUMISOR TM 61 (RTM) 62. TINUVIN 622 (RTM) + CHIMASSORB 2020 (RTM) + SANDUVOR 3050 (RTM) 63. TINUVIN 622 (RTM) + CHIMASSORB 2020 (RTM) + SANDUVOR PR-31 (RTM) 64. TINUVIN 622 (RTM) + CYASORB UV 3346 (RTM) + TINUVIN 770 (RTM) 65. TINUVIN 622 (RTM) + CYASORB UV 3346 (RTM) + TINUVIN 765 (RTM) 66. TINUVIN 622 (RTM) + CYASORB UV 3346 (RTM) + TINUVIN 144 (RTM) 67. TINUVIN 622 ( RTM) + CYASORB UV 3346 (RTM) + TINUVIN 123 (RTM) 68. TINUVIN 622 (RTM) + CYASORB UV 3346 (RTM) + compound of formula (B-3-a), where El2 is hydrogen-69. TINUVIN 622 ( (RTM) + CYASORB UV 3346 (RTM) + HOSTAVIN N 24 (RTM) 70. TINUVIN 622 (RTM) + CYASORB UV 3346 (RTM) + DIACETAM 5 (RTM) 48 This paper size applies the Chinese National Standard (CNS) A4 specification ( 210 x 297 mm) '(Please read the notes on the back before filling this page)-# ». I-line · 572952 A7 ___B7_ V. Description of the invention (0) 71. TINUVIN 622 (RTM) + CYASORB UV 3346 (RTM ) + ADK STAB LA 52 (RTM) 72. TINUVIN 622 (RTM) + CYASORB UV 3346 (RTM) + ADK STAB LA 57 (RTM) 73. TINUVIN 622 (RTM) + CYASORB UV 3346 (RTM) + ADK STAB LA 62 (RTM) 74. TINUVIN 622 (RTM) + CYASORB UV 3346 (RTM) + ADK STAB LA 67 (RTM) 75. TINUVIN 622 (RTM) + CYASORB UV 3346 (RTM) + GOODRITE UV 3034 (RTM) 76. TINUVIN 622 (RTM) + CY ASORB UV 3346 (RTM) + GOODRITE UV 3150 (RTM) 77. TINUVIN 622 (RTM) + CYASORB UV 3346 (RTM) + GOODRITE UV 3159 (RTM) 78. TINUVIN 622 (RTM) + CYAS〇RBUV 3346 (RTM) + formula (B-9-a) compound in which E25 is hydrogen 79. TINUVIN 622 (RTM) + CYASORB UV 3346 (RTM) + UVINUL 4049 (RTM) 80. TINUVIN 622 (RTM) + CYASORB UV 3346 (RTM) + formula ( B-10-a) compounds, where E29 is hydrogen 81.11] ^ 117 taken 622 (1 ^ cent) + 0 y ^ 3 301 ^ 11 ¥ 3346 (1 ^ 14) + formula 佴 -14) compounds, where & It is hydrogen 82. TINUVIN 622 (RTM) + CYASORB UV 3346 (RTM) + SUMISOR TM 61 (RTM) 83. TINUVIN 622 (RTM) + CYASORB UV 3346 (RTM) + SANDUVOR 3050 (RTM) 84. TINUVIN 622 (RTM) + CYASORB UV 3346 (RTM) + SANDUVOR PR-31 (RTM) 85. TINUVIN 622 (RTM) + UVASIL 299 (RTM) + TINUVIN 770 (RTM) 86. TINUVIN 622 (RTM) + UVASIL 299 (RTM) + TINUVIN 765 (RTM) 87. TINUVIN 622 (RTM) + UVASIL 299 (RTM) + TINUVIN 144 (RTM) 88. TINUVIN 622 (RTM) + UVASIL 299 (RTM) + TINUVIN 123 (RTM) 89. TINUVIN 622 (RTM) + UVASIL 299 (RTM) + compound of formula (B-3-a), wherein E12 is hydrogen 90. TINUVIN 622 (RTM) + UVASIL 299 (RTM) + HOSTAVIN N 24 (RTM) 91. TINUVIN 622 (RTM) + UVASIL 299 (RTM) + DIACETAM 5 (RTM) 92. TINUVIN 622 (RTM) + UVASIL 299 (RTM) + ADK STAB LA 52 (RTM) 93. TINUVIN 622 (RTM) + UVASIL 299 (RTM) + ADK STAB LA 57 (RTM) 94. TINUVIN 622 (RTM) + UVASIL 299 (RTM) + ADK STAB LA 62 (RTM) 95 . TINUVIN 622 (RTM) + UVASIL 299 (RTM) + ADK STAB LA 67 (RTM) 96. TINUVIN 622 (RTM) + UVASE, 299 (RTM) + GOODRITE UV 3034 (RTM) 97. TINUVIN 622 (RTM) + UVASIL 299 (RTM) + GOODRITE UV 3150 (RTM) 98. TINUVIN 622 (RTM) + UVASIL 299 (RTM) + GOODRITE UV 3159 (RTM) 99 · TINUVIN 622 (RTM) + UVASIL 299 (RTM) + formula (B-9 -a) Compounds, where E25 is hydrogen 49 This paper size applies Chinese National Standard (CNS) A4 specifications (210 x 297 mm) (Please read the notes on the back before filling this page) Order. • Line-572952 A7 __B7___ V. Description of the invention (W) 100. TINUVIN 622 (RTM) + UVASIL 299 (RTM) + UVINUL 4049 (RTM) 101. TINUVIN622 (RTM) + UVASIL299 (RTM) + compound of formula (B-10-a), of which E29 It is hydrogen 102. Dingbei 1 ^^ 622 (1 ^^ ) + 1 ^ eight 311 ^ 299〇 ^%) + compound of formula (3-1- &), where & is hydrogen 103. TINUVIN 622 (RTM) + UVASIL 299 (RTM) + SUMISOR TM 61 (RTM) 104 . TINUVIN 622 (RTM) + UVASIL 299 (RTM) + SANDUVOR 3050 (RTM) 105. TINUVIN 622 (RTM) + UVASIL 299 (RTM) + SANDUVOR PR-31 (RTM) 106. TINUVIN 622 (RTM) + UVASORB HA 88 (RTM) + TINUVIN 770 (RTM) 107. TINUVIN 622 (RTM) + UVASORB HA 88 (RTM) + TINUVIN 765 (RTM) 108. TINUVIN 622 (RTM) + UVASORB HA 88 (RTM) + TINUVIN 144 (RTM) 109 . TINUVIN 622 (RTM) + UVASORB HA 88 (RTM) + TINUVIN 123 (RTM) 110.111 ^ take 622.01%) + 1; ¥ 80 3〇1 ^ like 88 (10 ^) + formula 汨 -3- &) Compound where £ 12 is hydrogen 111. TINUVIN 622 (RTM) + UVASORB HA 88 (RTM) + HOSTAVIN N 24 (RTM) 112. TINUVIN 622 (RTM) + UVASORB HA 88 (RTM) + DIACETAM 5 (RTM) 113. TINUVIN 622 (RTM) + UVASORB HA 88 (RTM) + ADK STAB LA 52 (RTM) 114. TINUVIN 622 (RTM) + UVASORB HA 88 (RTM) + ADK STAB LA 57 (RTM) 115. TINUVIN 622 (RTM ) + UVASORB HA 88 (RTM) + ADK STAB LA 62 (RTM) 116. TINUVIN 622 (RTM) + UVASORB HA 88 (RTM) + ADK STAB LA 67 (RTM) 117. TINUVIN 622 (RTM) + UVASORB HA 88 (RTM) + GOODRITE UV 3034 (RTM) 118. TINUVIN 622 (RTM) + UVASORB HA 88 (RTM) + GOODRITE UV 3150 (RTM) 119. TINUVIN 622 (RTM) + UVASORB HA 88 (RTM) + GOODRITE UV 3159 (RTM) 120. TINUVIN 622 (RTM) + UVASORB HA 88 (RTM) + compound of formula (B-9-a), where E25 is hydrogen 121. TINUVIN 622 (RTM) + UVASORB HA 88 (RTM) + UVINUL 4049 (RTM) 122.111 ^^ 明 622 (1 ^^) + 1 ^ 八 3〇1 ^) ^ 88 (1 ^^) + Formula 卬- 1 (^) compound, of which £ 29 is hydrogen 123. TINUVIN 622 (RTM) + UVASORB HA 88 (RTM) + compound of formula (Bla), where & is hydrogen 124. TINUVIN 622 (RTM) + UVASORB HA 88 (RTM ) + SUMISOR TM 61 (RTM) 125. TINUVIN 622 (RTM) + UVASORB HA 88 (RTM) + SANDUVOR 3050 (RTM) 126. TINUVIN 622 (RTM) + UVASORB HA 88 (RTM) + SANDUVOR PR-31 (RTM) 127. TINUVIN 622 (RTM) + UVINUL 5050 H (RTM) + TINUVIN 770 (RTM) 128. TINUVIN 622 (RTM) + UVINUL 5050 H (RTM) + TINUVIN 765 (RTM) 129. TINUVIN 622 (RTM) + UVINUL 5050 H (RTM) + TINUVIN 144 (RTM) 50 This paper size applies to Chinese national standards (CNS) A4 size (210 x 297 mm) (Please read the back of the precautions to fill out this page)

