460576 A7 ---------B7 五、發明説明（1 ) 發明背景 本發明所屦技術領域 本發明係關於一種含有高濃度界面活性劑、安定且展現 優良洗淨性能之濃厚系液體清潔劑組合物。 技術背景 經濟部中央標準局員工消費合作社印製 H. --- It. - - - 1^1 I I^-- n : . J) (請先閲讀背面之注意事項再填寫本頁) 液體清潔劑一般而言除了比粉末清潔劑具有更佳之對水 溶解性、且具有可直接塗布於沾污部分之優點外，在製造 程序方面，亦有不如粉末清潔劑般須用及乾燥設備等複雜 裝置之長處。然而’液體清潔劑卻具有粉末清潔劑所未見 之相分離、沉澱或污濁等安定性的問題，因此在其界面活 性劑之组成、鹼劑之種類及水分含量等，必須費心地加以 考慮。尤其是，（如沸石等水不溶性物質則當然如此，無 須多提），當添加其它金屬離子封鎖劑，或是以聚合物等 分散劑爲首之增藤劑物質時，此等調配方式將成爲阻害其 士疋性之原因’故而在ί周配入増條劑時需特別加以注意。 通常爲提高安定性’技藝界中已提出可添加對甲苯磺酸鹽 等增溶劑及乙二醇、丙二醇或乙醇等溶劑，但是相較於粉 末清潔劑’調配充分量之增滌劑對於液體清潔劑而言，仍 顯屬困難。 另一方面，最近的液體清潔劑多藉由增加界面活性劑濃 度及減少系統内水含量之方式，來進行可降低標準用量之 ί展縮化嘗試。但疋’此等濃厚系之液體清潔劑卻造成其本 身的調配比以往更爲困難’況且其欲大量地添加增滌劑， 亦屬不易。 本紙張尺度適用中國國家標準（CNS ) Α4規格（2ί〇χ297公釐） 經濟部中央標準局員工消費合作社印裝 /4 Ρ Ο 5 7 6 Α7 ----- Β7_ 五、發明説明（2 ) 特開平7-53993號公報曾揭示一種可安定地調配於液體 清潔劑之固體粒子；特言之，爲一種在泥污洗淨力及再附 著防止性方面極佳之增滌劑。此公報所載之增滌劑係—種 在以聚乙二醇爲主鏈之物質上與（甲基）丙烯酸及單乙晞性 不飽和單體發生接枝反應所得之高分子化合物；然而該公 報中卻全然未提及於含有高濃度非離子界面活性劑之系统 中（如非離子界面活性劑占界面活性劑之8 〇重量％以上 者），其增滌劑之性能及洗淨力如何。非離子界面活性劑 對於油污之洗淨力極佳，且較之陰離予界面活性劑又具有 較低之臨界膠微粒濃度，因此十分利於濃縮化。然而其卻 易於受到增蔽劑添加之影響，故極須開發安定性更高之增 務劑。 由上，本發明之目的在於提供一種在以非離子界面活性 劑爲主要界面活性劑而調配之濃厚系液體清潔劑中無損其 安定性’而能具有極佳之泥污洗淨性能及再附著防止性能 的液體清潔劑組合物。 本案之發明者在經過種種研究後’發現藉由調配特定高 分子化合物於含有具非離子界面活性劑之高濃度界面活性 劑的系統中’可在不損其安定性之前提下仍具備優異洗淨 力，由此完成本發明。 發明内容 亦即，本發明係提供一種 水分含量在60重量％以下之濃厚系液體清潔劑组合物， 該組合物包含：（A) 2 0 - 8 0重量％之界面活性劑，其中非 -5- 本紙張尺度適用中固國家標準（CNS ) A4規格（210X297公董） (請先聞讀背面之注意事項再填寫本頁) 訂' ς〇57 6 Α7 ________Β7 五、發明説明（3 ) 離子界面活性劑占8 0重量％以上之比例，及（B ) 0.1 -丨5重 量°/。之高分子化合物’其係令聚醚化合物之主鏈與含有丙 烯酸及/或甲基丙烯酸（甲代烯丙基酸）爲主體之單乙烯性 不飽和單體發生接枝聚合反應所得者。各成分之含量係以 組合物爲基準，而殘餘部分則爲水D 發明詳細説明 以下兹詳細説明本發明之濃厚系液體清潔劑组合物。 本發明中（A)成分之非離子界面活性劑，特言之，係以 使用聚環氧乙烷及/或聚環氧丙烷型的非離子界面活性劑 爲佳’尤以選用下列（1)_(3)中1或2種以上爲主要使用者 更佳： (1) 於碳數8-16之一級醇上加成平均5-15莫耳之環氧乙 烷後所得之聚環氧乙烷烷基醚， (2) 於碳數8-16之二級醇上加成平均5_15莫耳之環氧乙 燒（EO)後所得之聚環氧乙燒披基醚， 經濟部中央橾準局員工消費合作社印製 I I I ..... - I - I H ^ - - -I I- - n I XT 4 、τ (請先閱讀背面之注意事項再填寫本頁) (3) 於碳數8-16之一級醇或二級醇上加成平均5_15莫耳 之環氧乙烷及平均1-5莫耳之環氧丙烷後所得之聚 環氧乙貌聚環乳丙燒拔基魅。環氧乙虎與環氧丙坑 之加成順序並無特別限制’不論是嵌段聚合或無規 聚合皆可。至於使用何種物質，則係依清潔劑之用 途、目的及安定性而加以選擇。 在其它的非離子界面活性劑方面，可用如聚環氧乙規燒 基苯基醚類、蔗糖脂肪酸酯類、脂肪酸甘油單酯類、高級 脂肪酸烷醇醯胺類、聚環氧乙烷高級脂肪酸烷醇醯胺 -6 - 本紙張尺度適用中國國家標準（CNS 規格（210X297公釐） ς〇57 6 Α7 Β7 五、發明説明（4 ) 胺氧化物類及披基糖站類等。其中烷基糖苜以下式（3)所 表之烷基糖甞類爲佳： ^-(OR^xGy (a) 式中，R1爲直鏈或支鏈、碳數8-18之烷基、烯基或烷苯 基；R2爲碳數2-4之亞烷基；G爲衍生自碳數5或6之還原 糖之殘基；X爲平均値0-6之數，而y則爲平均値1-10之 數。 將此烷基糖苷以1 -1 〇重量％ (較佳爲1 · 5重量％)調配於 組合物中，即可進一步提高液體清潔劑組合物之安定性。 本發明中由於非離子界面活性劑占全部界面活性劑之 8 0重量％以上’故不僅具有洗淨力及安定性，亦極適於 濃縮化。本發明之濃厚系液體清潔劑组合物因含有高濃度 的界面活性劑，因此其黏度將很容易遭受提高。此時，爲 降低液體清潔劑之黏度’在前述（1 )_( 3 )之非離予界面活 性劑中’較佳可併用衍生自一級醇與二級醇者。 經濟部中央樣準局員工消費合作社中製 (請光閲讀背面之注意事項再填寫本頁) 本發明之濃厚系液體清潔劑组合物中，除了非離子界面 活性劑以外’亦可在界面活性劑中添加1 5重量％以下（較 佳爲1 - 1 0重量％ )之陰離予界面活性劑。陰離子界面活性 劑可使用一般清潔劑中所添加之界面活性劑，尤其是續酸 鹽型、硫酸鹽型及/或羧酸鹽型之陰離予界面活性劑。具 體而言，下列（4)-(7)中所示即爲最佳者： (4) 具有平均碳數丨〇_2〇之烷基的烷基苯硫酸鹽； (5) 具有衍生自平均碳數1〇_2〇之直鏠—級醇或直鍵二 級醇之烷基、或衍生自分支醇類之烷基，卫其i分 本紙張尺度__家標準（CNS ) 们 經濟部中央棒率局員工消費合作杜印裝 3057 6 Α7 ___ Β7 五、發明説明（5 ) 子内平均加成了 0.5-6莫耳之環氧乙烷後所得之烷基 醚硫酸鹽； (6) 具有平均碳數10-20之烷基或烯基的烷基或烯基硫 酸鹽； (7) 平均碳數8-18之脂肪酸鹽。 此等陰離子界面活性劑之對應離子可選自鈉、奸、鎂、 鈣及乙醇胺類等之陽離子及彼等之混合物。當添加前逑陰 離子界面活性劑時，係以其酸型進行調配，或亦可以添加 鹼（如乙醇胺等）之類的方法進行。 至於其它之界面活性劑方面，則可在不阻害安定性之條 件下，凋配入已知可添加於清潔劑之陽離子界面活性劑及 兩性界面活性劑。 本發明濃厚系液體清潔劑纽合物所含全部界面活性劑之 濃度，係屬2〇-80%(較佳爲30-60重量％)之高濃度。 (B)成分之咼分子化合物，係在聚_化合物之主鏈上與 以丙烯酸及/或甲基丙晞酸爲主體之單乙烯性不飽和單體 發生接枝聚合後所得之向分子化合物。其中聚醚化合物較 佳爲下式（1)所表者： Y-0 (ch2ch20)„h ⑴ 式中Y爲氫、甲基、苯基或苄基，較佳爲甲基或苯基；η 爲平均加成莫耳數，較佳爲2 _ 2〇〇之數。特別是以聚乙二 醇爲骨架，且其一端具有烷基，或是苯基或苄基等芳基者 較佳。可將特別是主鏈上有甲基或芳基者以最安定的方式 調配於本發明之濃厚性液體清潔劑组合物中。 -8 - 本紙張尺度適用十國國家標準（CNS ) Α4規格（21〇χ297公餐 I I I -- ------ - I- I. A I -I I- -----1 IK、1τ- (請先閱讀背面之注意事項再填寫本頁) 1386號專利申請案 中文說明書修正頁(88年12月） A7 B7 五、發明说明（6 ) -----—_.r -----修1 i 本年月gmz- 經濟部中央標隼局負工消費合作社印裝 在丙烯酸及/或甲基丙烯酸以外，可使用的不飽和羧酸 包括如順丁烯二酸、反丁烯二酸、亞甲基丁二酸及無水順 丁烯二酸等。本發明之高分子水溶性聚合物，係在以丙烯 酸及/或甲基丙烯酸為必要結構之化合物上加上其它的不 飽和羧酸’再將之接枝聚合於聚醚化合物後所得者。可利 用習知的自由基引發劑作為聚合起始劑。本發明所用之高 分子化合物是以將含丙烯酸及/或甲基丙烯酸之單乙晞性 不飽和單體’以最少1 / 4以上之重量比例，對作為主鏈之 聚謎化合物進行反應所得者最佳。具體的高分子化合物之 製法可為*在氮氣流下，溫度為9 0 °C以上（較佳於100-200 C之溫度下）’ 一邊攪拌聚醚化合物，一邊緩慢地分別滴 入單乙烯性不飽和單體及起始劑，即可得呈酸形式之本發 明高分子化合物.若要將之形成鹽類，則僅需在冷卻後以 氫氧化鈉等鹼劑中和之，即可輕易獲得鹽類。此外，亦可 如陰離子界面活性劑般，先以其酸形式調配，然後再於液 體清潔劑中行中和反應^分子化合物之調配比例為· 1 5重量％，較佳為〇 5 · 1 〇重量％。 么本發明 < 高分子化合物，係將含丙締酸及/或甲基丙烯 酸 < 單乙埽性不飽和單體以至少丨/4以上之重量.比例，對 作為主鏈之聚醚化合物進行反應所得者^ ，主本發明组合物之剩餘部分為水；而本發明之濃厚系液體 清潔劑中水分含量在60重量％以下時特別是即使在40 重量。/。以下時，即可得到安定的液體清潔劑。 •9- :2们公釐） I ' n n , n n 線 {讀先閲讀背面之注意事項再填寫本頁} 4^57 6 五、發明説明（7 ) 本發明之實施熊进 在不損及安定性及洗淨力之條件下，可於本發明濃厚系 液體清潔劑组合物中添加習知可調配於清潔劑之成分作爲 選擇性成分。例如，聚乙二醇、羧甲基纖維素等聚合物： 聚乙缔峨咯啶酮等變色防止劑；擰檬酸、一縮二乙醇酸、 磷酸或其鹽等金屬螯合劑；鹼性碳酸鹽、鹼金屬矽酸鹽或 規醇胺等鹼劑（也可作爲P H調節劑使用）；蛋白酶、纖維 素酶、脂酶等酵素；氣化鈣、甲酸、硼酸等酵素安定劑； 聚矽氧烷等消泡劑；乙醇等低級醇類；苯磺酸鹽、對甲苯 磺酸等低烷基苯磺酸鹽：丙二醇、乙二醇、聚丙二醇聚 乙醇等甘醇類，士息香故鹽、尿素等助溶劑；丁基經甲 苯、二苯乙烯化甲酚、亞硫酸鈉、亞硫酸氫鈉等酸化防止 劑；蒂諾帕爾CBS 半―社製）等勞光染料；藍 彩劑；一般於液體清潔劑中爲安定之習知香料；抗菌防腐 劑等。