TW491871B - Block oligomers containing l-hydrocarbyloxy-2,2,6,6-tetramethyl-4- piperidyl groups as stabilizers for lower polyolefin - Google Patents

Abstract

A product obtainable by (1) reacting a compound of the formula (Α) with a compound of the formula (β) in a molar ratio of 1.2:1 to 1.4:1; (2) reacting the end groups of the formula (γ) being present in the product of the reaction (1) with e.g. dibutylamine in a molar ratio of 2:1.7 to 2:3; the reactions (1) and (2) being carried out in an organic solvent in the presence of an inorganic base; and (3) transferring the groups of the formula being present in the product of the reaction (2) to groups of the formula, said transfer being carried out by reacting the product of the reaction (2) with a hydroperoxide in a hydrocarbon solvent in the presence of a peroxide decomposing catalyst; R1 is in particular a hydrocarbyl radical, B is e.g. N-(2,2,6,6-tetramethyl-4-piperidyl)-butylamino, R is e.g. 2,2,6,6-tetramethyl-4-piperidyl and R2 is e.g. hexamethylene. The products obtained are useful as light stabilizers, heat stabilizers and oxidation stabilizers for organic materials, in particular synthetic polymers such as polyolefins.

Description

491871 A7 B7 V. Description of the invention (f) The present invention is directed to a specific block oligomer containing 1-hydrocarbonoxy-2,2,6.6-tetramethyl-4-piperidinyl, and Applications as light stabilizers, thermal stabilizers and oxidation stabilizers for organic substances, especially synthetic polymers, and · Regarding organic substances for this purpose. In addition, the present invention is further limited to an intermediate product. The stability of synthetic polymers M2,2,6,6-tetramethylpiperidine derivatives has been disclosed in, for example, US-A-4,086,204, US-A-4,331,586; US-A-4 , 335, 242; US-A-4 * 234 * 707; US-A-4, 459, 395; US-A — 4,492,791; US-A-5, 204, 473; EP-A-53 , 77 5; EP-A-357, 223; EP-A-377, 3 24; EP-A-462.069; EP-A-782, 994; and GB-A-2, 301, 106. The present invention is particularly derived from a product obtained from ... 1) a compound of formula (α) (please read the precautions on the back before filling this page)

, 1T §Γ. Printed by the Central Bureau of Standards and the Ministry of Industry and Consumer Cooperatives

CI /

CI

N should be anti-physical compound \ — / / IV type 1 and this paper size applies Chinese national standard (rNS) Λ4 specification (210X 297 mm) 491871 A7 B7 V. Description of invention (V)-N——R I Η

5 is 2 Don't special, If) Ground 1 1 ··: Compared with 43, ♦ 3 1 1 ♦: To, 1 4 1 Such as •: Example 13, to · 1 11:: or 6 2, 3 • 1. 1: 1 is 4 to Example · 1 to 1 · Ear to 3 Mo 1 · (: 1 should be reversed from the existence of \ 1/2 base end \ — / 7 / f \ (Read the notes on the back and fill out this page)

N

N 7

CI

N-巳 物 合 化) I δ A / IN formula and the Central Standards Bureau of the Ministry of Economic Affairs, Bureau of Industrial and Military Consumer Cooperatives, Yin Lai Jia Xing}, 4 * Under: 3 • In the base: 2 Storage group 2: Alkali} } To 2 machines ~ I δ 7 to no I ί · 2 and G 1: middle ί: 2 agent type} is the end-of-line unique end product of the soluble base machine, one product ί 6 in} 2 · yes 2 is 2} Example: 2 inverse ratio 2 and Yu Erzhi} in Mo 2 1 deposit should: inverse 2 should be reversed} {地;; 3 8 This paper size applies the Chinese National Standard (CNS) Λ4 specification (210X 297 mm) 491871 A7 B7

jlL V. Description of the invention (Λ V,: drop: Ϊ.

Ui

(G- 丨) into group base of formula (G — I I)

(Please read the notes on the back before filling in this page) (G-Π) The conversion is made by reaction 2) Tritium and hydrogen peroxide, in a hydrocarbon solvent and in the presence of a hydrogen peroxide decomposition catalyst get on;

Ri is a hydrocarbyl reactive group or a 0—Rt is an oxy group; R2 is a C2—alkylene, C4—Ci2 alkylene, C5—C7 cycloalkylene, C5—C7 cycloalkylene di (Ci—C4 alkylene), Ci —C4 alkylene di (C5-C7 cycloalkylene), phenylene di (Ci · C4 alkylene) or C4—Ci 2 alkylene, which is composed of 1, 4 monopyrazinediyl, 1◦one or> ; N — Xi interrupted, Xi is Ci-Ci 2 rattan or (Ci-Ci 2 alkoxy) several groups, or has one of the following definitions of R4; or R2 is a formula (I a a), (I-b) or (I-c) group basis: This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 491871 A7 B7 V. Description of the invention (+

(l-a) • CH ^ —CH—CH «I 2〇 Ic = 〇 I X2 (l-b)

(lc) m is 2 or X2 is Ci-Ci8 alkyl, Cs-Ci2 is substituted or substituted by 1, 2 or 3 Ci-C4 alkyl; phenylphenyl is substituted by 1, 2 or 3 Ci — C-C 9 phenylalkyl 3 cycloalkyl, which is unsubstituted * which is unsubstituted or substituted in alkyl or Ci-C4 alkoxy; C which is unsubstituted, or in phenyl It is substituted by 1 · 2 or 3 Ci—C alkyl groups; and 4 (Please read the notes on the back before filling out this page) Printed by the Central Standards Bureau, Cargo Workers and Consumers Cooperatives 2 RC R is divided into R, N, I, I, 3 3 RX ο: Radical I Radical should be group anti-A

Η

C This paper size applies to China's national standard ((, NS) Λ4 specifications (210X 297 mm)

C-butane-2 or \) // (\ 491871 A7 B7 R 3,; R4 and R5 (same or different) are Ci-CiS alkyl »C5 — Ci 2 cycloalkyl * which is unsubstituted Or substituted by 1, 2, or 3 Ci—C4 alkyl groups; C3-Cl8 alkenyl, phenyl, which are unsubstituted or substituted by 1, 2, or 3 Ci—C4 alkyl groups or Ci_C4 alkoxy groups -C7-C9phenylalkyl, which is unsubstituted or substituted with 1, 2 or 3 Ci-10 alkyl on phenyl; hydrofuryl or C2-C4 alkyl * It is substituted at the 2, 3, or 4 position by mono-OH, Ci-C8 alkoxy, di (Ci-104 alkyl) or a group of formula (III); substitution for tetra is an amine (III). Ministry of Central Standards Bureau MX, printed by cooperatives Y is a 0 —, a CH2 —, a CH2 ch2 — or> N-C Η 3 •, and R3 is also hydrogen or a N (R4) (Rs) In addition, it is a group group of formula (III); X is a 0 — or> N — R6 ;, Rs is Ci — Ci8 fluorenyl, C3 — C18 dilute, Cs — Ci 2 cycloalkyl, which is unsubstituted Or substituted by 1, 2 or 3 Ci-C4 alkyl; C7-C9 phenylalkyl, which is unsubstituted -U- This paper uses the Chinese national standard date (rNS) Λ4 size (210X297 mm) (Please read the precautions on the back before filling this page)

^ 1871 A7 B7 Description of the Invention (b) (Please read the notes on the back before filling this page) or substituted with 1, 2, or 3 Ci-C4 alkyl groups on the phenyl group; tetrahydrofuran, a formula (G — I ), Or a Cz-C4 alkyl group, which is substituted at the 2, 3, or 4 position by a 10H, Ci alkoxy group, a di (Ci_C4 alkyl) amino group, or a group group of formula (III) of

I R has one of the definitions of Re above and B has one of the definitions of A above. The conversion from formula (G — I) to formula (G — I I) can be similar to that described in US — A — 4,921,962, which is incorporated herein by reference.

The definition of Ri is based on the hydrocarbon solvent used in reaction 3). Ri is preferably a hydrocarbon group having 5 to 18 carbon atoms. The central standard of the Ministry of Economic Affairs is printed for another second consumer cooperative ^

Ri is especially Cs — Ci 8 alkyl, C5 — Ci 8 alkenyl, C5 — Ci 8 alkynyl, Cs — Ci 2 cycloalkyl, which are unsubstituted or substituted by Ct — C4 alkyl; Cs — Ci 2-cycloalkenyl, which is unsubstituted or substituted by Ci-C4 alkyl; a bicyclic or tricyclic hydrocarbon group having 6 to 10 carbon atoms, or C7-C9 phenylalkyl, which is unsubstituted Substituted or substituted by C i -C4 alkyl on phenyl; and the hydrocarbon solvents in reaction 3) are based on Ri (C 5 ~ C 1 8 alkyl, C5-CiS alkenyl, C5-Ci8 alkyne —C i 2 cycloalkyl, which is unsubstituted or substituted with Ci-C4 alkyl; C5 —Ci 2 cycloalkenyl, which is unsubstituted or substituted with Ci-C4 alkyl; A bicyclic or tricyclic hydrocarbon group with 6 to 10 涸 carbon atoms -12- This paper is based on the Chinese National Standard (CNS) Λ4 size (210X 297 mm) Central Standard Jujube Bureau of the Ministry of Economic Affairs 491871 A7 B7 V. Description of the invention (7), or c7-c9 phenylalkyl "is unsubstituted or substituted by C i-; C 4 alkyl on phenyl). According to another preferred embodiment of the present invention, R i is heptyl, octyl, cyclohexyl, methylcyclohexyl, cyclooctyl, cyclohexenyl * α -methylbenzyl or 1,2,3,4 Tetrahydrocycloalkyl, and the hydrocarbon solvent in reaction 3) is (according to Ri) heptane, octane, cyclohexane, methylcyclohexane, cyclooctane, cyclohexene, ethylbenzene or Tetralin. According to a preferred embodiment, Ri is octyl or cyclohexyl * and the hydrocarbon solvent of reaction 3) (according to Ri) is octane or cyclohexane. Examples of alkyl groups containing not more than 18 carbon atoms are methyl, ethyl, propyl * isopropyl, butyl, 2-butyl, isobutyl, pentyl, 2-pentyl, hexyl, heptyl , Octyl, 2-ethylhexyl, tert-octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, hexadecyl and octadecyl . Ri is preferably C6-Ci 2 alkyl, especially heptyl or octyl. R4, Rs and Re are preferably Ci-C8 alkyl, especially Ci-C * alkyl. An example of an alkyl group substituted by -0H is 2-hydroxyethyl. Via Ci-10 alkoxy, preferably C2-C4 substituted by Ci-C4 alkoxy, especially methoxy or ethoxy (example of alkyl 2-methoxyethyl, 2-ethyl Oxyethyl, 3-methoxypropyl, 3-ethoxypropyl, 3-butoxypropyl, 3-octyloxypropyl, and 4-monomethoxybutyl. -13- This paper Standards in China ("NS" Λ4 size (210X 297 mm)) (Please read the notes on the back before filling out this page.) 491871 A7 B7 V. Description of the invention (2) Via a bis (Ci-C4 alkyl) amino group, preferably a dimethylamino group or :; an example of a C2-C4 alkyl group substituted with an ethylamino group is 2-di Methylaminoethyl, 2-ethylaminoethyl, 3-dimethylaminopropyl, 3-diethylaminopropyl, 3-dibutylaminopropyl and 4-diethyl Amino group butyl. / ^ \ The group of formula (III) is preferably a N OO \ ^ / A preferred example of a c2-c4 alkyl group substituted by a group of formula (III) is 0- (ch2) —. The group base of the following formula is particularly good / ^ \ ^-(CH2 > 2 — Ο Examples of C5 —Ci 2 cycloalkyl groups which are unsubstituted or substituted via 1, 2 or 3 Ci —C4 alkyl groups are cyclopentyl, methylcyclopentyl, dimethylcyclopentyl, cyclohexyl, Methylcyclohexyl, dimethylcyclohexyl, trimethylcyclohexyl, tert-butylcyclohexyl, cyclooctyl, cyclodecyl and cycloundecyl. Unsubstituted or substituted cyclohexyl are -14- ~ This paper uses China National Standards (CNS) Λ4 specifications (210X297 mm) (please read the precautions on the back before filling this page), and 11 will be awarded by the Ministry of Standards and Technology. Printed by the Consumer Cooperative 491871 A7 B7 _ V. Description of the Invention (q) A preferred example of a bicyclic or tricyclic hydrocarbon group having 6 to 10 carbon atoms is 1, 2, 3, 4 tetrahydrocycloalkyl. A preferred example of a C5 -Ci 2 cycloalkenyl substituted or substituted by Ci -C4 alkyl is cyclohexenyl. Examples containing no more than 18 carbon atoms are allyl, 2-methylallyl Alkenyl, butenyl, hexenyl * undecenyl and octadecenyl. Among them, alkenyl having a saturated carbon atom at the first position is preferred, and allyl is particularly preferred. Examples of alkynyl are pentynyl or octynyl. Examples of phenyl substituted with 1, 2 or 3 Ci-C4 alkyl or Ci-C4 alkoxy are methylphenyl, dimethylphenyl * Trimethylphenyl, tert-butylphenyl, di-tert-butylphenyl, 3,5-di-tert-butyl-4 4-methylphenyl, methoxyphenyl, ethoxybenzene And butoxyphenyl. Examples of C7-C9phenylalkyl which are unsubstituted or substituted with 1, 2 or 3 Ci-C4 alkyl groups are benzyl, methylbenzyl, di Methylbenzyl, trimethylbenzyl, tert-butylbenzyl, and 2-benzylethyl. Benzyl is preferred. Examples of fluorenyl groups (fatty, cycloaliphatic or aromatic fluorene) containing not more than 12 carbon atoms are methyl, ethyl, propyl, butyl, butyl, pentyl, hexyl, heptyl , Octyl and benzamyl. (:! A (: 8 alkylfluorenyl and benzamidine groups are preferred, ethenyl is particularly preferred. An example of a (Ci 2 alkoxy) carbonyl group is methoxycarbonyl, -15- this paper size Applicable ^ Chinese national standard binding ((: ^) 8 4 specifications (21 (^ 297)) (Please read the precautions on the back before filling this page)

, 1T 491871 A7 B7 V. Description of the invention () Ethoxycarbonyl, propoxycarbonyl * Butoxycarbonyl • pentoxycarbonyl, hexyloxycanyl, heptyloxycarbonyl, octyloxycarbonyl'nonoxy Carbonyl * decyloxycarbonyl, undecyloxycarbonyl and dodecyloxycarbonyl. Examples of alkylenes containing not more than 12 carbon atoms are ethylene, propylene, trimethyl, tetramethyl, pentamethyl, hexamethyl, octadecane, tenmethyl and twelve methyl. Examples of R2 are C2-C8 alkylene or C4-Cs alkylene, and especially C2-c6 alkylene 'is preferably hexamethylene. An example of C4-C: 2 olefin is 3-hexene. An example of Cs-C7 cycloalkylene is cyclohexylene. Example of C4 alkylene interrupted by 1,4-piperazinediyl --- · ------ 0 II (Please read the precautions on the back before filling this page) as --N N-CH2CH2

， 1T or -CH2CH2CH2— NN ——CH2CH2CH2- Printed by the Ministry of Substandard Standards Bureau M Industrial Consumption Cooperatives 1—- interrupted by a 0—such as 1, 2 or 3—0—Ci 2 alkylene Examples are 3-oxapentane-1'5-diyl, 4-oxaheptane-1,7-diyl, 3,6-oxaoctane-1,8-diyl, 4, 7- Dioxadecane-1, 110-diyl, 4, 9-1-6-The paper size is suitable for China National Standards (CNS) Λ4 specification (210X 297 mm)

i 'Description of the Invention u) Dioxadodecane-1,12-diyl, 3,6,9-trioxadeca ~? -1,1 1-diyl and 4,7,10-trioxy Examples of heterotridecane-1,1 3 -diyl0 interrupted by > N — Xi C4 -Ci 2 alkylene are: ^ C Η 2 C Η 2 C Η 2 -N (X 1)-C Η 2 C Η ζ-Ν (X ι)-CHz CH2 CH2 —, especially ~ CHz C Η 2 C Η 2-Ν (C Η 3)-CH2 C Η 2-N (CH3)-CH2CH2CH2-0

An example of Cs—C7 cycloalkylene di (Ci—C * alkylene) is cyclohexyl dimethylene. (Please read the notes on the back before filling this page)

C supports two rings, two supports, and 4 iso-C and I supports one, two rings, and two supports.