n ϋ ϋ ϋ n I ^ OJ · nn ϋ an n ϋ n I nnnn I ϋ ϋ I -1 -1 n ϋ · ϋ n ϋ nnn ϋ n I 572952 A7 __ B7___ V. Description of the invention (4) 130.TINUVIN 622 ( RTM) + UVINUL 5050 H (RTM) + TINUVIN 123 (RTM) 131; 11 ^^ 1 ^ take 622 (1 ^ > 1) + 11 ¥ take 111505 (^ (1 ^^) + formula (3-34) Compound where & 2 is hydrogen 132. TINUVIN 622 (RTM) + UVINUL 5050 H (RTM) + HOSTAVIN N 24 (RTM) 133. TINUVIN 622 (RTM) + UVINUL 5050 H (RTM) + DIACETAM 5 (RTM) 134 . TINUVIN 622 (RTM) + UVINUL 5050 H (RTM) + ADK STAB LA 52 (RTM) 135. TINUVIN 622 (RTM) + UVINUL 5050 H (RTM) + ADK STAB LA 57 (RTM) 136. TINUVIN 622 (RTM) + UVINUL 5050 H (RTM) + ADK STAB LA 62 (RTM) 137. TINUVIN 622 (RTM) + UVINUL 5050 H (RTM) + ADK STAB LA 67 (RTM) 138. TINUVIN 622 (RTM) + UVINUL 5050 H (RTM) ) + GOODRITE UV 3034 (RTM) 139. TINUVIN 622 (RTM) + UVINUL 5050 H (RTM) + GOODRITE UV 3150 (RTM) 140. TINUVIN 622 (RTM) 4- UVINUL 5050 H (RTM) + GOODRITE UV 3159 (RTM ) 141.11 ^^ Take 622 (1 ^ α + 1; ¥ 1 ^ 505011 (lamp 1 ^) + formula 94), where & 5 is hydrogen 142.TINUV IN 622 (RTM) + UVINUL 5050 H (RTM) + UVINUL 4049 (RTM) 143.111 ^ ¥ Take 622 (10 ^) + 11711 ^ 505011 (10%) + compound of formula (6-1 (^), of which £ 29 is Hydrogen 144. D11 ^ to 622 (1 ^^) + 1 ^ 1 ^ 505011 (1 ^^) + compound of formula (3-14), where & is hydrogen 145. TINUVIN 622 (RTM) + UVINUL 5050 H ( RTM) + SUMISOR TM 61 (RTM) 146. TINUVIN 622 (RTM) + UVINUL 5050 H (RTM) + SANDUVOR 3050 (RTM) 147. TINUVIN 622 (RTM) + UVINUL 5050 H (RTM) + SANDUVOR PR-31 (RTM ) 148. TINUVIN 622 (RTM) + LICHTSCHUTZSTOFF UV 31 (RTM) + TINUVIN 770 (RTM) 149. TINUVIN 622 (RTM) + LICHTSCHUTZSTOFF UV 31 (RTM) + TINUVIN 765 (RTM) 150. TINUVIN 622 (RTM) + LICHTSCHUTZSTOFF UV 31 (RTM) + TINUVIN 144 (RTM) 151. TINUVIN 622 (RTM) + LICHTSCHUTZSTOFF UV 31 (RTM) + TINUVIN 123 (RTM) 152. TINUVIN 022 (RTM) + LICHTSCHUTZSTOFF UV 31 (RTM) + formula (B- 3-a) Compound where & 2 is hydrogen 153TINUVIN 622 (RTM) + LICHTSCHUTZSTOFF UV 31 (RTM) + HOSTAVIN N 24 (RTM) 154. TINUVIN 622 (RTM) + LICHTSCHUTZSTOFF UV 31 (RTM) + DIACETAM 5 (RTM ) 155. TINUVIN 622 (RTM) + LICHTSCHUT ZSTOFF UV 31 (RTM) + ADK STAB LA 52 (RTM) 156. TINUVIN 622 (RTM) + LICHTSCHUTZSTOFF UV 31 (RTM) + ADK STAB LA 57 (RTM) 157. TINUVIN 622 (RTM) + LICHTSCHUTZSTOFF UV 31 (RTM) + ADK STAB LA 62 (RTM) 158. TINUVIN 622 (RTM) + LICHTSCHUTZSTOFF UV 31 (RTM) + ADK STAB LA 67 (RTM) 51 This paper size applies to China National Standard (CNS) A4 (210 x 297 mm) (Please read the notes on the back before filling out this page) --- — — — — Order --------- line. 572952 A7 B7, _ V. Description of the invention (lat.) 159. TINUVIN 622 (RTM ) + LICHTSCHUTZSTOFF UV 31 (RTM) + GOODRITE UV 3034 (RTM) 160. TINUVIN 622 (RTM) + LICHTSCHUTZSTOFF UV 31 (RTM) + GOODRITE UV 3150 (RTM) 161. TINUVIN 622 (RTM) + LICHTSCHUTZSTOFF UV 31 (RTM) + GOODRITE UV 3159 (RTM) 162. TINUVIN 622 (RTM) + LICHTSCHUTZSTOFF UV 31 (RTM) + compound of formula (B-9-a), of which E25 g hydrogen 163. TINUVIN 622 (RTM) -f LICHTSCHUTZSTOFF UV 31 (RTM ) + UVINUL 4049 (RTM) 164. TINUVIN 622 (RTM) + LICHTSCHUTZSTOFF UV 31 (RTM) + compound of formula (B-10-a), where E29 is hydrogen 165. T INUVIN 622 (RTM) + LICHTSCHUTZSTOFF UV 31 (RTM) + compound of formula (Bla), where Ei is hydrogen 166. TINUVIN 622 (RTM) + LICHTSCHUTZSTOFF UV 31 (RTM) -f SUMISOR TM 61 (RTM) 167. TINUVIN 622 ( (RTM) + LICHTSCHUTZSTOFF UV 31 (RTM) + SANDUVOR 3050 (RTM) 168. TINUVIN 622 (RTM) + LICHTSCHUTZSTOFF UV 31 (RTM) + SANDUVOR PR-31 (RTM) 169. TINUVIN 622 (RTM) + DASTIB 1082 (RTM) + TINUVIN 770 (RTM) 170. TINUVIN 622 (RTM) + DASTIB 1082 (RTM) + TINUVIN 765 (RTM) 171. TINUVIN 622 (RTM) + DASTIB 1082 (RTM) + TINUVIN 144 (RTM) 172. TINUVIN 622 (RTM ) + DASTIB 1082 (RTM) + TINUVIN 123 (RTM) 173. TINUVIN 622 (RTM) + DASTIB 1082 (RTM) + compound of formula (B-3-a), where Eu is hydrogen 174. TINUVIN 622 (RTM) + DASTIB 1082 (RTM) + HOSTAVIN N 24 (RTM) 175. TINUVIN 622 (RTM) + DASTIB 1082 (RTM) + DIACETAM 5 (RTM) 176. TINUVIN 622 (RTM) + DASTIB 1082 (RTM) + ADK STAB LA 52 (RTM ) 177. TINUVIN 622 (RTM) + DASTIB 1082 (RTM) + ADK STAB LA 57 (RTM) 178. TINUVIN 622 (RTM) + DASTIB 1082 (RTM) + ADK STAB LA 62 (RTM) 179. TINUVIN 622 (RTM) + DASTIB 1082 (RTM) + ADK STAB LA 67 (RTM) 180. TINUVIN 622 (RTM) + DASTIB 1082 (RTM) + GOODRITE UV 3034 (RTM) 181. TINUVIN 622 (RTM) + DASTIB 1082 (RTM) + GOODRITE UV 3150 (RTM) 182. TINUVIN 622 (RTM) + DASTIB 1082 (RTM) + GOODRITE UV 3159 (RTM) 183. TINUVIN 622 (RTM) + DASTIB 1082 (RTM) + Compound of Formula (B-9-a) Where E25 is hydrogen 184. TINUVIN 622 (RTM) + DASTIB 1082 (RTM) + UVINUL 4049 (RTM) 185. TINUVIN622 (RTM) + DASTIB f082 (RTM) + compound of formula (B-10-a), where E29 is Hydrogen 52 The size of this paper applies the Chinese National Standard (CNS) A4 specification (210 x 297 mm) 572952 A7 _B7___ V. Description of the invention (>) 186. TINUVIN 622 (RTM) + DASTIB 1082 (RTM) + Formula (B- 1-a) Compound where E! Is hydrogen 187. TINUVIN 622 (RTM) + DASTIB 1082 (RTM) + SUMISOR TM 61 (RTM) 188. TINUVIN 622 (RTM) + DASTIB 1082 (RTM) + SANDUVOR 3050 (RTM) 189. TINUVIN 622 (RTM) + DASTIB 1082 (RTM) + SANDUVOR PR-31 (RTM) 190. TINUVIN 622 (RTM) + LUCHEM HA B 18 (RTM) + TINUVIN 770 (RTM) 191. TINUVIN 622 (RTM) + LUCHEM HA B 18 (R TM) + TINUVIN 765 (RTM) 192. TINUVIN 622 (RTM) + LUCHEM HA B 18 (RTM) + TINUVIN 144 (RTM) 193. TINUVIN 622 (RTM) + LUCHEM HA B 18 (RTM) + TINUVIN 123 (RTM) 194. TINUVIN 622 (RTM) + LUCHEM HA B 18 (RTM) + compound of formula (B-3-a), where E12 is hydrogen 195. TINUVIN 622 (RTM) + LUCHEM HA B 18 (RTM) + HOSTAVIN N 24 ( RTM) 196. TINUVIN 622 (RTM) + LUCHEM HA B 18 (RTM) + DIACETAM 5 (RTM) 197. TINUVIN 622 (RTM) + LUCHEM HA B 18 (RTM) + ADK STAB LA 52 (RTM) 198. TINUVIN 622 (RTM) + LUCHEM HA B 18 (RTM) + ADK STAB LA 57 (RTM) 199. TINUVIN 622 (RTM) + LUCHEM HA B 18 (RTM) + ADK STAB LA 62 (RTM) 200. TINUVIN 622 (RTM) + LUCHEM HA B 18 (RTM) + ADK STAB LA 67 (RTM) 201. TINUVIN 622 (RTM) + LUCHEM HA B 18 (RTM) + GOODRITE UV 3034 (RTM) 202. TINUVIN 622 (RTM) + LUCHEM HA B 18 ( RTM) + GOODRITE UV 3150 (RTM) 203. TINUVIN 622 (RTM) + LUCHEM HA B 18 (RTM) + GOODRITE UV 3159 (RTM) 204. TINUVIN 622 (RTM) + LUCHEM HA B 18 (RTM) + Formula (B -9-a) compound in which E25 is hydrogen 205. TINUVIN 622 (RTM) + LUCHEM HA B 18 ( RTM) + UVINUL 4049 (RTM) 206. TINUVIN 622 (RTM) + LUCHEM HA B 18 (RTM) + compound of formula (B-10-a), where E29 is hydrogen 207. TINUVIN 622 (RTM) + LUCHEM HA B 18 (RTM) + compound of formula (Bla), where & is hydrogen 208. TINUVIN 622 (RTM) + LUCHEM HA B 18 (RTM) + SUMISOR TM 61 (RTM) 209. TINUVIN 622 (RTM) + LUCHEM HA B 18 ( (RTM) + SANDUVOR 3050 (RTM) 210. TINUVIN 622 (RTM) + LUCHEM HA B 18 (RTM) + SANDUVOR PR-31 (RTM) 21 l. TINUVIN 622 (RTM) + ADK STAB LA 63 (RTM) + TINUVIN 770 (RTM) 212.TINUVIN 622 (RTM) + ADK STAB LA 63 (RTM) + TINUVIN 765 (RTM) 53 This paper size applies to China National Standard (CNS) A4 (210 x 297 mm) (Please read the Please fill in this page for further information) ϋ ϋ n · ϋ 一 H 1: OJ · ϋ n 1 ϋ 1 n 1 · I · 572952 A7 __B7_ V. Description of the invention (β) 213. TINUVIN 622 (RTM) + ADK STAB LA 63 (RTM) + TINUVIN 144 (RTM) 214. TINUVIN 622 (RTM) + ADK STAB LA 63 (RTM) + TINUVIN 123 (RTM) 215. TINUVIN 622 (RTM) + ADK STAB LA 63 (RTM) + Formula (B- 3-a) Compound where El2 is hydrogen 216. TIN UVIN 622 (RTM) + ADK STAB LA 63 (RTM) + HOSTAVIN N 24 (RTM) 217. TINUVIN 622 (RTM) + ADK STAB LA 63 (RTM) + DIACETAM 5 (RTM) 218. TINUVIN 622 (RTM) + ADK STAB LA 63 (RTM) + ADK STAB LA 52 (RTM) 219. TINUVIN 622 (RTM) + ADK STAB LA 63 (RTM) + ADK STAB LA 57 (RTM) 220. TINUVIN 622 (RTM) + ADK STAB LA 63 ( RTM) + ADK STAB LA 62 (RTM) 221. TINUVIN 622 (RTM) + ADK STAB LA 63 (RTM) + ADK STAB LA 67 (RTM) 222. TINUVIN 622 (RTM) + ADK STAB LA 63 (RTM) + GOODRITE UV 3034 (RTM) 223. TINUVIN 622 (RTM) + ADK STAB LA 63 (RTM) + GOODRITE UV 3150 (RTM) 224. TINUVIN 622 (RTM) + ADK STAB LA 63 (RTM) + GOODRITE UV 3159 (RTM) 225 TINUVIN 622 (RTM) + ADK STAB LA 63 (RTM) + compound of formula (B-9-a), where E25 is hydrogen 226. TINUVIN 622 (RTM) + ADK STAB LA 63 (RTM) + UVINUL 4049 (RTM) 227. TINUVIN 622 (RTM) + ADK STAB LA 63 (RTM) + compound of formula (B-10-a), where E29 is hydrogen 228. TINUVIN 622 (RTM) + ADK STAB LA 63 (RTM) + formula (Bla) Compound where & is hydrogen 229. TINUVIN 622 (RTM) + ADK STAB LA 63 (RTM) 4 -SUMISOR TM 61 (RTM) 230. TINUVIN 622 (RTM) + ADK STAB LA 63 (RTM) + SANDUVOR 3050 (RTM) 231. TINUVIN 622 (RTM) + ADK STAB LA 63 (RTM) + SANDUVOR PR-31 (RTM ) 232. TINUVIN 622 (RTM) + ADK STAB LA 68 (RTM) + TINUVIN 770 (RTM) 233. TINUVIN 622 (RTM) + ADK STAB LA 68 (RTM) + TINUVIN 765 (RTM) 234. TINUVIN 622 (RTM) + ADK STAB LA 68 (RTM) + TINUVIN 144 (RTM) 235. TINUVIN 622 (RTM) + ADK STAB LA 68 (RTM) + TINUVIN 123 (RTM) 236. TINUVIN 622 (RTM) + ADK STAB LA 68 (RTM) + Compound of formula (B-3-a), where E12 is hydrogen 237. TINUVIN 622 (RTM) + ADK STAB LA 68 (RTM) + HOSTAVIN N 24 (RTM) 238. TINUVIN 622 (RTM) + ADK STAB LA 68 ( (RTM) + DIACETAM 5 (RTM) 239. TINUVIN 622 (RTM) + ADK STAB LA 68 (RTM) + ADK STAB LA 52 (RTM) 240. TINUVIN 622 (RTM) + ADK STAB LA 68 (RTM) + ADK STAB LA 57 (RTM) 241. TINUVIN 622 (RTM) + ADK STAB LA 68 (RTM) + ADK STAB LA 62 (RTM) 54 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (please first (Read the notes on the back and fill out this page)-# II n ft n ^ eJI ϋ ϋ nn ϋ · ϋ i .line 丨 · 572952 A7 _B7 _ V. Description of the Invention (θ) 242. TINUVIN 622 (RTM) + ADK STAB LA 68 (RTM) + ADK STAB LA 67 (RTM) 243. TINUVIN 622 ( (RTM) + ADK STAB LA 68 (RTM) + GOODRITE UV 3034 (RTM) 244. TINUVIN 622 (RTM) + ADK STAB LA 68 (RTM) + GOODRITE UV 3150 (RTM) 245. TINUVIN 622 (RTM) + ADK STAB LA 68 (RTM) + GOODRITE UV 3159 (RTM) 246. TINUVIN 622 (RTM) + ADK STAB LA 68 (RTM) + compound of formula (B-9-a), where E25 is hydrogen 247. TINUVIN 622 (RTM) + ADK STAB LA 68 (RTM) + UVINUL 4049 (RTM) 248. TINUVIN 622 (RTM) + ADK STAB LA 68 (RTM) + compound of formula (B-10-a), where E29 is hydrogen 249. TINUVIN 622 (RTM) + ADK STAB LA 68 (RTM) + compound of formula (Bla), where E! Is hydrogen 250. TINUVIN 622 (RTM) + ADK STAB LA 68 (RTM) + SUMISOR TM 61 (RTM) 251. TINUVIN 622 (RTM) 4- ADK STAB LA 68 (RTM) + SANDUVOR 3050 (RTM) 252. TINUVIN 622 (RTM) + ADK STAB LA 68 (RTM) + SANDUVOR PR-31 (RTM) 253. TINUVIN 622 (RTM) + CYASORB UV 3529 (RTM) + TINUVIN 770 (RTM) 254. TINUVIN 622 (RTM) + CYASORB UV 3529 (RTM) + TINUVIN 765 (RTM) 255. TINUVIN 622 (RTM) + CYASORB UV 3529 (RTM) Ten TINUVIN 144 (RTM) 256. TINUVIN 622 (RTM) + CYASORB UV 3529 (RTM) + TINUVIN 123 (RTM) 257. TINUVIN 622 (RTM) + CYASORB UV 3529 (RTM) + compound of formula (B-3-a), where Ei2 is hydrogen 258. TINUVIN 622 (RTM) + CYASORB UV 3529 (RTM) + HOSTAVIN N 24 (RTM) 259. TINUVIN 622 (RTM) + CYASORB UV 3529 (RTM) + DIACETAM 5 (RTM) 260. TINUVIN 622 (RTM) + CYASORB UV 3529 (RTM) + ADK STAB LA 52 (RTM) 261. TINUVIN 622 (RTM) + CYASORB UV 3529 (RTM) + ADK STAB LA 57 (RTM) 262. TINUVIN 622 (RTM) + CYASORB UV 3529 (RTM) + ADK STAB LA 62 (RTM) 263. TINUVIN 622 (RTM) + CYASORB UV 3529 (RTM) + ADK STAB LA 67 (RTM) 264. TINUVIN 622 (RTM) + CYASORB UV 3529 (RTM) + GOODRITE UV 3034 (RTM) 265. TINUVIN 622 (RTM) + CYASORB UV 3529 (RTM) + GOODRITE UV 3150 (RTM) 266. TINUVIN 622 (RTM) + CYASORB UV 3529 (RTM) + GOODRITE UV 3159 (RTM) 267. TINUVIN 622 (RTM) + CYASORB UV 3529 (RTM) + compound of formula (B-9-a), where E25 is hydrogen 55 paper sizes Use Chinese National Standard (CNS) A4 specification (210 x 297 mm) (Please read the precautions on the back before filling this page); # --- 1 --- Order---------- 572952 A7 ____B7_ V. Description of the Invention (Ο) 268. TINUVIN 622 (RTM) + CYASORB UV 3529 (RTM) + UVINUL 4049 (RTM) 269. TINUVIN 622 (RTM) + CYASORB UV 3529 (RTM) + Formula (B-10- a) Compound where E29 is hydrogen 270. TINUVIN 622 (RTM) + CYASORB UV 3529 (RTM) + compound of formula (B-1-a) where E! is hydrogen 271. TINUVIN 622 (RTM) + CYASORB UV 3529 ( RTM) + SUMISOR TM 61 (RTM) 272. TINUVIN 622 (RTM) + CYASORB UV 3529 (RTM) + SANDUVOR 3050 (RTM) 273. ΉΝυνΐΝ 622 (RTM) + CYASORB UV 3529 (RTM) + SANDUVOR PR-31 (RTM ) Examples of other stabilizer mixtures are the commercial product TINUVIN 622 (RTM) in the combination of 1 to 2 7 3 above, which is made of a compound of formula (A-2-a) and / or (A-2-b) Replacement combination

Where n2 and n2 * are a number from 2 to 20. Other examples of stabilizer mixtures are those in the above-mentioned combinations 1 to 2 7 3, the commercial product TINUVIN 622 (RTM) is expressed by the following formula (A-4-a) 56 ΐ Paper size applies Chinese National Standard (CNS) A4 specifications (210 X 297 mm) '(Please read the notes on the back before filling this page)