在此等選擇性成分中，丙二醇或乙二醇雖具有使濃 厚系液體清潔劑之安定性向上提高之性質，但此並不意味 須將其大量調1配；相反地，由於其對濃縮化有不利影響， 經濟部中央標準局員工消費合作社印製 故在調配時需使其濃度在2 〇重量％以下，較佳則在1 $重 量％以下。 實施例 兹於下面的實施例中説明本發明，但本發明之範圍並非 僅限於此等實施例。 合成例1 <高分子化合物（1 )之合成> 在備有溫度計、攪拌機、氮氣導入管、迴流冷卻器之玻 -10- 本紙張尺度適用中國國家標孳（CNS ) A4規格（210 X 297公釐） 經濟部中央標準局員工消費合作社印製 4^57 6 A7 j_______B7 五、發明説明（8 ) 璃叙反應器中，裝填入1〇〇重量比例、平均分子量爲1 500 之苯氧基聚乙二醇及5重量比例之順丁烯二酸，於氮氣流 中加熱之以令其溶解，在攪拌狀態下使之昇溫至1501。 然後’在保持溫度於1 5 0 -1 5 1 C的同時，分別於1小時内連 續滴入3 0重量比例之丙晞酸及4.5重量比例之二_第三丁 基過氧化物，再繼續攪拌4 0分鐘。冷卻後加入〗3 5重量比 例之純水，得高分子化合物（1 )。 合成例2<高分予化合物（2)之合成> 在備有溫度計、攪拌機、氮氣導入管、迴流冷卻器之玻 璃製反應器中，裝填入100重量比例、平均分子量爲2〇〇〇 之苯氧基聚乙二醇及1 0重量比例之順丁稀二酸，於氮氣 流中加熱之以令其溶解，在攪拌狀態下使之昇溫至1 45 °C。然後，在保持溫度於I45 -147°c的同時，分別於1小時 内連續滴入5 0重量比例之丙烯酸及2· 5重量比例之二.第 三丁基過氧化物’再繼續揽拌80分鐘。冷卻後加入150重 量比例之純水，得高分子化合物（2 )。 合成例3 <高分子化合物（3 )之合成> 在備有溫度計、攪拌機、氮氣導入管、迴流冷卻器之破 璃製反應器中，裝填入100重量比例、平均分予量爲1500 之單甲氧基聚乙二醇及10重量比例之順丁烯二酸，於氮 氣流中加熱之以令其溶解，在攪拌狀態下使之昇溫至145 °C。然後，在保持溫度於145-147X：的同時，分別於1小時 内連續滴入1 5重量比例之丙烯酸及1 ·0重量比例之二-第三 丁基過氧化物，再繼續攪拌100分鐘。冷卻後加入125重 -11 - 本紙浪尺度適用中國國家標準（CNS ) A4規格（210X297公釐） (請先閲讀背面之注意事項再填寫本頁) 訂. A7 B7 46057 6 五、發明説明（9 量比例之純水，得高分子化合物Ο)。 合成例4<高分子化合物（4)之合成> 在備有溫度計、攪拌機、氮氣導入管、迴流冷卻器之玻 璃製反應器中，裝填入1 00重量比例、平均分子量爲2000 之單甲氧基聚乙二醇及1〇重量比例之順丁晞二酸，於氮 氣流中加熱之以令其溶解’在攪拌狀態下使之昇溫至145 C。然後’在保持溫度於145_147t的同時，分別於1 ,〗、時 内連續滴入5 0重量比例之丙稀酸及2· 5重量比例之二第 三丁基過氧化物，再繼續攪拌60分鐘。冷卻後加入150重 量比例之純水，得高分子化合物（4)。 實例1 利用前述合成例所得高分子化合物（1 )-(4)及表1 -2所 示成分調配各種清潔劑组合物，再依下述方法測定保存安 疋性及泥沙再附著防止性。結果示於表卜2。 1 )保存安定性試驗 口將各組合物裝入1 〇〇毫升玻璃瓶中並密拴之，把此等樣 叩置於5 0 C及5。(：之恆溫槽中保存丨〇日。依下列基準，以 肉眼判定保存終了時各樣品之情況。 〇：無分離 '沉澱或混濁 △:略顯混濁 X :生分離、沉澱或混濁現象 2)泥沙再附著防止性能試驗 將綿製白布（金巾20〇3布）裁成10公分χ 1〇公分大 小，以5塊爲1組。在〗升的測試用清潔劑水溶液中加入園 -12- 本紙張尺度適^]目家辟（CNS仏規格（2歐㈣釐 (請先閱讀背面之注意事項再填寫本頁)460576 A7 --------- B7 V. Description of the invention (1) Background of the invention The present invention relates to a thick liquid containing a high concentration of surfactant, stable and exhibiting excellent cleaning performance. Detergent composition. Technical background Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy H. --- It.---1 ^ 1 II ^-n:. J) (Please read the precautions on the back before filling this page) Liquid cleaner In general, in addition to having better water solubility than powder cleaners, and having the advantage of being directly coated on the contaminated parts, in terms of manufacturing procedures, there are also complex devices that do not require the use of powder cleaners and drying equipment. Strengths. However, 'liquid cleaners have stability problems such as phase separation, precipitation, or turbidity that are not seen in powder cleaners. Therefore, the composition of the surfactant, the type of alkali agent, and the moisture content must be carefully considered. In particular, (such as zeolite and other water-insoluble substances, of course, no need to mention), when adding other metal ion blocking agents, or polymer additives such as dispersant led by the agent, these formulation methods will become Reasons that hinder his or her sexuality 'Therefore, special attention should be paid when formulating tinctures in Zhou. Generally, in order to improve stability, solubilizers such as p-toluenesulfonate and solvents such as ethylene glycol, propylene glycol, or ethanol have been added in the art world. In terms of agents, it is still difficult. On the other hand, most recent liquid cleaners have attempted to reduce the standard dosage by increasing the surfactant concentration and reducing the water content in the system. However, it is difficult to mix these thick liquid cleaners more easily than in the past, and it is difficult to add a large amount of detergent. This paper size applies to China National Standard (CNS) Α4 specification (2 〇297297 mm) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs / 4 Ρ Ο 5 7 6 Α7 ----- Β7_ V. Description of the invention (2) Japanese Patent Application Laid-Open No. 7-53993 has disclosed a solid particle that can be stably formulated in a liquid detergent; in particular, it is a clearening agent that is excellent in mud cleaning performance and re-adhesion prevention properties. The tackifier contained in this bulletin is a kind of high molecular compound obtained by graft reaction with (meth) acrylic acid and monoethylenic unsaturated monomer on a substance whose main chain is polyethylene glycol; however, the However, the bulletin did not mention at all the systems containing high concentrations of nonionic surfactants (such as nonionic surfactants accounting for more than 80% by weight of the surfactants). What is the performance and detergency of the detergent? . Non-ionic surfactants have excellent cleaning power for oil stains, and have a lower critical gel particle concentration than anionic surfactants, so they are very useful for concentration. However, it is easy to be affected by the addition of the shielding agent, so it is extremely necessary to develop a stabilizer with higher stability. From the above, the object of the present invention is to provide a thick liquid cleaner formulated with a non-ionic surfactant as the main surfactant without compromising its stability, and having excellent mud-cleaning performance and re-adhesion. Preventive performance liquid cleaner composition. After various studies, the inventor of this case 'discovered that by formulating a specific polymer compound in a system containing a high concentration of surfactant with a non-ionic surfactant', it can still be excellently cleaned without compromising its stability. The net force thus completed the present invention. SUMMARY OF THE INVENTION That is, the present invention provides a thick liquid detergent composition having a moisture content of 60% by weight or less, the composition comprising: (A) 2 to 80% by weight of a surfactant, wherein non-5 -This paper size is applicable to China Solid State Standard (CNS) A4 specification (210X297) (please read the notes on the back before filling out this page) Order 'ς〇57 6 Α7 ________ Β7 V. Description of the invention (3) Ionic interface Active agent accounts for more than 80% by weight, and (B) 0.1-5 weight ° /. The polymer compound 'is obtained by graft polymerization of the main chain of a polyether compound with a monoethylenically unsaturated monomer containing acrylic acid and / or methacrylic acid (methallylic acid) as a main component. The content of each component is based on the composition, and the remainder is water D. Detailed description of the invention The thick liquid cleaner composition of the present invention is described in detail below. The non-ionic surfactant of the component (A) in the present invention, in particular, is preferably a non-ionic surfactant of the polyethylene oxide and / or polypropylene oxide type. In particular, the following (1) is selected _ (3) More than one or two of them are better for main users: (1) Polyethylene oxide obtained by adding an average of 5-15 moles of ethylene oxide to a primary alcohol having 8-16 carbons Alkyl alkyl ethers, (2) Polyethylene glycol ethers obtained by adding an average of 5 to 15 moles of ethylene oxide (EO) to a secondary alcohol having 8 to 16 carbon atoms. Printed by the Bureau's Consumer Cooperatives III .....--I-IH ^----I I--n I XT 4, τ (Please read the precautions on the back before filling out this page) (3) At carbon number 8 -16 primary alcohol or secondary alcohol added with an average of 5-15 mol of ethylene oxide and an average of 1-5 mol of propylene oxide. There is no particular restriction on the order of addition of ethylene oxide and propylene oxide, either block polymerization or random polymerization. As for which substance is used, it is selected according to the use, purpose and stability of the cleaning agent. In terms of other nonionic surfactants, such as polyethylene oxide phenyl ethers, sucrose fatty acid esters, fatty acid monoglycerides, higher fatty acid alkanolamines, and polyethylene oxide higher fatty acids can be used. Alkanolamine-6-This paper size applies to Chinese national standards (CNS specifications (210X297 mm) ς 057 6 Α7 Β7 V. Description of the invention (4) Amine oxides and perylene stations, etc. Sugar alfalfa is preferably an alkyl glycoside represented by the following formula (3): ^-(OR ^ xGy (a) where R1 is a straight or branched chain, 8-18 carbon alkyl, alkenyl or Alkylphenyl; R2 is an alkylene group having 2-4 carbon atoms; G is a residue derived from a reducing sugar having 5 or 6 carbon atoms; X is an average number of 値 0-6, and y is an average number of 値 1- The number is 10. The stability of the liquid detergent composition can be further improved by blending this alkyl glycoside in the composition in an amount of 1 to 10% by weight (preferably 1.5% by weight). Ionic surfactants account for more than 80% by weight of all surfactants, so it not only has detergency and stability, but is also very