A is a sub-example of V) / alkylene ring 7 C-order (θ. Di {

C

Compounds in alkylene 4 C R ο) I, I, I, G, and Benzene as an example are better.} Compared with the basic group printed by the Central Standards Bureau of the Ministry of Economic Affairs τ-Consumer Cooperative

The 2 best C for property I is 2 R

C: alkylene

C

C alkylene ring 7 C

C-supported alkane bicyclo-supported 7-alkane C-ring I 7 5 c C

C

X

C Ν I > 1 or C I (ο or 1 group is from 醯 is 2 its 1, C 1 | alkane 1 2 C 1 is

C X 4 di-C-alkylene or alkane} 4-alkylene C-alkane

C 2 radical 'carbonyl's oxygen radical in the radical group is 2 R or 1 in the definition of 4 R as described in the above, or} This paper size applies Chinese National Standard Date (CNS) Λ4 specification (210X297) (%) Printed by the Intermediate Standards Bureau of the Ministry of Economic Affairs and printed by Hezhu News Agency 491871 A7 B7 V. Description of the invention () R 3, R 4 and R 5 (same or different) are (:! Ci 8 alkyl, (: 5 — Ci 2 cycloalkyl, which is unsubstituted or substituted via 1 * 2 or 3 Ci-c4 alkyl; phenyl * which is unsubstituted or via 1, 2 or 3 Ci-C4 alkyl Or Ci-C4 alkoxy substituted; C7-C9 phenylalkyl, which is unsubstituted or substituted on the phenyl with 1, 2, or 3 Ci-C4 alkyl; and R3 is additionally hydrogen Or one N (R4) (Rs) is another group group of formula (III); R6 is (: 1-Ci 8 alkyl group, C5—Ci 2 cycloalkyl group which is unsubstituted, or consists of 1, 2 Or 3 Ci-C4 alkyl substituted;

C7-C9 phenylalkyl, which is unsubstituted * or substituted with 1, 2, or 3 Ci-C4 alkyl groups on the phenyl group; or a group group of the formula (G-I). Also preferred products are among them: R2 is C2-C10 alkylene, cyclohexyl, cyclohexylene (Ci-C4) alkylene), Ci-C4 alkylene dicyclohexylene or phenylene (Ci- C 4 alkylene); R 3, R 4 and Rs (same or different) are Ci-Ciz alkyl, C 5-C 7 cycloalkyl, which are unsubstituted or consist of 1 * 2 or 3 C i -C 4 alkyl substituted; phenyl, which is unsubstituted or substituted by 1, 2 or 3 Ci-C 4 alkyl; benzyl · which is unsubstituted or benzene Ci-C4 alkyl substituted on the base; or N (R 4) (Rs) is additionally a group base of formula (III); and -1 8-this paper is suitable for China National Standard (CNS> Λ4 specification) (2 丨 0X 297mm) —— " ------ ·! (Please read the notes on the back before filling in this page) Order 491871 A7 _B7__ 5. Description of the invention (4) R 6 is Ci-Ci2 Alkyl, C5-C7 cycloalkyl, which is unsubstituted, or substituted by 1, 2 or 3 Ci-C4 alkyls; benzyl, which is unsubstituted, or by 1, 2 Or 3 Ci-C4 alkyl substituted; or a group group of the formula (G-I). The products are: R2 is C2-C8 alkylene; R3, R4 and Rs (same or different) are Ci-C8 alkyl · cyclohexyl * which is unsubstituted or substituted by methyl; stupid Is unsubstituted or substituted by methyl; benzyl or -N (R4) (Rs) is additionally 4-morpholinyl; and R6 is (: 1-C3 alkyl, cyclohexyl, It is unsubstituted or substituted by methyl; benzyl or a group of formula (G-I). Particularly preferred products are:

Ri is octyl or cyclohexyl, and the hydrocarbon solvent in reaction 3) is (depending on Ri) octane or cyclohexane;

Rz is Cz — C6 burner; the debt is owed by the Consumer Cooperative of the Central Procurement Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling this page) A is a group of N (R4) (Rs) or formula (II) R4 and R5 (same or different) are Ci-Cs alkane groups; or one N (R4) (R5) is another 4-morpholine 'group; X is > N-R s;

Re is Ci-Cs alkyl; and B has one of the definitions of A. __ -19- This paper size is applicable to Chinese storehouse standard cicada ((: milk) 8 4 size (210/297 mm) 1 ^ 1871 R_____ Printed by the Central Standards Bureau of the Ministry of Economic Affairs, τ- 消 f Cooperative, printed A7 B7 Invention Description ( θ) is also R 1 烨 octyl in reaction 3) or cyclohexane; R 2 is c2-c6 alkylidene. The best products are: or cyclohexyl * and the hydrocarbon solvent is (depending on Ri) Octane R is a formula (A is a N (R 4 and R 5 B are formulas (IX is > N -R 6 is C 1) for the reactant or fatty aromatic cumene cumene, fatty butyl hydrazone * Groups of methylhexyl ketone and G — I); R 4) (R 5); (same or different) is Ci-C8 alkyl; I); R 6 >-C 8 alkyl. The organic solvents of 1) and 2) are particularly aromatic hydrocarbons. Examples of hydrocarbons are toluene, xylene, trimethylbenzene, diisopropylbenzene and tert-butylbenzene. Examples of ketones are methyl ethyl ketone, methyl butyl ketone * methyl isopentyl hydrazone, ethyl butyl ketone, di-n-propyl ketone, methyl ethyl pentyl ketone. In particular, water-insoluble ketones are preferred (please read the notes on the back before filling this page). The preferred solvents for ketones are toluene, xylene, methylbutyl ketone, and methyl isobutane. Toluene and methyl isobutyl ketone are particularly preferred. Examples of inorganic rhenium used in the method of the present invention are sodium hydroxide, potassium hydroxide 20 This paper is suitable for Sichuan National Standard ((, NS) Λ4 specification (210X 297 mm) 491871 A7 B7 V. Description of the invention (), Sodium carbonate and potassium carbonate. Sodium oxide is preferred. Reactions 1) and 2) are preferably carried out in an inert gas, especially under nitrogen. The reactants of the formulae (cx) and (ii) are added to each other into a reactor at a temperature of 1 to 6o. Depending on the solvent used, the temperature may be, for example, increased to 80 to 85¾, and then after the reactor is closed, the temperature may be further increased to, for example, 1102 to 220, preferably 1501 to 160. Because this reaction is performed in a closed system *, the pressure increases with increasing temperature. Generally speaking, 3 to 8 bar, such as 4 to 6 bar, can be measured in the reactor. Because of the low boiling point of the solvent used * reaction 2) can also be conveniently performed in a closed system. Depending on the solvent used, the reaction 2) can be carried out at a temperature of, for example, 110 2 to 1 800, preferably 1 30¾ to 1700, especially 1 40¾ to 1 60¾. Because of the high reaction temperature, the pressure measured in the reactor is usually 3 to 8 bar, such as 4 to 6 bar. Printed by the Ministry of Standards, Mie Cooperative Cooperative (please read the precautions on the back before filling out this page) If necessary, after the reaction 2) is completed, the compound of formula (δ) and the final unreacted starting material may be Distillation is eliminated from the final mixture, or using general purification techniques. The product of reaction 2) can be conveniently isolated before reaction 3) 4 is performed. The peroxide decomposition catalysts used in reaction 3) are, for example, metal carbonyls, metal oxides * metal acetamidine pyruvate or amidoxane oxide, where the metal is selected from the group consisting of Period IVb, Vb, VIb , -2 The size of the paper is applicable to the national standard date ((, milk) 8 4 specifications (210, / 297 mm) 491871 A7 __B7_ V. Description of the invention (mountain) VI lb and VI II gold, preferably Vanadium (III) acetamidine pyruvate, cobalt carbonyl, chromium (VI) oxide, titanium isopropoxide (IV), titanium tetrabutoxide, molybdenum hexacarbonyl, molybdenum trioxide and the like. Best catalysts Is M 03. Suitable hydrogen peroxide is tert-butyl hydroperoxide, tert-pentyl hydroperoxide, tert-hexyl hydroperoxide, tert-octyl hydrogen peroxide, ethylbenzene hydroperoxide * Si Lin hydrogen peroxide or cumene (= cumene) argon peroxide. The best hydrogen peroxide is tert-butyl argon peroxide. In reaction 3), for every 1 mole present in reaction 2) Hindered amines of formula (G-I) in the product, using 2 to 8 moles * preferably 3 to 6 moles of hydrogen peroxide, 0. 001 to 0.1 moles, preferably 〇 · 005 to 0 · 05 mol of hydrogen peroxide decomposition catalyst and 5 to 30 mol, preferably 10 to 20 mol of hydrocarbon solvent: (Please read the precautions on the back before filling this page ) 、 1Τ Printed by the Consumer Standards Cooperative of the Central Standards Bureau of Didi Ministry

Conversion of sterically hindered amine group group of formula (G — I) to the following group group: Suspect 22- This paper size is applicable to the Chinese National Standard (CNS) Λ4 specification (210X 297 mm) 491871 A7 B7 Jing Bin Department * Marked by 扃 Μ, χ consumer cooperative printed $ 5. Invention Description (β)

It is carried out, for example, at 75¾ to 1 60¾, preferably 100t: to 1 50 υ. In reaction 3), when a sterically hindered amine group of the formula (G-1) is first treated with an aqueous hydrogen peroxide solution, treated in the presence of a hydrogen peroxide decomposition catalyst and in an inert solvent (such as described in US- Method A-4,69 1, 015) * The initial reaction product obtained in a very short time is equivalent to the N-oxy intermediate (-10Ri = oxy), which is highly dyed and can be used alone separate from. Therefore, other preferred embodiments of the present invention pertain to a product obtained from the above reactions 1) to 3), wherein the reactive group is 0 to ^ is an oxy group, and the hydrocarbon solvent used in the reaction 3) is The inert organic solvent * is preferably toluene or 1,2-dichloroethane. When the organic solvent of reaction 3) is a hydrocarbon having a labile hydrogen atom, when a hydrogen peroxide which is far more than the molar amount required for the conversion of the amine group to the relative N-oxy derivative is retained, and when the reaction is mixed If the substance is additionally heated to an appropriate temperature (preferably at 100t: to 150 * 0 hours) for a normal time, then the N-oxyl compound (which can be prepared from the original amine or used in this reaction process) Those who start the intermediate) and hydrocarbon solvents will advance to -23-degree. State of China (('Milk) 8 4 size (210' / 297 mm)) ---: --J ---- Φ ------ 1T ------ Φ— (Please read the notes on the back before filling in this page) 491871 A7 B7 V. Description of the invention (β) Step reaction to form the corresponding N-hydrocarbon Oxygen derivatives. In reaction 3), the original reaction mixture was colorless, but became highly dyed when the N-oxyl intermediate was formed. When this N-oxyl compound is converted to a colorless N-alkoxy product *, the color disappears. Therefore, it is important for this method that the color indicator M having an internal bond shows the degree of the reaction. When the reaction mixture becomes colorless, it means that the colored N-oxy intermediate is completely converted to the N-alkoxy product. An embodiment of the present invention also relates to a product obtained from the hydrogenation reaction 3) (wherein ORi is an oxygen group in the formula (G-II)) to obtain a product having the group (G-III) group (please read first (Notes on the back then fill out this page)

^ 1. The Ministry of Economic Affairs and the Central Bureau of the Ministry of Justice of the People's Republic of China, the negative JT-consumer Hezhu company printed the hydrogenation reaction according to conventional methods, such as in an organic solvent, such as formazan or ethanol, and a hydrogenation catalyst In the presence, palladium or carbon on carbon is preferred 1: 02, as described in 113-Aug 4,691, 0 1 5. 3. If necessary, reaction 3) The product obtained can be purified by one of the following methods: a) Decomposing the remaining peroxide and evaporating the solvent to obtain a crude solid product. rNS) Λ4 specification (210X 297 mm) Printed by Wu Gong Consumer Cooperative of the Central Standards Bureau of the Ministry of Industry, F 491871 A7 B7 i. Description of the invention (4). This solid product is stirred with an inert solvent such as cyclohexane * octane, hexane, petroleum ether, xylene, toluene, acetone, methyl ethyl ketone * ethyl acetate * butyl acetate, tert-butyl alcohol, Tert-amyl alcohol, isopropyl *, ethyl acetate, formazan, chloroform, dichloromethane, acetonitrile, diethyl ether, dibutyl ether and / or water. This mixture can be stirred while heating. After stirring * the mixture is cooled, the solid product is collected over time and then dried. b) The residual peroxide is decomposed, and the solvent is partially evaporated to eliminate the residue. A solid can be obtained, which is washed with an M-inert solvent, like one of the above solvents, and the obtained solid product can be quenched and then dried. c) The residual peroxide is decomposed, and the solvent is evaporated at a high temperature to obtain a melt. The hot melt is mixed with an inert solvent, like one of the solvents mentioned above (quenchable), and the precipitate is collected over time and then dried. Variations of this step include mixing hot melt and solvent * and then cooling the mixture to obtain a precipitate, or mixing the hot melt and solvent, followed by heating to dissolve any solids in solution, and then cooling to obtain a precipitate. . d) The residual peroxide is decomposed, and the solvent is evaporated at a high temperature to obtain a melt. This melt is dissolved in an inert solvent * like one of the above solvents (with or without heating), and then the excess solution is distilled off to concentrate the resulting solution. Then the solution and a second solvent are mixed at a high temperature, as described above. One of the solvents, so that the product precipitated. The solid product was collected by centrifugation and dried. More specifically, the product of reaction 3) is preferably purified by the following method. After reaction 3) is completed, the crude reaction mixture is cooled to 50C, and -25- this paper size Shizhou China Storehouse Mark (CNS) AAim (210X 297 / > t) I ---.----- ΦΙ — (Please read the notes on the back before filling out this page) Order ^ 1. Printed by the Shell Department Consumers Cooperative of the Central Bureau of Standards Preparation 491871 A7 B7 V. Description of the invention (,) Treat with 20% sodium sulfite aqueous solution until the concentration of residual oxides is reduced to below 0 ·. The aqueous layer was separated, and the product was concentrated under reduced pressure to concentrate the organic layer. The crude product was dissolved in an excess of t-butyl alcohol, and the solvent was removed by heating the solution under reduced pressure until the solid concentration was 50%. This solution was slowly added to cold formazan, and the precipitate was filtered, washed with methanol, and dried under vacuum in the presence of filtration. In general, the starting materials used in the above methods are conventional. Where they are not commercially produced * they can also be prepared in a similar way. The compound of formula (cx) can be prepared, for example, by reacting monocyanuric chloride with a compound of formula B-fluorene. The reaction is in a stoichiometric ratio and is carried out in the presence of an organic solvent and an inorganic base. It is also appropriate to prepare the compound of formula (") using the same solvents and inorganic bases of the above reactions 1) and 2). If required * After preparing the starting material of formula (a), reaction 1) can be carried out immediately without isolation. Compound of formula (α). Some starting materials of formula (/ 3) are described in, for example, WO-A-95 / 21,157; US-A-4,316,837 and US-A-4,743,688. Other embodiments of the present invention are a product obtained from the above reactions 1) and 2). Among them, the nitrogen atom in the group formula below -26- This paper size applies to the Chinese national standard date ((, NS) Λ4 size (210X 297 mm) (Please read the precautions on the back before filling this page) Order 491871 A7 B7 V. Description of the invention (yj)