ϋ I ϋ H ϋ nn · n ί II l ϋ n II ϋ n I n ϋ n ϋ ϋ ϋ l II ϋ n ϋ n ϋ ϋ ϋ I n I 572952 A7 B7 V. Description of the invention (N) Compound substitution combination -CH3I -CH-—C—CH2 2 I c = oI 0 1 CH ^ -CH —I c = o I 〇I A7 (A-4-a) where n4 is a number from 2 to 20, and h3c ch3 At least 50% of A7 is a monogroup, and the remaining A; (Please read the notes on the back before filling this page) H3c ch3 is ethyl. A particularly advantageous combination is the combination No. 1 and the relative combination in which TINUVIN 622 (RTM) is replaced by a compound of formula (A: 2-a) and / or (A-2-b), No. 8 5 and in UVASIL 299 (RTM) is a relative combination replaced by UVASIL 125 (RTM) or UVASIL 2000 (RTM), and the combination numbered 22, 43, 64, 106, 127 and 253. Other combinations which are particularly advantageous are the combinations numbered 1, 4, 5, 17 and 23. The commercial product nNUVIN622 (RTM) is equivalent to the compound of formula (A-U). The commercial product HNUVIN770 (RTM) is equivalent to a compound of formula (B-1-b) where & is hydrogen. The commercial product ΉΝυνΐΝ765 (RTM) is equivalent to a compound of formula (B-1-b) where & is methyl. The commercial product TINUVIN 123 (RTM) is equivalent to the compound of formula (B-1-b), where & is octyloxy 57 This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm)-— ϋ n ϋ nn I ϋ n ϋ ϋ n ϋ * 572952 A7 ___B7____ 5. Description of the invention (0 (Please read the notes on the back before filling this page) Commercialized product ΉΝυνίΝ 144 (RTM) is equivalent to the formula (B-1- c) Compound, where & is methyl. Commercial product ADKSTABLA57 (RTM) is equivalent to compound of formula (B-1-d), where & is hydrogen. Commercial product ADK STAB LA 52 (RTM) is equivalent to formula ( B-1-d) compounds where E! Is methyl. Commercial product ADKSTABLA67 (RTM) is equivalent to compound of formula (B-2-a), where & is hydrogen. Commercial product ADKSTABLA62 (RTM) is equivalent to formula (B-2-a) compound, where & is methyl. The commercial product HOSTAVINN24 (RTM) is equivalent to the compound of formula (B-3-b), where is hydrogen. The commercial product SANDUVOR3050 (RTM) Corresponds to the compound of formula (B-3-bl), where & 2 is hydrogen. The commercial product DIACETAM 5 (RTM) corresponds to the compound of formula (B-4-a), where Eπ is hydrogen The commercial product SUMIS0RTM61 is equivalent to the compound of formula (B-4-b), which is hydrogen. The commercial product UVINUL4049 (RTM) is equivalent to the compound of formula (B-5), where E16 is hydrogen. The commercial product SANDUV0RPR31 (RTM) Equivalent to compound of formula (B-8-a), where & is methyl. Commercial product GOODRITE 3034 (RTM) is equivalent to compound of formula (B-9-b), where E25 is hydrogen. Commercial product G〇〇 DRITE3150 (RTM) is equivalent to a compound of formula (B-9-c), where E25 is hydrogen. The commercial product GOODRITE3159 (RTM) is equivalent to a compound of formula (B-9-c), where & is methyl. The commercial product CHIMASSORB 944 (RTM) is equivalent to a compound of formula (C-1-a), where R6 is hydrogen. The commercial product CHIMASSORB2020 (RTM) is equivalent to a compound of formula (C-1-b), where R6 is hydrogen. Commercial The chemical product DASTIB 1082 (RTM) is equivalent to a compound of formula (C-1-c), where R6 is hydrogen. The commercial product CYASOBRBUV3346 (RTM) is equivalent to a compound of formula (C-1-d), where R6 is hydrogen. The commercial product CYASORB UV 3529 (RTM) is equivalent to a compound of formula (Cd), where r6 is methyl. The commercial product CHIMASSORB 119 (RTM) is equivalent to the compound of formula (C-2-a), where R13 is methyl. The commercial product UVASIL299 (RTM) is equivalent to the compound of formula (C-3-a), where R16 is hydrogen. The commercial product UVINUL5050H (RTM) is equivalent to the compound of formula (C-4-a), where R18 is hydrogen. The commercial product LICHTSCHUTZSTOFFUV31 (RTM) is equivalent to the compound of formula (C-4-b), where r18 is hydrogen. The commercial product LUCHEM HA B 18 (RTM) is equivalent to the compound of formula (C-4_c), where R18 is hydrogen. The commercial product ADKSTABLA68 (RTM) is equivalent to the compound of formula (C-5-a), where r3 () is hydrogen. The commercial product ADKSTABLA63 (RTM) is equivalent to the compound of formula (C-5-a), where r3. Is methyl. The commercial product UVASORB HA 88 (RTM) corresponds to a compound of formula (C-6-a), where R32 is hydrogen. The compound of formula (B-3-b-l) has the structure shown below: 58 This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) '一 " 572952 A7 _B7 V. Description of the invention (shirt)

The stabilizer mixture of the present invention is suitable for stabilizing organic substances and resists degradation due to light, heat or oxidation. Examples of these organic substances are as follows: 1. Polymers of mono- and diolefins, for example, polypropylene, polyisobutylene, polybutadiene-1, poly-4-methylpentyl-1ene, poly Isoprene or polybutadiene, and polymers of cycloolefins, such as cyclopentene or norbornene, other polyethylenes (which can be crosslinked if needed), such as high density polyethylene (HDPE ), High-density and high-molecular-weight polyethylene (HDPE-HMW), high-density ultra-high-molecular-weight polyethylene (H DPE-UHMW), medium-density polyethylene (MDPE), low-density polyethylene (LDPE), linear low-density polyethylene (LLDPE), (VLDPE) and (ULDPE). Polyolefins, that is, polymers of monoolefins, like the monoolefin polymers exemplified in the preceding paragraph, especially polyethylene and polypropylene, can be prepared by different methods, especially the following methods: a) free Reactive group polymerization (usually under high pressure and temperature). b) The catalyst polymerization reaction using = catalyst, this catalyst usually contains one or more than 59 of the IVb, Vb, VIb or VI II group on the periodic table. 297 mm) (Please read the notes on the back before filling out this page) — — — — — — — — ^ · IIIII — II. 572952 A7 ________B7_ V. Description of the invention (r?) Metals usually chase one or Various types, typically oxides, halides, alcohol esters, esters, ethers, amines, alkylates, alkenylates, and / or arylates, can be; r- or σ-covalent. These metal complexes can be free or immobilized on a substrate, typically activated magnesium chloride, titanium chloride (I I I), aluminum or silicon oxide. These catalysts can be soluble or insoluble in the polymer matrix, and these catalysts can be used in the polymerization reaction themselves, or can use activators, typically metal alkylates, metal hydrides, and metal halides. , Metal alkyl oxide or metal alkyl oxane, the metal may be a group I a, II a, and / or III A of the periodic table 'activator may further be ester, ether, amine or silane alkyl Modified catalyst systems are commonly referred to as Phillips, Standard Oil Indiana 'Ziegler (-Natta), TNZ (DuPont), metallocene, or unilateral catalyst (ssc). 2 · A mixture of the polymers mentioned in 1), for example, a mixture of polypropylene and polyisobutylene, a mixture of polypropylene and polyethylene (for example, p P / HDPE, PP / LDPPE), and a mixture of different types of polyethylene ( (Eg L DPE / HDPE). 3. Copolymers of mono- and diolefins, or copolymers with other ethylene monomers, such as ethylene / propylene copolymers, linear low-strength polyethylene (LLDPE) and mixtures thereof and low-strength polyethylene (l DPE), Propylene / butadiene-1 copolymer, propylene / isobutene copolymer, ethylene / butadiene-1-ene copolymer, ethylene / hexene copolymer, ethylene / methylpentene copolymer, ethylene / heptene copolymer, ethylene / Octene copolymer, propylene / butadiene copolymer, isobutylene / isoprene copolymer, ethylene / alkyl propylene copolymer 60 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page) Order: -line · 572952 A7 V. Description of the Invention (β) Ester copolymer, its copolymer with carbon monoxide, or ethylene / acrylic acid copolymer , And its salts (ionized compounds) and terpolymers formed by ethylene, propylene, and monodiene, such as hexadiene, dicyclopentadiene, or ethylenedi-orbornene; and mixtures between the copolymers And mixtures of polymers mentioned in 1) above, such as polypropylene / Ethylene / propylene copolymer, LD PP / ethylene-vinyl acetate copolymer (EVA), LDPE / ethylene-acrylic copolymer (EAA), LLDPE / EVA, LL DPE / E AA and has a staggered or scattered structure Polyalkylene-carbon monoxide copolymers, and mixtures with other polymers, such as polyamides. 4. Hydrocarbon resins (eg C5-C9), including their hydrogenated modifiers (eg, adhesives), and mixtures of polyolefins and starch. 5 · Polystyrene, poly (ρ-methylstyrene), poly (α-methylstyrene). 6. Copolymers of styrene or α-methylstyrene and diene or acrylic acid derivatives, for example, styrene / butadiene, styrene / acrylonitrile, styrene / alkylmethacrylate, styrene / butadiene Diene / alkyl acrylate, styrene / butadiene / alkyl methacrylate, styrene / maleic anhydride, styrene / acrylonitrile / methacrylate; high impact strength mixture of styrene copolymer And another polymer, such as polyacrylate, a diene polymer or an ethylene / propylene / diene terpolymer; and a block copolymer of styrene, such as styrene / butadiene / styrene, Styrene / isoprene / ethylene, styrene / ethylene / butene / styrene or styrene / ethylene / propylene / styrene. 7 · Graft copolymers of styrene or α-methylstyrene, for example, the size of the paper is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) (please read the precautions on the back first) (Fill in this page) »ϋ i · — nnn 一 -OT · It an ϋ n I na— I-_ ϋ n nn nnn ϋ ϋ ϋ I n I-572952 A7 _B7_ V. Description of the Invention (θ) Styrene, polystyrene-styrene or polystyrene-acrylonitrile copolymer; styrene and acrylonitrile (or methacrylonitrile) on polybutadiene; polystyrene Styrene, acrylonitrile, and methacrylic acid esters on butadiene; styrene and maleic anhydride on polybutadiene; styrene, acrylonitrile, and maleic acid on polybutadiene Anhydride or maleimide; styrene and maleimide on polybutadiene; styrene and alkyl acrylate or methacrylate on polybutadiene; in ethylene / Styrene and acrylonitrile on propylene / diene terpolymer; styrene and acrylonitrile on polyalkylacrylate or polyalkylmethacrylate; on Styrene and acrylonitrile on acrylate / butadiene copolymers, and mixtures with the copolymers listed in item 6), for example, copolymer mixtures of conventional A B S, M B S, A S A or A E S polymers. 8 · Halogen-containing polymers like polychlorinated pentadiene, chlorinated rubber, chlorinated or vulcanized chlorinated polyethylene, copolymers of ethylene and chlorinated ethylene, homoepichlorohydrin and copolymers, especially halogen Polymers of ethylene compounds, such as polyethylene chloride, polyethylene chloride, polyethylene fluoride, polyethylene fluoride, and copolymers thereof, like ethylene chloride / ethylene dichloride, ethylene chloride Compound / ethylene acetate or ethylene dichloride / ethylene acetate copolymer. 9 · Polymers prepared from α, / 3-unsaturated acids and their derivatives, such as polyacrylates and polymethacrylates; polymethacrylates, polypropyleneamine and polyacrylonitrile, with butyl acrylate Esters become shock modifiers. 10 · Copolymers formed between the monomers of 9) and other unsaturated monomers, such as acrylonitrile / butadiene copolymer, acrylonitrile / alkyl acrylic acid 62 This paper is applicable to China National Standard (CNS) A4 Specifications (210 X 297 mm) (Please read the notes on the back before filling this page)

^ OJa n I ϋ I n ϋ ϋ I nnn ϋ ϋ I n ϋ n Ii ϋ i_l ϋ ϋ nn ϋ ϋ ϋ ϋ ϋ I 572952 A7 _B7_ 5. Description of the invention (6.) Ester copolymer, acrylonitrile / alkoxyalkane Copolymers of acrylonitrile or acrylonitrile / ethylene halide or acrylonitrile / alkylmethacrylate / butadiene terpolymer. 1 1 · Polymers derived from unsaturated alcohols and amines or their halogenated derivatives or acetals, such as polyvinyl alcohol, polyvinyl acetate, polyethylene stearate, polyvinyl benzoate , Polyethylene maleate, polybutylene acetal, polyallyl phthalate or polyallyl melamine; and copolymers thereof with the olefins mentioned in point 1 above. 1 2 · Homopolymers and copolymers of cyclic ethers, such as polyolefin diols, polyethylene oxides, polypropylene oxides, or copolymers with dioxypropylene ethers. 1 3 · Polyacetals, like polyoxymethylene and those polyoxymethylenes, which contain ethylene oxide as a comonomer, are modified with thermoplastic polyurethane, acrylate or MBS. 1 4 · Mixtures of polyphenylene oxide and sulfide, and polystyrene oxide and styrene polymer or polyamide. 1 5 · Polyurethane derived from hydroxyl terminated polyether, polyester or polybutadiene on one side, and aliphatic or aromatic polyisocyanate on the other side, and its precursors. 16. Polyamide and copolymers derived from diamines and dicarboxylic acids and / or amine carboxylic acids or equivalent lactams, for example, polyamine 4, polyamine 6, polyamine 6 / 6, 6/10, 6/9, 6/12, 4/6, 1 2/1 2, polyamine 1 1, polyamine 1 2, starting from m-xylylenediamine and hexamethylene di_ Aromatic polyamines; polyamines derived from hexamethylene diamine and iso-peptides or / and p-peptides, with or without elastomers as modifiers, for example, poly-2,4, 4 One trimethylhexamethylene pair is missing 63 The paper size applies to the Chinese National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page)

--- I — — I Order · -------- U 572952 A7 V. Description of the invention () Amidoamine or poly ~ m-phenylene isopeptide amidine; and the above-mentioned polyamine and polyolefin 'olefin Copolymers, ions, or chemically bonded or grafted elastomers; or polyethers, such as block copolymers with polyethylene glycol, polypropylene glycol, or polytetramethylene glycol; and E PDM or AB S modified polyamide or copolyamide; and polyamines concentrated in the preparation process (RI M polyamidamine system). Polyurethane, polyimide, polyamidamine and polyimide and Polybenzimidazole. 18. Polyesters derived from dicarboxylic acids and diols and / or hydroxycarboxylic acids or equivalent lactones, for example, polyethylene terephthalate, polybutene parapeptide, poly-1, 4 Dimethyl alcohol cyclohexane terephthalate and polyhydroxybenzoate, and block copolyetheresters derived from hydroxyl terminated polyethers; and polymer modified with polycarbonate or MBS modified ester. 19. Polycarbonate and polyester carbonate. 2 0 · Poly maple, polyether mill and polyether ketone. 2 1 · Cross-linked polymers derived from acids on one side, urea, and melamine on the other side, like phenol / formaldehyde resins, urea / formaldehyde resins, and melamine / formaldehyde resins. 2 2 · Dried and non-dried alkyd resins. 2 3 · Unsaturated polyester resins derived from saturated and unsaturated dicarboxylic acids, polyhydric alcohols, and ethylene compounds as crosslinking agents, and their low-flammability halogen-containing modifiers. 64 ^^ scale applies Chinese National Standard (CNS) A4 specification (210 X 297 mm) " (Please read the precautions on the back before filling this page) Order --------- line · 572952 ΚΙ ______ Β7 ___ V. Description of the invention () 2 4 · Cross-linked acrylic resin derived from substituted acrylate, such as' epoxy acrylic resin, urethane acrylic resin or polyester acrylate. 0 2 5 · alkyd resin, polyester Resin and melamine resin crosslinked acrylic resin, urea resin, polyisocyanate or epoxy resin. 2 6 · Cross-linked epoxy resins derived from aliphatic, cycloaliphatic, heterocyclic or aromatic oxypropane compounds, such as those obtained from bis-A and bis-F bis-oxypropane ethers It can be cross-linked with traditional hardeners, like anhydrides or amines (either in the presence or absence of accelerators). 2 7 · Natural polymers, such as cellulose, rubber, gelatin and their homologous derivatives modified chemically, such as cellulose acetate, cellulose propionate and cellulose butyrate, or cellulose ether, Like methyl cellulose; and turpentine and its derivatives. 2 8 · A mixture (polymer mixture) of the above polymers, for example? ? / £ P DM, polyamide / E PDM or ABS, PVC / EVA,