suitable for concentration. The thick system of the present invention Because the body cleanser composition contains a high concentration of a surfactant, its viscosity will easily be increased. At this time, in order to reduce the viscosity of the liquid detergent, the non-isolated surfactants described in (1) _ (3) above "Medium" is better to be used in combination with primary alcohol and secondary alcohol. Employees of the Central Procurement Bureau of the Ministry of Economic Affairs, Consumer Cooperative Cooperative (please read the precautions on the reverse side and fill out this page) The thick liquid cleaner composition of the present invention In addition to non-ionic surfactants, it is also possible to add anionic pre-surfactants in an amount of 15% by weight or less (preferably 1 to 10% by weight) to the surfactants. Anionic surfactants can be used for general cleaning The surfactant added to the agent, especially the anionic surfactant of the continuous acid salt type, the sulfate type and / or the carboxylate type. Specifically, it is shown in the following (4) to (7): Best of all: (4) Alkylbenzene sulfates with alkyl groups having an average carbon number of 0-20; (5) straight-chain alcohols or straight bonds derived from an average carbon number of 10-20 Alkyl groups of secondary alcohols, or alkyl groups derived from branched alcohols Zhang Jiao__Standards (CNS) The staff consumption cooperation of the Central Bureau of the Ministry of Economic Affairs of the People's Republic of China Du Yinzhuang 3057 6 Α7 ___ Β7 V. Description of the invention (5) 0.5-6 Molar ethylene oxide was added on average Alkyl ether sulfates obtained afterwards; (6) alkyl or alkenyl sulfates having alkyl or alkenyl groups having an average carbon number of 10-20; (7) fatty acid salts having an average carbon number of 8-18. These anions The corresponding ions of the surfactant can be selected from the cations of sodium, sodium, magnesium, calcium, ethanolamine, etc. and their mixtures. When the anion surfactant is added, it is formulated with its acid form, or it can be added. Methods such as alkali (such as ethanolamine). As for other surfactants, cationic surfactants and amphoteric surfactants, which are known to be added to detergents, can be blended without hindering stability. The concentration of all the surfactants contained in the thick liquid detergent composition of the present invention is a high concentration of 20-80% (preferably 30-60% by weight). (B) The fluorene molecular compound of the component is a molecular compound obtained by graft polymerization with a monoethylenically unsaturated monomer mainly composed of acrylic acid and / or methacrylic acid on the main chain of the poly-compound. The polyether compound is preferably represented by the following formula (1): Y-0 (ch2ch20) h where Y is hydrogen, methyl, phenyl or benzyl, preferably methyl or phenyl; η It is an average addition mole number, preferably a number from 2 to 200. Particularly, polyethylene glycol is used as a skeleton, and one end thereof has an alkyl group, or an aryl group such as a phenyl group or a benzyl group. Especially those with methyl or aryl groups on the main chain can be formulated in the thick liquid detergent composition of the present invention in the most stable manner. -8-This paper standard applies to the ten national standards (CNS) A4 specifications ( 21〇χ297 Public meal III--------I- I. AI -I I- ----- 1 IK, 1τ- (Please read the precautions on the back before filling this page) Patent No. 1386 Amendment page of the Chinese manual of the application (December 88) A7 B7 V. Description of the invention (6) -----—_. R ----- Repair 1 i Month of this year gmz- Ministry of Economic Affairs Industrial and consumer cooperatives are printed in addition to acrylic and / or methacrylic acid. The unsaturated carboxylic acids that can be used include, for example, maleic acid, fumaric acid, methylene succinic acid, and anhydrous maleic acid. .Polymer water of the present invention Polymer is obtained by adding acrylic acid and / or methacrylic acid as the necessary structure to the polymer and adding another unsaturated carboxylic acid, and then graft-polymerizing it to a polyether compound. A conventional free radical can be used. The initiator is used as a polymerization initiator. The polymer compound used in the present invention is a monoethylenically unsaturated