Ci—C8 alkyl * C2—C8 hydroxyalkyl, 0, 1 OH, Ct—Ci 8 alkoxy (such as Ci—Ci 8 alkoxy or Cs—c! 2 cycloalkoxy), 1 CH2CN , C3-cealkenyl, C3-c6 alkynyl, C7-C9 phenylalkyl (which may be unsubstituted or substituted with 1,2 or 3 Ci-Ci alkyl groups on the phenyl group); or Ci —C8 fluorenyl substituted products can be prepared by methods similar to the above reactions 1) and 2), using appropriate starting materials. The nitrogen atom is preferably substituted by a Ci-C4 alkyl group, especially a methyl group. Those starting materials containing the following group bases (please read the notes on the back before filling out this page) Printed by the Central Standards Bureau of the Ministry of Consumer Affairs, JT. Consumer Cooperative

-27- The size of this paper is suitable for Sichuan National Standard (CNS) Λ4 specification (210X 297 mm) 491871 Α7 Β7 5. Description of the invention (Ί can be, for example, similarly described in US — Α-4,921,962; US4A 1 5,021,5 77 and US-A-5,204 * 473. The product of reaction 2) is not a single specific compound, but a compound having a molecular weight distribution. Polydispersity indicates the molecular weight distribution of the polymerized compound. In the present invention, the degree of polydispersity is the ratio of the weight average molecular weight (Mw) to the number average molecular weight (Mη). The closer the Mw / Mn value is to 1, the compound is monodispersed and has only one molecular weight, and no molecular weight. distributed. The narrow molecular weight distribution is characterized by a polydispersity (Mw / Mn) close to one. The degree of polydispersity of the preferred product of reaction 2) is 1 to 1'7 ', for example, 1.1 to 1.6, or 1.3 to 1.7, especially 1.3 to 1.6. Note that reaction 2 ) The products include, for example, less than 5 mole% ', especially less than 2 mole% or less than 1 mole, the terminal is not made by Xunquji (please read the precautions on the back before filling this page) The end of the cover is printed by the employee ’s consumer cooperative of the Central Standard Bureau of Dibu

A This paper size is suitable for China National Standard Cold (CNS) Λ4 specification (210X 297 mm) 491871 A7 _ B7__ V. Description of the invention (v1)) Reaction 1) When performed, it can form a ring structure compound of the following formula 1 byproduct

(Please read the precautions on the back before filling this page.) Printed by the Central Bureau of Standards of the Ministry of Economic Affairs, MΗConsumer Cooperative, and printed from US — Α — 4,442,250. This compound is known and can be less than 8 Mole% is present in the product of reaction 2). The product of reaction 2) preferably comprises a monodisperse compound of formula (M-I), a monodisperse compound of formula (M-II) ', a monodisperse compound of formula (M-III), and a formula of (M-IV) A mixture of monodisperse compounds. These compounds differ only in the number of repeating units. This paper is suitable for the Chinese national standard (rNS) Λ4 size (210X 297 mm) 491871.

A description of five

A

A

A

A

N

/ = N Ming N / Ya B ΙΓΝ ΝΥΒI Γ ΤΝ ΙΓΝΝ. / 丫 Β νφ

N — R

Ν I R

Ν — R

A r

I

A Γ Ν / Ah

\\ A rN, / Ya (M (Please read the notes on the back before filling in this page) ΤΝ τ ΝΝ. / Ya Printed by the Central Standard Soap Bureau of the Ministry of Economic Affairs T-Consumer Cooperative Β

Ν — R Β I, I AM radical response, anti}

A r / Ah Β

(M Μ) to (V ο Formula I 5 and I is, Μ and other special, and definite)% So I on the ear is like I ο is I 7 2 Μ to R (ο and, 4 R) Yes, I The total amount of physical compounds in existence -30- This paper size applies the Chinese National Standard (CNS) Λ4 specification (210X 297 mm) 491871 A7 B7 V. Description of the invention (| is ·· Μ Example 4 ί ratio and and No. 1 丨 matter to I in 1 I: Μ) 6 (V. Ο * I ο}} I or matter I Μ 1 in I {: mixed I and 6 in total > · total {I 1 于 和 I 至Pair} Μ 1 phase I ί: {I and 6% Μ, · ear 莫 Mo formula 5 6 *) ο I like I Example 〇I—- > 1 thing 1 and M mixed {of, matter) compound I ) MV (I formula I has Μ containing {于 和 在}: Preserve I based on I group 0 1) is a I) Μ I 3 (G shall, ί trans} in I of formula I

(G (please read the precautions on the back before filling this page) Set G / V format to be the base group.

(G-type Chinese products 3 should be reversed. The paper size shall be reversed. The paper standard shall apply the Chinese national standard (rNS) Λ4 specification (210X 297 mm). 491871 A7 B7. 5. Description of the invention (>)) P} I Μ) (V formula I from the beginning of the description {the above and MH are combined with the current phase > the reverse ions in the I stem I main I} ί combined V, chemistry I} some 1 I this P I is (I because this formula contains 1 kind of 1 and 0 is an example to implement it. The effect of the effect is to receive it. If it does not respond to the situation, the separate items are combined.} Form V I points P single > Formula I and I matter I combine to form 散, form separate form > I form I separate I point I to form single ✓ ✓vv VI / I form cover 3 The same thing is compounded, some of this thing is mixed, and the same thing is not the same as the number of voxels (please read the precautions on the back before filling this page)

Α * (Ρ- Printed by the Hegong Consumer Cooperative of the Central Bureau of Standardization of the Ministry of Economic Affairs

• Α (Ρ This paper is in the state of Shizhou, China's national standard ((: milk) 8 4 size (2 丨 0, / 297 mm) 491871 V. Description of the invention (4) A ··

N YA N B * Printed by the Consumer Goods Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs A7 B7 (p-m)

The total amount of compounds of formula (P — I) · (P — II), (P — III) and (P — IV) is 40 to 70 mole%, especially 50 to 65 mole% (relative to the total mixture Amount) ·, and Ri is hydrogen, a hydrocarbyl reactive group, or 0—Ri is an oxygen group;

Rz is Cz—Ci2, C4—Ci2, C5—C7 cycloalkylene, c5—C7 cycloalkylene (Ci—C4 alkylene), Ci—C4 alkylene di (c5—C7 cycloalkylene) ), Phenylene di (Ci-C4 alkylene) or C4-Ci 2 alkylene, which is composed of 1, 4 monomorphazine-33- This paper size applies to the Chinese National Standard Bee (CNS) Λ4 specification (210X 297 mm ) (Please read the notes on the back before filling this page)

491871 A7 B7 V. Description of the invention (4) Diyl radical, interrupted by 0—or> N—Xi, X! Is Ci—Ci 2fluorenyl or (Ci—Ci 2 alkoxy) carbonyl, or has the following R4 One of the definitions; or R2 is a group basis of the formula (I aa), (I-b) or (I-c)

(Bua) • CH2—CH—CH ^ I 2 ο Ic = 〇 (l-b)

(lc) Seal of the Industrial and Consumer Cooperatives of the Central Standardization Bureau of the Ministry of Economic Affairs m is 2 or 3, Xz is Ci—Ci 8 alkyl, and C5—Ci cycloalkyl, which are unsubstituted or composed of 1, 2 or 3 Ci Ci04 alkyl substituted; phenyl, which is unsubstituted or substituted with 1, 2 or 3 Ci Ci4 alkyl or Ci Ci4 alkoxy; C7-C9 phenylalkyl, It is Wei-34- (Please read the notes on the back before filling this page)

This paper size is applicable to China National Standards (CNS) Λ4 specifications (210X29 * 7 mm) ^ 1871 A7 B7 V. Description of the invention (Vj substituted or 1,2 or 3 C on phenyl! C__C4 alkyl Substituted; and the reactive groups X3 are independent of each other C2 — Ci 2 alkylene; A is an OR3, an N (R 4) (R $), or a group group of the formula (G-IV):

(G-IV) (Please read the precautions on the back before filling out this page) Member of the Central Standardization Bureau of the Ministry of Economic Affairs and Cooperation i printed to wood R 3, R 4 and Rs (same or different) are Ci-Ci8 alkane , C5-Ci 2 cycloalkyl, which is unsubstituted or substituted with 1 »2 or 3 Ci-C4 alkyl; C3-Ci 8 alkenyl, phenyl, which is unsubstituted or substituted by 1, 2 or 3 Ci-C4 alkyl or Ci-C4 alkoxy substituted; C7-C9 phenylalkyl, which is unsubstituted or substituted by 1, 2 or 3 Ci-C4 on phenyl Alkyl-substituted; tetrahydrofuranyl or C2-C4 alkyl, which is at the 2, 3, or 4 position by mono-OH, Ct-C8 alkoxy, di (Ci, mono-C4 alkyl) amine, or a formula (III ) Group replacement; -35 This paper size is suitable for China National Standard Cold (CNS) Λ4 specification (210X 297 mm) 491871 A7 B7 V. Description of the invention (v > (III) Y is a 0-, a CH2 —, A CH2 CHz — or> N-C Η 3; and R3 is additionally hydrogen or a N (R4) (Rs) is also a group group of formula (III); X is a 0 — or> N_R6; R6 is Ci-Cis alkyl, C3-Cl8 alkenyl, C5 Ci 2 Cycloalkyl, which is unsubstituted or substituted by 1 * 2 or 3 (: 1 C4 alkyl; C7-C9 phenylalkyl * which is unsubstituted or substituted by 1, 2 or 3 Ci-C4 alkyl substituted; tetrafuranyl, a group of formula (G-II), hydrogen (please read the precautions on the back before filling this page). -Consumer cooperative print

(G-II) or C2-C4 alkyl, which is at the 2, 3 or 4 position by a 0H * C! -C8 alkoxy group, a di (Ci_C4 alkyl) amino group or a group of formula (III) Base substitution; R has one of the above definitions of R6, and -3 6-This paper size is suitable for China National Standard Net ((, NS)) Λ4 specifications (210X 297 mm) 491871 A7 B7 — —— _ V. Description of the Invention (W) B has one of the definitions of A above. 0 The preferred mixture is:

Ri is octyl or cyclohexyl;

Rz is _C6 alkylene; R is a group group of the formula (G-II); A is a N (R4) (R 5); R4 and Rs (same or different) are Ci-C8 alkyl; B Is a group group of formula (G-IV); X is> NRe; and R6 is Ci—C8 焼 group 0 In the mixture of the present invention, the reactive group Ri can be regarded as two or more formulas (P — I), (P-II), (P-III) and / or (P-IV) linking group between the compounds, in which case a bridging group of formula (L-I) is then formed between the above compounds : (Please read the notes on the back before filling out this page)

(L-l)