PVC / ABS '' PVC / MBS, Pc / ABS, PB TP / ABS, PC / ASA, PC / PBT, pvC // CPE, PVC / acrylate, pOM / thermoplastic pur, PC / thermoplastic PUR, POM / Propanoic acid, pqm / mBS, PPO / HIPS, PP0 / PA6 · 6 and copolymer, PA / HDPE, PA / PP, PA / pPO, PBT / PC / ABS · or PBT / PET / PC. 29 · Naturally occurring and synthetic organic substances, which are pure compounds or mixtures of such compounds', such as' mineral oil ', animal and vegetable fats, and oils 65 X 297 mm) '----- (Please read the notes on the back before filling this page) ------- tr ------------------ -------------- 572952 A7 _____B7_____ 5. Description of the invention (), or oils, fats and waxes based on synthetic esters (eg, peptidate, adipate, phosphate , Triphenylhexanoate) and mixtures of synthetic esters and mineral oils in any weight ratio, typically those used as spinning compositions, and aqueous emulsions of the substances. 30. Water-soluble emulsions of natural or synthetic rubber, such as natural rubber latex or carboxylated styrene / butadiene copolymer latex. Therefore, the present invention further relates to a composition including a pair of organic substances which are degraded by light, heat or oxidation, and a stabilizer mixture as described above. Another embodiment of the present invention relates to a method for stabilizing an organic substance against degradation caused by light, heat, or oxidation, including adding a stabilizer mixture as described above to the organic substance. The organic substance is preferably a synthetic polymer, especially the aforementioned substances. Polyolefins are preferred, and polyethylene, polypropylene, polyethylene copolymers and polyolefin copolymers are particularly preferred. Ingredients (A), (B), and (C) may be added to the organic substance individually, or mixed with each other. Each of the components (A), (B) and (C) is preferably present in an organic substance in an amount of from 0.005 to 5%, especially from 0.001 to 1% or from 0.05 to 1% (relative to organic Depending on the weight of the substance). The weight ratio of the component (A): (B) or (A): (C) is preferably 10: 1 to 1: 100, especially 10: 1 to 1:10 or 5: 1 to 1: 5 . Other examples of weight ratios are 1: 1 to 1:10, such as 1 ·· 2 to 1: 5. The above ingredients can be added to organic matter in a conventional manner, for example, 66 paper standards are applicable to Chinese national standards (CNS ) A4 size (210 X 297 mm) (Please read the precautions on the back before filling this page)-Order --------- Line. 572952 A7 _____B7 _ V. Description of the invention (妗) Before or Add or apply dissolved or dispersed compounds to the organic matter during molding, and if necessary, then evaporate the solvent. The ingredients added to the organic substance may be powdered, granular, or a matrix containing these ingredients, for example, containing a concentration of 2.5 to 25% by weight. If necessary, the components (A), (B) and (C) may be mixed with each other before being added to the organic substance, which may be added during the polymerization, or 'cross-linking'. According to the present invention, the stabilized substance can be applied in a wide variety of types, such as film-like, fibrous, tape-like, molded compositions, contours, or adhesives used as paints, adhesives, or adhesives. Stabilized materials can also include various traditional additives, such as: 1 • Antioxidant oxo (ί: 1 · 1 · alkylated monophenols, for example, 2,6-di-tert-butyl-4-methylphenol , 2-Butyl-4,6-dimethylphenol, 2,6-Di-tert-butyl-4-n-butyl acid, 2,6-Di-tert-butyl-4 monoethyl acid , 2, 6-di-tert-butyl-4 4-isobutylfluorene, 2, 6-dicyclopentyl-4 4-methylfluorene, 2- (α-methylcyclohexyl) -4, 6-2 Methyl hydrazone, 2,6-octadecanoyl monomethyl hydrazone, 2,4,6-tricyclohexyl acid, 2,6-di-tert-butyl-4 monomethoxymethylphenol, 2,6-bis-nonyl-4-methyl acid, 2,4-dimethylformamidine-6- (1'-methylundecylamine-1-yl) fluorene, 2,4-dimethyl-6 — (1'-methylheptadecanyl-ι_yl) phenol, 2,4-dimethyl-methyl-6 — (1'-methyltridecane-1, _yl-67) This paper applies Chinese national standards (CNS) A4 specification (210 X 297 mm) (Please read the notes on the back before filling this page)-Order --------- Line-572952 A7 _B7 _ 5 Description of the invention ()) Phenol and its mixtures. 1 · 2 · Alkylthio, some cresol, for example, 2,4-dioctylthiomethyl-6-tert-butylphenol, 2,4-dioctylthio Methyl-6-methylphenol, 2,4-dioctylthiomethyl-6-ethylphenol, 2,6-dodecanylthiomethyl-4nononylphenol. 1 · 3 · Hydroquinone and its alkane hydroquinone, for example, 2, δ-di-tert-butyl-4-methoxy acid, 2,5-di-tert-butyl-terephthalate, 2 , 5-Di-tert-pentyl p-xylylenedifluorene, 2,6-di-phenyl-4 octadecyloxyphenol, 2,6-di-tert-butylhydroquinone, 2,5 -Di-tert-butyl-4-monohydroxyanisole, 3,5-Di-tert-butyl-4-anisole, 3,5-di-tert-butyl-4-monohydroxyphenyl stearyl Acid ester, bis (3,5-di-tert-butyl-4-phenyl) adipate. 1 · 4 · tocopherol, for example, α-tocopherol, / 3-tocopherol, r a Tocopherol, 5-tocopherol and mixtures thereof (vitamin E). 1 · 5 · Hydroxy thiodiphenyl ether, for example, 2,2'-thiobis (6- Monobutyl-4 methylphenol), 2,2 'monothiobis (4-octylphenol), 4,4' monothiobis (6-tert-butyl-3-methylphenol), 4, 4 'monothiobis (6-tert-2-methylphenol), 4,4' monothiobis (3,6-di-sec-pentylphenol), 4,4 'monobis (2,6 one-two) Methyl-1, 4-hydroxyphenyl) disulfide. 1 · 6 · Alkylene bisphenols, for example, 2,2'-methylenebis (6-tert-68) This paper is sized for China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling out this page) ------- Order --------- Line 572952 A7 B7 V. Description of the invention (M) Butyl -4-methylphenol), 2,2'-methylenebis (6-tert-butyl-4-ethylphenol), 2,2'-methylenebis [4-methyl-6- (α- Methylcyclohexyl) phenol], 2,2'-methylenebis (4-methyl-6-cyclohexylphenol), 2,2'-methylenebis (6-nonyl-4-methylphenol), 2,2 'monomethylbis (4,6-di-tert-butylphenol), 2,2' monoethylidenebis (4,6-di-tert-butylphenol), 2, 2 'one Ethylene bis (6-tert-butyl-4-isobutylphenol), 2,2'-methylenebis [6 — (α-methylbenzyl) -4—nonylphenol], 2, 2 ' Monomethylbis [6- (α, α-dimethylbenzyl) -4-nonylphenol], 4,4 'monomethylbis (2,6-di-tert-butylphenol), 4, 4'-methylenebis (6-tert-butyl-2-methylphenol), 1,1-bis (5-tert-butyl-4-hydroxy-2-methylphenyl) butane, 2, 6-bis (3-tert-butyl-5-methyl-2-hydroxy) -4-methylphenol, 1,1,3-tris (5-tert-butyl-4-hydroxy-1 2-methyl Phenyl) butane, 1,1-bis (5-tert-butyl-4, tris (2-methylphenyl) -3, η-h dihydrogenthiobutane, ethylene diether bis [3,3-bis (3'-tert-butyl-4, monohydroxyphenyl) butyrate], bis (3-tert-butyl-4, hydroxy-1,5-methyl-phenyl) bicyclo Pentamide, bis [2- (3'-tert-butyl- 2'-meridyl- 5'-methylfluorenyl)-6-tert-butyl- 4 -methylphenyl) parapeptide, 1 ,1 Bis (3, 5-dimethyl-2-hydroxyphenyl) butane, 2, 2-bis- (3, 5-di-tert-butyl-4 4-hydroxyphenyl) propane, 2, 2- Bis- (5-tert-butyl-4-hydroxy-2-methylphenyl) -4-n-dodecyl hydrosulfur 69 This paper is sized for China National Standard (CNS) A4 (210 X 297) Li> ----- III 1 --- · I --- I — I order --- III I--i ^ wi (Please read the notes on the back before filling this page) 572952 A7 ___ B7____ V. Description of the invention (W) -based butane, 1,1,5,5-tetra- (5-tert-butyl-4 amenthyl 2-methylphenyl) pentane. _1 · 7 · 〇- · N- and S-benzyl compounds, such as 3,5,3 ', 5'-tetra-t-butyl-4,4'-dihydroxy-diphenylmethyl ether, ten Octadecyl-4 monohydroxy-3,5-dimethylbenzyl hydrothioacetate, tri- (3,5-di-tert-butyl-4 monohydroxybenzyl) amine, bis ( 4 mono-tert-butyl_ 3 -hydroxy-2,6-dimethylbenzyl) dithio peptidate, bis (3,5-di-tert-butyl-4 4-hydroxybenzyl ) Sulfide, isooctyl-3,5-di-tert-butyl-4-mercaptobenzyl hydrothioacetate. _L_ · 8 · Hydroxybenzyl malonate, such as dioctadecyl-2,2-bis- (3,5-di-tert-butyl-2-hydroxybenzyl) -propane Diester, dioctadecyl-2- (3-tert-butyl-1, 4-hydroxy-5methylmethyl) monomalonate, dodecyl hydrothioethyl —2,2-bis— (3,5-di-tert-butyl-4—hydroxybenzyl) malonate, bis— [4-((1,1,3,3-tetramethylbutyl) ) Phenyl] -2,2-bis (3,5-di-tert-butyl-4 4-hydroxybenzyl) malonate. 1 · 9 · Aromatic compound via benzyl • For example 1,3,5-tri- (3,5-di-tert-butyl-4-hydroxybenzyl) -2,4,6-trimethyl Phenylbenzene, 1,4-bis (3,5-di-tert-butyl-4-hydroxybenzyl) -2,3,5,6-tetramethylbenzene, 2,4,6-trione ( 3,5-Di-tert-butyl-4-hydroxybenzyl) phenol 070 This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) '" (Please read the note on the back first Please fill in this page for matters); # nnn -ϋ nnn ^ OJ · nn · 1 ϋ ϋ 丨 572952 A7 _B7_ V. Description of the invention (in) 1 · 1 0 · three_ compounds, such as 2, 4 one pair (octyl (Hydrosulfanyl) —6_ (3,5-di-tert-butyl-4-monohydroxyaniline) —1,3,5-triazine, 2-octylhydrosulfanyl-4,6-bis (3, 5-1,2-tert-butyl-4-mercapto-aniline) -1,3,5-diazine, 2-octylhydrothio-4,6-bis (3,5-di-tert-butyl) -4-hydroxyphenoxy) -1,3,5-triazine, 2,4,6-tris (3,5-di-tert-butyl-4-hydroxyphenoxy ) —1,2,3-triazine, 1,3,5-tris— (3,5-di-t-butyl-4-monohydroxybenzyl) isocyanurate, 1,3,5 — Tris- (4-tert-butyl-3-hydroxy-2,6-di-methylbenzyl) isocyanurate, 2,4,6-tris (3,5-di-tert-butyl) —4 —Ethylphenylethyl) -1,3,5-trisene, 1,3,5-tris ((3,5-di-tert-butyl-1 4-monohydroxyphenylpropionamidine) —hexa Hydrogen-1,3,5-triazine, 1,3,5-trione (3,5-dicyclohexyl-4 4-hydroxybenzyl) isocyanurate. 1 · 1 1 · benzyl phosphonate, for example, dimethyl-2,5-di-tert-butyl-4-monohydroxybenzyl phosphonate, diethyl-3,5-di-tert Monobutyl-4 hydroxybenzyl phosphonate, octacosyl 3,5 bis-tert-butyl-1 4-monohydroxy benzyl phosphonate, octacosyl 5-tert-one Calcium salt of monoethyl ester of butyl-4-hydroxy3-methylbenzyl-phosphonate, 3,5-di-tert-butyl-4-hydroxybenzyl-phosphonic acid. _ 1 · 1 2 · Aminoaminophenols, for example, 4-hydroxy -lauryl tanilide, 4-monohydroxystearyl timonidine, octyl—N— (3,5—di—71 This paper is for China National Standard (CNS) A4 Specification (210 X 297 mm) (Please read the precautions on the back before filling this page) ·· # Order --------- Line 丨 Struggle!:. !!. 1 572952 A7 V. Description of the invention () tert-butyl-4 4-hydroxyphenyl) carbamate. 1 · 1 3 · Ethyl (3,5-di-tert-di-X ^-4-hydroxy phenyl and a mono- or polyhydric alcohol ester, such as and methanol, ethanol, stearyl alcohol, 1, 6 — Hexanediol, 1,9-nonanediol, ethylene glycol, 1,2-propanediol, neopentyl glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol, pentaerythritol, Tris (hydroxyethyl) isocyanurate, N, N'-bis (hydroxyethyl) ethylenedifluorene diamine, 3-thiaundecanol, 3-thiopentadecanyl alcohol, trimethylhexane Diol, trimethylolpropane, 4-monomethylol- 1-phosphorus-2,6,7-trioxabicyclo [2 · 2 · 2] octane. -1 · 1 4 · β — (5 — Tert-butyl-4__ ~ Mido-3-methylphenyl) propionic acid and mono- or polymethyl alcohol vinegar, such as, and methanol, ethanol, stearyl alcohol, 1,6-hexanediol, 1,9-nonane ~ diol, ethylene glycol, 1,2-propanediol, neopentyl glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol, pentaerythritol, tri ~ (Ethyl ethyl) isoamyl urate, N, N ' Ethylenediamine diamine, 3-thiaundecyl alcohol, 3-thiopentadecyl alcohol, trimethylhexanediol, trimethylolpropane, 4-monohydroxymethyl-1-phosphorus-2,6 , 7-trioxabicyclo [2 · 2 · 2] octane. 1 2 1 5 · / 3 — (3 1 ··························································· Esters of hydroalcohols, such as methanol, ethanol, stearyl alcohol, 1'6-pentanediol, 1,9-nonanediol, ethylene glycol, 1,2-propanediol, neopentyl Diethylene glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol, pentaerythritol, tris ((hydroxyethyl) isocyanuric acid 72) This paper size applies to China National Standard (CNS) A4 (210 X 297) Mm) ~ ---- (Please read the notes on the back before filling this page) i ^ i ^^ 1 ϋ n ϋ nn 0 I n ϋ ϋ— n I— I — 在 -ϋ n · ϋ n ϋ ϋ I · 1 ϋ ϋ n-572952 A7 ___B7 _ V. Description of the invention (ester, N, N,-bis (hydroxyethyl) ethylenediamine diamine, 3 monothiaundecanol, 3-thiapentadecane Alcohol, trimethylhexanediol, trimethylolpropane, 4-hydroxymethyl-1 2,6,7-trioxabicyclo [2 · 2 · 2] octane. 丄 ..16 · _3,5-Di-tert-Butyl 棊 -4 Monoester of hydroxyphenylacetic acid and polyhydric alcohol , Such as with methanol, ethanol, stearyl alcohol, 1,6-hexanediol, 1,9 monononanediol, ethylene glycol, 1,2-propanediol, neopentyl glycol, thio Diethylene glycol, diethylene glycol, triethylene glycol, pentaerythritol, tris (hydroxyethyl) isocyanurate, Ν, Ν, —bis (hydroxymonoethyl) ethylenediamine diamine, 3- Thiadecanyl alcohol, 3 pentadecanol, trimethyl hexanediol, trimethyl alcohol propane, 4 monohydroxymethyl-1-phospho-2,6,7-trioxabicyclo [2.2 • 2] Octane. 1 · 17 · θ— (3,5 ~ di-tert-butyl-1,4-hydroxy-1,1-benzene-1) ammonium propionate, such as N, N, -bis (3,5-di-tert-butyl) -4-hydroxyphenylpropanyl) hexamethylenediamine, Ν, Ν '-bis (3,5-di-tert-butylbutyl-4 4-hydroxyphenylpropanyl) trimethylenediamine, Ν, Ν,- Bis (3,5-di-tert-butyl-4-hydroxy-phenylpropionamidine) hydrazine, N, N >-bis [2 — (3-[3,5-di-tert-butyl-butyl-4 4 Hydroxyphenyl] propylammonium) ethyl] oxamine (Naugard ® XL-B is provided by Uniroyal). 1 · 1 8 · Ascorbic acid (vitamin C) 1 · 1 9 · Amine antioxidants, for example, N, -di-isopropyl-p-phenylenediamine, N, N > -di-sec-butyl- 1 P -Phenylenediamine 73 This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page); # Order -------- -Line | _! | · — 丨 |. 丨 572952 A7 ____ 2Z- V. Description of the invention (7 丨), N, n --- bis (1,4-dimethylpentyl) -P-phenylenediamine, N, n —-bis (1-ethyl-3—methylpentyl) -P—phenylenediamine, N, N ——bis (1-methylheptyl) -P-phenylenediamine, N , N ^ -dicyclohexyl-P-phenylenediamine, N, N-diphenyl ~ p ~ phenylenediamine, N, N-bis (2-naphthyl) -P-phenylenediamine, N-isopropyl-N / -phenyl-p-phenylenediamine, N- (1,3-dimethylbutyl) -N > -phenyl-p-phenylenediamine, N ~ ( 1-methylheptyl) -N / -phenyl-p-phenylenediamine, N-cyclohexyl-N > -phenyl-P-phenylenediamine, 4- (P-toluene Ii) —Diphenylamine, N, —Dimethyl-N, N—Di-sec-butyl-P-phenylenediamine 'diphenylamine, N-allyl diphenylamine, 4 Monoisopropoxydiphenylamine, N-phenyl-1naphthylamine, N- (4-tert-octylphenyl) -1naphthylamine, N-phenyl-2-naphthylamine, Octylated diphenylamines, such as P, P / -di-tert-octyldiphenylamine, 4-n-butylaminophenol, 4-butylfluorenylaminophenol, 4-nonaniminophenol , 4-dodecylaminophenol, 4-octadecylaminophenol, bis (4-monomethoxyphenyl) amine, 2,6-di-tert-butyl-4-dimethylamine Methylphenol, 2,4 / mono-diaminodiphenylmethane, 4,4 > -diaminodiphenylmethane, N, N, N /, N / -tetramethyl-1,4 / —Diaminodiphenylmethane, 1,2-bis [(2-methylphenyl) amino] ethane, 1,2-bis (phenylamino) propane, (0-methyl-yl) condensation Diguanidine, bis [4- (1 >, 3, dimethyldimethyl) phenyl] amine, tert-octylated N-phenyl-1naphthylamine, mono- and dialkylated Tert-butyl / tert-octyl diphenylamine mixture 74 This paper size applies to China National Standard (CNS) A4 (210 x 297 mm) (Please read the precautions on the back before filling this page) Order --- • line 丨 ^ ---- 572952 A7 _B7 _ 5. Description of the invention (? >), mono- and dialkylated nonyldiphenylamine mixtures, mono- and dialkylated dodecyldiphenylamine mixtures, mono- and dialkylated isopropyl / isohexyl Diphenylamine mixtures, mono- and dialkylated tert-butyldiphenylamine mixtures, 2,3-dihydro-3,3-dimethyl-1 4H-1,4-benzothiazine , Phenothiazine, mono- and di-alkylated tert-butyl / tert-octylphenothiazine mixtures, mono- and dialkylated tert-octylphenothiazine mixtures, N-allylphenothiazine Azine, N, N, N ,, N / —tetraphenyl-1,4-diaminobutane-2—anthracene, N, N—bis (2, 2,6,6—tetramethylmonomorphine-1 4-methylhexahexamethylenediamine, bis (2,2,6,6-tetramethylpiperidine-4 monoyl) sebacate, 2,2,6,6-tetramethylmeridine-4 -Ketone, 2,2,6,6-tetramethylmeridine- 4-ol. 2 · UV absorber and light stabilizer 2 乂 _ 丄 · 2 — (2 'monohydroxyphenyl) benzotriazole, For example, 2- (2,1-hydroxy-5'-methylphenyl) -benzotriazolyl, 2- (3'5'-1,2-tert-butyl-2'- Phenyl) benzotriyl, 2- (5'-tert-butyl-2'-hydroxyphenyl) benzotriazolyl, 2- (2'-hydroxyl-5,1 (1,1, 3,3-tetramethylbutyl) phenyl) benzo-triazolyl, 2-(3 ', 5'-di-tert-butyl- 2'monylphenyl) -5-chloro-benzene Pyridyl, 2- (3, -tert-butyl-2'-hydroxy-5, -methylphenyl) -5-chloro-benzotriazolyl, 2- (3,1-sec-butyl -5'-tert-butyl-2'-hydroxyphenyl) benzotriazolyl, 2- (2,1-hydroxy ~ 4, -octyloxyphenyl) benzotriazolyl, 2- (3, , 5 75 This paper size is in accordance with China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page) 1 ϋ nn 1 n 1 f 11 ttt n mwm— n line 丨· 572952 A7 Five B7, Description of the Invention (I1), one, two, one, t-pentyl, 2'-transylphenyl, benzotriyl, 2- (3 ,, 5 ,, bis (αα-dimethyl) Phenylbenzyl) ~ 2, monohydroxyphenyl) benzotriazolyl, 2- (3, a tert-butyl ~ 2, a 5 'mono (2-octylgasoylethyl) phenyl) ~ 5 ~ chloro monobenzotriazolyl, 2- (3, -tert-butyl-5, ~ [2-one (2-ethyl Hexyloxy) -ethyl]-2'-hydroxyphenyl) ~ 5 -Chloro-benzobenzotriyl'2-(3'-tert-butyl-2 '~ —Methoxyquinylethyl) phenyl) -5—Chloro ~ benzotrivalyl, 2-(3′-tert-butyl-2 ′ —Methranyl-5, — (2-methoxy Pseudoethyl) phenyl) benzotrivalyl, 2 ~ (3,-tert-butyl- 2'-hydroxy-5 '— (2-octyl-oxycarbonylethyl) phenyl) benzotri Oxazolyl, 2- (3, 1-tert-butyl-5, 1- [2- (2-ethylhexyloxy) carbonylethyl] -2'-hydroxyphenyl) benzotriyl, 2-(3 —Ten-Cycloyl—2′-Cyclo-5′-methylphenyl) benzo-triazolyl, and 2- (3, 1-tert-butyl- 2′-hydroxy- 5 ′-(2-iso Octyloxycarbonylethyl) phenylbenzotriazolyl 2,2'-methylene-bis [4- (1,1,3,3-tetramethylbutyl) -6-benzo A mixture of oxazolyl-2-ylphenol]; 2-a [3'-tert-butyl-5 '-(2-methoxycarbonylethyl)-2'-hydroxy-phenyl]-2fluorene-benzotris Esterification product of oxazolyl and polyethylene glycol 300, [R-CH2CH2-C〇〇-CH2CH2-] 2-where R = 3'-tert-butyl butanyl-4, monohydroxy-5, -2H-benzo Triazolyl-2 monophenylphenyl, 2-[2 > -hydroxy-3 >-(α, α-dimethylbenzyl) -5 '-(1,1,3,3-tetramethylbutane Based) monophenyl 76 (Please read the notes on the back before filling this page) Order --------- ff! ----------------- This paper Standards are applicable to China National Standard (CNS) A4 specifications (210 X 297 mm) 572952 A7 _________B7 _ V. Description of the invention (70) Benztriazole; 2-[2 > —Hydroxy-3 >-(1 , 1,3,3-tetramethylbutyl) ~ 5 /-(α, α-dimethylbenzyl) -phenyl] benzotriazole. 2 · 2 · 2-Benzylbenzone, for example, 4-Benzyl, 4-methoxy, 4-octyloxy, 4-decyloxy, 4-dodecyloxy, 4-benzyloxy Group, 4,2,4,4-trihydroxy and 2, monohydroxy-4,4'-dimethoxy derivatives. 2 · 3 · Ester of substituted or unsubstituted benzoic acid, such as 4-tert-butyl-phenylsalicylate, phenylsalicylate, octylphenylsalicylate, benzoylhydrazone Resorcinol, Bis (4-tert-butylbenzylhydrazone), Resorcinol, Benzobenzylresorcinol, 2,4-Di-tert-butylphenyl 3,5-di-tert-butyl Benzyl-4, Benzylbenzoate, Hexadecyl 3,5-di-tert-butyl-1, 4-hydroxybenzoate, octadecyl 3,5-di-tert-butyl-1, 4-1 Hydroxybenzoate, 2-methyl-4,6-di-tert-butylphenyl 3,5-di-tert-butyl-4-hydroxymonobenzoate 0 · 4 · aromatic ester , Such as ethyl α-cyanomonomethyl, / 3-diphenyl acrylate, isooctyl α-cyano / 3,0-diphenyl acrylate, methyl α-carbomethoxycinnamic acid Ester, methyl α-cyano- / 5, / 3-methyl-ρ-methoxy-cinnamate, butyl α-cyano point, and methyl-P-methoxy-cinnamate, Methyl-Carboxymethoxy-P-methoxycinnamic acid_ and 1 \ [-(0-Carboxymethoxy-5 / 5-cyanoethylene Base)-2-methyl Zhao D. 2 · 5 · Nickel compounds • For example 2, 2 '-thio-one-double-one [4 — (77 This paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) (Please read the precautions on the back first (Fill in this page again)