monomer containing acrylic acid and / or methacrylic acid, with a weight ratio of at least 1/4 or more, as a main chain. The best solution is obtained by reacting the polymer compound. The specific method for preparing the polymer compound can be: * Under nitrogen flow, the temperature is above 90 ° C (preferably at a temperature of 100-200 C) while stirring the polyether compound When slowly adding the monoethylenically unsaturated monomer and the starter separately, the polymer compound of the present invention can be obtained in the form of an acid. If it is to form a salt, only sodium hydroxide is needed after cooling. Salts can be easily obtained by neutralizing the alkaline agent. In addition, it can also be formulated as its anionic surfactant in its acid form, and then neutralized in a liquid detergent. The compounding ratio of molecular compounds is ·15% by weight, preferably 0.05% by weight. The polymer compound of the present invention is a mixture of acrylic acid and / or methacrylic acid and a monoethylenically unsaturated monomer to at least 丨A weight ratio of more than / 4, obtained by reacting a polyether compound as a main chain ^, the remainder of the main composition of the present invention is water; and the moisture content of the thick liquid cleaner of the present invention is 60% by weight or less Especially when the weight is below 40%, stable liquid cleaner can be obtained below. • 9-: 2mm) I 'nn, nn line {read the precautions on the back before filling in this page} 4 ^ 57 6 V. Description of the invention (7) The implementation of the present invention Xiong Jin can be added to the thick liquid cleaner composition of the present invention to adjust the cleanliness without compromising stability and detergency. The ingredients of the agent are optional ingredients. For example, polymers such as polyethylene glycol and carboxymethyl cellulose: discoloration inhibitors such as polyethylene errolidone; metal chelating agents such as citric acid, diglycolic acid, phosphoric acid or their salts; basic carbonic acid Alkali agents such as salts, alkali metal silicates or phytolamines (also used as pH regulators); enzymes such as proteases, cellulases, lipases; enzyme stabilizers such as calcium carbonate, formic acid, boric acid; polysiloxane Antifoaming agents such as alkane; lower alcohols such as ethanol; low alkylbenzene sulfonates such as benzenesulfonate and p-toluenesulfonic acid: propylene glycol, ethylene glycol, polypropylene glycol, polyethanol, and other glycols; Cosolvents, urea and other co-solvents; Butyl via toluene, stilbyl cresol, sodium sulfite, sodium bisulfite and other acidification inhibitors; Tinopar CBS semi-made) and other labor dyes; blue color agents; generally used in Among liquid cleaners are stable conventional perfumes; antibacterial preservatives, etc. Among these optional ingredients, although propylene glycol or ethylene glycol has the property of increasing the stability of thick liquid cleaners, this does not mean that it must be formulated in large quantities; on the contrary, due to its concentration It has an adverse effect. It is printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. Therefore, the concentration should be less than 20% by weight, and preferably less than 1% by weight. Examples The present invention is described in the following examples, but the scope of the present invention is not limited to these examples. Synthesis Example 1 < Synthesis of polymer compound (1) > In a glass equipped with a thermometer, a stirrer, a nitrogen introduction tube, and a reflux cooler-10- This paper is sized to the Chinese National Standard (CNS) A4 (210 X 297 mm) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 4 ^ 57 6 A7 j_______B7 V. Description of the invention (8) The glass reactor is filled with phenoxy with a weight ratio of 1000 and an average molecular weight of 1 500 Based on polyethylene glycol and 5 parts by weight of maleic acid, heated in a nitrogen stream to dissolve it, and heated to 1501 under stirring. Then 'while maintaining the temperature at 15 0 -1 5 1 C, continuously add 30% by weight of propionic acid and 4.5% by weight of bis_third butyl peroxide within 1 hour, and then continue Stir for 40 minutes. After cooling, the pure water of 3 to 5 weight ratio was added to obtain the polymer compound (1). Synthesis Example 2 < Synthesis of high-grade compound (2) > A glass