The meaning of Ri ¥ can be derived from the definition of Ri. These two reactions -37- This paper size is applicable to the Chinese national standard (rNS) Λ4 specification (210X 297 mm). Consumption of Hezhusha Printing Co., Ltd. 491871 A7 B7 V. Description of the invention: The difference in base is that Ri rice has one or two other bridge valences. Therefore, when Ri is cyclohexyl, it is equivalent to Ri to cyclohexane. Or cyclohexanetriyl, when Ri is octyl, it is equivalent to Ri to be octanediyl or octanetriyl. The product of the present invention and the above-mentioned mixture can effectively improve the light, heat and oxidation resistance of organic substances, especially synthetic polymers and copolymers. In particular, low color interaction and good color are observed on polypropylene, especially polypropylene fibers, especially polypropylene in the presence of flame retarders, and low-density polyethylene for agricultural use ( LDPE) film. It is particularly noteworthy that the products of the present invention and the above-mentioned mixtures themselves are flame resistance agents. Examples of organic substances that can be stabilized are: 1. Polymers of military olefins and diolefins, for example, polypropylene * polyisobutylene, polybutadiene-1ene, poly-4-methylpentyl-1ene, polyisoprene Olefins or polybutadienes, and polymers of cycloolefins, such as cyclopentene or norbornene, other polyethylenes (if required, they can be crosslinked), such as high density polyethylene (HDPE), high Density and high molecular weight polyethylene (HDPE-HMW), high density ultra high molecular weight polyethylene (H DPE-UHMW), medium density polyethylene (MDPE), low density polyethylene (LDPE), linear low density polyethylene (LLDPE) (VLDPE) and (ULDPE) olefins, that is, polymers of monoolefins, such as the monoolefin polymers exemplified in the previous paragraph, especially polyethylene and polypropylene can be prepared by different methods, In particular, the following methods: -3 8 _ This paper is suitable for China National Standard ((, NS) Λ4 size (210 X 297 mm) (please read the notes on the back before filling this page). Printed by the Central Ministry of Standards, Loan Workers, Consumer Cooperatives 491871 A7 B7 Explain (4) a) Reactive radical polymerization (usually under high pressure and high temperature). b) A catalyst polymerization reaction using a catalyst. The catalyst usually contains one or more metals of Group IVb · Vb, VI b or VI II on the periodic table. These gold tinctures usually have one or more types, typically: Oxides, halides, alcohol esters, esters, ethers, amines, alkylates, alkenylates and / or arylates, which may be π- or σ-covalent. These gold dysprosium compounds can be free or immobilized on a substrate * typically in activated magnesium chloride, titanium (III) chloride, aluminum or silicon oxide. These catalysts can be soluble or insoluble in the polymer matrix, and these catalysts can be used by themselves in the polymerization reaction, or an activator can be used, typically gold amidate, amidate hydride, aureate Base halide, metal alkyl oxide or metal alkyl oxane, the metal may be an element of group I a, II a, and / or II IA of the periodic table, and the activator may further be ester, ether * amine or silane Convenient modification of ethers. These catalyst systems are commonly referred to as Phillips, Standard Oil Indiana, Ziegler (-N a 11 a), TNZ (DuPont), metallocene or single-sided catalyst (SSC). 2. A mixture of polymers mentioned in 1), for example, a mixture of polypropylene and polyisobutylene, a mixture of polypropylene and polyethylene (for example, PP / HDPE, PP / LDPPE), and a mixture of different types of polyethylene (for example, LDPE / HDPE). 3. Copolymers of mono- and diolefins, or copolymers with other ethylene monomers, such as ethylene / propylene copolymers, linear low-strength polyethylene (LL DPE) and mixtures thereof, and low-strength polyethylene (LDPE) ， Acrylic-39- This paper is suitable for Sichuan National Standard (rNS) Λ4 specification (210X 297mm) * --------- P! (Please read the precautions on the back before filling this page) Printed by the Central Standards Bureau of the Ministry of Printing, printed by --T-Consumer Cooperatives 491871 A7 B7 V. Description of the invention (vV) / butadiene-1 copolymer • propylene / isobutylene copolymer, ethylene / butadiene-1 copolymer, Ethylene / hexene copolymer • ethylene / methylpentene copolymer, ethylene / heptene copolymer》 ethylene / octene copolymer, propylene / butadiene copolymer, isobutylene / isoprene copolymer, ethylene / Alkyl acrylate copolymers, and their copolymers with carbon monoxide, or ethylene / acrylic acid copolymers, and their salts (ions), and terpolymers of ethylene, propylene, and diene, like Hexadiene, dicyclopentadiene or ethylene di-orbornene; and mixing between the copolymers And the mixture of polymers mentioned in 1) above, for example, polypropylene / ethylene / propylene copolymer, LDPE / ethylene-ethylene acetate copolymer (EVA), LDPE / ethylene-acrylic acid copolymer (EAA), LLDPE / EVA, LL DPE / E AA and polyalkylene-carbon monoxide copolymers with a staggered or scattered structure, and mixtures with other polymers * such as polyamides. 4. Hydrocarbon resins (e.g., Cs-C9) 'include their hydrogenated modifiers (e.g., adhesives), and mixtures of polyolefins and starch. 5. Polystyrene, poly (P-methylstyrene) 'poly (α-methylstyrene). 6. Copolymers of styrene or ex-methylstyrene and diene or acrylic acid derivatives, for example, styrene / butadiene, styrene / acrylonitrile, styrene / alkyl methacrylate, styrene / butadiene Diene / Alkyd Acrylate's Styrene / Butadiene / Alkyl Methacrylate, Styrene / Maleic Anhydride, Styrene / Acrylonitrile / Methacrylate ·, High Impact Strength of Styrene Copolymer Mixture, and another polymer, for example, polyacrylate, -40- This paper size is applicable to Chinese national standard (rNS) Λ4 size (210X29 * 7 mm) (Please read the precautions on the back before filling this page ) Ordering line ^ 1871 Five _ ^^ __ The Ministry of Standards and Disposal of the Ministry of Economics and Industry separates and eliminates Hezhu News Agency A7 B7 Description of the invention (6) Diene polymer or monoethylene / propylene / diene terpolymer; Block copolymers with styrene, like stupid ethylene / butadiene / styrene * styrene / isoprene / styrene, styrene / ethylene / butene / styrene or styrene / ethylene / propylene / Styrene. 7. Graft copolymers of stupid ethylene or α-methylstyrene * For example * styrene on polybutadiene, on polybutadiene-styrene or on polybutadiene-acrylonitrile copolymer Styrene on polybutadiene and acrylonitrile (or methacrylic); styrene, acrylonitrile and methacrylic acid on polybutadiene; benzene on polybutadiene Ethylene and maleic anhydride; styrene, acrylonitrile and maleic anhydride or maleimide on polybutadiene; styrene and maleimide on polybutadiene Imines; styrene and alkyl acrylates or methacrylates on polybutadiene; ethylene and acrylonitrile on ethylene / propylene / diene terpolymers; polyalkyl acrylates or polyalkylenes Styrene and acrylonitrile on methacrylate; styrene and propylene on acrylate / butadiene copolymers, and mixtures with copolymers listed in item 6), for example, the conventional ABS, MBS, AS A Or copolymer blends of AES polymers. 8 · Halogen-containing polymers like polychlorinated pentadiene, chlorinated rubber, chlorinated or vulcanized chlorinated polyethylene, copolymers of ethylene and chlorinated ethylene, epichlorohydrin homo- and copolymers, especially those containing Polymers of halogenated ethylene compounds, for example, polyvinyl chloride, polyethylene chloride, polyethylene fluoride, polyethylene fluoride, and copolymers thereof 'like ethylene chloride / ethylene dichloride, ethylene Chloride / Ethylene Acetate or Ethylene Diene / Ethylene Acetate-4 1- This paper size applies to China National Standard (CNS) Λ4 specification (210X 297 mm) (Please read the precautions on the back before filling in this Page) 491871 A7 B7 V. Description of the invention (sand) Copolymer. 9 ♦ Polymers prepared from α, -unsaturated acids and their derivatives, such as polyacrylates and polymethacrylates; polymethacrylates, polyamidamine and polyacrylonitrile * κ acrylate Impact reformers. 1 0 · 9) The copolymer formed between the monomers and other unsaturated monomers, such as acrylonitrile / butadiene copolymer, acrylonitrile / alkyl acrylate copolymer, acrylonitrile / alkoxyalkyl Acrylate or acrylonitrile / ethylene halide copolymer or acrylonitrile / alkylmethacrylate / butadiene terpolymer. 11. Polymers derived from unsaturated alcohols and amines or their halogenated derivatives or acetals, for example, polyvinyl alcohol, polyvinyl acetate, polyethylene stearate, polyvinyl benzoate , Polyethylene maleate, polybutylene acetal, polyallyl phthalate or polyallyl melamine; and copolymers thereof with the olefins mentioned in point 1 above. 1 2 · Homopolymers and copolymers of cyclic ethers, such as polyolefin diols, polyethylene oxides, polypropylene oxides, or copolymers with dioxypropylene ethers. Printed by the Central Government Bureau of Dibei-T-Consumer Cooperative (please read the precautions on the back before filling this page) 13. Polyacetal, like polyoxymethylene and those polyoxymethylenes * which contain ethylene The oxide is treated as a comonomer, K thermoplastic polyurethane, acrylate or MB S modified polyacetal. 1 4 · Mixtures of polyphenylene oxide and sulfide * and polystyrene oxide and styrene polymer or polyamide. '1 5 ♦ Polyurethane derived from hydroxyl-terminated polyether, with poly or polybutadiene on one side, and aliphatic or aromatic polyisocyanate on the other side' and its precursors. -42- This paper size applies to Chinese national standard Wei (ms) Λ4 specifications (210X 297 mm) Printed by the Central Bureau of Standards of the Ministry of Freight and Consumers' Cooperatives 491871 A7 _ B7 V. Description of the invention () 16 · Polyamide and Copolymers derived from diamines and dicarboxylic acids and / or amine carboxylic acids or equivalent internally salted amines, for example, polyamine 4, polyamine 6, polyetheramine 6/6 · 6/10 * 6/9 · 6/12, 4/6, 1 2/1 2, polyamine 1 1 »polyamine 1 2 · aromatic polyamines starting from m-xylenediamine and adipic acid; Polyamines derived from hexamethylene diamine and isophthalic acid or / and terephthalic acid * with or without elastomers as modifiers, for example, poly-2,4,4-trimethylhexamethyl P-phthalamide or poly (m-phenylene isopeptide) amine; and the above-mentioned polyamines and polyolefins, olefin copolymers, ionized compounds, or chemically bonded or grafted amidines; or polyethers, such as Block copolymers of ethylene glycol, polypropylene glycol or polytetramethylene dienzyme; and KEPDM or ABS modified polyamines or copolyamides; and concentrated during the preparation process (RI M polyamine system) Polyamide 0 1 7 Polyurea, polyimide, polysaccharideamine and imidazole. 18. Polyesters derived from dicarboxylic acids and diols and / or hydroxycarboxylic acids or equivalent lactones, for example, polyethylene peptidate, polybutene peptidate, green-1, 4 Dimesylated cyclohexane para-peptides and polyhydroxybenzoates, and block copolyether esters derived from hydroxyl terminated polyethers; and K polycarbonate modified or MB S modified Polyester. 19. Polycarbonate and polyester carbonate. \ 20 · polymill, polyether mill and polyether 嗣. 21 · Crosslinked polymers derived from aldehyde on one side, phenol, urea and melamine on the other side, such as phenol / formaldehyde resin, urea / formaldehyde resin, and honey-4 3-This paper is suitable for China in China Standard (CNS) Λ4 specification (210X 297 mm) --------- f, (Please read the precautions on the back before filling this page) Thread-491871 A7 B7 V. Description of the invention (J) Amine / formaldehyde resin. 2 2; • Dry and non-drying alkyd resins. 23 · Unsaturated polyester resins derived from saturated and unsaturated dibasic acid and polyhydrogenase and ethylene compounds as crosslinking agents, and their low-flammability halogen-containing modifiers. 24 Crosslinked acrylic resins derived from substituted acrylates * For example, epoxy acrylic resins, urethane acrylic resins or polyester acrylates 0 2 5 Alkyd resins, polyester resins and melamine resins are crosslinked Acrylic resin, urea resin, polyisocyanate or epoxy resin. 26. Cross-linked epoxy resins derived from aliphatic, cycloaliphatic, heterocyclic or aromatic oxopropionyl compounds, such as products obtained from bisphenol A and bisphenol F bisoxypropyl ethers, It can work with traditional hardeners, like anhydrides or amines (either in the presence or absence of accelerators). 27. Natural polymers, such as cellulose, rubber, gelatin and their homologous derivatives modified chemically, such as cellulose acetate, cellulose propionate and cellulose butyrate * or cellulose ethers, like Methylcellulose; and printed by Zhengong Consumer Cooperative, Central Bureau of the Ministry of Economic Affairs, -------- f (please read the precautions on the back before filling this page) and their derivatives. 28 ♦ Blends (Polyblends) of the above polymers, such as PP / E PDM, polyamide / EPDM or ABS, PVC / EVA, PVC / ABS, PVC / MBS, PC / ABS, PP TP / ABS, PC / ASA , PC / PBT, PVC / CPE · PVC / Acrylic, POM / Thermoplastic PUR, P -44- This paper size applies to China National Standards (CNS) Λ4 specifications (210X 297 mm) outside 1871

Printed by the Ordnance Industry Consumer Cooperative of the Central Bureau of Standards of the Ministry of Discharge i. Invention Description (β) 〇 / Thermoplastic? 111 ^ *? 01 ^ / acrylate,? 0 ^ 4 / "88, PPO / HIPS, PP0 / PA6 · 6 and copolymer, PA / HDPE, PA / PP, PA / PPO, PBT / PC / ABS or PBT / PET / PC. 29 · Naturally occurring and synthetic Organic substances, which are pure compounds or mixtures of such compounds, for example, mineral oils, animal and animal fats, oils and waxes, or synthetic ester-based oils, fats and waxes (eg, phthalates, adipates Acid esters, phosphate esters, trimelates) and mixtures of synthetic esters and mineral oils in any weight ratio, typically those used as spinning compositions and aqueous emulsions of the substances. 3 0 · Natural or synthetic An aqueous emulsion of a rubber, such as a natural latex or emulsion of a carboxylic acid styrene / butadiene copolymer. The present invention also relates to a composition including an organic substance that is sensitive to degradation by light, heat, or oxidation, and The product or mixture of the present invention. The organic substance is preferably a synthetic polymer, more preferably a polymer selected from the aforementioned groups. Polyolefins are preferred, and polyethylene and polypropylene are particularly preferred. The present invention The other example of cricket is A method for a substance to resist degradation caused by light, heat or oxidation, including adding the product or mixture of the present invention to the organic substance. Depending on the nature of the stabilized substance, the end use and other additives, the product or mixture of the present invention may be Used in various quantities. -45- This paper size is ϋΐ Chinese national standard ((, milk) 8 4 size (210 \ 297 mm) (Please read the precautions on the back before filling this page), 11% * 梂 Quasi-Bureau Consumer Cooperatives Co., Ltd. Seal 491871 A7 B7 A 丨 • '丨' 一 _ V. Description of the invention) Generally speaking * It is appropriate to use, for example, 0.01 to 5% by weight of the product or mixture of the present invention (Relative to the weight of the substance to be weighed) • Preferably 0. 05 to 2% * especially 0. 05 to 1. The product of the present invention or a mixture thereof may be, for example, polymerized or cross-linked, Added to the polymeric substance at the time or later • In addition * they can be added to the polymeric substance in the form of pure substances or coated in rhenium, oil or polymer. In general, the products or mixtures of the invention can be Various party Addition to polymer materials, such as powder type dry mixing, or solution or suspension type wet mixing, can also be added in the form of a matrix containing the product or mixture of the present invention at a concentration of 2.5 to 25% by weight; in these In operation, the polymer used can be applied in the form of powder, granule, solution, suspension, or K latex. Μ The product or mixture-stabilized substance of the present invention can be used to produce moldings, films, and ribbons. Materials, monofilaments, fibers, surface coatings and the like. If necessary, other conventional additives suitable for synthetic polymers can be added to organic substances containing products or mixtures of the present invention, such as antioxidants, UV absorbers, Nickel stabilizers, pigments, fillers, plasticizers * corrosion inhibitors and metal deactivators. 'Specific examples of this traditional additive are: 1 · Antioxidant f 1 · 1 · Alkylated Monophenols · For example, 2,6-di-tert-butyl-1 4 -4 6-This paper is suitable for the Sichuan National Standard彳 ((, NS) Λ4 size (210X 297mm) (Please read the precautions on the back before filling in this page)

、 1T% 491871 A7 B7__ V. Description of the invention (M)-methylphenol, 2-butyl-4,6-dimethylphenol, 2,6-di-tert-butyl-4, n-butylbutyl , 2,6-di-tert-butyl-4-ethylphenol, 2,6-di-tert-butyl-4-isobutylphenol, 2,6-dicyclopentyl-4-methylphenol , 2- (α-methylcyclohexyl) -4,6-dimethylphenol, 2,6-octacosyl-4 monomethylphenol, 2,4,6-tricyclohexylphenol, 2, 6-Di-tert-butyl-4 4-methoxymethylphenol, 2,6-di-nononyl-4 4-methylphenol · 2,4-dimethyl-2-6- (1,1-methyldeca 1-alkane- 1-yl) phenol, 2, 4-dimethyl- 6- (1,1-methylheptadecanyl- 1-yl) phenol, 2,4-di-methyl- 6- (1, 1 Methyltridecane-1,1-yl) phenol and mixtures thereof. 1,2 · Alkylthiomethylphenol, for example, 2,4-dioctylthiomethyl-6-tert-butyl age, 2,4-dioctylthiomethyl-6-methylphenol, 2,4 Dioctylthiomethyl-6-ethylphenol, 2,6-dodecanylthiomethyl 4-nonylphenol. Printed by the Ministry of Justice, Bureau of Standards and Consumption, Hezhu Co., Ltd .--------- f, (Please read the precautions on the back before filling out this page) Line 1 · 3 · Hydroquinone and Its alkylated hydroquinone, for example, 2,6-di-tert-butyl-4, methoxyphenol, 2,5-di-tert-butylhydroquinone, 2,5-dione Tert-pentylhydroquinone, 2,6-diphenylphenyl-4 octadecyloxy, 2,6-di-tert-butylparaphenylene, 2,5-di-tertiary Butyl-1, 4-butyl-tert-butyl-1, 4-mono-hydroxyanisole, 3,5-di-tert-butyl-1, 4-hydroxyphenylstearate, di-1 (3,5-di-tert-butyl-4-hydroxyphenyl) adipate. -47- This paper uses the Chinese national standard ((, NS) Λ4 size (210X 297 mm) in the Ministry of Economic Affairs. T consumer cooperatives printed $ 491871 Α7 Β7 V. Description of invention (wV) 1 · 4 · Tocopherols, such as α-tocopherol, yS—tocopherol, 7-tocopherol, S—tocopherol and mixtures thereof (vitamin E). 1.5 · hydroxylated thiodiphenyl ether, such as * 2 * 2 'monothiobis (6-t-butyl-4-methylol), 2,2' monothiobis (4-octylphenol), 4,4 'monothiobis (6-tert-butyl) -3-methylphenol), 4,4 'monothiobis (6-tert-2-methylphenol), 4,4' monothiobis (3,6-di-sec-pentylphenol), 4, 4'-bis (2,6-dimethyl-4-hydroxyphenyl) disulfide. 1 · 6 · alkylidene bisphenols, for example, 2,2 ^ -methylenebis (6-tert-butyl-1 4 monomethylphenol), 2,2 'monomethylbis (6-tert-butyl-4 monoethylphenol), 2,2T monomethylbis [4 monomethyl-6 — («—methyl Cyclohexyl) phenol], 2,2'-methylenebis (4-methyl-6-cyclohexylphenol), 2,2, monomethylbis (6 —Nonyl-4 monomethylphenol), 2,2,1-methylenebis (4,6-di-tert-butylphenol), 2,2′-ethylidenebis (4,6-di-tert-butyl) Butylphenol), 2, 2'-ethylidenebis (6-tert-butyl-1, 4-isobutylphenol) * 2, 2, methylidene [6 — (c (monomethylbenzyl) -1 4 monononylphenol], 2, 2 'monomethylbis [6 — (α, α —dimethylbenzyl) 4 monononylphenol], 4, 4 ′ monomethylbis (2,6 — Di-tert-butyl phenol), 4,4 > Monomethylbis (6-tert-butyl-2'-methylphenol), 1,: L-bis (5-tert-butyl-4-hydroxyl One 2-methylphenyl) butane, 2,6-bis (3-tert-butyl-5-methyl-2-hydroxybenzyl) -4 methyl, 1,1,3-tri ( 5 —tert-butyl-1 4 ~ 48- This paper is suitable for the middle threshold national standard of the state ((, NS) Λ4 specification (210X 297mm) --------- f (Please read the Please fill in this page for the matters needing attention) Printed by Didi Zhongxing Standard Bureau, Soldier Cooperative Co., Ltd. 491871 A7 B7 5. Description of the invention (…) 2-methylphenyl) butane * 1 · 1 bis (5-tert-butyl-4, hydroxy-1,2-methylphenyl) -3-n-dodecylhydrothiobutane, ethylene Diether bis [3,3-bis (3 # -tert-butyl-4'-hydroxyphenyl) butanoic acid]], bis (3-tert-butyl-4-hydroxy-5-methyl-phenyl ) Dicyclopentanyl, bis [2 — (3 # mono-t-butyl- 2′-hydroxy-5′-methylbenzyl) -6-tert-butyl-4 4-methylphenyl) p-peptidic acid Esters, 1 »1-bis (3,5-dimethyl-2-hydroxyphenyl ·) butane, 2,2-bis- (3,5-di-tert-butyl-1, 4-merylphenyl) ) Benzene, 2,2-bis (5-tert-butyl-4, meridyl, 2-methylphenyl), 4-n-dodecylhydrothiobutane, 1, 1, 5, 5-tetrakis (5-tert-butyl-4, hydroxy-1,2-methylphenyl) pentane. 1 · 7 · 0 — · Ν — and S — benzyl compounds, such as 3,5,3,, (3,4-tetra-t-butyl-4,4, -dihydroxy-diphenylmethyl ether, Octadecyl-4 monohydroxy-3,5-dimethylbenzyl hydrothioacetate, tris (3,5-di-tert-butyl-4-hydroxybenzyl) amine, bis (4-t-tert-butyl-3-hydroxy-2,6-dimethylbenzyl) dithio-peptide, bis (3,5-di-t-butyl-4-4-hydroxybenzoate Group) sulfide, isooctyl-3,5-di-tert-butyl-1, 4-hydroxybenzyl hydrothioacetate. '1.8 · hydroxybenzyl malonate, such as di (Octadecyl) 2,2-bis- (3,5-di-tert-butyl-2-transylbenzyl) monomalonate, dioctadecyl-2 1 (3 1-tert-butyl-1-49- This paper size is suitable for China National Standard ((, NS) Λ4 size (210X 297 mm) (Please read the precautions on the back before filling this page) f