------- Order ------- ——Line L 572952 A7 ___B7___ V. Description of the invention (1,1,3,3-tetra-methylbutyl) phenol] nickel complex, such as 1: 1 or 1: 2 complexes, with or without additional reactive groups, like n-butylamine, triethanolamine or n-cyclohexyldiethanolamine, nickel dibutyldithiothiocarbamate, Nickel salts of monoalkyl esters of 4-hydroxy-3,5-di-di-tert-butylbenzylphosphonic acid, such as methyl or ethyl esters, and nickel complexes of ketoxime, such as 2-hydroxy-4A Phenyl undecyl ketone oxime, 1-phenyl-4 4-lauryl-5-hydroxypyridyl nickel complex, with or without additional reactive groups. · 6 · Ethylenediamine diamine, such as 4,4'-dioctyloxyoxopanamine '2' 2 '-dioctyloxy-5,5' -di-tert-butoxy- Amifenidine, 2,2'-docosadecyloxy-5,5, one-two-tert-butoxypanidineaniline, 2-ethoxy-1'-ethoxypanidine, Ν, Ν 'One bis (3-dimethylaminopropyl) ethylenediamine diamine, 2-ethoxy-5-tert-butyl-1 2'-ethoxyfluorhexidine and its 2-ethoxy-2 A mixture of 'monoethyl-5,4'-di-tert-butoxyanilide and a mixture of ortho- and meta-methoxydisubstituted oxotetanil, and 0- and p-ethoxy -Disubstituted oxotetanil. 2 · 7 · 2 — (2 -Hydroxyl) -1,3 · 5 -Tris—e.g. 2,4,6-tri- (2-Hydroxy-4 -octyloxy-phenyl) -1 , 3,5-triazine, 2- (2-hydroxy-4 4-octyloxyphenyl) -4,6-bis (2,4-dimethylphenyl) -1,3,5-triazine ， 2 · — (2,4-dihydroxyphenyl) -4,6 —bis (2,4-dimethylphenyl) -1,3,5-triazine, 2,4-bis (2-hydroxy —4 monopropyloxyphenyl) —6— (2, 4-dimethyl) 78 This paper is sized for China National Standard (CNS) A4 (210 X 297 mm) (please read the precautions on the back first) (Fill in this page) Order --------- f f ----------------------- A7 572952 V. Description of invention (Gan, Yi! _, 3,5-triazine, 2- (2-hydroxy-4-octylphenyl) fluorenylphenyl) -4'6-bis (4-methylphenyl) -1'3'5 2 Mono (2-Cyclo-4dodecyloxyoxy)-4-6 6-bis (2,4-dimethylphenyl) -1,3,5-tri_, 2-[2 Monohydroxy-4 mono (2-hydroxy-3 -butyloxy-propane (Phenyl) phenyl] -4,6-bis (2,4-dimethyl) -1,3,5-tri-, 2-a [2-Cyclo-4- (2-Cyclo-3-octyl) Oxymonopropyloxy) phenyl] -4,6-bis (2,4-dimethyl) monofluorene, 3,5-triazine, 2- [4- (dodecyloxy / tridecyl Hydoxy-2-mercaptopropoxy) _2-mercapto-phenyl] -4,6-bis (2,4-dimethylphenyl) -1,3,5-triamidine, 2 ~ [2-Hydroxy-4 ((2-hydroxy-3-dodecyloxy-propoxy) phenyl]] 4-'6-bis (2,4-dimethylphenyl) -1,3,5 -Triazine, 2- (2-hydroxy-4,4-hexyloxy) phenyl-4,6-diphenyl-1,3,5-trifluorene, 2- (2-meryl-4-methoxyphenyl A) 4 ′ 6 -diphenyl-1 ′ 3 ′ 5_triazine, 2,4,6-tris (2-xiangyl-4— (3-butoxy-2-meryl-propoxy) ) Phenyl] -1,3,5-triazine, 2- (2-hydroxyphenyl) -4- (4-methoxyphenyl) -6-phenyl-1,3,5-triazine, 2— {2—Cyclo-4— [3— (2-Ethylhexyl—1— Yl) -2-Ethylpropoxy] phenyl} -4,6-bis (2,4-dimethylphenyl) -1,3,5-triazine. 3. Metal deactivators, such as N, N, Diphenylethylenediamine diamine, N-salicyl-N, -salicylhydrazine, N, N, double (salicylamine 79) The paper size is applicable to Chinese National Standard (CNS) A4 (21〇X 297 public love 1 '(Please read the precautions on the back before filling this page) Order --------- line 丨 · 丨!丨 li 572952 A7 __B7______ V. Description of the invention (77) yl) hydrazine, N, N, -bis (3,5-di-tert-butyl-4, tris-phenylphenyl-propionamidine) hydrazine, 3-salicylamino 1,1,2,4 Triazolium, bis (benzylidene) ethylene dihydrazine, hydrazine, dihydrazine, hydrazidine, isophthalamidine, dihydrazine, sebacamide, bisphenylhydrazine , N, N '1,2-Ethyl hexamethylene dihydrazide dihydrazine, N, N' One pair (salicylidene) ethylene dihydrazide hydrazine, Ν, Ν, one double (salicylidene) monothiopropyl Dihydrazine. 4. Phosphites and phosphonates such as triphenyl phosphite, diphenyl alkyl phosphite, phenyl dialkyl phosphite, tri- (nonylphenyl) phosphite, trilauric acid Tris (octadecyl phosphite) 'stearylstearyl pentaerythritol diphosphite, tris (2,4-di-tert-butylphenyl) phosphite, diisodecyl pentaerythritol Diphosphite 'bis (2,4-di-tert-butylphenyl) pentaerythritol diphosphite, bis (2,6-di-tert-butyl-4-methylphenyl) pentaerythritol-1 Phosphite, diisodecyloxy pentaerythritol diphosphite, bis (2 '4 t-butyl- 6-methylphenyl) pentaerythritol diphosphite' bis (2,4,6 — Trinyl (tert-butylphenyl) pentaerythritol diphosphite, tristearyl sorbitol triphosphite, four (2 '4 t-butyl-t-butylphenyl) 4, 4, biphenyl Bisphosphonic acid ester, 6-isooctyloxy-2,4,8,1 0-tetra-t-tert-butyl- 1 2 Ηdiphenyl [d, g] -1,3,2-dioxo Phosphorus, 6-Fluoro-2 4,8,10-tetra-t-butyl-12-methyl-diphenyl [d, g] -1,3,2-dioxophosphine, bis (2,4,2-di-tert-butyl -6 —Methylphenyl) methylphosphite, bis (2 '4 121 & 80) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Please read the back Note for refill this page) • — — III — — · 11111111 I! 572952 A7 B7 V. Description of the invention (cut) — Butyl-6 monomethylphenyl) ethyl phosphite, 2, 2 V, 2 Xi—Azine [Triethyldi (3,3 ', 5,5'-tetra-t-tert-butyl-1, 1 / biphenyl-2,2 > -diyl) phosphite], 2 monoethylhexyl (3,3,5,5,5 ^ -tetra-tert-butyl-1,1, biphenyl-2,2 diyl) phosphite, 5-butyl-5-ethyl A radical 2— (2,4,6—tri-tert-butylphenoxy) —1, 3,2—dioxaphosphorane. Particularly preferred are the following phosphites: tri (2,4— Di-tert-butylphenyl) phosphite (Irgafos®® 168, Ciba-Geigy), tris (nonylphenyl) phosphite , (Please read the back of the precautions to fill out this page)

(ch3) 3c > ^^ 〇 (ch3); 3/3

(CH3) 3C \ IΛ 'ρ—ο—ch2ch2- C (CH3) 3 Ν (Β) ^ · 11111111 IAW · ------- This paper size applies to China National Standard (CNS) A4 (210 χ 297 Mm) 572952 A7 B7 V. Description of the invention (7?)