reactor equipped with a thermometer, a stirrer, a nitrogen introduction tube, and a reflux cooler was charged with a weight ratio of 100 and an average molecular weight of 2000. The phenoxypolyethylene glycol and 10% by weight maleic acid are heated in a nitrogen stream to dissolve them, and the temperature is raised to 1 45 ° C under stirring. Then, while maintaining the temperature at I45 -147 ° C, continuously add 50% by weight of acrylic acid and 2.5% by weight of the dropwise within 1 hour, respectively. The third butyl peroxide 'continues to mix 80 minute. After cooling, 150% by weight of pure water was added to obtain a polymer compound (2). Synthesis Example 3 < Synthesis of polymer compound (3) > A glass-breaking reactor equipped with a thermometer, a stirrer, a nitrogen introduction tube, and a reflux cooler was charged with a weight ratio of 100 and an average dose of 1500. The monomethoxypolyethylene glycol and maleic acid in a proportion of 10% by weight were heated in a nitrogen stream to dissolve it, and the temperature was raised to 145 ° C under stirring. Then, while maintaining the temperature at 145-147X :, continuously drip in 15% by weight of acrylic acid and 1.0% by weight of bis-third butyl peroxide over 1 hour, and continue stirring for 100 minutes. After cooling, add 125 -11-This paper wave scale is applicable to Chinese National Standard (CNS) A4 specification (210X297 mm) (Please read the precautions on the back before filling this page) Order. A7 B7 46057 6 V. Invention Description (9 The amount of pure water is used to obtain a polymer compound 0). Synthesis Example 4 < Synthesis of polymer compound (4) > A glass reactor equipped with a thermometer, a stirrer, a nitrogen introduction tube, and a reflux cooler was charged with a single weight of 100 weight ratio and an average molecular weight of 2000. The oxypolyethylene glycol and 10% maleic acid are heated in a nitrogen stream to dissolve it, and the temperature is raised to 145 C under stirring. Then, while maintaining the temperature at 145-147t, continuously drip 50% by weight of acrylic acid and 2.5% by weight of the second third butyl peroxide at 1, respectively, and continue stirring for 60 minutes. . After cooling, 150 parts by weight of pure water was added to obtain a polymer compound (4). Example 1 Various detergent compositions were prepared using the polymer compounds (1)-(4) obtained in the aforementioned Synthesis Example and the components shown in Table 1-2, and the storage stability and the prevention of sediment re-adhesion were measured by the following methods. The results are shown in Table 2. 1) Storage stability test Each composition was put into a 100 ml glass bottle and tightly tied, and these samples were placed at 50 ° C and 5 ° C. (: Stored in a constant temperature bath for 〇0 days. The condition of each sample at the end of storage is judged by the naked eye according to the following criteria. 〇: No separation 'precipitation or turbidity △: Slightly turbid X: Raw separation, precipitation or turbidity 2) Test for preventing re-adhesion of sediments The cotton white cloth (Golden towel 203 cloth) was cut into a size of 10 cm x 10 cm, and 5 pieces were used as a group. Add -12 liters of test detergent aqueous solution to the paper -12- This paper is suitable for size ^] mesh Jiapi (CNS 仏 specifications (2 Euros (please read the precautions on the back before filling in this page))
、1T 經濟部中央標準局員工消费合作社印製 460576 A7 B7 試驗。 洗淨時間 清潔劑濃度 水的硬度 水溫 洗濯 五、發明説明（10 ) 藝用鹿沿紅土，用塔古特測定機依下列條件進行 <實驗條件> 1 0分鐘 0.08 % 〇 4, 1T Printed by the Consumer Standards Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 460576 A7 B7 test. Washing time, detergent concentration, water hardness, water temperature, washing time. 5. Description of the invention (10) The art deer along the red soil was performed with a Targut tester under the following conditions < Experimental conditions > 10 minutes 0.08% 〇 4
2 0°C 以流動的2 0 °C自來水洗濯5分鐘 再污染防止性’係先以自動記綠之色彩計（島津 製）測定洗淨前之原布（白布）及試驗後之污染布於4 米時之反射率，再由下式求出其再污染防止率： 、 再污染防止率（％)=(試驗後之反射率/原布之反射率）〇〇 〈％先閱讀背面之注意事項再填寫本頁j -訂. 經濟部中央標準局員工消費合作社印製 本紙張尺度遍用中國囷家標率（〇^>八4規格（2]0乂297公釐） A7 46057620 ° C Wash with running 20 ° C tap water for 5 minutes before re-pollution prevention is based on the automatic green color meter (made by Shimadzu) to measure the original cloth (white cloth) before washing and the polluted cloth after the test. The reflectance at 4 meters, and then the repollution prevention rate is calculated by the following formula: 、 Repollution prevention rate (%) = (Reflectivity after the test / Reflectivity of the original cloth) 〇 ＜〈 Read the note on the back first Please fill in this page again j-order. Printed by the Consumers' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. The paper size is commonly used in China. (Standard) (8 ^ 4) (2) 02297mm