1, 1T printed by the Central Bureau of Standards of the Ministry of Standards, Shellfish Consumer Cooperative, 491871 A7 B7 V. Description of the invention (4) 4-hydroxy-1,5-methylbenzyl) malonate, didodecyl hydrosulfide Ethylethyl-2,2-bis (3,5-di-tert-butyl-1, 4-hydroxybenzyl) malonate, bis- [4-a (1,1,3,3, tetramethyl) Butyl) phenyl] -2,2-bis (3,5-di-tert-butyl-4 4-hydroxybenzyl) malonate. 1 · 9 · Aromatic hydroxybenzyl compounds · For example 1,3,5-tris (3,5-di-tert-butyl-4 4-hydroxybenzyl) -2,4,6-trimethyl Phenylbenzene, 1,4 bis (3,5-di-tert-butyl-1, 4-hydroxybenzyl), 2,3,5,6-tetramethylbenzene, 2,4 »6-trione ( 3,5-di-tert-butyl-4 4-hydroxybenzyl) phenol 0 · 10 · triazine compounds, such as 2,4-bis (octylhydrothio) -6- (3,5-di 1-tert-butyl-4 4-hydroxyaniline) -1,3,5-triazine, 2-octylhydrosulfanyl-4,6-bis (3,5-di-tert-butyl-4-hydroxy (Monoaniline)-1,3,5-triazine, 2-octylhydrothio- 4,6-bis (3,5-di-tert-butyl- 4 -hydroxyphenoxy)-1,3 , 5 -triazine, 2,4,6 -tris (3,5-di-tert-butyl-4 -hydroxyphenoxy) -1,2,3-triazine, 1,3,5 -trin (3,5-di-tert-butyl-4 4-hydroxybenzyl) isocyanurate, 1,3,5-tri- (4-tert-butyl-3- Phenyl-2,6-di-methylbenzyl) isocyanurate, 2,4,6-tris (3,5-di-tert-butyl-4, 4-hydroxyphenylethyl) -1, 3,5 —triazine, 1, 3,5 —tri-50 — This paper size is applicable to China National Standard Soldier (CNS) Λ4 specification (210X 297 mm) --------- f, (please first (Read the notes on the back and fill out this page)

* 1T 491871 Printed by the Central Bureau of Standards of the Ministry of Economic Affairs and the Consumer Goods Cooperative of A7 B7 V. Description of the invention , 3,5-triazine, 1,3,5-tris (3,5-dicyclohexyl-4 4-hydroxybenzyl) isocyanurate. 1 · 1 1 · benzylphosphonates, for example, dimethyl-2,5-di-tert-butylbutyl-4 monohydroxybenzylphosphonate, diethyl-3,5-ditert Monobutyl-4 monohydroxybenzyl phosphonate * octacosyl 3,5 di-tert-butyl mono-4 monohydroxy-benzyl phosphonate, octacosyl 5-tert-one Calcium salt of monoethyl 4-butyl-hydroxy 3-methylbenzyl monophosphonate, monoethyl ester of 3, 5-di-tert-butyl 4-hydroxybenzyl monophosphonic acid. 1 · 12 · fluorenylaminophenol, for example, 4-monohydroxy 醯 lauryl aniline, 4-monohydroxystearyl tetanil, octyl-N— (3,5-di-tert-butyl-4-hydroxy Phenyl) carbamate. 1 · 13 · / 3-(3,5-Di-tert-butyl-4 4-hydroxyphenyl) propionic acid and mono- or polyhydric alcohol esters, such as and methanol, ethanol, stearyl alcohol, 1, 6-hexanediol, 1,9 monononanediol, ethylene glycol, 1,2-propanediol, neopentyl glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol , Pentaerythritol, tris (hydroxyethyl) isocyanurate, N, N 'bis (hydroxyethyl) ethylenediamine diamine, 3-thiaundecanol, 3-thiopentadecanol, trimethyl Hexane diamidine, tris-methyl-propane, 4-hydroxymethyl- 1-phosphorus 2 · 6,7-trioxabicyclo [2 • 2 · 2] octane. 1 · 14 · / 9 Mono (5-tert-butyl-1, 4-hydroxy-1, 3-methylbenzene-51- This paper size applies to Chinese National Standard (rNS) Λ4 specification (210X 297 mm) (Please read first Note on the back then fill out this page) #-·

1. 1T line 491871 A7 __B7__ 5. Description of the invention (4) Group) Propionic acid and mono- or polyhydrogenated esters • Such as "and formazan * ethanol * stearyl alcohol, 1, 6-hexanediase, 1 , 9 monononane monodiol, ethylene dienzyme, 1, 2-propane dienzyme, neopentyl dienzyme, thiodiethylene dienzyme, diethylene glycol, triethylene dienzyme, pentaerythritol, three Mono (hydroxyethyl) isocyanurate, N, N > —Bis (hydroxyethyl) ethylenedifluorene diamine, 3- warm undecanol, 3-thiapentadecanyl alcohol, trimethylhexyl Dioxan, trimethylolpropane, 4-monomethylol-1, 1-phospho-2,6,7-trioxabicyclo [2 · 2 · 2] octane. 1 * 1 5 · > 3-(3,5-dicyclohexyl-4 acylphenyl) propionic acid and mono- or polyhydric alcohol esters, such as with methanol, ethanol, stearyl alcohol, 1, 6 —Hexanediase, 1,9-nonanediol, ethylene glycol, 1, 2-propanediol, neopentyl glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol, Pentaerythritol, Tris (hydroxyethyl) isocyanurate, N, N'-bis (hydroxyethyl) ethylenediamine diamine, 3-thiaundecanol, 3-thiapentadecanol, trimethyl Hexanediol, trimethylolpropane, 4 monohydroxymethyl-1 monophosphoryl 2,6,7-trioxabicyclo [2 · 2 ♦ 2] octane. The Central Bureau of Standards of the Ministry of Economic Affairs only eliminates the seal of the cooperative (please read the precautions on the back before filling out this page) 1 · 1 6. 3, 5 —di-tert. 1-butyl-4 4-hydroxyphenylacetic acid and Esters of mono- or polyhydric alcohols such as and methanol, ethanol, stearyl alcohol, 1,6-hexanedienyl, 1,9 monononanediol, ethylene glycol, 1,2-propanedial, new Amyl glycol, thiodiethylene glycol, diethylene glycol, triethylene dienzyme, pentaerythritol, tris (hydroxyethyl) isocyanurate, Ν, Ν, bis (hydroxymonoethyl) ethyl Dimethyldiamine, 3-thiaundecane-52- This paper size applies to the Chinese National Standards (CNS) Λ4 specification (210X 297 mm) 491871 Α7 Β7 printed by the Central Standards Bureau of the Ministry of M Description of the invention (called) Fermentation, 3-thiapentadecanol • trimethylhexanediase, trimethyl alcohol propane, 4-monohydroxymethyl-1, 1-phospho-2, 6, 7-trioxabicyclo [ 2 · 2 • 2] octane. 1 · 17 · /? — (3,5 —di-tert-butyl-4 4-hydroxyphenyl) propionate, such as N, N'-bis (3,5-di-tert-butyl) One 4-hydroxyphenylpropanyl) hexamethylene diamine, one bis (3,5-di-tert-butylbutyl-4 4-hydroxyphenylpropanyl) trimethylenediamine, Ν, Ν 'one bis (3, 5-di-tert-butyl-4-hydroxy-phenylpropanyl) hydrazine, N, N'-bis [2- — (3-[3,5-di-tert-butyl-4-hydroxyphenyl]] Propyl) ethyl] oxamine. 1 * 18 * ascorbic acid (vitamin (:) 1.19 · amine antioxidants, for example, N, N / -diisopropyl-ρ-phenylene diamine, N, N, 1,2 sec-butyl-1 ρ-phenylenediamine, N, N < -bis (1,4-dimethylpentyl) -ρ, phenylene diamine, Ν, Νχ-bis (1-ethyl-3, methylpentyl) One ρ —phenylene limb, Ν, Ν ′ — bis (1 monomethylheptyl) — ρ —phenylene diamine, Ν * Ν / one dicyclohexyl—ρ — phenylene diamine, Ν, Ν ' Monodiphenyl-ρ-phenylenediamine, N, N /-bis (2-naphthyl) -ρ-phenylenediamine, N-isopropyl-N, one benzyl-ρ-benzyl diamine , Ν— (1,3-dimethylbutyl) -N′-phenyl-ρ′-phenylene diamine, N— (1-methylheptyl) -N ′ —phenyl-ρ —phenylene Diamine, N-cyclohexyl-N'-phenyl-ρ-phenylene diamine, 4-((p-toluidine) -diphenylamine, N, N, dimethyl-N, ^^ One Two One Two -53- (Please read the precautions on the back before filling out this page), 11 paper size; f l Chinese National Standard Binding (rNS) Λ4 specification (210X 297 mm) Printed by MJ-Consumer Cooperative of the Central Standardization Bureau of the Ministry of Justice 491871 A7 B7 V. Description of the invention (#) monobutyl-p-phenylenediamine, Diphenylamine, N-allyldiphenylamine, 4τ ~ isopropoxydiphenylamine, N-phenyl-1, 1-diylamine, N- (4-tert-octylphenyl) -1 Mononaphthylamine, N-phenyl-2naphthylamine, octylated diphenylamine, such as P, P, 1,2 tert-octyldiphenylamine, 4 η-butylamino Phenol, 4 monobutylaminoamino phenol, 4 monononylaminophenol, 4 dodecylaminophenol, 4 octamethylaminophenol, bis (4-methoxyphenyl) amine, 2, 6-Di-tert-butyl-1, 4-dimethylaminomethylphenol, 2,4'-diaminodiphenylmethane, 4,4, diaminodiphenylmethane, N, N , N ', N, tetramethyl-4,4, -diaminodiphenylmethane, 1,2-bis [(2-methylphenyl) amino] ethane, 1,2-bis ( Phenylamino) propane, (0-tolyl) biguanide, bis [4 a (1 ^ ^ 3, a Methylbutyl) phenyl] amine, tert-octyl N-phenyl-1naphthylamine, single and dialkylated tert-butyl / tert-octyldiphenylamine mixtures, Single and dialkylated nonyldiphenylamine mixtures, single and dialkylated dodecyldiphenylamine mixtures, mono- and dialkylated isopropyl / isohexyldiphenylamine mixtures Mixtures, single and dialkylated tert-butyldiphenylamine mixtures, 2,3-dihydro-3,3-dimethyl-1,4Η-1,4,1-benzothiazine, phenothiazine, single And dialkylated tert-butyl / t-octylphenothiazine mixture, mono- and dialkylated tert-octylphenothiazine mixture, N-allylphenothiazine, N, N , N < »N /-Tetraphenyl-1,4-diaminobutane-2-ene, N, N-bis (2, 2, 6, 6, 6-tetramethylmonopiperidine-4 4-yl-6 Methylene diamine, double (-54- --------- Φ— (Please read the precautions on the back before filling this page)