P ——〇——CH2CH (C4H9) CH2CH3 (C)

(CH3) 3C c (ch3) 3 (ch3) 3c (D)

° x °) 0 j L0

CH 3 | / 3 J ° \-< x: >-. Seven (E) (Please read the notes on the back before filling this page) P-〇—c18h37

(F) H37C ~ 〇 --P

p—〇ch2ch3 (G) — · II I ---- order --------- I ---- 5 · hydroxylamine, for example, N, N -dibenzyl derived from hydrogenated tallowamine Hydroxylamine, N, N-diethylhydroxylamine, N, N-dioctylhydroxylamine, N, N-di-laurylhydroxylamine, N, N-di (tetradecyl) alkylmeramine, N, N-di (hexadecyl) hydroxyamine, N, N-di (ten 82) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 572952 A7 _B7_ V. Description of the invention (work) 8 Alkyl) hydroxylamines, N-hexadecyl-N-octadecylhydroxylamine, N-heptadecyl-N-octadecylhydroxylamine, N, N-dialkylmerylamine. 6. Nitrones, for example, N-benzyl-α-phenyl-nitrone, N-ethyl-α-methyl-nitrone, N-octyl-α-heptyl-nitrone, N-lauryl One α —-f —honoyl nitrone, N-tetradecyl—α-tridecyl mononitrone, N—hexadecyl—α-pentadecyl mononitrone, Ν—octadecyl Yuanyi ^ Seventeen Yuanyi Nitridone, N-hexadecyl Yuan-α-heptadecyl-nitronone, N-octadecyl-α-pentadecyl-one nitrone, N-ten Seven-membered group-α-seven-membered group-nitronone, N-eighteen-membered group-α-hexadecyl-one nitrone, derived from hydrogenated tallow amine N, N-dialkylhydroxylamine nitrone. 7. Thio synergists, for example, dilauryl thiodipropionate or distearyl thiopropionate. 8. Pergassing detergents, such as / 3-thiodipropionic acid esters, such as lauryl, stearyl, tetradecyl or tridecyl esters, hydrothiobenzimidazolyl, or 2-hydrogen Zinc salts of thiobenzimidazole, zinc dibutyl dithiocarbamate, di (octadecyl) disulfide, pentaerythritol tetraol (Θ-dodecyl hydrogenthio) propionic acid salt. 9. Polyamide stabilizers, such as copper salts combined with iodide and / or phosphorus compounds, and salts of divalent manganese. ] 0 · Alkali co-stabilizers, such as melamine, polyvinylpyrrolidone, dicyandiamide, tri-allyl cyanurate, urea derivatives, hydrazine derivatives, amines, polyamides, polymers Urethane, alkali metal or alkaline earth metal salt of higher fatty acid 83 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page) Order --- ------ f · ----------------------- 572952 A7 ____________ 5. Description of the invention (W), for example, calcium stearate, Zinc stearate, magnesium succinate, magnesium stearate, sodium ricinole and potassium hexacarbonate, antimony pyrocatechuate or zinc pyrocatechin. 1 1 Nucleic acid agents, for example, inorganic substances, such as talc, metal oxides, magnesium oxide, phosphates, carbonates or sulfates, such as titanium dioxide or preferably alkaline earth metals; organic compounds, such as mono- or polycarboxylic acids and their Salts, such as 4-tert-butylbenzyl, adipic acid, diphenylacetic acid, sodium succinate, or sodium benzoate; polymeric compounds, such as ionic copolymers (ionomers). Particularly preferred is 1,3: 2,4 bis (3 ', 4'-dimethylbenzyl fork) sorbitol, 1,3: 2,4-two-part p-methylbenzyl fork) Sorbitol, and 1,3: 2,4 bis (benzylidene) sorbitol. 1 2 2 .... filling and reinforcing agents, for example, calcium carbonate, silicate, glass fiber 'asbestos' talc, high-sensitivity clay, mica, barium sulfate, metal oxides and hydroxides, carbon black, graphite, Powder or fiber of wood powder or other natural products, synthetic fiber. 1 2 3 Other additives, such as plasticizers, lubricants, emulsifiers, colorants 'flow additives, catalysts, flow control agents, optical brighteners, fire retardants' antistatic agents and blowing agents (blowing agents) ). 1 4 ″ benzopyranone and fluorenone, for example, are described in US-A-4,325 '863; US_A-4,338,244, US-A-5,175,313; US-A- 5,216,052, US-A_5,252,643, DE-A-4, 316 '611; DE-A-4,316,622; DE-A-4,316, 876; EP-A-0, 589,839 or EP-A-0,591,102 or 3-ί: 4 — (2 — ethoxyloxyethoxy) phenyl] 5, 7 —di-tert 84 _______ This paper size applies China National Standard (CNS) A4 Specification (210 X 297 mm) (Please read the precautions on the back before filling this page) ------- Order --------- Line '572952 A7 _B7 _ 5. Description of the invention (P) monobutyl-benzofuran-2-one, 5,7-di-tert-butyl-1 3-[4-mono (2-stearyloxyethoxy) phenyl ] Benzofuran-2 monoketone, 3,3 bis [5,7-di-tert-butyl-3--3- (4-[[2-hydroxyethoxy] phenyl) benzofuran-2-one], 5, 7-di-tert-butyl-3-(4-ethoxyphenyl) benzofuran-2 monoketone, 3- (4-ethoxyloxy-3,5-dimethylphenyl) -1 5, 7 — Uncle Eryi — Benzo-benzofuran 2-ketone, 3- (3,5-dimethyl-4-trimethylacetoxy) -5,7-di-tert-butyl-benzofuran 2-ketone , 3-(3,4-dimethylphenyl) -5,7-dione. Tert-butylbenzofuran-2-one, 3-(2,3-dimethylphenyl) -5, 7-Di-tert-butyl-benzofuran-2-one. The total weight ratio of ingredients (A), (B) and (C) to the total weight of traditional additives is, for example, 100: 1 to 1: 100 or 10: 1 to 1:10. The following examples will illustrate the present invention in more detail, Unless specifically stated 'All percentages and parts are by weight. The light stabilizers used in Examples 1 to 4: TTNTTVTN 791 fRTIVn: a mixture of TINUVIN 770 (RTM) and CHIMASSORB 944 (RTM) in a weight ratio of 1: 1. 85 This paper size applies to China National Standard (CNS) A4 (210 X 297 public love) (Please read the precautions on the back before filling this page) --I--II Order--III 1--I · 572952 A7 B7 V. Description of the invention (W) Compound (B small a-1): Η — Ν

0—C— (C15-C17alkyl)

〇II H3C ch3 TINUVIN 770 (RTM):

h3c ch3 TINUVIN 765 (RTM): 〇 II (ch2) 8—c—o

(Please read the notes on the back before filling this page) #

H3C ch3

o II _ (CH2) g--C——O

TINUVIN 123 (RTM): h17c8o

〇-c-

oII 〇 II (ch2) 8—c—o

------- Order --------- Line 'TINUVIN 144 (RTM):

〇II o —c- c—— c4h9

86 This paper size applies to China National Standard (CNS) A4 (210 x 297 mm) 572952 A7 B7 V. Description of the invention (W)

K D A

57 LA B

c- 2 H c. 〇

ο Η = c——c——〇 ο Η = C——C——ο C. 〇 ο

HOSTAVIN N 20 (RTM): / CH2 h (9 ^) 9 -N

(Please read the notes on the back before filling this page) ------- Order --------- Line- HOSTAVIN N 24 (RTM): o

II / CH2CH ^ -C—O— (C12-C14alkyl)

U

I

This paper size applies to China National Standard (CNS) A4 (210 χ 297 mm) 572952 A7 B7 V. Description of the invention (mosquito) UVINUL 4049 H (RTM):

SANDUVOR PR 31 (RTM): h3co

CHZZC

(Please read the precautions on the back before filling in this page)-# ϋ n n n I 1: OJ9 I ϋ I n ϋ ϋ ·. Line 丨 GOODRITEUV 3034 (RIM): H3C CH3 a H3C ru y_ ^ ° 0 ^ ycH3 λτ

H—NN——CH2CH ^ —N, N—H H3c CH3 H3C CH3 GOODRITE UV 3150 (RTM): 88 This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 572952 A7 B7 V. Invention Description (W)

Compound a- 10- (B-

Η —N

CHIMASSORB 944 (RTM):

CYASORB UV 3346 (RTM): This paper size is applicable to China National Standard (CNS) A4 (210 x 297 mm) -------------------- Order --- ------ Line (Please read the precautions on the back before filling this page) 572952 A7 B7 V. Description of the invention (W)

n

(CH

(Please read the notes on the back before filling out this page); # ------- Order ---------,

CHIMASSORB 119 (RTM): 90 -I ϋ ϋ I nn ϋ n ϋ ϋ I ϋ n ϋ -ϋ ϋ ϋ ϋ ϋ I ϋ-This paper size applies to China National Standard (CNS) A4 (210 x 297 mm) 572952 A7 B7 V. Explanation of the invention (find) R · R ·

I I R · — NH — (CH2) 3— N — (CH2) 2— N — (CH2) 「NH — R, UVASIL 299 (RTM): CH, -Si——0_

H3C h3c (ch2) 3 〇 and λ

CH, where R ’is H3c — N

n-C4H9 UVASIL 2000 (RTM): Blend of UVASIL 299 (RTM) and polypropylene

CH 3

• CH 3 —N — I n-C4H9 N—CH, 'CH, CH, (Please read the notes on the back before filling this page) — II ϋ «III) 5J · II 1 III n UVINUL 5050 H (RTM) :

Η I

V LICHTSCHUTZSTOFF UV 31 (RTM): 91 This paper size is applicable to Chinese National Standard (CNS) A4 (210 x 297 mm) 572952 A7 B7 V. Description of the invention (?)

(Please read the precautions on the back before filling out this page) The paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) 572952 A7 ___ B7 ^ ___ V. Description of the Invention (f) Mixture (A-2) : A mixture of compounds (A-2-a) and (A-2-b) in a weight ratio of 4: 1

(A-2-a)

(A-2-b) Example 1: Light-stable 100 parts unsubstituted polypropylene powder of polypropylene homopolymer film (melt index: 3 · 8 g / 10 minutes at 230 ° C and 2160 Measured in grams) neutralized 0.05 parts of pentaerythritol-tetra {3- (3,5-di-tert-butyl-4-hydroxy) propionate}, 0.05 parts in a Brabender plasticity meter. Tri {2,4-di-tert-butylphenyl} phosphite, 0.1 part of calcium stearate, 0.25 part of titanium dioxide (Anatase) and the stabilizer mixture shown in Table 1, in Homogenize at 2000 ° C for 10 minutes. The obtained substance is between two aluminum foils of a laboratory-grade crimper at a temperature of 2 1 93 \ paper. Applicable to China National Standard (CNS) A4 (210 X 297). (%) (Please read the precautions on the back before filling this page) IIIIIII Order ---------- 572952 A7 B7 V. Description of the invention () Compressed at 0 ° C for 6 minutes to make a thick 0 · 5 mm film, followed by cooling to room temperature in a water-cooled press, cutting the sample into a size of 60 mm X 25 mm, and exposing it to a WEATHER-OMETER Ci 65 (blackboard temperature 6 3 ± 2 ° C), No watering during the period). Periodically remove the sample from the exposure unit and measure its carbonyl content with an infrared spectrometer. The exposure time required to form a carbonyl absorption of 0.1 is a measure of the efficiency of a stabilizer mixture. The results are shown in Table 1. Table 1: Stabilizer mixture time to 0.1 carbonyl absorption (hours) Control group 220 0.20% TINUVIN 791 (RTM) (= previous technique) 4 595 0.10% TINUVIN 622 (RTM) + 0.05% CHIMASSORB 944 (RTM) + 0.05% ΉΝυνίΝ 770 (RTM) > 5 500 0.10% mixture (Α-2) + 0.05% CHIMASSORB 944 (RTM) + 0.05% TINUVIN 770 (RTM) > 5 500 Example 2: Polyethylene HD Film light-stable 100 parts of unsubstituted high-density polyethylene powder (density: 0.964CnT3, melting index: 5.0 g / 100 minutes, measured at 190 ° C and 2.160 g) in a Brabender plasticity Total and 0.03 octadecyl 3- (3, 94) This paper size applies to China National Standard (CNS) A4 (210 x 297 mm) (Please read the precautions on the back before filling this page)-Order --------- Line. 572952 A7 __B7 V. Description of the invention (7)) Neutralize 0.05 parts of pentaerythritol-tetra {3_ (3,5_di-tert-butyl_4_hydroxy) ) Propionate}, 0.05 parts of tris {2,4-di-tert-butylphenyl} phosphite, 0.1 part of stearic acid Ming '0.25 part of titanium dioxide (Anatase) and Tables 3A and 3B Shown The stabilizer mixture was homogenized at 20 ° C for 10 minutes. The obtained material was compressed between two aluminum foils in a laboratory-grade presser at a temperature of 2600 ° C for 6 minutes to prepare a 0.5 mm thick The film was then cooled to room temperature in a water-cooled press, the sample was cut to a size of 60 mm X 25 mm, and exposed to a WEATHER-OMETER Ci 65 (blackboard temperature 6 3 soil 2 ° C). watering). Periodically remove the sample from the exposure unit and measure its carbonyl content with an infrared spectrometer. The exposure time (To ") equivalent to the formation of carbonyl absorption of 0.1 is an evaluation criterion for the efficiency of the light stabilizer system. The results are shown in Tables 3A and 3B. Table 3A: Light stabilizer system Tαι (hours) T (U (hours) each amount of light stabilizer used is 0.075% * Light stabilizer system and TINUVIN 622 (RTM) combination each light stabilizer used Yes 0.05% *). No 235-ΉΝΜΝ 770 (RTM) + CHIMASSORB 944 (RTM) 2700 2980 TINUVIN 770 (RTM) + CHIMASSORB 119 (RTM) 2495 3035 96 This paper is sized according to China National Standard (CNS) A4 (210 x 297 mm) (Please read the notes on the back before filling out this page)

e H ϋ I n II ϋ II n ϋ I nn ϋ ϊ ϋ n I n ϋ ϋ I ϋ .1 ii ϋ ϋ | _1 I 572952 A7 _B7 V. Description of the invention (? TINUVIN 770 (RTM) + CYASORB UV 3529 ( (RTM) 3130 3510 TINUVIN 770 (RTM) + UVINUL 5050 H (RTM) 2790 3295 TINUVIN 770 (RTM) + DASTIB 1082 (RTM) 3285 3610 TINUVIN 770 (RTM) + ADK STAB LA 63 (RTM) 2670 2915 TINUVIN 770 (RTM ) + ADK STAB 68 (RTM) 2725 3425 TINUVIN 770 (RTM) + LICHTSCHUTZSTOFF UV 31 (RTM) 2320 3155 *) The total concentration of light stabilizer is 0.15%. Table 3B: Light stabilizer system T (U (hour). The amount of light stabilizer used is 0.075% *). T.0.1 (hour) light stabilizer system, combined with ΉΝϋνΐΝ 622 (RTM). The amount of light stabilizer used is 0.05% *). No 235-CHIMASSORB 944 (RTM) + 2280 3150 TINUVIN 144 (RTM) CHIMASSORB 944 (RTM) + 2245 2870 TINUVIN 123 (RTM) CHIMASSORB 944 (RTM) + 2530 3170 HOSTAVIN N 20 (RTM) 97 (Please read the precautions on the back before filling out this page) --I ---- Order · -------- * 5 ^ 1 ▲ This paper size applies to Chinese National Standard (CNS ) A4 specification (210 X 297 mm) 572952 A7 B7 V. Description of the invention un CHIMASSORB 944 (RTM) + GOODRITE UV 3034 (RTM) 2855 3020 CHIMASSORB 944 (RTM) + GOODRITE UV 3150 (RTM) 2320 2765 CHIMASSORB 944 (RTM ) + Compound (B-6-al) 2780 3435 CHIMASSORB 944 (RTM) + UVINUL 4049 H (RTM) 2925 3265 CHIMASSORB 944 (RTM) + Compound (B-10-al) 2965 3385 CHIMASSORB 944 (RTM) + Compound ( Bla-1) 2805 3130 CHIMASSORB 944 (RTM) + SANDUVOR 3050 (RTM) 2030 2550 CHIMASSORB 944 (RTM ) -f SANDUVOR PR-31 (RTM) 2400 2890 (Please read the notes on the back before filling this page) *) The total concentration of light stabilizer is 0.15%. Example 4: Light stabilization of polypropylene homopolymer film. 100 parts of unsubstituted polypropylene powder (melt index: about 3.8 g / 10 minutes, measured at 230 ° C and 2160 g) in a Brabender plastic meter and 0.05 part of pentaerythritol-tetra {3- ( 3,5-di-tert-butyl-4-hydroxy) propionate}, 0.05 parts of tris {2,4-di-tert-butylphenyl} phosphite, 0.1 part of stearin Acid bromide, 0.25 parts of titanium dioxide (Anatase) and the stabilizer mixture shown in Tables 4A, 4B, 4C, and 4D were homogenized at 200 ° C for 10 minutes. 98 pieces of aluminum foil This paper size is in accordance with Chinese National Standard (CNS) A4 specification (210 X 297 mm) 572952 A7 ______B7___ 5. Description of the invention (%), compressed at a temperature of 2 60 ° C for 6 minutes to make a thick one. · 5 mm film, followed by cooling to room temperature in a water-cooled press, cutting the sample into a size of 60 mm X 25 mm, and a WEATHER-OMETER Ci 65 (blackboard temperature 6 3 ± 2 ° C) Exposure, no watering during the period). Periodically remove the sample from the exposure unit and measure its carbonyl content with an infrared spectrometer.