7 B 五、發明説明（U ) 經濟部中央標準局員工消費合作社印製 表1 本 發明品 1 2 3 4 5 6 7 非離子性 界面活性劑(1) 50. 0 40. 0 40. 0 40. 0 (A) (a) 非離子性 界面活性劑(2) 50. 0 成 非離子性 fin η 分 界面活性劑(3) « 非離子性 界面活性劑(4) 60. 0 烷基糖茌 5. 0 ⑻ L A S — N a 6. 0 6. 0 8. 0 8. 0 5. 0 5. 0 成 E S 一 N a 5. 0 分 脂肪酸 1. 0 高分子化合物（1 ) 3. 0 3. 0 3. 0 3. 0 高分子化合物（2) 3. 0 ⑻. 高分子化合物（3) 2. 0 高分子化合物（4) 1. 0 聚丙晞酸制 (平均分子量5. 000) 單乙醇胺 4. 0 4. 0 4. 0 4. 0 4. 0 4. 0 4. 0 乙醇 3. 0 3. 0 3. 0 3. 0 5. 0 5. 0 5. 0 丙二醇 3. 0 3. 0 3. 0 8. 0 8. 0 "Τη. 夕廿·吖厶16. 0L 0. 5 0. 5 蒂諾帕爾CBS 0. 2 0. 2 亞硫酸鈉 0. 1 0. 1 0. 1 0. 1 0. 1 0. 1 0. 1 香料 微量 微量 微量 微量 微量 微量 微量 水 餘量 餘量 餘量 餘量 餘量 餘量 餘量 保存安定性 50T： 〇 〇 〇 〇 〇 〇 〇 5t： 0 1 〇 〇 〇 〇 〇 〇 泥沙再污染防止性 91 92 91 92 92 89 89 -14- (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（2I〇X 297公釐） 4 6 0 5 7 6 A7 B7 五、發明説明（12 ) • 表2 經濟部中央標準局員工消費合作社印裝 調配成分（重量％) 本發明品 比 較 品 8 9 1 0 11 12 13 14 非離子性" .界面活性劑⑴ 25. 0 25. 0 50. 0 40. 0 40. 0 (A) (a) 非離子性 界面活性劑(2) 10. 0 20. 0 成 分 非離子性 界面活性劑(3) 非離子性 界面活性劑(4) 烷基糖站 5. 0 (b) L A S - N a 3. 5 5. 0 6. 0 5. 0 成 E S —N a 10. 0 20. 0 分 脂肪酸 1. 0 1.0 1. 0 高分子化合物（1) 5. 0 高分子化合物（2) (B) 高分子化合物（3) 高分子化合物（4) 1.0 聚丙烯酸鈉 9 η π q Π ^ η ς (平均分子量5, 000) Urn U U. u U. j 單乙醇胺 4. 0 5. 0 4. 0 4. 0 4. 0 5. 0 5. 0 乙醇 2. 0 2. 0 3. 0 5. 0 2. 0 2. 0 2. 0 丙二醇 10. 0 1. 0 3. 0 3. 0 3. 0 3. 0 5甘彳厶16. DL 0. 2 U示亏一 if 0. 2 蒂諾帕爾CBS 0. 2 亞硫酸鈉 0. 1 0. 1 0. 1 0. 1 0. 1 0.1 0. 1 香料 微量 yihr. ι=* 微量 /ilrf. PS? 微量 微量 微量 微量 微量 水 餘量 餘量 餘量 餘量 餘量 餘量 餘量 sot: 〇 〇 〇 X 〇 X X W 付 3C 止 Ί：±· 5T： 〇 1 〇 〇 X 〇 X X 泥沙再污染防止性 90 89 74 92 82 86 80 -15- (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) Λ4規格（210X297公釐） 4 60576 A7 B7 五、發明説明（13 ) •非離子界面活性劑（1 ):工Y少铲y 120 (花王公司之商 品名，十二醇Ε Ο 11 · 7莫耳加 成物） •非離子界面活性劑（2 ) : y 7夕/ -小7 0 (曰本觸媒公 司之商品名’二級-C12、 C13醇EO 7.0莫耳加成物） •非離子界面活性劑（3 ) : /二f 7卜R - 9 (シX小7''十 ，、° >公司之商品名，卜' 〆/ _ 小 25 (C12-C15 醇 ， C12=21.7% ， 013=28.2% » C14=32.7%，C15=17.40/〇)之 EO 9.0莫耳加成物） 非離子界面活性劑（4 ):碳數1 2、平均E 0加成莫耳數 8、平均PO加成莫耳數2之聚 環氧乙燒聚環氧丙娱^燒基醚 •烷基糖苷：式（a)中R5=碳數8-16之烷基、x = 〇、 y = 1.3、G=葡萄糖殘基 • LAS-Na :碳數10-14之直鏈烷基苯硫酸鈉 • ES-Na :聚環氧乙烷烷基醚硫酸鈉（烷基碳數10_12， 平均EO加成莫耳數2.5) *脂肪酸：小十々夕L - 5 5 (花王公司之商品名，爲混合 脂肪酸，其組成爲C10 = l%、C12 = 57%、 C 1 4 = 2 2 %、C 1 6 = 1 0 %、C 1 8 = 3 %、C 1 8 : 1 = 6 %、C 1 8 : 2 = 1 % ) -16- 本纸張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公;t ) ^^^1 ^^^^1 ^^^^1 nn n^i ,τ (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 4 60 576五、發明説明（Μ Α7 Β7 (C 1 8 : η之η係表不飽和鍵結數） 亍、二予 < 彳厶16‘OL :蛋白酶（/本' /小X 4只夕六彳才 彳> 乂卜”-公司之商品名） ”示°今-七' iool :脂酶（/水/小宁4 乂夕〆彳才彳y 夕'' 只卜U •公司之商品名） 蒂諾帕爾CBS-X :日本千〆方彳年-公司之商品名，爲 螢光染料 餘量：使全體成爲100之水量 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印裝 -17- 本紙張尺度適用中國國家標孳（CNS ) Μ規格（210 X 297公釐） ，460576 第86111386號專利申請案 中文補充說明書(89年12月） 補充實施例 表3 調配成分(重量％) 本發明品 A B ㈧ ⑷ 成 分 非離子性界面活性劑(1) 40-0 25.0 非離子性界面活性劑(2) 非離子性界面活性劑(3) 非離子性界面活性劑(4) 烷基糖钻 5.0 (b) 成 分 LAS-Na ES-Na 脂肪酸 (B) 高分子化合物(1) 高分子化合物(2) 4.0 3.0 高分子化合物(3) 高分子化合物(4) 聚丙烯酸鈉 (平均分子量5,000) 單乙醇胺 3.0 3.0 乙醇 5.0 5.0 丙二醇 8.0 10.0 T 二 y If 彳厶 16,0 L 0.2 y示°7—七' 蒂諾帕爾CBS 0.2 亞硫酸納 0.1 0.1 香料 微量 微量 水 餘量 餘量 保存安定性 50°C 〇 〇 5°C 〇 〇 泥沙再污染防止性 90 89 U：\n*PE'>EN\CHL'AT\TE\B\2082B4F.D005,ven7 B V. Description of the invention (U) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 1 The product of the present invention 1 2 3 4 5 6 7 Nonionic surfactants (1) 50. 0 40. 0 40. 0 40 0 (A) (a) Non-ionic surfactant (2) 50. 0 Non-ionic fin η interface surfactant (3) «Non-ionic surfactant (4) 60. 0 Alkyl glycosides 5. 0 ⑻ LAS — N a 6. 0 6. 0 8. 0 8. 0 5. 0 5. 0 ES-N a 5. 0 points fatty acid 1.0 polymer compound (1) 3. 0 3. 0 3. 0 3. 0 Polymer compound (2) 3. 0 ⑻. Polymer compound (3) 2. 0 Polymer compound (4) 1. 0 Made of polypropionic acid (average molecular weight 5. 000) Monoethanolamine 4 0 4. 0 4. 0 4. 0 4. 0 4. 0 4. 0 Ethanol 3. 0 3. 0 3. 0 3. 0 5. 0 5. 0 5. 0 Propanediol 3. 0 3. 0 3 0 8. 0 8. 0 " Τη. Xi 廿 · Acridine 16. 0L 0. 5 0. 5 Tinopal CBS 0. 2 0. 2 Sodium sulfite 0. 1 0. 1 0. 1 0. 1 0. 1 0. 1 0. 