、 1T line A paper size applies to China National Standard Cold (CNS) Λ4 specification (210X 297 mm) _ 491871 Α7 Β7 V. Description of the invention (β) 2, 2, 6, 6-tetramethylpyridine 1 4 1 Group) sebacate, 2,2,6,6-tetramethylnesidine-4 monoone, 2,2,6,6-tetramethylnesiala 4-monool. s 2 · UV absorber and light stabilizer 2 · 1 · 2 — (2 # monohydroxyphenyl) benzotriazolyl, for example, 2 — (2 # monohydroxy-5, monomethylphenyl) -benzo Triazolyl, 2 — (3 '»5 # 1,2-tert-butyl-monohydroxyphenyl) benzotriazolyl, 2- (5'-tert-butyl-2, monohydroxyphenyl) benzene Benzotriazolyl, 2- (2, monohydroxy-5 '-(1,1,3,3-tetramethylbutyl) phenyl) benzo-triazolyl, 2- (3' * 5'-1 Di-tert-butyl- 2'-hydroxyphenyl) -5-chloro-benzotriazolyl, 2- (3'-tert-butyl- 2'-hydroxy-5,1-methylphenyl) 5-chloro-benzotrisalyl, 2- (3'-sec-monobutyl-5, 1-tert-butyl-2'-hydroxyphenyl) benzotriazolyl, 2- (2'- Hydroxy-4'-octyloxyphenyl) benzotriazolyl, 2- (3 ', 5'-1,2-tert-pentyl-2, monohydroxyphenyl) benzotriazolyl, 2-a (3, , 5, One pair one ("," -dimethylbenzylmethyl) -Z, printed by the Ministry of Justice Central Standard Jujube Bureau Zhen.T Consumer Cooperatives ( Read the notes on the back before filling out this page) Monohydroxyphenyl) benzotriazolyl, 2 — (3′-tert-butyl- 2′-hydroxy-5 ′-(2-octyloxycarbonylethyl) ) Phenyl) 5-chloro-benzotriazolyl, 2- (3'-tert-butyl- 5 '-[2- (2-ethylhexyloxy) -ethyl]-2T-hydroxybenzene A) 5-chloro-benzotriazolyl, 2- (3'-tert-butyl- 2'-hydroxy ~ 5, 1 (2-methoxycarbonylethyl) phenyl) -5-chloro Daiichiben-55- This paper is in the size of Shizhou China National Standard (Factory Milk) 8 4 specifications (210 '/ 297 mm) Ministry of Economic Affairs Central Standard Date Bureau Shellfish Consumer Cooperatives Seal 491871 A7 B7 V. Description of the invention (Θ) bistrisalyl, 2- (3'-tert-butyl- 2'-yenyl-5,-(2rmethoxycarbonylethyl) phenyl) benzotriazolyl, 2- (3 , 1-tert-butyl-1 -hydroxy-5,-(2-octyl-oxycarbonylethyl) benzyl) benzotriazolyl, 2-(3, 1-tert-butyl-5, 1-2- (2-ethylhexyloxy) carbonylethyl]-2 '- Phenyl) benzotriazolyl, 2- (3, dodecyl-2,1-hydroxy-5, monomethylphenyl) benzo-triazolyl, and 2- (3,1-tert- Butyl-1 2'-hydroxy-5 # — (2-isooctyloxycarbonylethyl) phenylbenzotriazolyl 2,2, 1-methylene-bis [4 1 (1, 1, 3, 3 — A mixture of tetramethylbutyl) -6-benzotrisialyl-2-yl]; 2- [3'-tert-butyl-5 '-(2-methoxycarbonylethyl)-2' Mono-hydroxy-phenyl]-2H-benzotriazolyl and the esterification product of polyethylene glycol 300, [R -CH2 CH2 — COO (C Η 2) 3] 2 — where R = 3, mono-tert-butyl -4'-hydroxy-5, 2H-benzotriazolyl-2-ylphenyl, 2- [2'-hydroxy-3 / 3-(oc, oc-dimethylbenzyl)-5 '- (1,1,3,3-tetramethylbutyl) monophenyl] benzotriazole; 2-[2 '-hydroxyl-3'-(1,1,3,3-tetramethylbutyl) -5, ((α, α-dimethylbenzyl) -phenyl] benzotriazole. 2 ♦ 2 · 2-Hydroxybenzophenone, for example, 4-monohydroxy, 4-monomethoxy, 4-octyloxy, 4-decyloxy, 4-dodecyloxy '4-benzyloxy , 4,2,4,4-trihydroxy and 2'-hydroxy-4,4'-dimethoxy derivatives. -56- ^ Paper size Chinese national standard >: (: milk) 8 4 size (210, / 297 mm) (Please read the precautions on the back before filling this page) Printed by Trade.X Consumer Cooperative 491871 A7 B7 V. Description of the Invention (4) 2 · 3 · Ester of substituted or unsubstituted benzoic acid, such as 4-t-butyl-phenylsalicylate * phenyl water Salicylate, octylphenyl salicylic acid, dibenzophenanthrene resorcinol, bis (4-tert-butylbenzylhydrazone) resorcinol, benzophenorylresorcinol, 2, 4 1,2-tert-butylbenzyl 3,5-di-tert-butyl-4-hydroxybenzoate, cetyl 3,5-di-tert-butyl-4-hydroxybenzoate · Octadecyl 3,5-di-tert-butyl-4-hydroxybenzoate, 2-methyl-4,6-di-tert-butylphenyl 3,5-di-tert-butyl -4 monohydroxy monobenzoate 0 2 · 4 ♦ Aromatic esters, such as ethyl α-cyano-1 / 3, / 3-diphenylacrylic acid, isooctyl α-cyano-3, 2 Monophenyl acrylate, methyl oc —carbomethoxycinnamate, Methyl α-cyano-fluorene, / 3-methyl-ρ-methoxy-cinnamate, butyl α-cyano point, > 9-methyl-P-methoxy-cinnamate, methyl α-Carboxymethoxy-ρ-methoxycinnamate and N-(> 9-Carbonmethoxy-1 / 9-cyanovinyl) -2-methylindole_〇2 · 5 ♦ Nickel compounds · For example 2,2'-thio-bis-one [4-((1,1,3,3-tetra-methylbutyl) phenol] nickel complex, such as 1 · 1 or 1: 2 complex With or without additional reactive groups * like η-butylamine, triethanolamine or η-cyclohexyldiethyl 'enzyme amine, nickel dibutyldithiothiocarbamate, 4 monohydroxy-3,5 -Nickel salts of mono-alkyl esters of di-tert-butyl benzylphosphonic acid, such as methyl or ethyl esters, nickel complexes of oxime, such as 2-hydroxy-4, 4-methylphenyl undecyl Ketooxime, 1-57- This paper size is applicable to the Chinese storehouse standard (CNS) Λ4 specification (210 × 297 mm) (Please read the precautions on the back before filling out this page) 491871 A7 B7 β) Central Ministry of Economic Affairs Ordnance Consumer Cooperative Prints Phenyl-4, Laurel-I-5 Monohydroxypyrazolyl Nickel Compounds > With or Without Additional Reacting Groups 0 2 6 • St eri C ally hind er ed ami ne S) • For example bis (29 2% 6 »6-tetramethyl monopiperidinyl) sebacate > bis (2 2 1 6 $ 6 tetramethyl-piperidyl) succinate > Bis (1% 2 f 2 1 6 6 pentamethylpyridyl) sebacate > Bis (1 9 2 $ 2 $ 6 $ 6 pentamethylpiperidinyl) η monobutyl-3 $ 5 1,2 tert-butyl- 4 hydroxybenzyl malonate t 1-(2-hydroxyethyl)-2 f 2, 6 »6-tetramethyl-4-hydroxypiperidine butane Acid Concentrates $ N $ N f One bis (2 > 2 f 6 $ 6 Tetramethyl- 4 -piperidinyl) Methylenediamine and 4 -tert-octylamino-2 $ 6 — Di Chloro — 1 > 3 t 5 monotriazine 9 tri — (2 $ 2 > 6 9 6 tetramethyl 4 1-Pyridinyl) > Four (2 f 2 $ 6 $ 6 Tetramethyl- 4-Piperidinyl) 1 1 2 9 3 f 4 Monobutane-tetracarboxylic acid ester $ 1 9 1 t — ( 1 $ 2 monoethanediyl) bis (3 3 9 5 $ 5 tetramethylpiperazinone) 4 monobenzyl — 2 $ 2% 6 > 6 tetramethylpiperidine 5 4 — stearin Methoxy- 2 $ 2 f 6 9 6 tetramethylmethylpyridine 9 bis (1 2 t 2 6 f 6 penta-methylpyridyl)-2-η-butyl-2-(2-hydroxy- 1 3 9 5 — Di-tert-butylbenzyl) malonate 9 3 — η-octyl-7 > 7 $ 9 9 9 one tetra (methyl-1 9 3 dream 8 — diazaspiro C 4 • 5] Sebacin 2 t 4 —dione 9 bis (1 monooctyloxy 2 9 2 V 6 > 6 — tetra-methylpyridyl) sebacate 9 bis (1 monooctyl Alkoxy-2 $ 2 9 6 $ 6 Tetramethylpyridinyl) -58- --------- P, (Please read the notes on the back before filling in this I), ιτ -line This paper size applies to China National Standard Net (rNS) Λ4 regulations (210X 297 mm) 491871 A7 B7 Printed by the Shell Department Consumer Cooperative of the Central Bureau of Standards of Didi Ministry. 5. Description of the invention. Concentrate of 6 —tetramethyl-1, 4-pyridinyl) hexamethylenediamine and 4-monomorpholino-2,6-dichloro-1,3,5-triazine, 2-chloro-4, 6-bis (4-a-n-butyl-amino-2,2,6,6-tetramethylpyridinyl) -1,3,5-triazine and 1,2-bis (3-aminopropylamino) ) Concentrate of ethane, 2-chloro-4 * 6-di (4-a-n-butylamino-1,2,2,6,6-pentamethylpyridinyl) -1,3, 5-triazine and 1,2-bis (3-aminopropylamino) ethynyl, 8-ethynyl-3-dodecyl-yl-7,7,9,9-tetramethyl-1, 3,8-triazapyrene [4 * 5] decane-2,4-dione, 3-dodecyl-1 1- (2,2,6,6-tetramethyl-1,4-meridinyl ) Pyrrolidine-2,5-dione, 3-dodecyl-1 1- (1,2,2,6,6-pentamethyl-4 piperidinyl) pyrrole A mixture of alkane-2,5-dione, 4 hexadecyloxy and 4 octadecyloxy-2,2,6,6-tetramethylmethylpyridine, 1 ^, 1 ^ / one double one Condensation products of (2,2,6,6-tetramethyl-4 piperidinyl) hexamethylene diamine and 4 cyclohexylamino-2,6-dichloro-1,3,5-triazine, 1,2-bis (3-aminopropylamino) ethane and 2,4,6-trichloro-1,3,5-triazine and 4-monobutylamino-2,2,6,6 — Condensation product of tetramethylpyridine (CAS Reg.'No. [1 3 6 5 0 4-9 6 -6]); N — (2,2,6,6 —tetramethyl-4pyridinyl ) -N-dodecyl succinimide, N — (1,2,2,6,6-pentamethyl-4 4-pyridinyl) -n-dodecyl succinimide-59 -_________-- (Please read the notes on the back before filling out this page)

The paper size of V and 11 papers is suitable for Sichuan National Standards (rNS) Λ4 specification (210X 297 mm) ^ 71 ^ 71 Printed by Wujing Dibei Bid Bureau, Beigong Consumer Cooperative Co., Ltd. Α7 Β7 Description of Invention (呌) Amine, 2-undecyl-7,7,9,9, tetramethyl-1, 1-oxyfluorene ~ 3,8-diazine-4, 4-oxy-spiro [4 · 5] decane, 7, 7, The reaction product of 9,9-tetramethyl-1,2-cycloundecyl-1, 1-oxa-3,8-diazine 4-oxospiro [4 · 5] decane and epichlorohydrin * 1,1 One bis (1,2,2,6,6-pentamethyl-4 4-pyridinyloxycarbonyl) one 2- (4-methoxyphenyl) ethylene, Ν, Ν '-bis-methyl phenyl-N , N, a bis (2,2,6,6-tetramethyl-1,4 pyridyl) hexamethylene diamine, 4 methoxy-methylene-malonic acid and 1,2,2,6, Diester of 6-pentamethyl-4 4-hydroxypiperidine, poly [methylpropyl 3 -oxo-4 1 (2,2,6,6-tetramethyl-4 piperidinyl) silane * cis Butadiene-α-olefin copolymer and 2,2,6,6-tetramethyl-1,4-aminoamine spray or 1,2,2, The reaction product of 6,6-pentamethyl-4aminoamine. 2 * 7 * ethylenediamine diamine, such as 4,4'-dioctyloxyoxopanidine, 2,2'-dioctyloxy-5,5'-di-tert-butoxy-amidine Tefaniline, 2,2'-docosadecyloxy-5,5,1-t-tert-butoxyfluortanilide, 2-ethoxy-2'-ethoxyfluortanilide, Ν, Ν ' A bis (3-dimethylaminopropyl) ethylenediamine diamine, 2 monoethoxy-5-tert-butyl-1 2'-ethoxyfluorethiline and 2 monoethoxy-2, A mixture of monoethyl-5,4'-di-tert-butoxyanilide and a mixture of ortho- and meta-methoxydisubstituted oxotetanil, and 0- and P-ethoxy One or two substituted oxotetanil. 2-8 * 2- (2-hydroxyphenyl) -1,3 · 5-triazine, Example-60- This paper size is the China National Standard (CNS) Λ4 specification (210X 297 mm) (please first Read the notes on the reverse side and fill in this page.) Consumers' cooperation with the Central Bureau of Jujube, Didi Ministry. Printing 491871 A7 B7 V. Description of the invention (today) Such as 2, 4, 6 — Trinity (2 — hydroxy 1 4 1 Octyloxymonophenyl) -1; 3,5-triazine, 2- (2-hydroxy-44-octyloxyphenyl) -4,6-bis (2,4-dimethylbenzene Yl) -1,3,5-triazine, 2- (2,4-dihydroxyphenyl) -4,6-bis (2,4-dimethylphenyl) -1,2,3,5-triamidine 2,4-bis (2-hydroxy-4-propyloxyphenyl) -6- (2,4-dimethylphenyl) -1,3,5-triazine, 2- (2-hydroxy -4-octyloxyphenyl) -4,6-bis (4-methylphenyl) -1,3,5-triazine, 2- (2-hydroxy-4dodecyloxy Phenyl) -4,6-bis (2,4-dimethylphenyl) -1,3,5-triazine • 2-[2-Hydroxy-4 1 (2 Hydroxy-3-butyloxy-propoxy) phenyl] -4,6-bis (2,4-dimethyl) -1,3,5-triazine, 2- [2-meryl-4 Mono (2-Cycloyl-3-octyloxy-propyloxy) phenyl] -4,6-bis (2,4-dimethyl) -1,2,3,5-triazine, 2- [ 4 (dodecyloxy / tridecyloxy 2-hydroxypropoxy) 2- 2-hydroxy-phenyl]-4, 6 bis (2, 4- dimethylphenyl)-1, 3 * 5 -triamidine, 2-[2-hydroxy-4-((2-hydroxy-3-dodecyloxy-propoxy) phenyl]-4,6-bis (2,4-dimethyl Phenyl) -l, 3,5-triazine, 2- (2-hydroxy-4-hexyloxy) phenyl-4,6-diphenyl-l, 3,5-triazine, 2- (2 -Hydroxy-4 monomethoxyphenyl) -4,6-diphenyl-1,3,5-triazine, 2,4,6-di [2 —Cyclo-4— (3-butoxy 1 2 —Jingji-61- This paper size is suitable for China National Standard Apple (('Milk) 8 4 Specification (210' / 297mm) --------- IP— (Please read the Precautions Complete this page)