The exposure time (Tu) equal to the formation of carbonyl absorption of 0.1 is the evaluation standard for the efficiency of the light stabilizer system. The results are shown in Tables 4A, 4B, 4C and 4D. Table 4A: Light stabilizer system D (U (hours) each used The amount of light stabilizer is 0.1% *). T (U (hour) light stabilizer, combined with ΉΝυνΐΝ622 (RTM) The amount of stabilizer in each light stabilizer system is 0.09% and the amount of ΉΝΝΝ622 (RTM) is 0.02% *). Without 310 ΉΝυνΐΝ770 (RTM) + 4520 5525 CHIMASSORB 944 (RTM) ΉΝυνίΝ 770 (RTM) + 4935 6255 CHIMASSORB 119 (RTM) ΉΝΙΝΝ770 (RTM) + 5980 > 6930 CYASORB UV 3346 (RTM) 99 Paper size applies to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page)

n I-04 · ϋ ϋ n ϋ ϋ ϋ ϋ · I 572952 A7 B7 V. Description of the Invention (P) TINUVIN 770 (RTM) + UVASIL 299 HM (RTM) 5365 > 6930 TINUVIN 770 (RTM) + UVASIL 2000 ( (RTM) 5785 6805 TINUVIN 770 (RTM) + CYASORB UV 3529 (RTM) 6010 6675 TINUVIN 770 (RTM) + UVINUL 5050 H (RTM) 2720 3225 *) The total concentration of light stabilizer is 0.2%. Table 4B: Light stabilizer system T (U (hour) The amount of each light stabilizer is 0.1% *) · T (U (hour) light stabilizer system, combined with the mixture (A-2) each light The amount of stabilizer in the stabilizer system is 0.075% each and the amount of the mixture (A-2) is 0.05% *). Without 310-TINUVIN 770 (RTM) + 4520 5475 CHIMASSORB 944 (RTM) TINUVIN 770 (RTM) + UVINUL 2720 3370 5050 H (RTM) *) The total concentration of light stabilizer is 0.2%. (Please read the precautions on the back before filling this page) 100 This paper size is applicable to Chinese National Standard (CNS) A4 (210 χ 297 mm) 572952 A7 B7 V. Description of the invention (p) Table 4C Light stabilizer system T 〇.i (hour) The amount of each light stabilizer used is 0.1% *). T. ”(Hours) Light stabilizer system, combined with ΉΝΜΝ 622 (RTM) The amount of stabilizer in each light stabilizer system is 0.075%, and the amount of TINUVIN 022 (RTM) is 0.05% *). No 315-CHIMASSORB 944 ( (RTM) + ΉΝυνίΝ 765 (RTM) 3775 4585 CHIMASSORB 944 (RTM) + TINUVIN 144 (RTM) 3485 3990 CHIMASSORB 944 (RTM) + TINUVIN 123 (RTM) 3055 3365 CHIMASSORB 944 (RTM) + HOSTAVIN N 20 (RTM) 3335 4325 CHIMASSORB 944 (RTM) + HOSTAVIN N 24 (RTM) 2795 3315 CHIMASSORB 944 (RTM) + ADK STAB LA 57 (RTM) 4065 5110 CHIMASSORB 944 (RTM) + ADK STAB LA 62 (RTM) 2725 3635 CHIMASSORB 944 (RTM) + ADK STAB LA 67 3045 3485 CHIMASSORB 944 (RTM) + GOODRITE UV 3150 (RTM) 3300 4115. 101 (Please read the precautions on the back before filling this page) --I-- 丨 丨 Order ---------- -Block I. ϋ n 1 «f— · 1 n ϋ ϋ II n ϋ ϋ III ϋ ϋ ϋ I · This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 572952 A7 B7 Jade, Description of the invention (i) (2) The same meaning as in the above (B) or (C). The above general description is also relevant to this second stabilizer mixture (applied in an appropriate manner) (can be used to stabilize organic substances against degradation caused by light, heat, or oxidation). The compound of component (AA-1) is described in, for example, US-A-4,609,698, which is incorporated herein by reference. The component (AA-2) compounds are described, for example, in EP-A-1,803, which is incorporated herein by reference. The preferred ingredient (AA-2) compound is FERRO AM 806 (RTM) or KOKANOX (RTM). The weight ratio of the component (AA-1) or (AA-2) to the component (B) or (C) is preferably 10 ·· 1 to 1: 100, especially 10: 1 to 1 · · 10 or 5: 1 to 1: 5. Other examples of weight ratios are 1: 1 to 1 ·· 10, like 1: 2 to 1: 5. The component (AA-1) or (AA-2), and the component (B) or (C) is preferably present in the stabilized substance in an amount of from 0.005 to 5%, especially from 0.01 to 1% or 〇.〇 5 to 1%, (relative to the weight of the substance). Ingredient (AA-1) is a compound of formula (AA_1-I) or (AA-1-II) (Please read the precautions on the back before filling this page)

------ Order --------- Line U 0—RilT0—

〇II c—RilT -c- R1—〇—E100 (AA-1 -I) E ';

O 〇 " c—R11T " C—0—R1 ~ 0 'o oII II —C—Ri ^ ~ c—E, 100 Π100 (ΑΑ-1-Π) 103 This paper standard applies to China National Standard (CNS) A4 Specifications (210 x 297 mm) 572952 A7 B7___ V. Description of the invention (〆) Where n1QQ is a number from 1 to 3, preferably 2; Runs that are not related to each other are C2-C18 alkylene, C4- C8 olefinic support, C4-C20 monooxy academy, C4-C20 polyoxy academy support, ring academy support, C7-C1G ring academy support --- academy support C8-C2G this support --- * academy support or the following group foundation

3 10Η R——c

R——C 3 10Η (Please read the notes on the back before filling this page) R. c I H_c

3 10H

R. • N

CH

CHICH

H3C

CH

ϋ nnnn ^ * eJ · I «I in n flu nn I ϋ nnn MMmK I n ϋ nnnn ϋ n I n ϋ ϋ ϋ i-— ϋ ϋ I This paper size applies to China National Standard (CNS) A4 (210 X 297 Mm) 572952 A7 B7 V. Description of Invention (/ C)

V-Y-V ^ 100 1 100 ^ 100 HX CH,

• N——CH—CH- KC CH, R, H, C CH,

or

2

12 Ή mi〇〇 is an integer from 2 to 10; X1〇o is a formula -〇- or -NR1 () 5-group; Yh) 〇 is C2-C12 alkylene, C4-C12 alkylene, which is represented by Interrupted by one or two -0- or -NH- groups; cyclohexyl, cyclohexyl-dimethylene, phenylene or phenylene-Z1G (rphenylene, where Z1G () is -0-, -CH2- or -S〇2-, Ri〇2 are unrelated to each other by a direct bond, G-Cu alkylene, C2-C6 alkylene, C5-C8 cycloalkylene, C5-C8 cycloolefin, benzene Support, C7-C12 * # Alkyl or the following group group 105 --------------------- Order --------- Line ιβ (Please Please read the notes on the back before filling this page) This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 572952 A7 B7 V. Description of the invention ((6) -CH——, ——CH2CH ^ —N-CH2CH ^ — or

(Please read the notes on the back before filling out this page) ιοο is 1 or 2; E10G is hydrogen, CVC8 alkyl, cyclohexyl, benzyl or R107-c〇-, R1Q8_0-C0- or (R1G9) ( Riig) n-C0- fluorenyl group; E, 1 () () is a group group of formula Rm0- or (R112) (Rii3) N-;

Ri〇3 is hydrogen, Ci-C6, C2-C7, oxymethyl ’phenoxymethyl or tolylmethyl,

Ri〇4 is hydrogen, Ci-Cs compound, 0 ·, -OH, -CH2CN, CV Ci8 compound, 'C5-C12 ring compound', C3-C6 alkyl, C7-C9 phenylalkyl, its Is unsubstituted or substituted with 1, 2 or 3 Cr-G alkyl groups on the phenyl group; or C ^ Cs fluorenyl, preferably hydrogen, Cr C4 alkyl, Q-Cs alkoxy Or cyclohexyloxy, especially hydrogen or methyl; R105 is hydrogen, CVCu alkyl, cyclohexyl, phenyl, benzyl, phenylethyl, or C8fluorenyl; 106 This paper is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 572952 A7 B7 V. Description of the invention (/ J) R112 is Q-Cu alkyl, allyl, cyclohexyl, phenyl, benzyl, c3-c12 Alkoxyalkyl, c4-c12 dialkylaminoalkyl 'group of formula (AA-1-I) or formula (AA-1-V); h3c CH, RwN-

CH factory CH2- h3c ch3 (AA-l-V)

Rin is a chloro 'C1-C12 radical, aiiyi' cyclohexyl or a group of formula (in); but it is limited to at least one of R101, Run, E1 () 〇 and E'1 () 〇 including the following formula Group base CH.

h3c ch3 and are limited to that each repeating unit in the formulae (AA-1-I) and (AA-1-II) may be the same or different. Ingredient (AA-2) is a compound of formula (AA-2-I)

^ 201 -C—CH 2 '^ 200 " (AA-2-I) (Please read the notes on the back before filling in this page) o = c 丨' 201 / '201 108 nnnnn δν innn ϋ n I ne ^ i i_i ϋ ϋ · ϋ I ϋ in n In n Hi nnnnn ϋ n This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 572952 A7 _ B7 _ V. Description of the invention ((4) of which n2G () And n2Q1 are unrelated to each other, a number from 1 to 50 R2 (H is hydrogen or C, C4 alkyl; X201 is -〇_ or > N-R2〇2: R202 is hydrogen, CVCu alkyl , Cyclohexyl, phenyl, benzyl, phenylethyl or CrCsfluorenyl; Y201 is Ci_C4 alkyl or a group of formula (AA-2-II);

(ΑΑ-2-Π) R203 is hydrogen, CVC8 alkyl, 0 ·, -OH, -CH2CN, C! -C18 alkoxy, C5-C12 cycloalkoxy, C3-C6 alkenyl, C7-C9 benzene Alkyl, which is unsubstituted or substituted with 1, 2 or 3 CVC4 alkyl groups on the phenyl group; or CrCs fluorenyl, preferably hydrogen, Cr C4 alkyl, alkoxy or cyclic Hexyloxy, especially hydrogen or methyl; Z20〇 is ethylene or a group of formula (AA-2-III) '| 204 -C—CH; (AA-2-III) (Please read the notes on the back first (Fill in this page again) o = c 202 202 109 ϋ · 1 H ϋ «ϋ ϋ nnnn ϋ n ϋ · 1 ϋ n I n ϋ —i ϋ · This paper size applies to China National Standard (CNS) A4 (210 X 297 (Mm) 572952 and-A7 B7 V. Description of the invention (M) R204 is hydrogen or C1-C4 academy; χ2〇2 has the same as χ2 (one of the definitions of ；; Y202 is a Ci8 academy or a formula (AA -2-II) group base; but its limitation is that the repeating unit in formula (AA-2-I) has a block or scattered distribution, and each of the repeating units in formula (AA-2-1) has Cover unit | 丨 '201

——C—CH ^ 〇 = C

I can be the same or different, and with the proviso that at least 2%, preferably at least 5%, the repeating unit in formula (AA-2-II) contains a group base of formula (AA-2-II). In the compound of the formula (AA-2-I), the terminal group is, for example, hydrogen or a group of the formula -CHNC ^ RmiVCO-X ^ -Yw. All the stabilizer mixtures described in the present invention can be used as light stabilizers for coatings, and it is preferable to use them in combination with a UV absorber. Suitable coatings are described in US-A-6, 117,997, column 26, lines 55 to 32, line 21. The following example illustrates the application of the second stabilizer mixture. All percentages and parts are by weight unless otherwise specified. Example A: Light Stability of Polypropylene Homopolymer 110 (Please read the precautions on the back before filling this page)

Order --------- Line J This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) 572952 A7 —_________ B7 V. Description of the invention (4) 1 0 0 unsubstituted Polypropylene powder (melt index: about 3.2 g / 10 minutes, measured at 230 ° C and 2160 g) neutralized 0.05 parts of pentaerythritol-tetra {3- (3,5-di- Tert-butylhydroxy) propionate}, 0.05 parts of tri {2,4-di-tert-butylphenyl} phosphite, 0.1 part of calcium stearate, 0.25 part of titanium dioxide (Anatase ) And the stabilizer mixtures shown in Tables 3a and 3b, homogenized for 10 minutes at 200 ° C. The resulting material was compressed between two aluminum foils in a laboratory-grade compactor at a temperature of 26 ° C 6 minutes, a 0.5 mm thick film was prepared, followed by cooling to room temperature in a water-cooled press, the sample was cut into a size of 60 mm X 25 mm, and a WEATHER-OMETER Ci 65 (blackboard temperature 6 3 ± 2 ° C) Exposure without watering during the period). Periodically remove the sample from the exposure unit and measure its carbonyl content with an infrared spectrometer. The exposure time required to form a carbonyl absorption of 0.1 is a measure of the efficiency of the stabilizer mixture and the results are shown in Tables 3a and 3b. Table 3a: Time required for stabilizer mixture to absorb 0.1 carbonyl group (hours) 0.05% (AA-1--1--1-A) and 0.05% TINUVIN 770 (RTM) 1585 0.05% (AA-1-II- 2-A) and 0.05% TINyVIN 770 (RTM) 2485 111 This paper size applies to China National Standard (CNS) A4 (210 χ 297 mm) (Please read the precautions on the back before filling this page)-ϋ «Ϋ ϋ I ί ϋ n 一 (eJa n 1 ϋ ϋ emmmw IB ^ i ϋ ϋ n I ϋ nn 1_1 n« ϋ ϋ · ϋ · ϋ I ϋ 1 II ϋ ϋ a ^ i · 572952 A7 B7 V. Invention Explanation (/ 4) 0.05% of (AA-1-II-3-A) and 2415 0.05% of ΉΝυνίΝ 770 (RTM) 0.05% of (AΑ-1-ΙΙ-4-Α) and 2100 0.05% of ΉΝυνίΝ 770 (RTM) 0.05% (ΑΑ-1-ΙΙ-5-Α) and 1895 0.05% TINUVIN 770 (RTM) Table 3b: Stabilizer mixture time (hours) until 0.1 carbonyl absorption (hours) 0.05% (ΑΑ-2 -I-3-Α) and 0.05% TINUVIN 770 (RTM) 2125 stabilizers used:

H, C CH

(Please read the notes on the back before filling this page)---I ---- Order-------- L ·

〇 0 II II 〇 a c one (ch2) factory c—〇

(= ΑΑ-1-Π-2-Α) 112 This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 x 297 mm) 572952 A7 B7 V. Description of the invention (// 〇 h3c ch3

H3C ch3

〇II

〇II HX CH, H—N) —〇—C— (CH2) “C—〇

c- ch2ch2- (= AA-1-II-3-A)

O—C—CH = CH—C—0

〇II

〇II

c- -CH 二 CH- (Please read the notes on the back before filling this page) (= ΑΑ-1-Π-4-Α) HX CH.