1 Spice traces Amount of trace, trace of trace, trace of margin, margin of margin, margin of margin, margin of margin, preservation stability 50T: 10,000, 005t: 0, 1, 000, 000, sediment re-pollution prevention, 92 92 91 92 92 89 89 -14- (Please read the notes on the back before filling in this page) This paper size is applicable to China National Standard (CNS) A4 specification (2I〇X 297 mm) 4 6 0 5 7 6 A7 B7 5 、 Explanation of invention (12) • Table 2 Printed and formulated ingredients of consumer cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs (% by weight) Comparative product of this invention 8 9 1 0 11 12 13 14 Nonionic " Surfactant ⑴ 25. 0 25. 0 50. 0 40. 0 40. 0 (A) (a) Nonionic surfactant (2) 10. 0 20. 0 Ingredients Nonionic surfactant (3) Nonionic surfactant (4) Alkyl sugar station 5.0 (b) LAS-N a 3. 5 5. 0 6. 0 5. 0 into ES —N a 10. 0 20. 0 fatty acid 1. 0 1.0 1. 0 high Molecular compound (1) 5. 0 Polymer compound (2) (B) Polymer compound (3) Polymer compound (4) 1.0 Sodium polyacrylate 9 η π q Π ^ η (average molecular weight 5,000) Urn U U. u U. j Monoethanolamine 4. 0 5. 0 4. 0 4. 0 4. 0 5. 0 5. 0 Ethanol 2. 0 2. 0 3. 0 5. 0 2. 0 2. 0 2. 0 Propylene glycol 10. 0 1. 0 3. 0 3. 0 3. 0 3. 0 5 Gan厶 16. DL 0. 2 U shows a deficit if 0. 2 Tinopar CBS 0.2 Sodium sulfite 0. 1 0. 1 0. 1 0. 1 0. 1 0.1 0. 1 Amount of perfume yihr. Ι = * Trace / ilrf. PS? Trace trace trace trace water balance margin balance margin balance sot: 〇〇〇X 〇XXW pay 3C stop: ± · 5T: 〇1 〇〇X 〇XX Prevention of sediment re-pollution 90 89 74 92 82 86 80 -15- (Please read the precautions on the back before filling this page) This paper size applies to Chinese National Standard (CNS) Λ4 specification (210X297 mm) 4 60576 A7 B7 V. Description of the invention (13) • Non-ionic surfactant (1): Industrial Y shovel y 120 (trade name of Kao Corporation, dodecyl alcohol E 〇 11 · 7 Mol addition product) • Non-ionic surfactant (2): y 7 evening /- 7 0 (The trade name of this catalyst company is' Secondary-C12, C13 alcohol EO 7.0 Molar adduct) • Nonionic surfactant (3): / 二 f 7 卜 R-9 (シ X 小 7 '' Ten, ° > the company's trade name, Bu '〆 / _ small 25 (C12-C15 alcohol, C12 = 21.7%, 013 = 28.2% »C14 = 32.7%, C15 = 17.40 / 〇) EO 9.0 Moore adducts) Non-ionic surfactants (4): Carbon number 1 2, average E 0 addition Mohr number 8, average PO addition Mohr number 2 Polyethylene oxide fired polypropylene epoxy ^ Alkyl ether • alkyl glycosides: in formula (a), R5 = alkyl with 8-16 carbons, x = 〇, y = 1.3, G = glucose residues • LAS-Na: straight chain with 10-14 carbons Alkyl benzene sodium sulfate • ES-Na: Polyethylene oxide alkyl ether sodium sulfate (alkyl carbon number 10-12, average EO addition mole number 2.5) * Fatty acid: small ten days L-5 5 (Kao Corporation The trade name of the product is a mixed fatty acid whose composition is C10 = 1%, C12 = 57%, C 1 4 = 2 2%, C 1 6 = 1 0%, C 1 8 = 3%, C 1 8: 1 = 6%, C 1 8: 2 = 1%) -16- This paper size applies to Chinese National Standard (CNS) Α4 size (210 × 297); t) ^^^ 1 ^^^^ 1 ^^^^ 1 nn n ^ i, τ (please Read the notes on the back and fill in this page) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 4 60 576 V. Description of invention (Μ Α7 Β7 (C 1 8: η is the number of unsaturated bonds) 亍, 2 I < 彳 厶 16'OL: protease (/ 本 '/ 小 X 4 夕 六六 才 才 彳) > 乂 "" company's trade name "" "present-seven' iool: lipase (/ water / Xiao Ning 4 乂 夕 〆 彳 才 彳 y '' only Bu U • company's trade name) Tinopar CBS-X: Japan's Chien Fang Nian Nian-the company's trade name, the remaining amount of fluorescent dye: make The total amount of water becomes 100 (please read the notes on the back before filling out this page) Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs -17- This paper size is applicable to the Chinese National Standard (CNS) M size (210 X 297 mm) ), 460576 Chinese Patent Supplement No. 86111386 (December 89) Supplementary Examples Table 3 Formulation Ingredients (wt%) The product AB ㈧ of the present invention Non-ionic surfactant (1) 40-0 25.0 Non Ionic surfactants (2) Nonionic surfactants (3) Nonionic surfactants (4) Alkyl sugar drill 5.0 (b) Ingredient LAS-Na ES-Na Fatty acid (B) Polymer compound (1) Polymer compound (2) 4.0 3.0 Polymer compound (3) Polymer compound (4) Sodium polyacrylate (average (Molecular weight: 5,000) Monoethanolamine 3.0 3.0 Ethanol 5.0 5.0 Propylene glycol 8.0 10.0 T Diy If 彳 厶 16,0 L 0.2 y Show ° 7-Seven 'Tinopar CBS 0.2 Sodium Sulfite 0.1 0.1 Fragrance trace trace water balance Storage stability 50 ° C 〇05 ° C 〇〇Prevention of sediment re-pollution 90 89 U: \ n * PE '> EN \ CHL'AT \ TE \ B \ 2082B4F.D005, ven