, 1T line printed by the Central Bureau of Standards, Machining and Consumer Cooperatives of Didi Ministry 491871 A7 B7 —__ V. Description of the invention (8) Propoxy) phenyl] -1,3,5-triazine, 2 — (2-hydroxy Phenyl) -4 4- (4-methoxyphenyl) -6-phenyl-1,3,5-triazine, 2- {2-hydroxy-1 4- [2-ethylhexyl-1 (Monooxy)-2 -propylpropyloxy] phenyl} -4,6-bis (2,4-dimethylphenyl)-1,3,5-triamidine. 3, metal deactivated fluorene, such as N, N, diphenylethylene dihydrazine diamine, N-Jialyl-N, salicylhydrazine, N, N, bis (salicylidene) hydrazine, N , N′-bis (3,5-di-tert-butyl-4-hydroxyphenyl-propanesulfonyl) hydrazine, 3-salicylamidoamino-1,2,4-triazole, bis (benzylidene) Ethyl hydrazone, hydrazone, acetanilide, isopeptide fluorenyl, hydrazone, sebacium bisphenyl hydrazone, Ν, Ν *-bis acetamidine hexamethylene dihydrazone Hydrazine, N, N 'one pair (salicylidene) ethylenedihydrazine hydrazine, N, N' one pair (salicylidene) thiopropylhydrazine dihydrazine. 4 ♦ Phosphites and phosphonates, such as triphenylphosphite, diphenylalkylphosphite, phenyldialkylphosphite, tris (nonylphenyl) phosphite, trilauric acid Diphosphite, tris-octadecylphosphite, distearyl pentaerythritol-^-o-phosphite * dione (2,4-di-tert-butylphenyl) phosphite, diisodecyl Dipentaerythritol diphosphite, bis (2,4-di-tert-butylphenyl) pentaerythritol di (phosphite, bis (2,6-di-tert-butyl-4-methylphenyl)- Pentaerythritol diphosphite, diisodecyloxy pentaerythritol diphosphine phosphonium, bis (2,4 t-butyl t-butyl-6-methylphenyl) pentaerythritol diphosphite, -62- The paper size is 14 Sichuan China National Standard Cold (CNS) Λ4 specification (210X 297 mm) ~ --------- P, (Please read the precautions on the back before filling this page) Printed by the Central Bureau of Standards only for the Consumer Cooperative 491871 A7 B7 V. Description of the invention (5Ί) Bis (2,4,6-trione (tert-butylphenyl) pentaerythritol diphosphite? Trihard醢 Sorbus glycosyl triphosphite, four (2,4,12-tert-butylphenyl) 4,4'-biphenylene diphosphonate, 6-isooctyloxy-2,4,8 10, tetra-t-tert-butyl- 1 2H-diphenyl [d, g] -1,3,2-dioxane, 6-fluoro-2,4,8,10-tetra-t-tert-butyl 12-methyl-diphenyl [d, g] -1,3,2-dioxetine, bis (2,4-di-tert-butyl-6-methylphenyl) methyl phosphite Esters, bis (2,4,2-tert-butyl-6-methylphenyl) ethylphosphite, 2,2 ', 2'-nitroazine [triethylbis (3,3', 5 , 5,4-tetra-t-butyl-1,1'-biphenyl-2, -diyl) phosphite], 2-ethylhexyl (3,3 ', 5,5,4-tetra-t-tert Monobutyl-1,1'-biphenyl-2,2'-diyl) phosphite. 5-Hydroxylamines, for example, N, N-dibenzylhydroxyamine, N, N-diethylhydroxyl Amine, N, N-dioctylhydroxylamine, N, N-dilaurylhydroxylamine, N, N-di (tetradecyl) hydroxylamine, N, N-di (hexadecane) ) Hydroxylamine, N, N-bis (octadecyl) hydroxyamine, N-hexadecyl-N-octadecylhydroxyamine, N-hexadecyl-N-octadecylhydroxyamine, N, N-dimethylamino via hydrogenated tallowamine. 6 · Nitroketones, for example, N-benzyl-cx-phenyl-nitronone, N-ethyl-α-methyl-nitrofluorene, N —Octyl—cx —Heptyl—Nitrofluorene 'N —Lauryl—CX —Undecyl Mononitrone, N —Tetradecyl —α — Thirteen Houses — 63 — Paper scale description; National Standard Bei (("5) 8 4 specifications (210: / 297 mm --------- · 1, (Please read the precautions on the back before filling in this page)) Printed by the Industrial and Consumer Cooperatives 491871 A7 __ B7__ V. Description of the invention (#) N-hexyl-, N-h hexaalkyl-α-h-pentyl-nitronone, N-h octyl-α-ten Heptadecyl-nitronone, N-hexadecyl-α-heptadecenyl-nitrazine I, Ν--h octadecyl-α-h pentadecyl-nitrazine · Ν-heptadecyl One ex-· h heptyl mononitrone, N-octadecyl-a--h hexaalkyl mononitrone, derived from hydrogenated cattle The amine N, N - dialkyl hydroxylamine nitrate Si. 7. Thio synergists, for example, dilauryl thiodipropionate or distearyl thiopropionate. 8. Peroxide cleaners, such as / 3-thiodipropionic acid esters, such as lauryl, stearyl, tetradecyl or tridecyl esters, hydrothiobenzoxazolyl, or 2-hydrogen Zinc salt of thiobenzimidazole, zinc dibutyl dithiocarbamate, octadecyl disulfide, pentaerythritol tetraol, four (/ 3-dodecyl hydrogenthio) propionate . 9. Polyamide stabilizers, such as copper salts combined with iodide and / or phosphorus compounds, and toilet articles of divalent manganese. 10 ♦ Basic co-stabilizers, such as * melamine, polyvinylpyrrolidone, dicyandiamide, tri-allyl cyanurate, urea derivatives, hydrazine derivatives, amines, polyamides, polyurea Alkane, higher fatty acid alkali metal or alkaline earth metal phosphonium salts * For example, calcium stearate, zinc stearate, magnesium succinate, magnesium stearate, sodium ricinole and potassium hexadecanoate, pyrocatechin Antimony acid or coke, zinc catechin. 11. Nucleic acid agents, for example, inorganic substances, like talc, metal oxides, like magnesium oxide * or magnesium oxide * phosphates, carbonates or sulfates of preferred alkaline earth metals; organic compounds, like mono- or polycarboxylic acids And its salts, such as, -64- This paper size is suitable for Chinese national standard ((, NS) Λ4 size (210X 297mm) --------- P! (Please read the note on the back first) Please fill in this page again) Order printed by the Ministry of Economic Affairs and the Ministry of Economic Affairs, printed by the Bureau of Work and Consumer Cooperatives 491871 A7 B7 V. Description of the invention (β) 4 Mono-tert-butylbenzyl, adipic acid, diphenylacetic acid, butyl Sodium diacid, or sodium benzoate; polymer compounds, like ionic copolymers (ionomers) ° 12 · Fillers and reinforcing agents, such as calcium carbonate, silicates, glass fiber * asbestos, talc, high-sensitivity clay, Mica, barium sulfate, metal oxides and hydroxides, carbon black, graphite, wood powder and other powders or fibers of natural products, synthetic fibers. 1 3 ♦ Other additives, such as plasticizers, lubricants, emulsifiers , Colorants, flow additives, ® media, flow control agents , Optical brighteners, fire retardants, antistatic agents and blowing agents 〇14 · benzofuranone and indone, for example, described in US-A-4, 3 2 5, 8 6 3; US + 4, 338,244, US-A-5, 175,313; US-A- 5,2 1 6, 0 5 2, US-A-5, 252,643, DE + 4, 316,611; DE-A- 4, 3 1 6, 6 2 2; DE-A- 4, 3 1 6, 8 7 6; EP-A-0,589,839 or EP-A-0,591,102 or 3 — [4-one (2-ethoxyethoxyethoxy) Phenyl] -5,7-di-tert-butyl-benzofuran-2-one, 5,7-di-tert-butyl-3- 3- [4-stearyl-2-ethoxyethoxy ) Phenyl] benzofuran-2-one, 3, -bis [5,7-di-tert-butylbutyl 3-(4-[[2-hydroxyethoxy] phenyl) benzofuran 2- Ketone], 5,7-di-tert-butyl- "3- (4-ethoxyphenyl) benzofuran 2-ketone, 3- (4-ethylacetoxy-3,5-dimethyl Phenyl) -5,7-di-tert-butyl-benzofuran-2-one, 3- (3,5-dimethyl-4,4-trimethylacetoxy) -65- paper size China National standard ((, NS) Λ4 specifications (2 丨 0 X 297 mm) (Please read the precautions on the back before filling out this page) Order line 1 Printed by the Military Industry Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs ~~ _ ? z__ i, & Description of Invention (&. ) ~ 5 »7-Di-tert-butyl-benzofuran-2-pyrene, 3- (3,4 dimethylphenyl) -5,7-di-tert-butylbenzofuran-2 Ketone, 3- (2,3-dimethylphenyl) -5,7-di-tert-butyl-benzylfuran- 2-fluorene. The ratio of the product or the mixture of the present invention to the traditional additives may be, for example, 1: 1. 5 to 1: 5. The product or the mixture of the present invention may also be used as a spike fixative, especially as a light-determining agent, such as for example Some photoreprints and other conventional materials in the field of reprinting techniques are described in Research Disclosure 1990, 31429 (pages 474 to 480). The present invention will be illustrated in more detail by the following examples * All percentages are calculated by K weight unless otherwise specified. In the structure of the following example chemical formula, η # represents the number of repeating units in the molecule and the resulting product is not uniform. The intermediate disclosed in Example 1A is characterized by a number average molecular weight Mη and a polydispersity Mw / Mn. GPC (Gel Permeation Chromatography) was used as the analytical step to separate molecules of different sizes and obtain the average molecular weight (Mw, Mη) and the molecular weight distribution of the polymer. This technique is well known and is described in, for example, "M 0der η Size-Exclusion Liquid Chromatography", edited by WW Yan et al. Et al., J. Wiley & Sons, NY · USA, 1 9 7 9 published, pages 4-8, 249-283 and 3 1 5-340〇-66_ > Paper size Hfl China National Standard ((: NS) Λ4 specification (210X 297 mm) " --------- f (Please read the notes on the back before filling in this page)

Once the 1T line is passed by the Central Ministry of Economic Affairs, the Ministry of Education, and printed by X Consumer Cooperatives ^ ^ 1871 A7 _B7 ^ _ V. Description of the Invention U |) The GPC analysis in the following example is performed in an HPLC instrument, Model ® TSP AS-1000 The device has a UV UV 100 UV / VIS detector with a wavelength of 250nm. The column used is 〃 GPC — SS — 250x7 * 7mmx3 / 8〃, Valco-Microgel-3 mixed glue. The eluent was tetrahydrofuran (flow rate: 1 ml / min)-Uvaso 1 (® Mer ck-1 · 0 0 0 1 6) + 0 · 02 dethanol / liter diethanolamine (® Fluka 31590) for spectral analysis . 0 · 5 g of sample was dissolved in 100 ml of eluent. The injection volume was 20α / 1 and the chromatographic time was 15 minutes. Example 1: A) Preparation of a compound of formula

In a solution containing 221 ♦ 2 grams (1.2 moles) of cyanuric chloride dissolved in 1 286 grams of xylene, under stirring and nitrogen atmosphere. • At -6 7-This paper applies Chinese national standard. ((, NS) Λ4 specifications (210X 297 mm) (Please read the precautions on the back before filling out this page) -5-¾ Line 491871 Printed by Hezhu Co., Ltd. V. Description of the invention (t >) 254 · 8 g (1 · 2 moles) of N-(2, 2 · 6, 6-tetramethyl-4-1-Phenyl)-1-1 D are added within 2 hours. The base amine is kept at a temperature of about 30 * 0 * when added. A thick but still suspension can be obtained. And it is maintained at the indicated temperature for 15 minutes. Then, add one within 2 hours. A mixture containing 176 · 3 grams of NaOH 30% (% w / v) aqueous solution and 200 grams of water, maintaining a temperature of about 3 ο υ, yields a thin suspension * and maintains at that temperature for 2 ♦ 5 hours. Then * The alkaline solution was separated, and the reaction mixture was added to a solution containing 300 g of water, 355.2 g (0.9 mol) N, N '-double (2 , 2, 6 To a mixture of 6-tetramethyl-1, 4-pyridinyl) -1,6-hexanediamine and 268.3 grams of NaOH 30% (% w / v) aqueous solution, 30 grams of xylene was added and the reaction was maintained The mixture was at the above temperature for 1 hour. Next, the reaction mixture was heated to 80 ° C within 1 hour and maintained at this temperature for another 1 hour. 380 g of xylene (68-82 mouths / 200 ~ 120mbar) was distilled off under vacuum, and then Add 170 g of xylene and 200 g of water. After sealing the reactor, the M nitrogen is inert, and the reaction temperature is heated to 1 60 P in 2 hours. Maintain the mixture at 4 1 6 0 for 6 hours (5 * 4 bar pressure) After cooling to 60C, add 89 · 0 g (0.69 gram) of di-n-butylamine and 86.4 g of Na0H30% (%-6 8 _ ^ paper size Shizhou China national standard ((, NS) Λ4 specification (2 丨 0X 297 mm) (Please read the precautions on the back before filling in this page) # 1 Ordering-Consumer Consumption and Printing by Zhuzhu Private Label 491871 A7 B7 V. Description of the invention (4) w / v) aqueous solution. The reactor was closed again, and the mixture was heated to 1 6 ο υ within 1 hour and maintained at this temperature. After 4 hours (5 bar pressure). After cooling to 60o, add 1 30 g of xylene and 150 g of water, heat the mixture to 9 2¾ with stirring, and then separate the aqueous solution 0 organic phase M400 g of Washed with water twice, filtered (80 °) and concentrated under vacuum (125-230 ° F / 350-lmbar). When cooled, the molten product gives a solid product with η · ρ · (melting point) = 133-137¾. Mη (by GPC = gel permeation chromatography) = 2060 g / mol.

Mw / Mn = l · 55 GPC analysis shows the spectrum shown in Figure 1. The proportion of the main single component in the obtained product is: π 7 = 1 compound: η '= 2 compound = 1 ♦ 07: 1 η 7 = 1 compound: η, = 3 compound = 0 · 81: 1 n == 1 compound: η '= 4 compound = 0 · 99: 1 These four main single components (n' = 1), (η '= 2), (η / = 3), (11 / = 4 ) The total amount of fluorene in this polydisperse < product is 60% Φ stool ear%. B) Preparation of the compound of the following formula 6 9-This paper size is applicable to China National Standard Ocean (〇 ^) 8 4 specifications (210, / 297 mm) --------- Φ-I Note on the back then fill out this!)

1T line 491871 A7 B7 V. Description of invention (called)

(Please read the notes on the back before filling this page)

1T mechanically stirred 100 ml 4-necked flasks of Yin Tiaoyi, a consumer cooperative of the Central Standardization Bureau of the Ministry of Economic Affairs, will be filled with 4 g (0.016 mol) of A) product and 0.04 g of MoO3, And 32 ml of cyclohexane. The mixture was heated to reflux temperature, and 8.24 g (0.064 mol) of 70% tert-butyl hydrogen peroxide was added over 30 minutes. Water was collected by azeotropic distillation and refluxed for 1 hour. The reaction mixture was transferred to a mechanically searched glass pressure bottle and maintained at 130 C for 5 hours. The reaction mixture was cooled to 70 ° F, and M03 was filtered. The solution of M2g of Na2S03 in 10 ml of water was washed for 1 hour (60 ° C), the different phases were separated, and the organic phase was separated by MgS 0 4 Dry and reduce the total volume to approximately 10 ml. Solution-70- This paper size applies to Chinese National Standard (() NS) Λ4 specification (210X 297 mm) 491871 A7 B7 V. Description of the invention (β) in 50 ml of formazan (5C), filter out the precipitate And drying it °! Yield: 5 · 5 7 g Melting point range: 129-152 ^ 1 H NMR: 0 * 85-2 · 4ρργπ (composite mixture); 3 · 2-3 * 45ppm (s, broad, NCH2 ); 3.55-3 * 70ppm (s, width, NOCH); 4.9-5 * 4ppm (s, width, NCH). The ratio of protons at 3 · 2 ppm, 3 · 55ppm and 4 · 9ppm is 2: 1 : 1 〇 1 3 c NMR: 82 ppm (NOC); 16 5 ppm (triazine C). (Please read the precautions on the back before filling this page) Prepared CV 2 2 examples of CV Η Economy Printed by the Ministry of Standards and Industry Bureau He Gong Consumer Cooperative

Hn c

n H 8 〇——c This paper size is applicable to China National Standards (CNS) Λ4 specification (210X 297 mm) 491871 A7 B7 V. Description of the invention (taste) Printed by a mechanical stirrer of Zhengong Consumer Cooperative, Central Standards Bureau, Ministry of Economic Affairs In a 100 ml 4-necked flask, 4 g (0.016 mol) of the A) product, 0,04 g of MoO 3, and 32 ml of n-octane were placed. The mixture was heated to reflux temperature and 10 · 3 g (0.08 mol) of 70% tert-butyl hydrogen peroxide was added over 30 minutes. Water was collected azeotropically and held under reflux for 6 hours. Wash out Mo〇3 * Solution of K2 g of Na2SO3 dissolved in 10 ml of water and rinse for 30 minutes (60 ^) * Separate the different phases, wash the organic phase with 10 ml of saturated NaC 1 solution, and K Mg S04 was dried and then evaporated to reduce the total volume to about 10 ml. The solution was dissolved in 50 ml of methanol (5¾) * The precipitate (soft glass body) was dried under vacuum (55 υ), then pulverized by a K-mill, and then dried under vacuum. Yield: 5 · 5 3 g Melting point range: 96 — 118¾ 1 H NMR: 0.85-2 · 4ρργπ '(composite mixture); 3.15-3 * 55ppm (s, broad, NCHz); 3.65-3.9ppm ( s, width, NOCH); 4.9 to 5.4 ppm (s, width, NCH). At 3 · 15 -72- >, the paper size applies the Chinese national standard _ ((, NS) Λ4 specification (21 × 297 mm) ---------? (Please read the precautions on the back before (Fill in this page)