'3

〇II o-c 〇II c—o

------- Order ί n I 1_1 ϋ I— 1_1 I _ ——CH—CH2-I 2 o = c I 〇

——CH—CH2-0 = C I 〇

n201 (= AA-2-I-3-A) 113 This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) 572952 A7 _B7_ V. Description of the invention (丨 (丨) where n2〇〇 The sum of Π201 is a number from 2 to 20 H3C CH, Η—Ν h3c ch3 〇II II C — (CH2) 8—c—ο

(= TINUVIN 770 (RTM)) (Please read the notes on the back before filling out this page) # 114 ^ OJ · · ϋ ϋ ϋ ϋ I n I ϋ ϋ I ϋ nnnnn ϋ ϋ nn ϋ ϋ ϋ ϋ nnnn ϋ · This paper size applies to China National Standard (CNS) A4 (210 x 297 mm)

Claims (1)

572952 098859 ABCD patent application scope (B-9-b), (B-9-c) or (B-10-a) compounds; H3C -CH, E: -N y · -N λ ⅡII-〇-C — (C15-C17alkyl) H3C ch3 O 0 II II 〇——C— (CH2) g—C——0 (B-l-b) H o II c- 〇 Hc — c. (Please read the notes on the back before copying this page) ό CH —Ic = 〇I o o H2 = c-c-o -d 1 丄 (B- ch3h3c, CH3 HQC ’ E where E! Is hydrogen, CVC4 alkyl, CrCio alkoxy, cyclohexyloxy, allyl, benzyl or ethenyl; 'This paper size applies to China National Standard (CNS) A4 (210 X 297 (Mm) 572952 A8 B8 C8 D8 (B-3-b) (Please read the notes on the back before filling out this page) Where EI2 has one of the meanings; ί • 16 (B-5) Line 1 where E16 has one of the definitions of E! (B-6-a) Where E18 has one of the definitions of E! This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 572952 A8 B8 C8 D8 Patent scope h3co CH =: C (B-8-a) where E23 has one of the meanings; h3c ch3 ^ H3C chy_ ^ ° ° y! VCH3 E2—NN—CH2CH—N; λN—Eλ '(B-9-b) (please first Read the notes on the reverse side and rewrite this page) h3c ch3 h3c ChU —NN— 〇v H3Cv CH, * ι'έ] Λ N——CH2CH ^ —N N——CH, CHr 7 < .n_ " e25 (B-9-c) N ^ N h3c CH3 Pv H3CV ch, N_CHXHr 7 <, N-E25 h3c ch3 where E25 has one of the meanings of EiS; 〇 〇 (B-10-a) Where E29 has one of the definitions of Ei: 4 This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 572952 A8 B8 C8 D8, the scope of the patent application (C ) Is of the formula (C small a), (C-1-b), (C small c), (C-1-d) '(C-2-a)' (C-3-a) '(C- 4-a) '(C-4-b)' or (C-5-a) compounds (please read the notes on the back before filling this page) or a product (C-6-a); (C-1-a) (C-1-b) (C-1-c) (C-1-d) This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) 572952 A8 B8 C8 D8, where the scope of patent application is b! Is from 2 to The number of 20, and R6 is hydrogen, CVC4, CVQo alkoxy, cyclohexyloxy, allyl, benzyl, or ethenyl (CH2h (Please read the precautions on the back before copying this page) (C-2-a) where R13 has one of the definitions of R6, CH, -Si——〇 Ι ch2) 3 〇 (C-3 -a), CH, H3C, h3c n ch3 ”b2 where b2 is a number from 2 to 20, and R16 has one of the definitions as shown in the above figure; this paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 572952 ο-one ο Plant A8 B8 C8 D8 patent application scope Where b3 is a number from 1 to 20, and R18 has one of the definitions of R6; b4 (C-5-a) where b4 is a number from 1 to 20, and R3. It has one of the definitions of R6; a product (C-6-a), which can be obtained by the reaction of a polyamine of the formula (C-6-la) and cyanuric chloride and a product of the formula (C-6-2- a) Prepared by compound reaction (please read the precautions on the back before writing this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 572952 098895 ABCD patent application scope H2N —— (CH2) —NH —— (CH2) -— NH —— (CH2) —NH2 (C -6-la) H—N-C4Hg (C-6-2-a) CH, R k32 which has one of the definitions of R6 2 · The stabilizer mixture as described in the scope of patent application item 1, wherein E1, E12, E16, E18, e23, e25, e29, r6, r13, r16, R18, R30 and R32 are hydrogen or methyl, and EdD R6 is additionally a CrCs alkoxy group. 3. The stabilizer mixture according to item 1 of the scope of patent application, wherein component (A) is a compound of formula (A-.la), wherein a number from 2 to 20, or a formula (A-2-a) or ( A-2-b) compounds, where n2 and n2 * are numbers from 2 to 20, component (B) is a compound of formula (B-1_b), where E! Is hydrogen, and component (C) is -1-a) Compound 'wherein bi is a number from 2 to 20 and R6 is chlorine, or a compound of formula (C-1-b) wherein r6 is hydrogen or propoxy. And bi is a A number from 2 to 20, or a compound of formula (C-1-d), wherein R6 is hydrogen or methyl, and bi is a number from 2 to 20, or a compound of formula (C-2-a), wherein R13 is Methyl, or formula (C-3-a) (Please read the precautions on the back before filling out this page)% This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 572952 A8 B8 s 6 Scope of patent application (please read the notes on the back before writing this page) Compounds, where Ri6 is hydrogen and b2 is a number from 2 to 20, or a compound of formula (C-4-a), where Ris is Hydrogen, and b3 is a number from 1 to 20, or a product (C-6-a)4. The stabilizer mixture according to item 1 of the scope of patent application, wherein component (A) is a compound of formula (A-1-a), where & is a number from 2 to 20, or formula (A-2-a ) Or (A-2-b) compounds, where n2 and n2 * are a number from 2 to 20, and component (B) is a compound of formula (B-1-by, where E! Is hydrogen, and component (C) Is a compound of formula (C-1-a), where b! Is a number from 2 to 20, and R6 is hydrogen. 5. The stabilizer mixture of item 1 in the scope of patent application, wherein component (A) is of formula ( A-1-a) compound, component (B) is a compound of formula (B-1-b), wherein E1 is hydrogen, and component (C) is a compound of formula (C-1-a), wherein R6 is hydrogen; or The linear component (A) is a compound of formula (A_1-a), the component (B) is a compound of formula (B-1_b), where E! Is octyloxy, and component (C) is a compound of formula (C-1-a) Where R6 is hydrogen; or component (A) is a compound of formula (A-1-a), component (B) is a compound of formula (B-3-a), where E12 is hydrogen, and component (C) is of formula ( C-1-a) compounds in which R6 is hydrogen; or component (A) is a compound of formula (A-1-a) and component (B) is a compound of formula (B-10-a), where E29 is And component (C) is a compound of formula (C-1-a), wherein R6 is hydrogen; or component (A) is a compound of formula (A-1-a), component (B) is of formula (B-1-b ) The paper size of this paper applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) A8B8C8D8, 572952 6. The scope of patent application, where Ei is methyl, and the component (C) is of formula ) Compounds, in which Rl3 is methyl. (Please read the notes on the back before writing this page) 6 · — a kind of composition, including a pair of synthetic polymers that are sensitive to light, thermal or oxidative degradation, and as applied The stabilizer mixture of item 1 of the patent, wherein each of the components (A), (B) and (C) is present in an amount of 0.005 to 5% (calculated relative to the weight of the synthetic polymer). The composition according to item 6, wherein the synthetic polymer is a polyolefin. 8 · The composition according to item 6 of the patent application, wherein the synthetic polymer is polyethylene, polypropylene, polyethylene copolymer or polypropylene copolymer 9 · A method for stabilizing a synthetic polymer against degradation caused by light, heat or oxidation, including the synthetic polymer Add the stabilizer mixture as described in the scope of patent application item 1, wherein each of the components (A), (B) and (C) is present in an amount of 0.005 to 5% (relative to the weight of the synthetic polymer). A stabilizer mixture, including '(1) Compound 10 of the following formula: The paper size applies to the Chinese National Standard (CNS) A4 (210 X 297 mm) 572952 A8B8C8D8 6. Scope of patent application h3c ch. H3C CH3 〇II 〇II H3c ch3 h3c ch3 C Η-N > -〇-C —— (CH2) 2-C-O- (N- (CH2) -O H.C CK 〇II II H3c ch3 c- O-C— (CH2) —C—0-, ^^ 1— (CH2) —ο h3c ch3 -CHoCH, h3c ch H, C CH 〇II 〇II Η—N -C-CH = CH-C-0 h3c ch3 N- (CH2) -0 h3c ch3 C- -CH two CH- H3C ο 3 Η C ο I OMNC 11 (Please read the notes on the back before copying this page) This paper size applies to China National Standard (CNS) A4 specification (210 x 297 mm) 572952 6. Scope of patent application A8B8C8D8 ——CH—CHj 0 = C 201 η where the sum of n2G () and n2G1 is a number from 2 to 20, and (Please read the notes on the back before writing this page) (2) —Compound of the formula 式 —ΝΝΝλ) ~ ° · 〇II h3c ch3 The weight ratio of ingredient (1) to ingredient (.2) is from 10: 1 to 1: 100. 11. A composition comprising a pair of synthetic polymers that are sensitive to light, heat or oxidative degradation, and a stabilizer mixture as described in item 10 of the patent application, wherein each of the ingredients (1) and (2) is present 0.005 to 5% (calculated relative to the weight of the synthetic polymer). 12. · A method for stabilizing a synthetic polymer against degradation caused by light, heat, or oxidation, comprising adding to the synthetic polymer a stabilizer mixture as in item 10 of the patent application, wherein components (1) and (2) There are 12 paper sizes for each of the paper standards applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 098895 ABCD 572952 6. The amount of patent application range is 0.005 to 5% (relative to the weight of the synthetic polymer) . (Please read the precautions on the back before filling this page) This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 572952 A7 B7 V. Description of the invention () " -------- 5- 一 叔-Butyl-4-mercaptophenyl) propionate, 0.1 part of stearic acid bromide, 0.25 part of titanium dioxide (Anatase) and the stabilizer mixture shown in Table 2, homogenized at 180 ° C. 1 〇minutes, the obtained material was compressed between two aluminum foils of a laboratory-grade compactor at a temperature of 210 ° C for 6 minutes to produce a film with a thickness of 0.5 mm, followed by a water-cooled compactor. After cooling to room temperature, the sample was cut into a size of 60 mm X 25 mm and exposed to a WEATHER-OMETER Ci 65 (blackboard temperature 6 3 ± 2 ° C) without watering. Periodically remove the sample from the exposure unit and measure its carbonyl content with an infrared spectrometer. The exposure time required to form a carbonyl absorption of 0.1 is a measure of the efficiency of a stabilizer mixture. The results are shown in Table 2. Table 2 :: Stabilizer mixture time to 0.1 carbonyl absorption (hours) Control group 465 0.20% of TINUVIN 791 (RTM) (= previous technique) 3 175 0.10% mixture (A-2) + 4 815 0.05% CHIMASSORB 944 (RTM) + 0.05% TINUVIN 770 (RTM) Mill polypropylene homopolymer film is light stable. 100 parts of unsubstituted polypropylene powder (melt index: about 2.4 g / 10 minutes, measured at 230 ° c and 2160 g) 95 in a Brabender plasticity meter This paper standard applies to China National Standard (CNS) A4 (210 X 297 mm) (Please read the notes on the back before filling this page) 572952 A7 B7 V. Description of the invention () CHIMASSORB 944 (RTM) + compound (B-6-al) 4230 5125 CHIMASSORB 944 (RTM) + compound (B-10-al) 3745 4730 CHIMASSORB 944 (RTM) + SANDUVOR 3050 ( (RTM) 2695 3280 CHIMASSORB 944 (RTM) + SANDUVOR PR-31 (RTM) 2835 4070 *) The total concentration of light stabilizer is 0.2%. Table 4D: Light stabilizer system T (U (hour) The amount of each light stabilizer used is 0.1% *). T (U (hour) light stabilizer system, combined with the mixture (A-2) each light The amount of stabilizer in the stabilizer system is 0.075%, and the amount of the mixture (A-2) is 0.05% *) · No 315-CHIMASSORB 944 (RTM) + 3775 4715 TINUVIN 765 (RTM) CHIMASSORB 944 (RTM) + 2835 3350 SANDUVOR PR-31 (RTM) * The total concentration of light stabilizer is 0.2%. ------------- i I (Please read the notes on the back before filling this page) i-line-Another embodiment of the present invention is a second stabilizer mixture, which contains (1) A component (AA-1) or (AA-2) as defined below, and 102 paper sizes are applicable to China National Standard (CNS) A4 (210 X 297 mm) 572952 A7 B7 92. 2. 3 V. Description of the invention (R106 is c2-c12 alkylene, c4-c8 alkenyl or xylyl; R107 is q-Cu alkyl, c2-c5 alkenyl, c5-c8 cycloalkyl, phenyl, 〇7-012phenylalkane Base or a group base of the formula (AA-1-III). (AA-1-III) Rl08 is Ci_Ci2 alkyl radical 'dilute propyl' cyclohexyl or phenyl; Rl09 is nitrogen 'Ci-Cg alkyl radical' palyl 'cyclohexyl' phenyl or c7-c1Q alkylphenyl , Rno is CVC8 alkyl, allyl, cyclohexyl, phenyl or C7-C10 alkyl phenyl; or R109 and Rho together form a 5-membered to 7 with the N atom to which they are bonded -Membered heterocyclic ring; Rill is a C1-C12 alkyl group, C3-C5 alkyl group, C5-C8 ring alkyl group, phenyl group, C7-C1Q alkyl group, C7-C12 phenyl group group, C3-C12 Cioxyalkyl, a group of-(CH2CH20) ml-0-CH3 group, a group of formula (AA-1-III) or a group of (AA-1-IV) group; (AA-1-IV) 107 This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page)-Install i-line · 8 572952-this report A8 B8 C8 D8 Correction too S2> 2. X Patent application scope 1. A stabilizer mixture including ingredients (A), (B) and (C), wherein the weight ratio of ingredients (A) :( B) is 10: 1 to 1: 100, and ingredient (A): (C) The weight ratio is from 10: 1 to 1: 100, wherein the component (A) is of the formula (A-1-a), (A-2-a), (A-2-b), (A-3 -a) or (A-4-a) compound; N-CH; -CH; -OOC-CH0CH: -CO- n1 where n! is a number from 2 to 20; (A-1-a) (please (Read the notes on the back before filling out this page) (A-2-a) 11 〇_ (A-2-b) where n2 and n2 * are a number from 2 to 20; component (B) is a formula (B-1-a), (B-1-b), (B-1- c) (B-1-d), (B-3-a), (B-3-b), (B-5), (B-6-a), (B-8-a) Paper size Applicable to China National Standard (CNS) A4 (210 X 297 mm)