, 1T-line one 491871 five _I___ Printed by the Central Standards Bureau of the Ministry of Industry and Technology Co., Ltd. A7 B7 Invention description (called) ppm, the proton ratio of 3 · 65ppm and 4 · 9ppm is 2: 1: 1. 13 C NMR: 78-84 ppm (NOC, C8 Hi 7 isomer mixture); 165 ppm (triazine C). Example I: Light spike effect on polypropylene fibers 2.5 g of stabilizer of Table 1, 1 g of tris (2,4 t-butyl-butylphenyl) phosphite, 1 g of monoethyl 3 * 5-Di-tert-butyl-1, 4-hydroxybenzyl monophosphonate, 1 g of calcium stearate and 2.5 g of titanium dioxide in a slow mixer and 1 000 g of polypropylene powder (with Melt index = 12 g / 10 minutes, measured at 2 30 ° C and 2 · 16 kg) mixing. Extrude the mixture at 200 — 23 〇 • Polymer pellets can be obtained, which are then converted into fibers using a pilot-type device (® 1 eonard-Sumirago (VA), Italy), and the following Operating under conditions: Extrusion temperature: 230 — 245 * 0

Extrusion head temperature: 255-260C Stretching ratio: 1: 3 · 5 Linear density: 1 1 denier / filament, K The fiber prepared by this method was fixed on a white board, and then the temperature was 6-5 WR Weather-O- Meter (ASTM D 2 5 6 5-8 5), blackboard temperature is 6 3 υ. -73- This paper size applies to Chinese national standard (CNS> Λ4 size (210X297 mm) --------- I (Please read the precautions on the back before filling this page). Thread 491871 Printed by A7 B7, Zhengong Consumer Cooperative of Zhongjia Standard Bureau. 5. Description of the invention (0) After the sample has been exposed for various times, use a constant speed tensiometer to measure the residual toughness, and then calculate the exposure to half of the initial toughness (τ50) The time required. Table 1: T5 O (hour) stabilizer Example 1A compound 2 7 4 0 The compound of Table 1 shows good light stability in polypropylene fibers. Example II: Photo spike determination for polypropylene tape 1 g of each of the compounds in Table 2, 1 g of tris (2,4-di-tert-butylphenyl) phosphite, 0.5 g of pentaerythritol tetra [3-(3,5 -di-tert-one Butyl-1, 4-hydroxyphenyl) propionate] and 1 g of calcium stearate and 1 000 g of polypropylene powder (with a melt index of 2 · 1 (measured at 23 0 ° C and 2 · 16 kg) Mix in an accelerated mixer. The mixture is extruded into polymer granules at 200-220 and then used in semi-industrial Type device which extends made 50 thick and 2 5 m m wide tape (® L e ο n a r d - S u ία i r a g billion (V A) - 11 a 1 y), and is operated under the following conditions:. V

Extrusion temperature: 210 — 230D Extrusion head temperature: 240-260 ^ Stretching ratio: 1: 6 -74- This paper size applies to Chinese national standard date ((, NS) Λ4 specification (210X 297 mm) --- ------ (Please read the notes on the back before filling this page)

1T line M71 A7 B7 V. Description of the invention (Μ) Μ The tape prepared by this method is fixed on a white board and exposed to a 65 WR Weather-O-Meter (ASTM D 2 5 6 5 -85). The blackboard temperature is 6 3 t 0 After the sample has been exposed for various times, the residual toughness is measured using a constant speed tensiometer, and then the time required for exposure to half the initial toughness (T50) is calculated. Example of Scheduler 1 A Compound 2 T 5 0 (hours) > 19 9 0 (Please read the notes on the back before filling out this page) Printed in Table 2 by Zhengong Consumer Cooperative, Central Standards Bureau, Ministry of Economic Affairs The compound showed good light spike characterization for polypropylene tapes. Example III. Interaction of pigments in polypropylene test boards 5. 625 grams of stabilizers from Table 3, 1 500 grams Pigment Blue 15 "Flush " (50% mixed in polyethylene) and 25.875 grams Polypropylene powder (having a melt index of approximately 14, measured at 2301 and 2.16 kg) was added to a Haake internal mixer (room temperature) (Haake Buchler Rheochord System 40, using 6000 pieces of The rotation speed of 111 ^ 〇1 ^ \ 61〇 ^ is 5 RPM (revolutions per minute). A 5 kg ladle is used to seal the bowl mouth. The temperature rises to 180 and maintains it at 180 °. The total time is 30 minutes. -75- This paper wave scale is applicable to the Chinese National Standard Cold (rNS) Λ4 specification (210X 297 mm) 491871 A7 B7 V. Description of the invention () The mixture is 30 minutes under 1 8 〇 Remove and cool to room temperature. The resulting mixture "referred to as a concentrate" needs to be reused. 0 · 900 g of this concentrate "3.600 g of titanium dioxide" Flush "(50% mixture / polyethylene), and 40 500 grams of polypropylene powder (having a melt index of about 14 at 2 3 0 C and 2.16 kg Amount) was added to a Η AKE AAKE mixing bowl-shaped container, the temperature was 1 60 ¾, the twisted-knife was rotated by K20RPM, and a 5 kg ladle was used to seal the bowl mouth. The temperature rose to 170 and the RPM rose to 125. The total time is 30 minutes. The molten mixture is removed at 1 70C * and transferred to a hand-operated tool (room temperature) and a circular test plate of 1 mm x 25 mm diameter is formed. The resulting mixture is called 〃letdown〃 This test board is called 〃Lowering Material Test Board 印. Printed by the Consumers Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page). (Letdown) test panel and delta E (CIE color difference equation) without halting agent control test panel. This measurement was performed using App 1 i ed Color Systems Spectrophotometer Model CS-5 (USA). The parameters are 400-700nm-scanning, small area inspection, reaction, fluorescent D65, 10-degree observation. The above method conditions are to simulate the manufacture of pigments and stabilizers (precursors) and subsequent reduction (let-down) ) (Dilution) to the final plastic article. Higher delta E values represent pigment aggregation and poor dispersion. delta -76- This paper size applies to the Chinese National Standards (CNS) Λ4 specification (210X 297 mm) The Bureau of Standards and Standards of the Ministry of Economic Affairs printed 491871 A7 ________B7___ 5. Description of the invention (7 丨) E value 0 5 or less can not see the difference by the eyes. Table 3: Stabilizer Delta £ Compound of Example 1A 0 · 8 Example IV: Dyeing thermoplastic olefin (TPO) particles from a mixed polyolefin mixture (polypropylene containing ethylene-propylene copolymer; ® p〇1ytr〇pe τρρ

518-01, manufactured by ® A. SchuliBan, I nc ;; Akron, Ohio, US A) and the additives listed in the table below are equipped with a one-size roll of Superior® / MPM 1 " single-roll extruder (24 : 1 L / D), K temperature 2 ο ου mixed, and then cooled in a water bath. Before extrusion and molding, the additives are dry-mixed in a tumble dryer. Additive: 0.25% *) @ 110 (1 3Β (red pigment Π7, color index 65300), 0.005 X *) of pentaerythritol tetra [3- (3,5-di-tert-butyl-4-hydroxyl Phenyl) propionate] 0.05% *) tris [2,4-di-tert-butylphenyl] phosphite, 0.235 *) 2- (2, -hydroxy-3, , 5'-di-tert-pentylphenyl) benzotriazole 0.23ί *) bis (buthyloxy-2,2,6,6-tetramethyl "4-piperidinyl) decane Acid ester 0.1% *) calcium stearate, about 10 × *) talc, and -77- This paper size applies to China National Standard (CNS) Λ4 specification (210 × 297 mm) ~ ----- ---- 0-1 (Please read the precautions on the back before filling this page} Order 1491871 A7 _B7_ V. Description of the invention (>) 〇 2 × *) Examples of V-1 or V-2 compounds * ) According to the weight percentage of the polyolefin mixture, the pellets were wedged in a BOY 30 M injection molding machine at about 19 OC to make a 1. 524 mm thick, 2〃 × 2〃 test plate. The test board is fixed on a metal frame and in a ® Atlas Ci65 Xenon Arc Weather-O-meter M blackboard temperature 7 0 * 0, 0 · 55 W / m 2, 340nm, 50% relative humidity, insidious Μ Light / Dark Cycle and Water Exposure (® Society of Automotive Engineers-SAE J 1960 Test Procedure-Exterior Automotive conditions) 〇 The test board is at approximately 6 2 5 仟 intervals on an Applied Color Systems spectrometer according to AS TM D2 244 — 7 9 Reflection mode measures color change. Gloss is measured at 0 ° in ® BYK-GARDNER Haze / Gloss Meter according to ASTM D 523. The stabilized samples showed good gloss durability under UV light exposure, and good resistance to color change. (Please read the notes on the back before filling this page) ^ wi.

Line 1T Printed by the Consumers' Cooperative of the Ministry of Standards and Loss Standards Bureau -78- This paper size is in accordance with China National Standard Cold ((, NS) Λ4 specifications (210 X 297 mm) 491871

Supplementary explanation Figure 1 is the GPC analysis spectrum of the product of Example Ⅰ-a

Claims (1)

491871 Α8 Β8 C8 D8 Positive 9! · 2 * _ Supplement 1 ♦ A method for preparing a substituted 2,2,6,6-tetramethyl-4 monopyridinyl block oligomer, the method includes: 1) making a compound of formula (α) React with a compound of formula (/ 3), (Please read the notes on the back before filling this page) -dream Η-Ν-1¾-Ν-Η (β) R ΗΧ Ν——Η -utl (Mole ratio is 1 ♦ 2: 1 to 1 ♦ 4: 1) 2) Existing in the reaction product 1) The terminal group of formula (7) f -Cl (γ) Ν ~ Ν B and formula (3) Compound A-Η (δ) (Reaction Molar ratio is 2: 1 ♦ 7 to 2: 3) Reaction; Reaction 1) -1- This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 491871 A8B8C8D8 patent application scope and 2) is carried out in an organic solvent and in the presence of an inorganic base; and 3) the group of formula (G-I) will be present in the reaction 2) the product (G-I) is transformed into the group base of formula (G — I I): (Please read the precautions on the back before filling in this page) (G-II) The conversion of this line is caused by reaction 2) The product and a hydrogen peroxide in a hydrocarbon solvent and a peroxide decomposition catalyst Carry out; during reaction 1), the temperature at the beginning is from 10t: to 85, and at the end is from 1 10 ° C to 2 2 0 t; the reaction temperature of reaction 2) is from 1 1 0 t) to 1 80 0 t; reactions 1) and 2) are carried out at a pressure of 3 to 8 bar; and a group basis of formula (G-1) per mole present in the product of reaction 2). Specifications (210 X 297 mm) 491871 A8 B8 C8 D8 6. Scope of patent application 闬 2 to 8 moles of hydrogen peroxide, 0 ♦ 0 0 1 to 0 ♦ 1 mole of peroxide decomposition catalyst and 5 to 30 moles of hydrocarbon solvent; Rl is C $ —Ci 8 Fluorenyl or C 5 —Cl 2 ring radical; and Rz is C2-c6 alkylene; R is a group of formula (G — I); A is a N (R 4) (R 5); R4 and R5 (same Or different) is Ci-C8 alkyl; B is a group of formula (II); (Please read the precautions on the back before writing this page) Order Line X is> N R 6; and R s is C i -C 8 alkyl. 2 ♦ If you apply for the method of item 1 of the patent scope, where: Ruler! Is octyl or cyclohexyl, and the hydrocarbon solvent in reaction 3) is (depending on R t) octane or cyclohexane. This paper size applies to Chinese National Standard (CNS) A4 specifications (210 X 297 mm) 491871 A8 B8 C8 D8 6. Scope of patent application (please read the precautions on the back before filling this page) 3 ♦ If the scope of patent application is the first The method according to item 1, wherein the organic solvent in reactions 1) and 2) is an aromatic hydrocarbon or fatty fluorenone, and the inorganic base is sodium hydroxide or potassium hydroxide or sodium carbonate or potassium carbonate. 4 ♦ The method according to item 1 of the scope of patent application, wherein: the peroxide decomposition catalyst is a metal mineral-based compound 'metal oxide' metal acetamidine propionate or metal burnt oxide 'wherein the metal is selected from the periodic table Metals IVb, vb, VIb, IIb and VIII. 5 ♦ The method according to item 1 of the scope of patent application, wherein: hydrogen peroxide is tert-butyl hydroperoxide, and the peroxide decomposition catalyst is Μ0 3 ° 6 · — a method for determining a lower carbon number Polyolefin is a mixture resistant to degradation caused by light, heat or oxygen, containing a compound of formula (P-I) 箪, a compound of formula (P-II), a compound of formula (P-III), and a compound of formula (P-III) P — IV) Monodisperse compounds. The difference between these compounds is only the number of repeating units. D8 Patent Application Park This paper size applies to Chinese National Standard (CNS) A4 specifications (210 χ 297 mm) 491871 A8 B8 C8 D8 Patent application scope formulas (P-I), (P-II), (P-III), and (P-IV ) The total amount of the compound is 40 to 70 mol% (relative to the weight of the total mixture), and the ingredients (P-I) and (P-II) '(P-I) and (P-III) and ( The mole ratio of the compounds of P-I) and (P-IV) is 0. 6: 1 to 1, 6: 1; Ri is C5—Ci 3 alkyl or C5—Ci 2 cycloalkyl; R 2 is C · 2 — C 6 alkylene; R is a group of formula (G — II); (Please read the notes on the back before writing this page) HC CH, (G-H) Line A is a N (R4) (R 5); C 8 焼 radicals R4 and Rs (both same or different) are C B and is a (G-IV) group basis; (G-IV) This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 491871 ABB8C8D8 6. Scope of patent application (please read the precautions on the reverse side before writing this page) X is yes> NRs; and R < 5 is Ci—C8 complex 0 7 · — a composition that is stable against degradation caused by light, heat, or oxygen, including a lower carbon number polyolefin and 0 ♦ 0 1 to 5% (Relative to the weight of the lower carbon number polyolefin), as in the patent application range No. 6. 8. The composition tree according to item 7 of the patent application scope, wherein the lower carbon polyolefin is polyethylene or polypropylene. 9 ♦ A method for stabilizing lower carbon number polyolefins to resist degradation due to light, heat or oxidation, including adding 0 to 0 1 to 5% (relative to the weight of lower carbon number polyolefins) of the synthetic polymer such as Mixture for scope 6 of the patent application. 1 0 · If the method of the scope of patent application is applied, it only includes steps 1) to 3) 〇1 1 ♦ If the method of the scope of patent application is applied, the product obtained in step 2) has a degree of polydispersity Γ: / Mη values range from 1.1 to 1.7. 1 2. A kind of polyolefin for stabilizing lower carbon number to resist light, heat or -7- This paper size is applicable to Chinese National Standard (CNS) A4 (210 X 297 mm) 491871 A8 B8 C8 D8 N r 巳 N compounds, including SM — II) single IS ib compounds, 6. Mixed patented compounds that are subject to degradation due to oxidation, a formula (M—III—a IV—a) monodisperse body weight The numbers are different, and the formula (M — I — a) military points — a) monodisperse compounds, the one: bulk compounds, and the formula (M — these compounds differ only in AN (please read the note on the back first) Matters are rewritten on this page) AA ΊΓΝ N. / Ah B-VN N——RN— R c C3 H3 h3 N N 丨 H I · N Xch3 ch3 2 Ίτ—Α N H3CH3C N N 丨 H ^ A 巳 This paper size is in accordance with Chinese National Standard (CNS) A4 (210 X 297 mm) 491871 A8B8C8D8 6. Scope of patent application N (M-IV-a) YA N ^ NB 4 (Please read the notes on the back before writing this page) The reactive groups A, B, R and R 2 are as defined in item 1 of the scope of patent application, And the total amount of compounds of formula (M — I — a), (M — II — a), (M — III — a), and (M — IV — a) is 40 to 70 mole% (relative to the total mixture ), And compounds (M-I-a) to (M-II-a), (M-I-a) to (M-III-a) and (M-I-a) to (M-IV-a) The ratio of moles in the line) is 0: 6: 1 to 1 ♦ 6: 1. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)